Document b5OD0kEXXv4O2KYjqea5aQw7D

%* Js'C * COV ANY CORRESPONT NCE p - - - ft TODIY: LOCATION: ATT*N OF: SUBJECT: Industrial Chemicals FROM DIV: Morristown LOCATION: Mr. J. M. Quinn Mr. J. M. DeVoe DATE: APPLICATION FOR PERMIT TO BURN FUEL OIL Industrial Chemicals Baton Rouge North Works July 3, 1974 to, %?4 1. Attached please find copies of permit request and emission inventory requested by the State of Louisiana in connection with our application for permit to burn fuel oil- We will hand deliver these documents today as per prior arrangement with you. P. B. Cornell, Manager Baton Rouge North Works FPT:rmcn Encs. Mr. E. E. Jamesy Mr. T. D. Kent./ Mr. A. J. vonFrank ASI 00005855 APPLICATION FOR APPROVAL OF EMISSIONS (Revised January 20, 1973) Send 14 copies to: Louisiana Air Control Commission P. 0. Box 6CSIC Nar Orloans, Louisiana 70160 Attention: Technical Assistance I. GENERAL INFORMATION Name of person or company requesting permit: % _______ Allied Chemical Corporation, IndustrialChemicals Division Address: P- * Box 271, Baton Rouge, Louisiana 70B2r Responsible Officer; P. B. Cornell Telephone No, 356-3341 Date Submitted: July 8, 1974 2. GEOGRAPHICAL LOCATION OF PLANT (Ascription of locetlon of plant or establIshmant end/or map section showing seme: Manufacturing^ facilities are located on the left (east) decending bank of the Mississippi River at Mi 232.81 above the Head of Passes on the south point of the property line and 233.46 Mi on the north point. This property covers approximately 200 acres, extending north to south approximately 3/4 mile from about 1/4 mile south of the Highway 190 bridge. It also extends about 1/2 mile to the east from the river. -I- ASI 00005856 Show ownership end use of adjoining procsrVy on map section or list below. List any residential areas near the plant or establishment and give distance from the plant or establ ishmant: These facilities are bordered on the north by the Kaiser Aluminum Company, by the Gulf States Utilities on the south, by the Ethyl Corporation on the east and by the Mississippi River on the west. These facilities are more than a mile from any residential area. 3. LOUISIANA AIR CONTROL O'*?*! <$rr* DM SSI ON I MVEHTORY QUESTIONNAIRE. A completed Emission Inventory Questionnaire (copy attached) is required. If a new 6 page questionnaire for This location h3S been previously submitted, give date of submission July , 197 4. A coTpIntod "revised" Emission Inventory Questionnaire must aiso bn submitted with this application. The Emission inventory Questionnaire must bo completed showing the entire emissions of the facility after modifications end/or additions. Estimated starting date of construction: __________ X.A._________ Estimi+ed date operatlon will begin: ______3rd Quarter 1974 New Facility:N.A._________________________ Addition: N*A._________________________ "Give a brief description of proposed action and attach such information as flow diagrams, schematic diagrams, drawings, etc. needed to convey an understanding of th processes Involved In the plant or establishment." Our present supply of natural gas is being curtailed by 4CF4. We therefore propose to substitute fuel oil ofO,7% sulfur for natural gas in the operation of six boilers in our steam turbine power house. Standby facilities for fuel oil burning are a part of the existing plant. Some changes will be made to obtain the most efficient utilization of the fuel oil on a continuous basis. LACCr *.FAOC-Oev. 1/20/73 *2* ASI 00005857 . IBEHTIFICATIOfi AND LOCATION OF EMISSION SOURCES Enctcj? a c!::tch shewing r-Gdflc location of point cr points of emission. She** eaprojM-orj dtsfnnco (In foot? or all such points from prcpo.'ty Ur..*. (acn etui to I on source shall bo numbered con secutively In the year of pnrnir request, For example, the first tor till eh e permit Is requested in 1973 ttould bo designated as 1-73. * Idontifration Number Kara and Dssorlpt'on of Source 1-74 . # Six stacks, one from each of six boilers in j our steam turbine power house. These slocks are numbered 56 through 61 on the current j Emission Inventory dated 7/B//U and | nvp nnproximately 100 ft. from the east !i' line which is ooroered by ic.e ..myi. corporation, approximately 1375 rt. trom the south line bordered by bult states i'tilities plant, aDproximately 2875 ft. to the north line bordered by the Kaiser Plant and anproximately 2125 ft. to the west line which is bordered by the Mississippi River. ----- - Idontiflection Number EMISSION Hi;7 3 SCF/ <5p* exit Velocity see Ft./Soc. Diem. Feet STACK Elev, Can be Above Sampled Grade Yes N'o 1-74 4493 306 19.6 7.0 80 ft X -- LACC-AFAOE-Rev. 1/20/73 3 ASI 00005858 SUMMARY OF EMISSIONS AND THEIR EFFECTS ON Af'OtCNT AIR Point Soure (Indlcat # on map) EMISSION Ibs/hr Air With Without Contam- Control Control 1nants Apparatus Apparatus 1-7 4* SO2 Stack #56 | |Ash Stack #57 | NO2 N.A. N.A. N.A. 610 13.1 67 Process Concentration of Pollulant Gases In risat ! 1 1 EFFECT C-!N _;A`_:nKvU* rI*oENr -Ti-u-r-A tR A i liaaros t "riix. Ground Property cod 1 1 Level \ Weight Discharge Gas lnput| L f no d Locations tons/hr PPM ug/(<i-> ; t-M ug/m-5 PPM u*i/m3 lorr.t. N.A. 8.2 xi 330 605,203 in" | 1.06 .1 63 0.26 KM N.A. N.A. -- 36 12,084 66,473 1 . - --rr.TT - 3.5 KM - 1.007 18.n 0.2b KM Rings 1 rrjsm Number cr Cpactty N.A. N.A. N.A. Stack #58 | Stack #50 | Stack #60 \ 1fAny necessary soot blow in" is e xpeeted to be in < ompl i[* nee ) 1 s Stack #61 | HZJ_ _ l* ii J__ ! Total amount of particulate 13.1 Ibs/hr. 1. PPM as used In this form refers to parts por million by volume. 2. Heat Input. The aggregate of heat content of oil fuels whoso products of corr-bustltlo pass through a stack or stacks. This Information should be included tor fuel burning equipment^only. 3* Fuel Burning Any stationary contrivance used In tbo process of burning fu)l or combustible material for the prl- Equlpment. mary purpose of producing heat or power by Indirect heat transfer. t 4* Process Any total weight of all materials Introduced into any specific prococs which may cause omissions. Weight. Solid fuel charged will be considered as part of the process weight, but liquid end gaseous fuels and combustion air will not. 4= * These six stacks, which a re close together and identical in capacity, are be i n" trealed as one point source in all calc ulations including the dispersion pa leu1ations. '**, Total in-put into six boilers of identical capacity. , property, line is too close For meanin-Ful dispersion cnlc t i tins. ASI 00005859 5. PROPOSED AIR POLL!/. A CONTROL List the Sir pol lotion ebetoont mi'r.ru".-;* thst rill bo utlllzstf to control tha c:"!rrwo os fthe sources for *i;.y plant or tslcb! ic.vant, if- r.o feci! itk : r.r^ copy oi;`7!* i?d, (!:/ Inn 5ter? i/r.fch ;;l ! 1 Vo tci.vrn to pr-avsr.v tha c.ilSEion cf stiff let;rn+ conri111cs of ,*oi fuicnis to resell- !r: vne?1;!rode levels, G!vo 'ii'.o scarce r.nd then the alK^oi-vant rvihod for oecn zoirco, Pnnss Ir.clu/o Information such es fiiTv'lr.os, us.tvjfzcfuror literstyro. spoc-l * icc+lon, cacechies r..it of f Icit.r.o *00 nesd.'d for evaluation of such conero! ecpdp.tent ar.cj tochniqv:s o-:od in coot rto11 i 113 cron source. Ploara Include; data rnsr each cs'tU,*.vh?i dote- c.TT.tlcn v:H! brain. Ar.y fnfonrctlcr. c'-out too rc-rhod LT.od for sbatelng tho scarce rill Ilc llitato the cw I yeti on cf the spoliation. Tt has been estimated that the emissions resulting orom a^nlic'-tior o* this permit will be in compliance. LACC-AFAOE-Rqv, 1/20/73 ASI 00005860 7. AUTHORITY This application Is submitted In accordance with the provisions of tho Regulations of the Air Control Commission, State of Louisiana. Industrial Chemicals Division Company P. 0. Box 271 Baton Rouge, Louisiana , Address \ s, <c, ^ ^ Signature of Responsible Officer P. B. Cornell Name of Responsible Officer Plant Manager Baton Rouge North Works Title of ^sponsible Officer (504)-356-3341 Signature of Professional Engineer Frank P. Turk Supervisor-Environmental Control Name (typed) and Title No. 4488________________________________ Professional Engineering Registration No. State Registered LACC-AFAOE-Rb v. |/2Q/73 ASI 00005861 ApPifjjyix Dispersion Calculation Form Figure I Horizontal Dispersion Coefficient * Figure 2 Vertical Dispersion Coefficient Figure 3 texlnuM Concenlratlcn Table I Exponential Table Table la Expcnonflel Tcble (Continued) Table 2 Conversion Feelers Pecgs I A-8A 9A 10 A II A 12 A 13 A HA UCC-AFAOE-Rav. 1/20/73 ASX 00005862 EFFECTS OF EMISSIONS ON AMBIENT AIR For purposes of this jlication, calculations based rocoontzed englnaar practice:; will bo accapiccl. Tho following rctercnccs may be helpful as a basis of calculalions of effects on ambient air. I. Workbook of Afnesphone Dispersion Estimates Environmental Protection Agancy Mr Pollution Technical Information Center Office of Technical Information and Publications Research Triangle P3rk, North Carolina 27711 2. Roconvnendsd Guide for the Prediction of Dispersion of Alrbcrne Irf l~u{ American Society of Mechanical Engineers 345 East 47th Street New York, New York 10017 Library of Congress No. 6S-3U23 issued In 1968 In order to ova-luato tho effects of a plants emissions upon the ambient sir, cirotphoric diion est must bo mdo. It has been the policy of Iho Technical Secretory and the Air Control Commission to require that ambient calculations show tho cumulative effects on the ambient air of tho entire facility after modifications for each pollutant emitlsd, The following calculations represent tho minimum requirement necessary to provide this information, in cases Involving multiple sources, the method of calculation will vary doaendfng on the number and location of the sources, in ihese cases, this form should be usod as a guide for calculating the effects cf out tip j_e_ sources. .......................... The general method as outlined in the Workbook of Atmospheric Dis persion Estimates is followed In these, calculations. Equation I is used In estimating the ground level concentration of a pollution along the centerline of the plume. Where X is tho estimated pollutant concentration in grams per mater 3 Q is the pollutant emission rate in grams per second U is the wind speed In meters per second C"y and are tho horizontal and vertical dispersion coefflents In meters (See Figures I and 2) H is the effec+ivu stack height In meters IT is a constant oqual to 3.1416 x is the downwind distance from the source in meters. LACC-AFAOE-Rev, i/20/73 * 1A * ASI 00005863 havti been dsnons+rated to be mo"o rep resent;-rive of a given source then the Holland equation Id acceptable. Equation ?: AH * hi (1,5 < 2.6G x I0"3p .Ts ~ Ta- d) u Ts tfhero AH ts the plume rt$G In meters Y$ Is (he stack gas exit velocity In irate rs/saeond d Is the Irek1-* rteck dlector In waters u Is Iho vine? speed In waters per second p Is tho atmospheric pressure In millibars Ts Is the stack temperature In degreos Kelvin Ta Is tho ambient air tempers'! uro In degrees Kelvin s (AH) (u) 5.95 in/sett 5.22 moter3 1,5 + (2,60 k 0-5 m"1 mb"* ^ (100mb) ( 570 CK " 298 K) (S.Zjn) (AH) (u) 258 In order +0 calculate the effective stack height (H) over 0 range of rind speeds, the value for tho plume rise (AH) must be found for each kind speed and aoded to tho physical height of the stack. l/CC-M7J0E-Sav. 1/20/73 2A ASI 00005864 u 0.5rt/scc I.Os/snc 2.0ia/*oc 3,C:c/sac 5.0>'*Vscc B.C^/sec IO.C,fri/$oC' I5.0fl/CGC 20,0'Vscc 2S.CVi(iC JO.G'Vcec 50.C'!/3OC (/iH u) / (u) <> 516 __ m < 255 m < 013L- tr. 386 m + 51. G n + 32.3 w + 25.8 17.2 12.q m m+ m+ in.3 n + 00 o> m* 5.2 m < h 24.4 24.4 24.4 24.4 24.4 24.4 .24.4 24.4 24.4 24.4 24.4 24.4 a m c. tn r M* Mc M* mQ m% mC mc h\ c mc m tr H 540.4 n 282.4 m -153^4 m 110.4 m 70 m 56.7 m 50.2 m 41.6 m 37.3 m 34.7 33 u at 20.6 m B, Concentration at Nearest Property Lino - The concentration at the nearest property lino Is calculated using equal ton (l), Equation Cl) shall be divided Into three sections to facilitate the calculation of tha concentration. X <x, o, of H) r ' 0 *1 ftxp (-{ (H/v* ) JL *.' All of the quantities In the term S^rcy^aro constant at a given distance dewm? I nd exccp! ^ and which vary with stability category; therefore, c value for (Q.'trcj.c* ) c&n easily bo found for each stability class. The values of\y end Tz can be obtained from Figures I and 2 by: (1) Find tha distance to the nearest property line on tha x cocr^ dlnste of tne Figure; (2) Following line perplndlcular to the x axis till It Intersects the appropriate stability curve; (3) Follo\;ing a line parallel to the x axis till It Intersects the Vy or ^ axis; 3A * LACC-AFAOE-P*v. I /20/73 ASI 00005865 (4) record below the value of or indicated Coefficients of Vertical and Horizontal Disporslon Th distance to the nearest property lino is ^0raters. = Helov/ ran?e of correlation Stabi1ity Class A 0 F * VI t rr\ EXAMPLE: A source Is 10,000 meters from the nearest property line. Using Figures I and 2 ine values of <7"y and 0s-z arc ap proximately 550 meters and 135 meters respectively using a D stability category. The rate of emission of the pollutant ( Q ) * 77 g/sec For A stability category: 0 (g/sec) n*}Vi (3.141 tin " m) < ~~1> g/sec-m2 For D stability category: 0 *( g/sec) Tr*r?vz <3.1416)1; m) ( * mT~ g/sec*m2 For F stability category: 0 'Wwy < g/sec) (3.14.6) ( m) ( rr.) g/sec_m2 LACC-AFAOE-Rev. 1/20/73 4A ASI 00005866 In tin? foilei.'Jng T/.2LE divide ihe rfftctlva sloe!; h'lgivf (111 for each v.lnd tpcod by the \rc. found :..`>ovC' for gscIi si.* bit Ivy colt'3017. v:i;:o r-r::D u m/soc 0.5 1.0 2.0 3.0 5.0 S.O io.o 15.0 20.0 25.0 30,0 50.0 S T A 0 1 l IT' Y CLASSES A1 0 j c K/<72 1< ! 1f 11 I s ! i The following Tables are used to calculate The pollutant concentration at the nearest property line. The value of Q/jTTV^^grfor each stability class found above Is used In Column I. Column 2 is made by taking the values from the table above for H/v>_ for each wind speed. "Column 3 fs determined by using the tables on page I2A and I3A. Column 4 is generated by multiplying columns I and 3 together and dividing by the appropriate wind speed." LACC-AFAOE-Rev. 1/20/73 5A * AS I 0005867 u 0.5 i 1.0 2.C 3.0 1 ' 5.0 | 8.0 | IQ.O 15.0 20.0 23.0 30.0 it 50.0 j corcciTKVrv.yiojiS r;?, a st/suitt (1) (2) <3> (4) (5) o i/Vl^ W'VV vf Tv/V* | |] XI Calculated 124-nr. AvGreno* J _" * II I i! i ! 1 i J 1 t1 1 i CCJxCCrfTR/vTIOVS FDft 0 STABILITY (I) (2) (3) (4) (5) u Q (H/^ CXp ["z( H/ifJ j C31cu 1 a ted 24-hr. AveragG* -rrvyV: 0.5 -------------------------1-----------1.0 I 2.0 3.0 | 5.0 J 6.0 10.0 15.0 20.0 1 25.0 30.0 50.0 | * The 24-hr. overage Is approximated by multiplying the calculated value by 0.36. UVCC-AFAOE-Rcv. 1/20/73 A5I 00005868 Cl) u0 '< r 0.5 1.0 2.0 3.0 cr'-.Eirrr/.Tio.vs fcr f stability (2) (K4) <5> u> X Calculated L_ (5) 24-hr. Averse:?e 5.0 6.0 10.0 15.0 20.0 t 25.0 30.0 50.0 ii * The 2<-hr. overage Is approximated by multiplying the calculated value by 0,36. C. Maximum Ground Level Concentration Figure 3 gives the distance to the point of maximum concentration^ max and the relative maximum concentration X w/<? as a function of effective stack height and stability. Using the proper stability ana effective stack height, the value of X can be found. This number is then multiplied by to give the maximum ground level ccncentraTlon. The value of the distance to the maximum concentration can be rood directly. LACC-AFAOE-Rav. 1/20/73 7A ASI 00005869 !CVH. CC,C'::T'^jjtws i< ; piO. Correlation N'.C. >1.C. \.C. t.O ;282. Lj3.23(10) *4j 1.16 (IP) "4 j!4.62(10v)-'4"' j4 1.66(10)\-4 2<0 !l53.43.47(l*)-"4|l.25(IJ)"4 SlDOdOf4 *0 36(IDv-p4 ; C:i Ic-,'1 evoa <24-iir.ovg. ; li} X.C. :|}i N.C. N. C. N.C. i { j !i:| 2.12(10)' 0.76(10)"5 | ;ii:.4;4.36(l:)"4;|.57(lj)"4 { ,.v \ k^ f r, ! 76 I 4.31(10)"T4 ]j 1.55(H)"4 I G0 !?.0 SJ.ij 4.31(10)^ jl.55(10)"4 J15.0 41.6 4,41 (ID)"4 1.59(10) "4 .0.0 37-3j 4.24(1 J)"4 1 1:53 a:)*4 25.0 34.7 4.00(10) "4 1.44(10) *4 h'n(VWp 33 3.08a:)"4 l.ll(IO)"4 50.0 29`6\ 2.46(D)"4 . 83(10) "4 l-I.SOdO)"4 ;0.65(I0)"4 }.5.l3(IGf^ |_L.65(10)' 2.31(10)"* j 0.65CI0)"4 J'l.08'10)"4 0.39(10)"* j rH' v-4 !* -4 0.66(10)_4 | 13.39(10)"4 1.22(I0)-4 !l.77(10) "4 h.5?(IOf4 j |.2/(10)^ j'2.10(D)"4 ;3.0b(l ')"A j i.! 1 (l .O-4 jjl.c6(lof4 b.08(!0)"4 jl.ll(IO)"4 i;2.16(D)"4 {3.08(ID)"4 jl.ll(lO)"4 J;2.05(10)"* i[2.l6(lj)"4 (3.78(10)"4 |jl. 54(10)"4 O.640O)"4 0.76(10)"* -- ).7ino)"4 | 0.78(10)"* j 0.74(10)"* | j:,.55(io)"* c The 24-hr. average is approximated by multiplying the calculated value by 0.3. - 03KKKIKD 01 STAGES TO KttCIKIK CCN'CEKT^VTI0\' ' u 0.5 1.0 ] 2.0 3.0 5.0 8.0 10.0 15.0 20.0 25.0 30.0 H 540.4 282.4 153.4 110.4 76.0 56.7 50.2 . 41.6 37.3 34.7 33.0 x, pittance to maximum Concentrerion A itabiIliy D iTeoiiivy F STcDi1i' y No correlation N.C. N.C. 0.7 15.0 N.C. 0.6 6.0 40.0 0.45 3.5 15.0 0.35; 2.0 8.0 0.26 1.6 4.8 0.25 1.0 3.8 0.22 0.8 2.8 0.19 0.7 2.4 0.18 0.65 1.9 0.17 0.64 1.8 50.0 29.6 0.16 lACC-AFAOc-Rev, 1/20/73 0.58 c CA c 1.7 ASI 00005870 DISTANCE DOWNWIND, km Figure l -Horizontal dispersion coefficient as a function of downwind distance from the source. LACC-AFAOE-Rev. 1/20/73 * 9A ASI 00005871 maUrt Figure 2 -Vertical dispersion coefficient as a function of downwind distance from the source. LACC-AFAOE-Rev. 1/20/73 ASI 00005872 LACC-AFAOE-Rev. J/2 0 /7 3 Figure J Distance of maximum concentration and maximum ,vu'0 as a function of slebihty (curves) and effective height (meters) of emission (numbers). SOLUTIONS TO EXPONENTIALS B = ep 1--O.W| The notation 2.16 E-I means 2,16 * 10 ' *S4 ASI 00005874 5a 8 0.00 1 0.10 > 0.20 -n 0*30 0.30 m -Ti1 0.30 o.eo < 0.70 o.ao -- 0*90 N) O 1.00 1.10 1.20 KM 1.30 1 .90 1.30 1.60 1.70 i.ao 1.90 2.00 2.10 ts 2.20 > 2.30 H 2.90 2.30 2.60 2.70 2.80 2.90 3.00 3.10 3.20 3.30 3.90 O.i'O 8 l.OoC 0 9.*>*E 9.0OE I 9.5bt t 9.21E fi.aat 8.361. .a*t 7.26t 1 6.67 *1 6.0'E S.9*t 1 9. B'E 1 9 3('K *.T6 -t 3.23E m \ 2.Tat 2.3F.E I ,9E l.6*L -1 1,3*C a | 1,1 nE | H.aoE 2 7. IOC -2 5.616 2 9.3oU 2 3,91 E -2 l.Mt -2 1.9*E 2 l.6*E -? 1.11E > e.i->E S.onf 9.32E -1 3 09fe -1 o.oi 0.02 0.03 1.00E 0 9.9*.E 1 9, TOf 1 9.33E I 9.19F 10.OOE 9.97E 9.TOE 9.50C 1 9.19E tO.OOE 9.9IE 9.79E 9.97E V.12E *\ ml a. Tp l .30E 1 t.ttp 1 7.20P 6.6LP -1 8.79E 8.25E | T.T?t 7.19E l 6.53E 0.69E 1 8.20E L 7.6bt -l 1.09E 1 6.39E -1 6.OIF 5.90F 1 o.otf 9.29P l 3 . TOF -1 3.20p l 2.79F 1 2.32E t 1 99p 1 1 .61* -l 5.93E 5.39E 9.7*t 9.1E 3.63E 3.1'C 1 2.69E - 1 2.2*t l 1.911 1.5'E 3.not 41 3,2 BE *.59E 9. he 1.60E 1 9.10E a 1 P.65E - i 2.73E i l.OTE 1.55E - 1.33F m\ l.o he 1 a. top -2 6.99E 2 5.9 BE -2 1.30E 1.03C 6.51 E *2 6.7*E *2 5.3*t -2 1.27E . 1 1.09E B.72E m2 9.62E -2 3.22E -*2 9.29E *2 3.37F -2 2.59F -2 1.93F -2 1.3SF 2 5.19E *2 3.23E -2 2.9-C -2 1.B9C 2 1 91 e 2 9.0TE 3.15E 2.9 IE 1.92* 1.3TE -2 .2 *2 -2 -2 1 .out 2 7.99p -3 V. 79* -J -3 2.99* -3 1.0*t *2 7. TOE 4 S.60E -3 9.09P -3 2.8E -3 1.02E -2 1.36E -3 9.9 3 - 3 3.91E *3 2.79E -3 0.09 9,99 9.90E l 9,72* -1 V.99 .1 -1 9.69* 9.15E 1.61E 1.01E 6.9e 1 *1 5.92* 3.Z2E fc.65p 1 5 , OHc I 1.5SE *1 3.06E 2.61E 2.20E l.<. 1.52c m1 1 1 l .2sp .01 E *>.t9t 6.91* 9. l*'E l 2 2 m2 3.97* 9.0 Tp 2. ]*>E 1.7 Ip 1.31* m2 ml ml ml mi *>, 9SF -3 1.21* 3 3.29* .3 3.7 H E .3 2.6t 3 0.06 9.99E ,, 1 9.99P 9.69E . ) 9.91E .1 9.0*P -1 8.60E a. top 7.55p 6.97P 6.37E -l 9,76p -- a 9.16P _ t 9.5 BE 9.C2E 3.50E 3.01E . t 2.56E .1 2.16E _ 1 1.1E 1 1.99F -1 1.22P 1 9.91E -2 7.96F .2 6.32F -2 9,9 IP -2 3.97P .2 2 99f .2 2.2BP -2 1 *72p -2 t. 29F .2 9.55F -J 7.00* .3 5.09F 3 3.66F 3 2.60* -3 0.06 9.98E -- 1 9.8 7p 1 9 * 6Tp _ 1 9.37E _ 1 9.00E -1 8.55E -- 1 e.o*E 7.69E . 1 6.91E 1 6.3 Ip -1 5.70P S.lOp .1 9.52E 3.9TP _ 1 3.95p 2,96p -- 1 2.52p _1 2.13p . 1 1.77p -1 l .9 Tp 1.70E -1 9. TOP .2 T.Tflp .2 6.1TE -2 9.B5P -2 J.78P .2 2.91* .2 2.22P -2 1.6Tp -2 .75P .2 9.26E -J 6.79p >3 9.92E .3 3.59p .1 2.5 1E -3 O.OT 9.99E -1 9.86C -l 9.6hE -l 9.39P -l 8.95P -l 8.5CE -l 7.99* -1 T.99E -l 6.85E -1 6.25E -1 5.69* -l 5.09E -l 6.96P -l 3.91E -l 3.39E -1 2.92P -1 2.9SE -1 2.09E -1 1.79 E -l I.99E -1 1.17E -l 9.50E -2 7.60E -2 6.03E -2 6.T3P -2 3.68E -2 2.83E -2 2.16E -2 1.63E -2 t.22E -2 8.98E -3 6.5SE -3 6.77P -3 3.92P -3 2.93E -3 0.08 9.97E .1 f.89E .1 9.6ZP -1 9.30E .1 .9tE .1 8.99E .1 7.9 9 p .1 7.3 B p .1 6. TOE .1 6.19E .1 5.5SE .1 6.99* .1 6 * 6 1 p .1 3 0* E .1 3.35E .1 2.87E .1 2.99E .1 2.05E .1 1* tie .1 1.91E -1 1.15E -t 9.29* _2 T.93E .2 5.89E .2 9.62E .2 3.59E .2 2.7p .2 2.10E .2 .5EE .2 1.18E -2 8.Tie >3 6.37E .3 6.61E .3 3.31E .1 2.35E -3 0.09 9.Tit -1 9.S2E -1 9.59E .1 9.27E -1 8.07 .1 8.90* -1 7,EC; -1 7.31* .1 .t>* . 6.136 -1 3.5?. .1 *,93E -1 9.35* .1 3.31* .1 3.30E -1 2.83E .1 2.90* .1 2,011 -1 1.3 o 1 1.J3E -1 1.13* t.occ t,;u 3.7;E 9.51E -1 .2 .2 -2 -2 3,9?* .2 2.61.* .2 2.0l -2 1.59E -2 1.15E -2 8.95E -I 6.17E -3 6.96E -3 3.2CE -3 2.27E -3 3.50 3.60 3.70 3.B0 3.90 9.00 9.10 9.20 9.30 9.90 2.(E -3 1.57E -3 1.07E 3 7.ire -4 *..9* .4 3.3ft -4 2.29E -4 i.9r. -4 9,6bK 6.25t -!> 2. t tp -3 1 .90E 3 1 .03* 1 7.05* 4 9.79p 4 3.22P 4 2.15* -4 1.92F 4 *1.75* -5 3.90* -4 2.09E *3 l .9?E 9. BnL 4 6.7C -4 9.61C 4 3 . lnE 4 2.03L 4 1.39E *4 8.86E -4 5.72E 1.9TE 1, IPb 9.63E 6.53E 9.9 3E ml 4 -4 -4 2.97E 1.99E 1.30E H.39E 3.9E 4 -4 4 5 -5 l.VOE 1.7 IE 9.1 HE 6.2h *.26F -3 3 4 -4 4 2.9b,; 1,99 1 .? H.t It 3.2CE .4 mH It -*> -4 1.93F 1,2BF B.89P 6.09C 9.09E -3 -3 -9 .9 .9 2.79* .9 l . 5 2 E -9 1 .20f fa 7.7flr -5 5.OIF -5 I.TTp 1.23E 8.5 1 p 5.B2P 3.93p -3 .3 .9 .9 .9 2.6 3p 1. T5E 1.15P 7.95P 9.Top .9 .9 -9 .5 -9 1.TIC -3 1.19E -3 8.20E -9 5.60E -9 3.70p -9 Z.53E -9 1.6BE -9 1.10E -9 7.13E -5 9.59E -5 t.65E .3 1.15E -3 T.89E .9 5.THE .9 3.63E .9 7.63E .9 l.ilE .9 1.05E .9 8.83E -5 9.3SE .5 1.59E -3 t.UE .3 T.&OE -9 5.HE -9 3.99E -9 2.33E .9 I.5'E -9 t.ote - 6.53E -3 9.19E -3 9.50 3.1,0 9,10 9. SO 3.90 . 9.01F -5 2.Set 1 . V1L -4 i.oie b.UL -4 1.B3P -3 2.93f -5 I.52F 3.9 b* -4 -5.02E -4 3 6 f,E -4 . 3?e - S 1.95t -4 9.02L -A 5.59 E 4 1.50E 2.21E 1 . J9E M.59E 3.2t 5 -6 l.T'-P S 2. t It S 1 .l.'E _s H.19* .6 3.0/E .4 3.2 Jr 2.'VF t.<v: T.fl JF 9.7 d E -3 -5 -3 -b 3.06E 1.9JE 1 . 2 Op T.'-iE H.iSE -5 -5 -5 -6 -9 2.92E 1.S9E 1.1 5E 7.0BE 5.UC -5 -5 -5 -6 -6 2.T9E _S 1.7:-E _5 1 .Oq* -5 9.79* .6 9.12E -6 2.&6E -5 1.'CE -5 l,Cl,' -5 fr.cct -6 J.o;i -3 LACC-AFAOE-Rev. 1/20/73 TABLE IA SOLUTIONS TO EXPONENTIALS 6 5.00 5.10 5.20 5. JO S.ftO 0.00 a J.ne -6 2.25b -ft l.JftC -6 2.95c -T ft.ftftb -T 0..H 1.55* -6 2.16E -ft 1.28E -6 T.56* -T 6,61F -1 M.oz J.JTC -6 2.05c -ft 1.21c -ft T.15E - ft.lP* -T O.OJ J.21E -6 t.o?E -6 1.15* -6 ft.TOE -7 T.96E -7 0.06 1.05E -ft l.B'E -6 1.9*i -6 ft.ftlE -T J.Tftc -r 0.05 2.90 -6 l.TftE -6 1.0ft* -6 6.09* -T J,55f -T 0.06 2.T6E -6 1.65E -6 9.B2E -T 5.TTE -T 3.3AE -T O.OT 2.62E -6 I.5TE -6 9.32* -T 5 , ft TE -T 3.1BE -1 0.08 2.ft9E .6 8l.f,t896E* -6 -7 5.191 -T 3.01E -T 0.09 2.31E -6 1 ft2E -6 8.16E -T ft . 7 1E -1 2.J5E -T 5.50 5.60 5.TO 5.80 5.90 6.00 6.10 6.20 6.JO 6.60 2.19c -1 1.56fc -T 8*8 IE --6 6.95b -8 Z.16E -9 l.52t 8.JTE -9 6.50t -9 <.*tE -9 1.2SE -9 2.56E -1 1.6TF -T 8.J2E -8 ft,68* .8 2.60F -8 l.*J* -8 T.P2* -9 6.2J* -9 2.Z6E -9 1,20* -9 2 ft?c -T l.Jlc - T.8ft --6 ft.ftlE -6 2.ft5* -8 I.J5E T.J5* -1 J.9TE -9 2.12E -9 1.I2E -9 2.29E -T i.ii.r -i T.*2E -8 ft.lftE -8 2.31E -8 1.2TE -8 ft.o?e -8 3.T3E -9 1.99E -9 1.05E -9 2.1TC -T 1.26E -T T.OIE -8 J.91E - 2. ME -S 1.20C -8 ft.ftlE -9 J.5U -9 1.9Tf .9 9.6TE-10 2.05E -T 1.17* -T 6.62E -J 3.TOE -8 2.06E -a 1.13E -5 6.12F -9 3.29E -9 l . T 6 *. .1 9.25F-10 1.9*E -T l.ME -T 6.25E -8 3.ft9 -8 1.9ftE -8 t.OftE .8 S.Tfte -9 J.09E -9 1.63E -9 8.6TE-13 I.eSE -7 1.05E -T 5.90* -8 3.29E -8 1.S2E -8 9.98E -9 5,`IE -9 2.91E -9 1.55E -9 8.13E-10 1.73* -T 9.6TE -8 5.5TE --8 J.ME -* .i.Ize -e 9,39* -9 5.00* -9 2.73* -9 l.*5E -9 T.62E-10 l.ftftE -1 9.321 .8 5.25* -a 2.93* .8 i.me -a 8.ME .9 ft.nc -9 2.56E -9 1.361 -9 7.1-E-10 6.50 6.60 6.TO 6.80 6.90 6.69b-10 J.*E-10 I.Tftb-10 9.10E-11 6.58r-ll 6.2TC-10 3.25E-10 1 .ftTC-10 8.50*-1l 6.29F-U 5.8'E-IO J.OSE-IO 1 5 *E-10 T.9ftt-ll ft. OnE-l1 5.50E-10 2.55E-10 1 .46E-10 f.m-n *. TjE-U 5.16E-10 2.ME-10 1.1TE-10 6.93E-11 l.ftE-M ft . 83* -1 J 2.5C - 1 3 1.2BE-1 3 6.ftTf-1 ) 3.25E-1 l 6.52E-10 2.3*>E-10 1.19E-10 6.0ftE-ll J.OJE-ll ft.2ft-10 2.19E-10 1. UE-10 ft.ftftE-11 2.J2E-U 3.9TE-10 2.0ft*-l0 l.Oftt-10 5.23E-11 2.631-11 3, T12-10 l ,911-10 9.7 ft.:-ii ft.721-11 2,561-11 T.OC T. 10 1.20 1.30 1.60 1.50 1.60 1.10 T.eo 1.90 2.29E-11 i.in-it 5l5ftt-l2 2.68C-12 1.21E-12 6.10E-1 J 2.6TE-U 1.3ftE-lJ 6.15E-I* l.ftOE-tft 2.14E-11 1.C5E-H 5.15E-12 2,ft 9E-12 1.19E-12 5.66E-1J 2.66E-1J l.2ftE-U 5.69E>lft 2.59*- 1ft 1.99E-U 9.81E-12 6.T9E-12 2.JTE-12 t.IIE-12 S.25E-1J 2.ftftE-l1 I.lftc-tJ 5.2ftE-lft 2.Jlc-lft i.iue-ii 9.UE-12 ft.fttE-IZ 2.15E-I2 1.03I E' -12 ft.BTE-lJ z.m.ti I.06E-13 ft.86E.lft 2.21E-1* 1.T6E-11 6.ME-12 4.15E-I2 2.O0E-12 9.55E-1J ft.52i:-13 Z.UE-13 9.JOE-1 ft ft,50E-tft 2.0ftE-lft l.ftlf-l 1 T.92F-12 3.86E-12 1,86*-12 5.87F-13 ft.19*- I ) 1.9SF-1J 9,0T.|6 ft.ltt-tft 1.89*.tft l.SOE-ll T.38E-12 J.59E-12 l.TJE-12 8.23E-13 3.BPE-13 t.eiE-13 a.39E-ift J.8ftE-lft t.Tfte-16 l.ftOE-U 9ft. TE-1 2 3.36E-12 1.tot-12 T.6ftE-13 3.60E-13 t.ft3e-13 7,TT-1ft J.55E-U 1.61E-1* 1.30E-11 ft.39E-12 3.101-12 Uft9c-12 T.OtE-13 3.3'.*. 13 l.5*C-lJ T.loE-lft 3.2ftElft .6i*-lft 1.22E-11 5.951-12 2,511-12 1.U1-12 6.5E-13 3.09E-13 1,6'.*-IJ t.ftJE-lft 3.0ftE-16 1.37E-16 8.00 8.1C 8.20 8. JO 8.60 1.2TE-16 5.66E-15 2.5U-15 l.lftE-lJ 6.TIE-16 1.1TF-1* 5.22E-15 2.31E-15 1.01E-15 *.38E-lft 1.06E-1 ft ft.BtE-15 2.1 IE-15 9.JCE-lft ft,DTE -16 9.96E-15 ft.ftftE-IS I.9&E-1S K.56E-I6 J.TOE-16 9.19E-15 ft,o*>E-l5 l.POE-15 T.8T-lft S.ftCE-lft 8 .ft8. 15 3.T7*-li l.ft6*-15 1.2ft*-l6 3.1JE-I6 T.82E-15 >.*8E-15 1.53E-15 6.66E-16 2,8T-16 7.22E-15 5.20E-15 1.ft IE- 15 6.13E-16 2.ftftE-16 ft.46E.13 2.99E-15 1.30E-13 5.4ftE-lS 2.63E-16 6.161-15 2.T2E-V5 1.17E-15 5.1GC-16 2.23E-16 8.50 8.60 8. T i 8.80 8.90 1.05t-16 I.Tlt-lT J.ATt-l l.iTc-H 6.ME-18 1.88*-lft / ,99*-lT J.36C-H l.ftOE-lT 5.TTF-IB 1. T>E-lft T.J3E-1T J.0*l-1T 1.28E-11 5.26E-16 1.59E-16 ft.TTE-iT Z.82E-1T 1.1 TE-1T ft 6 )E-1 8 1 .ftftE-16 ft.lTE-11 2.59E-1T 1.3TE-1T ft.ftlE-18 1 .JftE-lft S.A5'-1T 2.3 T* -1 T 9.8J*-:8 ft.o-f-19 1.23E-16 5.191-17 2.1TE-1T 9.00E-18 J.69E-18 1.I3E-16 ft.TS*-l7 1.79E-IT 8.23E-18 3.3TE-I8 1.03E-16 ft.SbE-11 1.B2E.1T T.53E-18 J.OdE-lS 9.69E-11 ft.OOE-11 1.67E-11 6,F*1-18 2.6.3E-18 Mto 9*00 2.5JE-18 2,16*-18 2.15E-I6 1.9TE.18 1 .JOE-18 1.6ftf - t 9 1.50E-18 t.JTf-18 1.25E-18 l.lftE-18 ooo o 9.10 9.20 9. JO 9.60 1.06E-18 6.18E-19 l.fcftt-19 6.59E-20 9.52E-19 J.81E-19 l.ME-19 4.92E-20 8.69c-19 J.ftTE-19 l.JTE-19 5.3-20 >.93-t9 S.1TE-19 1.25E-19 ft90E-20 T. 2ft-19 2.JOE-19 l.lftE-19 ft.ftftE-20 6.61*- 11 2.63f - l ) l.Oftf-19 ft.Ob*- 2J 6.03E-19 2.ftOE- 19 9,ft6-20 3.69E-30 5.50E-19 2.19E-I9 8.61E-20 3.3i-20 5.02E-19 t.9c*-19 J.06E-20 ft,5'E-19 I.C2E-19 1.1ft1-20 2,791-20 to oa 9.50 2.53E-20 2,JOE-20 I.09*-20 I.90E-20 l.TIC-20 i.5T*-;j 1.ft3;-20 1.30E-20 1.16E-20 1.07E-20 9.60 9.T7E-21 6,8JE-*1 B.OTE-21 T.29E-21 6.52 F. - 21 ft.01;-2 L s.ftAE-ri *.`?5F-2! ft.50*-2l ft.03E-2l to 9.TO J.ne-21 3.56E-21 3.05c-2t Z.77E-21 2.51E-21 2.26-'-n 2.0TE-21 1.!1TE~21 1.7CC-21 i ,5 9.80 9.90 1 .ft^E-21 J.271-22 ,1.2TE-21 ft 7 If -22 1.ISE-ZI ft.26-22 I.OftE-2l 3.8BE-22 v.ft3E-22 J.51E-22 8.55*-22 3.1 S * -3 T.T5E-22 2.BPE-22 T,c;r-22 2.50E-22 6.3(1-22 2.36C-22 5.76E-22 2.151-32 t. CONVERSION FACTORS ENGLISH TO METRIC UNITS Q'jsr.vi ty Eng 11sh Unit X Conversion Factor * Metric Unit Stack Height Stcck Velocity Grsv11y Vo lure Emission Wind sptrd Ambient Temperature Absolute Temperature Atmosphere Pressure Weight Rate of Pollutant Emission Concentration by Volume (0 deg C, 1000 mb) ft ft/S3C ft/sac2 ftVr.sc mp u knots dog F deg F In Hg lb Ib/hr ppm 0.3048 0.3048 0.3048 2,832 x I0'2 0.4470 0.5148 5/9 (deg F -32) 5/9 (ccg F -32) <273 25.4005 453.6 0.126 Molecular Weight 22,4 m m/sec <n/sec2 mVsec m/sec rn/soc deg C deg A urn Hg gm gm/soc mg/m^ LACC-AFAOE-Rev. 1/20/73 UA AS I 0005876 LOUISIANA STATE AIR CONTROL cu P. 0. P 6C530, NEW ORLEANS, LA. 70160 .icphone: (504) 527-5119 EMISSION' INVENTORY OUESTIONAIRE (Revision of 5/1/741 PAGE 1 OF 9 /Hied Chemicol Corporation (name of company) Industrial ChemicaW Division (parent company; if .above is a division) Submitted by company on July P. 1974 (date) This inventory includes emissions: a presently existing IS both presently existing and that fircpcsed additional emissions to be existing by 4th Quarter 1774. (date) File a separate report for each of your plants physically located in Louisiana. This inventory covers the following plant location: Baton Rouge North Works (name of plont in t<-;any usage) Baton RougeEast Baton Rouge (nearest town) (parish of plant site) INSTRUCT! C'IS- Answer alt questions. This inventory is requested under the. authority of the. Louisiana Ah Control law, Act 259 o{ 1964, ukidi gives to the Louisiana. Ait Conttol Ccmissixm ine pacer to develop such {acts and make such investigations as axe consistent with the purposes o{ this tew, [La, Revised Statues, Chap, 12, Title 40, Section 2201 et sey.I J{ certain questions ate not applicable, please indicate "none" or "not applicable" {"not applicable'' may be abbreviated as N.A.). Emission data is best obtained by actual Stack test, but may also be obtained by material balance, by tJie use o{ "emission {actors [see Compilation o{ Ait Pollution Emission factors, E.P.A. publication No. AP-42), ot by the use o{ pacers hid industry acta. The ccmpanyis responsible {or. the accuracy o{ the intg given. This data ray be checked on-site by state ot {ederat agencies. The giving c{ knowingly {else in{orration may subject the givers to penalties provided by law. Terms such as "nil", "trace", "negligible", "not signi{icant", etc., are not accept able. However, "less than xxx pounds per hour", ot a similar statement, will be satis factory [may be abbreviated as "<xx*/hr"). Please attach additional sheets i{ mote space is needed. An updated report should be submitted in the {utute token any one pollutant [e.g., total SOtotal CO, etc. ) changes mote than 10% {torn repotted values. ITEM 1 . . . ORGANIZATION ACTIVITIES A. This facility usually operates ^ days per week. This facility is not in operation on N.A. (days of the week not normally operating) B. This facility, as a whole, typically operates 365 days per year. (365 minus typical downtime and maintenance turnaround) C. Feak production season is Varies, not consistent , (name months) D. Shifts normally operated are as follows: 7am to 3pm D 3pm to 11pm 11pm to 7am D 8am to 4pa Jj 4pm to 12nidnight Q midnight to 8am H other, specify 6 AM to 2 PM, 2 PM to 10 FM, TO PM to 6 AM . Approximate number of employees at this location is 950 AS I 0005S77 AIR CONTROL COMMISSION EMISSION INVENTORY QUESTICNATr r.______________________________________ _____________________ PAGE 2 OF Q F. If the facility, as a whole, operates intermittently, give details on lines below: Tn.A. " ----------- G. Ownership of facility. Please check SKttaof the following:.where applicable: a corporation, partnership, or sole proprietorship P utility city goverrfnent state government O federal government S3 other, specify Industrial Development Board of the Parish nf efik. Inc.____________ H. Please check off the descriptive name that applies to your operation: S chemical aluminum ore reduction asphalt roofing Dpaint & varnish ferroalloy production asphaltic concrete feed & grain iron & steel mills bricks Dfertilizers aluminum production cement Dfish meal D gray iron foundry concrete batching sugar cane steel foundry pulp & paper coffee roasting P zinc processes lumber or pnrticli V'ar'1 Qother, specify_ I. Please give a very brief description of your operations, with emphasis on any possible sources of air pollution. Inorganic: Products are soda ash, caustic and chlorine. The raw materials are limestone, salt and coke. Emissions of particulates and smoke are associated with burning of limestone to produce soda ash which is powdery and subject to being emitted when handled Ammonia use and recover'/ is subject to being emitted, Electrolysis or brine produces caustic, chlorine and hydrogen wnicb are subject to peinq emitted. Organics: Chlorination of ethylene produces etnylene dichioride (tPC), Lrockmg or tiOC produces vmyl chloride monomer (VOvA). Vhese operations are subject to emissions. ITEM 2 . . . FUEL USE BY FACILITY AS A WHOLE Give figures for presently existing conditions, or, if this form is being submitted in conjunction with an Application for Approval of Emissions for a proposed change, for the proposed consumption. Basis 1973 consumptions ad- Consumption Rate lusted for substituting oJJ for td (give usual units) Sulfur Content (% by weight) Heat Content BTU 's per (specify units) A. Natural eas B. Process c-as _U.239.2S9. M CuFt 1 ,402,71 ; M Cut O.OJ37 Less than above 1.363 . Cu.Ft.(6),'rS-.?0" C. No. 1 to A fuel oil 41-, ,1 ,0 ) J qols. 0.7 max. 18,503-- Lb. D. No. 5 or 6 fuel oil N.A. E. Bark/ wood chios F. Coal (specify ash N.A. content and whether anthracite _or bituminous) G. Other (specify below) Diesel: 95.961 aals. Gasoline: 40,1 0) qal. 0.18 0.016 18.830 19,100 Lb. Lb L.P. gas: 3,152 gals. 0.073 19,500 Lb. B. If a *'fuel" is also used, in whole or part, as a "raw material" (i.e., is incorporated into the intermediate or final products), please give detaila below:________ __________ _ Limestone, mixed with approximately 8% coke is burned in the vertical shaft kilns. The CO? derived from both the decomposition of the stone and the burning of the coke is used in the sodo osh process^. ASI 00005878 ff; SSION INVENTORY QUESTIONNAIRE STATE OF LOUISIANA xR CONTROL COMMISSION TM 3 . . . MATERIALS USED, PRODUCED, STORED, OR TRANSPORTED Raw materials used at this facility: Name of material Amount How stored (use units mentioned (Be specific - e.g. in regulations, if floating roof tank, * apollcable) fixed roof tank, etc.) firp ne ;t PAGE 3 OF Q How moved (Pipeline, tank truck, etc.) .. Intermediate Products: See next page 2. Products: See next Pase ..... _ ITEM 4 EMISSION INFORMATION ON THE ENTIRE PLANT AS A WHOLE The Tates given here should correspond to the sum of the individual rates of the point sources listed in the Item 5 columns, for each individual type of air pollutant. A. PARTICULATE SOLIDS OR LIOUIDS l. Carbonaceous 2. Mineral (soecifv) 3. Organic (soecifv) . 4. Asbestos ^articles 5. Other (soecifv) Material Name Emission Rate Emission Rate (if reauested) (Lbs./hour) (Short tons/Yr.) Soot coke smoke - - NaCI. NaoCCh. CaC<3 )o MosMv fuaitis e - See Ad'da 1 oee Ad'da 1 See Ad'da 1 (In compliance) B. ORGANIC GASES OR VAPORS (If material belongs in multi sle classes, out in most reactive 1. Alkanes J. Alkenes/ Dienes (soecifv) 3. Alkvnes (scecifv) 4. Aromatics 5. Alcohols (specify) 6. Halogenated (specifv) 7. Other (sDecifv) 8. Other (soecifv) " See Ad'da 1 II II II II It II II See Ad'da 1 It II It II II II II See Ad'da ) ' II II II II It II II C. INORGANIC GASES OR VAPORS 1. Sulfur dioxide 2. Hydrogen sulfide 3. Carbon monoxide 4. Nitrogen oxides 5. A, , ., i 6. )>, ..... , , : (proposed oil burn.) See Ad'da 1 2.679 -- rz 6A%9 --jh------------ - 293 n55 451 See Ad'da 1 5ee Ad'da 1 " 7, JVrcart." - !;- 'ulfides 8. Other (sr<*cttv) ASI 00005879 ITEM 3 A. Raw materials used at this facility: Name of material Vr. 1973 Amount 1) Sodium chloride 1,893,773 NT 2) Calcium carbonate 735,975 NT 3) Coke 64,768 NT 4) Anmonia (carrier catalyst) 5) Hydrogen sulphide(carrier inhibitor) 6) Ethylene 7) Solvesso 150 (solvent) 8) Chlorine (purchased) 5,263 NT 814 NT 98,157 NT 50,000 NT 3,770 NT How stored How moved Salt dome Limestone pile Coke pile Fixed roof storage tanks Fixed roof storage tanks Not stored Fixed roof storage tanks Rail cars Solution mining, pipeline Scoup, rail & belt Scoup, rail & belt -Rail & pipeline Rail & pipeline Pipeline Rail & pipeline Rail & pipeline B. Intermediate Products: 1) Sodium chloride, brine 2) Sodium bicarbonate 3) Chlorine 4) Ethylene dichloride 1,552,246 NT NaCl Fixed roof storage tanks 962,885 NT Soda floor piles 162,580 NT gas Not stored 127,593 NT Fixed roof storage tanks Pipeline Conveyors Pipeline Pipeline C. Products: 1) Sodium chloride 2) Sodium chloride, brine 3) Sodium carbonate 4) Sodium hydroxide 5) Chlorine 6) Ethylene dichloride 7) Vinyl chloride 77,390 NT Elevated storage bin 264,137 NT NaCl Fixed roof storage tanks 607,5351MT Storehouse 264,254 NT Fixed roof storage tanks 12,220 NT 100,660 NT High pressure storages Fixed roof storage tanks 136,170 NT High pressure storage vessels Conveyors & rail Pipeline Conveyors, rail & marine Pipeline, rail & marine Pipeline & rail Pipeline, rail & marine Pipeline & rail ASI 00005880 f 5SIGN INVENTORY QUESTIONA IRE STATE OF LOUISIANA rtIR CONTROL CO:MISSION PAGE 4 OF 9 ! 5 *. . . POINT SOURCE INFORMATION ON EACH POINT (STACK) FOR EACH POLLUTANT Foint Source Descriptive name of the source. Can Point Stack Gas Idcntificction Vicost use lagan's teams ii stack elevation diameter exit Number. Vitcse the name ccurmonhj used is not be above velocity use same rumben. 6oily descriptive^ sampled? grade on plot plan showing sconce 'one stack has more than one See note See note toe.ctions, and pollutant, i.e., SOp CO, etc., h page. 7 2, page 7 in anj hand on. allow Hus one stack the same meters compute*, done number 0^ lines as pollutants. )> per calculation i Yes No meters meters second l 1_ )2 Firire stack. Brine Wells Pre heater stac i. Brine Wells X . _15.2 0.15 - X 2.44 -Q.25 , -8.36 33 *1 heater stack, brine Wells ?< . 9.14 _ _ Q.81- 1.4 4 4 thru 5 heater stack, urine Wells X 1.52 . _0,3. ... . 1.7 5 6 thru 8 ^'3 heater stack. Brine Wells X .... 4^7.. 0.61 1.1 6 9 thru 10 ^4 heater stack. Brine We 1 Is X 1.52 0.25 1.22 7 ll ff5 heater stack. Brine Wells X 4.57 0.41 ... _ 0.91 6 12 ^6 heater stock. Brine Wells X 6.09 0.61 _ _ 1 .M _ 9 13 thru 25 Vertical lime kilns X . 0____ . -NLA. NLA. . 0 13 thru 25 1 26 Vertical lime kilns Ki ns dust col ector. North X0 X 29.9 -N. A. . N.A. 0,91 _ 1R.9 .2 27 KJ ns dust col ector. N. Central X 29.9 0.51 12.8 .3 28 Ki ns dust col ector, S.Central X 29.9 0.48 12.8 .4 2v Ki ns dust col ector. South X 29.9 0.25 - i? 3 j thru 34 Lime slak ers (V.LT) 16 35 thru 37 Lime spalls (MLT) X 32.0 _ 0 Jr5 X 15.2 0.30 - 35 thru 41 Soda column vents (LCL) X 54.0 0.41 3.92 38 thru 41 Soda column vents (LCLl X 54.0 0.41 . 3.92 . i? 42 thru 45 ?Q 46 thru 47 n21 48 thru 51 52 thru 55 2? 56- thru 8l 2* 58 thru 8l 62 Vacuum engine vents (LV FLR) Ammonia absorbers (LAB) L!a ht soda ash dryers Bap dust collector (S.A.) Steam turbine power house Ste am turbine power house Old Power House X 37,2 X 8.5 X 51.8 X 51.8 X 24.4 X 24.4 X 24.4 0.41 0.15 2.13 0.30 2.13 2.13 2,13 3.48 2.26 1.44 - 5.96 5.96 4.36 25 27 28 _2_ 30 31 -2234 88 thru 68 67 66'by 73 /711 73 74 Gas turbine power house Baq dust collector, P&L, N, Sag dust collector, Buell classifier oog dust collector, r&L South Bag dust collector, rotary class. Bag dust collector, house system Bag vacuum ci eaner Dense Ash scrubber (KGS) Dense Ash scrubber (Ducon) X 10.1 2.74 X 27.4 0.61 X 0.71 X " 2829 0.46 X X X ""2fr7y.7-"--m-- 0.46 rf0r.4s6 X 27.T 0.71 X 32.0 0.91 5.33 ** - _ 35 "75 thru 93 36 v4 37 95 South chlorine , hvdroaen vents * Sou th salt scru bber, conveyor North salt scrubber, dryer X X X 7.62 15.85 18.29 0.07 0.33 0.45 2.33 -- - 38 "96-98 39 "99 40 1 JO 41 101 North chiorine, hydrogen vents No rth chlorine, mastic pots North chlorine, lead furnace North chlorine, tinninq furnace X -AL- T32 North chlorine, acid diD 1-- &443- 1 __ 103 thru 114 LL5__________________ Vinyl VJbyl cracking furnaces _c hi oxide (YCM) process1_ 45 116 Neutralization pond bypass X 12.19 0.91 X 9.14 0.33 9.14 0.76 X 9.14 9l4-X --------]fj4X 0.25 0.46 0V.5v1 , X ---80,35 ,0,41 x 7.62 0.15 N.A. N.A. 24.9 - N.A. 4 7_d3 . 32.3 1 1 . ASI 00005881 EMISSION INVENTORY QUESTIONAIRl STATE OF LOUISIANA AIR CONTROL CCMMISSSION PAGE 5 OF 9 ^Line Stack Stack This Point's r ----- Air Concentration Maximum Method of Yearly j kNo. 1| volume Temp. operating Contaminant in exit gases. actual determining emissior flow times (typical) Fo-t vzpou' on. continuous emission rate rate C Name or S&iti, emission rate Actual cubic meters houps days weeks symbol per' per per day week year UJliti Oi pGAti rate ptn rrJJJJjon by vo&vr.t to tiny oJji. Ton grams Sec noit 3 on pcuje 7 Short tons per year per ioticLj uit per se*cond nUZZigncm pcn second cubic. v.tXtn. * * 1- 36-56 2 0.41.... 2 Q4 - 3 <L4L_ 204 - 4 04 204 - 5 0.96 93 24 6 J.U i 04 - 7 0 M e V3 24 8 U.4b 93" 24 - - - 7 - 7 7 - Smoke - \Jone None - Mone 52 ^one - None 52 None 52 None - - - - Visual - Visual Visual Visual - - Visual Visual - - Visual - - Visual - 9 NA NA 24 7 52 CO 5.997 36.6 2 &4 1 ,273 10 NA NA 24 7 52 Particulates - -- - 11 12.46 22 24 7 52 Particulates 1.881 23.43 1 813 12 2.63 21 24 7 52 Farticulates 6.067 15.9 1 55 13 2.38 21 14 - - 24 7 24 7 52 Particulates 465 52 . articulates - 1 .1 1 -- 38 - 15 - - 24 7 52 (mostly wate vapor) - - 16 - .. 24 7 52 (mostly wate vapor) - - - "i 1118 2.07 2.07 21 21 24 7 24 7 52 CO 52" Nhh 11.061 1 .657 107.9 9.8 2 &4 2 S. 4 3,750 341 19 1 .84 26.1 24 7 52 NH3 600 3.0 2 & 4 103 20 0.C8 21 .1 24 21 20.53 46Q 24 22 - 24 7 7 7 52 Nhh 52 None 3.000 - 52 (no visible e nission) 0.2 .......... - 2 &4 Visual Visual 7 - - 23 127.23 149 24 7 52 SO? 330 77 2 &4 2679 24 127.23 149 25 15.51 149 26 125.55 204 27 - 28 - - 29 - - 30 - - 24 24 24 24 0 24 24 7 7 7 7 0 7 7 52 Particulates 13 52 None - 52 None -- 52 (no visible e missions) 0 (not in use) 52 (no visible e Missions) 52 (no visible e: Missions) 1 .65 NA - - - _ 2&4 2 &4 2 &4 Visual Visual Visual Visual 57 - 31 - - 24 7 52 (no visible e missions) - Visual - 32 33 - - 7 52 (no visible ei missions) - 24 7 52 (no visible ei nfssions) - Visual Visual - 34 - - 24 7 52 (no visible e Missions) - Visual - 35 0.17 43 24 7 36 24 7 37 24 7 52 Hydroaen 52 NaCI 52 NaCI 950.000 - - 16.4 * - 2 &4 -^ 570 - 38 NA NA 0 0 0 (emerqency i tse only) TO Visual NA 39 NA NA 0 0 0 (not in use) NA Visual NA 40 11.33 427 16 41 NA NA 0 7 6 52 rb 0.6 0 (not in use) - "OT----------- 1 TO------------ TO 0.24 " NA 42 "TO "TTA e 0 43 18.7 427 24 7 44 --4.16... J37 24 ' 7 45 - 0 (not in use) 52 None 52 All cases 5ee Ad'da 1 (Emergency use only) TO TO----------- NA ** - Visual - See Ad'dal th---------- See AcTdd N7C TS7T Represents total emission for all stacks in group. ASI 00005882 ? ` 3I0r: INVENTORY QUESTION IRE STATE OF LOUISIANA !R CONTROL COMMISSION PAGE 6 OF 9 5 .* . . POINT SOURCE INFORMATION, CONTINUED: Percent of Annual If this source (stack) Air Pollution Control Estimated Throughput is from a fuel-burning Equipment Control (to total 100%) heater or boiler, give Identification ' Efficiency the maximum duty rating Code in million BTU per hour Percent by Dac Mar June Sept of such heater or See note. 4, page 7 weight of Jan Apr July Oct boiler uncontrolled Feb Kay Aug Nov emission removed. % 7. 7. 7. See no-te 5, page. 7. 1 25 25 25 25 1 2_ - - - 1 2- - - - 1 ---- I 5 25 25 25 25 1 6- *- 1 7 25 25 25 25 1 8- - - - 1 9 25 25 25 25 1 .0 25 25 25 r25" .1 25 25 25 25 12 "23" 25 23 23 ' 13 25 25 25 25 14 25 "23H 25 25 15 25 25 25 25 16 25 25 25 25 NA 3.5 o 2.0 8.0 1.0 1 .0 4.0 NA NA nA nA NA NA RA NA . ._ 000 NA NA NA NA NA NA NA 000 _____ 000 008 008 008 008 NA NA NA NA NA NA . - NA ... r_____ NA___ . NA . _____ 0 0 about 10% About 70% about 70% about 70% NA NA 25 25 25 25 25 25 25 25 19 25 25 25 25 20 25 25 25 25 21 25 25. 25 25 NA NA NA NA 300 ______ ___________ 000 ooo........... . 000 000 _____ .. NA 0. 0_ . 0. _ 0 ........... NA . 22 25 25 25 25 23 25 25 25 25 ' 24 25 25 25 25 25 25 25 25 25 26 25 25 25 25 27 25 25 25 25 28 NA NA NA NA 29 25 25 25 25 30 25 25 25 25 31 T5~ 25 25 25 32 25 25 25 "23" 33 25 25 25 25 34 25 25 25 25 35 25 25 25 25 36 25 25 25 25 37 25 25 25 25 38 NA " NA ~n7T "ntt 39 NA TTa" NA NA 40 25 25 25 25 41 NA NA NA NA 42 NA NA NA' NA 25 _25_. 25 25 _2_ 25 _15_ 25 45 25 25 25 25 NA 820 820 128 813 NA NA NA NA NA NA NA NA RA ra 2786 NA NA 0.11 nA NA 74.0" NA NA 017 NA 000 0 000 0 NA 0 000 0 017 about 99% 017 about 99% 017 about 99% 017 about 99% 017 about 99% 017 about 99% 002 about 95% 6o2 about 95% 000 0 002 002 021 100% NA NA 000 0 NA NA NA NA NA NA 000 0 ____ 000 0 "Represents total for all stacks in group. ASI 00005883 1IS9IOH INVENTORY QUESTIONAIRE STATE OF LOUISIANA AIR CONTROL CONCUSSIONPAGE 7 or o ~ES TO ITEM 5: . If there is no clear-cut point of emission, no stack height (e.g., burning dumps, ultiple leaking valves, dust from moving equipment, etc.)* put zero in this column i . For non-round exits,, use the equivalent diameter, equal to 1.128 times the square oot of the cross-sectional area at the point of discharge. Enter the number of the method used, as follows: (1) By actual stack test (4) By making a conservative estimate based (2) By material balance on engineering analysis (3) By use of E.F.A. emission factors (5) By use of industry emission factors other than those supplied by the E.F.A. 4. Enter the proper code number, taken from the list below: 000 No control equipment on this source 002 Wet scrubber 028 Eliminate fuel oil combustion 005 Gravity collector 029 Change all fuel use to natural gas 008 Centrifugal collector 039 Catalytic Oxidation - Flue gas desulfur Oil Electrostatic precipitator ization 013 Gas scrubber 041 Dry limestone injection 014 Mist eliminator 042 Wet limestone injection 017 Fabric filter 045 Sulfur recovery plant use 019 Catalytic afterburner `046 Reduced emissions by changing process 021 Direct flame afterburner Only contncl devices that Ktdu.Lt tht ur.Lontxclled emissions normally associated taith the Spedic paottss should be KtpoKttd. Vo not Ktpoxi equipment that is a novnal pant o tht soutet activity even though tht quantity o pollutants emitted may be ntduttd. Fon example, a Kecaveay umeat is a nc-xmal pant dtf a knat pulp mill and should not be neponted as pollutant control equipment. 5. Assume that the pollutant load entering the control equipment is the normal, un controlled quantity for that specific process. If removal efficiency for a particular pollutant is unknown, leave the space blank; if there is no effective removal, then enter a zero in the column. ITEM 6 . . . PLANT LOCATION FOR AIR QUALITY MODELING Please provide below the Universal Transverse Mercator zone number and coordinates of your plant, to the nearest one-tenth kilometer. The zone number is 15 for .all locations except the extreme Eastern-most areas of Louisiana, the zone 15/zone 16 dividing line runs north-south about through New Orleans, The UTM coordinates can be und on U. S. Geological Survey maps, .scale 1:24,000, for your area. Zone No. 15______ Horizontal coordinate 3029'47" Vertical coordinate 91 0H'2I" Uffl.3--'- - *. COMPLjffi,CE STATUS Q0es y0ur facility have an approved "Compliance Schedule" on file with the Louisiana Air Control Commission? BTes, ONo, If yes, state whether not all actions listed in the schedule, if any, have been completed. OHave been com pleted, or no action was required. OHaa not been completed yet, but the timetable of increments of progress on schedule to date. fiHas not been completed yet, and unavoidabl elrcunstanccs havt- forced us to fall behind on the ti::..: able as * v ' ASI 00005884 JJ.ili.lj Vi bUU Ai, EMISSION* INVENTORY OOCSTIONAIRE AIR C0?.TR0L CCTJ'.lSSlON PAGE 8 OF o IT Pi 8 . . . REFUSE COLLECTIO:! fiNO DISPOSAL A. Amount of combustible refuse disposed of per year:365 N/T.______________________ ___________ (give the applicable units) . Description of refuse; check off applicable categories: B Paper scrap DRubber scrap B Wood scraps & sawdust Wet garbage or animal wastes B Other, specify; Asbestos ond general plant rubbish C. Method of refuse disposal; check off applicable catagories: City pickup On-site dump DOn-site incineration Contractor pickup DOn-site outdoor burning BOn-site landfill Other, specify:________________________________________________________________ ___________ D. If disposal is by contractor pickup, give the name and address of the contractor below: N A,___________________________________________________________________________ E. The on-site incinerator, if any, has the following design features: N.A, No on-site 1.-.* :..crat. r Afterburners Water scrubber installed Single chamber Primary & secondary Waste material is disposed of Multible chamber burners installed by being burned in a boiler F. Incinerator equipment data (if applicable): Manufacturer:N.A._________________ ',___________________________________________________________________ ____ Mode 1:_______________________________________ _ Capacity:___N .A._____________________________________ Years in operation: ITEM 9 . . . SUPPLEMENTARY INFORMATION *A. Approximately how much money have you spent on air pollution control equipment and operation in the past 10 years? Equipment $ 1 ,300,000 Operation $ 1,800,000 B. Please supply a unit plot plan or map which shows the locations of stacks or other emission point sources, together with the source identification numbers from Item 5, the plant boundaries, a distance scale, and the direction North. Please also show, on a separate diagram If necessary, the location of the plant in relation to nearest highways, r sidential areas, and towns. ATTACH THE PLOT PLANS, MAPS, OR DIAGRAMS TO THIS QUESTI0NAIRE. ITEM 10 . . . TOXIC GASES/HAZARDOUS MATERIALS A. Are there any substances used or produced in your facility which could cause im mediate injury to life or property, _if they were emitted to the atmosphere, which ate not already listed in this form as one of those which is presently being emitted to the atmosphere? (e-g.. Chlorine held for use in purifying cooling water, toxic gases gases used as catalysts, etc., which ordinarily do not escape) Please list any such substances below. If none, please so state.. Chlorine, anhydrous NHt, anhydrous HCI, vinyl chloride monomer____________________ ___ _ B. Does your facility use or produce asbestos, mercury (other than laboratory use), or beryllium in any amount *..*. -ocver? If di.swtr is yes, give dc;*ils tel.- - > ** sheet. If answer Is no, oirisi* write "No" below: Yes, we use asbestos to produce cell diaphragms. ASI 00005885 ! An on jn TCOY CUE ST I OKA IRE "TATE OF LOUISIANA . COirTRCL CO.'niSSION PACE 9 OF 0 *4 n . . personal and certification ? The manager of the facility, at the location covered by this questionaire, is as ows: ;le: r.e of Company: :iness street address/ P.O, Box: ty or town, Parish, Zip code: siness area code/ telephone No.: Poul B, Cornell___________ `__________________ Plont Manager_________________________________ Allied Chemical Corp., Industrial faem?cnU Div P.O. Pox 271____________________________________ y^s_ Baton Rouge. East Baton Rouge Parish f. 70821 356-3341_________________________________________ Rouae Person to contact at the site of the facility about air pollution control, if fferent from the above: ime: itlc: Jslncss telephone No./ extenalon: _______________________________________________ ________________________________________________________ _ _________________________________________ . If the company's air pollution control correspondence and documents are prepared at company headquarters office, at a different site, give the information on the person o be contacted below: Name: Title: Firm: (if prepared by a consultant) Company: (if prepared in-house) Firm or Company street address: City, Parish or County, Zip code: Area code/ telephone number: Fronk P, Turk_______ SupVrvi'sor-Environmentflj Control 'N .A', Tame" Tame Same" Tam* E. CERTIFICATION. I CERTIFY THAT THE INFORMATION PROVIDED ON THIS SUSMITTAl (INCLUDING ATTACHMENTS) IS CORRECT AND COMPLETE TO THE BEST OF MY KNOWLEDGE. Handwri,ten.signatuTte of managed, or other official F. B. Cornell, Plant Manager________ Printed or typed name of official above & title July 8, 197 4__________________________ _____ ____________ Date AS I 0005886 ADDENDA 1 ITEM 'O, STACK 13 5 NAME OF CONTAMINANT CONCENTRATION nnm Vinyl Chloride (C2H4C1) Ethyl Chloride (CjH^Cl) Chloroprene (C^H^Cl) CC14/1-1 EDC(*85% CC14) Benzene (cgHg) Triene (CjHClj) Chloroform (CMCl^) 1-2 EDC (C2H4C1) Ethylene (C2H4) Carbon Monoxide (CO) Solvesso 150 (90% C^g-Cj^) 400 800 900 1900 100 - 1500 7700 8500 8800 - ,,S1I5SIQM-PATE--------------------- GRAMS/SEC SHORT TONS/YR. 3.8 8.4 13.2 43.7 1.5 0.3 28.4 123.7 38.2 40.5 1.3 131.4 293.5 459.9 1519.9 52.6 8.8 985.5 4301.2 1327.1 1406.0 43.8 Totals 303 10529.7 ASX 0000588?