Document ayBjD8qgBBy7m1630VLB8YQN
AR Q.S.& _ 0 9 2 !
BIODEGRADATION (BOD/COD)
TEST SUBSTANCE
_____________________________________
Identity: A mixture containing perfluorooctanesulfonate;, whichmay also be referred to as PFOS, FC-95, or as a component of FX-3106. (1Octanesulfonic acid) (CAS # 2795-39-3).
Remarks: The 3M production lot number was 015G. The test sample is FX-3106, PO# S5233-004, EAI 85548, Sumitomo 3M Japan. Current information indicates it is a mixture of 2.31% PFOS, 2.6% diethylene glycol butyl ether, 83.38% water, 10% ethylene glycol, 1.36% Sultone foamer, 0.2% xanthan gum, 0.1% 2-biphenylol, sodium salt, tetrahydrate, and 0.05% benzotriazole.
The following summary applies to a mixture with incompletely characterized concentrations o f impurities. Data may not accurately reflect the biodegradability o f the fluorochemicaI component o f t/ie test sample.
METHOD: __________________________________________________
Method: Standard methods. Type: Aerobic GLP: No Year completed: 1985 Contact time: 20 days Inoculum: Stale sewage, Chemolite.
RESULTS____________________________________________________
Chemical Oxygen Demand (COD):
220,000 mg/kg 240,000 mg/kg (Replicate)
Carbonaceous-Biochemical Oxygen Demand (BOD):
5-Day:
4,700 mg/kg
10-Day:
63,000 mg/kg
20-Day: 72,000 mg/kg
CONCLUSIONS_______________________________________________
No conclusions given.
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133
003006
DATA QUALITY R eliability: Klimisch ranking 3. Study lacks description and records of the method followed. The inoculum was not properly characterized. There is no characterization of the test substance purity, and the study lacks analytical confirmation of the amount of fluorochemical proportion in the solution. REFERENCES________________________________________________ This study was conducted by the 3M Company, Environmental Laboratory, St. Paul, MN, Lab Request number C 2282,1985. OTHER__________________________________ ;___________________ Last changed: 6/26/00
003007
11-25-85
ENVIRONMENTAL LABORATORY PINAL REPORT
LAB REQUEST NO. C2282
REQUESTER NAME: EAR/MTE
fiP P f A K
PROJECT NO! 9973010100 D U E RECEIVED: 13-24-85 OSSC: FX-3106 LIGHT HATER-ENVIRONMENTAL
SCREEN
CONTRACT LA B :
CONTRACT. LAB COSTS
0
3M E - L HOURS:
10
ES T CMPLT DATES 1 1 - 2 9 - 8 5
DATE COMPLETED: 1 1 -2 6 -8 5
PO # S 5 2 3 3 -004 FOa SUMITOMO 3M E A I 8 5 5 4 8 .
SAMPLE DATE
CODE DESCRIPTION
TEST
RESULT
1 FX3106 LOT 0156
B0D-05 (CARBONACEOUS)
4700 MG/KG
BOD-10 (CARBONACEOUS)
63000 MG/KG
BOD-20 (CARBONACEOUS) _ 72000 MG/KG
COD (DICHROMATE REFLUX)
220000 MG/KG
F IS H ACUTE TEST
COMPLETE
2 DUP OF #1
COD (DICHROMATE REFLUX)
240000 MG/KG
* = CONTRACT LAB SUBMITTED BY
DATED
003008
ronmental Laboratory BOD Work Sheet -iks, Controls, and Standards
t7M - A PWO
BEST COPY AVAILABLE
LabRsq.No.^
C ?.0,c,
BODRunNo.
A n a ly s t,/
Oat* Started
SaedTypeli Source
, !H ~ t r. Seed Concentration
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^
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Date
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Nonsaadad Dilution - W ater Blank
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-Day BOD Readings
D
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'
Temp.
Date
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Botila No.
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Botti# No.
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_____ i 2 o __________
Praaant D.O. (C .)
5T-ZC' V- 3 ,? S ' o
0 .0 . Daplatlon (C. Ci)
O 2-
Avaraga D.O. Daplatlon \Ct Ci)
O- ~O
f 0 -^
C - T - O __________ _
Saad Controla
Botila No.
Sampla S ia
Initial D.O. (BO
Praaant D.O. (B .)
D.O. Daplatlon (Bi - B>)
13 Mi
_______ m , . -
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7 lo
0 - r/o
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_______ _______________
1 - Rk . L 9 . ____ ,__________ _____
_________
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Botti# No.
Sampla S ia
Initial D.O. (DO
3V 3 n - ' f f
r?
< 1 ___
Praaant D.O. (DO
t r f V 7o
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Total D.O. Daplatlon
(D. DO
Daplatlon Duo To Standard
___ X _ - Day BOD
. . y y d^ BOD
1 ^ * .... ? . c < f
3 .? i
3 - r v
S to
Vs 9
2 2 2 / C?
2 ______
h /i-3
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Btaaalum Hydrogan Phthalata Standard (optional)
Botila No.
Sampla S ia
Initial D.O. (DO
Praaant 0 .0 . (DO
Total D.O.
Daplatlon (0, - 0.)
Daplatlon Duo To Standard
. Day BOD
Avaraga Dav
BOD
1
003009
vlronmeiital Laboratory OD Work Shaat Sam ples
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BEST COPY AVAILABLE
Lab Req. N o.** Analyst j .
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Nltripaattapjnhlbltoi Cono. i y y N / M %
. A il
Data Started /A / '*' **"
Sample Deecrlptlon
BOD Run No.
......................., X l Analyst , __
_ . u - ^2 ^ 3T
- Day BOD Readings I Data | / y - <7 - f -T "
In itial Dilution In itial D ilution Factor
o f Sam ple diluted to
ml with Dl w ater
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Bottle Cose, of No. Sample'
Sample
Initial
Size* D.O. (Di)
PfM M t D.O.(D>)
Total D.O. Depletion
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Depletion Due To Sample (DOS)
___ S I Day BOD
ATym_ ot1oy
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Not: 1. Cone. = Concentration of sample (mVI o^ftoflV ih BOO bottles.
2. Sample Size a ml
sample or diluted sample added to BOO Bottle.
3. Samples with 0, S I and DOS2S2 used to calculate average BOO.
C om m ents
003010
>nmental Laboratory BOD Work Sheet <ks, Controls, and Standards
n 19738-A- PWO
BEST COPY AVAILABLE
'* '* '* * ^
C m * . c , O^at*1Start*d
BOD Run No.
<$^ ^ y
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J tc S--j
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SoodConeontratlon
^------------------------------- Day BOD Readings
Analyst / /
1Data
| //.//-r r
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____
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Botila No.
Initial D.O. (A.)
X` / V 6 ____ L a___________
9 - Yo
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Saadad Dilution Water Blank (optional)
Bottle No.
Initial D.O. (C.)
7C1 f'Y-f 97 Z-fO
1b X-?o
Saad Controls
Praaant D.O. (A.)
%.CO Y0 0
3 - / 0________,
D.O. Daplation (A.-Aa)
C-^fO
0-~3 / p .A t
Average D.O. Depletion
i i : __________
Present D.O. (C.)
7~. yc 7. ? i'
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D.O. Depletion (Ci C.)
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Average D.O. Depletion
V (Cl )
H
Bottle No.
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________________
Sample S in - 20
Initial D.O. <B.)
?-3<2
______ Z ^ A . ______
Prsent D.O. <B>
T2 - / 5 ^
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D.O. Depletion (Bi -B.)
/. / y 0 .00
Glucose Glutamic A dd Standard
Bottle No.
Sample S in
Initial D.O. (D.)
)
<1 . . <i
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J L _____ y . * /
Present D.O. (Dt)
Lc 0
y / ^
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Total 0.0. Depletion
(Or Dt)
Depletion Due ____UL Day
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BOO
Average BOD
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Bottle No.
Sample S in
Initial D.O. (Dr)
Present D.O. (0 .)
Total D.O. Depletion
(Dr Dt)
Depletion Due To Standard
. Day BOD
Average Day
BOO
0 1 1
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BEST COPY AVAILABLE
Analyct _
NUriJlMtNwtnNbnorCone.
( p to - ' s
tamp* Daigrtptlof
BOD Run No.
^^ ^
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J2.------------- -------------- Day BOD Raidings
Analyst ____________________
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Initial Dilution Initial Dilution Factor
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Bottle No.
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Note: 1. Cone. C oncentration! sample (ml/lo<jgA^h BOD bottles.
2. Samplo Size ml
temple or diluted eemple added to BOO Bottle.
3. Sampkis with 0, >1 and D 0S 2 uaed to calculate average BOO.
C om m enta
003012
jnm enlal Laboratory BOD Work Sheet As, Controls, and Standards
itrw-A-pwo
BEST COPY AVAILABLE
Lab Ftoq. NO.*1 . /
SaarfTyp A Sourea
g J )
O ats S ta rt ]
/t-t-K - r
. , Saad C oneantratlon
BOD Run No.
.... - J L P
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Bottle No.
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Praaant D.O. (A .)
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Average D.O. Oapiatlon
"J (A fA .)
,
Bottle No.
7 ci
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D.O. Depletion (C. - C.)
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Average D.O. Depletion
-v (C ..& )
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Bottle No.
Sample Size
Initial 0 .0 . (B .)
Present 0 .0 . (B .)
0 .0 . Depletion (B. B.)
73
_____ 7-73
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Stmtpie Size
initial D.O. (0 .)
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Total 0 .0 . Depletion
(Oi D.)
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H -H l
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frateaalum Hydrogen Phthalata Standard (optional)
Bottle No.
Sanple Size
Initial 0 .0 . (0 .)
Praaant 0 .0 . (0 .)
Total 0 .0 .
Oapiatlon (Ot 0 ,)
Depletion Oue To Standard
7 ' '/ Z. C - f
.
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BOD
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Day BOO
Avarage . Day
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003013
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^
Present O A .(D i)
7.'r (.(, o 2 b^' --
.--
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Note: 1. Cone. :< Concntratlq{u>( sample (mVl
BOD bottles.
2. Sample Siza * ml
aampit or diluted aampla addad to BOO Bottla.
3. Samples with D, >1 and DOS 2 uaad to calculata avaraga BOO.
Com m snts
BEST COPY AVAH ARLE
Iw
--------------- ------------------ 1-
003014
