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s Monsanto AROCLOR APR 1 1971 Reiint and Plartldzert for Chlorinated Rubber U Technical Bulletin 0-124 May, 1957 Monsanto Chemical Company, Organic Chamicatt Division, St. Louis 1, Mo. Introduction Monsanto produces a series of chlorinated biphenyls and polyphenyls Identified by the trademark Aroclor* for use as plasticizers and resins for chlorinated rubber base lacquers, varnishes and paints. These protective coatings are fire resistant, corrosion resistant, chemical resistant (to acids, alkalies and water), and have good electrical insulating properties. a v> MS' y 3 & s2r o' S" 3O $ r- no o When properly pigmented, these coatings have good weatherability. Chlorinated rubber films plasticized with an Aroclor grip common structural materials in strong adhesive bonds. Addition of an Aroclor improves the flexibility and life of chlorinated rubber and plastic coatings. 7e3 cr T I he formulations suggested in this bulletin are common in commercial practice. They are given as a starting point or guide in developing formulations that expand the outstanding qualities of these compounds. sl Aroclor: Monsanto Trademark. Reg. U.S. Pat. Off. The information contained in thii bulletin it, to our best knowledge, true end accurate, but ell recommendations or suggestions ere made without guarantee, since the conditions of use are beyond our control. The Morim.ito Chemical Company disclaims any liability incurred in connection with the use of these date or suggestions. furthermore, nothing contained herein shall be construed as a recommendation to use ary product in conflict with eisting patents covering any materiel or its use. 0613509 TOWOLDMON0037738 WATER_PCB-00022207 Some important applications for protective and decorative coatings plasticized with Aroclor compounds - - Wood and metal used in yachts, barges and other marine craft. Structural steel for bridges, buildings, roofs and power-lines. Structural materials at chemical plants, pulp and paper mills, textile mills, petroleum refineries and gas works for protection against acid fumes, alkalies and gas. Tank cars and other rolling stock and construc tion machinery for protection against corro sive materials and weathering. Equipment and stop-off lacquers used in elec troplating. Masonry floors and walls. Concrete swimming pools. Highway markings. Cable coatings requiring fire resistance, chemical resistance, and excellent electrical properties. Textile coatings resistant to chemicals, fire and water. -1 - . 0613510 TOWOLDMON0037739 WATER_PCB-00022208 TABLE OF CONTENTS Naming and Preparation of Aroclor Compounds.. Properties of Chlorinated Rubber General........ .................................................. . Physical______ _______ ____________ ______ Chemical Resistance............................. .......... Electrical........................................................... Mechanical........................... ............................ Thermal........................................................ . Physical-Chemical............................. ............... Viscosity Types............................................................... Solvent Compatibility.............................. .................... Formulation and Properties of Chlorinated Rubber Formulation for Aroclor Resins.................... Formulation for Aroclor Plasticizers............. Properties of Formulated Films................... Applications Alkaline-Resistant Coatings........................... Chemical-Resistant Finishes........................... Marine Finishes............................................... Emulsion Paints............................................... . Adhesives......................................................... Paper and Textile Coatings........................... Electrical Coatings______________ _______ Printing Inks..................................................... Resins for Chlorinated Rubber................................... Monsanto Plasticizers for Chlorinated Rubber......... Toxicity............................................ .............................. Shipping Information............................... ..................... Trademark Index.......... .......... ...................................... This bulletin replaces technical bulletin P-124. Page .. 3 .. 4 .. 4 .4 .. 4 .. 5 .5 .. 5 .. 5 .. 6 .. 6 .. 6 .7 .. 8 .8 .9 .9 .10 JO .10 JO II 12 12 13 TOWOLDMON0037740 WATER_PCB-00022209 Naming and Preparation of Aroelor Compound* Benzene Bubbled through molten lead Biphenyl end Terphenyl Mixture Cl, `a Chlorinated Biphenyls (,Aroelor 1200 Series) 1221,1232,1242, 1248, 1254,1260 Chlorinated Terphenyls (Aroelor 5400 Series) 5442,5460 Note: The last two digits in a numbered series refer to the degree of chlorination. Aroelor 1248 is a bi phenyl with 48 per cent chlorination. Aroelor 5460 is a terphenyl with 60 per cent chlorination. Two special mixtures are: Aroelor 4465--a 60:40 mixture (biphenyl to terphenyl) with 65 per cent chlorination. Aroelor 2565--a 75:25 mixture (biphenyl to terphenyl) with 65 per cent chlorination. The physical properties of the Aroelor plasticizers vary gradually with the degree of chlorination. At low percentages of chlorine, such as Aroelor 1221 and 1232, the compounds are clear and very,fluid. At 42 per cent they resemble vegetable oil; at 48 per cent they thicken slightly and look more like a medium-grade mineral oil. At $4 per cent chlorine, the compounds are quite viscous; if a bottle containing them is turned upside down, the bubble rises slowly to the top. At higher percentages, the biphenyls become gumlike, and a fingerprint on the surface lasts several days. Then at 68 per cent chlorine, the. range is complete; Aroelor 1268 is a white powder. The terphenyls (Aroelor 5442 and 5460) are both yellowish solids; The gradual change in physical properties often allows a processor to select a plasticizer particularly suited for his operation. For example, if he wants to dry mix the plasticizer, Aroelor 1268 could be used. It melts at higher processing temperature and can act as a solvent-plasticizer. TOWOLDMON0037741 WATER_PCB-00022210 Properties of Chlorinated Rubber "Parlon" is a mixture of two polymers with an average chlorine content of 67 per cent made by chlorin ating natural rubber. The typical properties of "Parlon" as given by the manufacturer, Hercules Powder Company, Wilmington, Delaware, are listed in Table I. Table I. Typical Properties of "Parlon" General Form as shipped...................... Color of film............................. Odor........................................... Clarity of film.......................... Taste.......................................... Moisture, per cent as shipped. White, granular powder Water white None Good None O.S maximum Physical Specific gravity.........................................................................................1.64 Specific volume, as shipped, in cubic inches per pound....................... 16.9 Bulking value, gallons per pound..........................................................0.0735 Index of refraction...................................................................................1.554 Chemical resistance to: Acids, weak.............................................................................................. excellent Acids, strong............................................................................................. excellent Alkalies, weak...........................................................................................excellent Alkalies, strong.........................................................................................excellent Salt spray................................................................................................. good Alcohols..................................................................................................... excellent Ketones......................................................................................................soluble Esters............. .................................................................... soluble Hydrocarbons, aromatic..........................................................................soluble Hydrocarbons, aliphatic...................... .................................................... good Oils, mineral....... ...................................................................................... good Oils, animal.............................................................................................. poor Oils, vegetable...................................... .................................................... poor Electrical (clear unplasKcized film*) Specific surface resistance, ohmsX 1010................................................ 2,000 Dielectric strength, volts per mil (ASTM method)..............................2,300 Dielectric constant at 25C. and 1,000 cycles..................................... 3.1 Power factor at 25C. and 1,000 cycles................................................0.0015 to 0.0030 Power factor at 25C. and 1,000 cycles, after immersion in water for 140 hours and surface wiped dry..................................0.0027 Films used in tests were laid down from a toluene solution. 0613513 | TOWOLDMON0037742 WATER_PCB-00022211 Properties, cont'd. Mechanic! (cleor unplasiicized -film*J 20-cp. type Tensile strength, pounds per square inch, dry............ .....4,270 Tensile strength, pounds per square inch, wet............................44,1,10000 Elongation, per cent, dry............................................... .... 3.6' Elongation, per cent, wet.............................................. .... 3.8 Modulus of elasticity, pounds per square inch............................. 1.4X1100*" Hardness, Sward index, per cent of glass.................... .... 90 Note: Flexibility of "Parlon" film increase? with viscosity of "Parlon" used, 1,000-cp. 4,850 4,360 3.3 3.4 -- -- Thermal (clear unplasticized film*) Burning rate.................................................................................... nonflammable Effect of dry heat on film........................................................... stable up to and at 125C. Softening point................................................................................ decomposes at 135 to 150C. Physical-Chemical (clear unplasticized film*) Effect of sunlight........................................................................... Discolors and embrittles Effect of aging................................................................................Very slight Effect of hot water........................................................................Blushes Effect of cold water...................................................................... None Moisture absorption (80# relative humidity for 24 hours), * per cent...................................................................................... 0.27 Moisture vapor permeability of 0,003-inch film (grams water/ square centimeter/0.01 centimeter/hour at 21C.).............0.2X10* Viscosity Types Viscosity Type 5 cp......... 10 cp......... 20 cp......... 12S cp......... 1,000 cp......... Table II. "Parlon" Viscosity Types Viscosity Range (eentipoises) ..... S to 7 8 to 12 .... 16 to 25 110 to 190 800 to 2,000 Examples of actual or suggested applications of the several viscosity types are given below: Type Example of Use 5 cp. In printing inks and as a fortifier for alkyd resin enamels. 10 cp. In high-solids finishes and as a fortifier for alkyd resin and oleoresinous varnishes and enamels. 20 cp. As a film-former in protective coatings andas a fortifier in enamels and varnishes. 125 cp, As a film-former in protective coatings, in paper lacquers, adhesives, and textile finishes. 1,000 cp, As a film-former in adhesives, textile finishes and other finishes where flexibility is important. Pilms used in teste were laid down from a toluene solution. Ob TOWOLDMON0037743 WATER PCB-00022212 Solvent Compatibility Solvents and solvent mixtures suggested for use in preparing formulations with Aroclor and "Parlon" are given in Table III: Table 1(1, Suggested Solvents for Compositions with Aroclor and "Parlon" "Amsco Solv/' B and E Amyl acetate Butyl acetate Carbon tetrachloride "Cellosolve" Diacetone alcohol Diethyl carbonate Ethyl acetate Ethylene dichloride Hi-Flash naphtha Methyl acetate Xylene Methyl ethyl ketone Methyl isobutyl ketone Methyl salicylate Notol Octyl acetate "Sovasol"*Nos. 74, 75 "Solvesso 100" "Tollac" Toluene "Union Aromatic Solvent" 3553-10 "Union Solvent No, JO" Formulations and Properties of Chlorinated Rubber Chlorinated Rubber Films Aroclor 1262 and 5460, resinous types, show good compatibility in chlorinated rubber films laid down from toluene solution containing 20 per cent of the plastic in ratios of 2:1 and 1:1 ("Parlon" to Aroclor). The plasticiser types, Aroclor 1242, 1254 and 1260, also show good compatibility. Formulations and properties of films derived from both resin- and plasticizer-type Aroclor are listed below. Table IV. Formulations for Aroclor Resin Ingredient Parts by Weight "Parlon," 20-cp........................ ................... 16 fiAroclor 5460............................. .................... ...........Dibutyl phthalate.................... - 16 16 12 12 8 8 12 12 4 --- 3 Tung oil, Thermolyzed, 976...,.................... - - 5 ---- Xylene or butyl acetate.............................. 76 72 71 76 73 12 12 3. 72. Table V. Formulations for Aroclor Plasticizer Ingredient "Parlon," 20-cp........................ .................... 20 Aroclor 1254 or 1260.................................. 4 Xylene........................................ .................... 76 Parts by Weight 20 7 73 20 20 70 0613515 TOWOLDMON0037744 WATEFLPCB-00022213 Films cast from these lacquers show improved characteristics due to Aroclor. Some of their advantages are listed below: Adhesion Unplasticized chlorinated rubber films have very poor adhesion, The lacquer film containing Aroclor 5460 gave good adhesion to aluminum, bare steel, primed steel, galvanized iron and "Transite" surfaces. Othei commercial resins, particularly oil-modified alkyd resins, gave better adhesion to glass, tin, copper, sealed wood and cellophane. The lacquer films plasticized with Aroclor 1254 or 1260 gave good adhesion to '`Transite," cellophane, gal vanized iron and primed sleet surfaces. Some of the other commercial plasticizers tested in similar films gave better adhesion to aluminum, tin, bare steel, copper and sealed wood surfaces. Though compounds with an Aroclor alone possess pronounced adhesive qualities, better adhesion to all of the surfaces results if mixtures of Aroclor or varied contents are used. Resistance to Aqueous Solutions Chlorinated rubber films with Aroclor 1254 or 1260 (plasticizers) and Aroclor 5460 (resin) show satisfac tory' resistance to solutions of 10 per cent hydrochloric acid, 5 per cent sodium Hydroxide, 5 per cent sodium chloride and water spot tests. Film Hardness Softer films were produced with Aroclor 5460 in ratios of 5:10 and 10:10 Mroc/or^Parlon") than with other commercial resins in similar mixtures. Likewise, softer films result from Aroclor 1254 or 1260 in ratios of 2:10 and 5:10 Mrocfor^Parlon") than with other commercial plasticizers at these concentrations. From these tests compounds with Aroclor are shown to have strong plasticizing action on chlorinated rubber. Cold-Cheek Resistance Aroclor 5460 Is superior to phenol formaldehyde resins in cold-check resistance imparted to chlorinated rubber films, but not as good as alkyds modified with long oil. Aroclor 1260 used as a plasticizer proved somewhat better than Aroclor 1254, Weather Resistance Pigmented chlorinated rubber finishes containing Aroclor have consistently withstood outdoor weather tests, but unpigmented finishes do not stand up well regardless of the resin or plasticizer used. Poor resistance to ultraviolet light is also a weakness of chlorinated rubber. Most pigments (except ultra marine blue) are usable with "Parlon" and are recommended if the coating is to be subjected to outdoor weather or ultraviolet light. However, pigment protection varies considerably. Inspection of alkyd enamels fortified with "Parlon" showed weatherability varied from 63 months with chrome green to 4 months for titanium dioxide--iron blue combinations. Sanding and Polishing Properties Plastic films compounded with "Parlon" and containing Aroclor 5460, 1254 and 1260 have shown satisfac tory sanding and polishing characteristics. - 7- 0613bl6 TOWOLDMON0037745 WATER_PCB-00022214 Alkaline-Resistant Coatings Applications Products containing Arochr and chlorinated rubber are highly resistant to alkalies and moisture. Paints with combinations of Arochr and chlorinated rubber are used in large quantities for concrete floors, walls, swimming pools and other surfaces. A paint formulation is given in Table VI. Table VI, Paint Formulation for Alkaline Surface (Parts by We:ght) Ingredient "Parlon," 20-cp. type.................. ......... Aroclor 1254................................. ......... "Rezvl 869".................................. .......... .....Aroclor 5460 or "Cumar P10"... ....."Beckosol 31"............................... Tung oil, Thermolyzed, 976....... .......... Titanium dioxide.......................... .......... Zinc oxide... ... Silica flour. ... Carbon black................................ ... Xylene........ ... Hi-Flash naptha........................... .......... Totals............................... .......... Formula 1 (basament floors) IS 10 8 -- -- -- 16 2 3 0.2 42.8 -- 100 Formulation Formula 2 (F,d. Sp,c. TT.P.9I| 18 10 -- 6 _ -- 16 2 -- 0.5 47.5 -- 100 (iwlmmlng poo 14.6 4.4 -- _ 2.9 4.4 19.7 6.5 -- -- -- 47.5 100 Chemical-Resistant Finishes Particular care is necessary in choosing resins and plasticizers for chemical-resistant paints. Chlorinated rub ber formulations with an Arochr have proved outstanding for acid and alkali resistance. Five formulations are shown in Table VII. Table VII. Formulations for Chemical-Resistant Paints (Parts by Weight) Ingredient Formulation 1 Intarior uso, acidt and alkalies "Parlon," 20-cp. type........... 16 Aroclor 5460.......................... 6.4 "Bakelite XJ-12895"............ "Rezyi 807" (solids)............ -- Aroclor 1254......................... . 8 Arochr 1260.......................... -- Tung oil, Thermolyzed, 976. . -- Iron oxide.............................. 16 Titanium dioxide.................... -- Zinc oxide.............................. -- Zylene...................................... 53.6 Hi-Flash naphtha................. -- Toluene................................... -- Totats........................ 100 2 Exterior use, acidi 16 -- 6.4 4.8 -- 4.8 16 _ -- 52 -- _ 100 3 Extarior uta, alkalies 16 -- 6.4 -- 4.8 -- 4.8 16 -- -- 52 -- -- 100 4 Maximum resistance, acids and alkalies 18 -- -- -- 8 6 -- 18 _ -- 39 11 _ 100 5 Soap resistant 12 6 -- -- -- -- 7.7 -- 18 6 28 10.3 12 100 0613517 TOWOLDMON0037746 WATER_PCB-00022215 These formulations were applied to metal bars or panels and tested for resistance. Formula I showed good resistance to 10 per cent hydrochloric acid and 5 per cent sodium hydroxide solutions. Formula 2 gave excellent outdoor protection to metal surfaces on plants manufacturing acids. Formula 3 performed well on exteriors of plants producing alkali. Formula 4 had excellent resistance to acids, alkalis and salt solutions. It also showed good adhesion to glass and other surfaces. Formula 6 proved good for resistance to warm, soapy water. Note: No finishes with Aroclor or chlorinated rubber are recommended for con tinuous exposure at temperatures above 140 F. Marino Finishes The marine industry makes great use of chlorinated rubber coatings plasticized with Aroclor to protect wood and metal on boats, barges and other marine equipment. They possess good resistance to salt water and their hard finish deters algae and other marine growth. A suggested formula for a white marine paint is given in Table VIII. Table VIII. Formulation for a Chlorinated Rubber Marina Paint Ingredient Parts by Weight "Parlon," 20-cp. type............................................................ 20 Aroclor 1254.......................................................................... 6 "Rezyl 869"........................................................................... 6 Titanium dioxide................................................................... 25 Xylene..................................................................................... 23 Hi-Flash naphtha.................................................................. 20 Total................................................................... 100 Emulsion Paints If chemical resistance is required on porous surfaces, Aroclor 1254 is often added to chlorinated rubber emulsion paints. The Hercules Powder Company reports that preferred water phases for such paints are either a 1 per cent distilled water solution of "Aerosol OT" or a 4 per cent dlstilled-water solution of sodium oleate. A lacquer-to-water ratio of 2.5 to 1 (by weight) is suggested for the complete emulsion. "Parlon" of any viscosity may be U9ed. A typical paint phase for such an emulsion paint is given in Table IX. 0613518 | TOWOLDMON0037747 WATER_PCB-00022216 Table IX. Formulation for Paint Phatt of Emulsion Paint Ingredient Parti by Weight "Parlon".............. Aroclor 1254....... "Cumar P10"...... Xylene.................. Hi-Flash naphtha Total....... ........ 28 ....... 14 .... 10 ........ 24 ....... 24 ........ 100 Adhesive* Chlorinated rubber adhesives with an Aroclor were developed originally for adhering labels to acid bottles because of their general resistance to chemicals. These adhesives are also of unusual interest because they are fire resistant. A typical formulation is given in Table X. Table X. Formulation for Chlorinated Rubber Adhesive Ingredient Parts by Weight "Parlon,1" 125-cp. type......................................................... 20 Aroclor 1254.......................................................................... 6 Aroclor 1260........................................................................... 6 Toluene................................................................................... 68 Total......................................................................... 100 Paper and Textile Coatings Chlorinated rubber coatings with Aroclor are worthy of consideration for specific end uses in the paper and textile coating fields. In general, this type of coating is restricted by odor and taste. Unpigmented fin ishes seem suitable for certain fabrics used indoors, but not for exposure to high temperatures or direct sunlight. Electrical Coatings Because of their desirable electrical properties, these compositions are useful for insulating and protecting electrical wire and apparatus from moisture. With selected fungistats and waxes, coatings of this type are used to protect electronic equipment in the tropics against moisture and fungi. The fire resistance of these plastics is an added dividend in the electrical field. Printing Inks Printing inks requiring a fast drying time and chemical resistance are often based on chlorinated rubber compositions plasticized with an Aroclor. These inks are especially useful on soap wrappers and boxes, bottle labels and many other commodities because of their alkali resistance. 0613519 ^ TOWOLDMON0037748 WATER_PCB-00022217 Other Resins and Plasticisers Compatible With Chlorinated Rubber The resins and Monsanto plasticizers given in Tables XI and XII are compatible with chlorinated rubber, but none gives the over-all desired qualities attained by using an Aroclor. The strong points and limitations of each are known. If their use is necessary for specific applications in chlorinated rubber, more detailed in formation on them may readily be found. Table XI. Retins Compatible with "Parlon" "Amberol 801, 806P, ST-137, F7" Aroclor 1262, 5460 "Aroplaz 920, 930, 93S, 940" "Bakelite" XR-3180, XR-4503, XR-4006, BR-2963, XJ-9868, BR-1329, BR-3360" "Beckacite 1112" "Beckamine P-138, P-2S4" "Super-Beckamine 3501" "Beckapol 1400" "Beckoso! 1 (solid), 18, 31, 34, 40, 1329" "Beetle" Resin 227-8 "Clorafin 70" Copal "Cumar P1Q" Dammar "Duraplex C-45-LV, C-48, C*49, C-50-LV, C-51, C-62, D-61, D-62, E-71, E-71-A, E-73" East India gum Ester gum Ethyl methacrylate "Esterol 750" ``Formvar" ``Gelva 2.5" "Glyptal 1247, 2450, 2454, 2458, 2464, 2466, 2500" "Lewisol 2L, 28, 33" Methyl methacrylate polymers "Veville R-3, R-10" "Pentalyn A, G, M, X" "Petrex 1, 130H" "Phenac 633-M" "Rezyl 116, X315, 412, 775, 803, 807, 829, 869, 880, 1103" Rosin Saiitolitc* MPH (sulfonamide-aldehyde resin) "Stabelite Ester 1, 2, 10" "Stabelite" resin "Super-Beckacite 1001" "Syntex HI, H3, H12,17, 213, 22, 28, 29, 32, 36" "Teglac 15, Z-152" "Velsicol AD6-3" "Vinsol" Table XII. Monsanto Plasticizers Compatible with "Parlon" Aroclor 1242 Aroclor 1254 Aroclor 1260 Dibutyl phthalate Diethyl phthalate Dimethyl phthalate Sanlictzer B-16 (butyl phthalyl butyl glycolate) Santicizer M-17 (methyl phthalyl ethyl glycolate) Tricresvl phosphate Triphenyl phosphate Sdntolitt, Monunto Trademark*. Reg. U.S. Pat Off. TOWOLDMON0037749 WATER_PCB-00022218 Toxicity Animal toxicity studies and 20 years of manufacturing and use experience indicate that Aroclor compounds are not serious industrial health hazards. If the materials are heated to volatilization, ventilation should be provided to prevent inhalation of vapors. This is true of other major components of the formulation as well as the Aroclor compounds. Repeated or prolonged skin contact should be avoided although there are few instances of skin irritation. Human patch tests with finished products containing Aroclor compounds have shown no irritation. Mon santo will furnish information on specific Aroclor compounds upon request. Shipping Information Regulations Standard Containers -- None -- Steel and Fiber (Aroclor 1268, 5460) drums. Rail Classification Chlorinated diphenyl (synthetic resin, liquid, NOIBN) Synthetic resin, liquid, NOIBN Snythetic resin, other than liquid, NOIBN -- Aroclor 1142, 1148, 1154, 1160, 1162, 1168, 1221, 1232, 1242,1248, 1254, 1260, 1268 -- Aroclor 1260 mix, 1262 mix -- Aroclor 2565, 4065, 4465, 5042, 5060, 5442, 5460 Truck Classification Synthetic resin powder, NOI Synthetic resin, lumps or solid mass, NOI -- Aroclor 2565 -- Aroclor 4065, 4465, 5042, 5060, 5442, 5460 0613&21 TOWOLDMON0037750 WATER_PCB-00022219 Trademark Index Trademark Company "Aerosol OT" "Amberol" "Amsco Solv" "Aroplaz" "Bakelite" "Beckacite" "Beckamine" "Beckopol" "Beckosol" "Beetle" Resin "Cellosolve" "Clorafin" "Cumar" "Duraplex" "Esterol" "Formvar" "Gelva" "Glyptal" "Hercolyn" American Cyanamid Company Rohm & Haas Company American Mineral Spirits Co. U. S. Industrial Chemicals Co. Bakelite Company Reichhold Chemicals, Inc. Reichhold Chemicals, Inc. Reichhold Chemicals, Inc. Reichhold Chemicals, Inc. American Cyanamid Company Carbide & Carbon Chem. Co. Hercules Powder Company Barrett Division, Allied Cbem. & Dye Rohm & Haas Company L. Sonnebom Sons, Inc. Shawinigan Resins Corp. Shawinigan Resins Corp. General Electric Company Hercules Powder Company "Lewisol" "Neville" "Pentalyn" "PetTex" "Phenac" "Reayl" "Solvasol" "Solvesso" "Stabelite" Ester "Stabelite" Resin "Super-Beckacite" "Syntex" "Teglac" "Tollac" "Troluoil" "Transite" "Velsicol" "Vinsol" Hercules Powder Company Neville Chemical Company Hercules Powder Company Hercules Powder Company American Cyanamid Company American Cyanamid Company Socony-Mobil Oil Company Esso Standard Oil Hercules Powder Company Hercules Powder Company Reichhold Chemicals, Inc. Flintkote Company American Cyanamid Company Neville Chemical Company Anderson-Pritchard Oil Corp. Johns-Manville Sales Corp. Velsicol Corp. Hercules Powder Company rta/POB--2M--1*1 R. WW:JRC V#7 IViM -13- PrlaU* la U.8.A. 0613522 TOWOLDMON0037751 WATEFLPCB-00022220 A R OC LO R Resins and Plasticizers for Chlorinated Rubber V Monsanto U, Monsanto Tachnkol B ulbtin 0 -1 2 4 M ay, 1957 Pr further information on th products described in this bulletin conteet the neirest Mensento offico. MONSANTO CHEMICAL COMPANY ST. LOUIS, MISSOURI AKRON ATLANTA BOSTON CHICAGO CINCINNATI CLEVELAND DETROIT HOUSTON LOS ANGELES MINNEAPOLIS NEW YORK SAN FRANCISCO SEATTLE WILMINGTON MONSANTO CHEMICALS LTD. London MONSANTO CHEMICALS (AUSTRALIA) LTD. Mnlboumo MONSANTO (CANADA) LTD. Monfrool Toronto Voncouvor 0613523 | TOWOLDMON0037752 WATER_PCB-00022221