Document a4zoBX5OgZoVRVqdg1G01Z8ea

"19) 9 CE [I an EP2811003 A1 (12) EUROPEAN PATENT APPLICATION published in accordance with Art. 153(4) EPC 43) DToait2e20pu4bicaBtuiolna:n 201450 (21) Application number: 12867129.4 51) mCao Taz Coo Tota SCOo9rK tse 19130 220625) Ccoo o fo2mmupm CO9K 1913422020 2 Dee atiliog SRR (86) PInotTerunaptaioOna2lnaRppAlDicSa2tion number: (87) WIntOer2na0t1i3on1a1l4p7u8bl0ic(a0t8i.o0n6n.u2m0b1e3rG:azete 2013132) (84) LGDeRAsiHTgRnaHBtUEedI5EC0oInGtSrHIacTCtiYLnIgGL2StTaOtLFesU:DLKVMEEGHESKFMITFNRLGNBG||(72)+ YInAhvNeinAtrIorTosa:skhaiyoshi BPDAeLsNiPgETnaRtOedRESxtSaEnsSoInSSKaiSsM:TR (30) ror: 03022012 0p012021840 (71) ANppGlicCaonrtsp:oration CRehhAiibnTaaIr2aO9s0h-Ni8o5r5k1ai(JsP)u. + CWhAiEbDaA2T0a.k5e5o1 (UP) chiarsahi Chiba 290-8551 (JP) Chiyoda-ku + TITooNkkGyypooe11t0r00o0-c08h01e00m45ic(OaJPPl)).Corporation (74) Representative: Thurston, Joanna et al LWMiootnhrdeoornsLS&oEnR1doo2gne4r0Rsi(vL6eL8rPs)ide (54) DLIIQSUPILDACYREYLSETMAELNCTOMPOUND,LIQUID CRYSTAL COMPOASNDILITQUIIDCORYNST,AL o(6n7)SaAinsat leatusoparnoevbiodf cahfaaruactcerriscioascuocmshpaossi iPhmumamxaimmaprteamtperreahrles nofeamnaemhaats,paassem vos.w CIsooyv.ort, a aageoseppiontearemslasnce,aaiagvhohdoeaecpbilcayyn.to 2UrlitnecyGaaanlcdomanpilhioSnaavwy loossuolsleopaolvrdeen. eedewnin lGeoaress aealaSrarpee nneoagla.e vfoelaagndehokdfionr.gra, alargeconastat,a ng sens ramhasopthoasne asnad cldoanyatsalpeccnompcoosmopnoutnhadtrhaausnga aspleglotaceomcpiocunad hsaviangkaoosomapraytlclomvpos4necanstoencsdonyda negmponeghntianmd muay ctoenmapneasstpeocri8cromgpouendcakv. pwaabsopy wiaghosocomopetia on. T <38 = ~ a w oor -- i iner entra e enn sos euis or Ee 0CO [0002] Ina liquid SeyEcs1)tL ot soe nnne e 0o es nritsoorness crystal display device, a classification based on an operating mode for liquid crystals includes a 0 nSsE lnTus nn L,ms eaSeosserte siegsofnnspnpnesi(A7caemteftoonnSaeesei0si)ot [ro [Emam Jommomomsamons .B m SE raam mE eT Ara vrT isa 1ea eorsee hysssaunted oTmTe C rs Eoe iiSrsr Tmmh aerrgSeiryn [0003] The devices include a liquid crystal composition having suitable characteristics. The liquid crystal composition .[[75os sSCmornmaanomeenns mae v5o | o Cre e s [ss 1 Large specific resistance Large voltage holding ratio and large contrast ratio " iargon cr RGR 0Co ydot ra tpa ss A Bt mas er, [0004] An oplical anisotropy of the composition relates 10 a conlrast ratio in the device. A product (an x d) of the . ep 2011 003 A1 A radia taingecrlooky MageAdesA tivaatpgacposI in aodA eNsOioatoA n restos 5 cmeotgmptgostsoiaeotnnaeNoasmioaeatrrsgadsodaesocleoenioeesmiaenm,ha osemoopoatoearnstohaovnsgalitathoBsteoeuassnaDn WtSd0oegesm opemrdeodaa aohvmeepecnormsepaoolsilhoyn htohadtavevipasesvs6eanvansnslhaoornheesdlrotinc1He.a:ksSuoicohehaoHoohfohfsooirrepaarvodlooafdmootpreaeandtsaoGeio,inSraamnye 0 nates yaplo, kdsve ovon and on. Fo10m0ap05om]niaAoncoonmapmorsyiitiaonotshaivovienig ea eposoieE tivuecdGieleucatrailceannsiasrodtkrooppyisis uoesenddfroore ranonAAMsdeSoveivceenahnaivinggttohoeegTsNSmomodte.oeBOnyTt0h0e 15 omordee.s oExarn slohe. ks yl oposton avn 1 PSE di atopy we acne PanHor chao Lst Fanti [0006] PatentliteratureNo. 1: JP 2007-50348A7. 5 ln. Sgr esp [0007] A desirable AM ns E ovens ov lr asE Tm, aera Sages oa device has characteristics such as a wide temperature range in which a device can be used, Sonoeeion YesaosNaidsaapovtatamaenadnaarb eagomnasmcoemicnth.easorsloagyspechresHanon Ohoi drove = Summary of monton ve = [0ak00n8e]ilmOpnaeltoof tshaenaiammcs okfe.thegrinsvenatioencris aaleiqmuidSaaciry.wstfamlTcmooSmpmossriteicopantsoaetmissstfyaianang ,abttmlelashtieonSet;aaofsbchhabrsoaocematearllisstHlicosrssmulch TAeivsanrdntgaitmsai.tsocbroaomnopoafasa7h0aasnatgisla,rteApltrotanotaioaymlas.1S0olyddllpdcsomtaicnoscmopoaopsyo,ranhh uSanasycdooampoovs. BO A inHS OR Sotto to Poem E1008h) TT romentonsonemsalutesasco mprstio ah hase] andea s aiasca nasapond GSeenmtovoemnhue pnososfccoommpoptaionnions tla )0s soca componet. nd caren Kcr # x3 x! . R! Fs 0] m 4 2 s oo D2)w n Sm EE E EEEe m r E e independently a single bond, ethylenoer carbonyloxy; X', X2, X and X* are independently hydrogenorfluorine; and m |g E y EE EFmE FC a E E C E C E E E C E EE E C E E Bi T rREEEEeeEE ErE mEE na m m m mmiET E e E h E E E T m-- oe en m e e m m e e p e e e m-- e a eeE E e E E s E E et--r e e a e a eRa ee nE--iae [0010] Anadvantageoftheinventionisaliquidcrystalcompositionsatisfyingatleastoneofcharacteristicssuchas. cpzon amaat AARONaE LCT a emes ee hes [0014] The invention includes the items described below. [0015] Item 1. A liquid crystal composition that hasa nematic phase and contains at least one compound selected x3 x! R1 Fs 1) m x4 x? Y R2. 71 R3 n srEEhEeR l W 2 on Ra smhRoArtu rtets ts re oo,se `wherein, R! is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carobroalknensyl having 2 to 12 carbons, and RZ On. on . FF Y . . we (O-(pron i) F . EP 2 811 003 Al FF , wrenCF 5 F 010 F F CF i 155 F . OO(rom 20 CF F =25 FFF . CF3 30 FF CF3 35 FF 40 i CF 45 CF3 * F 50 CF3 55 6 ((11--55)) (1-6) on(1-7) (1-8) (1-9) (1-10) (1-11) (1-12) : FF F " F FF " F F F . Rl Fa F (1-16) LOO F F om " FFF " F FF FF 10017) Item3. Theliquidcrystal composition accortdoiintegm 1,whereinthe first componeisnatt leastonecompound : [0019] item 5. The liquid crystal composition according to any one of items 1 lo 4, wherein the second component is. . . R? 3 @7 F . : Ep 2011003 A1 sO R2. OO 3 @12) F 5 T`[2w0hc2ear0er]ibno,ntsR,o2moafndakRT?ahanrue ivdnideype2sn1dlaen1tc2loymtaplhoksyoiltnhiaovninawgic1ctheot1r2acoasrfbaoannse,o1a,flwkrohxaeyrghaeevihng p1staao cc1oe2ndcacbroybmopfnosun,eianl.tkenylahatviongn2eto Compound Sled rom he grofoampuounpd preset formula 2-1) secorang oem 5 Compound om ha fou 10021] Item 7. The liquid crystal ocofGmpaosmiptiooun NacrcoerpdrisnagTteoditoeymo1, lwher2ei-n3t)he6s5ec0ongd coomepon.ent is at least one. la1e0a0ad2t2n]oneeiccteoommpm8.opuTnhusesslilequliededccry5s1t70amlmc0o3mporusitpoionofaGccocooBrmdoiupngnestno piatresmpa1rr, iweehedsrebiyynothmeaasec(on7(d2)1caocamscprosndrenangntgois0ea fmmo.im xtaoudfraaett 5000i21056027e)3%] bIryHtaawegmmee9.i10,.T3hTa%elboisyquhioadocknrRyhsytas1lt0lc2ao5mo%pWmobpseiyotgswitoofinoahnhccacornkdediasnrgatnoykaantoyaoncnneoyomsofpneioectsooetnfnmfs.smo1s1m0.8o,1 wn(h0ee,rieienntharereraacnotofgritenhoeiofnf5igrs%tacoeomypswonooennhet Compound Slced ome Group of cpu eeSSaIad oy or 38.8 Id Component: PB R4 x5 Z2 Y1 3) hTearcoanc,heRreisyaonel. 1ha4vminegn1i10o12nc.toiootn-,1pankoeenyihaavnisng.1J10 1r2 t1o4npsraoyfearlsk,er 5h-a0ving 2110412hcaanrgtoenrs.ng133C's 40 ZoCx3aonaer-r2ss,5o-dniylX, taetnrdah8ydraospyrmadn-o2p,oSd-dainylloyr on en: pyrimidine-2, 5-diyl: ZY21is afsaincgele,baonrdi, ndifluoromet mao: and 1 hyleneoxy, ethylene 1or C1o6m0p25ouned sml11e. dToomb(dhe fcoyusstlocfocmopmopsioounnaTcieedrinognfo bfyoom r10,lwh(r3s.n0trhe tnh (c3o26m3pan a ast one r{Ya @1) " = rR)) (33) . (YO OYe : F i . ROO oC . (36) . F ~O-O%F SF on w OCF; " F " R (48) F Q " F a " 0 . (OCJ R* (3-10) O04 a en - F F . "O-O-Oepzoraust on wO-O-Cor 13) g : wc O-O-Cor (3-14) w F Fr = R F oF (3-15) " FoF 5 CFs FoF r ve & ce OF ve " : 0 R* F F F (3-20) xo x7 F x5 x10 \e Y xe Y F x x12 x10 \e Y xe wo mH x1 x8 FF Xx ew x12 10 Y i" x8 x8 x? x7 ri 0, F F x8 0 O v1 x10 x8 = xe (3-24) LT tors To } EP 2811003 A1 `0c0o2m6p)ountdesmele12c.tedThfeomligtuhide gcrystraolfcocoommpuposoiulpnodnsarcecporredsienngtetdo blyefmor1m0u,lwah(e3r-e1i4n) atchceorthciirndgcoomtpeomne1n1.t i at least one `1c00o2m7p)ountdesmele1c3t.edThfeomliqtuhide gcrryosutpalofcocmopmopsoiuinodnsarcecporredsienngtetdo beymfo1r0m, awh(e3r-e1i5n) atchceortdhirndgctoomtpoene1n1.t i at least one. 5 [0028] Hem 14. The liquid crystal composiion accordingto lem 10, wherein the third component is at least one `compound selected fom the group of compounds represented by formula (3-17) according to te 11. `0c0o2m8p)ountdesmele1c5.tedThfeomlithue gcrryosutpalofcocmopmopsoiulnodnsarcecporredsienngtetdo blyefmor1m0u,lwah(e3r-e2i1n) atchceorthdiirndgctoomtpoene1n1.t i at least one 10. c0o0m3p0)ountdosmele1c6.tedThferolm ithue gcrryosutpalofcocmopmopsoiulnodnsarcecporredsienngtetdo blyefmor1m0u,lwah(e3r-e2i2n) atchceorthdiirndgctoomfpeomne1n1.t i at least one `1c0o0m31p)onentteimsn17.thTehreanlgieqouifd 5cr%ysbtyalweciomgphots0iti6o5n%acbcyowrediignhgttboaasneyd oonneth oftloteamlswe1i0ghttoo1f6t,hewhueiredincraysatatlocoomfpotshiettihoinr.d o10fa032n)emattiecmp1h8a.sTe his 7li0qu"iCd corryhsitgahlecro,mapnosoipttiiocnalaacnciosrdaitnogpy (a2n5yCo)naetoafwlaevemlse1ng1t0h17o,f5w8he9reniannoammeatexrismuism0.t0e7mpoerrmaotruer.e #5 a1n0d03a3d]ieletcetmric19.anAisoqluriodpycr(y2s5talC)dialspalafyrdeeqvuiecnecyinoclf1udking Htshe2zqouridmocrrey.stal composiion according to any one of tems 1 oa, 10034) tom 20. The liquid crystal splay device accorcing oem 19, wherein an operating moidntehe liquid crystal mdiosdpleayindetvheicleiqiusidacTryNstmaolddei,spaanyEdeCvBicmeodise,ananacOtiCveBmmaadrex,maondeP.S mode, a PSA mode or an FPA mode, and a ving 10035) 10036] Tehmeti.nveUnsteioonlftuhretlhieqruiidnccrlyusdteasl tchoempfootloiwoinngaclceomrsd:in(g1l)otahneycoonmepcofsitteomns,11fu0rt1h8ericnoanltaiiqnuinigdcarnyospttiacalldldyiisaccptaeiyv.e `compound; (2) the composilon, uriher containing an additive suchasan antixidant, an ulraviole ight absorber, an 25 a(4n)taidoeaviinceg aignecnltu,dianpgotlhyemecroimzpaobslieiocno,mapnodunhdaanvdaiaTnpNogl,ymEeCrBiz,atOiCoBn,aIlPrS,;FF(3S)aornPASMAdemvoidcee;in5)claudirnagntshmeiscsoimvpeosdietvoirc:e including the composition: (6) useofthe compositionas a composition having the nemaic phase; and (7) use as an optical 10037) aTchteivecocmopmopsoistiitoinonobfytaheddiinnvegnttihoenopwiilcablleyeaxcptliavienceodmnpotuhnedortdoetrhedecsocmrpiobseitdiobne.low. First, a constlutn of the `component compounds i the composilwoinlbe explained. Second, main characterisotfitchsecomponentcompound anda main efectof the compound on the composition wil beexplained. Thid, a combionfcaomtpoineontns in the `composition, a preferred raotfthoe component compounds and the basi thereofwil be explained. Fourth, a preferred `embodimenthtecomponentcompounds wilbe explained. Fifth, specific examples of thecomponentcompounds will btheeshcoowmnp.onSeixntth,caonmpadoduinidvse twhialtbmoaeyxpbleaimniexde.dwLiatsh,thaecnoampppiocsatiotniwoofintlhbeeecxopmlpaoisnietdo.nSweivlenbteh,exmplaeinedt.fohrsynothedsizisng 25 t[h0e03i8n]ventFiirosnti,sthcelacsosnisftiietdutnitoon cofomthpeosciotmpiooAnneanntdccoommppoousnidtsoninB.theCocmopmopsoistiioonAnwimlabyefeuxtphlearinceodn.taTihneacnoympootsheirtiuoniodf c(1r)y,stcaolmcpoomupnoudn(d2,)tahnedadcdoitmipvoe,uanndi(m3p)u.ri"tAynoyrotthheirkleiqiunidadcdriysttiaoln cootmhpeoluinqudi"dcrmyesatnalscaomlipqouiudncdryssetlaelccteodmpfrooumncdodmipfoeruenndt 4 fofofmutchoermpaoudndj(1)tu,hceocshmaprtaocutinerdins(t2i)gcas.ndTcheoamdpdoituinvde (i3). nSucchhaelocpotuimcpadolulyneadctiissvemecodmpwoiutnhdt,hethceomapnosiictxioindfartnht,eheutpruarvpiolseet iignhctluadbessorabecro,mpadoyuen,dtmhiexaendinoaaripnrgocaegsesns,ucthheapsolpyrmeeprairzaatbiloen cofomthpeocuonmdpaonndentthecpoomlpyomeurnidzsa.tiEonveinniailnotrh.eTchaeseimwphueirye the compound is liquid crystalline, the compound i classified as the impuriy herein 4 (130).03A8l)ermCoemsposseintiiaonl"8mceonasnissttshtestsheenctoamlpyoosfictoiomnpmoaunydcsonstealectthedafdrdoimticvoemapnodutnhdei(1m)p,ucroym,pobuutnddoe(2s)naontdcocnotmaipnouannyd plioqsutidiocnryAstahlasc.omCopmopuonsditdiiofenrBenitsfpormefetrhreecdotmopcooumnpdoss.itCioomnpoAsiintviioenwBofhacsoastsmreadlulcetrionnu.mbCeormopofsictoimopnanAenistsprtehfaenrrceodmt-o `composition 8 in view of possibilty of further adjusting physical properties by mixinganyother uid crystal compound. c1h0a0r4a0c)teriSsetciocnsdo,f tthhee cmoamipnoscihtaironacwtilerbieseotxfpitlchasienecdo.mpTohneenmtaicnomcphoaurnadcstaenrdistohtfeihmcaesincoemffpeoctnsenf!thceomcpoomupndosuanrdoesnsutmh.e marized in Table 2 on the basis of advantageous effects of the invention. In Table 2, @ symbol L stands for large" or "high." a symbol M stands for "medium." and a symbol S stands or "smal" or "low The symbols, M andSrepresent a cassifcation based on a quatative comparison among the component compounds, and 0 (zero) means "a value is neary zero" " : [Vom|S mrtpCos mpeound_(i2)|| Csormpuounsid (3]) [ [or s|| t W+n|m s || e|s m] wr i | a re npn on am [0041] Upon mixing the component compounds with the composition, the main effectsof the component compounds 5 perature and decreases the viscosity. Compound (3) increases the maximum temperature and increases the dielectric [0042] Third, the combinationofcomponents in thecomposition, the preferred ratio of the componentcompounds and re n ee p rr r er e21 third component. The preferred combination of the components in the composition includes the combination of the first a oem eonrmse cseomees rss, [0043] A preferred ratio ofthe first componentis about 3% by weight or more for increasing the dielectric anisotropy, [0044] A preferred ratioofthe second component is about 25% byweightor more for increasing the maximum tem ee or e rearet r o 3 35% byweight to about 75% by weight. bFEeedeie SE Us , Ts 35 [0046] Fourth, the preferred embofo thed compi onem ntcoe mpoun ndst will be explained. R' and R* are independently EEEe a esNramTeky `having 1to 12 carbons for increasing the stabilittoy ultravioletlightor the stability to heat. Rand R?are independently [0047] Preferred alkylis methyl, ethyl, propyl, butyl, pentyl, hexyl, hepotroyctyll. Furtherpreferredalkylisethyl, propyl, [0048] Preferred aliksmoetxhoxyy, ethoxy, ,propoxy, butoxy, pentyloxy, hexyorlheoptyxloxyy. Further preferred alkoxy 10049] Preferred alkenyl is vinyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3 `pentenyl, 4-pentenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl or 5-hexenyl. Further preferred alkenyl is vinyl, 1- ee tn ee ne hexenyl, 3-pentenyl, and 3-hexenyl for decreasing the viscosity. Cis is preferred in the alkenyl such as 2-butenyl, 2m TE iB e eetns attmeyL r merlm y e ns teaoy nosoe r ean) [0051] Alkyldoesnot includecyclic alkyl. Alkoxy does not includecyclic alkoxy. Alkenyl does not includecyclic alkenyl. [0052] RiAnangd ring B are independently 1.4-cyclohexylene, 1.4-phenylene, 2-fluoro-1.4-phenylene, 3-fluoro-1,4- " P2811 003 At 1SniennyglnnAogsrBG2sr15, &.cfy4opcrhera-yeonhr1dee,ceTrewaonsionfigaroervaiynscfoisnsgy,Aahnnc &nipsha2oyria3nmaoyrbiencerneatsiiangl fheeorpeantl.anProottye.a R1.3I5N0GxaC1-42-5y.cdnye,txryaahnyeo.p1yraphne2n.y5ie-ndsy2|fuoofrpoy-1i&npeh2a5nd,.3Tcurooof-a1rphieannyinegn,G3.w5hdefnlupciso-2,1 o6srh4nymiaeyneb,s 5 eInncrteaaslinagihfeiraenptc.laPrnesfoerleody1, a0nd131..4c5yc1on4eyisenhfoar nrrsaaysinageannseinsmg ancuiarcaaten,s.14shenyans P[0u05t3]as2121isa sisgilngolebobno,daotryldencoreoarscianrgbtohnyivaancyosTlwyo, oafndarcrarabyo2n1yownheonr incr2eaosrin3gmtahye bmoadxeintmalempfearbeen, 0 i2o2o'nsicaalsoirngierboond., dPrieuloarroemdat2t2y1asn.alceye, abtohnloonr doreecaasribnogxnye.viTswcoosotyf.aarnidraArlyc2omwehtenanpeion2.y foot c4remaasyinbgo ne delete ansotopy 10054] X', X2, X3, X4, X5, XE, X7, XB, X, X19, X'! and X'2 are independently hydroorfgluoerinne. Preferred X', X2, 6 nX[30e,05Xv54i],coXs5tY,yX.i6, fXTu,oXr8i,,XOc,hXi1r9i,nX,1f1uocrrX'o2imseftlhuoorniynoe fforuionrcrcemaseitngy.therdiaelerctericYa'nissoltruonpye, afnorddheycdrreoagseinngfotredevcirceoasstiyn.g e[m0p0e5r6]aturTeh.en, mf 1.2 or 3. Prefered m 1 or decreasing h vio, and 2 or 3 for rsasing te maximum 20 stabi to uravolt ight o heat. [0057] Further, ni1s, 203r. Preferred nis 1 fordecreasing the viscosiatnyd,3forinctr he meaxa imus mtei mpernatug re. [0058] Further, pis 1, 2,3 or 4. Preferredpis 2for increasing the maximum temperature, and 3 for increasing the b[1e02l0co5w9,]a_RrSFibafotlrho,kaytkhnleoshsnpaevcihinafgvici1ne1gx0a1m1p12lec1sa2rbcofaorntbshoenocsro.amlpRko7ennayenlndhtaRvciaongrmp2no1dup1ne2cwdnaidsrlebbonentsys,hoaawnni.dghRItn citshheanpnrpeaeferlrdreehdnactvoymipao1lu1yndh12adevcsiacgrrbi1obne0sd or straight-chain alkenyl having 2 to 12 carbons. RY is independently straight-chain alkyl having 1 to 12 carbons. 25 iP[n0rc0ll6u0ad]eesscPrcoeomfmpeproroueundndcd(o12m6)p.o1nu)lnaodntde(1s)cocimnocpmlopuudoneusdncd(o1(m12p-7o11u1.)ndtPoa(1rc-to1i-m1up)aortuyoncdroe(m2fp1eo3.ru1ns)d.c(oF1m-up1-o1eu)n.drFe(u1er)trhneecrdcpcreeosfmerpcrooemdupncoou(mn2p)docu(n1u6de-(1s1.) 5 2pp-ro1e1fu)e,nre2ddc)ocnmocplmoupudoenusdncd(o2(-m35p)-1oc)u,nlcdoe(m2sp1-oc1u)on,mdpP(o2ru-n7od-f(13c5c.o1om)pm.opcuoonmdupn(o2ud-n1(d031i(n)6c-ad1ens)d,ccocomompmpopouounundndd32-311--1-4)-11t,)oc,oPcmaopmropuiontudny(d2p(43o--f11r5,r1)e,Fdurcctoohmem-r B3-o1u4n1d),(31c6o.m1p).oucnodmp(o3u5-n1d)(,3c21o-m1p)ouanndd (c3o.m2p1o1u)nadnd(3c22o.m1p).ouPnda(r3.c22s1preered compound 3) inca compound # OreFn a F FF redyer, F v 1 (1-3-1) P2811 003 41 FF , we -(gron F "= O-O-FCreF n " F F . e-em F - FFF royHom F FF " redHH) . F red{hom " F wer (1-5-1) re (74) (1-8-1) (1-101) (1-111) (1-12-1) : EP 2 811 003 Al CF3 5 FF 10 CF3 F "15 FF F CF3 "20 F FF 25 . CF3 30 oOF F 35 CF " FFF 40 CF 45 50 ROO F QeF CF FF 55 6 .17 (1-13-1) (1-14-1) (1-15-1) (1-16-1) em(1-17-1) (1-18-1) ee(1-19-1) (2-1-1) Ep 2811003 a1 Rw RL) we Ry)coo(yre PM (2-2-1) (2-3-1) (2-4-1) . CoO (2-7-1) F - RAO (281) F * R'7.Oreo pLHse (2-10-1) R OOOn @-12-1) Ep 281100a31 F O 7 OOO R rd po RLOF RL) RL {HHYa F v " Fe F - " FF (OO --~ ocr, " 9. OO F F 0 v wo ey (3-1-1) 32-1) (3-3-1) (34-1) 37-1) 6 Ep200103 141 F } woe F P rH)-oFf v F "OO - F FF wO-O-(r F u F OE F F - F } OE - OCF F v (310-1) 311-1) (313-1) (3-14-1) (3-151) (3-161) R?: ` 0 i : Fe F F F F FF (3-18-1) . R F F RS g F F F Oo F F Fc - R EF o F F " = OOCE: Ai RE > F Fc A) . (3-21-1) (3-21-2) (3-21-3) (3-22-1) Ep2011 00431 CeO ona F F Fe F 1 7 \ 20 F h RY FF Fe F FF F v (323-1) I" 2 d - F Fe Fo oF (3-241) CC[p0o0im6cp1ao]luynaSdciixatvnhe,d catheopadadmimteirvpeahaothtanaot nmulaiyonbermhiTxahed apwtivtcihalathyevactoeimvperocsoitmtip.oonuwn1idlhbe.miexxapeldiaiinctedah. mhSenuccghoamagnpenaotds.diitipfveerlivnecmlepudreosasatehee Br11r0 rcompohuned (5 A rheftetd oatoisiogoptiacoalkaocneecoBmapoiunnds schootta 5 wATegOaess.pAornvds Prfaredratars nn 1303 f abou D1. by weight 0 abot 2%by wet. HHCyC CHa HC CH, " Q 5 @1 Ceti 0 - [ o \oA)oO0pio "482 CHy HOOOneTM N HC 2 ep2om ansar re . CaHy o.C- eti (4-4) CH 0 Cott " F on 9) CeHis CHs . Fo[0062] The antioxidant is mixed with peA the composition for the purpose of preventing a decrease in specific resistance (CHs)s CHa OH (5) (CHs)s . [0063] Preferred examples of the antioxidant include compound (5) where ris an integer from 1 to 9. In compound ee FD oee be mt epose t ne oI rh es a vA etoe r oleOOo BaoL nronmai aA Bmommratestaasins [0064] Preferred examples of the ultraviolet ight absorber include a benzophenone derivative, a benzoate derivative ie aro Looe o e so plon t papnt er t savs e ches co toon 1, [0065] A dichroic dye such as an azo dye or an anthraquinodynee is mixed with the composition to be adapted for a e D rD a e reteeT gno vs At enpaneo maveSeteontAE rSeO eht mons earag,ien SfPoS coonanApitornRoerpe.eAopaynoeentpthtoy esSeoepsuSlpka pc.ei ie aepos nremtepL e s epa StoO 45 device havinag guest host (GH) mode. A preferred ratio of the dye is in the rangeof about 0.01%byweightto about oor eee rOaDs Ae sR emi Sh Sel (registered trademark; BASF) or Darocure 1173 (registered trademark; BASF), each being the photopolymerization L ee S e amSI e Le e E SA s E)O OE Ne TA CTeooE oerrmt e ecsS oSmA anissEr yim sncSsAine oarrToess s Cr Gaoa enmogS tent snens etm msrnne [0068] Any compounds whose synthetic methods are not described above can be prepared according to the methods. I fi m or mers eStCs)CSnTTn rTeesetorerroE ) sesarOn inrh eoka eySenn rei sSreeopbe [0069] Last,theapploifthceca omptosiitioonwn illbeexplained.Thecompositoiftohne invention mainly hasa minimum PR pa tAotT os ssere Tee ee esgnpoAneTp Ea erSeploAo ensA AbA rsreoenrrosss [0070] The composition can be used for the AM device. The composition can also be used for a PM device. The eOOe T T c0aTT1m)nepTrb hee nscrropsesome aatvcpns eerrireirse sndi dareaascrn coTne ,tga TeoTnhnantever bsaedoenednonh n eeeenaneeniss es rmstesienPooerergmiesceieiynoerni,t)1s1 45 measurement, according lo an extrapolation method: (extrapolated value) = {(measured value of a sample for meas- urement) - 0. 85 x (measured value of base liquid crystals)/} 0.15. When a smectic phase (or crystals) precipitated at Tr arate (10% by weight: 90%byweight), (5% by weight: 95% by weight) and (1%by weight: 99%byweight). Values of a L[Nm G ener a Sl iy Essays [0072] Components of the base liquid crystals were as described below. Aratio of each component is expressed in CoH ~ oN 24% u pm p soeoanrOs o nn--eoCnr O-nnrooe nneox [0073] Characteristics were measured according to the methods described below. Moosftthe methods are applied r B E E SEE r e na [0074] Maximum temperature of a nematic phase (NI; C): A sample was placed on a hot plate in a melting point i EI ErneN a e e E [0076] Viscosity (bulk viscosity; n; measured at 20C; mPa-s): A cone-plate (E type) rotational viscometer was. F |E EB B e BB E a E E e Er a E E s E iw E y e e r R T E a vn ----rn [0079] Dielectric anisotropy (As; measured at 25C): A sample was put in a TN device in which a distance (cell gap) E EE ER SEEErEEe EE RE e RE rees [0080] Threshold voltage (Vth; measured at 25C; V): An LCD-5100 luminance meter madebyOtsuka Electronics i Ep 2011 003 41 ot1o60m08%1e)annVsoiilmtt,aagaennenao.dAiGtnovgterrcsatehioo(HcvhRoS2;5t) mbaaoangvwsoeelrdaegsdweaoattg205a%s;ubb1a:sasATlteHsade,wvaisceusicomfoorlrmesa.suAreamernet1awaas pptolihcee 5 Gaoyvep,laenddiaonnenededveovanwdis sdoeovnsiwnes chlarwgeed.laAtdeacbayliongavdehgee,vaAspMssevsols(81067TRmTlolsseccaonndss wiShVa) BTisghaspmeeadnvwoimheoeutr,daayx.rAevaotAagesehonldvalool8e uprerardea onsfa1rzaaotAlgoaxisein a105.ni ce vas elemined rea 10 d[6i0om8n2e,]natnViolmha,ngaenndholoddivtnignscrawetaios(VcsHhaRaa.25d:)wmibenoaawsuernneduaovt 6ga0csuru0aTlSA:EdTeehssdewe.avseASupmuisciersofmvoerottemaresga.ssu(Ar0eammerinctreohsveacadoasnpdpuslal1 5he1a) SLeaspapeic o1uhtTeHrdeavrdesaeanAhedevbice waeavsoRcnahgasrgce.uAed3e30c.8ahyoorlnagse1was2muunrycfofa167emllsaesamn.dsAwriena 15. 5a10s0v83a]ndasVhoalotiaongoneuhrtoaldicianaygh.arAtvaoodVteHaviRgc.se3h;womaseladasdauitrtoee3d2wi6p6e:rcrenatavgSeetoafgi1hy6.soAALToN1dtevi5cg.e tussd ovfamteessdubeynmensshd 8 eimsirdaeaatgweinn lth.t farn2d0amcoilngia,pwAasK3tc5o2m2e6rwse.s 4sler gwhaspriesosocrimeorcoutrheydaevpiceUSarHdSh0r0n(emadcsobey Ulsahgienwe)a,samnesssaudrseadntocr b15e7tmweielnssnceonvdscAacnoimphoskghonsoincg waasg2e0 cVHoRn.3eshal.arnegsessuanbiVE0Ri,aveecalyieng 2 A10v0o86nofVEolRp.e h8opledsienrarbaytoG0(V%HmR.o&em,eaasnudretdeatr2p0r-f1ra4nyA, 9T5N%Goefcmeori,o icha sample ws fc as tleadgnhs icnognaan.dIpn meessbtVhAiR6A0Cfdoerc5ay0i0nghuvesa,gandansnmtesaslede0fonr t16wemiessclonlc.yA mceomspsoesnigona = a(00u85)naRroespoVnsRe tihmoa;a amarsssuSredaatb205hoit;.ml AnLCD-5100 inane meter mabydOtsueka Elson Co. Liasn sedfoa wrhmieamsal rdaemTanNtdeAviGche rhcisnwas arhcaslo(gcoenGa4m9p),bA oenepwasoeane5r abs staa1 w5eis szS.AOsae mmiplcs eawass nardcasiinttahndgeadweasw8asGroardeiast.edRwitch That fowmavese(ct0iHoin, p5e,rp0a5riscaacyondo)twherdeov5pe, anodtahneaemvoeun.t Oof Ing 20 vnaensTmitued romuotun Fdnegvhiceowrasspmoanrdaroed0%Thvaamrasxmiimuamn,aoAruteofmgh(cxoeislspeocnodnsst)o 1a00p%ervioadnosfmmiaencneesadnedd fcohacnhgaenfgono1m0%60r%anasnmisamnicasnoc0to 0v%anvsamnisamnitcaencAe.rsApfoanlsiame (1 i3sksuemcoofnd) n3spaearoiiomda15nemeedara 55 f0a0lBliEm)e. Elastic constant (K; measured st 25: ) :HP4294A LCR Meer mde by YokogawaHowlPackrd Geoowaasssussuebosxetesasweasme2Dntm.iAcsoammpeAtwvaroasug.teian hhrzoantloanOlV1e0gn2t0 cswoams wahpapaonlnececo(lsanlags)ebcowoenn 40 C(HVaaynpwdeaorcbeuakineied pqnulJaaepatnvieoskoea)ng(sTw2h9e)rNeaRnmkdaaensuKaeoogrynoN2Se.g0ms1)r.eadnpvLda.a)glea7uonf5detaahsaecisdoofCs1y1al20cDdaeKpv3a3icwHear)neadonbvoaioankep(EpsltoeaDvseobttaaolgnse (1271158of)neNos.amKe2H2awnadybocoka.lAcunlsuaacohnsetaentv3omeadneveonaof hvealnesofcKa1r1 ianndaK3151n. Ga2 aond 25.519 on page S1a60m8p7l)e waSsponciiecde.ssAiDaCnvcooxgem1e0asVuirweadsstap2i5e; ocme:versso3l n1a6a5D1Osucppuedrieh1nel0etcsiooadensr,s1w0esimeernotfea 5 Roaapveoressseotranolc wcaasrecna)cu(edaflomoIchoenfsoilaotwiong ecqua.tor (pec restance) = (otage) (oHEe capacy n[0i05h8 LHuoldcaClhpysail H(a:ndmoaasnts(rEexaodtnoBoevmanfonmpaapraactuer)e.upa mA1h9e,la(l50i8cdhInw2a0s00m,easruurseed sGco.o1r4i).n3gAgaep 50 GvaacsinnalfonoInrgisowaswesdgasrcalel a4nd3a 0psaondra moeormosacmopper(aaudt fnomre2:hrMs,AaJnd hsrno, gNaipn(2Co-rap7e)rabieotnw,eeAn lap (Pia cladacing own ain heh alechageES TESS 35: B-2x (@- al x tame. ** e7003s839s]5e0Gn,a.sescpAhercocmaiaeetr.oggrAoacpshaiscpahanaoSlyrosils(:u2GmDC.B-.p11o4(t8ainGgnaislh)C3hr0soa.mmabtproleger0ai.h3moa3rd.eaibynmSd3ehidmkeadeezurCsor(2sp15o0r)autweiornGiewmaesstau2s6d0oCr = EP 2811003 A1 cJootmapnoeunadsa. sAtfatriotnharycphoasne,wnaasnkoelpatr)atm2a0d0ebyorA2geminnutTeesc,hntohleoogileasnncw.awsahseautseeddtofor28se0paCraattiaonraotfecoofm5poCnepnetr miinnoutth.e sAasmapmlpelerwecaosr.preApraerecdoirndearwcalsoCnRSeAsoClvuotmiaolno(p0a%bcymwaediegbhy,Shainmdahdezun|Cmoripcorroatliloenrtoorefnseeoqounalwas cneieeold. 5 cThoemrpeosuuntdisn.gchromatogram showed arelnton ie ofapeakand pak are corresponding to achofthecomponent c{o00l9u0m1ns mAsay aclhoebenvoeddiuftorinsgeptahrastaimnpglteh,eccohmrpoonnen,thceoxmaponuenadnsd: HPf-o1rt(h mnatyha3s0omb,ebusreed.0.T3hl2ommw,ifnimgicacpilkry 10 0R.e2s5toukmC)ormpaordaetiboyn AangdenBtP-T1e(cehnnlgag3e0sm,Ibn.orRc0.32 memn,giln3i0ck,nebsorse00..322m)mmaidme tbhyiSckGnEesnse0r.n2a5tuonma)lmPay.deLib.y mcaaypiatlsaonbecosluemdnfCoBPt1h-Mp5u0r-po0s2e5olfeanvgihdi5n0gma, boorvee0.r25ofmmpe,afksmoUfitchekncoemspsou0.n25dus.m) cde by Shimadzu Corporation 15 bC1e0al0mo9wa1.)tTohgAerrafmuaoictfoclririryqesuostipadlocncrdyossmtpatlocuaonmadpstoucan(ndsbtcehoendtenatueicmntbeededriunosftihnmegocaloemgp)sosoihftrtioohmnalimoaugyirabpcehyc.salaAclualcatotomedpoobfuytntcehse.pmaeWlthheaorndeaatsshedinecstachrpeiibgleardsy. 3co5l1um(onnse)desAccrciobreddianbgo.vea waetre(u%sbedy, waeciagthe)cotfotnheoequfciceyonfaeaccohmpofouthnedsuiwadsccaylautceodmpfooumndtshemaaytboe rheegaprdked 20 {d10e0s0dc9fr2i]inbtedoTnhbseeloiiwn.vTeanTbthlieeon3cwobiemlllpobowe:uneIdxnspTlaianbilCneeodm3p,ianrdacetotinaifvliegbuEyrxaawtimaopynloeoffs1Ea.xna4dm-pcElyxecasa.mhpelTxehyselnwieenvrieesnatdienossnc.riisAbnepodtreulsniitmnihgteesdsiybzmyebdotlhnesuaEmcxcabomrpdlnieensxg.t c10o.m2posyumnbdo.liAzerdatcoo(meprocunntdagcaet)eosfptohnedsqu tcheynuambecroofmphouendscosmpeoxupnrde.ssAedsyimbtorlms(o)fmweeaingshtapneyrcaennte(3lbayuwceriysgtahl 25 btaesreed,onVtahleuteostoflcwheairgahctoasfhteicqsuoifdireysctomlpcoosmiptoosntwoenr.eTshummuairdizceydsntl caosmtpopsirtion contain an imputy i addon Table 3 Method for Description of Compounds using Symbols R(Ag-Zy-Zy AR 9 Loftermial Group R-_ Symbol 4) Ring Stucture-A,-_ Symbol CCotta r non- x Collar 0C,Har ChCh Vmvon. i" CHHaCpeHyCHH=CyH: owvr ~> B CollarCHCH-C Hy mV 8) CFCH Ver CFACHC Har Veen & " 2)Right-terminalGroup-R' Symbol 2) "Car a " OCHane "on cHecH, v LCCHHEaCHC.HCeHCeH;r Wwnv -& ah C & srs) " Cum CHECHC Hy MVR check, vee a* aF CN w z ep 2011 003 A1 onium : ocs,onia 2; siyneod oe 2 "coo. & <3 (5 a 2 pnso -CH=CH- vTono . owto x: [Seman] Example 13-BB(F)B(F.F)-CF,3 Example 23-BB(F)B(F F)XB(F.F)-F x Los v=tos Oo { fk r ; F * Emp 1 [0093] . - . L000 SesmeERcr [wen[0%| [vweioeprew aanr||wni|] Eo TED 3-S8oB(RFFrIXBB(EFAFR)-EFAT[|e61s2n|| ha|| EBERT # comperaianghs [0094] Ni =76.T8c<-3C0;C; An= 0.127; Ac =6.7; Vth = 221 V; n = 8.6 mPa's. [ [vwia w mesne [|rw|s] joT[0edu0p9s5em]rdeidAtoelyidqauimdpcroaymstaat(l 5co-hmpomsdilteiomsnewatassfhooromrru,lpaCmteoodmtipnwiahriaecchsotmahesdcoocsmtpoonunnndoxrftahenofi.rsht cToermepxocnoepmnptooofsltrhoenniwnevepdnrtoioospnuweeadds nt . [[oaosssep[[aassrrooaa||5orre]] Ea ET SERENE |G5| 6)%| SBBPBEPAEERYE |522|15)% | SSBB FNBERIF -- eTyme urs [0096] NI=77Tc. <-21 0C ;AnC =0.; 127;Ac =5.6; Vth = 244V; n = 7.2 mPa's. 2 [0098] . seEmFncR [r|s3h%] seamerRcr [e|n| SEBBEBFACR |(H|3r%| [ [oomsae |[r w5e]] [sveor aan|we] s [[sseepalelawnse||nsrwel] " E[ E E sea ec en |t5] [sea[eorn|s5] SesrreEnT [60 " SHBBXBEFLF [z|orx| SHeBGERF |aa|v3y%| . S88PBEF NEFFYE|02|23)%| oRrBE AER | 6221 [0099] NI =80.6C; Tc <-20C; An = 0.108; As = 8.6; Vth = 2.08 V; n = 20.0 mPa-s. Example 3 [0100] (ssernn J[ooaorns |nion] : [oJ swssne|ew |[wm] . oE me le Tern [|wm] C mers TJaE e | . J f amesa es s las)) s ||) m me es n J[easo)ns s ||on) . (omesr ss[[moowunsn||on|n [mssi srn [aowrnns s||or|n - ( (m me a6e r m0||n r|| [sssmse[noom n|nonr \. uwemn [[m[ [J ssssrasrs esna ae|[[rm wemsm nmn [|||emoownnnnr]]]] * [0101] NI=82Tc. <-27 0C; AnC =0.; 115;A=z 9.1; Vth = 2.06V; =24.3 mPars. - l m ren e ea an s ||e] C ewR an |on . I C-- as Joa |e . Emr en fr ora |eon [[ssssseormf|pcoezamnn||eoornnn] " EP2811003A1 [0103] NI= 704C: T<2e 0C: An= 0.100; Ac = 7.7; ih = 191 Vin = 142 mPa. Exampl5o 5 og [ssaampaennes Ta[rwo[|ooanr]] [[T Svamse oa rs [ rrn [|o worr]] . [am Tews [or] SrRERS [e|oonv sE aaensa Jwon n |5) SEBERNSERT sSHeBFeBErRRSERIE |6219|5%| SSCERBFERBEEFFNNEEEERRIFT|| 6G2a2t1h)|| 5%% || [0108] NI=77.5C:Te<-20G; an=0.120: Ac = 105 Vin = 183Vi = 180 mars examples fot0g) = SsarEeeRsB |[(oamn||o]4h%| [[ seo mo[paae wne||rw]e] " f[ umesmalel||ewnee]] " [[assesoess llearso)||wwee]] [[savsosol[eearroosnn||woszen]| w seeBFRFE)RT [13e0) ||ra8n%|| SerrraEnE |ot|son%| " [ [ssmw weooiio roo n||noornn|| [swov|oezrn|oen = . 88 Te . Camp [0108] . J [[esSsmsaesrwmaraner5 [vzanr||noe]| 013 87.2204 1-500 Soommaarrnreersnn[[oaewrn|| ]| msmearrarnon [faewwn[|m=|] ow s e[[eei osnr[|m=)]| [w[ wpesmew fasy |=) Gwmsee {[ooww |aa)) [ wmmeer[[r oeon an ||a roenn [[sssssrrmorsrseanrnr [[eeann||e|| . [Eemaers[aeapnr|nt . J-- [0110] . " - [sosspmmaeernes[[eenn||o]i] [Swomserrener [[waewn[|oon|] [ T ms e e w Trw s ||owri]] moarr [Jeer || ooni]] [ [w ae w [l@eesr e ||ooir]] [ewJe es |roi] = EP 2811003 A1 (conte) E Searrernr E |ei|n| swer[onm |e| [SpHrBePmBeEenEsERE[|e6a2rn1[|9s5%x)| SaarRGERT |62|o)n| Ea CN [owe[e oo e [as] OMA) NI= Te<-820C1 ;An=20.11 8;4s=C7.2:Vh =227Vin = 15.0 mPa, Examples ic] V2BBBFF . [VeamesaPBRCr T|e1 r ||9 o%n]| [m[ s ya [[wertna [[wmonw]] Zswoerenr aon [een |on| . E [swo a [Corrm |n0] swesEnt [60 swemeERT |02|m 6%| serRrFIErRE |02| 26%| SBBPBE EERE |02|2 #%| ([09111134]) NTIhe6c6o7mpoCs;iiToon<s-i2n0ExCamapnle=s0.111301 3hcav=e8a5,laVrIgne=p2i23vidil=c2t3ic5 marPiaso.opy in comparison ith the com {puonshietronexaccecloerndtincghatroacCtoemripsatriactsive Example 1. Thereor, he laud crystal composton of the preset nvenlon has Industrial Applicabilly m19a1x1i5]numTehmepienrvaenutrionofcoannceammsicapqhausie.carlyoswamlicnoimmpuomsteomnpselsriantogfutahtrenasetmaolniepohfasceh,aarascmeailsvitsscossiutcyh, assaaibgeh 55 copativcaillalmigshltoapnyd,aaliagrghe sdialcbtii{c anhiesao,loopayu. aiadgestsplecciomrpeosissitoanncheaavianggaescuaasbilcboanlsatnacnetreghairgdhinsgtaatbeaislt wdoeovfithheacvhaairsanhcotgterrse.spoAnsqeuiimecr,ysltaarlgdeivspollaaygcevhiockeinigncrludinagalsauorcgheacocnotrmapsotsattoo,nailsoanpgplsieerdvitcoecHoenatndesoafnorAthM, n ep 2011 003 A1 anus cane ue or kd rt rotor, crys lisn a 0 ort, cams 1. cAoumpsoutndcrmepsosnieodn tbaytmhalsa nemava. I fhsatscomapndonceontnaann laesattoanneccomopouunndslleeaddffoom bhee ggroovup x3 x! " RA CFs 1) x4 m x2 2 = ef(w= e n e @) herein, isaly having 1112 carbons, aon hing 12 carbons alien ing 2 o 12ctor,xand 5 T Sire pan1icueonnsre 14Shonen, o e u 1 phon non. Site phoions 254 Iuoro-1,4-phenylene; Z'is independentlaysinglebond, ethory carl bane ylon xy;e X', X2, X3 an X*adre independently 55 2. Tomheetgroiupsot ammpposton acpcrorsdainnged0 anrm1 where teorrsmt amp1.o1neti aston compoundsoled hydrogen or fluorine; and m and n are independently 1, 2 or 3. js F rye 2 FF er zomonan r , RO rom 4 F 0 F F wren (15) 1s F FF . . . * F FFF w FF " FF > . - i EP 2 811 003 Al CF3 5 F 10 CF3 15 . CF3 F 20 FFF 25 CF F 30 Rr 335 F CFFs F 40 CF OOO "45 F FF CF3 "50 55 .36 (1-12) (1-13) (1-14) (1-15) ((11--1166)) (1-17) om(1-18) EP 2 811 003 Al FF C F3 (1-19) 5 FF FF wherein, R1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons. 10 3. The liquid crystal composition according to claim 1, wherein the first component is at least one compound selected from the group of compounds represented by formula (1-6) according to claim 2. 4. The liquid crystal composition according to claim 1, wherein the first component is at least one compound selected 15 from the group of compounds represented by formula (1-17) according to claim 2. 5. The liquid crystal composition according to any one of claims 1 to 4, wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-13): 20 R2 (2-1) 25 (2-2) 30 R2 35 R2 40 COO 3 (2-3) (2-4) (2-5) 45 (2-6) 50 R2 55 (2-7) ,37 EP 2 811 003 Al R2 5 1o0 R2A{ > <{ { ) { R? (2-8) (2-9) 15 20 25 OOO R22. 3 30 R2 F 3 (@21-122)) (2-13) 35 wherein, R2 and R3 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which at least one of hydrogen is replaced by fluorine. 6. The liquid crystal composition according to claim 1, wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) according to claim 5. 40 7. The liquid crystal composition according to claim 1, wherein the second component is at least one compound selected from the group of compounds represented by formula (2-13) according to claim 5. 8. The liquid crystal composition according to claim 1, wherein the second component is a mixture of at least one 45 compound selected from the group of compounds represented by formula (2-1) according to claim 5 and at least one compound selected from the group of compounds represented by formula (2-7) according to claim 5. 9. The liquid crystal composition according to any one of claims 1 to 8, wherein a ratio of the first component is in the range of 3% by weight to 25% by weight and a ratio of the second component is in the range of 25% by weight to 50 97% by weight, based on the total weight of the liquid crystal composition. 10. The liquid crystal composition according to any one of claims 1 to 9, further containing at least one compound selected from the group of compounds represented by formula (3) as a third component: 55 .38 P2811 003At Cee Gre x5 Pp x6 CwhleareicnyRclioshaelxkyalnhea.v1i.npg 1h1n2 cyarboins,nakeo,hav2ing.0o12rcoraoo.b-oorr1eannlky4eesnnyleh.h3a.ev5inlgnl2ucyo1-2e-capnrbroenesn:n,neg, 5 1e.3loxyanae2n5.s6yo.rlcaXhtayaonrpdybraone-ni,ndy5ep.ie)ndnaonytpyiymiodignea-, Suryine2: Y1 risinngl,e oanrdi,ndefocfrlosmoerlaymeanneoonyy.: andpsnz dork 1. oThemlatuhdGcryousptofccoommppoosutnodnsarcecporredsienngtoedlbyio1m0,awhere1i)nohefoirmdulcao(m2p6o)nents astanecompu selected F FF F F 3 ep2001031A1 [FE . 0 Sook, OO F " . . d Q yO-CE (3-10) * EY vF # FF F FF 5 . CFs FF r= o . (317) 5 F & a - R* . F FP F F F x x . F Xx x10 x8 Y x8 . (3-20) P2811 003 At x1 x8 x7 Fe x s R* 12 10 xe yt x8 (3-22) x1 x8 Fe Xx i R* 0 y! x12 x10 Nd 6 (3-23) = R* xX Fe xX (3-24) Xo ye 0 y! x8 hrs, R i aly having 1012 carbons, akory ving 11 12 carbonas aller having 210 12 carbons; XC, X8,X7,X8, X9, X10, X11and X 2are indepheydrnogd en e o fn luot rinel;aynd Y isfluorine,chlorineortriluoromethoxy. 35 12. Tfhoemltahuedgrcoyusptofccoommppoosutniodnsarcecporredsienngtoedlbyifor1m0,ulwahe(r3e-i1n)haecciodrdcionmlgopocnleantms11 astanecompund selected 15. fhomehde grcroyusptaolfccoommppoosuionndacrceoprredsienngtteodcbylafno1r0m,awh(a3r-s1n9thccthoiracntgoocamm 11pa. eoas nonsecomnpoutnd select 40 14, fTonmefhiedgrcroyusptaolfccoommppoostuinondarcecporredsinegntoedcbayimfo1r0,mwahe(r3-17)thacchorddincgotomcpaemn1a1. toenscsompetund selected 15. fTohmolhuedgcrroyusptaolfccoommpopsoituinondarcecporredsienngtteodblyanfo1m0i,lwahe(r3e.2i1n)thactchoirdcionmg0pocnaemnt1s1.aaonecompound selected 1. fTohmolhuedgcroupyofctompaounld rcepreosentmedcblypafno1or0,mwahse(r3e.ii22n)tahoctchoinrdcioantmogpoccnaemnct11.aoeasrtondcoimpogundstelecoted "0 1. Thhaerlaonugedocfry5st%ablycowmepiogshtot0n6a5c%cobrydiwngeiotanbyaasneeoofn tihmisa10w10e16i,owghtehhreeihnuairactryostfalthceomhpdsicoonm.ponents 15. TShheaus ies 7c0yCoafchoemrpo,siaontaacacnkfolooapnryyo(dn25oiCf)cnaatmwgsa1v1e1l7ng,iwhheorfi5n8a nianmomeuterts e0m.07paeomfrorasna,emntadteica Gelactic anisotropy (5G) at aquency of 1 1 20 mor, 15. Alla crystal dpa doi inciuing ie Iaidcystl composion acerding to anyoneof cis 1018. 20. Thu rysaldsply devs accordigtoclan 1, whean orperaetingimande nthe audcrystal laydevs EP 2811003 A1 is:a TN mode, an ECB mode, an OCB mode, an IPS mode, a PSA mode or an FPA mode, and adiving mode in the liu crystal splay devi i an active malrx mode. 21. Use of the liquid crystal composiion accordingto any oneofclams 110 181 a uid crystal display device. x " ep20m 00301 TERNATIONALSEARCHREPORT TIT TIE ErerESeaT sie s eons oe Sos seams i SoA ore (CO9K19/42(2006.01)1, CO9K19/12(2006.01)i, C09K19/16(2006.01)i, CO9K19/20 cri nrspe re BE EEE a BS), Coon1374, I RS TATE as De 0 Hemanis " w 3 dopr e ao m Gonr o, = a | or 2ommesseses n atnipron sok ant crosses, a 50m 2001 1.2000, A a | o2r zEoveI-ommSenxe sreniezne ncomp, a - PER rs . 2 i REE Tcamer E ETEE MAI... A oT Ee EpmrmmaomameI ee tt 4 be 07 documentering nce slo, se,exbbion oaber oxaas iSt oE r T TTTAGLRrtoh meta Fg de er "A docuof smseptnefty E TE r oT o 1 Loao on For PCT/(sIecoS ndshA eet)ZulI y 200 09). -- ss " EP 2 811 003 Al INTERNATIONAL SEARCH REPORT International application No. . oer | memsmees| PCT/JP2012/084032 5 C (Continuation). DOCUMENTS CONSIDERED TO BE RELEVANT Category* Citation of document, with indication, where appropriate, of the relevant passages Relevant to claim No. A JP 2004-182884 A (Chisso Corp.), 02 July 2004 (02.07.2004), entire text 1*0 && UUSS 22000044//00110088448899 AAll 1-21 15 .20 25 .30 35 .40 45 .50 rebm---- 55 Form P CT/ISA/2 0 (continuation of second sheet) (July 2009) .45 EP 2811003 A1 REFERENCES CITED IN THE DESCRIPTION This listof roforoncoscitedby the applicant i orth reader's conveniance only. I doos notorm partof tho European `poaxtcelnutdeddocaunmdentthe. EEPvOednistchloauigmhsgraelatlacbalrtoyhiansthbieseongatradk.en in comping the references, ators or omissions cannot be Patent documents cited in the description ++ UJPpS2050705073408A78[A020[60470]06 [0067] + UP SS9176221 A [0067] + JP S5716532A8 [0067] ++ IIPP HH2I230362265A1A[[100008667]76] + US 3650505 8 [0067] Non-patent literature cited in the description + + Organic Organic Syntheses. Reaclons. John John Wiey& Wiey & Sons, Sons, Inc, nc, [0068] [0068] + CompreOhrgeannicsSynithvesies. PergamonPress + 1N0e0w68E)xperimental Chemisty Course. Maruzen Co. LG, (0068) + M.IMAIta. Molecular CrystalsandLiquidCrystals, + L1i9q9u5i,dvCorlys2t5a9l,H3a7nd0b0o7o7k]. Maruzen Co, Lt, 2000, 196 (0088) "