Document bBJyr0D0JBV4kjGJZkqk4JJrO

MATERIAL SAFETY DATA SHEET pQMGCO A DIVISION OF PENNZOIL FNOOUCTS COMPANY '/CL J:PRODUCT IDENTIFICATION Manufacturer's Name PENRECO Address 4401 PARK AVENUE DICKINSON, TEXAS 77639 Emergency Telephone No. Trade Name Synonyms (713) 236-6070 DRAKEOL 21 MINERAL OIL USP WHITE MINERAL OIL II3 INGREDIENTS COMPONENT NAME CAS NUMBER WHITE MINERAL OIL 8042-67-5 HAZARDOUS IN BLEND PERCENTAGE MIN MAX NO , UV JJL'lFu ,,LULW WJCL-lAfUIKfV-U-- "UV - 100.00 CAS Number: 8042-47-5 MSDS Code: 001145 NFPA Hazard Identification Degree of Hazard Hazard Ratings Health: 0 Fire: l Reactivity: o 0 - Least 1 - Slight 2 - Moderate 3 - High 4 - Extreme COMPONENT EXPOSURE LIMITS OSHA PEL ACGIH TLV UNITS NO LIMIT N^O .L..I..M...IWTrjw.jfWJfej JifWJULUJUUUL.J JUUVULIJU-ML "k1 ""' Ia t" 'TrfiAw *{ wS, ..uViniiR yyaj ,3>r" """t"". ` ,,l jf. JWnKnXr:73L_iRj.?''Tyh. ` ,vwwUJjCL,,VJujCCjl.JL^-'l :L. LL"`31'3,i 3" iiJvL-r-r3LVLJWTLV, JVUL..UEK.L^JVdt^rAXnkji^LCiiwskibdfi&UUUI>WU<KBr&IIUWuC^^L`L`L,!'`C3------*-r3-r ` 3' ,, ... ^ vu.. , , ,,,, ,,,, 3..wwuUmJL-^L_.LJ~L..uLL,-JL,`L-1'V- -1.--V3 `v33v.WW~ JlHKljuUl.lOUULUIIllL`HL`ilL,LLi^!P_L>iVl-,^,w -- ``3" ""`v '--` `I-- -;-- -----fj "w.'I'.rr'.Ny Kyr* "lit-; "---f"j . mm J'.mm J,,_t, JtKJUJLJL*._^L JJy J- I: jw\,LlrjaIiw'birwdvuuuuiffcjJiruwii}5o.iuL'iiJotkj33uim.i-jifbL3*JUL2;kVL-iV,,^ uiS6IHHSHiuii6tLi`ii^'S!ys*J-,*uirf ,''AMrj:NH5TTmi5"Kf uw8iiLk$Svt>LJ!rji.{k - -_ ,, _________JLJL.V-.' LL*.`3 -tfJvLSvr "L-i! --3v*V.Lv-j":i^ JiL^W^3L^-;%iiinrlllt^::3 !3wWJU(kklUJW3333JUUCKAhKiLLUIIbLJL'U'JL'UU i-HiuiJuinjuuiHnn'njnnimjuL'iffiimniiiu'- --" ................Mil' 3,333-3. vj-jl...!jliujuuLJUjCy.5iuij|; `X. ^ ifi?> -y^>r.f .'.MU' i S33di.''3injiwi3jt!ifcRn7i3u3.rJ?3.r32uu.ijuujjL..jw..,....j.jjt:..jjuiK.JLL., ill',- 'S'niiiuuiK-^r^-KV^fn'PjnNniyiiiHKnwniuu'n--1> lhuj3!1;`{H;3vvSLL3uvu3iijjuuud,i.^ihkibiHiCv{>uwtKiuink;ujjiHii;uufijjLU.tf{Hd!fiiiituiitiL3LL1< v.- 3~v3 tBYr ENVIRONMENTAL, SAFETY A HEALTH r ". <713) 546-6227 :r, , ljOyrirtRK,.n>df --rfrf111f..n. .iMhni'tMH V w- / ^fCttm DATi APRIL 14, 1992 1~ yj ;-:;:,E:i!H:.::::":'-:iS^j:;.H;^j-:::.:^':;:.^::^:^'. DISCLAIMER OF WARRANTY: THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO US, AND REFLECTS OUR BEST PROFESSIONAL JUDGEMENT. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF SUCH DATA, THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, OR THAT ANY SUCH USE DOES NOT INFRINGE ANY PATENT. SINCE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS OF USE BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR. WE DO NOT ASSUME ANY RESPONSIBILITY FOR THE RESULTS OF SUCH APPLICATION. THIS INFORMATION IS FURNISHED UPON THE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR PURPOSE. REQUIRED UNDER USDL SAFETY AND HEALTH REGULATIONS FOR SHIP REPAIRING, SHIPBUILDING, AND SHIPBREAKING (29 CFR ISIS, t916, 1917). DO 085513 CONFTDFNTTAl I1 MSDS CODE: 001145 PRODUCT: DRAKEOL 21 MINERAL OIL USP PAGE 2 OF 6 EYE CONTACT THIS PRODUCT IS MINIMALLY IRRITATING TO THE IVES UPON DIRECT CONTACT. BASED ON TESTING OP SIMILAR PRODUCTS AND/OR COMPONENTS. SKIN CONTACT THIS PRODUCT IS NOT EXPECTED TO CAUSE ANY SKIN IRRITATION UPON DIRECT SINGLE OR REPEATED AND PROLONGED CONTACT; HOWEVER, SIMILAR CHEMICAL COMPOSITION PRODUCTS APPLIED TO THE SKIN OF LABORATORY ANIMALS RESULTED IN MINIMAL TO SLIGHT DERMAL IRRITATION. INHALATION THIS PRODUCT HAS A LOW VAPOR PRESSURE AND IS NOT EXPECTED TO PRESENT AN INHALATION HAZARD AT AMBIENT CONDITIONS. CAUTION SHOULD BE TAKEN TO PREVENT AEROSOLIZATION OR MISTING OF THIS PRODUCT. THE PERMISSABLE EXPOSURE LIMIT (PEL) AND THRESHOLD LIMIT VALUE (TLV) FOR THIS PRODUCT AS OIL MIST IS 5 MG/M3. EXPOSURES BELOW 5 MG/M3 APPEAR TO BE WITHOUT SIGNIFICANT HEALTH RISK. THE SHORT-TERM EXPOSURE LIMIT FOR THIS PRODUCT AS AN OIL MIST IS 10 MG/M3. SEE HEALTH DATA SECTION BELOW. INGESTION INGESTION IS RELATIVELY NON-TOXIC UNLESS ASPIRATION OCCURS. THIS PRODUCT HAS LAXATIVE PROPERTIES AND MAY RESULT IN ABDOMINAL CRAMPS AND DIARRHEA. SEE HEALTH DATA SECTION BELOW. HEALTH DATA EXPOSURE TO A LARGE SINGLE DOSE, OR REPEATED SMALL DOSES OF MINERAL OIL BY INHALATION, ASPIRATION OR INGESTION LEADING TO ASPIRATION CAN LEAD TO LIPID PNEUMONIA OR LIPID GRANULOMA. THESE ARE LOW-GRADE, CHRONIC, LOCALIZED TISSUE REACTIONS WHICH ARE NOT FATAL. SHORTNESS OF BREATH AND COUGH ARE THE MOST COMMON SYMPTOMS. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC> HAS CONCLUDED THAT HIGHLY REFINED MINERAL OILS ARE GROUP 3 SUBSTANCES, "NOT CLASSIFIABLE AS TO THEIR CARCINOGENICITY TO HUMANS,' BASED ON INADEQUATE HUMAN AND INADEQUATE ANIMAL EVIDENCE. IARC HAS ALSO CONCLUDED THAT THERE IS NO EVIDENCE FOR THE CARCINOGENICITY TO EXPERIMENTAL ANIMALS OF WHITE OILS WHEN ADMINISTERED BY ROUTES OTHER THAN BY INTRAPERITONEAL INJECTION. THIS SUBSTANCE IS NOT CARCINOGENIC ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD. qq 085514 CONFIDENTIAL I MSDS CODE: oon5 PRODUCT: DRAKEOL 21 KXWRAL OIL U5P PAGE 3 OF 6 MSDS CODE: ooiias PRODUCT: DRAKEOL tl KXfERAL OIL USP PAGE 4 OF 6 I I1 MSDS CODE: 001145 PRODUCT: DRAKEOL 21 K1NERAL OIL USP PAGE 5 OF 6 I I* MSDS CODE: 001145 PRODUCT: DRAKEOL 21 KHCRAL OIL U5P PAGE 6 OF 6 STEPS TO BE TAKEN IF .M.VATi.ETMRIA..L IS bci cAccn no KtLfcM&tU UK SPILLED consult health effect information in section hi, personal health protection information IN SECTION V, FIRE PROTECTION INFORMATION IN SECTION VI, AND REACTIVITY DATA IN SECTION VII. NOTIFY APPROPRIATE AUTHORITIES OF SPILL. CONTAIN SPILL IMMEDIATELY. DO NOT ALLOW spill to enter sewers or watercourses . remove all sources of iqnition . absorb with appropriate inert material such as sand, clay, etc., laroe spills may be picked up using VACUUM PUMPS, SHOVELS, BUCKETS, OR OTHER MEANS AND PLACED IN DRUMS OR OTHER SUITABLE CONTAINERS. WASTE DISPOSAL METHOD all disposals must comply with federal, state, and local peculations, the material, if spilled or discarded, may be a regulated waste, refer to state and local regulations. CAUTION! IF REGULATED SOLVENTS ARE USED TO CLEAN UP SPILLED MATERIAL, THE RESULTING WASTE MIXTURE MAY BE REGULATED. DEPARTMENT OF TRANSPORTATION (DOT) REGULATIONS MAY APPLY FOR TRANSPORTING THIS MATERIAL WHEN SPILLED. WASTE MATERIAL MAY BE LANDFILLEO OR INCINERATED AT AN APPROVED FACILITY. MATERIALS SHOULD BE RECYCLED IF POSSIBLE. IX MISCELLANEOUS HANDLING AND CTnDArC OIUKMLit REQUIREMENTS do not transfer to unmarked containers, store in closed containers away from heat, sparks, OPEN FLAME, OR OXIDIZING MATERIALS. THIS PRODUCT IS NOT CLASSIFIED AS HAZARDOUS UNDER DOT REGULATIONS. FIRE EXTINGUISHERS SHOULD BE KEPT READILY AVAILABLE. SEE NFPA 30 AND OSHA 1910.106--flammable and combustible liquids. ADDITIONAL INFORMATION THIS product is not known to contain any sara title hi, section sis reportable chemicals at 0,1 greater than i.ox (o.ix for carcinogens). THIS product is on the toxic substances CONTROL ACT <TSCA) inventory. BOILING POINT MELTING POINT APPEARANCE ODOR VAPOR PRESSURE SOLUBILITY goof n/a transparent water-white liquid ODORLESS. * imm hg * 7of SOLUBLE IN HYDROCARBONS. PERCENT VOLATILE nil VAPOR DENSITY (AIR-1) no data EVAPORATION RATE (EE-1) i SPECIFIC GRAVITY o/60F MOLECULAR WEIGHT varies DO 085518 CONFTDFNTT Al MATERIAL SAFETY DATA SHEET DOW CHEMICAL U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 25123 PO'"DUCT NAME: VECTOR <E) 421 1-D STYRENIC BLOCK COPOLYMER PAGE: 1 EFFECTIVE DATE: 08/16/90 DATE PRINTED: 05/07/92 MSD : 002756 1* INGREDIENTS': <% W/W, UNLESS OTHERWISE NOTED) STYRENE-ISOPRENE BLOCK COPOLYMER ADDITIVES CASt 025038-32-8 >98% (1% THIS DOCUMENT IS PREPARED PURSUANT TO THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). IN ADDITION, OTHER SUBSTANCES NOT 'HAZARDOUS' PER THIS GSHA STANDARD MAY BE LISTED. WHERE PROPRIETARY INGREDIENT SHOWS, THE IDENTITY MAY BE MADE AVAILABLE AS PROVIDED IN THIS STANDARD. 2. PHYSICAL DATA C .31!... I r.' G i J N T if u i , * r ! ' i...C A B I... E. V A r . i"' R i::. S S ' N E G L 1 G I B I... L . DENSITY NOT APPLICABLE SOL.. IN WATER: NEC I ICICLE SP. GRAVITY: 0.92 APPEARANCE : NATURAL 20L0R PELL.ET ODOR: NONE 3 FIRE AND LIT LO/jO;, HAZARL DATA: FLASH POINTMETHOD USED NOT APPLICABLE NOT APPLICABLE CLAMMABLE LIMITS LNOT A PPL ICADL E UFA...: MOT APPLICABLE ENTINGUISHJ.NG MEDIA: WATER FOG, FOAM, 002, AND DRY CHEMICAL. RIRE AND EXPi OSI ON HAZARDS AVOID INHALATION OP SMOKE. FIRE -ptcHIINC EQUIPMENT; BREATHING APPARATUS. WEAR POSITIVE PRESSURE, SELF-CONTAINED .. REACTIVITY DATA: STABJ.LI 'Y (CONDITIONS TO AVOID) DO NOT STORE ABOVE 200 F. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) STRONG OXIDIZING \CONTINUED ON PAGE 2) NO INDICATES A TRADEMARK OF THE DOW CHEMICAL. COMPANY OPERATING UNIT OF THE DOW CHEMICAL COMPANY DO 085519 OONFTDENTTAl .DOW CHEMICAL U.S.A.* MIDLAND , M.I 48674 EMERGENCY PHONE: 517-636-440G PRODUCT CODE: 25123 PP"'HJCT NAME: VECTOR <R; 4211-D STYRENIC BLOCK COPOLYMER PAGE: 2 EFFECTIVE DATE; Ob/16/90 DATE PRINTED: 05/07/92 MSD: 002756 4* REACTIVITY DATA: <CONTINUED) AGENTS. HAZARDOUS1 DECOMPOSITION PRODUCTS: CARBON MONOXIDE AND ORGANIC C 0 M P 0 U N D S Li P 0 N C 0 M B U S T10 N . H A Z i-i R D 0 U S P 0 L Y M E RIZ A T ION: W11,,. N 0 T 0 C C U R . S. ENVIRONMENTAL AND DISPOSAL INFORMATION' A C T10 N T 0 T A K E F 0 R ' S PIL i.. S : S W E E P U F:' 0 R p.[ C K U P WIT H A N IN D U S T RIA L. uISPCSV.L METHOD. RECLAIM, JJPf IN A CHEMICAL INCINERATOR, OR BURY IN AN APPROVED LANDFILL I i1 ! A C C 0 R D A N 0 E WIT H F7 E D E R A L , STATE, AND LOCAL REGULATIONS. 6. HEALTH HAZARD DATA EYE: SOLID OR DUST MAY CAUSE MECHANICAl. ACT TON. ITaTION OR CORNEAL, INJURY DUE TO SKIN CONTACT: ESSENTIALLY N0N1EEI7aTING TO SKIN INJURY ONLY MECHANICAL (iBSOPF :dn PPURER" .' i. IN A B S G E P i .1.0 i TO PHYSICAL i i -i E ^ i .1. C f-: . j. N G i- f- D U S l. ORAL. LD5f HAS NOT BEEN DETERMINED. SINGLE DOSE ORAL T0XICT.T Y VS BELIEVED TO BE VERY LOW,. NO HAZARDS ANTICIPATED FROM SWAlJ .OWING SMALL AMOUNTS INCIDENTAL TO NORMAL H A N D i....!. N G 0 p E R A T10 N. INHALATION. DU MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. SYSTEMIC AND OTHER EFFECTS: ADDITIVES ARE ENCAPSULATED IN THE PRODUCT AND ARE NOT EXPECTED TO BE RELEASED UNDER NORMAL PR0CESSING CONDITIONS* C 0 N TIN U E D 0 N P a G E 3 ) E > INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY , OPERATING UNI 0F: THE DOW CHEMICAL COMPANY DO 085520 CONFIDENTIAL DOW CHEMICAL U.S. A.* MIDLAND , MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE- 25123 PP"UCT NAME : VECTOR <R> 421 1 ~D STY REN I. C BLOCK COPOLYMER PAGE: 3 EFFECTIVE DATE- 03/16/9G DATE PRINTED: 05/07/92 MSD; 002756 7, FIRST AID: EYES: IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES. M E C I-1A NIC A L E F F E C T S 0 N i_ Y . SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER INDUSTRIAL HANDLING. INHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. CONSULT A RHYSPCI AN. G HANDLING PRECAUTIONS CT'C SURE GUIDELINE (S- NONE ESTABLISHED FOR COPOL'7 MER . VENTILAl I Oil - GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS. RESPIRATORY PROTECTION: FOR MOST CONDITIONS, NO RESPIRATORY PROTECTI ON SHOULD BE NEEDED; HOWEVER, IF HANDLING AT ELEVATED temperature;:' without sufficien" ventilation, use an approved AI P" r UR IFY .[ NC FT SPIFF TOR. IN DUS'"Y AThOSPHERES , USE AN APPROVED DUS f RESPIRA COR. ' i.!! P L1., I ION : Nil F'kELAu * 1 UNi.-, 0 i HER' i HaN CLEAN BODY--COVERING CLOTH INC SHOULD BE. NEEDED. EYE PROTECTION: USE SAFETY GLASSES. IF THERE IS A POTENTIAL FOR EXPOSURE TO PARTICLES WHICH COULD CAUSE MECHANICAL INJURY TO The EYE, WEAR CHEMICAL GOGGLES. ''. ADD 111 ON Ai.. INF ORMA i" I ON : SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRODUCT CAN ACCUMULATE ELECTROSTATIC CHARGES WHEN RUBBED, CHAFED OR ABRADED. STATIC DISCHARGE IN THE PRESENCE OF VOLATILE OR FLAMMABLE MIXTURES PRESENTS A POTENTIAL FIRE OR EXPLOSION HAZARD. EQUIPMENT SHOULD PROVIDE A MEANS FOR DISSIPATING ANY CHARGES THAT MAY DEVELOP. CONTINUED OH PAGE 4) (R.) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY . ,h OP FRA':' I; 'G UNIT OF 7 ME LOW CHEMICAL COMPANY DO 085521 CONFTDFNTTAl DOW CHEMICAL U * S * A * * ,MIDLAND ill 48674 EMERGENCY PHONE 517-636-4400 PRODUCT CODE. . 3', 23 PP " UC7 NAME : VECT0R ( R ) 421 i --D 2 T V RENIC BLOCK COPOLYMER PAGE: 4 EFFECTIVE DATE: 08/16/90 DATE PRINTED: 05/07/92 MSD; 002756 ADDITIONAL INFORMATION: (CONTINUED) COMPOUNDING OF PRODUCT IN HIGH CHEAP EQUIPMENT CAN CAUSE THE TEMPERATURE TO RISE* DO NOT ALLOW THE TEMPERATURE TO EXCEED 450F* MAINTAIN A FIRE WATCH IF 45OF IS REACHED* MSI); REVISED SECTION S P E CIA L. P R E C A U T10 N S ) * 'OR INFORMATION REGARDING STATE/PROVINCIAL AND FEDERAL REGULATIONS SEE THE REGULATORY INFORMATION SECTION* R> INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY OPERATING UNIT OF THE DOW CHEMICAL COMPANY 00 O855,, CON^TOBNTTAi DOW CHEHICAl. U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 25123 =T UCT NAME: VECTOR ',R> 421 1-D STYRENIC BLOCK COPOLYMER PAGE: R~i EFFECTIVE DATE: 08/16/90 DATE PRINTED. 05/07/92 MSD: 002756 PECULATORY INFORMATION: (NOT MEANT TO BE ALLTMINCLUSIVE--- SELECTED REGULATIONS REPRESENTED. ) NOTICE- THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE LOCATION TO ANOTHER; IT IS the BUYER'S RESPONSIBILITY "0 ENSURE THAT ITS ACTIVITIES COMPLY WITH FEDERAL, STATE OR PROVINCIAL, AND LOCAL.. i-AWS . THE FOLLOWING SPECIFIC INFORMATION IS MADE FOR THE PURPOSE OF COMPLYING WITH NUMEROUS FEDERAL, STATE OP PROVINCIAL, 'ML LOCAL ,..;T i-'!,' N" l"FG UL AT IONS. LEE MFC SHEET FOR HEAL ! H mND SAFETY INFORMATION.. J ... K L-:. G U L A1 I 0 N S TARA HAZARD CATEGORY- THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES'' PROMULGATED UNDER SECTIONS 211 AND 312 OF THE SUPERFuND Ah END MR N i mNii KEAU HUH J. ..A i I ON ML i Ul i / ci6 (ShRA f 1 i LE III) AND I. ONSIDERED, UNDER APPLICABLE DEFJNITT0NS, TO MEET THE FOLLOWING LA,EGDRIES. 0 T T J I-'I VII ,1E T A T-1 J H A Z A R D L A T E G Cl P' i' 1R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY 'ME INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. CONSULT THE DOW CHEMICAL. COMPANY LOR FURTHER INFORMATION. Gi: EPAYINC UL I' 7 OF THE DOW CHEMICAL COM FAN r DO 085573 CONFIDENTIAL in A r R I A L. SAFETY DATA HEET DOW CHEMICAL U,S,A,- MIDLAND, MI 43674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 26961 FF JCT NAME. VECTOR (R) 6240-D STYRENIC BLOCK COPOLYMER PAGE: 1 EFFECTIVE DATE: 03/02/92 DATE PRINTED: 05/07/92 MSD: 003544 INGREDIENTS (% W/W, UNLESS OTHERWISE NOTED) STYRENE-BUTADIENE BLOCK COPOLYMER ADDitive: CASS 009OG3-55-8 >98% <1% "`HIE DOCUMENT IE PREPARED PURSUANT TO THE OS HA HAZARD COMMUNICATION STANDARD (29 CFR 1910,1200)* IN ADDITION, OTHER SUBSTANCES NOT 'HAZARDOUS' PER THIS OSHA STANDARD MAY BE LISTED, HYSICAL DATA r i.j 1 L IN G :"U ,[`U ."V, PRESS' NEC.!. GIRLE. ' i -w ', 1) 1:: i'- S j. i i . i > 0 I i-i ! ' I... IC A B L. i.:. soi... i:i' water negligible SP , GRAV.i.Ti 1 A. 92 APPEARANCE. NATURAL COLOR PEL LET OR CRUMBS ODOR: NOME '/ EIRE AND E>PLOSION HAZARD DATA: FLASH Pi 11 NT. METHOD USED NO I U-'U.. I CABLE NOT HP PL !' CABLE r ; ^,v,fi p; E : h - PEL: NOT MR.,'L I.CABLE NOT APPLICABLE EXTINGUISHING MEDIA: UhTER FOG, FOAM, 002, AND DRY CHEMICAL, E I ! ' F A N D E X i:' i... 0 5' IQ1> H A Z A R D S : AVOID I N H A1. A TIG N 0 F SMOKE, i PF L.:x.,!E XL., EOUIPMEilT BRE ATI-I ING APPARATUS , WEAR POSITIVE PRESSURE, SELF-CONTAINED REACTIVITY DATA- STABILITY: (CONDITIONS TO AVOID) DO NOT STORE ABOVE 200 F, INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) STRONG OXIDIZING (CONTINUED ON PAGE 2) P) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY GPERhT I LG; UNIT OF THE DOW CHEMICAL COMPANY DOW CHEMICAL U.E.A.* MIDLAND, MI 48674 EMERGENCY PHONE : 517-636-440 PRODUCT CODE. 26961 RP ' " UCT NAME VECTOR vR) 6240-i) STYRENIC BLOCK COR01..YMER PAGE: R-1 EFFECTIVE DATE: 03/02 /92 DATE PRINTED: 05/07/92 MSD: 003544 REGULATOR i' INFORMATION: (NOT MEANT TO BE ALL-INCLUSIVE -- SELECTED REGULATIONS REPRESENTED*) NOTICE: THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH AND BELIEVED TO EE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE LOCATION TO ANOTHER; I"' IS THE BUYER'S RESPONSIBILITY TO ENSURE THAT ITS ACTIVITIES COMPLY WITH FEDERAL, STATE OR PROVINCIAL, AND LOCAL LAWS. THE FOLLOWING SPECIFIC INFORMATION IS MADE FOR THE PURPOSE OF -COMPLYING WITH NUMEROUS FEDERAL, STATE OR PROVINCIAL, '.IND !. OCAL LAWS ANA REG CL, Of IONS.. SEE ,-S ') .'"'HE ET -OP HEALTH AND ."ACL", T InF ORMA i ION regulations SARA HAZARD CATEGORY- TILLS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE ERA "HAZARD CATEGORIES" PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPER FUAD AMENDMENT AND REACT: ICR IZ AT I ON :-L : OF i?8o > SARA TITLE III) AND ON side: ELL, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CAiEGORIES POT TO HAVE MET ANY HAZARD CATEGORY ;R) INDICATES a TRADEMARK OF THE DOW CHEMICAL. COMPANY 'Til: INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, IMPRESS OR IMPLIED, IS MADE. CONSULT THE DOW CHEMICAL COMPANY FOR -CRT'HEP: INFORMATION. - OR ERA TING UNIT OP HE LOW CHEMICAL COMPANY 0 0855?5 CONFrOENTTAP DOW CHEMICAL U*S.A** MIDLAND MI -48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE : 26961 PR UC" NAME : VECTOR (R) 6240-D STYRENIC BLOCK COPOLYMER PAGE EFFECTIVE DATE : 03/02/92 DATE PRINTED: 05/07/92 MSD 0G3544 REACTIVITY DATA' (CONTINUED) AGENTS, HAZARDOUS DECOMPOSITION PRODUCTS: COMPOUNDS UPON COMBUSTION* CARBON MONOXIDE AND ORGANIC HAZARDOUS POLYMERIZATION: WILL NOT OCCUR * ENVIRONMENTAL.. AND DISPOSAL INFORMATION ACTION TO tale FOP SPILLS. SWEEP UP OP PICK UP WITH AN INDUSTRIAL Pi.... o Jh LLEAWi::.K * i"'J! ,! i i i 0 Lui\ i A i i-iLK L uR D11 RUSAL , 11SP0SAI... !",E7'HOD :: ECL 71 vi, BURN IS A CHEMICA!... INCINEkATOP, 0R PURi IN AN APPROVED LANDFILL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL PEC ULA7 I ONE, A* HEALTH HAZARD DATA: EYE. SOLID OR DUST nAv CAUSE TERRA! ION OR CORNEAL INJURY DUE TO MECHANICAL ACTION, SKIN COSTA..A . ESSENTIALLY NONIRRITATING TO SKIN* INJUP i ONI... 7* MECHANICAL S < IA /UkI' r I ON PRGPEPT: `I,:* Si. ,i. rj & S0RI-'T I 0?i IS UNl. I K rv i)ijE ' 0 PH YS I. C.il. I SLEET.r ON SINGLE DOSE ORAL l.L-30 HAS NOT BEEN DETERMINED* SINGLE DOSE ORAL TOXICITY IS BELIEVED TO BE VERY LOU * CONSIDERED TO BE PHYSIOLOGICALLY INERT* NO HAZARDS ANTICIPATED FROM SWALLOWING SMALL AMOUNTS INCIDENTAL TO NORMAL HANDLING OPERATIONS* INHALATION DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT* SYSTEMIC AND OTHER EFFECTS. ADDITIVES ARE ENCAPSULATED IN THE PRODUCT AND ARE NOT EXPECTED TO BE RELEASED UNDER NORMAL PROCESSING CONDITIONS* i CONTINUED ON PAGE 3) R> INDICATES A TRADEMARK CF THE DOW CHEMICAL COMPANY , -JPhRATIRG UNIT OF THE DOW CHEMICAL COMPANY DO 085526, CONFTOFNTTAl DOW CHEMICAL. U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636 -- 400 PRODUCT CODE- 26961 PP'MJCT' NAME: VECTOR <R> 6240--D STYRENIC BLOCK COPOLYMER PAGE: 3 EFFECTIVE DATE: 03/02/92 DATE PRINTED: 05/07/92 nsh 003544 7. FIRST AID: EYES: IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES. MECHANICAL IFF EC TO ON:... f .. SKIN- WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL. ,'C ?l"'nPFR INDUSTRIAL HANDLING. INHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. PHYSICIAN. CONSULT A r. uanDl.:u:g r RELAU'n: jN' L X P S U K E G IJ i DL. .1. i' ; E. S i : N 0 NI:. '... S '< A D!.. IJ H L D r t.; k L 0 r L L t M E:. i \. VENTILATION: GOOD GENEKAl. VENTILATION SHOULD BE SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS , RESPIRATORY PROTECTION FOR MOST CONDITIONS, NO RESPIRATORY PROTECTION SHOOl.D BE NEEDED; HOWEVER, IF HANDLING AT ELEVATED TEMPERATURES WITHOUT SUFFICIENT ./ENTILATION, USE AN APPROVED A1R-?UR IFTING RFSP: F' A70. I N DUSTY ATf0SPHEF- ES , USE AN AM" ROVED DUST REGPIRmTGk. SKIN f RGVECTI ON : NO CCiiU'"' I DNS 0 HER THAN CLEAN BODY-COVERING ci...Gth::ng smouli be needed. ETE PROTECTION: USE SAFETY GLASSES. IF THERE IS A POTENTIAL FOR EXPOSURE TO ^ARTICLES WHICH COULD CAUSE MECHANICAL INJURY TO THL ETE, WEAR NREMI CAL GOGGLES. '. A D D171 ,J N A 1_ IN F 0 R M A 710 N . SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRODUCT CAN ACCUMULATE ELECTROSTATIC CHARGES WHEN RUBBED, CHAFED GR ABRADED. STATIC DISCAHARGE IN THE PRESENCE OF VOLATILE OR FLAMMABLE MIXTURES PRESENTS A POTENTIAL FIRE OR EXPLOSION HAZARD. ECUIPMENT SHOULD PROVIDE A MEANS FOR DISSIPATING ANY CHARGES THAT MAY DEVELOP. CONTINUED ON PAGE 4) (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL. COMPANY UPEPATINC UNIT OF THE DOW CHEMICAL COMPANY DO 085527 CONFIDENTIAL DOW CHEMICAL IJ * S' * A . * MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE- 26961 PR "UCf NAME. VECTOR <R> 6240-D STYRENIC BLOCK COPOLYMER PAGE: 4 EFFECTIVE DATE- 03/02/92 DATE PRINTED- 05/67/92 MSD: 003544 T , A D DIT10 N A L. 3: N F 0 R M A T10 N : (C 0 N TIN U E D) COMPOUNDING OF PRODUCT IN HIGH SHEAR EQUIPMENT CAN CAUSE THE TEMPERATURE TO RISE* DO NOT ALLOW THE TEMPERATURE TO EXCEED 4501- * MAINTAIN A FIRE WATCH IF 4EOF IS REACHED. MSDS STATUS REVISED SECTION (APPEARANCE) i;: 0 R INFORMATION REGARDING STATE/PROVINCIAL AND FEDERAL REGULATIONS SEE THE REGLJLAT0R T INF0RMAT10N SECTION. ( R > INDICATES A TRADEMARK OR THE DOW CHEMICAL COMPANY < OR ERA']'INC UnIT OF THE DOW CHEMICAL. COMPANY DO 085578 CONFIDENTIAL SOW CHEMICAL U.S.A.# MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 "RODLCT CODE: 25383 rP OCT NAME: VECTOR (R > 8550-D .STY REN IC ELOCK COPOLYMER PAGE R--1 DEFECTIVE DATE: 03/02/92 DATE PRINTED 0 5 / 0 7 / 9 2 M S D: 0 03544 ".ECUi... ATOPY INFORMATION '..NOT MEANT TO EE ALL-INCLUSIVE..... SELECTED EDUCATIONS' REPRESENTED, > 'OTICE: THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE, HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN, REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE ... JCATION TO another j IT IS THE BUYER'S RESPONSIBILITY TO ENSURE "MAT ITS ACTIVITIES COMPLY WITH FEDERAL. STATE OR PROVINCIAL, -ND LOCAL LAWS, "HE FOLLOWING SPECIFIC INFORMATION IS MADE FOR THE PURPOSE OF COMPLYING WITH t iJMEROUS FEDERAL, STATE OR PROVINCIAL, <'.> cTM.!. Lows Ai'r' ij,..Av t " iff sheet "or . ea and " 1:. ) i' J. uk/hi i Ij(j ,, .. a i.> * Kl. \.v\J 1--!"i i X wJ i '< i.S .:::::::::::: r. TAKA HAZARD CATEGORY : THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE PA "HAZARD CATEGORIES" PROMULGATED UNDER SECTIONS 31i AND 312 OF THE UR FREUND AMENDMENT AND RE AUTHOR 1ZATI On Hd OF 1986 v. SARA TITLE III) AND onsidered, under applicable definitions, "o meet the following ::a I EGORIES . 13T TO H -VE MET ANY HAZARD CATEG0R: R) INDICATES A TRADEMARK OF THE DOW CHEMICAL. COMPANY "HE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, /PRESS OR IMPLIED, IS MADE. CONSULT THE DOW CHEMICAL COMPANY OR FURTHER INFORMATION. >' OPERATING UNIT OR THE DOW CHEMICAL COMPANY DO 085529 CONFTDFNTIAl MATERIAL safety data sheet DOW CHEMICAL U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE. 25383 'T LiCT NAME. VECTOR <R) 8550-D STYRENIC BLOCK COPOLYMER PAGE: 1 EFFECTIVE DATE: 03/02/72 DATE PRINTED: 05/07/92 MSD: 003544 !. INGREDIENTS- (% W/U, UNLESS OTHERWISE NOTED) STYRENE-BUTADIENE BLOCK COPOLYMER ADDITIVES GAS* 009003-55-8 >98% <1 % THIS DOCUMENT IS PREPARED PURSUANT TO THE OSHA HAZARD COMMUNICATION STANDARD <29 CER 1910.1200). IN ADDITION, OTHER SUBSTANCES NOT 'HAZARDOUS' PER THIS OSHA STANDARD MAY BE LISTED. WHERE r ROfRIET ARY INGREDIENT SHOWS, THE IDENTITY MAY BE MADE AVAILABL.il AS PROVIDED IN THIS STANDARD. 2. PHYSICAL DAiA: ' ' UI i... 1N G P 01N T N 0 T A P P L ; C A B L E VAP. fRESS NEGLIGIBLE VAF'. DENSITY NOT APPLICABLE SOL. IN WATER: NEGLIGIBLE SP. GRAVITY 0.92 APPEARANCE: NATURAL COLOR PELLET OR CRUMBS ODOR: NONE 3 FIRE AND EXPLOSION HAZARD DATA FA S H F 01N T : METE 101 USED N 0 T A P F L. IC A B L. E NUT APPLICABLE i- ; a mm ad: e:"!-;:::ts L r L i < U mI"' F' L. 1 C A B I... I::. UFi.: ;: 0 T Apr LI CABLE EXTINGUISHING MEDIA WATER FOG, FuAm, (102, AND DRY CHEMICAL. LIRE AND LET LOS I OH HAZARDS: AVOID INHALATION OF SMOKE. FIRE-FIGHTING EQUIPMENT: BREATHING APPARATUS. WEAR POSITIVE PRESSURE, SELF-CONTAINED REACTIVITY DATA: STABILITY (CONDITIONS TO AVOID) DO NOT STORE ABOVE 200 F. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) STRONG OXIDIZING CONTINUED ON PAGE 2) ;R.-' INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY ni" OPERATING UNIT OF THE DOW CHEMICAL COMPANY D0 085530 confidential DOW CHEMICAL 0*2.A** MIDLAND, MI 48674 EMERGENCY PHONE: 517-636~440G PRODUCT CODE. 25383 :T "LJCT NAME: VECTOR (R) 8550-D S'TYRENIC BLOCK COPOLYMER PAGE: 2 EFFECTIVE DATE: 03/02/92 DATE PRINTED: 05/07/92 MSD : 003544 4* REACTIVITY DATA: (CONTINUED) AGENT2, HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE AND ORGANIC C 0 M P 0 U N D S U P 0 N C 0 M B U S' T10 N , HAZARDOUS POLYMERIZATION: WILL NOT OCCUR * 5. ENVIROnmENTAi. AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS: SWEEP UP OR PICK UP WITH AN INDUSTRIAL ' A,'"L"JM C!.. LANFP. PL!T INTO CONTAINER rr,;-; E ISPOSAL . DISPOSAL METHOD r, E C i... AIM , BURN IN A CHEMICAL INCINERATOR, OR BURY i.N AN APPROVED LANDFILL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS, o, HEALTH HAZARD DATA. EE SOLID OR DUST MAY CAUSE IRRITATION OR CORNEAL INJURY DUE TO MECHANICAL ACTION, SKIN CONTACT: EESENTIALLY NONIRRITATING TO SKIN. INJURY ONI..'-, MECHANICAL SKIN ad/ORFTTONrrupepties* SKIN ABSORPTION UNLIKELY DUE TO PHYSICAL INGESTION S' ISOLZ" DOSE ORAL LD50 HAS NO i BREN DETERMINED. SINGLE DOSE ORAL TOXICITY IS BELIEVED TO BE VERY LOU, CONSIDERED TO BE PHiSI CLOG 1CALLY INERT. NO HAZARDS ANTICIPATED FROM SWALLOWING S AMOUNTS INCIDENTAL TO NORMAL HANDLING OPERATIONS. INHALATION: DLJSI MAV CAUSE IRRITATION TO UPPER RESPIRATORY TRACT, SYSTEMIC AND OTHER EFFECTS: ADDITIVES ARE ENCAPSULATED IN THE PRODUCT AND ARE NOT EXPECTED TO BE RELEASED UNDER NORMAL PR 0 C - E S SIN G CONDITIONS. (CONTINUED ON PAGE 3) ' R) INDICATES A TRADEMARK UP THE DOW CHEMICAL COMPANY OPERATING UNIT OF THE DOW CHEMICAL COMPANY ^D 08SFO, C0^IOP,fS.1 -Ml. 0OW CHEMICAL U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 25333 PF-DUCT NAME: VECTOR (R) 8550-0 STYRENIC CLOCK COPOLYMER PAGE: 3 EFFECTIVE DATE: 03/02/92 DATE PRINTED: 05/07/92 MSD : 003544 7* FIRST AID: EYES: IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES. MECHANICAL EFFEC7 S ONLY SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER INDUSTRIAL HANDLING. INHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. PHYSICIAN. - CONSULT A C. HANDLING PRECAUTIONS EXP0SURE GUIDEL.INE(S . N0NEESTAB!...ISHZD F0R C0P0LYMER . VENTILATION. GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS. RESPIRATORS PROTECTION: FOR MOST CONDITIONS, NO RESPIRATORY PROTECTION SHOULD BE NEEDED; HOWEVER, IF HANDLING AT ELEVATED TEi"IPER ATURES WITH0UT SUFFICIENT VEL'NTIL..A7' 10N , USE AN APpR0 VED A IP -i: UR IF S'TNG RESPIRATOR. IN DUSTY ATMOSPHERES USE AN APPROVED DUST RESPIRATOR. SKIN PROTECTION: NO PRECAUTIONS OTHER TUAN CLEAN LODYCOVERING CLOTHING SHOULD BE NEEDED.. EYE PROTECTION; USE SAFETY GLASSES. IF THERE IS A POTENTIAL. FOR EXPOSURE TO PARTICLES WHICH COULD CAUSE MECHANICAL INJURY TO THE LIVE, WEAR CHEMICAL GOGGLES. i-iDD1770NhL INFORMATION : SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRODUCT CAN ACCUMULATE ELECTROSTATIC CHARGES WHEN RUBBED, CHAFED OR ABRADED. STATIC DISCAHARGE IN THE PRESENCE OF VOLATILE OR FLAMMABLE MIXTURES PRESENTS A POTENTIAL FIRE OR EXPLOSION HAZARD. EQUIPMENT SHOULD PROVIDE A MEANS FOR DISSIPATING ANY CHARGES THAT MAY DEVELOP. 1 CONTINUED ON PAGE 4) ' R > INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY OPERA!IN UNIT OF THE DOW CHEMICAL COMPANY confidential DOW CHEMICAL U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 25383 PRODUCT NAME: VECTOR (R) 3550-D STYRENIC BLOCK COPOLYMER PAGE: 4 EFFECTIVE DATE. 03/02/92 DATE PRINTED: 05/07/92 MSD: 003544 9* ADDITIONAL INFORMATION: (CONTINUED; COMPOUNDING OF PRODUCT IN HIGH CHEAP EQUIPMENT CAN CAUSE THE TEMPERATURE TO RISE. DO NOT ALLOW THE TEMPERATURE TO EXCEED 450F* MAINTAIN A FIRE WATCH IP 450F IS REACHED. MSDS STATUS. REVISED SECTION 2 (APPEARANCE) INFORMATION REGARDING STATE/PROVTNCIAL AND FEDERAI. R E G U... A T 0 R Y IN F 0 R M A T10 N S E C T ION. INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY REGULATIONS SEE U1' . ! ;*i , p. i'! Lv <J N .L I :: o mp any 00 O85533 CNFrOENTTA( M A T E R I A L SAFETY DATA SHEET DOW CHEMICAL U.S.A.* MIDLAND, MI 4367-4 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 25128 "f UCT NAME VECTOR <R) 6241-D STYREN1C BLOCK COPOLYMER PAGE: i EFFECTIVE DATE: 03/02/92 DATE PRINTED: 05/07/92 MSB. 003544 1* INGREDIENTS: < % W/U, UNLESS OTHERWISE NOTED) STYRENE-BUTADIENE BLOCK COPOLYMER ,-iDDITIVES CAS* 009003-55-8 >9S% <1% THIS DOCUMENT IS PREFARED PURSUANT TO THE OSHA HAZARD COMMUNICATION STANDARD <29 CFE 1910.1200). IN ADDITION, OTHER SUBSTANCES NOT 'HAZARDOUS' PER THIS OSHA STANDARD MAY BE LISTED. WHERE PROPRIETARY INGREDIENT SHOWS, THE IDENTITY MAY BE MADE AVAILABLE AS PROVIDED IN THIS STANDARD. PHYSICAL DAT/:, - 1 4. I... J. N (:, PUj. N I ' 1 ! L1 t A I - I L ,i. U II... VAP. PRESS: NEGLIGIBLE VAi-'. DENS ITT : NOT APPLICABLE . ' t.J I.... .1. N W A T E P N E G L1GIS3 L E SP'. GkAVIT i : 0 . /'2 APPEARANCE NATURAL COLOR PELLET HR CRUMBS ODOR: NONE. 3 FIRE i-,ND EXPLOSION HAZARD DATA. FI A S H F 01I'. r; E T H 01) USED: N 0 T A F !-' i... IC A B L E N U I' A i::' p L,, 10 A B L C FL A MM ABUS !. THUS - 1 !... ' i U . - / J i A UAL: NOT APPLIChBLF EXTINGUISHING MEDIa. WATER fog, FOAM, CG2, AND DR f CHEMICAL. FIRE aND EXPLOSION HAZARDS: AVOID INHALATION OF SMOKE. -IRE- FIG Pi 11N C E 0 UIP MEN T : BREATHING APPARATUS. REaCTIVITI DATA: WEAR p OS I i IV E P R E S S U R E , S E L. F - CON I AIMED STABILITY: (CONDITIONS TO AVOID) DO NOT STORE ABOVE 200 F. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) STRONG OXIDIZING (CONTINUED ON PAGE 2) :R) indicates A trademark OF THE DOW chemical company ",'f GPERATIilG UNIT CP THE DOW CHEMICAL COMPANY 00 085534 cONF TOFisJT IA1 DDL CHEMICAL U.S.A.* MIDLAND, MI 48674 EMERGENCY F HONE: 517-636-4400 PRODUCT' CODE ; 251 28 ;"i; UCT NAME: VECTOR (R) 6241~D STYRENIC BLOCK COPOLYMER PAGE: R-1 EFFECTIVE DATE : 03/02/92 DATE PRINTED: 05/07/92 MSD: 003544 REGULATORY INFORMATION <NOT MEANT TO BE ALL-INCLUSIVE--- SELECTED tEtULATIONS REPRESENTED.j NOTICE: THE INFORMATION HEREIN IS PRESENTED IN GOOD FAITH AND RELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SI-IOUN ABOVE * HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORS REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER FROM ONE .-.OCAnON TO ANOTHER, IT IS THE BUYER'S RESPONSIBILITY TO ENSURE HAT IIS ACTIVITIES COMPLY WITH FEDERAL, STATE OR PROVINCIAL, AND LOCAL LAWS, THE FOLLOWING SPECIFIC INFORMATION IS MADE FOR THE PURPOSE 0- COMPLYING WITH NUMEROUS FEDERAL.., STATE OR PROVINCIAL, t"'g lccr,l. las.-iri> ccul.;, i:.. see ;s AFETY I i\ FORM A 7 I On , lzt cr :.ealth and . NEGbL-A i IONS zr. r: x:, ::::r- r:, r::;r, SARA HAZARD CATEGORY THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE ERA "HAZARD CATEGORIES' PROMULGATED UNDER SECTIONS 311 AND 312 OF THE , orsis'refund amendment ind p.eautiiorj:zation act iVSo <sara title iid and J, ONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING I A i E GLORIES : .:'0T TO ! IA V[.. KF'; NN Y r! A... AKl) C A TEG0R Y *R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. CONSULT THE DOW CHEMICAL COMPANY F0R FU R T HER 1N F 0R M A TION. i--,N ui-'Ei'' i i'i INC UNIT JF 'THE DOW Ci-iEMJ CAL COMPANY DO 085535 CONFIDENTIAL DOW CHEMICAL U*S*A*><- MIDLAND, MI 43674 EMERGENCY RHONE: 517-636-4400 PEOUiCT CODE: 25128 PR' 'OCT NAME: VECTOR (R) 6241-D STYRENIC BLOCK COPOLYMER RAGE: ; EFFECTIVE DATE: 03/02/9; DATE PRINTED: 05/07/92 MSD: 003544 4* REACTIVITY DATA: (CONTINUED) AGENTS* HAZARDOUS DECOMPOSITION PRODUCTS: COMPOUNDS UPON COMBUSTION* CARBON MONOXIDE AND ORGANIC HAZARDOUS POLYMERIZATION: WILL NOT OCCUR* ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS SWEEP UP OP PICK UP WITH AN INDUSTRIAL V,AT-i. CLEANER. FUT INTO CONTAINER FOR DISFGSAi. * DISLOSA... METHOD RECLAIM, BURN IN A CHEMICAL INCINERATOR, OR BURY IN AN APF ROVED LANDFILL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL. REGULATIONS* 6. HEALTH HAZARD DATA' EYE SOLID OR DUST MAY CAUSE IRRITATION OR CORNEAL INJURY DUE TO MECHANICAL. ACTION. SKIN CONTACT: ZSSENTIAL L NONIRRITAT TNG TO SKIN. INJURY ONLY. MECHANICAL. S K IN A BSD R P T ION . IK IN A B S 0 R P T10 N IS U NI... I !< E I... Y I) U E I 0 i;:' H Y SIC A L '""'UP LF 'T !. F, S . ...N LEST I ON SINGLE DOSE CkAL L..DEO HAS NOT BEEN DETERMINED.. SINGLE DOSE ORAL. TOXICITY IS BELIEVED TO BE VERY LOW. CONSIDERED TO BE PH Y S10L0C IC ALL Y I HERT . N0 H AZ ARI)S ANTICIP ATED FROM SWALLOWING Small amounts incidental to normal handling operations. INHALATION: DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT* SYSTEMIC AND OTHER EFFECTS: ADDITIVES ARE ENCAPSULATED IN THE PRODUCT AND ARE NOT EXPECTED TO BE RELEASED UNDER NORMAL P R 0 C E S SIN G C 0 N DIT10 H S . (CONTINUED ON PAGE 3) (R) INDICATES A TRADEMARK DF THE DOW CHEMICAL COMPANY ..S OPERA I'liL:; UNIT OF THE DOW CHEMICAL. COMPANY 0 085536 CONFIDENTIAL DOW CHEMICAL U.S.A.* MIDLAND, MI 48674 EMERGENCY PHONE: 517-636-4400 PRODUCT CODE: 25123 PR' "U:;T NAME: VECTOR (R) 6241 -D STYRENIC BLOCK COPOLYMER PAGE: 3 EFFECTIVE DATE: 03/02/92 DATE PRINTED: 05/07/92 MSD: 003544 7. FIRST AID. EYES': IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES. MECHANICAL EFFECTS ONLY. SKIN. WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL "0 AROPER INDUSTRIAL HANDLING. INHALATION. REMOVE TO FRESH AIR IF EFFECTS OCCUR. PH rSICIAN. CONSULT A E X P 0 SI j R C G UID E LIN E . S) NON E E S' T A B LIS h E D F 0 R C 0 P OL f'niER . VENTILATION: GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR hOST CONDITIONS. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS, RESPIRATORY PROTECTION. FOR MOST CONDITIONS, NO RESPIRATORY PROTECTION SHOULD BE NEEDED; HOWEVER., IF HANDLING AT ELEVATED TEMPERATURES WITHOUI SUFFICIENT VENTILATION, USE AN APPROVED A IP-PUR I EYING RESPIRATOR.. TN DUSTY ATMOSPHERES, USE AN A P P R 0 V E D I) U S T R E S PIR A T 0 R . PKIP! PklFi LOTION NO PRECAUTIONS 01 HER 1 -is-N CLEAN BODY-COVERING CLOTHING SHOULD BE NEEDED. EYE PROTECTION: USE SAFETY GLASSES. IF THERE IS A POTENTIAL FOR EXPOSURE TO FARTICLES WHICH COULD CAUSE MECHANICAL INJURY TO TUC EYE, WEAR CHEMICAL GOGGLES. " . ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRODUCT CAN ACCUMULATE ELECTROSTATIC CHARGES WHEN RUBBED, CHAFED OR ABRADED. STATIC DISCAHARGE IN THE PRESENCE OF VOLATILE OR FLAMMABLE MIXTURES PRESENTS A POTENTIAL FIRE OR EXPLOSION HAZARD. EQUIPMENT SHOULD PROVIDE A MEANS FOR DISSIPATING ANY CHARGES THAT MAY DEVELOP. :CONTINUED ON PAGE 4) (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY OFEEAT IMG UNIT OF THE DOW CHEMICAL COMPANY 0 085537 confidential DOW CHEMICAL U*S*A. MIDLAND, MI -48674 EMERGENCY PHONE: 517-636-4480. PRODUCT CODE: 25)28 PP'-'XJCT NAME: VECTOR < R) 6241-D STYRENIC BLOCK COPOLYMER PAGE: 4 EFFECTIVE DATE: 03/02/9:2 DATE PRINTED: 05/07/92 MSD: 003544 9. ADDITIONAL. INFORMATION, lCONTINUED) COMPOUNDING OF PRODUCT IN HIGH SHEAR EQUIPMENT CAN CAUSE THE TEMPERATURE TO RISE * DO NOT ALLOW THE TEMPERATURE TO EXCEED 450F, MAINTAIN A FIRE WATCH IF 450F IS REACHED* . MSDS STATUS: REVISED SECTION 2 \APPEARANCE) FOR INFORMATION REGARDING STATE/PROVINCIAL AND FEDERAL REGULATIONS SEE T H E RE G U LA T 0 R Y INFORMA TION SECTION* ;R> INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY 4 u i" f'i I Ji I.1. T OF I HE DOW CHEMICAL. COMPANY DO 085538 CONFIDENTIAL JUL-16-'92 THU 09:45 ID:CPE TECHNOLOGY CENT TEL NO:FAX 504 309 2254 4951 P02 r MATERIAL SAFETY DATA SHEET Dexco Polymers* Houston. TX 77079 Emergency Phone: 517-636-4400 Grade Code; 25441100 Product Code: 24828 Page: 1 Product Name: VECTOR 4411-D STyRENIC BLOCK COPOLYMER Effective Pate; 8/16/90 MSPS: 002786 1. INGREDIENTS; (% w/w, unless otherwise noted) Styrene-isoprene block copolymer CAS# 025038-32-8 Additives >98% <1% Tills document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, oth r substances not "Hazardous* per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA; BOIUNG POINT: VAP. PRESS.: VAP. DENSITY: SOL IN WATER: SP. GRAVITY: APPEARANCE: ODOR: Not applicable Negligible Not applicable Negligible 0.92 Natural color pellet None 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT; Not applicable METHOD USED: Not applicable FLAMMABLE LIMITS LFL: Not applicable UFL: Not applicable EXTINGUISHING MEDIA: Water fog, foam, C02, and dry chemical. FIRE AND EXPLOSION*HAZARDS: Avoid inhalation of smoke. FIRE-FIGHTING EQUIPMENT: contained breathing apparatus. (Continued on Page 2) Wear positive pressure, self Indicates a Trademark of Dexco Polymers * A Dow/Exxon Partnership ^0 085539 C0NFTD5NTTAI JUL-16-'92 THU 09:45 ID:CPE TECHNOLOGY CENT TEL NO:FAX 504 389 2254 #951 P03 MATERIAL SAFETY DATA SHEET Dexco Polymers* Houston, TX 77079 Emergency Phone: 617-636*4400 Grade Code: 25441100 Product Code: 24828 Page: 2 Product Name: VECTOR 4411-D STYRENIC BLOCK COPOLYMER Effective Date: 8/16/90 MSPS; 002756 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Do not store above 200- F. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and organic compounds upon combustion. HAZARDOUS POLYMERIZATION: Will not oocur. 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS: Sweep up or pick up with an industrial vacuum cleaner. Put into container for disposal. DISPOSAL METHOD: Reclaim, bum in a chemical incinerator, or bury in an approved landfill in accordance with federal, state and local regulations. 6. HEALTH HAZARD DATA: EYE: Solid or dust may cause irritation or corneal Injury due t mechanical action. SKIN CONTACT: Essentially non-irritating to skin. Mechanical injury only. SKIN ABSORPTION: Skin absorption is unlikely due to physical properties. INGESTION: Single dose oral LD50 has not been determined. Single dose oral toxicity is believed to be very low. No hazards anticipated from swallowing small amounts incidental to normal handling operations. (Continued on page 3) Indicates a Trademark of Dexco Polymers A Dow/Exxon Partnership 0n conftdfnt?a, JUL-16-'92 THU 09:45 ID:CPE TEONOLOfiY CENT TEL NOsFAX 504 389 2254 8951 P04 MATERIAL SAFETY DATA SHEET Pexco Polymers* Houston, TX 77079 Emergency Phong: 517-636-4400 Grade Code: 25441100 Product Code: 24828 Page: 3 Product Name: VECTOR 4411 -D STYRENIC BLOCK COPOLYMER Effective Date: 8/16/90 MSDS; 002756 6. HEALTH HAZARD DATA: (Continued) INHALATION: Dust may cause irritation to upper respiratory tract. SYSTEMIC AND OTHER EFFECTS: Additives are encapsulated in the product and are not expected to be released under normal processing conditions. 7. FIRST AID EYES: Irrigate immediately with water for at least 5 minutes. Mechanical effects only. SKIN: Wash off in flowing water or shower. INGESTION: No adverse effects anticipated by this route of exposure incidental to proper industrial handling. INHALATION: Remove to fresh air if effects occur. Consult a physician. 8. . HANDLING PRECAUTIONS: EXPOSURE GUIDELINE (S): None established for copolymer. VENTILATION: Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations. RESPIRATORY PROTECTION: For most conditions, no respiratory protection should be needed; however, if handling at elevated temperatures without sufficient ventilation, use an approved air* purifying respirator. In dusty atmospheres, use an approved dust respirator. SKIN PROTECTION: No precautions other than clean body-covering clothing should be needed. (Continued on page 4) Indicat s a Trademark of DexcoPolym rs A Dow/Exxon Partnership C0DN0 FDFNTrai JUL-16-'92 THU 09:46 ID:CPE TEONXOGY CENT TEL NO:FAX 504 389 2254 8951 P05 MATERIAL 8AF ETY DATA 8HEET Daxco Polymers" Houston, TX 77070 Emergency Phone: 517-636-4400 Grade Code: 25441100 Product Code: 24820 Page: 4 Product Name: VECTOR 4411 -D STYRENIC BLOCK COPOLYMER Effective Date: 8/16/90 _____ _______ __ ___________ MSDS: 002756 8. HANDLING PRECAUTIONS: (Continued) EYE PROTECTION: Use safety glasses. If there is a potential for exposure to particles which could cause mechanical injury to the ye, wear chemical goggles. 9. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Product can accumulate electrostatic charges when rubbed, chafed or abraded. Static discharge in the presence of volatile or flammable mixtures presents a potential fire or explosion hazard. Equipment should provide a means for dissipating any charges that may develop. Compounding of product in high shear equipment can cause the temperature to rise. DO NOT ALLOW THE TEMPERATURE TO EXCEED 450* F. MAINTAIN A FIRE WATCH IF 450* F IS REACHED. MSDS STATUS: Revised section 9 (Special Precautions). For information regarding state/provincial and federal regulations, see the Regulatory Information Section. Indicates a Trademark of Dexco Polymers * A Dow/Exxon Partn rship C0^r7, JUL-16-'92 THU 09:47 ID:CPE TEONXOGY CENT TEL NO:FftX 504 389 2254 1*951 PBS MATERIAL SAFETY DATA SHEET Dexco Polymers* Houston, TX 77079 Emergency Phone: 817*636-4400 Grade Codo: 25441100 Product Code: 24825 Page: R-1 Product Name: VECTOR 4411-D STYRENIC BLOCK COPOLYMER Effective Date: 8/16/90 MSDS: 002756 REGULATION INFORMATION: (Not meant to be all-inclueive-selected regulations represented.) NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ from one location to another, it is the buyer's responsibility to assure that it's activities comply with federal, state or provincial, and local laws. The following specilic information is made for the purpose of complying with numerous federal, state or provincial, and local laws and regulations. See MSD Sheet for health and safety information. U. S. REGULATIONS SARA HAZARD CATEGORY: This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and Is considered, under applicable definitions, to meet the following categories: Not to have met any hazard category. The Information Herein Is Given In Good Faith, But No Warranty, Express or Implied, Is Made. Consult Dexco Polymers For Further Information. <S> Indicates a Trademark of Dexco Polymers * A Dow/Exxon Partnership Oo Co/vp ?8SS43