Document bO0MY0G5xONqDV11K1RQGwwZ0

//ff/fysf-zyCSC- - ^^7 'S-eJ-Zpo 0UT>#-t J//H " ZDe*"^ 'f rfcS1*r td P.O. Box 1410 - 1600 E. Hill St., Long Beach, CA 90801 - Telephone: (213) 427-5471 IMPORTANT SAFETY INFORMATION DO NOT DISCARD March 1989 GS ROOFING PRODUCTS CO P 0 BOX 70339 CHARLESTON HGTS SC 29405 0035 Attn: Safety Manager In accordance with "right-to-know," laws and the OSHA Hazard Communi cation Standard (29 CFR 1910.1200), Petrolane is sending you the enclosed Material Safety Data Sheet (MSDS). Study the MSDS prior to product use and make it available to each of your employees who handle and use the product. If you resell the product, provide an MSDS to your customers. We call attention to the information relating to odorization of propane which can be found in Section III, "Physical Data." The following paragraphs elaborate on the MSDS information. Discuss this material with your employees. A small amount of a foul smelling odorant is added to propane to act as a warning agent in case of leakage or accidental release. All odorants have limitations. For instance, some people have a perma nently impaired sense of smell. Colds and allergies can cause a temporary reduction in ability to smell. The propane odor can be masked by competing strong odors. High concentrations of the odorant can temporarily desensitize a person's sense of smell. The most common odorant, ethyl mercaptan,`can be converted to a less, odorous compound by oxidation. The.phenomenon is called "odor fade." Oxidizers are most usually rust, moisture and air. A new tank -just placed in service is susceptible to odor fade. Several fills of the tank may be required before the oxidation reaction is completed. You can reduce the potential for odor fade. Every propane container must be purged of moisture and air before first use. Never leave an empty container open to the atmosphere after use because air and moisture could reactivate the oxidation process. Regularly check the odor level in a tank. Call us if the odor level is faint. Petrolane appreciates your business. We will continue to supply quality products and service along with the information necessary for you to maintain a safe, healthful workplace. Petrolane Safety Department BIRD 022695 MATERIAL SAFETY DATA SHEET P.O. Drawer 1410 - 1600 E. Hill St. Long Beach. CA 90801 Contact: Safety Department - Telephone: (213) 427-5471 February 1989 WARNING STATEMENT DANGER! Extremely Flammable. Keep away from heat sparks and open flame. Vapor reduces oxygen available for breathing and may cause suffocation in confined spaces. Use only with adequate ventilation. Odor mav not provide adeouate warning of potentially hazardous concentrations. Vapor is heavier than air and collects in low levels. Liquid mav cause freeze bum similar to frostbite. E ProductldOTtiftcatton^^ Product Name: Petrolane Propane Chemical Name: Propane Transportation Emergency Telephone: 800-424-9300 (CFEMTREC) Synonyms: LP-Gas. Bottled Gas Chemical Family: Paraffinic Hydrocarbon Chemical Formula: C,H, DOT Proper Shipping Name: Liquefied Petroleum Gas DOT Hazard Class: Flammable Gas NFPA Classification: Health 1 Slightly Toxic Fire 4 Extremely Flammable Reactivity 0 Stable DOT ID. Number UN1Q75........................................... m "Hazardous Irigred t entsSj 0SHA ACGIH Component CAS Number % PEL Ty/ Ethane 74-84-0 0-6 None established Simple asphyxiant Propane 74-98-6 87-97 1000 ppm (8hr) Simple asphyxiant Propylene 115-07-1 0-5 None established Simple asphyxiant Butane 106-97-8 0-Z5 None established 800 ppm (8 hr) Six? Boiling Point: -44F % Volatile by Volume: 100% Melting Point: -309eF Solubility in Water Insoluble Vapor Pressure: 208 psig (max.) @ 100F Evaporation RateIBu Ac-1): N/A Vapor Density (Air=1): 1.5 Gas Volume @ Atm. Pressure & 60 F Specific Gravity (H,0=1): 0.504 (Cu. ft gas/gal. liquid): 36.4 Appearance and Odor Colorless, odorless in pure form. Propane contains a foul smelling, skunk-like warning agent(odorant). The odorant is effective, in most instances, but not everyone can smell the odor. The ability of people to detect odors varies widely. Also, certain chemical reactions with material in the propane system can reduce the propane odor level. No odorant will be 100% effective in all circumstances. If odor level appears to be weak, notify propane supplier immediately. ftfna--iand ^xo-losil onk-Qa;t;il Flash Point (Method Used): -156"F (estimated) Flammable Limits (% Volume in Air): Lower 2.1% Upper 9.5% Extinguishing Media: Dry chemical, foam or C02 for small fires. Stop flow of gas firsL Special Fire Fighting Procedures and Precautions: Elimimate sources of ignition. Evacuate area. Notify fire department. Allow only trained, properly protected personnel in area. Shut off source of gas, if possible. Allow fire to bum itself out after gas flow is shut off. High volume water supply can be used to cool heat-exposed pressure containers and nearby equipment. Approach a flame enveloped container from the side, never the head ends. Use extreme caution when applying water to a container which has been exposed to heat or flame for more than a short time. Shock of cool water on hot metal could cause container rupture. For uncontrollable fires and when flame is impinging on container, withdraw all personnel and evacuate surrounding vicinity immediately. Unusual Fire and Explosion Hazards: Products of combustion may yield carbon monoxide, a toxic gas. Uncontrolled vapors spread rapidly, are heavier than air and are extremely flammable. RaactlvttvPatal Stability: Stable Conditions to Avoid: High heat sparks, open flame Materials to Avoid: Strong oxidizing agents Hazardous Decomposition Products: Incomplete combustion can cause carbon monoxide, a toxic gas. Hazardous Polymerization: Will not occur Conditions to Avoid: None BIRD 022696 VI .-Heal th Hazard Dattfl t Product is not listed as carcinogenic by NIP, IARC or OSHA. Product may contain a trace, but detectable amount of benzene, a chemical listed by the State of California and known to cause cancer or reproductive toxicity. Routes of Entry / Acute Effects of Overexposure: Inhalation: Exposure to high concentrations of the vapor causes dizziness, drowsiness, nausea or unconsciousness due to anesthetic properties. Skin Contact: Liquid can cause freeze bums similar to frostbite if contact with skin occurs. No skin absorption is expected. Eye Contact: Liquid can cause freeze bums if contact with eyes occurs. Ingestion: Ingestion is not expected to occur in normal use. Chronic Effects of Overexposure: No abnormal reactions reported following exposure to 1000 ppm for 8 hours per day, 5 days per week, for 2 weeks. Medical Conditions Generally Aggravated by Exposure: Persons with chronic respiratory diseases should avoid exposure. VII: 'U" Emergency and FirstAldProceduresi Eye Contact: Flush with water. Obtain medical assistance if contact with liquid has occurred. Skin Contact: If freeze bum occurs, remove contaminated clothes, shoes and jewelry. Immerse burned area in warm (not hot) water. Keep immersed. Call for medical assistance. Inhalation: Remove victim from further exposure and into fresh air. Provide oxygen if breathing is labored. If victim , is unconscious, seek immediate medical attention. If breathing has stopped, give artificial respiration. Ingestion: Not expected to occur in normal use. VIII. Spi:i 1 or Leak Procedures7) Product is extremely flammable. Vapor is heavier than air and may collect at lower levels. Flammable concentrations may be present helow nose level. If there is a leak but no fire, do not light the escaped gas. Eliminate all ignition sources. Do not smoke, use a nearby phone nr actuate electrical switches. Evacuate the area. If possible, remove leaking container to safe area. Stop flow of gas or allow vapor to disperse in a safe area. Water spray can be used to help dilute vapor concentration in air. Dispose of gas only by controlled burning in compliance with local laws and regulations. llX.: Hantfl ing ;andStorage Precautions 1 Store in an authorized location (outside, detached storage is preferred) with adequate ventilation. Keep away from heat and ignition sources. Inspect cylinders frequently for leaks, dents, gouges and corrosion with emphasis on bottom of cylinder. Store cylinders in upright position or with pressure relief valves in vapor space. Do not drop or abuse cylinders. Keep container valve closed and plugged when not in use. install protective caps when cylinders are not connected for use. Empty containers retain some residue, so they should be treated as if they are full. lx. : : Personal Protection -Information I Ventilation: Use adequate ventilation to maintain exposures below recommended limits. Respiratory Protection: Use a NIOSH-approved respirator if area is thought to contain unknown concentration of gas. Eye Protection: Use safety goggles or safety glasses with side shields. Protective Clothing: No special garments are necessary, but avoid skin contact with liquid because of possibility of Ireeze bum. Propane resistant gloves are recommended. PCI v Communtcationwith EmaloveBs and Purehasers -. v i This Material Safety Data Sheet (MSDS) alerts the reader to the potential safety and health hazards of propane. It also contains valuable reference material relating to the sate use and handling of the product. Make sure that this information is shared with all employees and purchasers wno use or handle the product. It is an important part of the OSHA hazard communication program. This information is believed to be accurate as of the date of issue, but is offered without guarantee. Conditions of use and suitability far use are beyond Company control, therefore, all risks of use of the product are assumed by the user. COMPANY EXPRESSLY DISCLAIMS ALL WARRANTIES DF EVERY KIND INCLUDING WARRANTIES OF MERCHANTIBILITY AND FITNESS FOR ANY PARTICULAR PURPOSE. Company assumes no responsibility for any Injuries or damages caused by the product even if safety procedures are followed as outlined herein. Nothing herein is Intended to be construed as permission or recommendation for use of the product in any manner which might infringe existing patents. ________________________________________________ BIRD 022697 MATERIAL SAFETY DATA SHEET P.O. Drawer 1410 - 1600 E. Hill St, Long Beach. CA 90801 Contact; Safety Department - Telephone: (213) 427-5471 Ha ::Wami hg:Stateerrt;;i DANGER! Extremely Flammable. ' Vapor re'duces oxygen available for breathing and may cause suffocation in confined spaces. Liquid may cause freeze bum similar to frostbite. lna::;:::;:Pr<3eluct.v3cteht1fja5a -'C Product Name: petrolane Propane Chemical l^me: Propane Synonyms: L^Gas, Bottled eas Chemical Family: Paraffinic Hydrocarbon Chemical Formula:^. C3H, Transportation Emergency Telephone: 800-424-9300 (CHEMTREC) NFPA Classification: . Health I ^Siightly Toxic - - --^-fefSKteemelv Flamroahlfry??- __ ~ ill vHaaa Composition (Typical) % (aoprox.) Exposure Limits Propane Propylene Butane 92 0SHA PEL for Propane is 1,000 ppm (8 hrs.) 5 ACGIH TLV: Simple Asphyxiant (propane) 3 Product is a simple-asphyxiant in high concentrations. Product is not listed as a carcinogen or potential carcinogen by NTP, 1ARC or 0SHA. HV.^-V'.-.Rhvsieal .Data ij Boiling Point: -44F Specific Gravity (H20=1): 0.507 Vapor Pressure: 208 psig (max) @ 100F % Volatile by Volume: 100% Vapo* Density (Air=1): U Solubility in Water: insoluble Appearance and Odorr Colorless liquefied petroleum gas. Propane sold for fuel contains a foul smelling warning agent (odorant). figaetl.V^ty-.OataTr Stability: Stable Hazardous Polymerization: Will not occur Hazardous Decomposition Products: Incomplete combustion can cause carbon monoxide. Materials to Avoid: -Strong oxidizing agents IV.I.-.:.: - F:treiand :.Exotosion ;OataTl Flash Point (Method Used): -156F (estimated) Flammable Limits (% Volume in Air): Lower 2.1% Upper 9.5% Extinguishing Media: Dry chemical, foam or C02 for small fires. Stop flow of gas first. . Special Fire Fighting Procedures and Precautions: Evacuate area. Notify fire department. Allow only properly protected personnel in area. Shut off source of gas, if possible. Allow fire to bum until gas flow is shut off. Adequate water stream can be used to cool exposed equipment and vapor space of containers. Approach a flame enveloped container from the side, never the head ends. For massive, uncontrollable, fires and when .flame Js....impinging on. vapor jspace of _containers,, withdraw - Fire and Explosion Hazards: Products of combustion may yield carbon monxide. Uncontrolled vapors spread rapidly, are heavier than air and are extremely flammable.' April 1985 BIRD 022698 < Vir.i -t Handling; and'StoragePrecauttonsTl ' Store in an authorized location (outside, detached storage is preferred) with adequate ventilation. Keep away from heat and ignition sources, inspect cylinders frequently for leaks, dents, gouges and corrosion with emphasis on bottom of cylinder. Store cylinders in upright position. Do not drop or abuse cylinders. Keep container valve closed and plugged when not in use. Install protective caps when cylinders are not connected for use. IVIXI. POT ^Transportatlon Oata?:] Shipping Name: Liquefied Petroleum Gas Hazard Class: Flammable Gas US. Number. l)N 1075 g-X.':- : Health iHazartt-Oata:;! Marking: Liquefied Petroleum Gas / UN 1075 Label: Flammable Gas Placard: Flammable Gas / UN 1075 Effects of Overexposure: Liquid can cause freeze bums similar to frostbite if contact with skin occurs. Large concentration of vapor in atmosphere can cause asphyxiation due to oxygen displacement Inhalation of smaller quantities of vapor can cause respiratory irritation, dizziness, nausea or drowsiness. & ;-6inergeiwy^and^,trst.yAt<3'.-Rroceciuresvj y;:'-Eye. Conte't^^J^Vwith^waGr.^QWjpnr^ Skitrd^aetf^f^ffWM!:hum^c^r3;::remw^ burned area in warm (not hod''water. - Keep7~irmriersed. ^ Callfor medical., assistance.' ' ?,.' Inhalation: Remove victim from further exposure and into fresh air. Provide oxygen if breathing is labored. If victim is unconscious, seek immediate medical attention. - If breathing has stopped^ give artificial respiration. Ingestion: Not expected to occur in normal use. pay- ^Personal:^Protection Informatlon ) Ventilation: Use adequate ventilation to maintain exposures below recommended limits^ Respiratory Protection: - Use a NIOSH-approved respirator if area is thought to contain unknown concentration of gas. Eye Protection: Use. safety goggles or safety glasses with side shields. Protective Clothing: No .special garments are necessary, but avoid skin contact with liquid because of-possibility of freeze bum. Propane resistant gloves are recommended. pCIX - .Sp.(l;l.i;or`.-M:eak^.Preceffiires-.-i Product is extremely flammable. If there is a leak but no fire, do not ignite the gas. Eliminate ail ignition sources. Evacuate the area. If possible, remove leaking container to safe area. Stop flow of gas or allow vapor to disperse in a safe area. Use water spray to help dilute vapor concentration in the air. Dispose of gas only by controlled burning in compliance with local laws and regulations. IXIIX, Communication :^l*h.:;Ensx1^etM::and.;Purehaseri?( This Material Safety Data Sheet (MSDS) alerts the reader to the potential safety and health hazards of propane. It also contains valuable reference material relating to the safe use and handling of the product Make sure that this information is shared with all employees and purchasers wrtio use or handle the product. It is an important part of die OSHA hazard communication program. This information is believed to be accurate as of the date of issue, but is offered without guarantee. Conditions of use and suitability for use are beyond Company control, therefore, all risks of use of the product are assumed by the user, company expressly disclaims all warranties. of_.-eyery.Jc.ind _lnc.lud.ing-Warranties _of..merchantltaili ty-and.jf.Ltness_far.any_____________________ caused by=-the;'pmduct-^eh^if^afei^T^*odSxj^^ere-fOTTewed-a^'6utTTfd-heTO^;-^Rdthi n`ir^: herein is Intended to be construed as permission or recommendation for use of the product in any manner which might infringe existing patents. ____________ __________________________________ BIRD 022699