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S42 31:5301 OCCUPATIONAL SAFETY AND HEALTH STANDARDS SUBPART G--OCCUPATIONAL HEALTH AND ENVIRONMENTAL CONTROL (Code of Federal Regulations* Title 29, Chapter XVII, Part 1910, 36 FR 10466, May 29, 1971; 36 FR 15104, August 13, 1971; 36 FR 23208, December 7, 1971; 37 FR 332, January H. 1972; 37 FR 6576, March 31, 1972; 37 FR 11320, June 7, 1972; 37 FR 22139, October 18, 1972; 37 FR 24749, November 21, 1972; 38 FR 10929, May 3, 1973; 38 FR 20074, July 7. 1973, 39 FR 3755, January 29, 1974, 39 FR 12343. April 5, 1974; 39 FR 19468, June 3, 1974; 39 FR 35896, October 4, 1974; 39 FR 41848, December 3, 1974) Subporl Occupational Health and Environmental Control S 1910,93 Air contaminant*. An employee's exposure to any mate rial listed In table 0-1, 0-2, or G-3 of this section shall be limits m accord ance with the requirements of the follow ing paragraphs of thu section. <*) Table 0-2: (1) Materials with names preceded bv "C--Ceiling Values. An employee's ex posure to any material In table 0-1, the name of which is preceded by a "C" (ejr,, C Boron trlfluonde), *> at no exceed the value given lor that material In the table. <2) Other materials--8-hour time weighted averages. An employee's expo sure to any material in table 0-1, the name of which Is not preceded by "C", In any 8-hour work shift of a 40-hour work week, shall not exceed the 8-hour t.tme weighted average given for that material In the table. (b) Table 0-2: (1) 8-hour time weighted averages. An employee's exposure to any material listed in table 0-2, in any 8-hour work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average limit given for that material in the table. (2) Acceptable ceiling concentrations. An employee's exposure to a material listed In table 0-2 shall not exceed at any time during an 8-hour shift the ac ceptable celling concentration limit given for the material in the table, except for a time period, and up to a concentration not exceeding the maximum duration and concentration allowed In the column under "acceptable maximum peak above the acceptable concentration for an 8-hour shift". (3) example. During an 8-hour wort shift, an employee may be exposed to a concentration of Benzene above 25 p.pjn. (but never above 50 p.p.m.) only for a maximum period of 10 minutes. Such ex posure must be compensated by expo sures to concentrations leas than 10 p.pjn. so that the cumulative exposure for the entire B-hour woik shift does not exceed a weighted average of 10 p.pjn. (c) Table 0-3: An employee's expo sure to any material listed in table 0-3. In any 8-hour work shift of a 40-hour work week, shall cot exceed the 8-hour time weighted average limit given for that material in the table. (d) Computation formulae: (1X1) The cumulative exposure for an 8-hour work shift shall be computed as follows: g=c.r.+c*r*+ . . . c.r. s when: X la the equivalent expoaure for the work ing shift. C la the concentration during any period of time T where the concentration remains constant. T la the durstiub In hour* of the expoeure at the concentration C. The value of E shall not exceed the 8hour time weighted average limit In table 1219-74 Copyright 6 1974 by The Bureau of Notional Affairs, Inc. [Sec. 1910.93(d)] 55 RSV 00113^8 31:5302 REFERENCE FILE 0-1, Q-2, or 0-3 for the material Involved. <11> To Illustrate the formula pre scribed in subdivision U) of this subpara graph. note that lsoamyl acetate has an 3-hour time weighted average limit of 100 p.pm. (table 0-1). Assume that an employee is subject to the following exposure: Two botxn cspoaura it 160 p.pxa. Two boon u|wuw it 78 p.pn. Four Pours exposure at 60 P4un. Substituting Information In formula, we have 9X160+ 9 X 76 +4 X 50 =IUt p-p-m. e Since 81.35 p.pjn. is leas than 100 p.pm.. the 5-hour time weighted average limit, the exposure is acceptable. (3) (1) In ease of a mixture of air con taminants an employer compute the equivalent exposure as follows: r Where: L, ^ L. I* is tbs equivalent exposure for tbe mixture. C la the concentration of a particular oontamtnent. lU tbe exposure limit for that contami nant, from table 0-1, 0-3. or 0-6. The value of shall not exceed unity (1). (h) To illustrate the formula preecilbed in subdivision (1) of this sub- paragraph, consider the following exposures: UaeU Actual aon* mntraaoe SepHeoonr Mtoor Urn* wIaTtcWhtaId ewnwitw letcM (Tabl* 0-1)........... fOOp.p.m... 1,400 p.pjn HaUiim (Table ^l),,. 44 p.pjn.... 300 p.p.m. TMaaaa (TabU 0-2)............40 P-Pd____ 600 p.pjn. - Substituting in the formula, we have: 500 46 40 *-=--------+ + 1X00 900 900 *-=0.500+0.234+0.300 *.=0*36 Since E. Is lew than unity (1), the expo sure combination la within acceptable ifcniti. (e) To achieve compliance with para graph (a) through <d) of this section, administrative or engineering controls must first be determined and Imple mented whenever feasible. When such controls are not feasible to achieve full compliance, protective equipment or any other protective measures shaij be used to keep the exposure of employees to air contaminants within the limits pre scribed In this section. Any equipment and/or technical measures used for this purpose must be approved for each par ticular use by a competent Industrial hygienist or other technically qualified person. Whenever respirators are used, their use shall comply with 11910.134. Tabls G--1 Acrulrtrhrdc................. . 300 Aertor.e........................................ Acetonitrile............................. .. Acetylene dtchlotlda. aee 1. 2- Dlrhlomethylmr...................... Acrylamide--Skin. Aaylenllrlle--Skin...... ............... AMrin--Skin................................. Ally! ilenhol--Skin..........-......... Ally] eMoodf.i........................... CAIlylelyeirtyl ether (AOE). AHrl propyl dlMlilde.............. . 6-Amlneethanei. a* Ethanol- UllB(............................. 6-AinlnopyrtdlM........................ Ammonia........................... Ammonium aoiiamata (Am* mate)................................... n-Amn acetate............................. one.Amyl acetate......................... Aniline--Skin............................. Anbldlne <o. p-taotnen)--Skin.. Antimony and compounds (a* Bb)........................................ ANTU (alpha naphthyl thiourea).................................... Aram le and cempounda (a* As). Aralne............................................ Attnphoe-methyl--Skis............. Bartom (soluble compound*)... EBentwulnone, om Quinone. . rnteyl prreild*...--............. Beoxyi cnlortd*............................ Biphenyl. aee Dtphenyl.......... . BJaphoicri A. act DlsUddyl other........................................ . Boron oxide............................... C Boron trtfluoftde...................... Bromine. ....................... .... Bromoform--Skin........................ Butadiene <1. 2-batadkne)..... Betanethlel. ae Butyl mer- spun........................ . f-Rutanone.................................... 3-Buuty ethanol (Butyl Cat ted**)--Bkln............................ Borel acetate In-butyl amtala). -Botyl acetate__ .......------Urt-Bntyl inltU.._..... Butyl aloehoi........................ --. -Butyl alcohol....... iwvButyl alcohol......................... C Burylaoun*--Skin.................. C tert-Bniyl dimmate*(as CrOl--Bkln............................... n-Bulyl glyrldyl ather (BOB).. Butyl marcaptan.............. pJert-Butyltoluena...................... Caklam arsenate........... . Calcium aside............................... Camphor............. ...................... Carbary! (Beetn)____ ..._____ Carbon black.......... . Carbon dloxIda............................. Carbon monoxlda.............. Chlordanc--Skin................. . Chlorinated camphene--Skin... Chlorinated diphenyl oxide....... `Chlorine............ ............... Chbeinc dioxide............... C Chinnne tnfluonde..... C Chloroaeetaidehyde.......... a-Chtoroacetopbennn* (pbenerylchlonda)................... Chlorobentene (monochloro- benaene)............. (hChlarobentylldene meiofloniirlk <OCBM>....... ChlorobromomeUiahe.......... .... X^hioro-I.S-buUdMM. mo Cbloroprena.......____ ....... Chkrodlphenyl (42 percent Chionnei--Bkln........................ . Chlorodlphonyl (64 percent Chlonne)--Bkln....................... . IChloro.I.S^poxypropane. mo EpKhlorhydrtn........................... tChtoroethanol. M Ethylene cMorohydrtn............. . Cblaraethylene, NT Vinyl chionde____ ____ _ C Chloroform (inchloro- mnnimi............ ..................... l-Chloro-l-tiiUopropaM.............. Ihloropkrln........................... .hloropreno ilehlerv-lA1 butadiene)--Skin...................... 9 1.000 40 1 61 60 1 1120660 61 1 6B 1,000 300 10 140 600 100 140 0 40 14 14 6000 1 6611 1 60S 60S VO V 61 mt./U` M0 20 3.400 70 14 66364 U61* 6 u1S2 6t4 82IB9 4B0 14 6B 6t 66 6B 63 63 6B U 2 6I 7 1300 BBC 940 714 MO M0 BOD 440 600 14 3a70t 40 B 1.400LB B6B B 66 66 B 66 6a 4 66 640 64 1.040 l 64 100 67 Taslc o-l--Continued Chromium, ad. chromic. Metal and Insni. salts............................... Coal tar pitch Totatllee (ben- sane miable fraction) anthra cene, BaP, phenanthrena. mdlru, chryxena, pyrtna..................... Cahalt metal fume and dost..................... Cooper fume__ _____ _________ ____ ___ _________ 61 i Cotton duet (raw).................................................. I Crap herbicide............................ U CmoT (all bomeri)--Skin........... fi 22 Crotonajdehyde............................... 3 B Cumene--Bkln................................. 80 349 Cyanide (as CN)--Bkbi........................................ 4 Cyclohetane........................... 100 1,060 Cyelohetanol.................... (0 300 Cyeloheianone................................. 40 300 Cyelohexenc..................................... 400 1.016 CyciepenUdlana............................. 7B 300 2.4-0.......................................................................... 10 DDT--Bkln.............................................................. DDVP, an Dtchlereoa...................................... Oecahonne--Skin.......................... 60S Demecefi-Skln................................................. 1 66 61 Dlaeecone alcohol (4-hydraty- 4-methyl-24>entanone).............. 60 1,2-diamInoechant. are Kthylenediamlne............................................... Dlaxomelhanr........ ........... ............. 63 Dtborane................... 61 Dlbutrlphthalate--............................................ C Dlehlorobeniene.................... CO 64 61 4 600 p-Dlehleroberuene.......................... 76 480 DlehlorodlSuoromethaae............. 1.000 4.040 1.5-DichloroAA-dlmethyl hydantola................................... ....................... 1,1-Dlehlororlhane.............. ........... 100 63 400 l.^Dichloroethylene...................... C Dlehloroethyl ether--Skto... 300 14 700 40 Dlchloromethane. tee Methyknechlorlde............................................ DiehloromcnoAuoromethane... 1,000 C I.I-Dtchloro-i-rutroethan*.... 10 4,300 40 14-Dlchlerepropane. me Propylenediehlortde................................ .... Dleiilorotatrafluoroethane........... 1.000 Dlehlcrvoa (DDVP)--Skin...................... .... Dleldrin-Skla........................................... Dtathylamlne........................ Diethylamide ethanol--Skin. .. 3S 10 7.000 6129 Dlethykether. see Ethyl etbw..........................-..........------ DUhipeodltrromoreethan*............ UO _ C DIclycMrl ether (DOE)_____ 64 E6 Dlhydroxybenaaoe, aee nydroqutnone.............................................. Dlbobutyl ketona........................... 40 DUaopropylatnlne--Skin........... 4 340 Dlmethotymetbane. sea Mcthylal............................................................................... Dimethyl acetamide--Skin..... 10 64 Dkmethylamlae............................... 10 U Dlmethylamlaoberuena. aae Xrlldene.................................... -................. ............................... DlmihTlan1iln(NKllmethyl- ,, aniline)--Skin.................................... 4 *S Dlmethylbeniene. are Xylene........... ................. -......... .. Dimethyl l.2-dlbrx>mo-'2,2-di- ehioroethyi phoaphaie. (Dlbrom)................................................................ * DlmethyUooramide--Skin........ 10 60 3,4-Dlmethylheptaaone. aoc Dllaobuiyi ketone...............................................-............- l.t'DlmcihylhydratLne--Skin... 64 > Dlmethylphihalau................................................. } Dlmethybullaw--Skin........... I 6 Dtnitrobenxrna (all laomeni-- Skin....................... ............................................... DlnlUoeheraoi--Skin........................................... Dlnltroioluene--Skin...................... -.................... Dloxane (Diethylene dioxide)-- Skin...................................................... Diphenyl................. .......................... 100 440I Dlphmylmethane dllaoo'anaie (Me Methylene bttpnenyi laoeranate (MDT)........................................ Dlpropyienc gkyeoi methyl ether--Bkln........................................ >00 400 Di-aee. oetyl phthalate (Dl-3. ethyihexyiphthalau)......................................... f. Endrln--Bkln..................... .................................... F.pkchlorhydrin--Skin_____ .... 8 EPN-Skln................................................................ 1,7-Epoxyprepane. Sea a* Propyleneoxlde................................................................... .. 2,9.-.P...p.c.r.y.-l..p.r.e.p.a.n..o.l...ae.e.............................. See (ootootea at end a( table. Occupational Safety & Haalth Rapertar (Sac. 1910.934)1 66 RSV 0011349 31:5304 REFERENCE FILE Tails G-2 (c) Methods of compliance--(1) n- ffineering methods, (i) Engineering con Aco*pl*bJ nutlaait puk iben trols. Engineering controls, such as. but Ifaunal U boor tint vmhM average Acceptable the acceptable ceilln* eoucecui- catitnr tton tor an Hwof 9hJ. eooeentrauoc ---- not limited to, isolation, enclosure, ex haust ventilation, and dust collection, CeoceoUtttoa Mtilmua dvmUeo shall be used to meet the exposure limits prescribed In paragraph (b) of this section. Bewane (Z97.4-19W]....................................... 1Qp.p.m...............ap.p.n.. BatTlUtua n4 beryllium compoumls ................ (U7<2^1Vi'u). Oadmlam Join* (2J7.9-19I0>........................ _____________ .... Cadmium drat (ZJ7.&-1V70)C-ImuM'---... (L4mc./M*. Cartoon dlntlAd* (ZI7.9-19M)........................ 3D p.p.m........ Kp.pji.. Carbon UUaetdertd* (ZJ7.17-1997)......... 10 p.p-m___ .... SSp.pjn... Uiplenadtbromtde iZJ7Ji-l*T0l.......... 3D p.p.m........ SO p.p.m... Btbyltna dichlartde (ZJ7.ii-i9*9).......... 10p.p.m........ lQOp-p-m. Ponmldahyde (ZX7.IMB87).-....................... Spp.m... Hydrates fluortd* CZ37 29-1999)............................ do........ .. Sp.p.m.... .. Wp.pjn........ tominatto. .. 3*aVHa....... SOmlaulu. .. ioo p.p.m______ 1>*. .. 300 p.p.m....... I minuter Id lap 4 hour*. .. SOp.pm........ Smtnutra. .. X Ppm....... Imlnutaain anjr I bout*. .. 10p.p.m........ tominute*. (11) Local exhaust penttlaflon. fa) Local exhaust ventilation and dust col lection systems shall be designed, con structed. Installed, and maintained in accordance with the American National Standard Fundamentals Governing the Design and Operation of Local Exhaust Systems. ANSI Z9.2-1971. which Is In corporated by reference herein. Tloondaaadusi (ZX'.JS-UM)........................ 2.m*./W. Lead end Itetnorfantr compound* (Z*7.II- Umi^M1. <b) See 11910.6 concerning the avail ability of ANSI Z9.2-1971, and the Matty! ddortd* (Z37.I9-1MB)..............................loop.pja. 300 p.p.m.... Metbyton* Chloride <237.3-1MB)...................too p.jun...........i.ooo p.p.m.. .. SOOp.p.m............Imlouter In Mr S boun. .. 3.000 p.p.m.........9 minuter in wyttouL maintenance of a historic file In connec tion therewith. The address of the Amer ican National Standards Institute is Oman* (alkyl) marcnrr (Z37JO-1M0) Styiwe (ZJ7.19-I9SB)............................ tot tagju ... 0.04 atJii *.. lOOp.pjn..... SOD p.p.m.... Trichferoethytone (737.19-1907)..............................do....................... do. TatraebkruatbrloB* (U7WHf)..........................d..................do, Toloan* (W7.1J-IB07).............. Hydroftn (utOd* (Z37J-1M0). 309 p.pjs 100 P4UB.... 30 p.p.m......... . 900 p.p.m.............flBlWWlP up S boun. . SOOp.p.m....... I minuter In aoy 3 boun. ______do...__ ____ Imtnutrrln any 9 bourn. .. BOO p.p.m....... lOmlautaa. .. 90p.p.m............. 10mlnataaooca only V o given in 11910.100. (Ul) Particular tools. All hand-op erated and power-operated tools which may produce or release asbestos fibers In excea of the exposure limits pre scribed in paragraph fb> of this section, such as. but not limited to, ssws. scorers, Mercury (Z37.S-197!)................................. . Cbromfc acid and chromate* (ZT7.7-19711 1XBI./10MI. .....do I.... other rnrrf* able mpoaura abrasive wheels, and drills, shall be pro vided with local exhaust ventilation sys tems In accordance with subdivision (U) of this subparagraph. Tabu O -Hj&mitL Derrs Aerodynamic diameter (unit dtnWty ipbert) Percent Paulof dector (2) Work practices--(l) Wet methods. Insofar as practicable, asbestos shall be handled, mixed, applied, removed, cut. Bubalanc* Mppcfe Uf/M> scored, or otherwise worked In a wet 10 state sufficient to prevent the emlmlon toUca: Crystal!)oa: Quarts iraaptrmbk)............... SO tomc/K* "` ... . * %SIOH-9 *SIO+2 Qoaru (total dual)............. .................... . 2.1 71 as ID a to i Ttae measurements under this ante refer to tho us Of of airborne fibers in excess of the ex posure limits prescribed in paragraph (b) of this section, unless the usefulness of the product would be diminished thereby. CriatoballU: IT** H th eahie calculated (rem lha cooni nr mass formulae for quaru. Tndjrmlt*: Uar H Uir Tniu* calculated Iron the for mulae lor quart*. Amorphous. incJudlnr natural tflatnmnoo* earth.................. an ABC Instrument, If the respirable traction of eool due Is determined rrilh a M RE the fituneorraspondlnK to that of 3.4 Mg/M* In the labia for eo*l dust l 44 MglH*. (U> Particular products and operations. No asbestos cement, mortar, coat s 1910.93* Asbestos. ing. grout, plaster, or similar material containing asbestos shall be removed () Definitions. For the purpose of from bags, cartons, or other containers this section, (1) "Asbestos" Includes In which they are shipped, without being SB BOmc/M* ehrysotlle, smoslte. croddollte. tremo- either wetted, or enclosed, or ventilated %81Q, lite, anthophyllltc. nd actlnollte. (2) "Asbestos fibers" means asbestos so as to prevent effectively the release of airborne asbestos fibers in excess of the (Heater (leer than 1% crys talline silica): Mira........................................ 30 BoapMone................................ Tafo(non-aabesua-rorm)... 30 J0 Tale(nbreus). Uaa asbestos Itmlt ................................. TramoUta (aaa talc, Obrousl Portland eastern........... *0 Oractolu (natural)......... U Coal dual (respirable traction laaa than 1% SIOil...................................... l.lmc/M' for more than 9% SlOi. I0mt/M* Inert or Nulmnee Dust: Respirable traction___ Total dust..................... %StOH-3 19 9mtfM> 90 IBms/M1 Nora: CcneerrloQ Caetort-- mppefXJ*.!-million panicles par cutofe meter -particles per et. * "111torn of panicles per cable toot of olr, baaed oi tmptnfer samples counted by Uffil-fltld technic* * The percentage of rrysteUlnii aUlca la lb* fortnuli h ms amount determined Iron air-boms mmoles t eept In thoaa Inftenee* In whieh other meiboda bare ben Mown to bo applicable 1 Aa determined toy th membtana filter method a wfiXpha** contrast mafnlAcailon. fibers longer than S micrometers. (b) Permujible exposure to airborne concentrations of asbestos fibers--(1) Standard effective July 7. 1972. The 8-hour time-weighted average airborne concentrations of asbestos fibers to which any employee may be exposed shall not exceed five fibers, longer than S micrometers, per cubic centimeter of air. as determined by the method pre scribed In paragraph (e) of this section. (2) Standard effective July t. 1976. The 8-hour time-weighted average air borne concentrations of asbestos fibers to which any employee may be exposed shall not exceed two fibers, longer than 5 micrometers, per cubic centimeter of air, as determined by the method pre scribed in paragraph (e> of this section. (3) CeilinQ concentration. No em ployee shall be exposed at any time to airborne concentrations nf asbestos limits prescribed in paragraph (b> of this section. (Ill) Spraying, demolition, or removal. Employees engaged in the spraying of asbestos, the removal, or demolition of pipes, structures, or equipment covered or Insulated with asbestos, and in the removal or demolition of asbestos In sulation or coverings shall be provided with respiratory equipment In accord ance with paragraph (d) (2) (ill> of this section and with special clothing in ac cordance with paragraph <d)(3> of this section. (d) Personal protective equipment-- (1) Compliance with the exposure limits prescribed by paragraph (b> of this sec tion may not be achieved by the use of respirators or shift rotation of em ployees. except: (1> During the time period necessary to install the engineering controls snd Both ooneettcratton and pereont quarts tor the aoell cation of thto UaJt ara to toe ^Urmlnsdltomtbolriitol poHinc a dsa-stlector trlth the toUovtra eharacurtufos Cooialalnc < t% quarts; K > 1% quaru, use quart: Unit. fibers in excess of 10 fibers, longer than 5 micrometers, per cubic centimeter of air. as determined by the method pre scribed in paragraph (e> of this section. to institute the work practices required by paragraph <c) of this section: (11) In work situations in which the methods prescribed In paragraph <c> of Oecupotienoi Safety & Haolth Raparlar [Sac. 1910.93a(d) (llliil) 4 RSV 0011350 OCCUPATIONAL HEALTH S43 31:5303 Tuu G-l--Continued ubctanea pjjjn.1 Ethanethlol. aea Ethytaef* eepun..................................... Bthenoismlne.............................. ftEthexyeihmnot--Skin........... 3-ElhocyethylacrMie (CeUo- elve acvtate)--Ikln............. 3 300 in Ethyl serylaw--Shin.......... Ethyl alcohol (ethanol)............. Kthylamlne........................ . Ethyl tee-amyl kaiona (ft methy l-X-hept anone)............... BUtyl bentena......... .................... Ethyl bromide............................ Ethyl butyl ketone (JRepunone)...................... . Ethyl chloride.............................. Ethyl ether.................................... Ethyl |orma(a............................... 400 L00 10 28 too 300 60 Lorn 400 too C Ethyl marakptan................ ID Ethyl illlcaw................................ Ethylene chlorohydrln--Skla. . in 8 Bthylerwdlemtn*.................. . Ethylene dlbromtd*. see 1,3* Dibromoethane........................ .. Ethylene dlchlorlde, m 1.3. 14 Diehioroeihana........................... C Ethylene f/Teoi dlnltrate and/or Nitroglycerin --flkln... Ethylene glycol monomethyl ether acetate. >e Methyl wUomIt* acetate........................ Ethylene tain*--Skin................. Ethylene oclde........................ . <0 EthyUdlne chloride, see 1,1 DldMt oroethene ......... N-E thy(morpholine--8kts...... Perbam........................................... Twroeanadlum dual................. Ftaaorlde (ai F)................... Fluorine......................................... at FliMretrkhloromethane............ 1.000 Fannie add................................... 8 Furfural--Skin........................... < Furluryl aloohoi........... ......... . 60 Olyddol (2>Epoiy.l. propanol).................. ............. 90 Glycol monoethyl ether, Me E-Eclmyettianol............... Outhion $, eae Aitnpho*- methyl.......................................... Hahthun.........................__ _ Reptoehlor--Skin........................ Bepum fadteptane}....,......... Rsnchtoatthana--SUn............. Baxachkesenaphthalaie--Skin.. Btzanr (n-hesane).............. . ftBexanone.............................. Beione (Methyl bobutyl ketone)........................................ me-Hexyl aoetate.......................... Rydnabe--Skin....................... Hydrogen bromide...................... C Hydrogen ehlonde................... Hydrogen cyanide--Skin....... Hydrogen peroxide (W%),..... Hydrogen arkenlde....................... 00 1 BOO in in 60 1 3 B 10 I o. os Bydroqulnona............................. C Zodlna......................................... Iron oxlda lame............................ . 0.1 Isoeroyl acetate........................... 100 Isoemyl aloohoi............................. too Uobotyl acetate........................... ISO laobQtyl aloohoi............................ 100 Mima..................................... V Seopropyl aeotota.......................... 980 looprapyt aleobol.......................... 400 laoprapylamina............................ s Zsoprapybther.............................. 100 Isopropyl gtycidy) ether (IQE). 0 Eelam............................................ al Load arwMta................................................... Lindane--Skin.......... ......... .......... ... Lithium hydride............... .................. .......... L-P.G. (Uqulfled petroleum t.ooa Mslethton--Skin................ MaMe anhydride.............. CHiKriilayipoadrdni...................... . Methviethlot, see Methyl mmnptan....................... . ftMathasyetbaool, aee Methyl 428 29 ................... Methyl Methyl acetylene (prepyne)___ Methyl aeetylene-prepedieM Methyl eeryleta--Skin................ Methytal (dlmaUtcey malheaa).. Methylaaim.................... Methyl amyl alcohol aa* Methyl bobutyl rarttnol. 300 L 000 LOW LOW 300 10 mtJin S 740 840 1.400 100 1,200 19 UO 438 HO 230 2 400 1 200 300 36 180 t19t M IS t 19 0.2 kwo 9 79 200 uo . ai 48 2,000 10 as 1,900 410 410 HO LI IP 7 11 1.4 as 2 I 10 28 990 TOO SOD 140 NO 000 12 2.100 MO IIIII as aou L*oa 18 18 1 M0 . 18 910 LUO L900 MOO 360 12 Tuu G-l--Conrlaoed Subetenc* p.pta.* Methyl (n-emrl) k0m 2- Heptanone)..................... 100 486 C Methyl bromide--Skin-.--.. 20 SO Methyl butyl ketone, *e* ft leianone......................................... Methyl celteolva--8kln........ 29 10 Methyl mllmalTe aeatata--dkia 25 120 Methyl chlorotmm.............. MO 1.000 Melhyleydoheean*............. 000 2.000 UethylcyeloheiaAOI............ 100 420 fr-Mcthytcyclohetenone--Skin.. 100 *00 Methyl ethyl ketone (MEK). *ee 2-Bounone....__ ........________ Methyl formate....................... 100 290 Methyl Iodide--Skin....... ........... 6 M Methyl UobtoyfearWnol--Skin. 21 100 Methyl bobutyl ketone, me Heaona. MfLhyl bocysnele--Skin....... C Methyl merctpUn-- -- ........ Methyl methacrylate........... 403 10 tn 40 ID 410 Methyl propyl kstoiM, see ft C Methyl ................................... 100 >itphnyl Isocyanate (MHDD.... an Molybdenum Soltibla compound*............ Insoluble compounds.......... Monomethyl aniline--Skin. .... C Monomethyl hydrazine-- Skin............................................ 0.2 Morpholine--Skin.................... to Naphtha (coaltar)........... . too Naphthalene................... Nickel carbonyl...... ......... ...... 10 a ooi Nickel, metaland soluble empds,asNl............................... Nicotine--Bklru........... . Nltrtc acid........ .. Nitric oxide......... .............. 28 RNliroaiilllne--Skin.............. Itmbeitsan* -Skin.................. p-NHroehlcccbefixer*- Skin--... Nltreethane....................... 1 1 ioo........ NitrogenUlotlde............... Nitrogen trlfluaride.................... 10 NUroglvcarln--Skin............ 43 Nltromeihsn*. _ too 1-Nitropropene.....___ ...------- 28 2-Nllropropens.......___ ...... NltrotMuene--Skin............ . 36 NKreirtchlororeethene, see Chloropterln..,,........................... OotaehloronaphthmUm--Skin..., "Octane.................. HO *OU mist, mlnmal................ Osmium tetroxlde________ ....... Oxalic add........................................ Oxygen dlBuurlda....... ............... Oienr............................................. aw ai Paraquat--9kln............................... Paratnlon--Skin.................. 1'entaborane........... ............... . aau Pentachloronaphlhalone--Skin... Pentecbloropbenol--Skin-...--... penteft*.................. ............ 1,000 2-Penlanone.................................. Perchloromeihyt mercaptan.... Perchloryl fluoride........ ............. 20a0 t Petmleuco dtrtUUtas (naphtha). 900 Phenol--Skin................................ P-Pbsnylen* dlamina--Skin.......... Phenyl ethw (ranor)........... Pbenyl ethet-biphcnyl mixture >(*apor)................ . Pbenyletliylene. see Styrene......... Phenyl glyddyl ether (POE)... PhenrlAydratina--Skin........ Phoaurtn (Mevinphoa H )-- 8ktn_........................................... .. Phoa*cne (caroonyl chloride)... Phosphine.................................... ai as PlMBphoric add............. ............. Phosphorus (yallow)............. Phosphorus penLachlorlde._____ _ Phosphorus pentasulftds................ Phoephortts trichloride......... as PhthalK anhydride.......... 3 Picric add--Skin............................. Plea) (ftPlv*lyUl,ft Indandlona)............. . Platinum (Soluble Salta) as Pt.................................................... ProDarcy) alcohol--Skin............. Propane......... ............... ikPnpyl acetate................ Propyl alcohol.......... . vPropyl nitrate................. Propylene dlehlonde..... Propylene |m|ne--Skin......... Propylene oxide........... L00O aoo an 23 78 2 too Propyn*. see Methylaoetylene... *yethnim.................................... . *Trtdlne............................... 8 lulnone................................ . 41 IDX--Skin........................ ,--. 490 s u 9 as> TO 440 60 aoc i as s B0 8 no 29 a 380 00 90 10 0.1 3.930I an l at a2 as ai : a oi as as 2,960 TOO iarss 4,000 is ai T SO 23 ai as as l ai i 1 2 12 ai at aan LH0 940 6W UO uo M0 16 44 LX TaBLp G-l--Continued F-B-me myM Rhodium, Metal tarn* and duals, u Rh................................... ............. . Soluble salt*.............................. RonnaL.................................... Rouiken* (Mmnutlsl).................................. .. Selenium compounds (as Be).......................... .. Befcnmm hexafluoride................. a 06 Bllrer, metal and totubls coopounds........................................ 11 a HI 10 as a a oi Sodium flueecec*tat* OOSO>-- Skla...................................................... ............ Sodium hydroxide........................................... SUblne................ a9 "Stoddard solvent___ ......____ SOB Strychnine....................... . aa 2as 2.S0 an Sulfur dioxide.................. S Sulfur hexafluoride................... 1,000 Sulfuric add....................... aoaui Sulfur moooeMcrMe............. Sulfur penufloortde..................... 1 a 039 s ass Bulfuryl Bucrlde........................... t Syiiox, ere Dcmetoo ............................... so 14.iT.......................... "..................................... to Tenuhim.......... ............. . TEDP--Skte..................................................... Tellurium........................ .. Tellurium hnsfluodde___ ..... 403 TEPP--SMn..... ................................................. C Terphenyb.......................... 1 1.1.1.2-TetnehlBu-2j-dlituorO' aIasi as aw s ethane........... ........................... 1.1.2.2-TetrachlarwlJ-diauar^ ethane..................................... 00 00 an* 4,170 l.l.22Ttraehlxoethane--akin TetrachloroethyleM. aea Farchbruathrlena....... ......... ............ . Tetrachlorcmcthanc. aea Carbon letraehbrtde...................................................... Tetraehlonmaphthalene--Skin..................... Tetraethyl bad (aa PM-SElo..-................ a2 078 Tetrahyonlunrt.................. 200 Ml) Tetxamsthyl bad (aa Pb)-- Skin................................................................... Tetramethyl oicdnaiiurlla-- Skin............................................. aI Tetnnltramathaas............. 1 Tetryl (2.4.6-trtnltropbenyl- Btethylaltrainins)^kln--........................ Thallium (aolubb com^^jfluud*)--Skla as TL................................. . ai s Tin (Inoixsab cmpda. except extdee......................... .............................. Tin (eeganb enpds)......... ......................... P Tnlninr 11 illlsnrrsiiale a03 a3 i aM S-Tololdbte--Skirt......................... I 21 Toxapbenc. see Chlorinated camphen*........................................................... Tributyl phaaphaxe.......................... M.l-Trtchloroethane sec Methyl Chloroform............ ...................... .. 1,1.9-Trtchloraethane-- Skin-- 10 Tltanlumdloxfde............ .. ..... Titchtoromethana, tea Chloro form............................................................. ....... TflrhlnmntTihihahna flktn $ IJLftTrlchlauprepan*......... . 90 >00 l.l>Trtd>loro 1.2,3-tflfltwrv- eihana...................... LO0O Trlathylamln*............................... 29 7,9i0n0 TnAuoromonobromamathaM.^ LOW au 9,4.ftTrlultropheiiol. aa* Picric add......................................................... ............. l,t.S-Trtnltroph*nylm*tl>yl- nitramtne. sa* Telryl....................... hitiltrotcluen*--Skin___ __ rrtorthoctmyi pheephirt*................... Laii mphenyl phosphate............................... narpsoun*.......... .. 100 MO Jnnlum (soluble compound*).. 408 Iranium (Insoluble vmpouuck)... 429 ' Vanadium; ViOidojt..................... ................................... ViOilum*............................... ........................ aa<i 'Inyl bantane, ice Styrene................... 1 r1nylcyanidN tea Acrylonitrile________ ...... 1 rlnyl toluene... ............... 190 1 >'artartn_................ ................. (yltne (xylol).................. ............ 100 . Cylldlne--Skin..................... 9 ftuium................................................. . at 4X8 26 1 ! Inc ehlorlde fume.......................... I line odd*fume..................... ....... 1 l llrtonhim compound* (a* Zr)..._____...... liTO Addition. Pant of vapor or tu per atUlen parts o4 coutaiTriasted air by voiuiM at 29* C. aad TOO mm. H> pi Hours. Approximate alUUmma M parttctUif* per cubte meter of air. (No footnote "c~ b used to avoid eoaitldoa vftft Celline vatu* noiatloca.) i Aa atmospheric concentration of not more tbaa 0.02 p.p.m^ or peeaonal prctectMe may be neommrr to avetd haadaeha As sampled by method that does pot ooOact vapor. t Tor control of gaaaral room air, fcioMfle nwniCsrlDf baaaentlal tor personnel control. (Vinyl dilorido deleted at 39 FR 12343, April 3, 1974( 34-75 Copyright C 1973 by The Bureau of National Affoirs, Ine, [See. 1910.331a) Table G-1] 3 RSV 0011351 TOXIC SUBSTANCES sv 31:33a this srclicn are either teclu'k. lly uot feasible ur fta>ible to An vxtutii- insiiiii- trp safety or health of tl,c laaploy:.* or other employees will lx: niipuiivd by hLs dent lo reduce U,\* ruborm* concent* i- t:.0 ot u respirator, such employe-,, nii.-H lions of psh.-jiei* fibers below Hie limits be rotated to suio-.'.ir job or j:i\en the incscribfd lv pnrorr^jh (b'l of this opportunity tc tnur>*:r lo n dilti i\ *; po section: or sition whose duties r.r is able to perionn (ill) In emw.encn3. with the same -m;.'a:.cr. In the same <iv> Whcr** br<li respirators .and per sonnel rolaton arc allowed by subdivi graphfcal urea .mu v. ith Ml;.* miihl* srriiority, status. tutd rate oi pay he hurl just sions 0. (ii . or tun of till-; subpara prior to such tranr.frr. if such a dub rent graph. nixl noth arc pr.qeUcahlo. person position Is available. nel rut*ilk).-i shall tx* preferred c.jki u-v.d. i3> Special clothmi;: The employer (?) Whore a respirator Is permitted by xubparegi.'tpli <li of this perm rapli. it shall provide, and i canire the use of, r.nectal clothing. .-.ueh as. coveralls or similar shah be M.-I'j.'trd from aruon.T tho.,st ap v.holc body clothing, head covering.;, proved by Lhe Zinrcr.i: cf Mines. Depart gloves, and foot coivrinys for any em ment of the interior, nr the National In ployee exposed to i.irbomc* conrc-t-.ira- stitute for Occupation*! Sufevv and tiens of asbestos fiber.*, which exceed the ntlth. Derailment of Health. I2du:t- ceiling level prescribed in paragraph (b) tiou, and Welfare, tinder the pi-ovi>ious of of this section. 30 CFR Part H (.17 F.R. C244, Mr.L. 2o. (4) ciiangu roeina: (i) At any fixed 1972). ami shall be used In accordance place oi employment I'vrjose-i to aii&Tne with subdivl-i.ms (i>, til). (Ill), eml (iv> concentrations of arbrstos fibers in ex of this subpr.ru graph. cess of the exposure limits prescribe.I i:j (i) Air .*ari/j/lnp respirators. A reusa paragraph (b) of thi.s section, tile tm* ble or single .:*e nlr purifying rejuiralor, ph'.vcr shall provide chain.'? room.: for or a respirator described in subdivision employees working rt-uularly at the place. (11) or (:ii) of (his subparagraph, ahull Ui> Clothes lockers: Tlic employer be used to reduce the concentrations of shall provide two sepande lockers or con airborne esbcslos fibers in the respirator tainers for each eiEj^oycc. so separated below the exposure limits prescribed in or Isolated as to prevent contamination paragraph (b> of. this rcetion. when the of the employee's street clothes from his celling or the e-hour time-weighted aver work clothes. age airborne concentrations of asbestos (Hi) Laundering: ia) Laundering of fibers are reasonably expected lo exceed asbestos contaminated clothing rtuijl be no more than 10 times those limits. dona so as to prevent the release of air iii) Pou-erctl air purifying respirators. borne asbestos fibers in excess of the e A full facepiece powered air purifying . posure limits prescribed in paragraph lb) respirator, or a powered air purifying of this section. respirator, or a respirator described in (b> Any employer who gives asbestos- subdivision (ill) of this subparagraph, contaminated clothing <o another jxtoan shall be used to reduce the concentra for luundering shall inform such person tions of airborne asbestos fibers In the of the requirement in (a) of this subdi respirator below the exposure limits pre vision to effectively prevent the release scribed In pavngrcpli (b) of this section, of airborne asbestos fibers in excess of when the ceiling or the 8-hour time- the exposure limits juescrioed in para weighted average concentrations of graph (b) of this section. asbestos fibeis arc reasonably expected (c> Contaminated clothing shall be to exceed 10 times, but not 100 times, transported in scaled impermeable baj'.-. those limits. or other closed, impermeable container.-, (ill) Type *`C" supplied-air respirators, and labeled In accordance with para continuous /low or pressure-tie.r^r.nd graph (g> of this section. class. A type "C" continuous flow or pres (c> Method of measurement. All de sure-demand. supplied-air respirator terminations of airborne concentrations shall be used to reduce the concentra of asbestos fibers Minll be made by the tions of airborne asbestos fiber:: In the membrane filter method at 400-450 x respirator below the exposure limits pre (magnification) (4 irPlimeicr objective) scribed in paragraph <b> of this .v*tt;on, with phase contrast illumination. when the ceiling or the 8-hour liinc- (f) Monitoring--<1) Initial tfetermi- (il) Cctr.nllng frequw.icy end paltorr After the ijiHi d dfle: ti<in:i: ions require by i-ut'i'ar.'iciajih <l) of thi.s puragraiv sarnpjt- -l-oil l>c of such frequency at patten, as to represent with icesenab amirury tii, levels of exi-i-iurc of err plovers. Tn <:o fpse rhr.ll the samplinc I done at intervals greater than 6 monii for employers whose exposure tc asbcsU may re.-.-.anably be foreseen to cxcec the lin'i1 . prescribed by pavageuph (t oi this: ration. <3> ?:t'iro;ti;ien./ai monitcttnv--(l samples shall be eo)levied from sref.s c a work environment wh>.h are represent aflve of the airborne coiKentv.uioriS c asbestos fibers which mr.v rexch clr breathing aone of employees. .Somp!? shall be collected on u nicmbiane fir.* of 0.8 micrometer porosity mounted b: an open-face filter holder. Samples shaf be taken for the dslcnrinr.tion of the Shour tin'.e-wclghied averuce airbom concentrations ana c.( the ceiling con ccutratious of asbestos fiber;.. tii* Sampling frequency end patternf After the ir.iliai deteiminntlons re>iutrci by subparagraph (1) of thi.s paragrripb samples shall be of such frequency ant pattern as to represent witn reasonably accuracy the levels of exposure of thr employees. In no case shall sampling 1% at intervals greater than 6 months foi employees whose exposures to nsbesta mny reasonably be foreseen to exceei the exposure limits presc1bed in para graph (b) of this section. (4) Employee observation of monitor ing. AfTcr.ted employees, or their rep resentatives, shall be gtven a reasonable opportunity lo observe any monitoring required by this paragraph und shall have access to the records thereof. (g) Caution signs and labels. (1) Cau tion. signs. (1) Posting. Caution cigns shall be provided and displayed at each location where airborne concentlalions of asbestos fibers may be iii excess of the exposure limits prescribed in paragraph <b) of ttus section. Signs shah be posted at such a distance from such a location so that an employee may read the signs and take necessary protective steps be fore entering Ihc area marked by the Mens, stem shall be posted at all ap proaches to areas containing excessive concentrations of airborne asbestos fibers. welghted average airborne concentra nations. Within 6 months of the publi (in sipn spfn/tcflfionj. The warning tions of asbestos fibers arc reasonably cation of this section, every employer situs-required by subdivision (1) of this expected to exceed 100 times those limits. shall cause every place of employment subparagraph shall conform to the re (iy> Establishment of a respirator pro where asbestos fibers ore released to t'.- quirements of 20" x 14" vertical format gram. (a) The employer shall establish monitored in such a v.-r.y as to determine signs specified in 8 1910.145(d) (4). ar.d a respirator program in accordance with whether every employee's exposure to to this subdivision. The signs shall dis the rcnuircmi-nls of the American Na asbestos fibers is below the limits pre play the following legend in the lower tional Standards Practices for Respira scribed in paragraph <b> of this sec panel, with letter sizes and styles of a tory Protection, ANSI Z88.2-196&. which tion. K the limits are exceeded, the em visibility at least equal to that specified Is incorporated by reference herein. ployer shall Immediately undertake a In this subdivision. b. See S1910,C concerning the avail ability of ANSI Z83.2 -1969 and the main tenance of an historic file in connection compliance program in accordance with pare graph (c> of (IPs section. (2) Personal monitoring--(!) Sam Legend AllKIlOl ................ Notation 1" Sans Serif. Gothic or therewith. The address of the American ples shall be collected from within the Dlock. National Standards Institute is giver in I 1910.100. <e) No employee shall Lc assigned lo tasks requiring the use of rcsoimtor* if, bused upon his most recant examination, an examining physician detenni;; that breathing zone of the employees, on membrane filters of n.C micrometer po rosity mounted iu mi open-face filler holder. Samples shall be taken for the determination of Lho 8-hour timeweighted average aiilwme concentra Duct HiAsrd_____-_________ Avoid Breathing Dust... Wear Assigned Protective Equipment. Do Not Hcmatn tn Area 41" Snot Serif, Gothic or block. <4 "Gothic. 4 "Gothic. ^4" Gothic. the employee will be unable to function tions ond of the ceiling concentrations of Unless Your Work Ko- normally wearing a respirator, or that asbestos fibci^s. qnlrss It. 4-29-7G Copynqlif Hj 1976 by The Sureou el Noticnu! Affais( Inc. {See. 1910.1001('jHlH'i}] 13 RSV 0011352 '31:8303 REFERENCE FILE Lcpcnri Kouttun (J) * tee-teal ezriininrtloa --1) Gen Breathing Asbeaina D*rl 14 print Gothic. Mmj c* UASARtaUt Tc Teur.SecJOi. eral. The employer rhrUJ provide or make available at his cost, medical examina tions relative to exx>sure to asbestos re Spacing between i>r<\t slwU L>e at leant equalto liclght of the i*ppor of Any two lines. (2) Caution labele--(1) Lcl li.ig. Cau tion labels .'hall 'c rLlxed U/ all raw materials, rnlxtiu-tv., scrno, we'-i.e, debris, and other products coniainhjg ar-tentos fibers, or to their containers, except that no label is required r.-hsre rr*:-?'e* fibers have been modified by t btvrfing epent, coating. btnder. or other mricrial co that durine any rearer.nbl.v forc^retble use, handling, ztorege. disyorwl. pre.-Cistne. or transportation, no airborne concentra tions of arbtrios fiber-, in of the exposure limits pit: bribed In paragraph (b) of this section will be rdcr-v.-d. (il) Labe! spcctflcr.Hons. The caution labels required by subdivision <!> of this subparagraph shall be print/'.1, in letters of sufficient sire and ccnLrrn as to be readily visible and legible. The label shall state: Cauoiom Contain* Asbestos Fl'iere quired by tills paragraph. <2> Pnplccement. The employer eucll provide or make avctUhlc to inch ofhis employers, within 30 culcndir days fol lowing his first employment in nn occupation exposed to rirhurne con- ccntrs tions of asbestos fibers, a comprohenrlvc medico1 examination, which -hall include, as a minimum, a chest reentgcnogrcui (posterior-anterior 14 x 17 inches), a history to elicit symptom atology of respiratory disease, and puimo.naiy function tests to include forced vital capacity (FVC) and forced expiratory volume at 1 second <FEVi.). "(S) /.nnr.-.t! examinations. On or be fore January 31, 1973, and r.t least An nually thereafter,' evvry employer shall provide, or make Available, comprehen sive mciical examinations to tveh ef his cmplcyi.cs engaged lri occupations ex posed to alrbcrne concentrations of As bestos fibers. Such annual examination shall Include.- os a minimum, a chest roentgenogram (posterior-anterior 14 x 17 Inches), a liistory-to elicit symptom Avoid creating Duel atology of respiratory disease, and ' Bre*tbi,*.g >sbitco Dust K:y Ceuso pulmonary function tests to include Serious Bodily Harm forced vital capacity (FVC) And forced (h) Noviskecpinff--(2 > CJcrnljiy. All expiratory volume at 1 second (FEV,.). external surfaces in cr.y place of employ ment shall be maintained free of accu mulations of asbestos fibers if. with their dispersion, there would bo on excessive concentration. (4) Tennination of emploi'mcnt. Tie employ^:.-* shall provide, or make Avail able. within 30 calendar days before or after the termination of employment of any employee engaged in an occupation (2) Waste disposal. Asbestos waste, exposed to airborne concentrations of scrap, debris, bags, containers, equip asbestos fibers,-a comprehensive medical ment, and fcshestos-contamlnated cloth examination which shall Include, as a ing, consigned for disposal, which may minimum, a chest roentgenogram (pos produce in any reasonably foreseeable terior-anterior 14 x 17 inches), a history use, handline storage.-processing, dis to elicit symptomatology of respiratory posal, or transportation airborne concen disease, and pulmonary function tests trations of asbestos fibers In excess of the to include forced vital capacity (FVC) exposure limits prescribed in paragraph and forced expiratory volume at l second (b> of this section shall be collected end (FITVt.). disposed of In sealed Impermeable bags, (5) Rcceni'examtnartons/No medical or other closed^ Impermeable containers. examination is required of any em (1) Recordkeeping--(II Exposure rec ployee. if adequate records show that ords. Every employer shall maintain rec the employee has been examined in ac ords of any personal or environmental cordance with this paragraph within the monitoring required by this section. Rec past 1-year period. ords shall be maintained for a period of at least 20 years And shall be made avail able upon request to the Assistant SeerctruT.of lAbor for Occupational Safety and Health, the Director of the National Institute for Occupational Safety and Health, and to authorized representa tives of either. (6) Medical recoras--(1) Mainte nance. Employers of employees examined pursuant to this paragraph shall cause to he maintained complete and accurr.te records of all such medical examina tions. Records shall be retained by employers for at least 20 years. 11910.10010)0) amended at 41 IR 11505. (U) Access. The contents of the rec March 19, 1976) ords of the medical examinations (2) Employee access. Every employee required by this paragraph shall l>e made and former employee shall have reason available, for Inspection and copying, able access to any ivcord required to be to the Assistant Secretary of Labor lor maintained by subparagraph ih of this Occupational Safety and Healtu. the paragraph, which Indicates the em Director of NIOSH. to authorized physi ployee's own exposure to asbestos fibers. cians and medical consultants of eitner -'(Si-Employee notification. Any era- of them, ami. upon the request of an em ployce found to have been exposed at any ployee or sormcr employee, to his physi tlmo to airborne concentrations of asbes cian Any physician who conducts-a tos fibers in excels of the limits pre medical cxc'iunatlon required by this scribed In paragraph (b) of Cltln sccUon paragraph shall furnish to the employer shall be notified in writing of the expo of the examined employee all the infor sure as soon os practicable but not later mation specifically required by this thAn S days of the finding. The employee paragraph. And any other medical In shall also be timely notified of the cor formation related to occupational ex rective action being taken. posure to asbestos fibers. 5 1910.1 002 Co.1 tai phcli voletilrii <fiItrprrutii/n of t-.-rro, Xsnwd * See. 1910.1000 (Table Zl.enai tar pitch \ dallies include the fused poly cyclic hytfrecr-rbons which v-hutfiize from the distillation residues of cool, petroleum, wood, and other organic mat ter. |?7 PR 2-74 Effective November 21. 1972J N-lr: Po ihc mein- l. ir ,`t. rr.unl f.\:' lif-vi. l:;.' ,ju *! U! .T PnHJ.'.ii';- >-_ ,. ` .'..*.;.> vve;; x. by utv .| % 191MC03 4-N*ttrobi|ihenyl. (a) Scope and application. (1) This faction applies to tuiy area in which 4-Nitrobiphcnyl, Otemlcal Abstracts Bcrvice Registry Number t`2333 is mmmlactured, processed, repaukssed, re leased, handled, or stored, but siiall not apply to transshipment in sealed con tainers, except for the labsting require ments under paragraphs (e> (2), (3), and (4) of this section. (2) This section shall not apply to eolid or liquid mixtures containing less Ur.n 0.1 pcrcer.t by weight or volume of 4-Nitrobiphonyl. (b) OeA'iiiions. For the purposes of this section: <1> "Absolute filter" Is one capable of i-ctoining 99.97 percent of a mono disperse aerosol of 0.3 pm particles. (2) '`Authorized employro1' means an employee whose duties require him to be in the regulated area and who has been specifically assigned by the employer. (3) "Clean change room" means a room where employees put on dean clothing and/or protective equipment In on environment free of 4-Nitrobipbenyl. The clean cliangc room shall bo con tiguous to and have an entry from a shower room, when the shower room facilities arc otherwise required in this section. (4) "Closed system" means an opera tion involving 4-Nltrobipheuyl where containment prevents the relcass of 4Nitroblphenyl into regulated areas, nonreguiated areas, or the external environ ment. (5) "Decontamination" means the In activation of 4-Nitroblphenyl or Its safe disposal. (0) "Director" means the Director. National `Institute for Occupational Safety and Health, or any perron di rected by him or the Secretary of Health. Education, and Welfare to act for the Director. (7) "Dispotal" means the safe re moval of 4-Kitroblphenyl from the work environment. (8) "Emergency" means an unforseen circumstance- or set of circumstances re sulting in the rcle-ise of 4-Nltroblpberyl which znay result in expo.TUre to or con tact with 4-Nktroblpbenyi. (9) "External environment" means any environment external to regulated andnonregulated areas. (10) "Isolated system" means a fully enclosed structure other than the vessel of contaiur.icnt of 4-Klt-robiphenyl, which is impervious to the passage of 4NltrobJphcnyJ. arul wlilch would prevent Occupational Safety A Health Reporter (Sec. 1910.1003161(101* 14 RSV 0011333