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MICROBIAL INHIBITION (DEHYDROGENASE TES -SUBSTA ICE ACTIVITY) Identity:A mixturecontainingperfluorooctanesulfonawthei,ch may alsobe referredtoas PFOS, FC-95, oras a component ofFC-206A. (1Octanesulfoniaccid)(CAS # 2795-39-3). Remarks: The 3M productionlotnumber was cc 785-22. The testsample isFC-206A. Currentinformationindicateistisa mixtureof0.92% PFOS, 18.75% diethyleneglycolbutylether,75.44% water,1.83% Hydroxy foamer, 1.75% sodium octylsulfate1,.2% poloxyethylenemonooctylphenylether, 0.06% sodium laurylsulfatea,nd 0.05% benzotriazole.. The followingsummary applies to a mixture with incompletely characterizedconcentrations of impudiies. Data may not accurately retlectthe toxicityof the fluoruchemical component of the testsample. MET IOD: Method: TTC. GLP: No Year completed: 1979 Analyticalmonitoring:Amount offormazanformed (asdeterminedwitha spectrophotometermeasuring % transmittance). Statisticamlethods: Graphed the measured % transmittance. Test organism source: Activatedsludge mixed liquorfrom theMetropolitan Wastewater TreatmentPlant(Pig'sEye Plant),St.Paul,MN. Test condition: Dilutionwater: Deionizedwater Syntheticsewage: Nutrientbroth(0.1g/100 mL mixed liquora)dded approximately1-hourpriortostartoftest.The mixed liquorwas kept aerated priorto the test. Stock and testsolutionpreparation: A primarystocksolutionwas prepared by dissolving22 g oftestmaterialto 100 mL withdeionized water. The stocksolutiownas then diluted(1mL ofstocksolutionto 100 mL deionizedwater)to prepareDilutio#n1. Dilutio#n2 was preparedby adding 1 mL of Dilutio#n1 to 100 mL deionizedwater. These solutionswere used topreparethetestconcentrations. Test vessels: Not given. Number of concentrations: fiveplus2 blankcontrols Incubation Temperature: 37:t 1 'C Totalsuspended solidson day of testing:10.6gA-(TSS). Element Basis: Microbialdehydrogenase activitbyy formationof formazan. Incubation time: 15-minutes. RESULTS Nominal concentrations: Blank control,10, 100, 1,000,10,000,and 100,000 mg/L. Element values: Not given. CONCLUSIONS No conclusionsgiven. No triphenylformaza(nTF)standardcurvewas prepared inordertodetermine pmoles ofTF produced inthetestsolutions, thereforea, plotofpercentinhibitiovns.logconcentrationswas not constructedtodeterminethe EC50 value based on dehydrogenase activity.. Submitter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133 DATA QUALITY ReliabilityK:limischranking3. Study lacksdescriptioannd recordsofthe method followed.The inoculum isnot properlycharacterized.There isno characterizabonofthetestsubstance purityand the studylacksanalytical confirmationoftheamount offluorochemicalproportioninthe solutions. REFERENCES The studieswere conducted by the3M Company, EnvironmentalLaboratory, Lab Request Number 4970S, 1979. OTHER Last changed: 6/26/00 FORMI Iofto-e-ewo SAMPLE DESCRIPTION Fc--2-o6 A ENVIRONMU4TAL File: No. ENOR. LAB - WORK SHEET Date:.// 2 Analyst: Hrs.: 10 5 7 -9 f p !@4ToeK 45OLU7-IOAJ.' ITF .2,2. o pof 20 (0 2aO l@@ lt-U -TIO AJ 2 AotLlkZ, /0 a Pop H@L N@,s T-Tc 2Z!l 1490 0-S'O--J 6@oYKlA4,44; AA", o At4,A or4. 4,s0 4-.5' 0 S"O S71, 0 /.o o /,o 3r7t /'OC fv Reviewecxy: File:PTON'. ENVIRONMENTAL ENGR. LAB - WORK SHEET SAMPLE DESCRIPTION 0,6 A- 7T c- Date: Analyst: iu-@ce, 0 1t _.zs 0v Reviewed by: FORM I*$ao-a-pwo SAMPLE DESCRIPTION Fe--206hee, r7gs--2-2- ENVIRONMENTAL T File: No. ENOR. LAB - WORK SHEET c)ato: - 2- Analyst: Hm: 70 -S 4 4datL::@6@ FAi-o-PAl L.S Of, -tk Off 4L 2@@ I 10 IOD 1000 ID,ot)O 'D0 C>D 0 s-o,olo 3r+, o 44.3 S-080 h ul Att IPIov 7-ddAdd-4 A,?L) S-Oolo7T7 Rai *a grill oog @ot 0006/ oo/ 0/ '70Y-1rVo@7 -T+f- T-T-- 7-T -T7-T --t- -T- fII iI zi I INI@I ZI I -FTT-F ol p 13 1 13 ' xo I -TTT7- -LITT- -- - - --- I-] t---FT-T- 4iJ@-4: SOL4h 'V-7 III [it t ii -------- L -L-L.-t I I I TT- Li F 11 ET-= I i LE I I IT op cz oo T T--H--- - - ---- I f-T-7 - - - - - -- - - - - - - - - ---- Lob Req. No. -ftscription lxvig*mmtalLab utips pop Anlyst Std NsthO" (14U ed.) pp. sg-g&.sft.2" - solid$ Calculatum:"/I pp. aft.in-C. . on"o Oil K residuxe 1009 iu 64we Datemmyw -Li"2-9I-f AdP Gross Weight "Sid" wel9t (al 2- o 0.70 .2@2,oz070 7 (o 020@, 0.0 loqoo Desckrvtion Of I ds Crucible weight (s) Resd=ue -X-C-ilh(t2) Residue A@ IJ iL L SS