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Chemical properties Incineration high temp. Properties of PTFE C2F4 F C Al C2F4 + 2 H2O + O2 ==> 2 CO2 + 4 HF Density Melting point Reactivity Temperature of use Toxic reaction products Mass Flow PTFE Flow Liquid semi-product PTFE content in the semi-product Part on the surfaces Part remaining in the baths PTFE on the product PTFE worn out PTFE to aluminium recycling (end of life) PTFE to MSWI (end of life) PTFE to landfill (end of life) 100 g/mol 19 g/mol 12 g/mol 2.7 t/m3 2.2 t/m3 327 C cold = inert < 260 C > 400 C 40 kg/a 45 % 30 % 70 % 5.4 kg/a 18.75 % 61.25 % 10 % 10 % PTFE in waste water Estimation of damages Env. Impact factors Fluorides into the waste water HF into atmosphere Use of MSWI Toxic FHC's into the atmosphere (H4C2F2) Use of landfill (CH) Use of landfill (UTD, germany) 12.6 kg/a 3.2 UBP/g F 13.3 UBP/g HF 594 UBP/kg Abfall 6500 UBP/g 36 UBP/L 142 UBP/g Load balance Monetarisation Accumulated damage Use of 40 kg/a liquid semi-product Use of 40 kg/a liquid semi-product 1 t CO2 - Emission 1 t CO2 - Emission Use of 40 kg/a liquid semi-product Esimation of benefits The typical piece Coated surface Mean density of PTFE Typical piece, L Typical piece, B Typical piece, H Typical piece, volume Typical piece, weight Typical piece, surface Typical piece, PTFE weight PTFE concentration in typical piece Nr of typical pieces Weight of all typical pieces 39,770 UBP/a 37,105,361 UBP/a 1,000,000 UBP 150 CHF 5,566 CHF/a 18,000 m2/a 0.300000 g/m2 10.0 cm 8.0 cm 1.0 cm 0.000080 m3 216 g 0.0196 m2 0.005880 g 27 mg/kg 918,367 198,367 kg Types of benefits Lubrication properties ... whereof critical (no more product) Chemical resisntence Altefco turnover 80 % 60 % 20 % 4.5 Mio CHF Algorithms for the estimation of benefits Turnover of the client going down because product is no more possible (e.g. blood pump) Nr of typical pieces in machines 551,020 A Turnover of Altefco with these pieces 2,700,000 CHF Turnover ratio 0.01 Lost turnover of machines 270 Mio CHF Due to missing lubrication properties pieces will have a shortet lifetime B B C D Aggregated benefit Nr of typical pieces in machines Life time with use of PTFE Life time without use of PTFE Price of the piece without PTFE Cost for use of pieces with PTFE Cost for use of pieces without PTFE Benefit due to use of PTFE Corrosion due to missing chemical resistance Nr of typical pieces in machines Turnover of Altefco with these pieces Turnover ratio Value of the products Corrosion within Benefit due to use of PTFE Turnover of Altefco Use of 40 kg/a liquid semi-product 183,673 20 a 5a 0.80 0.90 Mio CHF 2.88 Mio CHF 1.98 Mio CHF 183,673 0.90 Mio CHF 0.30 2.10 Mio CHF 2.0 a 1.05 Mio CHF/a 4.50 Mio CHF/a 277.53 Mio CHF/a % 76 0.76 24 0.24 100 g C2F4 ==> 80 g HF COF2, HF Info Altefco Guess by Altefco Guess by Altefco PTFE to environment (cold) PTFE to Al recycling Al recycling with flue gas (F) treatment Al recycling without flue gas (F) treatment 1.0125 kg/a 3.3075 kg/a 0% 100 % TEFLON to MSWI => HF => PTFE to landfill (VVEA CH) (cold) PTFE to MeOH sludge 0.54 kg/a 0.54 kg/a 12.6 kg/a Worstcase estimate Acidification Derived from AOX (worst case) kofaktoren Schweiz 2021, Tabelle 24 Ecoinvent 3.9.1. municipal solid waste CH kofaktoren Schweiz 2021, Tabelle 36, analog Br kofaktoren Schweiz 2021, Tabelle A kofaktoren Schweiz 2021, Tabelle A 16.4 UBP/kg case A) only HF but no toxic HFC's case B) only toxic HFC's, no HF 1 kg NMVOC - Emission 1 kg NMVOC - Emission Use of 40 kg/a liquid semi-product 12000 UBP 9 CHF 27,829 CHF/a zB. 10 x 8 x 1 cm3 0.030 mg/cm2 Limit for application of the PFAS restriction 50 mg/kg B A C D ossible (e.g. blood pump) Machines that cannot be produced without Altef-/Ematef-pieces 40-50% of ca. 10 Mio CHF for ALTEF und EMATEF The Altefco piece will cost typically 1% of the cost of the machine Zero effect Fluorides in the waste water (F-) HF in waste air Alternatively: Toxic FHC's into waste air (p.e. H4C2F2) Use of MSWI's Use of landfills Use of UTD landfill (germany) 1.0125 kg/a 9.99 kg F-/a 0.00 kg HF/a 5.70 kg H2C2F2/a 13.14 kg/a 0.54 kg/a kg/a UBP = Ecopoints according to the methodology of ecological scarcity Load 31,956 UBP/a 0 UBP/a 7,805 UBP/a 37,065,600 UBP/a 9 UBP/a 0 UBP/a