Document aDVw5XXMaEN1ozvK6EG9rmzYy

: NOTICE THIS MATERIAL MAY : BI : '. ! PROTECTED BY COPYRIGHT LAW (. . ... ' Title ).,U.S17 Code -- - asResearcher . all responsiblity for proper :.use . : :. .. . i. :. :. .: : .. . .. . . FILE COPY irIN , DEVELOPMENT DIT JoviN ** : : CONFIDENTIAL ANNUAL RESEARCH REPORT 1946 . . .: ., . . .. 2 . . .:: .. .: : . .. . : 22: : .. . . . :: :: . .. ". .. . ! ? . .. . E 1. 1 X . . .. . ! . .. . WAAR . . REFERENCE COPY FROM MONSANTO COMPANY , RECORDS , WUA00131 WASHINGTON I.NUNIVERSITY ST LOUIS 47 . ! . N .. DEVELOPMENT DEPARTMENT . . 40 . . . us . ANNUAL RESEARCH REPORT - 1946 LOUIS ST : SCIENTIFIC -WORLD CONTACT IN : : mhe practice of visiting outside ent laboratories, universities , and research similar noonrg- panroizfaittiognrosu,psgofvoerrn listUNIVERSITY im1mWaTeh1eacnesnrtttt:'ipsvD1uishArtepais.peoscassoaretbmmeaseperotenrnafitsrrekoteiedfinsneugopimniftnhetpegedaorielapnalslatbotts,rnhetgeta,aosmmtthMaaenoojoynfrlsiooatnegfnfecrtosotohhurnophgtoshsaaelasonctgioboziepfncaertatnbaeilorcvondtataerrsiedadlewnwddnbhinsyostpueeptarhrni.eoedscrsodDTtpteheeoivvseetohllfooepp , ilitstWASHINGTON visited by to initiate the divisions, and contact . Because several with which of the size of the seemed advisable and the wide ,WUA00131 B ogttiohnfeetoMaegrsroevrsnaassipslapshtno.itcontahsliiTnisbhsepimslDrieetienaypddVafioroastmrnfitdesctnhrateewlpliniiolnlalrgmbtsboaeorniaonmnttoacatdreihineereitsnawgvi,intihsathoietbtfshroedthaciedvoirivcsgecuiorroolv-anuaetps1reas1dgheaainvttoebteyretraheaggesursesltueamdr ing several divisions. those RECORDS While this program was directed principally at government laboratories, universities , and similar ncoonn-tpacrtosfiwt itohr itCOMPANY ganizations , the organizations is tivities of the latter group . value of broad contacts with industrial research recognized, and is planned to expand the ac Development Department to include coverage of this MONSANTO OLEFINS FOR SANTOMER SE FROM COPY rocDafoannygottoeaAlnechtsfeaiitndsussdbybueyfnoeidsnpreerSuertasnasokndtaitnenobramgllisewchraasyeaesdltlt.uso,dyatdTonhedtetoelorvtmhcadealieuntteeeeernmostthoifinreueerCca,eotvhspiaelooillyvfaimnabdlteuhiurleiissttyinroymf atahnnisteoderrmbCsiaoehaouliln.rgces butylene polymers in the C , range for Santomerse . REFERENCE T3A1. . . . . . .. . . .. .. . .. in " . .. . .. . . . . . . . . . . . . . . UAVTTTT. . . . ... . " . With the mon- view of .. . .. . forecasted shortage of most aromatic samoza chemicals v basic to our operations, we have initiated , at the request of the Pur mcmhaasteinrgialsDeoprarstmuietantb, lea survey to locate substitutes . We earietheprarnteiwcuslaourlrycesintoefreraswted proper for responsibility ll assumes ). Researcher ,..SCode U (17 Title LAW COPYRIGHT BY &4 EPROTECTED Taurus :MATERIAI THIS NOTICE ! . in WA . SEN .105. SPECIAL PRODUCTS (BIOLOGICAL CHEMICALS ) use . LOUIS ST IN UNIVERSITY IN , WASHINGTON 1. . .? , WUA00131 .. . INSECTICIDES proper * . .. for Santobane 14 . . utilityVE considerable time was given to developing compositions Santobane to meet trade requirements . The emulsifiable formu . itfifty oilSSSR tion was outstanding and as yet no competitive product has been neuonn-hduthenedqruedadel taetonrmd ina. tioTnhseooplfvreethnpetasrasatoinoldnubthoilfiitsythceoonf cDeDnTtrsaoitneluatihopanpsroawxlaismsoabtabeesleyend responsibility all around very satisfactory . assumes . : Although work was still ).dsts , Monsanto was not done in the prepared to development manufacture of satisfactory these materials . and the consummation of this work is in the future . Researcher (,.A .. XF SS . COM INS pp1jo9oo4lusd6ns.d,iAsb-aleoTppfphatirosrDotDixmTaqim,oul vaaewtnathetbitlichytuhyela=92owtp8iaorfos,n0ds0ous0socluhltdoptwioaoassunntdtthhsraeeapogtrsfrebetesrSataeawtinneegttreoehnbdptarnacJoeahpfnepitufmroaoirtrcxhymaiemlun.1laatahteinaolddyn July , Code 1 USwere 13009b,e0e0n017 Title 1 S . .. M .::RECORDS KA Extensive field Santobane applied in tests at Stuttgart, Arkansas indicated various ways was not effective in the cothnatrtolLAW of rice root maggot. COMPANY AUTO ::.. :. .1 . B . HexaethyNl UTetraphosphate . The objective was to test as an insecticide what appeared COPYRIGHT BY MONSANTO We to be tests small - a to potentially undertake promising chemical ; and and arrange for research , on the basis application and large- scale testing and Sales Development of of these research this pro , 6 PROTECTED duct . FROM BE COPY : All objectives mentioned Tetraphosphate has moved from have the been test tuabcehietvoedca. rlHoet xsaceatlheyl MAY : in the space of six months . .. . . REFERENCE naSex LE . .. . ... ACERAT firstIt stil1. Monsanto market-. " producer . aW nhsdausccisebeeednedfoinunthdpelathcciahntigetfhtehanisdprmecshotesigmt eiwcaiodl efolynthetahdeCvoeAmrmptiaesnreiycdahnas.TMAHT.ERI.ISAL allcbeeernnedmeiansutrhaeblyInsineccretiacsideed in the minds business . . . of the companies con - . w :: .32 ,18 1 S 1 11Nw1V . - . . . W . 26. 7 . 110 . . .. . .- . . Santobrite and Santomers. diethylene triamino ) D. T . (Lorol Field development studies are planned for the coming year . use proper for LOUIS ST 3 . Customer Service IN Customer service work on germicide formulations and treated WS textiles has been continued during the year . responsibility all UNIVERSITY L " ..17 Screening tests fiftyApproximately one hundred and chemicals were screened . assumes fungistatic bactericidal propertiesfungistatisiisi , sufficient for additional ).WASHINGTON - . 4 Art for and this group twenty- one compounds evidenced with 4 showing promise . work . These compounds were as follows : during 1946 . From properties , development Researcher , 7,.... . . . . . . .. .. . . 1 -Dodecyl- 8 - OH quinolinium bromide N , N - dilbutyl ethylene thiourea . . . . . . .. .. . . . SCode U . . . .. WUA00131 .. edpha beta dichlorossamma - crotonolactone. .. -- - e .. . :; . , ; , MaisPSP www P1 wy ... - -- - - - SU 11 . - . ww . ,; . . . . . . . .. . . . . .. . . . . .. .. . . .. - . . .. . . ". . .. . . ma . . . .. . tetrahydrophthalonitr(iteHarvey ** . ... . . .. 3 -Methyl- 3 , 6 - endoXxVy- 1 ,. 2 , , -IO 3 6. . WA 22 RECORDS evideTnecningcomspuofufincdisensthomweedristomfoe r gfeurrmthiceidr adl eavecltoipvmiteyn,t with three studies . These Title materials were as follows : LAW .. manuten ... . . . . . . . . . .. . ortho- phenethylphenol COMPANY 1 - te tradecyl - 2 -methyl imidazole 1 - decyl - 2 -methyl imidazole COPYRIGHT BY MONSANTO ,: : WOOD PRESERVATION A . Field Inspections . CTED FROM Test plots at Gainesville , Fla . , Saucier, Miss . , and Crown COPY .. -- -. . . -. .. REFERENCE . Point , La . , were inspected to determine termite and rot resistance :.. of specimens , some of which are now in the eleventh year , :. .:. . The " Broach " house at the . W T. Ala . , was inspected to determine the Smith Lumber Company , Chapman state of powder post beetle , 1zinfestation following treatment 4 years ago NA A : *-* .. Swimo . -- - .. .. . . .. all. . : : .. * . Reports on UinN spections were prepared and circulated . General conclusions are : . : still. ;.. '!... Pentachlorophenol treated specimens after 10 - 11 years exposure. good NOTIC L 7 Y . . . .. * hi .. .. .B NOTICE THIS 111 . . Tetrachlorotoluene and Aroclor as s011 poisons . . . 1242 appear good Wallboard and decay with after 1 /2 % four Santobrite years . resistant to termites XXX Application Reswewawrch. MATERIAL MMAAYY aloDuosugolaisls Fir to posts were establish treated operating with Pentachlorophenol schedules . . in : BE: BEHiti it, . . 24 phrough a series of extensive tests , was established that Southern Yellow Pine cannot be setisfactorily treated with Sentobrite from buffered water solution . PROTECTED L SMS BY Various woods have been pressure treated to establish the utility of Pentechlorophenol in woods for harbor and dock structures . * se p er Work has been Naphthenate, ZiinncitiNatepdthetonadtee,veCloopppecromPpeanrtaatcivhelordoaphtaenoanteC,op COPYRIGHT www . NS (* - LAW Pentechlorophenol and Naphthenic AcidV-sCopper Pentachlorophenate as wood preservatives , using the " wood block test " 1 Title U.,17 A survey was preservatives ( to conducted looking towards development of augment Pentachlorophenol) which could bewopodro S all it. duced by Monsanto consK ide.ration the , On the basis of factors current benzene shortage , , and taking was decided into that ).Code 8wocuhldlobreinaatesduitcarebsleolptroodbuectm. adeThebychheymdricoalyl siasspoefctscholofrotthoilsuepnreob,lem po now being investigated by our Research Department : Researi ce Publications - Researther .. Asels tance was given in the preparation of the brochure , Wood Preservation with Santophen 20 " . This was published in September. assumes all BulletStyin 0 -44 , " Plant Design for Treating seasoned Wood with . Santophen 20 by the Hot -Cold SPOSOeBDslaoovfeplompprmeepenatraatinodnG, ebneeinregl Open Tank Method " , 18 a combined activity Engineering currently in of Development, . :: responsibility for Di Associati"o! . n Contacts . , Hisproper trans to mong ckoenetpactabwreaas smt aoinf tadienveedlopwm*itehn:ts. . in the field . of wood preserva use American Society of Testing Materials, Committee D - 1 , : COPY FROM , MONSANTO COMPANY .. . , RECORDS .. , ..: WUA00131 :: E WASHINGTON L .INUNIVERSITY ST LOUIS - ---- - - --- ---