Document ZJBx5b9dROrYzaEQxwbzowbbp

AR 226 _ 0675 CenGtrPho eone:A(R 8n14a)l2e 3y1.t8i0s 3c2 aleFaxL:a a(8b14)oc 2rS31a-i1th 2e5o9orCroO il(ee8g9ss4,)m ,2P3A1TI-e 61n5Dc8I.0 SSS Analytical Report = Fluorochemical Characterization of Surface Water Samples Port St. Lucie, FI (W2363) Centre Analytical Laboratory Report No. 023-014F re ee sr emeeee ct------ Testing Laboratory Centre Analytical Laboratory, Inc. 3048 Research Drive State College, PA 16801 ee emer ---- e ------ 3M Environmental Laboratory Contact Kent R. Lindstrom Bldg. 2-36-09 P.O. Box 33331 St. Paul, MN 55133-3331 Phone: (651) 778-5352 DS Requester Kris J. Hansen, Ph.D. 3M Environmental Technology & Safety Services Bldg. 2-3-09 P.O. Box 33331 : St. Paul, MN 55133-3331 pace 106s 000986 1 Introduction AcRneosauyllisclaafrreoLoarmcbeoPrptoaoroertreiSddLef.s,rLuItcnchi.ee,(aFCn.eanlTtyehs)iesfCooenfmiatrseheesti3uMsdyoEnfnusvmuibrrofenarmcaeesnwstaialtgneLeasdbaotrmoapthloeersyp.rrejTcihceetivsiea0dbr3ye3Ce0epnytarre . `Specific fluorochemical characterization by (LCIMS/MwaSs) requestedforall samples. liquid chromatog/rtanpdheym A total of8.`samples were mass.spectrometry Thesampleswe rep repagedandanaiyzedby L CI MS IM Sforthe foll receivedfor analysis. owingistof uorochemica ls: + Table 1: Target Anayss [Eertuoroociane Sufonvamide Iprosa----] TfihleewaintahlCyetnitcraelm.DetahtoadpurseedsweasnhvetarleeididasttheedbhiygCheensttrquea.lTithyedvaatlaiadvaatliioanbplreoattotchoisltainmde.resusare on 2 Sample Receipt iTn`hdcoielvliesdcatuimaolpnlsdeaastmepwsleewreceronsetunaboitmneisrutspepwdleiiernde.irnedCichveaiiidvunea-dlf.p-lcaSusatsmitpcolcyeosfnwoterarminaeetrriesocanenidvepwdreoosrnee0nn5to/e0td3pi/rn0eA0s.letrTvahecedhs.aeEmniptglhet 3 Holdirig Times Theanayical meihod stabity ofthe analytes used wasvaidatedagainst a maximumholding timeof ofinterestforlongerperiods hasnotbeendetermined, 14days. The * Pacez0es 000957 4 Methods - Analytical and Preparatory 44111 SLaCmpMlSeIPrMoSparation for LOMSIMS Analysis rLSeaOsmiMdpSulaIelsMScwheaorneraeil.ny.aSllAdtfroerapyth-eamdsiwleiitheexr2t0roa0rcttuioloonnof(f2Ss5PaE0m)pmlowealwsassoudstierudamnsltfoheiropesrudelpfoaatareeCsohvuetSoPsnEamtcopairreensmtoavne,. TdmiehstechaacrnadcretldriwdaagnesdwcatohselfeSrsPctEiefelocuctoeladunmawlinytshwia5ssmbyLthLeoOnf M4eSl0uM%tSedm,ewtihtTasnso1l0t0irn%ewaatmtmeeetrnhtasncrouelts.outne.Ad T51hmeaingposarirtegoensosonf `concenotftrheastamipolens prior toanalysis. 412 SampleAnalysisby LCMSMS hcIonelHuPmuLni.Cd,mBzaansbeaedlqopunhoatsohefe,eaxthtferafaconifstiahnejeicatnreaedtlaayinendefdporafsotrhseeadsctthahtarirooanucagrehyraspihlcaiqsauemidoi-upnththaesoecfcatviomlem.malToFgoorleaopshwitgcy oKmHrniPgodaLwnCnliacsfmepcpleoarrmraaptuoirouoennsc,d;sEh,mSoielIanecrVmcleuuodpilbirenosscgveiauradroveeteslodiacoanhrineazdpmeidiud,caaanfnlirda.tgaamEtcelecenduclrteardto,sepamrnaedyaindsesteenfcoatrerdaa.nloyyoliponnesgrac2thewadircdateerrainesgiice nooff agains standards. (AaSnHaRelMwy)lz.eetStah-mePpalcskeaasmrpwdleeHrPee1x1ea0c0tsxH.PLAtvosanyssiat5s/e1m6wc/ac0s0oaiupnpedrlaetnoeoamdh2evddMziecudsrbioynmgaMsssSelUMetcSitmedabMertSewaeMcelSno5nw2ams5u0os0enadnofgo bISne2fc3oar0mu0as.teionoaAflnpuunirapncoclseepaslnaoabnllyles.issTthawenedsHarPpdLeCrcafuornvrdemseM.dSIonTMhSeSm1ed0at0thao,dishsuosiwenecvdlefurod,redatneianlycAsaittsisascnwhdemeb.nttrenotcefoyr parametecrasn be foinautacnhmednt D. 5 Analysis 51 fACoar7l:tpihobeirnctaoctamilpobonruanldiosncoufrivnetwereess,aTnahleyczaeld:iabrtattihoenbpeaignsiwneraenpdreenpadroefdthaet a0n,a2l3y,tic80a,l s1e00q,ue3n5c0e, Gplo0om,teelndatdoorn1ce0oa0ec0ffhincpoioei.nntt(.p(1p)U)asnTindhgecoirgnefesiapcrioernnestgeroeofsfsdtiehoteneqmwumiaitnnhai1itoantwo(en7i)oghnwienvrgee,rsdhuesotetsrhomepiecn,oendyce.nAeirrscaoesptontotaaoeenss `curveis acceptaifbrle 20.985 (2 0.970). Callao standardsarepreparedusingthesameSPEprocedureusedforsamples. `iarcrooautnghicooeuntntchtrhaeaecrtkeaisniaotltanyisnsisd.+ersew-qeuroeen2fctaen.ea0laycCzt%eaudmapplevraailnuoced,eicails (ecvbeirayntadeeftotvhe.e sstaamnpdlared.jecatnonyss) Fortheresutsreportedhere, cafbraion criteria were met. Paceaces 000988 52 `BEexlxttarraanccttkiisoonnbbalnankkssswheoruedpnroetphaarevde aanndy taanragletyzaendalwyittehs epvreersyenetxtarfaocrtiaobnobvaetchheocfosnasmapelreast,oTnhe 1 lowevel cafbraton standard. Fr these samples, he exacion blanks wers compan lhIeanvveselicmaaeninbyrtattbairaogrnektsstaaninnadlatyrhtdee,sfoaprnrmdoesfaefnitteeaaktnnoomrwentahbhaoinvgoehlisetvhveelelnsoawmlwpeelvreeels.acasAlogbaviaannt,aoln(yhzesetdbalnaadfnaekrrsd.esvnearFcyairshiopghrsamples presented here the nstument banks are compliant. 5.3 `SSuurmorgoagleastpeiksesarenotacomponeofnhte LCMSIMS analytical method. 54 Matrix Spikes M1a0t0rinx gspiukseisngwaelrlecopmrpepoaurneddsfoorf ienvteerreystf.ielMd asiarmpslep(kexrcelcuodvienrgiebslaanrkes)giavtena icoAncetntraatiyon of tSShaaemmrppelfleoerseMsaChco-cuw6re8ad4teHmmahaattdisPspFpeOikrSeecraotevceloervvieeerlsisessbciegotniwufediecnanont7tl0by-eg1rd3ee0at%te.errmitnheadn.10AltoitmheesrtChre m`sopsikiinnggleeveclr,i Fied spikesweroalso propared on sample MC-601Hfo allcompounadtas concentaton of 100ng. using all C. All compounds csohmopwoeudnrdescoovfeirniteesrebset.twFeieenld7s0p-i1k3e0r%ecinavtehreiefsieladrsepiaklesso.given in Attachment 55 AhDleupfsllaeimdcpsalaetmerpselseulsts(einxcAltuidcihngmebnetrBk.s) were analyzed in dicate. Resuls re given along with 5.6 MirLelaclobyvoewrrayatoetfrowr1a3y3s%sCpoiinnktterhdoewli2t5Shnaagml.cpolsmpeipskoe.uAnldorfecionvteerrieesst faor2a5aoned2r5co0mgpalu.ncPsFwOaSrsshhoowmeedsa 70-in3eac0hLC%S.Resulsaregiven alongwitthe awcata 1Attachment. 57 SFriaoelumdgphbllaeanhkyRpseealrmacpatlreesdcacCornoisdmisgmteeedwnaotsfsaedmpdteydtcoontthaeineermsp.lyFcoornttyamiinelrlearnsdoafnatlyypeze|diwanlefrheiStaemreed. mraenponretirnagsmit.heothersamples. Thefiedbankfor his sample cidshow PFOSabovree 6 Data Summary . "Please seeAtachment 8fo a detaled isingofthe ansyica resus, 7 Data/Sample Retention `Samplesae disposedofane monn aterthe reparts isued unless otherwise speciied, Al efolledcetrrsonmiacindtaatianeisd abrycCheinvterde,on retrievable media and hard Copy reports are stored in data Pace ors 000989 8 Attachments 81 AtacAChrmaneCunsatdy 82 Atacment:Resus. 83 Atachmen G:Matix SpikeRecoveries (FedandLaboratorySpikes) 84 AfacLOhMSmISeRawnAnticDaD:ata 9 Signatures oni7.F"aery,Rarer G-peraions Manager . KevinJ oy,VicsPresident : sDahteo imagzceo ote OverLabMembers ConrbutoDnatga KDaavrieansSmaith ---- Tiffany Proctor pacesoes 000930 ANALYTICAL REPORT OA Centre Analytical 5508Rese Drive, StatsCaLlloag PbAoT83r01atSToH-2r31i-0e3 sFR,YSTIAncT.A ------------ Westen samp orn os iegam Egmirnmaas C0 =3 e2 aon uCEEnt t F&ia Const sn iemst mk 25. T'8 tsn `Meinod Detecson Limits are approsimately 2.5 ng. for PFOS and PFOSA and 7.5 ngfor POAA. rosa =3o E=E= roms p2=a =%Ee - i 3--Be-- em -- 000991