Document aJG864yoYBMKajker3MxLzaZY

CH-1003 REV. ** U O'1 CSMIUSMEO ttQ2 E. I. d u Po n t d e Ne mo u r s & Co mp a n y INCORPORATED Wil min g t o n , De l a w a r e 19898 CHEMICALS AND PIGMENTS DEPARTMENT JACKSON LABORATORY cc: J. G. Ishikawa, B-16234 S. C. Doberstein .ip i <..., v September 23, 1981 To: From: A. W. Bauer, B-16235 R. S. We.is (p9 1981 ANNUAL REPORT Attached are R&D Activities and Objectives and Major Cost Containment Programs for Aromatics and Colored Pigments. RSW: gmd Att, -1981 ANNUAL REPORT - R&D ACTIVITIES AND OBJECTIVES Aromatics Annualized savings of $5.3MM (2.9% of factory cost) resulted from the continuation of a vigorous cost reduction program. In addition, support for start-up of major projects for phthaloyl chlorides, 4,4'-oxydianiline, and 3,4-dichloroaniline (which in volves new reactor technology) was provided. Manufacture of mono and diethylaniline was reinstituted with a new, more economical/ safe process. In 1982 cost reduction effort will continue with an annualized commitment of $3.9MM (2% of factory cost). Support will be given for a new major market for phthaloyl chlorides in polyarylates manufacture. Specialty Chemicals Technical accomplishments in 1981 include the successful expansion of "lyzor" titanates to meet the demands for oil well treatment chemicals and support for fluorochemical expansion to meet the needs for the newly-developed threadline application. In 1982 support will focus on continued expansion of "Tyzor" titanates and Alsyl products, both needed for oil well stimulation and the fluorochemicals expansion program. Pilot plant activity will provide basic data for "Tyzor" and Alsyls expansions which will quintuple and quadruple capacities, respectively. Benefit Group Principal Program Cost Reduction Described in Cost Containment and Productivity exhibit Product Improvement Phthaloyl Chlorides for GE Capacity Increase New Process - Oxydianiline Regulatory Work None S. C. Doberstein:jla Sept. 21, 1981 N 26946.01 DUP050145968 COST CONTAINMENT Aromatic Products Our cost reduction commitment in 1982 is $3,9.MM (.2.0% of factory cost) from a potential of $5,9MM, due to improved yield, reduced materials, and energy savings. Major emphasis is in nitration and reduction processes with major savings in 3,4-dichloroaniline ($1.7MM), nitrotoluenes and nitrochlorobenzenes ($1.2MM), and phenylenediamines ($500M). Savings in 1981 were $5.3MM (2.9% of factory cost). S. C. Doberstein:jla Sept. 21, 1981 ^ 26946.02 DU P050145969 MAJOR COST CONTAINMENT PROGRAMS 0 ;P +J 3 3 (fAfl PO +J 3 to P e0 -p O u ft c 3s Eo 44 10 3 2w- .P -ri ip O 3p E ft (0 0) Jh CN 00 ON rH CO o CO <1) O H !S CN CO 00 00 ON ON rH rH in Oo rH O fl3 }H E& co CO 0) 5h CN 00 ON rH rH 0 CO 0O >< is CN CO 00 ON ON rH rH 3 co Z 3c o CO VD 00 z OO P o 4v4 +) to mo ft u <*> 0) > -H P 44 P c0o) (0 0) >4 Hc \ (0 tr- cH > 4-> ,10 p (0 1h (0 w -p a) ft> X 44 <u fi-tl 44 (0 3 3> toH *- o -P (U TO VP fopt P CO 3 Ol 3E PI U CcoN OV rH . CO ro CN 00 ON 0 in o CO ro co 00 on vp oo if) o ON CO CN CO O rH in <r so o S. CN 00 CN 00 CN CN CO 00 CO GO pD o> ON ON ON ON rH rH rH rH fv * 00.* CN CN O VP r> <N VP CN rH rH CN P 0) cv a so CO o 3V ft -i C<o -H3sP P C O 3 10 CO -H rH 4J o Hpo <D <0 > 0 HH -HN JH a> h 403 P a *P He Sto -u Q1rh m o rH V '0 rH 3 >* to 30 .3 > 3 >f 3 o O Cxi 3 p3P rH o 4o4 wfettKJOX W33 p 44 rH z CO t 3 31 33 N G SO O -H 3 rP 44 < A 3 3 30 0 > -Ip N o P 0 P -p I 0 P 3 rH - i4HO3 HfEt+3 l4Dp4 ifsr 0 p 4H4 z in % V& * % r*. o rP o Pm 3o >1 E 0 z to 3 tn 3 ^3 to 13 D 3O w >3 3 P m -p 3 -P C OE ip 4J U 3 30 0 -H 3 3 3 3 ft 3 P +> P > -P N <u E 0 o 0 3 3 >0 O P -P 0 3 P -P 3 -P E HE&+f3t Tf33t 3 -QP fPOt 3 33 rH 353p 43 Pft EH 3 4S34 rP Ip 4&-> T3P33S UtO3o ft DUP050145970 MAJOR GOST CONTAINMENT PROGRAMS 17 A ll d o lla rs on a c u rre n t ye a r b a sis HO ('- Pu Pin ns pu p tu in p GO P 8^ c I c o p in 0) > C H >1 psr\j pp u in to 0 ft o <#> -H rt G P C Vu MG pRS .ft \ CO tr G>H P in p C w Pp <nus ft ft X <0 P w u fit p10 ns oos p o Ip ions >< cooo 0). co aos n <N o l> * iH in in ' o 00 mco cr> o> rH <--i p 0) CN CO 0 o> ft rH G ns S in in o 1 to in n3 To3s o rH H 0) P O H ft rH *H U P <5 tu G iP fOt HS AU fl) rH >O oft G Kas a") DCH p\ G & rH ft <P We Mu 0) P P woo D s 4h (d A P A fit DUP050145971 COLORED PIGMENT PRODUCTS R&D ACTIVITIES AND OBJECTIVES Major Technical accomplishments during 1981 include successful trial manufacture of a new automotive gold pigment, based on quinacridonequinone, which should generate $470M in new pretax earnings by 1985. In addition, a new resinated copper phthalocyanine blue, with a 95M lb./yr. new business potential in 1982, was successfully developed and plant tested. Savings in yield and raw material usage during 1981 amounted to $2MM (2% factory cost). In 1982 we expect cost reduction programs to provide $1.4MM in annualized savings. Major technical emphasis in 1982 will be placed on improving and documenting existing process technology to help improve long-term Colored Pigments productivity. We also expect to complete development and test manufacture of several low rheology quinacridone reds for use in High Solids Automotive Enamels. Laboratory development of a potentially proprietary class of azo pigment based on anthranilamide derivatives is expected to be sufficiently complete to allow us to decide on their commercial viability as lead chromate replacements. P. A. Wriede September 21, 1981 N 26946.04 COLORED PIGMENT PRODUCTS Benefit Group Cost Reduction Product Improvement Capacity Increase Regulatory Work Principal Program Described in Cost Containment exhibit. Develop low rheology quinacridones for high solids automotive enamels. None. Develop low investment route for removal of heavy metals from Newark waste stream. P, A. Wriede/gmd September 21, 1981 DUP050145973 COST CONTAINMENT Colored Pigment. Products Cost reduction programs in 1982 include a commitment Of $0.8MM with a goal of $1.4MM (1.2% factory cost) in labor, yield, raw material, and energy savings, 1981 Savings were $2.OMM on an annualized basis, with major savings in raw materials and reduced substandard inventories. Longer range program involves replacement of acetic acid with sulfuric acid in the hydrolysis of disodium succinyl succinate ester, a critical quinacridone intermediate. Raw material cost savings of $60QM in 1984 are expected on new investment of $500M, P, A. Wriede September 21, 1981 DUP050145974 COLORED PIGMENT PRODUCTS A ll dollars on a current year basis. c o 4-9 N u 4-9 a 1/1 s- (0 4-9 O V) 09 4-> JCOo u. c o > .E >> u o 4-> 4-> O CO <o O LL. o cn CO 09 z > *r- 2 CD 3 4-9 C C *r-- 1. < 09 o 09 4-> >- Ue Q. co z 1--( CP z f- *9- Z </> LU cn sc z n +-> HH > (A C <: (O i- <e i-- CO r- 09 z CL. >- oX o (0 4*> H 09 00 S- * o Q. u JIT 4-9 09 os V) > /* o -D <0 u 5'w' 09 <0 VO z V r-- 00 o 3 09 u. E r- 31 CJ CM CO CT I CM in * o CM 00 p\ r-i iH o 2 CO CO <J) CM so o CO r*4 CM I I ID rH o CM CO CTi .H w <D CM 00 a\ rH CM O ON CO o CM CO 0s rH LO iH CM S<*U. 0CO) OQ. r-- C C7i a. CM m rH o (0 s -P o V +3 . C -H 3 13 3 P 13 P ft P O -H 3O 13 g 3 3 3 3 13 P Cfl 3 e oo O' 3 3 .M *rl 3 O P >, P p a) H o tn p 3 s p o PP o 3 >i 3 P P H U O O' C 3 3 H 3 P 3 > SO P 13 U > 3 O (0 f&t 3 3 33 3 -H 0O U -P s H o3> in iH m3 PO 3 *rl 3 P 13 P ft p 13 g 3 3 P 3a 13 3 Cn 3 3 SOP p omP XI o 3 3 -P 0 O' 3 3 3 P a) 13 3 13 > a>3c 3 ft 3 3 rl fUt 3 a CM to a ft 0) iu CO o cn o H VO +J Ot ft x: CO o3 po P30 (0 P 3 C o 3 rl H t> S 4J A 3O3 cO tn 0Po UP O M O: ' c H Q) * ft w DUP050145975 COLORED PIGMENTS PRODUCTS COST REDUCTION SUMMARY 1980 Actual 1980 Forecast 1981 Forecast Future $1509 $1060 $1002M $9128 Cl. 9% factory costs) (1.2% factory costs) (7.5% factory costs) . ! n tT PAWriede/kww 10/15/80 M DUP050145976