Document a13N3ERm4o0LpNrmd895gwJGy

m poii MATERIAL SAFETY DATA SHEET IDENTIFICATION Marne Titanium Dioxide Pigment (Slurries) Ti' Pure R-941, R-943 Synonyms ChemicalFamily TiOz, titania, rutile Inorganic Oxide OASName CAS RegistryMo. Titanium Oxide 13463-67-7 I.Q, Nos./Codes NIO$H Access No: XR22750 Manufacturer/Distributor Product Information and Emergency Phone E, I. du Pont de Nemours & Co., (Inc.) (302) 774-2421 Address Transportation Emergency Phone Wilmington, DE 19898 (800) 424-9300 HAZARDOUS COMPONENTS Materials) Approximate % Amorphous Silica R-941r 8% max (Dry Basis) R-943: 9% max (Dry Basis) PHYSICAL DATA Boiling Point, 760mmHg ~100C (212P) Specific Gravity 1.8-1.9 Vapor Density Same as water % Volatiles by w t. 36-38 form Liquid Appearance Opaque dispersion pH Information 7.0-10.0 FIRE AND EXPLOSION DATA Flashpoint Method Melting Point ~0C (32F) Vapor Pressure Same as water (Liquid component is water) Solubility In HVO Miscible - Dispersed solid is insoluble Evaporation Rate (Butyl Acetate = 1) Color Odor Slight White amine odor Octanol/Water Partition Coefficient Autoignition Temperature Will not burn Flammable Limits in Air, % by Voi. Lower Upper Fire and Explosion Hazards None Extinguishing Media Special Fire Fighting Instructions The data in thisMaterial Safety Datasheet relates only to thespecific material designated herein and does not relateto u m In combination with any other matarlalor In any procese. Tha Infonnationsetforlh herein is furnished free ofcharge and Is basedon technical data that Du Pont believe* to ba reliat4e.lt is intended for use by persona having technical shill and at thelrown discretion and risk. Since conditions of use are outbids cur control, we make no warrantiea. express or implied, and assume no liability in connection with any use of this information. Nothing herein is to be taken as a license to operate under or.a recommendation to infringe any patents. HAZARDOUS REACTIVITY Decomposition Will not occur Polymerization Will not occur HEALTH HAZARD INFORMATION ExposureUmits When dried, dusts may form. OSHA Time-Weighted Average (TWA for Ti02) is 15 mg/m3. The ACGIH TLV-TWA (nuisance dust) is 10 mg/m3 total dust or 5 mg/m3 respirable dust. There is some ambiguity about the OSHA limit because of the amorphous silicon dioxide content of Ti-Pure R-941 and R-943. Du Pont believes the ACGIH limit above best covers this case and has elected to observe that limit. The ACGIH recommended limit for amorphous silica in its 1980 Notice of Intended Change is 6 mg/m3 total dust and 3 mg/m3 respirable dust. Routes of Exposure and Effects: According to Du Pont inhalation tests in rats, dusts from this type of products produce an inert or nuisance dust response in the lungs. PROTECTION INFORMATION Ventilation Adequate to maintain exposure level as above. Personal Protective Equipment If exposure limits may be exceeded, use OSHA-permissible respirator. For air concentrations up to 75 mg/m3, use dust respirator. For higher concentrations and for additional information, see References below. 0lP0SAL PROCEDURES Aquatic Toxicity TLm 96 > 1,000 ppm Spill, Leak or Release Let dry or absorb with sand or other absorbent and shovel into container for disposal. Waste Disposal Comply with Federal, State and local regulations. If approved, may be removed to land disposal site. SHIPPING PRECAUTIONS Transportation DOT Hazard Classification: Not Regulated. Shipping Containers Railroad tank cars, tank trucks, and drums. Storage Conditions REFERENCES AND ADDITIONAL INFORMATION See Du Font's Ti-Pure R-941 and R-943 Data Sheets. For more information, refer to: 29 CFR 1910.134; 30 CFR 11.130 (tv); DREW (NIOSH Publication No. 78-210, "NIOSH/OSHA Pocket Guide to Chemical Hazards." The two NIOSH publications may be obtained from Dept. HHS/NIOSH, 4676 Columbia Parkway, Cincinnati, OB 45226, phone (513) 684-4287, DATE: 2/81 ED DUP050070483