Document aJYMRw490M3RXKznQbM798EYb

DISTRIBUTION COPY NUMBER 1-3 M. Townsend 4 F. E. Kearney 5-7 T. Bistline 8 R. Noble 9 G . Thomas 10 R. F. Ivory 11 Central Files 12 Technical Reports Library 1670 E3NA E2ND 1250 1250 1250 1250 R2C ABSTRACT ONLY H. A. Woltermann NOTE: Distribution of this report is restricted. Requests for additional copies should be made through the principal contact at the Monsanto location involved or the Manager, Environmental Sciences Center, Dayton Laboratory, Dayton, Ohio. ACKNOWLEDGEMENT Contributions of the following Dayton Laboratory personnel to this project are gratefully acknowledged: Analyses: G. Thomas G. Pitts COMPANY CONFIDENTIAL C11276 DOCUMENT CONTENTS Cover S h e e t .......................................................... Document Contents ................................................... Report .............................................................. Document Inventory ................................................. Sample Receipt Forms ............................................... Chain of Custody F o r m s ............................................. Analysis Request Forms ............................................. Monsanto Notebook Pages For: a. Extraction/Freparation ................................... b. Analysis/Data Reduction ................................... Instrument Logbook Pages ........................................... Computer Output and Chromatograms ................................... Additional Documentation ........................................... Page 1 3 4 LI 12 13 15 16 17 20 23 139 SUBJECT TO PROTECTIVE ORDER 00003 C11277 All samples had 50 uL of dodecane keeper added to them and then they were concentrated under a gentle stream of nitrogen and submitted for GC/MS analysis. The GC/MS analyses were conducted on a Hewlett/ Packard 5987 GC/MS Instrument. The analysis was conducted using a 60 m SP2330 capillary column. The mass spectrometer was operated In the selected Ion monitoring mode analyzing for Ions characteristic of both the native (unlabeled) 2,3,7,8-TCDO (m/z 257, 320, 322), chlorine-37 labeled 2,3,7,8-TCOO (m/z 328) and carbon-13 labeled 2,3,7,8-TCOO (m/z 332, 334). STANDARDS Standard solutions were prepared from standards that had been cross val Idated with a standard provided as a check sample by the EPA. Concentration of the internal standards conformed to the levels specified by the method. RESULTS The results of the analyses of the samples are given in table l. The tables also give all pertinent QA/QC information. It should be noted that small amounts of sample may lead to erroneously high or low concentrations due to possible Inhomogeneity of the sample.i ,r \ a_ '-Jil : c h r i s t t TO PROTECTIVE ORDER. OCGv-' G11279 TCTIO DATA REPORT MONSANTO COfPANY, DAYTON LABORATORY TABLE la. SWEEPINGS OC OOLiJW: SP2330 RF NATIVE: l.OOORE SURROGATE: 1.690 ETTR KIND ---- J *1 J 3i J J J J MR J J 4J R J PF J ER J CO J J VET CLEAN HOT -- -- BC 3.570 8C 5.910 ec 1.700 ec 2.010 BC 4.580 BC 6.030 BC 3.940 BC 2.800 BC 4.360 BC CS3fi_ BC 5.820 BC 1.120 BC 1.260 BC 5.000 9JRR PPB ICflL 320 332 X TCOO D.L, DATE TIME 322 334 ACC 320 322 257 3 2 8 + 3 3 2 334 N 4.68 15.55 1.99 3.87 ND ND 8.24 13,56 12.51 3.05 ND MO _ 9/7 -- 9/7 -- 9/7 -- 9/7 .11 9/7 .08 9/7 -- 9/7 -- 9/7 -- 9/7 9/7 9/7 -- 9/7 .79 9/7 .05 9/7 0503 .84 0523 .76 0543 .81 0603 .80 0623 H H 0703 H H 0743 .75 0803 .69 0823 .73 0903 .67 0922 .73 0942 .80 1246 H H 1002 H H .86 100. .74 84. .87 105. .83 64. .74 63. .67 103. .76 110. ,79 118. ,69 74, .81 128. .72 84. .69 65. .73 75. ,84 90. 188R2. 83727. 2709. 10577. 0. 0. 84155. 112218. 99006. 97684. 88864. 8451, 0. 0. 22496. 8719. 41604. 110660. 65853, 29751, 3358, 3246, 31486. 13269. 6672. 32783. 0, 0, 30429. 0. 0. 54167, 111929. 75663. 111376, 161839. 116064. 143014. 135442, 84807, 53068. 146866. 67821. 66480. 121024. 74700. 75374. 10520, 10379. 60689. 0, 0. 51944, 0. 0. 88063. 28586. 3335.T. 22426, 30462, 20803. 24016. 34763. 41998, 30539. 4U92. X 31463. 46919. X 65192. 83792. 79786, 100672. 44015. 63417. 34523. 47703. 56048. 78200. 56861. 81910. 43098. 59336. I 66335. 78584. X FOR CONTRIBUTION BY NATIVE TCOO (SUBTRACT .009 OF M/E 322) . X: ISOTOPE RATIO OUT OF ACCEPTABLE RANGE Y: X ACaRACY CUT CF ACCEPTABLE RANGE JW SCAN SIGHING AND WORKUP EtINTERLABI W. L.H=NATT tcod spikes NTWOT DETECTED DLsDETECTtON LIMIT J=-JAR CD094 \ SUBJECT1J.TO , j. U ') PROTECTIVE ORDER, OOOCG C11280 TCDO DATA REPORT SANTO COWANY- DAYTON LABORATORY TABLE la. SWEEPINGS (Continued) GC CXLW SP2330 RF NATIVE: 1.043 RF SURROGATE: .907 SAMPLE N BER EITR NTH) GRANS WET CLEAN wght SJRR PPB ANALYTICAL 320 332 1 TCOO D,L. DATE TIME 322 334 ACC 320 322 257 328+ 332 334 BASE OF STAIRS J BCD 1,180 11.82 - 9/10 0844 .72 .84 131. 5514. 7629, 4749. 10773. IO3 4 5 . I225l/ + CORRECTED FOR CONTRIBUTION BY NATIVE TCOO (SUBTRACT ,009 OF H/E 322) WTE COOES: X: ISOTOPE RATIO OUT CF ACCEPTABLE RANGE Y: Z ACaRACY OUT OF ACCEPTABLE RANGE W^CTIJO BLPMf PARTIAL SCAN SEPARATE iIGHING ANO WORKUP WWLICMEWTBU) F^-FiaO BLANK L.HsfWTI TCO SPIKES ND=NOT DETECTED dl=detection limit JsJAR F" E W C =TCDD9$ CTVE ORDER,1 - 4 Vi S L B J c C T ,0 r.-.O LGC7 C11281 TCOO DATA REPORT MONSANTO COPANY, DAYTON LABORATORY TABLE lb. WIPES OC COUWfc SP2330 NATIVE: 1.000 RF SURROGATE: 1.630 SAfFLE > IRFR -- EXTR HTHO -- INSIDE N UALL J *" >5STACliER J I XER J DRVEW vac pip J HAW J 1J hicH SPIKE LOU SPIKE J J CLEAN -- BC BC BC BC BC BC EC BC MS TODD -- NO ND ND ND NO ND 18.15 6,56 ANALYTICAL D.L. DATE TIME ---- -- ,40 9/7 .49 9/7 1022 1306 .42 9/7 1326 .44 9/7 1346 .52 9/7 1406 .51 9/7 1451 -- 9/7 -- 9/7 1511 1531 320 322 ---- HH HH HH HH **44 4444 ,72 .52 SIKR 332 X 334 ACC ---- .71 66. .74 72. .76 74. .72 73. .69 82. .50 93. .70 85. .53 103. 320 -- 0, 0. 0. 0, 0. 0. 18911, 6954. 322 -- 0. 0, 0. 0, 0. 0, 26432. 8507. 257 -- 0. 0. 0. 0, 0, 0. 17323. 7487, 325+ -- 45005. 39667. 48299. 45453, 42785. 49443. 39735. 43942, 332 -- 40353, 33584. 40191. 37149. 30553. 33924. 26615. 27661. 334 N -- .. 56919, X 45152. I 53067. X 51649, X 44U0, X 42316. X 35083. 33353. CORRECTED FOR CONTRIBUTION 0Y NATH TCOO fSUBTRACT .009 OF N/E 322) MITE CODES: X: ISOTOPE RATIO OJT OF ACCEPTABLE RANGE Y; % ACCURACY CUT CF ACCEPTABLE RANGE NB=tTHOD BLAMi PARTIAL SCAN ^SEPARATE iFIGHINT, AND UORWP IMBRICATE (INTERLAR) f^FIELD BLAMi1 L.,H=NAT1VE TCDO SPIKES ND=NOT DETECTED DL=0ETECT10N LIMIT vKWi '".ENAflE =TCDD95 C ' C aW i -iAL SUBJECT TO PROTECTIVE ORDER 0L0C3 C11282 TABLE 2. CALIBRATION SUMMARY Wg/Kg NATIVE TCDD 0.534 5.34 1.335 13.35 33.5 0.534 5.34 53.4 1.335 0.534 5.34 53.4 1.335 13.35 33.5 RRF (NATIVE) 1.117 0.917 0.920 1.000 1.045 - 1. 145 1.012 1.061 0.999 0.993 1.045 DATE 9/7 9/7 9/7 9/7 9/7 9/7 9/7 9/7 9/7 9/10 9/10 9/11 9/11 9/10 9/10 TIME 0423 0443 0843 1042 1102 1205 1224 1429 1554 2144 2204 0005 0205 1527 1547 RRF SURROGATE 1.712 1.808 1.520 0.906 0.919 0.848 0.896 0.900 - 0.970 in al SUBJECT T3 P^ cr i di'/E ORDER. o*^ r Cl1283 TABLE 3. QUALITY CONTROL SUMMARY ITEM SURROGATE ACCURACY //DATA POINTS 23 4 MEAN S.D. 88.9 20.3 * * Not technically correct to report recoveries for internal standard calculated results. SUBJECT TO p r o t e c t i iv il e o r d e r . o_o.ro C11284 DOCUMENTATION INVENTORY FORM Monsanto Research Corporation Dayton Laboratory I. Sample Information Sample Identification: ///TKo JNumber of Samples: (p A n a l y t e O (3 ^ 6 - T > "D Matrix: W iP c S Method: D O if& M n o fii o F 3,V*,S-T<=>D V S a u . A/to S r ia ie n t II. Documentation Control Copies Attached Initials (a) Sample Receipt Form (b) Internal Sample Tracking Form (c) Sample Tags (d) Airbill (Number ____________ ) (e) Chain of Custody Form (f) Analysis Request (Log Number / 9 Y o 9 o ^ > / ) <ST -- . <sr . -- -- <S-r r V _-r (g) Extractlon/Preparatlon notebook pages (NBP) a A 7 3 A W 9 &T (h) Analynsbips ___________ Instrument Logbook pages 15/j ^ 7 ^ . 7 5 <cr <3rr Computer Data Files ______________ hard copy output Chromatograms y r / 67 (1) Data Reduction n b p < :e A f if / u y s is V 8 P _____ x/ ?T- (j ) Final Report (k) Additional Documentation y . r (note immediately upon acquisition) .Sr^BZbS V 7 3 , <g '6 ^ 7 a/BP ikui ;File Complete iK#4 (s^nature) SUBJVE*CT'A. TOJ.PR. OTE--CT-,ItV--Ear-OTRDER. 0i /7 5?T8v (date) 011285 Sample Receipt Form Monsanto Research Corporation Dayton Laboratory Customer Identification: frirTKO____________________ MRC Log Number: O ^ V 0 5 >n 1__________________ Airbill Number: T>cu \ V ^ Cno^A^lE-__________ Date: H SFfr 3H_________ Sample Receipt Information: '(a) Shipping Containers (b) Custody Seals (c) Chain of Custody Forms (d) Sample Tags (e) Sample Containers (f) Agreement of Sample Documentation Initial Rl (li damaged (describe below) No. Cahs'ervE) (describe sealing below) intact___ absent No. Zl . absent No /&> damaged (describe below) No./(& no (describe discrepancies) Additional Description (if sample numbers not listed on chain of custody form, list here and contact SMO). v /i t h 7 K o f jd z r n F ij t io f t W A f a r r t a m P F R i K s '\\ V A*i - ' ",,3ftTF'~rwE grdeb. SUBJECT t o PROTEGI 0LC12 C1286 S A M P U IDENTIFICATION LOG HRC Job N:. _______________________ Customer Representative /?),% * > - ContracL No. ________________________ Plant Name or Code -Mrru. KRC Contract Manager _____________________ Team L e a d e r _____________________________ Samoi ing Location --Rur.H Date Type of Sample i umber Sampled No. of Containers Analysis Required Sample recovered- By (Initials) and Comrenti 'U^C. \<1 ZS7? 2-l9 ~Dry. f*,<Q ' *j |J?r <S- ->9 Scis+* ~bor~ 6- 19 fVi.-Dt>c 3T- ><To^wi 23?^ 7.37V 2-^7? ICSY^ (ifV\ rvi.o '-'79 T>i T e cr^t |>\ ^ cul l/alu<* Cao-T -i37s> _ srb __________ 2*J Leotl S'o'ccn C-Jxl2sr* 37F & th - 79 rvucLet Lfi. IfTp-sr 2 IT 7 " > - 7 9 ~DrJ inlii St*.'}^ 2.3?? Idsr^ Ts-79 (vJ So'-A.+^N.*^c0/' /csr^ l>-7? ryiliiJL J>a_-KLrJ^VJVOCo rkvf^ -7c u ;9 rA io C r ^ vli^v.kH 1 Lx - J - S / ^ k ) A r i |1 __ !! a / /e <l.i -o'C %. AVJ K | 77 - -?/(- 1i i _. "79- T "1r/fAivJ KS/\ Oi -' /C<Ta X5/S \Vi r- p*-- 79- _u^r/7^4- (>/fc?sd Mir+L, W'" /M cs/1 i 1/ A rs V/ i P U TK\/CjJ 9-^-5? y ... - -.- :-k.',)j .j<^,--__*^_\'J1-i-m_, SUE ject r CiWt-- unuwi. Oi.o*n C11287 CHAIN OF U 1 M O D Y PfCUM) fasSS C12&8 NRC JOB HUMBER ......................... .. ............. CUSTOMER Rl'RESCHTA!IVt f-S. W / / r ^ ' CONTRACT NUMBER _________________________ _____________ CONTRACT MANAGER ____________________ PLANT NAME OR CODE __________________ HKC TEAM LEADER _________________________ (Specific information on samples 1s available on attached "Sample Identification Log") Signatures Date T Ime Remarks Team Leader Verification of Collected Samples: Relinquished by - Relinquished by: Logged-1n-by: Received by: Received y f t A f / ? : o e n ____________________________________ .* r.4 ; ?A/gy Y'5 o J o Received for Analysis by: * A t Method of Shipment: ^ V r r 've r Number of Contilners: / C o /v - T - ^ ---- -- Special Instructions (Sample preservation, security, delivery to, etc.) _ f.-i(-i*)i \ ----------------11-- 1po-- /o /J./t^SC'*//} jP --------------------vt-r- * * ____________________ ,w Q & Y s * y o ' 7> __________ _ U S----------------- A N A L Y S IS R EQ U EST " < i r r i Y T ^ H W r f t O Z O ! \ II CANTO RESEARCH CORPORATION REQUESTER** '< charge no." | DAYTON LABORATORY tidRn `/ J V . If i. rtPLE DESCRIPTION NUMBER Of B0TTU5 : j i NUMBER OF SAMPHS ~ j ^ REPORT RESULTS TOFILES t m & f i iro^i f. S /fc'W 'VW 8-73 'ixy -Tl W & f o WiGR S/isr'DoZ / f i lt T - % 4*1 TrTl r ^ r n > e 2 -7 "? f f t r & s r fuV/k W iP t ANALYSIS REQUEST T ? * " * * * FIUS XiaVi *5- 7 ? f i n & L k Sicr/o// t t Y V M I E f y d F -ft - f f l * o - i rt.Y / / / b ^ v n - & & & S S b x T B P T j - F f y t r I 'M l S S r A c K f i t f i S & L t *7 ? M i S O L t ST s-n w *> m * f " /ts :-7 ? M i s a i SFc t i 0 ^ s ^ i M ' b o c ^ 3 - 7 1 M i H > L E l c T o / / / A Y Cofrft " INQUIRED ANALYSIS" f j - Z t J S i b t F/i j E$. 7, x f & t o V & w RECORDED BY: 1 i SAMPLES FOR: THofW? SAMPLE LOCATION 2 -> o a > 3 , 1, t - r c KNOWN HEALTH HAZARD PRESENTED BY SAMPLE: -- REFERENCE TO PREVIOUS WORK (REQUEST#, JOURNAL,ETC.) * ' rOMPLETION DATE TIME ALIOTED FOR ANALYSES ANALYST HOURS INST. TIME ANALYTIC L TECHNIQUE ** GAS CHROMATOGRAPH'1 ULTRAVIOLET VISIBLE INFRARED EMISSION.* EDAXXRF MICROSCOPY OTHER OUAL SEMlOUi LNT. NMRi HPLC XRD ICP ATOMIC ABSORPTION MASS SPEC GC/MS AUTO ANALYZER _ QUANT REQUIRED qA/QC if*1 "V " w- * SUBJECT TO '** ^ - 7'w f-r A _7 . ! i iAs u roncD ^ 4 4 A A ---^11289 'SAMPLE DISPOSAL: AFTER REPORT COMPLETE CD DISCARO CD R n U R W L iC G i9 *0LD FOR C D DAYS C D DAYS 3 1 VO 06STT0 c '000 * o o e iiK io N n o H v o v a w 7:"vr M *r , * IV V;* c i I 3 3 r 3 n s V ! " -V .____ J"1-V O ^9* -- fJjfv'PCr 'ITI y -- T t vr v\ <- .* ?> f*S '" T ?*'''$ 1 1-ft -A,. . -*-Lt . *- 'i '2r '.' -*'-? '7 -" .? -`A * b ' V '5 7 7 7 s 7t V 't *'&' v ^ .<-* 11/, r*.- - J '-* 4 > -v P 7 * ' - r,> f^ V r -.'i r > ? r -O ^ ?r T 1sr* ^ <S>50| _>V^r f "V t?Sf> V -.-rj -n * (Tlvo . y j r j t ~ n j Qf/> ,, * V " V S 77^ Q?ift O 7 _____ !_____________ - t / 'I tfl s *V~ T ' rG % y A i '''- ? - * ' 'v b^vt j -J, '- '- 'y - CT7 Wi -'^'7 1>-- * - '? -r-*-'-' > * y -----------------------1--------------------- 1 / * f - f i1--------------------- '*"*? '''n'*y'/""'*HV > / b* -- I 1 j -r*---- ---i w *r # 1 >.r? * * .'p -y r * ,* , ^ */r*i t / 9 r -10 i IC -Z1 c. t ? r - . r jfl r' -o f r i f jo X * c rtC in r>S9 X j n ,3^ - w s --V n / y L '?/9 *--%S ? *V -- ? J* -- *F b X T T j :;r j.T C*` <Vpp.--^ W >/ >/'* i/ ! T "(fr /o-c ^ 7- > -j ^ 0 7 i cr^cvn irfc->r\ ? x -if/y -^ y r r r*** t t _ 5 r ? r -m^ ift'c b v / . ^y/^y 7 V ft^ sr j o V k IfS *'*V ^ u 5u /W C T )` >0 O r c,3 V !W Y im 4 b ' T> i l'-y ._J 1' " C r T r T I ^ r -otyoT O --F y r ^ f (/ i"93^ J----ti - -f -- - f P-Z/S/6 -- --^ / 3l 0 1 ---------- ----X . \ ^--N / " O a/U .A 'N Sfl) A i 0 3 tfVd3Ud " - L C X /tS/i C ^ W F T l ^ JJJ} * 6f2822 N ANVdWOD OJ.NVSNOW -oh go r iD srsn s SUBJECT MONSANTO COMPANY N? 227: i TC90Ovniftnfcl I o sano caaw. m oi im m njpr I (c aun TTVc BfTW 1,0 BFananti t.uo S a n .f N fl rn * me am n s :x a j twmstioct j w er' J arm e wc a j IM j j WO* SPITT j im v u e j r ac K IC c r K *C am V aaLW icx. 320 337 X TOO EU. OUT TW m 33* KT * * II. IS 4.3* .10 in 1/7 .*3 V7 ,u in .53 f/7 .51 t/7 -- V7 -- n 1033 mm 1 tm MM t>* Mt 1*0* 1*51 MMMM J511 .T? 1391 .3 44. .74 73. .74 74. .73 73. .41 13. .ao n . .70 . .13 103. 230 322 W 331* 331 33* 0. 0. 0. 0. 0. 0. IW ). *75. 0. 0. 430. 40TO. 34717. I 0. 0. 71*47, 3BM. SIC . I P. 0. TU . *01*1. 3X147. 1 0. 0. 0 0 3 . 371*1. 31*4*. I 0. 0. *77*5. 3050. 44110. 1 0. 0. MM, 27774. 4330. t 2*433. 17371. TITS. so is . arm . *507. 74T. 43*43. 77441. 33*3. * ume-TO T Q x n iv n r Tivt rae tu rn e r .oc* <r p/t a rt CODES: t: i: 1IWteKistaTOoffOfPf KffSTCtTfPf'MSLnFaceacE <*-c tx s t a *+ *rin . sr b -5P*te ! ic ac ia c t wuuc*ir::rpu>i FM1R.D n a L.aoTinttot sr.s BX7T SE7ECTF5 B.TTD1unit am fiu m e tea. SUBJECT TT r.iOi'iUiiVE ORDER. I BBAO ano u n okasto oo i t OOj / U JEC T OB NO. MONSANTO COMPANY '/ A jZQVv . ^ A ^ a Z___ I /JNEPP AA NR I O MY (S I GM A T U R C S / N? 2273252 D A TE ^ )y? y TOBMTXxran m c p rp q m . mtt* lid m t tir (E a U M MTXtt M MTKl 1.00 M U K & H tt .K T M T-I ICF OM cm *T TIO OEM K K M X 9 STAUS J > 3 M IO W M I MM.TTIC. 3 a s i i t a a.1- w t m e S Z 33* C 1 1 .0 - */tO OBU .72 .M 131. 3 a i* . oe 2 T 33B* 332 XM 7 l . . ICT7X I O C . i r a i , *aman ratcamuaniatirmtm rat iutmct . v we ara SRI ssccst IT:l 1ISCKTSTMECMTTIAOTOCLIFt CKTE*0PT*ra*l 1MMMXOE wewx arar HM/nin som MSPMMTTX'.aoc o iena awcmrtjufi rasisi ama auve rat v i r a DLCFTOETTnT.TELTI)MIT FIliMVC rao* ^ ^ 'ROT UVE ORDER. C11293 M C AO AMO UMOKNSTOOQ Mr OATE i Gi: Mims**?) Hf'i.MwnCdwr'ow*non IIATTIIN i.aikiraiuhv Suoj CI JOO NO.. D A Il__________________________________ U _______ D uo Anu UH01HST00D By Ml Signa i u r _____________________________________ Da t e ___________________________________ u MRC-DA N? 15IG7- Date wvi > c t Job Number Net Time T tme or 0ay CRN 7920 AR Oise Pack i 1 ii ol i i II *I i i' FRN Sp . 7 '1 r / ? V .1 i J ) V ' r ' W r w v,^ ; 07 -r;^ v 7 *fV H <| `i3fn ?ir(i M '''v - p p ( I V.-'jy/u l/l GC Conditions Run KS Conditions Tine >kJlt T/tres AOC MassR Del , ** !I O J O 1 I t ' ! i i i> V f /. ~/t>< * l_ I n/ Al'o* (i L Qce o UJ >; D i I liJ *- O r-: ru o C11297 0C023 321.6-322.6 amu.^UL PE MIX SP233G 2O0-1/3/2S BTL*G1 o File >B285 1 333,0-334.6 amu.2UL .1068/. 43/. 19 SP2330 200-1/3/250 BT F i l e > B 2 3 5 1 3 2 1 . 6 - 3 2 2 . 6 a m u . 2 U L .1063/. 48/. 19 SP2330 200-1/3/250 BT a j. ---- s oOO'iTcrriVE ORQt-R. OC 024 C11298 GC/MS default file: >B2851::01 CIS d a t a f i l e h e a d e r f r o m : >B2 8 3 i Sample: Mise : 2 UL SP 2 . 3 10 30 68/ 20 . 0 4- 81// .31/92 50 O p e r a t o r : GARY BTL403 BTL# Sys. It: 1 MS model : 87 SU/HW r e u . : CA Method file: SP2330 Tun ing file:: APE 101 Source t e m p . : 250 Analyzer temp.: 0 MS 9/ 07/ 8 4 - ALS # : 0 No. of e x t r a r e e ord s : T r a n s f er line t e m p . 4:-23 C h r o m a t o g r a p h i c t e m p e r a t u r e s : 50. C h r o m a t o g r a p h i c t im e s , min. : 0.0 C h r o m a t o g r a p h ic rate, deg/min: 2 0 . 0 300. 2.0 0.0 M/Z s 333.9 First Second peak peak is is baseline drop tangent skimmed cc oo rr rr ee cc tt ee dd area. area. Peak it mR.i nT.. fi rst sc an max sc an s1ca sa nt u pi edat kh rau area 1 11.965 231 23S 241 2 11.965 231 238 241 10 77189 10 7 7 1 99 M/Z = 331.9 S Fe ci or ns dt peak peak is is baseline drop tangent skimmed corrected corrected area, area. Peak # R.T. min. f irst sc an max sc an s1ca s a t n peak width rau area 0. 0.0 0.0 0. 0. 0 0.0 0. 0.0 0.0 co rr, area 55769 32164 co rr. y. 100.00 57.67 Co r r . area corn. 11.965 11.965 196 238 196 238 232 232 86 212076 86 212076 39044 34185 1S070.. 0506 332/334 CALCULAT ION R-GlobalC 0) = '001 M/Z = 327.9 subject to F irst peak is baseline drop corrected area. Second peak is t angent skimmed co rrected area. * P e aItk R.T. min. f irst scan s cmaanx s1ca s a t n peak width raw c o r r . area area 1 11.985 234 239 252 2 11.985 234 239 252 18 7 74 2 0 18 77 42 0 M/Z = 321.9 F irst peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. P e attk R.T. min. first scan max sc an s1ca s a t n wpi edat kh raw area 40394 38612 Coa rrera. 1 11.985 236 239 244 2 11.935 236 239 244 8 31404 8 31404 14244 12784 '4 J A co rr. 108.00 95.59 corn. y. 100.00 89.75 0C025 C11299 S M/Z 3 319.9 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skimmed corrected area. Peak 4 R. T. fi rst min. scan max scan 1ast peak sc an u idth r au area 1 11.985 236 239 245 2 11.985 236 239 245 9 29683 9 29683 >BS85v corr. area 11035 10288 corr. y. 100.00 93.23 320/322 CALCULATION R - G l o b a U 1) * .7747 tVZ 257.0 Fi rst peak is basel ine drop corrected area. Second peak is tangent skimmed corrected area. Peak * R.T. f irst min. sc an max sc an 1ast peak sc an u idt h rau area 1 12.005 237 240 248 11 36930 2 12.005 237 240 248 11 36930 corr. area 8869 8456 corr. * 100.00 95.34 (320 + 322)/< 332 +334) CALCULATION R - G l o b a K 3) = .2655 C328')/<332 + 334) CALCULATION R-Global( 3) = .4247 . . ..;r\L SUBJECT TO P^OTECTiVE ORDER. 00026 C11300 File >B2S52 333.6-334.6 amu. 2UL I .068/.43/.19 SP2330 200-1/3/250 BT File >B2S52 321.6-322.6 amu.^UL 1 .068/. 43/.19 SP2330 200-1/3/2S3 ST OC 02.7 Cl1301 GCyMS default fi lei >B2852::01 MS data file header from i >B2852 Sample: 2UL 1.068/.48/.19 Operator: GARY Misc ; S P 2 3 3 0 2 00-1 >'3/250 BTL#05 BTL# S y s . #: 1 MS model* 87 S U / H U rev.: Cfl Method file: SP2330 Tuning file: APEI01 Source temp.: 230 Analyzer temp.: , 0 MS 9x07/84--4: 5 ALS # : 0 No. of ext r a records: 2 T r a n s f e r line temp. : 0 Chromatographi c temperatures : 50 . 300. 0. 0. 0. Chromat ograph ic t im e s , min. : 0. 0 2.0 0.0 0.0 0.0 Chromatographic rat e f deg/mi n : 20. 0 0.0 0.0 0.0 0.0 M/Z = 333.9 Fi rst peak is base 1ine drop corrected area. Second peak is t angent skimmed corrected area. Peak R.T. fi rst min. scan max scan 1ast peak sc an u idt h raw area 1 11.990 233 238 240 2 11.999 233 238 240 7 78765 7 78765 corr. area 64562 40461 corr. 7. 100.00 62.67 M->Z = 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak * R.T. f irst min. scan max scan 1ast peak sc an width raw area 1 11.990 202 238 277 2 11.990 202 238 277 75 196550 75 196550 c orr. area 44750 35862 corr. * 100.00 80. 14 332/334 CALCULATION R - G l o b a K 0) = .6931 M/Z = 327.9 Fi rst peak is b a s e 1 ine d r o p c o r r e c t e d area. Second peak is t angent skimmed corrected area. Peak # R.T. f irst min. sc an max sc an 1ast peak sc an w i d t h raw area 1 11.990 2 11.990 232 232 233 233 251 251 19 899 8 7 19 8 9 0 8 7 M/Z = 321.9 First peak is base 1 ine drop c orrec t ed area. Second peak is t angent skim med cor r e c t e d area. Peak # R.T. min. fi rst sc an max sc an 1ast peak sc an w i d t h raw area 1 12.610 233 239 251 18 1 9 8299 000282 12.010 233 239 251 18 198299 . c orr. are a 46052 45909 corr. area 161525 156530 corr. '4 130.00 99.69 corr. * 100.00 96.91 011202 s M/Z = 319.9 First peak is b a s e l i n e d rop c o r r e c t e d area. S e c o n d peak is tangent s k i m m e d c o r r e c t e d area* Peak # R.T. first min. scan max scan 1ast peak scan u idth raw area 1 12.051 237 241 253 2 12.051 237 241 253 16 119567 16 119567 corr. area 83727 33623 corr. X 100.00 99.83 320/322 CALCULATION R-G1obal< 1) .7566 M/Z * 257.6 First peak is base 1 ine drop corrected area. Second peak i s tangent skimmed corrected area. Peak # R.T. first min. sc an max scan 1ast peak sc an width raw area 1 12.051 237 241 248 2 12.051 237 241 248 11 111239 11 111239 c orr. area 65853 65330 corr. ; 100.00 99.21 <320 + 322 >/< 332 +334) CALCULATION R - G 1obal< 3) = 3 .6 75 4 < 3 2 8 0 / 0 3 2 + 334) CALCULATION R-Global< 3) .5625 U3JEC7 TO PROTEC.T.IViEj.CiR.EER. ' 00035 C11309 SP2330 200-1/3/259 RUN 3P2339 200-1/3/259 RUN M m tooj \ \ H I OJ _ * Ol OCOJ . to & IOOJ C\O r\l 1 Ol _ O) oOJ o. File >B28S5 321 .6-322.6 amu.2UL UT-22S File >52855 333.5-334.6 amu.^UL UT-262S to IO 01 01 `0 OJJ V-- 3 On eD - vO OJ 01 0 1 <D CCOO OJ rOC-OJ Ul li> uCOO>J m CO m LO <OXJl OJ U) oIO OJ C\O G01' _ G' OJ Cl. 10 cd z u> ; s> i:n-i \ CO \ - i COCDDJ _ ' O'i CO 01 _ l/> LO 0o1 01 ' 01 I 1-- IOiI-l r> ID Ol e <r. H co OJ "D iti ON r UOiJ 1 e' en OinJ lo Ul Uu>i > CO CD CO Ol CQ ,'v OJ Ol oo 'H O (> O oo fl". Ml r) r--. ;) im O UJ Vo- o. o VM ui ^i m i/) MS data file header from : >B2833 Sample! 2UL UT-2623 Operator: GARY MS 9/07/84 .5:43 Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 R U N B T L # I 1 BTL#11 Sys. #: 1 MS m o d e l : 87 S W / H U r e u . : Cfl ALS # : 0 Method file: SP2330 Tuning ftle: APEI01 No. of e xtr a records: 2 Source temp.: 250 Analyzer temp. : 0 Transf er line t e m p . : Chromat o g r a p h ic t e m p e r a t u r e s : 59. Ch r o m a t o g r a p h ic t imes, min. : 0.0 Chromatographi c rate, deg/min: 20.0 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 M/Z 333.9 First peak is b a s e l i n e dro p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. f irst min. sc an max sc an 1ast peak scan u idth raw area corr. area corr. y. 1 12.010 2 12.010 239 239 239 239 243 243 4 44316 4 44816 24016 8238 100.00 34.31 M/Z = 331.9 First peak is b as e 1 in e 'drop c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. min. f irst scan max scan 1ast peak sc an u idt h raw area corr. area corr. y. 1 12.010 2 12.010 237 237 239 239 244 244 7 43313 7 43315 20803 19546 100.00 93.96 332/334 CALCULAT ION * R - G l o b a l < 0) = .8662 M/Z = 327.9 First peak is b a s e l i n e drop c o r r e c t e d area. Sec on d peak is tangent s k i m me d c o r r e c t e d area. Peak 4 R.T. fi rst min. scan max scan 1ast peak sc an u idth rau area 1 12.030 230 240 250 20 76616 2 12.030 230 240 250 20 76616 (1/2 = 3 2 1 . 9 Fir st peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. f ir s t min. sc an max scan 1ast peak sc an u idth rau area 1 12.030 2 12.030 233 233 240 240 244 244 6 16978 6 16978 0G037 '-- \ I Ii corr. area 31516 28446 corr. y. 100.08 90.26 corr. area 3358 3328 corr. y. 100.00 99. 1 1 C11311 M/Z = 319.9 First peak is ba sel ine drop corrected area. Second peak is tangent skimmed corrected area. Peak ft R. T. f i r s t min. scan max sc an 1ast peak sc an u i dt h r aw area 1 12.050 239 241 242 3 9363 2 12.050 239 ' 241 242 3 9363 >3266 co rr, area 2709 2659 co rr. y. 1 0 0 .0 0 9 8 . 15 320/322 CALCULATION R - G I o b a l C 1) = .8067 fl/Z = 2 57 . 0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak If R.T. min. f irst scan max scan 1ast peak s c a n u idt h raw area 1 12.050 240 241 242 2 9286 2 12.050 240 241 242 2 9286 corr, area 3246 3187 corr. * 100.00 98. 18 <320 + 322 )/<332 +334) CALCULATION R - G 1 o b a l < 3) = .1354 <328')/<332 + 334) CALCULATION R - G l o b a K 3) = .7025 0G028 j d ZAJL lOTcCTIVE ORDER, 7 C11312 GC/r MS c Samp Mi sc Sys. Me Sou M/Z Fir Secoi Peak # 1 2 M/Z : Fi r Secor Peak * 1 2 332/3 R-Gl o M/Z = Firs Secn Peak * 21 M/Z = First Secont Peak * 21 File > B2SS6 3 3 3 . 6 - 3 3 4 .6 amu.-UL UT -2 62 6 3P2330 200-1/3/2S0 ? File >B2356 321.6-322. amu.2UL UT-2626 SP2330 200-1/3/25O 4 70 PROTECTIVE ORDER. OC Go 9 C s n/2 * 319.9 First peak is b a s e li ne drop c o r r e c t e d area. Se cond peak is tang en t s k i m me d c o r r e c t e d area. Peak ft R. T. first min. scan max scan 1ast peak sc an wid th raw area 1 12.132 241 245 252 11 3 3 7 4 3 2 12.132 241 245 252 11 3 3 7 4 3 corr, area 10577 9829 ccrr. / 100.00 92.93 320^322 CALCULATION R - G l o b a l < 1) .7971 M/2 = 257.0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R. T. f ir st min. sc an max scan 1ast peak scan width raw area 1 12.152 2 12.152 243 243 246 246 251 251 8 33832 8 33832 corr. area 6672 6624 corr. 5 108.00 99. 28 (320 + 322)/(332 +334) CALCULATION R - G l o b a l ( 3) = .3111 (328')/(332 + 334) C A L C U L A T I O N R - G l o b a l ( 3) = .4276 V ------- -T * * * .a ` c f TO PROTECTIVE ORDER. '' 0C041 C11315 File >B2357 333.-334.6 a/nu.2UL UT-2627 SP2330 200-1/3/250 PUH BL File >B2S57 321.6-322.6 amu,2UL UT-2627 SP2330 200-1/3/250 RUN BL 2000- 1000- 0"7 i"i-- n -- :-- r--i-- i-- i-- |-- t-- i-- r-- r-j-- i-- n -- i-- j-- i-- i-- i-- i-- |-- r 10.0 10.5 11.0 11,5 12.0 12.5 File > B2857 3 1 3 . 6 - 3 2 0 . 6 -amu.^UL U T - 262 7 t--i 'I-- i-- i-- r- i-- [-- i-- i-- i-- r--i-- i-- i i r | i-- i-- !-- i-- | 13.0 13.5 14.0 14.5 15.0 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BL 3000 4000 -- , . T-r . , r- - -T-J -i I t~I i t f | ' I-I r ' ' 1 1 1 1 ' I ' ' | --r -- | 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 15.0 r'""' v* . , . s > SUBJECT TO ?r.CTEJ. \ 1 '' L 00042 C11316 G O n S de Tau 11 f i l e : > B 2 8 5 7 ::0 1 MS data file header from : >B2857 Sample: 2UL UT-2627 Operator: GARY MS 9/87/34 Mise : SP2330 200-1/3/258 RUN BLT#15 BTL#15 Sys. #: 1 MS model: 87 S W / H U reu.: CA ALS tt : 0 Method file: SP2339 Tuning file: APEI01 S o u r c e t em p .: 250 A n a l y z e r temp tm 0 No. of e x t r a records: 2 Transfer line temp. : 6: C h r o m a t o g r a p h i c t e m p e r a t u r e s : 50. C h r o m atographie times, min. : 8.0 C h r o m a t ographi c rat e t deg/min : 20.0 308. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 M / Z =* 3 3 3 . 9 F irst peak is b as e li ne drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak ft R.T. min. first scan max scan 1ast peak scan width raw area 1 12.212 2 12.212 248 246 249 249 253 253 7 92187 7 92187 corr. area 41192 39683 corr. ym 100.00 96.34 M/Z = 331.9 F irst peak is b a s e 1 ine drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. min. f irst scan max scan 1ast peak scan width raw area corr. area corr. 4 1 12.192 2 12.192 245 245 248 248 254 254 9 97418 9 97418 30539 29922 100.00 97.98 332/334 CALCULATION R - G l o b a l < 0) = .7414 M/Z = 327.9 F i rs t peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d pe ak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R.T. fi rst min. sc an max sc an Iast peak sc an w i d t h raw area 1 12.212 2 12.212 246 246 249 249 253 253 7 87136 7 87136 M/Z = 321.9 F irst peak is b a s e 1 ine <drop c o r r e c t e d area. S e c o n d peak is t an g e n t s k i m m e d c o r r e c t e d area. Peak it R.T. min. f ir s t sc an max sc an 1ast peak sc an w i d t h raw area I 0. 000 2 0.000 254 254 0 253 0 253 -1 -1 0 0 00043 corr. area 30429 25973 corr. *4 100.00 85.36 corr, area 2196 2196 corr. * 100.00 100.00 C11317 S M/Z a 319.9 .. First peak is b a s e l i n e drop c o r r e c t e d area. Se co n d peak is tang ent sk i mme d c or r e c t e d area. Peak # R. T. f irst min. sc an max scan 1ast peak scan width raw area 1 0.000 2 0.000 254 254 0 253 0 253 -1 -1 0 0 >$3267 corr. area corr. y. 2190 100.00 2190 100.00 320/322 CALCULATION R - G T o b a U 1) = .9975 M/Z - 257.0 F ir s t peak is b a s e l i n e dro p c o r r e c t e d area. S e c o n d p ea k is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. min. fi rst sc an max sc an 1ast peak sc an ui d t h rau area 1 0.000 2 0.000 254 254 0 253 -1 0 253 . -1 0 0 com, area 4259 4259 com. X 100.00 100.00 <320 + 322)/<332 +334) CALCULATION R - G l o b a l < 3) = .0612 < 3 2 8 0 / 0 3 2 + 334) CALCULATION R - G l o b a l < 3) = .4239 4 SUBJECT ro iOTECTVE C S D C i 0C044 C11318 rile >32859 3 3 3 . 6 - 3 3 4 . 6 amu. 2U L UT -2 62 8 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT 10000- A r\s* 1 0 . 00-K'10`.S '11*.0 ' `11*.5 ' 12*.0 `12*.5 File >B2359 327.6-328.6 amu.ZUL UT-262S i ~r i 1 * 1 1i 1 1 1 -- i ' * i 13.0 13.S 14.0 14.5 15.0 S P23 30 2 0 0 - 1 / 3 ^ 2 5 0 RUN BT File >B2359 321.6-322.6 amu.SUL UT-2623 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT SUBJECT TO PROTECTIVE ORDER. OG 04 5 GC/MS default file: >B2859::0l MS data file header from : >B2859 Sample: 2UL UT-2628 Operator* GARY MS 9/07/84 -7:03... Mi sc : S P 2 3 3 0 '200-1/3/230 RWN B T L # 1 9 B T L # 1 9 Sys. *: 1 M S model! 87 S W / H U r e u . : CA A L S tt : 0 Method file: SP2330 T un i n g file: APE1 01 No. of e x t r a r ec or d s : 2 Source temp.: 230 Analyzer temp.: 0 Transfer line temp. : 0 - C h r omtographic temperatures : 50 C hr o m t o g r a p h ic times, min. : 0. 0 C h r o m a t o g r a p h ! c rate, deg/m in : 20. 0 300. 2.0 0.0 0. 0.0 0.0 0. 9.0 0.0 0. 0.0 0.0 M/Z = 333.9 F irst peak is b a s e l i n e d r o p c o r r e c t e d area. S e\c,on d 1 peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. min. first scan max s c an 1ast peak s c a n U idt h r au area corr. area corr. 2 12.112 2 12.112 242 242 244 244 247 247 5 84884 5 84884 46919 36026 100.00 76.78 M/Z = 331.9 Fi rst peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak .# R.T. min. f ir st scan max scan 1ast peak sc an width raw area corr. area corr. 1 12.112 2 12.112 242 242 244 244 246 246 4 - 81589 4 81589 31465 29057 100.00 92.35 332/334 CALCULATION R - G l o b a l < 0) = .6708 M/Z = 327.9 F irst peak is b a s e l ine d r o p c o r r e c t e d area. Seco nd peak is ta ngent s k i m m e d c o r r e c t e d area. t ^ "" - i - , ,j J j SUBJECT TO PROTECTIVE 0. * Peak * R.T. min. first scan max scan 1ast peak scan u idt h raw area corr. area corr. 1 if 2 12.112 12.112 242 242 244 244 247 247 5 222328 5 222323 M/Z = 321.9 i f irst peak is b a s e l i n e drop c or r e c t e d area. S e c o nd peak is t a n g e n t s k i m m e d c o r r e c t e d area. 54167 50527 100.00 93.28 Peak :1* R.T. min. first scan max scan 1ast peak sc an w i d t h raw area corr. area corr. */. :1 2 0.000 0.000 248 248 0 247 0 247 -1 -1 nr r 0 2667 100.00 0 2667 100.00 Cl1320. s (1/Z - 319.9 First peak is b a s e l i n e drop c o r r e c t e d area. Se co nd peak is tangent s ki m m e d c or re c t e d area. Peak R. T. f irst min. scan max scan 1ast peak sc an u i"d t h nau area 1 2 0.000 0.000 248 248 0 247 0 247 -1 -1 0 0 corr, area 2280 2230 corr. Ji 100.00 100.00 320^322 CALCULATION R - G l o b a 1 < 1) =* .8547 M>Z = 257.0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak :* R.T. f irst min. scan max scan 1ast peak s c a n u idt h raw area 1 0. 000 2 0.000 243 248 0 247 0 247 -1 -1 0 0 corr. area 16042 16042 corr. v. 100.00 100.00 (320 + 322)^(332 +334) CALCULATION R - G l o b a l ( 3) = .0531 <328" )/`<332 + 33 4 ) C A L C U L A T I O N R - G l o b a l < 3) - .6907 f \ 00047 C11321 Fil? >B2S61 333.6-334.6 amu.2UL UT-2630 SP 2 33 0 200- 1/3/250 RUN BT Fil? >B2361 321.6-322.6 amu.^UL UT-2630 SP2330 200-1/3/250 RUN BT 00048 C11322 GC'MS default fil: >B2S61::01 MS data file header from i >B286l` Sample: 2UL UT-2630 Operator: GARY MS 9 ' 0 7 ' 8 4 . .7:43 Mise : SP2330 200-1'3/250 RWN BTL#23 BTL#23 Sys. i 1 MS mode 1 i 87 S W ' H U r e u .: CA 'ALS # : 0 Method file: SP2330 Tuning file: APEI01 No. of e x t r a records: Sourc e t e m p .: 252 finalyzer t e m p . : 0 Transfer line temp. : ' Chromatographie temperatures : 50 ; C h r o m a t o g r a p h i e tim e s , min. ; 0. 0 ; Chromat o g r a p h ic rate, d e g ' m in: 20. 0 <* M^Z = 333.9 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. P e ak # R .T , first min. sc an max sc an last peak scan width raw ar ea corr. area corr. V. . 1 12.051 238 241 247 2 12.051 233 241 247 9 116088 9 116086 85792 77314 100.00 90. 12 M'Z = 331.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d area. Peak # R.T. first min. sc an max sc an 1ast peak sc an w i d t h r aw area com. area corr. 1 12.071 2 12.071 237 237 242 242 243 248 11 1 3 9 1 5 6 11 1 3 9 1 5 6 65192 58449 100.00 89.66 332'334 CALCULATION R - G l o b a K 0) * .7599 M'Z = 327.9 SUBJECT TO .1 Zi First peak is base 1 ine drop corrected area. Second peak is tangent skimmed c o r rected area. Pe ak -* R.T. fi rst min. sc an max sc an 1ast peak scan width raw area corr. area corr. */ 1 12.091 239 243 247 * 2 12.091 239 243 247 8 522313 8 522313 112583 85895 100.00 75.29 M'2' = 321.9 F irst peak is baseline drop c o r r ected area. Second peak j s tangent skimmed corrected area. Peak ;# R.T. f irst min. sc an max scan 1ast peak sc an width raw area corr, area corr. ym * 1 12.091 238 243 252 ' 2 12.091 238 243 252 14 166613 111929 100.00 14 166613 111474 99.59 0G049 C11323 s M/Z = 319.9 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skimmed co rr ect ed area. Peak :# R. T. first min. scan max scan 1ast peak sc an u idt h rau area 5 1 12.091 2 12.091 23d 23d 243 243 254 254 18 1 2 5 2 8 5 18 1 2 5 2 8 5 >>2M corr. area 84155 31356 corr. ij 100.00 96.67 320^322 CALCULATION R rG l o b a l C 1) = .7519 ns Z = 257. 0 F irst peak is b a s e l i n e drop c orrected area. Second peak is tangent skimmed corrected area. Peak R. T. f irst min. sc an max scan 1ast peak s c a n ui d t h rau area 1 12.091 2 12.091 240 240 243 243 248 248 8 237548 8 237548 corr. area 75663 69135 corr. % 100.00 91.37 <320 + 322)/<332 +334) CALCULATION R - G 1o b a l < 3) = 1.2987 <328')/<332 + 334) CALCULATION R - G 1o b a l < 3) = .7390 A 0CQ50 C11324 File >B2S62 333.6-334,0 amu.SUL UT-231 SP23 39 200-1/3/250 RUN 2T 20000-j 10000-j Q-^ i i r i i" i i i I't j ` ) 'I <--r r i T-- 1-- i- --i i i' i i i - i f - i i - i i i i - i i - 7 i t i j 1 1 i t ) ; 10,0 10.S 11.0 11.5 12.0 12.5 13.0 13.S 14.0 14.5 15.0 File >52862 331.6-332.6 amu.^UL UT-2631 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN ET File >B2S62 321.6-322.6 amu.2UL UT-2631 SP2330 2O0-1/3/2S0 RUN BT 0C051 C11325 M$ data file header from : >B2862 Sample! 2UL UT-2631 Operator: GARY MS 9/07/84 .8:03... Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 3 0 RUN B T L # 2 5 B T L # 2 5 Sys. ft: 1 MS model: 87 S U / H U rev.: CA ALS ft : 0 -Method file: SP2330 Tuning file: APEI01 Ho. of ext ra records: 2 Source temp.: 232 Analyzer temp.: 0 Transfer line temp. : 0 * C h r o m t ographi c t e m p e r a t r e s : 50. C h r o m a t o g r a p h i c t imes , min. : 0.0 Chromt o g ra ph ic rate, deg /min : 20.6 ) MfZ 3 333.9 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 6.0 0. 0.0 0.0 F irst peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n ge n t s k i m m e d c o r r e c t e d area. Peak ft R.T. f irst min. sc an max scan 1ast peak scan y idt h ray area corr, area co r r . * 1 12.051 - 2 12.051 237 237 241 241 249 249 12 140692 100672 100.00 12 1 4 0 6 9 2 94366 93.74 M>Z = 331.9 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R.T. min. f irst sc an max sc an 1ast peak sc an y idt h ray area corr. area corr. '4 1 12.051 237 241 253 2 12.051 237 241 253 16 1720 53 16 17205S 79786 75693 100.00 94.88 332/334 CALCULATION R - G l o b a l < 0) = .7925 M/Z = 327.9 F irst peak is b a s e 1 ine d ro p c o r r e c t e d area. S e c o n d peak is t a n ge n t s k i m m e d c o r r e c t e d area. ... < SUBJECT TO PROTECT," .v- Peak :* R.T. f irst min. scan max scan 1ast peak scan u idt h ray area corr. area corr. y. ; 1 12.071 ' 2 12.071 238 233 242 242 247 247 9 624209 9 624209 144471 112899 160.00 73.15 M/Z a 321.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak ft R.T. f irst min. sc an max sc an 1ast peak sc an u idt h rau area corr. area corr. y. 1 12.071 2 12.071 237 237 242 242 256 256 19 2 2 6 3 4 4 19 2 2 6 3 4 4 161839 159537 100.00 93.61 0C052 C11326 n/z = 319.9 First peak is b a s e li ne drop c o r r e c t e d area. S e c o n d peak is tangent skim me d c o r r e c t e d area. Peak .# R. T. f irst min. scan max scan 1ast peak sc an w i d t h r aw area j 1 12.071 ; 2 12.071 236 236 242 242 257 257 21 1587 96 21 1 5 87 96 t \ 320/322 CALCULATION 4 R f G l o b a l C 1) - .6934 c or r . area 112218 110695 corr. 100.00 98.64 M>2 = 257.0 first peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. fi rst min. sc an max scan 1ast peak sc an w i d t h raw area 1 12.071 2 12.071 239 239 242 242 251 251 12 3 6 5 3 5 7 12 3 6 5 8 5 7 corr, area 116064 114768 corr. V. 100.00 98.88 <320 + 322)/<332 +334) CALCULATION R - G l ob al C 3) = 1.5187 < 3 2 8 0 / ( 3 3 2 + 334) CALCULATION R - G l o b a l < 3) = .7925 SUB. JECT TO P^OTE n- ip 00053 C11327 rile >32363 333.6-334. amu.^UL UT-2632 SP2330 200-1/3/250 RUN 3T File >B2S63 321.6-322.6 amu.2UL UT-2632 SP2330 200-1/3/2S0 RUN BT OC 054 C11328 MS data file header from : >B2863 Sample: 2UL UT-2632 Operator: GARY MS 9/07/84 8t23 Mise : SP2330 208-1/3/250 RUN BTL*27 BTL#27 Sys. tt: 1 MS model: 87 S U / H U reu. : Cfl A L S # : 8 Method file: SP2330 T u n i n g file: AFEI01 No. of e x t r a r ec or d s : 2 Source temp.: 230 Analyzer temp.: 0 Transfer line temp. : 0 'Chromatographi c t e m p e r a t u r e s : 50. Chromatographic times, min. : 0.0 C h r o m a t o g r a p h i c rate, d eg/min; 20. 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 - M/Z = 333.9 F irst peak is base 1 ine drop c o r r e c t e d area. Second peak is t angent ski mme d c o r r e c t e d area. Peak * R. T. f irst min. sc an max sc an 1ast peak scan width raw area com. area corr. 5; 1 12.891 12.091 238 238 243 243 249 249 11 9 5 5 1 5 11 9 5 5 1 5 63417 57070 100.00 39.99 M/Z = 331.9 F irst peak is b a s e l ine dr o p c o r r e c t e d area. Second peak is t angent skimmed corrected area. Peak # R ,T . f irst min. sc an max scan 1ast peak scan width raw area corr. area corr. j. 1 12.091 238 243 250 12 97 16 3 44015 100.00 2 12.091 238 243 258 12 97163 3901 1 8 8 . 6 3 .m 332/334 CALCULATION R - G l o b a K 0) a .6941 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. SUBJECT TO PROTECTIVE ORDER. Peak # R.T. f irst min. scan max scan 1ast peak sc an w i d t h raw area cor r . area corr. * 1 12.111 2 12.111 243 243 244 244 245 245 2 154992 2 154992 54287 53495 100.00 98.54 M/Z = 321.9 F irst peak is b a s e l i n e <drop c o r r e c t e d area. Second peak is t angent s k i mm ed c o r r e c t e d area. Pe sk * R. T. first min. scan 1 12.111 2 12.111 240 240 max sc an 244 244 last peak sc an width 253 253 13 13 raw area 184673 184673 corr. area 135442 134675 corr. V. 100.00 99.43 0C055 G11329 s M/Z = 319.9 First peak is b a s e l i n e drop c o r r e c t e d are*. Second peak is ta ngent sk im me d c o r r e c t e d area. Peak * R. T. fi rst min. `sc an max scan 1as t peak sc an u idt h r au area 1 12.111 2 12.111 239 239 244 244 257 257 18 1 4 3 1 6 6 18 1 4 31 06 *co r r . area 99006 98016 c orr. 160.00 99.00 * 320/322 CALCULATION R - G 1o b a l ( 1) = .7310 tl/Z = 2 5 7 . 0 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak tt R. T. f irst min. sc an max scan 1ast peak scan width raw area 1 12.111 241 244 251 2 12.111 241 244 251 10 2 5 7 7 6 8 10 2 5 7 7 6 8 corr. area 84807 83287 corr. 3S 100.00 98.21 (326 + 322)/(332 +334) CALCULATION R - G 1o b a l ( 3) = 2.1823 ( 3 280/(332 + 334) CALCULATION R - G 1o b a l ( 3) = .4940 00056 . C11330 File >E2864 3 3 3 .6-334.6 amu .2'JL .2 6 6 9 / .43/ .19 SP2330 2 0 9 - 1/3/250 RUN BT F i l e > B 28 64 3 2 1 . 6 - 3 2 2 . 6 a m u . ^ U L . 2 6 6 9 / . 4 3 / . 19 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT i-\ i. ORDER--- err t o 0 P 0 T F . C t 1 V E 0C057 C11331 GC/MS default file: >B2864::01 MS data file header from : >B2864 Sample: 2UL .2669/.48/.19 Operator: GARY MS 9 / 0 7 / 8 4 -8 Mise : SP2330 200-1/3/250 RUN BTL#29 BTL#29 Sys. #: 1 MS model : 87 SU/HW r e u . : CA ALS # : 0 Method file: SP2330 T u n i n g file: APE 181 No. of e x t r a r ec o r d s : Source temp.: 250 Analyzer temp.: 0 Transf er line temp. : 2 0 C h r o m a t o g r a p h i c t e m p e r a t u r e s : 50. C h r o m a t o g r a p h i c t imes i min, : 0.0 Chromatographi c rate, deg/min: 20.0 300; 2.0 0.0 0. 0.0. 0.0 0. 0.0 0. 0 0. 0.0 0.0 M/Z = 333.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta ng en t s k i m m e d c o r r e c t e d area. Peak .# R. T. fi rst min. scan max sc an 1as t peak sc an u idt h rau area corr. area corr. X 1 12.051 239 241 247 2 12.051 239 241 247 8 93249 8 93249 57993 57461 100.00 99. 08 M/Z = 331.9 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Pe ak # R.T. min. first sc an max scan 1ast peak sc an u idt h raw area corr. area corr. * 1 12.071 2 12.071 237 237 242 242 251 251 14 ' 8 5 3 7 4 14 8 5 3 7 4 41946 39741 100.00 94.74 332/334 CALCULATION R - G 1o b a l < 0) = .7233 M/Z = 327.9 -V, s u b j e c t t o p r o t e c t IV, First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent sk im me d c o r r e c t e d area. Pe ak # R.T. min. f irst sc an max sc an 1 ast peak sc an w i d t h raw area corr. area corr. X 1 12.091 241 2 12.091 , 241 243 243 247 247 6 236832 6 236832 68111 50903 100.00 74.74 M/Z = 321.9 First peak is base line drop corrected' area. Second peak is tangent skimmed corrected area. Peak # R. T. f irst min. sc an max sc an 1ast peak sc an w i d t h raw are a corr. are a corr. 7* 1 12.091 238 243 252 14 85830 42934 100.00 2 12.091 238 243 252 14 85830 42402 98. 76 oc 05 fil 1 3 3 9 s M/Z = 3 1 9 . 9 First peak is b a s e l i n e drop c o r r e c t e d are*. Second peak is tangent s k i m m e d c o r r e c t e d area. Peak # R. T. fi rst min. sc an 1 12.091 2 12.091 238 238 max scan 24.3 243 1ast peak sc an t u fdt h 252 252 14 14 r au area 59564 59564 corr. area 29450 28659 corr. * 100.00 97.31 320/322 CALCULATION R - G l o b a l < 1) * .6859 M/Z = 257.0 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R.T. f ir st min. sc an max scan 1ast peak sc an u idt h rau area 1 12.091 241 243 247 2 12.091 241 243 247 6 79116 6 79116 corr. area 22764 21423 corr. Ji 100.00 94. 1 1 (320 + 3225/(332 +334) CALCULATION R - G l o b a l < 3) = .7243 <328')/<332 + 334) CALCULATION R - G l o b a l ( 3) = .6777 SUBJECT TO PROTECTiYE ORDER. 00059 C11333 File >B2865 333.6-334. amu.^UL UT-233 S P23 39 200-1.'*3/250 RWN BT File > B2365 3 2 1 . 6 - 3 2 2 . 6 am-j.2UL UT- 26 33 SP2339 290-1/3/250 RWN BT 00060 C11334 ; GC /M S default file: > B2 96 5: :01 MS data file header from : >B2865 Sample: 2UL UT-2633 Operator: GARY MS 9 / 0 7 / 8 4 - _9.-03 Misc : SP2330 200-1/3/230 RUN BTL#31 BTL#31 Sys. 4: 1 MS m o d e l : 87 SU/HW r e v , : CA RLS # : 0 Method file: SP2338 Tuning file: APEI01 No. of e x t r a records: 2 Source temp.: 250 Analyzer temp.: 0 Transfer line temp. : 0 - C h r o m a t o g r a p h i c t e m p e r a t u r e s : 50. C h r o m a t o g r a p h ic times,i fn i n * 0.0 C h r o m a t o g r a p h i c r at e , d e g / m in: 20.0 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 M/Z 333.9 First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is ta ng en t s k i m m e d c o r r e c t e d area. Peak * R.T. f irst min. scan max sc an 1ast peak scan u idt h raw area corr. area corr. *4 1 12.044 2 12.044 243 243 244 244 247 247 4 75275 4 75275 42783 31329 100.00 73.36 M/Z = 331.9 F irst peak is b as e 1 in e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. fi rst min. sc an max sc an 1ast peak s c a n u idt h rau area corr. area corr. * 1 12.044 2 12.044 242 242 244 244 248 248 6 57725 6 57725 34523 30395 100.00 88.64 332/334 CALCULATION R - G l o b a l < 0) = .8084 -- - -- -, M/Z = 327.9 First peak is ba s e l i n e drop c or re c te d area. S e c o n d peak is t a n ge nt s k i m m e d c o r r e c t e d area. S U B J E C T T O p ".-r - - Peak 4 R.T. first min. scan max sc an 1ast peak scan width rau area corr. area corr. 1 12.065 2 12.065 242 242 245 245 249 249 7 171017 7 171017 67802 57949 100.00 85. 47 M/Z. = 3 2 1 . 9 F ir st peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is ta ng en t s k i m m e d c o r r e c t e d area. Peak * R.T, min. f ir st scan 1 12.065 2 12.065 239 239 max sc an 245 245 1ast peak sc an w i d t h 258 258 19 19 rau area 196646 196646 Or np corr. area 146866 143408 corr. * 100.00 97.65 C11335 s n/z = 3 1 9 . 9 First peak is b a s e l i n e drop c o rr ec te d area. Se cond peak is tang en t ski mmed c o r r e c t e d area. Peak # R. T. f irst min. sc an max sc an 1ast peak sc an w i d t h r au area 1 12.085 241 246 255 2 12.085 241 246 255 14 1 2 9 2 1 2 14 1 2 9 2 1 2 corr. area 97684 95332 corr. ;/ 100.00 97. 59 320/322-CALCULATION R - G 1o b a l < 1) A .6651 M/Z = 257,0 First peak is b a s e l i n e dro p c o r r e c t e d area. S e c o n d peak is t a n ge nt s k i m m e d c o r r e c t e d area. Peak # R . T. fi rst min. scan max sc an 1as t peak scan width raw area 1 12.085 2 12.085 243 243 246 246 250 250 7 126026 7 126026 corr. area 67821 62536 corr. y. 100.00 92.21 <320 + 322>/<332 +334) CALCULATION R-G 1o b a l < 3) = 3.1667 <328')/<332 + 334) CALCULATION R-Global< 3) = * .8689 subject to .r^,. 7 1 ' : -w ic.1 Tt-zV*cr 0(>*,3'1 00062 C11336 File* > B 2S66 333.-334.6 mu.^UL UT-2634 SP 2330 200-1/3/230 RUN ST File >B2366 321.6-322. amu.SUL UT-2634 SP2330 2 0 0 -1/3/250 RUN BT 00063 C11337 GC/MS default file: >B2866::01 MS data file header from : >B2866 Sample: 2UL UT-2634 ' Operator: GARY MS 9/ 07 /84 9:.22.._ Misc : SP2330 200-1/3/250 RWH BTL433 BTL#33 Sys. #: 1 MS model: 87 S U / H U r e u . : Cfl ALS It : 0 Method file: SP2330 T u n i n g file: R P EI01 No, of e x t r a r e c o r d s : 2 Source temp.: 252 Analyzer temp.: 0 Transfer line temp. : 0 C hr o m a t o g r a p h ic t e m p e r a t u r e s : 50. C h r o m a t o g r a p h i c t imes, min. : 0.0 C hr o m a t o g r a p h ic rate, d e g / m in : 2 0 . 0 300. 2. 0 0.0 0. 0.0 0.0 0. 0. 0.0 0.0 0.0 0.0 M/Z = 3 3 3, 9 First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. f irst min. scan max sc an 1ast peak sc an ui dth raw area corr. area corr. */. 1 12.031 2 12.031 236 236 246 240 246 246 10 105110 10 105110 78200 70850 100.00 90.60 M/Z = 331.9 F irst peak is b a s e l i n e idrop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak it R.T. fi rst min. sc an max scan 1ast peak sc an w i d t h raw area corr. area corr. 1 12.031 2 12.031 237 237 240 240 248 248 11 9 5 1 9 7 11 9 5 1 9 7 56043 51785 100.00 92.39 332/334 CALCULATION R - G l o b a l < 0> = .7167 M/Z = 327.9 First peak is b a s e l i n e dr op c o r r e c t e d area. Second peak is tangent sk i m m e d c o r r e c t e d area. a ^ \\ T SUBJECT TO ~>rrr~^'^j >- - /V e .jPn'T- Peak ' it R.T. first mi n. scan max sc an 1ast peak scan width raw area corr. area corr. 1 12.051 237 241 246 2 12.051 237 241 246 9 298800 9 298800 76453 60119 100.00 78.62 M/Z = 321.9 First peak is b a s e l i n e d r o p corrected- area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. min. 1 12.052 2 12.051 fi rst scan 238 238 max scan 241 241 1ast peak scan width 247 247 9 9 raw area 159832 150832 corr. area 121024 109243 corr. * 100.00 90.27 0G064 C11338 s n/Z = 319.9 First peak is ba s e l i n e drop corrected area. S e c o nd peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R .T . f irst min. sc an max scan 1ast peak scan width raw area 1 12.051 2 12.051 236 236 241 241 256 256 20 133584 20 133584 co r r . area 88864 86054 corr. % 100.00 96.84 320/322 CALCULATION R - C l o b a l < 1) = .7343 M/Z - 257.0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. fi rst min. sc an max scan last peak sc an width raw area 1 12.071 2 12.071 238 238 242 242 247 247 9 152622 9 152622 corr. area 74700 63855 corr. 7. 100.00 85.48 (320 + 322 )/ <332 +334) C A L C U L A T I O N R - C l o b a K 3) = 1.5634 < 3 2 8 0 / ( 3 3 2 + 334) CfLCULfTION R - G l o b a l < 3) = .5615 ' w J. 3?TAL SUBJECT TO PROTECTIVE ORDER, 00065 C11339 F i l e >B2S o 7 3 3 3 . 6 - 334.6 a m u . 2UI_ U T - 2 35 S P 2330 2 0 0 - 1/ 3/259 RUN BT F i l e >B2367 3 2 1 . 6- 322.6 a m u . 2 UL UT-2635 S P 2330 20 0 - 1/ 3/250 RUN BT MS data file header from : >B2867 Sample: 2UL UT -2635 Operator : GARY MS 9/07/84 Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN B T L # 3 5 B T L # 3 5 Svs. 4: 1 MS m o d * 1: 87 S U / H U r*u. : CA ALS # 0 Method file: SP2330 Tuning file: APEI01 S ou r ce t e m p .: 250 A n a l y z e r t e m p * ** 0 No. of e x t r a records: Transfer 1 in* temp. : Chromatographic temperatures 50 * C h r o m a t o g r a p h i c t imes , min. : 0. 0 C h r o m a t ographi c rat e, deg/mi n : 20. 0 300. 2.0 0.0 0 0. 0 0. 0 0e 0. 0 0. 0 0. 0.0 0.0 11/Z = 3 33 . 9 First peak is b a s e l ine dr o p c o r r e c t e d area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d area. Peak 4 R.T. first min. scan max sc an 1ast peak sc an w i d t h raw area com. area corr. 4 1 12.030 2 12.030 234 234 240 240 252 252 18 130366 18 130366 81910 78688 100.00 96.07 M/Z = 331.9 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d area. Peak # R.T. f irst min. sc an max sc an 1ast peak scan width raw area corr. area corr. 4 1 12.030 2 12.030 236 236 240 240 251 251 15 108161 15 108161 56861 55758 100.00 93.06 332/334 CALCULATION R - G l o b a U 0> = M/Z = 327.9 .6942 SUBJECT TO PROTECTIVE ORDER First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R.T. first min. scan max scan 1ast peak sc an w i d t h raw area corr. area corr. 5i 1 12.051 237 241 246 2 12.051 237 241 246 9 203074 9 203074 60784 56904 100.00 93.62 M/2 = 321.9 First peak is b a s e ) ine drop corrected area. S e c o n d peak is tangent s k i m m e d c o r r e c t e d area. Peak # R.T. f ir s t min. scan max scan Iast peak scan width raw area corr. area corr. y. 1 12.051 238 241 246 2 12.051 238 241 246 8 34928 8 34928 10520 9928 100.00 94.37 00G67 C11341 S M/2 = 319.9 7>?)2S1 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r ec te d area. Feak # R.T. f irst min. scan max scan 1ast peak scan uiidt h r au area corr. area corr. 7. 1 12.051 2 12.051 238 238 241 241 247 247 9 28746 9 28746 8451 7780 100.00 92.06 32 0/3 22 CfLCULfTION R - G l o b a l < 1) * .8033 M/Z = 257.0 First peak is b a s el ine d r o p c o r r e c t e d area. Second peak is tan gen t s k i m m e d c o r r ec te d area. Peak it R.T. first min. scan max scan 1ast peak scan width raw area 1 12.051 2 12.051 239 239 241 241 244 244 5 46929 5 46929 corr. area 10379 10161 corr. 100.00 97. 90 <320 + 322 > / ( 3 3 2 + 334) CALCULATION R-Global< 3) = .1367 <3 28 ')/ <33 2 + 334) CfLCULfTION R-G o b a l < 3) = .4373 00068 SUBJECT TO -- * - J j i ^ PROTECTIVE j ORDER. C11342 rile >32363 333.6-334.6 amu.^JL UT-2636 SP2330 200-1/3/250 RUN BT File >32363 321.6-322.6 amu.^UL UT-2636 SP2330 200-1/3/250 RUN 3T File >32863 256.7-257.7 amu.SUL UT-2636 SP2330 200-1/3/250 RUN BT 3300- 4300- 010.0 10.5 ll'.e 11*. 5 '12. a 12,5 13.0 13.5 1 4 . 0 ' "14.5 ' 'ls'.O SUBJECT TO PROTECTIVE ORDER. 00069 C11343 MS data file header from : >B2868 Sample: 2UL UT-2636 Operator: GRRY MS 9/07/84--10r02 Mise SP2330 200-1/3/250 RUN BTL#37 BTL437 Sys. #: 1 MS model : 87 SW/HN r e v . : CR RLS : 0 Method file: SP2330 Tuning file: RPEI01 Source temp.: 250 Rnalyzer temp.: 0 No. of e x t r a r ec or ds : Transf er 1 ine t e m p . Chromt o g r a p h ic t e m p e r a t u r e s : 50. Chromt o g r a p h ic times, min. ; 0.0 C h r o m a t o g r a p h ic rate, deg/min: 20.0 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 M/Z 333.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. *Peak R.T. f irst min. sc an max scan 1ast peak sc an wi dth raw area corr. area y.c o r r . 1 12.010 2 12.010 238 238 239 239 244 244 8 107248 8 107248 78584 74548 100.00 94.86 M/Z = 331.9 First peak is b as e 1 ine d r o p c o r r e c t e d area. Second peak is tangent s k i m m e d c or r e c t e d area. Peak R.T. f irst min. sc an max scan 1ast peak scan u idt h raw area c orr. area *corr. 1 12.010 231 239 256 2 12.010 231 239 256 25 139010 25 139010 66335 62047 100.00 93.54 332/334 CRLCULRTI ON R - G l o b a l C 0) .8441 M/2 = 327.9 F irst peak is basel ine d r o p c o r r e c t e d area. S ec on d peak is t a n g e n t s k i m m e d c o r r e c t e d area. 4Peak R.T. fi rst min. scan max sc an 1ast peak sc an w i d t h raw area 1 12.030 2 12.030 229 229 240 240 252 252 =M/Z 3 2 1. 9 23 318017 23 318017 F irst peak is b a s e l i n e dr o p corrected. area. S ec on d peak is ta n g e n t s k i m m e d c o r r e c t e d area. #Peak R.T. f irst min. scan max scan 1ast peak scan width raw area 1 0.000 2 0.000 253 253 0 252 0 252 -1 -1* 0C070 0 0 (T'T'-'r SUBJECT 7V>r^-_i_EC corr. area 88063 53839 *4c o r r . 100.00 61.14 corr. area 2708 2708 y.corr. 100.00 100.00 Cl1344 S n/Z * 319.9 First peak is ba s e l i n e drop c o r r e c t e d ire*. S e c on d peak is t a n g e n t s k i m m e d c o r r e c t e d re*. Peak tt R. T. f irst min. sc an max scan 1ast peak scan width raw area 1 0.000 2 0.000 253 253 0 252 0 252 -1 -1 0 0 corr. area 2193 2193 c orr. % 100.00 106.00 320''322 C A L C U L A T ION R - G lo b al i 1> = .6100 M/2 * 257.0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R.T. first min. scan max sc an 1ast pe ak scan u idth raw area 1 0. 006 0. 000 253 253 0 252 ' -1 0 252 -1 0 0 corr. area 6477 6477 c orr. Ji 106.00 106.66 (320 + 322>r (332 +334) CALCULATION R - G l o b a l ( 3) = .0338 (328' >/(332 + 334) C A L C U L A T I O N R - G l o b a l ( 3) = .6075 imitain miw<> CX c a w JwCTc^ :O:*i_3/ TO PROTECT!'/ 1AL ORDER, C11345 Orr Fi1e > 333.6-334,6 Arou.^UL UT-c6 SP2330 2 0 0 -1/3 /2 5 0 rum BT F i l e >2e"63 321.6-322.6 amu.SUL UT-2637 SP2330 2G0-1/3/250 RUM ET 20O0- File C*"T-*-!--i--i | 1 1 1 r i ' -- i-- i-- |-- :--i-- ' | i I r i | i 1 i 1 i t i--:--T-- i-- :-- :-- :-- i i i |--r-i--t--r--| 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 15.0 ES6? 313.6-220.6 air.'j.SUL UT-2637 2P2330 200-1 '3 '250 RWU ET 8090- 4000-' S----- ' ,-v 19.0 18 ll'.O 11 12.0 12.5 13.0 13.5 14.0 14.5 15.0 OC 0 7 2 C11346 a file header from : >B2869 : 2UL UT-263? Operators GARY MS 9/07/84 10:22 : SP2330 200-1/3/250 RUN BTL#39 BTL*39 : 1 MS models 87 SU/HU r e v . i CA ALS # : 0 od files SP2330 Tuning file: RPEI01 No. of ext r a records: 2 e temp.: 250 Analyzer temp.: 0 Transfer line temp. : 0 C h r o m a t o g r p h ic t e m p e r a t u r e s : 50. C h r ornaio g ra p hi c times, min. : 0 . 0 C h r o m a t o g r a p h i c rate, deg/min: 20. 0 300. 2. 0 6.0 0. 0.0 0.0 0. 0.0 0. 0 0. 0. 0 0. 6 333.. 9 peak is b a s e l i n e dr o p c o r r e c t e d area, j peak is ta ng en t s k i m m e d c o r r e c t e d area. R.T. f irst min. sc an max sc an 1ast peak scan width raw area"' corr. area corr. y. 12.010 12.01O 233 233 239 239 247 247 14 937 67 14 9 3 7 6 7 56919 53699 100.00 94.34 331.9 t p t ak is b as e 1 ine idrop c o r r e c t e d are a. d p e ak if t i ng s nt s k i m m e d c o r r e c t e d area. R.T. f ir s t min. s c an max sc an las t peak scan width raw area corr. area corr. * 12.010 231 239 253 12.018 231 239 253 22 104329 22 104329 40353 38571 100.00 95.58 Ci| ffr.ix io iN C o m n f s"I umamkii. .i .n im o is nmrn<un<>M i n t i m o n iw > *<34 C A L C U L A T I O N t>b a 1 ( 0 > " * 7090 / t = 327.9 st peak is b a s e l i n e drop corrected area. nd peak is t a ng en t s k i m m e d c o r r e c t e d area. R.T. min. first scan max scan last peak scan width raw area 12.051 237 241 245 12.051 237 241 245 8 133144 8 133144 = 321.9 st peak is b a s e l i n e drop c o r r e c t e d area, nd peak is t a ng en t s k i m m e d c o r r e c t e d area. R.T. first m 1n . scan max s c ari 1ast pe ak sc an w i d t h r aw area 0.000 6.000 246 246 0 245 0 245 -1 -1 00073 0 0 v ---^ - * Tj ( "' *^ - .. corr. ar e a 450G8 37980 corr. y. 106.00 84.38 corr. area 2725 2725 corr. 100.00 100.00 C11347 File >B2S70 33 3 .6 - 3 3 4 . 6 *mu.2UI_ 2.669/. 4 8 / .19 SP2330 2 0 0 - 1 / 3 / 2 5 9 RUN BT I i i t i F i l e > 2S 70 321. 6- 322.6 &iu . 2UL 2 . 669/ . 48/ . 19 SP2330 290- 1/ 3/250 RUN ET A o ; , 1 I f i '< . n '~ i " < 1 1 1 0 . 0 1 0 . 5 1 1 . 11 . 5 1 2 . 0 12 2 8 7 0 3 1 9 . 6 - 3 2 0 . 6 fTiU . 2 '-1L. 2 . 6 6 9 / .45 85(000 9^ "r" 4 0000- 0 I ' 1 1 ' i ' ' i 1 i ' '"~m~ I ' ' ' ' i '' i ' 1' i 1 1 ! 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 1 * .9 I11*'I 14.5 15.9 File > B 2 7 2 5 6 . 7 - 2 5 7 . 7 a m u . - U L 2 . 6 6 ? / . 4 8 ^ .19 2 P 2 3 29 2 9 0 - 1 / 3 ''250 RUN BT 30009- . 40000- 0~! 1 1 1 I ' i I 10.0 10.5 11.0 11.5 12 12 . -- i -- -- - i-- 8-- r-- 13.0 13.5 14.0 14.5 15.0 C11349 r. fi MS dat a Tile he ad er from : >B28?0 Sample: 2UL 2.669/.48/.19 Operator: GARY MS 9 / 0 7 / 8 4 16:42-_ ; Misc : SP2330 200-1/3/250 RUN BTL441 BTL441 Sys. 4: 1 MS model: 87 S W / H U reu. : Cfl RLS 4 : 0 Method file: SP2330 T u n i n g file: APE I0 1 No. of e x t r a records: 2 Source temp.: 250 Analyzer temp.: Transfer line temp. : 0 Chromatog ra ph ic tempe r a t u r e s : 50. Chromat o g r a p h ic times, min. : 8. Ch ro mat o gr ap hi c rat e , d e g / m i n : 20. 300. 2.0 0.0 0. 0.0 0.0 0. 0. 0 0.0 0. 0.0 0.0 n/2 = 333.9 First pe ak is b a s e l i n e drop corrected area. Sec ond pc ak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. first min. scan max scan 1ast peak sc an w i d t h raw area corr. area c orr. * 1 12.011 2 12.811 234 234 239 239 249 249 15 130146 15 130146 95136 93606 100.08 98.39 M'Z = 331.9 First p e ak is b a s e l i n e drop corrected area. Se co nd p c ak is t a n g e n t s k i m m e d c o r r e c t e d ar e a Pe ak R. T. f ir s t inin . sc an m ax scan 1ast peak sc an u idt h raw area corr. are a corr. */. 1 12.011 2 12.311 234 234 239 239 249 249 15 107070 15 107070 68550 66667 100.00 97.25 "*"*m**,, intrr*i) inw Ton* 352/334 CALCULATION R - G l o b a W : 0> = .7205 /, __ " "-^ -- ----, r ^ .. * x M--2 = 327. 9 First pe ak is b a s e l i n e drop corrected area. Sec ond pe ak is t a n g e n t s k i m m e d c o r r e c t e d area. Pe ak 4 P. T. fi rst min. sc an max scan 1ast peak scan u id th raw area corr, are a c orr. 1 12.631 2 12.031 237 237 24 6 246 243 243 6 147271 6 147271 6G433 56336 100.06 96,42 M/Z = 321.9 First pe ak is b a s e l i n e drop corrected area. S e c o n d pe ak is tangent s k i m m e d c o r r e c t e d ar ea. P e ak 4 R. T. first Tir1n . sc an max sc an 1&S t peak sc an u id t h r aw ar e a co r r . area corr, 1 12.031 2 12.031 236 236 240 240 248 24 8 12 531792 496560 100.00 12 5 3 1 7 9 2 4 8 01 6 S 96.71 C11350 r\f S M.'Z * 319.9 First p< ak is b a s e ! i n c d r o p c o r r e c t e d area. S ec on d pe ak is t a n g e n t s k i m m e d c o r r e c t e d area. Re ak ft R. T. fi rst min. sc an max scan 1ast peak sc an w i d t h raw area 1 12.031 2 12.031 235 235 240 240 248 248 13 3662 30 13 366230 >327o corr. area 337682 323696 corr. * 106.00 95.68 3 2 0 3 2 CALCULATION R - G l o b a l C 1> = .6801 M'Z = 257.0 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. f ir s t m in . s ca n max sc an 1as t peak scan width raw area 1 12631 2 12.031 236 236 240 246 24 6 246 10 3 5 58 37 10 3 5 5 8 3 7 corr. are a 300237 282357 corr. V 106.60 94.04 <320 + 322)/<332 +334) CALCULATION R-GlobaK 3> = 5.0962 <328')/C332 + 334) CALCULATION R - Gl ob al v 3> = .3423 c , ..... , . . : i i i SUBJECT TO PROTECTIVE ORDER. n r r C11351 File >E2S71 333.6-334.6 amu.-t-'L 2:6 .69/. 4/. 19 SP2330 208-1/3." 250 RUN ET 10000- 010 .0 e >E2S71 ' 1 1 ''' ;-r-1<-- Tj 1 0 . 5 ' 111. 11 .5 12.0 12.5 3 2 7 .6 - 3 2 .6 amu .2UL 26.69.'' .48/ 4 0 0 0 0- 20000- 'X. 4 - 1--1 T . ,-T ! , ,T. 1 I >-I I 1 1 I 1 [ I l . j I I T I -- !>' T I-T- .1-- 1 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 15.0 File- > E 2 7 1 32 1 . 6 - 3 2 2 . 6 aiTiu .2UL 2 6 . 6 9 / . 4 / . 1 9 SP2330 200-1/3/250 RWN ET 000 000^ 400000^ o-r-- i ``` i 10 .0 10.5 / X1 "T-- l-- !-- -- 1-- 1--1 `T l'"! > r . r~t r- 1 i r i--i--;--!----!-- i ) . i i" i - j 11.0 11.5 12.0 12.5 1 F: lr E2 :71 3 1 9 . 6 - 2 2 0 .6 a.mu .2 L 2 6 . 6 9 / .4 .19 400000- 010 .0 10!.5 ll`.0 1 1 2 5 6 . 7 - 2 5 7 . 7 fTi'J ttr>u*-J 1j4 00^10.*-- H 41 10.0 --- i < i i -i i ^ f'\ ' T 1 1 10.5 11.0 11.5 12.0 12.5 CLBJhCi TO PROTECTIVE ORDER. ,i i 1 .^ r ' ! -- "i 13.0 13.5 14.0 14.5 15.0 0CG78 C11352 Mb data file header from : >B28?1 S a m p l e : 2UL 26.69/. 4 8-'. 19 Operator: GRRY MS 9/07/84 M i s e : SP2330 200-1/3/250 RWN B TL*43 BTL43 Sv/s. #: 1 MS m o d e l : 8 7 SU/HU r e v . : C R R L S # : 0 Method File: SP2330 Tuning file Sourc e temp.: 250 finalyzer temp. R P E I00 1 1Ho. o f e x t r a r e c o r d s : Tr ans f e r ine temp. ! Chrcmat o g r a p h ic temperatures : 0 . 0C h r o m a t o g r a p h i c t im e s , m i n . : 2 0 . 0C h r o m a t o g r a p h i c r at e , de g / m in : 50. 3020. .0 0.0 0 0. 0. 0 0. 0. 0 0. 0. 0.0 0.0 0.0 H :02 - _ M'Z * 333.9 First pea k is b a s e l i n e drop corrected area. S e c o n d p e a k is t a n g e n t s k i m m e d c o r r e c t e d a rea. Peak R. T. min. first sc an m a >. s c an 1as t sc an pe ak ui a t h raw area 1 11.990 Cm 1 1 . 9 9 0 2 33 Cm J 238 238 243 24 3 11 00 119531 119581 M Z = 331.9 com. area 95141 65481 c or r . 100.00 68.80 .m F i r s t pe ak i s b i s e l i ne drop corrected area. S e c o n d p e a k i S t a n g e n t s k i m m e d c o r r e c t e d ar e a. F e ak R .T . f ir s t min. s c an m ax sc an 1 as t s c an peak width r au ar e a 1 2 11 22 .. 00 11 00 234 234 239 239 243 Cm 4 9 93295 9 93295 c or r . area 65854 47658 C or r . 100.00 72.67 322 334 CRLCULRTION R -G 1o b a 1i 0 ) = .6922 M I = 327.9 F i r s t peak is b a s e l i n e dr op c o r r e c t e d are a . S e c o n d p e a k is t a n g e n t s k i m m e d c o r r e c t e d ar e a. /* ' * --W S U B J E C T TO ----._ C.u Peak # 21 R.T. min. 11 22 .. 00 11 00 first scan 232 232 id/ scan 239 239 last scan 248 248 peak width 16 16 raw area 483585 483585 corr . area 220032 119551 cerr . / 100.00 54.33 M 'z = 3 2 1 . 9 * F i r s t p e ak iis b a s e l i n e drop cor area. S e c o n d p e a k iis t a n g e nt s k i m m e d c o r r e c t e d ar e a . F e ak * R.T. roi n . f 1r s t scan mar s can last sc an pe ak u id th r au area -* G5 <s> 2 12.010 235 235 239 239 244 244 9 4944280 9 4944260 C or r . area 4816579 3347396 c or r . /; 100.00 69.50 0C079 C11353 S M/Z 319.9 First Second peak peak is is baselin tan gent e ski Rd irmoepd corrected corrected area. area. Peak tt R. T. f irst min. scan max sc an 1ast peak scan u idth r au area 1 12.630 2 12.030 235 235 240 240 245 245 10 3 4 9 5 8 9 8 10 3 4 9 5 8 9 8 BT67I corr. area 3421448 2367786 c or r . y. 100.00 69.20 320/322 CALCULATION R - C l o b a l C 1) = .7103 H Z = 257.0 First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. P c ak R. T. first firin . sc an max scan 1as t peak sc an w i d t h raw area 1 12.030 2 12.030 235 235 246 246 245 24 5 10 2 8 9 9 0 3 5 10 2 8 9 9 0 8 5 corr. area 2808645 1870499 corr. 100.00 66.60 <320 322>/<332 334 > CALCULATION R - G 1o b a l < 3> 51.1695 < 3 2 8 ' V < 3 3 2 + 334 > CALCULATION R - G l o b al< 3 > = 1.0974 H i i i i m i i . i i i i t ' i i l u m i n i . I m ii ir w i l a t u i/m M iI h u J iii i;ji 00030 1w n u iE C T IV E C11354 ;- 1_ ^ fi1.1 O r e C11355 File >B2S74 333.6-334.6- amu .L .1068-'. 48 .1? SF233B 200-1^3^260 BT Fil e > B 2 3 7 4 3 2 7 . 6 - 3 2 8 . 6 afiiu .2UL .1068-''.48-'.!? SP233S 2 0 0 - 1 /3''250 BT J\ u1l0..0 10.6 11l'..0 11.3 12.0 "i--1--i--1--i--i--'--1--1--1--r 12.5 13.0 13.5 14.0 14.5 15.6 Fi l e > B 2 8 '~4 221 .6- 332! i 2UL .1063 .4 3.- .19 SP2 330 20 O- 1 325 BT 4 000- 2000* -- f0 .0 1O .6 * 1 l'.O F i l'e ? B 2 :7 4 31? .6- 22 0.6 200 - w , r v / v w v V f A . V ^ ' ...-Vv>.-- - i--i--j--r 1 1 7.... ~ i -r--- .- --. -T-T-! 5 14.0 14,5 15.0 O 2 0 0 - 1 '3 2 5 BT A f\ e-r 4 000-1 10\.5 1 !*. O 1 l'. 5 56 . 7 - 2 5 7 . 7 a m u .2 U L 1 2'.0 1 2*.E ' 1 i 13.0 13.5 . 1 0 6 S - ' .48-' . 1 ? SP2330 *---y 1 1 14.0 14.5 200-1-'' 3 2 5 0 --- 1 15.0 BT f\, \4^ i " "j 6 i 11i1-- 13.0 1G.5 11.0 11.5 * . -- % "y ~ .-- `7. j -i -. V *i !0 :VH OJvD^^- C11356 MS dit* fil* header from i >B2874 Sample: 2UL . 1068/. 48/. 19 Operator : GARY Misc : SP2330 200-1/3/250 . BTL403 BTL4 Sys. 4: 1 MS model: 87 SU/HW rev.: CR Method file: SP2330 Tuning file: .RPEI01 Source temp.: 250 An al y z e r temp.:' 0 MS 9 / 0 7 / 8 4 -1-2: 05 3 RLS 4 : 0 No. of e x t r a r ecords: 2 Transfer line temp. : 0 . Chromt ographi c t e m p e r a i ures c 56. Chromt ographi c t imes, min. : 0.0 Chromt o g r a p h ic r a t e , deg/mi n: 2 0 . 0 300. 2.0 0. 0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0. 0 -. M/Z * 333.9 First pe ak is b as e 1 in e d r o p c o r r e c t e d area. Sec ond pe ak is t a n gent s k i m m e d c o r r e c t e d area. Peak * R. T. first min. sc an m ax sc an 1ast peak sc an w i d t h raw area corr. are a corr. * 1 1 1.984 239 241 246 . 11.984 239 241 246 7 64648 40526 100.00 7 64648 39133 96.56 M/Z = 331.9 First p e ak is b as e 1 in dro p c orr ec ted ar e a . S e c o n d p e ak is t angent s k i m m e d c o r r e c t e d area. Peak 4 R. T. f irst min. scan 1 12.064 2 12.004 237 237 riiax sc an 242 242 1ast peak sc an w i d t h 256 250 13 13 raw area 59914 59914 c orr. are a 31392 29949 corr. * 100.00 95.40 \ : ; 2 \ * mCZ 332/334 CALCULATION r Tv ? -- - R - G 1o h a l < 0 > = M/Z = 327.9 .7746 s u b je c t l.L \ r ' " "r. ORDER, First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak 4 R. T. fi rst min. scan max scan 1ast peak scan width raw area 1 12.004 2 12.364 237 237 24 2 242 251 251 14 88629 14 880 2 9 M/Z * 3 2 1 . 9 First peak ii s base line drop correc ted area. S e c o n d pe ak iis t a ngent s k i m m e d c o r r e c t e d ar e a . Pe ak 4 R. T. f ir s t m in . sc an fiiax sc an 1as t pe ak sc an w i d t h raw area 1 12.024 241 243 246 2 12.024 241 243 246 5 23343 5 23343 corr. are a 35389 34003 corr. 100. 06 96.08 corr. are a 9083 7593 corr. e/*t 100.00 83.65 /* ; " r 7 nr C11357 s 319.9 F lrst pe ak is ba s e 1 ine d r o p c o r r e c t e d area. Sec ond pe ak is tangent s k i m m e d c o r r e c t e d area. F e ak * R. T. f irst min. scan max scan 1ast pe ak scan u idt h raw area 1 12.024 2 12.024 24 1 241 243 243 247 247 6 22029 6 22029 corr, area 6909 5748 corr. 7. 100.00 63.20 320'322 CALCULATION R - G l o b a U 1) = .7607 M-'Z = 257.0 First, peak is b a s e l i n e drop corrected area. S ec on d peak is ta n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. first n11 n . s c ari m ax sc an 1ast peak scan width raw area 1 12.024 238 243 248 10 39676 2 12.024 238 243 248 10 39676 corr. area 9536 8586 corr. * 100.00 90.04 <320 + 3 2 2)/< 332 +334) CALCULATION R - G l o b a l < 3> = .2224 t328' )^ (332 + 334) C A L C U L A T I O N R - G l o b a U 3> = .4909 ni ronniNii d itti is 1 OC0S4 C11358 file- > B 2 S 7 5 3 3 3 . 8 -- 334,6 .niu 2UL 1 .08.*' .48' .19 SP2330 260-1^3^25 ET Tile >33375 4 0 i*w*- 3 2 1 . - 3 2 2 . & aft.u,^'L 1 .0 .4 S /'.19 SF2330 260-1^3^250 ET 200 OO" "ile e-, io', e 10.5' 11.0 J '"i ~~=~~ 11 .5 12.0 1 1-T-- -- i-- !-- I-- r~-- i-- -- i-- r 12.5 13.0 1 i9 t -- 3 2 O .t* Lffiij.2 U L 1 .008-' .43-' .19 SP2 i -77 i ; . i-i~i ri i1 i i 5 14.0 14.5 15.0 0 2 0 0 -- 1 3 ''2 5 0 ET r: n r r t tr C11359 at a file he ader from >B28?5 le: 2UL 1 . 8 6 8 / . 4 8 / . 1 9 Operator: GARY : SP2330 290-1/3/250 BTL95 BTL# : l MS models 87 S U / H W rev.: CA thod file! SP2330 Tuning files.APEI01 rce temp.! 252 Analyzer temp.: 0 MS 9/07/84 12:24*.. 5 ALS # : 8 Ho. of e xt r a records: 2 Transfer line temp. : 0 Chromatographi c temperatures : 50 C h r o m a i ographi c t im e s , min. : 0. 0 C h r o m a t og r ap h i c r at e , d e g / m i n : 20. 0 300. 2.0 0.0 0. 0.0 0. 0 0. 0. 0 0. 0 0. 0.0 0. 0 *. _ 333.9 st p e al* is b a s e l i n e d r o p c o r r e c t e d area. nd peat is t an g e n t s k i m m e d c o r r e c t e d area. R.T. fi rst min. sc an max sc an last peak scan uidth r au area corr. area corr. 11.990 1 11.990 237 237 238 238 242 242 5 82220 56745 100.00 5 82220 15262 26. 90 -_ = 331*9 'St peak is b a se l in e dr op corrected area. :>nd peak is tangent s k i m m e d c o r r e c t e d area. R.T. f irst min. sc an m ax scan last- peak sc an u idt h r au area c orr. area corr. V 1 11.990 2 11.990 235 235 238 238 244 244 9 66175 9 66175 42136 41195 100.00 97.77 * * 5 oz c c 1 c z c 4 3e i '334 C A L C U L A T I O N 1o b ai < 0 5 .7426 = 327.9 rs-t peak is b a s e l i n e d r o p c o r r e c t e d area. end peak is t a n g en t s k i m m e d c o r r e c t e d area. -- _____ __ * ' -* _ .**% r -ivu/EC Is ' ; ! A L ` OROEH 4k R.T. first max * last peak * min. scan sc an scan uidth rau area corr. ar 'a corr. * 1 12.010 2 12.010 ! * 321.9 234 234 239 239 246 246 12 9 8 3 8 2 12 9 8 3 8 2 56154 54390 100.00 96.86 * m. irst peak is b a s e l i n e drop corrected' area. :o n d p e ak is t a n g e n t s k i m m e d c o r r e c t e d area. ak R.T. f irst max last peak 4 min. scan sc an s c an u i d t h rau area co r r . area corr. y. c C r- N a 1 12.018 2 12.010 237 237 239 239 24 3 24 3 6 180719 127919 100.00 6 180719 95278 74.48 C z n r 11360 MS data file header from : >B2676 Sample: 2UL UT-2638 Operator: GARY MS 9 / 0 7 / 8 4 -12::46 = . flisc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN B T L 4 4 5 B T L 4 4 5 Sys. i: 1 MS model : 87 S U/ H W reu. : Cfi RLS It : 0 Method file: SP2330 Tuning file: APEI0I Source temp.: 250 Analyzer temp.: 0 No. of e x t r a r e co rd s: T r a n s f e r 1 ine temp, C h r o m a t o g r a p h i c t e m p e r a t u r e s : 59. C h r o m a t o g r a p h i c times, min. : 0. 0 20.0 300. 2.0 0.0 -0. 0.0 0. 0 0. 0 .0 0 .0 0. 0.0 0. 0 M/Z 333. 9 First peak is b a s e l i n e dr o p c o r r e c t e d area. Se c o n d peak is tan gen t sk i mme d c or re c te d area. Pe ak R.T. fi rst min. scan max scan 1ast peak sc an u idt h raw area corr. area corr. y. 1 11.970 2 11.970 236 23d 237 237 242 242 6. 8 6 1 3 2 6 86132 59336 38648 100.00 65. 13 M/Z = 331.9 Fir st p e ak is b a s e l i n e >drop c o r r e c t e d area. Se c ond peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak It R. T. f irst min. scan max sc an 1ast peak sc an w i d t h raw area corr. area corr. 1 11.970 233 237 246 13 70827 43098 100.00 2 11.970 233 237 246 13 70827 41590 96.50 332/334 CALCULATION R - G l o b a l ( 0) - .7263 M/Z = 327.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. Sec on d peak is tangent sk im me d cor re ct e d area. Peak 4 R.T. min. fi rst scan max sc an 1ast peak scan width raw area 1 11.990 235 238 248 13 93453 2 11.990 235 238 248 13 93453 M/2 321.9 F ir st peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. fi rst min. sc an max scan 1ast peak sc an w id th raw ar ea 1 0.000 2 0. 000 249 249 0 248 0 248 -1 -1 0 0 '\ corr. area 51944 49747 c orr. ym 100.00 95. 77 corr. area 2224 2224 corr. V 106.00 100.00 G11363 S t r c 7 2 * 2 e C "V h r- S Z = 319.9 First peak is b a s e l i n e dr o p c o r r e c t e d *rea. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak * R. T. f irst min. scan max sc an 1ast peak s c a n w idt h r au area 1 0.000 2 0.000 249 249 0 24S 0 248 -1 ' -1 0 0 >62T7^ corr. area 2144 2144 corr. * 100.00 100.00 320-'32Z CfLCULfT ION R - G l o b a l < 1) = .9540 M,'Z = 257 .0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o nd peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. first min. s c an max scan 1ast peak sc an u idt h raw area 1 0.000 2 0. 080 24 9 249 0 248 0 248 -1 * -1 0 0 c orr. arc a 2759 2759 c orr. * 100.06 108.60 (320 + 322 )/ (332 +334) CfLCULfTION R-G1 obal ( 3) = .6426 ( 3 2 6 ) ^ ( 3 3 2 + 334) CfLCULfTION R -G l ob a lC 3) = .5069 j t H iuim irt .ir ii.it ii-i i n m m *num no j im h.m Vs*.' #7 3. TO 0 CC9 0 C11364 V 1 1 I fill 111 Ml VII..............I ' II III I f i I I llll IV| ; I <0 <& id V ur 0 10 CM UV'II LO fl NV f il fi f > VV H I1 <3 fi evi evi LO o . ( f i f i CO c>j f i V- I <>l fi i/ia . (u C u Vi Vi co LO >1 a ' a ^ 7> ro co f> \ O 'L i evi i. OIsi fIi -3 fi 1- D evi fi IO Zi <'t 33 fi ni * 'O n- fi co ci fi fi VIi CIO ' LO ' 0 I -f-i co fl (0 V i co I. fi M rj K I- iX i fi nr T o 'P' V i e> /V CD IO I- fl `V i. lit U1j * ! 1 Uv 'j c, 1 10 01 * 0 i 01 U l'JI l*i -- * l`* 01 i IL .O t*> OO O > Ui '01 ' - >7. 0 ' .iS 01 01 h*^ 3 LO Ol H -O* *.ai OJ i"i 1 U> *t* 's o- r- i. O ^ ,`u1 IM OJ O t U 01 T ) >!i Ol Ol ( M*` il il 1/ . i< . U if: m CO 00 z> O a. 0 01 n il I- L0 01 rI- * oj II -- 00 Ol s 0J nr -no-f MS dat a file header from : >B2S77 Sample: 2UL UT-2639 Operator: GRRY MS 9^07/,64-i 3 : . 0 6 ; t . Ml sc : S P 2 3 3 0 2 0 0 - l ' 3 ^ 2 5 0 R W N . B T L 4 4 7 B T L 4 4 7 Sy-s. ff: 1 MS model : 87 S W / H W rev. : Cfl RLS 4 0 Method file: SP2330 Tuning file: RPEI01 Source temp.: 250 Final yz er te m p 0 No. of e x t r a r ecords: 2 Transf er 1 ine temp. : 0 - Chromatographi c temperatures : 50 C h r o m a t o g r a p h i c t imes, min. : e. 0 Ch ro ma t o g r a p h ic rat e, de gxm in : 20. 0 300. 2.0 0.0 0 0. 6 0. 0 0 0. 0 0. 0 9. 0.0 0. 0 M/'Z 333 .9 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d area. P e ak 4 R T first min. scan max sc an 1ast peak scan width raw area corr. area corr. k 1 11.990 2 11.990 238 238 238 238 242 242 6 71474 45152 100.00 6 71474 33140 73.40 M/'Z = 3 3 1. 9 First p e ak is b a s e l i n e drop corrected area. Sec ond pe ak is t angent s k i m m e d c o r r e c t e d area. Pe ak 4 ft. T. first m in . s ca n max sc an 1ast peak sc an w i d t h raw area corr. ar ea corr. 1 11.990 234 238 244 10 52794 33584 100.08 2 11.990 234 238 244 10 5 2 7 9 4 30404 90.53 - * C X E T ? 3 X u aa rr 332/334 CflLCULRTION R - G l o b a K 0- = .7438 M'Z = 317.9 First peak is bas el i ne drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. ___ T 5 < _ ` Tj f D - lSx 7ATA 7?t -. i t AJ '* * * : -- i'c. 0 , ^ e ak 4 ft. T. f irst min. sc an max sc an 1ast peak sc an w i d t h raw area corr. area corr. 5i 1 12.010 2 12-. 0 1 235 235 239 239 249 249 14 83087 14 8 3 0 8 7 M/Z 321.9 First pe ak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is tangent s k i m m e d c o r r e c t e d ar ea. P e ak ft. T. f irst min. s can max s c an 1ast peak scan u id th raw area 1 0.000 2 0.000 250 258 0 249 0 249 -1 -1 0 0 39887 39492 100.00 99. 56 C11366 c orr. area 2178 2178 c orr. J; 100.00 100.00 z 0C092 S fl-'Z * 319.9 >WST7 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is tangent s k i m m e d c o r r e c t e d area. Peak R.T. first min. sc an max sc an 1ast peak s c a n ui dt h raw area corr. area c or r . * 1 0.000 2 0.000 250 250 0 249 0 249 -1 -1 0 2047 100.60 0 2047 100.66 320-322 CALCULATION R - G l o b a l t 1> * .9399 M/Z = 257.0 First peak is ba s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. P al: R.T. f irst min. sc an max scan 1ast peak sc an w i d t h raw area 1 0. 060 2 6. 606 250 250 6 249 0 249 -1 -1 6 0 corr. area 2717 2717 c orr. y< 100.66 106.66 C32G + 3 2 2 ) ^ 0 3 2 +334> CALCULATION R - G l o b a K 3) = .0537 (3 2 S ' t332 + 334> C A L C U L A T I O N ft-G1obal< 3; = .5035 i:urjiri(>i %cmmi'ihiahmn r',1 n i c im u iiv ii c i t a t i s i N( |i|> SUBJECT '0 -riu i-- ii v r_ ,-{jnR. 0G093 C11367 SP2330 200-1/3/25 RWH 0 Lf) C\l \ CO \ -* I 0 0 CVI _ C0o (O CM lL CO u n n i M i m / 1 u n i .......................................: ' n u i l ....................u m 0 Cm li- 0 u Ol \ CO t\H 00I VI 0 CO CO CM L 01 I0 (U CiL 0 li> Oi oi \ --< I 00 Oi 0 01 CO CM u M a m u .2UL UT-2 6 4 0 0 O" CO I tn Z> CO ir co CU I < CO co co C r- co OI M0 Gj 4r CM L. 0 0 Ol CO CO I ' r t IO CO r- co o ca 00 co O- 0 TT M> CM I \- 3 w D iE `fl 01 Ol CO I *0 f. OJ CO 0 rCO oi cu 0 Ul Oi Ll. 0 M'> 01 I I3 CM D `fl Ml C'l Ol CO I ' C'l CO O'j r0 Ol Ch 4/ u 1 r.ji i i / i i a I M I I I K I I I II |i ,| U* t* 1/1 iL ll* Al -- *) V, ",r V I AJ Li) Vl `AS') `A"*'41 -*3 w t-H *III JAI - Al I Al H li) Al D Tf | n Cj aj Al . Li) I A A) - I0) Al A| U. U) Al A) I *1 L Al D B D l- ur-> Al I r- iMi) *:) r^- AI AJ oc 09 -1 C11368 MS dita file header from : >B2878 Sample: 2L UT-2640 Operator: GARY MS 9/07/84 Mise : SP2330 200-1/3/250 RUN BTL49 BTL449 Sys. #: 1 MS model: 87 SW/HW reu. : CA ALS # : 0 Method file: SP2330 Tuning file: RPEI01 S o u r c e t e m p . ; 250 A n a l y z e r tem p fts* 0 No. of e x t r a records: Transfer 1 ine temp. : 13.-26 C h r o m a t o g r a p h ic t e m p e r a i u r e s : 50. C h r o m a t o g r a p h ! c t imes, mi n. : 0 . 0 Chromat ographic rate, deg/min : 20.0 300. 2.0 0.0 0. 0.0 0.0 0. 0 .0 0 .0 0. 0.0 0. 0 M/2 333.9 First pe ak is b a s e l i n e drop corrected area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d area. F e ak R.T. first min. sc an max sc an 1ast peak sc an w i d t h raw area corr. area corr. X 1 11.964 2 11.964 M/Z = 331.9 238 238 240 246 244 244 \ 6 82683 53067 100.06 6 82683 48456 91.31 F irst pe ak is b a s e l i n e d r o p c o r r e c t e d area. Sec ond peak is t a n g e n t s k i m m e d c o r r e c t e d area. P ak R.T. min. fi rst scan max scan 1 as t pe ak scan width raw ar e a corr. area corr. 1 11.964 235 246 250 15 6 9 9 6 6 40191 100.86 2 11.964 235 240 250 15 69906 37866 94.22 332/334 CALCULATION R-Gl oba lC 8? = .7574 M/2 = 327. 9 F irst peak is base 1ine drop c o r r e ct ed area. Second peak is tangent skimmed corrected area. Peak R.T. f irst min. scan max scan 1ast peak sc an w i d t h raw area 1 11.984 237 241 250 2 11.984 237 241 250 13 81 98 2 13 8 1 9 8 2 M/Z * 321.9 F irst pe a k 1 s base 1 ine d r o p c o r r e c t e d area. Second peak is t angent skimmed corrected area. Peak # R. T. fi rst min. sc an max s c ar. 1as t pe ak sc an w i d t h raw area 1 0. 000 2 0. 0 00 251 251 0 250 0 250 -1 -1 0 0 0CG95 * ' ,,. * *' * corr. area 48299 45575 c orr. * 100.00 94.36 cor r . area 2192 2192 c orr. 100.00 100.00 C11369 = 319.9 st peak is b a s e l i n e d r o p c o r r e c t e d irea, nd peak is t a ng en t s k i m m e d c o r r e c t e d area. R.T. f irst min. scan max scan 1ast peak sc an width r au area 12. 10t. 12. 18o- 251 251 251 251 251 251 0 221 0 2216 corr . area 2216 2216 corr. * 100.00 100.00 '322 CflLCULRTION iobal( n = 1.0107 e 257.0 -st peak is b a s e l i n e d r o p c o r r e c t e d area, ond peak is t a ng en t s k i m m e d c o r r e c t e d area. t. R.T. f irst max 1 as t peak m in . s c an s c a n sc an w i d t h raw area 1 0.000 2 0.000 252 252 0 251 0 251 -1 -1 0 0 corr. area 2692 2692 c orr. 100.G0 100.00 .0 + 3 2 2 C332 +334) CftLCULfTION Globali 3) = .0473 :" )s <332 + 334) C A L C U L A T I O N 1o b a l < 3> = .5177 ; t i j 2 < i i 1 k i 1 >\ ; a-- 1: .--V 0C096 C11370 MS dita file header from : >B2879 Sample: ZUL UT-2641 Operator: GARY MS 9 ' 0 7 / 8 4 13:46. .. Mise : SP2330 208-1/3/250 RUN BTL451 BTL451 Sys. *: 1 MS model : 87 S U/ H U r e v . : Cfi RLS : 0 Method file: SP2330 T u n i n g file:: fiPEIOl No. of e x t r a r ec o r d s : 2 Sourc e temp.: 250 finalyzer t e m p . :! ' 0 T r a n s f e r 1 ine temp.- : 0 C h r o m a : o g r a p h i c t e m p e r a t u r e s : 50. Chromat o gr a ph ic times, min. : 0.0 Chr omat. o g r a p h ic rate, deg/min: 2 0 . 0 300. 2.0 0.0 0. 0. 0 0.0 0. 6.0 0.0 0. 0.0 0.6 M/Z = 333.9 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R. T. f ir s t. min. scan max scan 1ast peak sc an w i d t h raw area corn. area corr. * 1 11.969 2 11.969 236 236 237 237 242 242 6 79315 6 79315 51649 28558 166.00 55.29 M/Z = 331.9 F irst peak is base 1 ine dro p c o r r e c t e d area. S e c o n d p e ak is t ange nt s k i m m e d c o r r e c t e d area. P e ak R. T. first min. sc an max s c ari 1as t peak sc an w i d t h raw are a corr. ar ea corr. % 1 11.990 234 238 246 12 63357 37149 160.00 2 11.990 234 238 246 12 63357 36297 97.71 332/ 33 4 CfiLCULfiTION R - G lo b a U 0) = M-Z = 327. 9 .719 3 - .. v_ F irst peak is b a s e l i n e drop correc t ed area. Sec ond peak is t angent skimmed corrected area. . P e ak R. T. first min. scan max sc an 1ast peak sc an w i d t h raw area corr, area 1 11.990 2 11.996 233 233 238 238 248 248 15 8 25 03 15 8 25 03 45483 43998 MrZ * 321.9 First pe ak is b as e 1 ine idrop c o r r e c t e d area. S e c o n d peak is t angent s k i m m e d c o r r e c t e d ar ea. - Peak R. T. f irst min. scan max sc an 1ast peak sc an w i d t h raw area corr. are a 1 0. 060 2 0.000 249 249 0 248 0 248 -1 -1 0 2164 0 2164 ' '1`sZ. c orr. /; 100.00 96.74 corr. V. 100.00 100.00 06098 C11372 s M^2 * 319.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent sk im me d co rr ec t ed area. Peak R. T. f irst min. scan max sc an 1ast peak s c a n u idt h rau area 1 0.000 2 0. 000 249 249 0 248 0 246 -1 -1 0 0 corr. area 2180 2180 c or r . S 100.00 100.00 320^322 CALCULATION R - G l o b a l < 1) = 1.0074 M.^2 = 2 S 7. 0 First peak is b a s e l i n e drop c o rr e ct ed area. S e c on d peak is t a n g en t s k i m m e d c o r r e c t e d area. Pe ak R. T. f irst min. s c an max sc an 1ast peak sc an u idt h ray area 1 0. 00O 2 0. 000 249 249 0 248 0 248 -1 -1 0 0 corr. area 2651 2651 corr. -e 106.86 106.00 <320 + 322)/<332 +334) CALCULATION R - G 1o b a l < 3) = .0489 C328')/<332 + 334) CALCULATION R - C l o b a H 3) = .5120 a2 ao u 00099 Z C11373 r i 1 OIO1 J 1 K \ 'v G'_ > i.n rsino/ n>i .. ,, . -1 -- * *bG1-* t IGV' i 1 11 O h) en _ 1 -r en !.. <.n -i I* lM*> ^ O f O 'S' il. en O rCCo?1 -j g * g * P=i1 wa en c h. ,- en f: irf *V11. r I- HJU ' t r. . cl._ ` n-i t. \ .J L eo ' i; * t *J 1I (, ; I , ;i .S y4 /\ , %i. T /C / (/> TJ ro eo *-* G* le en i G* rn O C) ;y ni '^ , CO * r ro en M it en *-* en_ c *-* H I'-* f.I.. G-' ' leeUn r-. eO H (/i lTeJ eo *-* t..,i G' * le' en G' I M 1en0 Um en K* II"1" O f f t* i*- ri r / .111,'Jt ' . / < ! ( Il -Il I ! if r i t, ,iiii.M ."c!'iii.V *l i n s 'nillT 9*fr-9*S 0 3 3 3 < ^ t J V J* 0 w i\l CO OO O G' "* O O O G w G G* i . f M M C1^. O* en CO ffoO Ci d' c ro d i~ c -c ro tfCUofoT* *n V a G) 00 V G> W Gl Mnd 053^vl-002 0E3dS (fw1nOOo0 GrO1o> G* ' ' C.e-nO~ *-f-* re0GV\o.n.) G? -U* 1 3TJ en -*1- >-- VL -H C? W0 IMU'I Mi .. U N II lt M I i / H M HAI U N IUI! I M O N | * f i s l l * W G> MS data file header from : >B2880 Simple: 2UL UT-2642 Operator: GRRY MS 9 / 0 7 / 8 4 14 ::0o-. Hisc : SF2330 200-1/3/250 RUN BTL#53 BTL#53 S y s . : 1 MS model: 87 SU/HU r e u . : CR RLS : 0 Method file: SP2330 Tuning file: RPEI01 Source temp.: 250 Analyzer temp.: 0 No. of e x t r a records: 2 Transfer line temp. : Q Chromat ogr aph ic t e m p e r a t u r e s I 50. Chromat gr aph ic t im e s , min. : 0.0 Chromatogr aphi c rat e , deg/min : 20.0 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0. 0 0.0 M/Z * 333. 9 F irst p ak is base 1 ine d r o p c o r r e c t e d area. Sec ond peak is tangent sk im me d c o r r e c t e d area. P t ak * R .T . first min. scan max s c an 1ast peak sc an u idt h rau area 1 11.970 2 11.970 235 235 237 237 241 241 6 71890 6 71890 corr, are a 44110 37189 c orr. * 100 .00 84 .31 M/Z = 331.9 First pe ak is b a s e l i n e drop corrected area. S e c on d pe ak i t ange nt- s k i m m e d c o r r e c t e d area. Peak R .T . first m ir_i. sc an m ax s c an 1ast p e ak sc an u id t h rau area corr. area corr. * 1 11.970 233 237 246 13 57077 30583 100 .00 C. 11.9 70 233 237 246 13 57077 29023 94 .90 332/334 CALCULATION R - G 1o b a l < 6) = .6933 ,-- - -, M.-Z = 3 27.9 L First, peak is b a s e l i n e d r o p c o r r e c t e d area. Sec on d peak is tangent s k i m m e d c o r r e c t e d area. Peak # R.T. min. fi rst scan max scan 1ast peak sc an ui dt h rau area 1 11.990 2 11.990 234 234 233 238 249 249 15 8 O 1 2 0 15 8 01 20 M/Z = 321.9 Fi rst peak is b a s e l i n e >dr o p c o r r e c t e d area. S ec on d pe ak is t angent s k i m m e d c o r r e c t e d area. Pe ak # R.T. "first m in . sc an max s can 1ast peak scan width rau ar ea 1 e. 0 0 0 2 0.000 250 250 0 249 0 249 -1 -1 0 0 OLICI 1 * -V-,__ corr . are a 42785 42425 corr. 5i 100.00 99.16 corr. ar e a 2146 2146 c orr. V 100.00 100.00 C11375 M/Z = 319.9 ^3^680 First peak is b a s e l i n e d r o p c o r r e c t e d area. Se co nd peak is tangent ski mmed c o r r e c t e d area. Feak R. T. first min. scan max: sc an 1ast peak scan width rau area corr. area 1 0. 000 2 0.000 250 250 0 249 0 249 -1 -1 0 2025 0 2025 corr. * 100.00 100.06 32 0/ 32 2 C A L C U L A T 1OH R - G l o b a l < 1) = .9434 M'Z = 257.0 F ir st peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. P e ak *# R. T. f irs t hiin . scan max s c an 1ast peak s c an width rau are a 1 0. 006 2 0.000 256 250 6 249 0 249 -1 -1 0 0 corr. are a 2635 2635 c orr. *; 106.66 106.00 <320 + 3 2 2 0 / 0 3 2 +334) CALCULATION R - G l o b a l < 3) = .6556 <32S'>/<332 + 334) CALCULATION R - G 1o b a l < 3> = .5726 VN U l l v u i l d i O I U I U U I N I K I J ( H J * U t l . M J M |> Id Ulti ; t j f 0 C102 c z 2 C11376 File- >E2SS1 333.6-334.6 it. u . 2UL 10.68/.4S-'-.19 SP 23 30 2 0 0 - 1 ''3-'250 RMN BT ut i1j m in h i n mu ni tiin i`.i m i* : i<ni u m i *vi< File >32331 321.6 2UL I0.es>'.46^.19 SP2 33 0 2 0 0 - 1 ^ 3 ^ 2 5 0 RUN BT II-* li 00103 2 C11377 G O MS default file: >B2881::01 MS data file header from : >B2B61 Sample: 2UL 10.68/.48/.19 Operator: GARY MS 9/07/84 14:29*.r Mlsc : SP2330 200-1/3/250 RUN BTL#17 BTL417 S^s. #: 1 MS model: 87 S W / H U reu. : Cfi RLS # : 0 Method file: SP2330 Tun ing file: RPEI01 No. of ext r a records: 2 Source temp. : 250 Rnalyzer temp. 0 T r a n s f e r 1 ine temp. : 0 - C h r o m t ographi c t e m p e r a t u r e s : 50. Ch ro mat ogr aph :c t imes , min. : 0.0 C h r o m t o g r a p h ic rate, d e g /min: 20. 0 300. 2.0 0. 0 0. 0.0 0.0 e. 0.0 0.0 0. e.e 0.0 M/2 - 333.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. f irst. min. scan max sc an 1as t peak sc an wi dt h raw area corr. area corr. * 1 11.990 2 11.990 236 23d 238 238 240 240 4 92026 54406 100.00 4 92620 44332 81.49 M/Z = 331.9 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. min. first sc an max s c an 1ast peak scan w id t h raw area corr. are a corr, '4 1 11.990 235 228 246 11 68116 42489 100.00 2 11.990 235 238 246 11 68116 36254 85.49 t C ftr i co iiuim i; c>n>s| v.tiAnin t,nnmai sr.i'oniioM 332/33 4 CRLCULRTI ON R - G l o b a l < 0) = .7796 -- W..- --- -_ -- "T y -\ M/Z = 327.9 F irst pe ak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d pc ak is tangent sk im m e d c orrec t ed area. .- -- .. Peak * R.T. first min. sc an 1 12.010 2 12.010 233 233 max scan 239 239 1ast peak sc an width 247 247 14 14 raw area 120057 120057 corn. area 85295 82537 corr. mA 100.00 96.77 M/2 321.9 First peak, is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is tangent s k i m m e d c o r r e c t e d area. Peak R. T. fi rst min. scan 1 12.010 2 12.010 236 236 max sc an 239 239 1ast peak scan width 243 243 7 7 raw area 2264061 2264061 n c l4 c \a corr. area 1781339 1746367 corr. 100. 00 98.04 C11378 < c 2 s H'Z *=319.9 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skimmed corrected area. Peak ft R. T. first mi n. sc an max scan 1ast peak sc an w i d t h raw area 1 12.01O 2 12.010 235 235 239 239 252 252 17 1500291 17 1560291 corr. area 1425933 1412435 corr. 7. 100.00 99.05 '*" 320S322 CALCULAT ION R - G l ob a lC 1) = .8005 V\'Z = 2 5 7 , 0 First peak is ba s e l i n e drop co rre c te d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Pe ak ft R. T. f i rst min. scan max scan 1ast peak scan width raw area 1 12.610 2 12.010 234 234 239 239 256 256 16 1 2 0 18 4 6 16 12 0 1 8 4 6 corr. area 1166166 1137966 c orr. y. 100.00 98. 69 <320 + 322)/< 332 +334) CALCULAT ION R - G l o b a l < 3) = 33.1299 C328 ')/'< 332 + 334) C A L C U L A T ION R - G l o b a l < 3> = .7155 7 t P if ni cn n i]ii.n ch. h i'TI (<n*pti>c tuiNMun s coiirdn.oiiN N il * /O O iiiiO fet' SU B JEC T TO PE n-1379 PO GD> s w 03 ro ow ro C3 V W ill'o IO CO IO o* I 0) fo IO dn' C IO I lo <7> -U co I*OD 0. P0i3 G3 I \ CO IO 0c3n XeI; 2 C11380 Mt . i iM >.' /(*< i w..li i f1i'*'* *; in* in V i,- tfii'i TT1 un Ai .il -* tn o G' QO V rwo tmo & 09 _ X4-jl4 i l-iO1 io ut Ut -1 w i to uo:t> <r, i=i c tn 10 tn -h ro (rTo> o j* to . ro <n r to_ (7/J> ro to M to ro tt.no' ?- 1 \ tron 7 jU. ;o i s: tn, w n Hf M * V oW to w rto-j w to to I w CO u 0s 3 c IcO I ro o* a to (0 r"o0 w to ro i - s to \ tron it G i u < i* n m i n n tiJ.ni h i rt Ji-un P**S| it im I GC/MS default file: >B2S82:!01 MS data file header from : >B2862 Sample: 2UL UT-2643 Operatori GRRY MS 9/07/84 disc : SP2330 200-1/3/258 RWN BTL*55 BTL455 Sys. : 1 MS model: 87 SU/HW reu.* CR RLS # : 0 Method file: SP2330 T u ni ng file: R P E 101 Wo. of e x t r a r e c o r d s : Source temp.: 250 finalyrer t e m p . : 0 Tr an s f e r line temp. 1 4 : 5 1 ___ Chromat ogr ap h ic te mp er a tu r e s : 50. Chromat ogr aph ic t imes 1 min. : 0.0 Chromat ogr aph ic rate, deg/min: 20.0 300. 2.0 0. 0 0. 0.0 0. 0 0. 0.0 0. 0 0. 0.0 0. 0 M/Z = 333.9 First. peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d pe ak is tangent s k i m m e d c o r r e c t e d area. Peak 1 R. T. first min. scan max scan 1ast peak scan u idth raw area corr. area c orr. *4 1 11.909 235 237 240 2 11.969 235 237 240 (1/2 = 3 3 1 .9 5 73651 5 73051 42316 32978 100.00 77.93 F irst pe ak is b a s e l i n e drop corrected area. S e c on d peak is t a ngent s k i m m e d c o r r e c t e d area. F't ak * R. T. first m in , scan max scan last peak scan u idt h rau area corr. a r e a corr. 4 1 11.969 233 237 248 15 64164 33924 100.00 c! 11.969 233 237 248 15 64164 32559 95, 98 332'334 CALCULATION P - G 1o b a l < 0' = .8017 M-Z = 327.5 ... ~ ^ c r ro P^OTiTc-nw-. ' ' ' F irs t peak is base 1 ine d r o p c o r r e c t e d area. S e c on d peak is tangent sk immed c o r r e c t e d area. Peak R. T. f irst tuin . scan max s c an 1ast peak sc an u idt h raw area corr. area c orr. 1 11.996 233 238 248 15 8 55 08 49448 100.00 2 11.950 233 238 248 15 8 5 5 0 8 47153 95.36 M/Z - 321.9 First peak is b as e 1 ine drop c o r r e c t e d area. S e c on d pe ak is t angent s k i m m e d c o r r e c t e d area. Pe ak # P. T. f irst min. sc an m ax scan 1ast pe ak sc an u idt h rau area corr. are a corr, X 1 0. 066 2 0.630 249 24 9 0 246 0 248 -1 -1 0 2233 100.06 0 2233 100.00 _^ . G11-381- s M.-Z * 319.9 First peak is b a s e li ne drop c o r r e c t e d area. Seco nd peak is tangent s k i m m e d c o r r e c t e d area. Feak ft R.T. first min. scan max sc an 1ast peak scan u idt h rau area 1 0. 000 2 0.000 249 249 0 248 0 248 -1 -1 0 0 3- corr. area 2162 2162 corr. * 100.00 100.00 320^*322 C A L C U L A T I O N R - G l ob a lC 1) = ,9682 M .'Z * 2 5 7 . 0 First peak is ba s e l i n e drop c o r r e c t e d area. Se co nd peak is tangent s k i m m e d c o r r e c t e d area. Pe.ak ft R.T. f irst min. sc an max scan 1ast peak s c a n ui dt h rau area 1 0. 000 2 0.000 249 249 0 248 0 248 -1 -1 0 0 corr, area 2557 2557 corr. 'A 100.00 100.00 <320 + 322 )**<332 +334) C A L C U L A T I O N R - G l o b a U 3) = .0576 C326*' )/ <332 + 334) C A L C U L A T I O N R - G 1obalC 3> = .6483 2 F |S i | V E SUBJECT TO PROTECTIVE 00108 Z C11382 file > B 2 S S3 3 3 3 . 6 - 3 3 4 .6 aitili 2 U L U T t 2 4 4 SP2336 200 - 1 / 3 / 2 5 0 RUM BT File- > B 2 3 3 3 2 1 . 6 - 3 2 2 . 6 l[Ti U 2UL U T -264'4 SP233G 2 B 0 - 1/3^250 RUN BT J 0 fi0 4 0 0 O` " P " 1--1-- I-- :-- :-- I-- i-- -- !-- :-- I-- t-- |-- i-- n --i-- i-- i-- i-- i-- |-- r10.0 10.5 11.0 11.5 12.0 12.5 3 1 3 . 6 - 3 2 0 .6 iniu .2UL U T - 2 6 4 4 I i | i i i i-- i"i 1 i :11" i 1 J 1 |i i 'i i | 13.0 13.5 14.0 14.5 15.0 S F' 2 3 30 200-1 / 3 -2 5 O R t.iH B T 11 i- \i 1= 0C109 z C11383 GC/MS default file: >B2883i:01 MS data file header from i >B2883 Sampl e t 2UL UT-2644 Operator: CRRV MS 9/07/84 Mise i SP2330 209-1/3/250 RUN BTL457 BTL#57 Sys. 41 1 MS model: 87 SW/HU rev.: CA ALS # : 8 Method file: SP2330 T u n i n g file: fiPEiei Source temp.: 250 finalyzer temp. 0 No. of e x t r a r ecords: T r a n s f e r line t e m p . 15: 11... Ch ro mt ographi c t e m p e r a t u r e s i 50. Chromtographic times, min. i 0.0 Chromtographic rate, deg/min: 20.0 300 . 2. 0 0. 0 0 0. 0 0. 0 0. 0.0 0. 0 0. 0.0 0.0 M/Z 333.9 F irst peak is b a s e l ine drop c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R. T. fi rst min* scan max sc an 1ast peak scan width raw area corr. area c orr. */. 1 11.963 2 11.963 239 239 243 240 245 245 6 64015 38083 100.00 6 64015 27307 71.70 M/Z = 331.9 F irst pe ak is b a s e l i n e d r o p c o r rect ed area. Sec ond peak is tangent skim med c or re c te d area. Peak R.T. first min. sc an max scan 1ast peak s c an u idt h rau area corr. area corr. k 1 11.984 11.984 235 235 241 241 251 251 16 59207 16 59207 26615 25775 100.00 96.84 332/334 CALCULATION R - G 1ob al ( 0) = .6989 M/2 = 327.9 F irst peak is b a s e l ine <drop c o r r e c t e d area. Sec ond peak is tangent s k i m m e d c o r r e c t e d area. '7* ^ *w _ T O P ^ O T r i-- ., P e ak R.T. min. f irst scan max scan last peak scan width rau area corr. area c orr. k 1 12.004 2 12.084 238 238 242 242 251 251 13 7 21 87 13 72187 39973 38348 100.08 95.93 M/Z * 321.9 F irst peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is tangent s k i m m e d c o r r e c t e d area. Peak # R.T. first min. sc an max sc an 1ast peak sc an w i d t h rau area corr. area corr. % 1 12.004 2 12.004 240 240 242 242 247 247 7 49469 26432 100.00 7 49469 19372 73.29 0G11O G11384 s ns2 * 319.9 First peak is b a s e l i n e drop co r r e c t e d ire*. Se c o n d peak is tang en t sk immed c o r r e c t e d ire*. Peak R. T. f irst min. sc an max scan last peak s c a n ui d t h raw area 1 12.004 ` 240 2 12.004 240 242 242 249 249 9 39735 9 39755 corr. area 16911 13560 corr. *4 100.00 71.70 320/322 CRLCULfTIOH R - G l o b a l < 1) * .7133 P1/Z 2 5 7 . 0 First peak is ba s e l i n e drop c or r e c t e d area. S e c o n d peak is t a n g e n t ski m m e d c o r r e c t ed area. Peak * R.T. first min. scan max scan last peak scan width raw area 1 12.804 2 12.604 240 240 242 242 249 249 9 41947 9 41947 corr. area 17323 14335 corr. *4 100.00 82.75 <320 + 322)/(332 +334) CRLCULRTION R - G l o b a l < 3) = .7608 <328'>/< 332 + 334) CALCULATION R - G l o b a l < 3) = .6142 OC ill c r* C11385 File > B2884 3 3 3 . 6 - 3 3 4 . 6 i mu .2UL UT^-2645 S P23 30 2 0 0 - 1 / 3 ^ 2 5 0 RUN BT i s i n.<i,r,i'4'H 'n im in ii. i>`l n< r, i, iT i i :D .uu-inr F i l e > B 2 88 4 321 .6-322.6 afT(U.2UL U T - 2 6 4 S SP2330 200-1/3/2S0 RUN BT r -T-^ --- ------------ n r -i A. *- fj i i Ml ' ? Vi >fit l'ir ) GC/MS default file* >B2884:iQl MS data file header, from i >B2884 S a mpln 2UL UT-2645 Operator* GARY MS 9/07 /8 4 15:.31... Misc i SP2330 200-1/3^250 RUH BTL459 BTL459 $ys. 1 1 MS modelt 87 SU/HW r eu.i CA ALS i 0 . Method filet SP2330 Tuning filet APEI01 Ho. of e x t r a record*! 2 Source temp.: 250 Analyzer temp.t 0 T r a n s f e r lin e temp. : 0 *** C h r o m a t ographi c temp era tu res ! 50. C h r o m a t ographi c t imes, mi n. : 0.0 Chromatograph!c rate, deg/mint 20.0 300. 2.0 0.0 0. 0.6 0.0 0. 0.0 0.0 0. 0. 0 0.0 M/Z 333. 9 F irst peak is bas e line dr o p c o r r e c t e d area. Second peak is tangent skimmed corrected area. Peak R.T. f irst mi n. s c a n max scan 1ast peak scan width raw area corr. area corr. Si 1 11.969 2 11.969 2 36 236 237 237 240 240 4 63191 4 63191 33383 28653 100.00 85. 83 M/Z * 331.9 First peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. fi rst min. scan max scan 1ast peak scan width raw area corr. area corr. * 1 11.990 235 238 246 11 52378 27661 100.00 2 11.990 235 238 246 11 52378 26385 95.39 cohimoi s cnumiuiiON purr*LO wrw 90 TM (c^R id o n u 'N o charts | 332/334 CALCULATION R - G l o b a l < 8> = .8286 cr ' v M/Z = 327. 9 Fi rst peak is b a s e l i n e d r o p c o r r e c t e d area. Second peak is tangent sk immed corrected area. "S U 3 j r r - r i pro tective o r d er ' Peak R.T. first min. scan max scan 1ast peak sc an w i d t h raw area corr. area c orr. X 1 11.990 235 238 248 13 73204 44019 100.00 2 11.990 235 238 248 13 73204 42550 98.86 M/Z - 321.9 F irst peak is b a s e l i n e drop corrected area. Sec on d peak is tangent sk i mm ed c o r r e c t e d area. Peak * -- 1 2 R.T. min. -- ---- 12.010 12.010 first scan -- --- 237 237 max sc an --- 239 239 1ast sc an -- --- 243 243 peak width -- --- 6 6 raw area ------- 23045 23645 0C113 corr. area ----- .-- 8567 6206 11387 corr, * 100.00 72. 95 NO IIP M>70 OfSrtO s 1 W 319.9 First peak is b a s e l i n e drop c o r r e c t e d arts. Seco nd peak is tangent skim me d c o r r e c t e d area. >15900^ Peak R.T. f irst min. scan max sc an 1ast peak sc an ui d t h rau area corr. area corr. Ji 1 1.990 2 11.990 235 235 238 238 245 245 10 28464 10 284 64 6954 6474 100.00 93. 10 320/322 C ALCU L A T IOH R - C l o b a H l> = .6174 M / Z * 2 5 7 . 9 Fir st peak is b a s e l i n e d r o p c o r r e c t e d area. Se con d peak is tangent s k i m m e d c o r r e c t e d area. Peak R.T. f irst mi n. s c a n max scan 1ast peak scan ui dt h rau area 1 12.010 2 12.010 235 235 239 239 245 245 10 3 16 87 10 3 1 6 8 7 corr. area 7487 6737 corr. '4 100.00 89.98 (326 + 322)/(332 +334> CALCULATION R - G l o b a l ( 3> = .2533 (328')/<332 + 334) CALCULATION R - G l o b a K 3) =- .7198 ---- SUBJECT TO PRO CTIVE ORDER# 00114 C11388 T il t > B 2 6 B 5 3 3 3 . 6 - 3 3 4 . 6 iniu 2UL . 2 6 6 9 / . 4 8 / . 1 9 SP2330 2G0-1/3/250 RUN BT toniti!v<jixj.ti1) File- > B 2 8 8 S 3 2 1 . 6 - 3 2 2 . 6 a m u .2UL . 2 6 6 9 / . 4 8 / . 1 9 SP2330 200-1/3/259 RUN BT 0011 s C11389 GC/MS default file* >B2885s*01 MS data file header from i >B2885 Samp 1e i 2UL .2669/. 48/. 19 Operator* GARY MS 9 / 0 7 / 8 4 15:54-- Mi sc : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN B T L # 2 9 B T L H 2 9 S y s . #i 1 MS model* 87 SU/HW reu.i CA ALS # : 0 Method file* SP2330 Tuning file*RPEI01 Source temp,: 250 Analyzer temp.* B No. of e x t r a records* 2 T r a n s f e r line temp, r 0 Ch ro mat ographic t e m p e r a t u r e s * 50. Chromatographic times, min. * 0.0 C h r o m a t o g r a p h i c rate, deg/mi nt 2 0 . 0 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0.0 0.0 M/Z 333.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S ec on d peak is tangent s k i m m e d c o r r e c t e d area. Peak #* R.T. min. first scan 1 11.969 2 11.969 236 236 max sc an 237 237 1ast peak scan u idt h 242 242 6 raw area 66036 66036 corr. area 41466 25473 corr. 5s 100.00 61.43 M/Z = 331.9 F irst peak is ba s e l i n e drop corrected area. S e c o n d P ak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. fi rst min. scan max sc an 1ast peak sc an widt h raw area 1 11.969 227 237 255 28 85164 2 11.969 227 237 255 28 85164 c orr. area 29164 27330 c orr. '4 100.00 93.71 Iiij' I M i* m i w t o i.c i n i a o i s c o n r o n ttitM m c o n i N ciiaiits) 332/334 CALCULATION R - G l o b a U 0> = .7033 M/Z = 327.9 F irst peak is bas el i ne dr op c o r r e c t e d area. Secon d peak is tangent s k i m m e d c o r r e c t e d area. X * - 'vVf* *-m SUB.?EC7 ~ *>-e r t * ' , Peak R.T. first min. scan max scan 1ast peak scan width raw area corr. area corr. Ji 1 11.996 231 238 251 28 85511 42731 160.00 2 11.990 231 238 251 20 85511 41161 96.33 M/Z 321.9 F irst peak is baseline dr op c o r r e c t e d area. Second peak is t angent skimmed c o r r e c t e d area. Peak * R. T. fi rst min. sc an 1 12.010 2 12.010 237 237 max scan 239 239 1ast peak sc an wi dt h raw area 243 243 6 47193 6 47193 0011 corr. area 25605 18531 c orr. '4 100.00 72. 37 n (AT 'iOER, 1 QQft Nt i HP * t?7 0 OFMO ri/Z - 319.9 First peak is ba seline drop* corr rc te d area. Second peak is tangent s k i m m e d c o r r e c t e d area. Peak R.T. fi rst min. scan max sc an 1ast peak scan width raw area 1 11.990 2 11.990 235 235 238 23 8 247 247 12 46973 12 46973 corr. area 22229 21065 corr. 'A 100.00 94.76 3 2 0 / 3 2 2 CfLCULfTIOH R - G l o b a K l> - .8682 tl/Z *= 2 5 7. 6 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. f irst min. sc an max sc an 1ast peak scan width raw area 1 12.010 235 239 246 11 45806 2 12.010 235 239 246 11 45806 corr. area 18933 17981 corr. * 100.00 94.97 <320 + 322>/<332 +334) CALCULATION R - G 1o b a l < 3> - .6772 < 3 2 8 0 / ( 3 3 2 + 334) CALCULATION R - G l o b a l < 3> = .6017 "Vsf- SUBJE'~` TO PROTECTIVE ORDErT* 00117 m 1a m OC 118 C11392 - >B2S90 333.6-334.6 *mu.2UL .1068/.48/.19 SP2330 260-1/3/250 BT le >E2&'96 321.6-322.6 aniu.2UI_ .1068/.48/. 19 8000' SP2330 200-1/3/250 BT 4008- 0*T--i-- i-- n -- |-- i-- i-- !-- i'f-r r -i -i-- |-i r i~i"l-- i-- i-- i-- r-- ]-- r-r-i-- t--j-- i-- i-- r-i- ]-- i-r t i -- t -r i-- i-- fi- !-- i-- :-- | 10.0 10.S 11.8 11.5 12.0 12.5 13.0 13.5 14.6 14.5 15.0 le > 2 0 9 6 3 1 9 . 6 - 3 2 6 . 6 amu.ZUL .1 0 6 8 / .4 8 / .19 SP2330 206-1/3/258 BT 0C119 C11393 ?[""( i'otiiuf c h m iio ") tnuPHir iiMixoi s t:(inrun *ni'H m irrato nr r|>** S M^Z 319.9 > $ 13*0 First peak is ba se!in* drop c o rr ec te d irea. Seco nd peak is tangent sk im m e d c o r r e c t e d *rei. Peak ft R.T. fi rst min. sc an max sc an 1ast peak scan u id th rau area 1 11.777 216 225 238 20 71761 2 11.777 218 225 238 20 71761 corn. area 30181 29711 corr. * iee.ee 98.44 3 2 0 / 3 2 2 CfLCULfTION R - G l o b a l < 1) * .6209 M/Z 257.0 First peak is bas el i ne drop c o r r e c t e d area. S e co n d peak is tangent s k i m m e d c o r r e c t e d area. Peak ft R.T. f irst min. sc an max sc an 1ast peak scan width rau area 1 11.777 2 11.777 219 219 225 225 237 237 18 18 64139 64139 corr. area 19013 17526 c orr. 100.00 92. 19 <320 + 322 )/< 332 +334) CfLCULfTION R - G l o b a l < 3) = .2547 <326 ')/(332 + 334) CfLCULRTION R -- Globali 3) = .3567 * j N( l III' '> ,'/ ( ) ( Hi.l t > -- - ^ U TO PROTECTIVE ORDER. 0G121 C11395 O li3 96 00122 IO A CD GD CD OO 0 M il I li *I ? ii l V ,, I n V W TO W il CO IO <? I I0IOO. (T\ U3'1 c IO 0 lT\ A co TJ r co co 0 ro 0 0 I -* \ CO r\o <n w |i il n 11- b h a ih T I M iai-mi w rv V w W A V bJ to -D O) _ OOJJ ;n I IO O.tv' o1 ro A m u .2UL 1 . 0 6 8 / . 4 8 / . 19 SP2330 206-1/3/250 ro_ in oj_ o.\ Ol M -- -O tnl M tn. w w -t w I (>MIIII It S !. lU l'tJtlilll (litt I .I J Ml mH I'"' MS dit t fil* header from >B2891 Sample: 2UL 1.068/.48/.19 Operator: GARY MS 9/10/64 22:04--- Mi * c : S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 BTLi05 BTL 5 Sys. : 1 US model: 8? SUI/HU rew.i CR flLS : 0 Method file: SP2330 Tuning file: APEI01 0S o u r c e t e m p . : 2 5 0 Analyzer temp. : 0Ho. of e x t r a r e c o r d s : 2 Transf er line temp,, : Chromt ogr aph ic t e m p e r a t u r e s : 0 . 0C h r o m a t o g r a p h i c t i m e s , m i n . : 2 0 . 0C h r o m t o g r a p h i c r a t * , d * g / m i n: 50. 3020. .0 0.0 0 0. 0. 0 0. 0. 0 0. 0. 0.0 0.0 0.0 M/Z - 333.9 Fir s t p e a k is b a s e l i n e drop corrected area. S e c o n d p eak is t a n g e n t s k i m m e d c o r r e c t e d area. Pe ak R. T. min. f lr s t sc an m ax sc an 1ast sc an pe ak width raw area 1 11.764 C, 1 1 . 7 6 4 223 223 229 229 254 254 31 2 2 5 0 9 9 31 2 2 5 0 9 9 corr. arc a 166447 162045 corr. *4 100.00 97. 36 M ;Z * 3 3 1 . 9 First peak ls baseline d r o p c o r r e c t e d ar e a. Se c o n d p e a k lis t a n g e n t s k i m m e d c o r r e c t e d ar e a. Pe ak P. T. f i r s t m in . scan m ax s c an 1ast scan pe ak width r aw are a 1 11.764 2 11.764 223 223 229 229 243 243 20 20 172067 172067 c or r . area 130947 128637 c or r . 100.00 98.24 NIIIHIMHI)t MWINO.I |s m . 113 awilUO 3 IH l*Jt 332/334 CALCULAT ION R - G 1o b a l < 0) = .7867 n.-z - 3 2 7 . 9 S^Jtcr ro F irst p e ak is b a s e l i n e d r o p c o r r e c t e d ar e a. Second peak is t angent skimmed corrected area. , Peak / 1 2 P. T. min. 11.785 11.765 f ir s t sc an 223 223 M/Z * 321.9 max scan 230 230 1ast sc an pe ak width 246 246 23 23 r aw area 158160 158160 corr. are a 1 1 1378 108813 F ir st pe ak is b a s e l i n e drop corrected area. S e c o n d p e ak is t a n g e n t s k i m m e d c o r r e c t e d a r e a. Peak 1 2 R. T. min. 11.785 11.785 f ir st s c an 225 225 max sc an 230 230 1ast sc an 246 246 pe ak width 2211 r aw ar e a 401604 401804 c or r . ar e a 359909 351278 corr. V, 100.00 97.76 c or r . 100.00 97.60 C11397 ( H"M Iu/ L li tIH I IN s Y\sZ * 31 9 . 9 >W8U First peak is b a s e 1ine drop co rrected re. Second peak is tangent sk im me d co rrected *re*. Peak It R.T. first min. scan max scan 1ast peak s c a n u idt h ru area corr. area 1 11.785 2 11.785 219 219 230 230 256 256 37 380462 309718 37 360462 300357 corr. 100.00 96.98 * -- 320^322 CALCULATION R - G lo b al < 1) .8605 M/'Z * 2 5 7 . 0 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak *# R.T. min. first scan max scan 1ast peak scan u idt h rau area 1 11.785 2 11.785 224 224 230 230 251 251 27 252992 27 252992 * corr. area 185114 182408 corr. Si 100.00 98. 53 *- <320 + 322 > C332 +334) C A L C U L A T I O N R- Glo ba lC 3) = 2.2516 <328/>/<332 + 334) CRLCULfTION R - C l o b a l < 3) = .3636 I i SUBJECT T 0 'r*nr~~: * i `J r- 0G123 C11398 le > B 2 89 7 3 3 3 . 6 - 3 3 4 . 6 * m u . 2 U L 1 0 . 6 8/ .4 8' .1 9 SP23 36 2 0 0 - 1 / 3 / 2 5 0 RUN BT ile > B 2 8 9 7 3 2 1 . 6 - 3 2 2 . 6 air.u.SUL 10.68/. 48/. 19 SP2330 200-1/3/250 RUN BT I OC 124 C11399 S M/Z - 315.9 First peak is b a s e l i n e drop corrected area. Second peak is tangent skimmed, corrected area. Peak R.T. f irst min. scan max scan 1ast peak s c a n ui dth r au area 1 11.810 2 11.810 213 213 229 229 253 253 40 2778746 46 2778746 corr. area 2694226 2668846 c orr. * 100.00 99.06 320^322 CALCULATION R - G 1 o b a l ( 1) .8272 nsz 257.0 Fi rst peak is b a s e l i n e d r o p c o r r e c t e d area. Se co nd peak is tan gent s k i m m e d c o r r e ct ed area. Peak . R.T. fi rst min. sc an max sc an 1ast peak sc a n u idt h rau area 1 11.830 2 11.836 216 216 236 238 249 249 . 33 33 1801888 1801888 corr. area 1722160 1693268 corr. * 100.00 98.32 (320 + 322)/<332 +334) CRLCULflTION R - G l o b a l ( 3) * 23.167 (328 ' )s (332 + 334 ) C A L C U L A T I O N f i - G l o b a K 3) = .3356 ei o8CU a [ j * -3 s u b j e c t ro i E C T J'/F^ ORD7?. C c c 0G126 C11401 File >B2S99 333.6-334.6 imu.SUL UT-2629D SP233& 200-1/3/250 RUN BI File File F i l e >B899 321.6-322.6 amu.^UL UT-2629B SP2336 200-1/3/250 RUN ET F ile F ile nr.1 err C11402 G O M S de fa ul t fi lei >B2899 : i 0 1 MS data file header from i >B2899 Sample: 2UL UT-2629D Operator! GARY MS 9/11/84 01.44.., Mi ac ! S P 2 3 3 0 2 0 0 - 1 / 3 / 2 3 0 R U N B T L 2 1 B T L # 2 1 Sys. #i 1 MS mo d e 1 i 97 SU/'HU rev.i C A ALS it i 0 Method file: SP2330 Tun ing file: APEI01 No. of e x t r a records: 2 Source temp.: 250 Analyzer temp.: 0 Transfer line temp, i 0 - C hr o m t o g r a p h ic t e m p e r a t u r e s I 50. Chromt ographi c t imes, min. ! 0.0 Chromatographi c rate, d e g / m i m 20.0 300. 2.0 0.0 0. 0.0 0.0 0. 0.0 0.0 0. 0. 0 0.0 . M/Z 333.9 F irst peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak - R.T. first min. scan max sc an 1ast peak scan width raw area corr. area corr. '4 1 11.789 223 228 238 13 39408 12251 100.00 2 11.789 225 228 238 13 39408 11952 97.56 M/Z - 331.9 Fi rst peak is b a s e l i n e dro p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. first min. sc an max scan 1ast peak scan width raw area corr. area corr. *4 1 11.809 2 11.809 224 224 229 229 234 234 10 3 11 55 10 3 1 1 5 5 10345 9205 100.00 88.98 332/334 CALCULATION R - C l o b a l < 0) = .8444 M/Z - 327.9 F ir st peak is b a s e l i n e d r o p c o r r e c t e d area. Se co nd peak is tangent sk i m m e d c o r r e c t e d area. . Peak '# R.T. f irst min. scan max sc an 1ast peak s c an wi dth raw area 1 11.809 226 229 237 11 42324 2 11.809 226 229 237 11 42324 M/Z 321.9 F irst peak is base 1 ine <drop c o r r e c t e d area. Sec ond peak is tangent sk i mm ed c or r e c t e d area. Peak ft R.T. first min. scan max sc an 1ast peak scan width raw area 1 11.809 225 229 239 14 35923 2 11.809 225 229 239 14 35923 0(j<iS cori'. area 10842 10039 c orr. i 100.00 92. 59 corr. area 7629 7104 corr. *4 100.00 93. 12 ._ C.114 03 s M/2 * 319.9 First peak is ba se li ne drop c o r r e c t e d area, Second peak is tangent sk im me d c o r r e c t e d area. Peak R. T. first min. scan max scan 1ast peak sc an u id t h rau area 1 11.830 2 11.830 225 225 230 230 234 234 9 24198 9 24198 corr. area 5514 4443 corr. *4 iee.ee 80.56 320/322 CALCULATION R - G 1 o b a l < 1) = .7228 M/Z 257.0 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is ta n g e n t s k i m m e d c o r r e c t e d area. Peak R.T, first m in . scan max sc an 1ast peak sc an ui'dt h rau area 1 11.869 2 11.809 227 227 229 229 233 233 20973 6 20973 corr. area 4749 4680 corr. % 100.00 85. 91 (320 + 3225/(332 +334) CALCULATION R - G l o b a l C 3) = .5817 (328')/(332 + 334) CALCULATION R - G l o b a l ( 3) - .4768 001*9 C11404 Fil* >B2903 333.6-334 .6 *mu.2UL .2669/. 48' .19 SP2330 200-1/3/2S0 RUH BT F i l e >B2903 321 . 6 - 3 2 2 . 6 aiiu.SUL . 2 6 6 9 / . 4 8 / . 19 SP2330 2 0 0 - 1 / 3 / 2 5 0 RUH BT 0G130 C11405 MS dAtt file header from i >B2903 Simpl ei 2UL .2669 / . 48/. 19 O p e r a t o r * GfiRY MS 9 / 1 1 / 6 4 - 2:-85 Misc : S F2 33 0 2 0 0 - 1 / 3 / 2 5 0 RUN- BTl 29 BTL29 Sys. *: 1 MS model* 87 SW/HU rev.* CR RLS # * 0 Method file: SP2330 Tun ing file: RPEI01 No. of e x t r a record: 2 Sourc e t e m p . : 2 5 0 final yz er t e m p .: 0 T r a n s f e r l i n e ttirip. : 0 - . C h r o m a t o g r a p h ic t e m p e r a t u r e s : 50. C h r o m a t ographi c t imesi min. : 0.0 C h r o m a t o g r a p h ic rate, deg/min: 2 0. 0 300. 2.0 0.0 0. 0.0 0.0 0. 0. 0 0.0 0. 0. 0 0.0 M/Z 333.9 F i rs t peak is b a s e l i n e dr o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak ft * R. T. f irst min. scan 1 11.763 2 11.763 219 219 M/Z = 331.9 max sc an 225 225 1ast peak sc an u idt h 241 22 241 22 rau area 154286 154286 com. area 109670 105347 com. *4 100.00 96.06 * ' F irst peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak ft R. T. f irst min. sc an max sc an 1ast peak scan u idt h rau area com. area corr. * 1 11.763 2 11.763 221 221 225 225 241 241 28 132155 20 132155 92415 88415 100.60' 95.67 * 5 5 Zc cL 5 Gz \ J u a C* j-- 332/334 CfiLCULRTI ON R - G l o b a l ( 0) = .8427 M/Z = 327.9 First peak is ba s e l i n e drop c o r r e c t e d area. S e c o n d pe ak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak i R.T. first min. scan max scan 1ast peak s c a n ui dt h rau area 1 11.783 221 226 242 2 11.763 221 226 242 21 1 1 8 8 3 9 21 1 1 8839 M/Z * 321.9 t F irst peak Second peak is b a s e 1 ine <drop c o r r e c t e d i iangent skimmed corrected area. area. Peak ft R.T. min. first sc an max sc an 1ast peak sc an u idt h rau area 1 11.783 221 226 241 2 11.783 221 226 241 28 101979 20 101979 nr * *"A s u b je c t t o 'p r t-'-Tj/n C H D E P , c orr. area 72240 68670 c orr. . 5i 100.00 95. 06 c orr. area 61939 60189 corr. V, cfs 100.00 97.17 z C11406 s M-'Z * 319.9 First peak is ba s e l i n e drop c o r r e c t e d *ri. Second pc 4k is tangent ski mined c o r r e c t e d area. Peak R.T. fi rst min. scan max scan 1ast peak s c an ui dt h raw area 1 11.803 2 11.603 222 222 227 227 240 240 18 88129 18 8 81 29 corr. area 50347 50275 corr. 100.00 99.86 320/32 2 C R L C U L R T 1ON R - G l o b a l ( 1) = .8128 M / Z `= 2 5 7 . 0 F irst p ea k is b a s e l i n e drop corrected area. S e c o n d pe ak is t angent s k i m m e d c o r r e c t e d area. Peak ' R. T. fi rst min. scan max scan 1ast peak sc an w i d t h raw area 1 11.603 223 227 239 16 7 6 5 7 9 2 11.803 223 227 239 16 76579 corr. area 35907 35211 corr. Ji 100.00 98.06 (320 + 322) / (332 +3345 CRLCULRTI OH R - G l o b a l < 3) = .5556 (328' >'''(332 + 3345 C R L C U L R T I O N R - G l o b a l < 3> = ,3547 | iH w .d 4 ^ ^lJ SU3JECT TO PROTECTIVE ORDER 00132 C11407 File > B2907 3 3 3 . 6 - 3 3 4 . 6 *mu 2UL 2.669/ .48/. 19 SP23 30 2 6 0 - 1 / 3 / 2 5 0 RUH BT 20000- --i-- i-- n -- i-- i-- r 1 1'I -I-- i i i i i i ~l-- i-- i-- I-- i-- I r 10.0 10.5 11 6 11.5 12.0 12.5 >1 1 13.0 ii'l 13.5 14.0 14.5 15.0 File >29 07 3 3 1 .6-332.6 *mu.2UL 2 . 6 6 9 / . 4 8 / . 1 9 S P23 30 2 0 0 - 1 / 3 / 2 5 0 RUN BT File- > 2 9 0 7 3 2 1 . 6 - 3 2 2 . 6 *mu .2UL 2 . 6 6 9 / . 4 3 / . 1 9 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN BT i.iiAfim. con unii (i Phi .o nifi h r, N ( III* ' J 0 ( . *( * C11408 MS data fil header from i >B2907 Samp 1e : 2UL 2* 6 6 9 / . 4 8 / . 1 9 Operat ori CAR Y MS 9/11/84 Misc I SP2330 200-1/3/250 RUN BTLft41 BTLft41 Sys. tti 1 MS modeli 67 S U / H U rev. t CA ALS ft 1 0 M e t h o d f i 1ei S P 2 3 3 0 Tuning file* APEI01 Ho. of e x t r a rec o r d s : Source temp.: 250 Analyzer temp .i 0 Transfer 1 ine temp. : Chromtographi c temperatures : 50 C h r o m a t o g r a p h i c t imes , min. : 0. 0 C h r o m t ographi c rate, deg/mi n : 20. 0 300. 2.0 0.0 0. 0.0 0.0 0, 0. 0 0. 0 0. 0.0 0. 0 M/Z 333.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak ft R.T. first min. scan max scan 1ast peak scan u idth raw area corr. area corr. */. 1 11.774 2 11.774 216 216 229 229 250 250 34 205931 134089 100 .00 34 205931 133953 99 .90 M/Z = 331.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak ft R.T. first min. scan max scan 1ast peak scan width raw area corr. area c rr. 1 11.774 2 11.774 216 216 229 229 248 246 32 177960 112232 100 .00 32 177960 108600 96 .76 332^334 CALCULAT IOH R - G l o b a l < 6> = .8370 M/Z = 327.9 First peak is bas el i ne dr op c o r r e c t e d area S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d a r e a P 'ak ft R. T. f irst min. scan max sc an 1ast peak sc an width raw area 1 11.794 2 11.794 226 230 220 ' 236 251 251 31 160851 31 160851 M/Z 321.9 F irst peak is b a s e 1 ine drop co r r c c t e d area. S e c o n d pc ak is t a n gent s k i m m e d c o r r e c t e d area. Peak ft R. T. f irst min. scan max sc an 1ast peak scan width raw area 1 11.794 2 11.794 215 215 230 230 248 248 33 800755 33 800755 nrn n . ul lV corr. area 94325 94170 c orr. y. 100.00 99.84 ORu c orr. area 735019 717677 corr. y. 100.06 97.64 ciuno s tlsZ * 319.9 Firs* peak is b a s e li ne drop c o r r e c t e d area. Second peak is tangent s k i m m e d c o r r e c t e d area. Peak R. T. f irst min. scan max scan 1ast peak sc an ui dth rau area 1 11.794 2 11.794 223 223 230 230 257 257 34 694491 34 694491 Corr, area 624893 616699 corr. 5i iee.ee 98.69 320^322 CALCULATION R - G l o b a U 1> - .8502 11s2 .* 2 5 7. 0 F irst peak is b a s e 1 ine d r o p c o r r e c t e d area. S e c on d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. f irst min. scan max scan Tast peak scan width rau area 1 11.794 C 11.794 224 224 230 238 252 252 28 .28 504553 504553 corr. area 434217 425355 corr. 4 100.08 97. 96 (320 + 322>/(332 +334) CALCULATION R - G l o b a l ( 3> = 5.5209 (328')/(332 + 334 ) CALCULATION R - G 1o b a l ( 3) = .3561 1 2 C<X Cu *" V. c 0C135 i J r':;! si 7 v z. c 'C c k C2 C11410 w co m <o m <o an u .SUL 2 6 . 6 9 ^ .48*'. 19 S P 2 3 3 0 2 0 0 - l ' 3 ' 2 5 8 RUN CO CO cvt (Vi M "1 L' ..... C11411 0C136 SP2330 200-1/3/250 RUN \ co \ cr. cO ,0*04 3 Ol D I \ O0O5JJ u> OJ O) Codd <O7l` m OCDD CD OD <55 OJ u. CL U5 OJ 0S0 <D OJ (0 0 a0.1 05 ^r \ c> OJ 3 oi 0O5J I 05 OD 0. 01 OD CODD Ol CD U5 * Ij5 OJ 0\5 I 5. & i\l 00D55 Ol ai/t, o- \ c'oT \ O* OJ 3 Ol II B 4 rt'OuiJ i r`0 u> *j cCoD O* Ol M ) MS data file header from i >B2908 Sample: 2UL 26.69/.48/.19 O p e r a t o r i GfiRY MS 9 / 1 1/84-15I-4? . . Mise i SP2330 200-1/3/230 RUN . BTL43 BTL443 Sys. it 1 MS model: 87 SW/HU r e o . i CR RLS I 0 Method filei SP2330 Tuni ng fil ei R P E 1 0 1 No. of e x t r a records! Source temp.: 230 finalyzer temp.i 0 Transfer line temp. : Chromatograph!c temperatures i 50. C h r o m at og rap h! c t imes p min. i 0.0 Chromatographi c rate, deg/min: 20.0 300. 2.0 0.0 0. 0.0 0. 0 0. 0. 0 0.0 0. 0.0 0.0 M/Z - 333.9 First peak is b a s e l i n e d r o p c o r r e c t e d area. S e c o n d peak is t an gent s k i m m e d c o r r e c t e d area. Peak * R.T. first min. scan max sc an 1ast peak sc an w id th raw area 1 11.796 219 231 252 2 11.796 219 231 252 33 242219 33 242219 M/Z * 331.9 F 1rst peak is base line drop corrected area. S e c o n d pc ak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. f 1rst min. sc an max scan 1ast peak sc an w i d t h raw area corr. area 171836 171401 corr. '4 100.00 99.75 corr. area corr. 4 . * \ \ *? CI aC4&ccc C i : 1 11.816 2 11.816 224 224 232 232 244 244 20 181045 139325 20 181045 139225 332/334 CRLCULRTI ON i R - G 1obal( 0 > - i 1 | M/Z = 327.9 .8108 <1 su bject i First peak is bas el v ne drop corrected area. ! S e c o n d peak is t a n g e n t sk im m e d c o r r e c t e d area. , Peak 1*' # i __ R.T. min. | 1 11.837 | 2 11.837 1 \ M/Z - 321.9 i first scan 226 226 max scan 233 ' 233 1ast peak scan width 242 242 16 16 raw area 243276 243276 ! First peak is baseline drop c o r r e c t e d area. j S e c o n d peak is tangent s k i m m e d c o r r e c t e d area. corr. area 208968 205100 Peak # R.T. first min. scan max scan 1ast peak scan width raw area c or r . area 100.00 99.93 1 ,,r 1 1 l? m ` F T T 7 A T* '" '-'-''VE C R D Eri corr. '/. 100.00 98.18 c orr. V. c c 1 11.837 2 11.837 222 222 233 233 248 248 26 9985550 9930924 100.00 26 9985550 9824702 98. 93 z or 1 C11412 s fl/Z 319.9 First p e e k is b a s e l i n e drop corrected Are a . S e c o n d p(Ak is t a n g e n t s k i m m e d c o r r e c t e d Are a . yWcf Peak i R. T. min. f irst sc .n m ax sc An 1ASt pe Ak sc An width raw Are a c or r . Are a 1 11.837 2 11.837 219 219 233 233 250 250 31 8 2 0 8 8 5 7 8 1 4 7 1 6 7 31 8 2 0 8 8 5 7 8 0 5 6 9 5 7 c or r . 100.00 98.89 320/322 CALCULATION R - G l o b a K 1) .8204 M/Z 257.0 1F ir s t pC Ak i s b a s e i n e drop correc ted area. S e c o n d pe Ak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak .# R. T. min. first sc an m ax sc an 1as t sc an pe ak width raw area 1 1l.e37 n 24L 11.837 224 224 233 33 246 246 .2222 5182106 5182106 c or r . are a 5128184 5047290 corr. V, 100.00 98. 42 <320 + 322)/<332 +334) CALCULATION R - G l o b a l < 3) = 58.1000 <328')/<332 + 334) CALCULATION R - G l o b a U 3> = .3841 SUBJECT TO "" \ L ORDER- 0G1L8 ci1 4 1 3 t o 3.' 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