Document ZxxQGZ58QryvNRmdXMkMXKOJ
CCuurrrreenntt CCGG FFCC W Waassttee SSttaattuuss ((222211227722 IIbbss..llyyrr aass ooff 88//22111/0000))
BFC wastLosttothe
[] FC Waste Lost to the Sewer 38%
TT
@[] TTWWraarnssataefefsrforrosfemtmdoePoooPrtuaorntoododufsfeucCCctdtsGGs 13% B[]FFCCvWiassttwe nInncciinneerraatteedd 49%
nA by Mr pet ier tn tbc er C3460 Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
pr-- 3MA00043765
11773355..00000011
EExxhhiibbiitt 11773355
State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862
GF rqFM-3256 ROT) I~F-8733 Fost [] F-8451
I]]] F-8167
BFems ~aF-8775 Rise I~ F-1256 R73 [] F-7843 GETS 8 F-7757 Grams [] F-8228 OFT ~ F-8769
FFCC W Waassttee DDiissttrriibbuuttiioonn
o
o%
sy rma oa 5 1 sam
=2-%
"3m%o e 4% eS s N \ J 2
2%12%
"1j%oo
1%
=1% 8%
(es
------ 1% 1%
. 0T= 0%
-1%
- = 1%
0%
12%
"0%
=2% BF BRC BFE ~F-8400
I~1FC-98
BrMOS BRONS BF7IM E~FM-3149 I~F-8439
OF7IGI Ooi: BAN [] F-7161 [] F-8462
BF-8469 I]]F-7164 [] F-6050
A|< <
=2%
0%
GFoT ~F-5372 BRMGO I~F-8450 MR [] F-8485
. 10%
1%
PWS BRC BFM-3141 BETIS ORGAD 8F-7786 BEE GRGT2 [] F-8463
I~1FC-95 IBF-8443 [] F-6272
WEG ==F-6514 PMO ~FM-3173 OFOT2 [] F-8772
Ii
Pa12%
1% 1%
-0%
o0% Brits ~F-5619 OFEU0 I-IF-8178 OFWAO [] FM-4200
BRT ~F-7535 FANS ~F-4865 DF [] F-4866
GRA B]F-4863 WRTIGO I~F-7160 BREN [] F-9131
I~ F-8260
mere ==F-7524 WETS F-7939 Grew [] F-5372 WErS0 F-7510 Gre [] F-8229 OFM ~ F-7584
8 F-9125
Bers 8F-7126 OFS FI F-9142 ORTS [] F-7785 Few: B F-6952 Bee [] F-8701 BETIS I~1F-7153
I~ F-8728
EME I~F-8497 BROW la F-9144 RMD [] F-8420 WEAN ~ F-7117 BEST [] F-8702 BFW F-6567
~F-9126
OES r~F-7151 BESS F-9146 BRM [] F-8421 ORGS FI F-6537 BR [] F-8703 Brass I~ F-6566
rq F-8729
GET BF-7152 GFOUD B F-9179 RMS [] F-8452 BMAD I~ FM-4074 BESH [] F-8761 Gaz ~ F-8227
8 F-9124
GRANT BFM-3373 OFWMOS B FM-3405 ORGS [] F-8485 MEST = F-8777 WESTO F-8776 ORwad IFI FM-3131
"a F-7755
BRAY I~FM-3702 OF) B F-8469 GROG [] F-8798 BFOtR I~ F-9132 OF [] F-9100 ORM B FM-3144
~ F-2196
BRENT 1]]]F-8217 GRoM0 I~ F-9110 BRGTC [] F-9176 GR4 ~1F-9127 Gren: [] F-9112
B F-8275
BES I~F-9117 FS F-8439 WEIN F-7946 DFO: r~ F-9128 BES [] F-5522
13 F-8166
GFM3E ~FM-3602 Brass: I~ F-8652 ORS [] F-7522 ORES B F-8757 OF2mn [] F-2191
Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
3MA00043766
11773355..00000022
FFCC WWaassttee bbyy TTyyppee
we3no Bottoms FC's [Ib/yrl 59%
marian Process FC's [Ib/yr]
|26%
| i7Samreson Cleaning FC's [Ib/yr]
15%
Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
3MA00043767
11773355..00000033
PPrroojjeecctteedd RReessuullttss bbyy OOccttoobbeerr 11,, 22000000 ((PPhase |I CCoommplpelettee))
Projected ncuron o Projected Incineration of Waoy tconet 1.1000 Waste by October 1,2000
TM7%
romea. FC Waste Inciflerated
Currently
-49%
EAL
remem FC Waste Remaining at CG
31%
FC wise fom Prous FC Waste from Products Toons oo 00 Transferred out of CG
by13%
iAis pct ogo rtf.5 teoir rr 3 068 Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
swan 3MA00043768
11773355..00000044
[Fm Dteomsahn)dT||eDtemamaynd| 5 tots| mwWwasmrsstetee| ||| wRveamdesructeeed [mim FM-3256 [Fs |e [wees Ts| sme |sso [were F-8400
Demand [Iots/yr]
31 8
Demand [Ib/y~ 296774 36985
Iots/yr 31 8
lotal Pc Waste [Ib FC
waste/y~ 49321 34366
FCWaste Reduced
[Ib FC wastely~
37860 25959
% T% 22 22 16 38
0T8otwalaWsastt)e Bldg. [wwe 15 ss[=] 15
Total Waste
BC [Ib waste/yr]
34
1356129
33
% FC in
wmWaste 4%
|
FC-98
7
35000
7
26755
26221
12 50
25
87/49
198989
13%
F-8469
6
[Fs [sree | s |ms| [sTel 1s | | mes [wer] F-5372
8
[Pwo aTomo To [Tafel Bs [nl 1 FM-3141
4
[FessTa tom | &| ome |wm |alwl [ome] wore | ow | FC-95
4
0 LC 7: SCN 0 7 0 | F-6514
106
[Esso zm| | ew | o[ale| 15|x] 0 | ox | F 56!9
0 I 0 0I | F-7535
15
[Fass 5[som | 5|ew | w |olewl | =|wos| ww | F-4863
5
OL A 0 A 3 3 0 0 ---- F-8733
7
36000
6
71442
8
13350
4
19200
4
276000
106
27030
60500
15
50260
5
72000
7
20750 12150 9935 9753 9200 6919 6035 6030 5488
20750
9558 6919 5000
9 59 5 65 4 69 4 74 4 78 3 81 3 84 3 86 2 89
15
45
15
45
15
33
25
87/49
15
37
15
33
15
70
15
33
15
45
53993~ 284952
161764 249200 42500
189245
4% #REF!
6% 4% 16%
3%
FM-3149
7
[7 Fos[7T7 o 07[ww[IJ ol0o 2 F-8439
7
22935
7
25000
7
4281 3500
2 91 2 92
3515
3
[0 7370300
sww[7 301620
1%
||
F-7164
1 O6
317400
106
[[CPEmeees[o5sT [om em |Io5|2 veo F-8450
8
29600
8
3356 2631
|[T3356i[vt21res9945l3151[| 32
1 mow [1 wm |
F-7786
[NCrEes F-8443
NE252
24000
5
ww0[ 0 E2O| 3260
2
ms 1920 1823
1 96
3
70
138355
1%
[le7l0 T 0_ 1T 0| 1 97
[[CCrrFFMoa-8-3m1s17e7s83 os84ss8 [[waa72480m40n9020| [e 7848 | | v11eo5408o00n| | [lfo11lew99l 78 l15I|&33 |w _6_2m 1_16 --|Tw2% ||
F-4865
[[FCrrese F-7160
6.5
46800
7 2 TTweow| 2
10100
7
1073
27T | eeo 2
664
|[T0oJol00 fe99e99 l7w275 [ [m83=73 w ] 15T 1710
1% 1|
F-8451
[[EFsree F-7161
17
28600
17
660
2 v7 [w7w0[>||w w 2
7800
2
432
660
| [--w432
JJoo00lrw99w 99 l 1= 51 3] 2
||
F-8462
2 2 F-6050
17 1 O6
95000
397
0
70ISS JS --B 658619
300
0
0 7 1155 332662 I----|
F-8485
[[FFeemm F-8463
7
92000
7 7l[oewee 17
148000
| w8217463 [[Jfo or 00r1 1512T5 4[ 5/74 1 |
F-6272
[[Froamo F-8772
5 5230 T[wwo1138o4040n40
1 | % o9386 [[--Jfool 00l|[7[wml 1TT1|
FM-4200
10
[[ PaE ssss6[[rwemss F-4866
6
145313 73955
T| o 000 |[JToo00rlI7 o275 [ |&w7807 |lw10w500 | o0--x% ||
F-9131
[IFEee F-8167
3 69
15000
T2 em62600
I To 00
To00f8 A o0 le76 le7610 -- -- --||
F-8260
8
37360
0
[EFTor7 msTo --fm oA r 7Talo -- -- 1-- F-9125
30
22800
0
0
7
31
0
7
41
F-8728
35
[FEeTmTeTmw0l F-9126
30
22750 9600
T -- o00
--
0
To0 r
7
41
7Im0 7
42
-- 1 --
[[rrFFo--89e71m2294er]----=63
22750
TTeaom 40000
--T1 o -- 00
[To tol 00r[ r 7771[a3234 l11
F-7755
[F2 zF-2196
2 4
[s<15047o79032[ --J -- 00 0 o +4 lwo10 r ----|
F-8275
226362
0
25
87
F-8166
10
Lr 20I -- -- 0 ---- F-8775
5
C77 -- 0---- F-7524
10
2 0I --I SN 0 0 -- F-7126
9
OL 1 0SS I -- 0 ---- F-8497
3
SB 0 | F-7151
3
2 120 I -- -- 0 ---- F-7152
5
[wes 2[den1 Jorrslel | FM-3373
2
io IIS -- -- 0 ---- FM 3702
Cro 1 per F 8217
Cer 1 T JorT 1TT F-9117
[er1 ---- 1 for+-- 111 FM-3602
[Emelsm TT Jor Ts 1 | F-1256
[Fre-- Tse 1 tor+ T&T F-7939
0 0 ---- 0 ---- F-9142
ET. ES ----0 -- ---- F-9144
[Per----111 tor+ 1 1 1 F-9146
1SS -- -- ri -- -- F-9179
[Pwsss----1 1p Jor 1 FM-3405
2 SS ---- 0 ---- F-8469
J ---- 0 ---- F-9110
2 JIS -- -- 0 -- -- F-8439
LE J ---- I-- ---- F-8652
Ceme 111 Joltwi1 lwl--1 F-7843
113244 103532 87319 37115 21625 21361 20722 14877
939
2O5 2506 1175 904
8655 5850 2950 85O
0
15
52
0
15
51
0
15
27
0
15
27
0
15
33
0
15
33
0
15
54
0
15
59
0
15
59
0
0
0
0
6
0
7
42
0
7
42
0
6
44
0
0
0
0
15
45
0
15
45
0
15
70
0
7
41
0
15
45
MPMraaodtdeeectAaivvveaialOaiblearbbbIyyndl3P3MeaMelffmooerrrIInvns.spp3eecMcttiiooNnon.aannCdd2.CC0oo4pp.yy8ii3nn0gg9aass CCoonnfifiddeennttiiaall IInnffoorrmmaattiioonn:: SSuubbjjeectctttoo
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00000055
A3M0A000040343776609
Process
Process FC's
toy) Div | Bottoms c's thy)_| Tota waterpov [Ib/y~ meTo 1 wm --T@wm 13312 [ef es swe ew 84
Cleaning FC's [Ib/y~ 0 8335
Bottoms FC's[Ib/y~ 37860 25959
Total Water[Ib/y~ 837132 6035
Water
ister pyle) |water i [Ib/y~ 0 com [ees | wow 0 |ws[0 | sexo | 0
Cleaning Water[Ib/y~
652286 6035
BottomsWater [Ib/y~ 184846 0
Scrubber &jet water[Ib/y~ 9672000 2496000
26221
[0TmIwo wen10 ome | mow |mmo] 0 [ots tee mm% |_o | wim | ges | ze] 0 [oT mw TwoTwo 1 0 | oo[mow | asco | 41 [ess we Io | ee |ms | ew| 0To | 9558 [oo[ww oT www [0[wm 0[0 | 0
[Co[re r r w 5 mos |r o[wes oo | 0 | 0 [oT wowIso | we | 0 |wew| 0 | meow | 0 [oes 1 en | mew 0 |sw | mew |zen | 0
535 1750 1150 122 195 4007
6035 1031 675
0 19000 11000 9853
0 0
0 5000 4813
321481 309511 292656 32000 142496 396693
331965 183989 136537
232950 0 0 0
36416 0
0 0 0
88531 225511 91000 20000 106080 396693
331985 183989 58350
0 84000 201656 12000
0 0
0 0 78187
0 1872000 2496000 1248000
0 0
0 1560000 2184000
[C oo o41096T To w 358060 1 1 ws00
73394
56370
17024
0
0
To womTo 0 [wo ow[_0 o[ |w0 eaw1] 110750
0
110750
0
0
[[mooo1r901 --Twwe16ww019 1o 7%373959T 6 | wm3e3w6w052s5 |vo1oo9e00o9e9r2[|mm1o4e505ww33 [ ]o 000 T | z32e3409e7620o0000001|
r ----0 /---- 1920 1 ----0-- r rr 138040 0 01 r 1380410 0-- 1
r ee E r E|
o --r ----wv r r er r r 11 r 1
--00 ----001J 64-- 6302 r---- ---- --1 ----1 -- 1 --
r rr rr r
-- r ------r r r01 r 1
r rr rr r
r 1 r 1 r
r n r -- e --I-- r -- --
1 rr 1 r
r rr r 1 r 11
--r -------- r rr r rr rr
n 11 S e S 1 ---- --
r ----------r r r01 r 11
1 r1 r1 r
Y r r r0r 1r 1r 1
1 On -- 1 -- -- -- --
r rr r 111
1 rr 1 r
r rr r 1 r 11
On rr 1--1 -- 1 E--
r ---------- r r r r r
r r r r r
1 r1 r1 r
1 --rr 1 p
MPMraaodtdeeectAaivvveaialOaiblearbbbIyyndl3P3MeaMelffmooerrrIInvns.spp3eecMcttiiooNnon.aannCdd2.CC0oo4pp.yy8ii3nn0gg9aass CCoonnfifiddeennttiiaall IInnffoorrmmaattiioonn:: SSuubbjjeectctttoo
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00000066
A3M0A000040343777700
or a Bottoms "P" Process 5F'"spPerorceosst|, R"apn=k||FCC'lsepaanrinLgo|t] R"acn*k|[FCB'osptteormos|t] rank VisoWrapsotre FC. FCs per Lot FT a1oTTm TsoTT 7m 429 C1Te[7 ms [+1oT omTo | 11
"P" Rank
4
"C .... B"
Cleaning
"C"
Bottoms
FCs per Lot Rank FC's per Lot
0
1221
1042
1
3245
"B" rank
5 1
Process Water per FC
Waste 0 0
Cleaning Water per FC
Waste
0.72
Bottom's Water per FC
Waste 4.88 0
3748
1
76
0
8.88
C2 J 0 1 2| 0
292
4
3167
2
J 20 3| 0
144
7
1375
4
FoT o Tze [s 51oT ow =m | 10
31
2463
3
0
I J 1 71 J -- | 2389
2
49
0
3.81
Fo T= roTT Two 0
38
0
r o rrr ss r w r[su|_| 0
402
3
0
CJ S 0S.J| 0
206
5
1000
6
165.48 126.86 79.13 163.93 544.00 99.00
55.01 178.46
4.42 18.33 1.22
0
0
96
8
688
7
86.44
16.24
599
3
12
0
F IrC oTwS 7ro S 1 I T wea 0
500
2
0
13.44
197.95 31.64
|
0
0
FeI T= 24
202
[
32
sw--[5]--w--s 6
100
999.96
[-- 89o.89 -- 0oo |
SE
-- -- --B-- y-- -- -- -- --|
r--I rrr -- r -- r --r --
rrr rrrrrr|
ES -- rr -- -- r -- --1 --1 ---- 1-- oo
SE F -- F -- -- -- E-- YS-- S---- -- --|
r--r r -- r rrr 11 r 1
Sr S -- rr --r -- --rr -- -- -- ----
r rr r r1 r 11
ES E -- -- -- -- -- E -- -- ---- -- -- -- |
SS r -- --r -- -- r -- ---- 11 -- 1 --
r rrr r rr r r
r rr--r r--tr r--@r r--r r--r @r rr rr r
r r rr r r r r 1r 11
rrr Er YS-- Srr --|
rrr EY1 S-- S 1 -- 1|
r r rr r rr r r
EF S -- -- -- -- T -- ---- --
I rr -- r -- --r ES -- r-- r--
r I r Er E -- -- 1 -- 1 --
r rr r rT r TT
r r rr r rr rrT rT rT r
Er E --r -- -- --r ----
r r----r--fr-- r r rrr r rr
r rr t r1 p 11
TT
MPMraaodtdeeectAaivvveaialOaiblearbbbIyyndl3P3MeaMelffmooerrrIInvns.spp3eecMcttiiooNnon.aannCdd2.CC0oo4pp.yy8ii3nn0gg9aass CCoonnfifiddeenntitiaall IInnffoorrmmaattiioonn:: SSuubbjjeectctttoo
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00000077
W3MMAA000000443377T711
E eF-m5372E er T 1 T TT T Ttoe0 rrr rr T T TT T
[2 FFF--e787482o50 ----1 I1 -- tr o00 r E1 EE---- --1--
F-8421
[[FFeass F-8452
1
JJoo00 rrT TT |
F-8485
0
[emer F-8798 F-9176
--1
to00 r 1 11
[ema F 7522 [emer| F 7757 2 F 75!0 OLF-6952
A F-7117 [rer F-6537 [Pars | FM-4074 [Pom F-8777 [rom F-9132 [Eom F-9127
267448
ssemwe 54600
Tfoo 0olra44[7 787 1 1 1
5713
J JSS 5710
-- -- -- --
o o
6
17
0 i 4
10
-- ---- --
28463
Tem3SS 10468
o
15
36
----Jor0 ww o
15
32
------
9420
TTe 1|
JJooo0 rl|[+15 w[ 37ml ||
Tee8820mo4950 1[J Tooo lI o w 7175 [w ws73O3lr|
4121
o
7
41
(== TT TT [TTT TT ] F-9128
[2 ewe F-8757
1
3541
1J1 2770
T I T TooorErE
7
4 1
41
1T 0 T
--
[[rFFFo--e8822i22m89 |----1JT1 oooo r 1 1 1 TT 11
F-8761
[e ro e---- F-8702
f 1 T F T
Jtoo0o rr--r+T -- 1 TT 1
[[eeFFw--8877e6e013 1 ----11Jf1 o00orrt11 1 1
F-8776
[[eesoe F-9100
----
1 --1 [J Jo00 r 1 o 1T 1 r T 1
F-9112
e 1 m F-5522
w49e5920 IS
----to0o r Y 77 1 J42 -- &-- 1
[[reFFo--e28179s6e19 ||1 s346w47057e5 || JToo00ll|2255 [e[ 8877 l--11|
22 F-7584
J J 2906 -- ---- -- C 00 4S 1 1-- -- 0 -- ---- --
[[eFsFFe66o55r66s76 ||o 1570 p po00 r 1p 5 51
F 8227
[eI saI FM 3!3!
--1 --[ --J --or r0o ET -- --T -- -- |
r -- FM 3!44 -- r r r rrr 0 r r r r r
[-- fas [ r--rT-- wos[7 wor w r [ r-- r1 r r 1 r --1 r
C To ---- O ------ Totals %
221272 38.2
136715 61.8
% with
scrubber
MPMraaodtdeeectAaivvvaeaiilOaarbbdlleeerbbIyyn33PMMalffomoreIInvrns.spp3eecMcttiiooNnon.aanCnd2d.CC0oo4pp.yy8ii3nn0gg9aass CCoonnfifiddeennttiiaall IInnffoorrmmaattiioonn:: SSuubbjjeecctt ttoo
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00000088
M3MA0A000004433777722
O 1 n 1 E-- t rt r r eS r SY r rr rr r 1 r1 r r 1 r 1 r r rr T r Se S r S r ES -- r 0 r SY | 1 -- 1 1 1 r 1r 1 -- r 1 r 1 r 1 r1 r r r r r r r 1 r 1 r r r r r r e rAe r SY S-- r 0 r SY 1 r] r n 0 e SY SS -- r rr r 011
LT Teme [T eT + [mmr ww| vem | wees | em|wmer| mew | 53602
Ce Tw T ["w m[ _] 24
30960 14
118732 54
3649204
516728 14
2571787 70
560689 15
60745204
1
4
1
Ininertodianatored Incineratedttransferred Negiatle Negligble
Trsierod vias Trans~rredWaste 90 27669.0 B13
WaWsatseteolisnn0cd4inneeerrawteodd 3 109046
49
FCWaso FCWaste Remanag Remaining wes 84557
38
Projected Pr~ected Incnraton Incineration 12 1~612
Progcad Waste Pr~ectedWaste Raman Remaining oes 67945
sew 57096000
[a94
PMMraaodtdeeectAaivvveaialOaiblearbbbIyyndl3P3MeaMelffmooerrrIInvns.spp3eecMcttiiooNnon.aanCnd2d.CC0oo4pp.yy8ii3nn0gg9aass CCoonnfifiddeennttiiaall IInnffoorrmmaattiioonn:: SSuubbjjeectctttoo
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00000099
W3MA0A000004433777733
Product
Name
Engineer
Base FC (POSF, C8 Acid, etc.)
Cleaning method (causitc, sulfuric, etc.)
Demand [Iots/yr]
Demand [Ib/yr]
Total FC Waste [Ib FC
waste/yr]
FC's lost to
the sewer
% T%
[Ib/yr]
FM-3256
=e=eele Ll F-8400 oe em [ae[on [LIT FC-98
C8 acid fractionation fraclionated PECHSF (FC-98)
FC-98 reaction and drying
oe] me Jol [ae [Tal LLL F-8469
HQ115 reaction
a feed f ce LoJST F-5372
FC-24
d LeleLn eLl T] FM-3141 lee em[ae[we [Tala LET FC-95
Distilled EBSF (FC-98) FC-95 reaction and drying
DG
C8 Acid
KIH
PECHSF
KIH
PECHSF
Caustic and Water caustic caustic
BLH
PMSF
Butyric, water
BLH
Cl, PMSF Acid
Butyric, water
KIH
EBSF
KIH
PSF
caustic caustic
31
296774
49321
22 22
49321
8
36985
34366
16 38
8407
7
35000
26755
12 50
26755
6
36000
20750
9 59
20750
8
71442
12150
5 65
12150
4
13350
9935
4 69
8155
4
19200
9753
4 74
9753
ssm Le| =e slg Lil F-6514
C8 acid powder
DG
C8 Acid
water
106
276000
9200
4 78
4O07
[ome| opmmomrosis |on[oorinma| wwe | 0 [om|ew[alu] ow| F-7535
Dry Lithium Salt for FC-24/28
lon orem[new | om| [ml LT] F-4863
Distilled PDSF (FC-120)
lam ee[| oe | | [om [aLL] F-8733
Acid Hydrate Distill FC-156
fiat all il Erte] FM-3149
[rom] voor [anPT we [0Tom ww[ofa] we| F-8439
Crude EBSF (FC-98) HQ115 drying
f aad Le F-7164
One Plated C8 Acid for FC-143/118
BLH
PMSF Lithium salt
KIH
PDSF
BLH
PMSF
KIH BLH
EBSF PMSF Lithium in]ide
salt
DG
C8 Acid
caustic water caustic water caustic water none
FS i Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
27030
6919
3 81
15
60500
6035
3 84
6035
5
80260
6030
3 86
1031
7
72000
5488
2 89
5488
7
22935
4281
2 91
4281
7
25000
3500
2 92
3500
106
317400
3356
2 94
0
3MA00043774
11773355..00001100
Description and Composition of sewered waste FC's lost to the
[Process step(Ib/yr,cornposition)]
air [Ibhyr]
co[rm o mmmme Description and Composition of air emissions
FC's incinerated
Description and Composition of incinerated waste
[Process step(Ib/yr,composilion)]
[Ib/yr]
[Process step(Ib/yr,composition)]
222706 Ibs/yr total waste is produced from
sinreCho 1 fractionation bottoms. Of this 17% are FCs and 83%
is water, sulfuric acid and filter cell. 665598 Ibe/yr
a ones mene on total waste is produced from cleaning. Of this 2%
are FCs and 98% is water and sodium hydroxide.
CCenn Distillation(?,>99% water,<1% FC's (64
Ib/yr));Cleanup(14371 Ib/yr, 42% water, 58% FC's) Water washes/filtration (189,286 Ib/yr, 86% water,
geen 14% FC's);Cleaning(89066 Ib/yr, 99.4% water, 0.6% FC's) Bottoms(103,000 Ib/yr, 81.6% water, TEA, H2804, EoH UCEu14b .44FwEe yCoa, n LiOH, Li Carbonate, 18.4% FC's);Clean-up
otvo utsac one sscoh a emGt. co etnrcs any Iowboilers lost out of the vacuum system will be
0
condensed and sent to the sewer through the hot well.
| ee To negligible
Charging, Distillation, Draining
TO ToT negligible
Charging, Draining
0 25959 none
Based on the material from Decatur, no amount is predicted since the amount todate is zero.
Bottoms(25959 Ib/yr, 100% FC's)
(227,261 Ib/yr, 99% water, TEA, H2SO4, LiOH, Li Carbonate, 1% FC's)
wa TN Bottoms(212656 Ib/yr, 94.8% water LiHSO4,
LixSO4 H2804, SIC2, 5.2% FC's);Clean-up (92150
EE Ib/yr, 98.75% water, LiHSO4, LixSO4,H2SO4, sic2, 1.25% FC's)
= m Eae Distillation (?, ':1% FC's, < 41 Ib/yr FC's); Clean-up (20122 Ib/yr, 99.4% water, 0.4% FC's); Bottoms (19992 Ib/yr, 60% water, 40 % FC's) Water washes/filtration (145973 Ib/yr, 93% water,
mem TCO 7% FC's);Cleaning(106275 Ib/yr, 99.8% water, 0.6%
negligible negligible negligible
Charging, Distilling, Draining
1780
EE Bottoms(1780 Ib/yr, 100% FC's)
FC's)
negligible
Charging, Draining
none
This is based on theoretical powder yields
calculated for Lots 194-199 & 10001-10012.30% of
"etpv ar wr nnd the total powder losses are assumed to end up in
the sewer system. The total amount of waste to the
etsoe 070i 017 Toes rtm 60100 sewer is estimated to be 400700 Ibs/yr. Of this 99%
PEE wege | n) iswater.
73405
This is based on inert balances for lots 19z~199 & 10001-10012
[compmm|wowem|ooimeonron| Clean-up (338000 Ib/yr, 98.2% water, 1.8% FC'a)
Distillation(?,>99% water,<1% FC's (258
EE5 R TT To -- | Ib/yr));Cleanup(183989 Ibtyr, 99.6% Water, 0.4% FC's) Bottoms (63,000 Ib/yr, 94.2% water H2804, mm TT Li2SO4, 5.8 % FC's); Clean-up (59,025 Ib/yr, 98.9% water H2SO4, Li2SO4, 1.1 % FC's) Water washes/phase splits (60566 Ib/yr, 93% Ems Water, 7% FC's);Clean-up (17110 Ib~ryr, 99.5% Water, 0.5 % FC's)
Clean-up (114,250 Ib/yr, 96.9% water, 3.1% FC's)
negligible negligible negligible negligible negligible
CITT r em r This reactor is almost never cleaned.
0
Charging, Distillation Charging, Draining
5000 none 3356
FS -- Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
Bottoms(5000 Ib/yr, 100% FC's)
61163 Ibs/yr of total waste are produced from distillation bottoms Of this 5 5% are FCs and 94 5% being sulfuric acid
potassium dichromate, and filter cell. 3MA00043775
11773355..00001111
Bldg.
Total Waste % FC in
BG [Ib waste/yr]
Waste
Fe 15
34
1356129
15
33
25
87!49
198989
4% 13%
15
45
53993~
4%
BR
15
45
284952
#REF!
ILek 15
33
25
87f4,9
161764
6%
15
37
249200
4%
[el|]1 15
33
15
70
42500
16%
Lalol a] 15
33
189245
3%
lel 15
45
lal 15
33
[owo en|] w| 3
70
301620
1%
LLL T] 15
32
Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
3MA00043776
11773355..00001122
Pps F-8450 F-7786
RC8 Acid from RC8 NH3 Salt FC-122
mee DG
BLH
C8 Acid PMSF Lithium salt
Caustic and Water water
Ee 8
29600
2631
1 95
2631
5
24000
1920
1 96
1920
is tllss t] o le F-8443
N-Ethyl Fosea monomer, FX-13
FM-3173
ffactionated butyric acid (FC-23)
JPS KIH
POSF PBSF
Acetone caustic
326O
1823
1 97
1800
28492
1500
1 97
1500
F-8178
aoe| comcrrern |om | ow | we [0[an on[o]u] wn] F-4865 [erm | eros [er|ow | mews12Ton[on Tole] or| F-7160 Lar|commtcmase| 0| ome| en |v Lom] eo Jou] | F-84.51 [ore | eevee |or ow| sme 2 om| en [elu]=] F-7161
20% Aq Ammonium Sslt (FC-118)
C10 sulfonic acid (FC-120) MeFOSEMA decolorization One-Plated Recovered C8 Acid Methyl FOSEMA reaction
DG KIH JPS DG JPS
C8 Acid PDSF POSF
C8 Acid POSF
None caustic Acetone, water flush
none Acetone
88
740000
148O
98
148O
6.5
46800
1073
0 99
1073
2
10100
664
0 99
664
17
28600
66o
0 99
0
2
7800
432
0 99
0
F-8462
Recovered C8 - 35% NH3 Salt
DG
C8 Acid
Acetic Acid
17
95000
397
0
397
F-6050 F-8485
FC-118/143 Ammonium Salt Slur Triflic monohyd
DG BLH
C8 Acid PMSF C1 Lithium
salt
Acetic Acid water
J OO 9 IO F-8463
Ce Domrmncomme | a| ror | meT=Te|a F-6272
Recovered C8 - 20% NH3 Salt 50J50 ET FOSEMA:ODMA Polymer
DG JPS
C8 Acid POSF
Nene Acetone, xylene
mim -------------------- Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
1 O6
658619
300
7
92000
276
17
148000
143
2
13444
98
9
30o
0
276
A0
143
ITs] 0
0
rn 3MA00043777
11773355..00001133
191183 Ibs/yr of total waste is produced while
= purforming the re-acidification/phase split steps. Of r Th a this 0.1% are FCs with the remaining 99.9% being
sulfuric acid and water. 19964 Ibs/yr of total waste is )roduced while draining bottoms from the distillation
ER= EA eno Of this 4% are FCs with the remaining 96% being =pen, sulfuric acid and filter cell. 147152 Ibs/yr of total
waste is produced while cleaning. Of this 1.1 % are FCs with the remaining 98.9% being sodium hydroxide and %~ter.
[mmmeo s mem ee[ pT mo T n] e Clean-up (140,000 Ib/yr, 98.6% water, 1.4% FC's)
SSEeES ea 1 .Water of reaction. 2.3 Water/NaCl washes to remove acids. 36# acrylic acid, 12# H2SO4, 108# ms NaCI, 4986# water (1823# EtFOSEA)('150# EtFOSEA) mEToi eee Fractionation (?, ~1% FC's. ~ 10 Ib FC's/yr); e | Cleaning (90946 Ib/yr, 99.98% water. 0.02% FC's); e Bottoms (31777 Ib/yr, 95% water, 5% FC's)
0 negligible
0 negligible
10# heptane from heptane strip from batch. Charging, Fractionating, Draining
0 32 none
1. Pre-run acetone boil. 2. Heptane strip from batch. 3. Postrun acetone boil. 3,100# - 2000# acetone, 1,050# heptane, 32# EtFOSEA
This assumes a 99% yield based on powder
weights. This is an assumption based on
engineering judgement since pcducs does not
re Hooe fe r| accurately repot[ the yield do to inacurate heel
weights. This does include residual powder left in the premix drums. However this neglects any rinse
FEES water used to clean the premix drums, pump and hoses. An estimated 7400 Ibs (20% solids) total is lost per year. Water washes(199,304 Ib/yr, 99.7% water. 0.3% FC's);Cleaning(1,958,830 Ib/yr, 99.97% water,
T_T
0.03% FC's)
negligible
Charging, Draining
0
(664# MeFOSEMA) Flush solids in reactor to sewer
with water. 6000# flush water
0
N/A
0
Pre-run and post-run acetone boilouts.
13210 Ibs/yr of total waste are produced from distillation
bottoms. Of this 5% are FCs an~ 95% are sulfuric acid with
The reactor is almost never cleaned
0
660
trace amounts of dichromate.
r e m rI N/A
0
N/A
39700 Ibs/yr of waste are produced while cleaning.
Of this 1% are FCs and 99% are water and acetic
acid
0
approximately 24500 Ibs/yr total waste are produced
from cleaning. This assumes that 0.1% of the F-
6514 demand is lost while cleaning during the F-
432
Post run
0
[ompvommeymmmeommen|meeTT] 6050 step Clean-up (160276 Ib/yr, 99.8% water, 0.2% FC's)
negligible
kettle cleaning.
---- ]| 8,000# acetone, 432# MeFOSEMA
EE ------ 715 IbsJyr of total waste are produced during
disconnecting hoses, flushing lines, and washing
totes. Of this 20% are FCs and 80% is water.
0
0
Solvent strip of FM-3546 raw material. 14# acetone
N!A
0
vented
98
Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
10,014 solvent,
7022# acetone, 100# filter cake
2600# xylene, 60# (98# EtFOSEMA
--Amsco G
polymer) 3MA00043778
11773355..00001144
TT 3
70
138355
1%
15
33
62116
2%
LooLe|] 25
87
151710
1%
Lele]|] l= | 7
33
15
32
CI 1 15
36
"TH 15
36
15/25 45{74
"II seTI T Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
a3MA00043779
173355..000015
F-8772
20% Aq Sodium Salt (FC-1090)
FM-4200 F-4866
SECarbowx 350 Chlor F/FC760 Ammonium P-decane (FC-120)
DG
C8 Acid
5 JPS
KIH
ROH [CI] with SOCI2 PDSF
Acetic Acid
Solvent acetone
18000
36
36
10
145313
6
73955
4
F-9131
[el eT fe aTeaTe oLo] F-8167 [ioe] mpm | sefumedsmstz | [| [IT] F-8260
Crude Trimesoyl Trichloride TBAPCL/TMS curative Tributylallylphos chloride
filmes seas stsnitioiol i F9125
[am|smc | mn[ne| comme|[om[ 0[J] ] F-8728
HX 868 Aziridine Imidation HX-752 AZIR. CUR. FIN. Strip
ArylOOH [CI] with
JPS
SOCI2
Acetone
3
JPS
Aryl Phos. Chl. Salt
Water Flush
69
JPS
Aryl Phos. Chl. Salt
Dilute acetic acid, acetone, dilute ammonia solution
15000 62600 37360
JPS JPS
Aryl Aziridine
Acetone, caustic, water flush
30
Aryl Aziridine
Caustic, acetone
35
22800 22750
0
0
0
0
0
0
0
0
0
o
0
0
0
F-9126
HX-868 Aziridine Purify
JPS
Aryl Aziridine
Acetone, water flush
30
96OO
0
0
0
[om] mee | maTerme | zm |e Teme fe | 2] F-8729
Final HX752 Blend
JPS
Aryl aziridine
acetone
22750
[ima] smo| Tema! ae Tem] = JITo] F-9124
Distilled TMTC Solution
JPS
Aryl Acid Chloride
Solvent
40000
Co]_rmmme Lon [or[orm To I LIT] F-7755
Scotchban (FX-840)
HAH
POSF
bulk mixed cleaning solvents
10793
ame be s a F-2196
Crude EPX Catalyst
PJG
PMSF
Acetone
5470
Iner~s for ~pray
Pri_p]----mm--e_gro-- mm T_o TTL 1FT F-8275
FC Solvent for FC-143/118
DG
drying
226362
0
a P E -------- E --Tr----nne F-8166
SF-2
KIH
Inert
none
10
113244
0
F-8775
PF-5058
KIH
Inert
5
103532
o
ee F-7524
Heat Trt PTAA LB for FC-40
KIH
Inert
FCHC-123
10
87319
o
mi ------------r------ Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
ne 3MA00043780
11773355..00001166
TET This is based on an assumption that 1% of the F-
8772 material (20% solids) could be caught up on
LEthe vessel walls after draining. The amount of acetic mm te acid used for cleaning is based on 08/99 YTD data.
The amount of water used for cleaning is based on
prema 6000 Ibs used per cleanup. Based on 08/99 YTD
data a total of 3 cleanups are required to produce 18000 Ibs of F-8772. The total waste produced would be approx. 18115 Ibs/yr.
(195,519 inorg salt; 8,583 chlorinated product; no
TE FC) (195,519 inorg salt; no FC) Total waste per yr SN Ces 529,486 lb. 1615 HCI# from kettle sweetener;
86,900# off-gas/x's SOCI2 neutralization salts,
a 108,620# x's NaOH for neutralization; rest water; No =FC
HN7OO
-- EE-- RI--E -- From vacuum strip of excess SOCI2 reactant. 203# product chloride; 497# flush hexane; No FC
| A e l a , | 73,500
20,000# pre-run acetone; 3380# filter cake( 2366# chlorinated product, 1014# clay); 50,120# solvent flush
(6014# chlorinated product); no FC
(165,248 - 485# HCI, 14,700# NaCI, 26,692#
ns ee| Na2SO3, 15,874# NaOH, 4549# DMF, 49# SOCI2,
260# TMTC product. No FC) (146,088 - 485# HCI,
EE i 14,700# NaCI, 26,692# Na2SO3, "15,874# NaOH, Te | 88,337# water. No FC) Dilute HCI solution for E prete ed [vem reactor sweetener. Neutralize rxn oft-gases and
180-122# ~lunene, 49# SOCI2, 9# DMF.
one 18,980 - 6000# nr acetone, 260# TMTC E FERETEt pr ps e msions )roduct, 4540# DMF,
Pre-series, post-series acetone cleaning. Vacuum solvent
P [mmm |E |ww | eE rT,w] excess thionyl chloride with caustic solution (69,310, no FC)(311 Ib FX-5166 curative. No FC.) Post-series water flush of ribbon blender (253,088. No FC) (440 pounds excess allyl chloride
No FC) Neutralize excess allyl chloride in scrubber
No FC None
Solvent strip to concentrate and purify the batch. 6160# toluene. No FC 35
44~ Ibs allyl chloride vapor lost during vacuum strip. Nc
[e3m--] strip to concentrate and purify batch.
Lost during blending to exhaust; captured in separator. No FC.
48# allyl chloride; 1680# aqueous ammonia; 2275# butyl
with 50 % caustic.
64
FC
36,000
celloaolvs; no FC
(5,340 inorg, potassium salts, no FC) (5,340 inorg.
[EERS E Pot. Salts, no FC) Phase split water phase away from organic product phase, caustic boils, water flushes
(110,985 - none is FC) (22,750 - 6125# NaOH, 16,625#water. No FC.) Pre-series dilute caustic
boilout
ee = e meTmn wo 570 CO2, no FC
Gas evolution as reaetion product.
735# toluene. N
FC
Assume 1% of solvent stripped from batch is vented.
None 14000# acetone, 73,500#toluene. No
FC
6000# waste acetone solvent
Pre-series and post-series acetone bctlout. Solvent strip of organic product phase.
18000#-9000#
90 - 6# butylene
WcB omne pieereM|EE9L2E (6030# isopropyl ether, 2520# toluene, 450# butylene imine. No FC) Waste wash w~ter phase separation. Between lot reactor water flush.
imine, 60# isopropyl ether, 24# teluene. No
FC
EEE E= E | rema em. Assume 1% of solvent stripped from batch is vented.
acetone, 6030# ~sopmpylether, 2520#
bluene, 450# butyleneimine. No
FC
Pre-series and post-series acetone boilout. Solvent strip of organic product phase.
(17,850 - 1050# HX-752 product, 16,800# acetone. No FC)
[reN/A
None
1The1[e 1e None
N/A None
None
Pre-run and post-run acetone boilouts. Pre-run and post-run solvent boils yield 39,600# waste
[nie]] solvenl.
_ r t 1 r + t T 1 --------------_---------------------- i" 7SH" Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
]11 waar 3MA00043781
11773355..00001177
7
7O
25
87
10500
0%
7
7O
Cel 1 6
61
ARE 7
31
7
41
7
41
Ail 7
42
Le 7
33
CTT 7
24
J 1 -- 4
10
Ll 1 25
87
He ---- 15
52
15
51
PH--1--] 15
27
oh i ae Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
Ro3MA00043782
11773355..00001188
[e em we m Twm a [eT F-7126
Heat treated PTAA Inert (FC-5312)
KIH
Inert
none
9
37115
0
[rar| rkeares || owe [3 me| s[Le F-8497
frac top PTAA iner~ (FC-5312)
KIH
Inert
caustic
3
21625
0
A --.-- -- F-7151
Perm treated PTAA (FC-5312)
KIH
Inert
oaustio
3
21381
0
[om| Sermmmerears|e wea ww pe F-7152
Si-gel Trt PTAA Iner~ (FC-5312)
KIH
Inert
none
5
20722
0
FM-3373
Si-gslC8F18/C8F160
KIH
Inert
none
2
14877
0
p> on erm fr FM-3702
FC-104
KIH
Inert
none
939
0
[rem |remerr--owe------pe---- F-8217
Fractionation for SF-2
KIH
Inert
0
Dw wom terme wep F-9117
PF-5056
KIH
Inert
none
0
FM-3602
FC-75
KIH
Inert
none
0
gl F-1256 F-7939 F-9142
meme One Plated Acid for FC-26 Perfluorosulfonic acid Esterifica4ion of C8 Acid
[glen DG LMT
C6 Acid C8 Acid
|
oo None
Water Flush
[L121 2O5 2506
LMT
C8 Acid
water Flush~'acetone boil
1175
L00IT.
0
F-9144
C8 Distilled Alcohol
LMT
C8 Acid
water Flush~'acetone boil
9O4
0
water flush, caustic boil,
F-9146
Distilled Polyfoma Monomer
LMT
C6 Acid
aoelone boil, water flush
0
[Tr E mer rase pe F-9179
Polyfoma in H FE7100 (FC-732)
LMT
C8 Acid
acetone
0
[sm | em Femme{Oi --Gvies[wer] FM-3405
Gycline Persulfonicacid CPLX
LMT
C8 Acid
water boil
0
[rem | Grntomes or wep F-8469
Li Trifluo Meth Sulfonimide
BLH
8655
0
[Fm omnes wr we [La F-9110
Aqueous Lithium FC96
BLH
5850
0
[Tos moe Br1 Pas pe F-84.39
Lithium Bis-Trifluoromethane
BLH
2950
0
F-8652
[res oem we pe F-7843 r wrms pr F-5372 Cre pee we pr F-7785 [re smear fe F-8420
F-8421
EE -- -------- ai -- F-8452 EC -- 0 ---- ------------2i-- -- F-8485 [row cto Wr pe F-8798 [Troncme emo -- F-9176 [ [s |e St eteiw |G | or| s wae|fe rr ~ [oe| Gmwitrorems oo | eo pe ~ I -- ------. -- i . -- ~ [rr Teta way pr F-6952 rememreso ww pr F-7117 [rar meres ww pe F-6537 [er | minpe r FM-4074
N-Butyl FOSEA Monomer:FX-189 Li cake recovery Crude Triflic Acid
FX-9161 Foam Slabilizer Stabilized C8 Acid in inerts C8 Acid (>96% C8;0.0-0.5%HB)
Triflic Anhydride 30% Lithium Salt (Aq) Triflic Acid Monohydrate Polyfoma in C6 Inerts (FC-722)
100% Polyester for FC 22~ Qro'Jnd PET for FC 22~ PET for FX 22~
FC-126 Ammonium Salt Slurry One Plated C8 Acid for FC-126
Spray Dried FC-126 Camphene Catalyst
BLH BLH BLH BLH BLH BLH BLH BLH BLH BLH
DEN DEN DEN DG DG DG EEG
85O
0
0
0
0
0
0
0
0
0
0
267448
0
54600
0
5713
0
5710
0
28463
0
10468
0
9420
0
0
F-8777
[ror tomtom wwe fr F-9132 i -- 1R-- -- -- F-9127
[rm S Ae ts pr F-9128 [Rs roe oe pr F-8757 [rem wmes -- ws pe F-8228 I -- i ----------i-- -- F-8229
640MW PECH Mono-0L/Dioxslane Dist Trimesoyl Trichloride HX-868 Final Solvent Strip
HX-868 Blend and Package Peo-600 diacetate TEPAN HX879 TEPANOL
JPS JPS JPS JPS JPS JPS JPS
8245
0
8090
0
4121
0
3541
0
2770
0
0
0
F-8701
4500MW PECH DIOL/"FRIOL (RXN)
JPS
0
[ror mmmromero ws per F-8702
4500MW PECH Polyol (Purify)
JPS
0
[Fam sss ee fT F-8703
4500MW PECH Polyol/Dioxolane
JPS
0
[ro -- Tse te yo ---- F-8761
Triphenyl Sulfonium Chloride
JPS
0
[rar |wpe} F-8776
640MW PECH Mono-0L (Rxn)
JPS
0
nA by Mr pet ier tn tbc er C3460 Made Available by 3M for Inspection and Copying as Confidential Information: Subject 1o Protective Order In Palmer v. 3M, No. C2-04-6309
wanes 3MA00043783
11773355..00001199
T F + -- F r F T T F r ---- F F F F
Me EE | e 1 This material is drained off of the F-7164 run when needed. Any associated wastes have been accounted for in the F-7164 process.
seret F = F = F F F t F -- 1 + F = -- -- -- F F F 1 F g F se--ie_s-- -- ----.-- ---- --- , ---- ----1---- --.-- F -- ----- , .-- -------F F t F F r F s -- ------ -- -- ---- -- .----- -- +--t F F F F = F F -- --+ -- --F -- -- = tF+ Frr--= -- F -- --+ 1-- ---- -- --F ------ ---- - ---- ---- -- --[i MadeAvailable by 3M for Inspection and Copying as Confidential Information: Subject 1o Protective Order In Palmer v. 3M, No. C2-04-6309
3MA00043784
11773355..00002200
TE 15
27
EE 15
33
Br 15
33
Et 15
54
He 15
59
E e --e e -- 15
59
L e r6 L e e
7
42
7
42
6
44
E = EEe E 15
45
Er---- 15
45
Ee 15
70
PE 7
41
Ee 15
45
= = 1 a = = = a Ee = 4
8
Ee 4
7
er 6
17
Et 4
10
Ee 15
36
EE 15
32
EE 15
37
E -- E 7
70
Er---- 15
33
EE 7
41
-- 7
41
EH 4
10
min ----------= = e = E = = ----= ----e e = --=-- Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
Fn 3MA00043785
11773355..00002211
er mmm F-9100 Pees Pep F-9112 n= = : F-5522 [ro]smc|F&F F-2191 Fre wet F-8769 Cereb F-7584 Eeere ,~6,=567 [Fm rre | Grae e e Fb t ] ~ p er ee e e eF F e ----F --b --t + ----F H ---- ---- FM ~!dd
Triton X100 Chloride DICB Curative FC-93
perfluoroctanesulfonic acid (FC-93) Sulfonic Acid in IPE
Purified PFBF for I-1176
~-~n~u~= ("20% u~ ~^,*
FX 91 ~5 Foam Stabilize;
Frast~natcd C9F!~0 ~n~s
JPS JPS KIH KIH LKR LKR
~
P~G
~
0
0
4959
0
44O7
0
36755
0
o
2906
0
1570
0
0
o
o
0
221272
aAin pet emt Crean. ts io 1GE Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
-- 3MA00043786
7173355..00002222
7|
7
42
| 25
87
FE F E r e r 25
87
4
10
E 1 e E n ] 15
51
= 1 eeee eF ses |
aAin pet emt Crean. ts io 1GE Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
o-- 3MA00043787
11773355..00002233
RRaannkikningq SSttrraatteegqiieess..
Total FC
a Ranking by FC's per Lot ----
Waste
Total FC
"C .... B"
Demand
Demand
[Ib FC
Waste
"P" Process FC's "P"
Cleaning
"C"
Boffoms
"B"
Product
FM-3256
Ee rere Fe ee F-8400
FC-98
ee eH ae F-8469 ne | F-5372 Es eet H e ee ee FM-3141 EE eH FC-95 He taa t H t s s F-6514 ata Pe a = F 55! me a pe | F-7535 He rerr Hee ee F-4863 Heree ae F-8733 Fo reH e ae s FM-3149
F-8439
men tmn | F-7164
F-8450
em eee ee Ey F-7786 Feet ttf t--+------+++ F-8443
Eos tsett +++ FM-3173
F-8178
ee ofa Far FFF F-4865 efe e e F-7160 East teeta++++++ F-8451
F-7161
et -- Ht + F-8462 Het F-6050 etre ttt F 8485 Eee F-8463 Here F-6272 = I--r-------- F-8772
[Iots/y~ 31 8 7 6 8 4 4 106
15 5 7 7 7 106 8 5 2 4 88 6.5 2 17 2 17 106 7 17 2 3
[Ib/y~
296774 36985 35000 36000 71442 13350 19200 276000 27030 60500 50260 72000 22935 25000 317400 29600 24000 3260 28492 746000 46800 10100 28600 7800 95000 658618 92000 148006 13444 18000
Iots/yr 31 8 7 6 8 4 4 106
15 5 7 7 7 106 8
waste/y~ 49321 34366 26755 20750 12150 9935 9753 9200 6919 8035 6030 5488 4281 3500 3356 2631 1920 1823 1500 1480 1073 664 660 432 397 300 276 143 98 36
Rank
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 18
per Lot 429 11 3746 0 0 10 2389 0
0 0 0 599 0 0 24
Rank 4 1
2
FC's per Lot 0
1042 76 292 144 31 49 38
Rank
1
4 7
FC's per Lot 1221 3245 0 3167 1375 2463 0 0
rank 5 1
2 4 3
402
3
0
206
5
1000
96
8
688
3
12
0
500
2
0
0
32
202
6
100
aAin pet emt Crean. ts io 1GE Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
rs 3MA00043788
11773355..00002244
Ranking by % FC in Waste Stream %FC'sin
%FC'sin
% FC'S in
Process
Cleaning
Bottoms
Water
Cleaning
Water
Bottoms Water
Water
Ce tae] Process Water [Ib/y~ 0 0
Stream 100 100
Water[Ib/y~ 652286 6035
Stream 0 58
[l~y~ 184846
0
Stream 17 1 O0
232950 0
Ena | 0 ete 0
36416
ss 0 f twa= t 0 fH 0 Ee ns| 0
10
88531
1
0
225511
1
0
91000
1
100
20000
1
21
106080
0
0
396693
1
0
331965
2
0
183989
1
0
58350
1
0
0
84000
18
201656
6
12000
45
0
0
0
0
0
0
0
100
78187
6
56370 0
te 0 eeE -- F F F F f F E t F E ee -- -- F t --e -- F F F F -- -- t oT F F u -- t a ne-- -- e -- +e -- F F F F -- ] -- -- + -- e--y 190992
7
17024
1
0
110750
3
0
0
0
0
145533
1
0
0
0
0
0
100
0
100
aAin pet emt Crean. ts io 1GE Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
-- 3MA00043789
11773355..00002255
1 F ---- --F ----7F -- 171-- -- -- --------
Et -- -- i ---- 516728 105132 1
2433747 495162
4
560689
492
#DIV/0!
100
#DIV/0'.
4
nA by Mr pet ier tn tbc er C3460 Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
swan 3MA00043790
11773355..00002266
SSttrraatteeggiieess ffoorr FFCC WWaassttee RReedduuccttiioonn
RRaannkk PPrroodduucctt SSttrraatteecglyy
AAccttiioonnss
[7 eErE P1
FC-98
P2
FC-95
P3
FM-3149
a. Incinerate and or minimize all washes
poem hJ2"i6oetr20rpse et reor $w2a9t1h7 a. Incinerate and or minimize all washes
m-- peTeesreper-- vCerov5ecr TO ee a. Incinerate and or minimize.
. Incinerate. Cost would be $0.70tlb aq waste or $181,420 per year or $25,917/lot. 2. Use 2 smaller initial washes? Complete.
. Incinerate. Cost would be $0.70tlb aq waste or $60,566 per year or $8,652/Iot.
Ee Ee P4
FM-3256
a Continuous fractionation to remove HB's prior to FM-3256 process
Complete
lo RatesHasowem2se 1 Hos gear recy! b. Reduce # H2SO4/#FM-3256 lc Us thatshsort f1o rPecresossucotyyereessvcised c. Use methanol as bottoms solvent
. Need longer agitator - Priority!! 2. Process study needed.
. Process study needed.
d. Incinerate
Incinerate. Cost would be $0.70/Ib aq waste.
c1
F-8400
=C2
F-8439
erC3
F-7535
ie e re C4
F-8469
C5
F-4863
foC6
F-8450
orC7
F-5372
io Far C8
F-8733
em a. Minimize water I TryheoH b. Try MeOH lc ncrchean tvaete c. Incinerate clean-up water & nose d. Incinerate
a. Minimize water b. Incinerate a. Minimize water b. Incinerate
a. Incinerate a. Incinerate a. Incinerate
er a. Incinerate
1 chert Cos$07t50aoq vasnte . Incinerate. Cost would be $0.75tlb aq waste or [1077 errr 1471k $10,777 per year or $1,347/Iot. Tero som pow . Remove solids prior to wash fo 02sutras 2. Try 2 smaller washes 1 cher Cost$02o08uavbseeor . Incinerate. Cost would be $0.20tlb aq waste or 223% errr S32640t. $22,852 per year or $3,264/Iot. 1 cee Co$s0208tsavae s cr . Incinerate. Cost would be $0.20tlb aq waste or 587600 er eoror S4281t $67,600 per year or $4,508/Iot.
. Complete
f[eToers Cosie0t20v%seoasg . Incinerate. Cost would be $0.20tlb aq waste or
557.0% er earor 57 cx $37,004 per year or $7,400/Iot. [eae Go02t 0%sas ver . Incinerate. Cost would be $0.20/Ib aq waste or 25.402 ereror 5 e00t $29,432 per year or $3,680/Iot. Terie Co To a ase . Incinerate. Cost would be $0.20Jlb aq waste or 18452 ereror 52.3080 $18,432 per year or $2,304/Iot. [Pers Cov 0200esevner 1. Incinerate. Cost would be $0.20Jlb aq waste or 17208 erer reir $11,804 per year or $1,688/Iot.
MPMraaodtdeeectAAivvveaailOairbdlleearbbybnyl33PMMealffoomrreIInvrn.sspp3eeMcc.ttiiooNnon.aanGnd2d.CC0oo4pp.yy5ii3nn0gg9aass CCoonnffiiddeennttiaall IInnffoorrmmaattiioonn:: SSuubbjjeectcttoto
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00002277
M3MAA00400I4T37S9!1
TE a [BB212 B3 a freemen B4 a B5 Fe B6
Iressaincretomamazebctons F-8400 F-8469
a. Incinerate/minimize bottoms a. Incinerate/minimize bottoms
FM-3141
a. Incinerate/minimize bottoms
b. Try MeOH as solvent vs H20
F-5372
a. Incinerate/minimize bottoms
FM-3256
b. Incinerate/minimize bottoms
F-4863
B7
F-8733
a. Incinerate
B8
F-8450
a. Incinerate
Hopw n liCope . Complete . Complete
_________|
. Incinerate. Cost would be $0.70tlb aq waste or
$10,124 per year or $2,531/lot.
L LTL--iTag---- -- . Review w/"C1 6 Sigma Team" e 2. Incinerate. Cost would be $0.35/Ib aq waste or a $74,430/yr or $9,304/Iot.
ffew Eme me] . Incinerate. Cost would be $0.70/Ib aq waste or $155,894/yr or $5,029,1ot. Incinerate. Cost would be about $8,560/Iot. . Incinerate. Cost would be $0.35/Ib aq waste or
$29,050/yr or $4,150/lot.
st ta y mot oy omen cn Made Available by 3M for Inspection and Copying as Confidential Information: Subject to
Protective Order In Palmer v. 3M, No. C2-04-6309
11773355..00002288
sr 3MA00043792
EFCC W Waassttee TTeeaamm leans Mike Rappel
Lynn Running George Bentz
nA by Mr pet ier tn tbc er C3460 Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
swam 3MA00043793
11773355..00002299
PHASE I COST ESTIMATE
Coe Loneiamm me [mzae[ge[or Product E peeE OEETE TOD ERTeSeE TE FC-98
FC-95 F-5372
S Se t e Et FM-3256 F-8733 F-8450 F-4863
S SEEEAA EE E eh e A F-8400
Waste Type
Process Process Bottoms Bottoms Bottoms Bottoms Bottoms Bottoms
Lbs. of Waste (FC and
Water) per Year
259171 45974 15714 37860 6876
799 5000 25959
Cost to Incinerate
per lb. of Waste
0.36 0.4 0.75 0.75 0.75 0.75 0.75 0.75
Cost to
Incinerate per
Year
93301 18390 11786 28395 5157
599 3750 19469
Total Cost For
Barrels per Year
12959 2299 786 4102 344
87 250 1298
Total Cost per
Year
106260 20888 12571 32497 5501
686 4000 20767
Lots per
Year
7 4 8 31 7 8 5 8
3STa7E2000F-- 872esind1na 20%ot hso dt cs Total
397353
Note 1. F-5372 and F-8733 are predicted as using 30% water to help drain fron reactor.
RE EAE 2. FM-3256, F-8450, F-4863, and F-8400 are predicted to be able to drain straight bottoms.
3. FC-98 and FC-95 are predicted to use the same amount of water as last year. 4. Drum oost is based on $65 drums for F-8450 and F-3256 along with $30 drums for other wastes. 5. Drums are assumed to held 600 Ibs of waste.
180847
22123
202970
SE Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
--3MA00043794
11773355..00003300
Product
Lbs. Product
Cost per Demand per Produced per Increase in Cost
eae --] Lot 15180 5172
Year
35000 19200
Lot 5000 4800
per Ib of Product
3.04 1 08
1571
71442
8930
0.18
1048
296774
9573
0.11
786
72000
10286
0.08
86
29600
3700
0.02
-- a-- ---- ---- ---- -- 8O0 2596
50260 36985
10052 4623
0.08 0.56
nA by Mr pet ier tn tbc er C3460 Made Available I~y 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-630g
pr-- 3MA00043795
11773355..00003311
PPllaann FFoorrwwaarrdd PPhhaassee !I
PPrroodduucctt
CChheemmiiccaallNNaammeeWaWsatsteeTTyyppee LbLsbs..FFCCMWasasttee
HeMtehthoodd
EEnnPg,qriionnjeeeecortroonn EEststiCimmoamapttelededtDDiaaotnte oof.
Project
Completion
FM-3256
C8 Acid
Bottoms
37860
b. IncinerateJminimize bottoms
Dean Graham
Complete
[=[ee FC-98
PECHSF
[eeProcess
[= 26221
ee-- a. Inoinerate/minimiz~ all washes.
ee]=] Lynn Running
Complete
FeF-8400 F 5372 F0-95
ee em fe ee PECHSF C1, PMSF Acid POSF
Bottoms Bottoms Process
25959 11000 9558
a. Incinerate a. Incinerate~minimize bottoms a. Incinerate/minimize all washes.
Lynn Running Lynn Running Lynn Running
Complete 09/15/00 Complete
F-4863
PDSF
Bottoms
5000
a. Incinerate
Lynn Running
Complete
F-8733
[r eee e Tew ee] F-8450 m [ e R E em e es s e] ee ee] Tolal
PMSF C8 Acid
Bottoms Bottoms
4813 799 121210
a. Incinerate a. Incinerate
Briana Hagen Dean Graham
09/01100 10/01/00
iAis pct ogo rtf. 5 teoi rr3 r 068 Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
swan 3MA00043796
11773355..00003322
Phase II
PPrroodduucctt
[omFM-3256 FM 3141
CChheemmicicaall NNaammee WWasatseteTTyyppee L Lbsb .FFCCs WWaas. sttee
MeMtehthoodd
een En,qineer on `PPrroojjeecctt
esas Estimated Date of `CCoommpplleettiioonn
wpme ee] C8 Acid EBSF
Process Bottoms
13312 9853
a. Use vacum pump instead of jets.
a. Incinerate/minimize bottoms b. Try MeOH as solvent vs H20
Dean Graham Lynn Running
To be determined. To be determined.
F-8400
PECHSF
Cleaning
8335
a. Minimize water b. Try MeOH c. Incinerate clean-up water d. Incinerate
Lynn Running
To be determined.
[rrF-7535 F-8439
emPMSF Lithium salt
PMSF Lithium salt
ee pee Cleaning Cleaning
6035 3500
a. Minimize water b. Incinerate
a. Minimize water b. Incinerate
pee Lynn Running Briana Hagen
To be determined. To be determined.
FM-3149
[== 1 =T=]= Fem[ew]m=] F-8450 [m=] w= ew] ww Fee [ewe] meee] F-5372 [rm Temes]ee] ve Fee [eee] ee F-4863
[ [ = | TM[=e =T ] = e[erem w [o eewe ] |=e = ]| F-6733
EBSF C8 Acid C1, PMSF Acid
PDSF PMSF
Process Cleaning Cleaning Cleaning Cleaning
4196 161g 1150 1031 675
a. Incinerate and or minimize. a. Incinerate a. Incinerate a. Incinerate a. Incinerate
Lynn Running Dean Graham Lynn Running Lynn Running Briana Hagen
To be determined. To be determined. To be determined. To be determined. To be determined.
eee Made Available by 3M for Inspection and Copying as Confidential Information: Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
--3MA00043797
11773355..00003333