Document ba9zxKDMvmBO7YovKyO5NNqjo

NALCO MATERIAL SAFETY DATA SHEE PRODUCT NALCO 5196 CORROSION INHIBITOR Emergency Telephone Number , Medical (70S) 920-1510 (24 hours) ' 40 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5196 CORROSION INHIBITOR DESCRIPTION: A solution of alkyl primary amine NFPA 704M/HMIS RATING: 3/3 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS 0 OTHER Our hazard evaluation has identified one or more hazardous ingredient(s) under OSHA's hazard Communciation Rule, 29 CFR 1910.1200. Their identity is being claimed a trade secret, Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% 0 o1 Primary amine Proprietary SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes burns to skin and eyes. Do not get in eyes, on skin or on clothing. Wear goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. PAGE 1 OF 8 SAL 000009686 NALCO CHEMICAL COMPANY OWE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 AQEA TC0-3Of5-i OOO MATERIAL SAFETY DATA SHEET NALCQ G S 240 PRODUCT NALCO 5196 CORROSION INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 4 FIRST AID INFORMATION ( CONTINUED ) NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Can cause injury or damage. Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Can cause severe irritation. Can cause allergic contact dermatitis in susceptible individuals. Can be harmful. May cause irritation to the respiratory tract and lungs. * SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): Primary amine LDse = 750 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): Primary amine LD,,, = 2,600 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 6.6/8.0 Corrosive PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: 104/110.0 Extremely irritating SKIN SENSITIZATION: Skin sensitization expected. OTHER TOXICITY RESULTS: Primary amine. Bacterial mutagenicity bioassay (Ames) negative. PAGE 2 OF 8 SAL 000009637 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS S05B3-119B AC3EA 7"g-3Q5-iOOO N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5196 CORROSION INHIBITOR Emergency Telephone Number Medical (706) 920-1510 (24 hours) G S 2 40 SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless to light yellow FORM: Liquid ODOR: Ammonia DENSITY: 8.2 lbs/gal. SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 0.98 60 Degrees F ASTM D-1298 pH (NEAT) = 12 pH (at 1%) 11.5 ASTM E-70 VISCOSITY: 34 SUS @ 100 Degrees F ASTM D-2983 FREEZE POINT: -20 Degrees F ASTM D-1177 POUR POINT: Less than -30 Degrees F ASTM D-97 FLASH POINT: Greater than 200 Degrees F (TCC) ASTM D-56 PERCENT VOLATILE BY WEIGHT: 3 75 Degrees F NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Greater than 200 Degrees F (TCC) ASTM D-56 * It EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, * carbon dioxide or other extinguishing agent suitable for Class B fires. Use * water to cool containers exposed to fire. For large fires, use water spray or * fog, thoroughly drenching the burning material. * it UNUSUAL FIRE AND EXPLOSION HAZARD: Ammonia, CO, CO* may be evolved under fire conditions. * * SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: N-nitrosamines, many are cancer causing agents to laboratory * animals, may be formed when certain amines are mixed with nitrous acid, organic* or inorganic nitrites or atmospheres with high nitrous oxide concentrations. * * Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. * * Avoid contact with strong acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. * FEEDING EQUIPMENT: Do not use with aluminum, copper or brass, Plasite 7122, Plasite 8-4005, hypalon, viton, Buna-N, polyurethane, rubber, vinyl or neoprene. * * * PAGE 3 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER AREA "700-305- 1 OOO ,000 a** NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NALCQ 6 S 2A 40j & PRODUCT NALC0 5196 CORROSION INHIBITOF cEimnvefrygvernicvy/ Tiweilveppnhuonnev nNvurmnubverr MMeeddiiccaall((770088))992200--11551100((2244 hhoouurrss)) r SECTION 9 REACTIVITY INFORMATION ( CONTINUED ) THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. * SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles. A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. Keep the spill away from heat, sparks, flames and welding operations. Ventilate area and evacuate employees from exposure if the airborne concentration exceeds the TLV. Refer to Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of * * PAGE 4 OF 8 SAL 000009689 NALCQ CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6Q5S3-119B AREA "70Q-305-10CT N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5196 CORROSION INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hours) GS240 SECTION 11 SPILL AND DISPOSAL INFORMATION < CONTINUED ) a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be incinerated in accordance with local, state and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - ORGANIC AMINE COMPOUND SECTION 14 REGULATORY INFORMATION * * The following regulations apply to this product. FEDERAL REGULATIONS: * OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Primary amine - Corrosive, sensitizer Primary amine = 10 ppm, STEL 20 ppm Workplace Environmental Exposure Limit (WEED CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. PAGE 5 OF 8 SAL 000009690 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 605B3-119S AqpA 7ce-^~5-i ooo G S 2 40 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5196 CORROSION INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard -- Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C S. D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. PAGE 6 OF 8 SAL 000009691 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1190 APfi 7CP-3G5- '030 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5196 CORROSION inhibitor NALCO Emergency Telephone Num ber Medical (706) 920*1510(24 hours) G S 240 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Primary amine Water Trade secret 7732-18-5 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J, P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. I ARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for PAGE 7 OF 8 SAL 000009692 NALCO CHEMICAL. COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 709-5Q5- 1 GOO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5196 CORROSION inhibitof Emergency Telephone Number Medical (706) 920-1510 (24 hours) SECTION 17 BIBLIOGRAPHY ( CONTINUED ) Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 04/18/90 DATE PRINTED: 08/18/90 PAGE 8 OF 8 SAL 000009693 NALCQ CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 ARE A 7C3.3n5.iQOQ