Document aBy3Vx7xLzzz52XV0RDB849KR
FILE NAME Quigley QUIG DATE 1972 May 25
DOC QUIG020
DOCUMENT DESCRIPTION Material Safety Data Sheet with Cover
Letter from Johns Manville
Manville Corporation
22 East 40th Street New York N.Y. 10016 Executive Offices
May 25 1972
Mr. J. J. Marino
Chief Engineer
Quigley Company
235 E. 42nd St.
Inc.
New York N. Y. 10017
Dear Mr. Marino
an
A
x4
Recently you requested toxicological information concerning
Manville Asbestos Fibre
~
Enclosed please find Data Sheet providing
a U. S. Department of Labor the requested information
Material
Safety
If you require additional information assistance please contact me
and I can be of any further
Very truly yours
ir 3. Reitze
W. B. Reitze
Manager Accident Prevention and Health Administration
WBR mw Encl
09 0635
k^mk^m koptowaak
Mostumst
Aparnval Expires April 30 1971
'
U.S. DEPARTMENT OF LABOR
WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standards
MATERIAL SAFETY DATA SHEET
Form No. 158-005.4
1989
|
MANUFACTURER'S NAME Manville Corp. ADDRESS umber Street City State and ZIP Code
22 East 40th Street New York N.
CHEMICAL NAME AND SYNONYMS
Chrysotile Asbestos
CHEMICAL FAMILY
Asbestos
SECTION I Y. 10016
| FORMULA
;
EMERGENCY TELEPHONE NO
212-532-7600 Ext542 |
we
TRADE NAME AND
Asbestos
Chrysotile
es
SYNONYMS 1
J
t
Asbestos
ee
eee
od
_..
SECTION II HAZARDOUS INGREDIENTS
PAINTS
PIGMENTS
PRESERVATIVES & SOLVENTS =o *
Not Applicable
CATALYST
11
| Units
ALLOYS AND METALLIC COATINGS |:
BASE METAL ALLOYS
Not Applicable
.
" \
| TLY
VEHICLE H
METALLIC COATINGS
"
ii
SOLVENTS
"
ADDITIVES
1
OTHERS "
FILLER METAL "
PLUS COATING OR CORE FLUIX
OTHERS
11
|
: "
it |
ry
HAZARDOUS MIXTURES OF OTHER LIQUIDS SOLIDS OR GASES
Chrysotile Asbestos Fibre
For TLV see attached copy Federal
Register 12/7/71
Vol
36
Mi
ia
Approx | |
No.234 +! 8
| fi
TLV Units
100
hour time weighted average 5 fibres greater than 5 microns in length
Concentrations for 15 minutes
above 5 an hour
fibres not up to 5 hours
to exceed 10 fibres per 8 hour day
permitted
_
SECTION IIT PHYSICAL DATA
ti
MOILING POINT F.
SPECIFIC GRAVITY H
} 0
hi
VAPOR PRESSURE mm Hg VAPOR DENSITY FAIR 1 SOLUBILITY IN WATER
PERCENT VOLATILE
H
BY VOLUME %
ii EVAPORATION RATE
t
11
t
i !
APPEARANCE AND ODOR
White Fibrous Dry Material - No Odor
;
1|
' SECTION IV FIRE AND EXPLOSION HAZARD DATA-
F
FLASH POINT Method used EXTINGUISHING MEDIA
| FLAMMABLE LIMITS
Flammable
.
'
Lel
|
{
Uel
Lj
i {!
[:
SPECIAL FIRE FIGHTING PROCEDURES "
'
;
a
UNUSUAL FIRE AND EXPLOSION HAZARDS 1
WBR -
.
5/25/72
li
7]
{
i
i
09 0636
VALUE
THRESHOLD EFFECTS OF EFFECTS OVEREXPOSLIRE
S
V Lh 9aees VV
rTV PAG
of
MAIO BATA
pee
BATA
See May
Section II and attached cause pulmonary disease
OSHA regula effectit ve efifeo ctinve
|
by inhalation
12/7/71
EMERGENCY EMERGENCY AND FIRST AID PROCEDURES
Avoid
breathing
excessive
dust
when
,
handling
_ dumping mixing etc.
See caution label on
.. !_... ~---
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE
CONDITIONS TO AVOID
*
STABLE
x | Avoid breathing excessive dust
Materials to avoid
A
7
INCOMPATABILITY i
None
.
i
HAZARDOUS DECOMPOSITION DECOMPOSITION PRODUCTS
i
None
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
v
x
Avoid breathing excessive dust
i
.
SECTION VII SPILL ON LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Vacuum clean spillage
; 11
Repair broken
bags
If sweeping is necessary wet down spillage
respiratory equipment when required
WASTE DISPOSAL METHOD
Place waste in closed containers
Dispose of
closed containers
Avoid breathing excessive dust
Use
approved i
wastien
{i
i
SECTION VII SPECIAL PROTECTION INFORMATION
}
RESPIRATORY PROTECTION RESPIRATORY
approved Specify
respirator - See OSHA Part 1910 -
SSPPEEC CIIAAL L
LOCAL EXHAUST
VENTILATION
PROTECTIVE GLOVES
General TLV MECHANICAL
Control with mechanical
dust collection equipment to within TLV
| EYE PROTECTION
OTHER
OTHER PROTECTIVE EQUIPMENT Use respiratory equipment per OSHA Part
;
1910
12/7/71
Ie
|
E
- 12/7/71
SECTION IN
PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
SPECIAL RECAUTIONS
Maintain
Maintain
good
housekeeping
housekeeping
i
practices
practices
OTHER PRECAUTIONS Vacuum clean waste and place in closed containers
SEE CAUTION LABEL ON BAG
1.
a
-
ae
tho
ose
4
09 0637
RULES AND REGULATIONS
CHRYSOTILE ASBESTOS
amended Bubelance Aa
follows follows
Table 0-3 reads
TAS --MINERAL Dvare
as
Mppsf
Mg
be used to meet the exposure limita prescribed in paragraph s of this section Where such engineering methods are not feasible or do not otherwise reduce the concentrations below those prescribed in
comply with the requirements of these subparagrapha relating to the operations involved The requirements of this paragraph are in addition to those prescribed in paragraph b of this section
>
Milica
Crystalline
narta trespirable
this section Quartz total dust
paragraph a of this section respiratory protective devices shall be provided and used in accordance with paragraph c of
c 1 When posure to asbestos
the dust
Umits of exprescribed in
2 All hand- or operated tools which produce asbestos dust such as but not limited to saws scorers abrasive wheels and drills shall be provided with local exhaust ventilation and dust collectors in accordance with the American
Cristobalita Use bh the value calciated from the
paragraph a of ceeded and when
this section are exengineering controls
National Standard Fundamentals Governing the Design and Operation of Local
count of mass formulas for
required by paragraph b of this section Exhaust Systems ANSI Z9.2
1971
QUASTE Tridymita Um 14 the value
calentated from the for
maine for quarts Amorphous including natural
diatomaceous diatomaceous earth
Bilicata flera than talne lica Mica
Rompeione
1
erys
are not feasible or do not otherwise re-
duce the concentration of asbestos dust
below those prescribed in paragraph s
shall re of this section the employer
80mg quire the use of respiratory protective de-
8101
vices The selection of respiratory
protective devices shall be limited to
those specified in the remaining sub-
paragraphs of this paragraph c
3 Employees exposed to the spraying
of asbestos or the demolition of pipes structures or equipment covered or insulated with asbestos shall be provided with respiratory protective devices in accordance with paragraph 4 of this section
e Asbestos cement mortar coatings
Tale
Portland ment
Graphita dat Graphita
Graphita natural
respirable respirable
John John 6% B101
For more than % 810
.
eee eaten
1 The employer shall require that each employee test his respiratory protective device before each use in order
to insure a proper fit according to the
manufacturer's instructions The em-
grout and plaster shall be mixed in closed bags or other containers
f Asbestos waste and collected and disposed of
or other containers
scrap shall be in sealed bags
ployer shall further provide for effective
g All cleanup of asbestos dust and
Inert or Nuisance Dust Raspirable traction Total dust lee 28
training or supervision of employees in the testing of respiratory protective devices for fit before their use
blowing shall be cleaners No dry formed
performed by sweeping shall
vacuum
be per-
NOTE Conversion factors-
ppcx ppcx
million particles particles per c.c.
per
cuble
mater
2 For an atmosphere containing not more than 25 fibers per milliliter greater than 5 microns in length over an hour
Millions of particles per cuble foot of air based on
plager surples counted by light techn^"catechn^"ca The percentage of crystalline silica in the formula
is the amount determined from borne samples ex-
the the rept in
instances in which other methods have been
shown to be appucable
As
determined by the membrane Alter method at
xpha xpha 430 '
xpha contrast magnification Both concentration and percent quarts quarts for the applt-
cation of this imit are to be determined from the fraction
puting a selector with the following characteristics
average or more than 50 fibers per milliliter over any period of 15 minutes & reusable or single filter type respirator operating with negative pressure
during the inhalation phase of breathing approved by the US Bureau of Mines under the provisions of 30 CFR Part 14
Bureau of Mines Schedule 21B or a valveless respirator providing equivalent protection shall be used
Aerodynamic diameter unit density aphare
Percent pang selector
3 For an atmosphere containing not more than 250 fibers per millilter greater than 5 microns in length over an hour
50 50
average or more than 500 ^...bers per milliliter over any period of 15 minutes a powered filter positive pressure res-
pirator approved by the US Bureau of Mines under the provisions of 30 CFR
The raments under this note refer to the use of as ABC Latroment If the respirable fraction of coal dast is determined with aM MRE the figure corresponding
to that of 2.4 Mg Min the table for coal dust 4.8 Mg ,
2. A new 1910.93a is added to Part
1910. The new 1910.93a reads a.s
follows
1910.93
Asbestos dust
a The hour weighted average airborne concentration of asbestos dust to which employees are exposed shall not exceed 5 fibers per millikter greater than 5 microns in length as determined by the membrance filter method at 400-450x magnification 4 millimeter objective phase contrast illumination Concentrations above 6 fibers per milliliter but not to exceed 10 fibers per milliliter may be permitted
up to a total of 15 minutes in an hour for
up to 5 hours in an hour day
b Engineering methods such as but not limited to enclosure vacuum sweeping and local exhaust ventilation shall
Part 14 Bureau of Mines Schedule 21B shall be used
4 For an atmosphere containing
more than 250 fibers per milliliter
greater than 5 microns in length over
an hour average a type C positive pres-
sure supplied respirator approved by
Mines under the U.S. Bureau of
the pro-
visions of 30 CFR Part 12 Bureau of
Mines Schedule 19B shall be used
5 The employer shall establish a
respirator program in accordance with
the requirements of American National
Standard Practice for Respiratory Protection Z88.2-1969
8 The respirators provided each employee shall be properly inspected cleaned repaired and stored
d 1 When an employer has employees who are exposed to asbestos dust exceeding the limits prescribed in paragraph a of this section and the exposure results from the operations described in the remaining subparagraphssubparagraphs
of this paragraph d the employer shall
3. Section 1910.12 is amended by changing paragraph a in order to apply the emergency standard prescribed in the new 1910.93a which is published in this document to construction work which is subject to the Act The amendment is
necessary in light of the rule of regulatory construction set forth in 1910.5 As amended 1910.12 reads as follows
1910.12 Construction work
a Adoption and extension of es-
tablished safety and health standards
for construction The standards pre-
scribed by Part 1518 of this title and in
effect on April 28 1971 are adopted as
occupational safety or health standards
under section a of the Act and shall
apply according to the provisions
thereof to every employment and place of employment of every employee en-
gaged in construction work Each em-
ployer shall protect the employment and
places of employment of each of his
employees engaged in construction work
by complying with the appropriate
standards rescribed by this paragraph
2
The standards prescribed in
1518.55 of this title shall apply in the case of the exposure of any em-
ployee in construction work to airborne
asbestos dust
a e
Efective date These amendments become effective immediately upon
publication in the FEDERAL REGISTER 12-7-71
Sec 6 84 Stat 1596 29 U.S.C. 658
retary's Order No. 12-71 86 F.R. 8754
Sec-
Signed at Washington D.C. this 2d ,
day of December 1971
G. C. GUENTHER Assistant Secretary of Labor
PR Doc.71 1786D3oc.71 17863Filed 12
6 am71
a]
=
FEDERAL REGISTER VOL 36 NO TUESDAY DECEMBER 7 1971
nn
Oa FFA