Document ZMXeooGJbe7RmaXZ76exV5a8

9 MATERIAL SAFETY DATA SHEET AND SAFE HANDLING AND DISPOSAL INFORMATION e CLEAN ACROSS AMERICA AND THROUGHOUT THE WORLD ZEP MANUFACTURING COMPANY P.O. BOX 2015 ATLANTA, GEORGIA 30301 ISSUE DATE: 01/24/92 SUPERSEDES: ZEP HC 2000 PRODUCT NO- 5077 SECTION I - EMERGENCY CONTACTS TELEPHONE: (404) 352-1680 BETWEEN 8:00 AM - 5.00 PM (EST) MEDICAL EMERGENCY: (404) 435-2973 (404) 351 -2952 (404) 432-2873 NON-OFFICE HOURS. WEEKENDS AND HOLIDAYS. PLEASE CALL YOUR LOCAL POISON CONTROL TRANSPORTATION EMERGENCY: (404) 922-0923 CHEMTREC: 1-800-424-9300 TOLL-FREE ALL CALLS RECORDED DISTRICT OF COLUMBIA: ( } (202) 483-7616 ALL CALLS RECORDED SECTION II - HAZARDOUS INGREDIENTS DESIGNATIONS " SODIUM METASILICATE " silicic ocid <H2-Si-03> disodium sail, water glass. CAS# 6834-92-0. RTECS# W9275000. OSHA Dust Limit-2mg-m3 IIor powders onlyl @ " ETHYLENE GLYCOL MONOBUTYL ETHER " 2-butoxyethanol. butyl cellosolve. CAS# 111-76-2. RTECS# KJ8575000. OSHA PEL (SKIN)- 25 ppm * SODIUM HYDROXIDE " caustic soda, soda lye. CAS# 1310-73-2. RTECS# WB4900000, OSHA/ACGIH CEILING LIMIT-2 MG M3 TLV (PPM) N/D 25 N/D EFFECTS (SEE REVERSE) COR TOX IRR CBL TOX COR @ Identifies chemicals listed under SARA-Secbon 313 lor release reporting SECTION III - HEALTH HAZARD DATA Special Note: MSDS data pertains to the product as dispensed Irom the container. Adverse health effects would not be expected under recommend' conditions of use (diluted) so long as prescribed safety precautions are practiced. Acute Effects of Overexposure: Corrosive on contact Overexposure will produce tissue destruction particularly on mucous membranes of eyes, mouth, and respiratory tract Eye contact may produ severe irritation and blindness unless immediately (lushed Concentrated solutions may produce immediate skin damage Dilute solutions may produce severe irritati which intensities as contact continues Inhalation of mists may produce severe nasal and respiratory irritation o permanent damage Ingestion will produce tissue dama ol the gastrointestinal tract Overexposure by inhalation may cause respiratory irritation Ingredients in this product may aggravate existing skin. eye. or respirati disorders Chronic Effects of Overexposure: Repeated or prolonged exposure ol skin can produce chrome dermatitis characterised by redness, scaling, and blistering Repeated exposure to spray mists may lead chronic eye inflammation, chronic respiratory tract irritation or lung damage Animal studies indicate a potential for liver, kidney, or red blood cell damage Relevance these studies or exposure levels which might produce these ellects in humans has not been established None ol the ingredients are listed as carcinogens by IARC. NT or OSHA Esf'd PEOTLV- Not established Primary Routes of Entry: Inh. Skin HMIS Codes' HEALTH 3.FLAM 0,REACT 0.PERS PROTECT B CHRONIC HA2 YES FIRST AID PROCEDURES: Skin: Immediately Hush contaminated skin with plenty of water lor at least 15 minutes Get medical attention immediately Eyes' Immediately Hush eyes with plenty ol water lor at least 15 minutes, occasionally lilting upper and lower lids Get medical attention at once Inhale: Move exposed person to tresh air It irritation persists, get medical attention promptly Ingest II swallowed, do not induce vomiting If vomiting occurs, keep head below hrp level Get emergency medical attention immediately. SECTION IV - SPECIAL PROTECTION INFORMATION Protective Clothing: Eye Protection: Respiratory ProtectionVentilation: Wear a face shield, rubber or neoprene gloves, a rubber apron, and impervious footwear Wear splash-prool salety goggles especially il coniacl lenses are worn No extra measures are needed if ventilation is adequate Provide local exhaust/venlilation as needed to keep concentration ol vapors below exposure limits (PEL7LVI SECTION V - PHYSICAL DATA Boiling Point (F)- 213 F Specific Gravity: 104 Vapor Pressure (mmHg): Percent Volatile by Volume (*'.): 93 4"i Vapor Density (air = 1): > t Evaporation Rate (WATER =1). Solubility in Water- COMPLETE pH (concentrate): 13 2 pH (use dilution of ) Appearance and Odor: A RED LIQUID WITH A "BUTYL" ODOR_____________________ __________________________________________ 28 > I0 NO SECTION VI - FIRE AND EXPLOSION DATA Flash Point CF) (method used): Flammable Limits: Extinguishing Media: Special Fire Fighting: Unusual Fire Hazards: NONE() LEL N/A UEL N/A Noncombustible Wear sell-contained positive pres Breathing apparatus Fire exposed drums should be cooled with stream ol water DO A 061723 CONFTDFNTT Al. ZEP MANUFACTURING COMPANY MATERIAL SAFETY DATA SHEET SECTION VII - REACTIVITY DATA PAGE 2 stability: incompatibility (avoid), 'olymerization: Hazardous Decomposition Stable Strong acids and oxidizing agents Will not occur Carbon dioxide, carbon monoxide and other unidentified organic compounds SECTION VIII SPILL AND DISPOSAL PROCEDURES itep* . be Taken in Case Material is Released or Spilled: Observe salely precautions m sections 4 & 9 during clean-up Absorb spill on an inert absorbent material (e g Zep-O-Zorb). pick up and place in a clean DOT pecilication container lor disposal Wash area thoroughly with a detergent solution and then rinse well with water Vaste Disposal Method: iquids cannot be sent to landtills unless solidified Unusable product and some collected, spent use-dilutions may require disposal as a hazardous waste at a permitted 'catmenustoragerdisposai lacility In most states hazardous wastes in total amounts ol 220 lbs Or less per month may be disposed of m a chemical or industrial waste indlill II company oltluent is ultimately treated by a publicly owned treatment works, neutralization of spent tank-solutions with subsequent discharge to the sewer may c possible Consult local, stale and federal agencies for proper disposal method in your area 1CRA Hazardous Waste Numbers: D002 (SEE ABOVE) SECTION IX - SPECIAL PRECAUTIONS 'recautions to be Taken When Handling and Storing: .tore lightly closed container in a dry area at temps between 40-120 degrees F Store away from strong acids and oxidizing compounds Keep product away Irom skin nd eyes Do not breathe spray mists or vapors Clothing or shoes which become contaminated with substance should be removed promptly and not reborn until lorouohlv cleaned Keep out ot the reach ol children SECTION X TRANSPORTATION DATA >OT Proper Shipping Name COMPOUND. CLEANING. LIQUID iOT Hazard Class: CORROSIVE MATERIAL OT I D. Number: NA17G0 PA TSCA Chemical Inventory: ALL INGREDIENTS ARE LISTED PA CWA 40CFR Part 117 substance (RQ in a single container). DOT Labei/Placard: CORROSIVE SODIUM HYDROXIDE. 1000# NOTICE auk you lor your interest in. and use ot. Zep products p Manufacturing Co >s pleased to be ol service lo you by pplymg this Material Safety Data Sheet (or your files Zep inulacturmg is concerned lor your health and safety Zep oducls can be used salely with proper protective equip;ni and proper handling praciices consistent with label itruenons and the MSOS Before using any Zep product. sure to read the complete label and the Material Safely ta Sheet , a further word of caution Zep wishes lo advise that nous accidents have resulted from the misuse of mptied containers Empty containers retain residue )uid and/or vapor) and can be dangerous 00 NOT pres- rue. cut. weld. braze. solder, drill, grind or expose such niainers to heat, flame, or other sources of ignition, they ly explode or develop harmful vapors and possibly cause ury *ath Clean empty containers by triple rinsing th ' or an appropriate solvent Empty containers st bv .1 to a drum recondihoner before reuse TERMS AND ABBREVIATIONS USED IN THE MSOS BY SECTION ALPHABETICALLY CTION II: HAZARDOUS INGREDIENTS R Carcinogen A chemical listed by (he National Toxicol- y Program (NTP). the International Agency tor Research Cancer (IARC) or OSHA as a definite or possible human ncer causing agent S * Chemical Abstract Services Registry Number - A iversally accepted numbering system lor chemical sub- mces `L Combustible * At temperatures between 100*F and 3*F chemical gives oil enough vapor lo igmie if a source ignition is present as tested with a dosed cup (ester \S. Cenirai Nervous System depressant reduces the activ- ol the bram and spinal cord % ifl Corrosive * Causes irreversible alterations m living sue teg burns) SIGNATIONS Chemical and common names ot hazardous redients t Eye Irritant Only Causes reversible reddening and/or ammanon ol eye tissues OSUR UMlTS The time weighted average (TWA) air- -ne concentration at which most workers can be fixposed houl any expected adverse ellects Primary source* inOe ACGih TLVs, and OSHA PEL $ <TWA STEl and ceiling its) iCGIH American Conference ol Governmental industrial tygiemsts 'ElUNG The concentration that should not be exceeded i the workplace during any part of the working exposure )SHA Occupational Safety and Health Administration *L Permissible Exposure Limn* A set ol lime weighted iverage exposure values established by OSHA. lor a tormai 8-hour day and a 40-hour work week 'PM Parts per million - unit ol measure lor exposure mils S) SKIN Skin contact with substance can contribute lo verall exposure \TEL Short Term Exposure Limit* Maximum concentration for a continuous 15-mmute exposure period TLV. Threshold Limit Value * A set ol time weighted aver age exposure limits, established by the ACGIH, tor a normal 8-hour day and a 40-hour work week F8L Flammable At temperatures under I00*F, chemical gives oft enough vapor to ignite if a source of ignition is present as tested with a closed cup tester HAZARDOUS INGREDIENTS Chemical substances deter mined to be potential health or physical hazards by the criteria established m the OSHA Hazard Communication Standard 29 CFR 1910 1200 HTX Highly toxic - the probable lelhal dose tor 70 kg (ISO lb) man and may be approximated as less than 6 teaspoons <2 tablespoons) IRR Irritant Causes reversible effects m living tissues (eg inflammation) primarily skm and eyes NtA: Not Applicable - Category is not appropriate for this product N/D Not Determined > insufficient information lor a deter mination for this item RTECS* Registry of Toxic Effects ot Chemical Substances - an unreviewed listing ot published toxicology data on chemical substances SARA Superlund Amendments and Reauthorization Act Section 313 designates chemicals for possible reporting for the Toxics Release Inventory SEN Sensitizer Causes allergic reaction alter repealed exposure TOX. Toxic The probable lethal dose lor a 70 kg (ISO lb) man is one ounce (2 tablespoons) or more SECTION III: HEALTH HAZARD DATA ACUTE EFFECT An adverse etlect on the human body Irom a single exposure with symptoms developing almost imme diately alter exposure or within a relatively short time CHRONIC EFFECT Adverse ellects that are most likely to occur Irom repealed exposure over a long period ot time. ESro PEUTLV. This estimated, time-weighted average, ex posure limit, developed by using a formula provided by the ACGIH. pertains to airborne concentrations from the prod uct as a whole This value should serve as guide lor provid ing sale workplace conditions lo nearly all workers HMlS CODES Hazardous Material Identification System a rating system developed by the National Paint and Coating Association lor estimating the hazard potential ol o chemi cal under normal workplace conditions These risk estimates are indicated by a numerical rating given in each ol three hazard areas (HeaMh/Flammobility/Reactivily) ranging Irom a low of zero to a high of 4 A chronic hazard is indicted with a yes Consult HMIS training guides lor Personal Pro tection letter codes which indicate necessary protective equipment PRIMARY ROUTE OF ENTRY The way one or more haz ardous ingredients may enter the body and cause a generalized-sysiemic or specific-organ toxic etlect ING Ingestion - A primary route ol exposure Ihrough Swallowing of material INH Inhalation A primary route of exposure through breathing ol vapors SK/N A primary route ot exposure through contact wiih the skin SECTION IV: SPECIAL PROTECTION INFORMATION Where respiratory protection is recommended, use only MSHA and NlOSH approved respirators and dust masks MSHA Mine Safety and Health Administration NlOSH National Institute lor Occupational Salely and Health. SECTION V: PHYSICAL DATA EVAPORATION RATE, il refers lo the rale Ol change Irom the liquid stale to the vapor slate at ambient temperature and pressure in comparison to a given substjnee (eq water) pH A value representing the acidiiy or alkalinity ol an aqueous solution (Acidic pH = t, Neutral pH 7. Alkaline pH = t4) PERCENT VOLATILE. The percentage ot the product (liquid or solid) that will evaporate at 212*F and ambient pressure SOLUBILITY IN WATER. A description ot the ability ol the product to dissolve m water SECTION VII: REACTIVITY DATA HAZARDOUS DECOMPOSITION Breakdown products expect ed to be produced upon product decomposition or (ire INCOMPATIBILITY Material contact and conditions 10 avoid to prevent hazardous reactions POLYMERIZATION Indicates the tendency ol the product's molecules lo combine in a chemical reaction releasing ex cess pressure and heat STABILITY Indicates the susceptibility ot the product to spontaneously and dangerously decompose SECTION VIII: SPILL AND DISPOSAL PROCEDURES RCAA WASTE NOS. RCRA (Resource Conservation and Re covery Act) waste codes (40 CFR 261) applicable to the disposal ot spilled or unusable product from the original container SECTION X: TRANSPORTATION DATA CWA Clean Water Act RO Reportable Quantity The amount ot the specific ingre dient that, when spilled to the ground and can enter a Storm sewer or natural watershed, must be reported to the National Response Center, and other regulatory aqencies TSCA Toxic Substances Control Act a federal law requir ing all commercial chemical substances to appear on an inventory maintained by the EPA DISCLAIMER All statements, technical information and recommendations contained herein are based on available scientific tests or data which we behave to be reliable The accuracy and completeness ol such data are not warranted or guaran teed We cannot anlicipale all conditions under which this information and our products, or the products ol other manufacturers in combination with our products, may be used Zep assumes no liability or responsibility lor loss or damage resulting Irom the improper use or handling ol our products, from incompatible product combinations, or Irom the failure to follow instructions, warnings, and advisories m the product's label and Material Safety Data Sheet dice Revised 8 91) 00 A 0617?4 CONFIDENTIAL