Document b5Ydzg3Z6Ov8bOyBxm37g3K3Z
Shell
MATERIAL
97367 <4-85)
24 HOUR EMERGENCY ASSISTANCE
SAFETY DATA SHEET
MSDS NUMBER ^
840,076-1
GENERAL MSDS ASSISTANCE
PAGE 1
SHELL: 713-473-9461 CHEMTREC: 800-424-9300
SHELL: 713-241-4819
ACUTE HEALTH *'
FIRE
&1
. REACTIVITY
7* \ ~
^ LEAST - 0 HAZARD RATING
HIGH - 3
SLIGHT - 1 EXTREME - 4
MODERATE - 2
for acute and chronic health effects refer to the discussion in Section III
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READ OUR PRODUCT SAFETY INFORMATION
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SECTION 1
ASBESTOS PRODUCT ^
NAME:
CHEMICAL k AMOSITE. CHRYSOTILE, CROCIDOLITE AND OTHER FORMS COVERED BY THE
NAME r 0SHA HEALTH STANDARD
FAMILY
SHELL CODE
W WWWWW
~________
SECTION II-A NO.
P ASBESTOS
PRODUCT/INGREDIENT COMPOSITION
CAS NUMBER
PERCENT
1332-21-4
100
SECTION II-B NO. ACUTE ORAL L050
P NONE
ACUTE TOXICITY DATA ACUTE DERMAL LD50
ACUTE INHALATION LC50
SECTION in
HEALTH INFORMATION
THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).
EYE CONTACT DUST MAY CAUSE MECHANICAL IRRITATION TO THE EYES.
SKIN CONTACT HIGH CONCENTRATIONS OF DUST ARE IRRITATING TO THE SKIN AND MAY CAUSE "ASBESTOS CORNS." BENIGN, WART-LIKE GROWTHS.
INHALATION INHALATION OF ASBESTOS FIBER MAY CAUSE ASBESTOSIS (FIBROSIS OF THE LUNGS), LUNG CANCER OR MESOTHELIOMA (SEE OTHER HEALTH EFFECTS).
INGESTION ASBESTOS HAS A LOW LEVEL OF ACUTE TOXICITY UPON INGESTION
LAM 026466
SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. BREATH, COUGH, CHEST PAIN, FATIGUE AND WEIGHT LOSS.
LUNG DAMAGE (SCARRING. AND TUMORS) MAY BE EVIDENCED BY SHORTNESS OF CYANOSIS (BLUISH DISCOLORATION OF THE SKIN), CLUBBING OF THE FINGERS.
ABS-044419
PRODUCT NAME: ASBESTOS
MSDS 840,076-1
PAGE
2
AGGRAVATED MEDICAL CONDITIONS PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. IMPAIRED LUNG FUNCTION FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL.
OTHER HEALTH EFFECTS THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, THE NATIONAL TOXICOLOGY PROGRAM AND THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF ASBESTOS IN BOTH HUMANS AND EXPERIMENTAL ANIMALS. THEREFORE, THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE.
SEE SECTION VI FOR ADDITIONAL HEALTH INFORMATION.
SECTION IV
OCCUPATIONAL EXPOSURE LIMITS
OSHA
NO. PEL/TWA
PEL/CEILING
TLV/TWA
ACGIH TLV/STEL
OTHER
P
0.2 F/CC
. 1 F/CC*
PI
P2
P3
P4
2 F/CC.A1 0.5 F/CC,A 1 2 F/CC,A 1 0.2 F/CC,A 1 2 F/CC,A 1
F/CC= FIBERS/CUBIC CENTIMETER; *30-MINUTE EXCURSION LIMIT. P1= AMOSITE; P2 = CHRYSOTILE; P3 CROCIDOLITE; P4 = OTHER FORMS.
SECTION V
EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT FLUSH EYES WITH PLENTY OF WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN CONTACT REMOVE CONTAMINATED CLOTHING/SHOES AND WIPE EXCESS FROM SKIN. FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH SOAP AND WATER. IF IRRITATION OCCURS. GET MEDICAL ATTENTION. DO NOT REUSE CLOTHING UNTIL CLEANED.
INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.
GIVE ARTIFICIAL
INGESTION DO NOT INDUCE VOMITING. IN GENERAL. NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF MATERIAL ARE INGESTED. HOWEVER, GET MEDICAL ADVICE.
SECTION VI
SUPPLEMENTAL HEALTH INFORMATION
ASBESTOS CAUSED NO DOSE-RELATED INCREASE IN SISTER-CHROMATID EXCHANGE LEVELS IN CH0-K1 CELLS. HUMAN FIBROBLASTS OR HUMAN LYMPHOBLASTOID CELLS. HOWEVER, MITOTIC DELAY WAS INDUCED IN CH0-K1 CELLS AND HUMAN FIBROBLASTS. CHINESE HAMSTER OVARIAN FIBROBLASTS SHOWED AN INCREASE IN THE SISTER CHROMATID EXCHANGE RATE UPON EXPOSURE TO ASBESTOS. ESCHERICHIA COLI AND SALMONELLA TYPHIMURIUM SHOWED ASBESTOS NOT TO BE MUTAGENIC. CYTOGENETICS IN VITRO ASSAY FINDINGS WERE POSITIVE; ASBESTOS WAS NOT METABOLICALLY ACTIVATED.
MARKED TO EXTREME HYPERPLASIA OF THE BONE MARROW AND ABERRATIONS OF HUMORAL AND CELLULAR IMMUNITY HAVE BEEN REPORTED IN INDIVIDUALS EXPOSED TO ASBESTOS.
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS CONCLUDED THE FOLLOWING: "CIGARTETTE SMOKING AND OCCUPATIONAL EXPOSURE TO ASBESTOS FIBERS INCREASES LUNG CANCER INCIDENCE INDEPENDENTLY; WHEN THEY OCCUR TOGETHER. THEY ACT MULTIPLICATIVELY." THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEE EXPOSURE.
LAM 026467 ABS-044420
PRODUCT NAME: ASBESTOS
MSDS 840,076-1
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SECTION VII
PHYSICAL DATA
BOILING POINT: NOT AVAILABLE (DEG F)
SPECIFIC GRAVITY: >1 (H20=1)
MELTING POINT: NOT AVAILABLE (DEG F)
SOLUBILITY: (IN WATER)
NEGLIGIBLE
EVAPORATION RATE (N-BUTYL ACETATE =1): NOT AVAILABLE
APPEARANCE AND ODOR: FIBROUS SOLID
VAPOR PRESSURE: NOT AVAILABLE (MM HG)
VAPOR DENSITY: NOT AVAILABLE (AIR=1)
SECTION VIII
FIRE AND EXPLOSION HAZARDS
FLASH POINT AND METHOD: NONE
FLAMMABLE LIMITS /% VOLUME IN AIR
LOWER: -
UPPER: -
EXTINGUISHING MEDIA USE WATER FOG, FOAM. ORY CHEMICAL OR C02.
SPECIAL FIRE FIGHTING PROCEDURES AW PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER.
SECTION IX
REACTIVITY
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION PRODUCTS ARE HIGHTLY DEPENDENT ON THE COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE PARTICULATES AND GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION.
SECTION X
EMPLOYEE PROTECTION
RESPIRATORY PROTECTION DO NOT BREATHE DUST. IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.1001 OR 1926.58 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR EQUIPPED WITH HIGH-EFFICIENCY PARTICULATE CARTRIDGES. FOR ADDITIONAL REQUIREMENTS, REFER TO 29 CFR 1926.58(H).
PROTECTIVE CLOTHING
AVOID CONTACT WITH EYES. WEAR SAFETY GLASSES AND CLOTHING. WEAR CHEMICAL-RESISTANT GLOVES REQUIREMENTS, REFER TO 29 CFR 1926.58(1).
OR GOGGLES AS APPROPRIATE. AVOID CONTACT AND PROTECTIVE CLOTHING. FOR ADDITIONAL
WITH
SKIN
ADDITIONAL PROTECTIVE MEASURES FOR ADDITIONAL REQUIREMENTS, REFER TO 29 CFR 1926.58(G).
ABS-044421
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SECTION XI
ENVIRONMENTAL PROTECTION
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SPILL OR LEAK PROCEDURES PREVENT BODILY CONTACT WITH SPILLED MATERIAL. WEAR PROTECTIVE CLOTHING AND APPROPRIATE RESPIRATOR.
VACUUM THE AREA WITH A VACCUM CLEANER EQUIPPED WITH HIGH-EFFICIENCY PARTICULATE AEROSOL (HEPA)
.PRODUCT NAME: ASBESTOS
MSDS 840,076-1
PAGE
4
FILTERS. FOR ADDITIONAL REQUIREMENTS ON CLEANUP AND DISPOSAL, REFER TO 29 CFR 1926.58(L). AVOID GENERATING DUST. PUT INTO CONTAINERS FOR DISPOSAL.
SECTION XII
SPECIAL PRECAUTIONS
FOR ADDITIONAL REQUIREMENTS. REFER TO 29 CFR 1926.58 OR 29 CFR 1910.1001. AS APPROPRIATE.
SECTION XIII
TRANSPORTATION REQUIREMENTS
DEPARTMENT OF TRANSPORTATION CLASSIFICATION: ASBESTOS WITH 1 POUND OR GREATER OF FRIABLE ASBESTOS PER CONTAINER IS REGULATED BY DOT IN CLASS ORM-E.
NONFRIABLE ASBESTOS AND FRIABLE ASBESTOS IN QUANTITIES OF LESS THAN 1 POUND PER CONTAINER ARE NOT REGULATED BY DOT.
D.O.T. PROPER SHIPPING NAME: HAZARDOUS SUBSTANCE, SOLID. N.O.S.
OTHER REQUIREMENTS: NA 9188
SECTION XIV
OTHER REGULATORY CONTROLS
THIS MATERIAL IS LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES.
IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE EDS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.
SECTION XV
STATE REGULATORY INFORMATION
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES: OTHER PRODUCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE APPLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YOU SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.
STATE LISTED COMPONENT
PERCENT
STATE CODE
ASBESTOS (CAS NO: 1332-21-4
100
CA, FL. IL. MA, ME. MN, PA, RI. CA65
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PRODUCT NAME: ASBESTOS
MSDS 840,076-1
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CA * CALIFORNIA HA2. SUBST. LIST; CA65 = CALIFORNIA SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX. SUBST. LIST; MA = MASSACHUSETTS SUBST. LIST; ME = MAINE HAZ SUBST. LIST; MN = MINNESOTA HAZ. SUBST. LIST; NJ = NEW JERSEY HAZ. SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST. LIST; RI = RHODE ISLAND HAZ. SUBST. LIST.
THIS MATERIAL CONTAINS A CHEMICAL OR CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY.
SECTION XVI
SPECIAL NOTES
THIS MSDS REVISION HAS CHANGES IN SECTIONS XIII, XV. SEE ENVRIONMENTAL DATA SHEET FOR WASTE DISPOSAL AND OTHER ENVIRONMENTAL INFORMATION.
THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.
DATE PREPARED:APRIL 03. 1992
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READ OUR PRODUCT SAFETY INFORMATION ...AND PASS IT ON
(PRODUCT LIABILITY LAW REQUIRES IT)
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SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210
LAM 026470 ABS-044423
Shell
ENVIRONMENTAL DATA SHEET
97449 (9-87)
EDS NUMBER 840,076
PAGE 1
PRODUCT ^ ASBESTOS
fPRODUCT .
CODE
WWWWW
SECTION I NO.
P ASBESTOS
PRODUCT/COMPOSITION COMPONENT
CAS NUMBER 1332-21-4
PERCENT 100
SECTION II
NO. EHS RQ (LBS)
CD
SARA TITLE III INFORMATION
EHS TPQ (LBS) ( *2)
SEC 313 ( *3 )
313 CATEGORY (*4)
p YES
311/312 CATEGORIES (*5 )
H-1, H-2
----------------------------------------- ---------- ---------------------------------------------- FOOTNOTES-------------------------------------------------------------------------------- -------------------
1 * REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
-3 = TOXIC CHEMICAL. SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM
*5 =* HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING
HEALTH H-1 " IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL P-3 FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 REACTIVE HAZARD
SECTION III
ENVIRONMENTAL RELEASE INFORMATION
EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT. UNDER EPA-CERCLA CSUPERFUND") RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE REPORTABLE QUANTITY MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-8802.
THE REPORTABLE QUANTITY (RQ) FOR A RELEASE OF THIS MATERIAL IS 1 LB.
SECTION IV
RCRA INFORMATION
IF THIS MATERIAL BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS.
LAM 026471 ABS-044424
PRODUCT NAME: ASBESTOS
EDS 840,076
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THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.
DATE PREPARED:JULY 05, 1989 ---------- ------------ ---------------
SHELL OIL COMPANY SAFETY, INDUSTRIAL HYGIENE AND ENVIRONMENT P. 0. BOX 4320 HOUSTON, TX 77210
FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL (713) 241-2252
FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461
CHEMTREC: (800) 424-9300
LAM 026472 ABS-044425