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AROCLOR" PLASTICIZERS A series of inert, chemically-resistant, fire-retarding plasticizers compatible with wide variety of resins, PLASTICIZERS *NlMn(criti'ir<J Ktrln llk0'>st'id ith l,,T piltnt. MONSANTO MAKES NO WARRANTIES AS TO THE FITNESS OR MERCHANTABILITY OF ANY PRODUCTS RE I ERRED TO, m iuiiivn oi Miufjdou wil Korn rtMnci io- UlnMinTormidonei inaoixliimilil<uiit;lounjnwHn:loii(imj(.'' Organic Chemicals Division / GOO N. Lindbergh Blvd. / Si Louis, Missouri 63166 rx.72b5B . TOWOLDMON0032844 WATER_PCB-00017313 AROCLOR PLASTICIZERS A series of Inert, chemically resistant, fire retarding plasti cizers compatible with a w,ide variety of resins. 0*72859 TOWOLDMON0032845 WATER_PCB-00017314 Properties as Plasticizers The Aroclor resins/plasticizers and their blends have a very unusual set of properties which make them extremely useful products. Their most important characteristics are: ' Low Cost Highly Compatible Chemically Stable Fire Retardant Excellent Adhesion Another very useful aspect of this product line is the fact that a continuous range of properties can be achieved by using combinations of the Aroclors and their blends. Some of the physical properties which can be controlled through product selection-are shown on the following pages. OA72860 TOWOLDMON0032846 WATER_PCB-00017315 -3- Key to Nomenolal-ure 5400 Series These products are chlorinated terphenyls. The last two digits indicate the chlorine content of the material, e.g., Aroclor 5460 is a chlorinated terphenyl with 60 percent chlorine. Undlstilled Aroclors are available and are designated by a 5000 series vs. the 5400 series. They are somewhat higher in color but otherwise have product characteristics similar to the distilled products. 6000 Series These products are blends of Aroclor 5460 and Aroclor 1221, a biodegradable mono chlorinated biphenyl. The last two digits indicate the percentage of Aroclor 5460 in the blend, e.g., Aroclor 6062 is'a .blend containing 62 percent Aroclor 5460 and 38 percent mono chlorinated biphenyl.' Miscellaneous Blends Other product blends containing such other materials as Santicizer 140 for improved fire retardancy, or toluene/ xylene for lower viscosities will also be made available as the demand for these specialty products develops. 0^72361 TOWOLDMON0032847 WATER_PCB-00017316 AROCLORS Adhesion/Tack Hardness Flexibility Fire Retardance Volatility Chlorine Content Viscosity Density ' Permanence Compatibility 543254425460 --------------------- increasing-----------------> --------------------- increasing------------------------------------- decreasing------------------------------------ increasing--------------------- :-------------- decreasing---------------.-------------------- increasing------------------------------------- increasing---------------- (1* --------------------- increasing-----------------* --------------------- increasing---------------- e----------decreasing-----------------O- 0-172862 | TOWOLDMON0032848 WATER_PCB-00017317 AROCLOR BLENDS 6040 Adhesion/Tack --------- Hardness --------- Flexibility -- ------ Fire Retardance --------- Volatility --------- Chlorine Content -------- - Viscosity --------- Density --------- Permanence --------- Compatibility --------- 6050 6062 ---------increasing ---------lncreasing- ---------decreasing ---------increaslng- ------r-decreasing- :---------increaslng- -------- lncreasing- --:--increasing- ---------increaslng- ----decreasing- 6070 6090 -4om --3^ 0<i?2863 TOWOLDMON0032849 WATER_PCB-00017318 -6- Applloablons Listed below are some of the applications where these products can be used: . Aroclor Blends 6040 Polyvinyl Acetate Emulsion Adhesives ' ' SBR Adhesives Miscellaneous applications where a high degree of flexibility is- required. 6050 Chlorinated Rubber and other Resin systems for coating^. Inks 6062 Polysulfide Sealants/Adhesives Chlorinated Rubber Coatings and Adhesives SBR Coatings and Adhesives Miscellaneous- applications where high chlorine content, high tack, are required. Inks 6070 Polysulfide Adhesives - Chlorinated Rubber Adhesives Miscellaneous applications where very high chlorine content and very high tack are required. 6090 Radiation Curing Applications oV'*8b`' I TOWOLDMON0032850 WATER_PCB-00017319 -7- Aroolors 5^32 5442 5460 Polysulflde Sealants/Adhesives . Chlorinated Rubber Coatings and Adhesives SBR Coatings and Adhesives Surface Coatings . Hot Melt Adhesives, Surface Coatings 0*726<>5 TOWOLDMON0032851 WATEFLPCB-00017320 PHYSICAL PROPERTIES 0? AROCLORS AND AROCLOR BLENDS Property Aroclor 1221 Appearance - Clear, mobile oil AP.OCLORS Aroclor Aroclor 5432 5442 Clear, yellow viscous liquid Clear, yellow sticky resin Aroclor 5460 Aroclor 5o4o Clear, yellow to amber brittle resin or flakes Clear, light yellow . mobile oil AROCLOR BLENDS Aroclor Aroclor Aroclor 6050 6062 6070 Clear, light yellow mobile oil Clear, yellow viscous liquid Light yellow sticky resin. Aroclor 6090 Light yellow ' resin Color, Maximum *100 APHA 2 NPA 2 NPA 2 NPA (Molten) (Molten) (Molten) 2 NPA 2 NPA 2 NPA 2 NPA 2 NPA Specific Gravity *1.182 - 1.263 - 1.470 1.192 1.290 (asy , (25 V. , (90/ 25 c) 15.5 c) 15-5 c) 1.670 25 c) 1.330 - 1.342 - 1.405 - 1.418 - 1.35 1.362 1.425 1.438 (25/ 0 , (65/ . ^ (65% , (90/ 0 , 15-5 c) 15.5 c) 15.5' c) 15.5 C) Acidity, *0.014 Maximum (Mg KOH/Gm - .05 -05 0`. 035 .035 0.035 .035 035 Moisture ppm - _ - - ' 250 250 250 250 - Maximum WATER_PCB-00017321 PHYSICAL PROPERTIES OP AROCLOKS AND AROCLOR 3LENPS Property Aroclor 1221 Viscosity *38-41 (ASTM D-88) (100 F SUS) AROCLORS Aroclor Aroclor 5432 5442 50-60 (210 F SUS) 300-400 (210 F SUS) Aroclor 5460 " ' Aroclor 6040 122-132 (100 F SUS) AROCLOR BLENDS Aroclor Aroclor Aroclor 6050 6062 6070 105-115 (130 F SUS) 50-60 (210 F SUS) 82-92 (210 F SUS) Aroclor 6090 -- Flash Point 286-302 F Minimum (Cleveland Open Cup) 477 Hone to Boiling 270 290 340 Fire Point 349 0 F Minimum (Cleveland Open Cip) >662 None to Boiling 300 335 550 Softening - - 46-52 98-105 - '' Point C - 64-70 TV 03 O' Monsanto Specifications WATER_PCB-00017322 PRODUCT CODES AMD DRUM WEIGHTS Code Container Net Weight Pounds AROCLORS 5060 5432 5442 5460 1040-450-04-009 1040-460-04-009 Multi-wall Bag 55-Gallon Metal Drum 5-Gallon Metal Drum 1040-470-04-009 40-Gallon Metal Drum 1 5-Gallon Met&l Drum 1040-480-04-009 Multi-wall Bag 50 600 60 450 50 50 AROCLOR BLENDS 6040 1045-040-04-009 6050 6062 /OSo. CD 1045-050-04-009 1045-062-04-009 ' ' 55-Gallon Metal Drum 5-Gallon Metal Drum 55-Gallon Metal Drum 5-Gallon Metal Drum 55-Gallon Metal Drum 5-Gallon Metal Drum 600 55 600 55 600 60 Gross Weight Pounds Approximate Volume F! 504 " 0.97 648 65 10-3/4 1 469 56 7-2/3 1-1/12 50-1/2 0.97 648 60 ' 648 60 648 65 10-3/4 1 10-3/4 1 10-3/4 '1 TOWOLDMON0032854 WATER_PCB-00017323 PRODUCT CODES AND DRUM WEIGHTS Product 6070 6090 Code Container Net Weight Pounds 1045-070-04-009 55-Gallon .Metal Drum 5-Gallon Metal Drum . 600 60 1045-090-04-009 40-Gallon Metal Drum 5-Gallon Meta-l Drum 500 . 50 Gross Weight Pounds 648 65 519 56 Approximate Volume Fl3 10-3/4 1 7-2/3 1-1/12 Z l> 9 O' TOWOLDMON0032855 WATER_PCB-00017324 1 12- Toxiolty and Safe Handling Inhalation At ordinary temperatures, the Aroclor chlorinated poly phenyls have not presented industrial toxicological pro blems. The hazard of potential toxic exposure varies with their volatility: the lower-chlorinated, more volatile ones present more of a potential problem from the standpoint of both inhalation and skin contact. When Aroclor plasticizers are used at elevated tempera tures, engineering controls must be applied, either by the use of closed systems or by effective local-exhaust ventilation together with general workroom exhaust. Vapor of the liquid Aroclor plasticizers at room tempera ture should not be breathed in a confined space, and no vapor of any Aroclor evolved at elevated temperatures should be allowed to be dispersed into the general work room. Skin Contact Continuous or repeated skin contact with the Aroclor plasticizers must be avoided by the use of gloves and protective garments, because of the possible occurrence of a condition called chlqracne. Although reports of this condition caused by Aroclor are rare, it can be produced by excessive skin contact. If any Aroclor is spilled on the skin, the skin should be washed in the usual manner with a soap solution. A burn caused by contact with a hot Aroclor should be treated like any ordinary burn. Aroclor plasticizer adhering to the burned area need not be removed immed iately, unless treatment of the burn demands it, in which case either soap and water or repeated washings with a vegetable oil are recommended. o*1z6l TOWOLDMON0032856 WATER_PCB-00017325 JMI ii DISTRICT SALES OFFICES ALL DIVISIONS ATLANTA, GEORGIA 3032S Lenox Towers East 3400 Peachtree Pd. N. E. -- Suite 1711 Jet: (404) 577-2260 BOSTON, MASSACHUSETTS 02149 Everett Station Tel. (617) 387-5010 CHICAGO, ILLINOIS 3158 Pcs Plaines Ave. Pcs Plaines, Illinois 60018 Tel. (312) 296-6088 CINCINNATI, OHIO 4520$ 1501 Madison Road 7cf. (513) 751-6707 CLEVELAND, OHIO 44122 3645 Warrensville Center Rd. Jet. (216) 991-5400 DETROIT, MICHIGAN 48235 500 Northland Towers East 7cl. (3)3) 357-0910 HONOLULU, HAWAII 96812 205 Pacific International Bldg. 677 Ala -Moana Bhd., P. 0. Box 3824 Tel. (80S) 512-744 HOUSTON, TEXAS 77002 1300 Main Street Tel. (713) Capitol 3-4011 LOS ANGELES, CALIFORNIA 90022 6670 E. flotilla St. Tel. (213) 723-2492 MINNEAPOLIS; MINNESOTA 55402 912 Nortbstar Center 110 S. SevenOT St. Tel. (612) 339-4651 NEW YORK, NEW YORK 10017 277 Perk Avenue Tel. (212) 922-4111 PITTSBURGH, PENNSYLVANIA 15222 No. 4 Gateway Center Bldg. Room 534 Tel. (412) 261-215$ > ST. LOUIS, MISSOURI 63166 ' 800 N. Lindbergh Blvd. Tel. (314) Oxford 4-1000 SAN FRANCISCO BAY AREA ' 2710 Lafayette, Santa Clara, Calif. 95052 Jet. (403) 243-0414 SEATTLE. WASHINGTON 93104 911 Western Avenue Tct. (20$) Main 2.4203 SPRINGFIELD, MASSACHUSETTS 01101 730 Worcester Ave. Tel. (413) 788-6911 WILMINGTON, DELAWARE 19803 2005 Concord Pike, Fairfax Tel. (302) Olympia 8-6531 Additional District Offices are maintained by: Agricultural Division LULING. LOUISIANA 70070 P. 0. Box 174 Tel. (604) 784-6263 MEMPHIS. TENNESSEE 38113 1023 Riverside Drive P.0. Box 13248 Tel. (901) Whitehall 7*3181 Textiles Division AKRON. OHIO 44313 3030 West Merkel St Tel. (216) 836-7941 , ATLANTA. GEORGIA 30303 Atlanta Merchandise Mart 240 Peachtree St.. N.W. Tel. (404) $77-2260 CHARLOTTE, NORTH CAROLINA 28202 Wachovia Bank Building 129 West Trade St Tet. (704) 376-8871 ENGLEWOOD CLIFFS, N. J. 07531 661 Palisades Avo. Tel. (201) 668-2161 NE'IV YORK. NEW YORK 350 Fifth Ave. Tel. (201) 656-5100 Hydrocarbons & Polymers Divislon-Llon Oil EL DORADO. ARKANSAS 71730 Lion Oil Building Tel. (501) Union 3-3111 JACKSON. MISSISSIPPI 39209 P. 0. Box 10937 Westland Station Tel, ($01) 352-3648 LITTLE ROCK, ARKANSAS 72203 1615 West Seventh St Tel. (501) franklin 6-2437 MEMPHIS. TENNESSEE 38113 1023 Riverside Orive P. O.BOX 13248 ' Tel. (901) Whitehall 7-3161 Organic Chemicals Division (Rubber Industry) AKRON. OHIO 44311 920 Brown Street P. 0. Box 2307 Tel. (216) Hemlock 4-1921 MONSANTO, 800 N. LINDBERGH BLVD., ST. LOUIS. MISSOURI 6316S 0<,nttn TOWOLDMON0032857 WATER_PCB-00017326