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(19) (12) (21) 201810315387 .8 (22) 2018 .04 .10 (65) CN 108531135 A (43) 2018 .09 .14 (73) 100085 6-2607 (72) (74) () 11413 (10) CN 108531135 B (45) 2021.05.07 (56) CN 102660229 A ,2012 .09 .12 CN 102719226 A ,2012 .10 .10 CN 105885798 A ,2016 .08 .24 CN 105586009 A ,2016 .05 .18 CN 102719226 A ,2012 .10 .10 CN 201104043 Y ,2008 .08 .20 CN 1475544 A ,2004 .02 .18 CN 102559146 A ,2012 .07 .11 CN 1460703 A ,2003 .12 .10 CN 1210130 A ,1999 .03 .10 EP 0516093 A1 ,1992 .12 .02 CN 1388887 A ,2003 .01 .01 CN 1361399 A ,2002 .07 .31 (51)Int .Cl . C09K 5/04 (2006 .01) F25B 45/00 (2006 .01) (54) (57) 23331 13331 1 1 1 3 31 1 2232 ODPGWP 1 13 1 CN 108531135 B CN 108531135 B 1/1 1 . 23331111 33 10%15% 2%5% 20%25%15%25% 10%15% 20%30% 100%145150 2 .1 23331111 33 10%15% 2%5% 20%25%15%25% 10%15% 20%30% 100%145150 3 .1 2 CN 108531135 B 1/13 [0001] [0002] 100150 100 150 [0003] ODP() GWP() GWP [0004] ODPGWP [0005] ODP0GWP [0006] [0007] 23331 1 3 3 31 1 1 1 3 31 1 2232 [0008] 015 [0009] 015 [0010] 1540 [0011] 1530 [0012] 825 [0013] 1530 [0014] [0015] 3 CN 108531135 B 2/13 23331 1 3 3 31 1 1 1 3 31 1 2232 [0016] 015 [0017] 015 [0018] 1540 [0019] 1530 [0020] 825 [0021] 1530 [0022] [0023] 2 3 3 31 13331111331 12232ODPGWP [0024] [0025] 1 [0026] [0027] 20011 1 HCFC () HFC () ODP ( ) GWP ( ) HFC ODP0 GWP R134a (1 1 1 2 ) [0028] GWP 4 CN 108531135 B 3/13 100 [0029] [0030] 1100150 ODP GWP [0031] 2150 HFCPOE(polyolester ) R170 R14R23 [0032] [0033] [0034] 300R141b()R123( ) R124 () R245fa () R236fa () 2050 R290 () R22 () R125 () R218 ( )R32()7595 R23( )R170()R116()R13()R41() 125135R14()NF3() 150170 R50 () 180200 R740 () R744 () [0035] 120 ODP0GWP R14 NF3 NF3 GWP17200 R14 GWP7390 R14 R13CFC ODPR170R14 R116R23R23GWP12200R41GWPR14 R23GWP14800R41 GWP [0036] GWP [0037] [0038] R740()R728() [0039] R50()R784() [0040] R14() [0041] R23()R41() 5 CN 108531135 B 4/13 [0042] HFO1234yf(23331)HFO1216()HFO 1225()HFO1234ze(13331) [0043] HFC245fa(11133)HFC245ca(11223 )HCFO1233zd()HFO1336mmz(2) [0044] ODP0GWP [0045] [0046] 015 [0047] 015 [0048] 1540 [0049] 1530 [0050] 825 [0051] 1530 [0052] 100 [0053] [0054] 1 [0055] ODP0R14R23GWP GWP1200GWP [0056] 2 [0057] HFCPOEPOE 150 [0058] 3 [0059] R50R41R50R41 R50R41 R784R50 [0060] HFO1234yf(23331)HFO1234ze(13331) SAE international()HFO1234yf HFO 1234yf(HFC134a) HFO1234yf [0061] [0062] [0063] 05 [0064] 510 [0065] 2530 [0066] 2530 6 CN 108531135 B 5/13 [0067] [0068] [0069] [0070] [0071] [0072] [0073] [0074] [0075] [0076] [0077] [0078] [0079] [0080] [0081] [0082] [0083] [0084] [0085] [0086] [0087] [0088] [0089] [0090] [0091] [0092] [0093] [0094] [0095] [0096] [0097] [0098] [0099] [0100] [0101] [0102] [0103] [0104] [0105] 1520 2030 100105 510 05 2030 1520 2025 2030 105115 510 05 1525 1520 1525 2030 115125 510 210 2530 1520 1520 1525 125135 1015 25 2025 1520 1525 2030 135145 1015 25 2025 1525 1015 2030 145150 100150 7 CN 108531135 B 6/13 ODPGWP [0106] [0107] R740 () R728() R50()R784() R14() R23()R41() HFO1234yf(2333 1)HFO1216()HFO1225()HFO1234ze(13331 ) HFC245fa (1 1 1 3 3) HFC245ca (1 1 2 2 3 )HCFO1233zd()HFO1336mmz(2) [0108] 015 [0109] 015 [0110] 1540 [0111] 1530 [0112] 825 [0113] 1530 [0114] ()10bar18bar1 .5bar4bar [0115] 100150 ODP GWP [0116] [0117] [0118] 1 1234 5 100150 [0119] [0120] 1 [0121] 100 8 CN 108531135 B 7/13 [0122] R505R14 25R23 25 HFO1234fa 15 HFO1336mmz10HFC245fa 20 [0123] 25100210psi 25psi [0124] 2 [0125] 100 [0126] R505R14 30R23 30 HFO1234fa 15 HFO1336mmz10HFC245fa 10 [0127] 25100210psi 25psi [0128] 3 [0129] 102 [0130] R7402R50 6 R14 27R2328HFO 1234fa17HFO1336mmz 10HFC245fa10 [0131] 25100210psi 25psi [0132] 4 [0133] 105 [0134] R7405R50 10R14 25R2325HFO 1234fa20HFO1336mmz 10HFC245fa5 [0135] 25100210psi 25psi [0136] 5 [0137] 105 [0138] R7405R50 0 R14 25R2320HFO 9 CN 108531135 B 8/13 121615 HFO1234yf 10 HCFO1233zd 15 HFO1336mmz 10 [0139] 25 110 230psi 28psi [0140] 6 [0141] 110 [0142] R74010R50 5 R14 30R2315HFO 121610 HFO1234yf 10 HCFO1233zd 10 HFO1336mmz 10 [0143] 25 110 230psi 28psi [0144] 7 [0145] 115 [0146] R7407R50 3 R14 20R2317HFO 121610 HFO1234yf 13 HCFO1233zd 15 HFO1336mmz 15 [0147] 25 110 230psi 28psi [0148] 8 [0149] 115 [0150] R7408R784 2 R14 20 R23 10 HFC41 10 HFO1234yf 15HFO122510HFC245ca 5HCFO1233zd10 HFO1336mmz(2)10 [0151] 25 120 240psi 26psi [0152] 9 [0153] 120 [0154] R7405R784 10 CN 108531135 B 9/13 5 R14 25 R23 10 HFC41 7HFO1234yf 10 HFO1225 8 HFC245ca 10HCFO1233zd10HFO 1336mmz(2)10 [0155] 25 120 240psi 26psi [0156] 10 [0157] 125 [0158] R74010R 7840R14 25 R23 10 HFC41 10 HFO1234yf 15HFO122510HFC245ca 5HCFO1233zd5 HFO1336mmz(2)10 [0159] 25 120 240psi 26psi [0160] 11 [0161] 125 [0162] R7405R728 5R505 R1430R23 10 HFC41 5 HFO 1234yf15HFO1234ze 55HFC245fa 10HFO1336mmz5 [0163] 25 130 250psi 28psi [0164] 12 [0165] 130 [0166] R7403R728 5R502 R1428R23 10HFC4110HFO 1234yf15HFO1234ze 25HFC245fa 10HFO1336mmz10 11 CN 108531135 B 10/13 [0167] 25 130 250psi 28psi [0168] 13 [0169] 130 [0170] R7403R728 2 R50 10 R1430R23 10 HFC418 HFO1234yf10HFO1234ze 57HFC245fa 10HFO1336mmz5 [0171] 25 130 250psi 28psi [0172] 14 [0173] 135 [0174] R7405R728 5 R50 10 R1425R23 10 HFC41 10 HFO1234yf15HFO1234ze 55HFC245fa 5HFO1336mmz5 [0175] 25 130 250psi 28psi [0176] 15 [0177] 135 [0178] R7408R728 5R505 R1422R23 10 HFC41 5 HFO 122520HFO1336mmz 25 [0179] 25 140 260psi 30psi [0180] 16 [0181] 140 [0182] R7405R728 5R503 R1425R23 12 CN 108531135 B 11/13 10 HFC41 7 HFO 122515HFO1336mmz 30 [0183] 25 140 260psi 30psi [0184] 17 [0185] 140 [0186] R7408R728 7R502 R1420R23 10 HFC41 8 HFO 122525HFO1336mmz 20 [0187] 25 140 260psi 30psi [0188] 18 [0189] 145 [0190] R7405R728 5R505 R1420R23 10HFC4110HFO 122520HFO1336mmz 25 [0191] 25 140 260psi 30psi [0192] 19 [0193] 145 [0194] R7405R728 8 R784 5 R1422R23 15 HFC415 HFO1234yf 10 HFC245fa 30 [0195] 25 150 280psi 32psi [0196] 20 [0197] 148 [0198] R7405R728 10R7843 13 CN 108531135 B 12/13 R1425R23 15 HFC41 10 HFO1234yf 12 HFC245fa 20 [0199] 25 150 280psi 32psi [0200] 21 [0201] 150 [0202] R7405R728 5 R784 2 R1420R23 15 HFC41 10 HFO1234yf 15 HFC245fa 28 [0203] 25 150 280psi 32psi [0204] 22 [0205] 150 [0206] R7405R728 10R7842 R1425R23 10 HFC415 HFO1234yf 15 HFC245fa 28 [0207] 25 150 280psi 32psi [0208] [0209] "" "......" [0210] [0211] 14 CN 108531135 B 13/13 15 CN 108531135 B AS. C ) C 5 Po s- r Z5 Ts 1 0 L2 < To 4441IES *it It 1 1/1 16