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* Tenneco P6 Tiers l, A fconeco Company MATERIAL SAFETY DATA NUM86S 156 (Approvedby U.$. 0*p*nmwi of Labor tt "aaaantially aimllpr" to FOAM OSHA-2Q1 SECTION I IDENTIFICATION OF PRODUCT "1 MANUFACTURER'S NAMt EMERGENCY TtUFHONf NO. TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT tOOMU 609-386-9200 713-479-3411 RIVER R0A0, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822 trade naif* anosynonym* TENNECO PVC RESIN 175, 185, 190, 195, 200, 225, 225F, 225PG, 225SG, 250, 250-3, 10R, 501. 530. 540 CHEMICAL NAMt ANO SYNONYMS POLY(VINYL CHLORIDE), PVC HOMOPOLYMER chemical family CHL0R0HY0R0CAR80N POLYMER MOLECULAR FORMULA (CHgCHCl )n MOL WT SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT threshold % limit VALUE COMPONENT THRESHOLD % LIMIT VALUE OSHA Standard 1910.93q(. 1017) on vinyl cfiToride sets a permissible exposure llmit^o? Ippm averaged over any 8 hr. period and 5ppm over any 15 min. period. On the basis thati joiyvinyl chloride may contain and release small amounts of monomer, the Standard | applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or> transportation of PVC, but not to handling or use of "fabricated products", as defined, if not subject to processing sufficient in time or temperature to cause mass melting. APPEARANCE and ooor White powder, odorless OtUNO FONT (DEGREES FAHRENHEIT) Not applicable VAPOR PRESSURE (MM. OF MERCURY) Not applicable VAPOR dcsity (Ain > 1) Not applicable solubility in water Negligible SECTION III PHYSICAL DATA (mdeelgtrinegespfoainhtrenheid Not app.li.cable Softens about 160 - 180*F SPECIFIC GRAVITY (WATER * 1) 1.4 percent volatile (BY WEIGHT) Approx. 1* (Moisture) evaporation RATE Not applicable SECTION IV FIRE ANO EXPLOSION HAZARD DATA flashfoint(specifymcthooi ignition about 73$*F auto- flammable limits LOWER ^ffifWfiFrfgout 850 F (ASTM D-1929) (PERCENT BY VOLUME) Not applicable FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical. SPECIAL FIRE-FIGHTING PROCEDURES Water spray or fog may be helpful in reducing flame intensity and absorbing irritating funes. UPPER unusualpireaph)EXPLOSIONhazardb NPPA lists ignition temperatures of 725*F for layer and 1220'F^ for PVC dust cloud. Produces combustible gases above 570*F. Fire conditions produce hydrogen chloride, requiring protective equipment. Thi, intannswn M lumliUM itAoul w*rrnt>, hfibifiia iiuhiiwiiwi aCWnM (tom MWCM BMInnwdd tv Ttwrwnwwee PMyfirnntr, II#I tBAt accvrMt tnd Ttnntet PWvmra dot* not UKin, my iu, ^anMMWStMP R ftttntt i CvVlPRIMt smmummA itaopcmomnssnuhcthtnuomir-o--wn mimmiai ISaoNlor, uMng my prtewct mm Ii imm. ifc'NUU 8u TPOLSNA SECTION V HEALTH HAZARD DATA THRESHOLD LIMIT VALUE See Section II_______ ^ None expected - Inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces funes Irritating to eyes and respiratory tract requiring local exhaust). EMERGENCY ANO PIRET AtO PRC*X*ES Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water. SECTION VI REACTIVITY OATA STABILITY unstable stable INCOMPATIBILITY (Mtnl to AVOW) None in ordinary use. conditions to avcro Normal processing temperature, about 350*F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition produces HC1, and CO and C02 (above 570 F). HAZARDOUS POLTMEIVZATION may OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X None in ordinary use. SECTION VII SPILL OR LEAK PROCEDURES EPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep up and remove to disposal container. WASTE disposal method Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION respiratory protection tsoAcity iw*i In case of concentrated dust, use Bureau of Mines approved dust respirator (NIOBM TC-21C-132 or equivalent). See Sections II and IX. VENTILATION lCAL EXHAUST ror not orucessina. handling. ^e1ftLto elevated stack. tfenTilate enclosed spaces. PROTECTIVE GLOVES Not ordinarily required. EYE PROTECTION Safety glasses. other protective EQUIPMENT None required for ordinary handling. For hot processing local exhaust, safety glasses and aloves are recommended. SECTION IX SPECIAL PRECAUTIONS OSHAPRECAUTIONS TO BE TAKEN IN HANDLING AND 3TORINO Standard 19l0.93q(. 1017) requires monitoring and ^ab!nngeo1Ui8n*Contifnsa??ny?a2fi]or?d!-$1ny? ^hlSrl^e^^a^ance^Suspect^gent1'. w PVC resins with a low monomer content make it easier to operate below the OSHA action level of 0.5ppm in a processor's work area, assuming normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developments on resins and on regulations are pending. OATE 3/12/84 KAMI ANOTTTLi 0. GOODMAN, PRODUCT REGULATIONS 'N00 87 wa*f maiHi 156 GSZSi Tenneco Polymers A >nn*co Company MATERIAL SAFETY DATA (Approval by U. S. Oaparttnpnt 0/ Labor as "aasantially almllar" to FOAM OSHA-20) NUMBER 157 SECTION 1 IDENTIFICATION OF PRODUCT MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. TFNNEC0 POLYMERS, INC.. RESEARCH & DEVELOPMENT 1 609-386-9200 AOORESS river ROAD, P.o. BOX 129, FLEMINGT0N, NEW JERSEY 08822 traoe name and synonyms jenNECO PVC DISPERSION RESIN 1716. 173Q. 1732. 1735. 1738. CHEMICAL NAME ANO SYNONYMS POLY(VINYL CHLORIDE) PVC 1742. 1750. 1755. 1756. 1757. 1159____________________________________________ CHEMICAL FAMILY CHL0R0HYDR0CARB0N POLYMER MOLECULAR formula (CH?CHCl)n MOL WT SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT THRESHOLD % UMIT value COMPONENT THRESHOLD % limit value (UNITS) (UNITS) OSHA Standard 1910.93q(.1017) on vinyl chloride sets a permissible exposure limit of lppm averaged over any 8 hr. period and 5ppm over any 15 minute period. On the basis tnat polyvinyl chloride may contain and release small amounts of monomer, the Standard applied to tne manufacture, reaction, packaging, repackaging, storage, handling, use or transportation of PVC, but not to.handling or use of "fabricated products", as defined, if not -su-b-.i-e-c-t -to----p--r--o--c--essssiinnqg sufficient in time oirr tteemmppeerraattuurree ttoo ccaauussee mmaassss mmeeTTtitin~a. APPEARANCE AND ODOR White powder, odorless. BOIUNG POINT (DEGREES FAHRENHEIT! Not applicable VAPOR PRESSURE (MM OF MERCURY) Not applicable vapor DESiTY (AIR = 1) Not applicable SOLUBILITY IN WATER Negligible SECTION III PHYSICAL DATA MELTING point (DECREES FAHRENHEIT} Not applicable Softens about 160 - 180F SPECIFIC gravity (WATER ** 1) 1.4 PERCENT VOLATILE (BY WEIGHT) Approximately 1% (moisture) EVAPORATION RATE (8UTYLACETATE n Not applicable SECTION IV FIRE AND EXPLOSION HAZARD DATA CLASH POINT (SPECIFY METHOD) Ignition about 735F autc flammable limits DEGREES FiAgHnREiNtHiEoITn) about 850F (ASTM 1929) (PERCENT BY VOLUME) LOWER Not applicable, FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical.____________________________________ SPECIAL FIRE-FIGHTING PROCEDURES Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fines. UPPER unusual fire and explosion hazaros NFPA lists ignition temperatures of 752F for layer and 1220 F for PVC dust cloud. Produces combustible gases above 570F. Fire conditions produce hydrogen chloride, requiring protective equipment. TENOO 88 Thit intoonMion it tumitnad witnout warranty. rwmwmiM, inducamant > itctnt* ol in, mnd, aacapt mat it is aceurata to in* o*tl ol Ttnnaco Polymara LnOJtHaB1 or o*otainad trom tourrt, MiitvM 0, Ttnntco . . -------- --------- . Polyman A ..A to M aceurata and S*'n'* ,.AA ,AW TmnaooISPMrv1y1m1 o'IrMa oI oat not Miami n, itgti rampontlBilry lor i/ho' rtnanci upon tatna SECTION V HEALTH HAZARO DATA THMSMOLSUMITVALUt See Section II _______________________________________ ________ ___ __________________________ pmcrsonovcMxiKMuM None expected - Inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract requiring local exhaust). EMERGENCY AND PIRIT AlO PGOCttU*** Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water. STABILITY unstable stable '"'Sone'TrTonSTnafy0,use. SECTION VI REACTIVITY DATA conditions to avoio Normal processing temperature, about 350#F causes slow darkening and decomposition. Higher heat X increases rate and evolution of HC1. Soluble in certain ketones and organic solvents. HAf)ver^C08^^ produces HC1, and CO and CO2 (above 570*F). .HAZARDOUS pocymemzation MAT OCCUR WILL NOT OCCUR conditions to avoid X None in ordinary use. SECTION VII SPILL OR LEAK PROCEDURES EPS TO SE TAKEN in CASE MATERIAL IS RELEASED OR SPillEO Sweep up and remove to disposal container. waste DISPOSAL method Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION respiratory protection isp*ei*y t,pi In case of concentrated dust, use Bureau of Mines approved dust respirator (NIOBM TC-21C-132 or equivalenl0- See Sections II and IX. VENTILATION f^STffrocessing. Ivary" hand! i nq. s^enk to elevated stack. ^e6ntilate enclosed spaces. PROTECTIVE GLOVES EYE PROTECTION Not ordinarily reouired. Safety glasses. Noneother protective equipment required for ordinary handling. For hot processing local exhaust safety glasses and gloves are recomnended.--------------- -------------------------------------------------------------- SECTION IX SPECIAL PRECAUTIONS OS HA Standardprecautions to betaken in hanouno and storing 1910.93q(.1017) requires monitoring and other precautions in storage, handling and use of polyvinyl chloride, and also labeling at PVC "Contains Vinyl Chloride-Vinyl Chloride is a Cancer-Suspect Agent". New PVC BRins with a low monomer content make it easier to operate below the OSHA action level of 0.5ppm in a processor's work area, assuming normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developmments on resins and oh regulations are pending. DATE 3/12/84 NAME AND TITLE D. GOODMAN, PRODUCT REGULATIONS SHEET NUMSCR 157 LTtMtcoj TennecoPo' Tiers A 'fcnntco Company MATERIAL SAFETY DATA NUMBER 158 (ApprovoO by U S. Dpptrimtnt of Libor as "annually timlltr" to FORM 0SHA-20) SECTION I IDENTIFICATION OF PRODUCT MANUFACTURE*'! NAME TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT EMERGENCY telephone NO. 609-386-9200 201-782-4011 aOORESS RIVER ROAD, P.0. BOX 129, FLEMINGT0N, NEW JERSEY 08822 trade name ano synonyms TENNECO PVC COPOLYMER RESIN 305, 314, 315, 318, 382, 388, 389, 390, 391 , 400, 521 CHEMICAL NAME ANO SYNONYMS VINYLCHLORIDE - VINYL ACETATE COPOLYMER, VC/VAc COPOLYMER CHEMICAL FAMILY CHL0R0HYDR0CARB0N COPOLYMER MOLECULAR FORMULA (CHgCHCl)x(CH2CHOCOCH3)y MOL WT SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT THRESHOLD % UMIT VALUE COMPONENT THRESHOLD % LHUTT VALUE (UNITS) (UNITS) 0SHA Standard 1910.93q(.1017) on vinyl chloride sets a permissible exposure limit of Ippm averaged over any 8 hr. period and 5ppm over any 15 minute period. On the basis that polyvinyl chloride may contain and release small amounts of monomer, the Standard applies to tne manufacture, reaction, packaging, repackaging,.storage, handling, use or transportation or PVC, but not to.handling or use or "fabricated products , as defined, if not subject to processing sufficient in time or temperature to cause mass mpTting.__ SECTION III APPEARANCE ANO OOOR White powder, faint ester odor. BOILING POINT (DEGREES FAHRENHEIT) Not applicable VAPOR PRESSURE (MM OF MERCURY) Not applicable VAPOR DESITY (AIR m 1) Not applicable SOLUBIUTY IN WATER Negligible PHYSICAL DATA MELTING POINT (DEGREES FAHRENHEIT) .N.o.t app,li.cab. ,le Softens about 140 - 160F. SPECIFIC GRAVITY (WATER x 1) 1.35 - 1.4 PERCENT VOLATILE (BY WEIGHT) Approximately 1% (moisture) EVAPORATION RATE {BUTYLACETATE * Not applicable SECTION IV FIRE AND EXPLOSION HAZARD DATA flash point (specify method) I an i t i on about 735F (DEGREES FAHRENHEIT) _______________ for PVC (ASTM D-1929). flammable umits (PERCENT BY VOLUME! FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical. LOWER Not applicable. UPPER SPECIAL fire-fighting procedures Water spray or fog may be helpful in reducing flame intensity and absorbing irritating furies. UNUSUAL FIRE ANO EXPLOSION hazards NFPA lists ignition temperature of 1274F for dust cloud. Produces combustible gases above 570F. Fire conditions produce hydrogen chloride, requiring protective equipment._________ ____________________________________ ________ TN information i, tumimad wttnout warranty. toprtMntalion. mducomont or itcmoo Ol my kind. omeopt inn it t oecurMo to in* MM at Tonnoco Polymor, KnontiAOg* or ootoinod liam wurcoo BMIouod By Tonnoco Polymor, to BO OCCurOK ond Tonnoco Polymor, Oo* not mumr ,ny logoi rooeonoiBilty tor uO* or roironco upon mm CuMomori ora oncourogod to conduct thorr own toon. Solor, uolng my product 'Oad It* loMt -pp QQ TPOLo*3 f c JkMRCBMOLD LIMIT VALUE IPsS.ee Section II SECTION V HEALTH HAZARD DATA irncn m oviwmiuRi None expected - inert resin. See Section IX. Prolonged breathing of concentrated .dvull ffii respiratory pr0duceS furos 1rritat<"3 emergency ano first aio pgocol*sb Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water. SECTION VI REACTIVITY DATA stability UNSTABLE stable Normalconditions to avoio processing temperature, about 350*F causes slow darkening and decomposition. Higher heat X increases rate and evolution of HC1. INCOMPATIBILITY (Mtianal* lo Avoidl None in ordinary use. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION products Thermal decomposition produces HC1, and CO and CO? (above 570#F). haZAROOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X None in ordinary use. i SECTION VII STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SPILL OR LEAK PROCEDURES Sweep up and remove to disposal container. WASTE DISPOSAL METHOO Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION respiratory protection isppciiy tyo*i In case of concentrated dust, use Bureau of Mines approved dust respiratory (NIOBM TC-21C-132 or equivalent). See Section II and IX. VENTILATION roces s i n g. ^r^^f^fary* handling. s^lent to elevated stack. Ventilate enclosed spaces. PROTECTIVE CLOVES Not ordinarily required. EYE PROTECTION Safety glasses. other protective equipment None required for ordinary handling. For hot exhaust, safety glasses and qlvoes are recoirmended. processing local SECTION IX SPECIAL PRECAUTIONS epB^icautions to be taken in handling ano storing OSHA Standard 1910.9 3q (* 1017) requires monitoring and ml^wrp^S2yil22su5!)w?tRW9.'-.!!anS,].i.99rS9^-i,5* PVC "Contains Vinyl Chloride-Vinyl Chloride 9f is P&Y!wis<jj|ioridjj^antj a"Cmcer-Suspect Agent". also New l1ambe]ling resins with a low monomer content make it easier to operate below the OSHA action leve of O.Sppm in a processor's work area, assuming normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developments on resins and on regulations are pending. TENQ0 91 r LTIMMCA TennecoPof Tiers a ifcmwco Company ( MATERIAL SAFETY DATA number 159 (ApprovoO by U S. Oopartmant of Labor aa "aaaonttally tlmilar" to FORM 0SHA-20) SECTION I IDENTIFICATION OF PRODUCT MANUFACTURERS NAME TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT CMCAGENCY TELEPHONE NO 609-386-9200 AOOMCSS RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822 trade name ano synonyms TENNECO PVC COPOLYMER DISPERSION RESIN 0565, 0665 (0565-1) CHEMICAL NAME ANO SYNONYMS VINYLCHLORIDE - VINYL ACETATE CHEMICAL FAMILY CHL0R0HYDR0CARB0N COPOLYMER COPOLYMER, VC/VAc COPOLYMER MOLECULAR FORMULA (CH2CHC1 )xfCHgCH0C0CH^v mol wt SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT THRESHOLD Va LIMIT VALUE COMPONENT threshold % LIMIT VALUE . (UNITS) (UNITS) 0SHA Standard 1910.93q(. 1017) on vinyl chloride sets a permissible exposure limit of lppm averaged over any 8 hr. period and 5ppm over any 15 minute period. On the basis that polyvinyl chloride may contain and release small amounts of monomer, the Standard applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or transportation of PVC, but not to.handling or use of "fabricated products", as defined, hf not subject to processing sufficient in time or temperature to causp mass mpTt.inp SECTION III APPEARANCE ANO ODOR dhite powder, faint ester odor. SOILING POINT (DEGREES FAHRENHEIT) Not applicable VAPOR PRESSURE (MM OF MERCURY) Not applicable VAPOR oesity (AIR *1) ,. Not applicable SOLUBILITY IN WATER Negligible PHYSICAL DATA MELTING POINT (oegreesFahrenheit) N0t applicable Softens about 140 - 160F. SPECIFIC GRAVITY (WATER x t) 1.4 PERCENT VOLATILE IBY WEIGHT) Approximately ]% (Moisture) evaporation rate (BUTYLACETATE * 1) Not applicable SECTION IV FIRE AND EXPLOSION HAZARD DATA aSfflSMK*''?" tion about 735-F for PVC (AS7M D-1929) FLAMMABLE LIMITS (PERCENT 8Y VOLUME) FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical. MX LOWER applicable SPECIAL FIRE FIGHTING PROCEDURES UPPER Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes. ______________________________________ _______________ unusual fire ano explosion hazaros NPPA lists ignition temperature of 1274F for dust cloud. Produces combustible gases above 570F. Fire conditions produce hydrogen chloride, requiring protective equipment. Thu information ta hittiltnad without warranty. raemaantation. inoucomont or ucana* o* any kino, aicapt thAt ) it accw'tta to ho MOt Of TannocP Pttymdta anowtoOB* or aotamoo tftm aourcaa MtMvN By Tannoco Polymara to W accurata and Tanndeo Polytnora do*a not aaiuma any '0LraMOruMeilpr uM or raiianen uoon aama 1 (JQ 92Cualomora art onrnuraQH to conduct thair own laaia. Balora uamg any product raaO ita laMt TPOL2SA3 SECTION V HEALTH HAZARD DATA f THRESHOLD LIMIT VALUE See Section II neno*wn*x>o*M None expected - inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes Irritating to eyes and respiratory tract requiring local exhaust). ememmncy ano piret aio RROClDum* Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water. SECTION VI REACTIVITY DATA stability UNSTABLE stable INCOMPATIBILITY (Matwiaii to trout) None in ordinary use. conditions to avoid Normal processing temperature,about 350BF, causes slow darkening and decomposition. Higher heat X increases rate and evolution of HC1. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION PAOOUCTS ,,, Thermal decomposition produces HC1, and CO and COj (above 570 F). HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR conditions to avoid None in ordinary use. X SECTION VII SPILL Oft LEAK PROCEDURES pi PS TO K TAKEN IN CASE MATERIAL iS RELEASED OR SPILLED Sweep up and remove to disposal container. waste disposal method Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION respiratory protection i$oaei*y typai in case ot concentrated dust, use Bureau of Mines approved dust respiratory (NIOBM TC-21C-132 or equivalent). See Sections II and IX. $r Wp ro ce s s i n g. SPCV&nt to elevated stack. T8r*Norb<fnlary hand!inq. 0T*^?entilate enclosed spaces. PROTECTIVE gloves EYE PROTECTION Not ordinarily reauired. Safety glasses. other protective eouipment None required for ordinary handling. For hot processing local exhaust, safety glasses ana gloves are recoinnended. SECTION IX SPECIAL PRECAUTIONS OS HAPRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING Standard I9l0.93q (. 1017) requires monitoring and other precautions in storage, handling and use of polyvinyl chloride, and also labeling PVC "Contains Vinyl Chloride-Vinyl Chloride is a Cancer-Suspect Agent". New PVC ins with a low monomer content make it easier to operate below the OSHA action level of 0.5ppm in a processor's work area, assuning normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developments on resins and on regulations are pending. DATf 3/12/84 NAME AND TTTLZ D. GOODMAN, PRODUCT REGULATIONS `t'ENOO 93 BMIET NUMBER ICO LTEMtCO Tenneco Pol* Tiers A TbiwscO Co^oany MATERIAL SAFETY DATA NUMBER 166 {Approved by U S. Oapartmam of Labor as "assantlally similar" to FORM OSHA-20) SECTION I IDENTIFICATION OF PRODUCT MANUFACTURERS HAM* TENNECO POLYMERS, INC., RESEARCH 4 DEVELOPMENT EMERGENCY TELEPHONE NO 609-386-9200 ADORESS RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822 TPAOC name AND synonTm-s CTTKE & 2022, 202ZA, 2024, 2025, 2052, 2060, 2300, 2385, 2580, TENNECO PVC COMPOUND, CABLE 2700, 2710C, 2710C4, 2712, 2714, 2730, 2775. 2780. 2800. chemical name ano synonyms 2803, 2804, 2814, 2SI4-1F, 2820, 2825 , 2826 , 2880 , 2900 , 2901-1 , POLYVINYL CHLORIDE) COMPOUND. PLASTTfI7ED (FLEXIBLE) 2905 29Q8, ?914, 2922, 2951 chemical family MOLECULAR FORMULA MOl_ NT CHLOROHYDROCARBON POLYMER (CHpCHCI )n SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT THRESHOLD % UMIT VALUE COMPONENT threshold % uaarT VALUE Antimony Compound (0-2.5%) Barium Compounds (0-0.8%) Carbon Black (0-1.2%) Diethylhexyl Phthalate (0- 30%) - 0.5 mg/m3 Diglycidyl Ether - 0.5 mg/m3 Lead Compounds - 3.5 mg/m; Mineral Oil - 5.0 mg/m3 Titaniun Dioxide (0-0.2%) - 0.5 (0-6.0%) - 0.2 mg/m:: (0-0.3%) - 5 mg/m; (0-7.0%) - 15 mg/m3 SECTION III PHYSICAL DATA appearance AND ODOR Colorless, white, black or colored pellets, practically odorless. BOILING POINT (DEGREES FAHRENHEIT) Not applicable VAPOR PRESSURE (MM OF MERCURY) Not applicable vapor D$mr (AIR * 1) Not applicable SOLUBILITY IN WATER Negligible ioIgrees^fahrenheit) Not applicable Softens about 160 - 180F SPECIFIC GRAVITY (WATER 11 1.22 - 1.48 percent volatile (BY WEIGHT) Essentially non-volatile Evaporation Rate (BUTYUACETATE = w Not applicable SECTION IV FIRE AND EXPLOSION HAZARD DATA flash point (specify metmcoi Not applicable (QpEOlaREsEStFiAchSizENeHErTO genera,l,ly over 400 F, C0C FLAMMABLE LIMITS (PERCENT SY VOLUME) LOWER Not applicable UPPER FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical. specialfire-fmshtingprocedures water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes. Shut off current in electrical equipment or wiring. unusual fire and explosion hazards nFPA lists ignition temperature of 608"F for PVC plasticizer dust cloud and miniimm concentration of 0.035 oz/cu. ft. Fire conditions produce hydrogen chloride, requiring protective equipment. TEN00 94 Thi, intormAtion I, lumianad without warranty. raomaantanon. inducamant or ueanaa oFiny kino, oieopl tnt .( i aecurata to tho o**t ot Tannaeo Polymora knowIMS* o' ootamad from aoortaa tMliavad Oy Ttnnoco Polymora 10 M accurate Tonnoco Polymer, Oom not urumi any iogal reaeonaiBilty for uM or rananca upon Mttw Cuatomora ara ancourasod to conduct tnair own taata Bator, uamp any product raad It, laoal ____________________________________ -(_ X SECTION V HEALTH HAZARD DATA THRESHOLD UNIT VALUE See Section II inters o* overexpcbure None expected In normal handling. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract, requiring local exhaust). emergency amo nwt mo i------- -Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing move to fresh air, flush eyes with water). SECTION VI REACTIVITY DATA STABILITY unstable stable Norma^coNomoNB to avoid processing temperature, about 350*F pauses slow darkening and decomppsition. Higher heat X increases rate and evolution of HCl. INCOMPATIBILITY (MAIRfiai, 10 XOMl None in ordinary use. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION products Thermal decomposition prod uces HC1, and CO and CO? (above 570F). HAZAROOUS polymerization may OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X None in ordinary use. SECTION VII SPILL OR LEAK PROCEDURES |TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep up and remove to disposal container. waste disposal method Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION PESWftATOflV PROTECTION (Specify typ*i None required in ordinary handling. See Section IX. LOCAL EXHAUST Tor not processing. MECHANICALJORARTAI} . . For orainarv handlina. PTcf^c&iGLgvfSves for hot processing. SPECIAL vent to stack or scrubber* \Zen\"i 1 ate enclosed spaces.________ EYE PROTECTION , Safety glasses. other protective equipment None required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recotnnended. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS to be taken in handung and storing OSHA Standard 1910.93q(.1017) on vinyl chloride limits axposure to lppm (8 hr av.) and requires monitoring and other precautions in storage, ^ndling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride - lyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject "mass melting", as defined. New, low monomer content PVC compounds simplify operatior )elow the OSHA O.Sppm action level and compliance, assming normal conditions and /entilation in a processor's work area. Further developments on resins and regulations ire pending.--------------- --------------------------------------------------------------------------------- TEWOO 95 DATE 3/12/84 NAME AMO TITLE D. GOODMAN, PROOUCT REGULATIONS SHEET NUMBER 166 Tenneco Poiymors A TBnriBCQ CotWOBRY MATERIAL SAFETY DATA NUMBER 167 (Approved by U S- Dapartmaot of Labor as "assantiaiiy similar'' to FOAM OSHA-X) SECTION I IDENTIFICATION OF PRODUCT MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. TENNECO POLYMERS, INC., RESEARCH AND DEVELOPMENT 609-386-9200 aooress P.0. BOX 129, RIVER ROAD, FLEMINGTON, NEW JERSEY 08822_ trade name anostnonyim EXTRUSION TENNECO PVC COMPOUND, & MOLDING 3026 , 3063 , 3066 , 3078 , 3083 , 3086 , 3092 , 3098, 3153M, 3159, 3160, 3169, 3179. 3189, 3200. 3211 CHEMICAL NAME AND SYNONYMS POLY(VINYL CHLORIDE) COMPOUND PLASTICIZED (FLEXIBLE) i"ucyirAi FAMILY CHLOROHYDROCARBON POLYMER | MOLECULAR formula JpHgCHCI )n __ mol wt SECTION II HAZAAOOUS COMPONENTS OF MIXTURES COMPONENT Bari tin Compounds Diethyl hexyl Phthalate Mineral Oil Tin Organic Comp. Epoxidized Soybean Oil THRESHOLD % LIMIT VALUE (UNITS) (0-1.3%) - 0.5 mg/m| (0- 38%) - 5 mg/nr (0-0.8%) - 5 mg/nw (0-2*3%) - 0.1 mg/m^ (Q-2.5%1 - 0.5 ma/m3 COMPONENT threshold % LIMIT value (UNITS) Titaniun Dioxide (0- 1%) - 15 mg/m3 Carbon Black (0-0.5%) - 3.5 mg/m3 SECTION III PHYSICAL DATA APPEARANCE ANO OOOP Colorless, white. black or colored pellets, practically odorless. BOILING POINT (0GPEES FAHRENHEIT) Not applicable VAPOR PRESSURE (MM OF MERCURY) Not applicable VAPOR OESITY iAlR * 1) Not applicable solubility in water Negligible id!grees'fahrenheit) Not applicable Softens about 160 - 180F SPECIFIC GRAVITY (WATER a 1) 1.20 - 1.40 PERCENT VOLATILE I8Y WEIGHT! Essentially non-volatile EVAPORATION RATE iButylaCetate = ti Not applicable SECTION IV FIRE ANO EXPLOSION HAZARD DATA flash point (sfecify methooi Not applicable (0EG8EESFAHRENHEIT) ,, "iasticizer generally over 400 F, COC flammable umits (PERCENT SY VOLUME) FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical. LOWER Not applicable UPPER SPECIAL FIRE-PIOHTING PROCEDURES Water spray or fog may be helpful in reducing flame intensity and absorbing irritating funes. Shut off current in electrical equipment or wiring. NF^Aunusual fire and explosion hazaros lists ignition temperature of 608'F for PVC-plasticizer dust cloud and minimtxn concentration of 0.035 oz.cu. ft. Fire conditions produce hydrogen chloride, requiring protective equipment.___________ TEN0096 Thia infonnatlOA I, lumiahad without warranty. fagraaantation. indueamant or iicaflM ol any mnd Iicwl tnat .< >, accural, to Iha Mat ot Tannoeo PolyiMf* anowiadga or oota<nod Horn aouieoa Bana*ad Oy Tannaco PWytnara to O* occurata Mid Tannoeo Poiymar, 300, not aaaum, any local raaoonaibtlty tar uao or rolioneo uoon tama Cuotomon ara aneouragad to conduct moir own ttatt Satora u ng any oroduct raad It, iteai SECTION V HEALTH HAZARD DATA JWWRRIESHOLD LIMIT VALUE ime Section II fmcrt or oviw*>ou None expected in normal handling. (Processing at high temperatures produces Irritating to eyes and respiratory tract, requiring local exhaust). fines EMERGENCY AMO AlO AMOC8XJHC1 Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing move to fresh air, flush eyes with water). SECTION VI REACTIVITY DATA STABILITY UNSTABLE STABLE conditions to avoio Normal processing temperature, about x 350*F, causes slow darkening and decomposition. Higher heat increases rate and evolution of HC1. INCOMPATIBILITY (M*tril* to *Ph None in ordinary use. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION products Thermal decomposition produces HC1, and CO and CO2 (above 570*F). HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X None in ordinary use. SECTION VII EPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SPILL OR LEAK PROCEDURES Sweep up and remove to disposal container. WASTE DISPOSAL method Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SppciIy typt\ None required in ordinary handling. See Section IX. VENTILATION (WWITrocesslin. handling. tf!lfLto stack or scrubber. tfSWilate enclosed spaces. protective gloves EYE PROTECTION Cotton gloves for hot processing. Safety glasses. other protective eowpment None required for ordinary handling. For exhaust, safety glasses and gloves are recoimended. hot processing local SECTION IX SPECIAL PRECAUTIONS OSHAprecautions to be taken in hanounq and storing Standard 1910.93q(. 1017) on vinyl chloride limits osure to lppm (8 hr av.) and requires monitoring and other precautions in storage, dling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to T,mass melting", as defined. New, Tow monomer content PVC compounds simplify operation below the OSHA 0.5ppm action level and compliance, assuring normal conditions and ventilation in a processor's work area. Further developments on resins and regulations are Pending._________________ _tfnoo97 lOATE NAME AND TITLE I SHEET NUMBER 1 LTWHtCOj Tenneco Polymers A l>nnco Company MATERIAL SAFETY DATA NUMBER 169 (Approve by U.S. Dapartmant ot Labor as "assantialty similar" to FORM OSHA-SO) SECTION 1 IDENTIFICATION OF PRODUCT MANUFACTURER'S NAME TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT AOORESS RIVER ROAD, P.0. BOX 129, FLEMIN6T0N, NEW JERSEY 08822 TAAOE NAME ANO SYNONYMS TENNECO PVC COMPOUND, RIGID CHEMICAL NAME ANO SYNONYMS P0LY(VINYL CHLORIDE) COMPOUND CHEMICAL FAMILY CHLOROHYDROCARBON POLYMER 3711, 3750, 4703 MOLECULAR FORMULA (CH2CHCl)n EMERGENCY TELEPHONE NO 609-386-9200 MOL WT SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT Carbon Black Lead Compounds Mineral Oil (0-0.6%) (0 - 4%) (0-0.5%) THRESHOLD % limit value (UNITS) COMPONENT THRESHOLD % limit value (UNITS) 3.5 mg/nr 0.2 mg/m3 5 mg/m3 Tin Organic Compound (0-2%) - 0.1 mg/m3 Titaniun Dioxide (0-1%) - 15 mg/m3 ' SECTION III PHYSICAL DATA appearance ano odor White, Black or Colored Pellets, practically odorless. SOILING POINT (DEGREES FAHRENHEIT) Not applicable MELTING POINT (degreesFahrenheit) Not applicable Softens about 160 - 180F VAPOR PRESSURE (MM OF MERCURY) Not applicable VAPOR desity (AiP 1) Not applicable solubility in water Negligible SPECIFIC GRAVITY (WATER > 1) 1.32 - 1.42 PERCENT VOLATILE (BY WEIGHT) Essentially non-volatile EVAPORATION rate IBUTYLACETATE = 11 Not applicable SECTION IV FIRE AN D EXPLOSION HA2AR D DATA iQmtlonflash point (Specify METHOD) about 735F dlltOi flammable limits <MfgnUYoffMlfeout 850F (ASTM D-1929) (PERCENT BY VOLUME) LOWER Not applicable. UPPER FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical * specialpire fightingprocedures Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes. Shut off current in electrical equipment or wiring. unusualpmeanoexplosionhazards NFPA lists ignition temperature of 752*F for layer and 1220"F for PVC dust cloud. Produces combustile gases above 570aF. Fire conditions produce hydrogen chloride, requiring protective equipment. TEN00 98 Thu information i* fumitnod without warranty, rapraaantation. mducamant or iieanaa 0( any kino, aicapt tnai >t ia acc-jrata to lha Mat of Tannaco Poiymar, knowtaoga e SECTION V HEALTH HAZARD OATA THRESHOLD LIMIT VALUE lip See Section II___________________________________________ ____ ___________________ ______ tmcTswoviwxnMi None expected in normal handling. (Processing at high temperatures produces funes irritating to eyes and respiratory tract, requiring local exhaust). emergency amo aia*t ajo procedures Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing move to fresh air, flush eyes with water). SECTION VI REACTIVITY DATA STABILITY UNSTABLE STABLE conditions to avoid Normal processing temperature, about 350F, causes slow darkening and decomposition. X Higher heat increases rate and evolution of HC1. INCOMPATIBILITY (Matviatt io *V0MI1 None in ordinary use. Soluble in certain ketones and orqanic solvents. HAZARDOUS DECOMPOSITION PROOUCTS Thermal decomposition produces HC1 and CO and CO? (above 570F). HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS to AVOIO X None in ordinary use. SECTION VII IAS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SRILLED SPILL OR LEAK PROCEDURES Sweep up and remove to disposal container. WASTE DISPOSAL METHOO Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SMOty tyc*> None required in ordinary handling. See Section IX. -LOCAL EXHAUST For not processing. -FMoECrHAoNrICdAiLn(GawrwyrU).hand!i. no. PROTECTIVE GLOVES Cotton gloves for hot processing. . SPECIAL t vent to stack or scrubber. V^rftf'ilate enclosed spaces. EYE PROTECTION Safety glasses. Noneother protective equipment required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recommend. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING )SHA Standard 1910.1017 (.93q) on vinyl chloride limits posure to lppm (8 hr av.) and requires monitoring and other precautions in storage, ndling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to mass melting", as defined. New, Tow monomer content PVC compounds simplify operation below the OSHA O.Sqpm action level and compliance, assuning normal conditions and ventilation in a processor's work area. Further developments on resins and regulations are pending.___________ ________________________________________ TENfltm- OATE , , N #A . NAME AND TITLE r. /-nCinuA*! nnnmirT OCClII ATTHMC bmcit number ICQ LTfBNECQj Tenneco Polymers a fconsco Company MATERIAL SAFETY DATA NUMBER (Approve by u.S. Departmint of Labor at "aaaantially similar" to FORM OSHA-20f SECTION 1 IDENTIFICATION OF PRODUCT MANUFACTURER'S NAME TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT aOORESS RIVER ROAD, P.0. BOX 129, FLEMINGT0N, NEW JERSEY 08822 EMERGENCY TELEPHONE NO 609-386-9200 TRADE NAME ANO SYNONYMS TENNECO PVC COMPOUND, RIGID 3773, 3774, 3775 CHEMICAL NAME ANO SYNONYMS POLY(VINYL CHLORIDE) COMPOUND CHEMICAL family CHL0R0HYDR0CARB0N POLYMER MOLECULAR FORMULA (CH2CHCl)n MOL. WT I j * t SECTION II COMPONENT HAZARDOUS COMPONENTS OF MIXTURES % THRESHOLD LIMIT VALUE (UNITS) COMPONENT Tin Organic Compound (0-3%) - 0.1 mg/m^ 9 % THRESHOLD UMIT VALUE (UNfTS) SECTION III PHYSICAL DATA APPEARANCE ANO ODOR White or colored pellets, practically odorless. BOILING POINT (DEGREES FAHRENHEIT) Not applicable melting point lOEGREES FAHRENHEIT) w0t rdd li cable l,u *" arr 1 ' c Softens about 160 - 180F VAPOR PRESSURE (MM. OF MERCURY) Not applicable i)SPECIFIC GRAVITY (water *35 ^7"77 O3, *3577775c 3774 71.4*4* - 1*.4a8w 1.40 - 1.44 VAPOR OCS1TY (AIR * 1) Not applicable SOLUBILITY IN WATER Negligible PERCENT VOLATILE (BY WEIGHT) Essentially evaporation rate non-volatile ibutylacetate * 11 Not applicable ! SECTION IV FIRE AND EXPLOSION HAZARD DATA flash point (s^cifymethooi Ignition about 735F auto flammable LIMITS ^^!TfifPMIBout 850* F (ASTM D-1929) (PERCENT BY VOLUME) lower Not applicable UPPER FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical. SPECIAL FIRE-FIGHTING PROCEDURES Water spray or fog may be helpful in reducing flame intensity and absorbing irritating funes. Shut off current in electrical equipment or wiring. unusual fire ano explosion hazards NFPA lists ignition temperature of 752'F for layer and 1220'F for PVC dust cloud. Produces combustible gases above 570*F. Fire conditions produce hydrogen chloride, requiring protective equipment. TENO 100 THib <e Jui-ftiBK+rt witiyvii Grammy finfunmiwi .rruumri HfSRx ol aftv eicsotthai i n irrurst* m i^ msi r* Pnivmefi knowiade* Of I SECTION V HEALTH HAZARD DATA > LIMIT VALUE fee Section II effects on ovcMxrcauM None expected In normal handling. (Processing at high temperatures produces funes irritating to eyes and respiratory tract, requiring local exhaust). fMEROENCY AMO FW*T AIO MOC&XiM* Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing, move to fresh air, flush eyes with water) SECTION VI REACTIVITY DATA STABILITY UNSTABLE STABLE INCOMPATIBILITY (Matarialt lo vOKT. None in ordinary use. conditions to Avao Normal processing temperature, about 350F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition produces HC1, and CO and CO2 (above 570*F). HAZARDOUS POLYMEKlZATION MAY OCCUR WILL NOT OCCUR CONDITIONS to avoid X None in ordinary use. , S SECTION VII SPILL OR LEAK PROCEDURES STEPS to BE taken IN CASE material is released or SPILLED Sweep up and remove to disposal container. waste disposal method Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Sppciiy typPI None required in ordinary handling. See Section IX. VENTILATION LOCAL EXHAUST For not processing. ^cHAwcA^owy handling. V^nt^to stack or scrubber. !\/eTnilate enclosed spaces. PROTECTIVE GLOVES EYE PROTECTION Cotton gloves for hot processing. Safety glasses. None requi redother protective equipment tor ordinary handling, hor hot processing local exhaust, safety glasses and gloves are reconmended. SECTION IX SPECIAL PRECAUTIONS jaecAUTioMs to c taken in handling and stoking OSHA Standard 1910.101?(. 93q) on vinyl chlori de TTmTts posure to lppm (8 hr av.) and requires monitoring and other precautions in storage, brandling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride - Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to mass melting", as defined. New, Tow monomer content PVC compounds sinplify operation below the OSHA O.Sppm action level and conpliance, asswring normal condition; and ventilation in a processor's work area. Further developments on resins and regulations are pending. TENO 101 Tenneco Polymers A T#no#co Cofnpsny MATERIAL SAFETY DATA (Approved by U.S. Ooportmortt of Libor "osiontio/ly timihr" to FOAM 0SHA-30) NUMBER 200 SECTION I IDENTIFICATION OF PRODUCT MANUFACTURER'S ***** TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT AOORESS RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822 EMERGENCY TELEPHONE NO. 609-386-9200 trade name ano synonyms TENNECO PVC COMPOUND, RIGID 3780, 3782 CHEMICAL name ANO SYNONYMS POLY(VINYL CHLORIDE) COMPOUND CHEMICAL FAMILY CHL0R0HYDR0CAR80N POLYMER MOLECULAR FORMULA (CH2CHC1),, MOL. WT SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT Tin Organic Compound THRESHOLD % limit value (UNITS) (0-3%) - 0.1 mg/m'* COMPONENT Acrylic Resin (0-2%) - 10 mg/m3 (ACGIH) threshold % LIMIT VALUE (UNITS) SECTION III PHYSICAL DATA appearance and ooor White or colored pellets, practically odorless. BOILING POINT (DEGREES FAHRENHEIT) Not applicable VAPOR PRESSURE (MM. OF MERCURY) Not applicable VAPOR DESITY (AIR m 1) Not applicable SOLUBILITY IN WATER Negligible (MDEeLgTrINeGesPFOaINhTrenheit) .N.o.t applicable Softens about 160 - 180F SPECIFIC GRAVITY (WATER * D 1.32 - 1.42 PERCENT VOLATILE (BY WEIGHT) Essentially non-volatile EVAPORATION RATE (BUTYLACETATE * 11 Not applicable SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (SPECIFY METHOD) T an 1 H On about 735F auto-(DECREES FAHRENHEIT) flammable umits (PERCENT BY VOLUME) igmtion about 850F (ASTM D-19291 FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical LOWER Not applicable UPPER SPECIAL FIRE-FIGHTING PROCEDURES Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes. Shut off current in electrical equipment or wiring. unusual fire and explosion hazards nFPA lists ignition temperature of 752 F for layer and 1220F for PVC dust cloud. Produces combustible gases above 570*F. Fire conditions produce hydrogen chloride, requiring protective equipment. TEN0 102 TTil, intonnpinni< Iihaipam JtPOMt wrrntr..'pmantition Inpuepmpnt of iiepnMOl iny kind. ic*e< tn,i it , iccurit, t0 Phi of T*nr*co Poiymw, knowi*dgiy SECTION V HEALTH HAZARD DATA THRESHOLD UM1T VALUE See Section II M^P_t_E_C__T_*or overexposure None expected In normal handling. (Processing at high temperatures produces Irritating to eyes and respiratory tract, requiring local exhaust). fumes EMERGENCY ANO FIRST AlO PROCEDURES Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot proce-sing, move to fresh air, flush eyes with water). SECTION VI REACTIVITY DATA STABILITY UNSTABLE STABLE conditions to avoio Normal processing temperature, about 350*F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1. INCOMPATIBILITY (Matanai* to l*oT None in ordinary use. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition proc uces HC1, and CO and CO? (above 570F). HAZARDOUS polymerization MAY OCCUR WILL NOT OCCUR conditions to avoio X None in ordinary use. SECTION VII SPILL OR LEAK PROCEDURES PS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SRILLED Sweep up and remove to disposal container. waste disposal mEThoo Bury in an approved landfill. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION <SpAeif> iypi None requi red in ordinary handling. See Section IX. VENTILATION local exhaust For hot Drocessina. handling. ^tfr#rfL<2)1t>ves for hot processing. ^encLto stack or scrubber. ifen^ilate enclosed spaces. EYE PROTECTION _ _ . . Safety glasses. other protective eowpment None required for ordinary hamdling. For hot processing local exhaust, safety alasses and qloves are recommeinded. 1 SECTION IX SPECIAL PRECAUTIONS OSHAprecautions to be taken in handling and storing Standard 1510.101?(. $3q) on vinyl chloride limits osure to lppm (8 hr av.) and requires monitoring and other precautions in storage, f dling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride yl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to Tlma$s melting" as defined. New, low monomer content PVC compounds simplify operation jelow the OSHA O.Sppm action level and compliance, assuming normal conditions and ventilation in a processor's work area. Further developments on resins and regulations a-r-e-----p--e--n--d--i-n-g--.--------------------------------------------------------------------------------------------------------------- Tm 1q3--------------- 0ATE 3/12/84 Dname and title GOODMAN, PRODUCT REGULATIONS 200SHEET number [TCNNCCQJ Tenneco Polymers AlfcnrttCO Company MATERIAL SAFETY DATA NUMBER 168 (Approved by U.S. Dapartmant of Labor as "assantiaity similar" to FORM OSHA-20) SECTION 1 IDENTIFICATION OF PROOUCT MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. TENNECO POLYMERS, INC., RESEARCH AND DEVELOPMENT 609-386-9200 ADDRESS P.0. BOX 129, RIVER ROAD, FLEMINGT0N, NEW JERSEY 03822 traoe name and synonyms 1684, 1688, 1689, 1755-1 , 1755-5, 1776-2, TENNECO PVC COMPOUND, RECORD 1809, 1815-2 , 1820-6 CHEMICAL NAME AND SYNONYMS VINYL CHLORIDE - VINYL ACETATE COPOLYMER CHEMICAL FAMILY CHL0R0HYDR0CARB0N COPOLYMER MOLECULAR FORMULA (CH2CHC1) x fCH?CH0C0CH3*v mol. wt SECTION II HAZARDOUS COMPONENTS OF MIXTURES COMPONENT THRESHOLD V. LIMIT value (UNITS) COMPONENT Carbon Black (0.1-1%) - 3.5 mg/m3 Lead Compounds (0 -2%) - 0.2 mg/m3 THRESHOLD % LIMIT VALUE (UNJTSJ SECTION III APPEARANCE AND ODOR Black pellets, practically odorless BOILING POINT (DEGREES FAHRENHEIT) Not app1icable VAPOR PRESSURE (MM OF MERCURY) Not applicable VAPOR OESITY (AIR =1) Not applicable SOLUBILITY IN WATER Negligible PHYSICAL DATA MELTING POINT (DegreesFahrenheit) Not applicable Softens about 130-150F SPECIFIC GRAVITY (WATER - 1) 1.35 - 1.39 percent volatile (BY WEIGHT! Essentially non-volatile evaporation rate (Butylacetate n Not applicable SECTION IV FIRE AND EXPLOSION HAZARO DATA I qn 11 On about 735F(FOLEAGSRHEPEOSIFNaTh(SrPeEnChIFeYitM) ETHOfDQl r^v1 c (AST^ 0-1929) FLAMMABLE UMITS (PERCENT BY VOLUMEl fire EXTINGUISHING MEDIA Water spray, carbon dioxide or dry chemical lower UPPER Not applicable________ SPECIAL FIRE FIGHTING procedures Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fines. Shut off current in electrical equipment or wiring. unusual fire and explosion hazaros nhPa lists ignition temperature of 608F for PVC-plasticizer dust cloud and minimun concentration of 0.035 oz./cu. ft. Fire condi tipQV Deduce hydrogen chloride, requiring protective equipment. TENT)'04 Tun infwmatlon I, lumnnad Wimout iramy. rwnwnntio" induowni tx Hchm o< ,ny >ind mcppi tun 1 1 Kcmm to m owl 01 Tnneo Polym#., imowiup* o> SECTION V HEALTH HAZARD DATA HWSHOLO LIMIT VALUE f\ See Section II___________________________________________ _____ ____________ EFFECTS OK OVEREXPOSURE None expected In normal handling. (Processing at high temperatures produces irritating to eyes and respiratory tract, requiring local exhaust). funes EMERGENCY AMO FIRST AID PROCEDURES ~ Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing move to fresh air, flush eyes with water). SECTION VI REACTIVITY DATA stability UNSTABLE STABLE Normalconditions to avoid processing temperature, about 350*F causes slow darkening and decomposition. Higher x heat increases rate and evolution of HC1. INCOMPATIBILITY (Malarial, to *OMl> None in ordinary use. Soluble in certain ketones and organic solvents. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition produces HC1, and CO and CO? (above 570F). HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS to avoid X None in ordinary use. SECTION VII SPILL OR LEAK PROCEDURES TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep up and remove to disposal container. waste Disposal method Bury in an approved landfill SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY protection (Sppcily tytwi None required in ordinary handling. See Section IX. ventilation XOCAL .EXHAUST For hotiprocessinq. F^MoECrHAoNIrCdALin(GawrWyfill ,han.d.l.ing. ^en'^to stack or scrubber. tfenilate enclosed spaces. protective gloves EYE PROTECTION Cotton gloves for hot processing. Safety glasses. other protective eowpment None required for ordinary handling. For hot processing exhaust, safety glasses and gloves are recommended. local SECTION IX SPECIAL PRECAUTIONS precautions to se taken iH hanoling ano storinq OS HA Standard 1910.9 3q (.1017) on vinyl chloride limits ^hpsure to lppm (8 hrs av.) and requires monitoring and other precautions in storage Iwdling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride - Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to t'mass melting", as defined. New, Tow monomer content PVC compounds simplify operation below the OSHA O.Sppm action level and compliance, assuning normal conditions and ventilation in a.processor's work area. Further developments on resins and regulations are pending._____________________ ______________ ________________ TENO 105_________ DATE /a n /* a NAME ANO TtTiW T1 JINNCCO, MATERIAL SAFETY DATA SHEE tenneco POLYMERS, INC. ?. 0. BOX 2511 HOUSTON, TX 77001 1. MATERIAL IDENTIFICATION 1material trade NAME synonyms Methyl Met hanol Alcohol, Wood Alcohol, 2* hour emergency telephone tenneco 713 179.3111 Carblnol wochemtrec pep-moo /chemical family formula Alcohols /CH^OH CAS NO. 67-56-1 II. INGREDIENTS material .Methanol MBOBNO. nn0RT,VJ; HAZARD RATING* 1- 1 m (IT-) health FIRE REACTIVITY 0 LEAST 3 HIGH 1 SLIGHT 4 EXTREME 2 MODERATE . NFpA 704 COMPOSITION Methyl Alcohol % 99*9 toxicity oata 8 hr TWA 200ppm (260mg/m^) (skin) Human Eye-5ppm Oral-LDLo 3k0mg/kg _ Inhalation-TCLo 86o00mg/ni (irritate: Rat - Oral LD^q I3gm/kg III. PHYSICAL OATA | --SOILING POINT. 70n*m/Hg ! SPECIFIC GRAVITY. Hj0= 1 -- --! VAPOR PRESSURE. mnVHg VAPOR DENSITY, AIR x 1 -- lL8F (61.5C) 0.791 96 % 68F ( 20C ) 1.11 o, hsolubility in h j by weight - * \ -evaporation rate, butal acetate Molecular Weight Melting Point -- - Totally misci: 1.6 32.01 -lllF (-97.:" %VOLATILES. BY VOLUME -- 100 appearanceanoooor Clear, colorless liquid with characteristic alcohol odor, less pure grades may have a pungent, oily odor. IV FIRE AMO EXPLOGWN DATA FLASH POINT ANO TEST METHOD 5bF (12.2C) TCC AUTO IGNITION temperature 867F (161c) FLLMMABIUTY UMITS IN AIN. % BY VOLUME LOWER 6 UPPER 36.5 EXINGUISHING MEDIA Dry chemical, alcohol type foam, COjg, . Water may be ineffective. Use water spray to cool fire exposed containers. Use alcor.nl resistant foam to extinguish large fires or to blanket spill to reduce vapors- SPECIAL PIPE FIGHTING PROCEDURES Class 13 flammable liquid. Avoid water streams which may splash and spread flamming liquid. Vapors are heavier than air and may flow along surfaces to distant ignition sources and flash back. Fire fighters shoul UNUSUAL FIRE AND EXPLOSION HAZARDS use self-contained breathing equipment and protective clothing for fires enclosed areas. TEN(fl06 Reacts violently to oxidizers. Keep away from heat, sources of .gr.ition. 3urns with a clear, almost invisible flame, especially hard to see in str jVt* lACTIVfTY DATA staEutv I x] STABLE 1 HAZAPOQUS POtnMMZATlON i UNSTABLE | | MAY OCCUR M309 NO. 1 C PAGE 2 OP 4 MATfWAL Vi- - i (y 1 WILL NOT OCCUR coNornoNS ano matcnals to avoid Avoid strong oxidizing agents, excessive heat, sources of ignition. hazaaoous oecoMPosrnoN pmooucts carbon monoxide, carbon dioxide VL OCCUPATIONAL EXPOSURE UNITS OSHA TLV - 200ppm 8 hr TWA (afiOrng/m^) Skin ACGIH(198L) adds"Skin" notation V1L HEALTH INFORMATION Methanol is a poisonous chemical that can affect the body through inhalation, shin ^sorption or ingestion. ^^nalation causes dizziness, nausea, visual impairment, respiratory failure, muscular incoordination, and narcosis. Ingestion can produce blindness, dizziness, headache and in amounts of 10Q-250ml can be fatal. Skin contact causes irritation, dryness, dermatitis and erythema. Eye contact causes irritation. Toxic effects from repeated over exposure to methanol are accumulative ar.d effect the I central nervous system, especially the optic nerve. These symptons may linger for several days after exposures. VH. EMERGENCY AND FIRST AID PROCEDURES Skin - wash with soap and water immediately after contact. immediately. Launder before reuse. Remove contaminated clothing Eyes - Flush with large amounts of water for 15 minutes, getting under eyelids. Contact physician if irritation persists. Inhalation - remove to fresh air. Restore breathing if necessary. Administer oxygen if breaching difficulty persists and contact physician for advice. Ingestion - Drink large amounts of water, milk or sodium bicarbonate to dilute material in stcmach. Induce vomiting if victim is conscious. Consult physician for additional advice and treatment. TENO 107 Page 3 OF 4 "*0* NO. MATERIAL ________ _____________________________________________________________________ 110 _______ vr^n:; IX EMPLOYEE PROTECTION__________________________________________________________________________ RESPIRATORY PROTECTION Provide adequate ventilation or exhaust to meet TLV requirements. Air supplied or self-contained breathing equipment recommended for exposures above TLV. PROTECTIVE CLOTHING Rubber gloves and rubber protective aprons or clothing required to prevent shin contact. Goggles or face shield should be used to protect face and eyes from splashing. other PROTECTIVE MEASURES Eye wash and safety shower should be provided in area of use. X ENVIRONMENTAL PROTECTION SPILL CLEAN-UP PROCEDURE Eliminate all ignition sources. Stop spill or leak if it can be done safely. Contain spill to smallest area possible. Use absorbent materials to soak up small spills. Larger spills should be recovered for reuse or disposal. Spills in critical areas can be diluted with water to reduce fire hazard during cleanup. Do not allow to material to enter sewers, drains or waterways. waste disposal Waste materials should be disposed of by a licensed solvent waste disposal company. Federal, state and local regulations msut be followed. ENVIRONMENTAL HAZARDS Aquatic toxicity rating - TLm 9&: over 1000 ppm. XI. SPECIAL PRECWraOWM________________________________________________________________________ Store in closed containers in cool place. No smoking allowed in areas of use or storage. Use explosion-proof electrical fixtures. Containers should be electrically grounded/bonded during material transfer to prevent static spark. Corrosive to lead and aluminum. TENO 108 TRANSPORTATION REQUIREMENTS DOT SHIPPING NAMI Methanol or methyl alcohol OOT CLASSIFICATION Flammable liquid IMCO class - 3.2 MSOSNO 1IQ PAGE t OF 4 MATERIAL ooti.o.no.un hazaao class UII1230 UN1230 XIH. OTHER REOULATORY CONTROLS None determined THIS INFORMATION relates only TO the SPECIFIC material DESIGNATED AND may not be valid for such material used in combination with any other materials OR in any PROCESS. SUCH information is TO the BEST of this company s knowledge ano BELiEVEO accurate and reliable as OP the DATE INDICATED. HOWEVER, no REPRESENTATION. WARRANTY or GUARANTEE is MADE AS to ITS ACCURACY. RELIASILTY or COMRLfTtNSSS. IT IS THE USERS RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITASLENESS ANO COMPLETENESS OF SUCH INFORMATION FOR NIB OWN PARTICULAR USE. TENNECO POLYMERS INC. P. 0. BOX 2511 HOUSTON, TX TT001 A TENMICO COMPANY DATE PREPARED August , 1985 approved sy E. Wayne Drusch TENNECO OIL PROCESSING & MARKETING (713) 757-3113 rocatt* n* TENO 109