Document bB85B2OBXeeeZ56B6NQxoL4DD

i' TM I b. K N H L M A 1 L RIAL SAFETY DA 1 A J H L T 341 iSSUE DATE: SEPTEMBER 12, 1985DATE UPDATED: CHEMICAL NAME: CYCL'OHEXENE OXIDE MARCH 10, 1986 Ctio MANUFACTURER NAME/ADDRESS; NIROYAL CHEMICAL COMPANY, INC. DRLD HEADQUARTERS' MIDDLEBURY CT 006749 MANUFACTURER PHONE NO: 703-723-367Q_____ 800-424-9300 FCMHgERMCTFRNEPI - CAS OR TRADE NO. 0286-20-4 EPA REPORTABLE QTY CHEMICAL FAMILY:EPOXIDE DOT SHIPPING NAME: FLAMMABLE LIQUID, N.Q.S. DQJL HAZARD CLASS: FLAMMABLE LIQUID_____________ SUBSIDIARY RISK: UN r.D. NUMBER: 1993 ALIAS: NAUCARD CHO * SECTION 1 PHYSICAL DATA/HAZARDOUS INGRED * *******tt********tt***tt#JHHt*JMt****tHIHHHt*******tMt-*****IMt#*******tttt*********** JBQTi TNG..POINT Q760MM HG 266 DEG. F VAPOR PENSTTY (AIR=1) NOT DETER. SflLUBH TTY (WEIGHT*/ IN WATER) INSOL.IN WATER EREF7TNG/MFI TTNf. POINT N/A *m I IMF A vm ATTl F PH flF SON IT TONS; NOT LISTED VAPOR PRESSURE: T DETERMINED EVAPORATION RATE: NOT--LISTED ----------- Y(H20=1) BULK DENSITY NOT LISTED APPEARANCE AND ODOR: COLORLESS LIQUID; PUNGENT, OFFENSIVE ODOR HEAT OF SOLUTION NOT- LISTED INGREDIENT: CYCLOHEXENE OXIDE y. INGREDIENT s -1- wyii.' . A. . / < C' -. 1 'X-' s - , ..1 .:1 , ,....; -.. . . i ` 1 - v ' lh SL 049684 ***#*****#**#*#-###***#**#**##****#***##*##*******#****#*********#**#********* * SECTION 2 & 3 FIRE/EXPLOSION HAZARD DATA FLASH POINT DEG F (METHOD USED> +10-6 DEG- F (TOC) FLAMMABLE LIMITS IN AIR(X BY VOLUME) LEL: UEL: 1-15 12-36 EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL rPFCTAI FT RE -EIGHT TNG PROCEDURES SPECIAL FIRE FIGHTING PROCEDURES: PROTECT AGAINST INHALATION OF COMBUSTION PRODUCTS. UNUSUAL HAZARDS: FLAMMABLE LIQUID. #****#****#*#***##**##**###**#**********##****#*#******##*#**##*#**#*#******* * SECTION 4-1 HEALTH HAZARD DATA *#****#**##*#*###**#*####*#*###***####***#*######****#****#*##*#**#####**##* PERMISSIBLE EXPOSURE LIMITS: ACGIH TLV: NOT DETERMINED OSHA-PEL: NOT DETERMINED MFRS RFC:______________________________ CARCINOGENICITY STATUS (SOURCE): -------------------------- N.IOSH RFP.ORTS-IHAT THIS MATFR.IAI...ENHANCES THE CARCINOCE- NICITY OF ETHYLENE DIBROMODE IN RODENTS. TOXICITY DATA: EFFECTS OF OVEREXPOSURE, ETC. -SPECTFT_C_HAZARIUS): TOyTO_RY. T1FRMAI FVPngllRF. MODFRATFI Y TOXTC BY ORAI EXPOSURE- CONTACT WITH EYES, WILL CAUSE SEVERE IRRITATION- INHALATION OF VAPORS CAN CAUSE RESPIRATORS IRRITATION- EXPERIMENTAL EVIDENCES SUGGEST MUTAGENIC POTENTIAL. gOTXMICAOgLyO.gGnYU.TINF.F(OXR)OMAFT-IOFNNTR--Y--2--.-.-..INHALATION, SKIN . ABSORPTION ---------------------------------- RAL TOXICITY: LD50 (RATS) - 1,05 G/KG DERMAL TOXICITY: LD50 (RABBITS) - 0.6 G/KG INHALATION TOXTCTTY: C5Q (RATS 4 HR.) - ?AA9 PPM IRRITATION EYE (RABBITS) - SEIV\_E_R_E. MUTAGENICITY: AMES SALMONELLA - POSITIVE CHRONIC: THE FEEDING TO MICE OF UP T0"220 PPM AND RATS OF UP TO 600 PPM FOR _mn YFAR.y DTP woT pgnmirr&M TMrpPArrn thmop TMrmFMrr **#**********##**#####*###########*#*#**#**#*####******#**#*.###*****.*##****.**** * SECTION 4.2 EMERGENCY/FIRST AID PROCEDURE ttftttftftKSttfrttttttttKtttttt************************************************************** INHALATION: REMOVE TO FRESH AIR. 5- SL 0496S5 EYE CONTACT: FLUSH WITH WATER FOR *5 MINUTES. GET MEDICAL ATTENTION. WAIh Thoroughly WITH SOAP AND WATER. INGESTION: NONE _L-LSID.. NOTES TO PHYSICIAN (INCLUDING ANTIDOTES) NONE LISTED. ***************##*##*#*#**#**#*****##**##**####*##*****##*##**#**#*#********* ****#**#***tt#********tt**S*E#CttT*I*O*NJM5 tJHREHAHCHTIHVItT*Y***D*A*T*A*#tt**#***##*********tt*******#***4* STABILITY: STABLE (? AMBIENT TEMPS. & PRESSURES CONDITIONS TO AVOID: ____ NONE LISTED____________ HAZARDOUS POLYMERIZATION: NOT. LISTED____________________ CONDITIONS TO AVOID: NONE LISTED INCOMPATIBILITY (MATERIALS TO AVOID): HIGH REACTIVE WITH ACID, BASES AND MANY ORGANIC COMPOUNDSHAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON UNDER BURNING CONDITIONS. rr, SL 049686 ******************************************************************************* SECTION 6 SPILL OR LEAK PROCEDURES S TEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED -' mENGMOTVOE OALSL-L--- SSOHUORVCEELS- OF INin IGNITION. ABSORB ON INERT MATERIAL. USING NON-SPARKSECURE CONTAINERS POR-.eR.QPER DISPCSAt ------USE PERSONAL.. PROTECTIVE EQUIPMENT AS OUTLINED. WASTE DISPOSAL METHOD: TN ACCORDANCE WTT-U EPA/RCRA REGULATIONS -Aft-CFR 261-24 (A) <-1.X,- IGNITABILITY D01 . ENVIRONMENTAL EFFECTS HAVE NOT BEEN DETERMINED. *********************************************m***************************^^**^ *************************S*E*C*T*IO*N***7*.1***S*P*E*C*I*A*L**P*R*O*T*E*C*T*O*N*************************** RESPIRATORY PROTECTION.;____ _______ ___________ _ IN THE ABSENCE OF ADEQUATE VENTILATION, USE NIOSH CERTIFIED RESPIRATORY PROTECTION FOR ORGANIC VAPORS. ************************1 **' *' *,. .` *1**.. *v>w *1.^. *4,'?A'!-t`*^ **mJ**?^*.-`.T~*M" *tv?*T,,V*,' *v*.'i&A*ft'i*i i ***i *J*^M`*,^*.|HtM"M^***^4t *************************S*E**C*T*IO*N***7*.2***S*P*E*C*IA**L**P*R*O*T*E*C*TO**N**D*A*T*A********************* VENTTI ATTflNf TYPF1 :_____________________________________________________________________________________ LOCAL EXHAUST VENTILATION STRONGLY RECOMMENDED TO MINIMIZE VAPOR EXPOSURE. EYE PROTECTION: GOGGLES OTHER PROTECTIVE EQUIPMENT AVOID ALL PERSONAL CONTACT GLOVES: IMPERVIOUS ^***************************************f*************************************: ***************..*...*..*...*..*..*. ****-*S*E*C*T*I*O*N**8*.*t***S*P*E*C**IA*L**P*R*E*C**A*U*T*IO*N*S****************** ** *<; -gPFCTAl.. PRFHAtITT P1M.<T ^ >"' Sfe______________ ""... ' STORAGE: STORE AWAY FROM SOURCES OF DIRECT HEAT AND IGNITION SOURCES. KEEP CONTAINERS CLOSED WHEN NOT IN USE. GROUND DURING TRANSFER OPERATIONS. STORE IN A WELL-VENTILATED AREA. *****************************|t#*****jMt****ftjt***#*********!tjMt*****. * SECTION- 8.2 REFERENCES ' REFERENCES; NONE LISTED. p-ivp?.**# *####*#*##*##******#*##***##*##*####***###**###*##**#########**#*****#*****#**** SECTION 8*4 MISC INFORMATION x**#**#####*###**###*#****####*#*##****#*#**##*##**#*#*####**#*#****#**********MISC INFORMATION: TONE LISTED* , r>., :v y. ' : `vV; ,r - ; T(*\ . V\V,- - $...'...... "... : i;.v . . ,V$