Document ZL3V1Vx02kkMEg6V3GroveD8

ss PRT Hie OKA1Y2 his g: 1g Study Title "TENNESSEE RIVER VALLEY SAMPLES 6 1733 i Author Mark E. Ellefson Revised Report September 12, 2003 PerfoMErnmviionnmgentLlaLabboroatroray tory Buiing 236.00 925 Bush Ave Spa, WNS5100 Project Identification 3M Environmental Laboratory Stud#y E02-0443 Total Number of Pages 28 _--_mmm Report E02.0443 Ton. RiverVatSamples TABLE OF CONTENTS Listof Tables... ---------- asl SHAY INOMMEON sss SUMMEIY..cses sms-------- [ -- com------------ Test andAnalytical Reference SUBSINGS................... mn" fC ------ ml MOtNOG SUTIMEIIES......cecocv as---- won PrODATDNONy MONOGS......cocorrn smmsmm---- SAMPIOANBSIS.....crr sn csm--------_ Analytical Result ...... ---- mms DBR SUB osm smd SHBSHCEI MONOGS ccc smni2s StatoefCmONeCIInSIOtN crn rmms-------- ListofAHBCHMONS.......c.cocrc sn -- nmi Signature Page... " m------ AttacAh:Amnaelytnictal Method and SOP DEVIBONS ......c...vssrsrvinsnnns 28 AMBCHMENtB:Data SUMMENYTaDIES.....crvrrnnrrsssnsonnniros 80 AHBChMIONCt: SAMPle CHIOMBOGEAS crores 81 AttachmenDt: Sample PrepSheets, Test SubsatndaTenstcSyeste,m Information................230 AttachmenEt: Notes 10 File.............. A ----- IM EmicnmentalLaboratory Page2ar278 ---------------------- ReportE02.0443 Torn. RiverVaseySamples Li oFTs ABLtES Tabl1e. Sample Location,Sample Type, and Analylical Data Summary. .. I Table 2: Characterizationofthe Test and Analytical Reference SUBSIANCES. cv... Table3a. DescripotfFiiosnhTissueAnalyzed i this Study. mmm] Table 3b. DescofrRivierpWalteriAnaolyzned in this Study... smn `Table3c. Description ofRiverSedimentsAnalyzed i ths SGY.....c...uvun wondl `Table4a. FishTissue Sample Preparation Method. cmmmm--_ `Table4b. Preparation ofExtractedCalibration CurvesfortheFish TISSue............... 9 `Table4c.Fish TissueAnalyical Data Quality Objectives. m-- Table 4d. River Water SamplePreparation Method............ mmm-- Table de. River Water Sample Data Quality OBJOCIVES ................crursvrrnsonsnsnne0] `Table 41. RiverSedimentSample Preparation Meod.................wssmmsensec] 0 Table 4g. RiverSediment SampleDataQuality OBJEC ..............rurcvrusseencnd 1 Tabl5e. SampleAnalysis Information. a ---- : `Table 6a. PFOSCalibration Standard Reprocessing SUMMAY .......ouwesommermsn] 4 `Table6b. FOSA Calibration StandardReprocessing SUMMANY ........... nonilB `Table6c.PFOACalibration Standard Reprocessing SUmmary............. wns `Table6d. PFHS Calibration StandardReprocessing SUMMBIY ............ wn Table Ge. PFBS Calibration Standard Reprocessing Summary. mm--_ Table 7a. Cafish ANGIYHCE! D2. corr mmmm----] Table 7b.Large moaundtSmahllmouthBassATBIYICal DBA. .....curcvsurvennnsns 22 Table 7c. RIVEr WaterAMICI DAB. ....ececeveeinesnsinsssiesvss 23 "Table 7d. River Sediment ANBIIal DBta................ moth Table8. Sample Location, Sample Type,andAnalytical Data SUMMAIY............. 25 aM Envonmental Laboratory Pagesal2re _--mm m m-- ---- Tar. ReVeySampls STUDY INFORMATION Requestor 3DaMleELnviBraocnmoenntal Laboratory B9i3d5g,Bu2s3h8.A0v0enue S0t5.1P.a7u7l8,.M47N3655105 SMtaurdkyE.DiErlelcitsoorn 3BiMdg.En2v.ir3o8n.m0ental Laboratory 9S3t5.PBauuslhMANve5n5u1e06 651.776.5405 `Study Location 3TeMstEinnvgiFraocnmietnytal Laboratory B9Slt3d.5gP.aBu2ul-s,3hEMA-N0v9e5n5u1e06 WMialricaLm KA.ndReerasgoenn,,ALnaalbyotriactaolrCyhMeamniasgter Cindy M. Carson, Analytical Chemist OExgpnejreinmkeantKarlupDlajtaonsi:n, Analytical Chemist `SSaammppllee AAnnaallyyssiiss nCotmipsloenti:o2n6: J1u2nNeo2v0e0m2ber 2002 LocationofArchives Aaclcoorridgiinnagltroa3wMdaSttaanadnadrtdh OpreerpaotritnhgaPvreocbeedeunreasr.chiRveemdaaitnhinog3sMpeEcnivmiernosnmpeenrttaailnLinagbooratthoery analyial phase of nis study wil bo archived at tha 3 Environmental Laboratofrory a ong as the quality of the preparation affords evaluation. aM Emicomentl ates Pagoactzre _--mmmm-- Report E02.0043 Ton,RiverValySamples SUMMARY eee `FTisehn,nerisvseerewaRtievre,rannedarritvheer s3eMdiDmeecantturs,amApllaebsawmearfeacciotlyl.ectTehdefsraommptlhersewleorceatainonaslyiznetdhef.or p(ePrFfOlAu)o,ropbeurtfaunoersouolcftoannaetes(uiPfFoBnSy)l,ampiedrefl(uFoOroSh)e,xaannedsuplefrofnuaotreo(oPcFtHaSne),suplefrofnlautoero(oFcOtSan)o.ateThe tahneanlyasneaslywzeirneg tachceommupsliinsgheHdPLbCy-eExltercatctrionsgprthaeylSMaamspslSepseucsiirnogmeSlorlyd(PHhPaLsCe/EESxItMrSac)t.ion (SPE) and m`iSlaemp2l9i6n.g LSoecmaptiiionng1L(oScL+a1t)ionwa2s(SlLo-c2a)lewdadsowancrsoisrseathmeorfivtehref3rMomftachieit3yMnefaacriiFtoyxatCriveeerkmaitlreiv3e0r1 `Sampling location 3 (SL-3) was upstream from the 3M facilty at river mile3075. Analytical results are presented in Table 1: Table 1. Sample Location, Sample Type, and Analytical Data Summary. ETE `SamplingLocation & `Species Sampled [IEEE oi PrHS gig) [a [oe [FooSeA [[oh2 SLA. (n=6) SL2.Cne7) SL3.C (n=6) CERT) Ere] ERT EER <U0Q 100 4100 dl00 <u0Q 609 (ee) 113 (ey oa 10a ion <100 4lo0 di0a <loa _is2(4e <UoQ 4100 <od' <ioa sss <U0Q 4100 <10Q <u00 169 (2. <log <Ll00 dice ----<llo0 loa loa dion <ioa dion ion pT sSLL21.. RRWw SL3, RW GParoms) pPgrmHlS) ePFOmA g[mTtY) (ppraoms) <ioa 400 <lod _ <dica _<ioa log <lioa oo <loo <ioa PFBS [a [ Fosa pros [C2 [ [Cr [CE (9/9) SL2G.eRls 5a377 <1w0oa rdieog d1w sin | 457 EEE ``CS=odCiamteFniissh.,HLigWh as =Largemobiass, SH <uoa =SmallmouthBase, FW 127 = Riverwate, pica value wesstalsticayeliminatedwing Dixons Tes. am 6RS = ver ate wuarmbceraoflFifscrho>mtsLsLcOehQsadNmupmlibnegroofatFiisohnAnalyzed).Onlyone River Water and onaRiverSedimentsample SM Envionmanta Laboratory Page 501278 _--nmm Repent E02.0443 Ton. ver Vay Samplos PURPOSE n"Tdhe PpuFrOpSosien osfptohrits-csatuugdhytsfiosh,pfeirvefrorwamtqeura,ntaintdatiivveerscsreedeinmienngtsforfrPoFmBtSh,rPeHsSam,piPiFnOgAl,ocFaOtiSoAns,of the Tennessee River near Docatur, Alabama. TEST AND ANALYTICAL REFERENCE SUBSTANCES Table 2: Charactorizationofthe Testand Analytical Reference Substances. `Compound EE 3StMorLaagbeorCaotnordyfons Physica Description (Rory PFPeHrSf,uca rohexanesufonate|rPoeseuaorooctanesifroonn-|| ZEPeLorOlruNcraoonctanoals BSiVg.Sp2e3c6i.a2l8y-M1a1laria, | aBiMdSp2o3c6a-l18y-M1a0taras, | 3BiMdSgpe2c3a6l-l18y-M1a0lorak, |Froen [Frozen [Frown | y Light yellowwarysod oes | Undetermined 950% | [rity iat Compound prus id SuPfFoBnS,atPeolassium Perfuorobutane | PPeFrOfSu,orPoootcatsasnieusmufonete 3M Specialty Materials, Big. SM Laboratory denticaton `UWnhdietteePromwidneerd SM Environmental Laboratory Page or278 _--_-- Reporter ossa Torn,Rie Vata Sams TEST SYSTEMS Table3a. Description of FishTissueAnalyzed nthisStudy Fotos: [S[ ourcee ~m ~ essooRver| "Types LaCartgfiesMhouth Bass. Small Mouth Bass eoCo mi Downstream fom te Wi Tacit `(Aicvreorsmsihoe3v0e1)r fomth 3M facity Upstreamofthe SH faciy (river mile 307.5) +The fish were fled and representative aliquots of the filets were analyzed. Table3b. Description ofRiverWatarAnalyzed inthisStudy Ee [Swe_ ont |r . lors eninas Location3 [TemessooRive|r Chiled (approximately C) "Downstream from the 3M facility `Acrosshe iverfrom the 3M faci U(ipvsetrrmeiaemo3f07h.e5)SW facly Table 3c. DescriptionofRiverSediments Analyzed in this Study [Sace ---- l ono s| ne [i omy bisiid TTomemeorve|r Chilled (approximately 4C) Downstream from the 3M facility "Across thfiverfrom the 3M faciy Upstream of he SM facly (iver mie 307.5) aM Enveonmans Labs Pageotare EE Report E020043 -- Ton. RiverVaySamples METHOD SUMMARIES `RTihveercoSnecdeinmteranttisonwseorfePdFetBeSr,miPnFeHdSb,yuPsFiOnAg,SFolOiSdAP,haansdePExFtOraSctiinoFni(sShPTEi)ssaunsd, HRiivgehrPWeartfeorr,maanndce Liquid Chromatography-ElectrosprayMass Spectrometry (HPLCESIMS). PREPARATORY METHODS + TWahteerfo,lalonwdinRgitvaebrlSeesddiemsecrnitbseatmhpelessa.mplDeatpareQpuaarlaittiyonObmieectthiovdess f(oDrQtOhe)FairsehaTlissosugei,veRnifvoerreach `sample preparation method. Fish Tissue Sample Preparation Method Table4a.FishTissueSamplePreparation Method 5 Fis TISUE SAPLE PREPARATION Mi |[21]| Apeplroosmiomgamtln2e0voafsFcish rTisisueagndmiLoofASsTMmTyaipnodi1Weatonesrphwaerrooehrofomnoiogeesnotizemd Esraacuhnhssomiohopog1oh.nno0eiimmtLoon.gwnaoganfsadtaho,molgenaelo edFtoo3FpseRpcaarDatseam1p5mleLs.cTohnwtasiabcgecoso.mpiehebdy Meartis1xs.sp0pkimekedosfw(ihWtoShm)1ow0ge0orunoLaolpforwpar1s0e0Fduanmorsliv.oensreypdoeoasrncohtoohmenorg1ceo5nnatmta.ienc.inoIgnntahtcishecotafsutebeoat.neTashdtodMioSnsal substances. "s50mhLoffoara2c0skimoinnraoitew30an0stenpm.added & heconus bes.Tho boswerocappaendd [6 `speomratmanit.ne camswarscried a306 or 0 ris Gy "Thosupomatantwas Gecantodronow 50TLcartfugetubesanddictedwit40 mLof "WeartoerpslaCc-e1d8oTounvcaicuounmalmaSradplPdask a1n3d,p6r0e0-SoPnEcclioornnodsnwihhaliaocnhegdm7a0nmneLrr.oservors ``mAOLp)np.raomWxohimseatntoemfloty1she0tommefLtihoasfnmwoealishhpaanudoblleowdaatnsopuualglcehd,dmtor0ro1ougwha,clAoelSruwTmaMnssTayanapddoe16dW(vo5a1lc0oumwu)am.swaWedhsdeaepndpt(lh5ed-r.1a0 WVaacsuounmyoathsmaclolalummonu.nTthofewcaoolarmentswertheenroetsleontw,edth1s0i0pdcockwas med 1810pthe [|aIumee0slpsuorhotnstwtaosmostco7lveceodrTsheecoluumnhswefrooaprloocwoendittiodenyadfoEatceaost .miserso . [70[heanaeswero hod romthe SPEcommswith 2.0m.ofmethanolnoauovias. Soa he reparation worksfohroothcretxasctamounts, mes, speeds, ic. SMEnvironmentalLaboratory Paogr2e76 _--mmm---------- sms I Table 4, Proaraton of Extracted CalbrationCurves forth Fi Ts, TRe oerotn omocriadnwPoesSsoocarp bcrAtLsabsnseadndterostC2abO0AoTrCeOS070 TFra otrpa ept e hriecscoe ssravp savirsee alncisde bbFeernoTTaeseo es a [= |] ]A1prp0ronexikmaaotrelly 10 gofFishTissueand 40mLof ASTM oovasvoniorssvwspp Ty pe 1 Waterwere omroribes co mb ine d and | [3 Fahuowasspikedwintheprosotemindsmaurtofspesoon. Tabledc.FahTiss Anaya DataCua Objectives [1|RTAilesaymopwlaessweoorroopprnotpeooonddi4ne5ipcooatfre,oeTmmhoa%RShoDsssh.oyuK obfoo5r2o a54% EsA t BT P o E re lrR .corr ofon se oo Feao h eolr ScrinitkEsT w aconotSeave eSwebeoa TaIa SOOTpo om e mFaaahAa sooBeynn s i, [5[Wc olo corio ngvarwasv] + River WatrSamplePreparaMttihoond Tae46, RiverWatrSamplePrparatohons WnaryeC18rTeenaoeSeao e SE kie teag10amos `Ai pproximeartealyn1t0 rmmLofaeT mreptahsastnoeoloo wamsmanidedomeo edSotoosbtheecr oSerluvTmenisTai3nnedddthae(ivnTatcoarulue)smwwagiHssia1rpnptlio0eerd,. s om barit v Herver pa ons pcos PE To eT I, ramsatzms _---- on szous -- Table4d. RiverWaSampl Propastion Method [3| hoaltoswooots romthcolumnswin 20mi.ofmethanol nk auovie A-- frntaeci eeonrsi ooh Ss S e escbrSterlrostoHrtaac,Woate aorsansodas veer Eo537soacTm or aVAS [3 Nomati spikeswer promoddung hosampleproparation of fo ivrWarsapien + Riv Sediment SampleProaraitohons Tale4, RiverScSiampmlePrnopartaon Method Taa f r vre 3 veeSoianomtefsoe ay eaetien, Teo t So |= rmeT alt ali |`Approximately20gofsedimentand WL Fg oT 35mLof 1%Acetic:AGH (9qUeoUs)werecombined info [s[o4rTiE honovoseasCwTbeurTnoEccaneppcsectvasoSoonmnaamndcTorv.fE noesmSaPkeoonr0emin HGF0eRTdPVTT,OoFLei d sterroee brroorn peRreYpenhprbTrt rsyoaeetrssuhe he oo|bdoa iranld s),rWar eidne18 Te i pn riR oce R aeraa0ee,ny STR oraoemrnaSnohvredweSamoOih.o.e4Freadtdrbce ghtehbtoS$h7racSsooins olePsET rEET [70]TTa hoockoloecrtadvmaostanclwsaseheomadhediowpprroosSmoatnly200mF.EofcAoSrTiM TypTeh1Siaer. Sinem -- _--_--m Report 02043 Ton.River VatSamples Table4g.RiverSedimentSamploDataQuality Objectives a I rT, [+ i sampleswer propareidcialn.ThoKRSDshui bo's25% [2 vM alues, aworeps redi on acha cari.Ror shevi 50%of paced prsTowecodlebsboscaGanoudnsaon]tahSloyadzeamdaswsi,uhgGoterhsnetesseaidmnpgwloefasss,pwiikomeprdowspsrabeiproocrooadr.rocdHovFeoousgphwedhhoaoanfraobrvimsasStoxifvoanmrcwiaaoscn,nhoetd `xaWarttaoecrrtbwolhnaonpnkriso,ececrsosnss,eiwsdteirinagmpoerfwonaapntsaernu.otAtpcrcooofsveponittaebrevuanluTersowueghroh<ee7ntLrLeOprGepfoarratteiodnaaandsatin whichthoywora un. "cTuhroeR.ivVerSievdiemecnalttsvaamtpolnecsuwrverpeoqnuasrwiearlooudsUesidng38a CnoOrV-o.xiaciedSoVert Caloraion SAMPLE ANALYSIS ``TEhnevisraomnpmelnetsalweLrabeoarnaatloyrzyeMdeutshiondg EHTPSL-G8/-E1S55I.M1S."AnTahleysainsaloyftWicaasltmeetShiroedawma,sWbaatseerdExotnratchtes3orM Other Systems Using HPLC-ElectrosprayMass Spectrometry" oTfheeafcohllsoawmipnglet.able details sample run informeion, including the sequence and the run start date Tabl5e. Sample Analysis Information. Catfish [ ss 1owe| omic | Large Mouth Bass [2| Smolmosbass| s3 | ooeoozs |osunce | [set RverWeter || Tsl2 | ooweiz | | ouaetz | vzanoz | 2mgoz | RverSodments [Sz | 212 [12Nove| wet | f2Novoz | w2tiz | ioNeve|z SMEnvironmentsLaboratory Page 1101276 _--_---- Repo 02043 Ton. RiverVay Samples ANALYTICAL METHOD SaOmthpelreSyasntaelymssisUswiansgbHaPsLeCd-EolnecEtTrSo-s8p-r1a5y5i.M1as"AsnSapleycstirsoomfetWrays'.teMSettrheaanmo,lWeaxtterarctEsxtwrearcet.s Or aPnFaOlySzeledvuelssinwgerHePLevCaIlEuSatIeMdSvienrtshuesnceagliablriavteiojnonstmaonddea.rdsPFrBanSg,inPgFiHnSc,onPcFenOtAr,atFioOnSfAroamnd1m10i0z0= n4g13an(alPyFtOe/Am)L,..mzTh=e4t9ar8g(etFOfSonAs),wearnedamszfo=lo4ws9: m(PzFO=S)2.69T(hPeFaSna)l,yimic/azl=me3t9h9o(dPFuHsSe)d, fionrdiavniadluyasliisnsistrpurmeesnetsn.ted below; modifications may be necessary to optimize the method for AnalyticalEquipment ALniaqluyitdicCalhrcoolmuamtno:grKeaypsht:onAegieBnettHaaswisTMtC-Psa2cxk5a0rmdm,SeSruiemspa1r1ti0c0leLsiqiuzied Chromalograph system CCyoclluemTnitmeem:p9e.r5atmuirneu:t3es0 C FInljoewctriaotne:vo3l0u0mueL:i4mitno 20uL MobSiollevpenhtasAe: c2.o0mpmoMnenatmsm:onium acetate in water Solvent B: HPLC Grade Methanol Solvent Gradient: 0Ti0m0e #08% 005800 6100%% 355500 110000%% 695500 1100%% MSoafstwsarSep:ecAtgirloemnettCehre:mASgtiaetinotnHe~wAl.e0t8-.P0a3ckard Series 1100 APUMass Spectrometer Detector Fragmentor Voltage: mm/zz239099== 112000V mmilzz 44918.3== 1800V0.V miz 490 = 140V CGaapilnl=ar1y.V0oEltMagVe: 4000 V MGoadseT:eEmlpeecrtartousrper:ay3N5e0gatCive NDerybiunigzGearsP:re8s.s0uLre/:mi3n0. psig Analysis Type: Single lon Monioring (SIM) SM Emvionmenta Laborstary Page 1201276 --_-- Repon 02043 Tom. RiverVaySamples --_-- ANALYTICAL RESULTS Dataqualityobjectives outined in the Preparation Methodsseciion were met. Reigmrpersosveioqnuasn.iaQtuiaodnraotviecr tchuervceonfictewnatrsataipopnlireadntgoecaalpipbrroatpiroinastttaondtaherddsataa.ndAsllamcaplliebrdaatitoanfo curves had least-square fis of 0.990 or greater. + Cv1ao0ll0iu0bmrneaotfigo1n0SwuteLar.neduIansresddso.mfoerSittnhasentdcaaanlcriedbssr,arttiahonengi1cn.u0grvniengsci.omnLTchesnettarsnatdtaainroddnarwfdaroscmuiranvjpeepcrptooeixdnitamstathsemaladylla1en.r0ivtnoojleuctmieosn. (c1u,r2v,es2nwder5eurLu)n hbeifsowraesevdeornyeantaoleytxitceanldsethqeuelnocwee.ndPeorfctehnetcdaelviibarattiioonnscoufrveea.chCaclailbirbarattiioonn tsatragnedtacrodnwceenrteractalicounlawteerd.e eHxicglhu-deenddfcruormvtehpeociunrtvethcaatlcwuelartoioonust.sidLoowt-heand2c0u%rvcreipteoriinatsoftthhate wLeorweerouLtismiitdeofthQeu2an2t0a%ticorinte(rLiaLOwQe)r.e included in the curve calculations but excluded from the ComnatriniucialnigbraCtailoinbcrhateicoknwVaesriafniacaltyizoend(aCiClVe)a.st Feovrerqyuatnotnitsaatmivpeledestetormmionnaittioornsi,nsatrmuimde-nlteavleldri, witha mit of 20% deviation of the terget concentrations. + cLaoliwberratiLoinmicturovfe,Quwainthtiataletvieolnof(aLcLcOuQr)a.cyThwiethLiLnOQ20w%a,stheaqtuadlemtoontshterlaotweedstasrteasndpaorndsngrtehaeter than two times the response of analyte in the blank samples. + ScaylsibtreatmioSnuictuarbvileittoy.mFeiavseusryesttehme-spurietcaibsiilotnyosfttahnedarertdesntwieornetiamneaslyaznedd pbeeafokrasreeaa.chTihneital precision criterion of 5% for the mean area recovery was achieved. LianfborCmoanttiornolwaSspinkoetsu(sLeCdS)b.ecLauCsSestwheeraetpaersfuogrgmeesdtefodr itt hweaRsiviemrpoSsesdiibmleenttos.recHoovweervsepri,ktehde analytes from acidified water when river sediment was not presen. + ShMiaestdricimrxeitnSrtpii,skaempsl(eMsS.).DeMsaitriabxlsepmiaktersixwosrpeikpeerrefcoorvmeerdiefsorartoheF3i0s%h.TiNsostuealal nmdattrhiex sRpiivkeres met `aTnhde RFiivsehrTSiesdsuiemednattasawmapsloqusawnetriaetqeudaunstiinagteadnuesxitnrgacutneedxtcraalicbiroadticoanlicburravteiown hcuirvetsh.e RTivheer Water cdiaflfiebrreadt.ionThcuertvaeblreasngtheatthfaotlwloawscoinntjeacitnedeiwthaesr tfhreomca1iinbgra/tmioLntsot1an0d0a0rndgo/rmLth,ebsuatmtphleeraprnegpearuasteidon `almoentghowdiLhobwaetrcLhiumisteodfaQnudantthietaatniaolnys(iLsLdOaQt)e.foTr htheesaanmapllytoepsrfeoprareaatcihonsammeptlheodatLeLaOcQhSlowcilaltiboon annotated in the tabs. IM Envionments Laboratory Page 1301276 _--_--_--m wns amr i. 708Calbrtinstr pcaarny o[nao r mmo |stowa| E[CEomTes| mwmearne | ow | [imonim53] omen sans |roms [mmm | mae| mw] [CT reer s |o rmrni crs| ET E e EA -- sa _--m---- mts om is -- SmI s |mwm|asawe| [[mCommmar | momaao smee|| m osowm]] [[mimnmo | z| ommensaanoee | ssoowmse || [r[oe m ev ne |ems n | Ia rs es _--_-- I I or m---------------- |om | omemaie| rrr sow | [[oemeasr|| ommmmmoenwee awmw [[eimmmmao e| r] oommensoavmee || soowws]] [[mommnmias|m ] ome omnen |isom]| [ [rve|eov on omeeninm e |s |iimoemnn s]] [Commas| oom nae |v] om -------------- RS ot _--m mm----e-em e,e ----m nt en et Tas. pr cartonsnr presi sry C cms rE r ---- a [mmmas] ommre | ows] mr| ownome|im] [mmm | meee| wows | [wom | omios | wows]arn -- ra _--m--mnmm Mr nti -- I ---- EE ~ TIT Crm |ommm|asnom a| [ems| ommane ew [[iomrmmo ms[ |i mo s m n ni | romss [revs| om enne| imw | wr ES a uo trams om -- --_ Report E02:0443 "Torn.RiverValley Sampls Blanks. Memtehasoudrebloafnmkse,thMioldlb-aQcwkagtreoruntda.kenInthtrhiosuegxhptehreimseonlitd,pthhaesyewoerxteralcatbieolnedpraosce"sWsE,"p.roOvniedesdeat wfuanswpirtheptahreeCdatfofrisehascahmlpolceast.ionA.ccIenptthaebFliesvhaTliusessufeorpotrhteiobnlaonfktshwe eexrpelreismsentth,atnh5e0y%weorfethe Lower Limit Of Quantitation (LLOQ). All method blanks in this study met tis criterion. ThcaretriFdigsehs.TisTshueesseewgemreentloabfetlheed aesxp"eSrBi"meanntdaclosnosicsotnetdaionfemdemtehatnhooldtbhlaatnwkassfourstehde SfoPE ebxltarnakcst mpreet-ctohnedpirteivoinoeudsccorlituemrinosn.that did not have any sample added. Al of these method Soclovnteanmitnabtliaonnk.siMAectcheapntoalblbelasnoklsve(nmtebtlhaannkosl miunjsetctcioonnst)aipnrolevviedlesdofa tmaeragseturaenoalfyitnesltersusmtehnatn t5h0s%croiftterhieonLoewxceerpLtimtihte OfoflQlouwainntgi:tation (LLOQ). Al of the solvent blanks in this study met Nthoetecr-itSeorliaveanrtoBnloatnrkesctohradtewdebreolobw. etfheoSyrstoemSutabiltyinjectionsanddidnotpass 0we2r0e6c2a6useexdtrbayctceadrsraymovpelrefsr0o0m5h0ig(hPerFBlSev,elPFstHaSn,daarnddcPurFvOeAp)oianntsd.00T5h1e (soPlHvSe)n.t blTahneksse that were run after these points showed minimal camyover. wDa0s20c6a2u8sesdambpylcear0r0y5o1ve(rPfFrBoSm,tPhFeHhSig,h-alnedvePlFsOtAa)n,da0r0d5c2ur(vPeFHpoSi)n,t.anTdh0e0s5o3lv(enPtFHbSl)a.nksThis that were run afer showed minimal carryover. D(P0F2H0S6,29PFsOaAm,plaensd0P0F5O9S()P.FHTSh,isPwFaOsA,caFuOsSeAd,byancdamPyovFer fO0r0o6mS0h(iPg)hF-OlSe,v)e,l astnadn0da0r6d1curve poonintthse. quTahleit0y0o6f1thMeedtahlaa.nolThBleannekxthasdaampsliegnhifaidcatnrtalceevaelmoofunantaslyotfeasnabluytttehiasnhdawdansobeeflfeocwt tshaempLleL.OQThfoer anlelxatnasloyltveesn.t bTlhaenrkef(o0r0e6,7)thhea0d06no1mMientahlaannoallyBtleacnokncdeindtrnaottiionn.fluence the D(P0F2O0S7)0,2 Tshaimspwlaess0c0a4u2se(dPFbOySc)a,rr0y0o5v9er(fPrFoHmSthaenhdigPhF-OlSev)e,l0s0t6an0d(aPrdFOcSu)r,veapnodin0t.061The solvent blanks that were run after showed minimal carryover. cDa0r2r0y8o1ve2r(4f)rosmamhipglheesr0le0v1e6l s(tPaFndOaArdancdurFvOeSpAoi)ntasndor0s0y3s1te(mPFsOuAit)a.bilTithyepsoeintwse.reThcaeussoeldvebnyt b(lPaFnOkRs)thaantwde0r0e39ru(nPFafBtSe,r tPhFeHsSe,poainndtsPsFhOoAw)edhamdinciamrrayl-coavrerryforveorm.saSmeplmepsl.esSu0b0s3e7quent blanks showed minimal contamination. 1003231(1F1O2SsAa)m,p0l6e6s, 0(1P2FO(APFaBnSd,FPOFSOAA),,a0n6d8F(OFSOAS)A,),0a2n7d(0P7F1BS(,FOPSFAO)A.,aAlnldofFtOhSeAs)e,can be attributed to carryover from high-level standards or samples. IM EnvironmentalLaboratory Page 1901276 Report E02.0443 Toan, River Valley Samples DATA SUMMARY aTavbelreasge7ad,at7ab,fo7rc,saamnpdl7edgrporuepsse.ntRtehperdeasteantfaotriivnedicvhidruoamlastaomgplreasm.s aTraebplree8sesnutmemdairniAztetsacthhement C. sTaambplleess.7a,A7lbs,o7icn,claundded7dardeistphleaayvtehreaogne-ccoonlcuemnntraantdiocnosrfroerceteadchcosnectenotfrsaatmiopnlsesforstiannddivairddual dceovriraetcitoend, faonrddi%lutCiooenf/fciocniceennttorfatViaorniaftaicotno,rwshientnroadpupcleicdadbuler.ingThseamfpinlael vparleupearsarteipoonratenddabryeinjection v`soolmuemoeftdihfeferseanmcpesl.esTwhiethirnepaorgtreoduvpawleuresew<eLrLeOnQo,t athdejuasvteerdafgoer MvaatlruiexfSopritkhee Rgercoouvpewriaess.calWchuelanted uTshiengabtbhreevrieaptoirotnesd aarnaelyatsicfaolllvoawlsu:eSfLor--saSmapmlpelse>LoLcLatOiQona,nCd--thCeatLiLsOh,QLvMalu--eLfaorrgseammopultehs <baLsLs,OQ. `SM -- Small mouth bass, RW -- River Water, and RS - River Sediment. IMEnvironmental Laboratory Page 2001276 _-- Report 02.0643 Tenn, RiverValleySamples Table 7a. Catfish Analytical Data. 42rT| SStiicCrz|1 wSw40o0a|] SwwOoQa || w1i0oaa| | 08399 sa w5g07 55 SSTt.iCc2i1s|| alocaa|| awooaa| [ooaa|| s424 us2s0 SStiiiccazsz|| aacoaa|| wwoooa|| awcoaa|| 3429 saon7 SStiac.caez1|| sticas| aaolao|| aca| wwoaa|| woo | waooaa awa | [[7740 74 770058 738 sS4i.icc4a1z|| a4t0a0|| sticas| soa| wooaa|| wteoaa| ico| ica| a[37s 38 837 2 TET| SSSLiiTai.ccCeeess1||| waalooonaa||| iicooaan||| SwLiioooaaa||| eent ss %5710 gs Te SSLir1.cceesl|| Siices| aawooaa|| dica | taooaa || wo| o<iaoa | wioa | s[7s0 70 we1 es SSSttZazccCiiaz||| 1di0o0a|| aioe| ooaa|| wuoa | <wiooaa || oa| waood aioe SSCtZacCa212|| Staczs| a1i0o0a|| dca| ooaa|| woo | w<woioaa || wea | w<teoa0 aioe sSLiZaCcoe12|| Suzcas| a4o0a0|| aca| w<io0ag|| oa | wwiooaa || wwoa| w<oag aica SSSiUtzZaccC4ae1zs]|| aaawcoaaa||| i<wicooanq ||| aaSrricoooa||| <wLeoag won TE| sSiz2cGsorz|| Si3ces| w<iotoaa|| aoa| w<ioona || ica | 1wi0oaa|| Sica| <ona wica sSCi2zccee1z] | Sis ces| waoona|| arco| wdoona || ica | wooan|| woo| wtoona ica SSCtt2az6ce77r2s|| daaiocvaaa||| iicooaae||| wwwwooonaa||| aatioooase SsSitas3iccrrrsz||| aa4o0o0aa||| w<wi0oo0aa||| lwooaa|| Sica | <wtoaa Gio Te| SSL3a.2C221|| St3cas| amooaa|| <uoa| iioon || ica | wiicoaa|| arco| w4rooea wica SsStLi3a3Cc8aa31z3||| "<<wwooo0oa||| aadiiwocaaa||| <wiec0aa||| ia<wiciooaaa TT| SSLia3.cca4z1|| Stacas| aIioona|| aca| ooaa|| oa| w<iooaa || wuca | awooaa win SsSLia33cCcs6s?1s||| aaAcolaao||| wwwo0oo0a||| w<1o0aa || awco | <o0a ico SSLi33.cCee?1|| Staces| adlooa|| aca| w0oaa|| wioa | w<o0aa || Sioa | w4o0oa Sioa EaI iE] ) 2 06 esaisn|| 110003 0073 ssmme 2G6a0 | s[ezs 4% | ss s5i7s5 7o7s 1 53% iisrs || miesr 26x| 102 m0o7a is s7er wow iSi | 2 Twies aTmo swuss| t[eers 1s | 80 i280588 02 27095% I awzs | [v5e9 575s5 a51m oosux|| esoo 558077 10057% iEonne Pireo: iooan ooaa Twoon "wioaa woeoa g"irceay awioae wp"rirod)a 1T3S is 1T8S7 2775 60 60% 121 12 T1iss 22 a0TIdTT ppoereae) 3357 io 3851 wh TT2Tw 00a8 tooaa 23 25 wT 23 22 3MEnvironmentalLaboratory Page21ct278 -------------------------------------------------------------------------------- Report E020443 Tonn, River Valley Samples Table7b.Largemouthand Small mouthBassAnalytiDcataal. a. d Fon NE " FR gia) 9 gi) ing) SstLiiLmi2| oLLaOQ|| <LLoOaQ|| <we0a Siva| aoa| <tica| sic Sawooaq | [wTeos eweos 25821 aoa | eo wer dos SSLUivzmeez|| aarooan|| <<ioaa|| aooaa suiimes| soa| <ioo| aco Twooaa | [emse wwoa | sz 8e6mso ez ssoerie SSSCCCiiOwwsaTsz||| i<<i0coaaa||| owiwaooaa||| w<wiooonna ioTocaaa || mm[risz esTEwrsr ao7mm5e SSivi4we1z| i[4c10a0|| awwrooa| [i"eosn as | Tooa | T 77 CT wo m70m0 sutuwas| aco| aoa| woo a(@omienatod woo | ess ess 15% SSCTimMwesTz|| <<w0oaa|| <tuooaa|| wtooaa SUimss| aioa| suca| wioa rooaa | s[dsee aemsos 2p0r0)3 oa | swe mr o2% SsiCamNmeTz || siiowes| dooaa|| qica| a<tooaa|| suoa| d<wiooa aio Mwooaa | <woa | [swmse eso s6m8n7 ew a7=r3)m%s SSiizziMwai1z|| stzowts| aalooa|| swoa| <mooao|| coo| waooaa aca wroaa|| <Lo0aa wwoa| ion SSUZziMmza1z|| i4Io0aa|| <oaa|| <woia Sia ima| arco| ica| aio rwooaa| ai[2c8a 5 wwoa| aica SstZziMmostz|| 0<w0oa|| <<o0a|| awooaa SLzmss| aoa| ica| aio oacaa | v[i87s coq | ss w7ie 87 ie0eer SSSCitZ zaems?||| 4ar0ooaaa||| ooaa|| ion| <ooaa suo aIoa | si <iog | sss sseeees 22m Sr Sssiiessiiamrssz||| s4w0oo0ao||| oawioaoaa||| <aStioocaaa ri<ioooano || [datioocaae SsCt3aMm2a1z| [d1o0aa|| awooaa|| <wweoaa Sts mes| rca| <i| aica <Siiooaa | i[coaa <ioa | dion SsCt33omsy2|| wiooan|| <wo0n|| <wwoiona Si3imss| aroa| <tioa| wo oSiaon | [aooaa <uoa | aica SStL3aiDiWaTz|| St3.oues| a<Looaa|| awoa| liocaa|| wioa| <wtooa awoa arooaa || <iicoaa suca| wica SSLC33OoMw5s1z| susumss| <[1i0o0a|| sion| 4ai0oaa || ica| w<ieoaa woo aorao|| a<iooaa woa| ico SSSCtt3saO.twwwese1sz||| <awi1io0caao||| aaooaa|| swoa| w<woiona wica oroaa || owiase Sioa | aica SSCC33oDwMrTz|| sUs.wrs| a<wiooaa|| ica| awwooaa || wwoa| iwooa aca dooaa || <tooaa woa| ica SSta3si5iz|| staswrs| a0o0a|| Soa| a0o0a|| aica| w<o0e dion owwwoaoaa||| iawiioocnae WM Environments Laboratory Page2201276 sev en vr -- = 8 e a= (u SLaisz == BI ET ishi [ar ---- pNa E sy hind Rr a at == EC I S oa E = L E 5B B 0 |aa ET T E TT ) {ngimt) fe) re) pny B zE E I | e L u= n = --- 2 pS u RL csaS toSE r sername _-- ---- ------ e ee ee Report E02.0843 Tenn, River Valy Samples Table7d. RiverSediment AnalyticalData. oi [OC 036404s6 || s2e000aa4z4iSs1Li,t 11008s Vol (0g) 5a33 [rey 55500 aT 5417 0so3us ||3s00s4o5a1s,s5st3t 15305 a1 3045 |300452 5L3 83 a owrex pid rr=y " Seo0o4k5e | [s3p0o0a4s5y-1s50a2 15050 5i0s 046 | 30046252 52 31 a0r2 0 1o0r% 17 s330s40 | 30S0a4m8o352 On C1o7lumn AdjustpeHd]for ny Adjusteda3for Sample Average.SiStd Dew MSE a Jr o38u04s4 || 3300004444-21,5SL11 2257 113% CE138 2 and YC13V.0 (pig) 5 otouos eois | | [sReoass s3| ois2sts| a2o5a <ioa oi2a oa w1o24n oa prsxey oa Sooios ||Weo0uesTs.sStLs2|| Laouoaa Jie | oaezsiz| woo <000 oa Taooaa Sioa "wtoona oa so0is | saEnsTaTsal ico E Sioa E <iioo PreT) E us 36044 [ne | 30044-1501 E 62 y 3 3044 | 30442501 1 71 prey B1(0py) 708 E75R2 AT] oroofi | 0r0i4t15)3 oaa7 IEtr)) 3045 | 300452813 28 13 oEsre 130 Toa% <ioa SSoouos || 0wo0u6s,s5is0i2s]| atooaa aoloao ou |wouezsi2| wo oa aoloao woa 0to0a ica soi | se0ies sa] dion oa prey Sioa RI [rire 380041, 5U1 77 ph 148 360442 SC 24 162 [rako i818 E3ro By 04s |330s004u541s,,5SC31 224s 30045 | 3s0452 513 12 2083 0s i223 i 2 S00040s ois || | 0030844066-4152,35s51L232 7197 23 0185 13 T8as 128 1E8i}% i 32045_| 300463 SC2 hwios | Swe 32 eOn Crolu)mn ie Adusptedyforin Adsicd io for Sample re Awrago 2S%ti Oc Eon 333000404444 ||| S330o00044-e41s2, SsSUUL1 5o30r4 285318 332851153 3i51052 004055 ois ||330000445521,5U33 | 304s sU3 81 1 aTasss pr3weo1s2 1aei%se 3o0d4e6 ||33000045416,255122 eos | sso4s3st2 5805 105 2Ts 53 5is 25 1w=r% `Summafroirtehse average analyte concentration per sampling group and location are given below. IM Envhonmenta Laboratory Pago 2601276 --i -------------------------------------------- Report 020043 Ton.River VateySanpies Table 8. Sample Location, Sample Type, andAnalytical Data Summary. ET `4SSamppelciinegsLSoacmatpiloend [PSEFECBTCSY (ngoigy) tngigA [ os ors FEE <oa <0 <UOQ 60.9 (887 113 (6l6 SL2.C (n=1) <uoa Loa oq <0 <ioa ERY <toa <0 oa <loQ 15.246] SLA. LM (n=6) SL2. LM (n=) toa <a Loa <oa <Lioa' <oa <loq 853 (6/6) <loa 169 (214) SL3. LM (n=7) oq oa toa <Loq <0 rE <Lioa <oa <Lioa <iioa Loa River Water FEN sL2.RW SL3.RW ey PES ey [ee PFOS ee ee [rene Lo) (pgimt) 84 196 550 25 491 "oa <0 <woa <ioq <oq iio Loa oa <ioa <oa River Sediment PrBS [a ey ey PFOS [2 [2 [ [ [2 LEE 517 130 732 1440 3130 sL2.RS 437 <Loa <oa 141 457 EER C= CatFish, LM =Large 4s2 mou Gass, <oa SW =Small mouthbuss, R1N27= Riverwataer,d8RS = RiverSedime4n1ts6. Hliguh rmplobcfaiFeivsharl>ueLwLaOsGsNtatiusticamolfFsiabmhinAaneiaeldyzuresidn.gOrDilxyoor'nseQR-iTveesrtWater andon RiverSedimentsamplewere cOllacied from aach sampling locaton. Attachment B contains additional data summary tables. STATISTICAL METHODS v`Satraitaitsitiocnalanmdetshtaotdisstiwcealreexlaimmiinteadtitooncaolfcuolualtyiinnggadvaetraagpeosi,ntsstaunsidnagrdDidxevoina'tsiQo-nTse,s%t.coefficient of IM Environmental Laboratory Page2501276 orree-------------------------------------------------------------- Report 02013 Torn. RrVateySamples STATEMENT OF CONCLUSION Fish Tissue: FFiisshh iissssuueo oobbttaaiinneedd ffrroomm SSaammppllee LLooccaattiioonns12caonntdai3nceodnqluaainnteidfiqaubalnetilfeivaeblsleofleFveOlsSAofaPnFdOPSFOonSl.y. River Water: WPaFtOeSr. fWraotmeSraombptlaiinngedLofcraotmiosnam1pcloentLaoicnaetdioqnusan2tiafniadbl3edliedvenlostocfonPtFaiSn,quPaFntHiSf,iabPlFeOeAv,elFsOoSfA, and anaiytes. River Sediments: RPiFvOeAr,SeFdOiSmAe,ntaonbdtPaiFnOeSd.atRSiavemrplSeedLiomceanttioonbt1 acionnetdaaitnesdamqupalnetiLfoicabalteiolnev2elcsoonftaPiFnEeSd,quPeFniHiSf,iable l`qeuvaenltsifoifabPlFeBlSe,velFsOoSfAP,FaBnSd, PPFFOOSA., FROivSeAr,SeadnidmPeFntOSo.btained at sample Location 3 contained REFERENCES 1. 3SyMstEnevmisroUnsmienngtaHlPLMCe-tEhloodctErToSs-p8r-a15y5M.a1ss"SApenciarloomfyeWlsarysitse Stream, Water Extracts Or Other LIST OF ATTACHMENTS AttachmenAt: Analytical Method and SOP Davitions + Attachment B: Data Summary Tables. + Attachment C: Sample Chromatograms + Attachment D: Sample Prep Sheets, Test Substance, and Test System Information Attachment E: Notes to Fie REPORT REVISIONS TTyhpeognruampbheicralofefrirsohrssafmorplteheduantieadceshilgoncaattoirosnfwoarsTaabllseos1ad,d6e2d-1,6 7Taa,bl7ebs, 71da,nadnd8.8Twheeredecsocrrriepcttieodn.s ohfotshee rseapmoprltiendgnlotchaetiEonntsriwxerreepoardtj,uJsutle,d 2in00th3e(psruojmemcatr#y17a8n4d01n).tabRleesmo3av,e3d,twaondva3lcuetsofeofriPecFtHS iPnFfOivSeriwnaftiesrh aitn tsaabmlpelsin1galnodca8tiboencsa2usaendth3eyanwderPeF<OLALOiQn.sedRiem-ecnaltcautiastaemdplaivnegralgoceatviaolnue3sifnotrables 12nd 8 using LLOQ values for samples < LLOQ. MEmonment Laboratory Page 8276 Repo 02043 eee Tenn. Rover VoySampes `SIGNATURE PAGE We certiy that this reportisatrue and complete representationofthedata or this study: << Eefson, `Study Director 2g [12 fpz Date ez Wiliam K_Reagen, Testing Facilty Management 0123 Date MEnvionments Laboratory Pogo 270t276 C-- e---------------------- Report E020443 __. Ton River atey Samples ATTACHMENT A: ANALYTICAL METHOD AND SOP DEVIATIONS SM Emironmentl Laorstary Pagoasotzre Reon E020843 A ---- Torn River Vay Sansios `Document may be used,if current, for 14 days from 11/21/2002 33E MM EN NVIV RONMI ENTR ALLLAAO BORN ATOM RRYY ENTAL MeTHOD ANA OFWL ASTY ESTRS EAMI ,WATSER EXTRACTS OR OTHER SYSTEMS USING 'HPLC-ELECTROSPRAY/MASS SPECTROMETRY Method Number:ETS-8.155.1 AdoptionDate: {1/0 / RevisionDate: S/30/(0( Author: MarkL. AndeMarrksE.oEllnefs,on Approved By: plz -- Laboratory Manager L oly Date /3io0 fo) M Environments Laborstory Page 2901276 Report 02043 Ton.RiverVatey Sapes Document may be used, if current, for 14 days from 11/21/2002 10__ SCOPEANDAPPLICATION 11 Ssycsotpeer:usTuhsiisngmeHtPhLCo-dedleseccrtirboessptrhaye/amnaaslsyssipsecotfrwoamsettersy.tream,watersamples orother 111 Sstpaencdiafridc(asn)aalyntdeso,thieornsp,amraatmreitceerss, swiolllvebnetsd,efsoilnuetdioinnst,hqeuparloittyoccoolntorroltsh,eisnatmerpnlael preparation worksheet(s). 12 Applicable Compounds: Electrospray ionizable compounds. 13 Matrices: 13.1 WsyasstteemsSotrreaasmdseasnidgontatheedrisnysttheepmrsomtaocyocloonrssiastmopflaepqrueepoaursatainodn/owroorrkgshaeneitc(ss)o.lvent 132 WsaotluetrioSnasm.pTlheesmiantcrliuxdewitlalpwbaetedre,fginreodubnydtwhaeteprr,owtaocsotlewoartsearmapnldeoptrhepearraaqtuieonous `worksheet(s). 20 SuMmARYOFMETHOD 21 This method describes the analysisof electrospray ionizable compounds, using HPLC- seelleeccttrioosnproayfamsaisnsglsepeiocntrcohmaeratcrtyer(iHsPtiLcCo-EfS/pMarSt)i.culTarhecoamnpaloyusnids.isperformed by the mass 30 _ peanmions 31 qAutamdorsuppholeersiycsPtreemsssaulrleowIofnoirzvaatriionou(sAmPe)t:hoCdosmomfeirocniiazlatliyonavbaiyluatbilleiHziPnLgCa-vaErSi/etMySosfingle sIoounriczeast,iporno(bEeSsT),,anAtdminotseprhfearciesc.PTrhesessueriencchleumdiecbaultIaorneinzaottiolnim(iAtPedCt)o,:ETlheecrtmroosspprraayy, et. `vTahceiuounmi)z.ationintheseprocessesoccursatatmosphericpressure(i,notunder a. 32 `Eplreescsturroe,swphrearyeIboyniizoantsiionns(oElSu,tiEonSDa:reAtramnestfheorrdoedftiootnhizeaglaisopnhpaesrefvoirmetdinaytcahtamrogsephderic: droplets. These droplets are produced by the application ofa strong electrical field. 33 siMnagslseSqpecutroametdmearsr(sVsSeu)l:ecCtpoimvemodeertcelicatloelrys.maTnounfsaarcetsuerleedcMteSdosnytstheembsasairesoefqumiapspsedtoith charge ratio (w/z) and subsequently detected. 34 MspieccrifoimcaospserMataisosnoLfyannx /HPHLPC-ChEeSm/SMtSa.tiPolneaSsoefrtewfaerre0: Sthyestmeamnusaolftfwoarrtehdeesspiegcinfeidcf:orthe instrument software. SMEnmonmeo Laborer WM Envronmertal Laboratory wns Fst Peszaro Page 001276 _-------- Rogert E20443 Tenn. RrValey Samples Document may be used,if current, for 14 days from 11/21/2002 40 WARNANIDCNAUGTIOSNS 41 Health and Safety Warnings: 4.1.1 tUhseepcraoubteioenmpwiltohysthaevvoloagleocfatbalpepsrafooxrigtmhaeteeellyec5t0r0o0spVroalytpsr.obe. When engaged, 412 aWnhdeenyehwaenadrl.ing samples or solvents wear appropriate protective clothing, gloves, 42 Cautions: 42.1 bOapcekrparteesssuolrveeenxtcpeuemdsp4sb0e0lboawr,tahbeacPk1pr1e0ss0uwrieollfi4n0it0isbteearu(t5o8m0a0tipscis)h.uItfdtohwen. 422 Do not run solvent pumps to dryness. 50 INTenrRences 51 Tstoomriagneiomriazneyipnatesrtfoefrienncsetsrwumheenntaatniaolnytzhiantgcsoammpelseisn,coTnetfalocntswhiotuhltdhnesoatbmepulseoerdefxotrrsaacmt.ple 60 Equipment 61 E`quimpmeontdlisitinedtbhfeelroaiwwmdaactyabaaesmmotedtihfiioedddoeivninaotridoesrns.0optimizethesystem.Documentany 6.1.1 eMlieccrtoromsapsrsayPliaontifzoartmioLnCsZouMrcaes.s Spectrometer (or equivalent) equipped with an 6.12 HP1100 low pulse solvent pump,solventdegasser, column compartment, and autosampler or equivalent HPLC system. 70 SurruesAND MATERIALS 71 Supplies 7.1.1 Highpuritygradenitrogen gasregulated toapproximately 100psi(orhouasier system). 7.12 HsiPzeL)Coraneaqluyitviaclaelntc.olumn, sausacBetahsil C18 column (502mm, 5pmparticle: 7.13 Cappedautovialsorcapped 15 mLcentrifugetubes. 80 REAGANEDSTNANTDARSDS 81 Reagents: 8.1.1 Methanol, HPLC grade or equivalent. 3M Emon Libor AisUsoHPLC.sBaies)y pecomety Lr 3M Environmental Laboratory Page 31 of 276 ----ee ee ---- Report E020443 Tom. River Vatey Samples Document may be used, if current, for 14 days from 11/21/2002 8.12 M`wialtlerio-QTMeqwuaitvealre(atA,SaTnMd mtyapyebIe)palrlovwiadteedr ubsyeadMiinltlhii-sQmTetOhCodPlsuhsouslydstbeemMoirlli-QTM `another vendor. 8.13 Ammonium acetate, reagent grade or equivalent. 8.13.1 When preparing different amountsthanthose listed, adjust accordingly. 8132 `2a.m0mmonMiuammsmcoetnaituem.Paoceutraitnetsoolau2ti0o0n:0WLeviogluhmaeptprriocxfilmaastke,alydd0t.3h0e0 g aSptporroepraitartoeovmoltuemmpeeorfatMuirel.li-Q watmiexurnt,il allsoalrediissdolvesd. 8.1.4 Optrheeparrsaotlivoennwtosraknsdhseeotl.utionsmaybeusedassatedintheprotocolorthesample 82 Calibration Standards: 82.1 TyopfiScsaolllveynttwsotamnedtahrdosdabrleaannkasl(yMizleldwi-iQtwhactaecrh),gtrwooumpaotfrsiaxmbpllaensk.s,and aminimum o90TSAMrLLiEHANDLING 9.1 cSetnatnrdiafrudgseatnudbepsreopraortehdesrasmupitlaeblsemcaoyntbaeinsetrosreundtiinlcaanaplpyesidss.utovials,capped 15mL 92 `Ifaapnparloyxismiaswteillylb4edCeluanyieda,nsatlaynsdeasrcdasnanbdeppreerpfaorremdesda(mtpelfeigsemraatyobretermepferriagteurraetesdmaaty have a detrimental affect on the solubilityofsaturated solutions) 100 Quaurry ControL, 104 Blanks: 10.8.1 `Seoalcvhesnatmbpllaenskes,tm0etdhetoedrbmlianneksc,onatnadmimnaattriioxnoblracnakrsrayorveprr.epared and analyzed with 10.1.11 `WwhateenrotrheHPstLuCdygrmaatdreiocregsacnoincssiosltovefnhtisg,htlhyempuertihfioeddasnoldvmeanttrsisxucbhlaanskTsmypaey1 be represented by a ingle solvent blank. 10.12 aSnodlvmeanttriblxabnlkasnskhsosuhlodubledbaenaalnyazleydzeprdiaofrtetrotehaechnictailailbrcatiaonlcuirvecb.urrMveeatbhutotdpirbilooarntnkos thestudysamples. necessary. Ifcarryoveris problem,consecutivesolventblanksmaybe 102 Matrix Spikes: 10.2.1 Matrixspikesmaybeprepared foreachset ofextractedsamples(ifspplicabtloe the study) andanalyzedto determine extraction efficiency. IM EmreLitorory ingHPLCEBriasce Sosy Prd"otio 3M Environments Laboratory Pogedzotz1e ee Report E2043 Tenn.RiverVaty Samos Document may be used, if current, for 14 days from 11/21/2002 10.2.2 Matrix spike duplicates may be prepared periodically tomeasurethe precision associated with the analysis. 10.2.3 Analyze the matrix spike and matrix spike duplicate (ifprepared) in the same run as the original sample. 10.2.4Matrixspikeandmatixspike duplicateconcentrationsshouldfal inthemid- range oftheinital calibration curveor shouldbepreparedat1.5-Stimesthe endogenousconcentrationoftheanalyte. Spikeconcentshroualdtfailloinnthse low-angeofth initialcalibrationcurveifextremely low levels are expected. 103 Continuing Calibration Verifications: 103.1 `Csocnctuirnacuyionfgtchaelibcraaltiibornatvieornifciucravtei.ons (CCV) are analyzed to verify the continued 1032 Analyze a mid-range calibration standard ater every teath sample, with a `minimumofonepersample set. 104 Internal Standard/Surrogate Standard: 104.1 Anintemalstandard(S)maybeusedtoquantifythetargetanalytesby establishing arelationshipbetwentheratio ofanalyte responseto ISresponse: and aknownconcentraotfiothne anaolfiyntetreset. TheISshobeuspilkeddat `anamountthatwillfallwithinthemid-rangeofthecalibration curve. The IS shouldbe addedafertheextractionprocessandbeforeanalysis. 10.42 Asurrogatestandardmaybeusedforqualitycontrol.Thesurroisgusaetdteo quantitatively evaluate the entire analytical procedure including sample preparanadatnailyosins.Thesurrogateshouldbespikedatthebeginningofthe Sempleprepaarndashtouildofanll witthheloiwtno mid-ofrtheacalnibrgatieon curve. bo 111 Analyzethestacnurdvesaprirordtoandfolleacohsewtofisamnplegs.Theaveragofe twostandardcurvesmaybeplottedby linearregression(y =mx +b) weighted1/x,or qcuaaldirbartaitcionitcu(ryv=es2xs'ho+ubldxn+oct)buesifonrgcMeadstshrLoyungxhozreorot.hersuitablesoftware. The 11.1.1 The closing calibration curve may be excludedifthe CCV"s meet acceptable criteria. Ifonlythefirstcurve isused,thecalibration andstandardization `parameters are the same. 112 maIfitnhteeinnaitnicalecoalripbrreatpiaornecaunrveewdsoteansdnaortdcmuerevtea(ifcneccesseacrryip)taernitdapreeraafnoarnlmyzreco.utiene: 113 For purposesofaccuracywhen quantitating low levels ofanalyte, it may be necessary to use the low endofthe calibration curve rather than the full range. Example: when SMErvionmenalLabora Amiri sgHsCBssotSapc n Pesaro aM Environments Laborer Pose 3301276 --Repon 02043 TonRiver VaySamples: Document may be used, if current, for 14 days from 11/21/2002 attempting toquantitateapproximately 10 ppb ofanalyte,generate acalibrationcurve. `consistingofthestandardsfrom 5ppbto 100ppbratherthantheful rangeofthecurve. (5 pp010b00 ppb).Thiswilleduce inaccuracyattributedto linearregressionweighting of highconcentrationstandards. 11.4 Highand/orlowpointsmaybeexcludedfromthecalibrationcurvestoprovide abetterfit overthelinear rangeappropriatetothedataorbecausetheydidnotmeetthepreaderteearcmoiunnetdsaacrceenpottaantcleecarsittterwiiac.eLtohwa-tloefvtehlecmuertvhepoodibnltasnskhso.ulJdaulssobteiexffcoliruecdxecadliutfsitihoenoiornf calibrationcurvepointswillbenotedintherawdata. 11.4.1 Aminimunof 5poiatswil beusedtoconstructthecalibrationcurve. 120 _Procepures 121 Acquisitionset-up ~pleasereferencethe SOP thatpertainstothespecific instrument. Actualparameters will be recorded ontheinstrument printouts. 12.1.1 Sethetsamuplep lit. 12.111 Assign asamplelst filenameusingthefirs eterofthenameof the iannsdtrtuhmeednaty((T fo0rT0uck1efro)r,0Otch1teoyb2eearr(120,02f0o0r02o0n00T)u,ctkheerm).onItfhmo(r04eftohraAnpornile), listismade onthesameday,useincreasingletersofthealphabetstarting with Aattheendofth lst. 12.012 Assaimegthond (MS) fle. 12.013 Assignan HPLCprog(Inrletafilme). 12.014 Typeinsampledescriptionsand vialposition mummbers. 12.1.2 sTpoeccrteraotmeetaemrheetahdoidn,gcslaicnkdosnem lecteSIRi.t nStehtehiAcqouoisintdioimnocdzoentara3oalppaptrnoeplirtihaoetenamnnasds `mass10.499orotherapproprmiasastese. Afullseanisusualycollectiedn additotthieSIoRsn.Saveacquisitionmethod. SeetheMicromass MassLynx GUIDE TO DATA ACQUISITION foradditionalinformation. 12.1.3Typicallytheanalyticalbatch runsequencebeginsandendswith asetofsolvent standards. 12.1.4Saaftmeprleevesrayrteeanntalhsyazmepdlwei.tShoalcvoennttibnluainnkgscsahlioburladtiboenavnerailfyizceatdiopner(iCoCdVi)cianljtleoycted `monitorforpossibleanalytecarryover. 122 Usingthe Autosampler/Column Heater 12.2.1 Placesamplevialsintothesampletrayaccordingtothesamplelstpreparedin Section12.1.1. TM Envksomesnl Litenory Aoki slog PLECrBsemisps Spc Pagtotto SMEmonment Laborstoy Page s4o1278 Repent E2043 Torn. RrVatey Samples Document may be used, if current, for 14 days from 11/21/2002 12.2.2 Attach the proper analytical column in the column heater compartment. Ifusing theswitchingvalve, ensurethatthetubing i runtotheappropriateports. 123 Using the Inlet Editor 123.1 Set-up the HP1100 using the following conditioonrs at conditions the analyst considersapprfooropptrimailraesptonsee. Recordactualconditinotnhse instrument logbook: 123.41 Sample siz=e 10 kL injection 123.42 Flowrate= 300 ulmi. 12313 Cycle time = 10.0 minutes 1231.4 Mobile phase components: Solvent A: 2.0 mM Ammoniun Acetate in Water SSoollvveenntt BGr:adMieetnht:anol (TMiemOeH()min) %B 000 500% 1.00 5.00% 450 950% 800 950% 850 500% 100 Stop 124 InstrumentSet-up 12.4.1 Refer to the Platform LCZ User's Guide, the MassLyNnTx User's Guide, the ETS-9-36, "Operation and Maintenanceofthe Micromass Platform LCZ Electrospray/Mass Spectrometer",orthe SOPthatpertains to the specific instrument. 12.42Check thesolventlevelinreservoirsand refillifnecessary. 1243Checkthetipofthestainless steelcapillaryattheendoftheprobewithan eyepiece. Thetipshouldbeflatwithnojaggededges.Ifthetipisfoutnobde unsatisfactory, disassemble the probe and replace the stainless steel capillary. 124.4 Tum on the nebulizing gas. 12.4.5 Otphete unepn age. Cloni`Opcerakte'toinitiatethedesolvahteaiteorns. 12.4.6Opeathe InletEditor. 12.461 SetHPLC pump to "On". 12462 Setthesolventflowtothedesiredflowrate. 124.63 Observedroplets cooumtofithetnpofgthe probe.Afinemistshould be `expelledwithnonebulizing gasleakingaroundthetipoftheprobe. Readjust the tipofthe probeifno mist is observed. 3MEmber Libor AyingHBsPLCesnsya Specs Per0t10 IM Environmental Laboratory Pages ar276 Roper E02.0443 ToonRiverValey Samples Document may be used,ifcurrent, for 14 days from 11/21/2002 12.464 Allow to equilibrate for at least 10 minutes. 12.4.7 T`mhaeyicnhsatnrguemienntoursdeesrtthoeospetpiamriazmeettheersraetstphonosfeo.lAlcotwuianglspetaingrs.aThwmeisleelsbetetrteeicnogrrsdsed on theinstrument printouts. 1247.1 Dryinggas250-425 litershour 12472 ESInebulizing gas 10-15 lters/hour 12473 HPLC constantflowmode, flow rate 10 - 500 wLimin 12.474 Pressure<400bar(Thisparameterisnotset,it iaguidetoensurethe HPLC is operating correctly.) 1247.5 Source Block temperature 150. 1247.6 Desolvationtemperature 250. 12.4.8P`rsipnetcttrhoemteutnerepinafgoerwmaittihoint,sapnadraamleltoetrhse,rtahpepLlailceatblpeagien,fosrammaptlieonliastn,dmsatsorse it in the studybinderwith copics taped into theinstrumeatrun logbook. 1248.1 All copies must be initialed and dated. 1249Clickon statbuttonontheMassLyntoolbar.Ensurebeginanndeindningg `sample numbers encompass all samples 10 be analyzed. 13.0 DATAANALYSISAND CALCULATIONS 131 Calculations (including, but not limited fo): 13.1.1 Calculate matsix spike percent recoveries using the following equation: %Recovery= Observed Result - BackgroReusnuldt x 100 Expected Result 13.1.2 Calculatepercentdifferenceusingthefollowing equation: %Differenc=e ExpCone.-c CalcutlateedCodne. x 100 Expected Conc. 13.13 Calculate actual concentrationofanalyte in matrix (g/mL): On-ColumnConcentration (g/mL) x Dilution Factors = Calculated Concentration 140 METHODPERFORMANCE 14.1 The LiofmQuanititattion (LOQ) is method, analyte, and matrix specific. For many analytes, the LOQ concentration is selected as the lowest acceptable non-zero standard in the calibration curve. SMEon Laboraoy rt sgHPLFCBraesrsSpecs Pusbario IM Envionmental Laboratory Pages or276 --_------_--_--_--_--_--_---- ReportE0203 JE vr -- Document may be used,if current, for 14 days from 11/21/2002 142 Scoallvibernattaionndcmuervteh.odblankareacounts mustbe < %thatofthe loweststandardusedinthe 143 oTrheequcoaelffti0ci0e.n9t8o0.fdetermination (7) value for the calibration curve must be greater than 144 sCtoanntdianrudicnognCcaelnitbrraattiioonn. Verification (CCV) percent recoveries must be + 30%ofthe 145 Intemal Standard recoveries should be within + 50%ofthespikedconcentration. 14.6 I`fpecrrfioterrmieadliosnttedhienstyhsitsemmeatnhoddspaemrpfloersmreaanncaelsyezcteidoonraortehneortamcteito,nmsaaisndteetnearnmcienemdabyybtehe analyst. Docallauctiom nsine the n rawdatta. 14.7 f1ofodtantoatiesdtoonbteabrleeposratneddwdihsecnuspseerdfionrmtahencteexctriotfetrhieahraepvoernto. tbeen met,thedatamustbe 115590 _PPOOLLLLUUTTIIOONNPPRREEVVEENNTTIIOONNAANNDDWWaASSTTEEMMaAvNaAcGEEMMEENNTY 0+oo 151 SgalamspslpeiepextttreacwtawsatsetiesadnisdpfolsaemdmianbblreoskoelnveglnatssidcoinstpaoisneedrsinlhociagthedBiTnUthceonltaabionraetrosr,ya.nd 160 _Recomss 16.1 Bachpagegeneratedforastudymusthavethefollowinginformationincludedcitherin thinethegeraadteiornormehtahnoddw,rsiatmtepnloenntahmeep,aegxet:rascttuidoynodratper,odjielcuttniuonmbfaecrt,ora(ciqfuaipspiltiicoanbmlee)t,hoadn,d analyst. 162 tPoriinnctltuhdeetiunntehpeaagep, spamrploeplssttru,daiycfqaouiltsdieetri.onCmoeptyhtohedsaenpdaaglelsoathnedrtaapppeliinctabotleheiinfnosrtmrautmieonnt run logbook. 163 Plotthecalibrationcurvethenprintthesegraphsandstoreinthestudyfolder. 164 Prsitundtydabtiandienrt.egrationsummary,integrationmethod,andchromatogramsandfileinthe 165 Summarizedatausingsuitablesoftwareandstore inthestudybinder. 166 Back-up electronic data to appropriate medium. backed-up electronic data in the study binder. Record the file names and location of 167 DTootc#usm,enptuarittiyo,neoxfpiarnaatliyotn,e(asn)danstdoarlalgerecfoenrdeintcieonssu.bstances wil include trace numbers, 170 ATracHMENTS 171 None MEeveoamr Labor ii higPLECrBsoassso)n pcm Peesarto SU Environmental Laboratory Page 37 ot 276 Repo 02046 ee ---------- Ten. RiverVatey Samples Document may be used,if current, for 14 days from 11/21/2002 180 RerERsnces 18.1 SPlZat;foorrmFlLoCatZsRUsoeard',sWGuyitdhee,nMsihcarwoemMa2ss3U9KLZL;imUintietde,dKTiudnogrdRooma.d,Altrincham,WAL4 182 MSaRsZs;LoyrnFxloNaTts URsoeard',sGWuyitdhee,nMsihcarwoemMa2s3sULKZL;imUintietedd,TKuidnogrdRoome.d,Altrincham,WAL4 183 M`AalstsiLnychnaxmN,TWGAu1i4deSTRZo;DoartFalAocaqtusiRsoiatdio,nW,yMtihcernosmhaaswseUMK2L3im9iLtZe;d,UTnuitdeodrKRionagdd,om. 184 EEqTuSi-p9p-3e4d.w0i,t"hOpaeMraatsisonSapencdtMroamientteernDaentceecotforHaenwdl/eotrt2PPahcoktaorDdiHoPdLeCAr1r1a0y0DSeytesctteomr". 18.5 ElEeTcSt-r9-o3s6p.r0a,y/"MOpaesrsaStpieocntarnodmeMtaeirn"t.enanceoftheMicromassPlatform LCZ. 190 AFFECTEDDOCUMENTS 191 None 200 Revisions Revislon Rew Number Reason ForRevision Date 1 `Section 1: EalrgedthsopoofTtihelmeeCtohuondgbeyincludingaddionalmatics. Also sdded 09May01 Sections `1acoamdm2e:ntRsesmboovuetsdpeecfiefriccapcaersatmoestpeercsiwfiicllcoemdpeofuinndesd,i hi protocolo prepsheets. S`Seeccttiioonn33:; CRheamnogveeddtpoaarlalgorwapdihafemrCeonntvseynstteimosnsn!vdss.oZf-wSaprraey.probe erfce. SSeecctioo8n:n: BArdoaadsednpeadnthegthylpeoswoifnsgtorfoagetchon4ta5i0neofrasahnedrcmoanidvistoilovnesn.tssadsolitons. Section 10; Adsdeducomndmdenpitplsiceaablilsloyw.for exitinqualitycontrolsfordifereatypesof SSeeccttiioonn111:: AAddddeeddappaurraaggrraapphha(l1l.o4wi)nglofvoritnhgefeoxrclhueddirnogoppfiaheosfeccoenvdecpurovie.s sadmisiur `Section 12: Audmdbeerdocofmcmuernvetpsototsereeendcede.hespecificSOP's forsep. S`eScecttiioonn1126:: ACdomdeecdtperdgnrumabpehrionng,records of naysandsubstances. Section18: Addedreferenceto hemethodfo theHowlen-PackardLMS. SM EmitLatetoy SMEnonmerta Laboratory imE]ss - Pas100o110 Pagessarars Ropon Enzous Record of Deviation Ton. RiverVatey Samples 1. Identification Study / Project No. Deviation Type: (Check one) TN River Valley E02-0443 0sop AMethod 0 Equipment Procedure O Protocol 0 Other: Document Number: ETS4-04.0 Date(s)ofoccurrence: Ti. Descrip0tionTe:ws Joos -- JE 20 Required Procedure/process: _ETS-4-04.0 section 4 states, "It i the responsibility ofanyone: `handling form." samples to record the movementofthose samples on the internal chainofcustody AthcetucaolurPsreoocfetdhuries/sptruodcye.ss: The internal chainof custody forms were not generatedorused in Til. Actions Taken: No a dditional a ction w_i_ ll(sbuecthaaksena,maesntdhmeeinntfoirsmsauteid,o SOP revision, eic.) n cannot be recalled so lon g afer the fact. Recorded By: E ntp nfi 7 - Cin) IV. Impact on Study / Project `This deviation does not adversely affect the qualityofthe data. 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RiverValeySamples 02043 `Combined Large Mouth Bass Data Table Amant ar"om ram sS suhiiimer ida]l ammooaa||~tmmoooaaa{||somaooaaa scr.uk22| soa| soa| moo smooSao||am1W0o moa| si mheor Bmoeir mao se sSsrCiwTnissd sms) smooiacaa||| mmooioaan|||ms mooan oa| mimoooao||| 8d| aoa| mon moa| Gws 3s mwGirn mi me aepurmr oa RTssSTciLiheiaromsn--Bootoaaa|||| smamiioooaaaa|||"estssaosaa oea s || msooGaaa || ~Stoa--| [woeieys emGamssmsayeew sess J.! sisriTimirssessds]| ammioaaa|| mmdoieaad|| maioooaoa mBmooaao||as4M5s admaiey orwURe s5chinmseas]] ssooaa|| mmooaa|| mmooan mBooaa|| mwso meemi: aarm 4 Tas sScCzzUuukinasi1s|s| msHoooaaa||| mBmioobaaa||| bsmioosaaa Basoaao|| eamooaa me [35s2z71 uizzizl|a mmooaa||| matoooaaa||| ismioooan msodRaaE|| snaiicaa a ar SssezzamDiussesre|] aaootaao||--| Simmoooaaa||| mwooBiaoos Fmmoooaa|| awWsa remys ewsm s5s2iiadia) smoooo|| mmooaa|| omoona mmooaa|| suii bweeis mnee i:i sr 5sS3350uvirsda1)|] saoastaon||| atoobiaaog|| so--|Booioang ssuiz moa| moa| moa swoSao||uemwoosa soo| soa 4 5505) moa| aoa| mon mod| 8G _ wis55055U5ts3ia)a)timmooonaa||| Bsmiiosaaa||| saaiooosan 3usa moa| moa| mica BaBlooeaaa||B bmooaa ea| moa| mos Giz [35s33sisrssdat)l mimoooaan||| m~mBioooa--aa||| msHoooaaa [856ao86a||ashmooesa zi8550333 is nviseerss|]] omoaaiao||| sa miooan||o| msaoocaoo" Bawiooos || --smaiooossa-- TESs3soisruar)l 6ss0io3ao|||ammoooaaa|| mmioooaas Bnmiooasa||Sihmoooass" i scsi) ooo| moa| aida ac| aos s5a105 | Goo |Bomiaa m5o%a|| saotaa CEomrmaetcuagons, T r T stm n S gE an: wm T saT ru ox Sean: IEnvironment Laboratory Page 5401276 EE zens SE. Combines02c-o0r4s43o a meu we rion Em A Od] nelet"iwy yoem]a E EE EpEmE R ElEIE lEEET(EEElEEIRE2Eog EEElwg o=o o= EBplEmEll EEBBirrleEgEeTETEEmlTeEs yyewB2E EE Eaoolslt EeE e waooon8 o ClEBsElEEBllEE elseR sy E E o asls s E=nE C|o [ClEffs EaAnsle lElEgg SElIElilEE lls EeIEl EesEleIEs sEEEm E HEE ELE ii=o=2a= 2 i EapHHgEumAagAlF sElElElsITiIEEm I]RIIEIIEE=EETIEETERae &22BZso l=e : BEEFHAsEEEaRIIEELIEIIEEELeIIEEI ==z= CEE g BHoaH laEETlEE e EIHIEEsE E LLGiomio 5 ;i pFEs mSeAaAElERa RsIlEEIam F leIIEs EIaE @F =PG5ErR 2 EALEaRnIanEan TE Yom T= ssmme-- a EE e pm enim JR -_-- ots -- Bagg Bak ! 3 i J | + kog ! TREY : i i | i i spernppprerapey| pow | ii 7 ]1 | i ly) i ff HEE I EERE | | | ibl |iii]SH i |iji ii i4 Hide il i I Co oo EE -- Ch. l He mE Eig I fu ifn wl 11 1 | ing 3 FE gz Em FR ELIE ITI C1 -- CEf [Ii = BC easass frasar ss] fasensy] praniey ! : i Iii Ra zea38a| BRazaag| fsgosas] li siesssglicafalagieasafaghivacasaia zane } di Beagads) Beinedy aasasy lly FF rd a pd #1| frrsnens| Fumnans| frvaens] frenens] Freernafhd | ka bailbafta Lh [nnn | Iltilies, po i] aheiig]Hh i fi* ! : i : li i Ii { | aiii h i I-- : | | -- -_-- m ee ----_--_----_----ee LE SEE k FT BET |EEeEy i LL 1H st [ene ; 3 [11pazzeigangeaagisasy i Aas iy f i i I 22282352588 CB FT ileTr] iam | [img din 3 TE ComneraarroadTel ELE = HEIHE Ee CEEL E EE HEN E EE EE E EEEE Co _----_e-- e ie rie E02-0443 Tenn. River ValleySamples awSme|nn Ee | |Te Eefe E|Jon| J|Tw Location Averages eTfe] ; m | e ti taee en | on|Taeo|||[we [oorn|] Eee ww -- --=-- | ee > 1 - | FrWate,Sarge| <o0 | <oa | wos m EEnmim |=onf| m-|e||A e[ree Lo= SampleLocation 2 = a 490 ! Rene. r w irr os rare -- i| i iilH "El N K e pd iE LEEd A | pesle Roo E Bell Pol Bee [HH gi RH LH IRE : _--mo AomA A---------- E\ EE Ed i WEN EE ! YE pie I Bo pl Ht HE | IRE Re Been ba alll] - 7 "l 11111" FE. BEE i ihe El i 8 : paieit) Bom gi ell prasenini | Bi RH in fon El i i i Lil T| EEEERS E Lod a be | fvpi Qe ps RET iin / Boo Bor RT 1 HR Ell] | i EN i iTiiHEN a Ee Ti IE E LE d El | hoie seii Po Bo Roo Ell Youn Fo |i Rll 18 sa | EE Repo 02043 ATTACHMENT C: SAMPLE CHROMATOGRAMS ~~ Tenn.RiverValey Samples 3M Environmental Laboratory Pages of 276 Repo Eozous Ton RiverVteySamoies DReaptoartFilDea:te:DUD2E70-0AuSgE-.2D002 13:27 - rage 1 34 Environmental Laboratory 502-0443, Tenn. River Valley Samples DLToaa)bt'asDmfapitleeTa:}: \S2i6\--B1Jt,0sNt-ia2ro0gd0eo2r)\t2a3:r1g6et\chem\dudejr.1\D020626Extracted.b\DUDEO0S6.D OSMhippsecraItnIofnrofo ||| mTieman. River Valley Fish. Prep-i1n7aJu1n0: 02a.untGstHC/MLA. 20 Jun 02 CMMoeemttmhheondDtate || \27-\AuEg-t20s02t1a3:3r2gdeudted\zitaQ.ruia\ngDt0e2T0yt6p2e\6:EcxEtSrhTaDcetemd.\b\dD0u20d62e6ejxtxra ACDaisll DbFaoattcett.loer::| 4213.60-00000N0-2002 22:00 Cal Fi1e" Dubeo0es | TIanrtgeegtratVoerr:sioFna:lcon4.12 Compound Sublist: all.sub CCoonncdeVnatrriaatbiloen Formila: Ant *LoDcFal C*omCpponudnVdarViaabrlieable amps Fe mre are on ora oa + Environment Laborer But One nga LMtitCel laitge Pagee8.o1276 reeee------ EE-- ---- -- ResonE020443 += TomRiverVatey Sales -- ETRS BataFiler Etatanget target chester, (\DOZOS2NEHr soled RUIKCOSE.D. Par 2 Sa br i ie IIE ET a we TT i Ri i ` ne 20 ms am ii 5 i 30 Ton Ese | niey - TE ExactCog of Original Lone ates Intel Dato) SMEmirormentaLaboratory uma ------- Repon E020440 Ten Ruer VaySamos Bata Flies \\Etatargatstargetschentaeie, (\DORO2IEArsoted, NIIECCRS.D PE fd 3663/00 40 a 446 i al i? 38 ' i Eh 3 ood EE ee a me CB ; sa ;i wFod : 1 ; Fae 3 Bacoycigtn Low pe Initial Date. p---- page 001278 [-- Ten. verVay Somes DRaetpaortFilDea:te:DUD2E70-0m5ug8.2D002 13:27 - Page 1 3M Environmental Laboratory Df1r3ao3tgaBfaikleeH!l: \g \Be ust02-a04z43,geTetmn\. cRiavxe.rr1\VgDaOle2l0et4y2is6aEcnmtphFlaeestemd.ib\dDUuDEd0OSeE.)D 26 vin-z003 22:28 SkShPioraTntnefgro || mTeiaan. River Valley Fi)sh. Prep I1n7stdu10n: 0d2.udGHeId/r4MLA. 20 Jun 02 | Comment . eH5M5eeisttphhaoDBcdoaetc"teie!|+| $3\4s)\:Bo%tuasnct-a32r00g00e25t\t1232a::r50g50etS\cehedme\driudejQE ru.ain\tDE 02Ty0p6e2:b6uEpxBBtSorD0aecsted.b\D020626extra P5IE :n1tegFraacttt oorr;: 1Fa0l0c0o0n0ie Compound Sublist: all.sub i| CCoonadc'eVnatrriaatbiioen Formula: Amt *LocDaFl +CoCmppnoduVnadrViaarbilseble { wg Tw wr or ---- :| Emons ast Bact cz ofOignal Gin saDgaiso'ur Pret atzre _ RapE02aus To. Rus Vay Sargon ASHE BataFilet \atargut\ andtr,a(\rDOgZEeNtaictecdNhREeSOmSDk.D rae 2 a fo2a0l0 Bae 1 ho ewww retraite ewes at i 5wz {opi gai bd TE - ed) 7 A ; wd Tn 1 my " 2.2i Eg - 346736 384% 42 Cin `Exact Co: 2s nf Original Initial Date. aMEmomment Lavon Paez _--_--_------ Reseneazouss ToRr Vey Supe Bata Filet \\Etabangetsrs,ItNDaOnRgE sottedsIAcKRhEOoCRn,D Page 3 i os: tof 2 En [hs tok Pols ! 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CHC/MLA. 20 Jun 02 : MCoimsmcenIt.nfo :+ MMeetthhodDate Cal Date i: : \2276\--BAJtUusNgt--a22r00g00e22t\21t23a::r02g02etd\ucdheejmz\.diudejQrCua.lain\tDPi0lT2ey0:p6e2:D6UEDExESt0TrD0a4cSt.eDd.b\D020626extza ADlils bFoatcttloer:: 415.00000 J TIanrtgeegrtatVoerr:sioFna:lcon4.12 Compound Sublist: all.sub | CponndceVnatrriaatbiloen Formula: Amt *LoDcaPl C*omCpponudnvdariVaabrlieable pnts I wom wr aos Ga aie : { WM Environmental Laboratory Ba Copy c ofOrgtinal Ln filer Wal Dats Page 7401276 _------------------ee_--_--e _--_--_----_ Rap E243 J ---- RR TE Bata Files \Etabargetstarget emia r. [NSO Mote NEOSRTD pe rae 2 Tole | i oy ! ai |vosBe I EI 1 T3 ] NE3 A 30 328 34 3/6 3s : wi FE i ai - ibokped 8 fr ; BrCopay eOrigtin Lnar gpou s MEnmore ~ [---- eee---- er---------------- Reson 20043 Torn River VaySamsios Bate Fle SarESr EtdNe RE [, Ln git i : no Pfs ! wl 2 || ] me . vel |[ok bwroe 1 poe | ae : 3 TT eT : : Ba Copyc ofOrt igin C ital" 1aC fpaptr MEnronmenstabort Page 601276 Revo 020043 Torn RiverVlySamples DRaetpaortFiDlaet:e:DUD2E70-0A6u8g.2D002 13:27 " Page 1 3M Environmental Laboratory t [B02-0443, Tenn. River Valley Samples DLIaanjtbaDSauftpiele1a}:: Operator : m\S2i\7LaE--tJ1s0tNa-Mr2og04e0-t23\t0a1r:g2e8t{chem\dudejrI.nis\tD0I2D0:62d6Euxdterajcirted. b\DUDE0OS.D SMipteInIfnofo :| Tenn. River Valley Fish. Prep-17 Jun 03: CHO/MIA. 20 Jun 02 I MMCeeottmhhmoednDtate i+ \37\-heugt-3s00t2 a13r:22gdeurde\scsiarQuga\nDet03tT0y6p\2e6.cExhEtSTreOa.cnte\d.db\uDDd20es26jexxtr.a aDCilalsl DbFaoattcett.loer!:: 2512.60.000U0N0-2002 22:00 al"F11% "DuDB004>s || TIanrtgeegtratVoerr:sioFna:lcon4.12 Compound. Sublist: all.sub CCoonndceVnatrriaatbiloen Formula: Amt L+ocDaFl C+oCmppnoduvnadrViaarbilaeble comps as mn ee { ExactCopyof rial Caofiesnr Initial Date EE ---- ---- Report E020043 Tenn River Vay Samples EE a Rrer EE Data Files \\ERatargottargo(\tDEsZOcGZhEEaXtmA itecdhBiADdUeDEjSGrS,,D - Page 2 uel asi ; oa: ae com PE) i. 1P.4N: " iEkeot og) oe 3/08 320. oe Be 3s = re com TE C; ok i " gi I" eassi p o2im aMEnveonmanal Lasoratory -- LOC [aden Intel" pte PoIBrB Rape sszons a Tom. ivr VlySomes -- BataFile: \\ELstargetsta(r\DgOZ0eG2t6Esxtcrnhoteed,nB\tIUuDEeSOrSS,,D Pra : a " ioe 2 se i por Page 3 fe 2 ETE eee es ; TE | kw IE wo i : `BactCopyof Origa Sg et Ener abort Fue r9a28 --- Repo 020043 Tonner Vatay Samples DRaetpaortFilDea:te:\\E05t-aDteacr-g2e0t0\2ta1r3g:e0t7\chemdudeir. i\D02028.b\DUDEO0SS.D Page 1 3M Environmental Laboratory DLaatba'smfpileTai: \Si\oaE, ttsat)a02r-g04e43t\Tencn.arRgiveert1\V\ac0l0lh2e0ey6n3S8a\.mbpdl\ueDsUdDEe0j0SrE..D OTSpahjeorDaItnaogkroe::| 2mTe9in-ang.iN-R2i0v0e2r 02:15 Valley pish. prep-I1n7stou1Dn: 0d3udGeHs/Mi.IA. 20 Jun 02 WCioemcmenItnfo |+ MMCeeatlthhoDdaDtaet.e i+ 20\99\.-E0DtUesNct--a22r00g00e23t\t10a30r::04g18etd\ucdheejmr\.diudejQGru.aailn\"tDr0T2Iy0Ep6e2:8b.uBbb\eSsDTo0s2o0.6n28.m ABIlinsltegbFroaatctttoolrre::! 1F28.a0l0c0o0n0 Compound Sublist: all.sub : Target Version: 4.12 : CGonndceVnatrriaatbiloen Formula: Ant L*ocDaFl *ComCpponudnVdariVaabrlieable 1 -- oes mr ore os nara) i en ou WE ve wn aw : QC Flag Legend 1 - Compound response manually integrated. | Ba Copyoc f Orit ginal i LC n r fapngn Environment Laboratory Pogencrzrs EE -- Reon Eczoues Tern.Rr Vay Samples tn Fe Eat SSE, ERD rr? Se BS pe Hp AE ii i: ftse | 27 ii TTI II my1 3 - 300 323% 36 30 i 20. - TE Ph: w-e: 8 sei Fro 3 He ae ga We wh oe TR TEE Exact Copy of Digna cal Tatil aatfeue aM EmmonsLasorstoy Pantot2e --ee------------------------ Rept Erzous Tenn. verVataSompes Se ie St---------------- J pe i a 1 pr | a oa Ie 0.3 : 4 $ Sy Baonycotv LN (9hofor tnittal Date SMEneonmerir asesory [I ---------- e-- e---------------- ReportE020443 Tom.RiverVatey Sapien RDaetpaortFilDea:te:\\B0t5s-tDaecr-g2e0t0\2tar1g3:e0t7\chem\dudejr.i\D020628.b\DUDEOO64.D Page 1 3M Environmental Laboratory LDaabtaSwfpile1d:: S\L\-B2.tsItMaO3r-0g32e-r0\44t3azTgenent.\cRhiveemr\Vdauldlaey3rS.amibp\\lDeU0sD2EbOO6E2H8..D OSIpwnjepraDItanotfreo ::: mT2ei3na-nJ.UN-R2i0v0e2r 03:21 Valley Fish. Prep-I1n7stduInD: 02d.udGeHCj/irMLA. 20 Jun 02 HismeenTtnfo MMeetthhodD:ate Cal Date ::\\20B39t--sJDtUeaNcr--g23e00t00\22ta01r03g::e4081t\dcuhdeenj\zd.uidejrQC.uaial\nDtF0121T08y5}p2e6:D.UbDE\ESDGT00D2S006.2D8.m ADIlinslteFbgaorctatttolorer:!: F133.a0l0c0o0n0 Compound Sublist: all.sub ; Target Version: 4.12 } CCoonndceVnatrriaatbiloen Formula: Ant L*ocDaFl C+omCpponudnVdariVaabrlieable 4 conse es I i wom Rn wl i ac Flag Legend 1 M - Compound response manually integrated. i BetCozy yy aigp SM EnvironmentalLaboratory Page 8301278 rrr------------------------------ Roponexz oun LT -- te Fle SabEr ENa EES [oe a i kie 5 i HE TER ve sia a : i i ;2 ls 53 5 in Fs SM Envronmentl Lanes 423i CopyofOriginal a a, ital" peta Pansat276 EE ---- -- ve TRA sereBata File: \NEtstargettarget(i\DcI2h0eAZnS,sADdUuDEdCeOSr,,D ; Page 3 asl i3 4 Wn ! ; bed i EE: ifTE Ty ; ET i : r-------- Ba Cozy c of t ign a a Cat Panis -------- eee------------ RepentE020043 Ton. ReVeySamples DRaetpoartFilDea:te:\\E0t5s-tDeacr-g2e0t0\2tar13g:e0t7\chem\dudejr.i\D020628.b\DUDEG070.D Page 1 3M Environmental Laboratory : DLaatbaSfwileTd:: S\L\-E2.tsLtMa-4r-0g32e-t0\44t3arTgeennt,\cRhiveenr\Vdauldleeyjxs.amiBp\lDDeUs0D3EO5O6T2O08..D OIpnjerDaattoer 7p Info :: : m2i9a-J0N-2002 Tenn. River 04:26 Valley Fish. Prep-I1n7stduIDn: 03d.udeCjHrC./NiLA. 20 dun 02 iCoomcmentInfo : MMCaeeltthhoDadDtaet.e ::: \2093\--BDJte0scNt--a22r00g00e27t\0t10a3::r40g81etd\ucdheejmr\.diudejQCrau.lain\tDFi0lT2ey0tp6e2:D6U.BD5SE\T0DDO0S2O0.6D28.m ADlisl bFoatcttloer:: 317.00000 i TIanrtgegertatVoerr:sioFna:lcon4.12 Compound Sublist: all.sub i CCponndceVnatrriaatbiloen Formula: Ant L*ocDaFl C+oCmppnoduVnadriVaabrlieable 4 Compre as Wome wre mse ore i [ep hI SE an see i! QC Flag Legend M - Compound response manually integrated. i 11 Ea:t CopyofOriginal awniit iaDatot SM EnvironmentalLaboratory Pagetor2re _-- ReponEnz ous Ba File Satii g Br ARRe E, ee I ST -- - [ i pred fe ! i | TT i bed | ie | IR ee vai > nol SE si 1 MEnvironment Labora LaC aOfiaolpn Pa87got2e78 EI E ---- -- [-- Tom reySas ere tare OS ns 1i 5 it iq Bix PR + fn ia wT Wns Lx 1310/0: nitial cts >= Passpraere ---- ee-- e ---------------- Report E020083 Tou. RrVetaySapes RDeaptoartFilDea:te:\\05EDteact30a0r5 g1e3:t08\target\$c\Dh0e20m6\38d.udejr. b\DUE076.D Page 1 3m Environmental Laboratory DDaatba'smfpileTa}: S\h\-3E; tTsHtA2a02r-0g44e3tT\entn.arRigveertV\a\lDcl0eshybe6S2ma8mdpPlAueDsdUDeEOs0TxS..D . SOThapjpirDaIatntofero +N :|; Tm3ei5na_n7.UNR-i3v0e0r3 05:32 Valley Pish.Prep I1n7stdu10n:03d.udCeHsGr/i.MLA. 20 Jun 02 Po Comment} MiCMeaetaithhob`daDotaret:seie;:+ 420\259\.-B0Dt0es%ct--a32r00g00e23t\01t03a::r40g81etd\ucdheemi\irdudeQEjura.Enit\DTT0y2p0e6:S2u8BB.zS0bT0\DsD00.200.6.28m , TDIienfrtaesgFtraacttvooerrr::sioF1na::l0c0o0n0"0ia Compound Sublist: all.oub i | SCoonnicevnetrraitaitoen Formula: Ant L*ocDaFl C*omCpponudnvdariVaabrliesble ig -- me mre me Cn -- {|i 3ardrooirmtweon]m i a SGiWd mIVminEiaammem ontTeemmm nmaeemw sowapmmm emma eshaeeamm ow Uae raag tegen - Compound response manually integrated. i | act Copy ofOrigine Lat ageln Initial Dats MEmbonment Labonte Possanarzre ee---------------------------- Neoneszons To rey Soin AAI nr EE Pol | arr Fi] | w " fa . 3 Por wo ft { brit : B5E Sa--y Bact Coyof Origingt LAwCa alsofen. rammarrs _--e [-- Tom Rave Saris a Ft SE sr --------AA rs =ol OfRi eel Pa ra hs a Ae 4 i J 2 CobE t : wo CURE iE i w= i ; Butt i le Menomena asorsy [---- reeee------------------------------------ [mp Tom Rar Vat Samos RDeaptoartFilDea:te:\\05EDtecs3t0a05r1g3:e0t8 \target\\D0c2h0e2n8.\E\dDUuDEdGe0BjS..D Page 1 3 Environmental Laboratory E02-0443 Tenn River Valley samples OD1Lap3a3tabarasBtfapeitrleef'a!i|: $ortnfe | Tm\3Si3L\ea-Eh33t.i;sntmTa3ira0vg0see7rts\v0ta7al:r5lg5eeyt\Fcihsehm.\dpudrejerIin.psit\oDu01nD2:0o6d2iu8d.eGbg\AeD.LUiDAE.0082S0.Ddun 02 NCioeomtemheondItngo Neth'Date ||| : 0\3\-BDteact-a3r8g0e3t\1t3a:r0g1etS\ucbheermr\-diudejr.Giu\nDE02T0y6ee2:8 .BbA\R0020628.m aBCaErE"pbBaoitete:iteal!| o333o-30n-3003 0.48 integrator: Falcon EFI Sunso0s0.0. coommppouonudnd subStuiobnslist: alalt.etue | mesVenen Ta i CoonnaceVnatrriaatbiloen Formula: Amt *LocDaFl C*oCmppnoduVnadriVaabrliesble Compounts ous WomeRe rer ammonia ae i oO wmmmomowmoms ow | oc Flag Legend - Compound response manually integrated. 1 EtG rion bse 12/00/05 Initial Date. 3M EmonmensLaboratory Poumszatzre --_--m Reson Etzauas LT -- =Bata File: EaT RE STs \\EatargetitargetIc\DhOZe06m2\0,aAkIUaIEeSl00r9,,D. - Page 2 :a + q ped i p= | TR i em = 3 Ji pBee 2 TN Sse ; wm i an 3 i we 8 : Ee od 3467366 300 406 4% BaulCopy oforigins ha RL Enon Losey Posaetan -- Stzonn Tem Arve Sais aO rcna TS ss }I Ei |i J ra he 23 pros com ' i|fp n : | | SME sting 5 154 CopyofOng QC ater reo _-- Revo E0205 Tom. Fuerte Sampis PReaptoartFilDea:te!\\E09tsDteacrg3e0t0\star1g3e:t0\8chen\dudejr. \D020628.b\DUDE0102.D Page 1 3M Environmental Laboratory DLaa3bt'asBamftpiel"ea;: 3S\5L\.BomtLdaH0e0tT:E2a021r-00:g1240e3tT\enCn,arRigveer cLv\\aDlcolSehby6e2s8na[m\AplBdeIsuDEdOeL0i2..D HOSfpIpeSraItE nofro|:|miTeann. River Valley Fish. PrepI1n7stdu10n: 02d.udGeHOj/5sMIA. 20 dun 02 Lo MMCeeottmhhmoeDdantte": Si'bate" | 05\93\-7BD0te0act-2a30r00g0se3t\1cto3al:d0rs1gedt\ucdheesmi\sdudeG&ji"xa.nFt\D1T0y82p0e6:b2u0bE.ES5o\D0Ds002.006126 jo aBE IlinelteFBgaroS cattttooirr!::E1&Fa-l0cT o0n0 Compound Sublist: all.aub qiLo GCoenacaenrtiraateiioen Formula: Ant L*ocDaFl *CoCmppnoduVnadrivaabrlieable omens cs i 1 Qc Flag Legend - Compound response manually integrated. { 551Coy rn Come aginjon, SMEvora assy Pagns5 1275 _---- Rap Eszouss ToonRieVay Somos Be Fe CrAm NES -- Re J. y pre ; mE NE iEE45 : } Bod A Rr : nl - | tivd oi 34036 305 406 ae Enmore ECoc pyofot rigina Cac apes Es Pages [er Tom. Ror Vt Same Data Files \\Etatangetd\utdea,1r\DgI2e0StZE,ibAcDUhDEaL0m2.\D. - page 3 i ot i ie fog 8B PR i& LEE | aoi i 30 4.0 4m 4a ae |i JOT, Bact oy os Laome a"gozer Toots see--rs ----ea--rns-------------------------------------- Reson Eczoues Tom. RoverVey Samos DRaetpaortFilDea:te)\\0E5tbsetca3r00gset1\3t:a08rger\chem\dudesr.iB\\DU0D2E0OL60248..D Page 1 ) 3 Environmental Laboratory ! DLaatbasfpile1a:: S\1\3,EtSsatca0r2-g04e43t\Tetnna. rRgiveerr\\V0ac0ll2he0ey62mS8a\.mbpd\luDeUsdDEeO310r4..D STSpah3ioxBaItanottroe';|| Tm2ei5na-n3.0N-R2i0v0e2r 10:40 Valley Fi} sh. PrepI1n7geJu1Dn: 0sd.udGeH/jMirIA. 20 Jun 02 FR VVCeaottmhhmoednDtate | ; \0\9-EDtesc-t3a8r03ge1t3\:0t1ardugdeetl\rcihenQ\uadnutdeiyjpex:..ibB\\SDTD00220056202.8m ABCiasil'nbPaoattcett:loer!:| 261:50700000803007 o0r48 EET bubzo0s0.0 , TBnteE gtatNor: EFatcon Compound Sublist: all.sub || cGonndceVnatrriaatbiloen Formula: amt L+ocDaFl +CoCmppnoaunvdariVaarbilaeble i cmponss a mem are mn C-- i So mmm oTmommom i QC Flag Legend - Compound response manually integrated. :{ ELxotc CoyotfafOyreifgear : ta "i aM Emcomenta Lasso Pagnss tas ee-------------------- Repesizanss Tom. oe Vey Sums Sg eS wre SR fi q sa 4 oa : ow 6S 26 28 30 18 40 48 5.0 BE Go 68 7.0 78 80 88 90 i] Sa; 3 i lo 2 E ole 1 Mia 3 Pr ii > mod1 : flohree! 5 ExactCoofpOny: lnc sa/ifer Initial date. Cia ve he a Eminent -- vaso Tom Rewrite sumn Data Files \\Etatarget\targeti(c\DhI2e0nGZ\S,aENuDdUDeEjSLrO.4,,D. - Page 3 rw rot % 3 a i3 . 2a! / i i st iJ ) os iborgao Ms 1 i i ! `ExactCopyof Origins) hia VG/anV SE [-- -- een Roper E2044 _ Ton.RiverVatey Samples: DReaptoartFilDea:te:\\E05t-sDtaacrg2e0t0\2tar13g:e0t8\chem\dudejr.1\D02033.b\DUDE0105.D Page 1 : 3M Environmental Laboratory DLaatbaSufpileTd!: S\B\-E3t.stSarig-e0t22\t-a0r4g4e3t\Tcehnenm,\dRuidveejrr.Via\lDl0e2y06S2a6m.pbl\eDsUDE0105.D oSIptnjeeraDItanotfreo :| mT2el9na-nJ.0N-R2i0v0e2r 10:51 Valley Fish. Prep-I1ns7tduInD: 02d.udeCjHrO/.MiLA. 20 Jun 02 MCiosmcmentInfo |1 . MMeetthhodDate Cal Date. : \0299\--BDJte0scNt--a32r00g00e22t\10t30a::r04g18etd\ucdheejmr\.diudejQCrau.lain\tDFi0lT2ey0tp6e2:D8U.BDbSE\T0DD00S200.6D28.m ADisl bFoatcttloer:: 615.00000 J TIanrtgeegtratVoerr:sioFna:lcon4.12 Compound Sublist: all.sub ! CCoonncaenVtarraitaibolne Formula: Ant L*oDcFal C*oCmppnoduVnadriVaabrlieable i omponnis os. Womem win sow lp log) { on Sim Um tem ann ew we : QC Flag Legend - Compound response manually integrated. : Exact Copy of Ci i| Cwuaa alosdoeln WMEnviormentaLaboratory Page 10101278 e-- e e-- e ---------- EE-- -- -- -- Report 020043 Ep ---- Bo it St------ --- wa a RSS bwru hv |3a ae pe i pe { ow sa 3 gEJ i wai o Ae 3i ls w25: on 2 8 al : outCzof Oryginal Cine cagietor ital Dato) ---- Pogo 1201278 J nt bA r D ee Tm ers ;2 IT i 7 2el Enis 2 onl v Ii gE6 orl 1 3oa! $ ; ii BactCoofpOrigyine Lac 12/p, Initial le nin ty [-- FE Reon02003 ---- TennRiveValoy Samples DRaetpaortFilDea:te:\\0Et5s-tDaercg3e0t0\2ta1r3g:e0t8\chem\dudejx.i\D020628.b\DUDE0108.D Paige 1 3M Environmental Laboratory DLaatbasmfpileTa:: \SL\-E3t,otaSrHg1e-t03\2c-a0r4g4e3t\cTheennm.iduRdievsesr. V1a\l5l02e0y62S8a.mbp\lDeUsDE0108.D OIpnjerDaattoer :: m2i3a-J0N-2002 11:25 Inst ID: dudejir MSimsocInIfnofo : Tenn. River Valley Fish. Prep-17 Jun 02. CHG/MLA. 20 Jun 02 MCootmmheondt Meth Date :1 : \03\-EDtesct-a2r0g0o2et1\3t:a0r1gedtu\dcehjerm.i\dudQeuja.nit\DT0y2p0e6:26E.S5T\DD0206.28m CADalilsl DbFaoattcett.loer!:| 2157.-070U0N0-02002 00:48 Cal Filet DUDEOS0.D i TIanrtgegertatVoerr:sioFna:lcon4.12 Compound. Sublist: all.sub iii CCponndceVnatrriaatbiloen Formula: Ant L*oDcFal C+omCpponudnVdariVaabrilaeble Cope -- wow wrewer tai | Qc Flag Legend M - Compound response manually integrated. : 1! $ BaCopy ocOritgin: Gat 1240fon al Oato SMEmviomantaLaboratory Page 10401276 ---- ee--e ------------------------------------ Reso E0z0u2 L_ Tom. Ror vata Sais te FH Eas ti Eo E n RIOR wr Ean r ped ps pe pre J= i oh 4 pe TIT EE ee a we SET PR T1 Efsa i rz iS i biors rE i lp =24i! i ExConayocritgs Lo ayaten a WMEnvironment abort Page 105.1276 -_-- Reson Eczaues Bt ie CaBt. RED PcmY lo bal ie i q va J 1 oi i 13 so: _ Ton. Roar VaySamples ~s mE ul i Poole { os { I= eal 8 |i ExactCopy 6Original Line(lielen Initial Dato SWEnvonmanaLasorstoy Patogster --_--, Report E2003 Torn. RorVateySamples DRaetpaortFilDea:te:\\'E2t7s-tAagrg2e0t0\2ta1r0g:e0t8\chem\dudejr.i\D020629.b\DUDEO0S9.D Page 1 3M Environmental Laboratory DLaatbaSufpile1a:: \SL\-1E. eWBsO1t0a2-r04g43e,t\Tecnna.rRgiveetri\\VDac0l2lh0e5ye2m5Sa\Bmp(dlBeuUsEd0e08s3.sD OSThnpjperDaIatntofero :|| mT0ei1na-nJ.0L-R2i0v0e2r 04:25 Valley Fish. Prep-I1n7stJu1nD: 03d.udGeHCj/irMIA. 20 Jun 02 iCobmemenItnfo | MMCeeaitthhaoDtdaet.e ||| 32\07\--E7AtUusNgt--a22r00g00e22t\02t2a9:r:4g56etd\ucdheejms\.diudejQCrau.l"a1Fn\tDT0E2f0yEp6e2:9b.ubEb\TBDDo0200s.6eo29.m ADIingltebgForatactttlooerr::: 4F17a.l0c0o0n00 Compound Sublist: all.sub | Target Version: 4.12 CGoondceVnatrriaatbiloen Formila: Ant *LoDcaFl *CoCmppnoduVnadrViasrbilaeble 1 fr-- as Wome ora me Ga ae i : ctCay Gr. | Lmoealr" 13sfor aEmiormonaLabor Page107 at270 --_-- [er Tom Rorata Somes -Bata Files ET RE RES \\ELatargettargots11c30h2e06m29\,5c5hDUaDdE0n06r9,,0. - Page 2 os [B12 {o { ol ' ols ale ils 2lo a8 6 3E TAN us Blo BIS Ele Ths He ale als ale so | Bi EI 3 . 3 3a 3% 36 3 j wl Th | po i = - EL BatCopy eg Ling 13refor Co SMEneamona asso Page 828 EEE EE EE Renzsus SE AAAS Tw ww1 LL ee 3. Rd Tame io 5 Eee | oo i Bi : | pe ;: i Eats gas Lianeaffoufor rgd? FR _--m--P--VDV TM DOAoOoA--o _--_A--_A------ ,,-- , Report 02044 "= Tom.RverVataySamples RDeaptoartFiDlae:te:\2\E7tsMtuagrg2e0t0\2ta1r6g:e0t7\chem\dudejr.i\D020629.b\DUDE0127.D Page 1 34 Environmental Laboratory ' LDaabtaSufpile14;: \Si\-2B. tWEsoLta02r-0g44e3,t\Tetnna.rRgiveetrA\\VDacOl2lh0eLye2m5SaBdmYpuBlUedBsEe0s12r7..D SoIpntjeraiDtnaoftroe Mise nfo |: |: mT01ei.mJ.aUL.-R2i0v0e2r 11:23 Valley Pish. Prep-I1n7stouInD: 03d.udCeHUj/irMLA. 20 Jun 03 i MYCeeottmhhnoedDnta|te | \27)-AEugE-3s00c3a0r5:g35ecidudtejar.irgeQu1ra1nt0c.0h2T0ey6pne2:9\5B\aS0Tu0D2d0e62s5.zm DACila}sl DbFoaatcttteloer::| 1736.00-0J0U0N0-2002 22:46 Cal File: DuDE00SE.D { TIanrtgeegtratVoerr:sioFna:lcon4.12 Compound Sublist: all.sub |{| cCeonnaceVnatrriaatoiioen Formila: Amt L*ocDaFl C*oCmppnoduvnadriVaabrlieable Compt a more wre ra (a i 1: _ 3MEnvionmentalLaborstory oo ct Copyof Origin) GEe T iaafoy/or -- --_--PMmmAAlemAA AA Rupr Erzauss ++ Tom. RuerVally Samples Bt Fle ares chm EE BED rz SE TE RT al ii pe pd io] - ! Ed i ga {[I Ei i 3.00338 346 36 iw := | p--oe 28 Ee 3 GAwaL 1afgos 3MEmronmenisi Laboratory Pocatisanie _--m-- Rapoza mmm-mW;e- ee ------ += Tom.RueVaySais Fle rh EE. os ra ls 24 Ea = = i. | we |= H ii TBepse rT) :: ; Set og i i Lune. satiolor EAA Deen --_------ Report 02043 "= Tom. RiverVatey Samples DRaetpoartFilDea:te:D2UD7E-0RDuSgS.2D002 11:06 - rage 1 3M Environmental Laboratory DLaatbaSmfpile14:: \S\LB-r3s:taWrEgLeLt5\0t2a-r0g4e4t3\,cheTme\dmu.dejRri.vie\rB0v2a0l7l02ey s(a3m0pl7e5s2) .b\DUDE00SS.D oInpjerDaattoer :: Sfp Info: m0i3a-J01-2002 Tenn. River 07:02 Valley Fii sh. 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RieVaySamples ee het etmsr SEe T e RES re a TS SS J asi | I Ee dE i| ppesd 3 PoE 303203436 306 i: wei i i po oe Eos 3 Te Te ie 4% a Yo SMEmionmsmaiLaborsoy ee EnxawcctaCopy3ofOr/gi0nal DY rasbtierar _--nm------------ Report Eczous BR A -- nF tartare i RR AB va Pra ro om i we i Lie ue 3 5 : 2 PI com [ pet vot } $i ore Bal : i _ SM Envonmentl Laboratory 5 afl stCu of Origa: Cry Puetitere -- _--P--M--M--_A--AmNA---- Repo 02003 ~ Tom.RiverValSamples RDeatpaortFilDaet:e: \\2E7c-sAtuagr-g2e0t0\3ta1r9g:e0t8\chem\dudejr.i\D020629.5\DUDB00SA.D Page 1 3M Environmental Laboratory LDaabtaSmfpile14;: S\L\iB:tsCt3ar3g0e2-t0\44c3,azgTeemtn|.cRhievmerduVdaell)ery.Sia\mDpl0e2s0525 B\UBEO064.D SOTnprjeraiDtnaoftroe Mise Info |: |: m3i0a-0UN-2002 Tenn. River 23:51 Valley Fish. Prop-Iin7stdu1m0: 02d.udGHeOj/irMLA. 20 Jun 02 ! MMCeeottmhhmoedDn:tate :\: \2B7t-sAtuagr-g2e0t0\2ta0r9g:e39t\dcuhdeemj\rd.uidejrQ.u1a\nDt02T0y6p2e9:.bB\SDT0D20629.m DACilalsl bFDaoattcett.loer!:: 31280.-000U0N00-2003 33:46 Cal F11? `bubzooss.o | TZanrtgegertatVoerr:sioFna:lcon4.12 Compound. Sublist: all.sub i CCoonncaevnatrriaatbiloen Formula: Ant L+ocDaFl C*oCmppnoduVnadrViaarbilaeble comprante ss Women wre meen aan Go) oC Flag Legend M - Compound response manually integrated. ii 00 Copy Dg "ontc 12fefor mesm S SM EmP inent LaboR rato AiiY Page 11801276 --_-- [re [EE ---- Ft aetn A , NE os = ET ST o : nu | pos worm am wo fh :i pb= 8i 3 I. If 22: re EE:pt : rin 3 ; LSaCas 1roi3nngf0,o _ SM EmM oomenE ttLaw soo oweseomoyace 117otar6. _--Mm--PM--ASm___--e--e-- Repon E020043 "= Tom. RoverVatly Samples Bt Fle San SEe EGA rvs Pa 2=3 ee ow i wel 2 i 5a pu 7 i PE) | | i 8 ont { sil ! ea 3 i t aCory, LfHrL 5f,oto SM Enver Lavoro _---- Repo Eozous += Tom ResvaySapien DRaetpaortFilDea:te:\\2E7t-sAtuagr-g2e0t0\5ta1r0g:e0t3\chem\dudejr.i\D020629.b\DUDE0OGS.D Page 1 3M Eavironmental Laboratory DLaatbasmfpileTa!: \Si\oaB. tCs3t10a2-r04g43e,t\Tecnna.rRgiveert1\V\aBclOl2he0ye42m5SaBdmRpuBlEedsEeE0s06r5..D i oSIpnpjerDaIatnotfreo:: ec Ino | Tm0ei1na-n3.0-R2i0v0e2r 00:02 Valley Fish. Prep-Iin7stduInD: 03d.udGejHzY.MiLA. 20 Jun 02 MHCoaemttmhheonBdta"ce Cal `Date. |1: : 3 30\-\0B8t-M s3t0a0r5ge\ 2t\S3\aT.tE4SaE6rN gCetHe\mc\EhdsedMmejs\aed.eusdeCajAlra.yiBDi\olzDt00:s2209B6U2D9onwE.e0b:0\SDS0.2D06.2m9 AbIlinsltegbFroaatctetolorer:;: 21F9.a0l0c0o0n0 {Target Version: 4.12 Compound Sublist: all.sub i CCoonncdeVnatrriaatbiloen Formula: Amt +LocDaFl +CoCmppnoduvnadrViaarbilaeble compounds tas Kom ou er a (rage i Somme mmr om QC Mag Legena M - Compound response manually integrated. ] eee: a i GHC 12fiofor ta Duty _ T nn SMEmrE onmentlLaborR atory Tm EE Report 020443 Ste rs Na chon r ie REA a G8, +- Tom RiverVlySamples rz 1 oa L TIE IR TI ao ee ; - "Th {PElss3 ne[3 3.0632 34 3 ies . aa mm . 24 = i 22 FEE xt Ce; 0: Digingy CC ltl [2role Daty -- SM EnvionmeNntlLAborsiYory mm I. 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Prep-I1n7stJu1n0: 02d.udeCdHrC/.MiIA. 20 Jun 02 mCiotmeenTtnfo | MMCeaetlthhDoaDdtaet.e ||| 2\370\--EA3tuUsgNt--a22r00g00e25t\02t92a::r54g96etd\ucdheejmz\.diudejQarul.a"in\FtD10T12y0p6e:2b9u.BnbSE\oT0oD2s0s6.o29.m ADIinsltebgForatactttlooerr!:: 31F4.a0l0c0o0n0 Compound Sublist: all.sub , Target Version: 4.12 | CConndcveanrtriastbiioen Formula: Amt L*oDcaPl C+omCpponudnVdarViaarbilaeble i Coprnie r mr we oo) { rn prvi irndi oil | ge Flag tegena M - Compound response manually integrated. i :E at Capes ge litna (2loseef, WMEmonmentalLaboratory Page 12201276 rmrr-------------------------------------------------------- somata To orveeSern ES rs RT 260 fe nn2.0 ; ho i- SE i kvnol I E- IN : STE. 300 328 3 Tie wm :i i # ii Ree 3467368" 306 400 4% ner-- BactCozy Cihas,Pre --_-- Reoneszoss ae Fe SAE NETS - @ Tf 1 88: " ii ERROR SR ---- "e [I r 2 bor TE em HF oe 3 . ii ant uz 0p GC (afiolo `ital Daty 3MEnvironmentalLaboratoey re------------------------------ Reon E0z ous Tem. AvervatoySampes DRaetpaortFilDea:te:\\E2t7s-Rtuagr-g2e0t0\2ta1r0g:e0t6\chem\dudejr.i\D020629.b\DUDEOO76.D Page 1 34 Environmental Laboratory DLaatbastfpile1a:: S\L\-E1t.stCa-rdg-e2t0\2t-a0z4g4e3,t|cTheenmnd.udeR)isv.eriV\aD0l2l0e5y25SaDm\pDlUeDsEO076.D OSIhpnjperDaIatntofero ||| pT0le1ma-nJ.UL-R2i0v0e2r 02:03 Valley Fish. Prep-I1n7stduInD: 02d.udeGjHrC./WiLA. 20 Jun 02 {ComMmikeenItnfo Wethod |i | \\austarger\targer\chem\audesz 1\D030629.1\D020629.m ACMlaeslthbDaoDttaett.lee! ; 332707--0AUuNg--22000022 2029::4865 dude3z.l CQaula"nptiTTeype:bubBzS0T0Dse.0 | TDIianfrtgegeFrtaacttvooerrr::sio1Fn.a:0l0c0o0n40.12 Compound Sublist: all.sub CCoonncdeVnatrriaatbiloen Formula: Amt L*ocDaPl C*omCpponudnvdarViaarbliesble mnie -- mx or er a ae) i ve fay Dm me Sm ae we hw Qc Flag Legend M - Compound response manually integrated. : i asic: LC ie E 12fofor aM Enmronmental Laporte Page 2501276 reetee ------------------------------------------------ Revo E2002 TomRuervatay Samples ate 115 EAA iB EEE [ ES RR i ial i! pwael { ou om Le 48 ze 28 ae 3574s Ta Ele Tel ele ws Ye AE als ws vie : aor com Cr |: pseel -i i hod CokE i i pes 3 , Tae 3 3 a a ii p2Iy: Ra]" bo 5 ancy, AC (a rofor . 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" SY page 3 |i 8 3o) } Ca 3 de am ae = ron om i! pvril I pe Fay 3% tig PP : by | a RE Ru iy 3 | BCaoctnCopy; :, Co fo A Enon Aaboray Page 1301278 -- Repon Enz ous Tom River Vey Samples RDeaptoartFilbaet:e:\\2E7t-sAtuagr-g2e0t0\2ta1r0g:e0t7\chem\dudejr.i\D020629.b\DUDE0117.D Page 1 34 Environmental Laboratory ZDaabtasfpile14;: S\1\2,EtCosotl50a2-r04g43e, rT\enrn.arRigvearAc\ViDaOlc2l0ehy62eS-amBm\dpDlueUsDdEOeLiLTr.D SO13pE3e0rTDaIathvoderS ||: Tm0oi1wa-nJ.un-n2i0v0e2r 09:33 valley Pion. propI-nigeauIDn: 03d.udGeEj/ixMA. 20 Jun 02 HCeoTrmocmmeondItnfo Meth oBate |: | y3\)B-thautga-r3g0e0r3\c0a9c:g0e9t\dcuhdeenj\rd.uidedsQu1a]\n0t2T0y2p9e.:b\EpS0TD20625.m lBCiasfi'bbFoaatcttteloer!:| 1&3.00-000U0N0-2002 22:46 Sntegrator: Falcon ETE bubso0s0e Compound Sublist: all.sub | Taxol Version: 4.2 CCoonncdenVtarraitainotne Formila: Ame L*oDcEal C+oCmppnoduvnadriVaabrlieable 1 ante poh men re a bar) i 3 vto om mlm tm am eam em 1 QC Flag Legend - Compound response manually integrated. : actCopy on nCc r (2lolo 0 Eminent Lasoo page tsar2r8 Repo ecz0us ---- TomRhrvatySamps i it bedor SEENe ETS 2 CTS SST wi sa i pee i wm om my om ie 18 Te me me 38 ae us lee adele 5 als ws wo |a iLoRgiE B oscm be TTR i am " Bari.on actCopy of Orginal Ciuaalsole SM EnvonmentlLaboratory page135.1276 ReponEozouss ir bit RE NORS3 fi ] yu Tenn River ateSamples wr It "a RTA g eR es wi IE Pog FE : Bie 3 i 0 Seuttegy ign C[aait 12/40/02 I EviormantslLaboratory [-- Repon 02043 NN Tom. 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I e--e------------------------------------------------------------ Repon Ec2.0u43 ~~ Torn RiverVly Samples RDeaptoartFilDea:te:DU2D7E-0A0u8g3.2D002 11:06 - Page 1 a Environmental Laboratory . 502-0443, Tenn. River Valley Samples OTLDpaaajebtrabastnfapoibrleeTa:i:: Sm0\i\13aB-5t3:s0t-ea2r0eg0ed2t\t0a5r:5g6et\chem\dudejrI.nis\tD0I2D0:70d2ud(eDd2r07i02) .b\DUDE0083.D i CShoibmeomein0It2nf6o | : Tenn. River Valley Fish. Prep-i7 . dun 03. GHMLA. 20 dun 02 MMCeeattihh'opbadattee ||: 20\73\-mB0gtU-sL3-t30a00r05g3et0113\::t20a11rgduedte\scs.hiem\dEQuu1da5netj4rTT.Eyipa\:"D(b0Due2bIR0Do77.o00s2s2).n.b\D020702.m DiIinsltebgForatactttlooerr!:: 61F.a0l0c0o0n0 Compound Sublist: all.sub | Tarot Version: 4.12 ii CCoonndcenVtarraitaibolne Formula: Amt L*ocDaFl +CoCmppnoduVnadrViaarbilaeble cme : ry ma om ! 3 rom wm mr are me oTeo S oesmpo ens pr wane evonet i 30ErvirmentalLaboratory 53261CopyofOriginal GC (p2nfya tay am -------------------------------- Ropon E02.0043 +. 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Page sor275 e --_-- e ReporEnzous Tom Rar ValeySaris i it tba AES . he TES 1 [x i out wR SISTER ae a ee | i pe i gi i 5 Www a i [3 : 4' Lm=el yf BLaicnttCozy12apv 0for wm be SM EmvtenmenttLobes -- Repo Eszouss Tom Rave Samp Data File: \NERStargettarguti{\cDOhZOeBLmEA\,dAIuUDdEeOOdSSr,.D - page 3 wa Tr 3 bo be be 366 300 400 44% i= qi I~ ;a : bo : i wl ifs | EJ i i! 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Tom.RiverVatey samples RDeaptoartFiDlae:te:\\2B9t-sAtuagr-g2e0t0\2tar07g:e1t2\chem\dudejr.1\D0208128.b\DUDEO136.D Page 1 3m Environmental Laboratory LDaatbasufpileTa!: \38\0E4t0stargeEt0\2t-a0r0g43e,t(cTheemm\,duRdievjerr.1\vDa0l2l0e8y12s5a.cBpl\eDsUDEO136.D SoIopnjperaDItanotfreo::: Wisc Info : m1l3a-AUG-2002 12:14 503-0443-38040; Water Samples;Insnton-IGDL:P;dud6/e3j0r/.0i2; OK MMCeeottmhhmoedDn:tate :|\\2B5t-sAtuagr-g2e0t0\2ta0r7g:e0t6\dcuhdeemj\zd.uidejQru.ia\.nDt0T2y0p8e1.28.B5e\TDD.0208128.m DACilalls bDFoaatcttteloer::: 133-AUS-2002 1.00000 06:44 Cal File: DUDR0106.D i TIanrtgeegtratVoerr:sioFna:lcon4.12 Compound Sublist: all.sub | compote i ma as Home wre oes ban ei Te Se Tan en om prt=piey Som UIE om omnoow ------ WMEmionmentaLaboWratoYry iii 50 Cay ii L aa12n fooyfd Pago 191of276 f-- vr TomFray erin Data File ES \\EtstargetitargeI\tDOi2cORhIZeE,sE\AMuDEeOlLIr6.,D - Page 2 i ol sr, | NE : 8 Le 48 ze 28 do us 4s Fa Bis bls 4le ws ne 78 80 8.8 90 okajo] ' | wl | 8 8g 0.8 dan is PR 3 bo lgo=eo I" oe: ro si aa5.13 ola Hr istoiey A r-- e ------------------ EE---- f-- Tom Forney Sams Bata Filet \\tatargetitargetchem\auuesr, (\DOORZE.ENNIBEOL6.D Page 3 I] io wo TE CLE i fa o i: we RR ES ry DokE CofE gettin [Er a 12fref i Purashtaten _--mm rosonczzons [EE ---- RDaitbaotFilBee:te\\EEtastrarngetE\tYarget\chem\itchy.bi\\I1TC0K2101341.3D Page 1 3M Snvizonmental Laboratory Dp1ar5taaBfaiples !: \\Bcstarget\targec\chem\itchy. 23 4eovez002 13:40 \1021112.b\ITCHY0304 ESSFpoIacIRtnef,ro ||aHtOa3-0a43-#a-1; Water Blank; MemOeHtE1xc:rascecsofnis`oct 02, via erento MeVSiotorhRhoiBbdeeat'cee!||: B31\13\h-BeNtosvvta-a03r0ge0es5t\t255a::r0g86ett\ecehneym\iitTchyBG.uin\In1e02EH11o1n2a.o:bP\p1zO0221s1102.m , RBDihftEePnEatcatRteosnr: LR1ahLt0t0o0Tn00L Compound Sublist: all.sub 4 Compounds. ass. KEPRT DLTAT MESNOSE (ofa) (gfe) i 1 Erion ebony PactCopy a: 2, S1C [lof intha So: [-- ee---------------------------- [r-- Ton. Evervay Sarin -- ETE Bata File: \\Itatargetitargot(\iIcO2h1e12n,BsiAtToOnNy,, - Pace 2 ; wd iF j oe J pd - ik i Ba i 4 : wl wm i root 2 i 00 EJ SM Emcor Lost ~ FR Ca: Be 12 - Bb Pag testers ------ ve To rn Bata File: \NEtstarget\targetichemiitony, (\ORL12,BAITONYOM,D. - Page 3 i= pa iol {Top EE ol ror CL 13 rofs ronan ------------------------------------------------ -- SE --, enn e Bin: N NEe R pe ATgepchemi chy. 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FFsosenswwaesa TT--=TP EET Em TF OFT TOI IE] + [DFoensasDla=a Pesan = SRREOTOTNYSTTTTATS TETI SI TfTTy SA 1FR FaTvue-byosyz Fea = a [TA H TSTTNATTSI S rr T [FeeoFssRsEesNsTeEsBE EomN]S CI NTRTRSFETE RI T E ET TTRyr | [PeaNTse DEamna c TT I (P rr CoeneennTm= mTImNT YT TNHINT -- S Do curmlfSs inesan carmen _0JRG 3 osocaio_g14 Tov puneDAL pulphy a? 1b Eats Ton eon a)110Cone Do cwaerHvLiozTiao dM1u0m2s0nne nasm00H ietnerDemLeN FA l core vonL350 L111 1-UMspesnemnl commolaz ots vonZon 11512emC | como Taz Cru ADsr emi Ia D i rumt 20 corn TOL Le n/m UMC i ner Resse3000 mses P= tumgc1) convon amee100 CortaToOliEim Le 1X 1 DAOC wooLTl,OMS Coi7Spiing Standard 04 2032 = 77 AoponineGane |ponAmeosases 100 C1T8o: aTtuaens doarsKAO Gt wim sien em C0113TonNidingn,L116 20 cnn 20 5 eove,ma 4530 olgdet SB, Sedze rr Te te _ WMEnvionmentalLaborstoy . PREIS -- rr eeee -- ee ------ Repon czous Tom.Ruer Vay Samples eesSR03L033 Tennes"SsaempeleRLiovceatrioVnal1,lCeaytSaanmples. - p 3 : CC eTnE pose [3TAY ATATDTr rATeA AaeTIAeTIE g e Fe I r"18 FE aserSE ammwCTT IEe TT CI 1 CA0NDA3R 5 3 E Prenr sa [E--F oT Cees Boom TI TT EA DT IE y TE d915% J! CCeosesnnasl----INSTATH OTeETTQNT TTEOIIN Caeas hoand INR TIMTS TRIN 3,i: 3 FCaaeelI---- TTNENTS ST TPARSRTS SI T Ta | REPT Em A SY BSWAS TA I ny 83% 4 1 FCeeeaceessTD--aT a NT TSRI TSCTT ROT Fates T= NTE WY TTT Te 13s% 3% F[eosvesTBa=dTNA LTCT TT O OTP e --1----8--4303 e RErTIIE E n99 i; ECPoormesrs T= E = qD qE T ET F I T TVT THT ITS 9 =o I 33--------e3 cpmaim pun vol coro028G i Romero ZT 3/4rawpeBlyliy5021 sn TLA tCn : carondgn.Lo11OAL attenTOK 2 war HillDTCHS coteTon ke L120 cots tonL35pnla sf)BL.0Nomanlo cmoslQz cosTonTim o0H 2 ONC. rursoa ld lre) ed3 como Taz coin TonL23ipe U11K 2a C : croniesBDsm rome 1 enmmnegen(110.02inc. core von Rs ld 03 net weroILT-OCD0S a7Sn Sans [202277 CEES sominancoreLg hominids cone on geLAo /C Torn 82OC weno a A820 vi 9024Erp Coli ! TNA-HYLS OLateuty. tate rs ek wud el oe Psat Re mit Ga Ret 0) hiner ou RAATSELAH IM Enviomental Laborstoy Pago 2201278 ------------------------------ ReportE02.0043 Ten verVay Samples ReLg)g3 Sample TLeoncanle:ssLeaegReivMeourthValLloecyatSioanmpSlmesa os- t . I i CLIP i it Een RR Frrauu TT=og" f EU TP POI ATR TF 3 Ee I EE freeamaeL-- A Cyt Ay| EeEY C CO T I S iy SR fe |! [FPerzsueaalnTS F=ER EN LYER N TAS Se HE BITS INIA TS NTT S TS F i i eaehong NOI TNT SST HST EE FFp oesest Tbaone e TIA Oh TCTTe 3 E TPFO e J NA e e a f s5; EEEL >) KS] EE Be 7 A 2 TEV [8 vl 3. a CeowrTaonns.i9d0a0e kbinrseatpcencablidn] Denl crEotsmen701O16S1=L9n1p Cn 5 cwsvnlZiddpn La112).02tine Sot TOL52m100 wacoMIL= TOCDus cao TonM55 214 19(VC. cord on0i Ok(o Whenn 0 cuanonoT0Z. cu on2L2 o160/0m 2em. Eru2DrnmOernyee 22. owonmn [oz TS ol TON2S5pen 14ACIC un [90 {000m1 cos TonDn Ler1%.03an wae Hii-6 ToeMUS corr ioSamiarei00 0202-71. cullr61o19n)0s0cirn0 Aopcte cone opr pm sesscuul cron20110, ptt Ton Oc litt Le wiroz icstgn m tmeobnaoyp mea cA50b0 uf)Bid C18: TRAILS Outer oust, wr tm, Amn He ere reselD OlSEEi sty new SM EmionmentalLaboratory Page23301276 --_-- Report 020443 ~. Tom.RiverVatey Samples mre 0103 TenneSsasneoe RLiovcetroVna.llceuytSearmples 3 Bi [18 B 3 FFTn reseazeeenseDT o= sral A PT 7] ATPt C IM O oe S fr------t ------ -- 333 Fa oes E = 18 H PA s B ------------ A 3% i FEFFaraEassceeNcnTiTE ua=gN SSNTTITTT TTI OPI E 1eRTrEyE -------- R43 NS i [PeF rweecer oTT a=aSN cTNN HEAC NE TOHSmCNSrES TeSIEE SS SSIS S----t ----------{--388 F4}R EFereaeemeTm=e HMOT INS SETI INSS T TAT PCT1RSA------------------ nbo 3s {o3d% FFn rraeceE eTTd == NPVIONAENI RTSIASSI NATA(GAO H ----P --------3O3S5S i! :i [rr aeE=K LE I A I At UTs H E ESI e1 A 35 PA5 Fam = RN : FCarsaemsJ o o S V i H e iN C e I Tooh30e i curren, emeace, [ET 3 soo Qe empl SD ts v0 ml eaten[30g 1 (1 Guerk rte TO SCL wai ili - TCLWIS coteron10 LOIKes(4 can ong S52Con cme l0Z cosTonZale 180 Orin nO pe J 1 ! amo Tet rortBeODnsme Drom IE anvon Sper 11L-com ann [30__ 615.0) cut cots x2Dn snare 0 0 02032 = 77 cwniosnI 200R0e1rT10O,MS sommiancoep.01_rman JUL co on208 193 tem rendition Lo Qn gi won mea_4590 wl0 BE ron 1e 5, Tt -Ae SE . a 500. lyfro, uldild nnl HsoeiLibd(SE Orr 3 vans ----SM EnviroRnmeAntaMlLaEborNato,ry Pa ---- ResonEnz ous Tom AverVay Samples woRet zi0143 TennSeassmeepReiLveor cVLaalalgieeyoMSonaum,pnles - fE raeawr eu[eAonTTTL8 Ar EU TATNAEn B AATP 7re R o r] y FfeoeessCe=rIy, HA AECOTC EE I 1 O AETT rF I 0 R et rag He + am ------. ASSe 4 frase onl yCTT TET TENNESIT TR STIN oI -- EEE TES {i PFseussB=o KN STNRINTS TNTSS TET TTA TT 5TTRSi------------------17% FfFa rreae emeatT=m=mrSIT TIOTPIAT STCES NTI SIN NR ---------- EE SE E eC W "Ty t ----4 EE CoawnsT= TITWV IN PTI Re T |-- gY 3 corona (p01 02H, covsnr0850 1 oreo GD naepmnibidip]Shel Ean 70 doeLOD cara on(240 fo 112/00Une. ats TOLQu 130)BAP wae Mii -6 TOC Mus coronene pits81Uonemelo otto Ton jm. La 1K) 03 ton. wamefoz lsVonZLi o1110n 2 mc. cn To (Domsi n[n 0 seug) 23 } reruns300 indser /9 ott vonLAS Lr 11/0C2C.. canTm3S 60) cots von23 L011)B) cone wecioMiTlOClflR ys ca? SpiigSumanrai08(3032<9 carts vonL3C 164,2M3IE ovvoen1r6c2o0:epLhLee 1Xa(maEnNC10001 can Dosen am YS1r0yuv)nt oBits --- OlTn nn SH SAS" ton wirespke aShep SW Envionments Laborioy Page 235of276 _-- Report 20043 +. Tom RiverValSampes ore iat TenneSsasemeeRLiovceartiVoanl,lGeuytSamples an Ga A ) ls FC ecesr ,TA7TRSAYTEAC A0T1A7 aA0 re wt 4 ETEES d 7%AA 72 N4O EPreaess T= Fosse fmm NII IE CIE Hor HE nnss 5 ------ 3 i FFCeerEseeCeseTTd=l=lSSTIAHROE CISISNTTAITNO OIL SATTH SI --IN--R) -- m --s IN1 1j [FreseenTsTN==TNSIINNIT SETSTNE IN GT S CNaIrNdrT e f3 EE Te PE E E F 1 R 0S NRT OIgn EPSR pe ; FacesET=tW TTIE WR SN INE ET s IRE0 Foam:T= A TCHf i: FEraE sms TRt INe TEe T n eg S A $R35 3 772 3 i common Slam_112100 auc cas sro _02R(, > 1 somreei0 900 riearpnenMgdrie| sire TONIC2000 RL cowns oono12l0;g-(8yT_(CyDHtiSnt Enh TOME( S DOOLk. care ronL160on cote 100Ti D0 rsLo ry os TonZan Oleg. (Erne ID san (Drom IO : i como Taz ermineZODsande _tune20 eo ond 10 1610 enc. canrenlion [Eigen0) : cote 1S 0) n 18 Do t nC carsangsuw01 02033=17 weroitlsPls-(r0oc es) conn QUS0T 0Fe Apri Cone_LOIC Amtsacna_IC) ul onlene IC GUN CG83:G TNAFs LT onC carne von0000 30,30)wg_Avh = weonie: ma SA0 Jv hed 3155000 rs SOtEis GcarityrelaSvsia t ros _ sm EnI vionmontt Laboratory A -- o Page 2361276 [JA Eh T= oa = Ah Re 3? HLTA dl JMR ESS Ells sl 33 | 12RE3 NE&E4| [4 Co; iiTtg UNREES i[RasE Hd HEIR EA | } HR OEY | i EY IN 39 : | 131939 HAs 3 Le ea I IPANU RECRREEYE FERN 11 Ra Ta Cf HIalE ResontEnzones Tom. RhaVatey Samples srS3.i01) Tenne`ssete RriCvuearrveVcaflolreemyatdiSoanmples ~~ Ii CFEoST TE 1 1 a T 2 TAT7eTeaTBVuAPoPT m mrL e E e TohJali | CN EAa ipaPrZo r|7r7r Vor TATr r 7 0 gedemntoe] O y S rrr rr r r rrr Cee~~rrr rr rr r Por CIrr Ner r r e r | C rrrire r rr e r r e r rr rr rr s rs r1 Cr rrrrrrrrrrs re rr rr r rrre rr erNs C Co or C C rr rer ers r r Ny [ catvr Lpulo 3i once10200 Tatabputizn 358ml U cosvendme agesaw aio 21-0106 Pl . Sasa ron 50a A2seah --coi sis onlin pcr OY [HES caro on S021, Z8lA hs ColaT0AQYSS NV iGeas (UL somoreakT__ conTn10500200 cwtonio TAZ Gran 32 an 2_semeid ovine LUEL5G cant von[395 Zur 1 1% Lerman mm 82 eessit) caSon2oTen ns cvuo Le001) Fuses oh wawo [411-0 TOC Ploy eu? sph anes00.00021026203 033 0 ramenieol BEL cars ron LSID 35,87024 canon 530 33,32, TC orO x aaS 1S zsgoresn one: mn06306[viied 3m SaE GIT Torr 1350 AE ar Gv sore q AUS _- MEmronmenta Laborstry Paez rar on czous Tom Basar Non GLPSPE Columns ExtractionWorkshest Or A FE PrTepDats e: o6f202002 MetthiodRnovaianl: :BTro5.8-Ao4h54s0-- Co [mee] we| a | a. foe| om| mer| ow [memes lemoussoms| wom| Samer | wm [memes|| lszousson| som| Emer| ow | ormeem|| fszoussor |am| Emer| wm [ome | fszoussos| ams| mer| ow [ome || Jszoussora|ams | met| ow [eon | lezossssso|wn| hemer | ow [were|| i leousoomn| wom| tm [ow [mom loess | wom| tamer [ow [mom | lessen[wom| BEET[ow [meme VU lmousoms| son | tm | ow [momen lesoussue| sons| mie | ow |mom] | frsoussor| om | Emr| ow [eormee| | llsezrozuosuasssosos||s_om|| Emmaerr|| owwm[[omommeen|| | lemoussso| som| Emer| owJoe U lemousosn| som| emer[wm[oem || lseosusosn|aomm|| ammeet|| ooww [[omemeee lszoussson| som| amor|W|moeme| EE ree 1 I A ir =SN 0%conditioncolumnwith MeOH; CF washwithmili; C.[_fitersample; ees ene at cle eblosadect, fad wld i" Deu,Net mAegntTouos O ctor wus bard oft of mrs wed WT ay dy gros en gidelnn. beeen A a Repon E02.0083 eeee--------------mm _ Tom. ver Vata Sams Non GLP SPE Columns Extraction Worksheet [Ere [mf] pArreapiDatneis: OK7002 StMuadtyosNuRmevbiesrion: EE0zx04e43ss 613 ive orGescipton | fered used | sphomixused| volume Comments hove | om | Bier | ow [orm louse| som | BET| wo[ems fwoussor|om| mer | ow [RREESTT mousssnn| om| mer | ow [WREST fess] om| Sma | ow [emEeRgT bh I ~_rTT Crrr CIN po ! I TS 1 rrrrN rr IN or TN rrrN ! 1 [TN Lr_aci_onS_eps1(W|Ghorey 11] ncoma wi ox ai Kier samplec; mtintr reso nee oR TTD. lh . = Re-axhachon gf saws. ab 12h txtrition wos bused off of on E35 med WT vers aaly vse 0s 0 puideling ott Ubwty SMEnvironmental Laboratory Page2utotzrs :EiN | EEE] ETnEneRlTy2 o(lEToogTan4 -Cf HWEIE GL E lL R D:o HfiEleEs [EETiE]gy, | CWOHNEEE [E[wTalLi]fa | Hina] JA <3 " 3 13 ;MpHH nN : EE 3 _ Co 3MEnvioomentalLaboratory 58 |[FTIR [TTT )- iEl Fi Rl [0] wl SIRE EERIENED ENDNOTE A St ETE [TE] 3 (EEE EEE WHEE OEE C LW u GLE [[Tie GE = BRE TEE, lia heats - dE a - RA 2 oS g i kd I | i HH Ts CH H E - 0 f } : Gii fi: ESE i SF 1 AI : i Si Si h ml : i I:1d coal { i . if | oa HA AH Hh Ha A 1 1.9 I ] Tt jl il il i bs EE-- tH | gel HTT AS 5ES HH HEEEA|T |i i fh err! iy ddeaaesi | 2 ln 4 fee M El n ReponExz0us Tem. RarVally Samples | - i SINGLE COMPONENT PREPARATION LOG oa: 3) iC1 BPorogkerNeo,._3020050 i owcwsor_Lppn Spike ly so Wiles: PEISEOO, pam pip 4 2 PEOS sosnumeer_23 (202-233 i oe. loovt sane AA 3 | ; Consomsner overcomes : Putty: 22 ppm - Poco: T-- % [---- = i monASIA[yuwi Z]o y (PlhG Toc ples) B | FiniVoume: ml FinalConcentra: pm y swrssotocaion___ JM Flr Expratontais_23 Noy Go : ii Batol 4 : 44Cle [-- AY a lez gBl z = 3 SM EnviormenaLaboratory page 48276 ee nis rename J| MU L T L COMPONENT men PREPARATION L0G BookNo. _02002 Description: Yich Soke saver MeOH 1 DatePrepared:__(p [IX[ 0 aMTr#a :TNcAeGo 1(p praparecBy.__CAC | StorageLocator __NC Expintonvme___11/ 331020 ee ere EE |e TEETE Ihrem PRE a|eT BEER [oocor-17 |3ns | vrele3 [TK ES Tu7 4 f[oorrems ' Pros E [o pP fe pl 03.001 -4 [3S8o3n4 [2EI03 Slat | SRE Qa om ! 11 1 Ce ee i i ~~ ~-- t | t ---- IE = S A be =TTT] er T r I = Lol Zit Ect CopyofOrighal oo [.Tel ens ---- ee apn Ezous TomAarne Somos FE -- 1 1 SINGLECOMPONENTPREPARATION L0G PE poe__COC_ 2 1 omeown_logen Su.ebd 1 + @0d - Pec . our _0205023.5~, 1i a. 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H[r b--o g--ua - ont a - - AE oo Po2520278 rensizous Ten. vervaySain -------------------------------- - ome_2 Feb - - woe MA SINGLE COMPONENTPREPARATION LOG - owes _ECJY3JPEOA . osm 9030-030 e,_zn Pagan8o5 . 1| -a wen 0.579, swan 9/4 ES 35% = - a omwme_Q5YSS S MeOHr 4-6007 Hi P) 1 resvome I5mL reece 230pen eo some od Tle om one 28 2h 23, i !i a - - Eatonetoigs 2E =20e00b2ec Reviewedby. a plan. ks. ala MEntommera abort Preasserzre Reson Ez0M43 + Tom.RoverVaySamples _--_----,e-- . o SINGLECOMPONENTPREPARATION LOG " ou 3 Muy D2 sPoacokorhe,_c8z8en woe MIA . ouaice: PERS /| - 038,067 (C4Fy50:K) a a. suckmumoneTCR 00017-/0TC2 R-3]59 (othe) fa] [a TUNE__ososs, 1 sara q1y `" `Concentration or Pury. ooo | - rose 9 Z 3% 0.434 __J5, Other Comction. [= -- Sn o t MeOH, TH A=) rscoeenen__19, 29P3ht * commen 2 Fy " a] . oS yo) . nO enone 23 Noy 03 a . oo Enver aborsory pagezsactzre eens _ ren virsi i c=Leeoe Tce`SINGLECOMPONENT PREPARATIONLOG m--a--y - oescrptor EC nevi porn. Lest san eects {i- ees= io ssn A 2 opm Jog i - 1{. `Comectec AN -- arumber$e H,TNA-4530 iw omvoume__1 Don) BR -- lpr ew 08e eeeufpsler i" yy" 0 5 veinHA mers J -J om roeSais TCR Receipt & General Information eR? Joma VoRswwwes sess | re Ee Condon whepowder Sew cout | i e Ee en ns , wees i [Ewemabyinmmm OweEmemd ___ Cheowaly owe | S.J i I| i [rowicinean wes Das Checwdby(neaiome | Comoe wenwww EBoama m3 ensns n T Joes Dale TCheckedby Dale | ERE DERoerm sponas ermis i Ergot iss FOTIA 1 EE ippingcomments:NOTREGULATED, 3Mshipping IO wn ps4 i C3 ArchivediSubstance Not Avaliabl|e [a 1 sot prey nari f-- Repenezzaus Tom.Ror Vata Sampins TCR Receipt & General information ' fm Tower m EW EE Feiss26 a Ta TT 11 EE | -- i F-- rEeTre ---- 1 Em www CGrosommwoonsaesds eiJOF k Feast Dw nt a mnmre Fr in en47 irosB iCosdoe ima swcga uaasbtarscoi |i;! 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S ES SH ;: oma ANNEEEEmuEEEE op SSE oToii 8E ANmA EEEEH N En i i Soe 3 ANNEEEEELEEEE i VRS || aiit kSel ni :: HER LERRERNINNER FEE 8 EE sa LIT PRE ERTS RENS ET AL |g o em n : 1 INNER YEE, : ELAR EE i 18 3: _--mmm-- rs -- PRECINI SSLi EEEC ET E e Ti E lr le es fn i a g| EAT EAAAARE 3d 3id Bg a H HHT H ilN | SUISSE 2joo A2 C SeW oH E Ne a | g|7) EEN iiLsEG [E 8 WEE E S | : =r || EH i or S04 3A ld Q3 ul |1g8 lag dignasse 1 . 23 gl A ar a He TFSI SS wcwowesiewsy Paezsoum sha jel Ede] & 3 AE / Sy Sg iso : 9s HE a EE a T Isi 8FS N H 5i #i 8B: ISANSNEER nu EEEE 0NY | it 3i0] ||iS INCE AELS] JE] [aH]NdeE BEE2a LTTE I yA BT hi Ea i WS LLL 22 2 t 5- 3 I aTl 13417]] {| SEE CURSE | ;?-~ ! 5b Soln4 ; BI ISSETT WY I NS 1451 S"l4G28 FPA umBrrEEesTsainTnn jEEisGR Ene dol fn [1] X S| fd I Er E Hn] BL z e584 203 5158ES LE 84 ml 3| |N T opp SESE o8 ii t SE gnHg H ; i 2 ANNE Em eT . LiHAI:IEAS NECH ErEoEeErrane WNYNUg|| OEg H SS T nNSe 18 | [EEE 4] il] BEER 858 Lb ITU TT 3 ET : 1 HEH fT EE | ooo ceHsHs SEL _ ~ l1"ll dE grwl ! \| B5 Ls _-- m-- -- woe vomit i yl53 1 350% : JJ94944444 A] A i4o3 e] =| =3 | 3% {44.4444 dls ; {d2DT FT=| ISS hd581 2=Afeaaases iN ii oo 2 gi=< SHT TT] CHEE r NNTE S| NYg ; 3 NoH ul LIT] itbog 3 aE n3il 18gog78g | j[i BEE veA | IEo G| [TTT] i 8 sd eee |] c | 4 BLiE 11 E- 51d" j SE [7] = J = e| l= inl$ 14 386] 5| 13) |ZEEEEseesy | cuooo : ER FRR I=i= 2 BERS | ih LA 3/1 | ASB FF a 2 TS SS SS 1, i A essan _-_ - -- - -- Report E02-0443. .. Tenn. RiverValley Samples sd I 1a S igS ESy RITTI ;: IS i{ {FAANNEEmREunEa EmLavii ii M 8i 3% SSE rrr WC & S S oH HH Vx=| iii oB r o ne h $3] | (BLA ] tel] b 3187d333 D [EBr E Ee LEL[[H7ag]] {| EE on | oo SRLLLLLITN 219, leelelglga||| Cuol L453eSsS a NC RlSk > >> oo IM EnvironmentalLaboratory oo Page269of276 Report 02.0843 ATTACHMENT E: NOTES TO FILE Tem.RiverVatey Samples 3M Environment! Laboratory Page270 ot 276 _--mmmm--m-- Resort 02043 Toon.River leySamples _3M-- ENVIRONMENTAL LABORATORY Note to File Project or Study Number: E02-0443 LIMS Number: NA Affected Data: D020626Extracted, (Fish Tissue) D020628, D020629, and D020702 "LThe following samples were mislabeled nthirrespective shouldhavebeen labeasl1e-2d", The lst sas follows: sequences. They wereal labled as 1-1" when thy 'DDO02200662268E:xiDraUcDtEedD:OSDSUDanEdOODSUSD,ENOTS, a'Dn0d20629: DUDE0OG3 and DUDEDO9s, D020702: DUDEOOG2. BA2lllaonkfsth(eSBf)iswhetrisesdueonseamwpiltehpcraecpharSaatmiopnlewaLsocdaotinoen,atntht wsiatmhecatcimhed;itfheerreenfotrtey,pWeaotffeirsBhlafnrkosm(caWcBh)laoncadtiSoonl.veTnhtis aswrpacescnidoeotsnoaefnfysiiWsnchBebteohirenSgWBBandsaaltyaaznedcdo.SntBaTihnaeeredWfwoBirStehxaiannmdtihSniBLnagrwgeterheMsoaaunmatplhlyezoerpdrSewmpiaatlrhlaMttihoeounCtaphtrfaoincsaehlsysstanimcdpalleassr.eqiuFneodnrecpheessn.derenatsoofn,thtehere cT3.ohnetaiisnherti(sCsouelusmanmp2l)e,shwaedrweataenralaydzdeeddi(nCtorilpulmicnat3e),Eaanchthfiesnhhtoismsougeepnairzenetds(aCmoplluemwna4s)fbiresftwoerifgtwheadsosuetpairnattoead nto tltrhaiebpelrilpcealdtiewcsi.atthes"TahMreeSw"geeiwngeehrrtaetaesrdpeifrkreeocdmowrtidhteehdhtiohnmetohsgepei"nk1ea"tseorl(outwMisSosnofiatnhrCeaolFlsiuosmhgneTni7es.rsautepedreatpsthhiesettism.e)I.t sTnhoetsaunmtpilleCsathlautmwe6rethat "e4Tnhedfoigesnotiusssuaentahlayttewacosnucesntdratiinotnh.eexTthriascwteadsfidsethecrumrivneesdwdausrfirngom ptrhelfiimsihntairsysruaensgaem.pfilnedwiintghetxhpeelroiwmeesnttamountof `T5w.haes e"xEtnraabclteedd"fiinstihsesquueansttiatnadtairodncsuorftvweasrhea,dbut.0tpwpabscnuortvecaplociuntl.ateTdhiassppaoritnotfwtahsepcaurrtvoef.th calibration curve and e`5Txhceee1d0inngg/tmheLsrtiaenrdasrdbcyu1rv%eaponidn2t%i.ntThheEsxetrpaocinttesdLwaerrgenoMtoeuxtchluSdteadndraordmCuthrevceuhravedsa21n9d%tahnidr22in%clduesviioanthiaodnsn,o bneogtahtsiivdeese.ffect on the dta quality due 0 the point being surounded by at east two passing calibration points on a Recorded 5) 7 z[Tuo| WMEnvironmentalLaboratory Page [_of. Page271 of276. ------ [SS ee Tosi 3M ENVIORONNMEENNTTAALLLLAABBOORRAATTOORRYY Note to File ececeeeese Project or Study Number: E02-0443 LIMS Number: NA Affected Data: 1021112/River Sediments eeL\acbtounrtheoedSanmuplgegtCeSd)wearse Epermfoprmled tfoorehceovievsekr Seedimedntss. Hoowmevesr, tehe noermoan was noa sed TT2hheisinamcpolnesfwsrtfrmomethde seqcuoengcee1n0t211ony.ht re er le chy062 ar ok put fhe reportable nyse, 225% XR Ar-- Date: JFPL ec MEnmtonmens abr Pageof. rae 2orzms _------ nts ema I3MMENEVNVIIRROONNMMEENNTTAALLLLAABBOORRAATTOORRYY Note to File Project or Study Number: E02-0443 LIMS Number: NA Affected Data: D020812A and D020812B. AtEneT no8t 1S0 i8.2i2 rDtUr DreUeEpd BcsAr,,i Te oeoe2pne SrETp proTslnr Ieso,eeee dEaAeSma le Seatme,m------ intotwo separate sub-sequencesafter LC/MS analysis to simp datlaainalfysiys. .hToeneeeeaittetenneetr24170 To riots SDmx .heeloolr. nei LSees amsierrafnesenltoe tttt aiaanmm SSSmEySaminioln reroinrrte a Ao ins vSovw o=Tgr mn Er ak EESE erin Page3 of6. _--_-- Repo co20u2 -- 3M ENVIRONMENTAL LABORe ATOy RY Note to File J-- Project or Study Number: E02-0443 LIMS Number: NA Affected Data: D020626Extracted vs1Leeqtuh,eenD2cO0e200h36a.d206e5Ex,txriiarctcneiddgCnsVecqsueeinncceslptuhdeeesr,se hweTeshre.e naAntlelasontfyahcEeexdtsrCecCtxdViCswCetVreCcqOuurVavpnptoirliesaaernnd.dghAellheeessubmlsenenaqvuaeecntitfeodFuinsfdhenTis `Append B: Dats Sumnay Tale, Recorded By; Ve Date: 20 sw Eveamers aso PageYorb. Page 27st278 _-- Roper Eazoua Ton RiverVatay Samples _ 3M E-- NVI-- RONMENTAL LABORATORY Note to File Project or Study Number: E02-0443 LIMS Number: NA Affected Data: All Data N1ote: This stoexplainhow the quantitation wasperformoednthe dat. Tcihnaesstsean,ntciherisegihnclawelvihebilracctuitroivnsecpwuoraivsnetdswoanwsee,reenhte"eDrdiesidasibbltleoeddt"hcieunrqtvuaehnptsoioitfnatttwsiaosrnhesooawfntdawawrreeecroavnrederymthooevec0fud%rfvreowmatshethcuervaenaclaylzceld.atoInn.manTyy al dLneoottewursmeeindnd.atcTiuhornevseoefptophoieinnsLtsOtGhw.aeehasdti4l nRceclouvdeerdieisnttchhaaltiebxrcaetedieodntchuercvretcarlicuolratwieornse,<ho2wXevteher,sotlhveeyntwebrleannksolweveedlsfwnetrhee 2Ilnotwhoerraanwedgaattaivtehavtcaloumeears faosmigtnheedTaanrgeexttrsoefmtewaproes,ticvonecveanlturea.tiTohnsestehavtawlouueldarneocramsailllyynobteiqcueadndtiuteatteodthaesira very oafbaquoarnmtailtlatyiloanr,gaerveaclhueasnagleodntgow"itBhLvOeQry stmoaelllirmienaatceoaunntys.poTsshiebslee vcaolnufeuss,ioanl.ong with values that are blow the limit Recorded By: Ff eg. SM Emronmentl Labora Page S of6. Page 275276 _--_-- [e-- 3M ENVIRONMENA TALALAOBORRATOORYY Note to File Ton FerVoteSampen Project or Study Number: E02-0443 LIMS Number: NA Affected Data: Fish Tissue 1cL0entthreisfaugmepdleorparsehoprare aptroiceosnheonfd shtahkiesen(sSpo5a.fsTo,thce hnomuogiewfnapdirgoozcneaas0t(lSioeopo4nsn,the e homopgenati dheovmloogpeendotdsuraignagn.th homogenization proces.To Fomagenwtaes the sekenvistokne soon ZR Recorded By; -- Z Page of. --ME SM Ew nvonneo rsLooaw ay eslbemy rearsregaerzzerosm