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FROM A. B. MC KEE ALCOA TECHNICAL CENTER - C TO MEMBERS, CORPORATE HAZARDOUS MATERIALS CONTROL COMMITTEE 1980 August 28 RE: ALCOA MATERIAL SAFETY DATA SHEET MANUAL AMSDS No. 91, 114-122 For Preliminary Review and Comments _______ Please Respond by 1980 September 11______________ AMSDS NO. 91 114 115 116 117 118 119 120 121 122 Alcoa Electrical Joint Compound No. Fryquel 550 Hydraulic Fluid (ML925) Copper Sulfate Hydrogen Chloride Gas, Anhydrous 2-Nitropropane Pyridine Aluminum Fluoride Ammonium Hydroxide (ca 28%) Aniline Chlorobenzene SEP 3 - 1980 A. B. MC KEE ABM:km Attachment cc: Members of Corporate Hazardous Materials Control Committee H. P. Brueschke, Pittsburgh 19 R. L. Byers, Pittsburgh 07 A. E. Davis, Pittsburgh 24 R. E. Edgington, Pittsburgh 22 G. C. Heise, Pittsburgh 06 R. M. James, Pittsburgh 07 R. L. Miller, Pittsburgh 08 A. B. McKee, ATC-C B. N. Peak, Pittsburgh 18 R. T. Shillinger, Pittsburgh 03 J. R. Stemler, ATC-C D. A. Whitfield, Pittsburgh WPH3 Others R. W. Flanagan, Pittsburgh 07 r~f~i a. 411538 0227 For Internal Company Use Only - N o t To Be Distributed Outside The Company ALCOA MATERIAL SAFETY DATA SHEET HHAAZ7AARRDn rCWHAARRAACrTTFERRIISSTTIiCr?S; --------------- 1 No.__ vV// CD Flammable CD Combustible Toxic By: PRODUC^lectrica! CD Corrosive CD Explosive CD Ingestion Joint Compound No. CD Water Reactive CD Oxidizer CD Radioactive CD Chemically Reactive K Inhalation CD Absorption Phone No. Date: 2 Section 1. ^JW/^TERIAL DESCRIPTION Material Name:/v Electrical Joint Compound No. 2 (U.S. Pat No. 2,844,479) Chemical Name & Formula: Other Designation: Corporate Stock No.: Manufacturer: Alcoa Section II. INGREDIENTS % HAZARD DATA Petroleum grease Detergent to which fluoride has been added. 1F~L,UOfZ/PPTh<7fs- Fluoride .ess Than 5% Section 111. PHYSICAL DATA Physical Form: Grease Boiling Temp. - Freeze-Melt Temp.: - Vapor Pressure: - Evaporation Rate: - Specific Gravity: Density: ' Solubility In H20": Color: f7 Insoluble Odor: "P t Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Jgnition Temp. 450 F(3?.]LC)| I Flammability Limits In Air 1 In case of fire, use a dry chemical fire extinguisher. ' | Lower j Upper I j Section V. REACTIVITY DATA Keep away from strong oxidizers. j I 411538 0228 Section VI. HEALTH HAZARD INFORMATION | TLV OSHA PEL - FLUORIDE. = 2.5 mg/m3 - Inhalation - If EJC #2 is heated ___ ^significantly, the vapors can be irritatTnjp Skin Contact - May irritate skin; avoid skin contact (not a sensitizer); components are not abosorbed through the skin. Ingestion - May be harmful if swallowed. Do not take internally by virtue of the i fluoride known to be present. First Aid: Eye Contact - Can irritate eyes. Flush with water for 15 minutes; get medical attention. Skin Contact - Wash with soap and water. i f jSection VII. SPILL. LEAK & DISPOSAL PROCEDURES I l----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- _____ Section VIII. SPECIAL PROTECTION INFORMATION When heated, use with adequate ventilation and avoid breathing the vapors. Where respiratory protection is needed, NIOSH approved respiratory should be used. The selection of appropriate respiratory equipment should be based on the actual or potential airborne contaminants and concentrations present. Avoid skin contact. i j Section IX. SPECIAL PRECAUTIONS & COMMENTS I j Chemical substance components have been reported to the E.P.A. Office of j Toxic Substances in accordance with the requirements of the Toxic Substances | Control Act (Title 40 CFR 710). D. 0. T. Requirements Section X. REFERENCES AST.V. No.- Chemical Attracts Mo.: | CM A Chemical Safely Data Sheet No.: : NFPA Omdrs No.: NSC Cjla Sheets. ; SouDVr Pioduci Literature Other: Information heroin is given in good faith *as authoritative and valid; however, no warranty, express or implied, can be made. 411538 0229 For Internal Company Use Only -- N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No._ui s ALCOA HAZARD CHARACTERISTICS CD Flammable CD Combustible CD Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxid izer CD Chemically Reactive Toxic By: CD Ingestion CD Inhalation CD Absorption PRODUCT FRYQUELL 550 HYDRAlfT lu FLUID Pho-i>: i\io. Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: A fire resistant hydraulic fluid. Triaryl Phosphate, Other Designation: Diphenyl Mono(p-tert-butyiphenyl) phosphate p-tert-butylphenyl diphenyl phosphate Corporate Stock No.: Alcoa ML-925 Manufacturer: Stauffer Chem. Co., Westport, CT 06880 Section II. INGREDIENTS % HAZARD DATA . Triaryl Phosphite............................................................................................... Mol. wt. 382.4 99+ No TLV established (c6h5>2 C(ch3) 3 ec5H4]po4 Section III. PHYSICAL DATA Physical Form: Liquid Boiling Temp.: at 1 atm...................................................... Pour Point Temp.:............................................................ Vapor Pressure: at 25C............................................................ Evaporation Rate: Specific Gravity: 60/60F............................... Density: "Solubility In H20":..................................................................... Color:................................................................................................ Odor: Slight 735F (391C) -30 to +30F (-34 to -1C) Low 1.12 -- 1.21 0.1 g/100g of water Colorless to pale straw colored liquid Section IV. FIRE AND EXPLOSION DATA Flashpoint C.O.C. I Auto-Ignition Temp. 450F (232C) 1050F min. (566C) |Flammability Limits In Air . NA I Lo-ver t Upper ------ Extinguishing Media: Water fog, dry powder or carbon dioxide may be used. Fires of this material will tend to self-extinguish if the source of ignition is removed and the surroundings have not reached the autoignition temperature. Remove the ignition source where practical. Cool and/or smother the flame. Firefighters should wear NIOSH-approved self-contained breathing apparatus. When heated to decomposition, emits toxic fumes. Section V. REACTIVITY DATA This material is stable in closed containers at room temperature. It is not shock | sensitive and does not polymerize. Special storage facilities are not required, j Carbon steel is the preferred construction for storage tankage. Aryl phosphates | will hydrolyze with water at elevated temperature; hydrolysis is accelerated by acids ; or bases. Under ambient conditions no vigorous reactions arc expected with common | acids, bases, oxidizing agents or reducing agents. | This material is inert to all common metals but can be detrimental to certain plastics j and elastomers, especially vinyl based resins. 411538 0230 i No. 114 Fyrquel 550 Section VI. HEALTH HAZARD INFORMATION TLV none ESTABLISHED Tnhalation of excessive concentrations of vapor, mist, or spray can produce non-specific irritaLTM of the upper respiratory tract. Tests with rabbits indicate that the fluid can irritate skin ves. Ingestion of large doses may produce nausea, vomiting, cramps and diarrhea, the symptoms of gastrointestinal irritation. FIRST AID: Eye Contact: Flush eyes with running water for 15 minutes. Hold eyelids open for thorough flushing. Obtain medical help if irritation persists. Skin Contact: Flush well with water. Remove contaminated clothing promptly. Obtain medical help if irritation persists. Inhalation: Remove to fresh air. Consult physician if respiratory discomfort continues Ingestion: Give large amounts of water to drink and induce vomiting. Repeat until vomitus is clear. Obtain medical help. ( Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Provide ventilation. Contact safety and environmental personnel if large spill occurs. Contain and recover spilled material for reclaim or scrap. Remove ignition sources. Pick up small spills with absorbent solid. Residues are flushed with detergents and water to remove. Those involved in clean up should use protective equipment to avoid liquid contact or inhalation of mist or vapors. DISPOSAL: Scrap can be burned, but incinerator should have an alkaline scrubber to trap phosporus oxide fume. Follow Federal, State, and local regulations for disposal or reclamation. Section VIII. SPECIAL PROTECTION INFORMATION .v Because of its low vapor pressure, general ventilation is suitable where this material is used except when heated or misted. Under these conditions local exhaust ventilation may be desirable. Where thermal-oxidative degradation occurs, protection by an approved respirator may be required. Avoid repeated or prolonged skin contact by the use of rubber gloves and protective glasses for eye protection. An eyewash station and safety shower shall be located in the work area and be immediately accessible for emergency use. Section IX. SPECIAL PRECAUTIONS & COMMENTS Since the chronic exposure properties of this material are not fully known, handle with caution. Follow good personal hygiene practice. Prevent contact with liquid and inhalation of vapors, mists, and thermal-oxidative degradation products. D O. T. Requirements Section X. REFERENCES ASTM No.: CAS No.: CMA Che.f!:c.il Safety Data Sheet No.: N(- PA Gyaes NSC Data S-eets: Supplier P.-cJuct Literature: Other: 411538 0231 For Internal Company Use O nly -- N ot To He Distributed Outside The Company MATERIAL SAFETY DATA SHEET n0._ih ALCOA HAZARD CHARACTERISTICS CD Flammable CD Combustible LJ Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive Toxic By: 3 Ingestion CD Inhalation CD Absorption PRODUCT COPPER SULFATE Phone No. Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: Cupric sulfate pentahydrate, CuSO^-SI^O Other Designation: Copper (II) sulfate, Bluestone, Blue or roman vitriol Corporate Stock No.: Manufacturer: Many sources Section II. INGREDIENTS CuS0^*5H20 (36.1% water)... Mol. Wt. 249.7 % 99+ HAZARD DATA TLV 1 mg/m3 as Cu Oral, Rat LD^q 960 mg/kg of pentahydrate or 300 mg/kg of anhydrous CuSO^ Section III. PHYSICAL DATA Physical Form: Boiling Temp.: Solid (crystals or powder) Freeze-Melt Temp.: (4H20).................................................... Vapor Pressure: 230F(110C) See Section V Evaporation Rate: Specific Gravity:........................................................................... 2.284 Density: "Solubility In H2O": g/100g Color: Odor: None; has nauseous. at 0C, 31.6; at 100C, 203. Transparent, blue granular crystals (white metallic Taste (toxic) anhydrous) when Section IV. FIRE AND EXPLOSION DATA Flashpoint | Auto-Ignition Temp. NAINA . (Flammability Limits In Air | Lower ] Upper __________I_____________ NA________________________I---------I------- This material is a nonflammable solid. When heated above 230F (110C) material will melt and flow. It can splatter if water hits the hot melted material. Also, above 752F (400C) it can decompose to give off sulfur oxide (toxic!) If heated, tightly sealed containers may rupture from pressure of water vapor released from the crystals. Section V. REACTIVITY DATA This material loses water of hydration by slow efflorescence in dry air or rapidly on heating (-2H20 at 45C, -4H20 at 110C, and -5H20 at 200-300 C) to give white anhydrous cupric sulfate. Heating above 400C can decompose cupric sulfate to give cupric oxide and sulfur oxide. When dissolved in water, this material is slightly acidic. The solution can react with magnesium metal to evolve flammablp hydrogen gas. 411538 0232 No. 115 COPPER SULFATE______________________ Section VI. HEALTH HAZARD INFORMATION TLV 1 mg/m^ as Cu Copper sulfate is toxic! Ingestion of significant amounts is corrosive to the GI tract and can cause severe abdominal pain, nausea and vomiting. Death has occured in humans from ingestion of as little as 10 g (as CuSO^). Except for dust inhalation, the inhalation hazard of this material is low because of the low vapor pressure of the solid. It can irritate the skin and mucous membranes. FIRST AID: Eye Contact: Flush thoroughly with water for 15 minutes. Get medical help if irritation persists. Skin Contact: Wash exposed areas with water. Ingestion: Give victim 2 or 3 glasses of milk or water; induce vomiting. Follow with saline catharsis. Get medical attention. Inhalation: Remove from exposure. Rinse out mouth.with water. Get medical attention for serious exposure if irritation persists. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Advise environmental personnel. Sweep up or vacuum for recovery or disposal. Avoid dusting condition. If necessary use NIOSH approved protective breathing equipment to meet TLV dust requirement. Dispose via licensed disposer in compliance with existing regulations. Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate ventilation to meet TLV requirements, especially when dusting conditions are possible; use of NIOSH approved dust mask may also be indiciated. Where CuS04/water solutions are used, eye wash station shall be located in the work area and be immediately accessible for emergency use. Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in tightly sealed containers to avoid loss of some water of hydration - See Section V. Follow good hygiene practice in handling this material. D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No.: 007-75S-998 CMA Chemical Safety Data Sheet No.: N FPA Guides NSC Date Sheets: Supplier Product Literature: " Other: 411538 0233 For Internal Company Use Only - N ot To Be Distributed Outside The Company 0 ALCOA Section I. MATERIAL SAFETY DATA SHEET No. 116 HAZARD CHARACTERISTICS O Flammable 0 Combustible 0 Corrosive CD Explosive CD Water Reactive CD Radioactive CD Oxidizer CD Chemically Reactive MATERIAL DESCRIPTION Toxic By: CD Ingestion 3 Inhalation CD Absorption PRODUCT HYDROGENN CHLORIDE GAS Phone No. Date: Chemical Name & Formula: Hydrogen chloride gas, anhydrous HC1 Description: a gas, usually supplied in acylinder asaliquid under its own vapor pressure or as a compressed gas. Corporate Stock No.: Manufacturer: Many suppliers Section II. INGREDIENTS % HAZARD DATA Hydrogen chloride.................... HC1 Mol. Wt. 36.46 99 TLV Ceiling 5 ppm or 7 mg/m'5 Section III. PHYSICAL DATA Physical Form: Gas Boiling Temp.: at 1 atm.................................................... Freeze-Melt Temp.: 1 atm.................................................... Vapor Pressure: at 70F.......................................................... Evaporation Rate: Specific Gravity: Density: Vapor (air=l)................................................. "Solubility In H2O":at 0C, 1 atm............................. Color:............................................................................................... Odor: ............................................................................................... -121F (-85C) -173F (-114C) 613 psig 1.27 82.3 g/lOOg of water Colorless corrosive gas Sharp, pungent, suffocating odor Section IV. FIRE AND EXPLOSION DATA Flashpoint Nonflammable I Auto-Ignition Temp. I NA | Flammability Limits In Air I NA I Lower ! Upper I ------- I ____ Extinguishing media: Select that suitable for surrounding fire. This material is not flammable; but is can produce hydrogen gas upon reaction wtih certain metals, such as iron, especially in the presence of moisture. If cylinders of this material are present, in a fire situation, they should be. cooled with a water spray to prevent rupturing from pressure build up from heat. Fire fighters should use NIOSH approved self-contained breathing apparatus and full body protection. Section V. REACTIVITY DATA HC1 is a stable material as confined in a cylinder at room temperature; however, it is a reactive and corrosive material. It dissolves in water with liberation of heat to form hydrochloric acid, and thus is highly reactive with alkaline materials and with many metals (with which it reacts to liberate flammable hydrogen gas). 411538 0234 No. 116 HYDROGEN CHLORIDE GAS, ANHYDROUS Section VI. HEALTH HAZARD INFORMATION TLV 5 ppm ceiling Hydrogen chloride is corrosive to human tissue. Inhalation of gas concentrations mod erately above the TLV can damage the teeth and irritate the nasal passages. Inhalation of higher concentrations (50+ ppm) will cause choking and coughing and produce severe irritation and damage of the mucous membranes of the upper respiratory tract; 1300-2000 ppm is immediately dangerous to life. HC1 can cause tissue burns. (Anhydrous hydrogen chloride is more damaging than hydrochloric acid mist, since it has an additional dehydrating effect on tissues.) FIRST AID: Eye and Skin contact: Flush skin and/or eyes thoroughly with water immediately for 15 minutes. Get medical aid. Inhalation: Remove to fresh air; restore breathing if required. Oxygen can be given under proper supervision. Get medical aid. Keep patient warm. ( Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Follow emergency preplan for large leaks. Report significant leaks to safety and environmental personnel immediately. Remove sources of ignition. Supply ventilation. Stay upwind of leakage in outside areas. Those involved in emergency procedures must use full protective clothing and NIOSH approved self-contained breathing apparatus. Stop the leakage (Notify supplier if necessary.) Flush down the area with water spray, if required; and, after neutralization of washings flush to the sewer. Small leak location can be done by opening bottle of Concentrated NH^OH near the suspected leakage area. (White fumes will reveal the leak location.) Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation in areas of use or storage to meet TLV requirements. Face velocity of hoods should exceed 100 lfm. Use NIOSH approved respirator for low concentration or self-contained breathing apparatus and full protective clothing for emergency or non-routine conditions. Protective clothing and equipment such as rubber gloves, rubber aprons, and suitable gas-tight chemical goggles, should be used by those working with HC1 gas. Woolen outside clothing (or other acid resistant fabric) has been recommended. Eye wash fountains and instant-acting showers shall be located in work area and be immediately accessible for emergency use. Section IX. SPECIAL PRECAUTIONS 8t COMMENTS Emergency planning is required where large quantities of hydrogen chloride are used. Suppliers will usually cooperate in establishing emergency plans. Follow supplier's recommendations in handling cylinders of HC1. Avoid inhalation of hydrogen chloride. .If odor can be detected, workers are being overexposed. Odor of HC1 gives adequate warning for a prompt voluntary withdrawal from the exposure area. D.O.T. Requirements CORROSIVE GAS Section X. REFERENCES ASTM No.: CAS No.- 007-647-010 CMA Chemical Safety Data Sheet No.: NFPA G'j-des NSC Data Sheets: Supplier Product Literature: Other: 411538 0235 For Internal Company Use Only - N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. 11.7 B HAZARD CHARACTERISTICS m Flammable CD Combustible ( ALCOA Q Corrosive CD Explosive Toxic By: O Ingestion PRODUCT 2-NITR0PR0PRANE Water Reactive CD Radioactive CD Inhalation Phone No. Oxidizer CD.Chemically Reactive ID Absorption Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: CH3CHNO2CH3 Other Designation: Sec-nitropropane Corporate Stock No.: Manufacturer: Eastman Kodak Section II. INGREDIENTS 2-Nitropropane Mol. Wt. 89.09 HAZARD DATA TLV 25 ppm 90 mg/m^ Section III. PHYSICAL DATA Physical Form: Liquid Boiling Temp.:................................... ( Freeze-Melt Temp.:.......................... Vapor Pressure: at 20C............ Evaporation Rate: (BuAc=l) . . Specific Gravity: 25/4C............ Density: Vapor (air=l)_____ Solubility In F^O": Color: Odor: Colorless liquid Sweet 246F (119C) -135F (-93C) 13 mm Hg 1.1 0.9821 3.1 Moderate Section IV. FIRE AND EXPLOSION DATA FI?^',nf39.4C) T.O.C. j Auto-Ignition Temp. Flammability Limits In Air Lower Upper 75F (24 C) T.C.C. 1 802F (428C) _________% by Vol. *2.6 Extinguishing media: CO2, dry chemical, alcohol-type foam or water fog. Move containers from fire area if without risk. Wear full protective clothing. Overheated containers may rupture violently. Cool containers with water spray. Heavier than air vapors may travel some distance from source. NIOSH approved self-contained breathing appar atus should be available. I Section V. REACTIVITY DATA jThis chemical is stable under normal conditions and will not undergo hazardous poly|merization. Avoid exposure to strong oxidizers, alkalies, copper and lead. Alkali I or amine salts of 2-nitropropane may be explosive when dry. Burning may produce / I nitrogen and carbon oxides. V 411538 0236 No. 117 2-NITR0PR0PANE______________________ Section VI. HEALTH HAZARD INFORMATION TLV 25 ppm_____________________________________________ Vapors cause irritation of the respiratory tract. Overexposure may cause headache, nausea, narcosis and possible cyanosis with liver or kidney injury. Contact of liquid or vapors with eyes or skin will cause irritation. FIRST AID: Inhalation: Remove to fresh air. If not breathing give artificial respiration or if breathing is difficult, give oxygen and call physician. Eyes: Immediately flush with plenty of water for at least 15 minutes. Skin: Immediately flush generously with water. Section VII. SPILL, LffAK & DISPOSAL PROCEDURES Advise safety and environmental personnel. Eliminate all ignition sources. Stop leak if without risk. Use water spray to reduce vapors. Wearing suitable protective clothing absorb small spills on vermiculite or other absorbent material. Dike large spills for later disposal. Place saturated absorbent material in fiber drums for incineration or send to a licensed disposal or recovery site. Section VIII. SPECIAL PROTECTION INFORMATION Provide general ventilation and local exhaust as required. Use protective gloves and chemical safety goggles if splashing is possible. Section IX. SPECIAL PRECAUTIONS & COMMENTS Keep away from heat, sparks and open flame. Post no smoking signs. D.O.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM No..' CAS No.: 000-079-469 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: Eastman Kodak Other: (716-458-1000 XT 85566) 411538 0237 For Internal Company Use Only -- N ot To He Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. m ALCOA HAZARD CHARACTERISTICS 0 Flammable D Corrosive D Combustible CD Explosive Water Reactive CU Radioactive Q Oxidizer D Chemically Reactive Toxic By: CD Ingestion Inhalation O Absorption PRODUCT PYRIDINE Phone No. Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: C5H5N Other Designation: 118 Corporate Stock No.: Manufacturer: Several suppliers: Koppers, Reilly Tar & Chemical Section II. INGREDIENTS Pyridine ................................................................................................................... Mol. Wt. 79.10 % HAZARD DATA 8 hr TWA 95 OSHA & ACGIH X1978) 5 ppm 15 mg/nr5 Rat, Oral LDTM 891 mg/kg50 Rat, inhalation LC50 4000 ppm for 4 hr. Section III. PHYSICAL DATA Physical Form: Liquid Boiling Temp.: at 1 atm................................................. Freeze-Melt Temp.:..................................................................... 239F (115C) --44F (-42C) Vapor Pressure: at 13-2C.................................................... Evaporation Rate: 10 mm Hg Specific Gravity: at 20C....................................................... 0.983 Density: Vapor (air=l).................................................... "Solubility In H2O":.................................................................. 2.73 Soluble Color: Colorless to yellow Odor: Sharp, Nauseating odor; recognition threshold, 0.02 ppm in air Section IV. FIRE AND EXPLOSION DATA Flashpoint. T.C.C. 68F (20C) | Auto-Ignition Temp. I 9OOF (482C) (Flammability Limits In Air. % by Vol. I Lower I Upper 1.8 12.4 Extinguishing Media: Carbon Dioxide, dry chemical or "alcohol" foam. Water may be ineffective in putting out fire but can be used to cool fire-exposed containers or to dilute and flush spills. These heavy vapors may flow along surfaces to a distant ignition source and flash back. ; It is a dangerous fire hazard when exposed to heat or flame. Vapors form explosive mix- ' tures in air. Firefighters should use NIOSH approved self-contained breathing | equipment, eye protection against vapors and protective clothing. , ;Section V. REACTIVITY DATA ' Pyridine is a stable material when stored in closed containers at room temperature. does not polymerize. It This flammable liquid (OSHA Class IB) should be kept separate from strong oxidizing agents. Thermal-oxidative decomposition can produce toxic nitrogen-containing materials, including oxides of nitrogen, cyanides, etc. Pyridine is a weakly basic material; it.will reach exothermically with acids. Heated maleic anhydride is decomposed by pyridine with rapid gas evolution. 411538 0238 No. 118 PtRIDINE Section VL HEALTH HAZARD INFORMATION TLV 8 hr TWA 5 ppm Pyridine is toxic by inhalation of vapors and by ingestion. It is irritating to skin and may be absorbed through the skin. Eye contact is irritating and can be damaging. Excessive inhalation produces irritation of the respiratory tract, asthmatic breathing, headache, dizziness, nausea and central-nervous system depression. Ingestion will upset the GI tract. Systemic effects can include kidney and liver damage. FIRST AID: Eve contact: Flush immediately with plenty of running water, including under eye lids, for 15 minutes. Get medical help. Skin Contact: Wash contact areas well with soap and water. Remove contaminated clothing promptly. Inhalation: Remove to fresh air. If necessary, give artificial respiration. Ingestion: Contact physician immediately for gastric lavage. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Inform safety and environmental`personnel. Provide maximum explosion-proof ventilation. Eliminate sources of ignition. Stop discharge if possible. Personnel involved in clean up should use protection against liquid contact and vapor inhalation. Cover and absorb small spill with 9:1 mixture of sand and soda ash; pick up and place in a cardboard box with crumpled paper, scrap wood excelsior, etc. for prompt burning. Pyridine can be flushed away from sensitive location with a water spray. DISPOSAL: Burn waste material (as indicated above or in flammable solvent solution) in an approved incinerator with afterburner and scrubber. (nitrogen oxides emitted). Follow Federal, State and local regulations. High concentrations are dangerous to aquatic life-. Section VIII. SPECIAL PROTECTION INFORMATION Provide general ventilation and local exhaust ventilation to meet TLV requirements. NIOSH approved, self-contained breathing apparatus must be available for non-routine and emergency use. Protect skin against contact with liquid by use of butyl rubber gloves, aprons, other pro tective clothing as required by exposure risk. Use chemical goggles for eye protection. An eyewash station shall be located in the work area and be immediately accessible for emergency use. A safety shower is required where contact with large amounts of pyridine is possible. Section IX. SPECIAL PRECAUTIONS & COMMENTS Store as a flammable liquid (OSHA Class IB), away from acids and strong oxidizing agents. Outside or detached storage considered preferable. Protect containers from physical damage. Electrically bond and ground metal containers for transfers to prevent static sparks. Regular physical exam of exposed workers recommended. Restrict exposure of those with central nervous system, kidney, or liver disorders. D.O.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM Nc.- D2323 CAS No. 000-110-861 CMA Ch; -- :cal Safety Data Sheet No.: NFPA G'..cos NSC Oat; Sheets: No. 310 Supplier r-oduct Literature: Other: AIA Bulletin C-56 AIHA Hygenic Guide 8-63 411538 0239 For Internal Company Use Only - N o t To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No._u> ALCOA HAZARD CHARACTERISTICS CD Corrosive Water Reactive CD Oxidizer CD Explosive CD Radioactive CD Chemically Reactive Toxic By: CD Ingestion CD Inhalation CD Absorption Section I. MATERIAL DESCRIPTION Chemical Name & Formula: Aluminum Fluoride (Anhydrous); AIF3 Other Designation: PRODUCT . ALUMINUM FLUORIDE Phone No. Date: . Corporate Stock No.: Manufacturer: Allied Chem.Corp. Section II. INGREDIENTS Olin Corp. Stauffer Chem. Co. % HAZARD DATA Aluminum Fluoride....................................................................................... Mol. Wt. 83.98 Commercial Product contains about 85% A1F3 and 12-14% A1203. '85-90% TLV Not Established Section III. PHYSICAL DATA Physical Form: Solid powder or granules Boiling Temp.:............................................................................. Freeze-Melt Temp.:.................................................................... Vapor Pressure: at 1238C................. ................................. Evaporation Rate: Specific Gravity: at 25C......................................................... Density: "Solubility In H2O":............................................................. Color: White Odor: Odorless Sublimes at 2300F 2356F (1291C) 1 mm Hg (1260C) 2.88 Insoluble Section IV. Flashpoint FIRE AND EXPLOSION DATA I Auto-Ignition Temp. I Flammability Limits In Air Lower NOT FLAMMABLE____________| NA_____________________|-----------------------------------------------------------------|-------- When heated to sublimation conditions, emits toxic fluoride fumes. In fire area wear goggles and self-contained breathing apparatus. Avoid contact with dust. Use appropriate fire extinguishing agents for the specific fire conditions. Upper Section V. REACTIVITY DATA 1 This material is stable under conditions of storage, shipment or normal use. It | does not react hazardously with water and other common materials including acids 1 or alkalies. i I | 411538 0240 No. 119 ALUMINUM FLUORIDE______________ Section VI. HEALTH HAZARD INFORMATION TLV not AVAILABLE_________________________________ Symptoms following exposure: Respiratory irritation, possibl with nosebleed or vomiting. Continued exposure may aggravate bronchitis/asthma and cause increased bone density. Liquid or solid contact with the skin is essentially harmless. FIRST AID: For acute poisoning, see physician. Administer limewater orally. Provide intravenous infusion of glucose and injections of calcium gluconates. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Collect spilled powder in suitable containers. Minimze dusting and/or use approved respirator. Ship to approved disposal site. Conform to Federal, State and local disposal regulations. 'Low concentrations of this chemical may be harmful to aquatic life. 60 ppm may be lethal to fresh water fish. Section VIII. SPECIAL PROTECTION INFORMATION Use goggles to protect against airborne particles and NIOSH approved respirator fdr intermittent heavy dust exposure. Avoid breathing dust. Section IX. SPECIAL PRECAUTIONS & COMMENTS D.O.T. Requirements Section X. REFERENCES ASTMNo.: CAS No.: 007-7S4- 181 CcVIA Chemical Safety Data Sheet No.: N FPA Girdes NSC Data Sneets: Supplier Product Literature. Other: CHRIS (1974) 411538 0241 For Internal Company Use Only - N ot To Be Distributed Outside The Company MATERIAL SAFETY DATA SHEET No. 120 ALCOA HAZARD CHARACTERISTICS CD Flammable 0 Combustible 0 Corrosive O Explosive CD Water Reactive CD Oxidizer 0 Radioactive 0 Chemically Reactive Toxic By: 0 Ingestion 0 Inhalation O Absorption PRODUCT AMMONIUM HYDROXIDE Phone No. Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: Ammonium Hydroxide, Aqueous (approx. 28%); NH^OH Other Designation: Aqueous ammonia. Ammonia water. Ammonium hydrate Corporate Stock No.: Manufacturer: American Oil Co.; CF Industries Section II. INGREDIENTS Ammonium Hydroxide - Aqueous............................................................... Mol. Wt. 35.05 % ca 28. HAZARD DATA Inhalation TLV 1 ppm STIL - Ammonia gas 100 ppm for 30 minutes 500 ppm for 10 minutes Odor threshold is 50 ppm Section III. PHYSICAL DATA Physical Form: Colorless liquid Boiling Temp.:................................................................................. Freeze-Melt Temp.:........................................................................ Vapor Pressure: Evaporation Rate: Specific Gravity: (3 20C.......................................................... Density: "Solubility In H2O": Color: Colorless Odor: Sharp, irritating, ammonia odor 101F -107F (38. 5C) (--77C) 0.89 Section IV. FIRE AND EXPLOSION DATA Flashpoint - NOT FLAMMABLE | Auto-Ignition Temp. Flammability Limits In Air 1 ___________ I Lower 1 Upper This material not flammable. Use extinguishing agents appropriate for materials burning in fire area. NH^OH creates no special hazards of combustion products. Avoid contact with liquid and vapor. Wear goggles and approved self-contained breathing apparatus. 'Section V. REACTIVITY DATA This product is stable during shipment and storage. copper alloys and galvanized surfaces. It is corrosive to copper, 411538 0242 No. 120 AMMONIUM HYDROXIDE Section VI, HEALTH HAZARD INFORMATION TLV 1 ppm inhalation of NH3 Gas Contact of liquid or vapor with skin, mucous membranes, lungs or gastroenteric tract causes marked local irritation. Ingestion causes burning pain in mouth, throat, stomach with vomiting blood, passage of loose stool containing blood. Breathing difficulty, convulsions and shock may result. Exposure to 5000 ppm or ingestion of ( 3-4 ml may be fatal. FIRST AID: Inhalation: Move to fresh air. Give artificial respiration and oxygen if needed. Enforce rest. Ingestion: Do not induce vomiting. Lavage stomach with water or lemon juice, milk or demulcents. Delay may cause perforation of esophagus or stomach. Swelling of Glottis may necessitate tracheostomy. Eye or Skin: Wash with plenty of water. Short exposure can cause first-degree burns. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Wear self-contained breathing apparatus, goggles and rubber overclothing including gloves. Stop discharge if possible. Restrict access to the spill area. Stay upwind and use water spray to knock-down vapors. Isolate and remove spilled material. Dispose via a licensed operator in compliance with Federal, State and local regulations. Low concen trations (6-15 ppm) may be lethal to aquatic life. Section VIII. SPECIAL PROTECTION INFORMATION v If splashing is possible wear chemical safety goggles and safety face mask. Use protective clothing to avoid contact with skin. Use NIOSH approved self-contained breathing apparatus if TLV is or may be exceeded. If contacted by liquid, remove contaminated clothing and shoes -promptly. Flush affected areas with plenty of water. Section IX. SPECIAL PRECAUTIONS & COMMENTS Vapors cause sufficient irritation that personnel will find high concentrations intolerable. The effect is temporary. D.O.T. Requirements Section X. REFERENCES ASTM No.: CAS No. CMA Chemical Safety Oata Sheet No.: NFPAGudes NSC Data SheetsSupplier F-oduct Literature: Other: 411538 0243 For Internal Company Use Only -- N ot To Be Oistrlhuted Outside The Company MATERIAL SAFETY DATA SHEET N0._yi pa HAZARD CHARACTERISTICS PRODUCT CD Flammable ED Combustible ( ALCOA CD Corrosive CD Explosive Toxic By: D Ingestion ANILINE CD Water Reactive CD Radioactive 0 Inhalation Phone No. CD Oxidizer CD Chemically Reactive CD Absorption Date: Section I. MATERIAL DESCRIPTION Chemical Name & Formula: Aniline; C5H5NH2 Mol. Wt. 93.13 Other Designation: Aminobenzene; Phenylamine; Blue oil; Aniline oil Corporate Stock No.: Manufacturer: DuPont, Mobay Chem. Co. Section II. INGREDIENTS Aniline (commercial grade)............................................................ % 99.5 HAZARD DATA 8 hr TWA (skin) 5 ppm or 19 mg/m : STIL: 50 ppm, 30 minutes Toxicity by. ingestion - ld50 50-500 mg/kg Section III. PHYSICAL DATA Physical Form: Oily liquid Boiling Temp.: @ 1 atm.......................................................... 363F (184C) ( Freeze-Melt Temp.:..................................................................... 21F (-6.2C) Vapor Pressure: Evaporation Rate: Specific Gravity: @ 20C.......................................................... 1.022 Density: Vapor (air=l)............................................. "Solubility In H2O''-.................................................................. 3.2 Slightly soluble Color: Colorless to yellowish brown Odor: Weak aromatic amine like odor; odor threshold is 0.5 ppm Section IV. FIRE AND EXPLOSION DATA Flashpoint J Auto-Ignition Temp. B(ic?C) 8:8:________ j 1139F (615C) j Flammability Limits In Air 1 % by Vol. Lower 1.3 Upper Fire extinguishing agent: dry chemical, C02 alcohol-type foam. Toxic vapors are generated when heated. Vapor may explode if ignited in an enclosed area. Wear chemical protective suit and NIOSH approved self-contained breathing apparatus. Cool fire exposed containers with water. Section V. REACTIVITY DATA Aniline is a stable product. It has no hazardous reactivity with water or other | common materials. | Aniline can react vigorously with oxidizers. ( ii i 411538 0244 I i No. 121 ANILINE Section VI. HEALTH HAZARD INFORMATION TLV Symptoms following exposure: Acute - Blue discoloration of finger-tips, lips and nose. Nausea, vomiting, headache and drowsiness followed by delerium, coma and shock. Chronic Exposure: Loss of appetite and weight, visual disturbances and skin lesions. The most important body response is the formation of methomoglobin, with resulting anoxemia and depression of the central nervous system. FIRST AID: Remove victim to fresh air and call physician at once. Eye: Flush with water for 15 minutes. Skin: Wash thoroughly. If cyanosis is present, shower with soap and warm water, with special attention to scalp and finger nails. Administer oxygen till physician arrives. Section VII. SPILL, LEAK & DISPOSAL PROCEDURES Inform safety and environmental personnel. Avoid contact with liquid and vapor. Keep people away. Wear chemical protective suit and self-contained breathing apparatus. Stop discharge if possible. Isolate and collect spilled material. Water pollution can be harmfull to aquatic life. Dispose via licensed disposal company in compliance with existing regulations. Section VIII. SPECIAL PROTECTION INFORMATION Avoid contact with liquid and vapor. Wear splash proof goggles, rubber gloves and boots (if necessary). Use NIOSH approved breathing apparatus if the TLV is or may be exceeded. Section IX. SPECIAL PRECAUTIONS & COMMENTS If liquid is spilled on clothing, remove contaminated clothing (& shoes) and wash thoroughly. Aniline is a mild sensitizer and a poison. Local contact may cause dermatitis. D.O.T. Requirements Section X. REFERENCES ] ASTM No : CAS No.. 62-53-3 CM A Chemical Safety Data Sheet No. NFPA Gu;des NSC Da:: Sheets: Supplier P'oduct Literature: Other: 411538 0245 I For Internal Company Use O nly - N ot To He Distributed Outside The Company MATERIAL SAFETY DATA SHEET No,_if ALCOA HAZARD CHARACTERISTICS 0 Flammable CD Corrosive O Combustible 0 Explosive O Water Reactive 0 Radioactive 0 Oxidizer O Chemically Reactive Toxic By: 0 Ingestion 0 Inhalation O Absorption PRODUCT - CHLOROBENZENE Phone No. Date: Section 1. MATERIAL DESCRIPTION Chemical Name & Formula: Monochlorobenzene C.HgCl Mol. Wt. 112 .56 Other Designation: Phenyl Chloride, Benzene Chloride; Chlorobenzol Corporate Stock No.: Manufacturer: Dow, Monsanto Section II. INGREDIENTS Monochloroberizene................................................................................................ % 99.5% HAZARD DATA TLV 75 ppm 350 mg/rn^ Toxicity by ingestion LD50 mg/kg Rat 2910 Rabbit 2830 Section III. PHYSICAL DATA Physical Form:.............................................................................. Boiling Temp.: at 1 atm..................................................... Freeze-Melt Temp.: .................................................................. Vapor Density (air=l)................................................... Evaporation Rate: Specific Gravity: at 20C.......................................... Density: Liquid.............................................................. "Solubility In H2O":............................................................ .. . Clor:............................................................................................... Odor: ............................................................................................... Liquid 270F (132C) -50. IF (-45.6C) 3.9 Vapor pressure at 22.2C....... 1.11 9.19 LB/Gal Insoluble Colorless, Clear Sweet, Almond odor 10. mm Hg Section IV. FIRE AND EXPLOSION DATA FL .9C) 37F f 34.401 C.C. Auto-Ignition Temp. 1184F (640C) [Flammability Limits In Air [ Lower I Upper 1____________% by Vol.__________________( 1.3 | 7.1 Extinguishing agents: CO2, dry chemical, alcohol-type foam, water spray. Burning in an open flame can form toxic phosgene (see No. 58) and HC1 gas. Wear goggles, selfcontained breathing apparatus and full protective fire gear. Flash back along vapor trail may occur. Vapor may explode if ignited in enclosed area. Section V. REACTIVITY DATA This material is stable during shipment and storage and does not have hazardous reactions with water and other common materials. It does not under go hazardous polymerization. ( i 1 411538 0246 No. 122 MONQCHI.OROBENZF.NE____________________ Section VI. HEALTH HAZARD INFORMATION TLV : 75 ppm Symptoms following exposure: Fumes are irritating to skin, eyes and mucous membranes. Repeated skin exposure may cause dermatitis. Inhalation of vapors or mist may result in irregular pulse, deep and rapid respiration, drowsiness, unconsciousness and in damage to lungs, liver and kidneys. Acute vapor exposures can cause symptoms ranging from coughing to transient anesthesia to central nervous system depression. TRST AID: Get medical attention for all eye exposures and any serious over-exposure. Inhalation: Remove to fresh air. Give oxygen if needed. Ingestion: Dilute by drinking water. If vomiting occurs, drink more water. Administer saline laxative. !lEyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash exposed area with soap and water. Section VJI. SPILL, LEAK & DISPOSAL PROCEDURES Stop discharge if possible. Extinguish sources of ignition. Avoid contact with liquid and vapor. Keep people away. Isolate and remove spilled material. Dispose waste material in an approved incinerator or via an approved disposal facility in compliance with existing federal, state and local regulations. Small spills can be absorbed with paper towel and evaporated in hood. Section VIII. SPECIAL PROTECTION INFORMATION Provide adequate exhaust ventilation in areas of use to meet TLV requirements. Use NIOSH approved breathing apparatus (organic vapor-acid gas respirator or self-contained breathing apparatus) based on the actual or anticipated concentration. Wear goggles for eye protection and a face shield if splashing is possible. Section IX. SPECIAL PRECAUTIONS & COMMENTS Store in closed containers in well-ventilated area. ignition. Post no smoking signs. Keep away from sources of heat or D.O.T. Requirements FLAMMABLE LIQUID Section X. REFERENCES ASTM Mo.: CAS No.: 000-108-907 CMA Chemical Safety Data Sheet No.: NFPA Guides NSC Data Sheets: Supplier Product Literature: AIA Bulletin C-20 AIHA Hygenic Guide 2-64 Chris (1974) 411538 0247