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R22266 8.0 2 oT ARaz.g 2680 TRADESECRET StudyTile EVALUATION OF THE BIODEGRADABILITY OF USING THiEcCuLoOsSeEnD BsOToTrLE TEST Author John T. Gannon Jr., Ph.D. Study Completed on 8/18/95 . Report Revisedon 916195 ~ Performing Laboratory E. ICendturaPlonRtesdeearNcehmo&ursDevanedloCpmoemnptany AppGlliaesdgowandBusEinnveisrsonCmoemnmtuanlitMyic3r0o1b,ioPl.oOg.y BLoaxbo6r1a0t1ory Newark, DE 19714-6101 | EM Proj 2 . LaboratoryProjectID | AEM Laboratory Report No. 205-95 | | Page 1 of 8 = 8 3 10941480 ' DuPont AEMR 205.95 GENERALINFORMATION MaterialTested: a Synonyms/Codes: NONE `Submitter'sNotehookNo: N/A Sponsor: FWiLlPlRiam J. Brock ExperStiarmt&eConmpt letaioln; 7-11-95/ 8-8-95 : 8zg - a EID941481 DuPont AEMR 205-95 CEVALUATIO"N_)OUFSITNHGETHBIEOCDLEOGSREADDABBOITLTILTEY TOEFST SUMMARY The test chemical, using the 28-day Closed Botile Test. was tested for biodegradability The results of the 28-day Closed Bottle Test indicated that a peak of 12.1 % Biodegradability was observed at Day 28. A minimum of 60 % biodegradability is required to pass this test. In addition, the "pass level" of 60 % must be reached within a 14 day wthiantd[ow_ after exceedi"nJg thweas10no%t "leRveeal.dilTyherBeifoodreeg,raitdambalye."be cPolnecalseudHeodtTM" that failure to pass a "Keady Biodegradability TestTM does not imply that fe ' titemste.material will persist in the environment for an extended period of . i Study Conducted by: MaladBui iso `Wallace E. Bessicks (date) Microbiology Research Technician i Study Conducted by: Aacele,Onmedis~9/6/95 Nicole L. DiMondi (date) Senior Microbiology Technician Study Conducted by: B Georuge e4. FaisheAr xl oils (date) Senior Microbiology Technician | | RAeppporrotvedPrefpoarreIdssuaeBndy - bb]Roe ofr_ | | Jhn T. Gannon Jr., Ph.D. Research Microbiologist (date) 3 ~ 3. E1D941482 DuPont AEMR 205.95 Introduction/Purpose. The Closed Bottle Test was performed to determine if _ be used for = "Readily either water-soluble Biod or ewgartaedra-bilnes"o.lubTleh e Closed and vol a tBioltetleorTensotn-can volatile chemicals. In this test, measured and is considered the the Time-0 DO starting point. (Dissolved Oxygen) is The Closed Bottle Test is a closed to the system. Therefore, no system for the duration aodfditthieonatelst.dissIfolvtheed oxygen bacteria smheotualbdolibzee atdhdeed test chemical in this closed system, then oxygen. Consequently, biodegradation is they will measured use up ss the the loss dissolved of dissolved o28xy>gen60wi%t,hinantdhethcilsosleedveblototlfe.bioIdfegtrhaedaDbiOlit(yDihsassolvbeedenOxaycgheinev)edloswsitahtinDa1y4 cdoanyssidoefreedxc"eReedaidnigly10Bi%odebgiroaddeagbraldea"bilaintdy,nothefnurtthheertetsetstcinhgemiiscalneciesssary. Materials/Method . with The AEM CSlOoPsedMIBOoStIt-leP T"eRsetaddyetBeiromdiengartaidoanbilwiatsy: cColnodsuecdteBdottilne aTcecsotr"d.ancTehe - WsioulrmciengotfonthePOiTnoWc.ulumSefeorTatbhleeCl1 osfoerd mBaotuerliealTsestteswteads. the City of | Results/Discussion | 12.1 %Inbtihoedeg2r8a-ddaabyilCiltoyseatd DBaotytl2e8Te(sTta,bl[es_ 2 & 3 and FigJuresh1o).wedThaerpeefaorke,ofit i was determined that [__ 7) was not "Readily Biodegradable". i The control chemical, (Figure 1), therefore the test Sodium Acetate, exceeded is valid. The Theoretical 60 % biodegradability Oxygen Demand of C T) was calculated as 0.66 mg Oz per mg of active substance. not imPplleyasethantottehethtaetstfamialtuereriatlo pass will paers"iRsetadiyn tBhieodeegnrvaidraobnimleintyt Tfeosrt"andoes extended period of time. g 8 - -a- EID941463 : DuPont AEMR 205-95 cEVALUATIOUNSOIF NTGHETBHIEOCDLEOGSREADDABBOITLTILTEY TOEFST TABLE 1 Mme Description of Test and Control Substances rm shee mae _464--11 Sodium Acetate . || | g - 5. 0941484 : DuPont AEMR 205.95 Hed J iLE FI a pray) S enE o RLf > @ L|6 L(6|L9 SEN o ;25 { a5 oIO | ELpo " | =| ~ | Nm = I i| fa2 a a0 | f H i| L3E|E | | LLIB | | aa) a PUTER on fl = aS Ce g --_ 6. - 1 [ev : | -~ || | --_ DuPont AEMR 205-95 fTo BEEA LEE HHH LITT bis efTHTBed BTEE LLfHEEBE fs LE Il L J e BL | !i il | i ] i pie ge leRE(giEc Cd Ei TR! Y ElELELe LTHIESR FRLEE | EL ef I | ie L] L eEia B E ee I | i 4 bed 5H aL EHS ee + i Boivin I i IF |= a 1S] iE Hl i Hee Le HT EEL HS E : H i" [IF 18F FLLTBoeeaSla Ese -7- B kei s) E - Erosaises : DuPont AEMR 205.95 % BIODEGRADABILITY 4 o 3 8 8 8 38 3 & a 5 ila 3" | ~ o >= a i <f1 2 ) = e a 5ggc mn -=5l o o@2 zo 3 2 'm mn 5: n } | | Zz --_ -8- Ers42487