Document ba18K2oQXbwEXwkzj916QLgVZ

364 CHAPTER 14 1956 Guide Fuels and Combustion 365 The operating efficiency of a gas appliance can then be computed with sufficient precision by application of Equation 18. Percent Combustion Efficiency = Table 10. Average Flue Gas Dew-Point for Various Fuels* ofType Fuel :Average Dew-Point FTemperature. ('Gross Btu of fuel \ /total flue losses per\ Igas per cubic foot/ \cubic foot fuel gas)/ X 100 Gross Btu of fuel gas per cubic foot (18) Reference to Table 9 will show that ultimate C02 percentage values of fuel gases vary. While personal errors involved in C02, temperature, and chart determinations, would doubtless more than offset any inaccuracies due to universal use of the alignment charts shown, precise laboratory work may require a more exact method. For more complete information the reader is referred to Combustion, 3rd Edition, and Gaseous Fuels, (published , by American Gas Association) and particularly to tables covering various properties of different commercial gases included in these publications. Semi-Bituminous Coal........................................................... Bituminous Coal......................................................... Oil...................................................................... .................... Natural Gas...................................... .................................... Manufactured Gas........................................................... Propane Gas (2500 Btu/cu ft)................................. .......... Butane Gas (3200 Btu/cu ft)................................................ Butane-Air Gas Mixture (535 Btu/cu ft.......................... .. 68 84 93 in 127 137 119 124 121 removing soot from furnaces and boilers when properly Used.26 A discus sion of instruments and methods of evaluating smoke, will be found in Chapter 52. .' CONDENSATION AND CORROSION REFERENCES Sulfur" dioxide or sulfur trioxide, formed by the combustion of sulfur in fuels, are the principal corroding substances in flue gases. They become active whenever sufficient moisture is present for the formation of sulfurous or sulfuric acid,22 and they lower the dew points of flue gases appreciably. Therefore, unless heating equipment is designed for operation at flue gas temperatures.below the dewpoint, which is seldom the case, it is always ad 1 Five Hundred Tests of Various Coals in Househeating Boilers {U. S. Bureau of Mines Bulletin No. 276). 2 Combustion Efficiencies as Related to Performance of Domestic Heating Plants, by A. P. Kratz, S. Konzo and D. W. Thompson ( University of Illinois, Engineering Experiment Station Circular No. 44). 2.Quality of Anthracite as Prepared at Breakers, 1935 (1/. S. Bureau of Mines Re port of Investigation, R. I. 3283). visable to maintain temperatures above this value in all parts of the ap 4 Hand Firing Soft Coal Under Power Plant Boilers (U. S. Bureau of Mines Tech pliance. Excessive spot temperatures in the combustion chamber or else nical Paper No. 80). where, on the other hand, are also destructive in that they may result in rapid oxidation of ordinary heating surfaces. American Standard Require ments for gas furnaces, floor furnaces, and recessed heaters, for example, specify that minimum spot heating surface temperatures during normal operation must neither fall below 178 F (50 F above average dewpoint) nor exceed 875 F on any portion of the heating surface. In any event it is usually desirable to maintain flue temperatures within the limits in dicated not only throughout the appliance, but in its connecting vent, flue, or chimney as well. Otherwise, excessive condensation and corrosion problems, with resultant customer dissatisfaction, will in all probability s Combustion Flames and Explosions of Gases. Lewis and von Elbe (Cambridge University Press, 1938). 8 Oil Burning, by H. A. Romp (Martinus Nijhoff, 1937). ' ASTM Test Designation D287-39. 1ASTM Test Designation D611-43T. 8 Tomorrow's Fuel Oil, by W. A. Sullivan and E. B. Glendenning {Fueloil and Oil Heat, Vol. 4, No. 1. May 1945 p. 36). 10 The Correlation of Cetane Number with Other Physical Properties of Diesel Fuels {Journal of the Institute of Petroleum, Vol. 30, 1944, p. 193-197). 11 Characterization of Petroleum Fractions, by K. M: Watson, E. F. Nelson and G. B. Murphy {Industrial and Engineering Chemistry, Vol. 27, Dec. 1935, p. 1464). be the result. Average dewpoint temperatures of flue gases resulting from 12 Burning Index for Distillates, by J. C. Reid and A. B. Hersberger. Fueloil and the combustion of various fuels, when burned with the amount of excess Oil Heat, Vol. 5, No. 9, Jan. 1947, p. 90). air normally supplied to insure complete combustion, are shown in Table 10. 12 Carbon Hydrogen Ratio of Catalytically Cracked Distillate Fuel Oils, by S. P. Cauley and E. B. Delgass {The Oil and Gas Journal, Vol. 45, No. 12 July 27, 1946, SOOT p. 166). . The deposit of soot on the flue surfaces of a boiler or heater acts as an insulating layer over the surface, and reduces the heat transmission to the water or air. The Bureau of Mines Report of Investigations No. 3272s shows that the loss of seasonal efficiency is not so great as has been be 14 Rating of Fuel Oils by a Test Unit, by D. W. Locklin and G. V. Parmelee (ASHVE Transactions, Vol. 57,1951, p. 139). l Gaseous Fuels {American Gas Association, 1948, p. 32). 14 Gas Analysis and Testing of Gaseous Materials by V. J. Altieri (American Gas Association, First Ed. 1945). lieved, and usually is . not over 6 percent because the greater part of the 17 Tentative Methods of Test for Specific Gravity of Gaseous Fuels {American heat is transmitted through the combustion chamber surfaces. The Society for Testing Materials, ASTM Designation: 1070-49). Bureau of Standards Report BMS 5424 points out that, although the de 18 Standard Method of Test for Calorific Value of Gaseous Fuels by the Water- crease in efficiency of an oil fired boiler, due to soot deposits, is relatively Flow Calorimeter {American Society for Testing Materials, ASTM Designation: 900-48). . ' .! small, the attendant increase in stack temperature may be considerable. The soot accumulation clogs the flues, reduces the draft, and may pre . 18 American Standard for Installation of Gas Piping and Gas Appliances in Build ings. ASA Z 21.30 1950 {American Gas Association). i1 vent proper combustion. Soot can probably be most effectively removed 20 NBFU Standard for the Installation of Oil Burning Equipments--NBFU pam by a jet of compressed air, by means of a brush, or a vacuum cleaner. phlet no. 31. {National Board of Fire Underwriters). However, it has been found that copper chloride, lead chloride, tin chloride, zinc chloride, common salt and some other salts are partially effective m 21 Domestic Gas Range Research {American Gas Association Laboratories Bulletin 7, p. 64).