Document a14ER6Q1LM44ar6Rp9RjkY6pb

STLS E V E R N STL Chicago 2417 Bond Si reel University Park, IL 646B Tel: 708 534 5200 Tax: 703 534 5211 www.stl-inc.com SEVERN; TRENT ANALYTICAL REPORT JOE NUMBER: 332472 Prepared For :.. . . Wosoon Soiut io n s , I n c . 1400 Weston Way ':B u i l d i n g 'Wes~ Chester, FA 193 80-14 9 9 Project : Confidential Decacur Tennessee River A t t e n t i o n : J a i K e s a r i : TTT(3he..:.;; 12 ,/2 0 /2 0 04 Title: Project Manager E M a i l : r w r i ght.@sLl - i n e .c o m This Report Contains Leaders in Environmental Testing Date STT, C h i c a g o 2417 Bond Street University Park, IL 80466 PHONE: (708) 5 3 4 - 5 2 0 0 FAX, . : (708) 534-52.1 1 Pages Severn Trent laboratories, Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - TENNESSEE RIVER JOB# 232472 Data Summary................................................................1 Chain of Custody......................................................... 34 Case Narrative............................................................. 40 Raw Data...................................................................... 42 STL Chicago is part of Severn Trent Laboratories, Inc. S A M P L E IMF R HAT ! ON Dte: 12/20/2004 Job Number.: 232472 Customer...: Weston Solutions, Inc. Attn....---: Jai Kesari Project Number......... : 20004904 Customer Project ID___ : CONFIDENTIAL DECATUR Project Description___ : Confidential Decatur - Tehnessee River Laboratory ;Sample ID " Customer sample ID 232472-1 DL3-SD-LC1 232472-2 232472-3 DL3-SD-LOCQQ2 DL3-SD-LC003 232472-4 DL2-SD-L0C001 232472-5 DL2-SD-LGC002 232472-6 DL2-SD-LOC003 232472-7 DBC-SD-LOC001 232472-8 DBC-SD-LDC02 232472-9 DBC-SD-LOC003 232472-10 DOU-SD-LOC001 232472-11 DDU-SD-LOC002 232472-12 D0U-SD-L0C003 232472-13 DL1-SD-LOCOOI 232472-14 DLl-SD-LQC02 232472-15 DLl-SD-LOC3 232472-16 DMC-SD-LDC1 232472-17 232472-18 DMC-SD-LOC02 DMC-SD-LOC003 232472-19 DAA-SD-LOC006 232472-20 DAA-SD-LOC5 232472-21 232472-22 DAA-SD-LC004 DAA-SD-L0C003 232472-23 DAA-SD-LOC002 232472-24 DAA-SD-LDC001 ... Sample Matrix Soi L Soi L Soi l Soi 1 Soil soi 1 Soi 1 Soi 1 Soi l Soil Soi L Soi l soi l soi l Soi l Soi l Soi l Soi l Soi L Soi l Soil Soil Soi L Soi l Date . Sampled 12/01/2004 12/01/2004 12/01/2004 12/01/2004 12/01/2004 12/01/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 12/02/2004 . Time Date ^ Sampled. .= Received T ime .. Rete-iyed 13:00 12/04/2004 10:00 13:05 12/04/2004 10:00 13:20 12/04/2004 10:00 14:50 12/04/2004 10:00 15:10 12/04/2004 10:00 15:20 12/04/2004 10:00 08:50 12/04/2004 10:00 09:00 12/04/2004 10:00 09:15 12/04/2004 10:00 09:50 12/04/2004 10:00 10:00 12/04/2004 10:00 10:15 12/04/2004 10:00 11:50 12/04/2004 10:00 11:50 12/04/2004 10:00 11:55 12/04/2004 10:00 13:05 12/04/2004 10:00 13:10 12/04/2004 10:00 13:20 12/04/2004 10:00 16:00 12/04/2004 10:00 16:20 12/04/2004 10:00 16:35 12/04/2004 10:00 16:45 12/04/2004 10:00 17:00 12/04/2004 10:00 17:05 12/04/2004 10:00 STL Chicago Page 1 1 STL Chicago is part of Severa Treni Laboratories, Ine. M O h-l Hc/ STL Chicago is part of Severn Trent Laboratories, Inc. Job Nimber: 232472 CUSTOMER: Weston Solutions, Inc. Customer Sample ED Date Sampled..... Time Sampled..... Sample Matrix.... DL3-SD-LOC002 12/01/2004 13:05 Soil TEST METHOD Method Lloyd Kahn PARAMETE R/ T E S T D ES CR EPI ]ON % Solids Determination % Solids, Solid % Moisture, Solid Total Organic Carbon CSoils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS .PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 232472-2 Date Received...... 12/04/2004 Time Received...... 10:00 Date:12/20/2004 ATTN: Jai Kesari. . :SAMPLE RESULT 65.0 35.0 6200 FLAGS MDL 0.10 0.10 290 .... " -- T :-- -- : RL DILUTION .UHUS BATCH :DT- DATE/TIME /TECH 0.10 0.10 136297 136297 112/06/04 220Sclb '12/06/04 220S;clb 1100 mg/Kg 136694 12/07/04 1219 els In Description = Dry Wgt. Page 3 oC3 U si STL Chicago s part of Severn Trent Laboratories, Ine. Job Nunber: 232472 CUSTOMER: Weston Solutions,1 Inc. Customer Sample ID: DL3-SD-LOCC-D3 Date Sampled..... : 12/01/20D4 Time Sampled..... : 13:20 LABORATORY TEST RESULTS ' PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 232472-3 Date Received........ :12/04/2004 Time Received........ :10:00 Date:12/20/2004 ATTN: Jai (Cesari '"T &Cfj STL Chicago is part of Severn Trent Laboratoriesr ]nc. STL. Chicago m STL Chicago is part of Severo Treni Laboratories, Ino. STL Chicago o STL Chicago is part of Severn Trent Laboratori es, [ne. r- _l hz-n1 STL Chicago is part of Severn Trent Laboratori es, Inc. Job Number: 232472 ;:CUSTOMER': Weston :So lut ions i: Inc. Customer Sample ID: DEC-SD-LDC001 Date Sampled...... :12/02/2004 Time Sampled...... :05:50 Sample Matrix..... :Soi l TEST METHOD/ PARAMETER/TEST DESCRIPTION Method % Solids Determination % So lids , Soli d % Moisture, Solid Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid 00 LA3QRAT0RY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ED: 232472-7 Date Received........ :12/Q4/2D04 Time Received........ :10:00 Date:12/20/2004 ATTN: Jai Kesari SAMPLE RESULT Q FLAGS 42.7 57.3 270 MDL 0.10 0.10 aso Rl DILUTION UNITS BATCH DT DATE/TIME 't e c h 0.10 0.10 1 1 XW/o 136297 136297 12/06/04 2222 c lb 12/06/04 2222 clb 340 1 mg/Kg 136694 12/07/04 1513 els * n Description = Dry Wgt. Page 5 ________ TL Chicago STL Chicago is part of Severn Trent Laboratori es, [ne. Job Number: 232472 CUSTOMER : Weston Solutions , Inc. Customer Sample ID: DEC-SD-LQC002 Date Sampled...... :12/02/2004 Time Sampled...... :09:00 Sample Matrix..... :Soi l TEST METHOD Method Lloyd Kahn :PARAMETER/TEST DESCRIPTION % Solids Determination % Solids, Solid % Moisture, Solid Total Organic Carbon (Soils) TOC Average Duplicates, Solid O' LABORATORY TEST RESULTS . : : PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 232472-8 Date Rece ived...... : 12/04/2004 Time Received...... : 10:00 Date:12/20/2004 ATTN: Jaf Kesari SAMPLE RESULT- 44.5 55.5 28000 FLAGS MQL 0.10 0.10 1000 RL 0 1LiftEON- UH ITS BATCH -DT DATE/.T tttE TECH 0.10 0.10 136297 :136297 12/06/04 2225 c lb 12/06/04 2225 c lb 4000 mg/Kg 136694 12/07/04 540 els * In Description = Dry Wgt. Page 9 M u U -I STL Chicago is part of Severn Trent Laboratories, Inc. Job HuTiber: 232472 CUSTOMER: Weston Solutions. Inc. Customer Sample ID: DBC-SD-L0CDD3 Date Sampled...... :12/G2/2004 Time Sampled...... :09:15 Sample Matriji..... :Soil TEST WETHOP: !PARAMETER/TEST DESCRIPTION Method S. Solids Determination Si Solids, Solid Si Moisture, Solid Lloyd Kahn Total Organic Carbon {Soils} TOC Average Duplicates, Solid LABORATORY TEST RESULTS - : PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ED 232472-9 Date Received...... 12/04/2004 Time Received...... 10:00 s a m p l e ,r e s u l t ; FLAGS1 43.4 56.6 27000 0.10 0.10 720 RL 0.10 0.10 2300 Date:12/20/2004 ATTN: Jai Kesari UNITS BATCH DT DATE/T EHE TECH % 136297 12/06/04 22 28!cLb % 136297 12/06/04 2228 clb ira/Kg 13723S 12/13/04 1430 els * [n Description = Ory Ugt. Page 10 J=oC<utSJO U zn STL Chicago is part of Severn T rert Laboratori es, Inc. _| m STL Chicago is part of Severn Trent Laboratories, ]nc. Ci STL Chicago is part of Severn Trent Laboratories, ]nc. STL Chicago r*~t STL Chicaba is part of Severn Trent Laboratories, Inc- Job Number: 232472 CUSTOMER: Weston:Sollition s, :1nc Customer Sample ID: D L 1-SD-LOCO01 Date Sampled.......:12/02/2004 Time Sampled.......:11:50 Sample Matrix..... :Soil TEST METHOC; :PARAMETER/TEST:DESCRIPTION Method % Solids Determination % Solids, Sol id Moisture, Sol id Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT COMFIDENT[AL DECATUR Laboratory Sample ID: 232472-13 Date Received....... : 12/04/2004 Time Received....... : 10:00 Date:12/20/2004 ATTN Jai k'esari SAMPLE RESULT 'FLAGS 42.5 57.5 15000 :H&L 0.10 .10 500 RL DILUTION UNITS BATCH 0.10 0.10 h2000 % 136297 % 136297 mg/Kg 137233 DAtE/TlhlE TECH 12/06/D4 223? cLb 12/06/04 2239 clb 12/13/04 1604 z1s STL Chicago In Description = Dry Ugt. Page 14 STL Chicago is part of Severn Trent laboratories, Inc. Job Number: 2Z& 7 Z CUSTOMER: Weston Solutions, Inc. LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL OECATUR Date:12/20/2004 - ATTN: Jen Kesari in in STL Chicago is part of Severn Trent Laboratories, [no. o H 5TL Chicago is part of Severn Trent Laboratories, Inc. Job Wiriber: 232472 !CUSTOMER: Weston Solutions, Inc. :::::: V / Cus tomer Sairple[D : DMC -SD -LOCOi)1 Date Sampled...... :12/02/2004 TIme Sampled...... :13:05 Sample Matrix..... :Soil LABORATORY TEST RESULTS iRCJJEET: CONFIDENTIAL DECATUR Laboratory Sample ID: 232472-16 Date Received....... : 12/04/2004 Time Received....... : 10:00 ate:12/20/2004 ATTN: Jai Kesari STI, Chicago r- STL Chicago is part of Severn Trent Laboratories, Enc. Jab Nunber: 232472 CUSTOMER:: LJes-ta'n Solutions , 1n c . Customer Sample ID: DWC-SD-LQCD02 Date Sampled..... : 12/02/2004 Time Sampled..... : 13:10 Sample Matrix.... : Sei l LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL -DECATUR Laboratory Sample ID: 232472-17 Date Received.... . 1 2 / 0 4 / 2 0 0 4 Time Received___ 10:00 Date:12/20/2004 ATTN: Jai (Cesari STL Chicago STL Chicago is part of Severn Trent Laboratories, Ine. Job Number: 232472 CUSTOMER: Weston Solutions, Enc. Customer Sample ID: DMC-SO-LOCO03 Date Sampled...... :12/D2/20Q4 Time Sampled...... :13:2D Sample Matrix..... :Soil TEST METHOD Method Lloyd Kahn PARAMETER/TEST :DESCRIPT LOW % Solids Determination % Solids, Solid % Moisture, Solid Total Organic Carbon {Soils* TOC Average Duplicates, Solid O' LABORATORY TEST RESULTS PROJECT: CONFIDENTAl DECATUR Laboratory Sarnpl e ED: 232472-1B Date Received....... : 12/04/2004 Time Received....... : 10:00 Date:12/20/2004 ATTN: Jai Kesar5 . SAMPLE RESULT 33.B 61.2 12000 FLACS WEL. 0.10 0.10 310 RL DILUTION UNITS BATCH ,DT DATE/TTME TECH 0.10 0.10 136297 136297 12/06/04 2253 clb 12/06/04 2253 clb 2000 mg/Kg 137251 12/14/04 1135 els * In Description = Dry Ugt. Page 19 *0 U H-l Ht/5 STL Chicago is part of Severn Trent Laboratories, Inc. N on STL Chicago is part of Severn Trent Laboratories, Inc. Job Huinber: 232472 CUSTOMER : Weston Solutions f ]nc. - LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Date:12/20/2004 ATTN: Jai (Cesari : IN O h- STL Chicago is part of Severn Trent Laboratories, ]nc. Job Number: 232472 CUSTOMER: Weston Solutions Customer Sample ID: DAA-SD-LOC004 Date Sampled..... : 12/02/2004 Time Sampled..... : 16:35 Sample Matr ix .... : Soi L TEST METHOD Method Lloyd Kahn :PARAMETER/TEST DESCRIPTION % Solids Determination % Sclids, Solid % Me isture, SoL id Total Organic Carbon (Soils) TOC Average Duplicates, Solid rt LABORATORY TEST RESULTS : pRo.lFCT' cnNFrnputf Ai DF^AtffR : Laboratory Sample ID: 232472-21 Date Received...... : 12/04/2DD4 Time Received...... : 10:00 Date:12/20/2004 SAMPLE RESULT 24.4 75.6 59000 FLAGS MOL 0.10 0.10 57D RL ':D tLUT ]DM UNITS BATCH DT, DATE/TIM TECH 0.10 0.10 156298 136293 12/D/04 2342 c lb 12/06/04 2342 c lb 2200 mg/Kg 137251 12/14/04 1257 c Is * In Description = Dry Ugt. Page 22 ocCm U H STL Chicago is part of Severn Treni Laboratories, Ine. m -I Hoo STL Cilicago is part of Severn Trent Laboratories, Inc. TT U _l Hoo STL Chicago is part of Severn Trent Laboratares, Inc. Job Nunber: 232472 CUSTOMER: Weston Solutions,, Inc. Customer Sample lD :DAA-SD-LOCOD1 Date Sampled...... :12/02/2004 Time Sampled...... :T7:05 Sample Matrix..... :Soil TEST-METHOD PARAMETER/T.E ST.DESCRIPT ICM Method % Solids Determination % Solids, Solid % Moisture, Solid Lloyd Kahn Total Organic Carbon (Soils) ITOC Average Duplicates, Solid ur, LABORATORY TEST RESULTS PROJECT: CONRIDENTIAL DECATUR' Laboratory Sample ID: 232472-24 Date Received....... : 12/04/2004 Time Received..,___ : 10:00 Date:12/20/2004 ::ATTN : Jai Kesar i ;: SAMPLE RESULT 74.8 25.2 4000 READS MDL 0.10 0.10 280 RL DILUTION UNITS BATCH DT DA7E/TTME t e c h ; 0.10 0.10 136298 136298 12/06/04 2351 c lb 12/06/04 2351 clb 1100 mg/Kg 137251 12/14/04 1444 els STL Chicago * In Description = Dry tfgt. Page 25 STL Chicago is part of Severn Trent Laboratories, Itit. Job Number: 232472 LABORATORY CHRONICLE Date: 12/20/2004 CUSTOMER: Weston Solutions, Ihc. Lab ID: 232472-1 METHOD Method Lloyd Kahn Client ID; DL3-SD-LOC001 DESCRIPTION % Solids Deterinination Total Organic Carbon (Soils) Lab ID: 232472-2 METHOD Method Lloyd Kahn Client ID: DL3-SD-LOC02 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-3 METHOD Method Lloyd Kahn Client ID: DL3-SD-LOC03 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-4 METHOD Method Lloyd Kahn CLient ID; DL2-SD-L0C001 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-5 METHOD Method Lloyd Kahn Client ID: DL2-SD-LOC002 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-6 METHOD Method Lloyd Kahn CLient ID: DL2-5D-L0C3 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-7 METHOD Method Lloyd Kahn Client ID: DBOSD-LOCOOI DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472- METHOD Method Lloyd Kahn Client ID: DBC-SD-LOC02 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-9 METHOD Method Lloyd Kahn CLient ID: DBC-SD-LQC0U3 DESCRIPTION % Solids Determination Total Organic Carbon (Soils) Lab ID: 232472-10 CLient ID: DOU'SD'LOCOOI METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-11 CLient ID: DOU-5D-LOC002 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472'12 Client ID: DOU-SD-LOC003 METHOD DESCRIPTION Method % Solids Determination PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 12/04/2004 Sample Date: 12/01/2004 RUN# BATCH# PREP BT #CS) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2203 1 136694 136694 12/07/2004 1105 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/01/2004 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2203 1 136694 136694 12/07/2004 1219 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/01/2004 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2211 1 136694 136694 12/07/2004 1316 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/01/2004 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2214 1 136694 136694 12/07/2004 1343 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/01/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2217 1 136694 136694 12/07/2004 . 1410 DILUTION Date Recvd: 12/04/2004 sample Date: 12/01/2004 RUN# BATCH# PREP BT #($) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2220 1 136694 136694 12/07/2004 1504 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2222 1 136694 136694 12/07/2004 1518 DILUTION Date Recvd: 12/04/2P4 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #() DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2225 1 136694 136694 12/07/2004 1540 DILUTION Date Recvd: 12/04/2004 sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2228 1 137238 137238 12/13/2004 1430 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2231 1 137238 137236 12/13/2004 1504 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2234 1 137238 137238 12/13/2004 1518 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2237 DILUTION STL Chicago Page 26 26 STL Chicago Is part of Severn Trent Laboratories, Inc. Job Number: Z3Z47Z LABORATORY CHRONICLE Dat: 12/20/2Q04 CUSTOMER: Weston' Solutions, Inc. Lab ID: 232472-12 Client ID: D0U-SD-L0C003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-13 Client ID: DL1-5D-LOC001 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahh Total Organic Carbon (Soils) Lab ID: 232472-14 Client ID: DL1-SD-L0C002 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-15 Client ID: DL1-SD-L0C003 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-16 Client ID: DMC-SD-LOCQ01 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-17 Client ID: DMC-SD-LOCOD2 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-18 Client ID: DMC-5D-LC3 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-19 Client ID: DAA-SD-L0C006 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-20 Client ID: DAA-SD-LOC005 METHOD DESCRIPTION Method % Solids Dotermfnation Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-21 Client ID: DA-SD-LOC04 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-22 Client ID: DAA-SD-LOC003 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-23 Client ID: DAA-SD-LQC2 METHOD DESCRIPTION Method % Solids Determination PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 12/4/24 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 137238 137238 12/13/2004 1546 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2239 1 137238 137238 12/13/2004 1604 DILUTION Date Recvd: 12/04/24 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2242 1 137251 137251 12/14/2004 0954 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2245 1 137251 137251 12/14/2004 1036 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2248 1 137251 137251 12/14/2004 1052 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2251 1 137251 137251 12/14/2004 1117 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2253 1 137251 137251 12/14/2004 1135 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2256 1 137251 137251 12/14/2004 1153 DILUTION Date Recvd: 12/04/2004 Sample Date; 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136297 136297 12/06/2004 2259 1 137251 137251 12/14/2004 1218 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136298 13629 12/06/2004 2342 1 137251 137251 12/14/2004 1257 DILUTION Pate Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 136298 13Z98 12/06/2004 2345 1 137251 137251 12/14/2004 1355 DILUTION Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 136298 136298 12/06/2004 2348 DILUTION STL Chicago Page 27 27 STL Chicago is part of Severn Trent Laboratories, lncr Job Number: 232472 LABORATORY CHRONICLE Date: 12/20/2004 CUSTOMER: Weston Solutions, Inc. Lab ID: 232472-23 Client ID: DAA-SD-LOC002 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 232472-24 CLient ID: DAA-SD-LOC001 METHOD DESCRIPTION Method % Solids Determination Lloyd Kahn Total Organic carbon (Soils) PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 12/04/2004 Sample Date: 12/02/2004 RUN# BATCH# PREP ET #(5) DATE/TIME ANALYZED 1 137251 137251 12/14/2004 1426 DILUTION Date Recvd: 12/04/2004 Sampl RUN# BATCH# PREP BT #(S) 1 13629S 136298 1 137251 137251 Date: 12/02/2004 DATE/TIME ANALYZED 12/06/2004 2351 12/14/2004 1444 DILUTION STL Chicago Page 28 28 Job Number.: 232472 CUSTOMER: Heston Solutions, 1nc. QUALITY CONTRDL RESULTS PROJECT: CONFIDENTIAL DECATUR Report Date.: 12/20/2004 ATTW : .1fl Kes a ri .. Test Method... ^___ : Method Method Description. : % Solids Determination Parameter......... SO lds ; . . QC Lab ID Rageht MB 136Z97'001 MD 232472-1 Uni ts % % QC Result QC Result 0.1000 U 57.30000 Batch..... . 136297 Equipment Code... ' 1" ..... Analyst...: clb Test code.: :4S0LI0 True Value Orig. Value 56.60000 QC C a U . F * Limits 1.2 R 5.0 Date Time 12/06/2004 2200 12/06/2004 2206 ; Test.Method..... .' : Method Method ::Oesc ript ton.. : % Solids Determination Parameter.', : % solids c -t - Oc Lab ID Reagent MB 136298-001 Units % QC Result QC Result 0.1000 U Batch....... . .! 136298 Equipment; Code... Analyst......ctb Test Code. : ;4S0LlD True Value Orig. Value QC Calc. F * Limits ~ "" Date Time 12/06/2004 2300 !:Test Method. ] iV Lloyd Kahn . :Method Des oript ion,: Total. Organic Carbon (Soils) Parameter___ _ Organic Carbon,:Tot. (TOC) Batch......... .. : 136694 ::.... . Equipment Code, TOC4 .... Analyst. els Test Code, "TQC.:,..:: QC Lab ID Reagent Units lev 136694-002 I04KSTTC2 MB 136694-003 LCS 136694'004 I00FSTLK3 LCD 136694-005 100FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg ccv 136694'015 I04KSTTC2 CCB 136694-016 CCV 136694-015 I4KSTTC2 CCB 136694-016 mg/Kg mg/Kg mg/Kg mg/Kg QC ResuLt QC Result 1868.77 32.00 U 4241.04 4655.20 4241.04 2069.84 32.00 1968.90 32.00 U U True Value 2000.00 4780.00 4780.00 2000.00 2000.00 Orig. Value QC Calc. F * Limits Date Time 93 203.98 167.87 U 89 U 97 9 103 98 % 85-115 % 53-140 % 53-140 R 30 % 85-115 % 85-115 12/07/2004 0910 12/07/2004 0919 12/07/2004 0934 12/07/2004 0946 12/07/2004 1451 12/07/2004 1455 12/07/2004 1558 12/07/2004 1608 Test Method-.;... Method Descripti on.: Total Organic Carbon (Soils) Parameter..r,y Organic Carbon,.Tot. (TOC) QC Lab ID Reagent Units lev 137238-002 I04LSTTC2 MB 137238"003 LCS 137238-004 I00FSTLK3 LCD 137238-005 IFSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 1921.54 32.00 U 4777.02 3922.22 4777.02 CCV 137238-013 ID4CSTTC2 mg/Kg CCB 137238-014 mg/Kg 1942.20 32.00 U Batch.Equipment Code___ : TOC4 ..... Analyst...: Cls Test code.: t o c :: True Value 2000.00 4780.00 4780.00 2000.00 Orig, Value QC Calc. F * Limi ts Date T ime 96 201.57 190.34 U 100 U 82 20 97 % 85-115 % 53-140 % 53-140 R 30 % 85-115 12/13/2004 1348 12/13/2004 1352 12/13/2004 1413 12/13/2004 1421 12/13/2004 1628 12/13/2004 1633 STL Chicago Page 29 * %=% REC, R=RPD, A=ABS Di-ff., D=% Diff. 29 Job Number.; 32472 CUSTOMER: Weston Solutions, -Inc'-.! QUALITY CONTROL RESULTS /i/./.pROJEcT;: CONFIDENTIAL DECATUR Report Date.: 12/20/2004 ATTN: Jai Kesari1 Test Method....... : Lloyd Kahn . Method. Descriptron Total Organic Carbon (SoUs) ..... . Parameter...... ... : organic carbon. Tot- (TOC) ... Batch........... .: 137251 .Equipment Code... .: TOC4. ... Analyst. C.l5' ..... Test code.: TOC QC Lab ID Reagent Units ICV 137251-002 104LSTTC2 MB 137251-003 LC$ 137251-004 100FSTLK3 LCD 137251-005 IO0FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg c c v 137251-015 I04LSTTC2 CCB 137251-016 CCV 137251-015 I04L5TTC2 CCB 137251-016 mg/Kg mg/Kg mg/Kg mg/Kg QC Result 0C Result 1S45.40 32.00 U 5253.57 3766.01 5253.57 1912.79 32.00 1946.33 32.00 U U True VaLue 2000.00 4780.00 4780.00 2000.00 2000.00 Orig. Value QC Calc. F + Limits Date Time 92 202.37 182.86 U 110 U 79 33 96 97 Lfi i03n % 85-115 12/14/2004 0912 12/14/2004 0915 % 53-140 12/14/2004 0924 % 53-140 12/14/2004 0945 * R 30 % 85-115 12/14/2004 1238 12/14/2004 1244 % 12/14/2004 1622 12/14/2004 1626 .Test Method........ : Lloyd Kahn Method Desbript ien.: Total Organic Carbon (Soils) - ... 'Parameter.... ..... : TOC Average.'Duplicates .. QC Lab ID MS 232472-1 MSD 232472-1 Reageht Units I04KSTTC2 mg/Kg I04KSTTC2 mg/Kg QC Result 25233.05 25043.13 QC Result 25233.05 Batch........... .: 13694 Equipment Code... .:.T0C4 Analyst...: els Test'Code.-: T0CAV2 True Value 2000.00 2000.00 Orig. Value 11074.05 11074.05 QC Calc. F * Limits 93 % 53-140 105 % 53-140 12 R 30 Date Time 12/07/2004 1151 12/07/2004 1210 .Test Method..y . . y .-X-'L loyd Kahn Method Description.: Total Organic Carbon (Soils) Parameter. ;i i V j:TOC Ave rage Duplicates . : QC Lab ID MS 232472-9 MSD 232472-9 Reagent Units I04LSTTCZ mg/Kg I04LSTTC2 mg/Kg QC Result 35682,11 50360.91 QC Result 35682.11 Batch....... . ...,: 137238Equipment Code .... : TOC4 Analyst.. ! r'el Test- Cede : TOCAV2 True Value 2000.00 2000.00 Orig. Value 26794.36 26794.36 QC CaLc. F 59 108 59 * * Limits % 53-140 % 53-140 R 30 Date T ime 12/13/2004 1448 12/13/2004 1455 Test Method....... : Lloyd IC&h-h'-; ;;Method Description.; TotaL Organic Carbon (Soils) Parameter.......... : TOC Average Duplicates QC Lab ID MS 232472-14 MSD 232472-14 Reagent Units I04LSTTC2 mg/Kg I04LSTTC2 mg/Kg QC Result 28670.30 27895.17 QC Result 28670.30 Batch. . 137251 Equipment Code ___ : TOC4- Analyst... : els " Test Code. : TOCAV2 True value 2000.00 2000.00 Orig. Value 13600.90 13600.90 QC Calc. F 95 91 5 * Limi ts % 53-140 % 53-140 R 30 Date Time 12/14/2004 1019 12/14/2004 1026 S'l'L Chicago Page 30 * %=% REC, R=RPDr A=ABS Diff., \)=% Dl'ff. 30 QUALI! U R A N C E M E. T H 0 D $ R E F E E N : ES A N D N O T E S Report D'ie: 12/ 2/24 REPORT COMMENTS 1) A U p a g e s o f this report are integral parts o f t h e analytical data. Therefore, t h i s r e p o r t should be reproduced only in its e n t i r e t y . 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for landfill disposaL or incineration parameters. All other- solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting Limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen anaLyses are to be performed immediately after aqueous sample collection. Uheh these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on laboratory receipt. Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated Limit. < Not detected at or above the reporting limit. J ResuLt is less than the RL, but greater than or equal to the method detection Limit. B ResuLt is less than the CRDL/RL, but greater than or equal to the IDL/MDL. 5 Result was determined by the Method of Standard Additions. F AFCEE: Result is Less than the RL, but greater than or equal to the methoddetection Limit. Inorganic Flags (Flag CoLumn) ICV,CCV,ICB,CCB,ISA,ISB,CRI,CRA,MRL: Instrument reLated QC exceed the upper or Lower control Limits. * LCS, LCD, MD: Batch QC exceeds the upper or Lower control Limits. + MSA correlation coefficient is less than 0.995. 4 MS, MSD; The analyte present in the original sarnie is 4 times greater than the matrix s p i k e concentration; therefore, control limits are not applicable. E SD; Serial dilution exceeds the control Limits. H MB, EBl, EB2, EB3: Batch QC is greater than reporting Limit or had a negative instrument reading lower than the absolute value of the reporting limit. N MS, MSD: Spike recovery exceeds the upper or Lower control Limits. W AS(GFAA) Post-digestion spike was outside 35-115% control Limits. Organic Qualifiers (Q Column) U Analyte was not detected at or above the stated limit. N D Compound not detected. J Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuel pattern. 2 The chromatographic response does not resemble a typical fuel pattern. E ResuLt exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater- than reporting Limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or lower control Limits. EBl, EBZ, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the bLank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution wiLL be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The Lower of the two values is reported when the % difference between the results of two GC c o l u m n s ii Page 31 STL Chicago 31 a s s u r a n c e met hods R E F E R E N C E S A N D .ft.. D'.T. .. .".'.V R e p o r t D a t e : 12/20/ZQQm greater than 25%. Abbreviations AS Post Digestion spike (GFAA Samples - See Note 1 below) Batch D e s i g n a t i o n given to identify a specific extraction, d i g e s t i o n , preparation set, or analysis set CAP Capillary C o l u m n CCB Continuing Calibration Blank CCV Continuing Calibration verification CF Confirmation analysis of original Cl Confirmation analysis of A1 or D1 C2 Confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA L o w L e v e l Standard Check t GFAA; Mercury CRI Low Level Standard Check - ICP CV Calibration Verification standard Dil Fac Dilution Factor - Secondary dilution analysis D1 Dilution 1 D2 Dilution 2 D3 Dilution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard Low Level DSM Distilled Standard Medium Level EB1 Extraction Blank 1 EBZ Extraction Blank 2 EB3 di Blank ELC Method Extracted LCS E L D Method Extracted L C D ICAL Initial calibration 1CB Initial Calibration Blank ICV Initial Calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB Interference Check Sample B - ICAP Job No, The first six d i g i t s of the sample ID which refers to a specific client, project and sample group Lab ID An B number unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a m a t r i x free from the analyte of i n t e r e s t MB M e t h o d Blank or (PB) Preparation Blahk MD Method Duplicate M D L M e t h o d Detection Limit MLB Medium Level E x t r a c t i o n Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike D u p l i c a t e ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management S y s t e m CL IMS) PDS Post Digcstioh Spike (ICAP) R A R e - a n a l y s i s of original A 1 Re-analysis of D 1 A 2 R e - a n a l y s i s of D Z AS Re-analysis f D3 R D R e - e x t r a c t i o n of dilution RE R e - e x t r a c t i o n of original R C R e - extract ion confirmation RL R e p o r t i n g Limit RPD Relative Percent Difference of duplicate (unrouhded) analyses RRF Relative Response Factor RT Retention Time Page 12 STL Chicago 32 G U A L I T Y A s s u R 'A' N C E M E T H 0 D S.. . R E F E R E N C E S A' N N 0 T E; S' ... Re oort Oat 12/20/2004 RTW Retention Time Window Sample ID A 9 digit number unique for each six digits are referred as the job number SCB Seeded Control Blank 5D Serial Dilution (CaLcuLated when sample concentration exceeds 50 UCB Unsceded Control Blank SSV Second Source Verification Standard SLCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory ControL Samp Le LCDP pH Laboratory Control Sample Duplicate MDPH pH Sample Duplicate MDFP Flashpoint SampLe Duplicate LCFP Flashpoint LCS Gl Gelex Check Standard Range 0-1 GZ Gelex Check Standard Range 1-10 G3 Gelex Check Standard Range 10-100 GA Gelex Check Standard Range 100-1000 Nte 1: The Post Spike Designation on Batch DC for GFAA is designated with an "S" added to the current abbreviation used. Ex. LCS S=LCS Post Spike [GFAA); M$S=MS Post Spike (GFAA) Note Z: The MD calculates an absolute difference (A) when the sample concentration is Less than 5 times the reporting limit. The control limit is represented as +/ the RL. STL Chicago Page 33 33 CHAIN OF CUSTODY STL Chicago 34 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM 7 ^ .4 7 2 ^ -- - ... ---- _ p EXYGEN RESEARCH SAMPLE RECEIVING 3048 Research Drive State Coliege, PA 16801 PAGE _1_ of _2_ T: 814-231-8032 F: 814-231-1580 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari emall: i.kesariiwesto nsoIutions.com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: Charles Young P.O. #: Quotation #: SAMPLE ANALYSIS ExyLEMS # Client Sam pie Identif cation | j DL3 SD LOCQ01 0 041201 X DL3 SD LOG002 0 041201 3 DL3 SD LOC003 0 041201 A DL2 SD LOC001 0 041201 - - ...5____ DL2 SD LOC002 0 041201 (o DL2 SD LOC003 0 041201 1 DBC SD LOC001 0 041202 fc DBG SD LOC002 0 041202 DBC SD LOC003 0 041202 ______ L& U DOU SD LOC001 0 041202 ! DOU SD LOG002 0 041202 \X DOU SD LOC003 0 041202 & DL1 SD LOC001 0 041202 ______ it___ DL1 SD LOC002 0 041202 Collection Date 1-Dec-04 1-Dec-04 1-Dec-04 1-Dec-04 1-Dec-04 1-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2 -Dec-04 2-Dec-04 2-Dec-04 Collection T im e 13:00 XI 13:05 X 13:20 I T 14:50 X 15:10 X 15:20 X 8:50 X 9:00 X 9:15 X 9:50 X 10:00 X 10:15 X 11:50 X 11:50 X S a m p le M atrix 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment CHAIN OF CUSTODY cooler id n.: Fuelingwished By:^ Date Time Received By: S/ /rs t Cooler Temp. (DC) Date Time j. h>>o ------------------------------------------------------------------------_-_-_-_-_-_-m m Grab Sample C o m p o site No. of Containers TOC Comments X X X nXr X [TT X X X ** X X X 1 1PROJECT REQUIREMENTS Results Deadline: Sampfe Results Only Add Case^iarrative Add Quality Control Summary Add Calibration Summary 1 Add Raw Data LJ__ 1 Other: L Chicago CHAIN OF CUSTODY / ANALYSIS REQUEST FORM EXYGEN RESEARCH SAMPLE RECEIVING T: 314-231-8032 F: 814-231-1580 3048 Research Drive State Coliege, PA 16801 PAGE 233.4-72 \o 2 of 2 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jar Kesari email: i.kesariweston solutions, com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: diaries Young P.O. #: Quotation U. C o m p o site No. of Containers TOC SAMPLE ANALYSIS ExyLIMS # IS Lb n tft 11 *LO %\ 73 it Client Sam pie Ldentif cation DL1 SD LOC003 0 041202 DMC SD LOC001 0 041202 DMC SD LOC002 0 041202 DMC SD LOC003 0 041202 DAA SD LOC006 0 041202 OAA SD LOCOOS 0 041202 DAA SD LOC004 0 041202 DAA SD LOC003 0 041202 DAA SD LOCG02 0 041202 DAA SD LOC001 0 041202 Collection Date 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 2-Dec-04 Collection Tim e 11:55 13:05 13:10 13:20 16:00 16:20 16:35 16:45 17:00 17:05 4> a E CO Otn E X X X X X X X X X X Sam ple M atrix 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment 1 Sediment Comments X X X X X X X X X X CHAIN OF CUSTODY Cooler ID No.: Relinquished By; / Date Time fZ: jo Received By: ' VL 0 Cooler Temp. (<!C) Date Time i L f U - toe ___I PROJECT REQUIREMENTS |Results Deadline: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: I j SP 15 J _l H S am pfe Lot#: Sam ple No. H 2y ! - 2-^7 Analysis le t STL Chicago internai Sampie Custody Transfer Record Client: R elinquished by: R e c eiv ed by: ) jlJ r 6 D a te Tim e / V 7 /^ / Com m ents l> CHI-22-11-QQ1/C-1/99 STL Chicago rpjsckl Job Sample Receipt checklist Report Job Number.: 232472 Location.: 57222 Check List Number.: 1 Description.: Customer Job ID.... : Job Check List Date.: 12/04/2004 Project Number.: 20004904 Project Description.: Confidential Decatur Tennessee River Customer...... : Weston Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) Comments V2 Date of the Report..: 12/20/2004 Project Manager.... : rew Chain-of-Custody Present?.................. ....... Y Were samples dropped off at or picked up by STL?.. N Custody seal on shipping container?....... ....... Y ...If "yes", custody seal intact?................. Y custody seals on sample containers?............... N ...If "yes", custody seaL intact?................. Samples iced?....,... ........................ Y Temperature of cooler acceptable? 14 deg C +/- 2). Y 4.1 Samples received intact (good condition)?........ Y Volatile samples acceptable? (no headspace).... . correct containers used?.......................... Y Adequate sample voLime provided?................... Y Samples preserved correctly?...................... Y Samples received within holding-time?............. Y Agreement between COC and sample labels?......... Y Radioactivity at or below background levels?..... Y A Sample Discrepancy Report (SDR) was needed?.... N If samples were shipped was there an air bill #?., Y Sample Custodian Signature/Date....... Y Page 1 STL Chicago 38 . USAirbill Express TrtrvFereoiwdnwrj 8 1 * 7 0 1 7 2 5 3 3 5 ^ 1 From ate a - 3 -< w i 4a Express Package Service &T FadExPriorityOvernight f - X .'-k s tfb *.n c o ro tf r--1 FedExStandard Oxernigftt 1-- - Ktabus * sa (" J FedExFeat (hernight -- - 1-- ------------ Sender's i % Noma :- S V V -iJ K Compary \ aJ c^ t o *J 25L* 5SZ -a IS1/ Phone rxjtb , Fed6r2Da'/ -- 1 S^tirtltairaSiii*,* I*-I Fuve-ddEtxarEexsprieffs*s Saner liT.'Efat^r^rrig^'ihie.^nrisiatigPrB-Ectrinti-- Freight Service Psctawsekw iaia. ** T*m t ta rtk n * Address / V c i c ^ S r A T C '`b x u j b lIefJssa-ydF**reight -- 1SF^exdn6lrt2usDta-sysiFreight | I FedExSOai1Freight 1-----1 TfV-j i i s r e a-3T(~* J~ l _j\~ dDadvadiirtimtE.f ''I . tiff-- P FedEx Pafc* V ciiicfiiE .d iT iiifa t, P FedEx Btw f j FedEx j^ Q cQhthar Tube FnEn Isrpt P-iu a d r e c ti EhjriJyP^. YourInternal Brfliag Reference 8 SpecialHendlmg Fe*iatirtssinSediw3. "i r i HOW W eaker --: HOUJSgfcuiay 3 ~7B S jf.fs c ftt y ; .> v Ft5Lt fTH t( rQrnChilV(hT+iit^^TtToT-.Tr'.frtfjJEcrxtilfJ.ZcBlt>rt('tpci,H3faiis:d,&> 1 . ahrt.FdendfeEtxfeinfvc a tk r ncUrw$\$**nc$t _J -BtFedCTEocBtiwi ADrvtau.fcfthtif[a)n^dl0narfar&I3Payririf^ Q diS to^rK Company TttfcKh" tbgaL V ic& s I_____Deesitsthlnip>nbaOfGlrtncuaatat*aoitnetcfJaundnarouxam*! I Il-- i1 Nn I---1IX're5ts:Htn .1-- iIiVveisB'uDilvaid iI-- I DDrrivlticle^.ljXWH. Haopian -1 '5 '6Address i'V_________ tx'x f P r E S i p iS c V C ic lE iE L :. .il.ft^ ire d O i i } j u i s k j s i K J i i i l n '1l r i l - - j . > T b o : t - ^ ; !i n ^ s j ( i t t s ^ a d ! ? Cafgp Axxraft Only J ,Py>ntiit & u _ ___________________________ ,' 2 S f * G W1 o ^ ia t i M w t i PA. h x o s a r l.D . ZIP coI bo. D^Tm\^jr.t?Tfcn Address lesii^ucfciehiAildrasiEtthctolu.lacstiuj'lrfeu*goI'iesten. 'liicirIrf* L j fe cip ia(ri l_ j Third Party L j CreditCant |_J CasivCJiecf; f. LkUs/CxisbtTV/ CjM-t^ Sim'Zp- ap t e ly k f U Total Pj JoW W eiglTt m a lO e c lm lH u e t j TMaldwgee I fl< t? 0 1 7 3 2 3 3 5 ^ L-# < D ' ___S _________ _____ ^0 rQ'jVitilft.'itriijttiilQLi.jriwi^ai'i&ii'trofcnijliEr'.'iiHiSEttK.^idaai;. 8 Signto i '. ^ I_O_a_&_Zv,Atii*-- | L L Br a ;n P y im a rtu n a : m to faw arihs sttpirenl U.WJU n t& iiiH J EyrtCuT:a:d ift'te I: irtUnrir,' tiuH itiitu harness From i r r / i a i l u j ctoins. Quesiwns? tfisjt rxjpWjr t a # atfedexjcam . or o k la x e c F tte i Ija rS K 3 K ) Fir,- Uit ..V I'F j I # l t U ' C 'l m - S i i ] . K t i 'ftM lK e. ll i A. i.'a.IA v- ST1-Chicago CASE NARRATIVE Client: Job #; STL Chicago Wet Chemistry Case Narrative Weston Solutions, Inc. 232472 Date Rec'd: 12/04/04 This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average o f the sample burns is reported. 2. The method-recommended holding time of 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis. 3. The TOC calibration curves and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit. 5. The LCSs were within acceptance limits, although the RPD between the LCS and LCD in batch 137251 was high, at 33. 6. Duplicate matrix spikes were done on samples 232472-1,9, and 14. The recoveries were all within acceptance limits, except for the MS on sample 9, which was low, at 59%, As a result, the RPD between the MS and MSD on that sample was high, at 59. Please see the Quality Control Results pages for additional detail. 7. One burn of sample 232472-11 was an outlier and not included in the average. It is included in the raw data. Occasionally, the analyst failed to insert the sample boat into the furnace within the allotted time window, and the bum was cancelled or recorded a nondetect. Those burns are crossed out in the raw data. Wet Chemistry Section Manager STL Chicago 41 RAW DATA pC *** RUN LOG *** 1 0 <VZ ) 12/13/04 15:40 Ttal Organic carbon SoilO Method Code..: TOCS Batch Code.*.: 136694 Status_______ : RVWD Batch Date... : 12/09/04 Batch Tirine... : 1552 User Name.. .. : els QC Code___ TOCS Cale Code.. Location Code..: 57222 Equipment Code.: T0C4 Import Code___ : TEST CODE TTTTTT T T T T TT 00000CCC II1 C cC cC c C SssCC C s s2 3 4 A A A 2 A S VVV V 2A 234 2 2 SAMPLE: Grp Pos sample ID Di Lution TEST POS Date / Tim e 123 4 5 6 7 11 12 22 789 0 12 11 ICAL I04KSTTC1 0 12 __ ICV_I04KSTTC2_ 12/7/04 0910 0 13 __ MB__ 12/7/04 0919 0 14 LCS I00FSTLK3 3 12/7/04 0934 0 15 LCD I00FSTLIC3 3 12/7/04 0946 0 16 232483J _S__ 12/7/04 1013 0 17 232483_2_S__ 12/7/04 1039 0 18 232472JJ___ 12/7/04 1105 0 19 232472_1_S_MSJ04KSTTC2_8 12/7/04 1151 0 1 10 22472J _S_MSD_I04KSTTC2_8 12/7/04 1210 0 1 11 232472,,2_S_ 12/7/04 1219 0 1 12 23247Z_3_S__ 12/7/04 1316 0 1 13 232472_4_S__ 12/7/04 1343 0 1 14 232472 5 S 12/7/04 1410 0 1 15 __ CCV_I04KSTTC2_ 12/7/04 1451 0 1 16 1 17 ___ CCB__ 232472_6_iS___ 12/7/04 1455 0 12/7/04 1504 0 1 18 232472 7 S 12/7/04 151 0 1 19 232472_8 S__ 12/7/04 1540 0 1 20 ___CCV_I04KSTTC2_ 12/7/04 1558 0 1 21 __ CCS__ 12/7/04 1608 0 STL Chicago Page 1 43 *** QD Sunna ry (V2 ) Total Drgam'c Carbon (Soils) Report Date: 12/13/04 15:42 Method Code..: TOCS Batch Code...: 136694 Status...... : RVWD Batch Date...: 12/09/04 Batch Time*..: 1552 User Name.,..: cLs OC Code...*___ : TOCS Calc Code......: TOCS Location Code..: 57222 Equipment Code.: T0C4 Import Code____: Grp Smp Sample ID Pos Test Result Known Original Alternate QC Res F OC Res F 12 13 ICV I04KSTTC2 .__ M B _ 1 TOC 1 TOC 1868.77 -2.20 2000 93 1 4 __ lcs_ io ofstlk3_3 1 5 ___LCD_I0DFSTLK3i_3 1 9 232472_1_S_MSJ04K$TTC2_8 1 10 232472_1_S_MSD_I04KSTTC2_8 1 15 CCV 04KSTTC2 1 TOC 4241.04 4780 1 TOC 4655.20 4780 5 TDCAV2 25233.05 2000 5 TOCAV2 25043.13 2000 1 TOC 2069.84 2000 -2.20 -2.20 11074.05 11074.05 4241.04 25233.05 89 97 93 105 103 9 12 1 16 __ CCB__ 1 TOC -2.75 1 20 __ CCV_I04KSTTC2_ 1 21 __ CCB__ 1 TOC 1 TOC 1968.90 -1.70 2000 9B STI, Chicago Page 1 44 RAU TEST DATA <V2 ) Total. Organic Carbon (Soils) Method Code.. TOCS Batch Code .. 136694 Status--- RVUD Batch Date,.: 12/09/04 Batch Time...: 1552 User Name___ : ela SAMPLE : G rp Pos Sample ID 11 ICAL I04KSTTC1 12 ICV 104KSTTC2 13 MB 14 LCS JD0FSTLK3 3 15 LCD IQQFSLK3 3 1 6 232483 1 S 1 7 232483 2 S 1 & 232472 1 S 1 9 232472 1 S MS I04KSTTC2 8 1 10 232472 1 S MSD I4KSTTC2 8 1 11 232472 2 S 1 12 232472 3 S 1 13 232472 4 S 1 14 232472 5 S 1 15 CCV I04KSTTC2 1 16 DCB 1 17 232472 6 S 1 18 232472 7 S 1 19 232472 8 S 1 20 CCV I04KSTTC2 1 21 ___ CCB__ QC Code... Cale Code. Location Code..: 57222 Di Lution TOC mg/Kg TOC2 ms/Kg Report Date: 12/13/04 15:40 Equipment code,; TOC4 Import Code--- : T0C3 mg/Kg T0C4 mg/Kg TOCAV2 mg/Kg 1868.77 -2.20 4241.04 4655.20 762480.60 898082.25 11541.37 25233.05 25043.13 6433.21 21321.16 15123.74 20268.54 2069.84 -2,75 20722.28 26748.51 29178.00 1968.90 -1.70 944960.50 585017,33 10606.73 5934.45 18288.57 12654.71 15539.18 17023.62 26871.02 27369.32 853720.55 741549.79 11074.05 25233.05 25043.13 6183.83 19804.86 13889.22 17903.86 18872,95 26809.76 28273.66 STL Chicago Page 1 45 *** RAW TEST DATA (V2 ) Total Organic Carbon (Soils) Method code.. TOCS Batch Code... 136694 Status RVUD Batch Date...: 12/09/04 Batch Time...: 1552 user Name--- : els SAMPLE : Grp Pos SampLe ID 11 ICAL I04KSTTC1 12 ICV I04K5TTC2 13 MB 14 ICS ID0FSTLK3 3 15 LCD I00FSTLK3 3 1 6 232483 1 S 1 7 232483 2 S 1 8 232472 1 S 1 9 232472 1 S MS I04KSTTC2 8 1 10 232472 1 S MSD IQ4KSTC2 8 1 11 232472 2 S 1 12 232472 3 1 13 232472 4 S 1 14 232472 5 S 1 15 CCV I04KSTTC2 1 16 CCB 1 17 232472 6 S 1 18 232472 7 S 1 19 232472 8 S 1 20 CCV I04KSTC2 1 21 CCB QC Code... ___ : TOCS CaLc Code. TOCS Location Code..: 57222 Di Lut ion T0CAV3 mg/Cg TOCAV4 mg/Kg Report Date: 12/13/04 15:40 Equipment Code.: TQC4 Import Code __ : TOCR1 ug TOCRZ ug TQCR3 ug 93.4336 -0.3515 106.4501 141.9835 381.2403 359.2329 72.7106 166.5381 187.8235 95.2115 142.8518 104.3538 93.2353 103.4921 -0.4399 132.6226 141.7671 154.6434 98.4449 -0.2721 188.9921 175.5052 89.0965 122.2496 126.1911 88.5830 88.5733 93.6299 171.9745 128.6358 S'I L Chicago Page 2 46 *** RAW TEST DATA (V2 ) Total Organic carbon [Soils) Method Code.. : TOCS Batch Code t-r: 136694 Status--- : RVUD Batch Date...: 12/09/04 Batch Time...: 1552 User Name___ : cLs SAMPLE: Grp Pos Sample ID 11 ICAL I04KSTTC1 12 ICV I04KSTTC2 13 MB 14 ICS I00FSLK3 3 15 LCD I00FSTLK 3 1 6 232483 1 S 1 7 232483 2 S 1 8 232472 1 S 1 9 232472 1 S HS I04KSTTC2 8 1 10 232472 1 S MSD I4KSTTC2 8 1 11 232472 2 S 1 12 232472 3 5 1 13 232472 4 S 1 14 232472 5 S 1 15 CCV I04KSTTC2 1 16 CCB 1 17 232472 6 S 1 18 232472 7 S 1 19 232472 8 S 1 20 CCV I04JSTTC2 1 21 __ CCB__ QC Code... . TOCS Calc Code. ___ : TOCS Location Code..: 57222 Di luti on TOCR4 ug UT1 9 Report Date: 12/13/04 15:40 Equipment Code.: TOC4 Import Code___ : WT2 WT3 UT4 999 0.05 0.16 0.0251 0.0305 0.0005 0.0004 0.0063 0.0066 0.0075 0.0148 0.0067 0.0069 0.0046 0.05 0.16 0.0064 0.0053 0.0053 0.05 0.16 0.0002 0.0003 0.0084 0.0206 0.0069 0.0070 0.0057 0.0055 0.0064 0.0047 STL Chicago Page 3 47 *** RAW TEST DATA *** Total Organic Carbon (Soi li) M e th o d C o d e .. TOCS Batch Code * 136694 S ta tu s .. ,. RVLJD B a tc h D a t e . . : 12/09/04 B a tc h Time...: 1552 User N am e ,. . . : e l s SAMPLE: Grp Pos S am ple ID 11 ICAL I04KSTTC1 12 ICV I04KSTTC2 13 ME 14 Les I0FSTLK3 3 15 LCD I00PSLK3 3 1 6 232483 1 S 1 7 232483 2 S 1 8 232472 1 S 1 9 232472 1 S MS I04KSTTC2 S 1 10 232472 1 S MSD I04ISTTC2 6 1 11 232472 2 S 1 12 232472 3 S 1 13 232472 4 S 1 14 232472 5 S 1 15 CCV IQ4KSTC2 1 16 CCB 1 17 232472 6 S 1 10 232472 7 S 1 19 232472 S S 1 20 CCV I04KSTTC2 1 21 CCB QC code... Calc Code. L o c a tio n Code..: 57222 Dilution DLFAC N/A TCS mg/Kg 3,2000 1.0000 6.3745 5.2459 457.1429 457,1429 21,7687 24.2424 21.3333 9.0395 23.5294 23.0216 31.0680 3.2000 1.000Q 26.8908 27.3504 32.0000 3.2000 1,0000 (V2 ) Report Date: 12/13/04 15:40 Equipment Code.; TQC4 Import Code___ : TCS2 tPs/Kg TCSAV2 mg/ leg TICS mg/Kg S'I L Chicago Page 4 48 Calibration Report Print Date/Time: 2004/12/08 8:19:33 Cal. Curve ID: SOILCURVE Created: 11/11/200413:10 Calibration Factor (m): 1.043e+05 Y Intercept (b): -179095 rsquared: 0.99768 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -2842 0.000 1.690 No Sample Det 11/11/200410:41 10ugramC 1030911 10.000 11.603 11/11/200411:09 20 ugram C 1851054 20.000 19.468 11/11/2004 11:17 40 ugram C 5217374 40.000 51.750 11/11/2004 11:43 80 ugram C 7733118 80.000 75.875 11/11/200412:07 120 ugram C 11648646 120.000 113.423 11/11/200412:17 200 ugram C 19711002 200.000 190.738 11/11/2004 12:26 300 ugram C 30775554 300.000 296.843 11/11/200412:50 400 ugram C 42430328 400.000 408.608 Endpoint Time 11/11/2004 13:09 STL Chicago 49 Multiple Analysis Report Print Date/Time: 2004/12/08 16:11:31 Sample ID Result Std. Dev. RSD Mode ALT icv 93.4386 TC ICB-MB -0.3515 TC LCS 106.4501 TC LCD........................ ......... 141.9835.............. ...TC .. 232483-1 819.0103 TC 232483-1 -0.4330 TC 232483-1................ ............ 381.2403... ........... TC 232483-1 188.9921 TC 232483-2 359.2330 TC 232483-2................ ............ 175.5052... ........... TC 232472-1 72.7106 TC 232472-1 89.0965 TC 232472-1 ms.......................... 166.5381... ........... TC 232472-1 msd 187.8235 TC 232472-2 95.2115 TC 232472-2................ ............ 122.2496... ........... TC 232472-3 411.0267 TC 232472-3 142.8518 TC 232472-3................ ............ 126.1911... ........... TC 232472-4 104.3538 TC 232472-4 88.5830 TC 232472-5................ ............93.2353... ........... TC 232472-5 88.5733 TC CCV 103.4921 TC CCB........................ .........-0.4399............... ...TC .. 232472-6 132.6226 TC 232472-6 93.6299 TC 232472-7................ ............141,7671... ........... TC 232472-7 -1.0862 TC 232472-7 171.9745 TC 232472-8.............................154.6434... ........... TC 232472-8 128.6358 TC CCV 98.4449 TC CCB........................ .........-0.2721............... ...TC .. STL Chicago 50 Detailed Analysis Report Print Date/Time: 2004/12/08 16:12:28 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12080900 >J Timestamp: 12/08/2004(^9; 1 0 / Sample Type: Cal. Verificau&rr^ Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 93.4386 93.4386 9504832 0.726 1. /57 430 Lssi Message: Endpoint Timeout Sample ID: 1CB-MB Method. bo3t Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: ' 12G80915 Timestamp: 12/08/2004 69:19 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3515 -0.3515 10888 1.24? 1.123 120 Last M e ssag e : M o Sa m p le Detected S a m p le ID: L C 3 MeihCiu. Lost Oper-.-iyf ij . o A R O L ivi o d e : TC Q nna Iiinn L?^ .a !!inn T rfiHii. -t (IEOH C n i -i /'j a "7-0 jj/in, !D . * A - i L ___l . i'J U . i^ " L v L' J J U c fl '-J ] 1 !: : r ^ iC r - rJ ' , " 1 A a r O u t i t C tL U l 1 U 1" . iviuoe. Filename. jl i U U U G *n li oaiViple ivijc;. o a t u O l e Bsseitue Baseline -,4-1 n p o e -141 iipic i V 'j J -1 Tin re > M f! Oi ! fi. STL Chicago 51 Cal. Curve: SOILCURVE Operator ID: CAROL Timestamp: 12/08/2004 10:47 Rep # ppm C u g C R^w Data Beginning Ending Integration Baselihe. Baseline Time 1 175.5052 175.5052 1 8 3 2 7 3 5 ^ 1.519 2.518 327 Sample ID: 232472-1 Method: boat Cat. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081100 /" " 'x Timestamp: 12/08/200411:05/ Sample Type: Sample I / R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 72.7106 72.7106 7607989 7.802 8.790 248 Sample ID: 232472-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081109 Timestamp: 12/08/2004 11:15 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 89.0965 89.0965 9316705 0.968 1.965 297 Sample ID: 232472-1ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081144 Timestamp: 12/08/20 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 166.5381 166.5381 17392272 2.050 3.046 299 Sample ID: 232472-1 msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081203 Timestamp: 12/08/20' Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 187.8235 187.8235 19611904 1.336 2.335 411 Sample ID: 232472-2 Method: boat Cal. Curve: SOILCURVE Mode: TC Filename: 12081214 Timestamp: 12/08/2' s 12:19 I ST1. Chicago 52 Operator ID: CAROL Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 95.2115 95.2115 9954366 1.491 2.490 265 Sample ID: 232472-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081225 Timestamp: 12/08/2004 12:32 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Baseline Baseline Time 1 122.2496 122.2496 12773887 1.173 2.17 1 315 Integration Sample ID: 232472Method: boat Cal. Curve: SOlLCUR> Operator ID: CAROL p Mode: TC . O Filename: 12081258 Timestamp: 12/08/2004 13:09 , r Sample Type: Sample R e p # ppm C u g C FtawData Beginning Ending Integration Baseline Baseline Time / 1 411.0267 411.0267 42887416 1.120 3.121 480 Last Message: Endpoint Timeout Sample ID: 232472-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081310 Timestamp: 12/08/201 Sample Type: Sample "\ 13:16 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 142.8518 142.8518 14922276 2.492 3.487 280 Sample ID: 232472-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081327 Timestamp: 12/08/2004 13:33 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 126.1911 126.1911 13184911 0.913 1.911 Integration 287 Sample ID: 232472-4 Mode: TC STI, Chicago S3 Method: boat Cal. Curve. SOILCURVE Operator ID: CAROL Filename: 12081337 Timestamp: 12/08/2 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 104.3538 104.3538 10907726 0.986 1.982 290 Sample ID: 232472-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081355 Timestamp: 12/08/2004 14:01 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 88.5830 88.5830 9263153 0.995 1.994 258 Sample ID: 232472-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081404 X "" Timestamp: 12/08/2004^14:10 VSample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 93.2353 93.2353 9748293 1.024 2.019 282 Sample ID: 232472-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode. TC Filename: 12081416 Timestamp: 12/08/2004 14:21 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 88.5733 88.5733 9262139 0.790 1.787 276 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081445 Timestamp: 12/08/201 1 14:51 Sample Type: Cal. Vrifie ition Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 103.4921 103.4921 10613010 0.820 1,819 315 Sample ID: CCB Method: boat Mode: TC Filename: 12081452 STI, Chicago 54 Cal. Curve: SOILCURVE n n / % n Timestamp: 12/08/20o/l4:S5'") Operator ID: CAROL C ' ' ' Sample Type: Sample V R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4399 -0,4399 -20108 1.407 1.134 120 Last Message: No Sample Detected Sample ID: 232472-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081458 Timestamp: 12/08/20) Sample Type: Sample 1 15:04 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 132,6226 132.6226 13855682 1.051 2.050 304 Sample ID: 232472-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081506 Timestamp: 12/08/2004 15:11 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 93.6299 93.6299 9789441 1,386 2.385 260 Sample ID: 232472-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081512 Timestamp: 12/08/2 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending In Baseline Baseline Time 1 141.7671 141.7671 14809163 1.436 2.435 293 Sample ID: 23247^-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081523 Timestamp: 12/08/2004 15:26 Sample Type: Sample Rep # ppm C ug C \R a w Data Beginning Ending Integration taseline Baseline Time 1 -1.0862 -1.0862 -87503 2.763 1.222 120 aLast Message: No Sample DeWtecL ^C. t vJ- STL Chicago 55 Sample ID: 232472-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081528 Timestamp: 12/08/2004 15:34 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 171.9745 171.9745 17959180 0.856 1.856 324 Sample ID: 232472-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC . Filename: 12081535 Timestamp: 12/Q8/20W 15:40 VSample Type: Sample . Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 154.6434 154.6434 16151901 1.363 2.361 300 Sample ID: 232472-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081542 Timestamp: 12/08/2004 15:48 Sample Type: Sample R e p # p pm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 128.6358 128.6358 13439838 1.356 2.351 278 Sample ID: CCV Meth od: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081550 y* Timestamp: 12/08/2004 15:58 / Sample Type: Cal. Verificacin / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 98.4449 98.4449 10086693 1.084 2.084 301 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12081606 X_ Timestamp: 12/08/200446:08 j Sample Type: Sample / j R e p # p pm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.2721 -0.2721 -2606 1.000 0.970 120 Last Message: No Sample Detected STI. Chicago 56 STL C h ica g o Page No - 99 TO C in S o ils Book No.: ^ 7 ^ 7 M ethod: L lo yd K ahn Instrument Phoenix 8000 fT Q C 4 ) LabNat Batch: 2/3 6 & f `f CgjcylatiOQSi Date of Standard Curve: l l / t t / # ? TOC(mg/kg) =* ug C / grams sample Book 3 7 ^ 7 Rage# `f C MS, MSD Known Cona (mg/kg) 3 100 ugC/gram s sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rea 3 [observed mg/kq - avq. sample result fmo/ka)1 x 100 known concentration in mg/kg standard Tracesbilltv: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I(Curve) ^$TT^-I Stock II(ICV/CCV) JCHk- TTC "L LCS Source ID iO f-9Tl K"?LCS True Value V7 Acceptance Range ________ S a m p le ID : S a m ple W e ig h t (g) ug C C om m ents; Li S 0 -0 < 2O - ( b &. ? _ r / JfZ>, U 2 V k _ ^ . ir / r /></cz> / TTV vyZYY'JT#--- r .- / -/ 7r . n n - C L -- <7ft 0 ~ i r) a o & 3i 0 ' cj& o -& o 737772- / i -i o* CtH 11 1! - L . % -kliO ___ _ J ___ - : l n.OOC 0. O O y C r>. r, / V I ' 5 0 , 0 X-G !^ - I j 2j 2.067 ______ a nO C X J < f / T r i r - _c ^/ay<r/~ '.tit a i r - x 'J fV 7^ 9 Ptf-- rf 72/7f :t l . b t r . f / . 53/ . / S V X < X J ? <r f v /<r(./<k\ ? 3, r l T 2 t ? 3r > r v > ,/> i/ J J , V / v : p ? r , 2# r . * ,i * 2 7; z , "T f c ? T 777=tT T ^ I f ^ JjJ-hrZ? / 9 L (?r / f?.nnt>" 7-0 7 6 - c j c n o S^ z S . . ( ( ST 7n . <? . r T 7r 7)7<7 2P re p A n a lv s t / ^ / D ate: /2 / y/v A nalyst: D ata: R eview ed by:_ ( /lU D ate: / > / / W STL Chicago Pag* No.: 100 TOC in Soils Book No.: Method: Lloyd Kahn instrument Phoenix 6000 ITQC4 LabNet Batch:______________ Calculation*: Date of Standard Curve: TOC (mg/kg) = ug C / grama sample Book#_________ Page#___________ MS, MSD Known Cone, (mg/kg) * 100 ugC /gram s sample MS, MSD Observed (mg/kg) ug C / grams sample MS, MSD Ree. - fobserved mo/kq - ava, sample result (mg/koll x 100 known concentration in mg/kg Standard Traceability: (Note: Wbrking Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve)_____________ n StedCTTnCV/CCV)____________________ LCS Source ID _________ True Value________________ __.Acceptance Range Sample ID: SampleWeight (g) ugC Comments: 232VY72-C O a o r 7 . O Y f03.012/ tea nJ6 '-rrz-G 0 . 0 \ /32, W ~(f o o v T 93 C U t - 7 <7. O O $ "} J%L7CY \-*=h -e^e-n- y-- -lrC z-% *jU-fr/JrL^fLUsyjlessCZ-* -OOG v m.YiY i.. .. 0 0 i*3 ' ,' - 1 n>. n o 0 7 (L e<y -O^ ' . CLC^ n ./ 0 /Vl ,c m lAX^C 3tP Cf?. -a iay + \ ... \ \ Y \ \ \ \ Date: / V ? f a Data: / % (TlW Datv . J t i n J j U -- 1 CHl-22*U-09Sm-0SW 72c ** * RUN LOG *** (V2 ) 12/17/04 12:00 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code..,: 137238 Status...... RVUD Batch Pate... 12/16/04 Batch Time... 1129 User Name..... QC Code....... Calc Code..... els TOCS TOCS Location Code..: 57222 Equipment Code.: T0C4 Import Code___ : TEST CODE TT1TTTTTTTTTT OOOO0OO CCC I11 CCCCCccSSSCCC 23 4AAA 2A SSS VVV V 2A 234 2 2 SAMPLE: Grp Pos Sample ID Dilution TEST POS Dete / Time 123 45 6 7 1112 22 789012 11 __ ICAL_104LSTTC1_ 0 12 __ ICVJ04LSTTC2_ 12/13/04 1348 0 13 ___MB__ 12/13/04 1352 0 14 __ LCS_IQ0FSTLK3_3 12/13/04 1413 0 15 LCD I0QTSTLK3 3 12/13/04 1421 0 16 232472_9_S__ _ 12/13/04 1430 0 17 18 232472_9_S_MS_J04LSTTC2_6 232472_9_S_MSD_I04LSTTC2_6 12/13/04 1448 12/13/04 1455 0 * 19 232472_1Q_S__ 12/13/04 1504 0 1 10 232472J 1 _ S __ 12/13/04 1518 0 1 11 232472_12_S__ 12/13/04 1546 0 1 12 232472_13_S___ 12/13/04 1604 0 1 13 __ CCV_]04CSTTC2_ 12/13/04 1628 0 1 14 ___CCB__ 12/13/04 1633 0 STL Chicago Page 1 59 *** QC Sunmary *** (V2 ) Total Organic Carben (Soils) Report Date: 12/17/04 12:00 Method Code..: TOCS Batch Code...: 137230 Status.... . R V W Batch Date. 12/16/04 Batch Time. ..: 1129 User Name.. QC Code.... . : TOCS Calc Code..... : TOCS Location Code.. : 57222 Equipment Code.: C4 Import Code--- : Grp Smp Sample ID Pos Test Result Known OriginaL Alternate QC Res F QC Res F 12 ICV I04LSTTC2 1 TOC 1921.54 2000 96 13 ___ MBj__ 1 TOC -2.47 14 LGS I0DFSTLK3 3 1 TOC 4777.02 4780 '2.47 100 1 5 ___LCD_I00FSTLK3,,3 1 TOC 3922.22 4780 -2.47 4777.02 82 20 1 7 232472_9_S_MS_104L STTC2_6 5 TOCAV2 35682.11 2000 26794.36 59 1 a 232472_9ttS_MSD_1 D4LSTTC2_6 5 TOCAV2 50360.91 2000 26794.36 35682.11 108 59 4 1 13 CCV I04CSTTC2 1 TOC 1942.20 2000 97 1 14 ___ CCB__ 1 TOC -2.38 STL Chicago Page 1 60 *** RAW TEST DATA *** <V2 ) Total Organic Carbon (SoiLs) Method code.. TOCS Batch Code 137238 Status.... RVWD Batch Date__ : 12/16/04 Batch Time__ : 1129 User Name___ ; els SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 MB 14 LCS 100F5LK3 3 15 LCD J00FSTLK3 3 1 6 232472 9 S 1 7 232472 9 S MS IQ4LSTTC2 6 1 8 232472 9 s MSD I04L5TTC2 5 . 1 9 232472 10 S 1 10 232472 11 S 1 11 232472 12 S 1 12 232472 13 S 1 13 CCV I04CSTTC2 1 14 CCB PC Code... CaLc Code. --- TOCS Location Code..: 57222 Di L u tic m TOC mg/Kg T0C2 mg/Kg Report Date: 12/17/04 12;00 Equipment Code.: TOC4 Import code___ : T0C3 nig/Kg TOC4 mg/Kg T0CAV2 mg/Kg 1921.54 -2.47 4777.02 3922.22 28343.95 35682.11 50360.91 13442.57 6203.56 6273.73 13369.39 1942.20 -2.38 25244.77 12929.71 4815.30 6896.42 16271.71 26794.36 35662.11 50360.91 13166.14 5509.43 6585.07 14820.55 STL Chicago Page 1 61 *** RAU TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code. : TOCS Batch Code... : 137238 Status...... : RVUTl Batch Date...: 12/16/04 Batch Time...: 1129 User Marne___ : els SAMPLE: Grp Pos SBirple ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 MB 14 LC5 I00FSLK3 3 15 LCD I0QFSTLK3 3 1 6 232472 9 S 1 7 232472 9 S MS I04LSTTC2 6 1 8 232472 9 S MSD I04LSTTC2 6 - 1 9 232472 10 S 1 10 232472 11 S 1 n 232472 12 S 1 12 232472 13 S 1 13 CCV I04CSTTC2 1 14 CCB QC code....... : TOCS Calc Code..... ; TOCS Location Code..: 57222 Dilution TCAV3 mg/iCg TOCAV4 mg/Kg Report Date: 12/17/04 12:00 Equipment Code.: T0C4 Import code.... : TOCRl ug TOCR2 ug T0CR3 ug 96.0768 -0.3952 121.3363 105.5076 235.2546 235.5019 231.6602 131.7372 53.3506 52.6993 128.3461 97.1098 -0.3615 151.4686 131.8630 44.3008 74.4813 175.7345 STL Chicago Page 2 62 *** RAW TEST DATA *** CVZ ) Total Organic Carbon (Soils) Method Code,. TOCS Batch Code... 137238 Status ___ RVUn Batch Date...: 12/16/04 Batch Time...: 1129 lls*r Name.__: rls SAMPLE : Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV 104L5TC2 13 MB 14 LCS IO0FSTLK3 3 15 LCD I00FSTLK3 3 1 6 232472 9 S 1 7 232472 9 S MS I4LSTTC2 6 1 8 232472 9 S MSD I04LSTTC2 6 - 1 9 232472 10 S 1 10 232472 11 S 1 11 232472 12 S 1 12 232472 13 S 1 13 CCV I04C5TTC2 1 14 CCB oc Code... TOCS Code. TOCS Location Code..: 57222 Di luti on T0CR4 us WT1 9 Report Date: 12/17/04 12:00 Equipment Cixie. : TOC4 Import Code WT2 WT3 UT4 9S9 0.05 0.16 0.0254 0.0269 0.0033 0.0066 0.0046 0.0098 0.0086 0.0034 0,0096 0.05 0,16 0.0060 0.0102 0.0092 0.0108 0.0108 STL Chicago Rage 3 63 *** RAU TEST DATA #** Total Organic Carbon (Soils) Method Code,. TOCS Batch Code.,. 137238 Status...... RVUD Batch Date...: 12/16/04 Batch Time...: 1129 User Name___ : eis SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I4LSTTC2 13 MB 14 LCS I0QFSTLK3 3 15 LCD 10FSTLK3 3 1 6 232472 9 S 1 7 232472 9 S MS I04LSTTC2 6 1 8 232472 9 S MSD I04LSTTC2 6 1 9 232472 10 S 1 10 232472 11 S 1 n 232472 12 S 1 12 232472 13 S 1 13 CCV I04CSTTD2 1 14 CCS QC Code....... : TOCS Calc Code.... .: TOCS Location Code..: 57222 Di Luticrn Dl f a c N/A TCS mg/Kg 3.2000 1.0000 6.2992 5.9430 22.3776 24.2424 34.7826 16.0000 17.9775 16.6667 15.6863 3.2000 1.0000 (V2 ) Report Date: 12/17/04 1Z:Q0 Equipment Code.: TQC4 Import Code___ : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg STL Chicago -- Page 4 64 Multiple Analysis Report Print Date/Time: 2004/12/14 9:52:51 Sample ID Result Std. Dev, RSD Mode ALT 0 ugram C -8891 TC 10ugramC 911065 TC 20 ugram C 1853385 TC 40 ugram C .......................... 3745719... ........... TC 80 ugram C 7102662 TC 120 ugram C 11194916 TC 200 ugram C ......... ............... 18654032... ........... TC 300 ugram C 29462156 TC 400 ugram C 39451668 TC ICV.......................... ....... 96.0768............... ...TC .. ICB-MB -0.3952 TC LCS 121.3363 TC LCD........................ .........105.5078.............. ...TC .. 232472-9 232472-9 235.2548 151.4686 ' TC TC 232472-9ms.......................... 235.5019... ........... TC 232472-9msd 231.6602 TC 232472-10 131.7372 TC 232472-10.............. ............. 131.8830... ........... TC 232472-11 232472-11 53.3506 297.7806 TC TC 232472-11.............. ............. 44.3008... ........... TC 232472-12 52.6993 TC 232472-12 74,4813 TC 232472-13.............. ............. 128.3461... ........... TC 232472-13 CCV 175.7345 97.1098 TC TC CCB........................ .........-0.3815............... ...TC STL Chicago 65 7102562 -0,126 0.873 294 Sample ID: 120 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131219 Timestamp: 12/13/2004 1,2:28 Sample Type: TC Standai Rep # 1 ppm C ug C Raw Data Beginning Ending /Integration Baseline Baseline Time 11194916 -0.102 1.044 480 Last Message: Endpoint Timeout Sample ID: 200 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: / TC Filename: 2131239 Timestamp: 12/13/2004 12:46 Sample Type: TC Standard Rep # 1 ppm C ug C Raw Data iginning Ending Baseline Ba/eline Time 18654032 -0.( 0.932 344 Integration Sample ID: 300 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131252 Timestamp: 12/13/2004 12:59 Sample Type: TC Standard Rep # 1 ppm C ug C paw Data Beginning Ending baseline Baseline Time 29462T&6 0.063 1.062 375 Integration Sample ID: 4 00 u g /a m C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131311 Timestamp: 12/13/2004 13:19 Sample Type: TC Standard Rep# 1 p p m 0 u g C Raw Data Beginning Ending Baseline Baseline Time / 39451668 0.090 2.578 480 Integration Last Message: Endpoint Timeout Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _ Filename: 12131338 S' Timestamp: 12/13/2004 13:48 Sample Type: Cal. Verification STT, Chicago Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time t 96.0768 96.0768 9204630 0.183 1.238 480 Last Message: Endpoint Timeout Sample ID; ICB-MB Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131349 x Timestamp: 12/13/2004/13:52 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3952 -0.3952 -13127 0.965 0.754 120 Last Message: No Sample Detected Sample ID: LCS Method, boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131407 X" Timestamp: 12/13/2004 14:13 Sample Type; Sample ; R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 121.3363 121.3363 11966272 0.271 1.270 316 Sample ID: LCD Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131416 Timestamp: 12/13/2004 14:21 Sample Type: Sample \^ / Rep # ppm C ug C Raw Data Beginning Ending Integration 3^361inc Baseline Time 1 105.6078 105.5078 10408611 0.496 1.495 283 Sample ID: 232472-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131423 Timestamp: 12/13/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 235.2548 235.2548 23176808 1.442 2.438 303 Sample ID: 232472-9 Mode: TC STL Chicago Method: boat i f i M Cal. Curve: SOILCURVE Operator ID: CAROL Filename: 12131432 Timestamp: 12/13/2004 14:38 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 151.4686 151.4686 14931539 1.113 2.110 275 Sample ID: 232472-9ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131441 Timestamp: 12/13/20 Sample Type: Sample Rep # ppm C ug C Raw Data Be ginning Ending Integration Baseline Baseline' 1 235.5019 235.5019 23201124 5.272 Time 6.269 293 Sample ID: 232472-9msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode, TC Filename: 12131450 Timestamp: 12/13/2004^4:55 Sample Type: Sample ^ R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 231.6602 231.6602 22823070 3.950 4.944 262 Sample ID: 232472-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode; TC Filename; 12131457 Timestamp: 12/13/2004 15:04 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 131.7372 131.7372 12989809 1.282 2.280 301 Sample ID; 232472-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131505 Timestamp: 12/13/2004 15:11 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 131.8830 131.8830 13004151 1.472 2.471 273 Sample ID: 232472-11 Mode: TC STL Chicago 68 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Filename: 12131513 Timestamp: 12/13/200415:18 Sample Type: Sample y_ __ R e p # p pm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 53.3506 53.3506 5275908 0.888 1.885 257 Sample ID: 232472-11 Method: boat C a l Curve: SOILCURVE Operator ID: CAROL yHUode: TC Wfrlename: 12131521 ' Timestamp: 12/13/2004 15:28 [^ ij Sample Type: Sample Rep # ppm C ug C Rato Data Beginning Ending Integration Baseline Baseline Time 1 297.7806 297.7806 29329866 0.622 1.620 338 Sample ID: 232472-11 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131529 Timestamp: 12/13/2004 15:34 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 44,3008 44.3008 4385339 1,026 2.026 253 Sample ID: 232472-12 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131540 Timestamp: 12/13/2004 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 52.6993 52.6993 5211818 0.795 1.794 245 Sample ID: 232472-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131550 Timestamp: 12/13/2004 15:56 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 74.4813 74.4813 7355347 1.792 2.791 244 Sample ID; 232472-13 Method: boat Mode: TC Filename: 12131558 STL Chicago 69 Cal. Curve: SOILCURVE < 10 % Timestamp: Operator ID: CAROL ^ L / Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 128.3461 128.3461 12656091 1.375 2.372 265 Sample ID: 232472-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131610 Timestamp: 12/13/200416:16 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 175.7345 175.7345 17319508 0.787 1.786 308 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131620 Timestamp: 12/13/20 Sample Type: Cal. Verifi R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 97.1098 97.1098 9306287 0.730 1/730 437 Sample ID: COB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12131631 Timestamp: 12/13/200416:33 Sample Type: Sample / R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3815 -0.3815 -11780 1.324 1.164 120 Last Message: No Sample Detected STL Chicago 70 STL Chicago Page No.: ci TOC in Soils Method: Lloyd Kahn Book No. 3 1 ^ 7 instrument: Phoenix fiOQQ (TQC4 ) LabNet Batch / "3 3 Y Calculation; TOC (mg/kg) ug C / grams sample Data of Standard Curve:___ Book# P age#___7_0__7__-__ _ MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Rec. = robserved mo/ka - avd sample result fmo/VaN x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) T H L S T T f stock II (ICV/CCV) V c 9 i-S r r c LCS Source ID J X S True Value Acceptance Range f? ^ _________ Sample ID: Sample Weight (g) ug C 0 0.0 ? vr/ / / & < //. <?o 7<y / _ 2!, V 7 0 H ____ z ---------------- fa . C oC ----------- ------- ^ ----------------- - / / 7 T Z 7 i\ <? <Z.od> / & - /2 . c?9 Commenta: // 7 > Z 900 ir a 20& 3 ^ /, fzS r 90S. 9 1 9 * -T O '/ . t s c4 i? .O < a ie . 6 .0 W O -O pci 7C .?n /2 /r_^ (3 n jT L s n !^ ! -<?**. i1 ^ J. v ______ ! - t t i i _ - t O, - /( 'J ~ -U ------- - il C, n o t ' n . 0 0 Co 0 -0 O (,,0 (T- J O ) ? 0 ^ 2 b l4 H , 3L / <v. 9(<Hs / * 06Sv^J<T7V 1 11.C, ..rtfcni i n r / ryi. >> tV i2 -3 /. GC/Si G ?iT3iM3 T*? . fOK //.7 3 7 L O - O /O T - i'K i. < rn ? O , o f ' 7 3 , 3 7G <? & ~ r 1 r T ~ ~ ~ < 1 7 1 ,1 W G 0. n Of w *t ' o o y 5 / 2 / / fct- Prep Analyst Analyst Reviewed by; -- Date: Date: Date: ft-w J- M 7/oY CHf*22-12-09S/B -0WM STL Chicago TOC in Soils Pago No,: Book No.: 102 ~ ______ 7" 3 7 fr Method; Lloyd Kahn instrument Phoenix 8Q00 (T0C4 LabNet Batch:_______________ Calculation; Date of Standard Curve:___ _ TOC (mg/kg) = ug C / grams sample Book # _________ Page #_ MS, MSD Known Cone. (mg/kg) - 100 ug C / grams sample MS, MSD Observed (mg/kg) ug C / grams sample MS, MSD Rec. * fobserved mo/ko - avo. sample result (mg/kg)! x 100 known concentration in mg/kg Standard Traceability; Stock I (Curve) (Note; Working Standards are prepared dally from the noted Stock Solutions,) Q, (c>L Stock II (ICV/CCV) LCS Source ID LCS True Value Acceptance Range TdC *** RUN LOG *** (V2 ) 12/17/04 12:12 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code... : 137251 Status...... Batch Date.,, 12/16/04 Batch Time... 1228 User Name,,.. 0C Code..... Calc Code.... TOCS Location Code..:: 57222 Equipment Code.:: T0C4 Import Code--- : SAMPLE; Grp Pos Sample ID D i lution TEST CODE TEST POS Date / Time TTT TTTTT TTTTT OOOOOCCC II I C cC C C C C S sS C C C 23 4AAA 2A sss VVV V 2A 234 2 2 12 3 4 5 6 7 11 1 2 2 2 78 9 0 12 11 ___ I C A L J Q 4 L 5 T T C l _ 0 12 13 ___ICV_I04LSTTC2m ___M B _ 12/14/04 0912 0 12/14/04 0915 0 14 15 16 ___LCS_I00FSTLK3_3 ___LCD_I00FSTLK3_3 232472_14_S___ 12/14/04 0924 0 12/14/04 0945 rt 12/14/04 0954 0 17 232472_T4_SJ1S_IQ4LSTTC2_6 12/14/04 1019 0 1 232472J4_SJ1SDJ04LSTTC2_6 12/14/04 1026 0 19 232472_15_S___ 12/14/04 1036 0 1 10 1 11 Z 3 2 4 7 2 J 6 J ___ 232472_17_S___ 12/14/04 1052 12/14/04 1117 0 0 1 12 252472 18 S 12/14/04 1135 0 1 13 232472_19_S___ 12/14/04 1153 0 1 14 232472_20_S___ 12/14/04 1218 0 1 15 CCV 104LSTTC2 12/14/04 1238 0 1 16 ___CCB__ 12/14/04 1244 0 1 17 232472^21_S___ 12/14/04 1257 Q 1 18 232472_22_S___ 12/14/04 1355 0 1 19 232472_23_S___ 12/14/04 1426 0 1 20 1 21 232472_24_S___ 232676_1_S___ 12/14/04 1444 12/14/04 1458 0 0 1 22 232676 2 S 12/14/04 1513 0 1 23 232676_3_S___ 12/14/04 1533 0 I 24 232676_4_S___ 12/14/04 1553 0 1 25 ___CCV_I04LSTTC2_ 12/14/04 1622 0 1 26 ___CCB__ 12/14/04 1626 0 STI,,Chicago 73 *** QC Sunna ry *** V2 ) Total Organic Carbon (Soils) Report Date: 12/17/04 12:12 Method Code..: TOCS Batch Code..,: 137251 Status...... : RVUD Batch Date...: 12/16/04 Batch Time...: 1228 User Name---- : els QC Code....... : TOCS Calc Code..... : TOCS Location Code..: 57222 Equipment Code.: TOC4 Import Code..,.: Grp Smp Sample ID Pos Test Result Known Original Alternate QC Res F QC Res F J r-n 1 2 ___ICV_I04LSTTC2_ 1 TOC 1 TOC 1845.40 3.31 2000 92 14 15 ___LCS_I00FSTLK3_3 ___ LCD_IOOFSTLK3_3 1 TOC 1 TOC 5253.57 3766.01 4780 4780 -3.31 -3.31 5253.57 110 79 33 * 1 7 232472_14_S_MS_I04LSTTC2_6 5 TQCAV2 28670.30 2000 13600.90 95 1 8 232472_J4_S_MSD_I04LSTTC2_6 5 T0CAV2 27895,17 2000 13600.90 28670.30 91 5 1 15 ___CCVtJ04LSTTC2_ 1 TOC 1912.79 2000 96 1 16 ___CCB__ 1 TOC -2.58 1 25 ___CCV_I04LSTTC2_ 1 26 CCB 1 TOC 1 TOC 1946.33 2.56 2000 97 STL Chicago Page 1 74 *** RAW TEST DATA (V2 ) Total Organic Carbon (Soils) Method Cade.. : TOCS Batch Code... : 137251 Status...... : RVWD Batch Date... 12/16/04 Batch Time... 1228 User Name.... els SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV 04LSTTC2 13 MB 14 LCS IQ0FSLK3 3 15 LCD^IOOFSTLK 3 1 6 232472^14 S 1 7 232472- 14~S MS 104LSTTC2 6 1 8 232472 14"S_MSD I04LSTTC2 6^ 1 9 232472 15 S 1 10 232472^16" S 1 11 232472 17 S 1 12 232472 18 S 1 13 232472 19 S 1 14 232472_2 0 J ___ t 15 CC1M04LSTTC2 1 16 CCB^ 1 17 232472 21 S 1 18 232472^22 S 1 19 232472 23 S 1 20 232472 24 S 1 21 232676_ 1 S 1 22 232676 2 S 1 23 232676 3 S 1 24 232676^4 S 1 25 CCV I4LSTTC2 1 26 CCB- QC Code...... .: TOCS Calc Code.--- .1 TOCS Location Code. .: 57222 Dilution TDD mg/Kg TQC2 mg/Kg Report Date: 12/17/04 12:12 Equipment Code.: TOC4 Import Code..,.: T0C3 mg/Kg TOC4 mg/Kg T0CAV2 mg/Kg 1845.40 -3.31 5253*57 3766.01 14295.89 28670,30 27895.17 12274.05 19750.03 13700.38 12711,67 18230.22 3597.86 1912.79 -2.58 3B990.97 19458.21 6678.50 4123.68 8533*01 5555.61 1965.99 1532.89 1946.33 -2.56 12905.90 14946.84 22226.99 12114.72 11678.18 18103,89 1649.59 39113.10 18206.35 8473.30 3893.25 7579.76 4477.76 1512.31 1327.76 13600.90 2B670.30 27895.17 13610.44 20988.51 12907.55 12194.92 18167.06 2623.72 39052.04 18832.28 7575.90 4008.47 8056,39 5016.68 1739.15 1430.33 STL Chicago Page 1 75 *** RAW TEST DATA <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 137251 Status..... .: RVUD Batch Date...: 12/16/04 Batch Time,,,: 1228 User Name.---: cLs SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 ie 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 ICAL I04LSTTC1 ICV I04LSTTC2 MB LCS IQQFSTLK3 3 LCD IOOFSUK3 3 232472 14 S 232472 14 S MS IQ4LSTTC2 6 232472 14 S MSD I04LSTTCZ 6. 232472 15 S 232472 16 S 232472 17 S 232472 IS S 232472 19 S 232472 20 S CCV I04LSTTC2 CCS 232472 21 S 232472 22 S 232472 23 S 232472 24 S 232676 1 S 232676 2 S 232676 3 S 232676 4 S CCV I4LSTTC2 CCS QC C o d e . - T O C S Calc Code...... : TOCS Location Code..: 57222 Dilution T0CAV3 mg/Kfl T0CAV4 mg/Kg Report Date: 12/17/04 12:12 Equipment Code.: T0C4 import Code____: TOCR1 ug TQCR2 ug TOCR3 UB 92.2698 -0.5304 132.9154 1Q5.44B2 100.0712 180.6229 178.5291 169.3819 183.6753 135.6338 111.5627 187.7713 35.9786 95.6397 -0.4125 356.0106 266,5775 79.4741 72J644 160.4206 100.0009 39.9095 43,5342 97.3167 -0.4104 114.5625 182.3515 173.3705 95.7063 133.1313 204.5740 25.2388 320.7274 205.7318 94.0536 76.6971 125.8240 97.1674 39.1688 37.4427 STL Chicago Page 2 76 *** RAU TEST DATA *** (V2 ) Total Organic Carbon (Soi Ls) Method Code., : TOCS Batch Code... : 137251 Status..... .. : RVUD Batch Date...: 12/16/04 Batch Time... : 1220 user Name.... : els SAMPLE : Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 MB 14 LCS I00FSTLI3 3 15 LCD I00FSTLK3 3 1 6 232472 14 S 1 7 232472 14 S MS IQ4LSTTC2 6 1 8 232472 14 S MSD I04LSTTC2 6- 1 9 232472 15 S 1 10 232472 16 5 1 11 232472 17 $ 1 12 232472 18 S 1 13 232472 19 S 1 14 232472 20 S 1 15 cev I4LSTTC2 1 16 CCB 1 17 232472 21 S 1 18 232472 22 S 1 19 232472 23 S 1 20 232472 24 S 1 21 232676 1 S 1 22 232676 2 S 1 23 232676 3 S 1 24 232676 4 S 1 25 CC9 I04LSTTC2 1 26 CCB QC Code....... : TOCS Calc Code..... : TOCS Location Code.. 57222 Dilution TCR4 up UT1 g Report Date; 12/17/04 12:12 Equipment Code.: T0C4 Import Code___ ; UT2 WT3 a9 UT4 9 0.05 0.16 0.0253 0.0280 0.0070 0.0063 0.0064 0,0138 0.0093 0.0099 0.0088 0.0103 0.0100 0.05 0.16 0.0099 0.0137 0.0119 0.0175 0.0188 0.0180 0.0203 0.0284 0.05 0.16 0.0089 0.0122 0.0078 0.0079 0.0114 0.0113 0,0153 0.0082 0.0113 0.0111 0.0197 0.0166 0.0217 0.0259 0.0282 STL Chicago -- Page 3 77 *** RAW TEST DATA +** <V2 ) Total organic Carbon (Soils) Method Code..: TOCS Batch Code...: 137251 Status..,,...: RVWD Batch Date...: 12/16/04 Batch Time.,.: 1228 User Name :els SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 MB 14 LCS IQ0FSTLK3 3 15 LCD I00FSTLK3 3 1 6 232472 14 S 1 7 232472 14 S MS IQ4LSTTC2 6 1 8 232472 14 S MSD I04LSTTC2 6. 1 9 232472 15 S 1 10 232472 16 S 1 11 232472 17 S 1 12 232472 IS S 1 13 232472 19 S 1 14 232472 20 S 1 15 CCV I04LSTTC2 1 16 CCB 1 17 232472 21 S 1 18 232472 22 S 1 19 232472 23 S 1 2D 232472 24 S 1 21 232676 1 S 1 22 232676 2 S 1 23 232676 3 S 1 24 232676 4 S 1 25 CCV I04LSTTC2 1 26 CCB__ QC Code....____ : TOCS Calc Code..... TOCS Location Code..: 57222 Dilution DLFAC N/A TCS mg/Kg Report Date: 12/17/04 12:12 Equipment Code.: T0C4 Inport Code----: TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 6.3241 5.7143 20.1258 25.3968 25.0000 12.3077 18.7135 17.9775 15.8416 14.8148 12.6482 3.2000 1.0000 17.6796 12.8000 13.9130 8.6022 9.0395 8.0605 6.9264 5.6537 3.2000 1.0000 STI. Chicago Page 4 7S Multiple Analysis Report Print Date/Time: 2004/12/15 11:25;58 Sample ID Result Std. Dev. RSD Mode ALT ICV 92.2698 TC ICB-MB -0.5304 TC LCS 132.9164 TC LCD......................... .........105.4482.............. ...TC .. 232472-14 100.0712 TC 232472-14 114.8625 TC 232472-14ms......................... -0.3342... ........... TC 232472-14ms 180.6229 TC 232472-14ms 178.5291 TC 232472-15.............. ............. 169.3819.., ........... TC 232472-15 182.3515 TC 232472-16 183.6753 TC 232472-16.............. ............. 1733705... ........... TC 232472-17 135.6338 TC 232472-17 95.7063 TC 232472-18.............. .............111.8627... ........... TC 232472-18 133.1313 TC 232472-19 187.7712 TC 232472-19.............. .............2045740... ........... TC 232472-20 35.9786 TC 232472-20 25.2388 TC c c v ........................ .........95.6397............... ...TC .. CCB -0.4125 TC 232472-21 386.0106 TC 232472-21.............. .............3207274... ........... TC 232472-22 0.2170 TC 232472-22 266.5775 TC 232472-22.............. ............. 205.7318... ........... TC 232472-23 79.4741 TC 232472-23 94.0536 TC 232472-24.............. ............. 72 1644... ........... TC 232472-24 76.6971 TC 232676-1 160.4206 TC 2 3 2 6 7 6 -1 ............................. 125.8240... ........... TC 232676-2 100.0009 TC 232676-2 97.1674 TC 232676-3................. ......... 0.5417,,. . -,TC . 232676-3 39.9095 TC 232676-3 39.1688 TC 232676-4................ ............43 5342... ........... TC 232676-4 37,4427 TC CCV 97.3167 TC CCB........................ ......... -0.4104............... ...TC .. STL Chicago 79 Calibration Report Print Date/Time: 2004/12/15 7:57:25 Cal. Curve ID: SOILCURVE Created: 12/13/200413:36 Calibration Factor (m): 9.841 e+04 Y Intercept (b): -250134 r-squared: 0.99936 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -8891 0.000 2.451 No Sample Det 12/13/2004 11:24 10ugramC 911065 10,000 11.800 12/13/200411:42 20 ugram C 1853385 20.000 21.375 12/13/200411:48 40 ugram C 3745719 40.000 40.605 12/13/200412:04 120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/2004 12:28 200 ugram C 18654032 200.000 192.099 12/13/200412:46 300 ugram C 29462156 300.000 301.928 12/13/200412:59 400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/2004 13:19 STL Chicago NO Detailed Analysis Report Print Date/Time: 2004/12/15 11:26:07 Sample ID: ICV Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12140906 ^ Timestamp: 12/14/20o4 09:12 Sample Type: Cal. Verification---' Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 92.2698 92.2698 8829986 0.935 1.934 292 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12140912 Timestamp: 12/14/2' Sampl Type: Sample 09:15 R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.5304 -0.5304 -26435 1.499 1.164 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12140918 Timestamp: 12/14/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 132.9154 132.9154 13105751 1,035 2.033 301 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12140940 Timestamp: 12/14/20(^4 09:45 , Sample Type: Sample R e p # ppm C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 105.4482 105.4482 10402746 1.156 2 154 279 Sample ID: 232472-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12140948 Timestamp: 12/14/2004 09:54 Sample Type: Sample V. Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 81 IH. 1 100.0712 100.0712 9873606 1.187 2.186 276 Sample ID: 232472-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12140954 Timestamp: 12/14/2004 10:00 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 114.8625 114.8625 11329195 1.766 2.763 261 Sample ID: 232472-14ms ! Mode: TC Method: boat \ Cal. Curve: SOILCURVE A ,CV W Operator ID: CAROL /^ Filename: 12141002 Timestamp: 12/14/2004 10:09 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 -0.3342 -0.3342 -7120v 2.425 1.055 5 Integration Last Message: Canceled Sample ID: 232472-14ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141012 " Timestamp: 12/14/20GM 10:19 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 180.6229 180.6229 17800566 1.035 2.032 339 Sample ID: 232472-14ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141020 X Timestamp: 12/14/2004 10:26 Sample Type: Sample l / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 178.5291 178.5291 17594516 1.949 2.946 291 Sample ID: 232472-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141029 Timestamp: 12/14/2004 10:36 Sample Type: Sample^ R e p # ppm C ug C Raw Data Beginning Ending Integration j STL Chicago 82 f ' Baseline Baseline Time 1 169.3819 169.3819 16694363 1.546 2.545 336 Sample ID: 232472-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141040 Timestamp: 12/14/2004 10:46 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 182.3515 182,3515 17970678 1.611 2.611 290 Sample ID: 232472-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141047 Timestamp: 12/14/2 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 183.6753 183.6753 18100956 1.956 2.956 290 Sample ID: 232472-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141059 Timestamp: 12/14/2004 11:04 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 173.3705 173.3706 17086868 1.342 2.341 302 Sample ID: 232472-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141110 /' Timestamp: 12/14/2004 11:17 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 135.6338 135.6338 13373262 1.361 2.361 301 Sample ID: 232472-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141118 Timestamp: 12/14/2004 11:25 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 83 1 95.7063 9444066 1.740 2.739 257 Sample ID: 232472-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141125 ^ Timestamp: 12/14/2004/11:35 ) Sample Type: Sample yy Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 111.8627 111.8627 11033992 2.175 3.171 263 Sample ID: 232472-18 Method: boat 37 Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 121411 Timestamp: 12/14/2004 11:42 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 133.1313 133.1313 13127001 1.801 2.799 271 Sample ID: 232472-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141147 Timestamp: 12/14/201 Sample Type: Sample 11:53^ R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 187.7712 187.7712 18504028 1.385 2.383 320 Sample ID: 232472-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141157 Timestamp: 12/14/2004 12:06 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 204.5740 204.5740 20157560 1350 2.347 310 Sample ID: 232472-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141213 / Timestamp: 12/14/2004 12:18 Sample Type: Sample l Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 84 <UL/ 1 35.9786 35.9786 3566356 1.395 2.392 251 SamplelD: 232472-20 Method: boat Cai. Curve: SOILCURVE Operatorio; CAROL Mode: TC Filename: 12141221 Timestamp: 12/14/2004 12:25 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 25.2388 25.2388 2509477 1.619 2.619 212 SamplelD: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141231 Timestamp. 12/14/20 Sample type: Cal. Verifica Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 95.6397 95.6397 9161611 1.287 2.287 301 Sample ID: CCB Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141240 Timestamp. 12/14/20! Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4125 -0.4125 -14830 1.526 1.376 120 Last Message; No Sample Detected SamplelD: 232472-21 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141250 Timestamp: 12/14/2004 12:57 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 386.0106 386.0106 38012440 1.272 2.272 392 SamplelD: 232472-21 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Fiilename: 12141347 Timestamp: 12/14/2004 13:53 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration STL Chicago 85 Baseline Baseline Time 1 3207274 3207274 31588028 2 230 3.226 300 Sample ID; 232472-22 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TO - Filename: 12141354 f Timestamp: 12/14/2004 13:55 Sample Type: Sample V Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2170 0.2170 47116 2.246 3.226 18 Sample ID: 232472-22 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141400 Timestamp: 12/14/2004 14:06 Sample Type: Sample R e p # p p m C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 266.5775 266.5775 26259224 2.423 3.423 315 Sample ID: 232472-22 Method. boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141414 Timestamp: 12/14/2004 14:20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 205.7318 2057318 20271500 1.626 2.623 319 Sample ID: 232472-23 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename. 12141421 Timestamp: 12/14/2004 14:26 Sample Type: Sample l R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 79.4741 79.4741 7846678 2,156 3.152 251 Sample ID: 232472-23 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141428 Timestamp: 12/14/2004 14:33 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 1 94.0536 94.0536 9281424 1.776 2.772 258 Sample ID: 232472-24 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141440 Timestamp: 12/14/2 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 72.1644 72.1644 7127342 5.742 6 J 3 4 214 Sample ID: 232472-24 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141446 Timestamp: 12/14/2004 14:51 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 76.6971 76.6971 7573402 1.620 2.619 255 Sample ID: 23267 [-1 Method: boat Cal. Curve: S O ILC U R /E Operator ID: CAROL Rep # ppm C ug C 1 160.4206 160.4206 Mode: TC Filename: 12141452 ^ Timestamp: 12/14/200414:58 y Sample Type: Sample l y Data Beginning Ending Integration sline Baseline Time >496 2.668 3.667 277 Sample ID: 232676-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Fi!enam e\ 12141501 imp: 12/14/2004 15:06 Sample T^pe: Sample Rep # ppm C ug C Raw Data Beginning Baseline Baseline Time' 1 125.8240 125.8240 12407897 2.536 3.53T Sample ID: 232676-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141508 Timestamp: 12/14/200 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 87 Baseline Baseline Time 1 43.5342 43.5342 43519889 1.615 2.615 243 Sample ID: 232676-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141606 ^mestamp: 12/14/2004 16:10 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline NTime 1 37.4427 37.4427 3710442 1.649 2 ^ 4 4 228 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: ' 12141617 Timestamp: 12/14/2004 16:22 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 97.3167 97.3167 9326640 1.347 2-346 301 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12141624 ^-- Timestamp: 12/14/2004*16:26 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integiatiei Baseline Baseline Time 1 -0.4104 -0.4104 -14625 1.748 1.571 120 Last Message: No Sample Detected STL Chicago STL Chicago Page No.:_ TOC In Soil Book No.: J 7 7 / ~ Method: Lloyd Kahn Instrument: Phoenix aOQO {TQC4 LabNet Batch: j 3 ' l ''f i refutations: Date of Standard Curve: TOC (mg/kg) = ug C / grams sample Book# . 3 9 ^ 7 Pag e # f ( MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample M S , MSD Observed (mg/kg) = ug C / grams sample MS, MSDRec. = robserved mo/kd - avq. sample result fmo/kail xtOO known concentration in mg/kg y gdard Traceabilltv: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock 1(Curve) fTC / Stock (I (ICV/CCV) IO Y L<>r r ? ' x- LCS Source ID LCS True Value j i t G Acceptance Range 53 Sample ID: Sample Weight (g) ug C -o r ~ 7 2 jjfp r~ o . /C -0 ,0 Comments: ~~ LC<? tT p a X f~ 3 n u . ^2 / r . y y f ^ q .'y ifl'L - l'l /? ,& O 7 0 1 -in O &f ; / y . 9* 2T 1 1 - I (j - -- ---X^To. 0 V w__?_____ " 1 - / V / O^Cf /W .C is # i / %rfS? f t O C G H ./?Y .<r2?C ! ~ /r 0 .0 /T t /f. - ' 1 `C ....i oh* , ,,, f^jcS 2T / 'ftrAo _ '1 6 ..... _ . o o T3 6 oonsy (9 (y O ? f /T O . V O J 7 ,2 / ^ r <Ti7p 1- - c \ o -O~y ? ____ L - r i ? . (y < y ^ Y ' - /p 0 .O / / * / -/3 _ -/ 7 . - 2C ___ f n u . , y) ? _c;. i r!> - O l o ' o . K 3 o.0 r `i C T O C l / / / ^ 6Z 7 D itV .3 _ /T ? ?>3 2 .o y 7 V ? q i , (pJ 7 ___ 71 STL Chicago Prep Analyst Analyst Reviewed by: Date: y? f o Mc&nti&o Date: /2 Y ^ o i- ~ Date: ' / / / 7 CHI-32*i o9S45/q9 STL Chicago TOC in Soils Page Nq.:_ 7Book No,; n . 7 H 104 Method: Lloyd Kahn Calculation: TOC (mg/kg) = ug C / grams sample Instrument; Phoenix 8000 rrOC4) LabNet Batch: ( Date of Standard Curve: / J L / n / f l ~ Book # __ Page # fa f MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Ree. * fobserved mg/Ko - avo, sample result (mg/kg)1 x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions,) Stock I (Curve) T E M L S r i O I stockii(icv/ccv) T o w L ? H O LCS Source ID 'i o f'^ U ^ A .CS True Value Acceptance Range T 3 - /*?<?______ Sample ID: Sample Weight (g) ugC Comments: O O /b -0 Y /z r T T rn n T z T 0 ,0 0 1 1 3 i f O fe$ 1 -3-1 -Q O 320. 72,7/ I1 .. , o -- ?Q-__ "77'l. CZ / ----/i-O/^ -- TM " ^/7 o li o /i / r ---- -1 $ /$ -/ 'IWiJ * J/ 1 -0 /7 - / - 2 7 - 0.0 ( (J nfiY.TuF' -r : ^ s _ o . 0 1(1! 7 1 77v/ ~ -IO a a il 1 77 0O rr.o i n \ _ 7-2, / W a o tn l X C 9.1 J o, o h / 6 0 . Y2C& _____ l_____- / . n. n / c -- ' Z . 7 O f Y a /2 S ; ltfG /O 0 , 6 oc? * - 7 _ O . 0 2 - / 7 -- 2? n O .C iT _ 9 7 / 7Y . s n n 7, 0 2 . O Z -'S o ,o 3 ? , ro c-- ^V TFF- ;____- V O, O ' k ? 7 - Y__________ 0 . <7 <2 T Z o u ^------------------------ o , 0 7 TT^ -- o *r &w d' J m 77 T T ffe r -o W W :--------------------------------------------------------- - Prep Analyst: Analyst: Reviewed by:. STL Chicago s A. / \ Q - H : Date: / 2 / j /<? i Date: M ia R CH1-23-12-0I T*** RAU TEST DATA tr-frir CV2 ) % Solids Detenninstpn Method Code.. : SDL IDS Batch Code... : 136297 Status...... : RW D Batch Date.., 12/07/04 Batch Time...,: 105 User Hamo___ ,: d b SAMPLE: Grp Pos Sample ID 11 S MB 1 2 232472 S 1 3 232472 1 S MD 2 1 4 232472 2 S 1 5 232472 3 S 1 6 232472 4 S 1 7 232472 5 S 1 B 232472 6 S 1 9 232472 7 S 1 10 232472 8 S 1 11 232472 9 S 1 12 232472 10 S 1 13 232472 11 S 1 14 232472 12 S 1 15 232472 13 S 1 16 232472 14 S 1 17 232472 15 S 1 15 232472 16 S 1 19 232472 17 S 1 20 232472 15 S 1 21 232472 19 S 1 22 232472 20 S QC Code....... : SOLID Cale Code..... : %50L Location Code.. : 57222 Dilution %50LID % IUGT g 0.0 56.6 57.3 65.0 44.9 43.4 44.7 46.5 42.7 44.5 43.4 65.2 78.3 66.7 42.5 45.8 43.9 40.9 40.4 38.8 63.0 84.5 5.8501 9.4846 9.3896 9.2499 9.5568 9.0049 9.0212 9.0436 8.9749 5.5506 9.5770 9.1999 9.1558 9.3472 9.4751 8.7959 9.6572 8.9866 9.5519 9.0994 9.1537 9.1304 Report Dte: 12/20/04 9:04 Equipment Code. Import Code___ FWGT g 0.0002 5.3728 5.3760 6.0125 4.2884 3.9054 4.0295 4.2292 3.5345 3.9371 4.1562 6.2776 7.1694 6.2368 4.0226 4.0295 4.2351 3.6725 3.8576 3.5315 5.7661 7.7133 DRVWT g 1.2746 6.6439 .6422 7.2760 5.5501 5.1674 5.2864 5.4915 5.0948 5.1926 5.4548 7.5774 8.4798 7.5469 5,3356 5.3407 5.5441 4.9843 5.1704 4.8474 7.0769 9.0268 WETUT g 10.1245 10.7557 10.6558 10.5134 10.8185 10.2639 10.2778 10.3059 10.2352 10.1061 10.8756 10.4997 10.4662 10.6573 10.7881 10.1071 10.9662 10.2984 10.8647 10.4153 10.4645 10.4439 Page 1 k-k-k RAW TEST DATA kkk <V2 ) Page 2 Q> *** RAW TEST DATA (M2 ) % Solids Determination Method code.. SOLIDS Batch Code... 136298 Status RVWD Batch Date.,.: 12/07/04 Batch Time.. 105 User Name... ctb SAMPLE : Grp Pos SampLc ID 11 S MB 1 2 232469 21 S 1 3 232469 22 S 1 4 232469 23 S 1 5 232469 24 S 1 6 232471 1 S 1 7 232471 1 S MD 6 1 a 232471 2 S 1 9 232471 3 S 1 10 232471 4 S 1 11 232471 5 S 1 12 232471 6 S 1 13 232471 7 S 1 14 232471 8 S 1 15 232471 9 S 1 16 232472 21 S 1 17 232472 22 S 1 18 232472 23 S 1 19 232472 24 S 1 20 232481 2 S 1 21 232481 3 S 1 22 232481 4 S QC Code...--- .: SOLID CaLc Code..... : %SOL Location Code..: 57222 Dilution %SOUD % IWGT g 0.0 93.9 94.3 90.9 92.1 76.8 74.9 87.5 83.8 85.9 73.9 ao.3 82.4 78.6 81.0 24.4 33.0 62.1 74.8 84.6 83.6 85.7 9.1422 9.0207 9.0586 9.0702 8.9586 9.6841 9.3614 9.3983 8.7216 9.0841 9.3817 9.6362 9.2754 9.5614 8.8422 9.0717 8.9856 9.5459 9.0223 9.1457 8.9225 8.7797 Report Date: 12/20/04 9:04 Equipment Code.: Import Code___ FGT g 0.0035 8.4730 8.5400 8.2460 8.2469 7.4335 7.0134 8.2263 7.3111 7.8072 6.9373 7.7384 7.6431 7.5136 7.1653 2.2099 2.9610 5.9266 6.7472 7.7376 7.4557 7.5257 DRYWT g 1.3119 9.7883 9,8563 9.5672 9.5734 8.7286 8.3408 9.5606 8.6409 9.1344 8.2354 9.0627 8.9691 8.8408 8.4952 3.5409 4.2980 7.2596 8.0769 9.0721 8.7919 8.8619 WETWT g 10.4506 10.3360 10.3749 10.3914 10.2851 10.9792 10.6888 10.7326 10.0514 10.4113 10.6798 10.9605 10.6014 10.8886 10.1721 10.4027 10.3226 10.8789 10.3520 10.4802 10.2587 10.1159 Page 1 JtdtJt RAW TEST DATA % Solids Determination Method Code..: SOLIDS Batch Code...: 136298 Status...... : RVWD Batch Date.. : 12/07/04 Batch Time.. : 105 User Name... : Clb SAMPLE: Grp Pos Sample ID 11 S MB 1 2 232469 21 S 1 3 232469 22 S 1 4 232469 23 S 1 5 232469 24 S 1 6 232471 1 S 1 7 232471 1 S MD 6 1 8 232471 2 S 1 9 232471 3 S 1 10 232471 4 S 1 11 232471 5 S 1 12 232471 6 S 1 13 232471 7 S 1 14 232471 8 S 1 15 232471 9 S 1 16 232472 21 S 1 17 232472 22 S 1 18 232472 23 S 1 19 232472 24 S 1 20 232481 2 S 1 21 2324S1 3 S 1 11 232431 4 S QC Code... ___ : SOLID Calc Code. ___ : %S0L Location Codo..: 57222 Di lution TARE g 1.3084 1.3153 1.3163 1.3212 1.3265 1.2951 1.3274 1.3343 1.3298 1.3272 1.2981 1.3243 1-3260 1.3272 1.3299 1.3310 1.3370 1.3330 1.3297 1.3345 1.3362 1.3362 ASHWT g <V2 ) Report Date: 12/20/04 9:04 Equipment Code.: Import Code FASHWT g %M0IST % 100.0 6.1 5.7 9.1 7.9 23.2 25.1 12-5 16.2 14.1 26.1 19.7 17.6 21.4 19.0 75.6 67.0 37.9 25.2 15.4 16.4 14.3 %ASH % Page