Document aJ578JLXe6oKb0jrxk9aKNQ2B

ff 3M Specialty Materials May 23, 2000 3M Center St. Paul, MN 55144-1000 651 733 1100 3M Dr. Charles Auer, Director Chemical Control Division Office of Pollution Prevention and Toxics United States Environmental Protection Agency 401 M Street, Southwest Room 403, East Tower (Mail Code 7405) Washington, D.C. 20460 Re: Information on Perfluorooctane Sulfonates and Related Compounds - Additional Information f Y I - 500. 37? AR6-0378 O' rO'*#4 tv u o o rx T** -- ro CT Zs ZT Sr C n17rr0 r -h h \ ) ' rn i ---* Dear Charlie: I am enclosing additional information that did not get submitted with the recent May 18, 2000 submittal to you on perfluorooctane sulfonates and related compounds. This information includes: 1. An additional summary and report on N-ethylperfluorooctane sulfonamidoethanol (NEtFOSE Alcohol) and a revised N-EtFOSE Alcohol Bibliography Sheet that includes this report. 2. Information on N-methylperfluorooctanesulfonamidoethyl acrylate (MeFOSEA). 3. Information on Perfluorodecanesulfonate, Ammonium Salt (PFDS). 4. Information on Perfluorooctane sulfonylamido (ethyl) acetate (PFOSAA) and a revised PFOSAA Bibliography Sheet that references FC-127 as another synonym for this compound. 5. Information on N-ethylperfluorooctanesulfanamidoethyl acrylate (EtFOSEA) and a revised EtFOSEA Bibliography Sheet that references a study not included on the bibliography sheet last week. The Bibliography Sheets for MeFOSEA and PFDS were included as part of the May 18th submittal and remain unchanged. 4 Very truly yours, FYI-00-001378 William A. Weppner, Ph.D. FYI-0 0 -0 0 1 3 7 0 Director of Environmental, Health, Safety And Regulatory Affairs Specialty Materials Markets 3M Center, Bldg. 236-1B-10 (651) 733-6374 (phone) 85000000013 (651) 733-1958 (fax) E-mail: waweppner@mmm.com 85000000013 c41s I PO ~K c5 XT PO 000001 This page added by Terry O'Bryan/EPA to expand index o f FYI-0500-01378 submitted 5/23/00 1. Information on N-ethylperfluorooctane sulfonamidoethanol (N-EtFOSE Alcohol): Summary and report of Octanol/Water Partition Coefficient 2. Information on N-methylperfluorooctanesulfonamidoethyl acrylate (MeFOSEA): Summary and report of Stability in Water (Hydrolysis) Summary and report of Octanol/Water Partition Coefficient 3. Information on Perfluorodecanesulfonate, Ammonium Salt (PFDS): Two summaries and reports on each of the following: Biodegradation; Acute Toxicity to Fish; Acute Toxicity to Aquatic Invertebrates; Activated Sludge Respiration Inhibition Test; Microbios Microtox Toxicity Test. 4. Information on Perfluorooctane sulfonamido (ethyl) acetate (PFOSAA): Several summaries and reports on each of the following: Biodegradation; Acute Toxicity to Fish; Acute Toxicity to Aquatic Invertebrates; Activated Sludge Respiration Inhibition Test; Microbios Microtox Toxicity Test. Summary and report of Bioaccumulation (analytical only) Summary and report of Acute Toxicity to Aquatic Plants (Algae) 5. Information on N-ethylperfluorooctanesulfonamidoethyl acrylate (EtFOSEA): Summary and report of Physical/Chemical Properties Two summaries and reports on Biodegradation Summary and report of Acute Toxicity to Fish Summary' and report of Activated Sludge Respiration Inhibition Test Summary and report of Bioaccumulation 000002 N-EtFOSE Alcohol Bibliography Synonyms: FM 3422, FM 3923, FM 4635, FM 4120, F 9353, FC-10 Physical/Chemical Properties Title Water solubility Letter Report. Boiling Point Information Determination of Vapor Pressure Curve by Dynamic Method for U1463 (Et FOSE) Internal Memo - Melting Point of FM-3923 N-Ethyl FOSE Alcohol Laboratory or Author 3M Env. Lab AScI ASci 3M SMMD Analytical Lab D ate C om pleted 11/15/77 11/30/98 11/6/98 11/22/99 Type Robust summary, relevant pages from "Analytical Methodology on FM 3422' Robust summary, letter report Robust summary, final report Robust summary, letter report Environmental Fate and Transport Title Tech Report - Biodegradation Studies of Fluorocarbons, Request for Laboratory work - BOD/COD, Memo - Chronological Review of Biodegradation Studies on FM3422, Tech Report - Biodegradation Studies of Fluorocarbons - II. (Robust summary for 4 documents) Tech Report - Bioconcentration of FM3422 in Bluegill Sunfish and in Channel Catfish, Tech Report - Aquatic Fate of a Fluorochemlcal: FM 3422 Tech Notebook copies - Analytical from fish bioconcentration studies Alkaline hydrolysis Laboratory or Author 3M Env. Lab C om pletion D ate Type 8 /1 2 /7 6 , July, 1977, 8 /1 2 /7 7 , 1 /9 /7 8 Robust summary, 2 technical reports, work request, review document 3M Env. Lab G. Vraspir 3M Env. Lab 5 /1 7 /1 9 7 7 , 1 0 /1 4 /7 7 , 3 /8 /9 3 1 /1 5 /7 6 - 2 /1 /7 8 1 1 /1 5 /7 7 Robust summary, 2 technical reports, critique by J.W. Glllett (Cornel) ??? Robust summary, relevant pages from "Analytical Methodology on FM 3422' Pilot studies on soil adsorption Evaluation of the Bioconcentration Potential of FM 3422 Tech Report - Adsorption of FM-3422 on Soil 3M Env. Lab 3M Env. Lab 3M Env. Lab 1 0 ,1 3 ,7 8 , 5 /1 9 /9 3 , 1 2 /3 0 /7 5 , 3 /7 /7 7 , 4 /1 2 /7 7 , 5 /9 /7 7 8 /1 6 /7 8 9 /1 /7 8 Robust summary, page from technical notebook, critique from S. Boyd (MSU) and 2 pages of data summaries. Robust summary, critique from G.W. Glllett (Cornell), technical report Robust summary, critique from S. Boyd (MSU), technical report 000003 Environmental Fate and Transport Title Tech Report - Analysis for Fluorochemicals in Bluegill Fish Laboratory or Author 3M Env. Lab C om pletio n D ate 5 /1 /7 9 Type Robust summary, critique from J.W. Gillett (Cornell), technical report Tech Report - Bioaccumulation of Fluorochemicals in Tenn. River, Tech Report Fluorochemicals in Tenneessee River Fish. Technical Report - Photolysis of FM 3422 on Soil Tech Report - FM-3422 Photolysis Study using Simulated Sunlight Tech Report - Determination of the Partition Coefficient (N-Octanol/Water) of FM 3422 3M Env. Lab 3M Env. Lab 3M Ag. Products Lab NOTOX Safety & Environmental Research 5 /2 2 /7 9 , 1 2 /2 8 /7 9 , 3 /8 /9 3 1 2 /1 0 /7 9 8/11/81 6 /2 /9 4 Robust summary, 2 technical reports, ciritque from J.W. Gillett (Cornell) Robust summary, technical report, critique from S. Boyd, MSU Robust summary, technical report Robust summary, technical report Summary Reports Title Laboratory or Author 3M Env. Lab C om pletion Type D a te 1 1 /1 5 /7 7 Technical report., Critique by S. Boyd (MSU) Exerptsfrom this report appended to solubility and alkaline hydrolysis robust summaries. Tech Report - Analytical Methodology on FM 3422 Tech Report - Analytical Methodology and Support Tech Report - Final comprehensive Report on FM 3422 3M Env. Lab 3M Env. Lab 1 /1 7 /7 9 2 /7 /1 9 7 9 , 3 /8 /9 3 Technical report. Exerpts from this report appended to solubility, alkaline hydrolysis,volatility, distribution coefficient, soil adsorption, biodegradation, and fish chronic toxicity robust summaries. Technical Report, critique by J.W. Gillett (Cornell) 000004 Ecotoxicity Elements Title Laboratory or Author C om pletion D ate Type The Effects of Continuous Aqueous Exposure to 78.01 on Hatchability of Eggs and Growth and Survival of Frv of Fathead Minnow fPimeDhales Dromelasl. Summary of Histopathological Examinations of Fathead Minnow (Pimephales promelas) Exposed to 78.01 for 30 Days.. Tech Report - Multi-Phase Algal Assay Test Method. EG&G Bionomics 3M Env. Lab June, 1978, Sept. 1978 12/30/81 Robust summary, 2 technical reports, exerpt from Tech Report - Analytical Methodology and Support (1/17/79) Robust summary, technical report. 000005 Perfluorooctane sulfonylamido(ethyl)acetate = PFOSAA Synonyms: FC-109, FC-109-X, FC-127, FC128, FC-129, E2113, E2566-2, R1904 Physical/Chemical Properties Title Laboratory or Date Author Completed Type Environmental Fate and Transport Title Tech. Report - Fate of Fluorochemicals in the Environmental (sic) (Warburg respirometer method for biodegradation of FC-128) Ready Biodegradability of FC-128 - BOD/COD Laboratory or Author 3M Env. Lab 3M Env. Lab Date Completed 8/12/76 7/8/77 Tech report - Analysis for Fluorochemicals in Bluegill Fish Ready biodegradability of FC-127 - BOD/COD 3M Env. Lab 3M Env. Lab 5/1/79 8/19/81 Ready biodegradability of FC-109-X - BOD/COD Pace Laboratories, Minneapolis, MN 12/31/87 Type Robust summary, technical report Robust summary, copies of data sheets Robust summary, technical report Robust summary, copies of data sheets Robust summary, copy of computer results from archives Summary Reports Title Laboratory or Date Author Completed Type Ecotoxicity Elements Title Acute toxicity of FC-128 to fathead minnow Acute toxicity of FC-128 to fathead minnow Acute toxicity of FC-128 to fathead minnow Acute toxicity of FC-127 to fathead minnow Toxicity of FC-127 to activated sludge respiration Laboratory or Author 3M Env. Lab 3M Env. Lab 3M Env. Lab 3M Env. Lab 3M Env. Lab Completion Date 5/18/74 6/29/74 8/26/77 7/24/81 8/14/81 Type Robust summary, copies of data sheets Robust summary, copies of data sheets Robust summary, copies of data sheets Robust summary, copies of data sheets Robust summary, copies of data sheets 000006 Ready Biodegradability: "Modified OECD Screening Test" for Fluorad FC-129 Microbios Microtox Toxicity Test - FC-109-X Activated Sludge Respiration Inhibition - FC109-X Acute Toxicity of E2566-2 to DaDhnia maana Acute Toxicity of E2566-2 to Fathead Minnow (Pimephales prometas) Biodegradation (methylene blue active substance) Acute Toxicity of R1904 to Daphnia magna Growth Inhibition of R1904 for Green Alga (Selenastrum capricomutum) Acute Toxicity of R1904 to Fathead Minnow (Pimephales prometas) Microbios Microtox Toxicity Test - FC-129 Inhibition of R1904 for Activated Sludge Respiration R1904 BOD Report for 3M Company RCC, Itingen, Switzerland 3M Env. Lab 3M Env. Lab ABC Laboratory, Columbia, MO ABC Laboratory, Columbia, MO Pace Laboratories, Inc., Minneapolis, MN ASci Corporation, Duluth, MN ASci Corporation, Duluth, MN ASci Corporation, Duluth, MN ASci Corporation, Duluth, MN ASci Corporation, Duluth, MN ASci Corporation, Duluth, MN 9/19/84 10/15/87 10/30/87 Robust summary, memo about study reliability, final report Robust summary, copies of data sheets Robust summary, copies of data sheets 1/9/88 Robust summary, final report 1/12/88 Robust summary, final report 2/15/89 Robust summary, computer report, copies of data sheets 6/17/97 Robust summary, final report 6/18/97 Robust summary, final report 6/27/97 Robust summary, final report 7/9/97 Robust summary, copies of data sheets 7/10/97 Robust summary, final report Jul-97 Robust summary, final report oooo<y? Ethyl FOSEA Synonyms: FX-13, B1228, D-1 Physical/Chemical Properties Title Determination of Physico-chemical Properties of Sample D-1 Laboratory or Author Mitsubishi Chemical Safety Institute Ltd., Yokohama, Japan Date Completed 2/14/96 Type Robust summary, final report Environmental Fate and Transport Title Ready biodegradability of FX-13 (BOD/COD) Ready Biodegradability Test of D-1 Bioaccumulation Study of Sample D-1 with Caro (CvDrinus canaio) Laboratory or Author 3M Env. Lab Completion Date 4/26/84 Mitsubishi Chemical Safety Institute Ltd., Yokohama, Japan Mitsubishi Chemical Safety Institute Ltd., Yokohama, Japan 10/31/95 11/30/95 Type Robust summary, copies of data sheets Robust summary, final report Robust summary, final report Ecotoxicity Elements Title Acute toxicity of FX-13 to fathead minnow Activated Sludge Respiration Inhibition Test FX-13 Laboratory or Author 3M Env. Lab 3M Env. Lab Completion Date 4/1/84 5/17/84 Type Robust summary, copies of data sheets Robust summary, copies of data sheets 000008