Document aDVOka9p599kxqjXJ7QmQRXjY
ANSUL
WsISlIl FIR6 PROTECTION MARINETTE. Wl S4143-254S
MATERIAL SAFETY DATA SHEET
Paqe 1 of 4
MANUFACTURER'S NAME____________ Prepared By
NITROGEN
Quick Identifier (In Plant~l)onfl)cn Namel
Ansul Fire Protection
Emergency
Wormald U.S. ,Inc._______________ Telephone No. (715) 735-7411 Date Prepared
Safety and Health Department____________ November 15, 1985 ~ ______
SECTION 1 - IDENTITY
Common Name: (Used on label
(Trade Name and Synonyms): Nitrogen_____________________
Chemical
Chemical
Name:___________ Nitrogen____________________________ Family:
Formula
N2
CAS No. 7727-37-9
Gas
SECTION 2 - INGREDIENTS
Part A - HAZARDOUS INGREDIENTS
Principal Hazardous Component(s)
(chemical and common name(s))%CAS No.TLVData
Nitrogen
100 7727-37-9
ACGIH Acute Toxicity None
Part B - OTHER INGREDIENTS Other Component(s) (chemical and common name(s)
% CAS No.
Acute Toxicity Data
SECTION 3 - PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data)
Boilinq
Specific Gravity
Point: -195.8 C (H20=1):
R77T"
Vapor Pressure (mm hgj: N7R"~
Percent Volatile by Volume (%): 100
Vapor Qensity (Air = 1): 0.98
Solubility in water: Slight
Evaporation Rate ( = lT: N/A - Gas at room temperature
Reactivity in Slight Water: Forms H2CO3
Appearance and Odor: Colorless gas with no odor.
SAL 000009492
NITROGEN SECTION 3 PHYSICAL AND CHEMICAL CHARACTERISTICS (cont.)
Page 2 of 4
Flash Point: None
Flammable Limits in Air % by Volume: N/A
Extinguisher Media: N/A
Auto-Ignition Temperature: N/A
Special Fire Fighting
Procedures:,^ * .< -
Though gas cylinders are equipped with pressure and temperature relief devices, they should be removed from
high temperatures or fire to avoid risk of rupture.
Unusual Fire and Explosion Hazards
None.
SECTION 4 - PHYSICAL HAZARDS
Stability Unstable [ ] Conditions
Stable
[X] to Avoid:
N/A
Incompatibility (Materials to Avoid): Can react violently with Li, Nd, Ti under proper
conditions.
Hazardous Decomposition
Products:
None
Hazardous Polymerization
May Occur [ ] Conditions Will Not Occur [X] to Avoid: N/A
NOTE: As used in Ansul cartridges, or cylinders, N2 is a gas compressed under pressures up to 2400 psi at 70 F.
SECTION 5 - HEALTH HAZARDS
Routes of Entry
THRESHOLD LIMIT VALUE: None listed.
Eye Contact:
Avoid contact with liquefied form of N2. Can produce chilling sensations and discomfort, also frostbite.
Skin Contact
Evaporation of liquid from the skin can produce chilling sensations. Frostbite can occur. Avoid N2 liquid.
Inhalation:
In high concentrations it is a simple asphyxiant - dizziness, shortness of breath, unconsciousness.
Ingestion:
Ingestion is not likely to occur since this material is gas at room temperature.
sal
009493
NITROGEN SECTION 5 HEALTH HAZARDS (cont.)
i' Page 3 of 4
Signs and Symptoms Acute Overexposure:
Dizziness, headaches, tinnitus, difficulty breathing, drowsiness, depending on length of exposure and concentrations.
Chronic Overexposure:
Compressed air illness.
*$ t
Medical Conditions Generally Aggravated by Exposure: None known.
Chemical Listed as Carcinogen or Potential
National
Toxicology Yes [ ]
Program
No [X]
I.A.R.C.
Yes [ ] OSHA Yes [ ]
Monographs No [X]
No [X]
SECTION 6 - EMERGENCY AND FIRST AID PROCEDURES
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes while holding lids open. If redness, itching or a
burning sensation develops, get Medical attention. Treat for frostbite if necessary.
Skin Contact:
Wash the material off the skin with copious amounts of soap and water for at least 15 minutes. If redness, itching, or burning occurs, get Medical attention. Treat for frostbite if necessary.
Inhalation:
Remove victim to fresh air. If cough or other respiratory symptoms occur, consult medical personnel. If not breathing, give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult, give oxygen. Consult Medical personnel.
SECTION 7 - SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify-TypeT: Not normally necessary if controls are adequate. If exposure
is prolonged, a self-contained breathing apparatus is recommended.
Ventilation
Local
Exhaust: Recommended in confined spaces.
Mechanical (GeneralTT Recommended
Protective
Eye Protection: Chemical goggles recommended when handling
Gloves: For contact
liquid. Full faceshield in addition if
with liquid.
splashing is possible.
Other Protective Clothing or Equipment: Protective clothing for contact with liquid.
SAL 000009494
NITROGEN
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SECTION 6 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES
Precautions To Be Taken In Handling
and Storage:
Store containers in a clean, dry, well-ventilated area
away from heat above 125 F. Store as a compressed
gas in DOT approved vessels. If cylinder is not
attached to a system, it must be safety capped to
protect against violent vessel movement or force of
escaping gas if valve is actuated or if seal is
accidentally punctured.
Other Precautions: Note Incompatibility information in Section 4.
Steps to be Taken in Case Material is Released or Spilled: Ventilate to outside.
Waste Disposal Methods:
Comply with all local, state, and Federal regualtions.
Form No. F-85313
SAL 000009495