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(conoco) Interoffice Communication To Chuck Glover From Tom Grumbles Date May 24, 1982 Subject PRINTING OF MATERIAL SAFETY DATA SHEETS Please print 100 copies each of the the Material Safety Data Sheets enclosed. (Conoco DR 811, Conoco DR 721, Conoco DR 821, Conoco CR 822). \C Thomas G. Grumbles ajo Enclosure 00002020 CCR 0 conoco MATERIAL SAFETY DATA SHEET Conoco Chemicals Company P.O. Box 19029 Houston, TX 77224 -' PRODUC^.IDENXiFICATIOMier^i^=r^it^,^,i:,y*' MANUFACTURER'S NAME Conoco Chemicals REGULAR TELEPHONE NO. 713/863-7804 EMERGENCY TELEPHONE NO, 318/491-5142 ADDRESS p Q . Box 2100. Bav Citv. TY 77434 TRADE NAME Conoco DR 822 SYNONYMS High Density Polyethylene H HAZARDOUS INGREDIENTST. - MATERIAL OR COMPONENT % HAZARD DATA | BOILING POINT (F.) VAPOR PRESURE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR MsattaaaaKgagMggM N/A N/A N/A N/A SPECIFIC GRAVITY (H.Q = 1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( =D MELTING POINT 0.957q/cm3 N/A N/A 133 C Translucent Odorless Pellets ' ` ssas FLASH POINT (TEST METHOD) N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL. LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL ARE FIGHTING PROCEDURES UNUSUAL FIRE Cool exposed resins with water spray to prevent melting and dripping Incomplete combustion can lead to formation of carbon monoxide/irri tating fumes and smoke. Self-contained breathing apparatus should be wurii i/ ern-eniTg cum intro--bjjdce" FIRST AID EYES; HEALTH HAZARDSINFORMATION,' If dust enters the eye, flush with large amounts of water SKIN: n/A INHALATION: N/A ingestion: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. ' Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. INGESTION: This material is not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health effects are expected to occur with exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene. THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m^ nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A CCR Q00002022 VT \ CONDITIONS CONTRIBUTING TO INSTABILITY REflCTIVmrOflTnS:' INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.- SPILL CE STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (specify in DETAIL!: if dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES: General ly not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A OCR 000002023 1MC0 HAZARD CUSS AND NUMBEH N/A UN NUMBER N/A ADR CUSS NUMBER US DOT CLASSIFICATION N/A EEC DANGEROUS SUBSTANCE CU5SIRCAT1GN EEC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBER 9002-88-4 TRANSPORTATION AND STORAGE USUAL SHIPPING CONTAINERS --. -J-Boxes Bags Dry flow cars Dry flow trucks ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE LOAOING/UNLOAOING TEMPERATURE VISCOSITY AT LOAOING/UNLOAOING TEMPERATURE HANDLING AND STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE The acove oata is saseo on tests ana exoenence whicn Conoco oetieves reiiaoie ana are sucoiied tor informational ourooses only. Conoco disclaims any liaoiiity tor damage or iniury wnicn results from the use of the aoove oata ana notning containec therein shall constitute a guar antee.1 WARRANTvfcr MERCHANTABILITY,pr reoresentation (inciuoing treeaom from patent liaoiiityj oy Conoco wrtn resDea to tne caia. tne orocuc: oescnbea. or their use for^ny soectfic ouroose. even it mat ouroose is known to Conoco. o\ rr tta; tat r\ CCR 000002024 MATERIAL SAFETY DATA SHEET Conoco Chemicals Company P.O. Box 19029 Houston, TX 77224 ! MANUFACTURER'S NAME PRDDUtrriDENTIFICATIOrt-- Conoco Chemicals REGULAR TELEPHONE NO. 713/863-7804 EMERGENCY TELEPHONE NO. 318/491-5142 ADDRESS P. 0, BOX 2100, Bay City, TX 77414 TRADE NAME Conoco DR 821 SYNONYMS High Density Polyethylene II --: V HAZARDOUS* INGREDIENTS; MATERIAL OR COMPONENT HAZARD DATA 1 j ffi BOILING POINT (*F.) VAPOR PRESURE {mm Hg.) IMDCID ncilPITV /AID _ -n SOLUBILITY IN WATER APPEARANCE AND ODOR N/A N/A N/A SPECIFIC GRAVITY (H,Q = 1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( = 11 MELTING POINT 1 Translucent Odorless Pellets 0.953g/cm3 N/A W/fl 132 C 51; i sy ; < ; * 1 q s. < ui ci m; 41 i; \i ^ FLASH POINT (TEST METHOD) N/A AUT0IGNIT10N TEMPERATURE N/A FLAMMABLEdLIMITS IN AIR. % BY VOL LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical {Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES Cool exposed resins with water spray to prevent melting and dripping Incomplete combustion can lead to formation of carbon monoxide/irritating fumes and smoke. Self-contained breathing apparatus should be UNUSUAL FIRE CCR V; HEflimHflZlMltlNFOB^ FIRST AID ^s* If dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. SKN: Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. INGESTION: This material is not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health effects are expected to occur with exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylen THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m^ nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A ,000 Z02*> CONDITIONS CONTRIBUTING TO INSTABILITY flEAcmnrojnmr INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PROOUCTS Burning or heating to high'-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Wi11 not occur. VII r ~~ SPILLOR LERICPROCEDURES^" . " t ' } r STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A CCR 000002027 I 1MC0 HAZARD CLASS AND NUMBER N/A UN NUMBER N/A HAZARD: CLASSIFICATION INFORMATION US DOT CLASSIFICATION N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION ADR CUSS NUMBER EEC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBER 9002-88-4 TRANSPORTATION AND STORAGE USUAL SHIPPING CONTAINERS Bags Dry flow cars Boxes Dry flow trucks ELECTROSTATIC ACCUMULATION HAZARD STORAGE-TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE LOADING/UNLOADING TEMPERATURE VISCOSITY AT LOAOIN&UNLOAOING TEMPERATURE HANDUNG AND STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE - The acove aata is Dasea on tests ana exoenence which Conoco oeiieves reusoie ana are sucoiied for informational purposes oniy. Conoco disclaims any iiaoiiity for carnage or miury whicn results from the use of tne above aata and notning containec therein shali constitute a guar antee. WARRANTY OF MERCHANTABILITY", or reoresentation {'including freeaom from oatent iiaoiiityj oy Conoco with resoect to the cata. the proQuct describee. or tneir use vor any specific purpose. even if that purpose is known to Conoco. rf- 000002028 (Conoco; MATERIAL SAFETY DATA SHEET Conoco Chemicals Company P.O. Box 19029 Houston. TX 77224 MANUFACTURER'S NAME PRODUCTIDENnnCATlON,- - . . **-V*i*' ` * Conoco Chemicals REGULAR TELEPHONE NO. 713/863-7804 EMERGENCY TELEPHONE NO. 318/491-5142 ADDRESS P. 0. Box 2100, Bav Citv, TX 77414 TRADENAME Conoco DR 721 SYNONYMS High Density Polyethylene ,^*4 .*l! II HAZARDOUS'INGREDIENTS':'; MATERIAL OB COMPONENT . %- HAZARD OATA i BOILING POINT (F.) VAPOR PRESUREImm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR S5S a4T>aen^v&r^*g -a*s*' >a><asB)^^* * -/* PUSH POINT (TEST METHOD) *- N/A N/A N/A N/A N/A SPECIFIC GRAVITY <H,0 = 1) PERCENT VOLATILE BY VOLUME {%} EVAPORATION RATE ( =D MELTING POINT Translucent Odorless Pellets 53*3 AUTOIGNITION TEMPERATURE N/A D.964g/cm^ N/A N/A 136 C FLAMMABLE LIMITS IN AIR. % BY VOL S LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES U* 1N1"USrUvmAL oFrIR>nE*' Cool exposed resins with water spray to prevent melting ana dripping. Incomplete combustion can lead to formation of carbon monoxide/irritating fumes and smoke. Self-contained breathing apparatus should be WU III ii ell 1 1 IIU Iw uin ineu space.--------------- CCR 000007029 t. HEALTH HAZARU INFORMATTOHF;" FIRST AID EYES: If dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. SKN' Molten resins will produce thermal burns. INHALATION: This material i s not expected to present an inhalation hazard under normal use INGESTION: This material is not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health effects are expected to occur wit exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylen THRESHOLD LIMIT VALUE (TLV) "3 ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A CCR 000002030 CONOmONS CONTRIBUTING TO INSTABILITY REACnvnTDfflft^ INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high\-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur. * - STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY {SPECIFY in detail): if dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. 4 S GLOVES: Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A CCR 000002031 i IMCO HAZARD CLASS AND NUMBER N/A UN NUMBER N/A HAZARD CLASSIFICATION INFORMATION I US DOT CLASSIFICATION N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUMBER EEC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBER 9002-88-4 - TRANSPORTATION AND STORAGE USUAL SHIPPING CONTAINERS ELECTROSTATIC ACCUMULATION HAZARD Bags, Boxes, Drv flow cars, Dry flow trucks STORAGE/TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE LQAOING/UNLOADtNG TEMPERATURE VISCOSITY AT LQADING/'UNLOAOING TEMPERATURE HANDLING AND STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE The acove Gaia is oaseo on tests ana exoenence wmcn Conoco oeiieves reiiaoie ano are suocued for inforrnationai ourooses only. Conoco disclaims any iiaoiiily for oarr.age or injury wnicn results from the use of the aoove aata ano nothing containea therein snail constitute a guar antee. WARRANTY Or MERCHANTABILITY, or reoresentation 'including freedom from oatent liaoiiiry) Oy Conoco wun resoect to tne cata. the oroouc oescnbec. or their use for any soecific ouroose. even if that ouroose is Known to Conoco. OCR 000002032 MATERIAL SAFETY DATA SHEET Conoco Chemicals Company P.O. Box 19029 Houston. TX 77224 * . *. <v ~ '. MANUFACTURER'S NAME i P. 0., Box rConoco rC. hem. ic,allps 2100, Bay City, TX 77414 TRADE NAME Conoco DR 811 SYNONYMS High Density Polyethylene REGULAR TELEPHONE NO. 713/863-7804 EMERGENCY TELEPHONE NO. 318/491-5142 II.- HAZARDOUS INGREDIENTS; MATERIAL OR COMPONENT . %- HAZARD DATA i BOIUNG POINT (F.) VAPOR PRESURE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR N/A N/A N/A N/A SPECIFIC GRAVITY (H,D = 1) PERCENT VOLATILE BY VOLUME {%) EVAPORATION RATE ( =D MELTING POINT Translucent Odorless Pellets 0.954g/cm^ N/A N/A 132 C i1 rssssaas^^ 5 [: i =?; \; 11 ^ a' < u a i i ? i ; a i f>u i -' FLASH POINT (TEST METHOD) N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL. LOWER N/A j UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE Cool exposed resins with water spray to prevent melting and dripping Incomplete combustion can lead to formation of carbon monoxide,irritating fumes and smoke. Self-contained breathing apparatus should be worn--if eideiinu unfilled space.---------------------------------------------------------------- -n H00002033 HEALTH HAZARttINFORMATIONS FIRST AID EYES: If dust enters the eye, flush with large amounts of water SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin, SKN' Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health_effects are expected to occur with exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene. THRESHOLD LIMIT VALUE (TLV) *3 ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: M/A INHALATION: N/A INGESTION: N/A OCR 000002.034- CONDITIONS CONTRIBUTING TO INSTABILITY REACTIVITY DATA- INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Wi11 not occur.- STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL): if dust is produced during handling of material an approved ai r-puri tying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES: General ly not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A CCR 000002035 11MCO HAZARD CUSS AND NUMBER N/A UN NUMBER N/A HAZARD CLASSIFICATION INFORMATION US DOT CLASSIFICATION N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION AOR CUSS NUMBER EEC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBER 9002-88-4 TRANSPORTATION AND STORAGE USUAL SHIPPING CONTAINERS ELECTROSTATIC ACCUMULATION HAZARD "B ags, Boxes, Dry flow cars. Dry flow trucks STORAG&TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE LOAOING/UNLOADING TEMPERATURE VISCOSITY AT LOAOING/UNLOADING TEMPERATURE HANDLING. AND STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE The acove oata is cased on tests ana expenence which Conoco oeiieves renaoie and are sucotieO for imormationai ouruoses only. Conoco disclaims any iiaoiiity for carnage or iniury which results from the use of the aoove cata ano nothing contained therein snail constitute a guar antee, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent iiaDthtyj oy Conoco witn resoect to the cata, ihe product oescrioed. or tneir use for any specific purpose, even if that purpose is Known to Conoco. 000002036 CCR