Document bBQODEDXayXEY0JRZLn35XGLg

0730 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) TEST SUBSTANCE___________________________________________ Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-203. (1Octanesulfonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-203. Current information indicates it is a mixture of 1.34% PFOS, 35% diethylene glycol butyl ether, 37.85% water, 20% ethylene glycol, 2.66 % Sultone foamer, 3% sodium octyl sulfate, 0.1% sodium lauryl sulfate, and 0.05% tolyltriazole. The following summary applies to a mixture with incompletely characterized concentrations of impurities. Data may not accurately reflect toxicity of the fluorochemical component of the test sample. METHOD:____________________________________________________ Method: ASTM E1367-90, Standard guide for conducting 10 day static sediment toxicity tests with marine and estuarine sediments. Type: Acute static GLP: No Year completed: 2000 Species: Corophium volutator Supplier: Not given. Analytical monitoring: pH and dissolved oxygen Exposure period: 10 days Test organism age: Adults Statistical method: LC50 values calculated by PROBIT analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). Calculation of NOEC by single-factor ANOVA followed by Bonferronis procedure. Test conditions: Dilution water: Natural seawater (34 ppt salinity) from an unpolluted site in Byfjorden, outside of Stavanger, Norway. Sediment collected at an unpolluted site. The sediment is a muddy sand an had an organic fraction of 0.7% and a silt fraction of 0.8%. Dilution water chemistry: Not given. Lighting: Not given. Stock and test solution preparation: Each test concentration was prepared by adding the test sample to 600 g damp sediment and 200 mL of seawater, then shaken for 3 hours. The sediment was split into three sub-samples, with an overlay of 400 mL seawater added to each and aerated overnight prior to study initiation. Exposure vessels: 600 mL glass beakers containing 200 g of test sediment and 400 mL of seawater with continuous aeration. 0006S4 Number of replicates: 3 Number of organisms per replicate: 10 Number of concentrations: four plus a blank control Water chemistry during the study: pH range (0-10 days): 7.7 - 8.1 (control exposure) 8.0 - 8.1 (3060 mg/kg exposure) Temperature range: 15 1 C Dissolved oxygen range (0-10 days): 91 - 94 % (control exposure) 74 - 97 % (3060 mg/kg exposure) RESULTS___________________________________________________ Nominal concentrations: Bk control, 91.1,501,1030, and 3060 mg/kg (dry weight). Element values: 10-day LC50 = >3060 mg/kg (sediment dry weight) 10-day NOEC = 3060 mg/kg (sediment dry weight) Element values based on nominal concentrations Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. CONCLUSIONS______________________________________________ The FC-203 10-day LC50was determined to be >3060 mg/kg (sediment dry weight). The 10-day No Observed Effect Concentration (NOEC) was 3060 mg/kg (sediment dry weight). Validity criteria fulfilled and reference substance was in the normal range. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY_______________________________________________ Reliability: Klimisch ranking = 2. This study meets the criteria for quality testing. However, sample purity was not properly characterized and the study lacks analytical confirmation of the amount of fluorochemical proportion in the solution. REFERENCES_______________________________________________ Test was conducted by RF Rogaland Research, of Stavanger, Norway at the request of 3M Norge, Lab reference number 99312-2, 2000. 0006S5 OTHER Last changed: 6/27/00 0006S6 NORSK AKKREDITERING Mr. P01 ROGALAND RESEARCH "FC-203 Light Water Brand AFFF" Toxicity tests Report RF-2000/002 Lab. ref. no.: 99312-2 No. of pages: 31 ISBN: Author: Elin Horve Cllent(s): 3M Norge Distribution restriction: Version No. / date: Vers. 1 / 06.01 2000 Research Program: Open from (date): Summary: The following test results were obtained with "FC-203 Light Water Brand AFFF": Toxicity: Skeletonema costatum Acartia tonsa Corophium volutator 72 h EC* 48 h LCM 10 d LCW (mg/l): 62 (mg/l): 200 (mg/kg dry weight): >3060 The results relate to the product as supplied by Novatech. Key-words: Toxicity, Skeletonema costatum, Acartia tonsa, Corophium volutator. No part of this document may be reproduced in any form without permission in writing by RF - Rogaland Research . (Study director S Inger Lisa Andersen 'a for RF - Rogaland Research Kre Netland 000687 LaD.rej.no. : 99312-2 ru \je - uj j i CONTENTS: 1. Preface.................................................................................................................................................... 3 2. Test for toxicity with Skeletonema costatum............................ 4 3. Test for toxicity with A cartia tonsa............................r......................................................... 10 4. Test for toxicity with Corophium volutator....................................................................... 15 5. Data sheet(s) ............................................................................. 20 0006S8 99312-2 'o PREFACE: Ecotoxicological tests were performed on "FC-203 Light Water Brand AFFF" in agreement with Novatech. The sample is a concentrate that normally will be used in a 3% solution. Tests were conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM1995 / SFT1998). The project was carried out at RF - Rogaland Researchfo r 3M Norge. All the tests were performed by RF - Miljolab. Study director was Senior Engineer Inger Lisa Andersen. The test results are presented in separate sections. The results relate to the product as supplied by Novatech. This test report is issued by a laboratory accredited by Norwegian Accreditation (NA). The accreditation states that the laboratory meets the NA requirements concerning competence, equipment and workingproceduresfo r all the test methods contained in the accreditation. It also states that the laboratory has a satisfactory quality assurance system, which includes internal quality control schemes, participation in interlaboratory comparisons, and the use o f certified reference materials and secondary reference materials. The tests performed are covered by the accreditation. This test report may not be reproduced in anyform other than infull, without the permission in writing by RF - Miljelab. 0006S9 T est fo r T o xicity Marine alga: Skeletonema costatum 000690 .U I./1 /./.U .. 99312-2 WJ .< i TEST REPORT GROWTH INHIBITION TEST WITH THE MARINE a l g a Skeletonema costatum fQl NORSK AKKREDITERING Nr. raa ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: i The 72 hours EC50 was calculated to 62 mg/1. The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: METHOD: NS-EN ISO 10253, 1998: Water quality - Marine algal growth inhibition test with Skeletonema costatum and Phaeodactylum tricomutum. TEST ORGANISM: Skeletonema costatum, strain NIVA BAC 1. A stock culture o f the test organism is kept at RF - Rogaland Research. PREPARATIONS: Natural seawater (salinity: 34 %o) from an unpolluted site in Byfjord was used as basis for the growth medium. The water was filtered through a GF/C filter, and briefly heated to about 75C prior to use. The seawater was enriched with nutrients according to ISO 10253, and recommendations from the Paris Commission. Test solutions were prepared from a stock solution. A stock solution o f 500.8 mg/1 was prepared by stirring 0.5008 grams o f the product in 1 litre o f growth medium. Other concentrations were prepared from this stock solution. INCUBATION: Test cultures o f 50 ml were incubated in 100 ml flat-bottomed flasks on an orbital shaker, 3 replicates for each concentration. Test cultures were inocu lated to about 2000 cells/ml from an exponentially growing inoculum culture. The test was run under continuous light (> 50 pE/nr-sek) from fluorescent" " tubes o f universal natural white type, at a temperature o f 20 2C. The test was run for about 72 hours, and subsamples o f 5 ml were taken from the test flasks each day for growth measurements. Algal growth was measured by fluorescence. pH measurements were performed as indicated on data sheet. 000691 Lab.ref.no.: 99312-2 Page 6 of 31 DATA ANALYSIS: CALCULATIONS: Growth rates were calculated by log linear regression on biomass (fluorescence) versus time, as described in NS-EN ISO 10253. ErCso: The inhibitory effect on the growth o f Skeletonema costatum is expressed as the concentration o f a product giving 50% reduction o f growth rate (ErCso). This effect concentration and the 95% confidence limit were calculated by the use o f the computer programme TOXEDO developed by VKI (Denmark), assuming a logarithmic normal distribution o f data. The programme also calculate concen trations inhibiting growth rate 10% and 90% (ErCio and ErC9o). NOEC: Calculation o f NOEC (No Observed Effect Concentration) is done by singlefactor ANOVA followed by Bonferronis procedure for comparing each concentration mean with the control mean. TEST RESULTS: Table 1. EC and NOEC values obtained with Skeletonema costatum. COMMENTS: Test substance E,Cio ErCso EfCo TC -203 Light Water Brand A F F F 13 (8.3 - 18) 62 (48 - 83) >100 NOEC: 32 - Values indicate concentrations giving 10%, 50% and 90% inhibition o fgrowth rate. Units in mgfl. Values are calculated by the computer programme TOXEDO (VKI, Denmark), and 95% confidence intervals are indicated. NOEC are calculated by using the computer programme CraphPad InStat 3.0. The results are based on growth rates for the time span 0 - 72 h, the period during which the growth is considered to be exponential in the control cultures (see growth curves). VALIDATION: The validity criteria given in the test protocol are fulfilled, in that the control cell density increased by a factor o f more than 16 in the test period (corresponding to a growth rate o f more than 0,9 d'1), the control pH did not -- vary by more than 1,0 units during the test and the 72 hours test results with 3,5-dichlorophenol was in the range normally found. Lab. ref. no.: Sample received.: Test period: Report date: 99312-2 20.09.99 04-07.10.99 06.01.2000 \Sp o t c _ Elin Horve Engineer Analytical technician ge Molversmyr Senior Research Scientist Quality Assurance Enclosed: Data sheets This test report is issued by a laboratory accredited by Norwegian Accreditation (NA). The report may not be reproduced in any form other than in full, without the permission in writing by RF - Miljalab. 000692 lab-ref.no.: 3I2-2 Page 7 o f 31 PRIMARY DATA: Growth inhibition test with Skeletonema costatum Test substance: "FC-203 Light Water Brand AFFF" Lab. ref.: 99312-2 Start date: 04.10.99 Cone, unit: mg/l Measurement: The biomass was measured by fluorescence: values in fluorescence units Concentration Time: 04.10.99 14:05 05.10.99 09:25 06.10.99 10:30 07.10.99 10:40 Growth PH pH rate Corre at start at end day -1 lation of test of test 0 0.11 0.59 9.2 56 2.39 0.998 0 0.15 0.63 7.9 59 2.14 0.997 0 0.13 0.62 9 54 2.29 0.997 8.3 8.4 0 0.14 0.63 6.4 47 2.07 0.999 0 0.14 0.62 6.3 48 2.06 0.999 0 0.12 0.71 7.1 55 . 2.20 1.000 0.32 0.32 0.32 0.13 0.82 9.2 0.13 0.77 9.6 0.14 0.84 12.5 61 66 71 2.30 2.32 2.43 1.000 1.000 0.999 8.4 8.4 1 0.14 0.77 11 70 2.36 0.999 1 0.14 0.69 12 65 2.41 0.996 8.4 8.5 1 0.16 0.63 8.3 60 2.13 0.995 3.2 0.18 0.58 8 63 2.05 0.990 3.2 0.14 0.59 7.1 52 2.12 0.997 8.4 8.5 3.2 0.12 0.6 6.6 50 2.17 0.999 10 0.14 0.58 8.5 64 2.22 0.995 10 0.16 0.34 4.4 48 1.79 0.974 8.4 8.5 10 0.16 0.6 7.6 68 2.09 0.994 32 0.14 0.43 4.4 42 1.86 0.992 32 0.12 0.39 5.3 46 2.05 0.990 8.4 8.4 32 0.13 0.3 3.6 30 1.79 0.979 100 0.1 0.04 0.1 0.3 0.00 100 0.09 0.18 0.3 1.35 0.65 0.987 8.4 8.2 100 0.08 0.06 0.21 1.3 0.52 0.784 Reference substance (3,5-dichlorophenol): 1.5 mg/l 0.14 0.47 1.85 1.5 mg/l 0.16 0.43 1.45 1.5 mg/l 0.16 0.45 1.45 4.2 3.3 2.9 1.39 0.999 1.19 1.000 1.19 0.999 8.3 8.2 Mean values: 0 0.32 1 3.2 10 32 100 0.13 0.6 8 53 0.13 0.8 10 66 0.15 0.7 10 65 0.15 0.6 7 55 0.15 0.5 7 60 0.13 0.4 4 39 0.09 0.1 0 1 Reference subst. 0.15 0.45 1.6 3.5 2.19 2.35 2.30 2.11 2.03 1.90 0.39 1.26 0.998 1.000 0.997 0.996 0.991 0.988 0.917 1.000 The result of the reference substance is within the range 1OTa,10 f f l) 6 9 3 lab.ref.no.: 99312-2 Page 8 of 31 GROWTH CURVES: Growth inhibition test with Skeletonema costatum Test substance: "FC-203 Light Water Brand AFFF" Lab. ref.: 99312-2 7n 0) oc 100 mg/l 'anon (hours) 000694 lab.ref.no.: 9312-2 Page y oj i l inhibition of the growth of Skeletonema costatum with: mg/1 (FC-203 Light Water Brand AFFF) Experimental data: Concentration in Growth rate FC-203 Light Water Brand AFFF Control 1 Control 2 Control 3 Control 4 Control 5 Control 6 Control mean : 0.32 0.32 0.32 1.00 1.00 1.00 3.20 3.20 3.20 10.00 10.00 10.00 32.00 32.00 32.00 100.00 100.00 100.00 2.39 2.14 2.29 2.07 2.06 2.20 2.19 2.30 2.32 2.43 2.36 2.41 2.13 2.05 2.12 2.17 2.22 1.79 2.09 1.86 2.05 1.79 0.00 0.65 0.52 Inhibition in percent . - 0 0.0 0.0 0.0 0.0 0.0 2.8 6.5 3.3 1.0 0.0 18.3 4.6 15.1 6.5 18.3 100.0 70.3 76.3 STATISTICAL PARAMETERS CALCULATED FROM CONTINUOUS RESPONSES 5 doses and 11 responses have been used during calculations. EC 10 : EC 50 : EC 90 : 13.33 61.95 288.00 95 % confidence limits : ( 95 % confidence limits : ( 95 % confidence limits : ( 8.29 .. 48.25 .. 186.95 .. Coefficient of determination :0.763 18.46) 83.10) 562.40) 000695 Lab.ref.no.: 99312-2 Page 10 o f 31 T est fo r T o xicity Marine herbivore: Acartiatonsa 000696 V-'*99312-2 TEST REPORT ACUTE TOXICITY TEST WITH THE MARINE COPEPOD Acartid tOllSCl fQl NORSK a k k r e d h e r in g Mr. POI ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The 48 hours LC50was calculated to 200 mg/1. The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: METHOD: ISO/DIS 14669 - 1997: Water quality - Determination o f acute lethal toxicity to marine copepods (Copepoda, Crustacea). Test ORGANISM: Acartia tonsa (Dana), supplied by the Marine Biological Laboratory, University o f Copenhagen. CULTIVATION: The test organisms were supplied as eggs, and were cultivated in accordance with the "Paris Commission - Ring Test Protocol" (VKI). Large copepodites and adults were used in the test. PREPARATIONS: Natural seawater (salinity: 34 %o) from an unpolluted site in Byfjord was used as basis for the dilution water. The water was filtered through a GF/C filter prior to use. Test solutions were prepared from a stock solution. A stock solution o f 1003 mg/1 was prepared by stirring 0.5017 grams o f the product in 1 litre o f dilution water. Other concentrations were prepared from this stock solution. INCUBATION: The test was run in glass containers (28 ml rolled rim vials) each containing 25 ml o f test solution and 5 animals, 4 replicates for each concentration. The vials were kept under a 16h/8h light/dark photoperiod at a temperature o f 20 1 C. pH and oxygen measurements were performed as indicated on the data sheet. 000697 Lab.rej.no.: 99312-2 fuge 1/ oj J1 DATA ANALYSIS: CALCULATIONS: The effect on the survival o f Acartia tonsa is expressed as the concentration o f a product lethal to 50% o f the test animals (LC50). The combined mortality per test concentration were used for calculation. The 24 hours and 48 hours LC50 values and the 95% confidence limit were calculated by using the standard procedure PROBIT Analysis, National Swedish Environmental Protection Board (Version 2.3,1990). This programme also calculate test concentrations lethal to 10% and 90% o f the test animals. NOEC: Calculation o f NOEC (No Observed Effect Concentration) is done by single factor ANOVA followed by Bonferronis procedure for comparing each concentration mean with the control mean. Test RESULTS: Table 1. LC and NOEC values obtained with "FC-203 Light Water Brand AFFF". Acartia tonsa 24 hours 48 hours LCio 160 (84-220) 76 (32-110) LCso LC90 340 (260-460) 740 (530-1400) 200 (140-270) 510 (350-1100) NOEC: 100 100 Values indicate 10%, 50% and 90% lethality after 24 and 48 hours. Units in mg/l. Values are calculated by PROBIT analysis, and 95% confidence intervals are indicated. NOEC are calculated by the computer programme GraphPad InStat 3.0. V a lid a t io n : The validity criteria given in the test protocol are fulfilled, in that the dissolved oxygen concentration at the end o f the test was greater than or equal to 4 mg/l, the percentage mortality in the controls was less than 10%, and the 48 hours LC50 o f 3,5-dichlorophenol (reference) was in the range normally found. Lab. ref. no.: Sample received.: Test period: Report date: 99312-2 20.09.99 06-08.10.99 06.01.2000 Elin Horve Engineer Analytical technician Age Molversmyr Senior Research Scientist Quality Assurance Enclosed: Data sheets This test report is issued by a laboratory accredited by Norwegian Accreditation (NA). The report may not be reproduced in any form other than in full, without the permission in writing by RF - Miljalab. 000698 99312-2 "o - PRIMARY DATA: Acute toxicity test with Acartia tonsa Test substance: Lab. ref.: Start date: Measurement: "FC-203 Light Water Brand AFFF" 99312-2 06.10.99 Number of dead Concentration (mg/I) Control 10 32 100 320 1003 Total number Number of specimen pr. vessel Specimen A C E pr. cone. B D F 5 55 30 5 5 5 5 55 20 5 5 55 20 5 5 55 20 5 5 55 20 5 20 ' 5 55 5 NUMBER OF DEAD 24 hours 48 hours ACE BDF Total ACE BDF Total 000 0 00 001 1 101 2 0 00 0 0 10 00 1 000 1 001 11 2 100 0 2 01 11 4- 2 12 3 44 2 73 14 555 5 55 5 20 5 20 Reference substance (3,5-dichlorophenol): 1.0 mg/I 5 55 0 20 2 54 30 5 55 100 3 130 The result with the reference substance is within the range normally found. 15 000699 99312-2 Test substance: "FC-203 Light Water Brand AFFF" Lab. ref.: Start date: 99312-2 06.10.1999 Measurements of oxygen and pH. Concentration (mg/l) Start Oxygen (mg/l) pH 24 hours 48 hours Oxygen pH Oxygen (mg/l) (mg/l) Control 7.6 8.1 7.2 10 8.1 8.1 7.3 32 8.1 8.1 7.1 100 8.1 8.1 6.7 320 8.0 8.2 6.1 1003 7.3 8.2 6.6 8.1 pH 8.1 8.2 8.2 8.2 8.1 Reference substance (3,5-dichlorophenol): 1.0 mg/l 7.7 8.1 7.3 8.2 000700 99312-2 T est fo r to xicity Marine Amphipode: Corophium volutator 000701 Lab.reJ.no.: 99312-2 Page 6 o f 31 TEST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE m a r in e a m p h ip o d Corophium volutator (S i NORSK AKKREOITERING ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The lOd LC50 was calculated to >3060 mg kg'1dry weight sediment. The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: METHOD: ASTM E l367-90, Standard Guide For Conducting 10 day Static Sediment Toxicity Tests with Marine and Estuarine Sediments. TEST organism: Corophium volutator, from an unpolluted site near Trondheim. CULTIVATION: The test organisms were supplied as adults (4-8 mm in size) and were held in aerated seawater at 15C. A small amount o f natural seaweed was used for feeding. Pr e p a r a t io n : Natural seawater (salinity: 34 %o) from an unpolluted site in Byfjorden outside Stavanger was used for dilution water. Sediment collected at an unpolluted site was used for preparing test sediments. The sediment is a muddy sand and was analysed for organic content and proportion silt for each test. Each test concentration was prepared by adding the product in 600 grams o f damp sediment in a plastic bucket. 200 ml o f seawater was added and the bucket was shaken for 3 hours. The sediment was divided into three beakers, 400 ml o f seawater was added to each, and the beakers were aerated over night. 10 animals were then randomly selected for each beaker. A sample o f the damp sediment was analysed for water content, and all concentrations are calculated as mg kg'1 sediment dry weight. INCUBATION: The test was run in glass containers (600 ml) each containing 200 g o f test sediment, app. 400 ml o f seawater and 10 animals, 3 replicates for each concentration. The beakers were kept under continuous aeration at a temperature o f 15 1C. pH and oxygen measurements were performed as indicated on the data sheet. 000702 99312-2 DATA ANALYSIS: CALCULATIONS: The effect on the survival o f Corophium volutator is expressed as the concen tration o f a product lethal to 50% o f the test animals (LC50). The combined mortality per test concentration were used for calculation. The 10 day LC50 value and the 95% confidence limit are calculated by using the standard PROBIT Analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). This programme also calculate test concentrations lethal to 10% and 90% o f the test animals. NOEC: Calculation o f NOEC (No Observed Effect Concentration) is done by single factor ANOVA followed by Bonferronis procedure for comparing each concentration mean with the control mean. TEST RESULTS: Table 1. LC and NOEC values obtained with "FC-203 Light Water Brand AFFF" Corophium volutator 10 days LCio >3060 LCjo LC90 >3060 >3060 NOEC: 3060 Values indicate 10%, 50% and 90% lethality after 10 days. Units in mg kg'1sediment dry weight. Values are calculated by PROBIT analysis. NOEC are calculated by the computer programme GraphPad InStat 3.0. VALIDATION: The validity criteria given in the test protocol are fulfilled, in that the dissolved oxygen concentration at the end o f the test was greater than or equal to 60 %, the percentage mortality in the controls were less than 15% and a test with Fluorantene (reference) was in the range normally found. The sediment used is found to be within accepted limits for organic content and silt fraction. Table 2. Characteristics of the sediment used for testing Organic content (%) 0.7 Silt fraction (%) 0.8 Lab. ref. no.: Sample received.: Test period: Report date: 99312-2 20.09.99 03-13.12.99 06.01.2000 Elin Horve Engineer Analytical technician Age Molversmyr Senior Research Scientist Quality Assurance Enclosed: Data sheets This test report is issued by a laboratory accredited by Norwegian Accreditation (NA). The report may not be reproduced in any form other than in full, without the permission in writing by RF - Miljolab. 000703 99312-2 PRIMARY DATA: Acute toxicity test with Corophium volutator T est substance: "FC-203 Light Water Brand AFFF" Lab. ref.: Start date: Measurement: 99312-2 03.12.99 Number of dead Total number Number of specimen pr. vessel NUMBER OF DEAD 5 days 10 days Concentration Specimen A C E (mg/kg dry weight) pr. cone. B D F ACE BDF Total ACE BDF Total Control 10 10 10 60 10 10 10 0 00 0 00 0 10 10 10 91.1 30 2 00 2 10 10 10 501 30 101 2 1030 10 10 10 30 100 1 3060 10 10 10 30 1 02 3 Reference substance (fluoranthene): 10 10 10 20.3 30 3 22 The result with the reference substance is within the range normally found. 7 ................ 000704 Lab.ref.no.: 99312-2 Page 9 o f 31 Test substance: Lab. ref.: Start date: "FC-203 Light Water Brand AFFF" 99312-2 03.12.99 Measurements of oxygen and pH. Start Concentration Oxygen (mg/kg dry weight) (%) pH 5 days Oxygen (%) pH Control 94 8.1 91 8.1 91.1 96 8.1 93 8.1 501 77 7.8 92 8.1 1030 97 8.1 93 8.1 3060 97 8.1 74 7.7 10 days Oxygen (%) pH 91 8.0 88 8.1 90 8.1 86 7.9 91 8.0 Reference substance (fluoranthene): 20.3 95 8.1 90 8.1 90 8.1 000705 Lab.ref.no.: 99312-2 Page 20 of 31 D ata Sheets 000706 Lab.ref.no.: 99312-2 Page 21 o f 31 HMS-DATASLAD (Heise-, Milje-- og Sikkerhetsdatablad) *s a a a x s a s a s a s x a a M s a s s a 3 3 8 s a a a s s a s a a s s a s s a a (a s s 3 s s s s s s 8 s s 3 3 s a x s s s a a a a a Dokumentnr.: Erstattet : 10-3814-0 Utgitt : 03/11/98 Versjon _ : 06.00 03/10/97 Skrevet ut : 11/11/98 Side 1 av 11 KMS-databladet er uzarbeidet av M i l jeavdelingen ved 3M Norge A/S. Telefon: 63 84 75 00 / Telefax: 63 84 17 88 1 IDENTIFIKASJON AV KJEMIKALIET OG ANSVARLIG FIRMA. Importer: 3M Norge A/S Kandelsnavn: <3! FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Deklaras jor.snummer, Produktregisteret: P-nr.: 002614. 1 i Telefon, Giftinformasjonssentralen: 22 59 13 00 2 OPPLYSNINGER OM K-ZMISK SAMMENSETNING. Informasjon om enkeltkomponenter, faresymbol(er) og risikosecninger STOFFNAVN CAS-nr VEKT-PROSENT VANN 7732-18-5 2-(2-3UTOKSYETOKSY)-STANOL / 112-34-5 (DIETYLENGLYK0LM0N03UTYLETER) Faresymboler/risikosetninger: Xi; R: 36 1,2-ETANDIOL 107-21-1 Faresymboler/risikosetninger: Xn; R: 22 SYNTETISKE DETERGENTSR Trade Secret FLUORALKYL OVSRFLATSAXTIVS STOFFER Trade Secret RESTER AV ORGANISES FLUORKJEMIKALIER Trade Secret 36 - 40 - 35 = 20 1-5 1-5 Ikke kjent 3 VIKTIGSTE FAREMOMENTER. 000707 Lab.ref.no.: 99312-2 Page 22 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Viktigste skadevirkninger Helsefare: Kan irritere eynene og huden. Sikkerhet: Miljefare: Spesialavfall. 4 FORSTESJELPSTILTAK. Tiltak ayne: Skyll straks aynene med rikelige mengder vann. Kontakt lege umiddelbart. Tiltak hud: Skyll huden med rikelige mengder vann. Hvis irritasjonen vedvarer/ kontakt lege. Tiltak innnding: Kvis symptomer oppstr, bring vedkommende bort fra eksponeringskilden. Sarg for frisk luft. Hvis symptomene vedvarer, kontakt lege. Tiltak svelging: Kontakt lege umiddebart. Fremkall brekninger kun i samrd med medisinsk personell. Gi aldri noe gjennom munnen til en bevisstlas person. 5 TILTAK VED BRANNSLUKNING. Egnet brannslukningsmiddel: Produktet er et brannslukkingsmiddel. Ikke egnet brannslukningsmiddel: Eksponeringsrisiko ved brann: Forbrenningsprodukter ved brann: Prosedyrer ved slukking av brann: Lab.ref.no.: 99312-2 Page 23 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM 6 TILTAK V2D UTILSIKTET UTSLI??. Personlige vernetiltak: Se vernetiltak under andre punkter i dette HMS-databladet. Tiltak ved utilsiktet utslipp: Ventiler omridet. Spill avgrenses umiddelbart. Dekk til med et absorberende materiale. Spill samles opp umiddelbart. Rengjar omridet med vann. Plasseres i en egnet beholder med lokk. Fjerning av kjemikalieavfall: Se punkt 13, Fjerning av kjemikalieavf all. 7 HNDTSRING OG OPP3EVAR2NG. i i !! Betingelser for sikker oppbevaring: Ml ikke lagres i omrider hvor produktet kan komme i kontakt med mat eller legemidier. Lagres ved temperatur under 49grader celsius. Lagres ved temperaturer over 0 grader celsius. Hold beholderen tect lukket r.ir produktet ikke er i bruk. Uforer.eiige materialer: Ventilasjon: Oppbevar emballasjen pi et godt ventilert sted. Sikkerhetstiltak for i forhindre brann: Sikkerhetstiltak for i forhindre eksplosjon: Ikkebrennbar, Sikkerhetstiltak for i forhindre statisk elektrisitet: Forholdsregler ved bruk: Hold emballasjen tett lukket. Rayking forbudt: Under bruk av produktet kan rayking forirsake forurensning av tobakken og/eller reyken og farlige dekomponeringsprodukter kan dar.nes. Se punkt 10, stabilitet og reaktivitet, skadelige dekomponenter. ii 8 EKSPONERINGSKONTROLL OG PSRSONLIG VERNEUTSTYR. I 99312-2 Page 24 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Oyevern: Unngi i fk damp, spray eller take i oynene. Bruk tette vernebrilLer med ventiier. Hindvern: 3ruk egnede verr.ehar.sker av her.siktsmessig materiale ved hindtering av produktez. Vernehansker av folgende materiale(r) anbefales: Butylgummi. Annet hudvern enn hindvern: Unngi hudkontakt. Andedrettsvern: Unng inninding av luftbiret materiale. 3asert pi konsentrasjonen av luftforurensninger i arbeidsatmosfaren velges en av folgende type(r ) godkjent incedrettsvern: halvmaske med filter mot organiske damper og vaskeformige partikler: A/P2SL. Svelging: Det mi ikke spises, drikkes eller roykes under arbeid med produktet. Vask utsazte omrider grundig med sipe og vann. Vask hendene etter hindtering og for spising. Anbefalt ventiiasjon: Kvis utsugr.ingsventilas jon ikke er tilstrekkelig, mi-egnet godkjent incedrettsvern benyttes. Sorg for tilstrekkelig ventiiasjon slik at campkonsentrasjonene holdes under anbefalte administrative norme; og/eller kontroller spray eller tike. Adm. normer for forurensning i arbeidsatmosfare, Februar 1996: VANN (7732-18-5) Anmerkninger: Ingen adm. norm. 2-(2-3UTOKSYSTOK3Y)-ETANOL / (DIETYLENGLYK0LM0N03UTYLETER) (112-34-5) 8-timers verdi ppm: 35 Anmerkninger: Amerikar.sk grenseverdi anbefalt av produsenten. (Ingen norsk adm. norm). 1,2-ETANDIOL (107-21-1) 8-timers verdi ppm: - (stov) 8-timers verdi mg/m3: 10 (stov) Takverdi ppm: 25 (damp) Takverdi mg/m3: - (damp) SYNTETISKS DETERGENTER (Trade Secret) Anmerkninger: Ingen adm. norm. FLUORALKYL OVERFLATEAKTIVE STOFFER (Trade Secret) Anmerkninger: Ingen adm. norm. RESTER AV ORGANISKE FLUORKJEMIKALIER. (Trade Secret) 8-timers verdi mg/m3: 0,1 Grenseverdi anbefalt av 3M. 0 i~ao.rej.no.: 99312-2 Page 25 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM 9 FYSISKE OG KJSMISXE EGENSKAPER. Tilstandsform, farge, lukt: Klar, ravfarvet vaske. pH : ca. 8.5 Kokepunkt/-intervaIl: ca. 100 C (Begynnende) Smeltepunkt/-intervall: Ikke relevant Flammepunkt : Ingen (Setaflash CC) Selvantennelighet: Ikke relevant Eksplosjonsgrenser, nedre: Ikke relevant Eksplosjonsgrenser, cvre: Ikke relevant Damptrykk: ca. 14.3 mmHg (Kalkulert v/romtemperatur) Loselighet i vann: 3landbar. Spesifikk vekt: ca. 1.05 (vann=*l) Damptetthet: ca. 1.21 (luft=l) (Kalkulert v/20C) Flyktige organiske forbindeiser (VOC): = 578 g/i SCAQMD Kalkulert v/20C. Fordampningshastighet : < 1 (butylacetat^l) Viskositet: Ikke kjent 10 STA3ILITET OG RSAXTIVITET. Forhold som skal unngs: Materialer som skal unngls: Ikke kjent. Farlige spaltningsprodukter: Karbonmonoksid og karbondioksid. Hydrogenfluorid. Giftige damper, gasser eller partikler. Dekomponering av bruksferdig blanding forventes ikke & representere noen risiko. ! OQOtl1 Lab.ref.no.: 99312-2 Page 26 o f 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Stabiliteli og reaktivitet: Stabilt. Farlig polymerisesjon vii ikke forekomme. 11 OPPLYSNINGER OM HELSEFARE. Effekter ayne: Mild ayeirritasjon: symptomer kan vare radhet, hevelse, smerter og trer. Effekter hud: Mild hudirritasjon (etter langvarig eller ggentatt kontakt): symptomer kan vare radhet, hevelse og klae. Effekter innindir.g: Sn enkelt overeksponering som overstiger anbefalte administrative normer, kan fere til: Pvirkning av sentralnervesystemet: symptomer kan vare hodepine, arhet, savnighet, manglende koordin.as jonsevne, nedsatt reaksjonsevne, slaret tale, svimmelhet og i ekstreme tilfeller bevisstlashet. Irritasjon (avre luftveier): symptomer kan vare srhet i nese og svelg, hosting og nysing. Effekter svelging: Dyreforsek utfcrt med organiske fluorkjemikalier, som finr.es i dette produktet, viser effekter som leverforstyrrelser, vekttap, manglende appetiti, slavhet samt effekter som pavirker neurologi, bukspytt, binyre og hematologi. Det foreligger ingen kjente helseeffekter for mennesker fra eksponering overfor organiske fluorkjemikalier nr de brukes som forutsatt og henhold til veiledning. Svelging kan- fere til: Pvirk.ning av nvrene: symptomer kan vare redusert urinmengde, blod i urinen og ryggsmerter. Aspirasjonspneumoni (Lungebetennelse som skyldes at fremmedlegemer kommer ned i lungene. En alminnelig rsak til tilstanden er oppkast.): symptomer kan vare hosting, pustevansker, gisping, hoste opp blod og lungebetennelse som kan vare livstruende. Informasjon om allergi, overfelsomhet: Kreftfremkallende egenskaper: 00 0712 Lab.ref.no.: 99312-2 Page 27 o f 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Arvestoffskadelige egenskaper: Reproduksjonsskadelige egenskaper: Andre skadevirkninger, helse: Et resyirr vedrarende produktets giftighet er tilgjengelig p foresporsel. Dette produktet inne'nolder en eller fiere organiske fluorkjemikalier, som muligens kan absorberes og lagres i kroppen over lengre tid, enten som utgangsmolekylet eller som nedbrytningsstoffer (metabolitter), og kan akkumuleres ved gjentatte eksponerir.ger. Det foreligger Ingen kjente helseeffekter for mennesker fra eksponering overfor orga'niske fluorkjemikalier nlr de brukes som forutsatt og i henhold til veiledning. Forekomsten av orgar.iske fluorkjemikalier i blodet til den generelle befolkningen og underpopulasjoner som arbeidere, har vart publisert sicen 1970 arene. 3Ms epidemiologiske studier av egne arbeidere viser ingen skacelige effekter. 12 OPPLYSNINGER OM MILJ0FAR2. Persistens/3iologisk necbrytbarhet: Dette produktet inr.eholder en eller flere organiske fluorkjemikalier son muligens ikke er nedbrytbare og forblir i miljaet (persistente). Andre skadevirkninger, milja: Nedbrytbarhet: COC (Chemical Oxygen Demand) * 1,1 g/g; 30D 20 dagers (3iochemical Oxygen Demand) * 1,1 g/g; BOD 20 dagers/COD * 1,00. Akvatisk giftighet: Statisk 96 timers LC50 for fisk {Fathead minnow (Pimephales promelas)) * 750 mg/1; Statisk 96 timers LC50 for fisk (Rainbow trout (Oncorhyncus mykiss)) 1300 mg/1; Statisk 48 timers LC50 for daphnia (Water flea (Daphnia magna)) 1600 mg/1 (1300-2100 mg/1); Statisk 48 timers LC50, Amfipode (Scud (Gammarus fasciatus)) * 1100 mg/1 (840-1300 mg/1); 48 timers EC50, Eastern Oyster embro-larvae (Crassostrea virginica)' - 47 mg/1 (10-234 mg/1); 48 timers LC50, Common mummichog (Fundulus heteroclitus) * 2500 mg/1 (1700-3600 mg/1); OO Lab.ref.no.: 993J2-2 Page 28 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM (360-710 mg/1); IC50 Respirasjon, Activated sludge ** > 1000 mg/1, ^ TTC (2 ,5,5-trifenyltetrazoliumklorid) test viste ingen ensymhemning for konservtras joner o d d til 1 0 0 0 mg/1. Sarg for avfallshandtering iht. gjeldende forskrifter. 13 FJERNING AV KJEMIKALISAVFALL. Metoder for fjerning av kjemikalieavfall : Spesialavfall. Lever avfall til en offendi^ godkjent innsamler, mottaks- eller behandlingsanlegg for spesialavfall. Anbefalte avfallsgrupper: HOVEDKATEGORI 07: AVFALL FRA ORGANISES PROSSSSER. UNDERXATEGORI 07 06 : Avfall fra P3D3 av fettstcffer, sipe, rengjaringsmidler, desinfeksjonsmidler og kosmetikk. EAX-kode 07 06 03: Kalogenerte organiske lasemidler, vaskevasker og moderlut. Avfallstoffnummer: 7151 Organisk avfall med halogen. Spesielle komponenter: ir.neholder flourforbindelser. 14 OPPLYSNINGSR OM TRANSPORT. ADR-klasse: siffer: bokstav: margnummer: CEFIC-kort: UN-nummer: ICAO-klasse: IMDG-klasse: IMDG-side: EMS-nr.: MFAG: 0Q0714 Lab.ref.no.: 99312-2 Page 29 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Ovrige opplysninger: Ikke transportsarlig gods. 15 OPPLYSNINGER OM LOVER OG FORSKRIFTER. Merkeetikett: Symbol(er): HELSESKADELIG (Xn) Inneholder: 2-(2-butksyetoksy)-etanol 35% Etylenglykol 20% R-setninger: Farlig ved svelging. Kan irritere aynene og huden. S-setninger: Unng innnding av damp/spraytetke. Unng kontakt med huden og aynene. Fr man stoffen i aynene; skyll straks grundig med stre mengder vann og kontakt lege. Etter hudkontakt, vask-med spe og vann. Ved svelging, kontakt lege omgende og vis denne beholderen eiler etiketten. Kun til industriell bruk. Ikke beregnet til bruk som medisinsk utstyr aller legemiddel. YL-gruppe: 00 Korr, yrkeshyg. luftbehov: vrige oppiysninger om merkeetiketten: Ovennevnte merking er basert p tidligere merkeforskrifter og vil vare finne p produktet en tid fremover. Merkingen vil imidlertid erstattes av felgende merking, som er basert p reviderte merkeforskrifter av januar 1998. Symbol: Ingen Inneholder: 2-(2-3utoksyetoksy)-etanol, 1,2-etandiol Kan irritere aynene og huden. Unng innnding av damp/spraytetke. Unnga kontakt med huden og aynene. Fr man S t o f f et i aynene; skyll straks grundig med stre mengder vann og kontakt lege. Fr man S t o f f p huden, vaskes straks med stre mengder spe og vann. Ved svelging, drikk to glass vann og kontakt lege umiddelbart. YL-gruppe: 00 00<D Lab.ref.no.: 99312-2 Page 30 of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Spesielle lover og bestemmelser: 1. Forskrift ora utarbeidelse og distribusjon av Kelse-, Miljo- og Sikkerhetsdatablad for farlige kjeraikalier. 2. Forskrift om klassifisering og merking av farlige kjeraikalier. 3. Forskrift om klassifisering, merking m.v. av stoff som kan medfare miljofare. 4. Forskrift om stoffkartotek. 5. Forskrift om spesialavfall. 6. Etc. 16 ANDRE OPPLYSNINGER AV 3ETYDNING FOR BRUXERNES SIXXSRKET OG HELSE. Anvendelsesomrder: Filmdannende skumkonsentrat for slukking av brann i hydrokarboner. Viktigste kilde(r) ved utarbeidelsen av HMS-databladet: Datablad fra 3M General Offices, St. Paul, Minnesota, USA. rsak til oppdatering: Hele databladet er revidert. Tilpasset nye merke- og KMS-databladforskrifter, fastsatt i januar 1998. Etc-. Sgne opplysnir.ger: Informasjonen pi dette HMS-databladet er i henhold til vire nvsrende oppiysninger og beste bppfatning angiende riktig bruk og hndteringen av dette produktet under normale forhold. Enhver bruk av produktet som ikke er i samsvar med dette HMS-databladet, elier som medforer bruk av produktet i kombinasjon med andre produkter eller enhver annen prosess er brukerens ansvar. 000 716 Lab.ref.no.: 99312-2 Page 31 o f 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM FOLGENDE PRODUKTES DEXXES AV DETTE HMS-DATA3LADST: 3M ID-nr. : XF-0008-0217-3 3M AFFF FC-203 Brannslukningss kum Produksjon 3M ID-nr. I : XF-0008-0099-5 3M Light Water 3% AFFF Fire Fighting Foam, FC-203,1000 L 3M ID-nr. : XF-0008-0070-6 3M Light Water 3% AFFF Fire Fighting Foam, FC-203, 200 L- 3M ID-nr. : XF-0008-0069-8 3M Light Water 3% AFFF Fire Fighting Foam, FC-203, 20 L I l II i ! I I 000717