Document bBMZzxE585MnbNo6r0MyQDZoZ

CLEAN ACROSS AMERICA AND THROUGHOUT THE WORLD'" ZEP MANUFACTURING COMPANY P.O. BOX 2015 ATLANTA, GEORGIA 30301 ISSUE DATE: 01/24/92 SUPERSEDES: ZEP HC 2000/ PRODUCT Ndi SECTION I EMERGENCY CONTACTS TELEPHONE: (404.1 352-1680 BETV/EEN 6:00 AM - S.00 PM lEST) MEDICAL EMERGENCY: (404) 435-2973 (404) 351-2952 (404) 432-2873 non-office hours, weekends AND HOLIDAYS. PLEASE CALL YOUR local poison control TRANSPORTATION EMERGENCY: (404) 922-0923 CHEMTREC: 1-800-424.9300 TOLL-FREE - ALL CALLS RECORDED DISTRICT OF COLUMBIA: (J (202) 483-7616 ALL C' A,LLCSS RECORDED SECTION H - HAZARDOUS INGREDIENTS DESIGNATIONS " SODIUM METASILICATE " Silicic acid (H2-SI-03) dlSOOium S*H water O'MSI CAS# 6834-62-0. RTECS# W0275000. OSHA Dust Limit-2mg'm3 (lor powders only) ____ @ " ETHYLENE GLYCOL MONOBUTYL ETHER " 2-bu!0xyemanol; butyl Cdlosolve. CAS * 1 t1-78-2; RTECS * KJ8575000. OSHA PEL (SKIM)- 25 opm - SOOtUM hvOROt:CE * caustic joes: sod* lye. CAS# 1310-73-2, RTECS# WBj900000; OSHA/ACGIH CEILING LIMIT-2 MG<M3 TLV (PPM) NiO 25 N/D EFFECTS (SEE REVERSE) COR TOX IRR CBL TOX COR /V pp < < identities chemicals wed under SARA-Secnon 313 lor release reporting___________________________________________________ SECTION III HEALTH HAZARD DATA Special Note: MSDS data pertains 10 the product as dispensed from the container. Adverse health effects woulc not be expected under recommer conditions of use (diluted) so long as prescribed safety precautions are practiced. Acute Effects of Overexposure: Corrosive on contact. Overexposure will produce tissue destruction particularly on mucous membranes of eyes, mouth, and respiratory tract Eye contact may pro<~ severe irritation and blindness unless immediately Hushed Concentrated solutions may produce immedleie skin demage Dilute solutions may produce severe irritf which intensities ss contact continues Inhalation o( mists may pioduce severe nesal and respiratory irritation or permanent damage Ingestion will produce tissue danOi the gestrointestmel tract. Overexposure oy inhalation may cause respiratory irritation. Ingredient! in this product may aggravate existing skin. eye. oi respira disorders. Chronic Effect* of Overexposure; Repealed or prolonged exposure of skin can produce chrome dermatitis characterised by redness, scaling, and blistering. Repeated exposure to spray mists may lee chronic eye mtlammation, chrome iesoirat0ry (tact irritation ot lung damage. Animal studies indicate e potential tor liver, kidney, or red blood cell damage Ralevanc these studies or exposure levels which might produce these effects in humans nas not been established. None of the ingredients ate listed as carcinogens by IARC. > or OSHA Eet'd PEl/TLV: Not established Primary Route* of Entry: Inh, Skin HMIS Code*; HEALTH 3.FLAM. 0.REACT 0.PERS PROTECT B ;CHRONlC HAZ Y6S ' FIRST AID PROCEDURES: Skin: Immediately flush contaminated $km with plenty ol water for at least IS minutes Get medical attention immediately. Eyes: immediately tiusn eyes with plenty ot watet tot at least :5 minutes, occasionally tilting upper and lower lids. Get medical attention at once. Inhale: Move exposed person to trash a>r it irritation persists, get meo>cal attention promptly Ingest- If swallowed, do not induce vomiting II vomiting occurs, keep head below hip level. Gel emergency medical attention immediately Protective Clothing-. Eye Protection: Respiratory ProtectionVentllatfon- SECTION IV SPECIAL PROTECTION INFORMATION Wear a face shield, rubber or neoprene gloves. a rubber apron, end impervious footwear. Wear splaah-oroot ssteiy goggles especially if contact lenses ate worn. No extra measure* are naeded if ventilation is adequate. Provide local exneust'ventuation as needed to keep concentration of vapors below exposure limits (PEL/TtV) SECTION V - PHYSICAL DATA Bolting Point (*F): 213 F specific Gravity: Percent volatile by Volume (%): 93 4% vapor Denaity (aln D: Solubility in Water COMPLETE pH (concentrate); Appearance and Odor A RED LIQUID WITH A ' butyl ' ODOR 1 04 >I 13 2 Vepor Pressure (mmHg): evaporation Rate (WATER pH (use dilution of); 23 > t0 N/D Flash Point (*F) (method used): Flammable Limit*: Extinguishing Media: Special Fire Fighting: Unusual Fire Hazards: SECTION VI - FIRE AND EXPLOSION DATA NOME() LEL N/A DEL N/A Noncombustibie. Wear seil-contained positive pres Breathing apparatus Fire exposed drums should be cooled min stream of water. A 06171 CONFIDFNTTA EP manufacturing company^ J\4ATEH1AU*SAFETY:DATA.SHEET.: SECTION VII REACTIVITY DATA PA6Er2i ibllity: lompatibility (avoid); lymerlatiorv ttrdoun Decomoo.ition, Stable Strong acrdi and oxidising agents. Will not occur. Carbon alO'.iOe. carbon monoxide, and other unidentified organic compounds SECTION VIII - SPILL AND DISPOSAL PROCEDURES *D$ to -a Taken in Casa Material it Released or Spilled: serve sataiv precautions n sections a & 0 dunng clean-up Absorb sprii on art men absptbtnt material (eg. Z0-O-2crb). pick up and place in a dean DO T tot'cetion container lor a&posai Wash e<e* thoroughly with a detergent solution and then rinse well with water, rate OiiDotai Method. uids cannot be sent to lanotms unless soidified Unusable product and some collected, spent use-dilutions may reduce disposal as a hazardous waste at o otrmitted atment/storage/disDOsai fac^ty in most states hazardous wastes m total amounts of 220 ib$ Or less per month may be disposed of,n a chamicsl or industrial waste c/iii. .1 company eiMuem s uUimateiy treated by a publicly owned treatment works, neutralization of spent tank-solutions with subseauent discharge to the sewer may possible Consult local, state and ledera* agenc/as for proper disposal method rn your area. RA Hazardous Waste Numbers. DOQ2 iS6E ABOVE)_________________________________________________________________________________ SECTION IX - SPECIAL PRECAUTIONS ccautiont to be Taken When Handling and Storing: >re tightly clostd container m a dry area at temps between 40-120 degrees F Store away from strong acids and oxidizing compounds. Koep oroduct away hom skm d eyes. Do not breathe spray mists or vapors. Clothing or shoes wnicn become contaminated wiih suostance should be removed promptly and not reborn untit iroughry cteaneo Kteo out oi the reach ol children SEGTiQNX^TRANSPORTATION DATA IT Proper Shipping Name: COMPOUND. CLEANING. UOUlO IT Hazard Class: CORROSIVE MATERIAL )T i.o. Number: NA1760 DOT L#bl/Piac#rd: CORROSIVE A TSCA Chemical Inventory. ALL INGREDIENTS ARE LISTED *A CWA 40CFR Part 117 substance (AQ in a single container): . SODIUM HYDROXIDE. 1000# NOTICE- *k you tor your inter*** in. end use of. Zap products. MaiHiiactunng Co <i pleased to be or service to you by flying mis Material Seitiy Oats Sheet tor your hies. Zto ulacturmg is concerned tor your neaith ana safety. Ztp tucts can pa used sa>iy with proper orotecitve equipt and proper hertaimq praciices consistent with ieosi ructions and the MSOS Beiore using any Zap product, lure to read me cumoi** rebel ar>0 the Material Safety > Sheet. a furthei word ot caution Zeo withes to aavise mat >us accidents nave resulted worn the misuse or pued coniemeK. Empty containers itiam residua ud anp/or vapor) and can oe dangerous. DO NOT pres it. cut. weid. braze, solder, arm. grind or expose suen tamers to heat. Marne, or other sources ot ignition; they expin ' v develop harmful vapors and pocsibiy causa y or . Clean empty containers by triple nrtsmg > wak an appropriate solvent. Empty containers t be cent to e drum reconditioner before reuse. TERMS AND ABBREVIATIONS USED IN THE MSOSBY SECTION ALPHABETICALLY T10N II: HAZARDOUS INGREDIENTS Carcinogen a chemical lifted by the Natrona* ToxicolProgram <WTP), the international Agency lor Research -ancer (IARC) or OSHa as a definite or possible human :er causing agent w* Chemical Abatreci Services Registry Number a ersaily accepted numbering system (or chemical sub- ces. Combustible At temperatures between 100*P and F chemical gives oft enouQh vapor 10 ignite ri a source nifion is present at lasted with a closed cue raster. : Central Nervous Syttem depressant reduce* the ectiv- I live Oram and spinal cord t t' Corrosive Causes irreversible alterations in living ie la o burns). .KViATtONS: Chemical and common names ot hazardous ediems. Eye irntani Only Causas reversal# reddening ano'Or mmanon of eye (issues. OSURE UM/TS The ume weiqhied averooe iTWAi eir- >e concentration at which most workers can be exposed Oul any expected adverse elite** Primary sources e ACQIH TLYs. and OSHA PEL* (TWA. ST!L arid ceiling S) '.Qtp* American Comerence ot Governmental industrial rgiemsis. iuno. The concentratton rnar should not be exceeded th# workplace Ounng any part ot iha working exposure Occupational Sataty and Health Administration :L Rermissioie Exposure limn- a set of time weronted rage exposure values eetebuthed bv QSKA. tor e irmai S-hour day and a 40-hour work week. >w- Pans per million wrui of ineasure for exposure sits. ) skin Skin contact with substance con contribute 10 ereu expotuie. i. Short Term exposure umit- Maximum concentration lor a continuous IS-rmnute exposure period. tlv. Threshold Limn Value A tel of time weighted aver age exposure limits, established by the ac&ih. tor a normal 9-hour day and a 40-hour work week. fBU Flammable At temperatures under tOO*F. chemical gives OH enough vapor to ignite H a source of ignition is present as tested with a closed cup tester HAZARDOUS INGREDIENTS Chemical substances deter mined to ot potential haetth or pnyeteer naaaros by me criteria established n the 0$ha hazard Communication Standard 29 CFR I90.1200 MTX' Highly lo*'C * th# probable lethal dose for 70 kg ft SO tb.) man and may be approximated aa 'ess than 9 teaspoons (2 tablespoons). /RR irritant - Causes reversible effects in living tissues (e.g. inflammation) primarily tkm and ayes. M/A Not Applicable > Category is not appropriate for this product. NjD: Not Determined insufficient information for a deter* mmanon tor this Hem. RTECS*: Registry of Toxie Effects of Chemical Substances an unreviewed listing of published toxicology data on chemical substances SARA, Superfund Amendments end Reaulhonxaiion Act Section 313 designate* chemicals for possible reporting lor the Toxics Release inventory SEN Sensitizer Causes allergic reaction alter repeated exposure TOX Toxic Th# probable lelhel dose for e 70 kg (ISO lb.) men is one ounce (2 tablespoons) or more. SECTION III: HEALTH HAZARD DATA ACUTE EFFECT. An adverse elite! on the humen body from e smgie exposure wih symptoms developing elmosf immedieteiy slier exposure or within a relatively short time. CHRONIC EFFECT Adverse effects that ere most likely to occur from repeated exposure over a tong period of time. C$rD PEUTIV: This estimated, time-weighted average, ex posure limit, developed by using a formula provided by the ACGIH pertains to airborne concentrations from the prod uct as a whole. This value should serve as guide tor provid ing sate workplace conditions to nearly an workers. hmi$ CODES. Hazardous Material identification System a rating syttem developed by me National Ramt #no Coating Association tor estimating me hazard potential of a chemi cal under normal workpiece conditions. These risk estimates era indicated by a numerical rating given m each or three hazard areas |HeaUh/FiemmOihty/Reactivi|y) ranging from a tow of zero to a high of 4 a chrome hazard is indicted with a yes. Consult hm/$ framing guides for Person*) Pro- lection latter codes which indicate necessary protective equipment. PRIMARY ROUTE OP ENTRY Th* way on# or more haz ardous mgredtami may enter th* body and cause a general* iZed-tysiemie or specific-organ toxic effect. ING. Ingestion A primary route of exposure through swallowing of material. iNH inhalation A primary route of exposure through breathing ol vapors $FIN. A primary route ot exposure through contact with th# Skin. SECTION IV: SPECIAL PROTECTION INFORMATION Where respiratory protection it recommended, use only msha and NiOSH approved respirators and dust masks. MSHA' Mine Safety end Health Administration NiOSH. National institute for Occupational Safety and Health. SECTION V: PHYSICAL DATA EVAPORATION RATE, it telers to (ha rate ot change Irom the liquid steie to me vapor state ai ambient temperature and pressure in comparison ro a given substance * g water) pH: A value representing ihe acidity or alkalinity of an aqueous solution (Acidic pH i; Neutral pH 7; Alkaline pH 14) PERCENT VOLATILE: The percentage of the product (liquio or sood) that wui evaporate at 2i2*F and ambient pressure SOLUBfUrr IN WATER: a description or tne ability ol me product to dissolve in water. SECTION VIJ: REACTIVITY DATA HAZARDOUS OECQMPOSfTIOtV Breakdown products expect ed to be produced upon product decomposition or fire. tNCOMPAT1BIUTYMaterial contact and conditions to avoid to prevent hazardous raactions. POLYMERIZATION: indicates the tendency of th# product's molecules to combine in a cnemical reaction releasing ex cess pressure and heat. STABiUTY: indicates the susceptibility of tne product to spontaneously and d*ngarous>y decompose. SECTION VIII: SPILL AND DISPOSAL PROCEDURES RCRA WASTE NOS. RCRA (Resource Conservation and Re covery Act) watt# codes <40 CFR 29) applicable to the disposal of spilled or unusaDie product irom the original container. SECTION X* TRANSPORTATION DATA CWA' Clean Water Aol AO. Reportable Quantify The amount of the specific ingre dient rhaf. when soilted <0 the ground and c*n amer o storm sewer or natural watershed, must be reported to the National Response Canter, and other regulatory agendas. TSCA* Toxic Subsrancas Contra Act - a federal taw requir ing ail commercial enemteai substances to appear on an inventory maintained by me ERA. OISCHIMER All tidlcnritnii. I*ctinlcl mlormtlion *nd <*comi*ndationi coni*nMi htfem at* besed on available .cienM.c (e.ia or data which we believe to be reliable The accuracy and ccmolelaneff ol such data are nol warranted or guaienteed vve cannot anticipate all condition, undo which ihi. tntorroaiton and bur product., or tha product, ol other manufacturer, in combination with our products may be utad. Zap e.iume. no liability or re.pon.ibllny lor iom or damope reeultmg from tha improoer uH or handling ot our product., Irom incompatible product combination., or Irom Iha failure lo loflow in.truciloK, warning., and tdviiOrie. in the product', lapel and Material Saltty Data Sheet ce Ravistd 941 t DO A 061716 CONFTDFNTTAL