Document ZnVz6bxK608Xwd9Vy1nEBpz08
BIODEGRADATION (BOD/COD)
TEST SUBSTANCE
Identity:A mixturecontainingperfluorooctanesulfonatweh,ich may alsobe referredtoas PFOS, FC-95, or as a component ofFC-603F. (1Octanesulfoniaccid)(CAS # 2795-39-3).
Remarks: The 3M productionlotnumber was 501. The testsample isFC603F. Currentinformationindicatesitisa mixtureof0.5% PFOS, 7% diethyleneglycolbutylether,82.95% water,2% acrylifcoamer,4% Alkylether sulfate1,.45% Xanthan gum, 1.4% calciumacetate,0.07% N-(3Chloroallyl)hexaminiucmhloride0,.5% tdethanolamine,0.05% sodium hydroxide,0.03% cis-1-(3-Chloroallyl)-3,5,7-tr1-iazoan-iaadamantane chloridea,nd 0.05% tolytriazole.
The followingsummary applies toa mixture with incompletely charactedzed concentrations of impuddes. Data may not accurately retlectthe biodegradabilityof the tluorochemical component of the test sample.
METHOD:
Method: Not noted. Type: Aerobic GLP: No Year completed: 1994 Contacttime: 28 days lnoculum: Not given.
RESULTS
Chemical Oxygen Demand (COD):
276,000 mg/kg
BiochemicalOxygen Demand (BOD): 5-Day: 20-Day: 28-Day:
47,700 mg/kg 230,000 mg/kg 296,000 mg/kg
CONCLUSIONS
No conclusionsgiven.
Submifter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133
DATA QUALITY
Reliability:Klimischranking3. Study lacksdescriptionand recordsofthe method followed.The inoculumwas not properlycharacterized.Sample puritywas not propedy characterizedand thestudy lacksanalytical confirmationofthe amount offluorochemicalproportioninthe solution.
REFERENCES
This studywas conducted by Pace, Inc.,ofMinneapolis,MN atthe requestof the 3M Company, Lab Request number Ml 655, 1994.
OTHER
Lastchanged: 6/26/00
DATE: 03/31/1994
)M ENVRROMMNTAL
LABORATORY
CONTRACT LABORATORY WORK ORDER BY PA;TAMETIR
LAB REQUEST NO. M165S
CONTRACT LAB PROJECT NVMBER SHIP DATE
: pace
: BILTWENVIR
PROJECT LEAD: SA BtAC1,4
TELEPHONE
61'@,-778-74S-@
rA:.c
-.omputer code
Test Name
--------- ---------
gazple Numberz --------------
sample AvailaLble Date ---------
Result
Due @)-ate ---------
f7C-D
P-CBOD-OS BOD-05 (C;@ADC,14ACE-DIJSI
P-CEOD-20 BOD-20 (CAkBO11ACLDUS)
1
P-C50D-29 w-toD-23 (CARBC),NACEOUS)
'1.4 4
4 i'@ 1':o54 4,- ' 1) 5 4
B iochomicalOxygen Demand
BOD@?bCBOD-,:5
Dat&Tmm in
Daterrwo OtA L411314t4
AraW
-T65
c 44.1et-qk/
=-Oes SOD and CBOD
Blank
Arw*sis
coffowt3
seacSWP Add Botde DI
ReWI3 U
pH Vol Vd lrthb.
rvtls
I(rrC (n-L)(CBOD)
0 NA No
Star*
0 NA No
Seed Conw SeW ConW Seed Control
4(.Lf5'
lrhbted
25 25 No 25 25 No 25 25 Yes
Seed Control
Inhibited 25 25 Yes
D2 DO ,DR_OPR@ ,i(DDi4Y)042,p
3, q 41.
-3 ii V
LCS
TV198 31
2 6 No
LCS
TVi98 31
2 6 No
2 0.021 2 OOks*
Ll
Z4,r --@s.
(,.-3
&
2 O-CO:@
2 0=
2
@57
2
2
41
2
LD
S ,Q
f
2
2 0 -ev@
2
1.(Lt
Iloo Boo
Seed Correcbon
(S-Ddo@r) 41. L,,
3M ffL Swd Cored
Vd (rrij
lntubdedSeed
Correcton
=
W,4 S"d (coma o0ow
-4-
2ML 3M.1)
CBODM/Larnglia
((DlD.2) - sd c,,cw) x 300 mL samp[evwtor vol.
((ol-D2)-wtixso c...ecoxo.3)00 mL sample vA. or vol.
D2 fflidbe > 1.0 DO DROP must be > 2.0
Se&4LotNo. IrgUbalorNo.
BatchN(L 520-M Dup No. LCS No.
pact',Inc.
MNINORG FORM MN3073,..
BiochemicalOxygen Demand
60D.-
CBODtL-6 X/
DaterramIn
Dat&TumOut 1412-9 AA*STl@'A
swoes BOD and CBOD
ArkilOs
ResLdts
Comments
Sead
Add Botdo Di
pH ',Iol
Inhb.
(nillmL CBOD
BW*
axyt.
0 NA No
BIM*
0 NA No
D2 DO DROP
800
(DI-D2)
Seed ConW Seed Conrd
25
No
25
No
Seed ConUd Seed Contrd LCS
[Mbted lrhuted TV198 t 31
25 25 Yes 25 25 Yes 2 6 No
LCS
TV198:t31
2 6 No
2 .02 YES 34
--(o.
lio33-S
2
li4
-& .
2 -4q
2
7.0
2
lzq 4-q G @c@ c>
2
e-
2
.23olo4@
2 DIS-1 2 m:@ 1 2 2
-0 1
3Y 4.9 --s17
13 0.0 E-1
-2-1 ;)3i4.of,
smdcarvm
SeedCorrection= ( coo-P
2
f 3co rrL (W2-L
[@@,c -0@j
S"d
InNbiteSdeedCorrection cotrlnbC"ODW
2 IIIZ
BODov/Loraglia -
(,-3 ((Dl-D-2s)eedcamemnx)300mL
samplewt or vol.
0, 'S,6
CB00ovILarn,w,.w -
((biD-2)- wtib.swd cwmmn) x 300rnL samplewt. of vol.
02 must be > 1.0
DO DROP mustbe> 2.0
se*ALoNto.
lnabatorNo.-Zl Bateh No. 10
Dup No.
LCS No. nic.0 pace
MNINORG FORM MN3073
Bio.chomicaOlxygen Demand
DOD-CBOD-ZI
Dawras In Y/ftriq 1636 Dat&Tmo Ott -1 -ti
k&"
Swrplos SOD and CBOD
Blank
3
carvwts
ResUts Urit3
pH
ffv&
Seed ConW SeW ConW Seed Control
Seed ConW LCS LCS
lrhbited lrhbted TV198 t 31 TV198 31
Lc
00
Seed Correction S..dC.W
OODW
d
SeadSwV Add Botdo 01 Vol Vol lnhil 0 (rnL)(ML) (CBOD) 0 NA No
0 NA No 25 25 No 25 25 No 25 25 Yes @L 25 25 Yes 2 6 No
2
2 D'07@
2
2
2 OL05,
2= 2
ri -+ -@ 1(40
-4 9'
2
2 Dt5
iZ3
2 )a)@
lot
2
2 9 CM
q3
2
W* Sad
lnhibdedSeed Correction (cared morep
2ft 3m
BOC)(NILar. ffglio I -
CBOD(n@IL-'@@f9f I
((Dl-D2) - saw cwmcdm) x 300 ML sample wL or vol.
((Dl-D2) - wwL swa cwmom) x 300 ML sample%%t or vol.
4.
D2 00 DROP (Dl4Y4 Boo
6,9
6q%tA-" 6.
A i-
9 A,;
L/
6.q o.q
D2 mustbe > 1.0 DO DROP mustbe > 2.0 SeedLotNo. rIQ(4 lnctibatNoor.
BatchNo.;201(o Dup No. LCS No.
pace,Tnc@.,&
MNINORG FORM MN3073