Document a39E6GNjzQB4VkV34kGV8mgM

MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920*1510(24 hours) GS 58* SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: TRI-ACT 1800 INHIBITOR DESCRIPTION: An aqueous solution of amines NFPA 704M/HMIS RATING: 3/3 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS 0 OTHER Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. C-nsult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # Cyclohexylamine Ethanolamine Methoxypropyl amine 108-91-8 141-43-5 5332-73-0 SECTION 3 PRECAUTIONARY LABEL INFORMATION APPROX.% 10-20 10-20 10-20 WARNING: Causes burns to skin and eyes. Combustible. Do not get in eyes, on skin, or on clothing. Wear goggles and face shield and rubber gloves when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * * * * * * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician at once. Remove to fresh air. Treat symptoms. Call a physician at once. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. SAL 000009831 PAGE 1 OF 8 P NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS BQ5S3-1 1 3B N INI A LCD MATERIAL SAFETY DATA SHEET PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1 510 (24 hours) 66 582 SECTION 6 TOXICOLOGY INFORMATION { CONTINUED ) COMMENTS: Redness, swelling, and blanching of the skin were noted. Scab formation was due to the corrosive action of the product. However, no systemic signs of toxicity were observed. SKIN SENSITIZATION: Cyclohexylamine can cause sensitization in susceptible individuals. * * * * PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): * EYE IRRITATION INDEX DRAIZE RATING: Corrosive * COMMENTS: Severe redness, swelling, and blistering of the conjunctiva were observed. Opacification of the cornea was also noted. Due to the extreme corrosive action of the test material, no Draize index rating could be assigned. * * OTHER TOXICITY RESULTS: Cyclohexylamine. A battery of tests including the * Ames test, sister chromatid exchange, cell transformation, mouse lymphoma and * rat hepatocyte/DNA repair provided inconclusive evidence of mutagenic activity.* SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: FLASH POINT: FORM: Liquid 8.2 lbs/gal. Completely 0.99 77 Degrees F 12.6 pH (at 1%) 11.2 5 cps 77 Degrees F 8 Degrees F 135 Degrees F (PMCC) ODOR: Amine ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 135 Degrees F (PMCC) ASTM D-93 * * EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbon * dioxide or other extinguishing agent suitable for Class B fires. Use water to * cool containers exposed to fire. For large fires, use water spray or fog, * thoroughly drenching the burning material. * 0 UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. * PAGE 3 OF 8 SAL 000009832 IMALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE ILLINOIS 60563-1 19B MATERIAL SAFETY DATA SHEET NALCO Emergency Telephone Number Medical (708) 920-1510(24 hours) G S 5,, 8 2 SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. For large indoor spills, evacuate employees and ventilate area. responsible for control and recovery should wear the protective equipment specified in Section 10. Those DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001 & D002. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O. S. CORROSIVE MATERIAL UN 1760 CONTAINS - CYCLOHEXYLAMINE SECTION 14 REGULATORY INFORMATION * The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Cyclohexylamine - Corrosive, combustible Ethanolamine - Corrosive, combustible Methoxypropylamine - Corrosive, combustible Cyclohexylamine = TWA 10 ppm, 41 mg/'m1 ACGIH/TLV Ethanolamine = TWA 3 ppm, STEL 6 ppm ACGIH/TLV 7.5 mg/m1 15 mg/m1 ACGIH/TLV SAL 000009333 PAGE 5 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVi 98 MATERIAL SAFETY DATA SHEET ALCQ PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510(24 hours) GS 582 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients arespecifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Ethanolamine - Section 111 Cyclohexylamine - Section 111 STATE REGULATIONS: * * * * * * * * CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: * * it * Cyclohexylamine Ethanolamine Methoxypropy1amine Water 108-91-8 141-43-5 5332-73-0 7732-18-5 * SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information, PAGE 7 OF 8 SAL 000009834 NAI.CO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NU-KOTE (041857-0218P -E0016293-4093 ) DATE OF ISSUE ! 12/13/89 PAGE SUPERSEDES 11/11/87 :G s 5 8 6 SECTION t - GENERAL INFORMATION CHEMICAL NAME 8 SYNONYMS N/A TRADE NAME & SYNONYMS NU-KOTE CHEMICAL FAMILY SILICONE SOLUTION FORMULA X<--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH CIV. OF NCH CORP ADDRESS (NUMBER. STREET. CITY. STATE & ZIP COOE) BOX 152170 IRVING. TEXAS 75015 PREPARED BY: RICHARD STOLLEY/T.S.CHEM. ! PRODUCT COOE NUMBER | EMERGENCY TELEPHONE NUMBER 4033 214-438-1381 SECTION II' HAZAROOUS INGREDIENTS THE HAZARDS PRESENTED BELCW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) NO HAZARDOUS INGREDIENTS PER 29 CFR 1910.1200(D) _HAZARO j TLV* J PEL* j CAS# SECTION 11A ' NON-HAZAROOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NO TRADE SECRET REGISTRY * 4O93S3-5020P MJ-KOTE SECTION III - PHYSICAL DATA PAGE : 02 BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM HG). VAPOR DENSITY (AIR-1) PH lOOK PERCENT, VOLATILE BY VOLUME <%> SOLUBILITY IN WATER VISCOSITY | 2 io ! 18 jo.6 j .0 j 60 i 11 SPEC GRAVITY (H20-1) 1 ! COLOR WHITE \ \ ODOR LEMON (1 CLARITY OPAQUE 1 1 1 EVAPORATION RATE (BU AC * 1 ) jO.IO j | COMPLETE :t.01S j NON -VISCOUS SECTION IV - FIRE AND EXPLOSION HAZARD FLA5H POINT (METHOD USED) NON-FLAMT.C.C. EXTINGUISHING MEDIA ALCOHOL" -- FOAM X<--FOAM j FLAMMABLE LIMITS 1 X<--C02 DRY X<--CHEMI CAL ,!j N/A t-EL WATER X-C--SPRAY SPECIAL FIRE FIGHTING PROCEDURES PRODUCT IS NON-FLAMMABLE. CHOICE OF EXTINGUISHING MEDIA DEPENDS ON NATURE OF THE FIRE. j UEL |N/A <--OTHER UNUSUAL FIRE & EXPLOSION HAZARDS SPRAY EXPOSED CONTAINERS WITH WATER TO PREVENT STEAM GENERATION. NFPA HAZARD RATING (O*I NS IGNIFI CANT; 1-SLIGHT2-MODERATE;3-HIGH;4-EXTREME}: O < -- HEALTH O <--FLAMMABILITY O <--REACT I V1TY <--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXP05URE) DIRECT CONTACT WITH THE EYES MAY CAUSE IRRITATION. SAL 000009835 (CONTINUED) SECTION X - STORAGE AND HANOL1NG INFORMAT1PAGE : 05 PRECAUTIONS TO BE TAKEN IN HANDLING ft STORING STDRE AT MODERATE TEMPERATURES. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USING. GS 5 86 SECTION XI - REGULATORY INFORMATION (PENNSYLVANIA RIGHT - TO-KNOW REQUIREMENT: N0N-HA2AROOUS INGREDIENT NAMES ARE WITHHELD AS A TRADE SECRET) CHEMICAL NAME N/A C.A.S. NUMBER UPpER % LIMIT THOSE INGREDIENTS LISTED teOVE ARE SUBJECT TC THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS ANC REAUTHOR IZATION ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED ANC LABELED FOR ROUTINE JANITORIAL WORN. DR THE PRODUCT IS USED ANC LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES), DR THE PRODUCT IS USED AND LABELED FDR MAINTAINING MCTOR VEHICLES. SECTION XII - TRANSPORTATION - (FOR FUTURE USE) APPLICABLE REGULATIONS _<--49 CFR <- * 1MCC SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER AEROSDL PROPELLANT(S) <--TARIFF 6 D <--IATA <--MILITARY AIR (A FR 71-4) | ID NUMBER | REPORT OTV | LIMITED OTY \ NET EXPLOSIVE WT. r \ N/A NU-KOTE________ SECTION XIII - REFERENCES PAGE : 06 THE INFORMATION CONTAINED HEREIN IS gASEC ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULT5 TC BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH CIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OB PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT JN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. 009836 SAL 000 MATERIAL SAFETY DATA SHEET MALCO PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical (708) 9201510(24 hours) &S 737 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5546 LIQUID DESCRIPTION: A blend of oxyalkyiated resin adduct esters and oxyalkylated alkylphenol formaldehyde resins in a heavy aromatic naphtha * w NFPA 704M/HMIS RATING: 2/2 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0 OTHER * 0= Ir.signif leant l = Slight 2=Moderate 3=High 4-Extreme * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient's) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 191C.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Heavy aromatic naphtha Naphthalene 64742-94-5 91-20-3 SECTION 3 PRECAUTIONARY LABEL INFORMATION 40+ 1-10 WARNING: Causes irritation to skin and eyes. Combustible. Prolonged inhalation * of vapor may be harmful. Do not get in eyes, on skin, or on clothing. Wear * goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. from heat and open flame. Keep container closed when not in use. Keep away * * Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * SECTION 4 FIRST AID INFORMATION EYES : SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician at once. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, PAGE 1 OF 7 SAL 000009837 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 196 N NALCO MATERIAL SAFETY DATA SHEET Emergency Telephone Number Medical (708) 920-1510 (24 hours) 6S737 SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) UNUSUAL FIRE AND EXPLOSION HAZARD: Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION * INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, * chromates, nitric acid, perchlorates, concentrated oxygen, permanganates; * which can generate heat, fires, explosions and the release of toxic fumes. * THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C02 may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory the volatility and toxicity are low. are generated, wear a NIOSH approved protection is not normally needed since If significant vapors, mists or aerosols or equivalent respirator. * * w For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended, * * * * VENTILATION: General ventilation is recommended. Additionally, local exhaust * ventilation is recommended where vapors, mists or aerosols may be released. * * PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles. A full slicker suit is recommended if gross exposure is possible. ' * * The availability of an eye wash fountain and safety shower is recommended. * If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * SECTION 11 SPILL AND DISPOSAL INFORMATION TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. PAGE 3 OF 7 000009838 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1199 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical (70S) 920-1510(24 hours) < S 7 37 SECTION 14 REGULATORY INFORMATION CONTINUED ) Naphthalene = TWA 10 ppm, STEL 15 ppm ACGIH/TLV 52 mg/m3 79 mg/m3 ACGIH/TLV Naphthalene = TWA 10 ppm, STEL 15 ppm OSHA/PEL 50 mg/m3 75 mg/m3 OSHA/PEL Heavy aromatic naphtha 100 ppm TLV Manufacturer's recommendation CERCLA/SUPERFUND, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ> substance and if 1,400 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802). SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (.TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) -- Delayed (chronic) XX Fire hazard -- Sudden release of -- Reactive hazard health hazard health hazard pressure hazard SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following ingredient(s), (with CAS * and % range) which appear(s) on the List of Toxic Chemicals. Naphthalene 91-20-3 1-10 TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: Consult Section 11 for RCRA classification. * * * * * * * * * * * * * * * * * * * PAGE 5 OF 7 sal 000009839 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 605B3-119B MATERIAL SAFETY DATA SHEET IMALCO PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical(708) 920-151 0(24 hours) S T 37 SECTION 17 BIBLIOGRAPHY ( CONTINUED ) CASARETT AND DOULL'S TOXICOLOGY, THE 3ASIC 5CIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Procter, N, H., and Hughes, J. P., eds., J. P, Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Remhoid Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E.f eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Fart 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration <CSHA>. THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200, PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 10/01/90 DATE PRINTED: 10/27/90 PAGE 7 OF 7 SAL 000009840 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 80563-1100