Document a4OLLgpMDdLmLpo9DzbyYVgQB

AR 286 807 BIODEGRADATION (OECD 301E) TEST SUBSTANCE Identity: ArefmeirxrteudretocaonstPaiFnOiSng, pFeCr-f9l5u,oroorocatsanaescuolmfponoanteen,twhoficFhC-m2a0y6CalEs.o b(1eOctanesuifonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot number was 502. The test sample is FC2d1i0.e65tC5hEy%.lsenoCeduirgluryemcnootlctibynulftoysrlumlefatathtieeor,n,1i7.n6d0i.5c0%a9tp%eoswliayttoiexsrya,et4mhi%yxltueurnreeea,mofo1n0.o.2o98c2t%%ySlPuplFhtOeonSny,elf1eot5ah%mere,r, 0.06% sodium lauryl sulfate, and 0.05% tolytriazole. cThhaerafocltleorwiiznegdscounmcmeantrryataipopnlisoefsitmopuarmiitxiteusr.e Dwaitthaimnacyomnpoltetaeclcyurately reflect the biodegradability of the fluorochemical componentofthe test `sample. METHOD Method: Modified OECD Screening Test, OECD 301E, with DOC Analysis Test type: Ready Biodegradability YGeLaPr:CoNmopleted: 1989 Analytical monitoring: Dissolved organic carbon (DOC), pH, D.0., and tSetamtpiesrtaitcuarlem.ethods: Results were determined by calculation of the % DOC rTeesmtovoerdgaansicsommspoaurrecde:to Atchteibvlaatendk control sludge mixed liquor collected from the aMentdrroeWsatosrteedwtaoteorrigTirnealatvmoelnutmePlparnito,r St. to uPsauel,asMiNno(cPurluemc)o.nditioned for 7 days Test condition: DMiilnuetriaoln Nwuattreire:ntMMileldiipourme:MilNluit-rQiTMenwtamteerdiumper OECD 301E method. Initial pH 7.0. Stock andtest solution preparation: A stock solution was prepared bmyedaidduimng(e1q0uimvaLloefntthtoe1t3es0t0smugbsTtOaCnIcLe)t.o `obtain a final test concentrationof40 mg oInnietiallitperHof7.m3i.neIrnoarldneurtrtioent DOCIL, 18.46 mLofthe stock Tsoelsuttivoenswsaelss:use1d00p0erm6L0E0rmleLntmeesytevroslcuomnet.aining 600 mi test solution ~ and capped with foam plugs. Incubator Conditions: Gallenkamp Constant temperature orbital shaker incubator (constant dark conditions) TAegimtpaetriaotn:ureS:hak2e2n+c2ontCinuously at 100 rpm 001701 N(ruemfebreerncoefsctoanndcaerndt)raatnidonbsla:nk1, plus sodium benzoate all in duplicate. standard Inoculum condition on test initiation: TSS 2227 mg/L (TSS in test flask 1.114 mg/L) Eloment Basis: and initial Decrease ipnHdi5s.4s.olved organic carbon compared to tThoestblsaunbkss.tance flask conditions: pD.H0:.:DaDyay070.83.1(b(obtohthdudpulpilciactaetse)s,),DaDyay282-85-8..58((bbootthhdduupplliiccaatteess)) RESULTS Nanodmitnesatlscuobnscteanntcreaattio~n4s:0 Blank control, mg DOCIL. sodium benzoate at ~20 mg DOCIL Element values: 28 Day Degradation --90% duplicate 1 and 91% duplicate 2. Mean value 91%. Remarks: Substance RTeesmtairnkgswafiseldc.onTdhuectveadluoens a mixture reported as described in the Test apply to that mixture and not the fluorochemical proportion alone. CONCLUSIONS The FC-206CE % biodegradation based on mean DOC removal was 91% after 28 days. The reference substance obtained 98% degradation, therefore the inoculum used was viable. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY rree-------- Reliability: Kiimisch ranking 2. Testing meets all criteria for quality testing. Hanoawleyvtiecra,l csoanmfpilremaptuirointyofwathse naomtopurnotpeorftyflcuhoarroacchteemriiczaeld parnodpotrhteiosntuindythleacks solution. REFERENCES --- The study was conducted by the 3M Environmental Laboratory, St. Paul, MN, ~ Lab Request number G1358-2, 1989. OTHER Last changed: 6/26/00 001702 A------ BEST COPY AVAILABLE iEB ---- mm Ready Biodeggadability issrouvto. GIES. EnionmentiLas -- Werkshot P50 = ol --s-- sample Ouscrivtion ModliCied OECD Screening Tact Soi Oot: 5222-89 FC-2038 lok 519 3 Analyst: SHR Fe 2ouct LorS02 Tr I ErpeDec sigw n enial -- =Two test chem1Riefec renta e Sul bstasnce, ... 1.Blank Control <man_duplicate 2 Runwith LR61200, Common Contrels, TeSeran ----DocAnalysesonDaye 0,1, 3,7, 14 Al, 27.238 IC Test Condittons5 J --Trwal volume = Loomdin [DcomClask --_--AMamtaras _-- TempZ3a2 a t 22 c 000000000 Do > 0.5 ma Ie vessels Orbiial Shaber- mmcubalat,av/00RPM,intheclark IC Teel Substances 2 Fg Q a EST ASR 4 EC-=206 of, lot Gog ClbE aN : wi SEmpsy RIERA hs 4 2 BE pg re ae waa, . Bono She SRR Dre DE Tn EA RP RSE Baa SEee a tr S Gi e RS spacbie el GAT RIR eeSsE BEST COPY Ava ronan 0wo Ready Biodggmdabiliny Lao Roques No. G6.1LB3O5O8. e anaimplfei Descripiioln oilifiedoEroOnEmCaDntSacrlerL.a.bn--a Work Test Sheet Jo1s PA Onto: A enenn Of oti 5-22-89fs Fn) Seba roars Sabi Ref: MB2e2793 z fe en -------------- Munecal NutrientMedium Peepucation al. gE a eT C CbE rCeopan307430 pez an Tis Lp zmepns ae Sl AER Tg S\U Ena AER ALENTF i stecilned EI EsaE BES oaSY a HM 505 cosas a 0 030 0 STE boy pembeane. Ciication lacie) ATE Ga IgyyE e OER SRARSTo RE a [ORR IS 5 fini DESeas ES BENETRI Sa EE RR Ra. rams 40 -- rr ---- BEST-- COPY A-- VAILAB-- LE ---- Ready Biodearabiliyy owmG6ne1l3v58802o0, mole boston Mol, SieEnvoiroynmen5t, al Lab --TesWt orkSh3eoeitz La LillSn tabild ized Foam angler sou ho One -- S=23-29 Anas SHB Refs M834arq:y ~ > = Ohtamedde Plant, 6B ol6o89 Com 4 Tne pie 7,2 = Poured th "Dp, `dar 00 ram inte STtahmoletsst steel Sieve Cone ---- blessed so sont atone api otcclrapn pp lene iLO Lutte Enis ple 2.0,155 2 2027 mls MINC-0O Sue sate hays io repla ~+ha o: b Va poration posal shougleLoo mnStausles Si cio, TL 5 - = az PP : : ETT TER Tnaculation af L Teer CNS ER Teer Lloyiiziliiso: REET Ee = gma er ask 0a5 tmeydy 225Cm,oBRRRESN:eStoeaTt] Lhninok 3s E e i E it Leyahkae ERE R FR C ABE BEST copy AVAILABLE Ready Buodggadabilivy oSion Suscrotin ModOiSECnvECirSoeinmveeneteamldgLaTbe.--snWorSkoSihreat Fe-go3ct Lot 519 Fe-20bcs Loi 503 ---- Test Solutions Pepacatton Lao roost No. 6.1358 70 Ove ----T--Z--AI R--L--_--_ Anaiyst: SSH, TTT ---- Fe:o3Jeord ooo. ----Toc = 330 coa male. ctach Lomd = Azomgc Toc --Sick Salad IDmL.[2 Minask Armr edii um e z.ddn oanyt Toc| mimi E ZB en seven rs mre SE, [R-- 1 AA maToC nem ema seroseem se ete. Tntest lasks want Hor . g Doc. fe reto resemremem ---- Homafe = BRO lek Jo 3 A2ma md = Jo.9lml stack [Jboomd --l-- eeSsto-- ickiSoolgoE v2 aJfoC uimcgt. ohJr- ooSMiioamwalR lzMoBscoa0 mFaeTdL oumc C = L3mE pcToc0fc Cot pple = 30.75mme sak [2 Sone LC zmaed = j30emd cea Jboapd fer oo Foal a Raa Js tsRR AEROSRS OF Be BIEST copy AVAILABLE Ready Biodaggadability EnviroLnabm--eWonrktSahelet `Sample Description Mochi Sled OLDSceeening Test Jol feocs torsiq Cob cE Lor saa -- BopoderPreparation LabRequest No. 1358 726%---- ---- ~~ oat 5-23-84 anaer _Seb TSeorasiafvoonciHoeAsRelS mGm AASr p ALmadbim alA SaiGVTlowg)MrEeE FERSCE joa) kSuH vr 03 b+ 1A5 = boo FORME gdb rs+i0.g 3 xagaq s =boo Adaornewel GY T 59765 T + 0.3 + 12.TT5T = LT oT o ChJ eiv eSC sob mRrsE 4 0.3 9 1as=boo oy, le +(aterence subetante. Shard wrk. 18 6 Roe AllTest Solutions Preparedincluplicare. Afi each.p to Td lar ot od SK mile -& ee aSIRT 0 Ld . us bythe = 200m0aliyun"t5 SLafUTSIeESZRA haberprioc soSilekreben 5 Era es a ped. SLANE Lolsask=as, plateqdl in amtalnotnlSheani1 temp (aie) pore incubaiac, in ii TELSPOSMBIMIVR ef ol halien od AR PAN Sd BEEETarelehinl ones SORES UE ih RR Ey, i A Re SE TAT edd ag ackiSafpal Dilla aaLe 00-1707 roman 0.000 Lab Request No6&18L0A0S,R ETL, EenreviroLGnabuml--eWonrtksaheelt #o2o9-- 5:L 8o3f:---- 8--9 KEE ) coTmemmepnetrTaetmep. iOn ritGal SnicidlHybi aARtEor MadiOiedO50SetrarniggTest ZBLesememm---- Bonbon beigedoB0RIR IE Bebe Dale Tals Temp 0 Faz aRga 524-84 SAB A 5:25:84 SB a 5:24:89 AR 2 Sass SAR 2 Sum AB & 3/8 SAB A G/-89 SMB a f-2-8 <i gl Su a 5-8 SHB 2] ImbTa empl C2e | -- -- 6-2-29 Sp 4 p9-29 SM A) -- bolA-89 Sa & beled SMA 2) . 00 14-8 SHB A bossa. SA gf | ous Seal f USWA Ls bopo-89. SB. A | 001708 BEST COPY AVAILABL rm rSeamdpolesDeesscription Fe-sobct Ready Bioclearadability Lab Roauost No. $2135 C%5 MoEclirCiueerl oSnLcambl--oWenoTretektsanh-e3lsi0t1nEp#ge29:0 --__--5---o3f3---L2--9 IY Tesr Flask Condivions, pra EE SELENE SRL NE ORAL TR NAS R20 Amn 45, A. 63,34 LiebeTe biSq 58 S9_5s as FCA3IC 7.3 84 4.5, 8.0 LA, SA Lc84L179 Le $1 Ss S& 519 } F206T 73 81 65, 81 3.83 Lie 320 5540 Sel 5aes FCAO7L.3I9T 5.92 63. Le98 9 A3 BC 65 Te S530 555 & rea BErLe wa GRR FR ar ol J ad 35 TE of Ca R ERe ERAeoRe TERR RY at BRE ge | BEE | a Tas || R TahETRT EE | . RBE ieET aesLe BeE s C e R nB euen Sided B bESERa IS ES n A Ui,GaAdL aa alRCe O RHI Ea NE, YE -17 AEP VA PIRrHTT CLORI (ARIiS) -- 1 SO 17:FURoRT BART Pie 1e 0 Y, 001770 ENVERONVENTAL LABORATORY BEST COPY AVAILABEEFIED OECD SCREENING TEST 301E READY BIODEGRADABILITY jStarrkaDamte Sagv = Analyst Test Swstace0 FC-0 Z0L0 CE 0 [ot0 SO0 R 000000 Test Concentration 40RS 20C [Le : inoculim Source Meiralaste TregimentPlantMixed LiguorSe Paul,Mn Concoefsunspetnderd soalidtsiniinoocunlun fresh (in mineral medium) -- pre-conditioned (restored to original volume) 2.227 a Je Carbon Determinations Carbon Analyzer = Dohrmann Yertex Inoculum Used: Fresh/Pre-conditioned Medium Elask Analyses `Time of incubation (days) (mg/L) ma a loaaliossfonoselomJasons oso] 2m Loseol10sJoasslo.on]erse]ssssJloeosssso| 2 B 5, lloo..3450a1[[00..1058 [J0o-.c0o4g0boo.ccvaosJ]o-o0-4do|rodw8llee..c2t453[l00o.-o002t14o]] bn baron Joanbolodoonaslool a a poseloonloaa]c.caf det 1 a cmon we 2 oy 2 Evaluation of raw data [onabrsn ls fusalsnar[acum niofin]sos. peaafras baualsnlinoliegrallyz [20.7315%.92[33Jolt1.47 [FALL3 1083077|3.70] [35.45]3.35" [32.49|29.e502 aval. 581 [3.027]3.252] |35:94]36.49 [3.97[10.07] 3.00]2.033]2850].gato| Flask Percent Degradation after t days ole So. Roa: =lk) er 01 3 7 Wu cw TT TT anal 0 som wo i fpmen] e0 ms0] + vo] Joafeqlislaaailaafar] | [37[as]poei7le)[18laafal| 2 } 001710 * EWIROWENTAL LABORATORY TT ww 4E730335 REST COPY AVAILABLE.) cory, senemmic esr ante anges "ELAS READY BIODEGRADABILITY Test swstarce SodiumBenzeak,Releence.Svbstanee Test Concentration 20 me Tne/L (34.3 mg J) Inoculum Source Meira LunsieTreatment Plant Mised LigrorSrBul, aw fresh (in mineral medium) --_ -- pre-conditioned (restored to original volume) 2.227=] IL Carbon Determinations Carbon Analyzer = Dohrmann Xertex Inoculum Used: Fresh/Pre-conditioned Medium FlaskAnalyses Time of incubation (days)- (mg/L) : wax rn bows] ononb focrfensoe] Me Joan 1.689brent[o.onfoies[acerfpoas|ozs] Lieo])913 [ost|oonpuse ossoo [os] 2 By Lo.t01[0.08 [0.008[o.cec|oottJo.cos[0.245[0.024] wean 1 B, loso-tt[o-040[0pasle-on oAumm+nBe,ameannP loss Joostougalpon [o-c23loop0[001g| [aFobwleosnss[heoones] z p334 1.017 Jp-o42]0.017] lo-082.|o Comin Chemical 4 o n]ia987 focOubslfomslors basossslors|t comet [oti] 70lero]osforeals1oauosas 2 5Lao]012.57 To.cur lo tgafe-cn [0.38703700.37| 0, Mm f[n19a.2s5l]2s0o.5s0b[oor-s0l7o0001s[|ot-oaimsds5p]a0o83s4es31]0oh].s3s1.e|] Evaluation of raw data Homes TT rao[ae Flask Percent Degradation after t days i =. = 1-flcmean - 0 1, 0 0 1 3 7 14 "28 0" mre0 wan 0B |[37[welr7l9go fia4[sa| - 001711 Co Re 1358 OECD Mockified ScreanTiesn+ogf Ready Blodlggradabiliy 3o1F FC-203CE and FC-AobCE Percent Degradation After Days(% Doc Removal) TSeos: Day 2D.2 > o> N DaoR DH a wB FC2a8cE =) [73 "2.1 8 38 83 a3 a3 FC-2a8E =2_ |-b.) 0.3 1A do 88 90 38 Fe-30ece-1| 67 1A 19 29 92 92 ao Fe-douce-3) 0A bq 15 942 a4 92 Cl Sam| 723 10 a7 ae 9a 98 as od ha 0.0% 100 97 leo 9 99 ag Ww .j % Doc Remover = [I = i, loo B 001712 06/23/2000 EANRVCIHRIOVNEMDENTFAILNALLABROERPOARTTORY 1 LRAEBQUERSEQTUOERSTNAMNEO:. GM1T7E9/8EAR DEPARTMENT: 0535 DPARTOEJECRTECENIO:VED9:9700051/32030/01989 DESC: FC-203 CE AND FC-206 CE BIODEG. DAY 0 ECOXNPTCRAOCMTP LDAATBE(:S):05/31/1989 DPARTOEJECCTOMPLLEEADT:ED:JH 0S6T/O0C2K/1989 3PHHONFEAXNON:O: 665511--777788--66413786 Please run in duplicate. SAMPLE DATE CODE DESCRIPTION RESULT MDL or (95% C.1.) 1 05/23/89 FC-203 1 mooeesasesnn 0c DISSOLVED ORGANIC CARBON 40 MG/L 2 05/28/89 FG-203 11 TTTTTTITIT oc DISSOLVED ORGANIC CARBON 41 MG/L - 3 05/23/89 F-20681 TTT Doc DISSOLVED ORGANIC CARBON 37 MG/L 4 05/23/89 FC-208 11 TTTTTIT ooc DISSOLVED ORGANIC CARBON 36 MG/L 001713 06/23/2000 EANRVCIHRIOVNEMDENTFAILNALLARBEOPROATROTRY 1 RLAEDQUERSETQOURESTNAMKEO:. GM1T7E6/7EAR PDERPOAJRETCMTENNTO:: 90957305013000 DDEASTCE:RELCAENIDVFEIDL:L 0ST5A/B23/F1O9A8M9BIODEG. DAY 0 CEOXNPTRCAOCMTP DLAATBES:):05/31/1989 DPARTOEJECCTOMPLLEEATDE:D:JH 0S6T/O0C2K/1989 aPMHONFEAXNON:O: 665511--777788--66413786 Please run all samples in duplicate. Sale oAtE | Gobe DESGRIPTION RESULT MOL or (95% G.I.) 1 05/23/89 MQ MQ BLANK Doc DISSOLVED ORGANIC CARBON 2 05/23/89 MEDIUM NUTRIENT <0.5 MG/L Doc DISSOLVED ORGANIC CARBON 0.8 MG/L 3 05/20/89 1ST RINSE FOAM SOLIDS Doc DISSOLVED ORGANIC CARBON 2000 MG/L 4 05/23/89 oo 5 05/20/89 000 05/23/89 o0c 7 05/23/89 2ND RINSE FOAM SOLIDS DISSOLVED ORGANIC CARBON GRD RINSE FON SOLIDS DISSOLVED ORGANIC CARBON 4TH RINSE FOAM SOLIDS DISSOLVED ORGANIC CARBON BLANK 1 conTROL 540 MG/L 150 MG/L 52 MG/L Doc. DISSOLVED ORGANIC CARBON <0.5 MG/L 8 05/23/89 BLANK IT CONTROL Doc DISSOLVED ORGANIC CARBON <0.5 MG/L 9 05/23/89 LEACHATE I Trmmmmmeeees 000 DISSOLVED ORGANIC CARBON 42 MG/L 10 05/23/89 LEACHATE II ~~" """"""""" 000 DISSOLVED ORGANIC CARBON 41 MG/L 1 05/23/89 PRE W-SOLIDS ~~ 77777777 oo DISSOLVED ORGANIC CARBON 1.3 HG/L ---- 0061714 06/23/2000 EANRVCIHRIONVMEEDNTFAILNALLABRUEHPAOIRUTNY - RLAEBQUREESQTUOERSTNAMNEO.: G1802 MTE/EAR PDERPOAJRETCHTENNTO:: 90593750013000 DDEASTCE:REFCGE-I2V0E3DC:E A0N5D/24F/C1-928096CE BIODEG. DAY 1 CONTRACT EXP COMP DLAATBE(:S)06/02/1989 PDARTOEJECCOTMPLLEEATDE:D:JH0S6T/O0C2K/1989 3PMHONFEAXNON:O: 65615-17-7787-86-6413786 Test shares controls & ref. substance with LR G1800, See LR 61801 for day 1 analysis. SAMPLE DATE CODE DESCRIPTION RESULT MOL or (95% C.1.) 1 ooc 2 Doc 3 oc 4 oc FC-208 T memes DISSOLVED ORGANIC CARBON FC-208 11 TTTTTTTTTOOC DISSOLVED ORGANIC CARBON Fo-206 2eanasacsas DISSOLVED ORGANIC CARBON FC-206 IT TTTTTTTTTTTC DISSOLVED ORGANIC CARBON 42 MG/L 44 MG/L 35 MG/L 36 MG/L 001715 06/23/2000 EANRVCIHRIONVMEEDNIFAILNALLABRUENPAOIRUTRY RLAEBQUERSEQTUOERSTNAMNOE.: G1801 MTE/EAR PDERPOAJRETCMTENNTO:: 90957305013000 DDEASTCE: RELCAENIDVFEIDL:L 0ST5A/B24/F1O9A8M9BIODEG. DAY 1 CONTRACT EXP COMP DLAATBE(:S):06/02/1989 DPARTOEJECCTOMPLLEEATD:ED:JH0S6T/0O2C/K1989 3PMHONFEAXNON:O: 665511--777788--66413786 Please run all samples in duplicate. Gweie owe eve ogschiprion RESULT MOL er (38% G1) 1 BLANK T CONTROL 0c DISSOLVED ORGANIC CARBON 1.9 MG/L 2 BLANK 11 CONTROL oc DISSOLVED ORGANIC CARBON <0.5 MG/L 3 LEACHATE I "77777777770 oc DISSOLVED ORGANIC CARBON 40 MG/L 4 LEAGHATE TT "7777777 Doc DISSOLVED ORGANIC CARBON 39 MG/L 5 soLIos 1 WASHED Doc DISSOLVED ORGANIC CARBON 0.7 MG/L 6 SOLIDS II WASHED 00C DISSOLVED ORGANIC CARBON 1.2 MG/L 7 LEACH & soLIos 1 oo DISSOLVED ORGANIC CARBON 42 MG/L 8 LEACH & soLIoS 11 Doc DISSOLVED ORGANIC CARBON 41 MG/L s REF SUB I SODIUM BENZ. oc DISSOLVED ORGANIC CARBON 20 MG/L 10 REF SUB II SODIUM BENZ. --- Doc DISSOLVED ORGANIC CARBON 21 MG/L 001716 06/23/2000 EANRVCAHIHVUENDMIFEAINLNALLADRUENPAOIRUTNT . LAB REQUEST NO. G1820 REQUESTOR NAME: MTE/EAR DEPARTMENT: 0535 DPARTOEJECRTECENOI:VED9:9700051/32060/01989 DESC: FC-203CE AND FC-206CE BIODEG. DAY 3 CEOXNPTRCAOCMTP DLAATBE(:S)06/05/1989 DPARTOEJECCTOMPLLEEADT:ED:JH0S6T/O02C/K1989 aPHMONFEAXNON:O: 65615-17-7787-86-6413786 Test shares controls & ref. sub with LR G1800; See LR G1819 for day 3 analyses SAMPLE DATE CODE DESCRIPTION RESULT MDL or (95% C.I.) 1 Doc 2 Doc 3 Doc a 00C FC 208 1 sremnneeeee DISSOLVED ORGANIC CARBON 41 MG/L FC 203 II TTTTTTTTTTOC DISSOLVED ORGANIC CARBON 40 MG/L FC 206 1 Termes DISSOLVED ORGANIC CARBON 32 MG/L FC 206 II TTTTTTTTTTTT DISSOLVED ORGANIC CARBON 33 MG/L 001717 08/23/2000 EANRVCIHIRVUENDMIFEAINLNALLABRUERPAOIRUTRY LAB REQUEST NO. G1819 RDPEERPQOAUJREETSCHTTEONRNTO::NAM90E95:73050M1T3E0/0E0AR DDEASTCE:RELCAENIDVFEIDL:L 0ST5A/B2.6/1F9O8A9M BIODEG. DAY 3 Plesse analyze in duplicate. (CONTRACT LAB(S): EDPXARPTOEJCEOCCMTOPMPLLEDEAADTT:EE:D:JH060/S60T/5O0/C21K/9189989 PaHMONFEAXNON:O: 665511--777788--66413786 Sawple OWE Got | DESORIPTION RESULT MDL or(95% G.I.) 1 oo 2 Doc a o0c BLANK T coNTROL DISSOLVED ORGANIC CARBON BLANK II CONTROL <0.5 MG/L DISSOLVED ORGANIC CARBON <0.5 MG/L LEACH T LeAcaTE DISSOLVED ORGANIC CARBON 31 MG/L 4 o0c 5 Doc 6 00 LEACH IT LEACHATE DISSOLVED ORGANIC CARBON SOLIDS I PRE-WASHED DISSOLVED ORGANIC CARBON SOLIDS IT PRE-ASHED DISSOLVED ORGANIC CARBON 33 MG/L <0.5 MG/L <0.5 MG/L 7 LEACH & SOLIDS I o0c DISSOLVED ORGANIC CARBON 30 MG/L s LEAH & SOLIDS Ir oc DISSOLVED ORGANIC CARBON 33 MG/L 9 REF SUB T SODIUM BENZ. Doc DISSOLVED ORGANIC CARBON <0.5 MG/L 0 REF SUB II SODIUM BENZ. -- Doc DISSOLVED ORGANIC CARBON <0.5 MG/L 001718 06/23/2000 LAB REQUEST NO. G1797 swt one ove EANRVCIHRIOVNEMDENTFAILNALLARBEOPROARTTORY CONTINUED oescmmerion | REsLT 12 05/23/89 ooc 13 05/23/89 Doc 14 05/23/89 oo 15 05/23/89 oc 16 05/23/89 0oc 17 05/23/89 oc PRE-W soLIos 11 DISSOLVED ORGANIC CARBON LEACH & soLIos DISSOLVED ORGANIC CARBON LEACH & soLIDS 11 DISSOLVED ORGANIC CARBON LEACHATE As-18 DISSOLVED ORGANIC CARBON REF SUB 1 SODIUM BENZ. DISSOLVED ORGANIC CARBON REF SUB II SODIUM BENZ. DISSOLVED ORGANIC CARBON 1.1 MG/L 43 MG/L 43 MG/L 2000 MG/L 21 MG/L 20 MG/L < MOLor (95% 6.1.) 001719 06/23/2000 ENVIRONMENTAL LABORATORY 1 ARCHIVED FINAL REPORT LAB REQUEST NO. G1834 REQUESTOR NAME: MTE/EAR DEPARTMENT: 0535 PROJECT NO: 9970013000 DATE RECEIVED: 05/30/1989 DESC: FC-203CE AND FC-206CE BIODEG. DAY 7 CONTRACT LAB(S): EXP COMP DATE: 06/09/1989 DATE COMPLETED: 06/02/1989 PROJECT LEAD: JH STOCK PHONE NO: 651-778-6438 3M FAX NO: 651-778-6176 Test shares controls & ref sub. with LR G1800; see LR G1833 for day 7 analyses SAMPLE DATE CODE DESCRIPTION RESULT MOL or (95% C.I.) 1 oc 2 Doc 3 Doc 4 oc FC 203 I Trommmeee DISSOLVED ORGANIC CARBON FC 203 II Tree DISSOLVED ORGANIC CARBON FC 206 T TTT DISSOLVED ORGANIC CARBON FC 206 IT crm DISSOLVED ORGANIC CARBON 33 MG/L 35 MG/L 30 MG/L 30 MG/L 0017720 06/23/2000 EANRVCIHRIOVNEMDENFTIANLALLABROERPAORTTORY 1 LRAEBQUREESQTUOERSTNAMNOE.: GM1T8E3/3EAR DPERPOAJRETCMTENNTO:: 90957305013000 DDEASTCE:RELCAENIDVFEIDL:L 0ST5A/B3.0/1F9O8A9M BIODEG. DAY 7 ECXOPNTCROAMCPT DLAATBE(:S):06/09/1989 PDARTOEJECCTOMPLLEEADT:ED:JW0S6T/O0C2K/1989 P3HHONFEAXNON:O: 665511-7-7787-86-4631876 Please run in duplicate. SWPLE DATE GODE DESCRIPTION RESULT MOL or(95% G.I.) 1 BLANK I CoNTROL o0c DISSOLVED ORGANIC CARBON <0.5 MG/L 2 BLANK TT sesanonssan oc DISSOLVED ORGANIC CARBON <0.5 MG/L 3 LEACH T oeeenneees 00c DISSOLVED ORGANIC CARBON 29 MG/L 4 LEACH TT reeenneeees Doc DISSOLVED ORGANIC CARBON 29 MG/L 5 sous 1 eens ooc DISSOLVED ORGANIC CARBON <0.5 MG/L 6 soos 11 tteeeeees 00C DISSOLVED ORGANIC CARBON <0.5 MG/L 7 LEACH + SLID 1 Doc DISSOLVED ORGANIC CARBON 32 MG/L 8 LEACH + so0LID 11 ooc DISSOLVED ORGANIC CARBON 27 MG/L 9 REF 1 SODIUM BENZ. ooc DISSOLVED ORGANIC CARBON 0.5 MG/L 10 REF 11 SODIUM BENZ. om 00c DISSOLVED ORGANIC CARBON 0.6 MG/L 001721 06/23/2000 ENVIRONMENTAL LABORATORY 1 ARCHIVED FINAL REPORT LAB REQUEST NO. G1874 REQUESTOR NAME: MTE/EAR DEPARTMENT: 0222 PROJECT NO: 9970013000 DATE RECEIVED: 06/06/1989 DESC: FC-203CE & FC-206CE BIODEG DAY 14 CONTRACT LAB(S): EXP COMP DATE: 06/16/1989 DATE COMPLETED: 06/12/1989 PROJECT LEAD: JW STOCK PHONE NO: 651-778-6438 3M FAX NO: 651-778-6176 Test shares controls and ref. substance with LR G1800; See LR G1873 for day 14 analyses. SAMPLE DATE CODE DESCRIPTION RESULT MDL or (95% C.I.) 1 Doc 2 Doc 3 oc 4 oc FC 203 I eeeeneeees DISSOLVED ORGANIC CARBON 5.0 MG/L FC 208 11 TTTTTTTTTOOT DISSOLVED ORGANIC CARBON 4.3 MG/L FC 206 T Srrmmeenees DISSOLVED ORGANIC CARBON 4.2 MG/L FC 206 II TTTTTTTTToot DISSOLVED ORGANIC CARBON 2.9 MG/L 001722 6/23/2000 EANRVCIHRIOVNEMDENTFAILNALLABROERPOARTTORY 1 RLEAQBUERSETQOURESTNAMNEO:. GHT1E8/7E3AR DPERPOAJRETCHTENNTO:: 09292720013000 DDEASTCE: RELCAENIDVFEIDL:L S0T6A/B0.6/1F9O8A9M BIODEG. DAY 14 CEOXNPTRCAOCMTP DLAATBE(:S):06/16/1989 DPARTOEJECCTOMPLLEEADT:ED:JH0S6T/O1C2K/1969 3PMHONFEAXNON:O: 665511-7-7787-86-4631876 SAMPLE DATE GOOE DESCRIPTION RESULT MOLor (95% G.I.) 1 BALNK CONTROL ooc DISSOLVED ORGANIC CARBON <0.5 MG/L 2 BLANK II CONTROL ooc DISSOLVED ORGANIC CARBON <0.5 MG/L 3 LEACH renee - 0c DISSOLVED ORGANIC CARBON 1.9 MG/L 4 J o0c DISSOLVED ORGANIC CARBON 3.2 MG/L 5 soos 1 CTTTTIeI ooc DISSOLVED ORGANIC CARBON <0.5 MG/L 6 soos 11 "TTT oc DISSOLVED ORGANIC CARBON <0.5 MG/L 7 LEACH + soLI0S 1 oc DISSOLVED ORGANIC CARBON 3.8 MG/L 8 LEACH + soups 11 ooc DISSOLVED ORGANIC CARBON 3.1 MG/L 9 REF SUB I SODIUM BENZ ooc DISSOLVED ORGANIC CARBON 0.8 MG/L 10 REF SUB II SODIUM BENZ ooc DISSOLVED ORGANIC CARBON <0.5 MG/L LL 001723 06/23/2000 ENVIRONMENTAL LABORATORY 1 ARCHIVED FINAL REPORT LAB REQUEST NO. 61907 REQUESTOR NAME: MTE/EAR DEPARTMENT: 0535 PROJECT NO: 9970013000 DATE RECEIVED: 06/13/1989 DESC: FC-203CE AND FC-206CE BIODEG. DAY 21 CONTRACT LAB(S:) EXP COMP DATE: 06/20/1989 DATE COMPLETED: 06/16/1989 PROJECT LEAD: JN STOCK PHONE NO: 651-778-6438 3M FAX NO: 651-778-6176 Test shares controls & ref. substance with LR G1800, see LR G1906 for day 21 analyses. SAMPLE DATE CODE DESCRIPTION RESULT MDL or (95% C.I.) 1 oc 2 Doc. 3 Doc 4 oc FC 203 1 Trem DISSOLVED ORGANIC CARBON 4.7 MG/L FC 203 IT Tren = DISSOLVED ORGANIC CARBON 4.7 MG/L FC 206 I Tree DISSOLVED ORGANIC CARBON 3.1 MG/L FC 206 TI Trnmneeeeees DISSOLVED ORGANIC CARBON 2.0 MG/L 0017724 06/23/2000 EANRVCIHRIOVNEMDENTFAILNALLARBEOPROARTTORY 1 LRAEBQUERSETQOURESTNAMNEO:. GM1T9E0/6EAR DPERPOAJRETCMTENNTO:: 09593750013000 DDEASTCE: RELCAENIDVFEIDL:L S0T6A/B13/F1O9A8M9BIODEG. DAY 21 CEXOPNTRCAOCMTP LDAATBE(:S):06/20/1980 DPARTOEJECCTOMPLLEEATD:ED:JH 0S6T/O1C6K/1989 SPMHONFEAXNON:O: 665511-7-7787-86-4631876 SWMPLE DATE CODE DESCRIPTION RESULT MDL or(65% 6.1.) 1 ooc 2 o0c 3 oc 4 Doc 5 0c 6 oc 7 oc 8 0c 9 Doc 10 ooc BLANK T CONTROL. DISSOLVED ORGANIC CARBON <0.5 MG/L BLANK II CONTROL DISSOLVED ORGANIC CARBON <0.5 MG/L LEACH LEACHATE _ DISSOLVED ORGANIC CARBON 2.3 MG/L LEACH II LEACHATE DISSOLVED ORGANIC CARBON 3.1 MG/L soLI0s 1 reeenneeees DISSOLVED ORGANIC CARBON <0.5 MG/L PE DISSOLVED ORGANIC CARBON <0.5 MG/L LEACH + soLIos 1 DISSOLVED ORGANIC CARBON 2.4 MG/L LEACH + soLIos 11 DISSOLVED ORGANIC CARBON 1.5 MG/L REF SUB I SODIUM BENZ. DISSOLVED ORGANIC CARBON <0.5 MG/L REF SUB II SODIUM BENZ. DISSOLVED ORGANIC CARBON <0. MG/L 001725 06/23/2000 EANRVCIHRIOVNEMDENTFAILNALLABROERPAORTTORY 1 RLEABQUERSETQOURESTNAMNEO:. GM1T9E3/6EAR DEPARTMENT: 0535 DPARTOEJECRTECENOI:VED9:9700061/31090/01989 DESC: FC-203CE & FC-2060E BIODEG. DAY 27 CEXOPNTCROAMCPT LAB(S:) DATE: 06/26/1989 DPARTOEJECCOTMPLLEEATD:ED:JW 0S6T/O2C3K/1989 P3MHONFEAXNON:O: 665511--777788--66413786 T27estanaslhyasreess. controls & ref. substance with LR G1800, see LR G1935 for day SAMPLE DATE cope DESCRIPTION RESULT MOL or (95% G.I.) 1 00c 2 Doc 3 Ed a oc FC-203 1 rome DISSOLVED ORGANIC CARBON 3.0 MG/L FC-203 II "TTT ~ DISSOLVED ORGANIC CARBON 4.2 MG/L FC-206 I rrnneneeees DISSOLVED ORGANIC CARBON 3.1 MG/L FC-208 II TTTTTTTIT DISSOLVED ORGANIC CARBON 2.9 MG/L 001726 06/23/2000 EANRVCIHRIOVNEMDENTFAILNALLABROERPOARTTORY 1 LRAEBQUERSETQOURESTNAMNEO:. GMT1E9/3E5AR DEPARTMENT: 0535 PDARTOEJECRTECENIO:VED9:9700061/31090/01989 DESC: LANDFILL STAB. FOAM BIODEG. DAY 27 CEOXPNTCROAMCPT DLAATBE(:S):06/26/1989 DPARTOEJECCTOMPLLEEADT:ED:JH0S6T/O2C3K/1989 3PMHONFEAXNON:O: 665511-7-7787-86-4631876 SAMPLE DATE | CODE DESCRIPTION RESULT MOL or (95% G.1.) 1 BLANK I CONTROL Doc DISSOLVED ORGANIC CARBON <0.5 MG/L 2 BLANK IT CONTROL ooc DISSOLVED ORGANIC CARBON <0.5 MG/L. 3 LEACH 1 LEACHATE - ooc DISSOLVED ORGANIC CARBON 1.8 MG/L 4 LEACH IT LEACHATE oo DISSOLVED ORGANIC CARBON 2.0 MG/L 5 soLIoS 1 mene ooc DISSOLVED ORGANIC CARBON <0.5 MG/L 6 soups 11 TTTTTTTTTTTT 00C DISSOLVED ORGANIC CARBON <0.5 MG/L 7 LEACH + soLIoS 1 0c DISSOLVED ORGANIC CARBON 2.8 MG/L 8 LEACH + soL1os ooc DISSOLVED ORGANIC CARBON 1.9 MG/L REF SUB I SODIUM BENZ 00c. DISSOLVED ORGANIC CARBON <0.5 MG/L 10 REF SUB II SODIUM BENZ Doc DISSOLVED ORGANIC CARBON <0.5 MG/L _ 0017727 06/23/2000 EANRVCIHRIOVNEMDENFTIANLALLABREOPROARTTORY 1 "LAB REQUEST NO. G1941 DREEPQAURETSMTEONRT:NAM0E5:35MTE/EAR DPARTOEJECRTECENOI:VED9:9700061/32000/01989 DESC: FC-203CE & FC206CE BIODEG DAY 28 CONTRACT LAB(S): DEAXTPECCOOMMPPLDEATTEED:: 060/62/72/31/9189989 PPHROONJEECTNO:LEA6D5:1-J7W78-S6T4O3C8K 3M FAX NO: 651-778-6176 TEST SHARES CONTROLS DAY 28 ANALYSES. + REF SUBSTANCE W/ LRG1800, SEE LRG1940 FOR SAMPLE DATE CODE DESCRIPTION RESULT MOL or (95% C.I.) 1 oc 2 oc 3 oc 4 Doc FC 203 1 Treen DISSOLVED ORGANIC CARBON 3.0 MG/L FC 203 II TTTTToeeeoes - DISSOLVED ORGANIC CARBON 4.8 MG/L FC 206 1 srmemeeeeees DISSOLVED ORGANIC CARBON 3.7 MG/L FC 206 II TTTTTTTTToon DISSOLVED ORGANIC CARBON 3.3 MG/L 001728 06/23/2000 EANRVCIHRIOVNEMDENTFAILNALLARBEOPROARTTORY 1 LRAEBQUERSETQOURESTNAM0E.: GM1T9E4/0EAR DEPARTMENT: 0535 CEOXNPTCROAMCPT DLAATBE(:S:)06/27/1989 DATE COMPLETED: 06/23/1989 DPARTOEJECRTECENIO:VED9:9700061/32000/01969 DESC: LANDFILL STAB FOAM BIODEG DAY 28 PPHROONJEECTNO:LEA6D5:1-J77H8-S6T4O3C8K SM FAX NO: 651-776-6176 SAWPLE DATE ODE DESCRIPTION RESULT | MOL or(o8% G.1.) 1 BLANK 1 conTRoL 00c DISSOLVED ORGANIC CARBON <0.5 MG/L 2 BLANK IT (CONTROL boc 3 oo ` DISSOLVED ORGANIC CARBON <0.5 MG/L Leach 1 LeAcHATE - DISSOLVED ORGANIC CARBON 4.1 MG/L LEACH TT LEAGHATE o0c DISSOLVED ORGANIC CARBON 4.4 MG/L 5 SOLIDS I PRE-WASHED oo DISSOLVED ORGANIC CARBON <0.5 MG/L 6 SOLIDS IT PRE -WASHED oo DISSOLVED ORGANIC CARBON <0.5 MG/L 7 LEA+SOLID 1 7777 Doc DISSOLVED ORGANIC CARBON 3.7 MG/L LessoLID 11 "Teen o0c DISSOLVED ORGANIC CARBON 3.9 MG/L o REF SUB T Na BENZOATE o0c DISSOLVED ORGANIC GARBON <0. MG/L 10 REF SUB II Na BENZOATE o0c DISSOLVED ORGANIC CARBON <0. MG/L 001729