Document Zn1qJDY3N3QQ3wBLOJZD89dRd

VINYUDENE CHLORIDE, INHIBITED UN1303 CAS #75-35-4 RQ FIRE Extremely flammable liquid and vapor Immediately evacuate area Only trained personnel equipped with NlOSH/MSHA-approved self-contained breathing apparatus should be allowed m area Toxic and corrosive fumes of hydrogen chloride can be formed Use foam, water carbon dioxide or dry chemicals to fight fire Use water spray to cool equipment exposed to fire uplosive peroxides may be formed by exposure to air EXPOSURE INHALATION Remove to fresh air If not breathing, give artificial respiration preferably mouth-to-mouth H breathing is difficult, give oxygen Call a physic/an EYE OR SKIN CONTACT, Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes ff irritation occurs, consutt a physician SWALLOWING. If conscious, drink large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If vomiting occurs administer additional water If unconscious, or m convulsions, take immediately to a hospital DO NOT give anything by mouth to an unconscious person SPILL OR LEAK Evacuate area, remove all ignition sources and provide maximum ventilation Only persons equipped with proper respiratory and skin/eye protection should be allowed in area Dike area of spill, using adsorbents such as sand or vermicuiite to avoid spread of spilled material Then pump diked material into covered container for disposal Any remaining material should be adsorbed on sand or vermicuiite and swept into closed containers for disposal After all visible traces including tgnitable vapors, have been removed thoroughly wet vacuum the area DO NOT flush to sewer If area of spill is porous remove as much contaminated earth, gravel, etc as necessary and place in closed containers for disposal Contaminated sawdust, vermicuiite, or porous surface may be disposed of in an approved hazardous waste management facility Recovered liquids may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility EMERGENCY Transportation Incident, Contact CHEMTREC 1800) 424*9300 in all other emergencies, contact PPG Industries, Inc Natrium WV (304) 843 1300 EXTREMELY FLAMMABLE E Dl I VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS Store m a cool, dry place away from direct sunlight and other sources of heat. Adequate ventilation must be maintained in storage areas to reduce fire hazard m the event of a leak. Wear goggles, gloves and skin protection when handling. Wear respiratory protection tn any case where exposure may be above permissible exposure limits Before unloading, purge air from unloading system with nitrogen and keep Vinylidene Chloride in a nitrogen atmosphere Avoid contact with air or oxygen. May create explosive peroxides. AVOID CONTAMINATION OF WATER SUPPLIES Handling, storage and use procedures must be carefully monitored to avoid spills or leaks. Any spill or leak has the potential to cause underground water contamination which may. if sufficiently severe, render a drinking water source unfit for human consumption Contamination that does occur cannot be easily corrected Container and system must be electrically grounded before unloading a Store only in closed, properly labeled containers For additional product information, contact PPG Industries, Inc PPG Industries Inc One PPG Place Pittsburgh PA 15272 Made in U S.A 1 1989 PPG Industries. Inc L9C-889D SEE REVERSE SIDE EOR PRECAUTIONS AND FIRST AID NOTE: READ AND REMOVE TAG BEFORE UNLOADING '4 VIIMYLIDEIME CHLORIDE, INHIBITED UNI 303 RQ CAS #75-35-4 EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT. SPARKS AND FLAME AVOID BREATHING VAPORS. Excessive vapor inhalation can cause illness or death Long-term, low-level vapor inhalation can cause kidney and liver in|ury USE WITH AOEQUATE VENTILATION: Ventilation must be sufficient to limit employee exposure to Vinylidene Chloride below OSHA Permissible Exposure Limit 1 ppm, 8-hour TWA (Time Weighted Average). AVOID CONTACT WITH EYES. SKIN OR CLOTHING. Eye or skin contact causes irritation and may cause burns DO NOT ALLOW AIR INTO CONTAINERS OR STORAGE VESSELS. Exposure of Vinylidene Chloride to air may form explosive peroxides DO NOT SWALLOW. * * FIRST AID + INHALATION. Remove to fresh air If not breathing, give artificial respiration, preferably mouth-to-mouth If breathing is difficult give oxygen Call a physician EYE OR SKIN CONTACT Immediately flush eyes and skin with water (soap and water for skml tor at least 15 minutes while removing contaminated clothing and shoes If irritation occurs consult a physician Thoroughly clean contaminated clothing and shoes before reuse or discard SWALLOWING1 If conscious, drink large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If vomiting occurs administer additional water If unconscious, or in convulsions, take immediately to hospital DO NOT give anything by mouth to an unconscious person NOTES TO PHYSICIAN: NEVER administer adrenaline following Vinylidene Chloride overexposure Increased sensitivity of the heart to adrenaline may be caused by overexposure to Vinylidene Chloride, 1 ^PG Industries Inc One PPG Place Pittsburgh PA 1 5272 SEE REVERSE SIDE FOR HANDLING AND STORAGE L9C-889D NOTE: READ AND REMOVE TAG BEFORE UNLOADING SL 071089  i?;u M gm ii v:i i lml ;:i v;m n:iii1 VINYUDENE CHLORIDE INHIBITED UN1303 CAS #75-35-4 RQ DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT. SPARKS AND FLAME. AVOID BREATHING VAPORS. Excessive vapor inhalation can cause illness or death. Long-term, low-level vapor inhalation can cause kidney and liver injury. USE WITH ADEQUATE VENTILATION: Ventilation must be sufficient to limit employee exposure to Vinylidene Chloride below OSHA Permissible Exposure Limit: 1 ppm, 8-hour TWA (Time Weighted Average). AVOID CONTACT WITH EYES, SKIN OR CLOTHING. Eye or skin contact causes irritation and may cause burns. DO NOT ALLOW AIR INTO CONTAINERS OR STORAGE VESSELS. Exposure of Vinylidene Chloride to air may form explosive peroxides. DO NOT SWALLOW. FIRST AID + INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen Call a physician. EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes. If irritation occurs, consult a physician. Thoroughly clean contaminated clothing and shoes before reuse or discard, SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting. Take immediately to a hospital or physician. If vomiting occurs, administer additional water. If unconscious, or in convulsions, take immediately to hospital. DO NOT give anything by mouth to an unconscious person. NOTES TO PHYSICIAN: NEVER administer adrenaline following Vinylidene Chloride overexposure. Increased sensitivity of the heart to adrenaline may be caused by overexposure to Vinylidene Chloride. ejj PPG Industries, Inc One PPG Place Pittsburgh, PA 15272 SEE REVERSE SIDE FOR HANDLING AND STORAGE L9B-889D j SL 071090  11.1k r>j1 ii f iV IL'Jkl VINYLIDENE CHLORIDE INHIBITED UN1303 CAS #75-35-4 RQ FIRE EXPOSURE SPILL OR LEAK Extremely flammable liquid and vapor Immediately evacuate area Only trained personnel equipped with NIOSH/MSHA-approved self-contained breathing apparatus should be allowed in area Toxic and corrosive fumes of hydrogen chloride can be formed. Use foam, water, carbon dioxide or dry chemicals to fight fire Use water spray to cool equipment exposed to fire Explosive peroxides may be formed by exposure to air INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth, If breathing is difficult, give oxygen Call a physician. EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes If irritation occurs, consult a physician SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting. Take immediately to a hospital or physician. If vomiting occurs, administer additional water. If unconscious, or in convulsions, take immediately to a hospital, DO NOT give anything by mouth to an unconscious person Evacuate area, remove all ignition sources and provide maximum ventilation. Only persons equipped with proper respiratory and skin/eye protection should be allowed in area Dike area of spill, using adsorbents such as sand or vermiculite to avoid spread of spilled material. Then pump diked material into covered container for disposal Any remaining material should be adsorbed on sand or vermiculite and swept into closed containers for disposal After all visible traces, including ignitable vapors, have been removed, thoroughly wet vacuum the area, DO NOT flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc., as necessary and place in closed containers for disposal Contaminated sawdust, vermiculite, or porous surface may be disposed of in an approved hazardous waste management facility Recovered liquids may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility. EMERGENCY Transportation Incident: Contact CHEMTREC (800) 424-9300. In all other emergencies, contact PPG Industries, Inc,, Natrium, WV (304) 843-1300 EXTREMELY FLAMMABLE DANGER! VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS. Store in a cool, dry place away from direct sunlight and other sources of heat. Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak. Wear goggles, gloves and skin protection when handling. Wear respiratory protection in any case where exposure may be above permissible exposure limits. Before unloading, purge air from unloading system with nitrogen and keep Vinylidene Chloride in a nitrogen atmosphere. Avoid contact with air or oxygen. May create explosive peroxides. AVOID CONTAMINATION OF WATER SUPPLIES: Handling, storage and use procedures must be carefully monitored to avoid spills or leaks. Any spill or leak has the potential to cause underground water contamination which may, if sufficiently severe, render a drinking water source unfit for human consumption. Contamination that does occur cannot be easily corrected. Container and system must be electrically grounded before unloading. Store only in closed, properly labeled containers. For additional product information, contact PPG Industries, Inc. PPG Industries. Inc One PPG Place Pittsburgh. PA 15272 Made in U.S.A. v01989 PPG Industries, Inc. L9B-889D SEE REVERSE SIDE FOR PRECAUTIONS AND FIRST AID SL 071091 VINYLIDENE CHLORIDE UN1303 RQ 5000 lbs/2270 kg CAS #75-354 FIRE EXPOSURE Extremely flammable liquid and vapor Immediately evacuate area Only trained personnel equipped with NIOSH MSHA approved self contained breathing apparatus Should be allowed m area Toxic and corrosive fumes of hydrogen chloride can be formed Use foam, water carbon dioxide or dry chemicals to fight fire Use water spray to cool equipment exposed to lire Explosive peroxides may be formed by exposure to air INHALATION Remove to fresh atr If not breathing give artificial respiration preferably mouth to mouth If breathing is difficult, give oxygen Call S physician EYE OR SKIN CONTACT Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes H irritation occurs consult a physician SWALLOWING If conscious, drink large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician ff vomiting occurs, administer additional water If unconscious, or in convulsions, take immediately to a hospital DO NOT give anything by mouth to an unconscious person SPILL OR LEAK Evacuate area, rerrvwe ail ignition sources and provide maximum ventilation Onfy persons equipped with proper respiratory and skm/eye protection should be allowed in area Dike area of spill, using adsorbents such as sand or vermiculite to avoid spread of spilled material Then pump diked material into covered container for disposal Any remaining material should be adsorbed on sand or vermiculite and swept into closed containers for disposal, After all visible traces, including ignttable vapors, have been removed, thoroughly wet vacuum the area DO NOT flush to sewer If area of spill is porous, remove as much contaminated earth gravel, etc. as necessary and place m closed containers for disposal Contaminated sawdust vermiculite, or porous surface may be disposed of in an approved hazardous waste management facility Recovered liquids may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility EMERGENCY Transportation Incident- Contact CHEMTHEC 1800) 424-9300 In all other emergencies contact PPG Industries Inc Natrium VW (3041 843-1300 EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS, e Store m a cool, dry place away from direct sunlight and other sources of heat. * Adequate ventilation must be maintained in storage areas to reduce fire hazard tn the event of a leak. e Wear goggles, gloves and skin protection when handling e Wear respiratory protection in any case where exposure may be above permissible exposure limits a Before unloading, purge air from unloading system with nitrogen and keep Vmykdene Chloride in a nitrogen atmosphere Avoid contact with air or oxygen. May create explosive peroxides AVOID CONTAMINATION OF WATER SUPPLIES. Handling, storage and use procedures must be carefully monitored to avoid spills or leaks Any spilt or leak has the potential to cause underground water contamination which may, rf sufficiently severe, render a drinking water source unfit for human consumption Contamination that does occur cannot be easily corrected a Container and system must be electrically grounded before unloading Store only m closed, properly labeled containers For additional product information, contact PPG Industries, Inc. 7 r# PPG induBU'e1; I'-.ir On? PPG Pnsbjrqi- pa 15272 Made in U S A. 1984 PPG Industries. Inc L120A-1A-1284C SEE7 REVERSE SIDE FOR PRECAUTIONS AND FIRST AID j NOTE: READ AND REMOVE TAG BEFORE UNLOADING VINYLIDENE CHLORIDE UI\I1303 RQ 5000 lbs/2270 kg CAS #75-35-4 DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT. SPARKS AND FLAME AVOID BREATHING VAPORS. Excessive vapor inhalation can cause illness or death Long-term, low-level vapor inhalation can cause kidney and liver m|ury m USE WITH ADEQUATE VENTILATION' Ventilation must be sufficient to limit employee exposure to Vinylidene Chloride below PPG Internal Permissible Exposure Limit 2 5 ppm, 8-hour TWA. 10 ppm, STEL (15-minute short-term exposure limit) AVOID CONTACT WITH EYES, SKIN OR CLOTHING. Eye or skin contact causes severe irritation and mav cause burns DO NOT ALLOW AIR INTO CONTAINERS OR STORAGE VESSELS Exposure of Vinylidene Chloride to air may form explosive peroxides DO NOT SWALLOW. FIRST AID + INHALATION. Remove to fresh air If not breathing, give artificial respiration, preferably mouth-to-mouth If breathing is difficult give oxygen Call a physician EYE OR SKIN CONTACT. Immediately flush eyes and skin with water (soap and water foi skml for at least 15 minutes while removing : laminated clothing and shoes If irntat'on occurs, consult a physician Thoroughly clean 'itaminated clothing and shoes before reuse or discard SWALLOWING' If conscious, drink large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If vomiting occurs, administer additional water If unconscious, or in convulsions take immediately to hospital DO NOT give anything by mouth to an unconscious person NOTES TO PHYSICIAN- NEVER administer adrenalin following Vinylidene Chloride overexposure Increased sensitivity of the heart to adrenalin may be caused by overexposure Vinylidene Chloride PPG industries Inc One PPG Place Pittsburgh PA 15272 L120A-1 A-1284C SEE REVFRSE SIDE FOR HANDLING AND STORAGE NOTE: READ AND REMOVE TAG BEFORE UNLOADING .< * * SL 071093 VINYLIDENE CHLORIDE UNI 303 RQ 5000 lbs/2270 kg CAS #75-35-4 FIRE Extremely flammable liquid and vapor Immediately evacuate area. Only trained personnel equipped with NIOSH/MSHA-approved self-contained breathing apparatus should be allowed m area Toxic and corrosive fumes of hydrogen chloride can be formed Use foam, water, carbon dioxide or dry chemicals to fight fire. Use water spray to cool equipment exposed to fire Explosive peroxides may be formed by exposure to air EXPOSURE INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes. If irritation occurs, consult a physician. SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting. Take immediately to a hospital or physician. If vomiting occurs, administer additional water. If unconscious, or in convulsions, lake immediately to a hospital. DO NOT give anything by mouth to an unconscious person. SPILL OR LEAK Evacuate area, remove all ignition sources and provide maximum ventilation. Only persons equipped with proper respiratory and skin/eye protection should be allowed in area. Dike area of spill, using adsorbents such as sand or vermiculite to avoid spread of spilled material. Then pump diked material into covered container for disposal. Any remaining material should be adsorbed on sand or vermiculite and swept into closed containers for disposal. After all visible traces, including ignitable vapors, have been removed, thoroughly wet vacuum the area. DO NOT flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc., as necessary and place in closed containers for disposal. Contaminated sawdust, vermiculite, or porous surface may be disposed of in an approved hazardous waste management facility. Recovered liquids may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility EMERGENCY Transportation Incident: Contact CHEMTREC (800) 424-9300. In all other emergencies, contact PPG Industries, Inc., Natrium, WV (304) 843-1 300 EXTREMELY FLAMMABLE ^9|k|C I VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS. Store in a cool, dry place away from direct sunlight and other sources of heat. Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak. Wear goggles, gloves and skin protection when handling. Wear respiratory protection in any case where exposure may be above permissible exposure limits. Before unloading, purge air from unloading system with nitrogen and keep Vinylidene Chloride in a nitrogen atmosphere. Avoid contact with air or oxygen. May create explosive peroxides. AVOID CONTAMINATION OF WATER SUPPLIES: Handling, storage and use procedures must be carefully monitored to avoid spills or leaks. Any spill or leak has the potential to cause underground water contamination which may, if sufficiently severe, render a drinking water source unfit for human consumption. Contamination that does occur cannot be easily corrected. Container and system must be electrically grounded before unloading. Store only in closed, properly labeled containers. For additional product information, contact PPG Industries, Inc. PPG Industries, Inc One PPG Place Made in U S.A. SL 071094 I ifililKI uu;1 nil ilJ i) tctiia ail i/`I filial:11 DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT, SPARKS AND FLAME. AVOID BREATHING VAPORS. Excessive vapor inhalation can cause illness or death. Long-term, low-level vapor inhalation can cause kidney and liver injury. USE WITH ADEQUATE VENTILATION: Ventilation must be sufficient to limit employee exposure to Vinylidene Chloride below PPG Internal Permissible Exposure Limit: 2.5 ppm, 8-hour TWA; 10 ppm, STEL (15-minute short-term exposure limit). AVOID CONTACT WITH EYES. SKIN OR CLOTHING. Eye or skin contact causes severe irritation and may cause burns. DO NOT ALLOW AIR INTO CONTAINERS OR STORAGE VESSELS. Exposure of Vinylidene Chloride to air may form explosive peroxides. DO NOT SWALLOW. FIRST AID + INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth If breathing is difficult, give oxygen. Call a physician * EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes. If irritation occurs, consult a physician. Thoroughly clean contaminated clothing and shoes before reuse or discard. SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting Take immediately to a hospital or physician. If vomiting occurs, administer additional water. If unconscious, or in convulsions, take immediately to hospital DO NOT give anything by mouth to an unconscious person. NOTES TO PHYSICIAN: NEVER administer adrenalin following Vinylidene Chloride overexposure. Increased sensitivity of the heart to adrenalin may be caused by overexposure to Vinylidene Chloride. PPG Industries, Inc f One PPG Place SL 071095 1 1/IMVI1 nciuc VIIMYLI UtIMt pm inoinp UnuUnlUC UNI 303 RQ DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT. SPARKS AND FLAME. AVOID BREATHING VAPOR. * USE WITH ADEQUATE VENTILATION. Ventilation must be sufficient to limit employee exposure to vinylidene chloride below PPG Internal Permissible Exposure Limit (2.5 ppm 8-hour TWA: 10 ppm-STEL) AVOID CONTACT WITH EYES, SKIN OR CLOTHING. Eye or skin contact causes severe irritation and may cause burns. AVOID CONTACT WITH AIR OR OXYGEN May fo'm explosive peroxide FIRST AID + INHALATION: Remove to fresh air If not breathing, give artificial respiration, preferably mouth-:; mouth If breathing is difficult, give oxygen Callaphysician EYE OR SKIN CONTACT Immediately flush eyes and skin with water (soap and water for skin' for at least 15 minutes while removing contaminated clothing and shoes lf ,rritaticn occurs consult a physician SWALLOWING If conscious, drmk larae quantities of water DO NOT .ndi.ce vomiting Taxe "nmecnatelv to rf hospital or physician If vomiting i'_rs anmincste: additional water If unconscious, or in convulsions take i"m-'cately to hcsp'tai DO NOT attempt to induce vomiting or give anything i". 'o an on rnnscious person INDUSTRIES PPG INDUSTRIES Inc One Gc'evvay Center `muS'.LUch pa 15222 (.1204 a r-, -c SEE REVERSE SIDE FOR HANDLING AND STORAGE NOTE READ AND REMOVE TAG BEFORE UNLOADING. VINYLJDENECHLORIDE UNI 303 RQ FIRE Extremely flammable liquid and vapor Immediately evacuate area Only ' trained personnel equipped with NtOSH MSHA-approved self-contained breathing apparatus should be allowed m area Toxic ano corrosive fumes of hydrogen chloride can be formed Use foam, water carbon dioxide or dry chemicals to fight fire Use water sprav :> cool equipment exposed to fire Explosive peroxides may be formed bv exposure to air EXPOSURE INHALATION. Remove to fresh air If not breathing give artificial respiration preferably mouth-to mouth If breathing is difficult, give oxygen Call a physician EYE OR SKIN CONTACT Immediately flush eves and skin wit1 water (soap and water for skint for at least 15 minutes while removing contaminated clothing and shoes If irritation occurs consult a physician SWALLOWING. If conscious, drink large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If vomiting occurs administer additional water If unconscious, or in convulsions, tak immediately to a hospital DO NOT attempt to induce vomiting or give anything bv mouth :o an unconscious person SPILL OR LEAK Evacuate area, remove all ignition sources and provide maximum ventilation Only persons equipped with proper respiratory and skm eve protection should be allowed m area Small spills Absorb on sand or vermiculite and place m closed vented container for disposal Large spills, Dike area Pump into closed containers for disposal Flush area w-th water and maintain ventilation until traces have evaporated DO NOT flush to sewer-mav create explosion hazard ( EMERGENCY Transportation Incident Contact CHEMTREC :800) 424 9300 In al other emergencies contact PPG Industries Inc Natrium VW (304) 843 130(3 E W9 | EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage Store in a cool, dry place away from direct sunlight and other sources of heat, Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak. Wear goggles, gloves and skin protection when handling. Wear respiratory protection in any case where exposure may be above recom mended limit [PPG - 2.5 ppm (8-hour TWA). 10 ppm (STEL)] Before unloading, purge unloading system with oxygen-free nitrogen Avoid contact with air or oxygen May create explosive peroxides Container and system must be electrically grounded before unloading. Do not store in open, unlabeled or mislabeled containers PPG INDUSTRIES, Inc One Gateway Center Pittsburgh, PA 15222 INDUSTRIES 1A-782B SEE REVERSE SIDE FOR PRECAUTIONS AND FIRST AID . NOTE: READ AND REMOVE TAG BEFORE UNLOADING. | SL 071097 litiUM uii ii rm in uraia 3 imuii nitfii ;i i VINYLIDENE CHLORIDE UNI 303 RQ DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT, SPARKS AND FLAME. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. Ventilation must be sufficient to limit employee exposure to vinylidene chloride below PPG Internal Permissible Exposure Limit (2.5 ppm 8-hour TWA; 10 ppm-STEL). AVOID CONTACT WITH EYES, SKIN OR CLOTHING. Eye or skin contact causes severe irritation and may cause burns. AVOID CONTACT WITH AIR OR OXYGEN May form explosive peroxide FIRST AID* INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes. If irritation occurs, consult a physician. SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting. Take immediately to a hospital or physician. If vomiting occurs, administer additional water. If unconscious, or in convulsions, take immediately to hospital. DO NOT attempt to induce vomiting or give anything by mouth to an unconscious person. INDUSTRIES PPG INDUSTRIES, Inc. One Gateway Center Pittsburgh, PA 15222 IT120A-1A-7R7R n miiiMiiuntcftiaai'i ha ima :t imhbi VINYL.IDENE CHLORIDE UNI 303 RQ -- FIRE Extremely flammable liquid and vapor. Immediately evacuate area. Only trained personnel equipped with NlOSH/MSHA-approved self-contained breathing apparatus should be allowed in area. Toxic and corrosive fumes of hydrogen chloride can be formed. Use foam, water, carbon dioxide or dry chemicals to fight fire. Use water spray to cool equipment exposed to fire Explosive peroxides may be formed by exposure to air. EXPOSURE INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes. If irritation occurs, consult a physician SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting. Take immediately to a hospital or physician. If vomiting occurs, administer additional water. If unconscious, or in convulsions, take immediately to a hospital. DO NOT attempt to induce vomiting or give 1 anything by mouth to an unconscious person SPILL OR LEAK Evacuate area, remove all ignition sources and provide maximum ventilation. Only persons equipped with proper respiratory and skin/eye protection should be allowed in area. Small spills: Absorb on sand or vermiculite and place in closed, vented container for disposal. Large spills: Dike area. Pump into closed containers for disposal. Flush area with water and maintain ventilation until traces have evaporated. DO NOT flush to sewer-may create explosion hazard. EMERGENCY Transportation Incident: Contact CHEMTREC (800) 424-9300. In al other emergencies, contact PPG Industries, Inc., Natrium, WV (304) 843-1300 W%A EXTREMELY FLAMMABLE E BP VAPOR HARMFUL WSm Bm. m explosive peroxides may be FORMED BY EXPOSURE TO AIR Handling and Storage Store in a cool, dry place away from direct sunlight and other sources of heat. Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak. Wear goggles, gloves and skin protection when handling. Wear respiratory protection in any case where exposure may be above recommended limit [PPG - 2.5 ppm (8*hour TWA); 10 ppm (STEL)] Before unloading, purge unloading system with oxygen-free nitrogen. Avoid contact with air or oxygen. May create explosive peroxides. Container and system must be electrically grounded before unloading. Do not store in open, unlabeled or mislabeled containers. INDUSTRIES PPG INDUSTRIES, Inc. One Gateway Center Pittsburgh, PA 15222 I T1 DOA.1 A 1Q1Q SL 071099 VINYLIDENc CHLORIDE FIRE Extremely flammable liquid and vapor Immediately evacuate area Onlv trained personnel equipped with NIOSH MSHA-approved self -contained breathing apparatus should be allowed in area Toxic and corrosive fumes of hvarogen chloride can be formed Use foam water carbon dioxide ur rtrs chemicals to fight fire Use water spray to cool equipment exposed to fire Explosive peroxides may be formed by exposure to air EXPOSURE Inhalation Remove to fresn air If not breathing give artificial respiration preferably mouth to-moum If breathing is difficult, give oxygen Cal! a physician SPILL OR LEAK Evacuate area remove all ignition sources and provide maximum ventilation Only persons equipped with proper respiratory and skin eve protection should be allowed in area Small spills Absorb on sand or vermiculite and place m closed vented container for disposal Large spJls Dike area Pump into closed containers tor disposal Flush area with water and maintain ventilation until traces have evaporated DO NOT flush to sewer--may create explosion hazard Transportation Incident Contact CHEMTREC1800)424-9300 In all other EMERGENCY emergencies contact PPG Industries Inc . Natrium. WV ;304i843-1300 CID 1 EXTREMELY FLAMMABLE vapor harmful EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage Store in a cool, dry place away from direct sunlight and other sources of heat Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak Wear goggles, gloves and skin protection when handling Wear respiratory protection in any case where exposure may be above recommended limit (ACGIH -- "lOppmj Before unloading purge unloading system with oxygen-free nitrogen Avoid contact with air or oxygen May create explosive peroxides Container and system must be electrically grounded before unloading Do not store in open, unlabeled or mislabeled containers INDUSTRIES PPG INDUSTRIES, Inc Chemicals Group One Gateway Center Pittsburgh PA ',5222 Ltttoa .. 57?- SEE REVERSE SIDE FOR PRECAUTIONS AND FIRST AID NOTE: READ AND REMOVE TAG BEFORE UNLOADING. SL 071100 VINYUDENJ CHLORIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT, SPARKS AND FLAME AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. Ventilation must be sufficient to limit employee exposure tovmylidene chionde below ACGIH recommended limit 10 ppm--ACGIH 1976) AVOID CONTACT WITH EYES, SKIN OR CLOTHING. Eve or skm contact causes severe irritation and mav cause bur ns AVOID CONTACT WITH AIR OR OXYGEN Wav form explosive peroxide + FIRST AID + INHALATION Remove to fresh air If no: o'--=a-h:ng give arvficial roscm ,,_,n pr-'Vr chi', mcuth-to mouth if breatnmg is p.moult giv=ox\gen Callnpm , . y EYE OR SKIN CONTACT. Immed'ateK h.isn nves and skin witn v ater ,,mn 3"c '.va'-1' <o' skin) for at leas' 15 minutes m removing conte"'..-. ,-,,d 1 jth'na and shoes If irritation occu's cor1-., i; a pm sen,in kO'JSTRIES P'-'G INDUSTRIES Inc Chemicals Group One Gateway Center PittsDurgn PA 15222 SEE REVERSE SIDE FOR HANDLING AND STORAGE MOTE READ AMD REMOVE TAG BEFORE UNLOADING I KAnlbruh IAIIUIM SAht IY UAIA LAND VINYUDENE CHLORIDE FIRE EXPOSURE Extremely flammable liquid and vapor. Immediately evacuate area. Only trained personnel equipped with NIOSH/MSHA-approved self-contained breathing apparatus should be allowed in area. Toxic and corrosive fumes of hydrogen chloride can be formed. Use foam, water, carbon dioxide or dry chemicals to fight fire. Use water spray to cool equipment exposed to fire. Explosive peroxides may be formed by exposure to air. Inhalation: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. SPILL OR LEAK Evacuate area, remove all ignition sources and provide maximum ventilation. Only persons equipped with proper respiratory and skin/eye protection should be allowed in area. Small spills: Absorb on sand or vermiculite and place in closed, vented container for disposal. Large spills: Dike area. Pump into closed containers for disposal. Flush area with water and maintain ventilation until traces have evaporated. DO NOT flush to sewer--may create explosion hazard. EMERGENCY Transportation Incident Contact CHEMTREC (800)424-9300. In all other emergencies, contact PPG Industries, Inc., Natrium, WV (304) 843-1300. EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Handling and Storage Store in a cool, dry place away from direct sunlight and other sources of heat. Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak, Wear goggles, gloves and skin protection when handling. Wear respiratory protection in any case where exposure may be above recommended limit. (ACGIH--lOppm) Before unloading, purge unloading system with oxygen-free nitrogen. Avoid contact with air or oxygen. May create explosive peroxides. Container and system must be electrically grounded before unloading. Do not store in open, unlabeled or mislabeled containers. m industries PPG INDUSTRIES, Inc. Chemicals Group One Gateway Center Pittsburgh, PA 15222 ui20A -1A-579A SEE REVERSE SIDE FOR PRECAUTIONS AND FIRST AID SL 071102 i m uu ;i h\ i iiji'tMa a u >h\ hi VINYLIDENE CHLORIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS KEEP AWAY FROM HEAT, SPARKS AND FLAMl. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. Ventilation must be sufficient to limit employee exposure to vinylidene chloride below ACGIH recommended limit (10 ppm--ACGIH 1976) AVOID CONTACT WITH EYES. SKIN OR CLOTHING. ' * Eye or skin contact causes severe irritation and may cause burns AVOID CONTACT WITH AIR OR OXYGEN May form explosive peroxide FIRST AID + INHALATION: Remove to fresh air If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen Callaphysician EYE OR SKIN CONTACT: Immediately flush eyes and skin with water (soap and water for skin) for at least 15 minutes while removing contaminated clothing and shoes If irritation occurs, consult a physician ^ ^ industries PPG INDUSTRIES, Inc. Chemicals Group One Gateway Center Pittsburgh, PA 15222 LT120A-1A-579A SEE REVERSE SIDE FOR HANDLING AND STORAGE SL 071103 Vlt.YLIDENE CHLORIDE INHIBITED Chemicals TECHNICAL GRADE FOR INDUSTRIAL USE ONLY NOT FOR FOOD, DRUG, COSMETIC 01! PESTICIDE USE DANGER! EXTREMELYtFI A VAPORHARMFULi 'yAt jp*: CAUSES EYEANDSKIN IRRITATION EXPLOSIVE PEROXIDES MAY RE FORMED SY EXPOSURE TO . i*>!,:*>*(wetf.Ui jpv'LA?*:v I Precautions KEEP AWAY FROM HEAT, SPARKS AND FLAME. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. Ventilation must be sufficient to limit employee exposure in work area as far as practical below ACGIH recommended exposure limit (see below). AVOID CONTACTWITH EYES. SKIN OR CLOTHING. Eye or skin contact auses severe irritation end may cause burns. DO NOT ALLOW /UR INTO CONTAINER. Exposure of uninhibited or inhibitordepleted monomer toalrmayform explosive peroxides. FOR ADDITIONAL INFORMATION contact PPG Industries, Inc. + First Aid + INHALATION OVEREXPO SURE--Remove person to fresh air If not breathing, give artificial respiration, preferably mouth-tomouth. If breathing is difficult, give oxygen. Cali a physician. r EYE OR SKIN CONTACT-- IMMEDIATELY flush with plenty of water (spap and water for skin) for at least 15 minutes. If irritation occurs, CONSULT A PHYSICIAN. Wash contami nated clothing before reuse. ' Handling and Storage . *-,j~ `i.W ' - w 'Vs I MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS. "C I Store in a cool, dry ptaoe, away from direct sunlight and other sources of heat : Adequate ventilation must be maintained In storage areas to reduce firs heard In event of a leak. ' Do not store In open, unlabeled or mislabeled containers. Wear goggles, gloves and skin protection when handling. . Wear respiratory protection In any case where exposure may be above ACGIH recorn , mended limit. , . e, - >2 Drum and system must be electrically grounded before unloading. ' Before, unloading, purge air from unloading system with nitrogen and keep vinyliderw chlorktelnhlm^natmosphem..l^^'.'- Relieve Internal pressure by slowiy loosening bung. NOTE: tt drum is bulged due to internal pressure, DO NOT ATTEMPT TO UNLOADS Immediately contact PPG Industries at (318) 882-1200 for disposal. '^ When empty, flush container with plenty of water IN CASE OF FIRE: Wear self-contained breathing apparatus for possible exposure toy toxic, corrosive gases. Use water spray to cool equipment >3 IN CASE OF SPILL OR LEAK: Soak up on absorbent materia/ and sweep into vented container for disposal. KEEP OUT OF REACH OF CHILDREN Recoinmemieti Exposure Limit (UNDER REVIEW AND SUBJECT TO CHANGE} 8-liotir time-weiijhted average (TWA): 10 parts per million American Cnnferniti:i! of Olivermiienl.il Imiustiial Hygienists--1977 SL 071X04 PPG INDUSTRIES INC Chemicals Group One Gateway Cuntcr Pt!t<-;ht irrih PA 1 A??? NET WEIGHT: 500 Pounds 226.8 Kilograms r 3t (OMk!dm TECHNICAL GRADE FOR INDUSTRIAL USE ONLY L, INHIBITED Chemicals NOT FOR FOOD, DRUG, COSMETIC OR PESTICIDE USE INDUSTRIES FYTPFMFIYFI VAPORHARMFUL CAUSES EYEAND SKIN IRRITATION EXPLOSIVE PEROXIDES MAY RE FORMED RY EXPOSURE TO AIR Precautions KEEP AWAY FROM HEAT, SPARKS AND FLAME. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. Ventilation must be sufficient to limit employee exposure in work area as far as practical below ACGIH recommended exposure limit (see below). AVOID CONTACTWITH EYES. SKIN OR CLOTHING. Eye or skin contact pauses severe irritation and may cause burns. * DO NOT ALLOW AIRINTOCONTAINER. Exposure of uninhibited or Inhibitor* depleted monomer toair mayform explosive peroxides. FOR ADDITIONAL INFORMATION con tact PPG Industries, Inc. -p* -' ,. ; + First Aid + INHALATION OVEREXPO SURE--Remove person to fresh air If not breathing, give artificial respiration, preferably mouth-tomouth. If breathing is difficult, give oxygen. Call a physician. EYE OR SKIN CONTACTIMMEDIATELY flush with plenty of water (sqap and water for skin) for at least 15 minutes. If irritation occurs, CONSULT A PHYSICIAN. Wash contami nated clothing before reuse. Handling and Storage MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS. Store in a cool, dry plaoe, away from direct sunlight and other sources of heat. Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak. Do not store in open, unlabeled or misiabeled containers. Wear goggles, gloves and skin protection when handling. Wear respiratory protection in any case where exposure may be above ACGIH recom mended limit. Drum and system must be electrically grounded before unloading. Before unloading, purge air from unloading system with nitrogen and keep vinylidene chloride in nitrogen atmosphere. -- Relieve internal pressure by slowly loosening bung. NOTE: if drum is bulged due to Internal pressure, DO NOT ATTEMPT TO UNLOAD. Immediately contact PPG Industries at (318) 882-1200 for disposal, When empty, flush container with plenty of water. IN CASE OF FIRE: Wear self-contained breathing apparatus for possible exposure to toxic, corrosive gases. Use water spray to cool equipment IN CASE OF SPILL OR LEAK: Soak up on absorbent materiel and sweep into vented container for disposal. KEEP OUT OF REACH OF CHILDREN Recuinmemleil Exposure Limit (UNDER REVIEW AND SURJECT TO CHANGE) 8-liimr time-weigliteil iivernge (TWA): 10 pints pei million Amerirmi Confluence of (iimuimienl.il Imlusltml Hygienists 1877 INDUSTRIES PPCT INDUSTRIES INC Chumiurjls Group One Gutow.-iv Guntur ITnubuitjh, F'A 1 b'222 ST. 071105 NET WEIGHT: 500 Pounds 226.8 Kilograms L120A-1B-7T8B DANGER* extremely flammable VAPOR HARMFUL MAY CAUSE BURNS EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR Keep aw.iv I;om heat, spmks. flames and open lights. Keep contninei closed. Avoid breathing vapor. Avoid contact with skin, eyes and clothing. Do not allow air into container. FIRST AID: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Flush skin with water. (Wash clothing before reuse.) IN CASE OF FIRE, use voder spray, foam, dry chemical or CO;'. HANDLING AND STORAGE KEEP CONTENTS UNDER INERT ATMOSPHERE IN DRY EQUIPMENT. Store in a cool dry place. RELIEVE INTERNAL PRESSURE by slowly loos ening bung. If drum is bulged due to internal pressure, promptly contact PPG Technical Service for advice on disposal. Remove bung and transfer contents in WELL VENTILATED AREA, Keep all open flame, lights and fire away. When emptied, promptly flush drum with plenty of water. Soak up SPILLS or LEAKS with sand and remove to safe area. lc nmi run jmll VINYLIDENE CHLORIDE (Inhibited) Chemicals JLP INDUSTRIES DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL MAY CAUSE BURNS Keep away from heat, sparks, flames and open lights. Keep container closed. Avoid breathing vapor. Avoid contact with skin, eyes and clothing. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, GET MEDICAL ATTENTION. KEEP OUT OF REACH OF CHILDREN HANDLING AND STORAGE Store in a cool dry place. RELIEVE INTERNAL PRESSURE by siowly loosening bung. Remove bung and transfer contents in WELL VENTILATED AREA. Keep all open flame, lights and fire away. Keep contents under inert atmosphere in dry equipment. Soak up spills with sand and remove to safe area. When emptied, promptly flush drum with plenty of water. 12 INDUSTRIES PPG INDUSTRIES, Inc. Chemical Division One Gateway Center Pittsburgh, Pa. 15222 SAMPLE NOT FOR SALE NET WEIGHT 45 LBS LOT NO. 1269 SL 071107 PPG Industries. Inc. its One PPG Place Pittsburgh. PA 15272 VI NYU DENE CHLORIDE , INHIBITED UN1303 TECHNICAL GRADE - FOR INDUSTRIAL USE ONLY / NOT FOR FOOD, DRUG, COSMETIC OR PESTICIDE USE KEEP OUT OF REACH OF CHILDREN! DANGER! * EXTREMELY FLAMMABLE * VAPOR HARMFUL I * EXPLOSIVE PEROXIDES MAY BE FORMED BY EXPOSURE TO AIR PRECAUTIONS: * KEEP AWAY FROM HEAT, SPARKS AND FLAME. * AVOID BREATHING VAPORS. * USE WITH ADEQUATE VENTILATION. * AVOID CONTACT WITH EYES, SKIN OR CLOTHING. * DO NOTALLOWAIR INTO CONTAINERS OR STORAGE VESSELS. * DO NOT SWALLOW. \ ' 1 A /\ + FIRST AID + j * INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. I * EYE OR SKIN CONTACT: Immediately flush eyes with plenty of water (soap and water for skin) for af least 15 minutes while removing contaminated clothing and shoes. If irritation occurs, consult a physician. Thoroughly clean contaminated clothing before reuse. Discard leather shoes. j * SWALLOWING: If conscious, drink large quantities of water. DO NOT induce vomiting. Take immediately FLAMMABLE to a hospital or physician. If vomiting occurs, administer additional water. If unconscious or in convulsions, take immediately to a hospital or physician. DO NOT attempt to induce vomiting or give anything by mouth. NOTES TO PHYSICIAN: Never administer adrenaline following vinyiidene chloride overexposure. Increased sensitivity of the heart to adrenaline may be caused by overexposure to vinyiidene chloride. HANDLING AND STORAGE: ; * MATERIAL SHOULD NOT BE STORED LONGER THAN FOUR (4) MONTHS. Store only in closed, properly labeled containers. \ * Store in.a cool, dry place away from direct sunlight and other sources of heat * Adequate ventilation must be maintained in storage areas to reduce fire hazard in the event of a leak. * Wear goggles, gloves, skin and respiratory protection when handling. * Avoid contact with air or oxygen. May create explosive peroxides. * Before unloading, drum and system must be electrically grounded. Also purge air from unloading system with nitrogen and keep vinyiidene chloride in nitrogen atmosphere. Relieve intemai pressure by slowiy loosening bung. NOTE: If drum is bulged due to internal pressure, DO NOTATTEMPT TO UNLOAD. Immediately contact PPGf. * AVOID CONTAMINATION OF WATER SUPPUES. * For additional product information, contact PPG Industries, Inc. LIQUID L9A-289A EMERGENCY TELEPHONE NUMBER, PPG INDUSTRIES, INC., NATRIUM, WV (304) 843-1300 Suppose you were making enough . film,to wrap all the pastrami sandwiches! glvimNew York. Who could supply ^*;ffie|vinylidene chloride? iiM : V -;, :>;j" SL 071log SL 071110 $ vX l ! f A ,, ///? A &. - :~ >> z-s --- i -`-fi-* VINYLIDENE*jjxi Emergency Situations Persons working in emergency situations should wear the equipment shown in drawing. Eye protection %apparatus Neoprene rubber gioves Hard hat KEEP IT AWAY FROM I Avoid sparks by electrically grounding all nonsparking tools. Storp this material In i KEEP AIR OUT OF ALL 1 Completely fill all tanks! drums and other oxygen, the vlnylidene ^hlorlde can react AUOID CONTAMINATE These metals and thelr^alloys, as well as peroxide or give off poisonous hydrogen " BREATHE THE l Be sure the ventilatjgflJS good before yoi wear your respirator.| Always wear closegoggles, rubber severe irritation or burns. Skin contact ct i EMEi FIRE When vinylidene chloride burns, it gives of that supplies air should be allowed in ttv out a fire, they can use carbon dioxide o SPILL OR LEAK Clean-up persons must wear eye and sk all ignition sources, get maximum veptila BREATHING TOO MUCI Acute overexposure will make a person When you can smell it, the vapor level is If a person faints, carry him into fresh ai give him oxygen. Call a doctor. EYES junergextcy situations Persons working in emergency situations should wear the equipment shown in drawing. Eye protection %apparatus Hard hat KEEP IT AWAV FROM FU Avoid sparks by electrically grounding all tan nonsparking tools. Storp this material In a co KEEP AIR OUT OF ALL VIP Completely fill all tanks drums and other con oxygen, the vinylidene chloride can react with AVOID CONTAMINATION These metals and their;aHoys, as well as cata peroxide or give off poisonous hydrogen chloi DON'T BREAtHE THE VAI Be sure the ventilatlgajs flood before you op wear your respiratory! ji . --doi^meithMiouidti Always wear close Tittiftff goggles, rubber glo\ severe irritation or burns. Skin contact can a Neoprene rubber gloves j Neoprene rubber boots FIRE When vinylidene chloride burns, it gives off pois that supplies air should be allowed in the are out a fire, they can use carbon dioxide or dry SPILL OR LEAK Clean-up persons must wear eye and skin pr< all ignition sources, get maximum veptilation BREATHING TOO MOCH l Acute overexposure will make a person act s When you can smell it, the vapor level is alre If a person faints, carry him into fresh air. If f give him oxygen. Call a doctor. EYES If vinylidene chloride liquid ge.s into your eye doctor right away. SKIN Inhibited vinylidene chloride irritates the skin, shoes. If a rash or burn shows up, see a doc SWALLOWING If the person is conscious, give him a quart c Call a doctor. If you can't get him to vomit, t If the person is unconscious or in convulsiom Don't give him anything by mouth. Emergency Telephone Num PPG Industries' Chemicals Group: (304) 843-1300 in Natrium, West Virginia, Telephone is manned to answer 24 hours a c DOCTOR^ AMBULANCE FIRE Statements and methods described herein are based On the best Inf PPG Industries, Inc., at the time of this public atlon. PPG Industries, practices and safety guidelines similar to the {statements or methods reduction of hazards In a particular facility. It Is the user's responslt and safety guidelines and precautions suited to the particular reqi vinylidene chloride Is used. (HP IT AWAY FROM FLAMES, SPARKS, HEAT AND DIRECT SONUGHT. void sparks by lectrldolly grounding all tanks, pumps, pipes, etc. Use only explosion-proof electrical equipment and onsparking tools. Stor? this material In a cool dry place. IEEP AIR 00]T OF ALL IRNYLIDENE CHLORIDE CONTAINERS. ompletely fill all tanks; drums and other containers with nitrogen to displace air. If the inhibitor gets used up by exposure to xygen, the vinylidene jfhlorlde can react with oxygen In the air to form an explosive peroxide. (VOID CONTAMINATION WITH CATALYSTS, COPPER AND ALOMINOM. hese metals and thelrelloys, as well as catalysts, can cause the vinylidene^chloride to decompose and form an explosive eroxide or give off poisonous hydrogen chloride gas. I0NT BREATHE THE VAPORS. e sur the v ntifatigflJs good before you open a drum, tank or other container. If you think there are vapors In th air 'ear your respirator. | |i.: -' IXmimLBI THELIQUID TOUCH YOUR EYES OR SKIN. _______ _ Iways wear close-fitting goggles, rubber gloves and protective clothing. If vinylidene chloride gets Into your eyes, It can cause avere irritation or burns. Skin contact can cause irritation and a rash. IRE /hen vinylidene chloride burns, it gives off poisonous and corrosive acid fumes. Only firefighters equipped with breathing apparatus lat supplies air should be allowed in the area. They should not try to put out a large fire if the leak has not been shut off. To put ut a fire, they can use carbon dioxide or dry chemical agents, also water spray or foam. Cool equipment by spraying with water iPILL OR LEAK lean-up persons must wear eye and skin protection, breathing apparatus that supplies air and spark-proof shoes. Get rid of II ignition sources, get maximum ventilation and try to shut off the leak. BREATHING TOO MUCH VINYLIDENE CHLORIDE VAPOR. cute overexposure will make a person act strangely. Continued overexposure can lead to unconsciousness and even death. Tien you can smell it, the vapor level is already much too high. Even if you cannot smell it, the vapor level may be too high, a person faints, carry him into fresh air. If he is not breathing, give him artificial respiration. If his breathing is difficult, ive him oxygen. Call a doctor. vinylidene chloride liquid ge:s into your eyes, wash them immediately with plenty of water for 15 minutes. Then see a octor right away. iKIN ihibited vinylidene chloride irritates the skin. Wash it off with plenty of water and soap whiie taking off splashed clothing and loes. If a rash or burn shows up, see a doctor. il/VALLOVUING the person is conscious, give him a quart of water to drink. Then get him to vomit by putting a finger far back in his throat, all a doctor. If you can't get him to vomit, take him to a doctor or hospital immediately. the person is unconscious or in convulsions, take him to a doctor or hospital immediately. Don't try to get him to vomit, on't give him anything by mouth. Emergency Telephone Number PG Industries' Chemicals Group: 04) 843-1300 in Natrium, West Virginia. Dlephone is manned to answer 24 hours a day. rJj OCTOR_______________ __:.-------------------- VJBULANCE___________________ RE itemenls and methods described herein are based on the best Information and practices known to G Industries, Inc., at the time of this publication. PPG Industries, Inc., does not represent that work ictlces and safety guidelines similar to the trtatements or methods contained herein will result In the Juctlon of hazards In a particular facility. It Is the user's responsibility to develop work practices d safety guidelines and precautions suited to the particular requirements of the facility where lylldene chloride Is used, PPG: A Concern for the Futur INDUSTRIES PPG INDUSTRIES, Inc. Chemicals Group One Gateway Center Pittsburgh, PA 15222 A-1234-120A 1M September 1978 Printed In U.S.A. [EEP IT AWAY FROM FLAMES, SPARKS, HEAT AND DIRECT SUNLIGHT. void sparks by electrically grounding all tanks, pumps, pipes, etc. Use only explosion-proof electrical equipment and onsparking tools. Stor^ this material In a cool dry place. (EEP MR OUT OF ALL UINYLIDENE CHLORIDE CONTAINERS. ompletely fill all tanks! drums and other containers with nitrogen to displace air. If the inhibitor gets used up by exposure to xygen, the vinylidene ^hlorlde can react with oxygen in the air to form an explosive peroxide. WOID CONTAMINATION WITH CATALYSTS. COPPER AND ALUMINUM. hes metals and thelr?alloys, as well as catalysts, can cause the vinylidene.chloride to decompose and form an exploslv eroxide or give off poisonous hydrogen chloride gas. lON'T BREATHE THE UAPORS. e sure the ventilatlgnJ? good before you open a drum, tank or other container. If you think there are vapors In the air, fear your respirator. \ __ IQNiTibklTH&LIQUID .TOUCH YOUR EYES OR SKIN. _______ _ Jways wear close-fiuirt goggles, rubber gloves and protective clothing. If vinylidene chloride gets Into your eyes, It can cause avere irritation or burns. Skin contact can cause irritation and a rash. IRE /hen vinylidene chloride burns, it gives off poisonous and corrosive acid fumes. Only firefighters equipped with breathing apparatus lat supplies air should be allowed in the area. They should not try to put out a large fire if the leak has not been shut off. To put ut a fire, they can use carbon dioxide or dry chemical agents, also water spray or foam. Cool equipment by spraying with water SPILL OR LEAK :lean-up persons must wear eye and skin protection, breathing apparatus that supplies air and spark-proof shoes. Get rid of II ignition sources, get maximum ventilation and try to shut off the leak. SREATHING TOO MUCH VINYLIDENE CHLORIDE VAPOR. cute overexposure will make a person act strangely. Continued overexposure can lead to unconsciousness and even death, /hen you can smell it, the vapor level is already much too high. Even if you cannot smell it, the vapor level may be too high, a person faints, carry him into fresh air. If he is not breathing, give him artificial respiration. If his breathing is difficult, ive him oxvoen. Call a doctor