Document Z8b695p8n6wG8vNqgdgJ5qxDV

Ou ui Ai ssSuryancSeat mrpelicngt Tlaasnk (100672) AmeAnR1dt2oRme1vie6sio-nnN0ots0: 71 7 `Efecive Da: nealg,e1o9f939 Amendment 1 to the EN-s Quality Assurance Project Plan and Associated SOP's for Empirical Human Exposure Assessment Multi-City Study Sampling Task To (Confidential) June 16,1999 Prepared by Battelle 397 Washington Street . Duxbury, MA 02332 . (781) 934-0571 APPROVALS "Dom Gar Sampling Task Leader : "RoBsataenlneaSBuablmTpaklQiAOnffger VBiactelsleNPirkojleatsManager S) iiAC Obl `Battelle Program QA Officer - we ow Di Te7-4-99 owe 000491 QFuael rAsmweanSPormte lio005) maenoareDor e_sr--ei50 Amendment 1 to the Quality Assurance Project Plan and Associated SOP's for Empirical Human Exposure Assessment Multi-City Study Sampling Task To (Confidential) June 16, 1999 Prepared by | Battelle 397 Washington Street - Duxbury, MA 02332 . (781) 934-0571 APPROVALS a SumTmoikLneadger "RosannaBuRI `Battelle Sampling Task QA Officer Var Mek Battelle Project Manager SBuanegleaPr(ogOQbA Oeiy - Dae a T 7-9-99ee owe - 000492 QMuaaliiCtiytAyssSuuradnycSeamPprloijnecgt PTlaasnk (N100672) AmEefnfdcntevnetDIat0e:ReJviusnieon,No19.991 Page 20f3 Objective p`Trhoeceosbsjeesctthivaetohfatvheisocacmurerneddwmiethntitontthhee QfiAelPdPpraongdrSamOoPfsthies tMouldtoic-uCmiteyntStcuhdayn.geTshteoisneitviearlalfield survey resulted protocol for the in several issuesthatrequire field study. either amendment or inclusion into the defined Protocol Changes * sSteucdtyi.onIn11a.d1.d4iatliotonong wtihethsaSmOpPleMs3h-iFg-hl6igdhetscerdiibnesbotthheolfatbheleisnegodfocsuammepnltess,cloalbleelcstweidldlubreing the `produced for "Trip Blank' samples. TchlieenQtsArPeqPuedsetscsraimbpelsetshewiclolllbeectcioolnloecftesdafmoprltewsfooratddhietiBoanttlealbloeraCtoorliuems.buTshfeaclialbiotryaotnolryi.eAs tthe include the clients `in house" environmental lab and a third party validation lab. f`iTehledaadcdtiivtiitoinesso.ftThoeesnesuunreexapceccutreatdessaammppllees ctorinptlreotlhae lnaubmelbienrgonfcoomnentcalianteurrsecsoylsletcetmedhadsurbienegn giimvpelnemmeanttreidx.foSlalmopwleedsbyfora B`aBt'.telSlaemwpilllescofnotratihneacnliuemnetrwiiclallciodnetnatiinfitehrethsaatmceornruemseproincdaslto a cidoennttaiifnietrhbeustawmiellncuomnetraiicnaal i`dKe"ntfioflilerowbiuntgwtihlelncuomntbaeirn.aS`aHm"pfloelslofwoirntghethvealmiudmatbieorn(leaxb.wPilOlTalWso Effluent ID: MC-101B, MC-101K, and MC-101H). Section 12.2ofthe QAPP indicates that samples will be shipped at the endofcach day ofonlelhowuinndgrecodlsleacmtpiloen.s iTnhaegliovgiesntidcaayl aatnvdasrcihoeudsulloicnagtidoifnfsiwciulllt,ieisnamsososctiactaesedsw,iptrheccolluldeecdtitnhgisover from occurring. The amendmenttothisprocess is to store the samples on ice overnight and ship them as early as possible on the following day. Also, the shipment ofsamples on a. Friday during a survey REQUIRES the prior scheduling ofreceipt on Saturday at either the tdehsetnianratriaonngefamceinlittsiemsu(sOtHbeormMaNd)eotro stheendDuthxebusarmypflaecsilittoy.thIefdseasmtpilnaetsioanrefascihliiptpieesdotno tDhuexbneuxrty, business day. * SOP M3-F-4.0 Defines the labeling requirements for the spiking ampoules.Therequirement is that each ampoule will be labeled individually with several piofeinc forme atis on. The aacmtpuoaullseisz,eotfhterheefoarmeptohueliensfoprrmeactliuodnesmualsltthbies riencfoorrdmeadtisoenpafrraotmelbyeainndg raettcaocrhdeedd. dTiroecftalcyiloitnattehe efficient and accurate labeling and spiking,a different approach will be initiated. s`Tthoereadmapnodulsehsipcpoendtaiinnsienpgaeraatcehctoynpteaoifnseprisk(ii.nc.g, saomlpuotuiolne(psotloraargaencdonnteauitnrearl ocromsptaonudnadrsd)s swtiollrabgee box). On the exteroiftohre container all required information will be assigned. On the individual ampoules, only the nameofthe compound class, e.g., polar or neutral (for polar `compound spiking mix or neutral compound spiking mix) and the intended matrix for 060493 QMuuallitt-yCiAysSstuaracnycSeaPmrpoljiencgtPTuasnk (100672) Amefredcnteinvte D1attoeR:evJiusneilo6n,No19:991 introduction will be affixed. This process will reduc the time required for labeling Page 3of3 and spiking while ensuring the accurate introductionofthe proper material to the sample. S`OThPeseM3pr-oFc-e7d.u0reSsecitnidoinca3t.e0adesstcerpitbheast trheequpirroecsetdhueresafmoprlceolcloencttaiinngewrattoebreawnidpseldudwgiethsammeptlheas.nol pFroilolrotwoinagndthfeolinliotwiailngfisealdmpsluirnvge.y Tahdiisscpursoscieosnswaadsdshehlodurbsettoweseanmpthleepcrooljleeccttimoannpargoecerduarneds. saepvreorcaeldtureea.m mTehmebreersuslttoofdtehtiesrmdiinsceiufstsihoenriesdtuhcattitohnisinprpoocteendtuiraelwciolnltnaomtinbaeticoonntwianrureadndtuerdisnugch scounbtsaeiqnuienngtpsousrsviebylse.coTnhteamuisneaotfigolnosvuefsfidciuernitnlgy croeldlueccteisotn,heapnodsstihbeilpirtoyhoifbictoinotnaomfimnaatteiroina.ls 000494 MULTICITY FIELD QAPP AMENDMENT 2 FISH and MICROLAYER WATER SAMPLING PLAN 000495 hQluta:CyuysSsuarayrcSaemrploineg plan Task (4100573 ) wand splTi eaeltots Quality AssurancAemPernojdemcetnPtla2ntaontdheAssociated SOPs for EmpiMruilctail-CHituymSatnudEyxpSoasmuprleiAnsgsTeasssmkent . To (Confidential) July 23,1999 Prepared by Batte1l5l2e9MWaersitneSeSqciueinmceBsaLyaRbooraadtory Sequim, WA 93382 : 360-681-3660 APFROVALS T Sepe Tak LT oner T R RalSampling o Task QA Officer l - -- m-------------- "MBaarschealNrisehcioskaManager Dae - SBawalaPryogam QA Officer Date - 000496 ST er geWsE Objective Thebesamends he QUPP40 S07 devsseeches ve ir amples. `Protocol Changes . iia hk . EE i a) Eee ---- > Samp Sr, = TE US ape eB ww TECISH Ee = L = na L =pe= --a --T -- a 000497 QualityAssurance Project Plan MudiSitu-dyCSaimptliyng Task (N100672) [Copa bredorfo (1 or) Sore packaging Amendment 2toRevision No.: | EffectiveDate: July 20, 1999 Thor Tio Page 3017 e v6)atSeionrs eotlaevsovo wei)l Es SS r|acinescbacekpaecek dppcoelcyrceoyhiocnrksebrmo| s tone 0) Not phnfornMseCdity Sry + Tabl4eisamended beloinocluwde bulk water,microlaycr,andfinfishsamples. Tabled.SampleTypes 20d Numberst Sampling LocationsatEach Cty EE -- , C[ Sowe |SumpleT PANrman(PAY)o |Ine Lt[acLtIrLoe]i ]suratsages| Wr ier [Samply eTealPEOSGadupliesi) NS TL | ---- boy) [RepmepN nL [Bulrkwaar|e SF[smaiplleB:aonTks:olTPoteOltSePrF(oiOs oGopohes) Fick Spike.TolPFOS !~ I iw ST Boor duplis? | 005 [7003 [70 PIGS rare [|FeDdSomEFmENe [| TC woio [F[ eilddBukiTsom&lPRWOorSry GUL E e p r hve) [FelglePaN [TL Sh [ies wer | [ SampS lTeoaPANlp PFS(e i plc) o TT T outlow) [FibopnlnyePsApNe FAY - L Te T] ] | Sap PEN IL CTC FEN (retailoutict) FiiGmpllea:rTeor] P&NFObSor(oian duGpF loicpatle)ege F T PHr L I e I----] -- TTTe |FNSoeiareomBapspwkloroepssaN borer QC roFOFEETP 1 I POT [ mSamplemneimnd ne 2L 2 5eT d kes).E P T TI T E-- f-------------------- eae 000498 QAuatyAsSirtwuadnyC cSeoPmrpol ljiencgtTyPslakn (10087) AmEefnfdcnteineD2a0t:Reuviysio0n,N1o9:991 [SPapBpuetEN eTomulPEaO rediliss) [TPT are dof rw ----r------ v {{ r popeF ee N --d_ --B_ m-- k 1 r[ma-- oe r N 1 ---- [Ffih||E Semple ndm borsory e Orga Tour| Se arisaad brio GC rar OXra waars | | me|| [rer TM6 |_|[| = polars: PROSI. FQOAvRa,tPeF:OTSOAR,IPPFFOOSSKA,WS N= mevil Eveof L OSES OF, FONI ECTFSE AmT i + Table is amendedbelow toincludebulk wateraad microlayersamples. El H oi = 8 iol Matrix and TablSe. QCSampbylMaetrisx. eRe [Lab [Spiker |'Fied 7] Per TTTTwos [fFeorplaaayrerPWreorS|-- ~ 7 --3 --T-- o-- ~ 1{J o--r qy| [--F Toanrga rWreorsn a[lGuy) FF PeN[T O16 TT Tm To Jo 1-1 ITT Tw Eee3 -- thf[Mom ----| eT To To To tm FOTW (affod | --f To -- JTp oT r To wor ror wo] 000499 Quel dswanes rjcPl Muli-CiyStudySampling Task(N100672) Amend 210RevisNioo.n1 Efctive Date: July 20, 1999 [--TearprO=STT [0[0 Tv To] Tegesont P 0 to "aPiMUtreeorR:raO1On0S0nEngOgEHrPRO8S. rar nian Caf pmlbecs inn apyeseofo >sonisecdimeentmt eepi.c aTwiT lobe cr ed oo m lsoo rSigTno Be rio- Organic flaotuonre site, only. P="Dpuoplleisc:atPeFaOSn,aPlOyAosAft,ihsPeFfOiSshsAa,mpPlFeOsS.AA, MSS6; Ne neutrals: EVMof FOSE-OH, FOSE-C,FOSE Amide Tale. Sandard Operating Procedures * Table 6 is amended below to include SOPs for finfish and `microlayer sampling. SECpeoillFlaintSnamFpilingloeofrsWeaVteaSepCtoforPfgoMCsPeehrer]r sGigoninlgSonpdle1n0fgortSeeMianlelCSisaPsrosjeot NACI Fi HyFi -------- neple CSiopninegy Tor ie MART P. re [ColnldHeamatliagonAqui Surice Mierosyer Sipe [VSBLiT0c70e6] [ColneeTicnloin o ikSeleDog STs + Sreeqcutiiroend)7.w3i.l1l ibseaombetnadiendedafsofroelalocwhss:taStceiwenhteirfeicfcioshllweicltlinbgepceorlmlietctsead.nd fishing licenses (if * S0ecdtiPoacni7f.i3c.N3oarntdhw1e1s.t1.N3aatrieonaalmeLanbdoreaasdtorfyol(loMwSsL: /TPhNeNBLat)tseulmlpelMianrginteeSacmiweinlclebseLaubsoinrgataory `Trimble Geocxplorer hand-held GPS to determine the exact location (coordinates) at cach sample collection location, rather thun # Garmin 12 XL system. The Trimble unit will be operated according 10 SOPNo. 3-164. Deviationsfrom this SOP will`be documented in the ficld and revisions to the QAPPwillbe submittedafter the field effort. + Section 7.3.5 is amendeasd follows:Microlayerand associated bulk water samples will be collected at each site where finfish are collected. Both sample types will be collected from `one locationwithin the matched sediment/water/fish site for cach. city. Samples will be collectedas describedforthe whole (bulk)watercollectedin association with the surface 000500 Out scons Ps MadiCity StudySamplingTusk(N100072) -- "EfectiveDate:uty30, 1595 `water source. Two litersofthe surface microlayer (MSL-T-022-00) and 2 Page 6of 17 Lofbulk water (SOP M3-F-2.0) will be collected into ESS (sic ESE) centified clean bottles. + Section 7.3.10 is amended as follows: Finfish species will include largemouth bass and s1m0arlelfmeroutothabnaysos,ifanna umbd erod f1d0ipfi efrecrt ehnatni `dspbelco uieegsin blell.oTnghiencgotmo mthoensunnafimsehf"abmliuleygilils"usedhere (Centrarchidac),includingpumpkinseed, redear `sunfish, warmouth, green sunfish, white crappie, andblackcrappie. The [nionttheeMa]y 14, 1999 QAPP no longerapplies. * Section 8 is amended as follows: Finfish, microlayer, and bulkwaltersampling arc scheduled totake plia nMoc bilee, AT, Pensacola, FL, Port St. Lucie, FL.in July 1999,and in Columbus, GA, Cleveland, TN, Deca ALtinuAurgu, st 1999. * SLeacbtoiroanto9r.y1 iiss tahemSae mplanisnfd golTe leoawd rs:LeMard.erDafvorethSherfeifsfhlearnfdrmoimcBraotltaeylelresMaamrpilniengS,ciMernc.esS.hreffler r`weiplolrbteinrge.spMorn.siSbhlreefffolrearllwislalmapllsionbgeacrteisvpitoinessi,bilnecflourdiindegamtoibfiyliinzgaptrioonb,ledemmsoabnidliczoartrieocnt,ivaend atchteioPrnosjwehcitlMeainnatgheerf,iealsda,papnrodpcroimatmeu.nicatingtheseactivities to the Duxbury QA officer, and + fTianbilseh8siasmapmleenrdaenddbmeilcorowltaoyeirnscalmupdleeMrr..DaveShrefifnlpleacre ofDr. Dennis Daubleasthe i FTmo Key Peoni h> a sarsarswsTorrens--we-- on Gunster Eatielle Duxbury = i -- Ei i flmail] es re oyPadOpersiosMumge T-952-5378 (wor T0488252 ny ray ST io rr er F Eie Fpre aam vgeees SDoosenri aave mo rE v A 000501 QCuiatyyAsSntruadnycSaermpelicntg TlaasmkV100673) A`mEfeectivneD2a1dt0R:mevuieysino2n0N,to15:9|9 MToro y ETe AiChen [RBuo RneEleTICmoTur0mbuse] SeTERT racer a) qi? Ro50o5Kmi6ng13A1vene TUOSET1039 ham) FBoleia Seelnlg Sampler Mico, | nCB oeleucmoOpblW Maurine 4p3s2Se0,c1cracss U5[r=vy] Sequim, WA98382 * Ssdeheliciptvpieeordnyv1ti1oa.o1M.vs2e.irsnKa iigmhmtAdee nlidvn aesrrd fyaetotlowetlMhoswerds.:aMdAidlrclehsmasiecslrhMooelwaanyreaiarnstTatamhbpelleaed8sd.r`eAsllw sbfsiehi soshwhsnl iapmipplneldTeavsbilaweiol8lv,ebrenight * Section 11.14isamenasdfolelowds: Twolabels il be providedforcachfinish sample ducoonuliblqeluceetZenidu.pmlObonecebraltgahbaste.ilTishsdpeollcaaucbmeeedlnostpnertdohoveniadtlehueamFniiannrurfamitfsiohvDielad.tesTacShrheiepsetetic.oonOonndfetlshabeeslaiasmpmpllleaa,bcpeaedlsbwwleietlllwlebeaees,ntuhe affixedto each microlayerbottleand bulkwater botde. . aTnadblpeer9cihs.amendedbelowtoinclude largemouthandsmallmouthbass inadditionto bluegill SampleSource Table 9. Sample Containers, Storage and Type |SuplsContainers"| Conditions, Prvservation undShipping - td orgsCondon FVaipoerpie TsPolyleiearceheouTs Y|alWreap-- clarecritigns-- piroecaci-- seseola.-- _PSciosorl ed som -------- Scourteidcgoenliz(i6-lockbagsd wisp in ubbiewnp. Seta IB Plantintake TLpecisied NopreerSovraGiNoFn). +Tap Tvrawsettrsotmfreeoomtpldame |(cpcrotilfyieed)yljnocr Sneesasblfirohmment ToS sous (cOourifiperdeciamed | Si oT ECT ++ w PSodsteehloratTiaoosn polyethylenejars 1 (eripfreedc)ios Sore coal 0) - + Gffluent Polyethylene jars f-- e ------T-- 000502 MQuulail-itCyitsyuSrtaudnycSeaPmrpoljiencgtTpalakn(N100672) A`Emffeectivne2Da1dn0:Remvuilseyion20n,No1t.3|99 T PGorrokncdhoepsthme i) + Boneless, sinless chicken oKreicgipaenlacchomeanwerT,n | and keep ems | SoreSoa(C ragesot bProerasktasndbecfhot dogs Rego fh sspeepcairfaitcecdoionlesrtso.re. o+ WEhmolemik |+ FWrhoivcebnrgereaedn beans - FOrregsahnoipcprleeasd or flow blasa) Crelgecbreaoncmh,oscom)alulmtouhth | abagls umfiolnpluastmic `sSimelcaltlibloemnocu1o1tl.lh8e.cb1atseisds.afmrEeolcmncdttehredoscahasoccfhkosilinltogewwdsie;lsTlibghenea"cttoeandrdagusectttshepedemcaaicteccso"hrdewidinlwglatitonecMlrSuL/d-seTel-da0ri2gm3ee-fmi0nos0uth.tshiFtaein.ndfish Finfishwilnotbecollectedfromthesitesdesignatedat "quiet"waterbodies. acSlieutcymt,iionsnuamm1p1fl.oe8.ls1ta.onidisdtaehnetmaifdieocautbnilaosend,bfoamlegelrgoiewdxds,i:dnaTtZoeidpialvnoidcdbuiaanligtfsiiaaslhnsodwfisslealabmlpeelpdelwrai,cteshdatmaippnlemi.entAghldaaanbtoeellawrniidntstheitdrhee, unoailrqumueienosunammipcfeilleo.IveDFr,insaihnghdwtpilrfloorjbeeschptilpanmcueemndbtoeanrsvciiaelrllibynaaespclopaooclseesdribbfeloetrwosenheitnphtmehdneatdyoofunobtllhleeobwdiaangygosasfansmdapomlipnnltgih.neg.or Freshicewill beplacedinthecoolerprior shipping. t`ghSm eecftiiei olnd.1Fn is1nhowiti.ilwsleabm ime8g,ehwneeu d.diegtdoh1atm eshdeof.onp) llelyaort2wcos, s:dtgeFt.iesrhmliennegtifhtwhielmlansostibseardeecqouradteedftoortahneanleyasriess(ticm,m2i0n0 Anewsectionis added: Section 119Water Sampling Associated with Finfish Collection * 0121.29-.010,Miaenrdoilsayseurmsmaamrpilziendg:beMliocwr.olayersamplingwil be performed according to SOP-T- 1. 2. LRoeccaotredthsietewaitnfeorrsaomuatricoen,anasdapapprooipnrtioatfea,cocnesfsi.eld log couditions, site location by GPS, observationsofthe fwoartmesr obrodayfiaenlddlvoigsibboleoksu(r.fgac.e,.weather SacacmupmluilnagtiDoantsa, Sadhjeaectent site features that could beofsignificance) on the Aquatic Microlayer 3. +. SRgelitansussepptelahqteuemi)ipacmnredonltaalbylyeorwcsoialnlmgepiclttetionrdgfrrmaiaicmnrteoahlrtaoyuuesgrthasbaflmuepnalnneeld(wslipetpvhreololuxoticmcaaottlielolenyc.t2iI0nngrsitenaplealawstieapdmepdrliaepnsbdowirftuehn.ntehl,e 000503 QuMaluitylAstsSutra-acnycSCeamPiprloijyencgt TPalsakn (N100672) AEmfeectne2Dde1t0emR:evJeiysin2o0n,Nto1.999| $. hTooriczoolnlteaclt maqouvaetmiecnmti,craolnadyewri,thddirpatwheitgsllaoswslpyl.atPeuvsehritchaelgllyaisnstpoltahteewtahtreorugghentthley,wiwpiePtrahgameniSdnoifmat7l allow band. liquid to drain through the funnel. The sampler frame will require support with one: 6. 7. RuSentcadreotrrctdhseoafmuplnlnielnlogifsentmaaircptcortsoiiltmtaeiyoaeinnstsdooacmiapntnlcehiboyltifquisiadun.amopyCllioennsrtg.itnhueestaomdpilpebtohtetglleacsaspplaantde iplnatcoitnhgetWhaetebrotto c 8. Rbeepseaamtpulnteidlatnhdespaumsphltehbeoprllateeitshfriolluegdh. tMhiensiammapllaeirrwsippaecr.eisallowed. 9. Rtiemceapantdhesasmapmlpelredbeoattlicfisceaciuornv.ly and check that sample botte s labeled properly with sample 10. CShamepclkewsiatrhephreoljedcitn-sapneciinfsiuclwatoerdkcopnltaanifnoerrg(uei.dg.anccoeolfeorr)swtiotrhagleeanodfunshdieprmreenfrtoigfersaatmiponlesa.t cpaorpnetpvaerinontexrpi.hmysaitcae4lldCy.aPmaacgkeitnogafaodrsbhrieapkmaegneotfresqaumirpelseusceoontfaibnuebrbslaenwdruaspeoorofathsetrumdayt,eriinsaulltaoted 11. gComuplietedatnhaedchanaticnc-hotefoct)uhsetoidnsyidfeoorfmt(hsc1eiSdoOfPeMaScLhs-hAi-p0p0e2d acnoodloetvhceorntpariojneecrt,-specific: * p1l1a.c9e.2aBcucolrkdwiantgetrosSaOmpPliMn3g-:F-B2u.l0k,waantdearssasmupmlmianrgizaesdsobceilaotwe.dwithfish collection wil take 1. 2. CLoocmaptleettehewthaetSetratsioounrcLeoagndanedptoiaatakoGfaPecScreesas.ding (SOP 3-164) as claosposssiebletothe 3. sWaimppeltihnegelxotceartiioonr.ofthe sampling bottle with methanol. 4. Submergethesamplebottlebelowthewatersurfaceand unscrewthebottlecap. S. tmhFiialcltrttohhleeaywmeaoctueitrshnoboofttttplhueelbblyoetdttuilrnetnioisntughpet-hrseiagmbhopttl.telTebhpoiatsrdapel.rloelcetdoutrheewwialtleernssuurrfeatcheaatnwda.tselrofwriongm trohteastuinrgfascoe 76.. RWeicpaeptthheebsoaumlpelweibtohttilaecutnhadneorlwaantedra.ffix a sample label. 8. 9. CPloamcpelethteestahmepclheaiinn-aofc-ocoulsetroodfy ifcoer.m. * c1a3l:i2brTatheedTarsidmebslceriGbPedSfuosrctdhefoGrafrimnfiinshGaPnSd (miScOrPolNaoy.er3/-b1u6l4k-0w1a)t.er position determinations is * Section 19.4 no longerappliesandshouldbedeleted. Sepcetrifoonr1m9be.5ydBtahcekmpaancukfaEclteucrterro.shosker: Maintenanceofthe backpack clectroshocker is * rSiencsteidonwi1t9h.6deMiiocnriozleadyewratSearm,palnedr:fiTnhalelymircinrsoeldavyietrhsmaemtphlaenrowlilbebteweriennssedamwpiltihnfgrleoschawtaitoenrs,. 000504 -- -- MuDudaliiCtyidysSeuwrancSeaPmrpleinsg TFalsan(N100573) AEmfefercdtinveeD2ntutot:ReJvuilsyio2n0N, o1:999| uHnotislonuepxtwuislc,beusedonthe sampler. Thesamplerwillthe beplaced aclean pPlaagsteic1b0a0fg17 a*ccuAratebpleylropewfClfeoeScrtAaqmtnhupalftiidineclgdFMidioartroxamlwa.eyTewhrileSlaFbimenpfrlieischnogrDedaintndagS.SuhNbeeseutwhrfs aascbeeaBeunlrm kefvWoiarsp temedsrbael Sralemoapwlilsitonoimgnn.ocrhuegded 000505 QHuCaylASsoseySs Ppriosalks109572 Tie FINFISH DATA SHEET Project: N100666-01 eenpsn oscion,! Teperi am frwo Sopnling Tncation mpBry [FS (FTErmira | wan tr [1 I 1 1 1 -- 7---- ---- ---- -- ee? tf Regushedoy: ere ou, } } -- " 000506 QuAalbituyAlssSu-lraynCcSeiaPmrptoljienycgtPTluasnk (V100672) AQUATIC MICROLAYERSAMPLING B16a2t9oWlesMatrSienqeuSicmieBnacyesRoLaabdoratory `Sequim, Washington 98382 Amfeectnivde 2Dm(o0veeR:evniusitony20,N1o3.|9 Page 120717 . Project Number: PhPoroneeic:t Manager: Fax Location: Date: Bote Lot Number: Collected by (initials): 31565 3D6a0v.e68S1h.e3t8r6e0r 300.081.3681 M--ob_il--e, AL matched site a I -- _---- -- SempleNumber MC41018 MCa102K MC4103 4 MC41048 HC4105K MC4106 H re(ctaoldeeb)yd:Sample DescrsinpdtAnialoysnis : TTMi"rMicroolayler a3BaMt(iylPlFeO(eSP;R5rO0S0cm-uipi)cateanaly500smie. esac:h) TMTirolPaOySeFril-aBHleannkn- B(aFttOeSd;(5e0m0ptmyLb)ote) P TTOS PrOSFFiieellddBBlanlk -3aHeMn(nieomnkp(yempbloyreb)ott) Rolinquished by: --- Da: Time: toe Included (YIN) Received by: oate: Time: Condon: 000507 Q#uualli-tCytyAsSstuuradnycSeaPmrpoljnegct PTlausnk (N100672) SUBSURFACE BULK WATER SAMPLING 1Ba5t2t9elWleesMtarSienqeuSicmieBnacyeLsRaobaodratory `Sequim, Washington 98382 Ameendcitnevnet 2DattoeRePvJoiugsliyeo2In0,3Noo1.f9:91|79 Project Number: Proejct Manager: Phong: Fax 31565 Dave Shreffier 330600..666811..33668610 Location; Date: Bottle Lot Number: Collected by (initials): --Mo_bi--le. AL matched site EE i--a---- remeeeeateentm-- Sample Number recorded by: Sample Description and Analysis (initials) -- MC41018 MC-4102K MC4103 H MC-4104 8 MC4105K MC-4106 H Relinquished by: Received by: Bulk water - Battelle (PFOS duplicate analyses: 500 mLeach) Bulkwa-t3eMr (PFOSduplicate analyses: 500 mL each) . `Bulkwater - Henion (PFOS duplicate `analyses: 500 mL each) Polarsfieldspike -Battelle(duplicateanalyses:500 mLeacn) Polars field spike -3M (duplicate analyses: 500 mL each) Polars field spike - Henion (duplicateanalyses: 500 mi.each) tee eet Date: Time: seers Ice Included (Y/N) Date: Time: Condition: 000508 Muluail-lCyidyssSaurcaynSeamrpoljioncgtTlaasnk(v100672) AQUATIC MICROLAYER SAMPLING B15a2t8elWeesMtarSienqeuSicmieBnacyesRoLaabdoratory `Sequim, Washington 98382 -------- AmEfceiinve2dDa0rmeR:eeuvilsnyio2nt0N,o1,9|99 Page I4of17 Project Number: PPrrooeniec:t Manager: Fax Location: . Oate: Bottic Lot Number: `Collectedb (intas): 316s 3D6a0v8e8S1h.r3e6f6e0r 360681.3681 --Pe_ns--acola, FL matched site J a ----__--_-- ir-- s `SampleNumber Me31018 Mest02K MC3103 H MC31048 MC3105K MC3108 H oicn dty: SampleDescrainpdAtriaosn 2 TMTicrMicoroalyer-a3BMat(ylPlFeOe(SP:FsrO0S0m-duip)licate analyses:500mi.each) MieFOSrFielldHBolanalnokn.yB(aPtRetOlSe;r6(e0m0p-mtyl)burs) _PPF FOOS FFiieeBBllaannkk-H3enMio(enmp(teympbtoyrbee)tte) Refquished by: --_-- Date: Time: tee Included (Y/N) Received by: Date: Tine: Condition 000509 uty Asnwares Proc ln MultSitu-dyCSaimptlinyg Task,(N100672) SUBSURFACE BULK WATERSAMPLING Battelle Marine SciencesLaboratory 1529 West Sequim Bay Road `Sequim, Washington 98382 Ans2n0dRevniseionn,1 ) Effective Date:FJueley lip 20, 1999 PPrProroonjesec:t MNaumnbaegre.r Fax Location: Date: Bottle Lot Number: Collected by (initials): 33D10a5v06e888S1t3i55e0r 360081 3081 "PensaFcLmoatlcheads,te -- TT -- Sample Number recordedby: Sample DesorapndtAinaoins (initials) MC-31078 NMSORAS0BKH C3108 TTTT PBBDouulkekuwwaatetekerdr--i3oBMat(ttPiSF(OPt(aSRePOdFtuOSprSdlcicdaul-tnpeicraanHtaelayasoenysa:lyn5ns0e0s0:mi5L00eomacLeh)cneahc)h) MNGORNSTHHK TTPaproeste ssiee3HMerconp(apiantntornna:yasb5es0s:0S0mo0oommtyccatn) Relinqushedby: -_-- Date Tore: Ice Incuded (vi) Rocsvedby: ome: Time: _-- Condton: 000510 MuQulailitCyiAyssSutraayncSeaPmrpoljienctg PTlaaskn (100672) AQUATIC MICROLAYER SAMPLING 1Ba5t2t9elWleesMatrSienqeuSicmieBnacyesRoLaabdoratory Sequim, Washington 98382 AmeAnldfemceinvte 2Da0teR:evJiusyio2n0,No15.09| Page 16/17 Project Number: Proejct Manager: Phone: Fax: Location: Date: Botte Lot Number. Collected by (inals): 31565 Dave Shretier 360.681.3660 360.681.3681 P--o_rt--St Lucie matched site a A -- --_-- Semple Number recGionrtdaelds)by: Sample Description ana Analyss mC61018 MC-6102K MC8103H MC51048 MC6105 K MC6106 H TTMiMcercorloalyeeyre-r-aBmat(tPlReO(SP;FSO0S0dmuLpl)icate analyses: $00 mi. eacn) P ~ OMS icrolaFyieerta- BHelnainoknB(aPtRtOiSe; (se0m0plmyL)bot) P -- P_R R--O OS SFFieiledB laa-H3nen Mn(kiemnk pt(aympbtoyrbtoeytte) Reinquished by: EE Date: Time: fee Included (Yi) Received by. ----- Date: Time: Condition: 000511 MluCcltdySeoyeSrmpjincgprii100672) SUBSURFACEBULK WATERSAMPLING Sequim, Washingon oesey 1`B5a2tt9elWleesMatrSienqeuSicmieBnacyesRLoaabdo.ratory ------ AEffnecticve2D1ai0teB:reaeyei3nt0,r3o5| Phone Project Number: Proejct Manager: Fax Location: Deer N ro Bote Lot Number Ceollected by ((iinniitials): 31565 sc0681.3080 Dave Shreffier 360.681.3681 -- T POISE Lucko ,FL maichoe dsie ws me ------ SUENATOR! eot078 MMCCs8110089HK. jMMrCCo-Es611t11e01n8K Reinuished by --_-- fc(incitialsb)y: SampoOesranpdAonyn + Suk trSate (PFOS duit spss00m.oc Sar en PFS prs rayne ny Bulkwat-e3Mr (PFOS duplicateanalyses:500mL.each) on edseen (mitemyen 30 cr --Pol as fi edsSppikee -3BMatt(eGlulpelc(adutpolaincaatleyasneasl:ys5e0s0;m5i0. 0 mL, ep eac h) one: Tine eo lncluded (vy -_-- Received by: Date: Time: 7 Condition: 000512 ENVIRONMENTAL MONITORING: PART TWO -- BIOSPHERE SAMPLING AND ANALYSIS Aflupolraoncthoemaiscsaeslsspuobtsetnatnicaelsenhavsirboenemnendteavleleoxppeodsubrye3toMpaenrdflouuotrsoiodcetaenxepesrutlsf.onOantee acnodmpootnheernt of this plan involves characterization of the geographic distribution of fluorochemicals in biotic and abiotic receptors. Two studies are in progress, one focused in the vicinityofthe 3M Decatur, Alabama manufacturing facility, and the other a much more comprehensive global biosphere monitoring program. The preliminary results obtained to date have been reported in the 3M Environmental White Paper the Environment: Sources, Dispersion, Fate and eEnftfietcltesd.""Sulfonated Perfluorochemicals in o`fTphre osdtuucdtyiionnthoepeDreactaitounrs,iAn ltahebalomcaalaernevaiirs obnemienngt.deSsaimgpneldestoofunthdeergsrtoaunnddwtaheteirm,pascutr,faicfeany, water, sediments and fish and bird species will be collected in May and June, 2000 for analyses. This data will be used to evaluate the environmental presence of fluorochemicals and to assess the potentialof any effects using ecotoxicological test results. M`TihcehBiigoasnphStearteemUonniivteorsriitnyg. pTrhoigsrpalmanwiassbediensgigvnieedweind caosnsaunltiatetriaotnivweitphroDcre.ssJotho nasGseesissygloofbal dpilsatnriisbuttoiocnonocfefnlturoartoecohenmtihcoasles.arAesasrewshuletrseafrleuoobrtoacihneemdicfarlosmartehedegtleocbatledeninvisraomnpmleenst,antdhe focus on additional sampling and analyses in those specific locations. Initially, samplesoftissues and blood plasma are being collected from archived specimens covering different species and locations. Areas of focus include North America (Great Lakes and coastal marine locations), the arctic region, and Europe. Species to be studied include lake trout, walleye, salmon, catfish, and brown trout; cormorants, eagles and albatross; mussels in progress and as adantdasihselolbftiashi;nemdarainndermepaomrmtaslgse;neraantdedo,thaedrdistpieocnieasl.sTuhbimsisssaimopnlsinwigllplbaen is made to EPA. Included in this section are the following documents: 1. LCMSMS Analysisof Extracts reported in: "Preliminary Report Analysis of Perfluorinated Compounds in Environmental Samples" by P. Jones and K. Kannan - 4/7/99 2. Final Laboratory Livers -- 4128/99 3M Reports on Analysis of Fluorochemicals in Wild Bird 3. Screening of PFOS levels in Eagle and Albatross - 5/8/98 000513