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March 21,2003
1301 K STREET. NW. SUITE 300 EAST WASHINGTON, DC 20005-7008
BOSTON
NEW YORK
SAN FRANCISCO
WASHINGTON, DC
202-626-3900
F 202-626-3961
Mark A. Greenwood
202- 626-3905
mgreenwood@ropesgray. com
Confidential Business Information Center (CBIC) O ffice o f Pollution Prevention and Toxics U.S. Environmental Protection Agency EPA East Building, Room 6428 1201 Constitution Avenue Washington, DC 20004-3302
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To Whom It May Concern:
On behalf o f Daikin Ltd. and Daikin America (hereafter "Daikin"), I am submitting copies o f a presentation that company representatives offered to staff o f the Office o f Pollution Prevention and Toxics on March 13, 2003. This package includes three copies o f two documents: (1) the slides presented to the Agency on March 13, which include highly confidential proprietary information; and (2) a sanitized version o f that same presentation that can be included in the docket known as AR-226. Daikin claims the first document as Confidential Business Information under all applicable statutes and regulations affecting voluntarily submitted information.
By way o f clarification, we have made a few corrections to the slides that were provided at the March 13 meeting. We corrected an error in one CAS number provided for a fluoropolymer chemical, and we have modified some o f the coloration in charts provided to make them easier to read if they are photocopied.
Please contact me at the address noted above if you have any questions, and I thank you for your attention to this matter.
Best regards, Mark A. Greenwood
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C o m p a q S an lt,ze
DAIKIN
DA1KIN
M arch 13, 2003
Company Overview Telomers
Industry Products Manufacturing
Polymers
Products Manufacturing
Other Issues
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DAIKIN
DAIKIN AM ERICA
Orangeburg, New York Headquarters/ business office 55 employees
Decatur, Alabama Telomer polymerization Fluoropolymer manufacture 300 employees In operation for 10 years
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U.S. Telomer Industry Players
Primary Manufacturers DuPont (Integrated monomer/polymer manufacture) Daikin (Polymerization of imported monomers Clariant (Import of own polymers) Asahi (Import of own polymers)
Other Manufacturers Dai-nippon Ink (Japan manufacture, distribution in US?) Nihon Mektron (Japan manufacture, distribution in US?)
Formulators Repellents (10-20) Surfactants (many)
Telomer Product Lines
Repellent Products
80% of telomer market
Carpet products (mill, commercial after market,
consumer after market)
Textile products (clothing, upholstery, nonwoven
Porous mineral products (stone, masonry, concrete)
Paper products
Surfactants
20% of telomer market
Fire fighting foam, floor polish wetting,
Photo film wetting, ink and paint levelers
Others
Mold Release
Current Daikin Products
DAIKIN
USA
__________ 4__________
US Consumer
Overseas
Formulator
'r Mill
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D A IK ilM
USA
Carpet/Paper
Overseas
US Consumer
D A IK l IM
CAS Numbers of Daikin's Telomer Products
(2002)
10
DAKIN
Applications and Distribution
(2002)
P ro d u ct No. T e x tile TG 012
TG 472 TG 5011 TG 532 TG 5S 3G TG 571 TG 573 TG 652 TG 656 TG 770
TG 992 TG 3020 TG K C 01
S u b to ta l |C arpet TG 3520 T S 2 TG 3010 1 X 5 3 3 *0 TG 3311 TG 3360 TG 452A TG 470 TG 472 TG 571
T yp ica l A p p lic a tio n
L e ath er .A p p arel " ' A pparel A pparel A pparel U p h o ls te ry A pparel
C o m m e rc ia l R e n e w e r C o m m e rc ia l Renevwer
A pparel A pparel
C arpet C arpet C arpet C arpet C arpet C arpet C arpet C arpet
C arpet
I T e lo m e r T o ta l
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II
DAHUN
CAS Numbers of Daikin's Telomer Products
(2003)
DAIKIN
Applications and Distribution
(2003)
P ro d u c t No._______ ______ T y p ic a l A p p lic a tio n
Textile
TG180
TG47QB
Apparel
TG470H
Apparel
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TG472A
TG5011
TG532
TG563G
TG571
TG573
TG575
TG6S6
TG770
TG815
TG991
TG992
TG3020
TGKC01
TGKC02
Subtotal
Carpet
TG3550
TG3020
TG3311
TG3360
TG452A
TG470B
TG571
Apparel
Upholstery Apparel
Apparel
Paper Apparel A p p a ia i
Carpet C arp et Carpet C arp et Carpet C a rp e t Carpet
Telomer Production Process
Japan
u.s.
DAIKim
Exposures and Wastes
Japan
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P 0 s u r e s
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DAUUN
Fluoropolymers produced at Decatur Plant
1. Emulsion Polymerization (With APFO) PTFE Fine Powder PTFE Dispersion
2. Suspension Polymerization (Without APFO) PTFE Granular FEP ETFE
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DAIKIN
Fluoropolymers made with APFO that are sold in the U.S.
1. PTFE Fine Powder Daikin-Polyflon PTFE
2. PTFE Dispersion Daikin-Polyflon PTFE
3. PTFE Low molecular Daikin-Polyflon PTFE; Lublon
4. FEP Dispersion Neoflon FEP Dispersion
5. Fluoropolymer Paint Base ZEFFLE
6. Fluoroelastomer DAI-EL Series
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Main Application for Fluoropolymers made with APFO
1. PTFE Fine Powder expanded membrane, wire/cable, tubing and fuel hose
2. PTFE Dispersion base for enamel and impregnation
3. PTFE Low molecular Weight additives
4. FEP Dispersion base for enamel
5. Fluoropolymer Paint Base architectural paint
6. Fluoroelastomers fuel hose, valve stem and tubing
DAIKIN
Decatur Plant Stewardship
> PFOA Industrial Hygiene Assessment of processes using PFOA conducted in 2001 to establish baseline exposure data - Air samples all well below ACGIH TLV - Potential exposure areas identified - Engineering controls were installed - PPE requirement changed - Training conducted employees on proper handling of PFOA
> Conducted baseline analysis of PFOA in blood of workers in 2001
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D A iK iN
Decatur Plant Stewardship
> Blood testing repeated in 2002 and significant reduction (>30%) was observed
> Continuing industrial hygiene assessment > Plant has ongoing project to recycle waste
PFOA to reduce emissions to environment
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PFOA Mass Balance
Decatur Fine Powders/Dispersion Process
Fine Powders PFOA Mass Balance
Decatur Alabama
> Two fluorochemical producers, Daikin and 3M, are next door neighbors
> Daikin plant is built on property purchased from 3M