Document b5EmrmY9o0JnB2xr9mdVRy5J3
DISTRIBUTION
COPY NUMBER
1-3 M. Townsend 4 F. E. Kearney 5-7 T. Bistline 8 R, Noble 9 G. Thomas 10 R. F. Ivory 11 Central Files 12 Technical Reports Library
1670 E3NA E2ND 1250 1250 1250 1250 R2C
ABSTRACT ONLY
NOTE:
Distribution of this report is restricted. Requests for additional copies should be made through the principal contact at the Monsanto location involved or the Manager, Environmental Sciences Center, Dayton Laboratory, Dayton, Ohio.
ACKNOWLEDGEMENT
Contributions of the following Dayton Laboratory personnel to this project are gratefully acknowledged:
Analyses: G. Thomas G. Pitts
CO M PAN Y CONFIDENTIAL
C11276
DOCUMENT CONTENTS
Cover S h e e r ......................................................... Document Contents ................................................... Report .............................................................. Document Inventory ................................. . . . . . . . . Sample Receipt Forms ............................................... Chain of Custody F o r m s .......... ; ................................. Analysis Request Forms ............ . . . . . . ............ . . . Monsanto Notebook Pages For:
a. Extraction/Preparation ................................... b. Analysis/Data Reduction . . . . . . . . ................... Instrument Logbook Pages ........................................... Computer Output and Chromatograms ................................... Additional Documentation . . . . . . ...............................
Page 1 3 4
11 12 13 15
16 17 20 23 139
SUBJECT TO PROTECTIVE ORDER
0U CC3
C11277
All samples had 50 uL of dodecane keeper added to them and then they were concentrated under a gentle stream of nitrogen and submitted for GC/MS analysis. The GC/MS analyses were conducted on a Hewlett/ Packard 5987 GC/HS Instrument. The analysis was conducted using a 60 m SP2330 capillary column. The mass spectrometer was operated In the selected Ion monitoring mode analyzing for ions character 1st1c of both the native (unlabeled) 2,3,7,8-TCDO (m/z 257, 320, 322), chlorlne-37 labeled 2,3,7,8-TCDD (m/z 328) and carbon-13 labeled 2,3,7,8-TCDO (m/z 332, 334).
STANDARDS
Standard solutions were prepared from standards that had been cross validated with a standard provided as a check sample by the EPA. Concentration of the Internal standards conformed to the levels specified by the method.
RESULTS
The results of the analyses of the samples are given In table 1, The tables also give all pertinent QA/QC information. It should be noted that small amounts of sample may lead to erroneously high or low concentrations due to possible 1nhomogene1ty of the sampleJ
t
SUBJECT TO PROTECTIVE ORDER,
Ow rV-r - nW L^g
C11279
TCDD DATA REPORT HCNSANTO CCiPANY. DAYTON LABORATORY
TABLE la. SWEEPINGS
GC CQUMs SP2330
& WTTVE: i.OOORF SURROGATE: l,50
ETTR KTHD
ORAHS WET CLEAN u w t
SURR
PP8 ANALYTIC. 320 332 X TCDO D.L. DATE TINE 322 334 ACC
320
322 257 328+ 332 334 N
DOOR J OORH J
PEEN J lL J
J
RJ ;DOOR J *J 'AIN J FNER J O RF J
OER J JST CO J
,.l
BC 3.570 4.68 -- 9/7
BC 5.910 15.55 -- 9P
8C 1.700 1.99 -- 9/7
BC 2,010 3.87 -- 9/7
BC 4,580 ND
.11 9/7
BC - 6,030 BC 3.940 BC 2.800
NO 8.24
13.56
.08 9/7 -- 9/7
-- 9/7
BC 4.360 12,51 -- 9/7
BC C 8 1 0 _97.7*\ -- 9/7
BC 5 ? 8 2 0 ^ 7 2
9/7
BC 1.120 3.05 -- 9/7
BC 1.260 ND BC 5.000 ND
.29 9/7 .05 9/7
0503 .84 0523 ,76
0543 .81 0603 .80 0623 HH
0703 HH 0743 .75 0803 .69 0823 .73 0903 .67 0922 .73
0942 .80 1246 HH 1002 H H
.86 100. .74 84.
.87 105. .83 64. .74 63.
.67 103, ,76 110. .79 118.
.69 74,
.81 128. .72 84.
.69 65. .73 75. .84 90.
18882. 83727.
2709. 10577.
0,
0. 84155. 112218.
99006. 97684. 88864.
8451. 0. 0.
22496, 8719. 41604. 110660. 65853, 29751.
3358, 3246. 31486. 13269. 6672. 32783.
0, 0. 30429.
0. 0. 54167. 111929. 75663. 111576, 161839. 116064. 143014.
135442. 84807. 53068.
146866. 67821, 66480. 121024. 74700. 75374.
10520. 10379. 60689. 0. 0. 51944. Q. 0. 88063.
28586. 33353. 22426, 30462.
20803. 24016, 34763. 41898, 30539. 41192, l 31465. 46919. X 65192. 85792. 79736. 100672,
44015, 63417. 34523. 47703. 56049. 78200.
56861. 81910. 43098. 59336. X 66335. 78584. X
iED FOR CONTRIBUTION BY NATIVE TCDO (SUBTRACT .009 OF H/E 322) .
X: ISOTOPE RATIO CUT OF ACCEPTABLE RANGE Y: X ACUFACY aiT CF ACCEPTABLE RANGE
1 BLAWC
1 SCAN
YTE SIGHING AND WORKUP
:ate(interlab BUW<
L.IWWTTVE TCDD SPIKES ND=NCT DETECTED
DL=CTECTTON UNIT
I.
=TCDD94
C G r w '-
S U B JtC T TO FROTECIiVc. ORDER,
OGOC
C11280
t
TCDO DATA REPORT MCNSANTO Cn-PiWY, dayton LABORATORY
TABLE la. SWEEPINGS (Continued)
GC COUJW: SP2330
RE NATIVE: t.043
RF SURROGATE: .907
SA*LE N BER
EXTR KTTC)
----
--
BASE O F STAIRS J
CLEAN
----
BCD
CRAMS WET U O tfT
--
1.180
SURR
PPB ANALYTICAL 320 332 l
T e tro D.L. DATE TIME 322 334 ACC
11,82 - 9/10 0844 ,72 .84 131.
320 5514.
322 257 328+ 332 334 7429. 4749. 10773, 10345. 12251,
+ 'ERECTED FOR CONTRIBUTION BY NATIVE TCDO (SUBTRACT ,009 OF H/E 322)
WTE COOES:
r. ISOTOPE RATIO a n OF ACCEPTABLE RANGE
Y: I ACaRACY a T CF ACCEPTABLE RANGE
W=NETHTO BLANK
PARTIAL SCAN SEPARATE WEIGHING AND WORKUP tWIFU CATE(INTERLAB) f^-FIELD BLAMC
l*H=NATIVE TCDO SPIKES ND=NOT DETECTED DL=DE7ECTI0N LIMIT KIAR
F" P W =TCD096
SUBJECT TO PROTECTIVE ORDER.
0cG G 7
C11281
1
TCOO DATA REPORT WNSANTO COMPANY, DAYTON LABORATORY
TABLE Lb. WIPES
OC Cairti! SP2330
RF NATIVE: 1,000
RF SURROGATE: 1.480
SAWLE f (RFR
SURR
EXTR NG
ANALYTICAL 320 332 X
MTHO CLEAN TODD D.L. DATE TI> 322 334 ACC
320
322 257 328* -332 334 N
INSIDE N UALL
"TNSSTAOiER
1 SGER dryfw vac m >
AMi
1
KioH SPIKE
LOU SPIKE
J J J J J
J
J J
BC BO
BO BO BC
BO BC BC
ND
NO
ND NP NO
ND
18.15 6,54
.40 9/7 ,49 9/7
.42 9/7 .44 9/7 .52 9/7
.51 9/7
-- 9/7 -- 9/7
1022 H H 1304 H H 1326 H H 1344 H H 1404 H H 1451 H H
1511 ,72
1531 .82
,71 44. .74 72. .76 74. .72 73. .69 82,
.80 93,
.70 88.
83 103.
0, 0.
0,
0,
0. 0.
18911.
4954.
0. 0,
0.
0. 0.
0,
26432, 8507.
0,
0. 0.
0, 0,
0,
17323. 7487,
45008. 39647, 48299.
45483. 42785,
49443. 39735.
43942.
40353. 33584.
40191. 37149. 30583.
33924. 26615. 27661.
56919. X
45152. X 53067. X
51649. X
44U0. X 42314. X
38083.
33383.
CORRECTED FCR CONTRIBUTION BY NATIVE TCDD (SUBTRACT ,009 CF N/E 322)
H)TE CODES:
X: ISOTOPE RATIO OiJT OF ACCEPTABLE RANGE Y: l ACMWCY (XIT OF ACCEPTABLE RANGE
NB=NETWD BLAHi PARTIAL SCAN =SEPARATE UE1GHINT. AND URWF
[tOLFLICATE(INTERLAB) f^FIELO BLAW
L>M=NATIVE TCDD SPIKES ND=NOT DETECTED OL=OETECTION UNIT
=JAR
-"".ENAflE =TCDD95
<^L A ' - J .y.
^ 71 VL
SU3JECT TO PROTECTIVE ORDER
CGC3
C11282
TABLE 2. CALIBRATION SUMMARY
yg/Kg NATIVE TCDD
0.534 5.34 1.335 13.35 133.5 0.534 5.34 53.4 1.335
0.534 5.34 53.4 1.335 13.35 133.5
RRF (NATIVE)
-
1.117 -
0.917 0.920 1.000 1.045
-
1.145 1.012 1.061 0.999 0.993 1.045
DATE
9/7 9/7 9/7 9/7 9/7 9/7 9/7 9/7 9/7
9/10 9/10 9/11 9/11 9/10 9/10
TIME
0423 0443 0843 1042 1102 1205 1224 1429 1554
2144 2204 0005 0205 1527 1547
RRF SURROGATE
--
1.712
-
1.808 1.520
0.906 0.919 0.848 0.896 0.900
. 0.970
SUBJECT i
r)
i'/E O R D E R -
C11283
TABLE 3. QUALITY CONTROL SUMMARY
ITEM
SURROGATE ACCURACY
//DATA POINTS
23 4
MEAN S.D.
88.9 20.3 *
* Not technically correct to report recoveries for internal standard calculated results.
i iY lA L S U 3 J E C T O P R O ! ACTIVE ORDER.
-O .i.O
011284
DOCUMENTATION INVENTORY FORM
Monsanto Research Corporation Dayton Laboratory
I. Sample Information
Sample Identification: ^ I T R o Number of Samples: )(p
S
A n a l y t e O , 3 ^ 0 - T c 3 > "D
Matrix:
Vy/pfS
Method: j)rreR!VMfl.T)0^ o F 3 , V ; 3 - T C ) D // fc/i_
StsIME^
II. Documentation Control
Copies Attached Initials
(a) Sample Receipt Form (b) Internal Sample Tracking Form (c) Sample Tags (d) Airbill (Number ____________) (e) Chain of .Custody Form
y --_
-- --
y
<ST
<ST -T < r
(f) Analysis Request (Log Number /8/o9o43 /)
? t . _
(g) Extractlon/Preparatlon notebook pages (NBP) 2 7 3 A W 9
y (S r
(h) Analysis NBP
____________
Instrument Logbook pages 15&fa"7H ,75
/ <Sr _
y <5- r
Computer Data Files ______________ hard copy output
Chromatograms
y &T <St
(1) Data Reduction
nbp <;e /ivfovsijs a/8P___
(j) Final Report
j <$r <S-r
(k) Additional Documentation
<r _
(note lnmedlately upon acquisition)
,SrA^T>fK>S ? tf? rW ic ,/J / / B ?
File Complete i W
-'fj^elh
(sfgjna'ture)
-^ ,._i Vi. _,r.* j--*.'~j '4 3
OBJECT TO PROTECTIVE ORDER.
O L O t.i
n srrsi
(date)
C 1 1 2 R F>
Sample Receipt Form
Monsanto Research Corporation Dayton Laboratory
Customer Identification: tlrfRO____________________
MRC Log Number: 1 - 0l- 0 5 >n 1__________________
Airbill Number:
L . W C - Q v-k IaE?-__________
Date: H $g?r AS___________________________________
Sample Receipt Information:
( a ) Shipping Containers (b) Custody Seals
( 0 Chain of Custody Forms ( d ) Sample Tags (e) Sample Containers (f) Agreement of Sample
Documentation
C a n t a c i ) damaged (describe below) N o . J _
present Cahsin> (describe sealing below)
intact
^presenf^ absent
No. A .
iresen')1 absent
HO./la
(''intact damaged (describe below) No./,
C5D
no (describe discrepancies)
n
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x. St-
(ST
--
Additional Description (if sample numbers not listed on chain of custody form, list here and contact SMO).
^ W i t h Tnourff TFj fio fl?PtrfT T f f r f M S
^ H* 1*' PROTECTIVE ORDER* SUBJECT TO
/> y\ IKmnAA QJi'gnature)
0CCJL2
C11286
SA .- m IDtKTIFICAT ION LOG
HRC Job H a . ________________________
Customer Representative / v W
Contract No. ________________________ MRC Contract Manager ____ ___________________
Plant Name or Code
-M m *
Team L e a d e r _____________________________
Samni1ng Rur. Date Type of Sample i Analysis Location Number Sampled No. of Containers Required
Sample recovered 8y (Initials) and Conran
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3 -7 ^
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C11287
CHAIN OF UnrODY RECORD
fa ' fy s s s
1 2&8
HRC JOB HUMOUR ........................... ............ .
CUSTOMER REWU'SCNTAU VL K S . /V/Z/'j-
* CONTRACT NUMBER ________________________________________
W C CONTRACT MANAGER ____________________
PLANT NAME OR CODE y % K s v r ^
_________________
MRC TEAM LEADER _________________________
(Specific Information on samples 1s available on attached "Sample Identlflcatlon Log")
O
Signatures
Date
T Ime
Remarks
Team Leader Verification of Collected Samples:
Relinquished by:
Relinquished by: Logged-1n-by:
Received by:
Received by:tf a
*/*/&/ /2!oO e n ____________________________________
Y-:5o
.J O
Received for Analysis by:
____________ ________________ ^ ____________
Method of Shipment: U . r r i e r
Kumber of Containers: / C o o /V
- /6 v ' -------
Sp ed ai Instructions (Sample preservation, security, delivery to, etc.)
. l
\
t\ \f\t
t.'i
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t-f 1 i p
/S/S /fJ/c^Ais >6?
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____________________________________________
, VjJ
A y- **, o v y ^ y p y _____________________________________
I ; CO
------------------------ ^
A N A LY S IS REQUEST
It ISANTO RESEARCH CORPORATION REQUESTER**
DAYTON LABORATORY
tlffitn
VIPLE DESCRIPTION
NUMBER OF BOTTLES:
/
> charge no." VM
NUMBER OF SAMPLES ~ j^
*?
REPORT RESULTS T0` FILES
p SttF&AH
8 -t 9 X Y t / h W g r -fl w # / i > f A S r ' b o o Z
;-7 ? A ifi& Lt X "
V f t T t o Ttot W i c l'7 //V it F t>osr
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ANALYSIS REQUEST T
FILES
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3 - 7 ? Ai/DJLt s f c W T R Y
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RECORDED BY:
SAMPLES FOR:
THoW\<? SAMPLE LOCATION
a ,3 , 7 , ? - T C i b i .
KNOWN HEALTH HAZARD PRESENTED BY SAMPLE: REFERENCE TO PREVIOUS WORK (REQUEST#, JOURNAL,ETC. *
'COMPLETION DATE
TIMEALLOTED FOR ANALYSES
ANALYST
HOURS
INST. TIME
ANALYTICAL TECHNIQUE
GAS CHROMATOGRAPHY ULTRAVIOLET VISIBLE INFRARED EMISSION .* EDAXXRF MICROSCOPY OTHER -- ----
QUAL_____ SEMIQUANT.
NMRI HPLC XRD ICP ATOMIC ABSORPTION MASS SPEC
j^ g c /m s
D AUTO ANALYZER __ QUANT_____
REQUIRED QA/QC
^ v-' - - s ~ . ! j. i A L , S U B J E C T T O P ^ r 7 r-TTi\/r r o n c o
UH 2 8 9
t o o t m " w k E I CZI DISCARO RETURWJC G A 5*>LD FOR 30 DAYS f l 60 DAYS
07
MONSANTO COMPANY
S U B JE C T JO B NO.
f(ih / f y ' a l e i ! V& l- V211.7
N? 2273249
date
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Code No. i
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SUBJECT
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N C AO AMD U M O t M T O O D y
O L O jJ 3
C11290
DATE
MONSANTO COMPANY
N? 227;
1ES0 DOTI PWT
IWKTD CQPMA. Vn lOHT<pr
w KamCaUTnMtW*i K1i..W80n0
s*nE ETTS
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--
ns:cE Mj. J r .*0 t/T
mMSTop J K ,*1 1/7
max*
J K FP .*7 1/7
n m r vr. m J 1C .u 1/7
.** J c Ml .37 1/7
* J K Ml .31 1/7
t*IO*SPUE J K 11.13 -- 1/7
i v u t J K .3* -- in
UM 330 337 X TU 3S 33 320
3S 7Sf 370 333 33* N
IOS MM IX MM 13 MM 1*4 MM 1*0 MM tai MM 1511 ,73 1331 .3
,71 4. .7* 77. ,7 T*. .77 73. .1 7.
17, .70 a . .O 103.
0. 0. 0. 300. m 9Mlf. 1 0. 0. 0. 31?. 33BH. *9152. I 0. p. 0. TU. in . 33M7. 1 0. 0. 0. CHS. 371*1. 31*41. I 0. 0. 0. 7WB. xrm . *4110. 1 <L 0. o. *. 33171. Z1U. I itn i. 3n. (Tra. sirs. THIS. xnci. 15. men. 77. QHl. r**i. r r i .
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SUBJECT 'O P.OfEUlVE ORDER.
KMAQ ANO UM OKHITOOO V
000.\7
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MONSANTO COMPANY
N? 2273252
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SUBJECT
PROTECTIVE ORDER.
011293
OLG!
M CA D AMO U N O M I T O O O B r
ATE
Monsanto Rfsf.anoi Contonation HATTON l.AiiOBATOBT
Su b je c t JOfl NO..
Da t e ------------------------------------------ 1)______Read And Understood Oy Me
SlCHATURE --- --
---------------- DATE...................
IS
MRC-DA
N? I5r.67
IK>A3> i=Date
CC
Job Number
Het Time
Time of Day
CRN
7920 AR Disc
Pack
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C11297
File >B285 1 333.6-334.6 amu.2UI_ .1063/. 43/. 19
SP2330 200-1/3/250
BT
File >B 2 3 S 1 321 .6-322.6 amu.2UL .1063/,43/.19
SP2330 200-1/3/250
BT
'J""71. . 4J. I A-*
. -- . onA-rrrri'/E O R D ^
0C024
C11298
GC/MS default file: >B2851::01
MS data file header from : >B2851
Sample: 2UL .1868/.48/.19
Operator: GARY
Mise : SP2330 200-1/3/230
BTL#03 BTL#
Sys. #:
1 MS model: 37 SW/HW reu.: CA
Method file: SP2330
Tuning file: APEI01
Source temp.: 230 Analyzer temp.:
0
MS 9/07/84- 4:23 3 RLS 4 : 0
No. of e x t r a records: 2 T r a n s f e r line temp. : 0
C h r o m a t o g r a p h ic t em p e r a t u r e s : 50.
300.
0.
0.
0.
Chromatographi c times,i min. : 0.0 2.0 0.0 0.0 0.0
C h r o m a t o g r a p h i c rat e , d e g / m in : 2 0 . 0 0.0 0 . 0 0.0 0.0
M/Z a 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. f ir st
min.
sc an
max scan
1ast peak scan width
raw area
corr. area
corr. Ji
1 11.985 231 238 241 2 11.965 231 238 241
10 7 7 1 8 9 10 77 1 8 9
55769 32164
100.00 57. 67
M/Z = 331.9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
corr. area
corr.
1 11.965 196 238 232 2 11.965 196 238 232
86 212076 86 212076
39044 34135
100.00 S7.56
332/334 CALCULATION R-GlobalC 0) -
.7001
M/Z = 327.9
SUBJECT TO
First peak is b a s e l i n e d r o p c o r r e c t e d area, S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. fi rst min. scan
max sc an
Iast peak scan width
raw area
corr. area
1 11.985 234 239 252 2 11.985 234 239 252
18 77420 18 77420
40394 38612
M/Z = 321.9
F i r s t peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
1 2
R. T. min.
11.985 11.935
f irst scan
236 236
max scan
239 239
1ast peak scan width
244 8 244 8
raw area
31404 31404
corr. area
14244 12784
d 'J
corr. *
100.00 95.59
corr.
y.
100.00 89.75
0025
C11299
S M/Z =* 319.9
First peak is baise 1 ne d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
n
R.T. f irst
min.
sc an
max sc an
1ast peak sc an u idth
rau area
1 11,985 23 6 239 245 2 11.985 23 239 245
9 29683 9 29683
>Ba&5v-
co r r . area
11035 10288
co r r . *
100.00 93.23
320/322 CALCULATION R - G 1o b a l < 1) a
.7747
M/Z * 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. f irs t
min.
scan
max sc an
1ast peak scan width
raw area
1 1 2 . 0 0 5 2 3 7 2 4 0 24 8 11 3 6 9 3 0
2 12.005 237 240 248
11 3 6 9 3 0
corr. area
8869 8456
corr. *
100.00 95.34
<320 + 322) / <332 +334) CfiLCULflTION
R-Globai< 3) =
.2666
<328' )/<332 + 334) CfLCULRTION
R - G 1o b a l < 3) =
.4247
"7
SUBJECT TO D"?ri irtr.CTiYE ORDER.
0G026
C11300
File >B2852 333.6-334.6 amu.2UL. 1 .068/.48/. 19
SP2330 290-1/3/250
BT
File >B2S52 321.6-322.6 amu.2L 1 .968/.48/.19
SP2338 299-1/3/250
BT
0C0,7
Cl-1301
GC/MS default file: >B2852::01
MS data file header from : >B2852
Samp 1e: 2 U L 1 . 0 6 9 / . 4 8 / . 1 9
0perat o r : GARY
Misc ; SP2330 200-1/3/250
BTL#05 BTL#
Sys. #:
1 MS model: 87 S W / H U rev.: Cfl
Method file: SP2330
Tuning file: RPEI91
Source temp.: 250 Analyzer temp.: , 0
MS 9 / 0 7 / 3 4 - 4
5 ALS : 0
Mo. of e x t r a records: 2 Transfer line temp. : 0
43'
Chromatographic temperatures
50. 300.
0.
0.
0.
Chromatographic times, min.
0.0 2.0 0.0 0.0 0.0
20.0
:0.0
0.0
0.0
0.0
M/Z = 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak .
R. T. f irst
min.
sc an
max scan
1as.t peak sc an u idt h
raw area
corr. area
corr.
X
1 11.990 233 238 240 2 11.990 233 238 240
7 78765 7 78765
64562 40461
100.00 62.67
M/Z = 331.9
F irst peak is b a s e l i n e d r o p c o r r e c t ed area. S econd peak is t a ngent s k i m m e d c o r r e c t e d area.
Peak #
R. T. f irst
min.
sc an
max scan
1ast peak scan width
raw area
co r r . area
corr. *
1 11.990 202 233 277 2 11.990 202 238 277
75 ` 196550 75 196550
44750 35862
100.00 30. 14
332/334 CALCULATION R - G l o b a l < 0) -
.6931
M/Z = 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area, S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. fi rst
min.
scan
max scan
1ast peak sc an w idt h
rau area
1 11.990 232 233 251 2 11.990 232 238 251
19 8 9 0 8 7 19 8 9 0 8 7
M/Z = 321.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. f i r s t
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 12.010 233 239 251 2 12.010 233 239 251
18 198299 18 198299
00028
J'
corr. area
46052 459Q9
corr.
X
100.00 99.69
c or r . area
161525 156530
corr.
X
109.00 96.91
C11302
s
HsZ = 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak tt
R. T. first min. scan
max sc an
1ast peak sc an width
raw area
1 12.051 237 241 253 2 12.051 237 241 253
16 119567 16 119567
corr. area
83727 83623
corr. */.
100.00 99.88
320/322 CALCULATION R - G l o b a l < 1) =*
.7566
M/Z * 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area.
S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. first
min.
scan
max scan
1ast peak sc an w idth
raw area
1 12.051 237 241 248 2 12.051 237 241 248
11 1 1 1 2 3 9 11 1 1 1 2 3 9
corr. area
65853 65330
corr.
108.00 99.21
<320 + 322)/<332 +334) CALCULAT ION
R - G 1o b a l < 3) =
3.6754
<328")/<332 + 334) CALCULATION
R - G l o b a l < 3) =
.5625
'.?j i I A L
T TO PROTECTIVE CREER. '
00035
C1309
file >B2855 333.6-334.6 amu.2UL UT-2625
3P2330 200-1/3/250 RUN BT
File >B28S5 321.6-322.6 *mu.2UL UT-2625
SP2330 200-1/3/250 RUN BT
C11310
s
tl/Z = 319.9
First peak is baseline drop corrected area. Second peak is t angent sk imined corrected area.
Peak #
R.T. f irst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 12.050
239 : 241
242
3
9363
2 12.050 239 241 242 3 9363
corr. area
2709 2659
corr.
100.00 98. 15
320/322 CALCULATION R - G l o b a 1 < 1) =
.8067
M/Z = 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d corre c t e d area.
Peak #
R. T. f irst
min.
sc an
max scan
1ast peak scan width
raw area
1 12.050 240 241 242 2 9286 2 12.050 240 241 242 2 9286
corr, area
3246 3187
corr. *
100.00 98. 18
<320 + 322)/<332 +334) C A L C U L A T I O N
R-Global( 3) =
.1354
<328')/<332 + 334) CALCULATION
R - G l o b a l < 3) =
.7025
c
OG 028
fr\OTECTIVE ORDER,
C11312
GC/r
MS c
Simp Mise Sys.
Me Sou.
M/Z
Fir Sec oi
Peak #
1 2
M/Z a
F in
Sec or
Peak #
1
2
332/3
R-Glo
M/Z =
F irs Secon
Peak #
1 2 M/Z =
F ir s i Sec ont
Peak #
1 2
File >B2S56 333.6-334.6 amu.2UL UT-2626
SP2330 200-1/3/250 F
File >B2S56 321.6-322.6 amu.^UL UT-2626
SP2330 200-1/3/250
s
Pt/2 - 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak #
R. T. f i r s t
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 12. 1 3 2 241 24 5 2 52 11 3 3 7 4 3 2 12.1 3 2 241 245 . 252 11 3 3 7 4 3
cor r . are a
10577 9829
corr.
s *%
100.00 92.93
320^322 CALCULATI ON R - G l o b a K 1) =
.7971
M/Z * 257.0
F i r s t peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
Ri T. f irst
min.
scan
max scan
1ast peak scan width
raw area
1 12.152 243 246 251 2 12.152 243 246 251
8 33332 8 33332
corr. area
6672 6624
corr.
%
100.00 99.28
C320 + 3 2 2)/<332 +334) CLCULflTION
R - G l o b a K 3) =
.3111
<328 '>/<332 + 334) C A L C U L A T I O N
R - G l o b a K 3) =
.4276
C " --CT TO PSOiECTlVE ORDER.
0C041
C11315
amu.SUL UT-2627
SP2330 200-1/3/250 RUH
CD
01
iS m
CD CD OJ
O nq
CD CD
CD CD
01
CD
File >B2857 321.6-322.6 amu.SUL UT-2627
2P2330 200-1/3/250 RUN
G1316
Ua
GI' ti -to
.* CO CO
co
CCll
o co
co
TT-n
o G> CP
CJ
-IO
CJ
-* r^-
cj
- Cl
CJ
KI r>
- IO .Clli
<Dn
G>
-- G) ^ C .|
CO I IO CO
'o O'
*-l ^
co
- G>
G>
r-
IO
co
CmJ
CJ
IO C'I
o\>
I G*
Cl _
Ci
Ci
Cl.
h-
CJ
\0 Cl --3
Cl
eiDti
r*.
io
CJ
VO
IO CJ N
IO
CJ
co o-
00042 -
t-- cijri
n I
i 1i--1 i> f'
0.
o
VuI til
y ZL)O
GC/MS default file.* >B2857::01
MS data file header from : >B2857
Samples 2UL UT-2627
Operators GARY
MS
9/07/34
Mite : SP2330 200-1/3/230 RUN BLT#15 BTL#15
Sys. #:
1 MS m o d e l s 87 S W / H U reu.s Cfl A LS # : 0
Method files SP2330
Tuning file: APEI01 No. of e x t r a records: 2
Sourc e t e m p .: 2 5 0 A n a l y z e r temp.i:
0
Transfer line temp. :
6:
Chromt ographi c t e m p e r a t u r e s : 50.
300.
0.
0.
0.
Chromatographi c t im e s , min. : 0.0 2.0 0.0 0.0 0.0
Chromtographi c rate, deg/mins 20.0 0.0 0.0 0.0 0.0
M / Z =* 3 3 3 . 9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak tt
R. T. f irst
min.
scan
1 12.212 2, 1 2 . 2 1 2
246 246
max scan
249 249
1ast peak scan w idt h
253 7 253 7
raw area
92187 92187
corr. area
41192 39683
corr.
ym
100,00 96.34
M/Z = 331.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R.T. f ir st
min.
scan
max scan
1ast peak scan width
raw area
corr. area
corr.
y.
1 12.192 245 248 254 2 12.192 ,, 245 248 254
9 97418 9 97418
30539 29922
100.00 97.98
332/334 CALCULATION,
R - G l o b a K 0) = M/Z = 327.9
.7414
V
SUB
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t sk imm e d c o r r e c t e d area.
Peak #
R.T. fi rst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
co r r . area
1 12.212 246 249 253 2 12. 2 1 2 L 2 4 6 24 9 253
7 87136 30429 7 87136 25973
M/Z = 321.9
F irst pe a k is- b a s e l i n e d r o p c o r r e c t e d area. -Second peak-^is tangent s k i m m e d c o r r e c t e d area.
Peak #
R.T. f irst
min.
sc an
max sc an
1as t peak sc an w i d t h
raw area
corr. area
1 0.000 2 0.000
254 254
' 0 253 0 253
-1 -1
0 2196 0 2196
corr.
y
190.00 85.36
corr.
y.
100.00 100.00
OC 043
C11317
S M/2 =< 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak #
R. T. f irst
min.
scan
max scan
1ast peak sc an ui dt h
r au area
1 0.000 2 0.000
254 254
0 253 0 253
-1 -1
0 0
>$3S67
corr. area
12 1 9 0 2190
corr. i
100.00 100.00
320/322 CALCULATION R - G l o b a l C 1) =
.9975
M / Z =* 2 5 7 . 0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d p e a k is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. fi rst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
1 0.000 2 0.000
254 254
0 253
-1
0 253 . -1
0 0
corr. area
4259 4259
corr.
'4
100.00 100.00
(320 + 322) /< 3 3 2 +334) C A L C U L A T I O N
R-G I o b a l ( 3) =
.0512
(328')/(332 + 334) CALCULATION
R - G 1o b a l < 3) =
.4239
00044
_ C11318
Fil >B2859 20000-1
333.6-334.6 aiTiu.2UL UT-2628
10000H
10.0 File >B2859
T-i-- I-- r-- I-- 1-- r
1 --I--r--n --I--[--I--i--1--I--I--r
10.5 11.0 11.5 12.0 12.5
331.6-332.6 amu.2UL UT-223
SP2330 200-1/3/250 RUN ET
SP2330
T-- -- J-- 1-- 1-- 1-- I-- ]-- I-- 1-- 1-- I-- I
14.0 , 14.5 15.0
2 0 0 - 1 / 3 / 2 5 0 RUN BT
File >B2359 321.6-322.6 mu.2UL UT-2628
SP2330 200-1/3/2S0 RUN BT
2000-1
F ile
\ \ \ i0 [ i t I--r------r ) I--I i - r-- --r t - | i i r i--r i i--[----i--i i-- ---t i i |- 1i i i |
10.0
10.5 11.0 11.5
12.0 12.5 13.0 13.5 14.0 14.5 15.0
>E2 3 5 9 3 1 9 . 6 - 3 2 0 . 6 -amu.SUL U T-2628
S P 2 3 3 0 2 0 0 - 1 ^ 3 ^ 2 5 0 RUN BT
Visse
SUBJECT TO PROTECTIVE ORDER.
0C-G45
GC/MS default file: >B2859::0i
MS data file header from : >B2859
Sample: 2UL UT-2628
Operator: GARY
MS
9/07/84 .7:03...
Mi sc : S P 2 3 3 0 '2 0 0 - 1 / 3 / 2 3 0 RWN B T L # 1 9 B T L # 19
Sys. #:
1 MS model: 87 SW/HU rev.: CA ALS # : 0
M e t h o d file': S P 2 3 3 0
T u n i n g file: APEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
Transfer line temp. : 0 -
C h r o m a t o g r a p h i c t e m p e r a t u r es : 50. 300. 0. 0. 0. Chro m a t ographi c t im e s , min. : 0.0 2.0 0.0 0.0 0.0 Chromatograph:c rate, d eg / m in : 20.0 0.0 0.0 0.0 0.0
M/Z 3 333.9
First peak is b a s e l i n e ' drop c o r r e c t e d area. S e1c;o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. f irst
min.
sc an
max sc an
1ast peak scan width
raw area
1 12. 112 2 4 2 24 4 2 47 2 12.112 242 244 247
5 34884 5 84884
corr. area
46919 36026
corr. 7.
100.00 76.78
M/Z - 331.9
F irst peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent skimmed corrected area.
Peak .#
R.T. f irst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr.
1 12.112 242 244 246 2 12.112 242 244 246
4 81589 4 81589
31465 29057
100.00 92.35
332/334 CALCULATION
R - G l o b a l < 0) =
.6706
M/Z = 327.9
Fi r s t peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
~
^ ' **" >*---=i>
1
4\i
I *7 J, .
SUBJECT TO PROTECTIVE GPDEI
Peak *
R.T. f irst mi n. sc an
max sc an
1ast peak scan width
raw area
corr. area
corr.
1 12.112 242 244 247
\ 2 12.112 242 244 247
5 222323 5 222323
54167 50527
100.00 93.28
.-
MfZ = 321.9
1 first peak Second peak
is b a s e l i n e drop is tangent s k i m m e d
corrected corrected
area. area.
Peak :
R.T. f irst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
corr. area
c orr.
'A
:i '2
t
0.000 0.000
248 248
0 247 0 247
-1 -1
0 0
O f n * r*
2667 2667
100.00 100.00
C11320/-
S: fl/Z = 3 1 9 . 9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak #
R. T. f irst
min.
sc an
max scan
1as t peak sc an w i'dt h
raw area
1
:2
0.000 0.000
243 243
0 247 0 247
-1 -1
0 0
corr. area
2230 2280
co r r .
100.00 100.00
320/322 CALCULATION R - G l o b a l < 1) =
.8547
M/2 = 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak :4
R. T. f irst
min.
sc an
max scan
1ast peak scan width
raw area
1 0.000 2 0.000
243 243
0 247 0 247
-1 -1
0 0
corr. area
16042 16042
corr. 7.
100.00 100.00
<320 + 322)/< 332 +334) CALCULATION
R - G 1o b a l < 3) =
.0631
< 3 2 8 0 / 0 3 2 + 334) CALCULATION
R - G l o b a l < 3) =
.6907
7
k
00047
C11321
File >B2861 333.6-334.6 inu.2UL UT-2630
SP2330 200-1/3/250 RUN BT
F i l e >2361 3 2 1 . 6 - 3 2 2 . 6 a m .j.2UL U T - 2 6 3 0
SP2333 200-1/3/250 RUN BT
00048
C11322
GC/MS default files >B2861:;01
MS data file header from : >B2S61
Sample: 2UL UT-2630
Operator; GARY
MS
9 / 0 7 / 8 4 _ .7:43
Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N B T L 2 3 B T L # 2 3
S y s . #:
1 MS model: 87 ' SU/HUI reu.: Cft 'ALS : 0
Method file: SP2330
T u n i n g file: A P E 101 N o . of e x t r a r e c o r d 3 !
Scure e t e m p .: 25 2 A n a l y z e r t e m p .:
0
Transfer 1ine temp. :
5
C h r o m a t ographic te m p e r a t u r e s : 50.
300.
0.
0.
0.
; Chro m a t ographic t imes, min. : 0.0 2.0 0.0 0.0 0.0
) Chromatographic rate, deg/min; 20.0 0.0 0.0 0.0 0.0
< Mi'Z = 3 3 3 . 9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R. T. f irst min. scan
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr. V.
. 1 12.051 238 241 247 2 12.051 233 241 247
9 116086 9 116036
85792 77314
100.00 90. 12
M/Z = 331.9
F irst peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R. T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr.
%
1 12.071 237 242 243 2 12.071 237 242 243
11 1 3 9 1 5 6 11 1 3 9 1 5 6
65192 58449
100.00 89.66
332/334 CALCULATION R - G l o b a l < 0) =
.7599
M/Z = 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d ' p e a k is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak .
r ;t . f irst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
1 12.091 239 243 247 2 12.091 239 243 247
3 522313 8 522313
M/Z = 321.9
F irst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. t . f irst
min.
scan
max sc an
1ast peak scan width
raw area
1 12.091 238 243 252 ' 2 12.091 233 243 252
14 1 6 6 6 1 3 14 .166613
0G049
c orr. area
112583 85895
corr. /
*%
100.00 76.29
corr. area
111929 111474
corr. Ji
100.00 99.59
C11323
s M>Z 319.9
First, peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak
R. T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
i i 12.091 236 243 254
2 12.091 23 6 243 254
13 12 5 2 8 5 18 12 5 2 8 5
> 6^1
corr. area
84155 31356
corn.
X
130.00 96.67
320/322 CALCULATION R 7 G 1 o b a l < 1) *
.7519
M/Z = 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R. T. f i r s t
min.
sc an
max scan
1ast peak scan width
raw area
1 12.091 240 243 248
2 12.091 240 243 248
8 237648 8 237648
corr. area
75663 69135
corr. *
100.00 91.37
<320 + 322) /<332 +334) CALCULATION
R - G 1o b a l < 3) a
1.2987
<3 2 8 /)/<332 + 334) CALCULATION
R - G 1o b a l < 3) =
.7390
00050
C11324
File > B2862 333.6-334.6 amu.2UL UT-2631
SP2330 200-1/3/250 RUN BT
File >B2S62 321.6-322.6 amu.SUL UT-2631
SP2330 200-1/3/250 RUN BT
OC 051
C11325
M$ data file header from : >B2862
Sample: 2UL UT-2631
Operator: GARY
MS
9/07/84 .8:03.
Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N B T L U 2 5 B T L # 2 5
Sys, #:
1 MS model: 87 SU/HW rev.i CA ALS # : 0
Method file: SP2330
Tuning file: APEI01 No. of extra records: 2
S o u r c e t e m p . : 25 2 A n a l y z e r t e m p . i:
0
Transf er line t e m p . s
C h r o m t o g r a p h ic t e m p e r a t u r e s : 50. 300. 0. 0. 0. : Chromtographic times, min. : 0.0 2.0 0.0 0.0 0.0 : C h r o m a t o g r a p h ic rate, d e g / m i n : 2 0 . 0 0. 0 0. 0 0. 0 0 . 0
n'(2 3 3 3 . 9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Pfrak
R.T. f irst
min.
scan
max scan
1ast peak sc an w idt h
raw area
corr. area
co r r .
y.
1 12.051 237 241 249
2 12.051 237 241 249
12 140692 1 00672 100.00
12 1 4 0 6 9 2
94366
93.74
M/Z = 331.9
First peak is base 1ine drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak tt
R.T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr, area
corr. V.
1 12.051 237 241 253 2 12.051 237 241 253
16 17 2 0 5 3 16 172058
79786 7569S
100.00 94.38
332/334 CALCULATION R-GlobalC 0) =
.7925
M/Z = 327.9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
SUBJECT TO PROTECT.
Peak :#
R.T. min.
1 12.071 ' 2 12.071
f irst sc an
233 233
max scan
242 242
1ast peak scan width
247 9 247 9
raw area
624209 624209
corr. area
144471 112S99
corr.
y.
100.00 73. 15
M/Z 321.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R.T. min.
1 12.071 2 12.071
fi rst sc an
237 237
max sc an
242 242
1ast peak sc an w i d t h
2 5 6 19 256 19
raw area
226344 226344
oc 052
corr. area
161839 159537
co r r .
y
100.00 93.61
C11326
s
M/Z = 319.9
First peak is baseli ne drop c o r r e c t e d area. Second peak is tangent skimmed c orr e c t e d area.
Peak .#
R. T. f irst
min,
scan
max sc an
1ast peak sc an u idt h
rau area
i 1 12,071 236 242 257
2 12.071 236 242 257
21 1 5 8 7 9 6 21 1 5 8 7 9 6
Vt 320/322 CRLCULATI OH
R f G l o b a K 1) =
.6934
M>Z = 257.0
first peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *:#
R. T. f irst
min.
sc an
max scan
1ast peak sc an u idth
rau area
1 12.071 239 242 251
2 12.071
239 242 251
12 3 6 5 3 5 7 12 3 6 5 8 5 7
corr. area
corr.
y.
112218 100.00
110695
98.64
corr. area
116064 114768
corr.
y.
100.00 93.33
C320 + 3 2 2 ) / ( 3 3 2 + 334) C A L C U L A T I O N
R - G l o b a l < 3) =
1.5187
(328')/(332 + 334) CALCULATION
R - G l o b a l < 3) =
.7925
"1s u b j e c t t o p r o t e c t ;'. - o *
OG053
C1327
File >B2363 333.6-334. amu.2UL UT-2632
SP2330 200-1/3/250 RUH BT
File >B2363 321 .6-322.6 amu.^UL UT-2632
SP2330 200-1/3/250 RUN BT
0G054
C11328
MS data fite header from : >B2863
Samples 2UL UT-2632
Operator: GARY
MS
9 / 0 7 / 8 4 8 l 23
Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N B T L # 2 7 B T L # 2 7
Sys. #:
1 MS model! 87 SU/HU reu.: CA ALS # ! 0
Method fite: SP2330
Tu n i n g file: APEI01 No. of e x t r a records: 2
Source temp.* 250 Analyzer temp.:
0
Transfer line temp. : 0 -
'Chromat o g r a p h ic t e m p e r a t u r e s : 50.
300.
0.
0.
0.
C h r o m a t o g r a p h i c t im e s , min. : 0.0 2.0 0.0 0.0 0.0
C h r o m a t o g r a p h ic rate, d e g / m i n : 2 0 . 0 0.0 0 . 0 0. 0 0. 0
M/Z = 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R. T. min.
1 12.091 2 12.091
first sc an
238 238
max sc an
243 243
1ast peak scan width
2 4 9 11 2 49 11
raw area
95515 95515
corr. area
63417 57070
corr.
y.
100.00 39.99
M/Z = 331.9
F i r s t peak is b a s e l i n e d r o p c o r r e c t e d area.. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. f i r s t
min.
sc ah
max sc an
1ast
peak
sc an w i d t h
raw area
corr. area
corr.
1 12.091 233 243 250 2 12.091 233 243 250
12 97163 12 9 7 1 6 3
44015 39011
100.00 88.63
.-
332/334 CALCULATION R - G l o b a l C 0) =
.6941
M/Z * 327.9
First peak is b a s e l i n e drop c o r r e c t e d area Sec ond peak is t an g e n t s k i m m e d c o r r e c t e d area e
SUBJECT TO PROTECTIVE ORDER.
Peak #.
R. T. f irst
min.
scan
max sc an
1ast peak sc an w idth
raw area
corr. area
corr.
y.
1 12.111 243 244 245 2 12.111 243 244 245
2 154992 2 154992
54287 53495
100.00 98.54
M/Z = 321.9
First peak is b a s e l i n e
drop corrected area m
S e c o n d peak is t an g e n t s k i m m e d c o r r e c t e d a r e a
Peak 4
R.T. f ir s t
min.
scan
max sc an
1ast peak sc an width
raw area
corr. area
corr. 7.
1 12.111 240 244 253 2 12.111 240 244 253
13 1 8 4 6 7 3 13 18 4 6 7 3
135442 134675
100.00 99.43
00055
C11329
M/Z = 319.9
First peak is baseline drop corrected are*. Second peak is tangent skimmed corrected area.
Peak #
R. T. f i r s t
min. 'sc an
max scan
1ast peak sc an w i d t h
r au area
1 12.111 239 244 257 2 12.111 239 244 257
18 1 4 3 1 0 6 18 1 4 3 1 0 6
com. area
99006 98016
com.
y.
100.00 99.00
.
320/322 CALCULATION R - G l o b a l ( 15 =*
.7310
M/Z = 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R. T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
1 12.111 241 244 251
10 2 5 7 7 6 8
2 12.111
241
244
251 . 10
257768
com. area
84807 83287
com. Js
100.00 98.21
(320 + 3225/(332 +3345 CALCULATION
R - G 1obalC 35 =
2.1823
(328'5/(332 + 3345 CALCULATION
R-Global< 35 =
.4940
00056
r--rhM'
C11330
File >B2864 333.6-334.6 amu.2UL .2669/. 43/. 19 SP2330 200-1/3/259 RUH BT
F i l e > B 2 8 6 4 3 3 1 , 6 - 3 3 2 . 6 a,mu.2UL .2 6 6 9 / . 48/. 19 S P 2 3 3 0 2 0 8 - 1 / 3 / 2 5 0 R U H BT
File > B2864 321 .6 - 3 2 2 .6 am u.2UL . 2 6 6 9 / . 4 3 / . 19 SP2330 20 9 - 1 /3 /2 5 0 RUN
BT
10900-
:
5000H
0 10.0
File >B2364
T "I--I--I--I--I--I--j--I" i --I--I--I--] I I--j--i--r 10.5 11.0 111..5 122..00 12.5
T T -- I-- I-- I-- :-- I-- :-- I-- I-- I-- I-- i-- ,|-- 1 I 1 1 1 1 13.0 13.5 14.0 14.5 15.0
3 1 9 . 6 - 3 2 0 . 6 a m u . ^ U L .2 6 6 9 / . 4 8 / . 19 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N BT
/I
.--- icrT T O drotECt !VE ORDER.
0CQ57
C11331
GC/MS default f i U >B2864;;0l
MS data file header from : >B2864
Sample: 2UL .2669/.48/.19
Operator: GARY
MS
9/07/84
Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 3 0 R U N B T L # 2 9 B T L # 2 9
Sys. #:
1 MS model 87 SU/HU r e u . : CA ALS * : 0
Method file: SP2330
Tun i n g file APE 101 N o . of e x t r a records:
Sourc e t e m p .: 23 0 A n a l y z e r temp.
0 Transfer line temp
-8:43
Chromat ographi c t e m p e r a t u r e s : 50. Chromatographi c times, min. : 0.0
Chromatographi c rate, deg/min: 20.0
300. 2.0 0.0
0. 0.0 . 0.0
0. 0.0 0.0
0. 0.0 0.0
fl/Z = 3 3 3 . 9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak
M
R. T. min.
1 12.051 2 12.051
f irst scan
239 239
max scan
241 241
1ast peak sc an w i d t h
247 8 247 3
raw area
93249 93249
corr. area
57993 57461
corr. 3
100.00 99.08
M/Z 3 331.9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
corr. area
corr.
y.
1 12.071 237 242 251
2 12.071
237 242 251
14 ' 8 5 3 7 4 14 85374
41946 39741
100.00 94. 74
332/334 CALCULATION
R - G l o b a K 0) = M/Z = 327.9
.7233
SUBJECT TO PROTECTIVE
First peak is b a s e 1 ine d r o p c o r r e c t e d area. Second peak is t angent skimmed corrected area.
Peak 4
R. T. fi rst
min.
scan
max sc an
1ast peak sc an wi d t h
raw area
corn. area
corr.
y,
1 12.091 241 243 247 2 12.091 241 243 247
6 236832 6 236832
68111 509O3
100.00 74.74
M/Z = 321.9
F irst peak s base 1 ine drop corrected' area. Second peak is t angent skimmed corrected area.
Peak *
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
corr. area
corr.
1 12.091 238 243 252 2 12.091 238 243 252
14 8 5 3 3 0 14 8 5 3 3 0
42934 42482
100.00 98.76
OC 05
m 1335!
s
M/Z = 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak *
R.T. f irst
min.
scan
max sc an
1ast peak scan width
r aw area
1 12.091 238 243 252 2 12.091 238 243 252
14 5 9 5 6 4 14 59564
corr. area
29450 28659
co r r .
y.
100.00 97.31
320/322 CALCULATION R - G l o b a l < 1) *
.6859
M/2 = 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. fi rst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
1 12.091 241 243 247 2 12.091 241 243 247
6 79116 6 79116
corr. area
22764 21423
corr.
y.
100.00 94. 1 1
<320 + 322)/<332 +334) CALCULATION
R - G l o b a l < 3) =
.7243
<328')/<332 + 334) CALCULATION
R - G l o b a l < 3) =
.6777
^ _,? j i7 A.7_j SUBJECT TO PCOTECTiVE ORDER, '
00059
C11333
rile >B2865 333.6-334. amu.SUL UT-2633
SP2330 200-1*-'3/250 RUIN BT
r i l e >B 2 S 6 5 3 2 1 . 6 - 3 2 2 . 6 a m u .2 U L U T-2633
SP2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUH BT
00060
C11334
GC/MS default file: >B2865::01
MS data file header from : >B2865
Sample: 2UL UT-2633
Operator: GARY
MS
9/07/84 .3.-03
M isc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 3 0 RUN BTL431 B T L # 3 1
Sys. :
1 MS model: 87 SW/HU rev.: CA ALS 4 : 0
Method file: SP2330
Tuning file: APEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
Transfer line temp. : 0 -
Chromatographi c tempe r a t u r e s : 50.
300.
0.
0. 0.
C h r o m a t o g r a p h ic t im e s i min. : 0 .0 2.0 0 . 0 0 .0 0. 0
Chromatographi c rate, deg/m in : 20.0 0.0 0.0 0.0 0.0
M/Z = 333.9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R. T. f irst
min.
scan
max sc an
1ast peak scan width
raw area
corr. area
co r r . Ji
1 12.044 243 244 247 2 12.044 243 244 247
4 75275
42703
100.00
4
75275
31329
73.36
M/Z = 331.9
Fi rst peak is b a s e l i n e d r o p c o r r e c t e d area. Se c o n d peak is t a ngent s k i m m e d c o r r e c t e d area.
Peak
R.T. f irst
min.
sc an
max sc an
1ast peak sc an wi d t h
raw area
corr. area
corr. *
1 12.044 242 244 248 2 12.044 242 244 248
6 57725 6 57725
34523 30395
100.00 88.04
332/334 CALCULATION
R - G l o b a l < 0? =
.8084
^:
M/Z = 327.9
First peak is b a s e l i n e dr op c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
SUBJECT
TO
rs^ ^ _
r -' * --- .'Ve
Peak 4
R.T. first
min.
scan
max scan
1ast peak scan width
raw area
corr.' area
corn. *
1 12.065 242 245 249 2 12.065 242 245 249
7 171017 7 171017
67802 57949
100.00 85.47
M/Z. = 3 2 1 . 9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. f ir st
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
corr. area
corr. *
1 12.065 239 245 238 2 12.065 239 245 258
19
196646
146866
100.00
19 1 9 6646 143408 97.65
O r rip
Cl 1335
s
n/Z = 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak #
R. T. f irst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 12.085 241 246 255 2 12.085 241 246 255
14 12 9 2 1 2 14 129 2 1 2
corr. area
97684 95332
corr.
y
100.00 97.59
320/322-CALCULATION R - G l o b a l < 1) 3
.6651
M/2 = 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. f irst
min.
scan
max scan
1as t peak scan width
raw area
1 12.085 243 246 250 2 12.085 243 246 250
7 126026 7 126026
corr. area
67821 62536
corr. *
100.00 92.21
<320 + 322) /<332 +334) CALCULATION
R - G l o b a l < 3) *
3.1667
<328' )/ <332 + 334) CALCULATION
R - G l o b a l < 3) =
.8609
S U B JE C T 7j-v r"
1Cl T -I`/c. 0
00G62
C11336
File > B2S66 333.6-334.6 mu . SUL UT-2634
S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT
20000-
fi
10 000"
File
l
______1
--------------------------
1r * --
1 1 I 1-- i i i 1 l
10 .0 10.5 11.0
J 1j ! i
1 1 .5
11| 1i
12.0
1i | 1i
12. S
> B2S66 331 .6-332.6 a m u . 2UL UT-2634
13.0
13.5
14.0
14. 5 I
ri
15.0
SP23 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT
File >B2366 321.6-322.6 amu.SUL UT-2634
SP2330 200-1/3/250 RUN BT
0G063
C11337
GC/MS default file: >B2866::01
MS data file header from : >B2866
Sample: 2UL UT-2634 `
Operator: GARY
MS
9/07/84
Mi sc : S P 2 3 3 0 2 3 0 - 1 / 3 / 2 5 0 R W N B T L # 3 3 B T L # 3 3
Sys. 4:
1 MS model: 87 S U / H U reu. : Cfl flLS # : 0
Method file* SP2330
T u n i n g file: APEI01 No. of e x t r a records:
Source temp.: 232 Analyzer temp.:
0
Transfer line temp. :
Chromatographi c temperatures
50. 300.
0.
0.
0.
Chromatographic times, min.
0.0 2. 0 0.0 0. 0 0. 0
20.0 0.0 0.0 0.0 0.0
9:.22
M/Z 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. f ir st
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 12.031 236 240 246 2 12.831 236 240 246
10 105110 10 105110
corr. area
78200 70850
corr. V.
100.00 90.60
M/Z = 331.9
First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak #
R.T. first
min.
sc an
max scan
1ast peak scan width
raw area
corr. area
corr.
1 12.031 237 240 243 2 12.031 237 240 248
11 9 5 1 9 7 11 9 5 1 9 7
56043 51785
100.00 92.39
332^334 CALCULATION
R - G l o b a l < 0) =
.7167
M/Z = 327.9
First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent sk i m m e d c o r r e c t e d area.
r'--"
7\ 7 ^ 'T A f
SUBJECT TO P R O TE C TIVcE of?r="-
Peak 4
R.T. first
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
corr. area
corr.
1 12.851 237 241 246 2 12.051 237 241 246
9 298800 9 29S800
76463 60119
100.00 78.62
9--
M^Z 321.9
First peak is b a s e l i n e drop corrected* area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R.T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr, *
1 12.051 238 241 247 2 12.051 238 241 247
9
150832
121024
100.00
9 150832 109243 90.27
0G064
C11338
s
P1/Z = 319.9
Fi rst peak is b a s e 1 ine d r o p c o r r e c t e d area. Second peak is tangent skimmed c o r r e c t e d area.
Peak #
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
r au area
1 12.051 236 241 256 2 12.051 236 241 256
20 133584 20 133584
corr. area
88864 86054
cor r .
V.
100.00 96.84
320/322 CALCULATION R-Global( 1) =
.7343
MAZ = 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
1 12.071 2 12.071
233 242 247 233 242 247
9 152622 9 152622
corr. area
74700 63855
corr. Ji
100.00 85.48
(320 + 322>/<332 +334) CALCULATION
R - G l o b a K 3) =
1.5634
<328')/<332 + 334) CALCULATION
R-Clobal < 3) =
.5615
CCi ii^ISNTfAL
SUBJECT TO PROTECTIVE ORDER.
00065
C11339
File >B2S67 333.6-334.6 amu.2UL UT-263S
SP2330 200-1/3/250 RUN BT
File >B2367 321.6-322.6 amu.SUL UT-235
SP2330 200-1/3/259 RUN BT
MS data file header from i >B2867
Sample: 2UL UT-2635
Operator: GRRY
MS
9/07/84 .9:42...
Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 3 0 RU N B T L # 3 5 B T L # 3 5
Sys. #:
1 MS m o d e l : 87 S U / H U rev.: CR RLS ft : 0
Method file: SP2330
Tuning file: RPEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
T r a n s f e r line temp. : --
C h r o m a t o g r a p h ic t e m p e r a t u r e s : 50. 300. 0. 0. 0. Chro m a t ographic times, min. : 0.0 2.0 0.0 0.0 0.0 Chromato g r a p h ic rat e , deg/min : 20.0 0.0 0.0 0.0 0.0
M/Z = 333. 9
F irst peak is b a s e l i n e d r o p c o r r e c t ed area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak ft
R. T. f irst
min.
sc an
max scan
1ast peak scan width
raw area
corr. area
corr.
y.
1 12.030 234 240 252 2 12.030 234 240 252
18 13 0 3 6 6 18 130366
81910 78688
100.00 96.07
M/Z = 331.9
F irst peak is b a s e 1 ine d r o p c o r r e c t e d area. Sec ond peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak ft
R. T. f i r s t
min.
sc an
max scan
1ast peak scan width
raw area
corr. area
corr.
ym
1 12.030 236 240 251 2 12.030 236 240 251
15 108161 15 108161
56861 55758
100.00 98.06
332/334 CALCULATION
R - G l o b a l C 0) = M/Z = 327.9
.6942
fTAT SUBJECT TO PROTECTIVE ORDEfl
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak * ft
R.T. f irst
min.
sc an
max sc an
1ast peak scan width
raw area
corr. area
corr. 5i
1 12.051 237 241 246 2 12.051 237 241 246
9 203074 9 203074
60784 56904
100.00 93. 62
M/Z = 321.9
F irst peak is base 1ine drop corrected area. S e c o n d peak is t a ngent s k i m m e d c o r r e c t e d area.
Peak ft
R.T. first
min.
scan
max sc an
1ast peak sc an wi d t h
raw area
corr. area
corr.
y.
1 12.051 238 241 246 2 12.051 238 241 246
8 34928 8 34928
10520 9928
100.00 94.37
00067
C11341
s
M/Z = 319.9
First peak is base 1ine drop corrected area. Second peak is tangent skimmed corrected area.
Peak tt
R. T. f i r s t
min.
scan
max sc an
1ast peak scan width
raw area
1 12.051 238 241 247 2 12.051 238 241 247
9 28746 9 28746
corr. area
8451 7780
corr. J;
100.00 92.06
320/322 CflLCULATION R - G l o b a l C 1) -
.8033
M/Z = 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak it
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
1 12.051 239 241 244 2 12.051 239 241 244
5 46929 5 46929
corr. area
10379 10161
corr. '4
160.00 97.90
(320 + 322)/(332 +334) CALCULATION
R - G 1o b a l < 3) =
.1367
( 3 2 8 0 / 0 3 2 + 334) CALCULATION
R - G l o b a l < 3) =
.4373
00068
j. '-i_
Ja
SUBJECT TO PROTECTIVE ORDER
C11342
File >B2368 333.-334.6 amu.SUL UT-2636
SP2330 200-1^3/250 RUN BT
File >B2363 321.6-322.6 amu.^UL UT-2636.
SP2330 200-1/3/250 RUN BT
'-i...i
.- . ,
SUBJECT TO PROTECTIVE ORDER.
0C069
C11343
MS data fil? header from : >B2868
Sample: 2UL UT-2636
Operator: GARY
MS
9/07/84 10r02
Mise : SP2330 200-1/3/230 RUN BTL*37 BTL#37
Sys. #: 1 MS m o d e l : 87 S W / H U rev.* CA ALS # : 0
Method file: SP2330
Tu n i n g file: APEI01 No. of e x t r a records: 2
Source temp.: 230 Rnalyzer temp.:
0
Transfer line temp. : 0 ~
C h r o m a t og r a p h i c t e m p e r a t u r e s : 50. 300. 0. 0. 0. C h r o m a t o g r a p h ic times,, min. : 0 . 0 2.0 0 . 0 0. 0 0. 0 C h r o m a t o g r a p h ic rate, deg/mi n: 2 0 . 0 0.0 0 . 0 0. 0 0 . 0
M/Z - 333. 9
F irst p e ak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d area.
Peak *
R. T. f irst
min.
scan
max sc an
1ast peak s c an width
raw area
corr. area
co r r . %
1 12.010 236 239 244
2 12.010 236 239 244
8 107248 8 107248
78584 74548
100.00 94.86
M/Z = 331.9
First peak is b a s e l i n e dr op c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. fi rst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
corr. area
c orr.
y.
1 12.010 231 239 256 2 12.010 231 239 256
25 139010 25 139010
66335 62047
100.00 93.54
332/334 CALCULATION R-GlobalC 0) =
.8441
M/Z = 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. Se c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. f irst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
1 12.030 229 240 252 2 12.030 229 240 252
23 318017 23 318017
M/Z = 321.9
First peak is b a s e l i n e dr op corrected, area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
1 0.000 2 0.000
253 253
0 252 0 252
-1 -1
0 0
OC 070
. ; "*
S U B J EwCl'*T T o rr'SrO-T--F-Tj..'f-.t'-
corr. area
88063 53839
corr. *
100.00 61.14
corr, area
2708 2708
corr.
s`.
100.00 100.00
C11344
s
M.'Z = 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak #
R.T. fi rst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
1 0.00O 2 0.000
253 253
0 252 6 252
-1 -1
0 0
corr. area
2193 2193
Corr. *4
100.00 108.00
3ZQ/322 C A L C U L A T I O N
R-G 1o b a l < 1) S
.8100
M.'Z = 2 5 7 . 0
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Pe ak #
R.T. fi rst
min.
sc an
max sc an
1ast pe ak sc an width
raw area
1 0.000 2 0.000
253 253
0 252 ' -1
0 252
-1
0 0
corr. area
6477 6477
corr. Ji
100.00 100.00
<320 + 322>/<332 +334> CALCULATION
R - G 1o b a l < 3) --
.0338
( 3 2 8 " >/<332 + 334) CfLCULfTIOH
R-Gl obal < 3) =
.6075
. i U i.5rkXj
SUBJECT TO PROTECTIVE ORDER*
C11345
File >*2869 333.6-334.6 A m u . SUL UT-263'
SP2330 200-1/3/250 RUM BT
File- > 2 6 6 9 i 1 .6-322 s* am u 2 U L U T - 2 6 3 7
SP2330 200-1/3/250 RUM BT
8080t
4000-
:
e10.0
L lv.x
10.5 11.0 11.5 10.9 12.5 13.0
I m m \ \
Oc 072
13.5
14.0
-v:
14.5 15.0
C11346
mini hois roHronniio* ihimmo Niwtim
a file header from ! >B2869
2UL UT-263?
Operator: GARY
MS
9/07/84 10:22
SP2330 200-1/3/250 RUN BTL#39 BTL#39
: 1 (IS model: 87 S U / H W rev.: CA A L S # : 0
od file: SP2330
Tuning file: BPEI01
e temp.: 250 R n a l yztr t e m p .:
0
Ho. of extra records: 2 Transfer line temp : 0
..
Chromat ographi c t e m p e r a t u r e s : 50.
300.
0.
0.
0.
C h r o m a t o g r a p h i c times, min. : 0 . 0 2. 0 0.0 0. 0 0. 0
C h r o m a t o g r a p h ic rate, d e g / m i n : 2 0 . 0 0. 0 0.0 0.0 0. 0
-
333.9
pe ak is b a s e 1 ine d r o p c o r r e c t e d area.
i peak is t a n g e n t s k i m m e d c o r r e c t e d area.
R.T. f irst
min.
scan
max scan
1ast peak scan width
raw area
corr. area
corr.
%
12.010 233 239 247 12.610 233 239 247
14 9 3 7 8 7 14 9 3 7 6 7
56919 53699
100.00 94.34
331.9
t p e ak is b a s e l i n e d r o p c o r r e c t e d area. d peak is tangent s k i m m e d c o r r e c t e d area.
R.T. 'f irst m iri. s c a n
max sc an
1ast peak sc an ui dt h
raw area
corr. area
corr.
y.
12.010 231 239 253 12.010 231 239 253
22 104329 22 104329
40353 38571
100.00 95.58
i34 C A L C U L A T I O N
z>b a 1 i 0 =
.7090
-* r*i-/- , __
n-- ^ J *' - >
if4| n T c m i o i w c
st peak is b a s e l i n e d r o p c o r r e c t e d area, nd peak is tangent s k i m m e d c o r r e c t e d area.
R.T. fi rst min. sc an
max scan
1ast peak scan width
raw area
12.051 237 241 245
12.051
237
24 1
245
8 133144 8 133144
321.9
:
pe ak is b a s e l i n e d r o p c o r r e c t e d area,
peak is t angent skimmed corrected area.
R.T. f irst min. scan
max sc an
1 ast p e ak scan w idth
r aw area
0.000 0.000
246 246
0 245 0 245
-1 -1
00073
0 0
corr . ar ea
45068 37980
corr.
y.
108.00 84.38
corr . area
2725 2725
corr.
y.
100.00 100.00
Ci l 347
File >B2S70 333.6-334.6 *mu UL 2.669/.48/. 19 SP2330 200-1/3/250 RUN BT
File > 2 8 7 0 321 . 6 - 3 2 2 . 6 iHiu .2UL 6 6 9 / . 4 8 / . 1 9 S P 2 3 3 0 2 0 8 - 1 / 3 / 2 5 0 RU N BT
80000-
.
40000-
0-T^
^ 1i'
10.0 10.5 11.0 11
12.0 12.5 13.0 13.S 14.0 14.5 15.0
C11349
MS data file header from
>B2870
Sample: 2UL 2.669/. 48/. 19
Operator: GARY
MS
9 / 0 7 / 8 4 l*8:42--,,
Misc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N ` BTL*t4 1 BT L 4 1
Sys. 0:
1 MS model: 87 S U / H M r e u . : Cfi RLS # : 0
Method file: SP2330
T u n i n g file: APE I 6 1 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
T r a n s f e r line temp. : 0
C h r o m a t ogr aph ic t e m p e r a t u r e s : 50. 300. 0. 0 . 0.
Chromat og r a p h ic times, min. : 0.6
2. 0 0 . 0
0. 0
0.0
C h r o m a t o g r a p h i c rat e , deg/mi n : 2 0 . 0 0 . 0 0 . 0 0. 0 0.0
M/Z * 333.9
First peak is b a s e l i n e
drop corrected area.
S e c o n d pe ak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R. T. f irst
min.
sc an
max scan
1ast peak s c a n uiidt h
raw area
corr. area
c orr.
y.
1 12.011 234 239 249 2 12.011 234 239 249
15 130146 15 130146
95136 93606
100.00 98.39
M/Z = 331.9
F i r s t pe ak is b a s e l i n e d r o p c o r r e c t e d area. Se c ond p e ak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R. T. fi rst. riiin . sc an
max scan
1ast peak scan width
raw area
co r r . area
corr. *
1 12.011 234 239 249 2 12.011 234 239 249
15 .*107070 15 107 0 7 0
68550 66667
100.00 97.25
332/334 CALCULATION R - G l ob al f 0> a
.7 2 0 5
M/Z = 32?. 9
cc S
' '-- v __ _ :
-
' -i i \
-
11t
O R Z *s
First pe ak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d pe ak is t a n g e n t s k i m m e d c o r r e c t e d area.
--
Pe ak
*
R. T. first m in . sc an
max scan
1ast peak scan width
raw area
corr. are a
c orr.
1 12.031 237 240 243 2 12.031 237 240 243
8 147271 6 147271
60493 58330
100.00 96.42
M/Z = 321.9
!
First peak Sec ond peak
is b a s e l i n e d r o p is t a n g e n t s k i m m e d
corrected corrected
area. area.
P e ak #
R. T. mi n .
first sc an
max sc an
1ast peak s c an wi d t h
raw area
corr. area
c orr.
**
1 12.031 236 240 246 2 12.031 236 240 24 8
12
531792
496500
100.00
12 5 31792 4 8 0 1 6 8 96.71
C1135
n ( >-
* r
z 3z
17
Q
C
J*
z
S M '2 * 319.9
First peak is baseline drop corrected area. Second peak is tan gent skimmed corrected area.
Fe ak ft
R. T. f irst
min.
sc an
max scan
1ast peak sc an u idt h
rau area
1 12.031
235 240 248
2 12.031 235 240 246
13 366 2 3 0 13 366230
corr. area
337682 323096
corr.
X
106.00 95.68
320^322 CFlLCULRT ION R-GlobalCl)*
.6801
1V2 = 257.0
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P e ak
R. T. Ai f 'i .
firs t scan
m ax scan
1ast peak 5 can width
rau area
1 12.031 236 240 &4& 2 12.031 236 240 246
10 3 5 5 8 3 7 10 3 5 5 8 3 7
corr, area
300237 282357
c orr. 'Iy
100.00 94.04
C320 + 3 2 2 ) / C332 +334) CRLCULRTION
R - G l o b a l C 3) =
5.0962
(328')/C332 + 334) C R L C U L R T I O N
R - G 1obal >. j> ~
,341 j
ff;i ntconking ciiftRisl t.iunm ittonnij.rournn.HON
C -:
SUBJECT TO PROTECTIVE ORDER.
n r C11351
File >B2S71 333.6-334,6 amu.2UL 26.69/.48/.19 SP2336 266-1/3/259 RUH BT
'i. vini*iinn
X
F i l e >E 2371 3 2 1 . 6 - 3 2 2 . 6 a m u .^ U L 2 6 . 6 9 / . 4 8 / . 19 SP2 3 3 2 6 0 - 1 / 3 / 2 5 0 RUM BT
8066 0O-
4 OOOOO*
0-J-- :-- i-- r-i-- i-- !-- :-- !-- i-- [-Ti-- i-- i-- i-- I-- i-- n -- r*-j-- r--- i-- -- !-- n -- t--j-- i-- i-- i-- :-- ;-- i-- i-- i-- -- ]-- i-- r-i-- i-- -- :-- i-- i-- :-- j 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 1 4 .G 14.5 15.6 F i l e >B 2671 3 1* . 6 - 3 2 0 .6 an,u . 2UL 2 6 . 6 9 / . 43 .19 S P 2 33 20 0- 1/ J / 250 RUM BT
I-
11
4 0 0 0 0 O-
0 n'
I ' I '! ! J I
10.0 10.5 1 1 .
- j ..u
/*!L'BJECT TO PROTECTIVE ORDER.
' I 1 ` 1 1 ' 1 1 J 1 1 ' I 1 > I 1 - i 1"1! 1 - i
11.5 12.0 12.5 13.0 13.5 14.6 14.5 15.0
OC0 7 8
C11352
MS data file header from i >B2S7l
S a m p l e : SUL 2 6 . 6 9 / . 48''. 19
Operator: GARY
MS
9/07/84 11:02*
Misc : SP2330 200-1/3/250 RUN BTL#43 BTL#43
Sys. #:
1 MS modeli 87 S U / H U rev.: Cfi ALS # : 0
Method file: SP2330
T u n i n g file: APEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
Transfer line temp. : 0 -
C h r o m t ographi c t e m p e r a t u r e s : 50.
300.
0.
0.
0.
Chro m t ographi c times, min. : 8.0 2.0 0.0 0.0 0.0
C h r o m t ogr a p h i c r at e , d e g / m in : 2 0 . 0 0.0 0. 0 0 . 0 0.0
M/2 * 333.9
First peak is base 1 ine d r o p c o r r e c t e d area.
S e c o n d peak is tan g e n t s k i m m e d c o r r e c t e d area.
Pe ak #
R.T. first min. scan
max scan
1ast peak scan width
raw area
corr. area
corr. *
1 11.99 233 238 243 2 11.990 233 238 243
M/Z = 331.9
10 119581 10 119581
95141 65461
100.00 68.80
First- peak is b a s e l i n e
drop corrected area.
S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Pe ak
R.T. first
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr. area
c orr.
y.
1 12.010 234 239 243 <" 1 2 . 0 1 0 234 23 9 243
9 - 93295 9 93295
65854 47853
100.00 72.67
332-'334 C A L C U L A T I O N R - G 1o b a 1 i 0> =
.6922
n/2 = 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
,,-- ______ v .,
SUBJECT TO
iE C 7
P e ak #
R.T. first min. sc an
m ax sc an
1ast p e ak sc an w i d t h
raw area
corr. area
c orr. *
1 12.010 232 229 248 2 12.01O 232 239 248
16
483585
220832
100.80
16 4 8 3 5 8 5 119551 5 4 . 3 3
M/2 = 321.9
F irst peak is b a s e l i n e
drop corrected area.
S e c o n d peak is t a n gent s k i m m e d c o r r e c t e d area.
Pe ak #
R.T. f ir st
min.
sc an
ma sc an
1ast
pe ak
scan width
raw area
corr. area
corr.
4
1 12.010 235 239 244
2 12.010 235 239 244
9 4944280 9 4944280
4816579 3347396
100.00 69.50
OC079
C11353
m /Z * 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak R.T. first
i
min.
scan
max sc an
1ast peak sc an u idt h
raw area
1 12.030 235 240 245 2 12.030 235 240 245
10 3 4 9 5 8 9 8 10 3 4 9 5 8 9 8
corr. area
3421448 2367786
corr.
100.00 69.20
320/322 C L C U L A T ION R - G l o b a K 1) =
.7103
M/Z * 257.0
First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is t an g e nt skimmed corrected area.
F e ak *
R.T. f irst
min.
scan
max scan
1as t peak s c a n ui dt h
raw area
1 12.030 235 240 245 2 12.030 235 240 245
10 2 8 9 9 0 8 5 10 2 8 9 9 0 6 5
corr. area
2808645 1870499
corr.
100.00 66. 60
C320 + 322 )/(332 +334) CALCULATION
R - G 1o b a l < 3) =
51 . 1695 ;
(.SI'S-' >' (332 + 334) C A L C U L A T I O N
R - G l o b a H 3) =
1 .0974
_
M
*
I Z | X
sZ
1 1lIus If re
SUBJECT m
__ ' ' " -1-* ^-L<
1- r u i ECTIVE C.lDr-;
000JO
C11354
i
!*
i"
. i i_u,i j v t .
nr
C11355
z
F i l e > 3 2 8 7 4 3 3 3 . 8 - 3 3 4 . 8 & nmiuu .-UL .1 6 68/ .48 .1?
SF233G 266-1/3/256
BT
F i l e > B 2 $ 7 4 3 2 1 . 8 - 3 2 2 . 5 a m u . . 1O S / .4 5 / . 1 9
SF2336 200-1/3/256
BT
SUBJECT TO PROTECTIVE ORDER.
nr
C11356
MS data file header from i >32874
Sample: 2UL .1068/.48/.19
Operator* GARY
Misc : SP2330 200-1/3/250
. BTL403 BTL#
Sys. ***
1 MS model* 87 SW/HU rey.: CA
Method file: SP2330
Tuning file: .APEI01
Source temp.: 250 A n a l y z e r temp.:'
0
MS 9/07/84 -12:65*_3 ALS : 0
No. of e x t r a reco r d s : 2 Transfer line temp. * 0
C h r o m a t o g r a p h i c t e m p e r a t u r e s : 50.
300.
0.
0.
0.
Chromatographic times, min. : 0.0
2.0
0.0
0. 0
0.0
20.0 0.0 0.0 0.0 0.0
M/2 * 333.9
F irst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d p e ak is t angent s k i m m e d c o r r e c t e d area.
Peak
p
R. T. f irst
min.
scan
m ax scan
1ast peak sc an w i d t h
raw area
corr. area
corr. y.
1 11.984 239 241 246 11.984 239 241 246
7 64648 7 64648
40526 39133
100.00 96.56
M/Z = 331.9
First p e ak is b a s e l i n e drop c o r r e c t e d area. Sec ond peak is t ang e n t s k i m m e d c o r r e c t e d area.
Peak it
R. T. f irst
min.
sc an
m ax sc an
1ast peak scan width
raw area
corr. area
corr. *4
1 12.004 237 242 250 2 12.004 237 242 250
13 59914 13 5 9 9 1 4
31392 29949
100.00 95.40
332/334 CALCULATION R - G l o b a K 0? =
.7746
M/2 = 327.9
C O JV , SUBJECT TO
P.^OTCv--
O`ROC
F i rst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P e ak #
R.T. f irst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
corr. area
co r r . *
1 12.004 237 24 2 251 2 12.004 237 242 251
14 8 8 0 2 9 14 8 8 3 2 9
25389 34063
100.00 96.08
M/Z = 321.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d p e ak is t angent s k i m m e d c o r r e c t e d area.
Pe ak #
R.T. fi rst
min.
s c an
m ax scan
1ast peak scan width
raw area
c or r . area
corr.
1 12.024 241 243 246 2 12.024 241 243 246
5 23343 5 23343
9683 7598
100.00 83.65
C11357
|C-irn"l c u r u i n g C i i * m s 1 i.nAriiii; C o n i hoi s t r>iiriin*iinN m u o i l * Nt w v<mn
S
Y\'Z
319.9
First peak is baseline drop corrected area. Second.peak is tangent skimmed corrected area.
Feak
R. T. first
min.
scan
max scan
1ast peak sc an w i d t h
raw ,a r e a
1 12.024 241 243 247 2 12.024 241 243 247
6 22029 6 22029
corr. area
6999 5748
corr.
V.
100.00 83.20
320.'322 CALCULATION R - G l o b a l C 1) =
.7607
Pl-'Z = 2 5 7 . 0
F i rst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Re ak *
R. T. first
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
1 12 . 0 2 4 238 243 248 10 3 9 6 7 6 2 12. 8 2 4 238 24 3 248 10 3 9 6 7 6
corr. area
9536 8586
c orr.
y.
100.00 90.04
C320 + 322 ) / C332 +334) CALCULATION
R - G l o b a C 3.'1 =
.2224
C328')x<332 + 334) CALCULATION
R - G l o b a K 3 > =
.4909
M O Ml'
OOOS4
*7i
C11358
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C11359
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lata file he a d e r from ! >B2875
-.le: 2UL 1 . 0 6 8 / . 4 8 / . 19
O p e r a t o r i GfiRY
MS
9/07/84
: SP2330 200-1/3/250
BTL05 BTL#
: 1 MS model : 87 S U / H U r e v . : Cfi fiLS : 0
rthod file: SP2330
Tuning file: .RPEI01 No. of e x t r a records:
jrc e t e m p . : 252 finalyzer t e m p . :
0
Transfer line temp. :
12:-24 .
Chromat ograph ic t e m p e r a t u r e s : 59. Chromat ograph ic t im e s , min. : 0.0 C h r o m a t og r a p h i c r at e , deg/mi n: 2 0 . 0
300. 2.0 0.0
0. 0.0 0.0 '
0. 0.0 0.0
0. 0. 0 0.0
S 333.9
r st peak is b a s e l i n e `d r o p c o r r e c t e d area. on d peak is t arg e n t s k i m m e d c o r r e c t e d area.
< R.T. f ir s t max last peak
min.
sc an s c a n
sc an width
raw area
corr. area
corr.
1 11.990 237 236 242 2 11.99 237 238 242
5 62220 56745 100.00
5 82220
15262
26.96
= 331.9
rst peak is b a s e l i n e d r o p c o r r e c t e d area. ond peak is t ang e n t ski m m e d c or ree ted area.
.k R.T. first
min.
sc an
1 11.99D 2 11.990
235 235
max scan
238 238
last peak sc an w i d t h
244 9 244 9
raw area
66175 66175
corr. iarea
42136 41195
c orr.
y.
10 0 . 0 0 97.77
:T
2/334 CRLCULRTION *1c<b a 1 i 0J =
.7426
I = 327.9
irsi peak is b a s e l i n e d r o p c o r r e c t e d area. :ond peak is t a n g e n t s k i m m e d c o r r e c t e d area.
ak R.T. fi rst ma x 1ast peak
#
min.
scan
scan
sc an w i d t h
raw area
1 12.010 234 239 246 2 12.016 234 239 246
12 9 8 3 8 2 12 9 8 3 8 2
2 * 321.9
irst peak is b a s e l i n e d r o p c o r r e c t e d area, cond peak is t a n g e n t s k i m m e d c o r r e c t e d area.
ak R.T. first m a x 1ast peak
4
min.
sc an sc an sc an w id t h
raw area
1 12.010 237 239 243 2 12.010 237 239 243
6 180719 6 180719
r\ f n n
Ar
- <--<GTE'-^V'E ORDER.
,c o r r . ar e a
56154 54390
corr.
y.
100.00 96.86
*
corr. area
127919 95278
corr.
y.
100.08 74.48
C11360
162
I
nikiw h
ritKHMOi s cw*f*>*>'**
MS data file header from : >B2876
Sample: 2UL UT-2638
Operator: GARY
MS
9 / 0 7 / 8 4 -12::46 =. .
Mise : SP2330 206-1/3/250 RUN BTL445 BTL445
Sys. 4:
1 MS model: 87 S U / H U rev. : Cfl ALS 4 : 0
Method file: SP2330
Tu n i n g file: APEI01 Ho. of e x t r a records: 2
Source temp.: 230 Analyzer temp.:
0
Transfer line temp. : 0 -
C h r o m atographie t emperat ures : 50.
300.
*0.
0 e 0.
C h r o m a t o g r a p h i c times, min. : 0 .0 2. 0 0 . 0 0. 0 0.0
Chroma tographi c rate , deg/min : 20.0
0.0
0.0
0. 0
0.0
M/Z * 333.9
First pe ak is b a s e l i n e d r o p c o r r e c t e d area. Sec en d peak is- t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R. T. f irst
min.
sc an
max scan
1ast peak scan u id t h
rau area
corr. area
corr. y.
1 11.970 236 237 242 2 11.970 236 237 242
6 86132 6 86132
59336 38648
100.00 65. 13
M/Z = 331.9
First peak is ba s e 1 ine dr o p c o r r e c t e d area. Se c on d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R. T. f i r s t
min.
sc an
max sc an
1ast peak sc an w i d t h
rau area
corr. area
corr. *
1 11.970 233 237 246
13
70827
43098
100.00
2 11.970 233 237 246
13
70827
41590
96.50
332/334 CALCULATION
R-GlobaU 0) =
.7263
M/Z = 327.9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d Are a .
Peak 4
R. T. fi rst
min.
scan
max scan
1ast peak sc an wi d t h
raw area
1 11.990 235 238 248 2 11.990 235 238 248
13 93453 13 93453
M/Z 321.9
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R. T. fi rst m in . sc an
max scan
1ast peak sc an wi d t h
raw area
1 0.000 2 0.000
249 249
0 248 0 248
-1 -1
0 0
c or r . area
51944 49747
c orr.
100.00 95. 77
cor r . area
2224 2224
c orr. '/
100.00 100.00
G11363 I
nfl CnnmnC C N tnlT I
S
IVZ * 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.'
Fe ak *
R. T. f irst min. scan
max scan
1ast peak sc an ui dt h
rau area
1 0. 000 2 0.000
249 249
0 248 0 248
-1 ' -1
0 0
> > 2 T 7 U>
corr. area
2144 2144
corr.
y.
100.00 100.00
320^322 CALCULATION R - G l o b a U 1) =
.9640
M/Z = 257.0
First peak is b a s e l i n e dr o p c o r r e c t e d areal S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak '#
R. T. first
min.
scan
max scan
1ast peak s c a n ui dt h
raw area
1 0.000 2 0. 080
249 249
0 246 0 248
'1 ' -1
.0 10
corr. area
2759 2759
c orr.
y.
100.00 100.00
C320 + 322 )/< 332 +334) C A L C U L A T I O N
R - G 1o b a l < 3) =
.0426
C328')/<332 + 334) CALCULATION
R - G l o b a l C 3) =
.5069
;<Sl n r c o h o i N n c i l * n i * | i.ntt'H'U cu N in o i s r ,n n r < i n n n N
j I If1 * / O <>(" i n
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C11364
C11365
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F i l e >B2S77 3 3 2 . 6 - 3 3 4 . amu .2UL U T - 2 6 3 9
o?
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MS data file header from i >B2877
Sample: 2UL UT-2639
Operators GARY
MS
9 / 0 7 / 8 4 -13i.06
Mise : SP2330 200-1/3/250 RUN . BTL447 BTL#47
Sys. #:
1 MS models 87 SW/HW r t v . ! CA ALS # : 0
Method file: SP2330
T u n i n g file: APE 101 No. of e x t r a records:
Source temp.: 250 Analyser temp.:
0
T r a n s f e r l i n e temp.i m -
,
C h r o m a t o g r a p h ! c tem p e r a t u r e s : 50. Chromat ograph ic times, min. : 0.0 Chromat ograph ic rate, deg/min: 20.0
300. 2.0 0. 0
0. 0.0 0. 0
0. 0.0 0. 0
0. 0.0 0.0
M/Z - 333.9
F i rst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P c ak 4
R. T. first
min.
sc an
m ax scan
1ast peak sc an w i d t h
raw area
corr. area
corr. /.
1 11.990 236 238 242 2 11.990 236 238 242
6
71474
45152
100.00
6
71474
33140
73.40
M/Z = 331.9
First pe ak is b a s e l i n e
drop corrected area.
S e c o n d p c ak is t a n g e n t s k i m m e d c o r r e c t e d area.
Pe ak 4
R. T. f i rst
min.
sc an
max sc an
1ast peak scan width
raw area
corr. area
c orr. *
1 11.990 234 238 244
10
52794
33584
100.00
2 11.99D 234 238 244
10
52794
30404
90.53
332/334 CALCULATION R -G 1o b a 1 i 0 ) =
.7 4 3 8
M = 327.9
Fi r s t peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent skimmed c o r r e c t e d area.
C 5"i^ t--'---rJ
P e ak 4
R. T. f irst
min.
sc an
1 12.610 2 12.018
235 235
M/Z * 321.9
max sc an
239 239
1ast peak sc an w i d t h
249 14 249 14
raw area
83067 83067
c orr. area
39667 39492
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d ar ea.
Peak 4
R.T. f irst
min.
sc an
m ax sc an
1ast peak scan width
raw area
1 0.000 2 0.000
250 250
0 249 0 249
-1 -1
0 0
cor r . area
2178 2178
00092
:'i I a l
c orr.
y.
160.00 99.56
C11366
corr. s
100.00 100.00
S
Mx2 = 319.9
>V)sm
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
ak R. T. first
max 1ast peak
min.
sc an
sc an s c a n w i d t h
raw area
corr. area
1 0.000 2 0. 00 0
25G 250
0 249 0 249
-1 -1
0 2047 0 2047
corr. *
100.00 100.00
3 2 0 '3 2 2 C A L C U L A T I O N
R - G 1o b a l k 1> =
.9399
M^2 = 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak t
R.T. first
min.
sc an
max sc an
1ast peak scan width
raw area
1 0.000 2 0.000
250 25G
0 249 0 249
-1 -1
0 0
corr. area
2717 2717
c orr.
100.00 100.00
<320 + 322)-'<332 +334) CALCULATION
R - G l o b a K 3) =
.0537
<328'* > / < 3 3 2 + 334) C A L C U L A T I O N
R - G 1o b a 1 < 3> -
.5035
c o H i n m s i; n n r . miai nifi
fr-ifni c o n u iN ii c u a t i s !
SUBj Euj iO
00093
\1
iVE RzJR.
C11367
iP
r\) G>
V
<3?
-* M
I>
Otosd.
G11368
i-ii ih i.' >( t(ti./.il
I1illlI.IIMOlNU ClilM'il
Ol
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00
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ro wro'ooj
00
OJ
m
n.
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to
<oOjiU'>)
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P=1 c Vo
a m u .2UL U T - 2 4 0
I 1O'0
SP2330 200-l'3^2S0 RWH
M rTo
to
ro
-i*
\ C\O rcon
73
l.ll*l'l<nIMil ...... l`l|(I/(itNiVI(IUt*
CO o
MS data file header from : >B28?8
Sampl e: 2UL U T - 2 6 4 0
Operators GARY
US
9 / 0 7 / 8 4 1 3 : : 2 6 t ..,
Mi sc ! S P 2 3 3 0 2 0 0 - 1 ^ 3 ^ 2 5 0 R W N B T L # 4 9 B T L # 4 ?
Sys. 4:
1 MS model i 87 S U / H U rev. s Cfi A L S # : 0
Method files SP2330
Tuning file: APEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:-' 0
T r a n s f e r line temp. : 0
C h r o m t ograph ic t e m p e r a t u r e s : 50.
300.
0.
0.
0.
Chromtographic time s i min. : 0.0 2.0 0.0 8.0 0.0
C h r o m a t o g r a p h ic r at e , d e g / m i n : 2 0 . 0 0.0 0.0 0.0 0.0
M/Z *= 3 3 3 . 9
First pe ak is b a s e 1 ine d r o p c o r r e c t e d area.
S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peal;
R.T. f irst
min.
sc an
max scan
1ast peak sc an width
raw area
corr. area
corr.
1 11.964 238 240 244 2 11.964 238 240 244
6
82683
53067
100.00
6
82683
48456
91.31
M.-'Z = 3 3 1 . 9
First pe ak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d pc ak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R.T. fi rst
min.
sc an
max sc an
1ast pe ak sc an w i d t h
raw area
corr. area
corr.
y.
1 11.964 235 240 250 2 11.964 235 240 250
15 6 9 9 0 6 15 69906
40191 37866
100.00 94.22
c.nap.itri.iinihiii s riinrniiAliUN litiIlAi<nivi c
CliilnI(i
332^334 CALCULATION R - G l o b a W 0) =
.7574
M.-Z = 3 2 7 . 9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R.T. fi rst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
1 11.964 237 241 250 2 1 1.984 237 241 256
13 8 1 9 8 2 13 8 1 9 8 2
M/Z - 321.9
F irst peak is base line drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. f irst m in . scan
max s c an
1ast peak sc an wi d t h
raw area
1 0. 060 2 0.000
251 251
0 250 0 250
-1 -1
0 0
OC 095
T-
-
corr. area
48299 45575
corr.
y
160.00 94.36
corr. area
2192 2192
c orr.
X
100.00 100.00
C11369
319.9
'st peak is baseline drop corrected area. 2 nd peak is tangent skimmed corrected area.
V R. T. first
max 1ast peak
min.
sc an sc an s c a n w i d t h
raw area
1 12.186 251 251 251 2 12.186 251 251 251
0 2216 0 2216
corr. area
2216 2216
corr. V.
100.00 160.00
'322 C A L C U L A T I O N
lobalC 1> =
1.0107
= 257.0
rst peak is- b a s e l i n e d r o p c o r r e c t e d area. :ond peak is tang e n t s k i m m e d c o r r e c t e d area.
-ik R. T. f irst
max 1ast peak
l nin . s c an sc an s c a n w i d t h
raw area
1 0.000 2 6.060
252 252
0 251 6 251
-1 -1
8 0
c orr. area
2692 2692
corr.
%
160.00 100.06
0 + 32 2 )/<332 +334) CALCULATI ON
G l o b a l < 3) =
.0473
23 /)/<332 + 334) CALCULATION
Globali 3) =
.5177
? 3 Fr - --- -- v-v i0
_
7 A "T *\ ;
?1D ai M L ,
- i
-
-i ?"
0C096
C11370
MS data file header from >B2879
Sample: 2UL UT-2641
Operator; GARY
MS
9 / 0 7 / 8 4 13:46. ..
Mise i SP2330 200-1/3/250 RUN BTL451 BTL#51
Sys. #:
1 MS model: 87 SU/HU rev.: CA ALS : 0
Method file: SP2330
Tuning file: APEI01
No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
Transfer line temp. : 0 -
Chr o m a : ogr a p h i c t e m p e r a t u r e s : 50. 300. 0. 0. 0.
Chromatographi c t imes t min. : 8.0
2. 0
0.0
0.0
0.0
C h r o m a t o g r a p h i c rate, d e g /min: 2 0 . 0 0. 0 0. 0 0 . 0 0.0
M/Z = 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d pe ak is t a n g e n t s k i m m e d c o r r e c t e d area.
P t ak *
R.T. first
min.
s c an
max sc an
1ast peak scan width
raw area
corr. area
c orr.
1 11.969 236 237 242 2 11.969 236 237 242
6 79315
51649
100.00
6
79315
28558
55.29
M/Z = 331.9
Firs t peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P e ak I
R.T. first
min.
scan
m ax sc an
1ast peak sc an w i d t h
raw area
corr. area
c orr.
X
1 11.99 234 238 246 2 11.990 234 238 246
12 63 3 5 7 12 6 3 3 5 7
37149 36297
190.00 97.71
332/33 4 CALCULATION
R - G 1o b a 1 C 0> =
.7193
-- ....
M/Z = 327. 9
F i r s t p e ak is b as e li n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P ak
R.T. f ir s t min. s c an
max sc an
1ast peak sc an w i d t h
raw area
1 11.990 233 238 248 2 11.990 233 238 248
15 82503 15 82503
" ' ''' 1Hv
corr. area
corr.
*
45483 ` 108.00
43998
96.74
M/Z * 321.9
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d ar ea.
!
Peak *
1 2
R.T. first
min.
scan
0.060 0.000
249 249
m ax sc an
0 0
1ast peak sc an w i d t h
248 -1 248 -1
raw area
0 0
corr. are a
2164 2164
corn.
100.08 100.00
00098
C11372 :
5
tl/Z * 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Peak
R. T. f ir s t
min.
scan
max scan
1asi peak scan width
raw area
1 0.000 2 0.00O
249 249
0 248 0 248
-1 -1
0 0
corr. area
2180 2180
c orr. *
100.00 100.00
320^322 CflLCULRTION R - G l o b a l < 1> =
1.0074
ns2 = 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P ak #
R. T. f i r s t
min.
sc an
max sc an
1ast peak sc an wid t h
raw area
1 0.000 2 0.000
249 249
0 248 0 248
-1 -1
0 0
corr. area
2651 2651
corr. /i
100.00 100.00
(320 + 322)/(332 +334) CflLCULRTION
R - G l o b a l ( 3) =
.0489
(328' )/(332 + 334) CflLCULRTION
R - G 1o b a 1( 3) =
.5120*
00099
V
* tr
C11373
n i e >BZS 3 3 3 . 6 - 3 3 4 . 6 *mu.2UL UT-2642
SP2330 266-1/3/250 RUH BT
ir*, at >m tv ( m u N'lttvi'ii ii i' 1( *: t * * m n i f >nt,ivir
File >2600 321.6-322.6 Amu.2UL UT-2642
SF'2330 2 6 6 - 1 / 3 / 2 5 0 RUN BT
2000-
-
9-t"1'...... I T . 10,0 10,5 11.0
;
11.6 12.0
. :.\L
" L' 3JCr T: -- T :~ " 'E ORDER.
12.5 13.0 13.5 14.G 14.5 15.0
n m nr\
C l1374
Im nicniiirvn cH*nr$| tinai'MiccuNiHoisrip"'OHtniN i*1r)o niyvon*
MS data, f i l e h e a d e r f r o m ! > B 2 8 8 0
Sample: 2UL UT -2642
Operat or: CARY
MS
9/07/84--14::06- .
Mise : SP2330 200-1/3/250 RUN BTL453 BTL#53
S v s . ft:
1 MS model: 87 SW/HU rev.: CA ALS : 0
Method file: SP2330
Tuni ng file: APEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
T r a n s f e r 1 ine temp. : 0 *
Chromatograph!c temperatures : 50 C h r o m t o g r a p h i c times, min. : 0. 0 C h r omatographi c rate, deg/min: 20. 0
300. 2.0 0.0
0 0. 0 0. 0
0m
0. 0 0. 0
0. 0.0 0.0
M/Z * 333.9
F i rst p e ak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t ar g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. first min. sc an
max sc an
last peak scan width
raw area
corr. are a
c orr.
'A
1 11.970 235 237 241 2 11.970 235 237 241
6 71890 6 71890
44110 37189
100.00 84.31
M/Z = 331.9
First peak is b a s e l i n e
drop corrected area.
S e c o n d p e ak is t an g e nt s k i m m e d c o r r e c t e d area.
Peak #
R.T. first m in . sc an
rriax scan
1as t p e ak sc an w i d t h
raw area
corr. area
c orr. /.
1 11.970 233 237 246 ' 13
2 11.970 233 237 246
13
57077 57077
30583 29023
100.00 94. 90
332/334 CALCULATION P - C l o b a l < 0) =
.6933
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
* Peak
*#
R.T. first
min.
scan
max sc an
1ast peak sc an width
raw area
1 11.990 234 238 249 2 1 1.996 234 238 249
15 80120 15 8 0 1 2 0
M / Z = '3 2 1 . 9
First peak is b a s e l i n e
drop correc ted area.
S e c o n d pc ak is t a n g e n t sk im m e d c orr.ee t ed area.
Peak *
R.T. "firs t ruin . s c a n
max sc an
1ast peak scan width
raw area
1 0.000
-c"k 0 . 0 0 0
250 250
0 249 0 249
-1 -1
0 0
olici
corr. are a
42785 42425
corr. *
100.00 99.16
cor r . ar e a
2146 2146
corr.
100.00 100.00
Cl1375
Nri iif
I
M-'Z = 319.9
^7880
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Pe ak
R. T. fi rst
min.
sc an
max sc an
1ast peak scan width
raw area
corr. area
1 0.000 2 0.000
250 250
0 249 0 249
-1 -1
0 2025 0 2025
c orr.
100.00 100.00
320.-322 CALCULATION R - G l o b a l C 1) =
.9434
M-'Z = 2 5 7 . 0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Pe ak *#
R. T. f irst m in . scan
max sc an
1ast peak sc an w i d t h
raw area
1 0. 008 2 0.000
250 250
0 . . 249 0 249
-1 -1
0 0
corr. are a
2635 2635
corr.
y.
100.00 100.00
(320 + 3225/(332 +334) CALCULATION
R - G l o b a l ( 35 =
.0558?
<32S 5/ (332 + 334 > C A L C U L A T I O N
R - G l o b a l < 35 =
.5726
t
'W
00102
c c c (5\
z
G11376
HU NiMfi
HIV*MIN Oinlllll
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File >B2S81 333.6-334,6
iJif <<'* *ir.r.ii.t:i t ;
ilit ,..111 in
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C11377
00103
li OJ
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400000
GC/MS default file: >B2881::01
MS data file header from : >B2S61
Sample: 2UL 10.68/.48/.19
O p e r a t o r s GfiRY
MS
9/07/84
Misc : SP2330 260-1/3/250 RUN BTL#17 BTL*17
Sys. is
1 MS model: 87 S U / H U reu.s Cfi RLS # : 0
Method files SP2330
Tuning file: RPEI01 No. of e x t r a records:
S o u r c e t e m p . : 25 0 R n a l y z e r temp. :'
0
Transf er 1ine temp. :
14:29 0-
1
Chromatographi c t e m p e r a t u r e s : 50.
300.
6.
0.
0.
Chromatographi c times, min. : 0.0
2.0
0.0
0. 0
0.0
Chromatographi c rate, deg/min: 20.0 0.0 0.0 0.0 0.0
- j. !_
M/Z * 333.9
First peak is b a s e l i n e drop c o r r e c t e d area.
S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. first
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr. ar ea
corr. Ji
1 11 .996 236 2 33 24 0 2 11 .990 236 2 3 8 2 4 0
4 92020 54400 100.00
4
92020
44332
81.49
M/Z = 331.9
First pe ak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d pe ak is tangent. s k i m m e d c o r r e c t e d area.
Peak
R ,T .' first
min.
sc an
m ax scan
1ast peak sc an width
raw area
c orr. area
c orr. Ji
-C"1.i
1 1.990 11 .990'
235 235
233 238
246 246
11 11
68116 68116
42409 36254
100.00 85.49
m in im o n<w m im
r.o m m u s
(fi) m c n u u i n c cM *nsJ
332/334 CRLCULBTION R - G 1ob al < 0) =
.7 7 9 6
M-Z = 327.9
F i rst peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
P e ak *
R. T. f i r s t
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 12.010 233 239 247 2 12.010 233 239 247
14 120 0 5 7 14 12 0 0 5 7
M/Z = 321.9
:
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. first
min.
scan
1 12.010 2 12.010
236 236
max sc an
239 239
1ast peak sc an w i d t h
243 7 243 7
raw area
2264061 2264061
00104
-- ____ " ..
`P JD i-- -!---- :* t,
corr. area
85295 82537
corr. J;
100.00 96.77
*"
corr, are a
1781339 1746367
corr.
100.00 98.04
C11378
N< l I i p < i p V O f i f n I O
WbO.M.N o iv ijo ii kotitinjiio.t
s ft.yZ = 319.9
>%M\
First peak is baseline drop corrected are*. Second peak is tangent skimmed corrected area.
Feak
R.T. fi rst
min.
sc an
tnax sc an
1ast peak sc an wi d t h
raw area
corr, area
1 12.010 235 239 252 2 12.010 235 239 252
17 1508291 1 4 2 5 9 3 3 17 1500291 1 4 1 2 4 3 5
corr. *
100.00 99.05
320-^322 CflLCULRTI ON R-GlobaK 1) =
.8005
M.'Z = 2 5 7 . 0
F irst peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent sk i m m e d c o r r e c t e d area.
Pe ak
R.T. first
min.
sc an
max scan
1ast peak sc an w id t h
raw ar e a
1 12.018 234 239 250 2 12.010 234 239 250
16 1201846 16 1 2 0 1 8 4 6
corr. area
1160166 1137966
corr. *
100.00 98.09
(320 + 322 5/(332 +3345 CALCULATION
R - GlobalC 35 =
33.1299
( 3 2 8 " 5 / ( 3 3 2 + 3345 CfLCULflTION
R.-Globa1( 35 =
.7155
m u H 3 U M P U o a i u 1`j;
SU3JECT TO P R O T rc -:- -r '
c\fAr\r-
C11379
t i n him
Mii-trM in iiivumi
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ra n
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SF'2336
Tile >B23S2 333.6-334.6 amu.^UL UT-2643
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C11380
CC/MS default file: >B2882::01
MS data file header from i >B2882
Sample: 2UL UT-2643
Operator: GARY
MS
9/07/84
Mise : SP2330 200-1/3/250 RUN BTL#55 BTL455
Sys. #:
1 MS model : 87 SU/HU rev. : CA ALS : 0
Met hod file: SP2330
Tuning file: APEI01 No. of e x t r a records:
S o u r c e temp . : 2 5 0 A n a l y z er t e m p
0
Transfer line temp. :
14:51.
C h r o m t ographi c temperatures : 50. Chro m a t o g r a p h ic t imes, min. : 6.0 C h r o m a t o g r a p h ic rate, d e g / m in : 2 0 . 0
309. 2.0 0. 0
0. 0.0 0. 0
0 0. 0 0. 0
0. 6.0 0.0
M/Z = 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second p e ak is tangent s k i m m e d c o r r e c t e d area.
Peak -4
R. T. f i rst
min.
scan
max scan
1ast peak sc an w idt h
raw area
corr. area
c orr.
'4
1 11.969 235 237 246 2 11.969 235 237 240
5 73051 5 73051
42316 32978
100.06 77.93
M/Z = 331.9
F i rst p t ak is b a s e l i n e dr o p c o r r e c t e d area. Se c ond peak is t a n g e n t s k i m m e d c o r r e c t e d area.
P e ak
R. T. f i rst m in . scan
max scan
1ast peak sc an u idt h
raw area
corr. -a r e a
corr.
'4
1 11.969 233 237 248
15 64 164
33924
100.00
11.969 233 237 248
15
64164
32559
95.98
. n tim o t R rm ipf'nam tN mir tM O w w fn n
k^nr, cnitpiN G C M in r il
332/334 CALCULATION
P - G 1 b a 1< 0> =
.8017
M-'-Z = 3 2 7 . 9
su^ fic r ro
P R o n c r iV5 ` ; one
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
$t Peak
#
R.T. first m in . sc an
max s c an
1ast peak sc an w i d t h
raw area
corr. area
c orr.
y
1 11.990 233 238 248 2 11.990 233 238 248
15 85508 15 8 5 5 0 8
49448 47153
166.00 95.36
M/Z - 321.9
First peak is b a s e l i n e
drop correc ted area.
S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Pe ak
P. T. first
min.
sc an
m ax scan
1ast pe ak sc an w i d t h
raw area
corr, area
corr.
1 0.060 2 0.060
249 249
0 248 6 248
-1 -1
0
2233
106.00
0
2233
160.00
--j
G 11381-
'c-'| ni r i i n u i N i i i : n i n r s | cnni'itir.rnNmnt s r,(mrin.iioM n i i f i i i n wrw on*
s
M/Z 319.9
First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area.
Feak
R. T. first
min.
sc an
max sc an
1ast peak s c a n ui dt h
rau area
1 0.000 2 0.000
249 249
0 248 0 248
-1 -1
0 0
corr. area
2162 2162
c orr. J;
100.00 100.00
320/322 CALCULATION R - G l o b a l C 1) =
.9682
M/Z - 257.0
First peak is baseline drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. first
min.
sc an
max scan
1ast peak sc an w i d t h
rau area
1 0.000 2 0.000
249 249
0 248 0 248
-1 -1
0 0
corr. ar c a
2557 2557
c orr. *
100.00 100.00
<320 + 322)/< 332 +334) CALCULATION
R - G l o b a l < 3> =
.0 5 7 6
<328')/<332 + 334) CALCULATION
R -- G l o b a l e i1 ~
.6483
c j
7 0 iMt'IO
NO Iic
rr-
-
.. ..c \_ L ,
SUBJECT TO PROTECTIVE CRCET.
0010A
C11382
File >E2SS3 333.6-334.6 .2UL UT-2644
SP2336 20O-1/3/250 RUIN BT
100005000-
J
0 -i-- i-- i-- i-- i-- i-- i-- i-- |-- i-- i-- i-- i-- | i i i-- i-- |-- i-- i-- i-- i-- |-- i-- i-- i i |-- i-- i-- i-- r - ]-- i-- i-- i-- i-- |-- i-- n -- r--j-- i i i-- r - ) 10.0 10.5 11.0 11.5 12.0 12.5 13.0 3.5 ' 14.0 14.5 15.0
File >B2B83 331.6-332.6 amu .2UL UT-2644
SP2330 200-1/3/250 RUH BT
4000-
1 '' ' | i 1 ' 1 1 i 1 11 i i
10 .0 18.5
1.0 11.5 12.0 12.
>B2883 327.6- . 6 artiu .2 U L U T - 2 6 4 4
13*. 0 '13*. 5 ' '14*. 0 ' '14*. 5 ' 'lV.0 SP2330 200-1/3/250 RUH BT
8000-
4000-- /v-- ^
o- ----1--T-- -10.0 10.5 11.0
V_/\-- 1i ' 11 1 i 1 1 1 i 1 11 1i 1* ' i1 ' 1 1 i i 1 1 1'i 11.5 12.0- 12.5 13.0 13.5 14.0 14.5 15.6
File >2883 3 2 1 . 6-322.6 amu.2UL UT-264'4 J
8600"
S P 2 3 3 0 2 6 0 - 1 / 3 / 2 5 0 RUIN BT
4000-
J
F ile
0 " |-- -- -- [--1-- -- i-- 1-- I-- I-- I-- 1-- i-- 1-- i-- |-- i-- i--i-- i-- I-- i-- i-- I I 1-- m -- i-- r-|-- i-- i-- i-- i-- |-- i-- i-- i-- i-- -- i-- r--i-- i-- |-- i-- i-- i-- i-- | 1O.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 15.0
>2833 3 1 3 . 6 - 3 2 0 . 6 amu . 2UL U T-2644
3F'2330 200 - 1/3'250 RUN BT
4000-
''Van*
10'. 0 F i l e >2883
4000-
10'.5 11'.0 11'.5 12.0 12'.5 2 5 6 . 7 - 2 5 7 . 7 amu . 2UL U T-2644
V--
1 3 .0 1 3 . 5 14'.0 1 4 .5 153'. O...
(T^;-"SP*'233-0"2 0 0 - 1 / 3/ 2 5 0 RUN
BT
_
i .,* f & i r - ------ '
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J c L ` l 0 PHOTECTJ','E OROER.
..................................................
10.0 10.5 11.0
.p
11.5
12.0
12.5
13.0
1I
||
13.5 14.0 14.5
15.0
OCIOS
C11383
(oil n ic a n p iN G c h a r t s '] r.n .p iu c itmnihoi 5 ctinpnHArioN hvffm o nfw tP*
GC/nS default file: >B2883::Q1
MS data file header from i >B2883
Sample: 2UL UT-2644
Operator: GARY
ns
9/07/84 15:11.
disc : SP2330 200-1/3/230 RUN BTL#57 BTL#57
Sys. #!
1 ns model : 87 S U / H U r e v . : CA A L S : 0
dethod file: SP2330
T u n i n g file: APEI01 No. of e x t r a r e c o r d s : 2
Source temp.: 250 Analyzer temp.
0 T r a n s f er 1ine temp. : 0 -
C h r o m a t o g r a p h ! c t e m p e r a t u r e s : 50. 300. 0. 0. 0. C h r o m a t o g r a p h ! c t imes, mi n. : 0 .0 2. 0 0. 0 0 . 0 0. 0 Chromatographic rate, deg/min: 20.0 0.0 0.0 0.0 0.0
n/2 333.9
F i rst peak' is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak tf
R. T. fi rst
min.
scan
max scan
1ast peak scan u idth
raw area
corr. area
corr. *
1 11.963 239 240 245 2 11.963 239 240 245
6 64015
38083 100.00
6
64015
27307
71.70
M/Z = 331.9
First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak *
R.T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr.
1 11.984 235 241 251 11.984 235 241 251
16 59207 16 5 9 2 0 7
26615 25775
100.00 96.84
332/334 CALCULATION R - G l o b a l C 0) =
.6989
*
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
P e ak
4
R.T. first m in . sc an
max scan
1ast peak sc an width
raw area
1 12.084 238 242 251 2 12.004 238 242 251
13 7 2 1 8 7 13 72187
n/z * 321.9
F irst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak
R.T. f irst
min.
sc an
max scan
1ast peak scan width
raw area
1 12.004 240 242 247 2 12.004 240 242 247
7 49469 7 49469
ocim
corr. area
39973 38348
c orr. *
100.00 95.93
-
corr. area
26432 19372
corr.
%
100.00 73.29
01138^
NO HP 9 2 7 0 O M O
s M/Z 319.9
First peak is baseline drop corrected res. Second peak is tangent skimmed corrected ire*.
Peak
R. T. f irst min. scan
max scan
1ast peak sc an ui dt h
rau area
1 12.004 ' 240 242 249 2 12.004 240 242 249
9 39755 9 39755
corr. area
18911 13560
c orr.
%
100.00 71.70
320^322 CRLCULRTI OH
R - G l o b a l < 1) *
.7155
M/Z- 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak
R. T. fi rst
min.
sc an
max sc an
1ast peak scan width
rau area
1 12.004 240 242 249 2 12.004 240 242 249
9 41947 9 41947
corr. area
17323 14335
corr. *
100.00 82.75
C320 + 322 ) / ( 3 3 2 + 3 3 4 ) `C R L C U L R T I ON
R - G l o b a l C 3) =
.7008
328')/<332 + 334) CRLCULRTION
R - G l o b a l C 3)
.6142
OCill
C11385
File >B2884 333.6-334.6 amu SUL UT-2645
SP2330 200-1/3/250 RUN BT
i<'i n> <:u n u i f i u * ; n T ; p t; iM r n ir
File >B2884 321 .6-322.6 amu.^UL UT-2645
SP2330 200-1/3/250 RWN BT
_s ! i "w :i i
SUB.iFTT T O PDATri-Tu/ir o n n r n
n r - f -i o
G11386
fJi 1 H(* U ^ y ( > C * f t A O
GC/ilS default file* >B2684*i01
MS data file header, from i >B2884
Sample* 2UL UT-2645
Operator* GARY
US
9/07/84
Hi sc t S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N B T L 4 5 9 B T L 4 5 9
$y%. t
1 MS Model* 67 S W / H W rev.i CA ALS * 0
. Hethod file* SP2330
T u n i n g file* APEI01 No. of e x t r a record:
Source temp.: 250 Analyzer temp.it
0
T r a n s f er 1 ine temp.. :
1S 3 1 ___
C h r o m a t o g r a p h ic t e m p e r a t u r e s : 50. C h r o m a t ographi c t imes i min. : 0.0 Chromatographic rate, deg/mini 20.8
3 0 0 i^ 2. 0 0. 0
0. 0.0 0.0
0e 0. 0 0. 0
0. 0.0 0.0
n/Z 333.9
F i rst pcalc is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent sk i m m e d c o r r e c t e d area.
Peak
*
R. T. f i r s t
min.
scan
max sc an
1ast peak scan width
raw area
corr. area
corr.
y.
1 11.969 236 237 240 2 11.969 236 237 240
4 63191 4 63191
33383 28653
100.80 85.63
n/Z 3 3 1 . 9
First pe ak is b a s e l i n e dr o p c o r r e c t e d area. Sec ond peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. f irst
min.
scan
max scan
1ast peak scan width
raw area
corr. area
corr.
y.
1 11.990 235 238 246
11
52378
27661
100.00
2 11.990 235 238 246
11
52378
26385
95.39
coniroisi:oh>h*ion pufpalowrwtora
* fSTREConutNo crtnii]
332/334 CALCULATION
R - G l o b al < 0> =
.8286
n/z = 3 2 7 . 9
F irst peak is b a s e l i n e drop c o r r e c t e d area. Se c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
c T-
S U B J E C T 1:
^ __ 1 '
-TCVE ORDER.
Peak
4
R.T. f irst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr.
y.
1 11.990 235 238 248 13 73204 4 4 0 1 9 1 0 0 . 0 0
2 11.990 235 238 248
13 73204
42550
96.66
n/z - 32 1 . 9
F irst peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak *
R.T. fi rst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
corr. area
11387
corr.
1 12.010 237 239 243 2 12.010 237 239 243
6 23045 6 23045
0G113
8567 6206
100.00 72.95
No Hp(i? 7 0 0 firt0
5
M/2 319.9
First peak is baseline drop corrected tret. Second peak is tangent skimmed corrected &rr*.
Peak
R.T. fi rst
min.
sc an
max sc an
last peak scan. w i d t h
raw area
1 11.990 235 238 245 10 2844 2 11.990 235 238 245 10 28464
>3w&\
corr. area
6954 6474
corr. 4
100.00 93. 10
320/322 C L C U L T ION R - G l o b a l < 1) =
.8174
M / 2 = 2 5 7 . 0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. first min. scan
max scan
1ast peak sc an w i d t h
raw area
1 12.010 235 239 245
10 3 1 6 8 7
2 12.010 235 239 245 10 31687
corr. area
7487 6737
corr. 4
100.00 89. 98
<320 + 322)/<332 +334) CflLCULRTION
R - G l o b a l < 3) =
.2533
<328') / <332 + 334) CRLCULflTlON
R - G l o b a l < 3) -
.7198
C*
X o
z u6
--
____________ - i i - > A ! L
SUBJECT TO PROTECTIVE ORDER.
00114
C11388
rc-
c\
z
File >B2S85 333.6-334.6 *mu 2UL .2669/.48/.19 SP2330 206-1/3/250 RUN BT File > B 2 8 8 5 3 2 1 . 6 - 3 2 2 . 6 a m u . 2 U L .2669/ .48/ .19 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT
< , n * P m c i,iiriMir>i
GC/NS default filet >B2885::01
US data file header from t >B2885
Samplet 2UL .2669/.48/.19
Operalori GRRY
HS
9/07/84 15:54-
ttisc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N B T L # 2 9 B T L # 2 9
S y s . #:
1 NS modelt 87 SU/HU reu.i CR ALS : O
Nethod filet SP2330
T u n i n g file: RPEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.i
0
Transfer line temp, : 0 -
C h r o m a t ographi c t e m p e r a t u r e s t 50.
300.
0.
0.
0.
C h r omatographi c t im e s , min. : 0.0 2.0 0.0 0.0 0.0
Chromatograph! c rate, deg/mint 20.0 0.0 0.0 0.0 0.0
n/Z 333.9
First peak is bas e l i n e drop c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R. T. f irst
min.
sc an
max sc an
1ast peak sc an w i d t h
rau area
corr. area
corr. */.
1 11.969 236 237 242 2 11.969 236 237 242
n/z = 331.9
6 66036 41466 100.00
6
66036
25473
61.43
First peak is base 1ine drop c o r r e c t e d area. S e c o n d p e ak is t a n g e n t s k i m m e d c o r r e c t e d area.
P e ak
R. T. fi rst
min.
scan
max sc an
1ast peak sc an uh dt h
raw area
corr. area
corr. 7.
1 11.969 227 237 255
28
85164
29164
100.00
2 11.969 227 237 255
28
85164
27330
93.71
le l'm c o n iM t c i i a m s i G iu rin e i.P N tn o is C im ra n M iO N n u i u i i t n i w i m
332/334 CALCULATION R - G l o b a K 6> =
.7033
n/Z = 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak
R.T. fi rst min. sc an
max sc an
1ast peak scan width
raw area
1 11.990 231 238 251 20 85511 2 1 1.990 231 238 251 20 85511
N/Z - 321.9
F irst peak is base 1ine drop corrected area. Second peak i s t angent skimmed corrected area.
Peak 4.
R.T. f irst
min.
sc an
max sc an
1ast peak sc an width
raw area
1 12.010 237 239 243 2 12.010 237 239 243
6 47193 6 47193
corr. area
42731 41161
corr. *
100.06 96.33
c orr. area
25685 18531
corr. *
100.00 72.37
C11390
N il u p (*? 7 0 0 fi/10
IUO. M ill OlVJJiltl NOIlVIlU.mOJ SIOIIINI) I
s n/Z - 319.9
First peek is baseline drop' corrected ere*. Second peek is tengent skimmed corrected ere*.
Peek tf
R.T. fi rst
min.
seen
mex sc en
1est peek seen u idt h
r*u eree
1 11.990 235 238 247 2 11.990 235 236 247
12 46973 12 46973
corn. eree
22229 21065
corr. 7.
100.00 94.76
320/322 CALCULATION R - G 1 o b * l < 1) =
.6662
M/Z = 257.0
F irst peek is b a s e 1 ine d r o p c o r r e c t e d eree. Second peek is tengent s k i m m e d c o r r e c t e d eree.
Peak
R.T. first
min.
seen
max seen
1est peek seen u idt h
ray eree
1 12.010 235 239 246 2 12.010 235 239 246
11 4 5 6 6 6 11 4 5 6 0 6
corr. eree
18933 17981
c orr. 7.
100.00 94.97
<320 + 322)/<332 +334) CALCULATION
R - G 1 o b e l C 3) =
.6772
C328'')/(332 + 334) CALCULATION
R - G l o b a l C 3) =
.6017
e ?
m n H J 0 I QUO 3 1 u [.-J
( c l 11 o n
/
V-r"
SUBJECT TOprotective o r d e r
OC 117
011391
OC 118
C11392
e >2890 3 3 3 . 6 - 3 3 4 . 6 * m u . 2 U L .i0 6 8 / . 4 8 / . 19
SP2330 200-1/3/250
ET
44
.le > 2 8 9 6 3 2 1 . 6 - 3 2 2 . 6 a m u .S U L .10 6 8 / . 4 8 / , 1 9
SP2330 200-1/3/250
BT
* z 3
|4
z3
0C119
C11393
QQ/I
|( h i r o n t i i N t ; c H n n i < i | i;nptiic c o m i n o ) S coneniiAiioN n u f r * io n f w ( " *
S M/Z * 319.9
> > 9^ o
First peak is basel i nt drop corrected ere*.
Second peak is tangent skimmed corrected area.
Peak
R.T. fi rst
min.
sc an
max sc an
.1 ast peak s c a n ui dt h
raw area
1 11.777 218 225 238 20 71761 2 11.777 218 225 238 20 71761
corr. area
30181 29711
c or r . 5!
100.06 98.44
320/322 CALCULATION R - G 1obal < 1) *
.8200
M/Z 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R.T. f irst m in . sc an
itiax scan
1ast peak scan w id th
raw area
1 11.777 219 225 237 18
2 11.777 219 225 237
18
64139 64139
c orr. area
19013 17528
com. *
100.00 92. 19
(328 + 322 >/(332 +334) CALCULATION
R - G l o b a l ( 3) =
.2547
(3 2 S ' >/(332 + 334) C A L C ULATION
R - G 1obalC 3> =
.3587
/
CT r o protective: \s * \ k n
0G1 2 1
z
C11395
Flit >B2691 333.6-334.6 *mu.2UL 1.058/.48 19
SP2339 208-1/3/250
BT
F i l e > 2 8 '?1 3 2 1 . 6 - 3 2 2 . 6 a m u . S U L 1 . 6 8/. 48/. 19
SP2330 200-1/3/250
BT
OC 122
cll396
MS data file header from : >B2891
Sample: 2UL 1.868/.48/.19
Operator: GARY
Mise : SP2330 200-1/3/250
BTL405 BTL#
$ys. #:
1 MS model : 87 S U / H U rev.: Cfi
Method file: SP2330
Tuning file: RPEI01
Source temp.: 250 Rnalyzer temp.:
0
MS 9/10/84 22:04--- ^ 5 RLS # : 0
No. of e x t r a record: 2 T r a n s f e r line temp. : 0
Chromat ographi c t emperatures : 50.
300.
0.
0.
0.
Chromatographi c times, min. : 0.0
2. 0
0.0
0.0
0.0
C h r o m a t o g r a p h ic rate, d e g / m i n : 2 0 . 0 0.0 0. 0 0. 0 0. 0
M/Z - 333.9
Fir s t peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R. T. fi rst min. scan
1 11.764 2 11.764
223 223
max scan
229 229
1ast peak scan width
254 31 254 31
raw area
225099 225099
corr. area
166447 162045
corr. *
100.00 97.36
.
M/Z * 331.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area.
P e ak
R.T. first
min.
sc an
max scan
1ast peak scan width
raw area
corr. area
corr. *
1 11.764 223 229 243 2 11.764 223 229 243
20 172067 130947 100.00 20 172067 128637 98.24
(oil n i c o r d in o t i i a H T S l r.tiA .i.ii; r o N in tn s cOHf**R*iON n u r i i n h i * to
332/334 CALCULATION R - G l o b & l < 0? =
.7867
M/Z * 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
s u b j e c t to p*o t; _ ' -
n u ltCTIVr ,
Peak /4
R.T. fi rst
min.
sc an
max scan
1ast peak scan width
raw area
corr. area
corr.
4`
1 11.785 223 238 24 6 2 11.785 223 230 246
23 158160 111378 100.00 23 158160 108813 97.70
M/Z 321.9
F irst peak is base 1ine drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R.T. fi rst
min.
sc an
max sc an
1ast peak sc an w i d t h
raw area
corr. are a
corr.
1 11.785 225 230 246 2 11.785 225 230 246
21
401804
359909
100.08
21 4 0 1 8 0 4 3 5 1 2 7 8 97. 60
C11397
n f-i/lfl
NO u p
5
MxZ * 319.9.
First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent s k i m m e d cprre c t e d r*.
Peak tt
R. T. f irst
min.
scan
max scan
1ast peak s c a n ui d th
rau area
1 11.765 219 230 256 2 11.785 219 230 256
37 380462 37 380462
corr. area
309718 300357
corr.
4%
100.00 96.98
.
320*'322 C A L C U L A T I O N R - G l o b a l < 1) *
.6605
M / Z '* 2 5 7 . 0
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is tangent, ski mm e d c o r r e c t e d area.
P ak -
R.T. f irst
min.
sc an
max sc an
1ast peak scan width
rau area
1 11.785 224 230 251 2 11.785 224 230 251
27 252992 27 252992
corr. area
185114 182408
corr.
4`
100.00 98. 53
<320 + 322)s <332 +334) CALCULATION
R - G l o b a l < 3) =
2.2516
<328'> '(3 3 2 + 3 3 4 ) C A L C U L A T I O N
R - G l o b a l < 3) =
.3636
i
I
I
?
G
. object'TO r;R O T ? -- 00123
C11398
c
crrc\>.
zC
le >B2897 333.6-334.6 *mu.2UL 19.68/.48/.19 SP2330 200-1/3/256 RUH BT
'ile > B 2 8 9 7 3 2 1 . 6 - 3 2 2 . 6 an.u.2UL 10.68/. 48/. 19 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT
l'
I|f|
i
351
OC 124
C11399
nu*M Ln w * r n n
s M/Z 319.9
yinum
First peak is baseline drop corrected area. Second peak is tangent skimmed, corrected area.
Peak
R.T. first mi n. sc an
max sc an
1ast peak sc an ui dt h
raw area
corr. area
1 11.610 213 229 253 2 11.810 213 229 253
40 2778746 2694226 40 2778746 2666846
c orr. ii
100.00 99.06
*"
320/322 CALCULATION *
R - G 1 o b a l ( 1> -
.6272
M / Z ` 257.0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak -#
R.T. f irst
min.
sc an
max scan
1ast peak sc an w i d t h
raw area
1 11.830 216 230 249 . 33 1801888
2 11.836 216 236 249
33 1601888
corr. area
1722160 1693268
corr.
106.00 98.32
C320 + 3 2 2 > / C 3 3 2 + 334) CALCULATION
R - G l o b a l < 3> =
23.6167
(328'' > / < 3 3 2 + 3 3 4 ) C A L C U L A T I O N
R - G l o b a l < 3) =
.3356
( S ( n t c o n o i M O c i < * n i s | f i n * . m e r u N i n o i s i :<i h m * m a m o n
N o HP n ? / 0 iir 1 0
00126
C11401
File >B2S99 333.6-334.6 amu.2UI_ UT-2629D
SP2330 200-1/3/258 RUH BT
File >2399 321.6-322.6 amu.SUL UT-2629D
SP2330 208-1/3/250 RUH BT
I; i
0G12.-7
011402
GC/MS default filii >B2899:i01
MS data file header from i >B2899
Sample* 2UL UT-2629D
Operatori GARY
MS
9/11/84
Mi sc I S P 2 3 3 0 2 0 0 - 1 ^ 3 / 2 5 0 R U N B T L * 2 1 B T L # 2 1
Sys. :
l MS m o d e l i 87 S U / H U reu.t Cfl A L S i 0
Method filei SP2330
Tuning file! APEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp. :
0
Transfer 1ine temp. :
01.44..
Chromatograph!c temperatures i 50.
300.
0.
0.
0.
C h r o m a t o g r a p h ! c t imes| min. i 0. 0 2 . 0 0 . 0 0 . 0 0. 0
Chromatograph!c rate, deg/mint 20.0 0.0 0.0 0.0 0.0
M/Z - 333.9
First peak is bas e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t sk im m e d c orreci ed area.
Peak
R. T. fi rst
min.
sc an
max sc an
1ast peak ' s c a n ui dt h
rau area
corr. area
corr. 7.
1 11.789 225 228 238 2 11.789 225 228 238
13 3 9 4 0 8 13 3 9 4 0 6
12251 11952
100.00 97.56
M/Z 331.9
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d 'area.
Peak *
R. T. f irst min. sc an
max scan
1ast peak sc an ui dt h
rau area
corr. area
corr. *
1 11.809 224 229 234 2 11.809 224 229 234
10 31155 10 3 1 1 5 5
10345 9205
100.00 68.98
C Oftpfrvo C H A R r r ] ORIFft'C CIJNIHOIS rDPWHArp>M IM IfM lO NiW
yl
332/334 CALCULATION R-Global(
ii G
.8444
M/Z - 327. 9
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
, Peak
#
R.T. fi rst m in scan
max sc an
1ast peak s c a n wi dt h
rau area
1 1 1 . 6 0 9 2 2 6 22 9 23 7 11 4 2 3 2 4 2 1 1 . 8 0 9 2 2 6 2 2 9 2 3 7 11 4 2 3 2 4
M/Z - 321.9
First peak is bas e l i n e drop c o r r e c t e d area. Second peak is tangent sk i m m e d c o r r e c t e d area.
Peak
R. T. fi rst
min.
scan
max sc an
1ast peak sca n u idt h
rau area
1 11.809 225 229 239 14 35923 2 1 1 .809 225 229 239 14 3 5 9 2 3
0C128
-------
--1
'i'.i,
;^ -- ,_
s u b j e c t t . ' j - ^ '* ` -1 '-'TECTIVE ,
corr. area
10842 10039
corr.
y.
100.00 92. 59
corr. area
7629 7104
corr.
v.
100.00 93.12
elidila
N O IIP f*?
mi i m i ' n i w w *
M-'Z 319.9
F irst peak- is b a s e l i n e d r o p c o r r e c t e d area, Seco n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak ft
R.T. first
min.
scan
max scan
last peak scan uidth
rau area
1 11.630 225 230 234 2 11.830 225 230 234
9 24198 9 24198
co r r . area
5514 4443
corr.
100.00 80.58
320/322 CALCULATION R - G l o b a l ( 1> =
.7228
M/Z * 257.0
F irst peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area.
Peak tt
R.T. f irst min. sc an
max sc an
1ast peak sc an width
rau area
1 11.8B9 227 229 233 2 11.809 227 229 233
6 20973 6 20973
corr. area
4749 4080
c orr. *
100.00 85.91
(320 + 322 >/(332 +334) CALCULATION
R - G l o b a l < 3> =
.581?
(32S'>/(332 + 334) CALCULATION
R - G l o b a l ( 3) =
.4768
jStl R f c o M i N Q c i i f t m s ) a f l * r m c r o N t f l o i s
M O IH * 'l i '7 0 0 (> * 1 0
w3JECT TO PROTECTIVE ORDER.
OC15c9
C l 1404
Fil* >B2903 333.6-334.6 *mu.2UL .2669^.46/.19 SP2330 290-1/3/250 RUN BT
t
!
F
File >B2903 321 .6-322.6 amu.SUL .2669/.48/. 19 SP2339 2 0 0 - 1 / 3 / 2 5 0 RUN BT
T 3
0G130
C11405
MS data file header from i >B2903
Sample: 2UL .2669/.48/.19
Operator: GARY
MS
9/11/84- 2:05
Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN- B T L 4 2 9 B T L 4 2 9
Sys. 4:
1 MS mod e l : 87 S W / H M rev.: Cfi AL S # : 0
Method file: SP2330
Tuning file: RPEI01 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.:
0
T r a n s f e r line temp. : 0 ...
_.
Chromat ograph ic t e m p e r a t u r e s : 50.
300.
0.
0.
0.
C h r o m a t o g r a p h i c t im e s , min. : 0. 0 2.0 0 . 0 0 . 0 0. 0
Chromatographi c rate, deg/min: 20.0
0. 0
0.0
0.0
0.0
M/Z * 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4'
R.T. first min. scan
max scan
last peak s c a n ui dt h
rau area
corr. area
c orr.
y.
1 11.763 219 225 241 2 11.763 219 225 241
22
154286
109670
100.00
22 154286 105347 96.06
M/.Z = 3 3 1 . 9
First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n gent s k i m m e d c o r r e c t e d area.
P e ak 4
R.T. f irst
min.
scan
max scan
1ast peak sc an w i d t h
raw area
corr. area
corr.
y.
1 11.763 221 225 241 2 11.763 221 225 241
20 132155 20 132155
92415 88415
100.00 95.67
t i l t i l R CO n o m o C H A F S I nnAPMlC CONINOi S CnnrfTHAnON M IM U tO NfW TlW i1
332/334 CALCULATION R - G l o b a K 6) =
.8427
CJ. .
M/Z = 327.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R .T . f irst
min.
sc an
max scan
1ast peak scan width
raw area
1 11.783 221 226 242 2 11 .7 8 3 221 226 242
21 1 i e 8 3 9 21 1188 3 9
M/Z * 321.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R.T. f irst
min.
scan
max sc an
1ast peak sc an w i d t h
raw area
1 11.783 221 226 241 2 11.783 221 226 241
20 101979 20 101979
SUBJECT TO protective:o r d e r
corr. area
72248 68670
c orr.
X
100.00 95. 06
c orr. area
61939 60189
c orr.
100.00 97. 17
C11406
N l) H P (l ? 7 0 O filO
s
M/Z 319.9
First peak is b a s e l i n e drop c o r r e c t e d Ares.
S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R.T. f irst
min.
sc an
max sc an
1ast peak sc an ui dt h
raw area
1 11.803 222 227 240 2 11.603 222 227 240
18 66129 18 68129
corr. area
50347 50275
corr. *
100.00 99.66
320^322 CRLCULflTION R - G 1o b a l < 1> =
.6128
M / Z `= 2 5 7 . 0
First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d p e a k is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak * tt
R.T. fi rst
min.
scan
max sc an
1as t peak scan width
raw area
1 11.803 223 227 239 2 11.603 223 227 239
16 7 6 5 7 9 16 76579
corr. area
35907 3521 1
corr. 5i
160.00 98.66
<320 + 322 )/(332 +334) CALCULATION
R - G l o b a K 3)=
.5556
< 3 2 8 0 / ( 3 3 2 + 334) CALCULATION
R - G 1o b a l < 3)=
.3547
-
fiII
[
m i'M to
jcl n t c a n o i x n E M .n r s j GRtF-iitc ri>Ntni>i 5
N(1 M P < i ; ' 7 0 r i f i l o
J. -j
4
SUBJECT TO PROTECTIVE ORDER.
00132
C11407
File >B2907 333.6-334.6 *mu.2UL 2.669/ .48/ .19 SP2330 200-1/3/250 RUH BT
File >B2907 321.6-322.6 *mu.2UL 2.669/.48/.19 SP2330 200-1/3/250 RUN BT
C l1 4 0 8
MS d*t* file he*der from i >B2907
Sample: 2UL 2.669/.48/. 19
Operator* GARY
MS
9 / 1 l/84--15:-2? _
Mise i SP2338 208-1/3/250 RUN BTL#41 BTL441
Sys. 4:
1 MS model : 87 SU/HM r e v . i CA ALS : 0
Method file: SP2330
Tuning file: APE 101 No. of e x t r a records: 2
Source temp.: 250 Analyzer temp.i
0
T r a n s f er 1 in e temp. : . 0 *"
Chromatographi c t emperatures i 50.
300.
0.
0.
0.
C h r o m a t o g r a p h ! c times, min. : 0. 0 2. 0 0 . 0 0 . 0 0. 0
C h r o m a t o g r a p h i c rate, deg/mi n: 2 0 . 0 0. 0 0.0 0 . 0 0.0
*.
.
M/Z 333.9
F i r s t peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak *
R.T. fi rst
min.
sc an
max scan
1ast peak s c a n ui dt h
raw area
corr. area
corr.
y.
1 11.774 218 229 250 2 11.774 216 229 250
34 205931 34 205931
134089 133953
100.00 99.90
M/Z = 331.9
F irst pe ak is b a s e 1 ine d r o p c o r r e c t e d area. S e c o n d peak is t a n gent s k i m m e d c o r r e c t e d area.
Peak
R.T. fi rst
min.
sc an
max sc an
1ast peak scan width
raw area
corr. area
corr.
y
1 11.774 216 229 248 2 11.774 216 229 248
32 177960 112232 100.00
32
177960
108600
96.76
m
c'i wi c t i R o i m o C N A n f f | r . n * p n j c l u n i m o i s :4 o n r c m M i o n o u r r * L O N f w n ' w
^
332/334 CALCULATION
R-Global(0>= M/Z = 327.9
.8370
t?
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R.T. fi rst mi n. s c a n
max scan
1ast peak sc an w i d t h
raw area
corr. area
1 11.794 220 230 251 2 11.794 228 230 251
31 160851 31 160851
94325 94170
M/Z * 321.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak 4
R.T. f irst
min.
sc an
max sc an
.last peak scan width
raw area
corr. area
1 11.794 215 230 246 2 11.794 215 230 248
33 800755 735019 33 800755 717677
nrt,i o a
tjv e o r d e r .
c orr.
y*
100.00 99.84
corr.
y.
100.00 97.64
C11409
N O IH J i * ? 7 D O lia li )
tHOiHIN tlltn iM I NOMVtHMMU) S IOMINOJ ItlK.IVMO ( S i m i l i DWIOItOJIM I1- >1
M-Z 319.9
First pe ak is b a s e l i n e drop c orrec ted area. S e c o n d pe ak is t a n g e n t s k i m m e d c o r r e c t e d ar ea.
Feak #
R. T. f ir st
min.
sc an
m ax scan
1ast pe ak sc an w i d t h
r au area
1 11.794 223 230 257 2 11.794 223 230 257
34 694491 34 694491
c or r . are a
624893 616699
c or r .
y.
100.00 98.69
320^322 CRLCULRTION R - G 1o b a 1 c 1) *
.8502
M 'Z . 2 5 7 . 0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peek is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak
R. T. f ir s t
min.
sc an
max sc an
1ast pe ak scan width
r aw area
1 11.794 224 2 33 252 C. 11 . 7 9 4 224 2 33 2 52
28 504553 28 504553
corr. ar e a
434217 425355
corr.
V,
100.00 97.96
(320 + 322 >/ ( 332 *-334) CftLCULftTION
R - G 1o b a l ( 3 ) *
5.5209
(328')/(332 334 ) CRLCULRTI ON
R - G 1o b a l ( 3) =
.3561
*
I
I
l1 O N
0C 135
C11410
File >B2906 333.6-334.6 *mu.2UL 26.69/. 48/. 19 SP2330 208-1/3/250 RUH BT
File >E2?6B 3 2 1 . 6 - 3 2 2 . 6 amu.^UL 2 6 . 6 9 / . 4 8 / . 1 9 SP2330 2 0 0 - 1 / 3 / 2 5 0 RUN BT
OCI06
Cll411
MS data file header from : >B290S
Sample: 2UL 26 .69/.48/.19
Operatori GARY
1MS
9 / 1 1 / 8 4 -15 :-4? . .
Mise * SR2330 200-1/3/250 RUN . BTL43 BTL43
Sys. il
1 MS model 1 87 SU/HU reu. i CA ALS i I 0
M e t h o d fi 1e I S P 2 3 3 0
T u n i n g fi lei R P E I 0 1
Source temp.: 250 Analyzer temp .i
0
No. of e x t r a recordsi
T r a n s f e r l i n e temp. ms
2 0
Chromatograph!c temperatures I 50
300.
0.
0.
0.
C h r o m a t o g r a p h i c t i m e s , min. I 0. 0 2 . 0 0 . 0 0 . 0 0 .0
C h r o m a t ographic ratei deg/mini 20. 0
0.0
0.0
0.0
0 .0
M/2 333.9
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent skimmed corrected area.
Peak #`
R . T. f i r s t
min.
scan
max scan
last peak sc an wi dt h
raw area
corr. area
corr.
%
1 11.796 219 231 252 2 11.796 219 231 252
33
242219
171830
100. 00
33 242219
171401
99. 75
-
M<2 * 331.9
First peak is baseline drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak #
R.T. first
min.
scan
max scan
1ast peak scan width
raw area
corr. area
corr.
Am
1 11.816 224 232 244 2 11.816 224 232 244
20
181045
139325
100. 00
20 181045 1 3 9 2 2 5 99. 93
332/334 CALCULAT ION
R-Gl obal (. 0) =
.8108
M/2 = 327.9
First peak is base 1ine drop corrected area. Second peak is tangent skimmed corrected area.
^ W J L u /'?J'T7 +
S U!BR Jrcv-r
*
- ____
^ PPOTP'--
-' --
' - -U
n 'pVE
O
RvD E Z .
-
Peak 4
R.T. first
min.
scan
max scan
1ast peak sc an width
raw area
corr. area
corr. *
1 11.837 226 233 242 2 11.837 226 233 242
16
243276
208908
100.00
16 2 4 3 2 7 6
205100
98. 18
M/2 321.9
,
First peak is base 1 ine drop corrected area. Second peak is tangent skimmed corrected area.
Peak 4
R.T. first
min.
scan
max scan
1ast peak sc an wi d t h
raw area
corr. area
corr.
y.
1 11.837 222 233 248 2 11.837 222 233 248
26 9985550 26 9985550
9930924 9824702
100.00 98.93
n r -f C11412
s, W/Z - 3 1 9 . 9
'pVf&rf
First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak ft
R. T. f i r s t
min.
sc an
max sc an
1ast peak sc an wi dt h
rau area
corr. area
1 11.837 2 11.837
219 ' 233 219 233
250 250
31 8 2 0 8 8 5 7 8 1 4 7 1 6 7 31 8 2 0 8 8 5 7 8 0 5 6 9 5 7
corr.
y.
100.00 98.89
320/322 CALCULATION R - G l o b a l < 1) -
.8204
tt/Z 2 5 7 . 0
First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area.
Peak .ft
R.T. fi rst min. scan
max scan
1ast peak sc an width
rau area
1 11.837 224 233 246 2 11.837 224 233 246
22 5182106 .22 5 1 8 2 1 0 6
corr. area
5128184 5047290
corr.
y.
100.00 98.42
(320 + 322 )/<332 +334) CALCULATION
R - G 1o b a l C 3) =
58. 1000
<3 2 8 / )/ (332 + 334) CflLCULfiTION
R - C l o b a H 3) =
.3841
if"- r : ~
____-- p!-T A. 1 J,.- i -i
SUBJECT TO PROTECTIVE ORDER.
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Cl1413
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MONSANTO COMPANY
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