Document Yrq6Q574aB5RjYNawLwqR2KEO

RCRA Compliance Branch INSPECTION REPORT Inspection Date(s): 6/12/2024 Inspection Announced: No Facility or Site Name: Facility/Site Physical Location: (city, state, zip code) Mailing address (if different from above): (city, state, zip code) Facility/Site Contact: Ducommun Aero Structures, Inc. 171 Stacey Road Coxsackie, NY 12051 see above Mary McCoy mmccoy@ducommun.com (203) 300-7303 EHS Manager RCRA ID Number: NYR000219550 Facility/Site Personnel Participating in Inspection: Mary McCoy EHS Manager Robert Hasenkopf Center Director Sunder Shelhamer Maintenance Lead Millage Howe Value Stream Manager mmccoy@ducommun.com rhasenkopf@ducommun.com sshelhamer@ducommun.com mhowe@dummon.com Inspector(s): Vince Damiano (ERG [EPA Contractor]) Vincent Damiano Digitally signed by Vincent Damiano Date: 2024.08.15 14:33:08 -04'00' 8/15/2024 EPA Supervisor Derval Thomas (EPA Region 2) DERVAL THOMAS Digitally signed by DERVAL THOMAS Date: 2024.08.19 13:59:27 -04'00' Inspection Report Authors: Vince Damiano RCRA Compliance Branch INSPECTION REPORT SECTION I - INTRODUCTION Purpose of the Inspection Objective EPA Region 2 identified Ducommun Aero Structures, Inc. ("Ducommun") as a target for a compliance evaluation inspection (CEI). The purpose of the inspection was to determine the facility's compliance with the Resource Conservation and Recovery Act (RCRA). The inspection was conducted by Vince Damiano (ERG). Opening Conference The inspector arrived at Ducommun at approximately 9:00 am on June 12th, 2024, for an unannounced RCRA inspection. Inspector Damiano first met with Robert Hasenkopf (Director), Sunder Shelhamer (Maintenance Lead), and Millage Howe (Value Stream Manager). Vince Damiano presented his RCRA inspector credentials to Mr. Hasenkopf, Mr. Shelhamer, and Mr. Howe and informed them that this was an EPA RCRA CEI that covered all RCRA regulations. Inspector Damiano inquired about any permitting requirements for the use of equipment that is not intrinsically safe in the process area and explained Ducommun's right to claim confidential business information (CBI). Ducommun indicated that no information included in this report was claimed as CBI. The inspection report and attachments present the results of the CEI. Facility/Site Description Ducommun produces structural and electronic components and subassemblies for commercial and military aircrafts. The facility receives sheet metal in bulk and performs "structural assemblies," primarily creating aircraft parts using techniques such as sheet metal cutting ("waterjet"), bending, cold-forming ("drop hammer"), stamping (punch and break presses), welding, assembling, coating (Everlube spray booths), etching and other operations. Ducommun began operations at this site in 2016 and employs approximately 230 employees. The facility consists of a 150,000 ft2 building sitting on a 20-acre plot. Facility representatives said the sheet metal is first brought to the Blank Cell Area where it undergoes shearing and waterjet cutting for processing. After the sheet metal is cut, it is brought to the main process area. In this area, parts molds are stored in the Die Storage Area and then pre-heated in ovens. The heated dies are used in hydraulic and electric hot die presses in the Hot Form Press Area. Sheet metal is then bent using break form press machines in the Press Break Area and the Hot Break Form Area. Parts are cleaned in one of 2 RCRA Compliance Branch INSPECTION REPORT five value streams using alkaline cleaners. Coating operations occur in the Everlube spray booths and then the final parts are painted in the paint booths. The site is currently operating as a Large Quantity Generator (LQG) of hazardous waste. Most of the hazardous waste generated is nitric/hydrofluoric acid mix used to clean parts in their value streams and Alodine 600/1200 used as a protective coating. The nitric/hydrofluoric acid mix and Alodine coating both carry D002 and D007 hazardous waste codes. The site also generates hazardous waste from their painting and coating activities which carries D007, D011, and F003 hazardous waste codes. The hazardous waste is picked up by Veolia ES Technical Solutions (NJD080631369) and transferred to Freehold Cartage Inc. (NJD054126164). Freehold Cartage will then transport the waste to one of two designated disposal facilities - Veolia ES Technical Solutions (NJD980536593) in Flanders NJ or Stablex Canada (NYD98075615) in Blainville, QC, Canada. The site also generates Oakite 160 Solution which is a caustic aluminum coating for etching processes and carries a D002 hazardous waste code. Paint debris, used oil, spent acetone, and universal waste are also generated at the facility. Ducommun operates under a New York State Facility Air Permit (Registration ID: 4-1928-00219/00003) issued on October 19, 2017. SECTION II - OBSERVATIONS The inspector arrived at the Ducommun facility in Coxsackie on the morning of June 12th, 2024. Following the opening conference and a discussion of the facility processes, the inspection team conducted a walkthrough starting at approximately 9:30 am. The inspector observed the Blank Cell area, the value streams, paint booths, Everlube spray booths, central accumulation area (CAA), and several satellite accumulation areas (SAAs). The inspector ended the walkthrough at 11:00 am. All photographs taken during the walkthrough are provided in Attachment 1. The photograph numbers in this report correspond to the numbers in Attachment 1. Further details regarding each of the areas observed during the walkthrough are discussed in the sections below. Blank Cell Area The inspection team observed the Blank Cell Area where bulk raw materials are stored and the sheet metal is cut using water and garnet. The wastewater from the cutting process is collected in sumps and sent to a series of underground settling tanks where spent garnet and water are collected. After the water is separated from the garnet, it is sent to a POTW to be treated and released. The inspector inquired about Ducommun having a permit or letter for approval to discharge wastewater to the Village of Coxsackie POTW, and Ms. McCoy provided correspondence with the POTW stating the facility is not a categorical 3 RCRA Compliance Branch INSPECTION REPORT pretreatment facility and a permit is not required (see Attachment 2). The inspector requested waste determinations for the wastewater being discharged, the garnet/water mix in the settling tanks, and the spent garnet following the inspection. The analytical results were provided by Ms. McCoy showing all three are non-hazardous (see Attachments 3, 4, and 5). The inspection team observed a 55-gallon drum and a 5-gallon container collecting used oil from the water-jet cutter which was not labeled as shown in Photograph 1 and 3. Ducommun personnel said the used oil is collected in the 5-gallon container and transferred to the 55-gallon drum once full. View of unlabeled 55-gallon drum of used oil. {Photograph 1, Attachment 1} 4 RCRA Compliance Branch INSPECTION REPORT View of unlabeled 5-gallon container of used oil. {Photograph 3, Attachment 1} Value Streams and Everlube Spray Booth The inspector observed two of the five value streams as each value stream is set up the same way. Each value stream processes parts based on size, with distinct value streams dedicated to small, medium, and large parts. Despite the size differences, all value streams serve the same purpose: bending, etching, heating, break forming, and cleaning parts before they are assembled. The parts are cleaned using a nitric/hydrofluoric acid mix. This mixture is kept circulating in open tanks and changed about once every two weeks. When changed, the used acid mix is transferred into a tote which is then stored in the CAA as hazardous waste. The inspection team also observed an Everlube spray booth where parts are coated in a protective coating to prevent damage when heated. A 35-gallon drum of acetone rags which was properly labeled as hazardous waste and closed was also observed in this area. No areas of concern were found at the value streams and Everlube spray booth. Paint Booth The inspector observed the VS3 paint booth where parts are painted before assembly. Two 55-gallon drums were observed in the paint booth's SAAs, one containing flammable enamel paint slow drain and the other flammable enamel paint quick drain (see Photographs 6 through 8, Attachment 1). Each 55-gallon drum was managed as a separate 5 RCRA Compliance Branch INSPECTION REPORT SAA. An acetone rag container was also present in the paint booth which was properly labeled as hazardous waste and closed. The inspection team found a red metal cabinet labeled as expired paint. The storage cabinet contained approximately 30 1-gallon expired paint cans as shown in Photograph 9. The facility stated in a follow-up email after the inspection that the expired paint is not considered waste because the facility uses it for training and troubleshooting purposes (see Attachment 6). View of metal storage cabinet containing expired paint in VS3 Paint Booth. {Photograph 9, Attachment 1} Waste Storage Areas The inspector observed the CAA for the site, where totes of nitric/hydrofluoric acid mix from the value streams, drums of spilled acid debris, totes of paint waste, and totes of acetone rags are stored before being picked up for disposal. The CAA is a storage shed separated into three different bays. Inside the first bay was a half full tote of nitric /hydrofluoric acid mix labeled as hazardous waste with an accumulation start date of June 5, 2024. There was also a 35-gallon drum of acidic spill debris properly labeled with the same accumulation start date of June 5, 2024. Behind the tote of acid waste, the inspector observed a 5-gallon carboy labeled as hazardous waste containing hydrofluoric acid and chromic acid with an accumulation start date of September 11, 2023, as shown in Photograph 12. When asked if they knew it was past the 90-day storage period, the facility personnel stated the container was from a spill and they were unaware that the container was being stored in the CAA. 6 RCRA Compliance Branch INSPECTION REPORT View of 5-gallon carboy containing hazardous corrosive waste stored past the 90-day storage period inside bay 1 of CAA. {Photograph 12, Attachment 1} The inspector observed the second bay in the CAA which contained four lined cardboard totes labeled as hazardous waste. One of the totes contained acetone debris and did not have an accumulation start date or indication of hazards of its contents on the label. The tote contained a DOT placard indicating a miscellaneous hazard was contained inside the tote, but the facility ships acetone debris out with waste code D001 (flammable). Therefore, the DOT placard did not constitute an appropriate indication of hazards of the container's contents. The tote was also open at the time of the inspection with no sign of waste being added into the container(see Photographs 13-14, Attachment 1). 7 RCRA Compliance Branch INSPECTION REPORT View of acetone debris tote stored with top opened inside the CAA. {Photograph 14, Attachment 1} Another tote contained paint debris and did not have an accumulation start date or indication of the hazards of its contents on the label. The tote contained a DOT placard indicating a miscellaneous hazard was contained inside the tote, but the facility ships paint debris out with waste codes D001 (flammable) and D007 (chromium). Therefore, the DOT placard did not constitute an appropriate indication of hazards of the container's contents. The tote was also open at the time of the inspection with no sign of waste being added into the container (see Photograph 18, Attachment 1). 8 RCRA Compliance Branch INSPECTION REPORT View of paint debris tote stored with top opened with no accumulation start date inside the CAA {Photograph 18, Attachment 1} The remaining two totes were labeled as Adhesive/Sealant Debris; one of which did not have an accumulation start date, while the other had an accumulation start date of April 30, 2024. Neither of the totes contained an indication of hazards of their contents on the waste label (see Photographs 15, 16, and 19, Attachment 1). The facility stated in a followup email that these two totes were pending analysis and provided the inspector with analytical results on the Adhesive/Sealant debris proving that the waste was nonhazardous following the inspection (see Attachments 6 and 10). The third bay of the CAA was used to store drums of product and materials. The inspector also observed a working communication device, fire extinguisher, and spill kit in front of the CAA (see Photographs 23 and 24, Attachment 1). Ducommun provided a follow-up email responding to initial areas of concern found during the inspection. In this email the facility included photographs of the acetone debris tote and paint debris tote properly closed and labeled with an accumulation start date. They also included an image of a manifest for the hazardous carboy found stored past the accumulation time limit, stating it was shipped offsite on 6/18/2024. These photographs can be found in Attachment 7. 9 RCRA Compliance Branch INSPECTION REPORT Universal Waste and Used Oil Storage The inspector observed the universal waste and used oil storage areas. In the used oil storage area, there was one 55-gallon drum containing used oil designated by a sign and a 55-gallon drum for oily debris also designated by a sign, however the drum storing used oil did not contain a label or marking on the container (see Photograph 20, Attachment 1). In the universal waste storage area, the inspector observed a 5-gallon container of lead acid batteries, properly labeled with an accumulation start date of November 2, 2023; and two 5-gallon containers of aerosol cans properly labeled with accumulation start dates of September 24, 2023 and March 19, 2024 (see Photograph 21 and 22, Attachment 1). Records Review The inspector reviewed the following compliance documents as part of the records review: Contingency Plan: In response to a request to provide the Contingency Plan, Ducommun provided a copy of their RCRA Contingency Plan which also includes emergency response procedures. The plan is dated with a last reviewed date of February 1, 2024. The RCRA Contingency Plan is provided in Attachment 8. Additionally, the facility provided several email correspondences with local emergency departments to coordinate dates so they can visit the site and become familiar with the layout and Ducommun's emergency response plans; this includes emails indicating local emergency responders have received a copy of their contingency plan, which can be found in Attachment 9. The Contingency Plan provides lists of key management personnel and indicates that the EHS Manager is the Plan Administrator. The plan states that if more than 2.5 gallons of hazardous material is spilled the Fire Department will be called; and that for a spill less than 2.5 gallons, the high hazard chemical incidental spill response procedure will be implemented. The beginning of the Contingency Plan provides five individuals who can serve as the emergency coordinator and provides their contact information. The plan includes lists of names and types of hazardous wastes present on site. Additionally, the contingency plan includes a list of emergency equipment and support including fire extinguishers, emergency PPE, eye wash stations, first aid kits, and spill containment kits. The location of these items can be found in the facility map in the beginning of the plan and the list outlines the capacity of each item. The Plan also includes location and directions for how to use their "Pump House" or fire pump system. The inspector also requested documentation that the latest version of the Contingency Plan has been submitted to local emergency responders. Mary McCoy provided a list of tracking results from USPS, sent in October 2023. She also provided email correspondence from December 2023 between herself and the Village of Coxsackie Police Department, the County Sheriff's Office, Veolia Emergency Response, Albany Medical 10 RCRA Compliance Branch INSPECTION REPORT Services, New York State Emergency Response Commission, and the local Fire department confirming the receipt of Ducommun's Contingency Plan; this documentation can be found in Attachment 9. Training Records: Every Employee of Ducommun is required to take an initial RCRA training and refresher training every year. Training records were reviewed on site during the inspection, all records were up to date. Waste Profiles: Ducommun provided the current waste profiles for the "Spent Garnet" dated June 14, 2024, and "Vault Sediment" dated June 14, 2024. The Spent Garnet is profiled as non-hazardous waste based on analytical TCLP results from 2018 being below regulatory detection limits for chromium and generator knowledge (see Attachment 5). The Vault Sediment from the underground settling tanks is profiled as non-hazardous waste based on 2023 analytical TCLP results (see Attachment 3). Waste Analytical: Analytical testing for the adhesive sealants, spent garnet, vault sediment, and wastewater discharged to the POTW were provided by Ducommun at the request of the inspector. The analytical results from 6/17/2024 for the adhesive sealant showed that it was non-hazardous (see Attachment 10). At the time of the inspection, the two adhesive sealant totes were labeled as hazardous waste, but Ms. McCoy stated they were waiting for these analytical results to come back. Analytical testing is conducted every year for the wastewater being sent to the POTW, Ducommun provided the 2023 results showing the wastewater is non-hazardous (see Attachment 4). The analytical results for non-hazardous Spent Garnet and Vault Sediment are attached to the waste profiles discussed above. Manifests: The inspector reviewed hazardous and non-hazardous waste manifests provided by Ducommun and viewed on RCRAInfo. All hazardous waste is picked up by Veolia ES Technical Solutions (NJD080631369) and transferred to Freehold Cartage Inc. (NJD054126164). Freehold Cartage then transports the waste to one of two designated disposal facilities - Veolia ES Technical Solutions (NJD980536593) in Flanders, NJ or Stablex Canada (NYD98075615) in Blainville, QC, Canada. Example manifests are provided in Attachment 11. Weekly CAA Inspections: Ducommun provided its year-to-date weekly CAA inspection log. The inspection log was reviewed on site during the inspection; the records were up to date and all weeks were accounted for. 11 RCRA Compliance Branch INSPECTION REPORT SECTION III - AREAS OF CONCERN The presentation of areas of concern does not constitute a formal compliance determination or violation. Regulatory Concerns 1. 6 NYCRR 373-3.9(d)(1) states that "A container holding hazardous waste must always be closed during storage, except when it is necessary to add or remove waste. ". The inspector observed a tote used to accumulate hazardous acetone debris in the CAA. The top of the tote was completely open, such that it was open even when waste was not actively being added or removed (see Photograph 14, Attachment 1). Additionally, the inspector observed an open tote that was used to accumulate hazardous paint debris also stored in the CAA. The top of the tote was placed inside the totes, such that it was open even when waste was not actively being added or removed (see Photograph 18, Attachment 1). 2. 6 NYCRR 372.2(a)(8)(i)(2) states that "marks the containers with the words "Hazardous Waste" and with other words that identify the contents of the containers." The inspector observed two totes used to accumulate hazardous paint debris and acetone debris in the CAA. The totes were labeled as "hazardous waste" but did not contain an indication of the hazards of their contents (see Photograph 13 and 17, Attachment 1). 3. 6 NYCRR 372.2(a)(8)(ii) states that " ... the date upon which each period of accumulation begins must be clearly marked and visible for inspection on all containers." The inspector observed two totes used to accumulate hazardous paint debris and acetone debris in the CAA. The totes were labeled as "hazardous waste" but did not contain an accumulation start date (see Photograph 13 and 17, Attachment 1). 4. 6 NYCRR 372.2(a)(8)(ii) states that "... a generator may accumulate hazardous waste on-site of generation for a period of 90 days or less..." The inspector observed a 5-gallon carboy containing hazardous corrosive waste stored past the 90-day accumulation limit with an accumulation start date of 9/11/2023 inside the CAA (see Photograph 11, Attachment 1) 5. 6 NYCRR 374-2.3(c)(4)(i) states that "Every container and aboveground used oil tank used to store used oil at a generator facility must be clearly labeled or marked with the words "Used Oil"." The inspector observed a 55-gallon drum and a 5-gallon container storing used oil without a label or marking inside the Blank Cell Area; and one 55-gallon drum storing used oil in the used oil storage area without a label. 12 RCRA Compliance Branch INSPECTION REPORT Closing Conference The closing conference took place on June 12, 2024, at approximately 1:30 pm. Attending from the facility were Mary McCoy, Robert Hasenkopf, Sunder Shelhamer and Millage Howe. Inspector Damiano was in attendance for the closing conference. Inspector Damiano discussed preliminary areas of concern and reviewed the list of documents he requested as follow-up to the inspection. The closing meeting ended at approximately 2:00 pm on June 12, 2024. List of Attachments These attachments are referenced throughout this report: Attachment 1: Photolog Attachment 2: POTW Response Regarding Permit Attachment 3: Vault Sediment Waste Determination Attachment 4: Wastewater Analytical Attachment 5: Garnet Waste Determination Attachment 6: Facility Follow up Email to EPA Attachment 7: Facility Follow-up Photographs Attachment 8: RCRA Contingency Plan Attachment 9: Emergency Responders Receipts Attachment 10: Adhesives Sealant Waste Determination Attachment 11: Waste Manifest Examples Post-Inspection Facility Correspondence Following the inspection, ERG provided a file transfer protocol link to Ducommun to allow them to upload pending documents requested during the inspection. Documents were uploaded by the facility, with the final documents uploaded on June 18, 2024. 13 RCRA Compliance Branch INSPECTION REPORT Attachment 01 Photographic Log Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #1 (DSCN7348) Date: 06/12/2024 Time: 09:51 Taken by: Vince Damiano Comments: View of 55-gallon used oil drum in Blank Cell Area missing the words `Used Oil' on the label. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #2 (DSCN7349) Date: 06/12/2024 Time: 09:51 Taken by: Vince Damiano Comments: View of 5-gallon container of used oil in Blank Cell Area which was unlabeled. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #3 (DSCN7350) Date: 06/12/2024 Time: 09:51 Taken by: Vince Damiano Comments: Another view of 5-gallon container of used oil in Blank Cell Area which was unlabeled. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #4 (DSCN73451) Date: 06/12/2024 Time: 09:54 Taken by: Vince Damiano Comments View of cardboard tote found on loading dock by CAA containing electronic waste, no areas of concern noted. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #5 (DSCN7352) Date: 06/12/2024 Time: 09:54 Taken by: Vince Damiano Comments: View of cardboard tote found on loading dock by CAA containing electronic waste, no areas of concern noted. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #6 (DSCN7353) Date: 06/12/2024 Time: 10:04 Taken by: Vince Damiano Comments: View of two 55-gallon drums containing hazardous paint waste at VS3 paint booth SAA. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #7 (DSCN7354) Date: 06/12/2024 Time: 10:04 Taken by: Vince Damiano Comments: Closeup view of label on flammable enamel slow drain 55-gallon drum in VS3 paint booth SAA. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #8 (DSCN7355) Date: 06/12/2024 Time: 10:04 Taken by: Vince Damiano Comments: Closeup view of label on flammable enamel quick drain 55-gallon drum in VS3 paint booth SAA. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #9 (DSCN7356) Date: 06/12/2024 Time: 10:05 Taken by: Vince Damiano Comments View inside of expired paint storage cabinet at VS3 paint booth, facility said paint is expired but not considered waste as it is used for training and troubleshooting purposes. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #10 (DSCN7357) Date: 06/12/2024 Time: 10:05 Taken by: Vince Damiano Comments: View of outside the expired paint storage cabinet at VS3 paint booth. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #11 (DSCN7358) Date: 06/12/2024 Time: 10:11 Taken by: Vince Damiano Comments: View of 5-gallon carboy containing hydrofluoric acid and chromic acid inside bay 1 of CAA with accumulation start date of 9/11/2023. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #12 (DSCN7359) Date: 06/12/2024 Time: 10:11 Taken by: Vince Damiano Comments: Another view of 5-gallon carboy containing hydrofluoric acid and chromic acid inside bay 1 of CAA with accumulation start date of 9/11/2023. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #13 (DSCN7360) Date: 06/12/2024 Time: 10:15 Taken by: Vince Damiano Comments: View of label on tote containing acetone debris inside bay 2 of CAA. The label did not contain an accumulation start date or indication of the hazards of its contents. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #14 (DSCN7361) Date: 06/12/2024 Time: 10:15 Taken by: Vince Damiano Comments: View of acetone debris tote seen in Photograph 13 stored with the top of the container open. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #15 (DSCN7362) Date: 06/12/2024 Time: 10:16 Taken by: Vince Damiano Comments: View of label on tote containing adhesive/sealant debris inside bay 2 of CAA. The label did not contain an accumulation start date or indication of hazards of its contents. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #16 (DSCN7363) Date: 06/12/2024 Time: 10:16 Taken by: Vince Damiano Comments: View of tote containing adhesive/sealant debris inside bay 2 of CAA. The label did not contain an accumulation start date or indication of hazards of its contents. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #17 (DSCN7364) Date: 06/12/2024 Time: 10:17 Taken by: Vince Damiano Comments: View of label on tote containing paint debris inside bay 2 of CAA. The label did not contain an accumulation start date or indication of hazards of its contents. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #18 (DSCN7365) Date: 06/12/2024 Time: 10:17 Taken by: Vince Damiano Comments: View of paint debris tote seen in Photograph 17 stored with the top of the container open. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #19 (DSCN7366) Date: 06/12/2024 Time: 10:17 Taken by: Vince Damiano Comments: View of second tote containing adhesive/sealant debris inside bay 2 of CAA. The label did not contain an indication of hazards of its contents. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #20 (DSCN7367) Date: 06/12/2024 Time: 10:24 Taken by: Vince Damiano Comments: View of 55-gallon drum of used oil and 55gallon drum of oily debris in used oil storage area. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #21 (DSCN7368) Date: 06/12/2024 Time: 10:27 Taken by: Vince Damiano Comments: View of one 5-gallon container of universal waste batteries and two 5gallon containers of universal waste aerosol cans. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #22 (DSCN7369) Date: 06/12/2024 Time: 10:27 Taken by: Vince Damiano Comments: View of labels on universal waste aerosol can containers with accumulation start dates 9/24/2023 and 3/19/2024. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #23 (DSCN7370) Date: 06/12/2024 Time: 11:39 Taken by: Vince Damiano Comments: View of communication device and fire extinguisher outside of CAA. Photograph Ducommun Aero Structures Inspection Photolog June 12, 2024 Identification/Notes Photo #24 (DSCN7371) Date: 06/12/2024 Time: 11:40 Taken by: Vince Damiano Comments: Signage for hazardous waste spill response area. Photograph RCRA Compliance Branch INSPECTION REPORT Attachment 02 POTW Response Regarding Permit McCoy, Mary From: Sent: To: Subject: Brock Juusola <bjuusola@delawareengineering.com> Friday, March 1, 2024 12:36 PM McCoy, Mary; David Varade RE: DAS NY Wastewater Permit This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Mary, My understanding that is that at some point in the past your process was reviewed and at that time it was determined that you are not a "categorical pretreatment facility" and a permit was not required. Thanks, Brock Juusola, P.E. Partner 28 Madison Avenue Ext. | Albany, NY 12203 518.452.1290 x234 (office) 518.429.0087 (mobile) www.delawareengineering.com From: McCoy, Mary <MMcCoy@ducommun.com> Sent: Friday, March 1, 2024 12:27 PM To: David Varade <wwtp2018@gmail.com>; Brock Juusola <bjuusola@delawareengineering.com> Subject: DAS NY Wastewater Permit Greetings, As per our conversation on February 28, DAS NY is not required to have a wastewater permit for the Village of Coxsackie at this time. If you could reply back to confirm or clarify, that would be great. Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 1 Attachment 2 Page 1 of 2 518.731.4650 office mmccoy@ducommun.com www.ducommun.com Safety Suggestions: EHSSupportNY@ducommun.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 2 Attachment 2 Page 2 of 2 RCRA Compliance Branch INSPECTION REPORT Attachment 03 Vault Sediment Waste Determination Form No.: Last Reviewed Date: Revision No.: Coxsackie, New York F-00663 Hazardous Waste Determination Worksheet - 10/17/2023 A Authorized By: WI-00216 Environmental Management System - Requirements Page 1 of 2 DCO Site: Coxsackie 171 Stacey Road Coxsackie, NY 12051-2613 EPA ID: NYR 000 219 550 Date: 6/14/2024 By: Mary McCoy Waste Stream Common Name: Vault sediment Check one: RCRA Haz Waste Non-RCRA Haz Waste Not Haz Waste RCRA Waste Codes: NA State Waste Codes: NA 0 Source Code: #N/A Form Code: #N/A Management Method: #N/A (For California sites, if this waste is subject to 22 CCR 66266.1 and is not recycled, attach justification.) UN#, Proper Shipping Name, Hazard Class, Packing Group: NA ERG: NA Check one: Ongoing RQ Threshold: NA Intermittent One-time Other information: The sediment from the settling vaults associated with the wastewater treatment plant ("pH Lab") is non-hazardous based on 2023 TCLP results. See attached. Waste generation process (listed, characteristic); chemicals used; location within facility: After pH neutralization at the pH Lab, the wastewater is discharge to the POTW via settling vaults. Sediment collects at the bottom of the vaults. Attachment 3 Page 1 of 18 #=CL# LIMS USE: FR - MARY MCCOY LIMS OBJECT ID: 70275899 December 27, 2023 Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Mary McCoy Ducommun Aerostructures 171 Stacy Road Coxsackie, NY 12051 RE: Project: WASTEWATER TREATMENT SL 10/28 Pace Project No.: 70275899 Dear Mary McCoy: Enclosed are the analytical results for sample(s) received by the laboratory on October 31, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: Pace Analytical Services - Melville If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew T. Nemeth matthew.nemeth@pacelabs.com 516-370-6042 Project Manager Enclosures cc: Linda Barley, Ducommun Aerostructures Pedro Dumaua, Ducommun Aerostructures Eugenia Lighthouse, Ducommun Incorporated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 2 of 18 Page 1 of 17 #=CP# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 Pace Analytical Services Long Island 575 Broad Hollow Rd, Melville, NY 11747 Connecticut Certification #: PH-0435 Delaware Certification # NY 10478 Maryland Certification #: 208 Massachusetts Certification #: M-NY026 New Hampshire Certification #: 2987 CERTIFICATIONS New Jersey Certification #: NY158 New York Certification #: 10478 Primary Accrediting Body Pennsylvania Certification #: 68-00350 Rhode Island Certification #: LAO00340 Virginia Certification # 460302 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 3 of 18 Page 2 of 17 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 Sample: VAULT Lab ID: 70275899001 Collected: 10/27/23 09:00 Received: 10/31/23 08:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 6010 MET ICP, TCLP Chromium 7471 Mercury Mercury Percent Moisture Percent Moisture Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville 3.0 <23.2 1.1 441 1.1 <1.2 <1.2 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 1.2 1 11/03/23 07:00 11/03/23 14:59 7440-38-2 23.2 1 11/03/23 07:00 11/03/23 14:59 7440-39-3 0.29 1 11/03/23 07:00 11/03/23 14:59 7440-43-9 1.2 1 11/03/23 07:00 11/03/23 14:59 7440-47-3 0.58 1 11/03/23 07:00 11/03/23 14:59 7439-92-1 1.2 1 11/03/23 07:00 11/03/23 14:59 7782-49-2 1.2 1 11/03/23 07:00 11/03/23 14:59 7440-22-4 Analytical Method: EPA 6010C Preparation Method: EPA 3005A Leachate Method/Date: EPA 1311; 12/15/23 22:20 Pace Analytical Services - Melville <0.050 mg/L 0.050 1 12/19/23 07:06 12/19/23 17:39 7440-47-3 Analytical Method: EPA 7471B Preparation Method: EPA 7471B Pace Analytical Services - Melville <0.063 mg/kg 0.063 1 11/07/23 07:00 11/07/23 14:23 7439-97-6 Analytical Method: ASTM D2216-05M Pace Analytical Services - Melville 43.3 % 0.10 1 11/01/23 08:04 Qual Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 4 of 18 Page 3 of 17 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 Sample: CACO3 TI#2 Lab ID: 70275899002 Collected: 10/28/23 09:30 Received: 10/31/23 08:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 6010 MET ICP Aluminum Cobalt Copper Iron Manganese Molybdenum Nickel Vanadium 6010 MET ICP, TCLP Arsenic Barium Cadmium Chromium Lead Selenium Silver 7470 Mercury, TCLP Mercury 7471 Mercury Mercury Percent Moisture Percent Moisture Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville 28100 97.3 82.7 6240 317 18.4 1350 6500 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 88.5 1 11/03/23 07:00 11/03/23 15:02 7429-90-5 22.1 1 11/03/23 07:00 11/03/23 15:02 7440-48-4 11.1 1 11/03/23 07:00 11/03/23 15:02 7440-50-8 44.2 1 11/03/23 07:00 11/03/23 15:02 7439-89-6 6.6 1 11/03/23 07:00 11/03/23 15:02 7439-96-5 8.8 1 11/03/23 07:00 11/03/23 15:02 7439-98-7 17.7 1 11/03/23 07:00 11/03/23 15:02 7440-02-0 22.1 1 11/03/23 07:00 11/03/23 15:02 7440-62-2 Analytical Method: EPA 6010C Preparation Method: EPA 3005A Leachate Method/Date: EPA 1311; 10/31/23 23:09 Pace Analytical Services - Melville <0.010 <0.20 <0.0025 0.027 0.029 <0.010 <0.010 mg/L mg/L mg/L mg/L mg/L mg/L mg/L 0.010 1 11/03/23 08:16 11/03/23 17:28 7440-38-2 0.20 1 11/03/23 08:16 11/03/23 17:28 7440-39-3 0.0025 1 11/03/23 08:16 11/03/23 17:28 7440-43-9 0.010 1 11/03/23 08:16 11/03/23 17:28 7440-47-3 0.0050 1 11/03/23 08:16 11/03/23 17:28 7439-92-1 0.010 1 11/03/23 08:16 11/03/23 17:28 7782-49-2 0.010 1 11/03/23 08:16 11/03/23 17:28 7440-22-4 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311; 10/31/23 23:09 Pace Analytical Services - Melville <0.00020 mg/L 0.00020 1 11/06/23 06:00 11/06/23 13:33 7439-97-6 Analytical Method: EPA 7471B Preparation Method: EPA 7471B Pace Analytical Services - Melville <0.034 mg/kg 0.034 1 11/07/23 07:00 11/07/23 14:24 7439-97-6 Analytical Method: ASTM D2216-05M Pace Analytical Services - Melville <0.10 % 0.10 1 11/01/23 08:04 Qual Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 5 of 18 Page 4 of 17 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 Sample: CACO3 TI#1 Lab ID: 70275899003 Collected: 10/28/23 09:45 Received: 10/31/23 08:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 6010 MET ICP Aluminum Cobalt Copper Iron Manganese Molybdenum Nickel Vanadium 6010 MET ICP, TCLP Arsenic Barium Cadmium Chromium Lead Selenium Silver 7470 Mercury, TCLP Mercury 7471 Mercury Mercury Percent Moisture Percent Moisture Analytical Method: EPA 6010C Preparation Method: EPA 3050B Pace Analytical Services - Melville 24000 116 191 8890 688 83.3 3510 6360 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 93.6 1 11/03/23 07:00 11/03/23 15:05 7429-90-5 23.4 1 11/03/23 07:00 11/03/23 15:05 7440-48-4 11.7 1 11/03/23 07:00 11/03/23 15:05 7440-50-8 46.8 1 11/03/23 07:00 11/03/23 15:05 7439-89-6 7.0 1 11/03/23 07:00 11/03/23 15:05 7439-96-5 9.4 1 11/03/23 07:00 11/03/23 15:05 7439-98-7 18.7 1 11/03/23 07:00 11/03/23 15:05 7440-02-0 23.4 1 11/03/23 07:00 11/03/23 15:05 7440-62-2 Analytical Method: EPA 6010C Preparation Method: EPA 3005A Leachate Method/Date: EPA 1311; 10/31/23 23:09 Pace Analytical Services - Melville <0.010 <0.20 <0.0025 0.066 0.017 <0.010 <0.010 mg/L mg/L mg/L mg/L mg/L mg/L mg/L 0.010 1 11/03/23 08:16 11/03/23 17:30 7440-38-2 0.20 1 11/03/23 08:16 11/03/23 17:30 7440-39-3 0.0025 1 11/03/23 08:16 11/03/23 17:30 7440-43-9 0.010 1 11/03/23 08:16 11/03/23 17:30 7440-47-3 0.0050 1 11/03/23 08:16 11/03/23 17:30 7439-92-1 0.010 1 11/03/23 08:16 11/03/23 17:30 7782-49-2 0.010 1 11/03/23 08:16 11/03/23 17:30 7440-22-4 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311; 10/31/23 23:09 Pace Analytical Services - Melville <0.00020 mg/L 0.00020 1 11/06/23 06:00 11/06/23 13:35 7439-97-6 Analytical Method: EPA 7471B Preparation Method: EPA 7471B Pace Analytical Services - Melville <0.034 mg/kg 0.034 1 11/07/23 07:00 11/07/23 14:26 7439-97-6 Analytical Method: ASTM D2216-05M Pace Analytical Services - Melville 1.1 % 0.10 1 11/01/23 08:05 Qual Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 6 of 18 Page 5 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 QC Batch: QC Batch Method: 326524 EPA 7470A Associated Lab Samples: 70275899002, 70275899003 Analysis Method: Analysis Description: Laboratory: EPA 7470A 7470 Mercury TCLP Pace Analytical Services - Melville METHOD BLANK: 1669310 Associated Lab Samples: 70275899002, 70275899003 Mercury Parameter Units mg/L Matrix: Water Blank Result <0.00020 Reporting Limit 0.00020 Analyzed 11/06/23 13:22 Qualifiers METHOD BLANK: 1668811 Associated Lab Samples: 70275899002, 70275899003 Mercury Parameter Units mg/L Matrix: Water Blank Result <0.00020 Reporting Limit 0.00020 Analyzed 11/06/23 13:25 Qualifiers LABORATORY CONTROL SAMPLE: 1669311 Mercury Parameter Units mg/L Spike Conc. 0.001 LCS Result 0.00098 LCS % Rec 98 % Rec Limits 80-120 Qualifiers MATRIX SPIKE SAMPLE: Mercury Parameter 1669312 Units mg/L 70276359002 Result <0.00020 Spike Conc. 0.001 MS Result 0.00099 MS % Rec 98 % Rec Limits 75-125 Qualifiers SAMPLE DUPLICATE: 1669313 Mercury Parameter Units mg/L 70276359002 Result <0.00020 Dup Result <0.00020 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 7 of 18 Page 6 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 QC Batch: 326642 Analysis Method: QC Batch Method: EPA 7471B Analysis Description: Laboratory: Associated Lab Samples: 70275899001, 70275899002, 70275899003 EPA 7471B 7471 Mercury Pace Analytical Services - Melville METHOD BLANK: 1669937 Matrix: Solid Associated Lab Samples: 70275899001, 70275899002, 70275899003 Parameter Units Blank Result Reporting Limit Mercury mg/kg <0.039 0.039 Analyzed 11/07/23 14:13 Qualifiers LABORATORY CONTROL SAMPLE: 1669938 Mercury Parameter Units mg/kg Spike Conc. 0.2 LCS Result 0.19 LCS % Rec 99 % Rec Limits 80-120 Qualifiers MATRIX SPIKE SAMPLE: Mercury Parameter 1669939 Units mg/kg 70275895001 Result 0.050 Spike Conc. 0.22 MS Result 0.28 MS % Rec 106 % Rec Limits 80-120 Qualifiers SAMPLE DUPLICATE: 1669940 Mercury Parameter Units mg/kg 70275895001 Result 0.050 Dup Result 0.049 RPD Qualifiers 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 8 of 18 Page 7 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 QC Batch: 326198 Analysis Method: QC Batch Method: EPA 3050B Analysis Description: Laboratory: Associated Lab Samples: 70275899001, 70275899002, 70275899003 EPA 6010C 6010 MET Pace Analytical Services - Melville METHOD BLANK: 1667298 Matrix: Solid Associated Lab Samples: 70275899001, 70275899002, 70275899003 Parameter Units Blank Result Reporting Limit Aluminum Arsenic Barium Cadmium Chromium Cobalt Copper Iron Lead Manganese Molybdenum Nickel Selenium Silver Vanadium mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg <10.5 10.5 <0.52 0.52 <10.5 10.5 <0.13 0.13 <0.52 0.52 <2.6 2.6 <1.3 1.3 <5.2 5.2 <0.26 0.26 <0.79 0.79 <1.0 1.0 <2.1 2.1 <0.52 0.52 <0.52 0.52 <2.6 2.6 Analyzed 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 11/03/23 14:21 Qualifiers LABORATORY CONTROL SAMPLE: 1667299 Parameter Aluminum Arsenic Barium Cadmium Chromium Cobalt Copper Iron Lead Manganese Molybdenum Nickel Selenium Silver Vanadium Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Spike Conc. 7210 79 314 145 209 218 130 12800 241 502 191 316 118 51.6 80.1 LCS Result 7370 76.9 321 152 232 234 130 11300 245 506 198 337 117 50.6 84.1 LCS % Rec 102 97 102 105 111 107 100 88 102 101 104 107 99 98 105 % Rec Limits 47-153 82-118 80-120 79-121 80-121 80-120 83-118 61-139 82-118 79-121 79-121 79-121 78-123 78-122 77-123 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 9 of 18 Page 8 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 MATRIX SPIKE SAMPLE: Parameter Aluminum Arsenic Barium Cadmium Chromium Cobalt Copper Iron Lead Manganese Molybdenum Nickel Selenium Silver Vanadium 1667880 Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 70275895001 Result 9400 9.5 38.1 0.12J 11.8 4.3 11.0 11000 31.6 222 0.45J 8.6 <0.55 <0.55 21.3 Spike Conc. 719 28.8 28.8 28.8 28.8 28.8 28.8 288 28.8 28.8 57.5 28.8 28.8 14.4 28.8 MS Result 12900 35.6 77.6 27.4 43.4 31.9 38.9 12900 61.0 266 54.8 37.4 25.5 14.7 52.7 MS % Rec 493 91 138 95 110 96 97 681 102 153 94 100 89 102 109 % Rec Limits Qualifiers 75-125 M1 75-125 75-125 M1 75-125 75-125 75-125 75-125 75-125 M1 75-125 75-125 M1 75-125 75-125 75-125 75-125 75-125 SAMPLE DUPLICATE: 1667879 Parameter Aluminum Arsenic Barium Cadmium Chromium Cobalt Copper Iron Lead Manganese Molybdenum Nickel Selenium Silver Vanadium Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 70275895001 Result 9400 9.5 38.1 0.12J 11.8 4.3 11.0 11000 31.6 222 0.45J 8.6 <0.55 <0.55 21.3 Dup Result 10300 8.9 41.7 <0.14 14.0 5.1 16.9 12900 32.3 239 <1.1 9.7 <0.55 <0.55 23.6 RPD Qualifiers 9 6 9 17 17 43 D6 16 2 7 11 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 10 of 18 Page 9 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 QC Batch: QC Batch Method: 326310 EPA 3005A Associated Lab Samples: 70275899002, 70275899003 Analysis Method: Analysis Description: Laboratory: EPA 6010C 6010 MET TCLP Pace Analytical Services - Melville METHOD BLANK: 1667890 Associated Lab Samples: 70275899002, 70275899003 Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L Matrix: Water Blank Result <0.010 <0.20 <0.0025 <0.010 <0.0050 <0.010 <0.010 Reporting Limit 0.010 0.20 0.0025 0.010 0.0050 0.010 0.010 Analyzed 11/03/23 16:55 11/03/23 16:55 11/03/23 16:55 11/03/23 16:55 11/03/23 16:55 11/03/23 16:55 11/03/23 16:55 Qualifiers METHOD BLANK: 1666667 Associated Lab Samples: 70275899002, 70275899003 Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L Matrix: Water Blank Result <0.010 <0.20 <0.0025 <0.010 <0.0050 <0.010 <0.010 Reporting Limit 0.010 0.20 0.0025 0.010 0.0050 0.010 0.010 Analyzed 11/03/23 18:00 11/03/23 18:00 11/03/23 18:00 11/03/23 18:00 11/03/23 18:00 11/03/23 18:00 11/03/23 18:00 Qualifiers LABORATORY CONTROL SAMPLE: 1667891 Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L Spike Conc. 0.5 0.5 0.5 0.5 0.5 0.5 0.25 LCS Result 0.48 0.50 0.50 0.51 0.51 0.48 0.24 LCS % Rec 96 99 100 102 101 96 97 % Rec Limits 80-120 80-120 80-120 80-120 80-120 80-120 80-120 Qualifiers MATRIX SPIKE SAMPLE: Arsenic Parameter 1667893 Units mg/L 70276026001 Result <0.010 Spike Conc. 0.1 MS Result 0.091 MS % Rec 91 % Rec Limits 75-125 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 11 of 18 Page 10 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 MATRIX SPIKE SAMPLE: Barium Cadmium Chromium Lead Selenium Silver Parameter 1667893 Units mg/L mg/L mg/L mg/L mg/L mg/L 70276026001 Result <0.20 <0.0025 <0.010 0.17 <0.010 <0.010 Spike Conc. 0.1 0.1 0.1 0.1 0.1 0.05 MS Result <0.20 0.094 0.098 0.26 0.088 0.045 MS % Rec 90 94 97 90 88 90 % Rec Limits 75-125 75-125 75-125 75-125 75-125 75-125 Qualifiers SAMPLE DUPLICATE: 1667892 Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L 70276026001 Result <0.010 <0.20 <0.0025 <0.010 0.17 <0.010 <0.010 Dup Result <0.010 <0.20 <0.0025 <0.010 0.17 <0.010 <0.010 RPD Qualifiers 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 12 of 18 Page 11 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 QC Batch: QC Batch Method: 331233 EPA 3005A Associated Lab Samples: 70275899001 Analysis Method: Analysis Description: Laboratory: EPA 6010C 6010 MET TCLP Pace Analytical Services - Melville METHOD BLANK: 1697319 Associated Lab Samples: 70275899001 Chromium Parameter Units mg/L Matrix: Water Blank Result <0.010 Reporting Limit 0.010 Analyzed 12/19/23 17:34 Qualifiers METHOD BLANK: 1669849 Associated Lab Samples: 70275899001 Chromium Parameter Units mg/L Matrix: Water Blank Result <0.050 Reporting Limit 0.050 Analyzed 12/19/23 17:52 Qualifiers LABORATORY CONTROL SAMPLE: 1697320 Chromium Parameter Units mg/L Spike Conc. 0.5 LCS Result 0.48 LCS % Rec 96 % Rec Limits 80-120 Qualifiers MATRIX SPIKE SAMPLE: Chromium Parameter 1697322 Units mg/L 70275899001 Result <0.050 Spike Conc. 0.5 MS Result 0.48 MS % Rec 95 % Rec Limits 75-125 Qualifiers SAMPLE DUPLICATE: 1697321 Chromium Parameter Units mg/L 70275899001 Result <0.050 Dup Result <0.050 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 13 of 18 Page 12 of 17 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 QC Batch: 325952 Analysis Method: QC Batch Method: ASTM D2216-05M Analysis Description: Laboratory: Associated Lab Samples: 70275899001, 70275899002, 70275899003 ASTM D2216-05M Dry Weight/Percent Moisture Pace Analytical Services - Melville SAMPLE DUPLICATE: 1665498 Parameter Percent Moisture Units % 70275896001 Result 7.1 Dup Result 7.0 RPD Qualifiers 1 SAMPLE DUPLICATE: 1665499 Parameter Percent Moisture Units % 70276026001 Result 0.82 Dup Result 0.84 RPD Qualifiers 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 14 of 18 Page 13 of 17 #=QL# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALIFIERS Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. BATCH QUALIFIERS Batch: 326352 [1] The post digestion spike for sample 70276026001 (PDS 1668164) did not meet acceptance criteria for Silver. Batch: 326357 [1] The serial dilution for sample 70275895001 (SD 1668171) did not meet acceptance criteria for Arsenic, Calcium, Iron, Sodium, Tin, and Zinc. [2] The post digestions spike for sample 70275895001 (PDS 1668172) did not meet acceptance criteria for all analytes except for Potassium. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 15 of 18 Page 14 of 17 #=CR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: WASTEWATER TREATMENT SL 10/28 70275899 Lab ID 70275899001 70275899002 70275899003 70275899001 70275899002 70275899003 70275899002 70275899003 70275899001 70275899002 70275899003 70275899001 70275899002 70275899003 Sample ID VAULT CACO3 TI#2 CACO3 TI#1 VAULT CACO3 TI#2 CACO3 TI#1 CACO3 TI#2 CACO3 TI#1 VAULT CACO3 TI#2 CACO3 TI#1 VAULT CACO3 TI#2 CACO3 TI#1 QC Batch Method EPA 3050B EPA 3050B EPA 3050B EPA 3005A EPA 3005A EPA 3005A EPA 7470A EPA 7470A EPA 7471B EPA 7471B EPA 7471B ASTM D2216-05M ASTM D2216-05M ASTM D2216-05M QC Batch 326198 326198 326198 331233 326310 326310 326524 326524 326642 326642 326642 325952 325952 325952 Analytical Method EPA 6010C EPA 6010C EPA 6010C EPA 6010C EPA 6010C EPA 6010C EPA 7470A EPA 7470A EPA 7471B EPA 7471B EPA 7471B Analytical Batch 326357 326357 326357 331269 326352 326352 326544 326544 326729 326729 326729 Date: 12/27/2023 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 3 Page 16 of 18 Page 15 of 17 Attachment 3 Page 17 of 18 Page 16 of 17 Attachment 3 Page 18 of 18 Page 17 of 17 Attachment 04 Wastewater Analytical #=CL# LIMS USE: FR - MARY MCCOY LIMS OBJECT ID: 70266147 August 30, 2023 Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Mary McCoy Ducommun Aerostructures 171 Stacy Road Coxsackie, NY 12051 RE: Project: SEMI ANNUAL 8/8 Pace Project No.: 70266147 Dear Mary McCoy: Enclosed are the analytical results for sample(s) received by the laboratory on August 08, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: Pace Analytical Services - Melville Pace Analytical Services - Greensburg If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew T. Nemeth matthew.nemeth@pacelabs.com 516-370-6042 Project Manager Enclosures cc: Linda Barley, Ducommun Aerostructures Pedro Dumaua, Ducommun Aerostructures Eugenia Lighthouse, Ducommun Incorporated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 1 of 30 Page 1 of 30 #=CP# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Pace Analytical Services Pennsylvania 1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601 ANAB DOD-ELAP Rad Accreditation #: L2417 ANABISO/IEC 17025:2017 Rad Cert#: L24170 Alabama Certification #: 41590 Arizona Certification #: AZ0734 Arkansas Certification California Certification #: 2950 Colorado Certification #: PA01547 Connecticut Certification #: PH-0694 EPA Region 4 DW Rad Florida/TNI Certification #: E87683 Georgia Certification #: C040 Guam Certification Hawaii Certification Idaho Certification Illinois Certification Indiana Certification Iowa Certification #: 391 Kansas Certification #: E-10358 Kentucky Certification #: KY90133 KY WW Permit #: KY0098221 KY WW Permit #: KY0000221 Louisiana DHH/TNI Certification #: LA010 Louisiana DEQ/TNI Certification #: 04086 Maine Certification #: 2023021 Maryland Certification #: 308 Massachusetts Certification #: M-PA1457 Michigan/PADEP Certification #: 9991 Pace Analytical Services Long Island 575 Broad Hollow Rd, Melville, NY 11747 Connecticut Certification #: PH-0435 Delaware Certification # NY 10478 Maryland Certification #: 208 Massachusetts Certification #: M-NY026 New Hampshire Certification #: 2987 CERTIFICATIONS Missouri Certification #: 235 Montana Certification #: Cert0082 Nebraska Certification #: NE-OS-29-14 Nevada Certification #: PA014572023-03 New Hampshire/TNI Certification #: 297622 New Jersey/TNI Certification #: PA051 New Mexico Certification #: PA01457 New York/TNI Certification #: 10888 North Carolina Certification #: 42706 North Dakota Certification #: R-190 Ohio EPA Rad Approval: #41249 Oregon/TNI Certification #: PA200002-015 Pennsylvania/TNI Certification #: 65-00282 Puerto Rico Certification #: PA01457 Rhode Island Certification #: 65-00282 South Dakota Certification Tennessee Certification #: TN02867 Texas/TNI Certification #: T104704188-22-18 Utah/TNI Certification #: PA014572223-14 USDA Soil Permit #: 525-23-67-77263 Vermont Dept. of Health: ID# VT-0282 Virgin Island/PADEP Certification Virginia/VELAP Certification #: 460198 Washington Certification #: C868 West Virginia DEP Certification #: 143 West Virginia DHHR Certification #: 9964C Wisconsin Approve List for Rad New Jersey Certification #: NY158 New York Certification #: 10478 Primary Accrediting Body Pennsylvania Certification #: 68-00350 Rhode Island Certification #: LAO00340 Virginia Certification # 460302 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 2 of 30 Page 2 of 30 #=SA# Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Lab ID 70266147001 Sample ID EFFLUENT 70266147002 EFFLUENT 70266147003 TRIP BLANK PACE-MV = Pace Analytical Services - Melville PASI-PA = Pace Analytical Services - Greensburg SAMPLE ANALYTE COUNT Method EPA 608.3 EPA 608.3 EPA 200.7 SM22 3500-Cr B EPA 300.0 EPA 350.1 EPA 625.1 EPA 624.1 SM22 4500-H+B EPA 335.4 EPA 624.1 Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Analysts CGTA CGTA JWT DJM RESE BNK RP1 TJD NAA CMT TJD Analytes Reported Laboratory 9 PACE-MV 22 PACE-MV 7 PACE-MV 1 PACE-MV 1 PACE-MV 1 PACE-MV 62 PACE-MV 39 PACE-MV 2 PACE-MV 1 PASI-PA 39 PACE-MV REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 3 of 30 Page 3 of 30 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Sample: EFFLUENT Lab ID: 70266147001 Parameters Results Units Collected: 08/08/23 11:30 Received: 08/08/23 16:00 Matrix: Water Report Limit DF Prepared Analyzed CAS No. Qual 608.3 GCSV PCB PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 608.3 GCSV Pesticides Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Methoxychlor Mirex Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 Metals, Total Cadmium Chromium Copper Lead Nickel Silver Zinc Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Melville <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L 1.0 1 08/15/23 13:08 08/16/23 19:27 12674-11-2 1.0 1 08/15/23 13:08 08/16/23 19:27 11104-28-2 1.0 1 08/15/23 13:08 08/16/23 19:27 11141-16-5 1.0 1 08/15/23 13:08 08/16/23 19:27 53469-21-9 1.0 1 08/15/23 13:08 08/16/23 19:27 12672-29-6 1.0 1 08/15/23 13:08 08/16/23 19:27 11097-69-1 1.0 1 08/15/23 13:08 08/16/23 19:27 11096-82-5 76 % 30 % 10-152 1 08/15/23 13:08 08/16/23 19:27 877-09-8 10-124 1 08/15/23 13:08 08/16/23 19:27 2051-24-3 Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Melville <0.050 ug/L <0.050 ug/L <0.050 ug/L <0.050 ug/L <0.050 ug/L <1.0 ug/L <0.10 ug/L <0.10 ug/L <0.10 ug/L <0.10 ug/L 0.21 ug/L <0.10 ug/L <0.10 ug/L <0.10 ug/L <0.10 ug/L <0.050 ug/L <0.050 ug/L <0.50 ug/L <0.10 ug/L <5.0 ug/L 0.050 1 08/15/23 13:08 08/16/23 19:21 309-00-2 0.050 1 08/15/23 13:08 08/16/23 19:21 319-84-6 0.050 1 08/15/23 13:08 08/16/23 19:21 319-85-7 0.050 1 08/15/23 13:08 08/16/23 19:21 319-86-8 0.050 1 08/15/23 13:08 08/16/23 19:21 58-89-9 1.0 1 08/15/23 13:08 08/16/23 19:21 57-74-9 L1 0.10 1 08/15/23 13:08 08/16/23 19:21 72-54-8 0.10 1 08/15/23 13:08 08/16/23 19:21 72-55-9 0.10 1 08/15/23 13:08 08/16/23 19:21 50-29-3 0.10 1 08/15/23 13:08 08/16/23 19:21 60-57-1 0.050 1 08/15/23 13:08 08/16/23 19:21 959-98-8 0.10 1 08/15/23 13:08 08/16/23 19:21 33213-65-9 0.10 1 08/15/23 13:08 08/16/23 19:21 1031-07-8 0.10 1 08/15/23 13:08 08/16/23 19:21 72-20-8 0.10 1 08/15/23 13:08 08/16/23 19:21 7421-93-4 0.050 1 08/15/23 13:08 08/16/23 19:21 76-44-8 0.050 1 08/15/23 13:08 08/16/23 19:21 1024-57-3 0.50 1 08/15/23 13:08 08/16/23 19:21 72-43-5 0.10 1 08/15/23 13:08 08/16/23 19:21 2385-85-5 5.0 1 08/15/23 13:08 08/16/23 19:21 8001-35-2 82 % 32 % 10-152 1 08/15/23 13:08 08/16/23 19:21 877-09-8 10-124 1 08/15/23 13:08 08/16/23 19:21 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Melville <2.5 ug/L 39.9 ug/L <25.0 ug/L <5.0 ug/L <40.0 ug/L <10.0 ug/L <20.0 ug/L 2.5 1 08/10/23 07:26 08/10/23 14:21 7440-43-9 10.0 1 08/10/23 07:26 08/10/23 14:21 7440-47-3 25.0 1 08/10/23 07:26 08/10/23 14:21 7440-50-8 5.0 1 08/10/23 07:26 08/10/23 14:21 7439-92-1 40.0 1 08/10/23 07:26 08/10/23 14:21 7440-02-0 10.0 1 08/10/23 07:26 08/10/23 14:21 7440-22-4 20.0 1 08/10/23 07:26 08/10/23 14:21 7440-66-6 Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 4 of 30 Page 4 of 30 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Sample: EFFLUENT Lab ID: 70266147001 Parameters Results Units Collected: 08/08/23 11:30 Received: 08/08/23 16:00 Matrix: Water Report Limit DF Prepared Analyzed CAS No. Qual Chromium, Hexavalent Chromium, Hexavalent 300.0 IC Anions 28 Days Fluoride 350.1 Ammonia Nitrogen, Ammonia Analytical Method: SM22 3500-Cr B Pace Analytical Services - Melville <0.020 mg/L 0.020 1 Analytical Method: EPA 300.0 Pace Analytical Services - Melville 12.1 mg/L 0.20 2 Analytical Method: EPA 350.1 Pace Analytical Services - Melville <0.10 mg/L 0.10 1 08/11/23 00:41 18540-29-9 H1 08/22/23 09:35 16984-48-8 08/13/23 13:30 7664-41-7 Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 5 of 30 Page 5 of 30 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Sample: EFFLUENT Lab ID: 70266147002 Parameters Results Units Collected: 08/08/23 11:36 Received: 08/08/23 16:00 Matrix: Water Report Limit DF Prepared Analyzed CAS No. Qual Field Chlorine and pH Field Temperature Field pH 625.1 MSSV Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene 4-Bromophenylphenyl ether Butylbenzylphthalate 4-Chloro-3-methylphenol bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenylphenyl ether Chrysene Dibenz(a,h)anthracene 3,3'-Dichlorobenzidine 2,4-Dichlorophenol Diethylphthalate 2,4-Dimethylphenol Dimethylphthalate Di-n-butylphthalate 4,6-Dinitro-2-methylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octylphthalate bis(2-Ethylhexyl)phthalate Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone Naphthalene Nitrobenzene Analytical Method: Pace Analytical Services - Melville 25.0 deg C 1 6.94 Std. Units 1 08/08/23 11:36 N3 08/08/23 11:36 N3 Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 SF Pace Analytical Services - Melville <0.96 ug/L <0.96 ug/L <0.96 ug/L <4.8 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <4.8 ug/L <0.96 ug/L <0.96 ug/L <4.8 ug/L <4.8 ug/L <4.8 ug/L <4.8 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <4.8 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L 0.96 1 08/11/23 22:56 08/14/23 22:42 83-32-9 0.96 1 08/11/23 22:56 08/14/23 22:42 208-96-8 0.96 1 08/11/23 22:56 08/14/23 22:42 120-12-7 4.8 1 08/11/23 22:56 08/14/23 22:42 92-87-5 0.96 1 08/11/23 22:56 08/14/23 22:42 56-55-3 0.96 1 08/11/23 22:56 08/14/23 22:42 50-32-8 0.96 1 08/11/23 22:56 08/14/23 22:42 205-99-2 0.96 1 08/11/23 22:56 08/14/23 22:42 191-24-2 0.96 1 08/11/23 22:56 08/14/23 22:42 207-08-9 0.96 1 08/11/23 22:56 08/14/23 22:42 101-55-3 0.96 1 08/11/23 22:56 08/14/23 22:42 85-68-7 0.96 1 08/11/23 22:56 08/14/23 22:42 59-50-7 0.96 1 08/11/23 22:56 08/14/23 22:42 111-91-1 0.96 1 08/11/23 22:56 08/14/23 22:42 111-44-4 0.96 1 08/11/23 22:56 08/14/23 22:42 91-58-7 0.96 1 08/11/23 22:56 08/14/23 22:42 95-57-8 0.96 1 08/11/23 22:56 08/14/23 22:42 7005-72-3 0.96 1 08/11/23 22:56 08/14/23 22:42 218-01-9 0.96 1 08/11/23 22:56 08/14/23 22:42 53-70-3 0.96 1 08/11/23 22:56 08/14/23 22:42 91-94-1 0.96 1 08/11/23 22:56 08/14/23 22:42 120-83-2 0.96 1 08/11/23 22:56 08/14/23 22:42 84-66-2 4.8 1 08/11/23 22:56 08/14/23 22:42 105-67-9 0.96 1 08/11/23 22:56 08/14/23 22:42 131-11-3 0.96 1 08/11/23 22:56 08/14/23 22:42 84-74-2 4.8 1 08/11/23 22:56 08/14/23 22:42 534-52-1 4.8 1 08/11/23 22:56 08/14/23 22:42 51-28-5 4.8 1 08/11/23 22:56 08/14/23 22:42 121-14-2 4.8 1 08/11/23 22:56 08/14/23 22:42 606-20-2 0.96 1 08/11/23 22:56 08/14/23 22:42 117-84-0 0.96 1 08/11/23 22:56 08/14/23 22:42 117-81-7 0.96 1 08/11/23 22:56 08/14/23 22:42 206-44-0 0.96 1 08/11/23 22:56 08/14/23 22:42 86-73-7 0.96 1 08/11/23 22:56 08/14/23 22:42 87-68-3 0.96 1 08/11/23 22:56 08/14/23 22:42 118-74-1 4.8 1 08/11/23 22:56 08/14/23 22:42 77-47-4 0.96 1 08/11/23 22:56 08/14/23 22:42 67-72-1 0.96 1 08/11/23 22:56 08/14/23 22:42 193-39-5 0.96 1 08/11/23 22:56 08/14/23 22:42 78-59-1 0.96 1 08/11/23 22:56 08/14/23 22:42 91-20-3 0.96 1 08/11/23 22:56 08/14/23 22:42 98-95-3 Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 6 of 30 Page 6 of 30 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Sample: EFFLUENT Lab ID: 70266147002 Parameters Results Units Collected: 08/08/23 11:36 Received: 08/08/23 16:00 Matrix: Water Report Limit DF Prepared Analyzed CAS No. 625.1 MSSV 2-Nitrophenol 4-Nitrophenol N-Nitrosodimethylamine N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine 2,2'-Oxybis(1-chloropropane) Pentachlorophenol Phenanthrene Phenol Pyrene 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Surrogates 2-Fluorophenol (S) Phenol-d5 (S) Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) 2,4,6-Tribromophenol (S) p-Terphenyl-d14 (S) 1,2-Dichlorobenzene-d4 (S) 2-Chlorophenol-d4 (S) 624.1 Volatile Organics 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Chloroethylvinyl ether Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 SF Pace Analytical Services - Melville <4.8 ug/L <9.6 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <4.8 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L <0.96 ug/L 4.8 1 08/11/23 22:56 08/14/23 22:42 88-75-5 9.6 1 08/11/23 22:56 08/14/23 22:42 100-02-7 0.96 1 08/11/23 22:56 08/14/23 22:42 62-75-9 0.96 1 08/11/23 22:56 08/14/23 22:42 621-64-7 0.96 1 08/11/23 22:56 08/14/23 22:42 86-30-6 0.96 1 08/11/23 22:56 08/14/23 22:42 108-60-1 4.8 1 08/11/23 22:56 08/14/23 22:42 87-86-5 0.96 1 08/11/23 22:56 08/14/23 22:42 85-01-8 0.96 1 08/11/23 22:56 08/14/23 22:42 108-95-2 0.96 1 08/11/23 22:56 08/14/23 22:42 129-00-0 0.96 1 08/11/23 22:56 08/14/23 22:42 120-82-1 0.96 1 08/11/23 22:56 08/14/23 22:42 95-95-4 0.96 1 08/11/23 22:56 08/14/23 22:42 88-06-2 34 % 22 % 73 % 72 % 74 % 71 % 61 % 57 % 4-79 1 08/11/23 22:56 08/14/23 22:42 367-12-4 5-55 1 08/11/23 22:56 08/14/23 22:42 4165-62-2 45-110 1 08/11/23 22:56 08/14/23 22:42 4165-60-0 43-114 1 08/11/23 22:56 08/14/23 22:42 321-60-8 23-146 1 08/11/23 22:56 08/14/23 22:42 118-79-6 27-144 1 08/11/23 22:56 08/14/23 22:42 1718-51-0 32-100 1 08/11/23 22:56 08/14/23 22:42 2199-69-1 37-96 1 08/11/23 22:56 08/14/23 22:42 93951-73-6 Analytical Method: EPA 624.1 Pace Analytical Services - Melville <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L 3.7 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L 34.5 ug/L 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 08/09/23 16:02 71-55-6 79-34-5 79-00-5 75-34-3 75-35-4 95-50-1 107-06-2 78-87-5 541-73-1 106-46-7 110-75-8 107-02-8 107-13-1 71-43-2 75-27-4 75-25-2 74-83-9 56-23-5 108-90-7 75-00-3 67-66-3 Qual Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 7 of 30 Page 7 of 30 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Sample: EFFLUENT Lab ID: 70266147002 Parameters Results Units Collected: 08/08/23 11:36 Received: 08/08/23 16:00 Matrix: Water Report Limit DF Prepared Analyzed CAS No. Qual 624.1 Volatile Organics Chloromethane Dibromochloromethane Dichlorodifluoromethane Ethylbenzene Methylene Chloride Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 4500H+ pH, Electrometric pH Temperature, Water (C) 335.4 Cyanide, Total Cyanide Analytical Method: EPA 624.1 Pace Analytical Services - Melville <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 08/09/23 16:02 74-87-3 08/09/23 16:02 124-48-1 08/09/23 16:02 75-71-8 v3 08/09/23 16:02 100-41-4 08/09/23 16:02 75-09-2 08/09/23 16:02 127-18-4 08/09/23 16:02 108-88-3 08/09/23 16:02 79-01-6 08/09/23 16:02 75-69-4 08/09/23 16:02 75-01-4 08/09/23 16:02 1330-20-7 08/09/23 16:02 156-59-2 08/09/23 16:02 10061-01-5 08/09/23 16:02 156-60-5 08/09/23 16:02 10061-02-6 101 % 97 % 91 % 73-122 1 75-122 1 80-120 1 08/09/23 16:02 460-00-4 08/09/23 16:02 2037-26-5 08/09/23 16:02 17060-07-0 Analytical Method: SM22 4500-H+B Pace Analytical Services - Melville 6.8 Std. Units 10.0 deg C 0.10 1 0.10 1 08/17/23 10:31 08/17/23 10:31 H3,H6, N3 H3,H6 Analytical Method: EPA 335.4 Preparation Method: EPA 335.4 Pace Analytical Services - Greensburg <0.010 mg/L 0.010 1 08/22/23 08:28 08/22/23 11:51 57-12-5 Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 8 of 30 Page 8 of 30 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Sample: TRIP BLANK Lab ID: 70266147003 Parameters Results Units Collected: 08/08/23 00:00 Received: 08/08/23 16:00 Matrix: Water Report Limit DF Prepared Analyzed CAS No. Qual 624.1 Volatile Organics 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Chloroethylvinyl ether Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dichlorodifluoromethane Ethylbenzene Methylene Chloride Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) Analytical Method: EPA 624.1 Pace Analytical Services - Melville <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L <1.0 ug/L 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 1.0 1 101 % 98 % 92 % 73-122 1 75-122 1 80-120 1 08/09/23 15:39 71-55-6 08/09/23 15:39 79-34-5 08/09/23 15:39 79-00-5 08/09/23 15:39 75-34-3 08/09/23 15:39 75-35-4 08/09/23 15:39 95-50-1 08/09/23 15:39 107-06-2 08/09/23 15:39 78-87-5 08/09/23 15:39 541-73-1 08/09/23 15:39 106-46-7 08/09/23 15:39 110-75-8 08/09/23 15:39 107-02-8 08/09/23 15:39 107-13-1 08/09/23 15:39 71-43-2 08/09/23 15:39 75-27-4 08/09/23 15:39 75-25-2 08/09/23 15:39 74-83-9 08/09/23 15:39 56-23-5 08/09/23 15:39 108-90-7 08/09/23 15:39 75-00-3 08/09/23 15:39 67-66-3 08/09/23 15:39 74-87-3 08/09/23 15:39 124-48-1 08/09/23 15:39 75-71-8 v3 08/09/23 15:39 100-41-4 08/09/23 15:39 75-09-2 08/09/23 15:39 127-18-4 08/09/23 15:39 108-88-3 08/09/23 15:39 79-01-6 08/09/23 15:39 75-69-4 08/09/23 15:39 75-01-4 08/09/23 15:39 1330-20-7 08/09/23 15:39 156-59-2 08/09/23 15:39 10061-01-5 08/09/23 15:39 156-60-5 08/09/23 15:39 10061-02-6 08/09/23 15:39 460-00-4 08/09/23 15:39 2037-26-5 08/09/23 15:39 17060-07-0 Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 9 of 30 Page 9 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 315737 EPA 200.7 Associated Lab Samples: 70266147001 METHOD BLANK: 1607022 Associated Lab Samples: 70266147001 Cadmium Chromium Copper Lead Nickel Silver Zinc Parameter Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: EPA 200.7 200.7 Metals, Total Pace Analytical Services - Melville Matrix: Water Blank Result <2.5 <10.0 <25.0 <5.0 <40.0 <10.0 <20.0 Reporting Limit 2.5 10.0 25.0 5.0 40.0 10.0 20.0 Analyzed 08/10/23 13:10 08/10/23 13:10 08/10/23 13:10 08/10/23 13:10 08/10/23 13:10 08/10/23 13:10 08/10/23 13:10 Qualifiers LABORATORY CONTROL SAMPLE: 1607023 Cadmium Chromium Copper Lead Nickel Silver Zinc Parameter Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L Spike Conc. 500 500 500 500 500 250 500 LCS Result 496 486 498 508 495 242 503 LCS % Rec 99 97 100 102 99 97 101 % Rec Limits 85-115 85-115 85-115 85-115 85-115 85-115 85-115 Qualifiers MATRIX SPIKE SAMPLE: Cadmium Chromium Copper Lead Nickel Silver Zinc Parameter 1607025 Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L 70266024006 Result <2.5 <10.0 <25.0 <5.0 <40.0 <10.0 <20.0 Spike Conc. 500 500 500 500 500 250 500 MS Result 518 505 521 528 493 197 523 MS % Rec 104 101 104 106 98 79 104 % Rec Limits 70-130 70-130 70-130 70-130 70-130 70-130 70-130 Qualifiers SAMPLE DUPLICATE: 1607024 Cadmium Chromium Copper Parameter Units ug/L ug/L ug/L 70266024006 Result <2.5 <10.0 <25.0 Dup Result <2.5 <10.0 <25.0 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 10 of 30 Page 10 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 SAMPLE DUPLICATE: 1607024 Lead Nickel Silver Zinc Parameter Units ug/L ug/L ug/L ug/L QUALITY CONTROL DATA 70266024006 Result <5.0 <40.0 <10.0 <20.0 Dup Result <5.0 <40.0 <10.0 <20.0 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 11 of 30 Page 11 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 315676 EPA 624.1 Associated Lab Samples: 70266147002, 70266147003 METHOD BLANK: 1606546 Associated Lab Samples: 70266147002, 70266147003 Parameter 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Chloroethylvinyl ether Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dichlorodifluoromethane Ethylbenzene Methylene Chloride Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % % Analysis Method: Analysis Description: Laboratory: EPA 624.1 624.1 MSV Pace Analytical Services - Melville Matrix: Water Blank Result <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 90 100 97 Reporting Limit 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 80-120 73-122 75-122 Analyzed 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 08/09/23 12:14 Qualifiers v3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 12 of 30 Page 12 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 LABORATORY CONTROL SAMPLE: 1606547 Parameter 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Chloroethylvinyl ether Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dichlorodifluoromethane Ethylbenzene Methylene Chloride Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % % QUALITY CONTROL DATA Spike Conc. 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 60 LCS Result 18.1 17.3 19.3 19.8 18.1 18.8 19.9 19.6 18.6 18.9 21.5 20.4 17.7 19.8 18.3 17.1 9.3 18.2 19.7 19.0 20.0 14.0 20.3 17.7 18.2 10.9 19.6 19.9 16.6 20.0 19.7 17.0 19.4 19.9 17.1 59.1 LCS % Rec 91 87 96 99 91 94 100 98 93 94 107 102 89 99 91 86 47 91 98 95 100 70 102 88 91 54 98 100 83 100 99 85 97 99 85 99 90 103 96 % Rec Limits Qualifiers 70-130 60-140 70-130 70-130 70-130 65-135 70-130 35-165 70-130 65-135 10-225 60-140 60-140 65-135 65-135 70-130 15-185 IH 70-130 65-135 40-160 70-135 10-205 62-135 25-175 70-135 10-146 v3 60-140 60-140 65-135 70-130 70-130 50-150 65-135 50-150 5-195 73-123 80-120 73-122 75-122 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1606706 MS 70266147002 Spike Parameter Units Result Conc. 1,1,1-Trichloroethane ug/L <1.0 20 MSD Spike Conc. 1606707 MS Result 20 18.5 MSD Result 17.5 MS % Rec 92 MSD % Rec 88 % Rec Limits RPD 70-130 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Qual Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 13 of 30 Page 13 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1606706 MS 70266147002 Spike Parameter Units Result Conc. 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Chloroethylvinyl ether Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dichlorodifluoromethane Ethylbenzene Methylene Chloride Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L 3.7 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L 34.5 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 20 ug/L <1.0 60 % % % MSD Spike Conc. 1606707 MS Result 20 17.1 20 19.2 20 19.9 20 17.9 20 18.3 20 19.3 20 18.8 20 18.3 20 18.2 20 18.3 20 21.1 20 17.7 20 19.7 20 21.3 20 15.7 20 4.3 20 18.4 20 19.3 20 17.8 20 53.0 20 10.2 20 20.2 20 16.5 20 17.1 20 7.5 20 19.5 20 21.3 20 16.7 20 20.6 20 22.3 20 15.9 20 19.6 20 18.1 20 14.2 60 59.5 MSD Result 16.5 18.5 18.3 17.3 18.5 18.4 18.1 18.4 18.3 14.6 25.9 16.8 18.9 20.7 15.3 5.1 17.0 18.3 16.5 50.8 10.0 18.9 15.7 16.4 7.1 18.8 20.6 16.4 19.6 20.7 14.6 18.8 17.3 12.9 56.9 MS % Rec 85 96 100 90 92 97 94 92 91 91 106 89 98 88 78 22 92 96 89 93 51 101 83 85 37 98 106 84 103 112 79 98 91 71 99 90 103 96 MSD % Rec 82 93 91 87 92 92 90 92 91 73 129 84 94 85 77 25 85 91 83 81 50 94 78 82 35 94 103 82 98 103 73 94 87 64 95 90 101 96 % Rec Limits RPD Qual 60-140 70-130 70-130 70-130 65-135 70-130 35-165 70-130 65-135 10-225 60-140 60-140 65-135 65-135 70-130 15-185 70-130 65-135 40-160 70-135 10-205 62-135 25-175 70-135 10-146 60-140 60-140 65-135 70-130 70-130 50-150 65-135 50-150 5-195 73-123 80-120 73-122 75-122 3 4 9 3 1 5 4 1 0 22 20 6 4 3 2 16 IH 7 5 7 4 2 7 5 4 6 v3 4 3 2 5 8 8 4 5 9 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 14 of 30 Page 14 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 316402 EPA 608.3 Associated Lab Samples: 70266147001 METHOD BLANK: 1610595 Associated Lab Samples: 70266147001 Parameter PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: EPA 608.3 608.3 GCSV PCB Pace Analytical Services - Melville Matrix: Water Blank Result <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 83 79 Reporting Limit 1.0 1.0 1.0 1.0 1.0 1.0 1.0 10-124 10-152 Analyzed 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 08/16/23 18:49 Qualifiers LABORATORY CONTROL SAMPLE & LCSD: 1610596 Parameter PCB-1016 (Aroclor 1016) PCB-1260 (Aroclor 1260) Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Units ug/L ug/L % % Spike Conc. 5 5 1610597 LCS LCSD Result Result LCS LCSD % Rec % Rec 3.7 3.9 73 78 3.9 3.9 78 78 64 66 74 75 % Rec Limits 50-140 8-140 10-124 10-152 RPD 6 1 Max RPD 30 30 30 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 15 of 30 Page 15 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 316401 EPA 608.3 Associated Lab Samples: 70266147001 METHOD BLANK: 1610590 Associated Lab Samples: 70266147001 Parameter 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC beta-BHC Chlordane (Technical) delta-BHC Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Methoxychlor Mirex Toxaphene Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: EPA 608.3 608.3 GCSV Pesticides Pace Analytical Services - Melville Matrix: Water Blank Result ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 103 87 Reporting Limit 0.10 0.10 0.10 0.050 0.050 0.050 1.0 0.050 0.10 0.050 0.10 0.10 0.10 0.10 0.050 0.050 0.050 0.50 0.10 5.0 10-124 10-152 Analyzed 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 08/16/23 18:13 Qualifiers LABORATORY CONTROL SAMPLE & LCSD: 1610591 Parameter 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC beta-BHC delta-BHC Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Spike Conc. 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 1610592 LCS LCSD Result Result LCS LCSD % Rec % Rec 0.30 0.28 76 70 0.26 0.25 65 62 0.24 0.20 61 50 0.25 0.24 63 60 0.26 0.25 66 62 0.29 0.27 72 68 0.31 0.29 78 73 0.30 0.28 74 71 0.24 0.23 60 57 0.28 0.27 70 66 0.31 0.30 78 74 0.32 0.30 79 75 0.37 0.36 94 90 % Rec Limits 31-141 30-145 25-160 42-140 37-140 17-147 19-140 36-146 45-153 10-202 26-144 30-147 23-163 RPD 8 4 20 5 6 6 6 5 5 5 5 6 4 Max RPD 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Qualifiers Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 16 of 30 Page 16 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 LABORATORY CONTROL SAMPLE & LCSD: 1610591 Parameter gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Methoxychlor Mirex Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Units ug/L ug/L ug/L ug/L ug/L % % Spike Conc. 0.4 0.4 0.4 0.4 0.4 1610592 LCS LCSD Result Result LCS LCSD % Rec % Rec 0.30 0.28 75 71 0.26 0.24 64 60 0.30 0.29 74 72 <0.50 <0.50 74 64 0.20 0.19 51 48 80 76 65 61 % Rec Limits 32-140 34-140 37-142 59-151 40-160 10-124 10-152 RPD 6 7 3 5 Max RPD 30 30 30 30 30 30 30 Qualifiers LABORATORY CONTROL SAMPLE: 1610593 Parameter Toxaphene Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Units ug/L % % Spike Conc. 20 LCS Result 18.6 LCS % Rec 93 102 87 % Rec Limits 41-140 10-124 10-152 Qualifiers LABORATORY CONTROL SAMPLE: 1610594 Parameter Chlordane (Technical) Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Units ug/L % % Spike Conc. 0.1 LCS Result <1.0 LCS % Rec 151 104 86 % Rec Limits Qualifiers 30-150 L1 10-124 10-152 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 17 of 30 Page 17 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 316106 EPA 625.1 SF Associated Lab Samples: 70266147002 METHOD BLANK: 1609131 Associated Lab Samples: 70266147002 Parameter 1,2,4-Trichlorobenzene 2,2'-Oxybis(1-chloropropane) 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'-Dichlorobenzidine 4,6-Dinitro-2-methylphenol 4-Bromophenylphenyl ether 4-Chloro-3-methylphenol 4-Chlorophenylphenyl ether 4-Nitrophenol Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Ethylhexyl)phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Dibenz(a,h)anthracene Diethylphthalate Dimethylphthalate Fluoranthene Fluorene Hexachloro-1,3-butadiene Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Analysis Method: Analysis Description: Laboratory: EPA 625.1 625.1 MSSV Pace Analytical Services - Melville Matrix: Water Blank Result ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Reporting Limit 1.0 1.0 1.0 1.0 1.0 5.0 5.0 5.0 5.0 1.0 1.0 5.0 1.0 5.0 1.0 1.0 1.0 10.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Analyzed 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 18 of 30 Page 18 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 METHOD BLANK: 1609131 Associated Lab Samples: 70266147002 Parameter Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone N-Nitroso-di-n-propylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine Naphthalene Nitrobenzene Pentachlorophenol Phenanthrene Phenol Pyrene 1,2-Dichlorobenzene-d4 (S) 2,4,6-Tribromophenol (S) 2-Chlorophenol-d4 (S) 2-Fluorobiphenyl (S) 2-Fluorophenol (S) Nitrobenzene-d5 (S) p-Terphenyl-d14 (S) Phenol-d5 (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % % % % % % % QUALITY CONTROL DATA Matrix: Water Blank Result ND ND ND ND ND ND ND ND ND ND ND ND ND ND 59 73 65 69 35 75 91 26 Reporting Limit 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 32-100 23-146 37-96 43-114 4-79 45-110 27-144 5-55 Analyzed 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 08/14/23 14:02 Qualifiers LABORATORY CONTROL SAMPLE & LCSD: 1609132 Parameter 1,2,4-Trichlorobenzene 2,2'-Oxybis(1-chloropropane) 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'-Dichlorobenzidine 4,6-Dinitro-2-methylphenol 4-Bromophenylphenyl ether 4-Chloro-3-methylphenol 4-Chlorophenylphenyl ether 4-Nitrophenol Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Spike Conc. 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 1609133 LCS LCSD Result Result LCS LCSD % Rec % Rec 17.4 16.6 69 66 19.6 16.7 78 67 22.4 19.9 89 80 19.8 18.8 79 75 18.9 19.2 76 77 14.6 14.9 58 60 26.5 25.5 106 102 23.0 21.8 92 87 20.6 19.8 82 79 20.3 17.6 81 70 16.9 15.7 68 63 18.3 18.7 73 75 24.7 23.9 99 95 26.4 25.8 106 103 21.5 21.0 86 84 20.5 20.0 82 80 22.1 19.8 89 79 10.0 <10.0 40 39 % Rec Limits 57-130 63-139 61-120 52-129 53-122 42-120 10-173 48-127 68-137 65-120 36-120 45-167 8-213 53-130 65-120 41-128 70-130 13-129 RPD 5 16 12 5 1 2 4 6 4 14 7 2 4 2 2 3 11 Max RPD 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Qualifiers Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 19 of 30 Page 19 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 LABORATORY CONTROL SAMPLE & LCSD: 1609132 Parameter Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Ethylhexyl)phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Dibenz(a,h)anthracene Diethylphthalate Dimethylphthalate Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone N-Nitroso-di-n-propylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine Naphthalene Nitrobenzene Pentachlorophenol Phenanthrene Phenol Pyrene 1,2-Dichlorobenzene-d4 (S) 2,4,6-Tribromophenol (S) 2-Chlorophenol-d4 (S) 2-Fluorobiphenyl (S) 2-Fluorophenol (S) Nitrobenzene-d5 (S) p-Terphenyl-d14 (S) Phenol-d5 (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % % % % % % % Spike Conc. 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 1609133 LCS LCSD Result Result LCS LCSD % Rec % Rec 20.0 18.7 80 75 22.1 20.1 89 80 23.3 22.5 93 90 26.8 25.9 107 104 22.4 22.2 90 89 23.9 23.4 96 94 21.1 21.2 85 85 24.2 22.8 97 91 21.7 22.2 87 89 18.7 18.8 75 75 17.1 15.4 68 62 22.5 21.4 90 86 21.6 21.0 87 84 22.1 21.6 88 86 23.4 23.4 94 93 22.5 22.8 90 91 25.3 23.9 101 96 22.6 21.0 90 84 22.3 20.4 89 82 23.3 23.6 93 94 23.1 20.7 93 83 17.5 15.7 70 63 22.1 21.9 88 87 11.3 9.6 45 38 17.3 15.1 69 60 23.2 22.5 93 90 19.1 18.6 76 74 18.8 16.8 75 67 11.2 10.5 45 42 23.0 22.0 92 88 18.0 16.7 72 67 19.5 17.3 78 69 20.7 19.3 83 77 23.6 22.2 94 89 8.5 8.4 34 34 21.2 20.2 85 81 70 60 96 90 69 63 81 75 34 30 77 68 85 80 27 27 % Rec Limits 60-132 67-115 43-120 10-194 42-133 32-148 42-140 10-195 25-146 49-165 43-126 29-137 10-140 44-140 8-120 19-132 10-200 10-120 10-120 43-121 70-120 38-120 8-142 10-106 55-120 10-151 47-180 14-198 25-72 68-124 36-120 54-158 38-152 65-120 17-120 70-120 32-100 23-146 37-96 43-114 4-79 45-110 27-144 5-55 RPD 7 10 3 3 1 2 0 6 2 1 10 5 3 2 0 1 6 7 9 1 11 11 1 16 13 3 3 11 6 4 7 12 7 6 1 5 Max RPD Qualifiers 30 30 30 30 v1 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 20 of 30 Page 20 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 315938 SM22 3500-Cr B Associated Lab Samples: 70266147001 METHOD BLANK: 1608147 Associated Lab Samples: 70266147001 Parameter Chromium, Hexavalent Units mg/L LABORATORY CONTROL SAMPLE: 1608148 Parameter Chromium, Hexavalent Units mg/L MATRIX SPIKE SAMPLE: Parameter Chromium, Hexavalent 1608149 Units mg/L SAMPLE DUPLICATE: 1608150 Parameter Chromium, Hexavalent Units mg/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: SM22 3500-Cr B Chromium, Hexavalent by 3500 Pace Analytical Services - Melville Matrix: Water Blank Result <0.020 Reporting Limit 0.020 Analyzed 08/11/23 00:40 Qualifiers Spike Conc. 0.2 LCS Result 0.20 LCS % Rec 98 % Rec Limits 85-115 Qualifiers 70265372022 Result <0.020 Spike Conc. 0.2 MS Result 0.20 MS % Rec 98 % Rec Limits Qualifiers 75-125 H3 70265372022 Result <0.020 Dup Result <0.020 RPD Qualifiers H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 21 of 30 Page 21 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 316718 SM22 4500-H+B Associated Lab Samples: 70266147002 SAMPLE DUPLICATE: 1612298 Parameter pH Temperature, Water (C) Units Std. Units deg C QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: SM22 4500-H+B 4500H+B pH Pace Analytical Services - Melville 70265582001 Result 7.5 7.2 Dup Result 7.6 7.6 RPD Qualifiers 0 H3,H6,N3 5 H3,H6 SAMPLE DUPLICATE: 1612299 Parameter pH Temperature, Water (C) Units Std. Units deg C 70266798004 Result 7.0 6.5 Dup Result 7.0 6.5 RPD Qualifiers 1 H3,H6,N3 0 H3,H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 22 of 30 Page 22 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 316844 EPA 300.0 Associated Lab Samples: 70266147001 METHOD BLANK: 1613045 Associated Lab Samples: 70266147001 Fluoride Parameter Units mg/L LABORATORY CONTROL SAMPLE: 1613046 Fluoride Parameter Units mg/L MATRIX SPIKE SAMPLE: Fluoride Parameter 1613048 Units mg/L MATRIX SPIKE SAMPLE: Fluoride Parameter 1613050 Units mg/L SAMPLE DUPLICATE: 1613049 Fluoride Parameter Units mg/L SAMPLE DUPLICATE: 1613051 Fluoride Parameter Units mg/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: EPA 300.0 300.0 IC Anions Pace Analytical Services - Melville Matrix: Water Blank Result <0.10 Reporting Limit 0.10 Analyzed 08/18/23 22:43 Qualifiers Spike Conc. 1 LCS Result 1.0 LCS % Rec 102 % Rec Limits 90-110 Qualifiers 70265613001 Result <0.10 Spike Conc. 1 MS Result 0.94 MS % Rec 93 % Rec Limits 90-110 Qualifiers 70266798004 Result <0.10 Spike Conc. 1 MS Result 0.89 MS % Rec 87 % Rec Limits Qualifiers 90-110 M1 70265613001 Result <0.10 Dup Result <0.10 RPD Qualifiers 70266798004 Result <0.10 Dup Result <0.10 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 23 of 30 Page 23 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 610176 EPA 335.4 Associated Lab Samples: 70266147002 METHOD BLANK: 2969629 Associated Lab Samples: 70266147002 Cyanide Parameter Units mg/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: EPA 335.4 335.4 Cyanide, Total Pace Analytical Services - Greensburg Matrix: Water Blank Result <0.010 Reporting Limit 0.010 Analyzed 08/22/23 11:44 Qualifiers METHOD BLANK: 2969631 Associated Lab Samples: 70266147002 Cyanide Parameter Units mg/L Matrix: Water Blank Result <0.010 Reporting Limit 0.010 Analyzed 08/22/23 11:50 Qualifiers 1j LABORATORY CONTROL SAMPLE: 2969630 Cyanide Parameter Units mg/L Spike Conc. 0.2 LCS Result 0.21 LCS % Rec 103 % Rec Limits 90-110 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2969632 MS 30612666001 Spike Parameter Units Result Conc. Cyanide mg/L 0.0069J 0.1 MSD Spike Conc. 2969633 MS Result 0.1 0.094 MSD Result 0.098 MS % Rec 88 MSD % Rec 91 % Rec Limits RPD Qual 90-110 3 ML MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2969634 MS 30613517006 Spike Parameter Units Result Conc. Cyanide mg/L ND 0.1 MSD Spike Conc. 2969635 MS Result 0.1 0.11 MSD Result 0.11 MS % Rec 101 MSD % Rec 103 % Rec Limits RPD 90-110 2 Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 24 of 30 Page 24 of 30 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 QC Batch: QC Batch Method: 316148 EPA 350.1 Associated Lab Samples: 70266147001 METHOD BLANK: 1609366 Associated Lab Samples: 70266147001 Parameter Nitrogen, Ammonia Units mg/L LABORATORY CONTROL SAMPLE: 1609367 Parameter Nitrogen, Ammonia Units mg/L MATRIX SPIKE SAMPLE: Parameter Nitrogen, Ammonia 1609368 Units mg/L MATRIX SPIKE SAMPLE: Parameter Nitrogen, Ammonia 1609370 Units mg/L SAMPLE DUPLICATE: 1609369 Parameter Nitrogen, Ammonia Units mg/L SAMPLE DUPLICATE: 1609371 Parameter Nitrogen, Ammonia Units mg/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: EPA 350.1 350.1 Ammonia Pace Analytical Services - Melville Matrix: Water Blank Result ND Reporting Limit 0.10 Analyzed 08/13/23 13:15 Qualifiers Spike Conc. 1 LCS Result 0.91 LCS % Rec 91 % Rec Limits 90-110 Qualifiers 70266163001 Result 17.4 Spike Conc. 10 MS Result 27.8 MS % Rec 105 % Rec Limits 90-110 Qualifiers 70266332006 Result 15.1 Spike Conc. 10 MS Result 25.8 MS % Rec 107 % Rec Limits 90-110 Qualifiers 70266163001 Result 17.4 Dup Result 16.0 RPD Qualifiers 8 70266332006 Result 15.1 Dup Result 14.2 RPD Qualifiers 7 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 25 of 30 Page 25 of 30 #=QL# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALIFIERS Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS 1j pH was adjusted to >12 from unpreserved bottle at bench H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased low. N3 Accreditation is not offered by the relevant laboratory accrediting body for this parameter. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have a low bias. Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 26 of 30 Page 26 of 30 #=CR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: SEMI ANNUAL 8/8 70266147 Lab ID 70266147002 70266147001 70266147001 70266147001 70266147002 70266147002 70266147003 70266147001 70266147002 70266147001 70266147002 70266147001 Sample ID EFFLUENT EFFLUENT EFFLUENT EFFLUENT EFFLUENT EFFLUENT TRIP BLANK EFFLUENT EFFLUENT EFFLUENT EFFLUENT EFFLUENT QC Batch Method EPA 608.3 EPA 608.3 EPA 200.7 EPA 625.1 SF EPA 624.1 EPA 624.1 SM22 3500-Cr B SM22 4500-H+B EPA 300.0 EPA 335.4 EPA 350.1 QC Batch 315921 316402 316401 315737 316106 315676 315676 315938 316718 316844 610176 316148 Analytical Method EPA 608.3 EPA 608.3 EPA 200.7 EPA 625.1 EPA 335.4 Analytical Batch 316515 316511 315800 316118 610216 Date: 08/30/2023 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 4 Page 27 of 30 Page 27 of 30 Attachment 4 Page 28 of 30 Page 28 of 30 Attachment 4 Page 29 of 30 Page 29 of 30 Attachment 4 Page 30 of 30 Page 30 of 30 Attachment 05 Garnet Waste Determination Form No.: Last Reviewed Date: Revision No.: Coxsackie, New York F-00663 Hazardous Waste Determination Worksheet - 10/17/2023 A Authorized By: WI-00216 Environmental Management System - Requirements Page 1 of 2 DCO Site: Coxsackie 171 Stacey Road Coxsackie, NY 12051-2613 EPA ID: NYR 000 219 550 Date: 6/14/2024 By: Mary McCoy Waste Stream Common Name: Spent Garnet Check one: RCRA Haz Waste Non-RCRA Haz Waste Not Haz Waste RCRA Waste Codes: NA State Waste Codes: NA 0 Source Code: #N/A Form Code: #N/A Management Method: #N/A (For California sites, if this waste is subject to 22 CCR 66266.1 and is not recycled, attach justification.) UN#, Proper Shipping Name, Hazard Class, Packing Group: NA ERG: NA Check one: Ongoing RQ Threshold: NA Intermittent One-time Other information: Spent garnet is not a RCRA hazardous waste. 2018 TCLP analytical results for chromium was below detection limits (see attached). Generator knowledge analysis of operations indicates that material is non-hazardous. The waterjet operations utilizes 200,000+ pounds of garnet every year. The non-hazardous portion of the waste streams is quite significant. Waste generation process (listed, characteristic); chemicals used; location within facility: Waterjet operations Attachment 5 Page 1 of 8 #=CL# LIMS USE: FR - STEVE CZARNECKI LIMS OBJECT ID: 7071555 November 29, 2018 Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 (631)694-3040 Steve Czarnecki Ducommun Aerostructures 171 Stacy Road Coxsackie, NY 12051 RE: Project: CHROME 11/19 Pace Project No.: 7071555 Dear Steve Czarnecki: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, John D. Stanton john.stanton@pacelabs.com (631)694-3040 Project Manager Enclosures cc: Eugenia Lighthouse, Ducommun Incorporated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 5 Page 2 of 8 Page 1 of 7 #=CP# Project: Pace Project No.: CHROME 11/19 7071555 Long Island Certification IDs 575 Broad Hollow Rd, Melville, NY 11747 New York Certification #: 10478 Primary Accrediting Body New Jersey Certification #: NY158 Pennsylvania Certification #: 68-00350 Connecticut Certification #: PH-0435 CERTIFICATIONS Maryland Certification #: 208 Rhode Island Certification #: LAO00340 Massachusetts Certification #: M-NY026 New Hampshire Certification #: 2987 Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 (631)694-3040 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 5 Page 3 of 8 Page 2 of 7 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 (631)694-3040 ANALYTICAL RESULTS Project: Pace Project No.: CHROME 11/19 7071555 Sample: USED GARNET Lab ID: 7071555001 Collected: 11/19/18 10:35 Received: 11/20/18 09:45 Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Matrix: Solid Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 6010 MET ICP, TCLP Chromium Analytical Method: EPA 6010C Preparation Method: EPA 3005A Leachate Method/Date: EPA 1311; 11/27/18 22:35 <0.50 mg/L 0.50 1 11/29/18 08:01 11/29/18 13:44 7440-47-3 Qual Date: 11/29/2018 02:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 5 Page 4 of 8 Page 3 of 7 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 (631)694-3040 Project: Pace Project No.: CHROME 11/19 7071555 QC Batch: 92948 QC Batch Method: EPA 3005A Associated Lab Samples: 7071555001 METHOD BLANK: 429089 Associated Lab Samples: 7071555001 Chromium Parameter Units mg/L LABORATORY CONTROL SAMPLE: 429090 Chromium Parameter Units mg/L MATRIX SPIKE SAMPLE: Chromium Parameter 429092 Units mg/L SAMPLE DUPLICATE: 429091 Chromium Parameter Units mg/L QUALITY CONTROL DATA Analysis Method: Analysis Description: EPA 6010C 6010 MET TCLP Matrix: Water Blank Result <0.50 Reporting Limit 0.50 Analyzed 11/29/18 13:42 Qualifiers Spike Conc. .25 LCS Result <0.50 LCS % Rec 85 % Rec Limits 80-120 Qualifiers 7071555001 Result <0.50 Spike Conc. .25 MS Result <0.50 MS % Rec 90 % Rec Limits 75-125 Qualifiers 7071555001 Result <0.50 Dup Result <0.50 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 11/29/2018 02:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 5 Page 5 of 8 Page 4 of 7 #=QL# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 (631)694-3040 QUALIFIERS Project: Pace Project No.: CHROME 11/19 7071555 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. Date: 11/29/2018 02:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 5 Page 6 of 8 Page 5 of 7 #=CR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 (631)694-3040 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: CHROME 11/19 7071555 Lab ID 7071555001 Sample ID USED GARNET QC Batch Method EPA 3005A QC Batch 92948 Analytical Method EPA 6010C Analytical Batch 92950 Date: 11/29/2018 02:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Attachment 5 Page 7 of 8 Page 6 of 7 Attachment 5 Page 8 of 8 Page 7 of 7 Attachment 06 Facility Follow up Email to EPA McCoy, Mary From: Sent: To: Cc: Subject: Attachments: McCoy, Mary Tuesday, June 18, 2024 12:37 PM Vince Damiano Dumaua, Pedro; Gutierrez, Jennette; Hasenkopf, Robert RE: Follow-up From EPA Visit on 6/12 Manifest Bonderite.JPG; Profiles Lab Results.zip; ER services Corres.zip; Manifests TSDF copies.zip; POTW corres - no permit.pdf; Debris pictures.zip; F-00713 Daily Waste Shed Inspection Form - EMS Rev A.xlsx Hi Vince, Here are the documents that I owe you: Contingency plan - this is huge, so I will overnight a thumb drive to you. Although I'm willing to try, it will be likely because of security that I won't be able to upload to an FTP site. Is your address 14555 Avion Pkwy #200, Chantilly, VA 20151? Correspondence regarding emergency services to visit facility and become familiar with layout o See "ER services Corres.zip" Signed manifests with the following manifest numbers: 002353387 VES 002353236 VES 002353002 VES 002236882 VES 002236763 VES 001914991 VES o See Manifests for TSDF copies Correspondence from POTW stating you do not qualify for a disposal permit o See POTW corres - no permit.pdf Waste determination Waste determination on spent garnet from water jets Waste determination on material accumulating in UST Waste determination (2023 results) on water being sent to POTW o See "Profiles Lab Results.zip" Follow up to your comments while you were here onsite: The 5-gallon container of hazardous waste with the accumulation date of September 2023 was shipped offsite on today, 6/18/24. It was placed in an area normally obscured by a 300-gallon intermediate bulk container, which is why the 5-gallon container was not seen during weekly inspections. We have created a small container area in the LT-90 to prevent this in the future. See Manifest Bonderite. To address the open and undated containers, we started daily inspections of the LT-90 to make following up on deficiencies easier and more timely. See attached inspection form. This form is not the same as the weekly inspection form, which is more comprehensive. The acetone debris and paint containers are now labeled and closed. See attached photographs. Regarding the expired paint in the cabinet, although expired paint cannot be used in production, which is why they're segregated, they still can be used on occasion for training, troubleshooting, etc.; hence, paint in that cabinet is not a waste. I don't see where containers of universal waste aerosol cans must be closed. See the attached fact sheet, which can be found here: https://dec.ny.gov/environmental-protection/wastemanagement/hazardous-waste/universal-waste 1 Attachment 6 Page 1 of 3  The adhesive/sealant waste that did not have an accumulation date was not a RCRA hazardous waste - see attached waste determination. That material was pending determination, and the lab issued the final report on June 12, 2024. M Mary A. McCoy, PE 203.300.7303 cell Safety Sugges ons: EHSSupportNY@ducommun.com From: McCoy, Mary Sent: Friday, June 14, 2024 11:07 AM To: Vince Damiano <Vince.Damiano@erg.com> Subject: RE: Follow-up From EPA Visit on 6/12 Hi Vince, It was nice to meet you. I'll have something for you shortly. M Mary A. McCoy, PE 203.300.7303 cell Safety Sugges ons: EHSSupportNY@ducommun.com From: Vince Damiano <Vince.Damiano@erg.com> Sent: Wednesday, June 12, 2024 3:58 PM To: McCoy, Mary <MMcCoy@ducommun.com>; Howe, Millage <MHowe@ducommun.com>; sshelhammer@ducommun.com; Hasenkopf, Robert <RHasenkopf@ducommun.com> Subject: Follow-up From EPA Visit on 6/12 Hello All, I am following up with a list of items requested from our inspection today. Contingency plan Correspondence regarding emergency services to visit facility and become familiar with layout Signed manifests with the following manifest ZjQcmQRYFpfptBannerStart This Message Is From an External Sender This message came from outside your organization. ZjQcmQRYFpfptBannerEnd Hello All, I am following up with a list of items requested from our inspection today. Contingency plan Correspondence regarding emergency services to visit facility and become familiar with layout Signed manifests with the following manifest numbers: o 002353387 VES o 002353236 VES o 002353002 VES o 002236882 VES o 002236763 VES o 001914991 VES 2 Attachment 6 Page 2 of 3  Correspondence from POTW stating you do not qualify for a disposal permit Waste determination on spent garnet from water jets Waste determination on material accumulating in UST Waste determination (2023 results) on water being sent to POTW Again, thank you for taking the time out of your day to meet with me. Please let me know if you have any questions or concerns. Any follow-up can be sent to myself or uploaded to the secure FTP site which I will share with you shortly. Thanks, Vince Vince Damiano Chemical Engineer, Chantilly Office Cell: (570) 956-1468 Vince.Damiano@erg.com 3 Attachment 6 Page 3 of 3 Attachment 07 Facility Follow-up Photographs Shipping manifest for 5-gallon container of hazardous waste with the accumulation date of September 2023 was shipped off site 6/18/24 Attachment 7 Page 1 of 3 Acetone debris tote closed and dated as of 6/18/2024 Attachment 7 Page 2 of 3 Paint debris tote closed and dated as of 6/18/2024 Attachment 7 Page 3 of 3 Attachment 08 RCRA Contingency Plan WI-00237 RCRA Contingency Plan Ducommun AeroStructures New York Coxsackie, NY Appendix 7.1 - Emergency Contact Information (F-00639) Appendix 2.1 - Immediate Emergency Procedures RCRA Contingency Plan Appendix 3.c)i) - High Hazard Chemical Incidental Spill Response Procedure (WI-00241 ) Appendix 2-4)b)iii) - Start of Fire Pump (WI-00250) Appendix 2.4 - Utility Shutoffs (WI-00240) Appendix 3.1 - Emergency Equipment (F-00637) Appendix 4.1.5.1 - Chemical Line Tank Concentrations Appendix 7.3 - Supporting Personnel I I 10 I 11 ' Appendix 2-1)a) - Shelter In Place (Tornado) (WI-00242) Appendix 2-1)b) - Medical Emergency (WI-00251) Appendix 9.4.4.2 - Agreement with Veolia Appendix 4.2 - Safety Data Sheets 6 0300 ' Coxsackie, New York Work Instruction: WI-00237 RCRA Contingency Plan - EMS Last Reviewed Date: 2/1/2024 Revision No.: D Title Page Page: 31 of 33 RCRA Contingency Plan Ducommun AeroStructures New York Coxsackie, NY Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 12 of 33 Map - 2' x 3' to be posted at the front of the plan A EXPANDED LOT C, ADDED LOT D B AREAS 13 AND 14 ADDED EMERGENCY EVACUATION C LAYOUT UPDATE TO INCLUDE ADDED VS5 9/27/2016 10/4/2016 07/29/19 RMP RMP ML Muster Point 2 EXIT *VS4 Passivation/Alodine Line w/ spill kit PARKING LOT D EXIT 1 DROPHAMMER EXIT 1 EXIT Receiving Door Blank Cell *RCRA hazarous waste storage area LT-90 EXIT 6 1 *Raw chemical storage VS3 Cleaning Line w/ spill kit EXIT High Risk Spill Kit pH Lab 4 RECEIVING 1 SHIPPING WOMENS 1 MENS BREAK ROOM 2 45 VS4 WELD ASSEMBLY 1 VS4 GENERAL ASSEMBLY A.P.E. LINE 2 4 VS4 WELD ASSEMBLY 1 VS4 MFG OFFICE VS3 MFG OFFICE PAINT VS3 ASSEMBLY VS2 ASSEMBLY 5 VS3 CLEAN LINE 4 1 LAB 1 QUALITY CLINIC NDT VS2 MFG OFFICE 1 1 VS2 FABRICATION 1 VS1 ASSEMBLY BOX BUILD AREA SHOP PATTERN VS1 MFG/ENG OFFICE EXIT EXIT High Risk Spill Kit PARKING LOT A 1 VS4 FABRICATION 1 1 1 Spill Kit (oil) 1 2 2 VS3 FABRICATION 1 1 1 4 5 EXIT 1 5 BLANKING 1 VS5 CLEAN LINE VS5 FABRICATION PAINT 1 1 VS2 FABRICATION MSDS 4 1 VS1 FABRICATION 5 VS1 CLEAN LINE 7 1 1 MAINT. COMPRESSOR ROOM 2 ROOM 1 1 EXIT VS5 FABRICATION EH&S DCC 1 1 1 1 FILE ROOM MENS IPT 7 CONF ROOM WOMENS MENS "OAKWOOD" CONF ROOM 4 31 1 1 1 CAFETERIA RECEPTION 1 1 "WELCOME" CONF ROOM GM OFFICE *VS1 Cleaning Line w/ spill kit EXIT PARKING LOT B EXIT Spill Kit *VS5 Cleaning Line w/ spill kit PARKING LOT C KEY 1 FIRE EXTINGUISHER, ABC 2 FIRE EXTINGUISHER, CLASS D 3 AED 4 FIRST AID 5 EYE WASH STATION 6 EMERGENCY PHONE 7 SHELTER IN PLACE AREA 8 EMERGENCY EVACUATION AREA 9 CHEMICAL STORAGE AREAS 10 Catch Basins Muster Point 1 F-00646 Site Safety Map - EMS Authorized by: WI-00237 RCRA Contingency Plan - EMS Last Reviewed Date: 10/24/23 Rev A Front view Scale: 1:400 Hot ovens/presses >1000F in western half of the building DAS ENGINEERING DRAWING AeroStructures-New York Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 26 of 33 Appendix 7.1 - Emergency Contact Information (F-00639) - to be posted at the front of the plan Coxsackie, New York Last Reviewed Date: 3/25/24 UNIVERSAL EMERGENCY NUMBER Form No.: F-00639 Emergency Response Contact Information Authorized by: WI-006216 RCRA Contingency Plan Revision No.: B Page: 1 of 3 Facility Phone: 9911 Cell Phone: 911 EMERGENCY COORDINATORS MAINTENANCE LEAD Primary First Alternate Second Alternate Sunder Shelhamer Mary McCoy Millage Howe Paul Bradt CELL: (518) 935- CELL: (203) 300-7303 CELL: (518) 764-8278 CELL: (518) 944-7956 7023 Alt cell: (860) 578-4008 Alt cell: (979) 221-8885 Third Alternate Fourth Alternate George Johnson Rob Moore CELL: (848) 888-2291 CELL: (518) 755-0227 EMERGENCY RESPONSE ORGANIZATIONS (NON-EMERGENCY NUMBERS - CALL 911 FOR EMERGENCIES) Primary Fire Department & Spill Village of Coxsackie Fire Department Fire Chief-Shawn Burdick firechief@villageofcoxsackie.com (518) 242-0032 Fire Department Earlton Fire House 1561 New York 81 Earlton, NY 12058 (518) 731-6683 Ambulance Town of Coxsackie Ambulance Nadine Erceg-Myrdycz, Chief of EMS (518) 731-3687 emschief@coxsackie.org Hospital Columbia Memorial Hospital 71 Prospect Ave Hudson, NY 12534 (518) 828-7601 Law Enforcement New York State Police Troop F Zone 1 Coxsackie Station c/o SP Catskill South Cairo, NY 12482 (518) 731-2333 Poison Control 800-222-1222 Law Enforcement Greene County Sheriffs Office 45 Haverly Mem Dr Coxsackie, NY 12051 (518) 943-3300 Urgent Care EmUrgentCare 11835 State Rt. 9W West Coxsackie, NY 12192 (518) 731-9000 Spill Veolia 9+1-800-354-2382 Dial "1" Hospital St. Peter's Hospital 315 South Manning Blvd., Albany, NY 518-525-1550 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 3/25/24 Form No.: F-00639 Emergency Response Contact Information Authorized by: WI-006216 RCRA Contingency Plan Revision No.: B Page: 2 of 3 OTHER ORGANIZATIONS NYDEC Spill Hotline National Response OSHA - (800) 321-6742 800-457-7362 Center (use their 24- hour toll free number 9+800-424-8802) Central Hudson (For electrical and outages) (845) 452-2700 FIRST AID RESPONDERS - USE THE PA SYSTEM - "CODE 3 [VALUE STREAM AND AREA]" Natural Gas Central Hudson Gas & Electric 800-942-8274 Name Phone Shift Name Phone Shift Name Phone Shift Mary McCoy 4650 1 Curt Abretske Page 2 Jessica Sturner Page 3 Philip Moritz Page 1 George Johnson Page 2 Charlie Buccino Page 3 Maximus Kelly Page 1 Lindsay Wexler Page 2 Robert Moore Page 3 Joseph McGiffert Page 1 Josh Benoit Page 2 Orland Perkins Page 1 Travis Knott Page 2 DUCOMMUN HAZMAT TEAM - USE THE PA SYSTEM - "HAZMAT [VALUE STREAM AND AREA]" Name Phone Shift Name Phone Shift Name Mike Hogan Page 1 George Johnson Page 2 Jessica Sturner Kris Hogan Page 1 Curt Abretske Page 2 Charlie Buccino Mike Czyzewski Page 1 Travis Knott Page 2 Mary McCoy 4650 1 Phone Shift Page 3 Page 3 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Form No.: F-00639 Emergency Response Contact Information Authorized by: WI-006216 RCRA Contingency Plan Coxsackie, New York Last Reviewed Date: 3/25/24 Revision No.: B Page: 3 of 3 Posting for RCRA hazardous waste storage area phone IN CASE OF AN EMERGENCY, 9911 AND notify the following personnel: EMERGENCY COORDINATORS MAINTENANCE LEAD Primary Mary McCoy CELL: (203) 300-7303 Alt cell: (860) 578-4008 Alt cell: (979) 221-8885 First Alternate Millage Howe CELL: (518) 764-8278 Second Alternate Paul Bradt CELL: (518) 944-7956 Third Alternate George Johnson CELL: (848) 888-2291 Fourth Alternate Rob Moore CELL: (518) 755-0227 Sunder Shelhamer CELL: (518) 9357023 OUTSIDE EMERGENCY PERSONNEL TO BE NOTIFIED, IF REQUIRED: [Coxsackie] Police Department 9+911 [State] Police Information Desk 9+(518)-622-8600 [Coxsackie] Fire Department 9+(518) 731-6510 For a spill inside the facility, the Emergency Coordinator or designee should call Veolia 9+1-800-3542382 Dial "1". If the Person-in-Charge determines that the facility has had a release, fire, or explosion which could threaten human health, or the environment, outside the facility, they must: 1. If the assessment indicates that evacuation of local areas may be advisable, immediately notify appropriate local authorities (9+911). 2. Notify: 2.1 Veolia 9+1-800-354-2382 Dial "1" 2.2 NYSDEC 9+ 1-800-457-7362 2.3 National Response Center (use their 24-hour toll free number 9+800-424-8802). The reports made for these incidents shall include the following: Your name and telephone number Name and address of the facility: Time and type of incident (for example, release, fire); Name and quantity of material(s) involved, to the extent known: The extent of injuries, if any; and The possible hazards to human health, or the environment, outside the facility. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 13 of 33 Appendix 2.1 - Immediate Emergency Procedures - to be posted at the front of the plan Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 14 of 33 1) For Shelter in Place (tornado) or Medical Emergency, go to Appendices 2-1)a) and 2-1)b) In the event of a fire, explosion or spill at the facility, personnel will execute the following steps: 2) Discovering personnel will: a) Tell a supervisor or manager immediately b) If they deem the situation dangerous enough, personnel are empowered to: i) Initiate evacuation of the facility. See Section 4)e) of this section. ii) Call 9-911 3) All team leads, supervisors, managers and emergency coordinators1 must: a) Assess emergency situations b) If there is sufficient immediate threat to human health and the environment i) Initiate evacuation of the facility. See Section 4)e) of this section. ii) Call 9-911 c) Immediately notify the emergency coordinator or designee who will implement the Contingency Plan in the following situations: i) Any spill of the materials listed in Section 4)c)i) of this section ii) A fire that cannot be extinguished with one extinguisher iii) Any explosion iv) Any other situation involving a RCRA hazard waste that poses a threat to human health or the environment 4) The Emergency Coordinator or designee will: a) Injuries i) Summon trained personnel to render first aid ii) Call 9-911 and summon EMS for more severe injuries b) Explosions and fires that cannot be extinguished with one attempt: i) Initiate evacuation. See Section e) of this section ii) Summon the fire department iii) Verify that Maintenance personnel will start the operation of the fire pump. The instructions on how to turn on the Fire Pump is posted at the Fire Pump House. See Appendix 2-4)b)iii) 1 See Section 7 of the main body of the Contingency Plan on page 6 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 15 of 33 iv) Inform the fire department that: (1) There are ovens and presses at temperatures greater than 1000F in the western half of the building (2) A water reactive material, Molten Salt Bath also known as "Caustic" and "ALKO-N", which is a potassium-based material, is located in the chemical lines at VS 1, 3 and 5. (3) There are chemical and waste storage sheds on the east side of the building by the back gate (4) There are drums of flammable liquids [acetone (99% - 100%), IPA (99%), and waste paint] in the Paint areas, next to VS4 Passivation/Alodine Line, and near Receiving Door #5 at Blank Cell. c) Spills i) If more than 2.5 gallons of these material has spilled, contact the Fire Department via 911. For less than 2.5 gallons, use WI-00241 High Hazard Chemical Incidental Spill Response Procedure. Only personnel who are hazmat trained are authorized to clean up the following material. See Appendix 4)c)i). (1) Hydrofluoric acid (2) Nitric acid (3) Nitric-hydrofluoric acid mix (4) Sulfuric acid (5) Sodium hydroxide (pH Lab "caustic") (6) Bonderite/Alodine raw material d) For other spills, if safe to do so: i) Stop the spill at the source ii) Contain the spill by laying down booms and pads iii) Clean up spills with sorbents and pads iv) Label waste containers e) Evacuation i) Evacuation is initiated by pulling a fire alarm, which are located by each pedestrian door exit ii) The primary rally locations are as follows: (1) Muster Point 1: the grassy area at the north corner of the facility property at the end of Parking Lot C closest to the front gate. (2) Muster Point 2: the east end of Parking Lot D near the gate iii) The EC or designee will instruct personnel to stay out of the way of emergency response vehicles. Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 16 of 33 iv) If the wind is blowing smoke towards a muster point or other unfavorable condition, the EC or designee will instruct personnel to report to an upwind muster point. v) The EC or designee will direct two personnel to stand at each gate to direct emergency vehicles and incoming personnel if the event happens during a shift change vi) The team leads or EC designee will take a head count and report to the EC and the fire department if there are any personnel missing vii) Personnel will remain at the rally points until dismissed by the EC or designee, manager or team lead viii) Cold weather evacuation: (1) Personnel will be advised to maintain extra clothing in their cars during cold weather months in the event of evacuation (2) When evacuation is initiated, personnel are to report to and remain at their muster point until they are cleared by the EC or designee to go to their cars to retrieve the extra clothing (3) Team leads and managers should allow personnel to proceed to their cars two at a time or in some other orderly fashion f) Supporting Personnel and Duties (1) Dispatch supporting personnel to execute their duties listed in Appendix 7.3. See Section 7.3 of the Contingency Plan for more information. Coxsackie, New York Work Instruction: WI-00237 RCRA Contingency Plan - EMS Last Reviewed Date: 2/1/24 Revision No.: D Title Page Page: 32 of 33 RCRA Contingency Plan Ducommun AeroStructures New York Coxsackie, NY Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 1 of 33 Contents 1. Introduction........................................................................................................................................................2 2. Emergency Procedures.......................................................................................................................................2 3. Emergency Equipment .......................................................................................................................................4 4. Chemicals............................................................................................................................................................5 5. Site Safety Map...................................................................................................................................................5 6. Post Emergency Actions .....................................................................................................................................6 7. Responsibilities ...................................................................................................................................................6 8. Copies of contingency plan.................................................................................................................................7 9. Arrangements with Authorities ..........................................................................................................................7 10. Amendment of the Contingency Plan ............................................................................................................. 10 11. Training ............................................................................................................................................................ 10 Map - 2' x 3' to be posted at the front of the plan................................................................................................. 12 Appendix 2.1 - Immediate Emergency Procedures - to be posted at the front of the plan ................................... 13 Appendix 2-1)a) - Shelter In Place (Tornado) (WI-00242)....................................................................................... 17 Appendix 2-1)b) - Medical Emergency (WI-00251) ................................................................................................ 18 Appendix 2-4)b)b)iii) - Start Fire Pump (WI-00250)................................................................................................ 19 Appendix 2.4 - Utility Shutoffs (WI-00240).............................................................................................................. 20 Appendix 3.c)i) - WI-00241 High Hazard Chemical Incidental Spill Response Procedure........................................ 21 Appendix 3.1 - Emergency Equipment (F-00637) .................................................................................................... 22 Appendix 4.1.5.1 - Chemical Line Tank Concentrations .......................................................................................... 23 Appendix 4.2 - Safety Data Sheets - to be posted at the end of the plan .............................................................. 25 Appendix 7.1 - Emergency Contact Information (F-00639) - to be posted at the front of the plan...................... 26 Appendix 7.3 - Supporting Personnel ..................................................................................................................... 27 Appendix 9.4.4.2 - Agreement with Veolia.............................................................................................................. 30 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 2 of 33 1. Introduction 1.1. Because the facility is a Large Quantity Generator (LQG) of RCRA hazardous waste, Ducommun AeroStructures New York, Inc. (DASNY) located at 171 Stacey Road, Coxsackie, New York, is subject to Title 6 New York Codes, Rules and Regulations 373-3.3 [preparedness and prevention] and 373-3.4 [contingency plans and emergency procedures]. 1.2. This Contingency Plan (plan) is designed to minimize hazards to human health or the environment from fires, explosions, or any unplanned sudden or non-sudden release of hazardous waste or hazardous waste constituents to air, soil, or surface water. 1.3. This plan describes the actions facility personnel will take to comply with 6 CRR NY 373-3.3 and 3733.4 in response to fires, explosions, or any unplanned sudden or non-sudden release of hazardous waste or hazardous waste constituents to air, soil, or surface water at the facility. 1.4. This plan also incorporates actions for emergencies not related to hazardous waste that include fires, spills, explosions and excludes shelter in place emergencies such as a tornado as well as responses to medical emergencies other than summoning emergency response services. 1.5. DASNY personnel will immediately implement the provisions of this plan whenever there is a fire, explosion, or release of hazardous waste or hazardous waste constituents which could threaten human health or the environment or a Shelter In Place or Medical Event. See Appendix 2.1. 2. Emergency Procedures 2.1. The immediate emergency procedures, which will be executed by the Emergency Coordinator or Emergency Coordinator Designee during the off shift, are located in Appendix 2.1, Immediate Emergency Procedures, which will be posted in the front of the plan for ease of reference. 2.2. The Emergency Coordinator will also: 2.2.1.Notify other appropriate State or local agencies with designated response roles if their help is needed. 2.2.2.Whenever there is a release, fire, or explosion, immediately identify the character, exact source, amount, and areal extent of any released materials. They may do this by observation or review of facility records or manifests and, if necessary, by chemical analysis. 2.2.3.Concurrently, assess possible hazards to human health or the environment that may result from the release, fire, or explosion. This assessment must consider both direct and indirect effects of the release, fire, or explosion (e.g., the effects of any toxic, irritating, or asphyxiating gases that are generated, or the effects of any hazardous surface water run-offs from water or chemical agents used to control fire and heat-induced explosions). 2.2.3.1. If the emergency coordinator determines that the facility has had a release, fire, or explosion which could threaten human health, or the environment, outside the facility, they must report their findings as follows: Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 3 of 33 2.2.3.1.1. If their assessment indicates that evacuation of local areas may be advisable, they must immediately notify appropriate local authorities. They must be available to help appropriate officials decide whether local areas should be evacuated; and 2.2.3.1.2. They must immediately notify either the government official designated as the on-scene coordinator for that geographical area, or the National Response Center (using their 24-hour toll free number 800/424-8802). The report must include: 2.2.3.1.2.1. Name and telephone number of reporter; 2.2.3.1.2.2. Name and address of facility; 2.2.3.1.2.3. Time and type of incident (e.g., release, fire); 2.2.3.1.2.4. Name and quantity of material(s) involved, to the extent known; 2.2.3.1.2.5. The extent of injuries, if any; and 2.2.3.1.2.6. The possible hazards to human health, or the environment, outside the facility. 2.2.4.During an emergency, take all reasonable measures when it is safe to do so necessary to ensure that fires, explosions, and releases do not occur, recur, or spread to other hazardous waste at the facility. These measures must include, where applicable, stopping processes and operations, collecting and containing released waste, and removing or isolating containers. 2.2.5.If the facility stops operations in response to a fire, explosion or release, must monitor for leaks, pressure buildup, gas generation, or ruptures in valves, pipes, or other equipment, wherever this is appropriate and safe to do so. 2.3. Evacuation 2.3.1.See Section 4)e) of Appendix 2.1 2.4. Utility Shutoffs 2.4.1.WI-00240 provides the instructions on the Utility Shutoffs, which is included in Appendix 2.4 of this plan. 2.5. Reportable Spills 2.5.1.The Emergency Coordinator or a supporting Emergency Coordinator must implement the reporting requirements of this section as soon as an emergency is stabilized. 2.5.2.Reportable spills include: 2.5.2.1. The following materials spilled or leaked into the environment in the quantities listed below or greater that cannot be recovered (cleaned up): NAME Acetone Sodium hydroxide CAS/313 Category Codes 67-64-1 1310-73-2 Reportable Quantity Air Land/water 5000 1 1000 100 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 4 of 33 Hydrofluoric acid (conc. 50% or greater) Sulfuric acid Nitric acid Chromic acid 7664-39-3 7664-93-9 7697-37-2 7738-94-5 100 100 1000 100 1000 100 10 10 2.5.2.2. The National Response Center (NRC) (800-424-8802) within 15 minutes and the NYS Spill Hotline (1-800-457-7362) within 2 hours of discovery must be contacted in the event of a reportable spill listed above. 2.5.2.3. Petroleum: 2.5.2.3.1. EPA/National Response Center 2.5.2.3.1.1. EPA has established requirements to report spills to navigable waters or adjoining shorelines. EPA has determined that discharges of oil in quantities that may be harmful to public health or the environment must be reported to the Natural Response Center (800-424-8802) within 15 minutes and include those that: 2.5.2.3.1.2. Violate applicable water quality standards; 2.5.2.3.1.3. Cause a film or "sheen" upon, or discoloration of the surface of the water or adjoining shorelines; or 2.5.2.3.1.4. Cause a sludge or emulsion to be deposited beneath the surface of the water or upon adjoining shorelines. 2.5.2.3.2. All petroleum spills that occur within New York State (NYS) must be reported to the NYS Spill Hotline (1-800-457-7362) within 2 hours of discovery, except spills which meet all of the following criteria: 2.5.2.3.2.1. The quantity is known to be less than 5 gallons; and 2.5.2.3.2.2. The spill is contained and under the control of the spiller; and 2.5.2.3.2.3. The spill has not and will not reach the State's water or any land; and 2.5.2.3.2.4. The spill is cleaned up within 2 hours of discovery. 2.5.2.3.2.5. A spill is considered to have not impacted land if it occurs on a paved surface such as asphalt or concrete. A spill in a dirt or gravel parking lot is considered to have impacted land and is reportable. 3. Emergency Equipment 3.1. Form F-00637 Emergency Equipment List - EMS, which is included in Appendix 3.1 provides a list of all emergency equipment related to hazardous waste at the facility (such as fire extinguishing systems, spill control equipment, communications and alarm systems (internal and external), and decontamination equipment), where this equipment is required. This list will be kept up to date. This Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 5 of 33 list also includes the location and a physical description of each item on the list, and a brief outline of its capabilities. 3.2. A bin located at the Pump House that contains emergency equipment such as radios, flashlights with wands, a copy of the Contingency Plan, and safety data sheets of high-risk chemicals are located inside the Pump House. 4. Chemicals 4.1. Chemicals onsite include but is not limited to: 4.1.1.Raw chemical storage sheds: 4.1.1.1. Hydrofluoric acid 4.1.1.2. Nitric acid 4.1.1.3. Acetone (99% - 100%) 4.1.2.Receiving Door #5 at Blank Cell 4.1.2.1. Acetone (99% - 100%) 4.1.2.2. Isopropyl Alcohol (99%) 4.1.3.Hazardous waste storage shed: 4.1.3.1. Spent nitric-hydrofluoric acid mix 4.1.3.2. Spent Bonderite solution 4.1.3.3. Spent Alodine solution 4.1.4.pH Lab 4.1.4.1. Sulfuric acid 4.1.4.2. Sodium hydroxide 4.1.5.Chemical lines. 4.1.5.1. Chemical line chemicals and their concentrations in the tanks are listed in Appendix 4.1.5.1. 4.2. Safety data sheets for the chemicals listed in this section are included in Appendix 4.2. 4.3. The facility contains other chemicals including 55-gallon drums of acetone and waste paint. 5. Site Safety Map F-00646 provides the Site Safety Map, which will be posted in the front of the plan (two copies), which shows the location of: 5.1. Chemical storage areas 5.2. Evacuation points Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 6 of 33 5.3. Other information including: 5.3.1.Fire extinguishers 5.3.2.AEDs 5.3.3.First aid 5.3.4.Eye wash stations 5.3.5.Emergency phone 5.3.6.Shelter-in-place 5.3.7.General location of hot ovens and presses 6. Post Emergency Actions 6.1. Immediately after an emergency, the emergency coordinator must provide for treating, storing, or disposing of recovered waste, contaminated soil or surface water, or any other material that results from a release, fire, or explosion at the facility. 6.2. The emergency coordinator must ensure that, in the affected area(s) of the facility: 6.2.1. No waste that may be incompatible with the released material is treated, stored, or disposed of until cleanup procedures are completed; and 6.2.2. All emergency equipment listed in the contingency plan is cleaned and fit for its intended use before operations are resumed. 6.2.3. The owner or operator must note in the operating record the time, date, and details of any incident that requires implementing the contingency plan. 6.2.4. Within 15 days after the incident, he must submit a written report on the incident to the Regional Administrator if the Contingency Plan is invoked for an incident related to RCRA hazardous waste. The report must include: 6.2.4.1. Name, address, and telephone number of the owner or operator; 6.2.4.2. Name, address, and telephone number of the facility; 6.2.4.3. Date, time, and type of incident (e.g., fire, explosion); 6.2.4.4. Name and quantity of material(s) involved; 6.2.4.5. The extent of injuries, if any; 6.2.4.6. An assessment of actual or potential hazards to human health or the environment, where this is applicable; and 6.2.4.7. Estimated quantity and disposition of recovered material that resulted from the incident. 7. Responsibilities 7.1. Emergency contact information is included on F-00639 Emergency Response Contact Information, which is included in Appendix 7.1, which will be posted in the front of the plan. 7.2. Emergency Coordinator Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 7 of 33 7.2.1.At all times, there must be at least one employee either on the facility premises or on call (i.e., available to respond to an emergency by reaching the facility within a short period of time) with the responsibility for coordinating all emergency response measures. This emergency coordinator must be thoroughly familiar with all aspects of the facility's contingency plan, all operations and activities at the facility, the location and characteristics of wastes and chemicals handled, the location of all records within the facility, and the facility layout. In addition, this person must have the authority to commit the resources needed to carry out the contingency plan. 7.2.2.In the absence of the primary Emergency Coordinator, Emergency Coordinator duties will `roll' down to the alternates in the order they are presented in the Emergency Contact Information. 7.2.2.1. When contacting the Emergency Coordinators, personnel will start with the primary and continue down the list in order until an Emergency Coordinator responds 7.2.3.During the off shift, the onsite manager, team lead or other identified designee will serve as the Emergency Coordinator Designee until the Emergency Coordinator arrives. The Emergency Coordinator Designee must be familiar with the Appendix 2.1, Immediate Emergency Procedures. 7.3. Supporting Personnel 7.3.1.The Assistant Emergency Coordinator for the off shift (second shift [non-business hours], third shift and weekends) will be identified in advance. The role of the Assistant Emergency Coordinator is to provide direction to the other supporting personnel in an actual event or drill. 7.3.2.The list of other supporting personnel are listed in Appendix 7.3. These personnel should exclude first aid and spill responders. 7.3.3.Training is discussed in Section 11. 8. Copies of contingency plan. 8.1. A copy of the Contingency Plan and all revisions to the plan must be: 8.1.1.Maintained at the facility: 8.1.1.1. In Compliant Pro 8.1.1.2. In the bin at the Pump House 8.1.1.3. In the drawer of the table near the Receptionist restrooms 8.1.1.4. With the listed Emergency Coordinators 8.1.2.Submitted to all local police departments, fire departments, hospitals, and State and local emergency response teams that may be called upon to provide emergency services. 9. Arrangements with Authorities 9.1. This section describes the arrangements agreed to by local police departments, fire departments, hospitals, contractors, and State and local emergency response teams to coordinate emergency services. Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 8 of 33 9.2. See Section 8 for distribution of the Contingency Plan 9.3. Emergency contact information is included on F-00639 Emergency Response Contact Information, which is included in Appendix 7.1. 9.4. Agencies and Organizations 9.4.1. The responding Fire Departments are as follows: 9.4.1.1. Village of Coxsackie Fire Department (primary for spills, fires and explosions) 9.4.1.1.1. Coxsackie Hose Company #3 P.O. Box 303 Coxsackie, NY 12051 9.4.1.1.2. Email address: firechief@villageofcoxsackie.com 9.4.1.1.3. Once a year, DASNY invites Village of Coxsackie Fire Department for a tour of the facility to allow them to become acquainted with the facility operations and layout 9.4.1.2. Earlton Fire House 9.4.1.2.1. 1561 New York 81 Earlton, NY 12058 9.4.2. Ambulance 9.4.2.1. Coxsackie Ambulance is the primary responding agency for injury response. 9.4.2.2. Mailing Address: 56 Bailey St Town of Coxsackie, NY 12051 9.4.2.3. Physical address: 117 Mansion Street Coxsackie, NY 12051 9.4.2.4. Email address: emschief@coxsackie.org 9.4.2.5. Non-emergency phone number: (518) 731-EMTS (731-3687) 9.4.3. Law Enforcement 9.4.3.1. The local law enforcement agencies are: 9.4.3.1.1. New York State Police Troop F Zone 1 South Cairo, NY 12482 9.4.3.1.2. Greene County Sheriffs Office Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 9 of 33 45 Haverly Mem Dr Coxsackie, NY 12051 9.4.3.1.3. Greene County Sheriffs Office 119 Mansion Street Coxsackie N.Y. 12051 Email address: sheriff@greenesheriffny.com 9.4.4. Local Emergency Planning Commission (LEPC)/State Emergency Response Commission (SERC) 9.4.4.1.1. Greene County Emergency Operations (LEPC) 25 Volunteer Dr Cairo, NY 12413 9.4.4.1.2. NYS Emergency Management Office 1220 Washington Ave, Building 22, Suite 101 Albany, NY 12226 Email address: SERC.OEM@dhses.ny.gov 9.4.5. Veolia 9.4.5.1. The third party contractor for spill response is Veolia; however, DASNY will contact the Village of Coxsackie Fire Department first 9.4.5.2. The facility maintains a contract with Veolia for spill response services, which is included in Appendix 9.4.4.2 of this plan. 9.4.6. Hospital 9.4.6.1. The hospitals to which the Continency Plan will be sent include: 9.4.6.1.1. Columbia Memorial Hospital 71 Prospect Ave Hudson, NY 12534 9.4.6.1.2. St. Peter's Hospital 315 South Manning Blvd., Albany, NY 12208 9.4.7. Urgent Care 9.4.7.1. The UrgentCare to which the Contingency Plan will be sent: 9.4.7.1.1. EmUrgentCare 11835 State Rt. 9W Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Page: 10 of 33 West Coxsackie, NY 12192 10. Amendment of the Contingency Plan 10.1. The contingency plan must be reviewed, and immediately amended, if necessary, whenever: 10.1.1. Applicable regulations are revised; 10.1.2. The plan fails in an emergency; 10.1.3. The facility changes--in its design, construction, operation, maintenance, or other circumstances--in a way that materially increases the potential for fires, explosions, or releases of hazardous waste or hazardous waste constituents, or changes the response necessary in an emergency; 10.1.4. The list of emergency coordinators changes; or 10.1.5. The list of emergency equipment changes. 11. Training 11.1. Personnel will be trained annually as follows: 11.1.1. Emergency Coordinators 11.1.1.1. On the entirety of the plan and their duties outlined therein 11.1.2. Emergency Coordinators Designees 11.1.2.1. The Emergency Coordinator Designee must be familiar with: 11.1.2.1.1. The Immediate Emergency Procedures in Appendix 2.1 11.1.3. Team leads: 11.1.3.1. The Immediate Emergency Procedures in Appendix 2.1 11.1.3.2. Their duty to identify supporting personnel during the off-shifts 11.1.4. Supporting personnel 11.1.4.1. The Assistant Emergency Coordinator - Instructions to provide to other Supporting Personnel 11.1.4.2. Department heads - their department duties during first shift 11.1.5. All employees 11.1.5.1. Evacuation plan 11.1.5.2. To contact the Emergency Coordinators if they have questions about the Contingency Plan 11.1.5.3. Shelter in Place (Tornado) Plan 11.1.6. First Aid Responders - first aid Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 11 of 33 [Blank - Reserved] Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 21 of 33 Appendix 3.c)i) - WI-00241 High Hazard Chemical Incidental Spill Response Procedure Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction: WI-00241 High Hazard Chemical Incidental Spill Response Procedure Revision No.: B Page: 1 of 6 PURPOSE (OBJECTIVE)/SCOPE Provide instructions on responding to releases outside of primary containment for the following materials: Hydrofluoric acid Nitric acid Nitric hydrofluoric Bonderite/Alodine Sulfuric acid pH lab caustic (sodium hydroxide) Alko-N if wet or in solution Oakite 61b if wet or in solution Consult WI-00237 RCRA Contingency Plan for more extensive instructions on evacuation and other emergency response procedures. APPLIES TO Ducommun AeroStructures New York Inc. PROCEDURE 1. Discovering personnel. Upon discovery of release or potential release of the material listed above outside of primary (intended) containment, discovering personnel will: 1.1 Direct personnel in the immediate area to clear the area within a 50-foot radius 1.2 Immediately notify their supervisor 1.3 Personnel are empowered to initiate an evacuation by pulling a fire alarm 2. Team Lead/Supervisor. The team lead/supervisor will: 2.1 Assess the spill 2.2 Evacuation and Outside HazMat Team 2.2.1 Plant evacuation and summoning the Outside HazMat Team via the Fire Department by calling 911 will be necessary under the following conditions: 2.2.1.1 Spill greater than 2 gallons 2.2.1.2 Visible vapor cloud 2.2.1.3 Odor detected PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction: WI-00241 High Hazard Chemical Incidental Spill Response Procedure Revision No.: B Page: 2 of 6 2.2.2 Pull fire alarm to evacuate 2.2.3 Call 911 to contact the Fire Department to summon the HazMat team 2.2.4 Summon contract spill team (e.g., Veolia) if deemed necessary 2.2.5 Instruct personnel to shut down processes if safe to do so (e.g., shut down can be done from another location; easy, single switch or valve operation as they are evacuating, etc.) 2.2.6 Consult WI-00237 RCRA Contingency Plan for more extensive instructions on evacuation and other emergency response procedures 2.3 If evacuation and outside hazmat team not required, clear the area 50-feet away of personnel 2.4 Control pedestrian traffic while remaining at a safe distance including providing verbal instructions and setting up barricades. Personnel may be instructed to assist in this step if safe to do so. See Section 4. 2.5 Notify the EHS Manager and the Hazmat Technicians by announcing over the PA system "HazMat team to [Area]". (See Appendix 2.5 for F-00639 Emergency Response Contact Information for more contact information). Inform them of the following: 2.5.1 Material released 2.5.2 Quantity 2.5.3 Location 2.5.4 Source of the spill 2.5.5 If the spill is ongoing 2.5.6 Other identified hazards 3. HazMat Technicians HazMat Technicians must be HAZWOPER trained!! If summoned to a spill, the HazMat Technicians will: 3.1 Respond as a team of four minimum 3.2 Two will `suit up' and respond. Two will serve as attendants. See Section 4. 3.3 Assess the spill and confirm the supervisor's assessment (e.g., material released, size, the emergency response, safe distances, etc.) including the need for evacuation. See paragraph 2.2 for more information on plant evacuation. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction: WI-00241 High Hazard Chemical Incidental Spill Response Procedure Revision No.: B Page: 3 of 6 3.4 Put on the appropriate PPE. See Table 3.4 of this document. 3.5 Assess the source of the spill 3.6 If the spill is ongoing and is beyond drops or weeps, STOP and call the fire department 3.7 If the spill is ongoing as drops or weeps, stop the spill if safe to do so 3.8 Use pads and socks designed for high concentration acids (`chemical/hazmat', `chemical hazmat') to contain and clean up the spill. Preferred: 3.9 Neutralize the spill with a compatible neutralizer such as Amphomag or a dilute calciumor magnesium-based neutralizer. Do not use potassium- or sodium-based neutralizers. Follow the instructions and add neutralizer slowly to prevent excess reactions. 3.9.1 Instructions for Amphomag: 3.9.1.1 Pour Amphomag slowly and directly onto the spill to contain and neutralize 3.9.1.2 The Amphomag will initially turn: 3.9.1.2.1 Reddish/pink to indicate that it is an acid 3.9.1.2.2 Blue to indicate that it is a base (caustic) 3.9.1.2.3 Yellow/green and when fully neutralized. Be aware that the material may still be reactive even when color indicates it is neutralized. 3.9.1.3 If there is any acid or base remaining anywhere based on the color, repeat step 3.9.1.2 until the color indicates that the material is neutralized. 3.9.1.4 Guidance on needed quantity spilled material for neutralization is below: 70% HF = 11 lbs Amphomag/gal spilled material 68% HNO3 = 4 lbs Amphomag/gal spilled material Bonderite: 7% HF/40%HNO3 = 3.3 lbs Amphomag/gal spilled material 25% sodium hydroxide = 1.8 lbs Amphomag/lb of spilled material 50% sulfuric acid = 0.65 lbs Amphomag/lb of spilled material PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction: WI-00241 High Hazard Chemical Incidental Spill Response Procedure Revision No.: B Page: 4 of 6 3.10 Equipment and Supplies 3.10.1 See Attachment 3.10 of this work instruction for preferred equipment. Attachment 3.10 contain Tables 1 and 2 from F-00637, Emergency Equipment List. 3.10.2 To absorb neutralized fluids or sweep up neutralizer or sorbent, use chemically non-reactive material including polypropylene materials/equipment with no metal parts. 3.10.3 Use pumps for the correct material. Using the wrong pump for these chemicals can damage the pump and create a safety risk. 3.11 Place cleaned up neutralized material in the following labeled drum type: Spilled Material Drum Material Nitric acid Stainless steel Alko-N if wet or in solution Carbon steel Hydrofluoric acid Nitric hydrofluoric Bonderite/Alodine Sulfuric acid Polyethylene pH lab caustic (sodium hydroxide) Oakite 61B if we or in solution 4. Attendants 4.1 The supervisor or designee will provide direction to the attendants 4.2 Attendants must: 4.2.1 Wear the following PPE: 4.2.1.1 Safety glasses 4.2.1.2 Safety boots 4.2.1.3 Latex/nitrile gloves 4.2.2 Remain at a safe distance and must not approach the spill 4.2.3 Stay out of visible vapor PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction: WI-00241 High Hazard Chemical Incidental Spill Response Procedure Revision No.: B Page: 5 of 6 4.2.4 Move away if they can smell an odor 4.2.5 Assist the responders by: 4.2.5.1 Retrieving supplies such as spill control material and depositing them at a safe distance to for responders to retrieve 4.2.5.2 Control traffic 5. Decontamination procedures: 5.1 For trace contamination, responding personnel will use a wet rag to wipe down the gear that they are wearing using wet rags provided by the assistants 5.2 For greater contamination, responding personnel will wipe down the gear that they are wearing using sorbent pads provided by the assistants 5.3 Responding personnel will then rinse their gear prior to removal of at either: 5.3.1 VS3 Cleaning Line; or 5.3.2 Outside at the southeast end of the building: 5.3.2.1 Assistants will set up the pallet stored at the southeast end of the building 5.3.2.2 Position the pallet outside near the spray hose at the southeast end of the building 5.4 PPE used in the implementation of this procedure should be thrown away 6. EHS Manager or designee. Provide for onsite technical support 7. Work Instruction Copies 7.1 Hard copies of this Work Instruction will be stored with the RCRA Contingency Plan and with each Ducommun HazMat Technician response kit. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction: WI-00241 High Hazard Chemical Incidental Spill Response Procedure Revision No.: B Page: 6 of 6 Attachment 3.10 PPE from F-00637 Emergency Equipment List Tables 1 and 2 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 19 of 33 Appendix 2-4)b)b)iii) - Start Fire Pump (WI-00250) WI-00250 Start Fire Pump - EMS Page: 1 of 4 Coxsackie, New York Last Reviewed Date: 7/28/23 Revision No.: A 1. Purpose The purpose of the Work Instruction is to provide Ducommun AeroStructures New York, Inc. (DAS NY) Maintenance personnel as well as second and third shift team leads with instructions on how to start the fire pump at the Pump House. 2. Scope The scope is for the facility at 171 Stacey Road, Coxsackie, New York. 3. Responsibilities 3.1. It is the responsibility of the EHS Manager to: 3.1.1. Revise this document 3.1.2. Provide training to applicable personnel 3.2. It is the responsibility of the Maintenance personnel and second and third shift team leads to know how to start the fire pump 3.2.1. If regularly scheduled Maintenance personnel will not be onsite, the Maintenance Team Lead or designee will notify the applicable shift team lead 3.2.2. If the second or third shift team lead will not be onsite, they must select a step up to operate the fire pump in their absence and to train that person 3.3. It is Maintenance's responsibility to start the fire pump; however, in their absence, it is the team lead's responsibility on second and third shift. 4. Definitions 4.1. Step up: person assigned to take the place of an absent leader 5. Procedure 5.1. The fire pump is located at the "Pump House", which is located along the main driveway to the facility. See Figure 1. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. WI-00250 Start Fire Pump - EMS Page: 2 of 4 Coxsackie, New York Last Reviewed Date: 7/28/23 Revision No.: A Pump House Figure 1 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. WI-00250 Start Fire Pump - EMS Page: 3 of 4 Coxsackie, New York Last Reviewed Date: 7/28/23 Revision No.: A 5.2. Method 1 for Starting the Fire Pump 5.2.1. The Diesel Fire Pump Controller is located in the Pump House. See Figure 2. Figure 2 5.2.2. Open the test valve at the bottom of the Controller. See Figure 3. You will see some water flow through the hose onto the floor. Figure 3 5.2.3. Immediately close it again. 5.2.4. Opening the valve will cause a pressure drop and the pump to start. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. WI-00250 Start Fire Pump - EMS Page: 4 of 4 Coxsackie, New York Last Reviewed Date: 7/28/23 Revision No.: A 5.3. Method 2 for Starting the Fire Pump 5.3.1. On the Control Panel (Figure 4) on the Diesel Fire Pump Controller (Figure 3): Figure 4 5.3.2. Turn the black dial to `MAN. 1' (manual) 5.3.3. Press the green START button to start the pump 5.4. Method 3 for Starting the Fire Pump 5.4.1. On the fire pump itself, push one of the two start switches up to start the pump. See Figure 5. This method can be used in the event of a power or battery failure. Figure 5 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 20 of 33 Appendix 2.4 - Utility Shutoffs (WI-00240) WI-00240 Utility Shutoff - EMS Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Page: 1 of 8 1. Purpose The purpose of the Work Instruction is to provide Ducommun AeroStructures New York, Inc. (DAS NY) Maintenance personnel as well as emergency response authorities guidance on the locations and instructions for main utility shutoffs. 2. Scope The scope is the utilities for the facility at 171 Stacey Road, Coxsackie, New York. Utilities included in this Work Instruction include electrical, water including sprinkler risers and natural gas. 3. Responsibilities 3.1. It is the responsibility of the EHS Manager to: 3.1.1. Revise this document 3.1.2. Provide training to Maintenance personnel 3.1.3. Submit this document to emergency response authorities as part of the RCRA Contingency Plan (WI-00237) 3.2. It is the responsibility of the Maintenance personnel to know how to shut of the utilities to the building 3.3. It is the responsibility of the Emergency Coordinators and designees, as defined in WI-00237 RCRA Contingency Plan, to have awareness of this procedure 4. Definitions 4.1. [RESERVED] 5. Procedure 5.1. Maintenance personnel will shut off the utilities in accordance with this work instruction when instructed to do so by: 5.1.1. Municipal, state, or contract emergency response personnel such as the fire department or hazmat team PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. WI-00240 Utility Shutoff - EMS Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Page: 2 of 8 5.1.2. Maintenance Team Lead 5.1.3. Any manager 5.2. Locations 5.2.1. Locations of the shut offs are provide in Figure 1, which is a map of the facility 5.2.2. A verbal description of the locations are include in Table 1. 5.3. Designations, instructions for shutoff and a photograph are include in Table 1. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Work Instruction: WI-00240 Utility Shutoff Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Page: 3 of 8 Natural gas main valve Two-inch water main Sprinkler system risers Switch Gear 1 Nitrogen shutoff Argon shutoff Switch Gear 2 Facility Water Main next to Fire Pump House North Three-inch water main PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Figure 1 Work Instruction: WI-00240 Utility Shutoff Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Page: 4 of 8 Utility Electrical Designation Switch Gear 1 Switch Gear 2 Location Description Maintenance Electrical Utility Room in Maintenance Department at north corner of the major section of the building Compressor Room at the west end along the right side of the major section of the building Instruction for Shut Photograph Off Pull lever down Pull lever down PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Work Instruction: WI-00240 Utility Shutoff Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Natural Gas Natural gas main valve Fire Riser Room in corner at north corner of the major section of the building Turn valve with wrench Page: 5 of 8 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Work Instruction: WI-00240 Utility Shutoff Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Page: 6 of 8 Water Two-inch main Fire Riser Room behind the risers at north corner of the major section of the building Turn both handles 90 degrees to pipe Three-inch main pH Lab Area at Turn handles northeast corner of 90 degrees to the building flow of pipe PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Work Instruction: WI-00240 Utility Shutoff Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Page: 7 of 8 Water Facility Water Main East end of Fire Pump House next to front driveway. Key to Pump House is in a combination lock box by the door. Turn valve. The curb key wrench is stored in the Pump House. Sprinkler System Risers Sprinkler System Risers Fire Riser Room in corner at north corner of the major section of the building Unlock valves. Turn valves. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Work Instruction: WI-00240 Utility Shutoff Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: B Nitrogen Argon Nitrogen Shutoff Argon Shutoff Near "Argon tank location", south end of Parking Lot C. Key to enclosure is in a combination lock box near the enclosure gate. Turn valves 90 degrees to the pipe Page: 8 of 8 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 22 of 33 Appendix 3.1 - Emergency Equipment (F-00637) Coxsackie, New York Last Reviewed Date: 11/7/23 Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 1 of 8 TABLE 1: SPILL RESPONSE KIT (PRIMARY) - Equipment location on F-00646 Site Safety Map PPE/EQMT SHORT DESCRIPTION PREFERRED QTY Gloves Neoprene or Butyl of at least 22 mil or Butyl Viton SHOWA; Chemical Resistant Gloves, 2XL, Glove Materials Butyl/Viton, 1 PR. Grainger Item # 56JH88; Mfr. Model #890-09 SHOWA Chemical Resistant Gloves: 14 mil Glove Thick, 14 in Glove Lg, Grain, 7 Glove Size, Black, 1 PR; Item # 191P06; Mfr. Model # 874R-07; UNSPSC # 46181504K2844 Each responder has a set. One of each size available with each set with spill kit. Boots Butyl Overboots ANDAX INDUSTRIES CBRN AIRBOSS; Sku: ABB2306-L Each responder has a set. One of each size available with each set with spill kit. Respirator Helmet M-405 3MTM VersafloTM Respiratory Helmet Assembly M405, with Standard Visor and Shroud, 1 EA/Case Part Number 173223M Product Number M4053M ID 7100009447UPC 00051131173224 Each responder has one. One available with spill kit. CAPACITY Chemical resistance including against hydrofluoric acid and nitric acid Chemical resistance including against hydrofluoric acid and nitric acid For use with supplied air. Breathing Tube BT-30 Breathing Tube: Versaflo, TR-300 Series/Versaflo Air Source/Versaflo Headtop; Grainger Item 11W054Mfr. Model BT-30 Each responder has one. One available with spill kit. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Coxsackie, New York Last Reviewed Date: 11/7/23 Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 2 of 8 3MTM Supplied Air Respirator Hose W-943550/07011(AAD) Air Regulator Assembly Blast Air Cart 3MTM Supplied Air Respirator Hose W-943550/07011(AAD), 1 EA/Case Part Number 070113M Product Number W-9435503M ID 7000005373UPC 00051131070110 Air Regulating Assembly: Air Regulating Valves, 3M Versaflo, 3M, Valve/Waist Belt, Versaflo Item 1AGD9Mfr. Model V-300 Air Systems International BA-50 Breather Box with cart connected to compressed air system One available with spill kit. One available with spill kit. One available with spill kit. Coveralls Sorbents Breather box; Air Pack Tychem 5000 Sorbent rolls Sorbent pads Air Systems International BB50-CO Breather Box connected to compressed air system One available at VS 1 Cleaning Line. DUPONT Hooded Chemical Resistant Coveralls: Tychem(R) 5000, Light Duty, Taped Seam, Tan, L, B, 6 PK, Item 4LTY3Mfr. Model C3127TTNLG000600 BRADY SPC SORBENTS, 40 Gal Capacity per Package, Chemical/Hazmat Roll, 150' Long x 30 Wide, Yellow, Polypropylene; MSC# 84371749, Mfr# CH30DP [BrightSorb High Visibility Safety Absorbent Roll] BRADY SPC SORBENTS, Pack of (12) 12 Gal, 4' Long, 3 Diam, Polypropylene Socks; Chemical, Each responder has a set. One of each size available with each set with spill kit. One with spill kit Chemical resistance including against hydrofluoric acid and nitric acid 40 gallons One pack of 12 with spill kit 12 gallons PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Last Reviewed Date: 11/7/23 Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 3 of 8 Yellow. MSC# 33778226, Mfr# CH412 Neutralizer Cleaning supplies Loose sorbents Amphomag (only this or other calcium/magnes um-based material) Brooms, brushes, dust pans, squeegees (Polypropylene, no metal parts) 5.9.1 PIG; Loose Absorbent, Chemical, Polypropylene, 5 lb. Grainger Item # 30RD06; Mfr. Model # HA8010 3 x 5 pound with spill kit 50-pound tote; 3-pound shaker 3 x 3-pound shaker with spill kit 1 x 50-pound tote with spill kit 70% HF = 11 lbs Amphomag/gal spilled material 68% HNO3 = 4 lbs Amphomag/gal spilled material Bonderite: 7% HF/40%HNO3 = 3.3 lbs Amphomag/gal spilled material 25% sodium hydroxide = 1.8 lbs Amphomag/lb of spilled material 50% sulfuric acid = 0.65 lbs Amphomag/lb of spilled material PRO-SOURCE; 24 General Purpose Polypropylene Push Broom; 3 Bristle Length, Wood Block, Threaded Handle Connection, Handle Sold Separately; MSC# 09319310; Mfr# SWP24 1 x each with spill kit CARLISLE; Angled Brooms; Width (Inch): 12in ; Handle Connection Type: Threaded ; Bristle Material: Polypropylene ; Brush Width: 12in. MSC# 95749271, Mfr# 41082EC09-Old REMCO; Dust Pans & Scoops; Type: Handheld ; 15 gallons See below Low chemical reactivity PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Coxsackie, New York Last Reviewed Date: 11/7/23 Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 4 of 8 Dust Pan Type: Handheld ; Width (Inch): 13 ; Body Material: Polypropylene ; Handle Length (Inch): 4 ; Handle Length: 4. MSC# 1439648; Mfr# 558116. BRUSH RESEARCH MFG. Broom/Squeegee Poles & Handles; Connection Type: Threaded ; Handle Material: Wood. MSC# 95946968; Mfr# H19 REMCO. Counter & Dust Brushes; Type: Bench Brush ; Brush Type: Bench Brush ; Bristle Material: Polypropylene ; Head Length (Inch): 7.0 ; Bristle Firmness: Medium. MSC# 14396865; Mfr# 451119 TOUGH GUY Recycled Trash Bags: 96 gal Capacity, 52 in Wd, 75 in Ht, 2 mil Thick, Black, 50 PK; Grainger Item 6FWH8Mfr. Model 6FWH8 When updated, update WI-00241 High Hazard Chemical Incidental Spill Response Procedure High Hazard Chemicals PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Coxsackie, New York Last Reviewed Date: 11/7/23 Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 5 of 8 TABLE 2: PORTABLE/MOBILE CHEMICAL SERVICE PUMPS PUMP PICTURE PUMP; ALLOWED CHEMICALS Custom changeout pump: Only for: Nitric hydrofluoric acid mix Nitric acid PUMP PICTURE PUMP; ALLOWED CHEMICALS Hand (siphon) pump: Only for: Hydrofluoric acid Shop Vac: Only for: Dilute nitric hydrofluoric acid Dilute nitric acid Dilute hydrofluoric acid When updated, update WI-00241 High Hazard Chemical Incidental Spill Response Procedure High Hazard Chemicals PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Coxsackie, New York Last Reviewed Date: 11/7/23 Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 6 of 8 TABLE 3: OTHER - Equipment location and quantity on F-00646 Site Safety Map Equipment Fire Extinguisher, ABC* Fire Extinguisher, BC* Fire Extinguisher, CLASS D* Emergency Phone Secondary spill response kit (outside near Maintenance doors) Version spill response kit Capacity A I; BC II 10 lb 30 lb Landline. Dial 9 for external. Absorption Capacity: 39 gal. Container: 55: gal Absorption Capacity: 15 gal. Container: 20 gal TABLE 4: FIRE PUMP HOUSE - BIN Copy of Contingency Plan Handheld Radios Flashlights with Wands General Flashlights Lantern High visibility vests Rain Ponchos, Space Blankets Quantity 1 8 2 4 1 8 Not specified PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 11/7/23 Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 7 of 8 TABLE 5: LESS-THAN-90-DAY AREA 65-gallon overpack Pads and socks Phone Quantity 1 Overpack full 1 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 11/7/23 Form No.: F-00637 Emergency Equipment List & Inspection Form - EMS Work Instruction: WI-006216 RCRA Contingency Plan Revision No.: B Page: 8 of 8 Table 1 Date Completed Signature Monthly Inspection Form Inspection Dates / Initials Table 2 Table 3 Date Completed Signature Date Completed Signature Table 4 Date Completed Signature Date: Table: Finding: Findings *Inspections documented on another form PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 23 of 33 Appendix 4.1.5.1 - Chemical Line Tank Concentrations Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 2/1/24 Revision No.: D Chemical Line Tank Concentrations First number in ID indicates value stream Tank ID 1-1 3-1 4-1 4-7 5-2 1-5 3-5 5-6 Name Constituent Spec High Limit Unit Alkaline Clean Oakite 61B 8 Titanium Nitric 60 Etch Hydrofluoric 7.0 oz/gal oz/gal. oz/gal. Page: 24 of 33 Measure Concentration Nitric Concentration Hydrofluoric Concentration 4-3 Passivation Nitric Acid 58 oz/gal. Acid Concentration 4-4 Aluminum Etch Oakite 160 5 oz/gal Concentration 4-6 Desmut Nitric Acid 57 oz/gal Acid Concentration Bonderite* C- 14.0 oz/gal Nitric Acid Concentration 4-9 Deoxidizer IC 6MU (Turco 1.1 oz/gal Turco Concentration Deoxidizer) 0.4 mils/hr/side. Etch Rate 4-10 Conversion 2.25 Alodine* 600 Coat 2 oz/gal pH Alodine Concentration pH 4-12 1.2 Conversion Coat Alodine* 1200 1.8 1-3, 3-3, & 5-4 Molten Salt Bath (Caustic) ALKO-N *Bonderite = Alodine oz/gal pH Alodine Concentration pH Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 27 of 33 Appendix 7.3 - Supporting Personnel (2 copies) Work Instruction: WI-00237 RCRA Contingency Plan - EMS Coxsackie, New York Last Reviewed Date: 10/24/23 Revision No.: D Page: 28 of 33 Immediately Emergency Response Supporting Personnel for Emergency Coordinator # DESIGNATION DUTIES FIRST SHIFT (DEPARTMENT) 1 Assistant Emergency For off 2nd shift, 3rd shift, weekends, during an event, select personnel and direct Not Applicable Coordinator them to perform actions 2 - 7 below 2 Emergency Retrieve the emergency coordinator bin at the Pump House, the spill control Maintenance coordinator support equipment (without the intent to respond to spills), assist with head count, etc. retrieval 3 Radio distribution Distribute hand held radios to the Emergency Coordinator or designee, each gate Maintenance and muster point 4 Front gate emergency Personnel stationed at front gate directing emergency vehicle traffic Engineering vehicle guide 5 Back gate emergency vehicle guide 6 Front gate incoming Personnel stationed at front gate directing incoming shift vehicle and personnel Human resources (primary) shift vehicle guide traffic to either: or Finance 7 Back gate incoming 1) Go home for actual events shift vehicle guide 2) Where to park in the event of a drill or possible false alarm 8 Non-responding Support the on-scene emergency coordinator either in person or via telephone As listed emergency including: coordinators 1) Immediately, contact the: a) Safety Manager b) Performance Center Director c) Maintenance Team Lead 2) Once the event is stabilized, via email, alert the other managers to the event including: a) Value Stream Managers b) Program Managers Coxsackie, New York Last Reviewed Date: 10/24/23 c) Quality Manager d) Engineering Manager e) Human Resources f) Controller Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 29 of 33 Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 17 of 33 Appendix 2-1)a) - Shelter In Place (Tornado) (WI-00242) Coxsackie, New York Last Reviewed Date: 3/25/24 Work Instruction.: WI-00242 Shelter In Place (Tornado Shelter) - EMS Revision No.: C Page: 1 of 3 1. Purpose The purpose of this work instruction is to provide instruction for a shelter-in-place event. 2. Scope This work instruction applies to Ducommun AeroStructures New York, LLC, (DAS NY) personnel at 171 Stacey Road, Coxsackie, New York. 3. Responsibilities 3.1. Safety Manager: Revise and maintain this work instruction. 3.2. Supervisors: Enforce this work instruction 3.3. All Employees: Follow this work instruction 4. Definitions 4.1. [Reserved] 5. References 5.1. WI-00237 - RCRA Contingency Plan - EMS 6. Procedure/Policy 7. The Safety Manager or an emergency coordinator in their absence will: 7.1. Monitor weather conditions 7.2. During a Tornado Watch, will listen to a weather radio 7.3. For severe weather including a tornado warning, make an announcement to seek shelter will be made over the Public Address System and using the Bullhorn located in the Maintenance Office. If the power is out, this announcement can be made throughout the plant using the Bullhorn . 8. Employees will: 8.1. Go to an interior room. There are several areas designated with signage (see Figure 1) as "Severe Weather Shelter Areas". 8.1.1. See attached F-00646 Site Safety Map - EMS for Shelter in Place Areas identified in red. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 3/25/24 Work Instruction.: WI-00242 Shelter In Place (Tornado Shelter) - EMS Revision No.: C Page: 2 of 3 8.1.2. Personnel that report to the following managers will seek shelter in the indicated locations. See Table 1. 8.2. Do not go near windows, doors or exterior walls. 8.3. Exit to these areas in an orderly manner. 8.4. Remain at the Shelter in Place until dismissed. 9. When the instructions to seek shelter is announced, the Manager or their step up will: 9.1. Provide access to their designated shelter areas for employees who do not have badge access. 9.2. Once inside the safe shelter conduct a head count to make sure all employees are present or accounted for. 10. Customers, Vendors, and Visitors are the responsibility of their hosts and need to be accounted for. 11. First Responders will bring bags if safe to do so. 12. The Safety Manager or an emergency coordinator will check with each Manager/Team Leader to tally a correct total facility headcount that has been made on the 1st Shift. 13. Off Shift Managers, supervisors and team leads will do this check on 2nd and 3rd Shifts. 14. Once the head count has been confirmed and it is determined to be safe, all employees will be informed to return to their work areas. Figure 1 PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 3/25/24 Work Instruction.: WI-00242 Shelter In Place (Tornado Shelter) - EMS Revision No.: C Page: 3 of 3 Department VS1/VS2 VS3/Blank/S_R VS4 VS5 Engineering Quality Maintenance Purchasing HR Finance IT Program Mgmt Program Mgmt Program Mgmt GM # Personnel 23 33 23 21 19 19 4 4 3 2 2 2 2 2 1 Table 1 Location Front Women's/Men's Restroom Hallway to Parking Lot C Men's Room in Front of VS1 DCC Maintenance Front Office Front Women's/Men's Restroom Maintenance Front Office Hallway to Parking Lot C Hallway to Parking Lot C Men's Room in Front of VS1 Men's Room in Front of VS1 Hallway to Parking Lot C Hallway to Parking Lot C Hallway to Parking Lot C Hallway to Parking Lot C Second shift, third shift, weekend work - Hallway to Parking Lot C PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 18 of 33 Appendix 2-1)b) - Medical Emergency (WI-00251) Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction.: WI-00251 Employee Injury Procedure - EMS Revision No.: B Page: 1 of 3 1. Purpose The purpose of this work instruction is to provide instruction in the event an employee is injured. 2. Scope This work instruction applies to Ducommun AeroStructures New York, LLC, (DAS NY) personnel in Coxsackie, New York. 3. Responsibilities 3.1. Safety Manager: Revise and maintain this work instruction. 3.2. Supervisors: Enforce this work instruction 3.3. All Employees: Follow this work instruction 4. Definitions 4.1. [Reserved] 5. References 5.1. WI-00237 - RCRA Contingency Plan - EMS 6. Procedure/Policy 6.1. Have a First-Aid Responder or equally trained person treat the injured person. 6.2. Determine if the person needs off-site treatment. 6.3. Ask permission to transport. 6.3.1. LIFE THREATENING: A person can refuse off-site medical treatment on the grounds of Religious or other personal reasons. If there is a question on the severity of their injury, (requiring professional medical treatment), the Authorities must be called (9911) and they (the authorities) will need to make a final determination. 6.3.2. NON-LIFE THREATENING: A person can refuse off-site medical treatment on the grounds of Religious or other personal reasons. If not life threatening, but requiring professional medical treatment; have the injured employee fill out: Ducommun Form EHS 2.18.4 Medical Release Form. Make sure to have the two witnesses sign the Form! PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction.: WI-00251 Employee Injury Procedure - EMS Revision No.: B Page: 2 of 3 6.4. Determine if they can be transported by private vehicle, or if an emergency vehicle needed. 6.5. Before transport in a private vehicle, make sure person is stable enough to travel. 6.5.1. If this is a Water-jet Injury, take a Medical Alert Card (located on Water-jet machine console) with you. 6.5.2. Talk calmly to the injured person, they are upset enough. 6.6. If transported in an Emergency Unit, the responding personnel will stabilize. 6.6.1. If this is a Water-jet Injury send a Medical Alert Card (located on Water-jet machine) with them. 6.6.2. The injured has the right to request a certain hospital. Columbia Memorial is the default. 6.7. While the person is coherent, make sure to get all possible information about the injury. 6.7.1. Sometimes as the injury becomes more painful a person may go into shock and forget details. 6.7.2. It's important to give the attending personnel all the details possible, including the Medical Alert Card if needed. 6.7.3. You are to either accompany or follow the employee as support and to make sure that they get treated with respect and have a clear understanding of what is going on as far as treatment goes. 6.8. Proceed to EmUrgentCare (Open 0900-2100) 11835 State Rt. 9W West Coxsackie (518) 7319000. Or to Columbia Memorial (Hudson) Emergency Room. 6.9. If the injured can fill out necessary paperwork, it can be done while waiting for admittance. Otherwise it may be done after the fact. Remember your activity in a calming demeanor will help alleviate a nerve racking situation for the injured. 6.10. When treatment has been administered and restrictions are being discussed, Ducommun has a Light Duty/Accommodation Program for those injured on the job. The employee must have the explicit documentation from the Health Provider stating they are cleared to return to work and/or if they have restrictions. If the injured employee has restrictions, HR will need an 6.11. Employment Capabilities Form completed by the Health Provider stating what specifically those restrictions are. This form needs to be reviewed and approved by HR PRIOR to the employee returning to work. Unless the person is totally incapacitated, this option needs to be discussed. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 10/24/23 Work Instruction.: WI-00251 Employee Injury Procedure - EMS Revision No.: B Page: 3 of 3 6.11.1. Remember when talking on behalf of the employee to the care-giver; do not assume an authoritative attitude. This only provokes the Health Provider. Just make them aware that the injured can be accommodated when they return to work. (with the proper documentation from the Health Provider as noted above) 6.11.2. As a note, let the injured know that if they are written out of work, Worker's Comp does not pay till after 5 days. They would have to take sick time etc. 6.11.3. Make sure that the restrictions return to work etc., is all in writing. Verbal is no good. 6.12. Once the necessary treatment and paperwork have been completed, bring the injured back to the facility for a quick de-brief. After that, the injured can go home for the rest of their shift. Please make sure that they can drive or can get a ride. 6.13. Remember that above all, this employee is hurting and they need to be treated with compassion & understanding. 6.14. Once the person has been treated and is stable; notify all concerned parties and HR and EH&S of the incident and current status. PRINTING NOTICE - Individuals are responsible for ensuring that they are using the governing version. Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 30 of 33 Appendix 9.4.5.2 - Agreement with Veolia January 1, 2023 Mrs Mary McCoy Ducommun Aerostructures, Inc 171 Stacey Road Coxsackie, NY 12051 RE: Emergency Response Cost & Procedures: Dear Mrs. McCoy: Veolia Environmental Services (Veolia) has the technical personnel and equipment capabilities to respond to Ducommun Aerostructures, Inc. emergency response needs. All waste disposal requirements can be managed according to the environmental services agreement to be completed for these services. Emergency Response Procedures In the event of a chemical spill or other emergency situation, it is important that pertinent information be accurately and efficiently relayed to VEOLIA personnel. Much time and money can be saved if the situation is assessed properly and the appropriate manpower and equipment are mobilized. The following steps should be taken when an employee is responding to a chemical spill/emergency and requests the services of VEOLIA. 1) If possible, identify the spilled chemical and quantity. Also note the location of the spill. 2) CALL VEOLIA AT 1-800-354-2382. Dial "1". 3) The information provided will be given to the "on-call" Veolia representative, who will initiate internal communications with Veolia operations personnel, and the response action will begin to develop. You will be contacted by a representative of Veolia with first response communications. 4) Once the level of response has been determined, the appropriate personnel and equipment will be mobilized. A subcontractor may be contacted to assist with the response. Emergency response equipment that will be on-site when a field crew is picking up chemicals. The following emergency response equipment is provided with each service vehicle at time of Page 1 of 11 service: 85 gallon drum over pack Vermiculite Personal Protective Equipment (tyveks, gloves, boots, respirators) ABC dry chemical fire extinguisher Fully equipped first aid kit including eye wash Drum opening tools, shovel, poly sheeting Empty containers pH paper to assess corrosivity Spare fuses, flashlights Reflective triangles Mobile phone Spill equipment available, if necessary, through the Emergency Response Clean-up Team (Subcontractor) Vacuum Truck Spill control trailer Special pumps and tools Large stock of absorbents (vermiculite, speedi-dry, booms, activated carbon, lime) Self-Contained Breathing Apparatus Earth excavation equipment and water-tight dump trailers Emergency Response Costs Annual Administrative Fee: $500.00 During normal business hours; Monday - Friday 8 am - 4 pm: $1,000.00 flat fee $115.00 per hour for a Field Supervisor $95.00 per hour for a Technician After normal business hours; Monday - Friday 5 pm - 7:59 am: $1,750.00 flat fee $172.50 per hour for a Field Supervisor $142.50 per hour for a Technician Sundays and Holidays: $2,250.00 flat fee $230.00 per hour for a Field Supervisor $190.00 per hour for a Technician Rates for additional services, equipment, and supplies, should they be required, are listed below. Page 2 of 11 Please return this quotation indicating your acceptance with your signature and purchase order number below. We value the opportunity to service your environmental needs. If you have any questions or concerns, please contact me at (518) 332-5529. Sincerely, Veolia Environmental Services Megan Pellam Megan Pellam Account Manager Cc: Renee Spadaro, TSR, Veolia ACCEPTED: Ducommun Aerostructures, Inc. By: Title: EHS Manager Date: 5/23/23 Purchase Order No: Page 3 of 11 2021 TIME AND MATERIALS RATES EMERGENCY RESPONSE FEES & RATES: Annual Administrative Fee: $500.00 During normal business hours; Monday - Friday 8 am - 4 pm: $1,000.00 response fee After normal business hours; Monday - Friday 5 pm - 7:59 am: $1,750.00 response fee Sundays and Holidays: $2,250.00 response fee Labor- North East Section 1.1 Environmental Personnel/Administrative Administrative Assistant/Field Clerk Health & Safety Specialist Field Chemist Field Technician Truck Driver (Commercial License - Haz Mat) Equipment Operator Foreman Superintendent Response Manager Engineer Hydrogeologist Scientist Principal Oversight/Technical Oversight Disposal Coordinator Biohazard/Reactive/Explosive Technician Biohazard/Reactive/Explosive Supervisor Railcar Specialist Firefighter Section 1.2 Marine Personnel U.S. Coast Guard Licensed Captain Deckhand Marine Superintendent/Non-diving Supervisor Commercial Diving Supervisor Regular Per Hour Overtime Per Hour Premium Per Hour $48.75 $107.00 $77.50 $95.00 $70.00 $70.00 $70.00 $89.00 $115.00 $114.50 $114.50 $114.50 $145.75 $53.00 $116.75 $175.00 $79.50 $70.75 $145.75 $69.00 $145.75 $116.50 $73.25 $107.00 $116.25 $142.50 $105.00 $105.00 $105.00 $133.50 $174.50 $114.50 $114.50 $114.50 $114.50 $79.50 $175.25 $175.00 $119.25 $106.25 $218.75 $103.50 $218.50 $174.75 $97.50 $107.00 $155.00 $190.00 $140.00 $140.00 $140.00 $178.00 $190.00 $114.50 $114.50 $114.50 $114.50 $106.00 $233.50 $175.00 $159.00 $141.50 $291.50 $138.00 $291.50 $233.00 Page 4 of 11 Commercial Diver Commercial Dive Tender Remote Vehicle Operator Sonar Technician Equipment $99.00 $70.75 $126.00 $127.25 2.1 Other Services Spill Report Expert Witness Testimony Subcontract/Rental Equipment 2.2 Personal Protection and Safety Equipment Level A Protection - Trelleborg Viking NFPA Suite Level A Protection or Equivalent Level B Protection w/Responder Level B Protection w CPF 1-2-3 Level B Protection w CPF 4 Level B Protection w Goretex Turnout Gear Level C Protection w/CPF 1-Proshield Level C Protection w/CPF 2 Level C Protection w/CPF 3 Level D Protection w/CPF 1-Proshield Cascade Manifold Breathing Air System w T Bottles Breathing Air Hose (50ft Section) Air Cascade Trailer Self Contained Breathing Apparatus (standby) Portable Eye Wash Rope Rescue kit (standby) Confined Space Entry Kit w/ Tripod Confined Space Entry OSHA Rope Kit Proximity Suits( W/SCBA) USCG Floatation Vest Nomex Suits Cold Weather Deck Suit CPF 1 Suits CPF 2 Suits CPF 3 Suits CPF 3 Suits, Expanded back CPF 4 Suits CPF 4 Suits-Encapsulated, expanded back Responder - Level B Responder - Level A EOD Suits ( Turn-out gear) Tyvek Suit Poly-coated Tyvek Suit Rain/Splash Gear PVC Acid Suit 2.3 Transport Equipment Automobile Pick-up Truck Response Managers Pick-up Truck (minimum $355.00) $148.50 $106.25 $189.00 $190.75 $198.00 $141.50 $252.00 $254.50 $114.00 Hour 2 times list rates cost plus 20% $2,500.00 $1,200.00 $975.00 $550.00 $600.00 $500.00 72.00 $136.00 $175.00 $47.00 $84.50 $17.50 $360.00 $190.00 $36.00 $51.50 $154.00 $1.00 $825.00 $21.00 $24.75 $51.50 $16.75 $47.25 $79.25 $146.25 $79.25 $156.25 $680.00 $1,240.00 $500.00 $15.50 $31.00 $25.75 $31.00 $55.25 $92.75 $190.00 Change Change Change man/day man/day man/day man/day man/day man/day man/day man/day sect/day Day Day Day Day Day Foot man/day Ea/day Day Day Each Each Each Each Each Each Each each Day each each set set day day day Page 5 of 11 Four Wheel Drive Vehicle Utility Truck (1 ton payload) Utility Truck (1 ton payload) w Lift Gate / Box Van Stake Bed Truck (5 ton payload) / Box Van Emergency Response Trailer (14 to 16 ft.) Emergency Response Trailer (18 to 25 ft.) Emergency Response Trailer ( > 25 ft) ER Command Center Trailer Semi-Tractor Rolloff Trailer Rolloff Truck Rolloff Box (20 yd) Rolloff Drop Charge Dump Truck Dump Trailer Flat Bed Trailer (40 ft) Low Boy Office Trailer Equipment Trailer ( Skidsteer) Utility Trailer (enclosed) (14 - 18) Semi-van Trailer (40 ft.) Tanker Trailer (non vacuum) (7,000 gal.) Tanker Trailer (non vacuum) (5,000 gal.) Sludge Tanker Trailer 2.4 Vacuum Equipment Vacuum Trailer Non-regulated waste, Hourly Vacuum Trailer Regulated waste, Hourly Straight Truck < 3,500 gallon capacity Non-regulated waste, Hourly Straight Truck < 3,500 gallon capacity Regulated waste, Hourly Straight Truck > 3,500 gallon capacity Non-regulated waste, Hourly Straight Truck > 3,500 gallon capacity Regulated waste, Hourly High Velocity Vacuum Truck (ie. supersucker, guzzler, hivac) Cyclone Separator for High Velocity Vacuum Truck Vacuum Unit (800 gal.; w/50 ft hose) (mini-vacuum) Vacuum Box Vacuum Box Drop Portable HEPA Vacuum units w/o Filter Mercury HEPA Vacuum w/o Filter HEPA Drum Vacuum w/o Filter Mercury HEPA Vacuum Filter HEPA Vacuum Filter Explosive Proof HEPA Vacuum Drum Vacuum (Air) Tornado Drum Vac (Electric) Utility Vacuum Vapor Scrubber Unit Pneumatic Vacuum Transfer Trailer 2.5 Waste Excavation and Handling Equipment Rubber-Tired Loader (CAT 930 or Equivalent) Crawler Dozer (CAT D-5 or Equivalent) Trackhoe Excavator (CAT 330 or Equiv.) Trackhoe Excavator (CAT 320 or Equiv.) Backhoe (Case 580 or Equivalent) Fork Truck Bobcat(Skidsteer) Skidsteer Sweeper $136.75 $114.50 $153.75 $300.00 $224.00 $308.00 $325.00 $1,030.00 $48.00 $33.00 $43.00 $12.50 $250.00 $37.00 $129.00 $52.00 $206.00 $57.00 $52.00 $52.00 $62.00 $33.00 $21.50 $20.50 day day day day day day day day hour hour hour day each hour day day day day day day day day day day $57.00 hr $72.00 hr $76.50 hr $98.50 hr $81.50 hr $104.00 hr $98.00 hr $31.00 hr $46.00 hr $52.00 day $250.00 each $77.00 day $360.00 day $221.00 day Replacement cost & 20% $135.00 each $155.00 day $62.00 day $155.00 day $35.00 day $1,020.00 day $258.00 hr $546.00 day $655.00 day $2000.00 day $1200.00 day $500.00 day $329.00 day $400.00 day $82.00 day Page 6 of 11 2.6 Mobile Treatment and Recovery Equipment Hydraulic Dredge Holding Tank (> 5,000 gal.) (5 day Minimum, plus mob/demob) Frac Tank (21,000 gal) (5 day Minimum plus mob/demob) Poly Storage Tanks (<500 gals) ( 5 day min) Poly Storage Tanks (>500- 5000 gals) ( 5 day min) Bag Filter Unit (Filters extra) Mobile oil/water separator/air stripper trailer 2.7 Pumping Equipment 1",2",3" Air Diaphragm Pump 2" Hydraulic chemical pump w/Power Pack 2" Submersible Electric Pump 3" and 4" Trash Pump 3" Submersible Electric Pump 4" Air Diaphragm Pump 4" Electric Centrifugal Sludge Pump 4" Hydraulic Sludge Pump w/ Power Pack 4" Submersible Electric Pump 6" Hydraulic Sludge High Head Pump w/Power Pack 6" Hydraulic Sludge Pump w/ Power Pack 6" Trash Pump 8" Hydraulic Sludge Pump w/ Power Pack 10" Trash Pump Utility pump / 12 Volt Transfer Pump Explosion proof electric Drum Pump Drum siphon pump Corken Compressor Blackmer Pump w Power Pack Diaphragm Pump Rebuilding Kit 1", 2", 3" Diaphragm Pump Rebuilding Kit 4" 2.8 HOSE Fittings Charge Suction 2" (20 ft section) (Non Chem) Suction 3" (20 ft section) (Non Chem) Suction 4" (20 ft section) (Non Chem) Suction 6" (20 ft section) (Non Chem) Fire 1.5" (50 ft section) Fire 2.5" (50 ft section) Fire 3.0" (50 ft section) 2" Solvent/petroleum 2" Acid/caustic 2" Disposable Flex hose 4"- 6" Disposable Flex hose 8" Disposable Flex hose 1", 2", 3" Chemical hose w/appropriate fittings 2", 3" Discharge (100' section) (non-chemical) additional Hydraulic hose (50' section) additional 2.9 Industrial Services Equipment Sewer Cleaning Truck / Jetter Water Truck 85 gpm, 2000 psi Intrinsicaly Safe Sewer Inspection Unit Non-Intrinsicaly Safe Sewer Inspection Unit Skid Mounted Jetter Water Unit(240 gpm, 2500psi) Sewer Jetter Water Truck 85 gpm,1500 psi Comb Jetter/Vac Truck (65 gpm, 3000 cfm) Comb Jetter/Vac Truck (85 gpm, 3500 cfm) Comb Jetter/Vac Truck (138 gpm, 4500 cfm) Priced per project $52.00 day $82.00 day $16.00 day $41.00 day $28.00 day $1,290.00 day $155.00 $360.00 $98.00 $206.00 $165.00 $258.00 $128.00 $465.00 $232.00 $1,030.00 $1,030.00 $309.00 $1,545.00 $515.00 $52.00 $155.00 $16.00 $1,000.00 $450.00 $360.00 $515.00 day day day day day day day day day day day day day day day day each day Plus Rebuild day ea ea $320.00 $10.50 $16.00 $22.00 $32.00 $27.00 $37.00 $43.00 $1.00 ft or $2.50 ft or $30.00 $1.50 $2.00 $3.25 $37.00 $52.00 Per transfer day day day day day day day cost & 20% cost & 20% 100' roll foot/day foot/day foot/day day ft/day $90.00 hr $165.00 hr $110.00 hr $143.00 hr $55.00 hr $95.00 hr $111.00 hr $132.50 hr Page 7 of 11 Easement Reel w/ Trailer Pump Trailer/Heat Exchanger 2.10 Oil Spill Equipment Drum Skimmer-Hydraulic w/Power Pack Drum Skimmer-Pneumatic w/o Power Pack Skim-Pac 2200 Weir Skimmer 2" Weir Skimmer Boom Boat - 18'-20' Boom Boat - 24' Jon Boat (12-14'; with motor) Jon Boat (12 - 14' without motor) Containment Boom - 18" Containment Boom - 18" (standby) Containment Boom - 36" Containment Boom - 36" (standby) Boom Anchor System Boom Lights USCG Floatation Vests VHF-FM Hand Held Radio Floto-pump Oil Blower, Gas Powered 2.11 Marine Specialty Equipment Shallow Air Package Deep Air Package (Single Chamber) Remote Operated Vehicle - Phantom HD2 Digital Side Scan Sonar Resonance Multi-Beam Sonar Sector Scanning Sonar Differential Global Positioning System 26ft Portable Survey Boat 28ft Portable Tug - 275hp Diesel Inboard 25ft x 35ft x 2.5ft Self-propelled Portable Crane Barge W/Spuds and 8,000lb Hydraulic Crane 40ft x 50ft x 4ft Portable Barge W/spuds 2.12 Compression Equipment Diesel Air Compressor < 300 cfm Air Compressor, < 300 cfm Hot Water Press. Wash Unit (2,500 - 3,000 PSI) Pressure Wash Unit (2,500 - 3,000 PSI) Pressure Wash Unit (1,000 - 1,500 PSI) Air Blower/Air Evacuator Waterblaster (10,000 PSI) Waterblaster (20,000 PSI) Air Hose (3/4", 50' section) Graco Wash Unit 2.13 Sampling and Analytical Equipment Photoionization Detector (PID Meter) O2/LEL/Toxic Meter (Quad Gas Monitor) Radiation Meter Laser temperature meter Jerome Mercury Monitor VM 3000 Mercury Monitor / Lumex Field Characterization Kit Megger Meter GPS Unit UHRA First Defender $40.00 hr $230.00 hr $740.00 $432.00 $155.00 $103.00 $464.00 $567.00 $110.00 $75.00 $2.00 $1.00 $3.50 $1.75 $77.00 $21.00 $21.00 $21.00 $82.00 $51.00 day day day day day day day day ft/day ft/day-Stby ft/day ft/day-Stby day each day Ea/day day day $260.00 day $950.00 day $1,236.00 day $650.00 day $1,545.00 day $310.00 day $103.00 day $950.00 day $950.00 day $1,500.00 day $750.00 day $305.00 $191.00 $220.00 $154.00 $103.00 $26.00 66.00 $131.00 $16.00 $103.00 day day day day day day hr hr sect/day day $155.00 $103.00 $103.00 $36.00 $360.00 $515.00 $30.00 $52.00 $25.00 $500.00 day day day day day day Per Sample day day day Page 8 of 11 Cyanide Meter Chlorine Meter pH Paper BTA Guardian Analyzer Ultraviolet Germicidal Lighting Draeger Air Monitoring Pump w/o tubes Draeger Tubes Asbestos Monitoring Pump Personal Air Sampling Pump Clor-n-oil test kit Clor-n-soil test kit Rocket Fuel Test Kit X Spray Sample Kit Smart II Biological Detection Tickets BTA Test Biological Test Strip (Agent Specific) Wipe Sample Kit Coliwasa Glass Sampling Tubes (4') Sample Thief, 75 ml Split Barrel Hand Sampler Hand Auger 2.14 Specialized Tools and Equipment Drum Cart Glove Box Tank Tap Machine Non-Sparking Tool Set Pressurized Gas Overpack Containers Plug & Patch kit Tank Truck Rollover Trans Kit/Hot tap kit Betz Valve-Tank Truck Rollover Forklift Drum Holder Evacuation Fan HEPA Negative Air Machine (w/o Filter replacement) Portable Flare Stack 2.15 Miscellaneous Equipment Generator (5 kW) Generator (15 kW) Generator (100 kW - 200 kW) Portable Light Set Intrinsically Safe Portable Lights, Portable Hammer Drill Air Hammer (bits extra) Chop Saw (Concrete/Metal) (Portable) (1 blade incl.) Cutting Torch (Oxygen/Acetylene Not Included) Hand tool allowance / Small tools Portable Welder Pneumatic Pipe Plugs Phone - Mobile SAT Phone Field Printer/Copier Field Computer Photo Documentation Chain Saw Portable Heater (Salamander) 3.1 Containers 2-5 gal. Plastic Pails $103.00 day $103.00 day $8.00 roll $675.00 day $103.00 day $16.00 day $10.00 each $26.00 day $33.00 day $21.00 each $26.00 each $4.50 Each sample $3.33 Each sample $113.00 each $150-500 each $77.00 each $23.00 each $3.25 each $3.25 each $41.00 day $16.00 day $21.00 day $100.00 day Priced per project $103.00 day $825.00 day $160.00 each $1,030.00 day $258.00 day $16.00 day $77.00 day $155.00 day $206.00 day $82.00 day $180.00 day $360.00 day $30.00 day $103.00 day $52.00 day $51.00 day $51.00 day $41.00 day $67.00 day $155.00 day $103.00 day $35.00 day $80.00 Call $31.00 day $21.00 day $30.00 day $51.00 day $51.00 day $14.00 each Page 9 of 11 5 gal. metal drum 14 Gallon Plastic Drum 20 gal Fiber Drum 30 gal. Plastic Drums 30 gal. Fiber Drums 55 Gallon Metal Open Top Drum (Reconditioned) 55 Gallon Metal Closed Top Drum 55 gal. Plastic Drums 85 gal. Overpack Drums (Metal) 95 gal. Overpack Drums (Plastic) Poison pack, 12A10 Asbestos Bag / Drum Liner 6 ml Cubic Yard Box - Gaylord IBC Container Tote (Reconditioned) 3.2 Packaging Drum Liner (Heavy Duty Corragated) Shrink Wrap Rolloff Box Liner (20 yd) 3.3 Gloves 4H Chemical Gloves Acid Gloves.(Milled Neoprene) Cloth Gloves Gloves, Winter Poly Liners Leather Work Gloves Nitrile Interior Gloves (NDEX) (50 pair/box) PVA Gloves PVC Gloves Solvex Gloves Viton Gloves 3.4 Boots Neoprene Boots PVC/Latex Disposable Boots (Nuke boots) Rubber/PVC Boots/Beta 3.5 Respirator Cartridges Respirator Cartridges - GME Respirator Cartridges - GME - P100 Respirator Cartridges - P100 Respirator Cartridges - Mersorb Respirator Cartridges - Mersorb - P100 3.6 Face/Eye Protection Face Shields Goggles Safety Glasses Welding Goggles 3.7 Cleaning Supplies Alconox (4lb box) Brute Force (1 gal) Mercury Decontamination Solution (HGX) Micro Blaze (5 gal) Micro Blaze Application Kit Paper towels (reinforced) (box) PCB Decontamination Solution (10 gal) Simple Green Trash Bags (100/box) Decon Pools (100 gals) $16.00 $46.00 $21.00 $48.00 $32.00 $53.25 $33.00 $75.25 $175.00 $206.00 $36.00 $2.50 $115.00 $180.00 $18.00 $26.00 $65.00 $6.50 $16.00 $2.25 $4.25 $6.00 $13.50 $36.00 $8.00 $15.50 $145.00 $26.00 $6.75 $125.00 $15.00 $23.00 $10.00 $26.00 $41.00 $8.50 $4.25 $6.25 $20.00 $26.00 $17.00 $10.50 $250.00 $315.00 $13.50 $270.00 $18.00 $5.25 $515.00 each each each each each each each each each each each each each each each roll each pair pair pair pair pair box pair pair pair pair pair pair pair pair pair pair pair pair each each pair each each each pound each day box each Gal. box each Page 10 of 11 DIRS BioChem Decon Kit 3.8 Sorbents/Neutralizing Agents Citric Acid Gap Seal Gypsum Oil dry / Floor dry / Grand sorb Sand bags Soda Ash Super Absorbent Powder (S.A.P.) (25gal pail) Vermiculite Absorbent Pads (17" X 19") Absorbent Boom (8" x 10') Absorbent roll (4'x150'/ Roll) 3.9 Miscellaneous Barrier Tape/Hazard Tape Chest Waders Fence Post Waste Manifests Drum Labels Plastic Snow Fence (50 ft) Poly Rope (3/8") Poly Rope, Nylon (1/2') Sample Jar (4oz) Sample Jars (1 qt.) Disposable Bailer Duct Tape Visqueen, 6ml, 20" x 100' Visqueen, 6ml, 40" x 100' $925.00 $82.00 $21.00 $16.00 $16.00 $2.25 $36.00 $47.00 $20.00 $95.00 $65.00 $125.00 $21.00 $77.00 $5.25 $5.25 $1.00 $36.00 $0.20 $0.30 $3.25 $3.25 $10.00 $6.75 $115.00 $270.00 kit bag each bag bag each bag each bag Bale each roll roll pair each each each roll foot ft each each each roll roll roll Page 11 of 11 ! PURCHASE ORDER 171 STACEY ROAD COXSACKIE, NY 12051 PHONE (518) 731-2791 . FAX (518) 731-6333 P.O. # FPU100957 Page 1 Change Sequence Supplier : S47031 NCEhWanPgUe RRCeHasAoSnE ORDER Order Date: 06-03-23 Buyer : Linda J Barley Phone : 518-731-4657 / 518-731-6333 Permit# Email : LBarley@ducommun.com Delivery Address Ducommun Aerostructures 171 Stacey Road VEOLIA NORTH AMERICA COXSACKIE 126 MORRIS RD. New York 12051 SCHENECTADY New York 12304 518-332-5529 Ref/Contact : Veolia ER standby a Request By : FPR020865/MCCOY Megan Pellam Ref : see attached BILL TO: DUCOMMUN AEROSTRUCTURES, ATTN: ACCOUNTS PAYABLE, 23301 WILMINGTON AVE, CARSON, CA 90745-6209 EMAIL FOR INVOICES ONLY : Accountspayable@ducommun.com If Ducommun pays for the freight cost per existing Purchase Order OR Agreement, AND has not specified a carrier on this order, for Less Than Truckload (LTL) or International Shipments, please contact your Ducommun location where the Purchase Order / Agreement originated and communicate the following: 1) Dimensions of shipment 2) Weight of the shipment 3) Class of Shipment and Description 4) When it is ready to be picked up 5) Your hours of operations for pick-up of shipment. A Ducommun contact will direct you with instructions. Please note, if the vendor of the Purchase Order or Agreement ships the product without consulting Ducommun, Ducommun has the right to reduce the invoice amount by the freight amount included on the vendor invoice. Ship Via On Site Service SBA Information : Terms of Payment 75 Net 75 Days Terms of Delivery SHP SHIPPING POINT Line Quantity Unit Item Seq Part Rev Description 10 1.0000 EA SAFETY RACK CLIPS 0 SAFETY SUPPLIES AND SERVICES SAFETY SUPPLIES Tax Account # Due on Dock Date N 531100 06/08/2023 Work Center F984 Unit Price 500.0000 Extension 500.0000 Emergency Response Cost & Procedures: 06/03/2023 12:16 pm ! 171 STACEY ROAD COXSACKIE, NY 12051 PHONE (518) 731-2791 . FAX (518) 731-6333 Change Sequence NCEhaWngPeURReCaHsAonSE ORDER PURCHASE ORDER P.O. # FPU100957 Page 2 Line Quantity Unit Item Seq Part Rev Description Tax Account # Due on Dock Date Unit Price Extension Veolia Environmental Services (Veolia) has the technical personnel and equipment capabilities to respond to Ducommun Aerostructures, Inc. emergency response needs. All waste disposal requirements can be managed according to the environmental services agreement to be completed for these services. Emergency Response Procedures In the event of a chemical spill or other emergency situation, it is important that pertinent information be accurately and efficiently relayed to VEOLIA personnel. Much time and money can be saved if the situation is assessed properly and the appropriate manpower and equipment are mobilized. The following steps should be taken when an employee is responding to a chemical spill/emergency and requests the services of VEOLIA. 1) If possible, identify the spilled chemical and quantity. Also note the location of the spill. 2) CALL VEOLIA AT 1-800-354-2382. Dial "1". 3) The information provided will be given to the "on-call" Veolia representative, who will initiate internal communications with Veolia operations personnel, and the response action will begin to develop. You will be contacted by a representative of Veolia with first response communications. 4) Once the level of response has been determined, the appropriate personnel and equipment will be mobilized. A subcontractor may be contacted to assist with the response. Emergency response equipment that will be on-site when a field crew is picking upchemicals. The following emergency response equipment is provided with each service vehicle at time of service: 85 gallon drum over pack Vermiculite Personal Protective Equipment (tyveks, gloves, boots, respirators) 06/03/2023 12:16 pm ! 171 STACEY ROAD COXSACKIE, NY 12051 PHONE (518) 731-2791 . FAX (518) 731-6333 Change Sequence NChEaWngPeURReCaHsoAnSE ORDER PURCHASE ORDER P.O. # FPU100957 Page 3 Line Quantity Unit Item Seq Part Rev Description Tax Account # Due on Dock Date Unit Price Extension ABC dry chemical fire extinguisher Fully equipped first aid kit including eye wash Drum opening tools, shovel, poly sheeting Empty containers pH paper to assess corrosivity Spare fuses, flashlights Reflective triangles Mobile phone Spill equipment available, if necessary, through the Emergency Response Clean-up Team (Subcontractor) Vacuum Truck Spill control trailer Special pumps and tools Large stock of absorbents (vermiculite, speedi-dry, booms, activated carbon, lime) Self-Contained Breathing Apparatus Earth excavation equipment and water-tight dump trailers Emergency Response Costs Annual Administrative Fee: $500.00 During normal business hours; Monday - Friday 8 am - 4 pm: 1,000.00 flat fee 115.00 per hour for a Field Supervisor 95.00 per hour for a Technician After normal business hours; Monday - Friday 5 pm - 7:59 am: 1,750.00 flat fee 172.50 per hour for a Field Supervisor 142.50 per hour for a Technician Sundays and Holidays: 2,250.00 flat fee 230.00 per hour for a Field Supervisor 190.00 per hour for a Technician 06/03/2023 12:16 pm ! 171 STACEY ROAD COXSACKIE, NY 12051 PHONE (518) 731-2791 . FAX (518) 731-6333 Change Sequence NChEaWngPeURReCaHsoAnSE ORDER PURCHASE ORDER P.O. # FPU100957 Page 4 Line Quantity Unit Item Seq Part Rev Description Tax Account # Due on Dock Date Unit Price Extension Goods $ 0.000 Costs 500.00 Tax $ 0.00 P.O. Total Signature $ 500.000 ! 06/03/2023 12:16 pm ! 171 STACEY ROAD COXSACKIE, NY 12051 PHONE (518) 731-2791 . FAX (518) 731-6333 Change Sequence NCEhWangPeURReCaHsAoSnE ORDER PURCHASE ORDER P.O. # FPU100957 Page 5 Line Quantity Unit Item Seq Part Rev Description Tax Account # Due on Dock Date Unit Price Extension Purchase Order Number and Line Number must appear on all shipping containers, packing lists, invoices, bills of lading & correspondence. Packing Lists Must Accompany Each Shipment. This Purchase Order is subject to Ducommun's terms and conditions dated 11/05/2020 as posted at http://www.ducommun.com/pdf/DCO_TC.pdf or you can request a copy from your buyer.Acceptance of the offer represented by this order is expressly limited to such terms & conditions without change or addition. The Seller's acknowledgment of this Order, commencement of work on the goods ordered or shipment of such goods, whichever occurs first, shall be deemed Seller's acceptance of the Order. This is the entire contract and any other terms or conditions proposed by Seller's acknowledgement shall not be binding upon Buyer. If applicable to the Order, please see http://www.ducommun.com/dco/supplierlinks.aspx or your buyer for a list of definition of Quality Clauses. You, the supplier, are required to flow down (all) purchase order requirements to your suppliers and they to their suppliers. Supplier Acknowledgement Printed Name, Signature and Date 06/03/2023 12:16 pm Coxsackie, New York Last Reviewed Date: 2/1/24 Work Instruction: WI-00237 RCRA Contingency Plan - EMS Revision No.: D Page: 25 of 33 Appendix 4.2 - Safety Data Sheets - to be posted at the end of the plan SAFETY DATA SHEET Issuing Date 30-Jul-2014 Revision Date 1-May-2015 #290 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING GHS product identifier Product Name Kolene Alko-NTM UN-Number UN1759 Recommended use of the chemical and restrictions on use Recommended Use In its molten state to condition surface scales and remove lubricants primarily from titanium components Uses advised against Avoid contact with aluminum, brass, bronze Supplier's details Supplier Address Kolene Corporation 12890 Westwood St. Detroit, MI TEL: 313 273-9220 Emergency telephone number Emergency Telephone Number CHEMTREC: 1-800-424-9300 Kolene Corporation (24 hour response) 313 273-9220 2. HAZARDS IDENTIFICATION Classification Acute Oral Toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Category 4 Category 1 Category 1 Subcategory 1A GHS Label elements, including precautionary statements Emergency Overview Signal Word Danger Hazard Statements Harmful if swallowed Causes severe skin burns and eye damage Appearance Colorless to white Physical State Solid bead/flake. Odor Odorless 2. HAZARDS IDENTIFICATION continued _____________________________________________________________________________________________ Page 1 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. General Advice Immediately call a POISON CENTER or doctor/physician. Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting. Storage Store locked up. Disposal Dispose of contents/container to an approved waste disposal plant. Hazard Not Otherwise Classified (HNOC) Not applicable Other information 0% of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Potassium hydroxide Potassium nitrate CAS-No 1310-58-3 7757-79-1 Weight % 75-85 15-25 * Where displayed, ranges reflect concentration variation from one product to another Trade secret * * 4. FIRST AID MEASURES _____________________________________________________________________________________________ Page 2 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Description of necessary first-aid measures Eye Contact Skin Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Consult a physician. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. Ingestion Drink plenty of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Immediate medical attention is required. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects No information available. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES ! SPECIAL FIREFIGHTING WARNING ! DO NOT USE WATER IN THE VICINITY OF THIS PRODUCT WHEN IN ITS MOLTEN STATE! Introduction of water or other volatile liquids on or in the molten salt bath may result in violent expulsion of the molten salt. Suitable Extinguishing Media This material is basically nonflammable and will not burn. Use water, CO2, or dry chemical extinguishers to fight fires in storage areas only. Unsuitable Extinguishing Media See warnings above. Specific Hazards Arising from the Chemical All water solutions of this product will be highly alkaline. Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge None. None. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. North American Emergency Response Guide No. 154. 6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 3 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Evacuate personnel to safe areas. Ensure adequate ventilation. In case of insufficient ventilation wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Environmental Precautions See Section 12 for additional Ecological Information. Methods and materials for containment and cleaning up Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. In case of accidental spill or leak, material should be shoveled up into steel containers for proper disposal. After cleaning, flush away traces with water. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Do not eat, drink or smoke when using this product. Do not take internally. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep containers tightly closed in a dry, cool and well-ventilated place. Reducing agents. Acids. Water. Organic material. Magnesium. Tin. Zinc. Aluminium. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name Potassium hydroxide 1310-58-3 Appropriate engineering controls ACGIH TLV Ceiling: 2 mg/m3 OSHA PEL (vacated) Ceiling: 2 mg/m3 NIOSH IDLH Ceiling: 2 mg/m3 Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Face-shield. Goggles. Respiratory Protection Manufacturer recommended gloves for handling corrosive materials should be worn. Impervious clothing. Safety shoes. Rubber boots. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES 9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________ Page 4 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Information on basic physical and chemical properties Physical State Odor Solid bead/flake Odorless Appearance Odor Threshold Colorless to white No information available Property Values pH Melting Point/Range 132C / 270F Boiling Point/Boiling Range 1390 C / 2534 F Flash Point None. Evaporation rate No data available Flammability (solid, gas) No data available Flammability Limits in Air upper flammability limit No data available lower flammability limit No data available Vapor Pressure Not applicable Vapor Density Not applicable Specific Gravity 2 g/cc (or ml) @ 20C Water Solubility Completely soluble Solubility in other solvents No data available Partition coefficient: n-octanol/waterNo data available Autoignition Temperature Nonflammable Decomposition Temperature No data available Viscosity No data available Flammable Properties Explosive Properties Oxidizing Properties Other information VOC Content (%) Not flammable No data available No data available No data available Remarks/ - Method All water solutions are strongly alkaline. None known None known None known None known None known None known None known None known None known None known None known None known None known None known 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Incompatible products. Incompatible materials Reducing agents. Acids. Water. Organic material. Magnesium. Tin. Zinc. Aluminium. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION _____________________________________________________________________________________________ Page 5 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Information on likely routes of exposure Product Information Inhalation Eye Contact Skin Contact Ingestion May cause irritation of respiratory tract. Causes serious eye damage. Corrosive to the eyes and may cause severe damage including blindness. Corrosive. Causes severe skin burns. Harmful if swallowed. Can burn mouth, throat, and stomach. Chemical Name Potassium hydroxide Potassium nitrate LD50 Oral = 214 mg/kg ( Rat ) = 3015 mg/kg ( Rat ) LD50 Dermal - LC50 Inhalation - Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization Mutagenic Effects Carcinogenicity No information available. No information available. Contains no ingredients above reportable quantities listed as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Potassium nitrate - - Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration Hazard No information available. No information available. No information available. Numerical measures of toxicity - Product Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document: LD50 Oral 567 mg/kg; Acute toxicity estimate 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Potassium hydroxide 1310-58-3 Persistence and Degradability Bioaccumulation Chemical Name Potassium hydroxide Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Toxicity to Fish Toxicity to Microorganisms LC50 96 h: = 80 mg/L static (Gambusia affinis) Daphnia Magna (Water Flea) No information available. Log Pow 0.83 No information available. _____________________________________________________________________________________________ Page 6 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Waste Disposal Methods Dispose of in accordance with federal, state, and local regulations Contaminated Packaging Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT UN-Number Proper shipping name Hazard Class Packing Group Description Emergency Response Guide UN1759 Corrosive solid, n.o.s. 8 II UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II 154 TDG UN-Number Proper Shipping Name Hazard Class Packing Group Description UN1759 Corrosive solid, n.o.s. 8 II UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II MEX UN-Number Proper Shipping Name Hazard Class Packing Group Description UN1759 Corrosive solid, n.o.s. 8 II UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II ICAO UN-Number Proper shipping name Hazard Class Packing Group Description UN1759 Corrosive solid, n.o.s. 8 II UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II IATA UN-Number Proper Shipping Name Hazard Class Packing Group ERG Code Description UN1759 Corrosive solid, n.o.s. 8 II 8L UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II IMDG/IMO UN-Number Proper Shipping Name Hazard Class Packing Group EmS No. Description UN1759 Corrosive solid, n.o.s. 8 II F-A, S-B UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II 14. TRANSPORT INFORMATION continued RID UN-Number UN1759 _____________________________________________________________________________________________ Page 7 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ Proper Shipping Name Corrosive solid, n.o.s. Hazard Class 8 Packing Group II Classification Code C10 Description UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II ADR UN-Number Proper Shipping Name Hazard Class Packing Group Classification Code Tunnel Restriction Code Description UN1759 Corrosive solid, n.o.s. 8 II C10 (E) UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II, (E) ADN Proper Shipping Name Hazard Class Packing Group Classification Code Special Provisions Description Limited Quantity Corrosive solid, n.o.s. 8 II C10 274 UN1759, Corrosive solid, n.o.s. (Potassium hydroxide), 8, II 1 kg 15. REGULATORY INFORMATION International Inventories TSCA DSL Complies Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No _____________________________________________________________________________________________ Page 8 / 9 Kolene Alko-NTM May 1 2015 _____________________________________________________________________________________________ 15. REGULATORY INFORMATION continued Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name Potassium hydroxide CWA - Reportable Quantities 1000 lb CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Potassium hydroxide Hazardous Substances RQs 1000 lb Extremely Hazardous Substances RQs RQ RQ 1000 lb final RQ RQ 454 kg final RQ U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Potassium hydroxide Potassium nitrate New Jersey X X Massachusetts X X Pennsylvania X X Illinois Rhode Island X X U.S. EPA Label Information EPA Pesticide Registration Number 16. OTHER INFORMATION Not applicable NFPA HMIS Health Hazard 3 Health Hazard 3 Flammability 0 Flammability 0 Instability 0 Physical Hazard 0 Physical and Chemical Hazards Personal Protection X Prepared By Issuing Date Revision Date Revision Note Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 30-Jul-2014 01-May-2015 Reformatted content JCMalloy Vice President - CTO General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9 Safety Data Sheet #224 Revision Number: 004.0 Issue date: 09/16/2015 1. PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Product type: Conversion coating Restriction of Use: None identified Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 IDH number: 594038 Region: United States Contact information: Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW MAY INTENSIFY FIRE; OXIDIZER. HARMFUL IF SWALLOWED. FATAL IN CONTACT WITH SKIN OR IF INHALED. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE CANCER. HAZARD CLASS OXIDIZING SOLID ACUTE TOXICITY ORAL ACUTE TOXICITY INHALATION ACUTE TOXICITY DERMAL SKIN CORROSION SERIOUS EYE DAMAGE SKIN SENSITIZATION CARCINOGENICITY SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE PICTOGRAM(S) HAZARD CATEGORY 2 4 2 2 1B 1 1 1A 3 Precautionary Statements Prevention: IDH number: 594038 Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat. Keep away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust or fumes. Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. Use personal protective equipment as required. [In case of inadequate ventilation] wear respiratory protection. Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Page 1 of 6 Response: Storage: Disposal: If SWALLOWED: Immediately call poison control or physician if you feel unwell. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical attention. Immediately call a poison control center or physician. If skin irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) Sodium borofluoride Chromium(VI) oxide Dipotassium hexafluorozirconate CAS Number 13755-29-8 1333-82-0 16923-95-8 Percentage* 30 - 60 30 - 60 10 - 30 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Symptoms: If inhaled, immediately remove the affected person to fresh air. If symptoms develop and persist, get medical attention. Remove contaminated clothing and footwear. For skin contact, flush with large amounts of water. Seek immediate medical attention. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Use media appropriate for surrounding material. Wear full protective clothing. Wear self-contained breathing apparatus. Oxidizing agent, may cause spontaneous ignition of combustible materials. Violent reactions may occur with organic materials or reducing agents. IDH number: 594038 Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Page 2 of 6 Hazardous combustion products: Irritating and toxic gases or fumes may be released during a fire. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate personal protective equipment. Do not allow product to enter sewer or waterways. Clean-up methods: Spills should be cleaned immediately to prevent dispersion of airborne dusts. Follow all local, state, federal and provincial regulations for disposal. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Avoid breathing dust. Wash thoroughly after handling. For industrial use only. Storage: Store in a cool, dry, well-ventilated area. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) Sodium borofluoride ACGIH TLV 2 mg/m3 TWA Inhalable fraction. 6 mg/m3 STEL Inhalable fraction. OSHA PEL None AIHA WEEL None OTHER None Chromium(VI) oxide Dipotassium hexafluorozirconate 0.05 mg/m3 TWA (as Cr) 5 mg/m3 TWA (as Zr) 10 mg/m3 STEL (as Zr) 2.5 mg/m3 TWA (as F) 0.005 mg/m3 TWA 0.0025 mg/m3 OSHA_ACT 0.1 mg/m3 Ceiling 5 mg/m3 PEL (as Zr) 2.5 mg/m3 PEL (as F) 2.5 mg/m3 TWA Dust. None None None None Engineering controls: Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided. Eye/face protection: Wear chemical goggles and face shield. Skin protection: Use of impervious apron and boots are recommended. Gloves should be tested to determine suitability for prolonged contact. Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: 9. PHYSICAL AND CHEMICAL PROPERTIES Solid Red-brown Bland Not available. 1.3 - 1.7 (2% solution) Not applicable Not applicable Not determined IDH number: 594038 Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Page 3 of 6 Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: Not applicable Not applicable Not applicable Not available. Not available. Not applicable Not applicable Moderate Not determined Not applicable Not available. Not available. 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: May liberate hydrogen fluoride. Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable materials. This product may react with strong alkalies. Reactivity: Not available. Conditions to avoid: This product is an OXIDIZING AGENT - avoid contact with organic material. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion IDH number: 594038 Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Page 4 of 6 Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Mists, vapors or liquid may cause severe irritation or burns. Prolonged or repeated breathing may cause ulceration of nasal membranes. Contact with broken skin may lead to formation of firmly marginated "chrome sores". Product contains chromium, which may cause an allergic skin sensitization reaction. Massive overexposures may lead to kidney failure and death. Following skin exposure to this product, the sensation of irritation or pain may be delayed. This product is severely irritating to the eyes and may cause irreversible damage including burns and blindness. This product may produce corrosive damage to the gastrointestinal tract if it is swallowed. Ingestion of small amounts of this product may result in potentially fatal hypocalcemia and systemic toxicity. Hazardous Component(s) Sodium borofluoride Chromium(VI) oxide Dipotassium hexafluorozirconate LD50s and LC50s None Oral LD50 (RAT) = 25 mg/kg Oral LD50 (RAT) = 29 mg/kg Oral LD50 (RAT) = 135 mg/kg Oral LD50 (RAT) = 80 mg/kg Dermal LD50 (RABBIT) = 30 mg/kg Inhalation LC50 (RAT, 4 h) = 0.087 mg/l Inhalation LC50 (RAT, 4 h) = 0.137 mg/l None Immediate and Delayed Health Effects Cardiac, Central nervous system, Developmental, Gastrointestinal, Irritant, Kidney, Metabolic, Reproductive Allergen, Blood, Central nervous system, Corrosive, Carcinogen, Developmental, Eyes, Gastrointestinal, Irritant, Kidney, Liver, Mutagen, Reproductive, Respiratory Allergen, Blood, Cardiac, Central nervous system, Corrosive, Gastrointestinal tract, Irritant, Kidney, Lung, Metabolic, Muscle, Teeth, Less weight gain and food intake. Hazardous Component(s) Sodium borofluoride Chromium(VI) oxide Dipotassium hexafluorozirconate NTP Carcinogen No Known To Be Human Carcinogen. No IARC Carcinogen No Group 1 No OSHA Carcinogen (Specifically Regulated) No Yes No 12. ECOLOGICAL INFORMATION Ecological information: No data available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. If discarded, this product is considered a RCRA ignitable waste, D001. This product contains chromium which is a hazardous waste (D007). 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Chromium trioxide, anhydrous Hazard class or division: 5.1 (6.1, 8) Identification number: UN 1463 Packing group: II DOT Hazardous Substance(s): Chromic acid, Zirconium potassium fluoride IDH number: 594038 Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Page 5 of 6 International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Chromium trioxide, anhydrous 5.1 (6.1, 8) UN 1463 II Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: CHROMIUM TRIOXIDE, ANHYDROUS 5.1 (6.1, 8) UN 1463 II 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. Chromium(VI) oxide (CAS# 1333-82-0). Chromium(VI) oxide (CAS# 1333-82-0). None above reporting de minimis Immediate Health, Delayed Health, Reactive This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Chromium(VI) oxide (CAS# 1333-82-0). Dipotassium hexafluorozirconate (CAS# 16923-95-8) 1,000 lbs. (454 kg) Chromium(VI) oxide (CAS# 1333-82-0) 10 lbs. (4.54 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes from the previous version in Section(s): 2, 4, 7 ,13 Prepared by: John DiCerbo, Sr. Regulatory Affairs Specialist Issue date: 09/16/2015 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 594038 Product name: BONDERITE M-CR 600 AERO known as ALODINE 600 Page 6 of 6 Safety Data Sheet #222 Revision Number: 005.0 Issue date: 04/04/2016 1. PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE M-CR 1200S AERO Product type: Conversion coating Restriction of Use: None identified Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 IDH number: 593964 Region: United States Contact information: Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW MAY INTENSIFY FIRE; OXIDIZER. HARMFUL IF SWALLOWED. FATAL IN CONTACT WITH SKIN OR IF INHALED. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE CANCER. OXIDIZING SOLID ACUTE TOXICITY ORAL ACUTE TOXICITY INHALATION ACUTE TOXICITY DERMAL SKIN CORROSION SERIOUS EYE DAMAGE SKIN SENSITIZATION CARCINOGENICITY HAZARD CLASS PICTOGRAM(S) HAZARD CATEGORY 2 4 2 2 1B 1 1 1A Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat. Keep away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust or fumes. Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. Use personal protective equipment as required. [In case of inadequate ventilation] wear respiratory protection. IDH number: 593964 Page 1 of 7 Product name: BONDERITE M-CR 1200S AERO Response: Storage: Disposal: If SWALLOWED: Immediately call poison control or physician if you feel unwell. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical attention. Immediately call a poison control center or physician. If skin irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) Chromium(VI) oxide Potassium tetrafluoroborate Tripotassium hexacyanoferrate Sodium fluoride Dipotassium hexafluorozirconate CAS Number 1333-82-0 14075-53-7 13746-66-2 7681-49-4 16923-95-8 Percentage* 30 - 60 10 - 30 10 - 30 5 - 10 5 - 10 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. Inhalation: Skin contact: Eye contact: Ingestion: Symptoms: Notes to physician: Extinguishing media: 4. FIRST AID MEASURES If inhaled, immediately remove the affected person to fresh air. If symptoms develop and persist, get medical attention. Remove contaminated clothing and footwear. For skin contact, flush with large amounts of water. Seek immediate medical attention. If irritation persists, repeat flushing and get medical attention. Discard any shoes or clothing items that cannot be decontaminated. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Get immediate medical attention. Do not induce vomiting. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. See Section 11. Ocular exposure to corrosive fluoride compounds has been treated with isotonic sodium chloride or magnesium chloride. Dermal exposure to corrosive fluoride compounds has been treated with calcium gluconate or calcium carbonate gel applied topically to the affected areas to relieve pain at the site of exposure. Treatment of hypocalcemia associated with corrosive fluoride compounds exposure may be corrected by intravenous calcium gluconate or calcium chloride. Treatment of hypomagnesemia may be corrected by intravenous magnesium sulfate. 5. FIRE FIGHTING MEASURES Use media appropriate for surrounding material. IDH number: 593964 Page 2 of 7 Product name: BONDERITE M-CR 1200S AERO Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Wear full protective clothing. Wear self-contained breathing apparatus. Oxidizing agent, may cause spontaneous ignition of combustible materials. Under fire conditions, decomposing material may form a hot, viscous foam. Violent reactions may occur with organic materials or reducing agents. Empty containers retain product residue, so obey hazard warnings and handle empty containers as if they were full. Irritating and toxic gases or fumes may be released during a fire. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Clean-up methods: Spills should be cleaned immediately to prevent dispersion of airborne dusts. Do not allow product to enter sewer or waterways. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Avoid breathing dust. Wash thoroughly after handling. For industrial use only. Storage: For safe storage, store between 5 C (41F) and 40 C (104F) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Store below 110 F (43.3 C). For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Chromium(VI) oxide Potassium tetrafluoroborate Tripotassium hexacyanoferrate Sodium fluoride Dipotassium hexafluorozirconate Engineering controls: 0.05 mg/m3 TWA (as Cr) 6 mg/m3 STEL Inhalable fraction. 2 mg/m3 TWA Inhalable fraction. None 2.5 mg/m3 TWA (as F) 5 mg/m3 TWA (as Zr) 10 mg/m3 STEL (as Zr) 2.5 mg/m3 TWA (as F) 0.005 mg/m3 TWA 0.0025 mg/m3 OSHA_ACT 0.1 mg/m3 Ceiling None None 2.5 mg/m3 PEL (as F) 2.5 mg/m3 TWA Dust. 5 mg/m3 PEL (as Zr) 2.5 mg/m3 PEL (as F) 2.5 mg/m3 TWA Dust. None None None None None None None None None None Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. IDH number: 593964 Page 3 of 7 Product name: BONDERITE M-CR 1200S AERO Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided. Eye/face protection: Wear chemical goggles or a full face shield. Skin protection: Chemical resistant, impermeable gloves. The use of butyl rubber gloves is recommended. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: Solid orange Bland Not available. 1.30 - 1.60 Not determined Not applicable Not available. Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Appreciable Not determined Not applicable Not available. Not available. 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: May liberate hydrogen fluoride. Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable materials. This product may react with strong alkalies. Reactivity: Not available. Conditions to avoid: Oxidizing agent, may cause spontaneous ignition of combustible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes IDH number: 593964 Page 4 of 7 Product name: BONDERITE M-CR 1200S AERO Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Mists, vapors or liquid may cause severe irritation or burns. Prolonged or repeated breathing may cause ulceration of nasal membranes. Contact with broken skin may lead to formation of firmly marginated "chrome sores". Product contains chromium, which may cause an allergic skin sensitization reaction. Massive overexposures may lead to kidney failure and death. Following skin exposure to this product, the sensation of irritation or pain may be delayed. This product is severely irritating to the eyes and may cause irreversible damage including burns and blindness. This product may produce corrosive damage to the gastrointestinal tract if it is swallowed. Ingestion of small amounts of this product may result in potentially fatal hypocalcemia and systemic toxicity. Hazardous Component(s) Chromium(VI) oxide Potassium tetrafluoroborate Tripotassium hexacyanoferrate Sodium fluoride Dipotassium hexafluorozirconate Hazardous Component(s) Chromium(VI) oxide Potassium tetrafluoroborate Tripotassium hexacyanoferrate Sodium fluoride Dipotassium hexafluorozirconate Ecological information: LD50s and LC50s Oral LD50 (Rat) = 25 mg/kg Oral LD50 (Rat) = 29 mg/kg Oral LD50 (Rat) = 135 mg/kg Oral LD50 (Mouse) = 80 mg/kg Oral LD50 (Rat) = 80 mg/kg Dermal LD50 (Rabbit) = 30 mg/kg Inhalation LC50 (Rat, 4 h) = 0.087 mg/l Inhalation LC50 (Rat, 4 h) = 0.137 mg/l None None Oral LD50 (Mouse) = 44.3 mg/kg Oral LD50 (Mouse) = 46.0 mg/kg Oral LD50 (Rat) = 32.0 mg/kg Oral LD50 (Rat) = 51.6 mg/kg Oral LD50 (Mouse) = 98 mg/kg Immediate and Delayed Health Effects Allergen, Blood, Central nervous system, Corrosive, Carcinogen, Developmental, Eyes, Gastrointestinal, Irritant, Kidney, Liver, Mutagen, Reproductive, Respiratory Cardiac, Central nervous system, Developmental, Gastrointestinal, Irritant, Kidney, Metabolic, Reproductive Cellular Blood, Cardiac, Central nervous system, Corrosive, Gastrointestinal tract, Irritant, Kidney, Metabolic, Muscle, Teeth, Less weight gain and food intake. Allergen, Blood, Cardiac, Central nervous system, Corrosive, Gastrointestinal tract, Irritant, Kidney, Lung, Metabolic, Muscle, Teeth, Less weight gain and food intake. NTP Carcinogen Known To Be Human Carcinogen. No No No No IARC Carcinogen Group 1 No No No No OSHA Carcinogen (Specifically Regulated) Yes No No No No 12. ECOLOGICAL INFORMATION Harmful to aquatic organisms. IDH number: 593964 Page 5 of 7 Product name: BONDERITE M-CR 1200S AERO 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. This product contains chromium which is a hazardous waste (D007). If discarded, this product is considered a RCRA ignitable waste, D001. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Chromium trioxide, anhydrous Hazard class or division: 5.1 (6.1, 8) Identification number: UN 1463 Packing group: II DOT Hazardous Substance(s): Chromic acid, Sodium fluoride International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Chromium trioxide, anhydrous 5.1 (6.1, 8) UN 1463 II Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Marine pollutant: CHROMIUM TRIOXIDE, ANHYDROUS 5.1 (6.1, 8) UN 1463 II Chromium trioxide 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. Chromium(VI) oxide (CAS# 1333-82-0). None above reporting de minimis. Immediate Health, Delayed Health, Reactive This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Chromium(VI) oxide (CAS# 1333-82-0). Chromium(VI) oxide (CAS# 1333-82-0) 10 lbs. (4.54 kg) Sodium fluoride (CAS# 7681-49-4) 1,000 lbs. (454 kg) Dipotassium hexafluorozirconate (CAS# 16923-95-8) 1,000 lbs. (454 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. IDH number: 593964 Page 6 of 7 Product name: BONDERITE M-CR 1200S AERO 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New information added in Section(s): 14 Prepared by: Jennifer Mckay, Regulatory Affairs Specialist Issue date: 04/04/2016 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 593964 Page 7 of 7 Product name: BONDERITE M-CR 1200S AERO Safety Data Sheet Revision Number: 005.0 Issue date: 07/06/2015 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product type: Restriction of Use: Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Rust dissolver None identified 06067 IDH number: 594403 Item number: 594403 Region: United States Contact information: Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW TOXIC IF SWALLOWED OR IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. HARMFUL IF INHALED. MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE CANCER. HAZARD CLASS ACUTE TOXICITY ORAL ACUTE TOXICITY INHALATION ACUTE TOXICITY DERMAL SKIN CORROSION SERIOUS EYE DAMAGE SKIN SENSITIZATION CARCINOGENICITY SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE PICTOGRAM(S) HAZARD CATEGORY 3 4 3 1A 1 1 1A 3 Precautionary Statements Prevention: Response: IDH number: 594403 Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe vapors, mist, or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. Use personal protective equipment as required. IF SWALLOWED: Immediately call a physician or poison control center. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Product name: BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Page 1 of 6 Storage: Disposal: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical attention. Immediately call a poison control center or physician. If skin irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) Chromic acid Hydrogen fluoride CAS Number 7738-94-5 7664-39-3 Percentage* 10 - 30 5 - 10 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Symptoms: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Rinse with large amounts of running water. GET MEDICAL ATTENTION IMMEDIATELY! If iced 0.13% benzalkonium chloride (Zephiran) solution or 2.5% calcium gluconate gel are available, the rinsing may be limited to 5 minutes, with the soaks or gel applied as soon as the rinsing is stopped. If benzalkonium chloride or calcium gluconate gel is not available, rinsing must continue until medical treatment is provided. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Get immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. See Section 11. Notes to physician: Ocular exposure to corrosive fluoride compounds has been treated with isotonic sodium chloride or magnesium chloride. Dermal exposure to corrosive fluoride compounds has been treated with calcium gluconate or calcium carbonate gel applied topically to the affected areas to relieve pain at the site of exposure.Treatment of hypocalcemia associated with corrosive fluoride compounds exposure may be corrected by intravenous calcium gluconate or calcium chloride. Treatment of hypomagnesemia may be corrected by intravenous magnesium sulfate. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Use media appropriate for surrounding material. Wear full protective clothing. Wear self-contained breathing apparatus. Unusual fire or explosion hazards: If evaporated to dryness, solid residue is an oxidizing agent and may cause spontaneous ignition of combustible materials. IDH number: 594403 Product name: BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Page 2 of 6 Hazardous combustion products: Flammable and explosive hydrogen gas may be formed when hydrofluoric acid reacts with certain metals. Hydrogen fluoride gas may evolve when chemical is subjected to prolonged high temperature. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear suitable protective clothing, gloves and eye/face protection. Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. Do not allow product to enter sewer or waterways. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of this product. Wash thoroughly after handling. For industrial use only. Use caution when combining with water; DO NOT add water to acid, ALWAYS add acid to water while stirring to prevent release of heat, steam and fumes. Storage: For safe storage, store at or above 40 F (4.4 C) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Thaw and mix thoroughly if frozen. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Chromic acid Hydrogen fluoride Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: 0.05 mg/m3 TWA (as Cr) 2 ppm Ceiling (as F) 0.5 ppm TWA (as F) (SKIN) (as F) 0.005 mg/m3 TWA 0.0025 mg/m3 OSHA_ACT 0.1 mg/m3 Ceiling 2.5 mg/m3 PEL (as F) 3 ppm TWA None None None None Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Red Sharp Not available. < 1 Not determined IDH number: 594403 Product name: BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Page 3 of 6 Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: > 100 C (> 212F) 0 F (-17.8 C) 1.14 - 1.17 Not determined Not applicable Not applicable Not applicable Not applicable Not determined Complete Not determined Not applicable Not available. Not available. 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: May liberate hydrogen fluoride. Decomposes with heat to produce oxides of nitrogen. Incompatible materials: Reacts with cyanides and sulfides to cause the release of poisonous gases. This material will react with glass, concrete, certain metals, silica containing materials, rubber, leather, and many organics. Avoid contact with organic materials, oils, greases, and any oxidizable materials. This product may react with strong alkalies. Reactivity: Not available. Conditions to avoid: Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes IDH number: 594403 Product name: BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Page 4 of 6 Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Mists, vapors or liquid may cause severe irritation or burns. Contact with broken skin may lead to formation of firmly marginated "chrome sores". Product contains chromium, which may cause an allergic skin sensitization reaction. Massive overexposures may lead to kidney failure and death. Following skin exposure to this product, the sensation of irritation or pain may be delayed. A component in this product may be harmful or fatal if absorbed through the skin, especially if skin is damaged. This product is severely irritating to the eyes and may cause irreversible damage including burns and blindness. This product may produce corrosive damage to the gastrointestinal tract if it is swallowed. Ingestion of small amounts of this product may result in potentially fatal hypocalcemia and systemic toxicity. Hazardous Component(s) Chromic acid Hydrogen fluoride LD50s and LC50s None Inhalation LC50 (RAT, 15 min) = 2689 ppm Inhalation LC50 (RAT, 1 h) = 1278 ppm Inhalation LC50 (RAT, 30 min) = 2042 ppm Inhalation LC50 (RAT, 5 min) = 4970 ppm Immediate and Delayed Health Effects Allergen, Blood, Carcinogen, Central nervous system, Corrosive, Developmental, Eyes, Gastrointestinal, Irritant, Kidney, Liver, Mutagen, Reproductive, Respiratory Allergen, Blood, Bone Marrow, Cardiac, Central nervous system, Corrosive, Irritant, Kidney, Liver, Lung, Muscle, Nervous System, Respiratory, Teeth Hazardous Component(s) Chromic acid Hydrogen fluoride NTP Carcinogen Known To Be Human Carcinogen. No IARC Carcinogen No No OSHA Carcinogen (Specifically Regulated) Yes No 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. This product, if discarded directly, would be a characteristic RCRA corrosive waste (D002). This product contains chromium which is a hazardous waste (D007). This product contains a component or components identified as hazardous under 40 CFR 261.24. U134: Hydrogen fluoride 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Corrosive liquids, toxic, n.o.s. (Hydrofluoric acid, Chromic acid) Hazard class or division: 8 (6.1) Identification number: UN 2922 Packing group: II DOT Hazardous Substance(s): Chromic acid, Hydrofluoric acid IDH number: 594403 Product name: BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Page 5 of 6 International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Corrosive liquid, toxic, n.o.s. 8 (6.1) UN 2922 II (Hydrofluoric acid, Chromic acid) Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Additional information: CORROSIVE LIQUID, TOXIC, N.O.S. (Hydrofluoric acid, Chromic acid) 8 (6.1) UN 2922 II IMDG-Code: Segregation group 1- Acids 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. Chromic acid (CAS# 7738-94-5). Hydrogen fluoride (CAS# 7664-39-3). Immediate Health, Delayed Health, Reactive This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Chromic acid (CAS# 7738-94-5). Hydrogen fluoride (CAS# 7664-39-3). Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg) Hydrogen fluoride (CAS# 7664-39-3) 100 lbs. (45.4 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New information added in Section(s): 1, 7, 9, 12 and 13. Prepared by: John DiCerbo, Sr. Regulatory Affairs Specialist Issue date: 07/06/2015 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Distributed by: Rudolph Bros. & Co. 6550 Oley Speaks Way Canal Winchester, OH 43110 Phone: 614-833-0707 Fax: 800-600-9508 e-mail: rbcsupport@rudbro.com www.rudbro.com IDH number: 594403 Product name: BONDERITE C-IC DEOXDZR 16R AERO known as TURCO DEOXIDIZER 16 REPL Page 6 of 6 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Hydrofluoric Acid, Aqueous (70%) Print Date 01/24/2017 Number : Product Use Description : Note : Manufacturer or supplier's : details For more information call : In case of emergency call : : : : 000000001807 Chemical-Technical application Synonyms: HF, Anhydrous HF, AHF, Hydrogen Fluoride, HF Acid For additional information, please visit http://www.HFacid.com (available 24 hours/day, 7days/week). Brainerd Chemical 1600 South Wilson Ave Dunn, North Carolina 28334 800-522-8001 +1-910-980-1088 (Monday-Friday, 8:00am-5:00pm) Transportation (CHEMTREC): 1-800-424-9300 (24 hours/day, 7 days/week) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : liquid Color : colourless Odor : stinging Classification of the substance or mixture Classification of the substance or mixture : Corrosive to metals, Category 1 Acute toxicity, Category 2, Oral Acute toxicity, Category 2, Inhalation Acute toxicity, Category 1, Dermal Skin corrosion, Category 1A Serious eye damage, Category 1 Page 1 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 GHS Label elements, including precautionary statements Symbol(s) : Print Date 01/24/2017 Signal word Hazard statements Precautionary statements : Danger : May be corrosive to metals. Fatal if swallowed, in contact with skin or if inhaled Causes severe skin burns and eye damage. : Prevention: Keep only in original container. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Do not get in eyes, on skin, or on clothing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing. Wear eye protection/ face protection. Wear respiratory protection. Response: IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Keep only in original container. Disposal: Dispose of contents/ container to an approved waste disposal plant. Page 2 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 Hazards not otherwise classified : Causes severe burns which may not be immediately painful or visible. May cause hypocalcemia (depletion of calcium in the body) which may be fatal. Specialized medical treatment is required for all exposures. Carcinogenicity No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Mixture Chemical name Hydrofluoric acid Water CAS-No. 7664-39-3 7732-18-5 Concentration 70.00 % 30.00 % SECTION 4. FIRST AID MEASURES Inhalation Skin contact : Remove to fresh air. Keep patient warm and at rest. Get competent medical attention immediately. If breathing has stopped, start artificial respiration at once. An authorized person should administer oxygen to a victim who is having difficulty breathing, until the victim is able to breathe easily by himself. Calcium gluconate, 2.5% in normal saline may be given by nebulizer with oxygen. Do not give stimulants unless instructed to do so by a physician. Victim should be examined by a physician and held under observation for at least 24 hours. : Remove the victim from the contaminated area and immediately wash the burned area with plenty of water for a minimum of 15 minutes. Limit washing to 5 minutes if treatment specific for HF exposure is available. Remove all contaminated clothing while washing continuously. After thorough washing for at least 5 minutes, the burned area should be immersed in Page 3 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 a solution of 0.13% iced aqueous Benzalkonium Chloride until pain is relieved. As an alternate first aid treatment, 2.5% calcium gluconate gel may be continuously massaged into the burn area until the pain is relieved. For burns not responsive to topical treatment (as measured by pain being present for longer than 30 minutes) a physician may inject 2.5% - 5% aqueous calcium gluconate beneath, around and in the burned area. Use of local anesthetics is not recommended, as reduction in pain is an indicator of effectiveness of treatment. Eye contact : Immediately flush the eyes for at least 15 minutes with large amounts of gently flowing water. Hold the eyelids open and away from the eye during irrigation to allow thorough flushing of the eyes. Do not use the benzalkonium chloride (Zephiran) solutions described for skin treatment. If the person is wearing contact lenses, the lenses should be removed, if possible. However, flushing with water should not be interrupted, and the lenses should be removed by a person who is qualified to do so. If sterile 1% calcium gluconate solution is available, water washing may be limited to 5 minutes, after which the 1% calcium gluconate solution should be used to irrigate the eye using a syringe or a continuous irrigation device. Take the victim to a doctor, preferably an eye specialist, as soon as possible. Ice water compresses may be applied to the eyes while transporting the victim to the doctor. If a physician is not immediately available, apply one or two drops of 0.5% tetracaine hydrochloride, 0.5% proparacaine, or other aqueous, topical ophthalmic anesthetic and continue irrigation. Use no other medications unless instructed to do so by a physician. Rubbing of the eyes is to be avoided. . Ingestion Notes to physician Treatment : Have the victim drink several large glasses of water or milk to dilute the acid. Do not induce vomiting. Do not give emetics or baking soda. Never give anything by mouth to an unconscious person. Give several glasses of milk or several ounces of milk of magnesia, any calcium containing antacid or grind up and administer up to 30 antacid tablets with water. The calcium or magnesium in these compounds may act as an antidote; however this has not been supported in the literature. Get immediate medical attention. Ingestion of HF is a lifethreatening emergency. : For large skin area burns (totaling greater than 25 square inches), for ingestion and for significant inhalation exposure, Page 4 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 severe systemic effects may occur. Monitor and correct for hypocalcemia, cardiac arrhythmias, hypomagnesemia and hyperkalemia. In some cases hemodialysis may be indicated. For certain burns, especially of the digits, use of intra-arterial calcium gluconate may be indicated. For inhalation exposures, treat as chemical pneumonia. Monitor for hypocalcemia. 2.5% calcium gluconate in normal saline by nebulizer or by intermittent positive pressure breathing with 100% oxygen may decrease pulmonary damage. Bronchodilators may also be administered. A booklet titled "Recommended Medical Treatment for Hydrofluoric Acid Exposure" is available from the Honeywell HF website: http://www.HFacid.com. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Foam Carbon dioxide (CO2) Dry chemical On dilution or dissolving in water, considerable heating always occurs. Contact with a relatively small quantity of water creates violent reaction generating much heat and spattering of hot acid If use of water is necessary use copious amounts Specific hazards during firefighting : Fire or intense heat may cause violent rupture of packages. Use a water spray to cool fully closed containers. Reacts violently with water. Do not direct water spray at the point of leakage. Contact with metals liberates hydrogen gas. Hydrogen gas is flammable and may form an explosive atmosphere. Diking with silicon materials is to be avoided. May form Silicon tetrafluoride gas. Special protective equipment for firefighters : Personal protection through wearing a tightly closed chemical protection suit and a self-contained breathing apparatus. No unprotected exposed skin areas. Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Page 5 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Immediately evacuate personnel to safe areas. Immediately contact emergency personnel. Ensure all affected individuals are in a safe environment. Wear personal protective equipment. Unprotected persons must be kept away. Keep people away from and upwind of spill/leak. Personal protection through wearing a tightly closed chemical protection suit and a self-contained breathing apparatus. Ensure all equipment (including Personal Protective Equipment (PPE)) is compatible with Hydrofluoric acid (HF). Environmental precautions : Prevent further leakage or spillage if safe to do so. Discharge into the environment must be avoided. Do not flush into surface water or sanitary sewer system. Do not allow run-off from fire fighting to enter drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities. Methods for cleaning up : Prevent spreading over a wide area (e.g. by containment or oil barriers). Diking with silicon materials is to be avoided. May form Silicon tetrafluoride gas. Suppress (knock down) gases/vapours/mists with a water spray (fog ). Do not direct water spray at the point of leakage. Use water spray cautiously and in large quantities. With acids neutralization takes place under development of heat. Do not pick up with the help of saw-dust or other combustible substances. Neutralize acidity with an appropriate alkaline material. Neutralize with caustics, lime, soda ash, baking soda or other appropriate alkaline material. Pay attention to the incompatibility statements in Section 10 when effecting neutralization. SECTION 7. HANDLING AND STORAGE Handling Handling : Wear personal protective equipment. Exhaust ventilation at the object is necessary. Ensure all equipment (including Personal Protective Equipment Page 6 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 (PPE)) is compatible with Hydrofluoric acid (HF). Perform filling operations only at stations with exhaust ventilation facilities. Specialized medical treatment is required for all exposures. Plan first aid action before beginning work with this product. When diluting, add acids to water, never the other way around. Do not swallow. Do not breathe vapours or spray mist. Do not get in eyes, on skin, or on clothing. Advice on protection against fire and explosion : No special precautions required. Storage Requirements for storage areas and containers : Keep containers tightly closed in a cool, well-ventilated place. Store in a place accessible by authorized persons only. Store away from incompatible substances. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective measures : Ensure that eyewash stations and safety showers are close to the workstation location. Plan first aid action before beginning work with this product. Ensure all equipment (including Personal Protective Equipment (PPE)) is compatible with Hydrofluoric acid (HF). Engineering measures : Use with local exhaust ventilation. Apply technical measures to comply with the occupational exposure limits. Eye protection : Wear as appropriate: Goggles or face shield, giving complete protection to eyes Hand protection : Protective gloves Gloves must be inspected prior to use. Replace when worn. Skin and body protection : Wear suitable protective equipment. complete suit protecting against chemicals Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Use NIOSH approved respiratory protection. Have available emergency self-contained breathing apparatus or full-face airline respirator when using this chemical. Hygiene measures : When using, do not eat, drink or smoke. Page 7 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 Provide adequate ventilation. Keep working clothes separately. Contaminated work clothing should not be allowed out of the workplace. Do not swallow. Do not breathe vapours or spray mist. Do not get in eyes, on skin, or on clothing. This material has an established AIHA ERPG exposure limit. The current list of ERPG exposure limits can be found at http://www.aiha.org/insideaiha/Gui deli ne De vel opm ent/ERPG/D ocuments/2011erpgweelhandbook_table -only.pdf. Exposure Guidelines Components CAS-No. Value Hydrofluoric acid Further : information 7664-39-3 TWA : Time weighted average Expressed as : as F Control parameters (0.5 ppm) Upda te 2008 Basis ACGIH:US. ACGIH Threshold Limit Values Hydrofluoric acid 7664-39-3 SKIN_DE S : Skin designati on: Can be absorbed through the skin. 2008 ACGIH:US. ACGIH Threshold Limit Values Further information : Expressed as : as F Hydrofluoric acid Further : information 7664-39-3 Ceiling : Ceiling Limit Value: Expressed as : as F (2 ppm) 2008 ACGIH:US. ACGIH Threshold Limit Values Hydrofluoric acid 7664-39-3 Conc : Concentr ation: (30 ppm) NIOSH IDLH (Immediately Dangerous to Life or Health Concentrations) 2005 NIOSH/GUIDE:US. NIOSH: Pocket Guide to Chemical Hazards Page 8 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Hydrofluoric acid 7664-39-3 Revision Date 05/19/2016 REL : 2.5 mg/m3 Recomm (3 ppm) ended exposure limit (REL): Hydrofluoric acid 7664-39-3 Ceil_Tim e : Ceiling Limit Value and Time Period (if specified) : 5 mg/m3 (6 ppm) Hydrofluoric acid 7664-39-3 PEL : Permissi ble exposure limit 2.5 mg/m3 Further information : Expressed as : as F Hydrofluoric acid Further : information 7664-39-3 TWA : Time weighted average Expressed as : as F (3 ppm) Hydrofluoric acid Further : information 7664-39-3 STEL : Short term exposure limit Expressed as : as F (6 ppm) Hydrofluoric acid 7664-39-3 TWA : Time weighted average (3 ppm) 2005 Print Date 01/24/2017 NIOSH/GUIDE:US. NIOSH: Pocket Guide to Chemical Hazards 2005 NIOSH/GUIDE:US. NIOSH: Pocket Guide to Chemical Hazards 02 2006 OSHA_TRANS:US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 1989 Z1A:US. OSHA Table Z-1-A (29 CFR 1910.1000) 1989 Z1A:US. OSHA Table Z-1-A (29 CFR 1910.1000) 02 2006 OSHA/Z2:US. OSHA Table Z-2 (29 CFR 1910.1000) Page 9 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Color : colourless Odor : stinging pH : Note: acidic Freezing point : ca. -76 C Boiling point/boiling range : ca. 65 C at 1,013 hPa Flash point : Note: Not applicable Print Date 01/24/2017 Lower explosion limit Upper explosion limit Vapor pressure Vapor density Density Water solubility : Note: Not applicable : Note: Not applicable : 183 hPa at 21.1 C(70.0 F) : 2.21 at 21.1 C 1.76 at 26.7 C : ca. 1.230 g/cm3 at 20 C : Note: completely miscible Ignition temperature Decomposition temperature : Note: Not applicable : Note: Fire or intense heat may cause violent rupture of packages. Page 10 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Corrosivity Revision Date 05/19/2016 : Note: Corrosive to metals Print Date 01/24/2017 SECTION 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Incompatible materials to avoid Hazardous decomposition products : Stable under normal conditions. : Hazardous polymerisation does not occur. : Glass and silicate-containing materials are attacked. HF contact with glass, concrete and other silicon bearing materials will yield silicon tetrafluoride gas. Pressure buildup from this process has been known to rupture glass containers. . HF contact with carbonates, sulfides and cyanides yield toxic gases such as carbon dioxide, hydrogen sulfide and hydrogen cyanide. Contact with alkalies and some oxides cause strong violent exothermic reactions. Contact with metals will yield hydrogen gas, a fire and explosive reactive hazard. On dilution or dissolving in water, considerable heating always occurs. When diluting, add acids to water, never the other way around. : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation Hydrofluoric acid : Acute toxicity estimate: 7.14 mg/kg Method: Calculation method : Acute toxicity estimate: 0.76 mg/l , vapour Exposure time: 4 h Method: Calculation method : Acute toxicity estimate: 7.14 mg/kg Method: Calculation method : Species: Rabbit Classification: Corrosive Page 11 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Method: OECD Print Date 01/24/2017 Further information : Note: Causes severe burns which may not be immediately painful or visible.The potential delay in clinical signs or symptoms for dilute solutions is given below. HF Concentration (Delay in Symptoms) >50% (Immediately Apparent) 20%-50% (1-8 hours) 0%-20% (Up to 24 hours)Symptoms might include pain, redness of the skin and possible tissue destruction.Hydrofluoric Acid will penetrate skin and attack underlying tissues.May cause hypocalcemia (depletion of calcium in the body) which may be fatal.Chronic exposure to fluoride has been reported to result in tooth mottling in children, bone fluorosis, and sometimes osteosclerosis in adults and children. SECTION 12. ECOLOGICAL INFORMATION Toxicity to fish Hydrofluoric acid : LC50: 107.5 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Test substance: Fluoride ion LC50: 925 mg/l Exposure time: 96 h Species: Gambusia affinis (Mosquito fish) Test substance: Fluoride ion Toxicity to daphnia and other aquatic invertebrates Hydrofluoric acid : EC50: 270 mg/l Exposure time: 48 h Species: Daphnia (water flea) Test substance: Sodium fluoride Further information on ecology Page 12 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods : Observe all Federal, State, and Local Environmental regulations. SECTION 14. TRANSPORT INFORMATION DOT UN/ID No. Proper shipping name Class Packing group Hazard Labels : UN 1790 : Hydrofluoric acid 8 I 8 (6.1) IATA IMDG UN/ID No. Description of the goods Class Packaging group Hazard Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) UN/ID No. Description of the goods Class Packaging group Hazard Labels EmS Number Marine pollutant : UN 1790 : Hydrofluoric acid : 8 : I : 8 (6.1) : 854 : 850 : UN 1790 : Hydrofluoric acid : 8 : I : 8 (6.1) : F-A, S-B : no SECTION 15. REGULATORY INFORMATION Inventories US. Toxic Substances Control Act Australia. Industrial Chemical (Notification and Assessment) Act Canada. Canadian : On TSCA Inventory : On the inventory, or in compliance with the inventory : All components of this product are on the Canadian DSL Page 13 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Environmental Protection Act (CEPA). Domestic Substances List (DSL) Revision Date 05/19/2016 Print Date 01/24/2017 Japan. Kashin-Hou Law List : On the inventory, or in compliance with the inventory Korea. Toxic Chemical Control Law (TCCL) List : On the inventory, or in compliance with the inventory Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act : On the inventory, or in compliance with the inventory China. Inventory of Existing : On the inventory, or in compliance with the inventory Chemical Substances NZIOC - New Zealand : On the inventory, or in compliance with the inventory National regulatory information US. EPA CERCLA Hazardous Substances (40 CFR 302) : The following component(s) of this product is/are subject to release reporting under 40 CFR 302 when release exceeds the Reportable Quantity (RQ): Reportable quantity: 100 lbs : Hydrogen fluoride 7664-39-3 SARA 302 Components : The following components are subject to reporting levels established by SARA Title III, Section 302: : Hydrofluoric acid 7664-39-3 SARA 313 Components : The following components are subject to reporting levels established by SARA Title III, Section 313: : Hydrofluoric acid 7664-39-3 SARA 311/312 Hazards : Acute Health Hazard Chronic Health Hazard CERCLA Reportable Quantity : 143 lbs Page 14 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 California Prop. 65 Revision Date 05/19/2016 Print Date 01/24/2017 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Massachusetts RTK New Jersey RTK Pennsylvania RTK WHMIS Classification : Hydrofluoric acid 7664-39-3 : Hydrofluoric acid 7664-39-3 : Hydrofluoric acid 7664-39-3 : D1A: Very Toxic Material Causing Immediate and Serious Toxic Effects D2A: Very Toxic Material Causing Other Toxic Effects E: Corrosive Material This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. SECTION 16. OTHER INFORMATION Health hazard Flammability Physical Hazard Instability HMIS III : 4* : 0 : 1 : NFPA 4 0 1 * - Chronic health hazard Hazard rating and rating systems (e.g. HMIS III, NFPA): This information is intended solely for the use of individuals trained in the particular system. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportat ion, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any Page 15 / 16 SAFETY DATA SHEET Hydrofluoric Acid, Aqueous (70%) 000000001807 Version 3.6 Revision Date 05/19/2016 Print Date 01/24/2017 material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties. Changes since the last version are highlighted in the margin. This version replaces all previous versions. Previous Issue Date: 11/06/2015 Page 16 / 16 Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : NITRIC ACID 42 BAUM Recommended use of the chemical and restrictions on use Recommended use : Industrial chemical Manufacturer or supplier's details Company : Univar Solutions USA, Inc. Address 3075 Highland Pkwy Suite 200 Downers Grove, IL 60515 United States of America (USA) Emergency telephone number: Transport North America: CHEMTREC (1-800-424-9300) CHEMTREC INTERNATIONAL Tel # 703-527-3887 Additional Information: : Responsible Party: Product Compliance Department E-mail: SDSNA@univarsolutions.com SDS Requests: 1-855-429-2661 Website: www.univarsolutions.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Oxidizing liquids Corrosive to metals Acute toxicity (Inhalation) Skin corrosion Serious eye damage : Category 3 : Category 1 : Category 3 : Category 1A : Category 1 GHS label elements Hazard pictograms : Signal word Hazard statements Precautionary statements SDS Number: 100000005010 : Danger : H272 May intensify fire; oxidizer. H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. : Prevention: P210 Keep away from heat. P220 Keep/ Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. 1 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 P234 Keep only in original container. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P390 Absorb spillage to prevent material damage. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P406 Store in corrosive resistant container with a resistant inner liner. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components CAS-No. Chemical name 7697-37-2 Nitric acid Any Concentration shown as a range is due to batch variation. Weight percent 50 - 70 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. SDS Number: 100000005010 2 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 If inhaled In case of skin contact In case of eye contact If swallowed : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. Move to fresh air. : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes. Wash contaminated clothing before re-use. Thoroughly clean shoes before reuse. : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Take victim immediately to hospital. : Clean mouth with water and drink afterwards plenty of water. Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion prod- : Nitrogen oxides (NOx) ucts Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. SDS Number: 100000005010 3 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 Use a water spray to cool fully closed containers. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Keep away from combustible material. Advice on safe handling : Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : Do not store near acids. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters CAS-No. Components Value type Control parame- Basis SDS Number: 100000005010 4 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 7697-37-2 Nitric acid Personal protective equipment Respiratory protection (Form of exposure) TWA STEL ST TWA TWA TWA STEL ters / Permissible concentration 2 ppm 4 ppm 4 ppm 10 mg/m3 2 ppm 5 mg/m3 2 ppm 5 mg/m3 2 ppm 5 mg/m3 4 ppm 10 mg/m3 ACGIH ACGIH NIOSH REL NIOSH REL OSHA Z-1 OSHA P0 OSHA P0 : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. In the case of vapour formation use a respirator with an approved filter. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid SDS Number: 100000005010 5 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 Colour Odour Odour Threshold pH Freezing Point (Freezing Point) Boiling Point (Boiling point/boiling range) Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density Density Solubility(ies) Water solubility Solubility in other solvents Partition coefficient: noctanol/water Auto-ignition temperature Thermal decomposition Viscosity Viscosity, dynamic : Clear, Colorless, light yellow, brown : pungent, Acrid : 0.75 - 2.5 ppm : <1 : -41 - -20 C (-42 - -4 F) : 117 - 120 C (243 - 248 F) : Not applicable : 1 (Butyl Acetate = 1) : No data available : No data available : No data available : 7 - 8 mmHg @ 20 C (68 F) 9 - 10 mmHg @ 25 C (77 F) : > 1(Air = 1.0) : 1.3551 - 1.4078 @ 20 - 25 C (68 - 77 F) Reference substance: (water = 1) : 1.35 - 1.48 g/cm3 @ 20 C (68 F) : soluble : No data available : log Pow: -2.3 : No data available : 110 C : 2 - 2.2 cps @ 20 - 25 C (68 - 77 F) SECTION 10. STABILITY AND REACTIVITY SDS Number: 100000005010 6 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : No dangerous reaction known under conditions of normal use. : Stable under normal conditions. : Corrosive in contact with metals Attacks many metals producing extremely flammable hydrogen gas which can form explosive mixtures with air. : Keep away from heat, flame, sparks and other ignition sources. Exposure to light. Exposure to moisture : Acetic anhydride Alcohols Alkali metals Bases carbide Carbon steel chlorates Chromic acid Combustible material Copper Cyanides Metals Organic materials Reducing agents sulfides water halogens : corrosive vapors Nitrogen oxides (NOx) Ammonia Amines SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute inhalation toxicity : Assessment: The component/mixture is toxic after short term inhalation. Components: 7697-37-2: Acute inhalation toxicity : LC50 (Rat, male and female): 2500 ppm Exposure time: 1 h Test substance: nitric acid Assessment: The component/mixture is toxic after short term SDS Number: 100000005010 7 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 inhalation. Revision Date: 08/02/2022 Skin corrosion/irritation Product: Remarks: Extremely corrosive and destructive to tissue. Components: 7697-37-2: Species: Rabbit Result: Causes severe burns. Serious eye damage/eye irritation Product: Remarks: May cause irreversible eye damage. Components: 7697-37-2: Species: Rabbit Result: Risk of serious damage to eyes. Carcinogenicity IARC OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is on OSHA's list of regulated carcinogens. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity No data available SDS Number: 100000005010 8 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Persistence and degradability No data available Bioaccumulative potential No data available Revision Date: 08/02/2022 Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential Additional ecological information : Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Univar Solutions ChemCare: 1-800-637-7922 Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION DOT (Department of Transportation): UN2031, NITRIC ACID SOLUTION, 8 (5.1), II IATA (International Air Transport Association): UN2031, NITRIC ACID SOLUTION, 8 (5.1), II SECTION 15. REGULATORY INFORMATION SDS Number: 100000005010 9 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 WHMIS Classification : E: Corrosive Material Revision Date: 08/02/2022 EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components Nitric acid CAS-No. 7697-37-2 Component RQ (lbs) 1000 SARA 304 Extremely Hazardous Substances Reportable Quantity Components Nitric acid CAS-No. 7697-37-2 Component RQ (lbs) 1000 Calculated product RQ (lbs) 1429 Calculated product RQ (lbs) 1429 SARA 311/312 Hazards : Oxidiser (liquid, solid or gas) Corrosive to metals Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation SARA 302 : The following components are subject to reporting levels established by SARA Title III, Section 302: SARA 313 7697-37-2 Nitric acid : The following components are subject to reporting levels established by SARA Title III, Section 313: Clean Air Act 7697-37-2 Nitric acid This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: 7697-37-2 Nitric acid The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: 7697-37-2 Nitric acid This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know 7697-37-2 Nitric acid 50 - 70 % Pennsylvania Right To Know 7697-37-2 Nitric acid 50 - 70 % New Jersey Right To Know 7697-37-2 Nitric acid 50 - 70 % SDS Number: 100000005010 10 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory SECTION16. OTHER INFORMATION NFPA: Flammability Healt h 0 3 1 OX OX Special hazard Instability HMIS III: HEALTH 3/ FLAMMABILITY 1 PHYSICAL HAZARD 4 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 =Extreme, * = Chronic The information accumulated is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made become available subsequently to the date hereof, we do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Univar Solutions Product Compliance Department (1-855-429-2661) SDSNA@univarsolutions.com. Revision Date : 08/02/2022 SDS Number: 100000005010 11 / 12 NITRIC ACID 42 BAUM Safety Data Sheet NITRIC ACID 42 BAUM Version 1.3 Revision Date: 08/02/2022 Legacy SDS: : R0001000 Material number: 16159804, 16160140, 16187019, 16175675, 16175673, 16175480, 16175213, 16176867, 16185891, 16185890, 16177631, 16162257, 16140229, 16136928, 16150007, 16145038, 16140587, 16144871, 16149532, 16148905, 16158754, 16145161, 16148826, 16145685, 16160177, 16150182, 16147852, 16140512, 16141265, 16141308, 16142289, 16141518, 16141319, 16141751, 16108058, 16004379, 554152, 554100, 104817, 74151, 105771, 71415, 73143, 89530, 55952, 88705, 55029, 124379, 127750, 156545, 501224, 20223, 20222 Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of Govern- LD50 Lethal Dose 50% ment Industrial Hygienists AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect Substances Level DSL Canada, Domestic Substances List NFPA National Fire Protection Agency NDSL Canada, Non-Domestic Substanc- NIOSH National Institute for Occupational es List Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi- cals EC50 Effective Concentration NOAEL No Observable Adverse Effect Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure Scenar- OSHA Occupational Safety & Health io Tool Administration EOSCA European Oilfield Specialty Chem- PEL Permissible Exposure Limit icals Association EINECS European Inventory of Existing PICCS Philippines Inventory of Commer- Chemical Substances cial Chemical Substances MAK Germany Maximum Concentration PRNT Presumed Not Toxic Values GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act. IARC International Agency for Research TLV Threshold Limit Value on Cancer IECSC Inventory of Existing Chemical TWA Time Weighted Average Substances in China ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act New Chemical Substances KECI Korea, Existing Chemical Inventory UVCB Unknown or Variable Composi- tion, Complex Reaction Products, and Biological Materials <= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50% SDS Number: 100000005010 12 / 12 NITRIC ACID 42 BAUM -BASF We create chemistry Chemetall expect more Safety Data Sheet Oakite 61B Revision date : 2022/12/09 Page: 1/11 Version: 3.0_________________________________________________(30687385/SDS GEN US/EN) 1. Identification Product identifier used on the label Oakite 61B Recommended use of the chemical and restriction on use Recommended use*: Detergents Unsuitable for use: Uses other than recommended * The "Recommended use" identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: Chemetall U.S., Inc. 675 Central Avenue New Providence, NJ 07974 - USA +1 800 526-4473 sds.na-chemetall@basf.com Emergency telephone number 24 Hour Emergency Response Information CHEMTREC: 800-424-9300, +1-703-527-3887 Other means of identification Chemical family: inorganic compounds, organic compounds 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard: 29 CFR Part 1910,1200 Classification of the product Skin Corr./lrrit. Eye Dam./lrrit. STOT SE 1 1 3 (irritating to respiratory system) Skin corrosion/irritation Serious eye damage/eye irritation Specific target organ toxicity -- single exposure Safety Data Sheet Oakite 61B______ Revision date: 2022/12/09 Version: 3.0 Label elements P< ictogra>m< : $> Page: 2/11 (30687385/SDS GEN US/EN) Signal Word: Danger Hazard Statement: H314 H335 Causes severe skin bums and eye damage. May cause respiratory irritation. Precautionary Statements (Prevention): P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing and eye protection or face protection. P264 Wash contaminated body parts thoroughly after handling. P260 Do not breathe dust or mist. Precautionary Statements (Response): P303 + P361 + P353 IF ON SKIN (or hair): Remove or Take off immediately all contaminated clothing. Rinse skin with water or shower. P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. P310 Immediately call a POISON CENTER or physician. P301 + P330+ P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P304+ P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents and container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard: 29 CFR Part 1910.1200 sodium carbonate CAS Number: 497-19-8 Content (W/W): >= 25.0 - < 50.0% Synonym: Carbonic acid, disodium salt Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0 Page: 3/11 (30687385/SDS GEN US/EN) Silicic acid (H2Si03), disodium salt CAS Number: 6834-92-0 Content (W/W): >= 15.0 - < 20.0% Synonym: Disodium metasilicate Trisodium phosphate CAS Number: 7601-54-9 Content (W/W): >= 5.0 - < 7.0% Synonym: No data available. Tetrasodium-pyrophosphate CAS Number: 7722-88-5 Content (W/W): >= 5.0 - < 7.0% Synonym: No data available. Silicic acid, sodium salt CAS Number: 1344-09-8 Content (W/W): >= 3.0 - < 5.0% Synonym: Silicic acid sodium salt Amides, coco, N-[3-(dimethylamino)propyl], alkylation products with sodium 3-chloro-2hydroxypropanesulfonate CAS Number: 70851-08-0 Content (W/W): >= 1.0 - < 3.0% Synonym: No data available. 4. First-Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Remove affected person from danger area. Keep warm, calm and covered up. Immediately remove contaminated clothing. Never give anything by mouth to an unconscious person. In case of intoxication, call a poison control center or physician for treatment advice, taking the packaging or the label of the product. Symptoms of poisoning may occur even after several hours, continue medical observation for at least 48 hours after the accident. If inhaled: Immediate medical attention required. Remove the affected individual into fresh air and keep the person calm. If breathing is irregular or stopped, administer artificial respiration. If on skin: Flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing immediately and clean before re-use or dispose it if necessary. Immediate medical attention required. If in eyes: Remove contact lenses, if present. Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. Immediate medical attention required. Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 4/11 GEN US/EN) If swallowed: Summon medical aid without delay. Do not induce vomiting due to aspiration hazard. Rinse mouth immediately with water. Keep at rest. Most important symptoms and effects, both acute and delayed Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11. Information on: sodium carbonate Symptoms: Overexposure may cause:, vomiting, circulatory collapse, death, diarrhea Information on: Silicic acid, sodium salt Symptoms: Overexposure may cause:, corneal injury, skin corrosion, severe pain, coughing, respiratory disorders, dyspnea, nausea, headache, vomiting, dizziness, diarrhea, abdominal cramps Information on: Silicic acid (H2Si03), disodium salt Symptoms: Overexposure may cause:, corneal injury, skin corrosion, severe pain, coughing, respiratory disorders, dyspnea, nausea, headache, vomiting, dizziness, diarrhea, abdominal cramps Information on: Trisodium phosphate Symptoms: Overexposure may cause:, Eye irritation, skin irritation, erythema, nausea, headache, vomiting, dizziness, diarrhea, abdominal cramps, Inhalation may provoke the following symptoms:, irritation of respiratory tract, coughing Information on: Tetrasodium-pyrophosphate Symptoms: Overexposure may cause:, corneal injury, skin corrosion, severe pain, coughing, respiratory disorders, dyspnea, nausea, headache, vomiting, dizziness, diarrhea, abdominal cramps Hazards: Dusts may cause mechanical irritation to eyes. May cause severe burns of the mouth and throat if orally ingested, as well as a danger of perforation of the oesophagus and the stomach. Indication of any immediate medical attention and special treatment needed Note to physician Antidote: Treatment: No known specific antidote. Symptomatic treatment (decontamination, vital functions). 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: carbon dioxide, alcohol-resistant foam, dry powder, water spray Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon oxides, phosphorus oxides Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 5/11 GEN US/EN) Fire will produce dense black smoke. Inhalation of dangerous decomposition products may cause serious damage to health. Advice for fire-fighters Protective equipment for fire-fighting: Appropriate breathing apparatus may be required. Further information: Cool closed containers in the vicinity of the source of fire. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Product itself is non-combustible; fire extinguishing method of surrounding areas must be considered. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Do not inhale dusts. For non-emergency personnel: Use personal protective clothing. Ensure adequate ventilation. Keep away from sources of ignition. For emergency responders: Advice on product handling can be found in sections 7 and 8 of this safety data sheet. Information regarding personal protective measures, see section 8. Environmental precautions Do not allow to enter drains or waterways. Do not discharge into the subsoil/soil. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environment Agency. Methods and material for containment and cleaning up Avoid dust formation. Contain and collect mechanically and dispose of in accordance with local regulations. Ensure adequate ventilation. 7. Handling and Storage Precautions for safe handling Avoid dust formation. Protect against moisture. Provide good ventilation of working area (local exhaust ventilation if necessary). Do not return residues to the storage containers. Smoking, eating and drinking are forbidden in application area. For personal protection see section 8. Comply with the health and safety at work laws. The workplace should be equipped with an emergency shower and eye-rinsing facility. Avoid contact with the skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Protection against fire and explosion: Avoid dust formation. Avoid all sources of ignition: heat, sparks, open flame. The relevant fire protection measures should be noted. Conditions for safe storage, including any incompatibilities Keep away from oxidising agents, from strongly alkaline and strongly acid materials. Further information on storage conditions: Keep container dry. Keep in a cool, well-ventilated place. Protect against moisture. Avoid direct sunlight. Close containers carefully once opened and store them upright in order to prevent any leakage. No smoking. No admission for unauthorised personnel. Always keep in containers of same material as the original one. Observe label precautions. Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 6/11 GEN US/EN) 8. Exposure Controls/Personal Protection No occupational exposure limits known. Personal protective equipment Respiratory protection: Respiratory protection required if exposure limit (if available) may be exceeded Hand protection: Chemical resistant protective gloves (EN ISO 374-1), butyl rubber gloves - material thickness: 0.5 mm, nitrile rubber (NBR) - 0.4 mm coating thickness, Performance level 6, corresponding to a breakthrough time of >480 min according to EN ISO 374-1, The protection glove should be tested for its specific suitability (e.g. mechanical strength, product compatibility, anti-static properties)., The gloves should be replaced immediately in case of damage or signs of wear. It is recommended to use preventative skin protection (skin cream). Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166) Body protection: Chemical resistant protective clothing according to DIN EN 13034 (Type 6) General safety and hygiene measures: Eye wash fountains and safety showers must be easily accessible. Avoid inhalation of dusts. Avoid contact with the skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation. This can be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations at the workplace below the occupational exposure limits, appropriate certified respirators must be worn. Remove contaminated clothing immediately and dispose of safely. Hands and/or face should be washed before breaks and at the end of the shift. Keep separated from food stuffs and feed stocks. 9. Physical and Chemical Properties Form: Odour: Odour threshold: Colour: pH value: Melting point: Freezing point: onset of boiling: Boiling range: Sublimation point: Flash point: Flammability: Lower explosion limit: Upper explosion limit: Autoignition: Vapour pressure: Relative density: solid odourless No applicable information white 11.5-12.5 (40 g/l) not determined not determined not determined not determined No applicable information not applicable not flammable not applicable not applicable not applicable (20 C) not determined No applicable information available. available. available. Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 7/11 GEN US/EN) Bulk density: Vapour density: Partitioning coefficient noctanol/water (log Pow): Viscosity, dynamic: Viscosity, kinematic: Solubility in water: Miscibility with water: Solubility (quantitative): Solubility (qualitative): Molar mass: Evaporation rate: 0.901 kg/m3 (20 C) No applicable information available. No applicable information available. No applicable (20 C) not applicable 41 G/L miscible No applicable No applicable No applicable not applicable information information information information available. available. available. available, 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Oxidizing properties: not fire-propagating Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions Dust can form an explosive mixture with air. Conditions to avoid Avoid dust formation. Avoid direct sunlight. Avoid humidity. Incompatible materials Keep away from highly acidic or alkaline substances as well as oxidants in order to prevent exothermal reactions. Hazardous decomposition products Decomposition products: When exposed to high temperatures hazardous decomposition products such as carbon monoxide, carbon dioxide, smoke, oxides of nitrogen may be produced., No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 8/11 GEN US/EN) Assessment of acute toxicity: Based on available data, the classification criteria are not met. Oral Type of value: ATE Value: 7,576 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. Inhalation Type of value: ATE Value: > 20 mg/I The product has not been tested. The statement has been derived from the properties of the individual components. Dermal Type of value: ATE Value: > 2,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. Assessment other acute effects Assessment of STOT single: Causes temporary irritation of the respiratory tract. Irritation / corrosion Assessment of irritating effects: Corrosive! Damages skin and eyes. May cause severe damage to the eyes. May cause severe burns of the mouth and throat if orally ingested, as well as a danger of perforation of the oesophagus and the stomach. Information on: sodium carbonate Assessment of irritating effects: Not irritating to the skin. Eye contact causes irritation. Information on: Silicic acid, sodium salt Assessment of irritating effects: Corrosive! Damages skin and eyes. Causes temporary irritation of the respiratory tract. Information on: Silicic acid (H2Si03), disodium salt Assessment of irritating effects: Corrosive! Damages skin and eyes. Causes temporary irritation of the respiratory tract. Information on: Trisodium phosphate Assessment of irritating effects: Skin contact causes irritation. Eye contact causes irritation. Sensitization Assessment of sensitization: Based on available data, the classification criteria are not met. Aspiration Hazard No aspiration hazard expected. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Based on available data, the classification criteria are not met. Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 9/11 GEN US/EN) Information on: Silicic acid, sodium salt Assessment of repeated dose toxicity: The substance may cause damage to the kidney after repeated ingestion of high doses, as shown in animal studies. Information on: Silicic acid (H2Si03), disodium salt Assessment of repeated dose toxicity: The substance may lead to shifts in blood composition following repeated exposure in animal experiments. Prolonged and repeated exposure may cause effects on the liver. Genetic toxicity Assessment of mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Assessment of carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity Assessment of reproduction toxicity: Based on available data, the classification criteria are not met. Teratogenicity Assessment of teratogenicity: Based on available data, the classification criteria are not met. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: There are no test results available for this product. Do not allow to enter drains or waterways. Based on available data, the classification criteria are not met. Persistence and degradability Assessment biodegradation and elimination (H2Q) No data available concerning biodegradation and elimination. Bioaccumulative potential Bioaccumulation potential No data available. Mobility in soil Assessment transport between environmental compartments No data available. 13. Disposal considerations Waste disposal of substance: Do not discharge into drains/surface waters/groundwater. Observe national and local legal requirements. Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0 Page: 10/11 (30687385/SDS GEN US/EN) Container disposal: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. 14. Transport Information Land transport USDOT Hazard class: Packing group: ID number: Hazard label: Proper shipping name: 8 III UN 1759 8 CORROSIVE SOLID, N.O.S. (contains disodium metasilicate) Sea transport IMDG Hazard class: Packing group: ID number: Hazard label: Marine pollutant: Proper shipping name: 8 III UN 1759 8 NO CORROSIVE SOLID, N.O.S. (contains disodium metasilicate) Air transport IATA/ICAO Hazard class: Packing group: ID number: Hazard label: Proper shipping name: 8 III UN 1759 8 CORROSIVE SOLID, N.O.S. (contains disodium metasilicate) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicable for this product. State regulations State RTK NJ PA CAS Number 7558-79-4 7758-29-4 7722-88-5 7558-79-4 7758-29-4 7601-54-9 7722-88-5 Chemical name disodium hydrogen orthophosphate Triphosphoric acid, pentasodium salt Tetrasodium-pyrophosphate disodium hydrogen orthophosphate Triphosphoric acid, pentasodium salt Trisodium phosphate T etrasodium-pyrophosphate Safety Data Sheet Oakite 61B Revision date: 2022/12/09 Version: 3.0___________________________________________________ (30687385/SDS Page: 11/11 GEN US/EN) NFPA Hazard codes: Health: 3 Fire: 1 Reactivity: 1 Special: HMIS III rating Health: 3 Flammability: 1 Physical hazard: 1 16. Other Information SDS Prepared by: Chemetall (now part of BASF Group) NA Product Regulations SDS Prepared on: 2022/12/09 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATASHEET Safety Data Sheet Oakite 160 Version 0.1 Revision Date 05/29/2015 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Oakite 160 Substance number : REL_1600 #120 Print Date 05/29/2015 Chemical usage : Cleaning Compound, Metal etching. Manufacturer or supplier's details Company : Chemetall US, Inc. Address Telephone Telefax Emergency telephone no : 675 Central Avenue New Providence NJ 07974 : (800) 526-4473 : (908) 464-4658 : CHEMTREC - 800-424-9300, 1-703-527-3887 (International) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour Hazard Summary powder white none Causes severe burns. Harmful if swallowed. GHS Classification Acute toxicity (Dermal) Skin corrosion Serious eye damage : Category 4 : Category 1A : Category 1 GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : Harmful in contact with skin. Causes severe skin burns and eye damage. : Prevention: 1 / 9 Safety Data Sheet Oakite 160 Version 0.1 Potential Health Effects Inhalation Skin Ingestion Aggravated Medical Condition Carcinogenicity: IARC ACGIH OSHA NTP Revision Date 05/29/2015 Print Date 05/29/2015 Do not breathe dust or mist. Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. : no : yes : yes : None known. No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : 2 / 9 Safety Data Sheet Oakite 160 Version 0.1 Revision Date 05/29/2015 Print Date 05/29/2015 Hazardous components Component CAS-No. Weight percent Sodium hydroxide 1310-73-2 70 - 90 Trade Secret Registry 735517-5122P 5 - 10 Unidentified ingredients are considered not hazardous under Federal Hazard Communication Standard (29CFR 1910.1200). Specific chemical identity of composition has been withheld as a trade secret. Exact percentage of composition has been withheld as a trade secret. SECTION 4. FIRST AID MEASURES If inhaled : Remove to fresh air. If symptoms persist, call a physician. If breathing is irregular or stopped, administer artificial respiration. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated clothing and shoes immediately. Get medical attention immediately if irritation develops and persists In case of eye contact : Rinse immediately with plenty of water for at least 15 minutes. Keep eye wide open while rinsing. Get medical attention immediately If swallowed : Rinse mouth. Drink plenty of water. Never give anything by mouth to an unconscious person. Get medical attention immediately SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Carbon dioxide (CO2) Dry chemical Foam Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for firefighters SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up : Material can create slippery conditions. : Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. Additional advice : Never return spills in original containers for re-use. 3 / 9 Safety Data Sheet Oakite 160 Version 0.1 Revision Date 05/29/2015 Print Date 05/29/2015 SECTION 7. HANDLING AND STORAGE Advice on safe handling : Add this product to surface of solution slowly to avoid spattering Do not add large amounts of product to solution at any one time. Do not add to hot water warmer than 43 degrees to 49 degrees C (110 degrees to 120 degrees F). Never add liquids to product Conditions for safe storage : Keep containers dry and tightly closed to avoid moisture absorption and contamination. Store indoors in a cool, well-ventilated place Protect from direct contact with water or excessive moisture. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Sodium hydroxide 1310-73-2 C C TWA C Control parameters / Permissible concentration 2.000000 mg/m3 2.000000 mg/m3 2.000000 mg/m3 2.000000 mg/m3 Basis ACGIH NIOSH REL OSHA Z-1 OSHA P0 Personal protective equipment Respiratory protection : If the occupational exposure limits cannot be met, suitable respirator equipment shall be worn. Hand protection Remarks Eye protection Skin and body protection Hygiene measures : Impervious gloves : Chemical resistant goggles must be worn. : Rubber or plastic apron : Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Wear suitable protective clothing. Wash hands before breaks and immediately after handling the product. Provide adequate ventilation. Avoid breathing dust or vapor. Keep away from food and drink. 4 / 9 Safety Data Sheet Oakite 160 Version 0.1 Revision Date 05/29/2015 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : powder Colour Odour pH Melting point/range Boiling point/boiling range Flash point Evaporation rate : white : none : 13.5, Concentration: 40.00000 g/l : no data available : no data available : does not flash : GLP: No information available. Upper explosion limit Lower explosion limit Vapour pressure Relative density Bulk density Solubility(ies) Water solubility : Not applicable. : Not applicable. : no data available : not applicable : 74.81 lb/ft3 : 150.00000 g/l (77 C) Partition coefficient: noctanol/water Auto-ignition temperature Thermal decomposition Viscosity, dynamic : no data available : No data available : No data available : No data available Print Date 05/29/2015 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Incompatible materials Hazardous decomposition products : Exposure to moisture. : Acids : Hydrogen, by reaction with metals SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: 5 / 9 Safety Data Sheet Oakite 160 Version 0.1 Acute oral toxicity Revision Date 05/29/2015 Print Date 05/29/2015 : Acute toxicity estimate : 4,223.000000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate : > 10.000000 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Acute dermal toxicity : Acute toxicity estimate : 1,552.000000 mg/kg Method: Calculation method Components: Sodium hydroxide: Acute oral toxicity : LD50 mouse: 6,600.000000 mg/kg LD50 rat: 4,090.000000 mg/kg Acute inhalation toxicity : LC50 mouse: 1,200.000000 mg/l Exposure time: 2 h Test atmosphere: dust/mist LC50 rat: 2,300.000000 mg/l Exposure time: 2 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 rabbit: 1,350.000000 mg/kg Trade Secret Registry: Acute oral toxicity : LD50 rat: 4,090.000000 mg/kg LD50 mouse: 6,600.000000 mg/kg Acute inhalation toxicity : LC50 rat: 2.300000 mg/l Exposure time: 4 h Test atmosphere: dust/mist LC50 mouse: 1.200000 mg/l Exposure time: 2 h Test atmosphere: dust/mist Skin corrosion/irritation Components: Sodium hydroxide: Result: Corrosive Serious eye damage/eye irritation Components: Sodium hydroxide: 6 / 9 Safety Data Sheet Oakite 160 Version 0.1 Result: Corrosive Classification: Corrosive Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity no data available Reproductive toxicity no data available STOT - single exposure no data available STOT - repeated exposure no data available Aspiration toxicity no data available Revision Date 05/29/2015 Print Date 05/29/2015 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity no data available Bioaccumulative potential Product: Partition coefficient: noctanol/water Other adverse effects : Remarks: no data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Refer to all federal, provincial, state and local regulation prior to disposition of container and unused contents by reuse, recycle or disposal. SECTION 14. TRANSPORT INFORMATION International regulation 7 / 9 Safety Data Sheet Oakite 160 Version 0.1 Revision Date 05/29/2015 Print Date 05/29/2015 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations SECTION 15. REGULATORY INFORMATION TSCA Status : All components of this material comply with US TSCA requirements. OSHA Hazards WHMIS Classification : Combustible dust, Toxic by inhalation., Harmful by skin absorption., Corrosive to skin : E: Corrosive Material EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components Sodium hydroxide CAS-No. 1310-73-2 Component RQ Calculated product RQ (lbs) (lbs) 1,000 1,149 SARA 311/312 Hazards : Acute Health Hazard SARA 302 SARA 313 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Massachusetts Right To Know Sodium hydroxide Pennsylvania Right To Know Sodium hydroxide Trade Secret Registry Trade Secret Registry New Jersey Right To Know Sodium hydroxide Trade Secret Registry Trade Secret Registry 1310-73-2 1310-73-2 735517-5122P 735517-5145P 1310-73-2 735517-5122P 735517-5145P 8 / 9 Safety Data Sheet Oakite 160 Version 0.1 NFPA: Flammability 0 3 1 Health Special hazard. Instability Revision Date 05/29/2015 Print Date 05/29/2015 HMIS III: HEALTH 3 FLAMMABILITY 0 PHYSICAL HAZARD 1 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Corrosive Alkaline SECTION 16. OTHER INFORMATION Safety Glasses, Gloves, Apron, Dust Respirator Further information Version 1.0 Revision Date 05/29/2015 Chemetall US, Inc. warrants that the products described herein will conform with its published specifications. The products supplied by Chemetall and information related to them are intended for use by buyers having necessary industrial skill and knowledge. Buyers should undertake sufficient verification and testing to determine the suitability of the Chemetall materials for their own particular purpose. Since buyer's conditions of use of products are beyond Chemetall's control, Chemetall does not warrant any recommendations and information for the use of such products. CHEMETALL DISCLAIMS ALL OTHER WARRANTIES INCLUDING THE IMPLIED WARRANTY OF MERCHANTABILITY AND FITNESS FOR ANY PARTICULAR PURPOSE IN CONNECTION WITH THE USE OF ITS PRODUCTS. 9 / 9 #514 Safety Data Sheet SULFURIC ACID Version 1.1 Revision Date: 09/01/2019 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : SULFURIC ACID Recommended use of the chemical and restrictions on use Recommended use : industrial chemical Manufacturer or supplier's details Company : Univar Solutions USA, Inc. Address 3075 Highland Pkwy Suite 200 Downers Grove, IL 60515 United States of America (USA) Emergency telephone number: Transport North America: CHEMTREC (1-800-424-9300) CHEMTREC INTERNATIONAL Tel # 703-527-3887 Additional Information: : Responsible Party: Product Compliance Department E-mail: SDSNA@univarsolutions.com SDS Requests: 1-855-429-2661 Website: www.univarsolutions.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin corrosion Serious eye damage : Category 1A : Category 1 GHS label elements Hazard pictograms : Signal word Hazard statements Precautionary statements SDS Number: 100000025928 : Danger : H314 Causes severe skin burns and eye damage. : Prevention: P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with 1 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Revision Date: 09/01/2019 water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P363 Wash contaminated clothing before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Substance Hazardous components CAS-No. Chemical name 7664-93-9 Sulfuric acid Any Concentration shown as a range is due to batch variation. Weight percent 50 - 70 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Clean mouth with water and drink afterwards plenty of water. Keep respiratory tract clear. SDS Number: 100000025928 2 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Revision Date: 09/01/2019 Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : sulfur oxides Gases hazardous to health may be formed. Sulphuric acid Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec- for firefighters essary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : Do not breathe vapours/dust. SDS Number: 100000025928 3 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Conditions for safe storage Materials to avoid Revision Date: 09/01/2019 Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. : Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. : Do not store near acids. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters CAS-No. Components 7664-93-9 Sulfuric acid Value type (Form of exposure) TWA (Thoracic fraction) TWA TWA TWA Control parameters / Permissible concentration 0.2 mg/m3 1 mg/m3 1 mg/m3 1 mg/m3 Basis ACGIH NIOSH REL OSHA Z-1 OSHA P0 Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and concen- SDS Number: 100000025928 4 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Hygiene measures Revision Date: 09/01/2019 tration of the dangerous substance at the work place. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : colourless, cloudy Odour : odourless Odour Threshold : No data available pH : < 1.0 Freezing Point (Freezing Point) : 3 C (37 F) Boiling Point (Boiling point/boiling range) : 329.44 C (624.99 F) Flash point : No data available Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : 1.0 mmHg @ 20 C (68 F) Relative vapour density : 3.4(Air = 1.0) Relative density : 1.403 @ 20 C (68 F) Reference substance: (water = 1) Density : No data available Solubility(ies) Water solubility : completely soluble Solubility in other solvents : No data available Partition coefficient: noctanol/water : No data available Auto-ignition temperature : No data available SDS Number: 100000025928 5 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Thermal decomposition : 340 C Revision Date: 09/01/2019 SECTION 10. STABILITY AND REACTIVITY Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No hazards to be specially mentioned. Conditions to avoid : Keep away from heat, flame, sparks and other ignition sources. Incompatible materials : acetylenes Acids Ammonia Combustible material Flammable materials Metals nitrates Nitriles nitrites Organic materials Oxidizing agents phosphorus Powdered metals Reducing agents water Peroxides SECTION 11. TOXICOLOGICAL INFORMATION Skin corrosion/irritation Product: Remarks: Extremely corrosive and destructive to tissue. Components: 7664-93-9: Species: Rabbit Result: Causes severe burns. Serious eye damage/eye irritation Product: SDS Number: 100000025928 6 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Remarks: May cause irreversible eye damage. Revision Date: 09/01/2019 Components: 7664-93-9: Species: Rabbit Result: Risk of serious damage to eyes. Germ cell mutagenicity Components: 7664-93-9: Genotoxicity in vitro : Test Type: Ames test Species: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative Carcinogenicity IARC OSHA NTP ACGIH Group 1: Carcinogenic to humans 7664-93-9 Sulfuric acid Group 1: Carcinogenic to humans No component of this product present at levels greater than or equal to 0.1% is on OSHA's list of regulated carcinogens. No component of this product present at levels greater than or equal to 0.1% is on OSHA's list of regulated carcinogens. Known to be human carcinogen 7664-93-9 Sulfuric acid Known to be human carcinogen Suspected human carcinogen 7664-93-9 Sulfuric acid Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity No data available SDS Number: 100000025928 7 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Persistence and degradability No data available Bioaccumulative potential No data available Revision Date: 09/01/2019 Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential Additional ecological information : Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Univar Solutions ChemCare: 1-800-909-4897 Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION DOT (Department of Transportation): UN2796, Sulfuric acid, 8, II IATA (International Air Transport Association): UN2796, SULPHURIC ACID, 8, II IMDG (International Maritime Dangerous Goods): UN2796, SULPHURIC ACID, 8, II SDS Number: 100000025928 8 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Revision Date: 09/01/2019 SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components Sulfuric acid CAS-No. 7664-93-9 Component RQ (lbs) 1000 SARA 304 Extremely Hazardous Substances Reportable Quantity Components Sulfuric acid CAS-No. 7664-93-9 Component RQ (lbs) 1000 Calculated product RQ (lbs) 2000 Calculated product RQ (lbs) 2000 SARA 311/312 Hazards : Acute Health Hazard SARA 302 : The following components are subject to reporting levels established by SARA Title III, Section 302: SARA 313 7664-93-9 Sulfuric acid : The following components are subject to reporting levels established by SARA Title III, Section 313: Clean Air Act 7664-93-9 Sulfuric acid This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: 7664-93-9 Sulfuric acid The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: 7664-93-9 Sulfuric acid This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know 7664-93-9 Sulfuric acid Pennsylvania Right To Know 7664-93-9 7732-18-5 Sulfuric acid Water California Prop 65 WARNING: This product can expose you to chemicals including Sulfuric acid, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. SDS Number: 100000025928 9 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Revision Date: 09/01/2019 The components of this product are reported in the following inventories: TSCA : On TSCA Inventory SECTION16. OTHER INFORMATION NFPA: Flammability 1 3 0 Healt h Special hazard. Instability HMIS III: HEALTH 3 FLAMMABILITY 1 PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 =Extreme, * = Chronic The information accumulated is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made become available subsequently to the date hereof, we do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Univar Solutions Product Compliance Department (1-855-429-2661) SDSNA@univarsolutions.com. Revision Date : 09/01/2019 Legacy SDS: : R0017947 Material number: 16125824, 16114349, 696270, 74735, 59641 Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of Govern- LD50 Lethal Dose 50% ment Industrial Hygienists AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect Substances Level DSL Canada, Domestic Substances List NFPA National Fire Protection Agency NDSL Canada, Non-Domestic Substanc- NIOSH National Institute for Occupational es List Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi- cals SDS Number: 100000025928 10 / 11 SULFURIC ACID Safety Data Sheet SULFURIC ACID Version 1.1 Revision Date: 09/01/2019 EC50 EC50 EGEST EOSCA EINECS MAK GHS >= IC50 IARC IECSC ENCS KECI <= LC50 Effective Concentration NOAEL Effective Concentration 50% EOSCA Generic Exposure Scenario Tool European Oilfield Specialty Chemicals Association European Inventory of Existing Chemical Substances Germany Maximum Concentration Values Globally Harmonized System NOEC OSHA PEL PICCS PRNT RCRA Greater Than or Equal To Inhibition Concentration 50% STEL SARA International Agency for Research on Cancer Inventory of Existing Chemical Substances in China Japan, Inventory of Existing and New Chemical Substances Korea, Existing Chemical Inventory TLV TWA TSCA UVCB Less Than or Equal To Lethal Concentration 50% WHMIS No Observable Adverse Effect Level No Observed Effect Concentration Occupational Safety & Health Administration Permissible Exposure Limit Philippines Inventory of Commercial Chemical Substances Presumed Not Toxic Resource Conservation Recovery Act Short-term Exposure Limit Superfund Amendments and Reauthorization Act. Threshold Limit Value Time Weighted Average Toxic Substance Control Act Unknown or Variable Composition, Complex Reaction Products, and Biological Materials Workplace Hazardous Materials Information System SDS Number: 100000025928 11 / 11 SULFURIC ACID Coxsackie, New York Work Instruction: WI-00237 RCRA Contingency Plan - EMS Last Reviewed Date: 10/24/23 Revision No.: D Spine Page: 33 of 33 WI-00237 RCRA Contingency Plan Ducommun AeroStructures New York Coxsackie, NY Attachment 09 Emergency Responders Receipts McCoy, Mary From: Sent: To: Subject: Shawn Burdick - Village of Coxsackie <firechief@villageofcoxsackie.com> Tuesday, January 24, 2023 10:44 AM McCoy, Mary Re: Site Visit This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. See you February 1 at 6:30pm Chief Shawn Burdick Firechief@villageofcoxsackie.com (518)-242-0032 On Jan 24, 2023, at 10:40 AM, McCoy, Mary <MMcCoy@ducommun.com> wrote: This email comes from outside the organization. Do not click links or open attachments unless it is an email you expected to receive. February 1? M Mary A. McCoy, PE 203.300.7303 cell From: Shawn Burdick - Village of Coxsackie [mailto:firechief@villageofcoxsackie.com] Sent: Tuesday, January 24, 2023 10:39 AM To: McCoy, Mary <MMcCoy@ducommun.com> Subject: Re: Site Visit This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. We already have Wednesday scheduled. It will have to be another day Chief Shawn Burdick Firechief@villageofcoxsackie.com (518)-242-0032 1 Attachment 9 Page 1 of 29 On Jan 24, 2023, at 7:51 AM, McCoy, Mary <MMcCoy@ducommun.com> wrote: This email comes from outside the organization. Do not click links or open attachments unless it is an email you expected to receive. Great! See you then. M Mary A. McCoy, PE 203.300.7303 cell From: Shawn Burdick - Village of Coxsackie [mailto:firechief@villageofcoxsackie.com] Sent: Tuesday, January 24, 2023 7:34 AM To: McCoy, Mary <MMcCoy@ducommun.com> Cc: Buccino, Charles <CBuccino@ducommun.com>; Roque, Gregory <GRoque@ducommun.com> Subject: Re: Site Visit This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. We already have something scheduled this Wednesday. Chief Shawn Burdick Firechief@villageofcoxsackie.com (518)-242-0032 On Jan 24, 2023, at 7:11 AM, McCoy, Mary <MMcCoy@ducommun.com> wrote: This email comes from outside the organization. Do not click links or open attachments unless it is an email you expected to receive. Hi Shawn, Does this time still work for you? 2 Attachment 9 Page 2 of 29 M Mary A. McCoy, PE 203.300.7303 cell From: McCoy, Mary Sent: Friday, January 20, 2023 1:36 PM To: Shawn Burdick - Village of Coxsackie <firechief@villageofcoxsackie.com> Cc: Buccino, Charles <CBuccino@ducommun.com>; Roque, Gregory <GRoque@ducommun.com> Subject: RE: Site Visit How about January 25, Wednesday, at 6:30 pm? M Mary A. McCoy, PE 203.300.7303 cell From: McCoy, Mary Sent: Friday, January 20, 2023 8:50 AM To: Shawn Burdick - Village of Coxsackie <firechief@villageofcoxsackie.com> Subject: RE: Site Visit No worries. Let me find out. M Mary A. McCoy, PE 203.300.7303 cell From: Shawn Burdick - Village of Coxsackie [mailto:firechief@villageofcoxsackie.com] Sent: Wednesday, January 18, 2023 4:44 PM To: McCoy, Mary <MMcCoy@ducommun.com> Subject: Re: Site Visit This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. When we did site visits in the past they have been on Wednesday evenings at 6:30pm, will this work? Sorry it took so long to reply it's been a busy week. Chief Shawn Burdick Firechief@villageofcoxsackie.com 3 Attachment 9 Page 3 of 29 (518)-242-0032 On Jan 13, 2023, at 2:08 PM, McCoy, Mary <MMcCoy@ducommun.com> wrote: This email comes from outside the organization. Do not click links or open attachments unless it is an email you expected to receive. Greetings, My name is Mary McCoy, and I'm the new EHS Manager at Ducommun here in Coxsackie. I'd like to invite your team for a visit of our site and to discuss a few things. Are you available on any Friday after 2 pm? Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated 4 Attachment 9 Page 4 of 29 and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 5 Attachment 9 Page 5 of 29 McCoy, Mary Subject: Location: Fire Department Visit Coxsackie Welcome Conference Room Start: End: Wed 2/1/2023 6:30 PM Wed 2/1/2023 8:30 PM Recurrence: (none) Meeting Status: Meeting organizer Organizer: McCoy, Mary Required Attendees:Buccino, Charles; Shawn Burdick - Village of Coxsackie Optional Attendees:Roque, Gregory Resources: Coxsackie Welcome Conference Room Fire Department site visit. Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com 1 Attachment 9 Page 6 of 29 McCoy, Mary From: Sent: To: Subject: McCoy, Mary Friday, October 27, 2023 1:13 PM Shawn Burdick - Village of Coxsackie RE: Contingency Plan Hi Sawn, Did you receive this message, which I sent yesterday? I wanted to check to make sure the files weren't too big. M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com From: McCoy, Mary Sent: Thursday, October 26, 2023 9:48 AM To: Shawn Burdick - Village of Coxsackie <firechief@villageofcoxsackie.com> Subject: Contingency Plan Hi Shawn, I've attached a RCRA Contingency Plan, which we are supposed to submit to you as per 40 CFR 262.262(a) and (b). These are two addresses that are listed in the plan. Are these the same organization? Coxsackie Fire Department 119 Mansion Street Coxsackie, NY 12051 Coxsackie Hose Company #3 P.O. Box 303 Coxsackie, NY 12051 Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com Safety Suggestions: EHSSupportNY@ducommun.com 1 Attachment 9 Page 7 of 29 McCoy, Mary From: Sent: To: Subject: Categories: OEM, SERC (DHSES) <SERC.OEM@dhses.ny.gov> Thursday, October 26, 2023 11:39 AM McCoy, Mary RE: Ducommun AeroStructures NY: RCRA Contingency Plan Saved to network drive This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Good morning Mary, The New York State Emergency Response Commission (NYS SERC) is in receipt of your Hazardous Waste Contingency Plan for Ducommun AeroStructures NY, located in Coxsackie, NY. If you have any questions please let me know. Thank you, Cynthia Zobel OEM Planning NYS Division of Homeland Security & Emergency Services 1220 Washington Avenue, Bldg 22 Albany, NY 12242 518-292-2353 Landline cynthia.zobel@dhses.ny.gov From: McCoy, Mary <MMcCoy@ducommun.com> Sent: Thursday, October 26, 2023 10:35 AM To: OEM, SERC (DHSES) <SERC.OEM@dhses.ny.gov> Subject: Ducommun AeroStructures NY: RCRA Contingency Plan You don't often get email from mmccoy@ducommun.com. Learn why this is important ATTENTION: This email came from an external source. Do not open attachments or click on links from unknown senders or unexpected emails. Greetings, As a large quantity generator of RCRA hazardous waste, Ducommun AeroStructures Inc. of Coxsackie, New York, (DAS NY) is submitting the enclosed RCRA Contingency Plan and Quick Reference Guide to you as per Title 40 of the Code of Regulations 262.262(a) and (b). Please acknowledge receipt. 1 Attachment 9 Page 8 of 29 If you have questions or comments, please contact me at (203) 300-7303 or mmccoy@ducommun.com. Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com Safety Suggestions: EHSSupportNY@ducommun.com From: NY.StateWatchCenter@dhses.ny.gov <NY.StateWatchCenter@dhses.ny.gov> Sent: Thursday, October 26, 2023 10:16 AM To: NY.StateWatchCenter@dhses.ny.gov Subject: RCRA Contingency Plan This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. NYSWC receives, thank you New York State Watch Center Office of Emergency Management Division of Homeland Security and Emergency Services 1220 Washington Ave, Building 22, Albany NY 12226 (518) 292-2200 | 5183224982@fax.ny.gov | NY.StateWatchCenter@dhses.ny.gov www.dhses.ny.gov This message was sent to the following: MMcCoy@ducommun.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 2 Attachment 9 Page 9 of 29 McCoy, Mary From: Sent: To: Subject: O'Rourke, Danielle <orourkd@amc.edu> Friday, October 27, 2023 2:10 PM McCoy, Mary RE: RCRA Contingency Plan This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Yes, I did, I apologize for the delayed response . I have sent it to our clinical management team for review. Danielle O'Rourke Occupational Medicine Coordinator Albany Med EmUrgentCare - Administration 1275 Broadway, MC-42, Menands, NY 12204 P:518-264-5598 F: 518-731-9119 orourkd@amc.edu Pronouns: She/Her/Hers Mon-Thurs 7:30-6 From: McCoy, Mary <MMcCoy@ducommun.com> Sent: Friday, October 27, 2023 1:16 PM To: Rogers, Alyssa <rogersa1@amc.edu>; O'Rourke, Danielle <orourkd@amc.edu> Subject: RE: RCRA Contingency Plan Greetings, I was wondering if you received the email below yesterday. I want to make sure the attachment wasn't too big. M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com From: McCoy, Mary Sent: Thursday, ZjQcmQRYFpfptBannerStart This Message Is From an External Sender This message came from outside your organization. Report Suspicious ZjQcmQRYFpfptBannerEnd Greetings, I was wondering if you received the email below yesterday. I want to make sure the attachment wasn't too big. M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com 1 Attachment 9 Page 10 of 29 From: McCoy, Mary Sent: Thursday, October 26, 2023 9:50 AM To: Rogers, Alyssa <rogersa1@amc.edu>; O'Rourke, Danielle <orourkd@amc.edu> Subject: RCRA Contingency Plan Greetings, I've attached a RCRA Contingency Plan, which we are supposed to submit to you as per 40 CFR 262.262(a) and (b). Would you please forward to the correct department and acknowledge receipt. Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com Safety Suggestions: EHSSupportNY@ducommun.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. CONFIDENTIALITY NOTICE: This email and any attachments may contain confidential information that is protected by law and is for the sole use of the individuals or entities to which it is addressed. If you are not the intended recipient, please notify the sender by replying to this email and destroying all copies of the communication and attachments. Further use, disclosure, copying, distribution of, or reliance upon the contents of this email and attachments is strictly prohibited. To contact Albany Medical Center, Saratoga Hospital, Glens Falls Hospital or Columbia Memorial Hospital, or for a copy of our privacy practices, please visit us on the Internet at https://www.albanymed.org/.' 2 Attachment 9 Page 11 of 29 McCoy, Mary From: Sent: To: Subject: McCoy, Mary Tuesday, June 11, 2024 11:09 AM Zach Saccoccie RE: Site Walk Through Hi Zach, I'll go ahead and take this off the schedule for June 12 for planning purposes. We are available any evening except the weeks of June 24 through June 28 July 22 through July 26 M Mary A. McCoy, PE 203.300.7303 cell Safety Sugges ons: EHSSupportNY@ducommun.com From: McCoy, Mary Sent: Monday, June 10, 2024 10:05 AM To: Zach Saccoccie <coxsackie3captain@gmail.com> Subject: RE: Site Walk Through No worries. M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com From: Zach Saccoccie <coxsackie3captain@gmail.com> Sent: Monday, June 10, 2024 10:13 AM To: McCoy, Mary <MMcCoy@ducommun.com> Subject: Re: Site Walk Through Mary the county just appointed a new haz-mat team chief. I have reached out to him in regards to joining us for the walk through. Once I hear back I will let you knoiw so we can set a date. sorry this is taking so long to get set up. Thanks ZjQcmQRYFpfptBannerStart This Message Is From an External Sender This message came from outside your organization. ZjQcmQRYFpfptBannerEnd Mary the county just appointed a new haz-mat team chief. I have reached out to him in regards to joining us for the walk through. Once I hear back I will let you knoiw so we can set a date. sorry this is taking so long to get set up. Thanks Capt Saccoccie 1 Attachment 9 Page 12 of 29 On Wed, May 22, 2024 at 6:54PM McCoy, Mary <MMcCoy@ducommun.com> wrote: Hi Zach, No worries. Does June 12 at 6 pm work for you all? M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com From: Zach Saccoccie <coxsackie3captain@gmail.com> Sent: Wednesday, May 22, 2024 11:54 AM To: McCoy, Mary <MMcCoy@ducommun.com> Subject: Site Walk Through Good Morning Mary, Sorry I'm just getting back to you. The month has been extremely busy. We would definitely like to schedule a visit with you guys. I see you'd like to have the Haz-Mat team there as well. Let me reach out to the team ZjQcmQRYFpfptBannerStart This Message Is From an External Sender This message came from outside your organization. ZjQcmQRYFpfptBannerEnd Good Morning Mary, Sorry I'm just getting back to you. The month has been extremely busy. We would definitely like to schedule a visit with you guys. I see you'd like to have the Haz-Mat team there as well. Let me reach out to the team and see if they are available. From there we can schedule a date if this works for you? -- 2 Attachment 9 Page 13 of 29 Coxsackie Hose Co#3 Saccoccie (518)626-1250 Captain Zach Coxsackie3captain@gmail.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 3 Attachment 9 Page 14 of 29 McCoy, Mary From: Sent: To: Cc: Subject: Categories: Collette, Gregg <gregg.collette@veolia.com> Wednesday, December 13, 2023 2:07 PM McCoy, Mary Cathy McNamara; Rice, Renee; Zeh, Gary Re: Veolia Emergency Response Services Saved to network drive This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Confirming receipt. Gregg Collette -PM Veolia Gregg.collette@veolia.com 508-683/9823 cell phone On Tue, Dec 12, 2023 at 9:57AM McCoy, Mary <MMcCoy@ducommun.com> wrote: Hi Gregg, I've attached a RCRA Contingency Plan, which we are required to submit to you as per 6 CRR-NY 373-3.3(g) AND 373.4. Would you kindly acknowledge receipt? Let me know if you have questions or comments. M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com 1 Attachment 9 Page 15 of 29 From: Zeh, Gary <gary.zeh@veolia.com> Sent: Tuesday, December 12, 2023 7:25 AM To: McCoy, Mary <MMcCoy@ducommun.com> Cc: Rice, Renee <renee.rice@veolia.com>; Barley, Linda <LBarley@ducommun.com>; Gregg Collette <gregg.collette@veolia.com>; Cathy McNamara <cathy.mcnamara@veolia.com> Subject: Re: Veolia Emergency Response Services This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Hi Mary, I'm adding Gregg Collette who is our Industrial Project Manager and would be your contact for Emergency Services and questions. Also adding Cathy McNamara who is our/your Account Manager and would be able to answer any questions about the Agreement or your Account. Thanks. On Mon, 11 Dec 2023 at 17:11, McCoy, Mary <MMcCoy@ducommun.com> wrote: Greetings, Do you folks know who our contact is for emergency response services? I'd like to send them/you all a copy of our Contingency Plan. Also, is there an expiration date on this agreement? 2 Attachment 9 Page 16 of 29 Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com Safety Suggestions: EHSSupportNY@ducommun.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. -- Gary Zeh Operations Manager II - NY Industrial Business VEOLIA NORTH AMERICA tel +1 518.389.4498 3 Attachment 9 Page 17 of 29 cell +1 518.419.4796 (preferred) efax +1 518.704.6959 3 Northway Lane, Latham, NY 12110 gary.zeh@veolia.com www.veolianorthamerica.com To help protect y our priv acy , Microsoft Office prev ented automatic download of this picture from the Internet. CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 4 Attachment 9 Page 18 of 29 McCoy, Mary From: Sent: To: Subject: Categories: Brianne Lee <blee@greenesheriffny.com> Tuesday, December 12, 2023 8:21 AM McCoy, Mary; Sheriff RE: Ducommun AeroStructures NY: RCRA Contingency Plan Saved to network drive This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Hi Mary, We have received this. Thank you! Brianne Lee Confidential Secretary to Sheriff Peter J. Kusminsky Greene County Sheriff's Office 45 Haverly Memorial Drive Coxsackie, N.Y. 12051 518-943-3300 x501 blee@greenesheriffny.com From: McCoy, Mary <MMcCoy@ducommun.com> Sent: Monday, December 11, 2023 4:38 PM To: Sheriff <sheriff@greenesheriffny.com> Subject: Ducommun AeroStructures NY: RCRA Contingency Plan Greetings, I've attached a RCRA Contingency Plan, which we are required to submit to you as per 6 CRR-NY 373-3.3(g) AND 373.4. Would you please acknowledge receipt? Let me know if you have questions or comments. Mary A. McCoy, PE EHS Manager Ducommun AeroStructures New York, Inc. 171 Stacey Road Coxsackie, NY 12051-2613 1 Attachment 9 Page 19 of 29 203.300.7303 cell 518.731.4650 office mmccoy@ducommun.com www.ducommun.com Safety Suggestions: EHSSupportNY@ducommun.com CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 2 Attachment 9 Page 20 of 29 SENDER: COMPLETE THIS SECTION Complete items 1, 2, and 3. Print your name and address on the reverse so that we can return the card to you. Attach this card to the back of the mailpiece, or on the front if space permits. 1. Article Addressed to: St. Peter's Hospital 315 South Manning Blvd. Albany, NY 12208 COMPLETE THIS SECTION ON DELIVERY A. Signature' , X 12Jdzd! B. Received by (Printed Name) O Agent O Addressee C. Date of Delivery D. Is delivery address different from item 1? O Yes If YES, enter delivery address below: O No li 3. Service Type li lllllll llll lllllll I 11111111111111111111111 O Adult Signature ,Adult Signature Restricted Delivery 6Z Certified Mail 9590 9402 8026 2305 5976 52 O Certified Mail Restricted Delivery O Collect on Delivery -.,--..-,;,...,.-, N:-,-,m-h-.-,,""r"r=,-,-,.n-.s-f,-.-, -,m-m-.s,-.r-v,-.,,,-._ -,a-be_/_) -----l O Collect on Delivery Restricted Delivery O Priority Mail EY"ress O Registered Mail' O Reiistered Mail Resa . Delivery O Signature ConfirmationTM O Signature Confirmation Restricted Delivery 7 0 15 15 2 0 0 0 0 0 7119 2 3 6 6 :~:~:: ~~: Restricted Delivery (over$500 PS Form 3811, July 2020 PSN 7530-02-000-9053 Domestic Return Receipt i Attachment 9 Page 21 of 29  1111111iiiU~ L \ \\ \\ \ First-Class Mail Postage & Fees Paid USPS Permit No. G-10 9590 9402 8026 2305 5976 52 United States Postal Service Sender: Please print your name, address, and ZIP+4 in this box Ducommun _ 171 Stacey Road Co,sackle, NY 1 O 'i@mR\VJffl ~ Attachment 9 Page 22 of 29 _; i-25 i 37 i - 2/21/24, 11:42 AM USPS.com - USPS Tracking Results ALERT: SEVERE WEATHER CONDITIONS ACROSS THE U.S. MAY DELAY FINAL DELIVERY OF Y... USPS Tracking FAQs Tracking Number: 70151520000071192366 Copy Add to Informed Delivery (https://informeddelivery.usps.com/) Remove Latest Update Your item was picked up at a postal facility at 9:17 am on October 31, 2023 in ALBANY, NY 12206. Get More Out of USPS Tracking: USPS Tracking Plus Delivered Delivered, Individual Picked Up at Postal Facility ALBANY, NY 12206 October 31, 2023, 9:17 am See All Tracking History What Do USPS Tracking Statuses Mean? (https://faq.usps.com/s/article/Where-is-my-package) Feedback Text & Email Updates USPS Tracking Plus Product Information See Less Tracking Number: Remove 70151520000071192397Attachment 9 Page 23 of 29 https://tools.usps.com/go/TrackConfirmAction?tRef=fullpage&tLc=6&text28777=&tLabels=70151520000071192366%2C70151520000071192397%2C... 1/4 2/21/24, 11:42 AM Copy USPS.com - USPS Tracking Results Add to Informed Delivery (https://informeddelivery.usps.com/) Latest Update Your item was delivered to an individual at the address at 10:45 am on November 6, 2023 in CAIRO, NY 12413. Get More Out of USPS Tracking: USPS Tracking Plus Delivered Delivered, Left with Individual CAIRO, NY 12413 November 6, 2023, 10:45 am See All Tracking History What Do USPS Tracking Statuses Mean? (https://faq.usps.com/s/article/Where-is-my-package) See More Tracking Number: 70151520000071192380 Copy Add to Informed Delivery (https://informeddelivery.usps.com/) Remove Latest Update Your item was picked up at the post office at 9:13 am on October 31, 2023 in HUDSON, NY 12534. Get More Out of USPS Tracking: USPS Tracking Plus Delivered Delivered, Individual Picked Up at Post Office HUDSON, NY 12534 October 31, 2023, 9:13 am See All Tracking History What Do USPS Tracking Statuses Mean? (https://faq.usps.com/s/article/Where-is-my-package) See More Attachment 9 Page 24 of 29 https://tools.usps.com/go/TrackConfirmAction?tRef=fullpage&tLc=6&text28777=&tLabels=70151520000071192366%2C70151520000071192397%2C... 2/4 2/21/24, 11:42 AM USPS.com - USPS Tracking Results Tracking Number: 70151520000071192373 Copy Add to Informed Delivery (https://informeddelivery.usps.com/) Remove Latest Update Your item was picked up at the post office at 3:47 pm on November 6, 2023 in EARLTON, NY 12058. Get More Out of USPS Tracking: USPS Tracking Plus Delivered Delivered, Individual Picked Up at Post Office EARLTON, NY 12058 November 6, 2023, 3:47 pm See All Tracking History What Do USPS Tracking Statuses Mean? (https://faq.usps.com/s/article/Where-is-my-package) See More Tracking Number: 70151520000071192359 Copy Add to Informed Delivery (https://informeddelivery.usps.com/) Remove Latest Update Your item was delivered to an individual at the address at 11:48 am on November 1, 2023 in SOUTH CAIRO, NY 12482. Get More Out of USPS Tracking: USPS Tracking Plus Attachment 9 Page 25 of 29 https://tools.usps.com/go/TrackConfirmAction?tRef=fullpage&tLc=6&text28777=&tLabels=70151520000071192366%2C70151520000071192397%2C... 3/4 2/21/24, 11:42 AM Delivered Delivered, Left with Individual SOUTH CAIRO, NY 12482 November 1, 2023, 11:48 am USPS.com - USPS Tracking Results See All Tracking History What Do USPS Tracking Statuses Mean? (https://faq.usps.com/s/article/Where-is-my-package) Text & Email Updates USPS Tracking Plus Product Information Track Another Package Enter tracking or barcode numbers See Less Need More Help? Contact USPS Tracking support for further assistance. FAQs Attachment 9 Page 26 of 29 https://tools.usps.com/go/TrackConfirmAction?tRef=fullpage&tLc=6&text28777=&tLabels=70151520000071192366%2C70151520000071192397%2C... 4/4 McCoy, Mary From: Sent: To: Subject: Categories: Sam Mento - Village of Coxsackie PD <smento@villageofcoxsackiepolice.com> Monday, December 11, 2023 6:55 PM McCoy, Mary Re: RCRA Contingency Plan Saved to network drive This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Good Evening Mary, Thank you for reaching out, yes I did receive the file. Thank you, Chief Samuel Mento Coxsackie Police Department 119 Mansion Street, Coxsackie N.Y. 12051 PD (518) 731-8122, Fax (518) 731-2508 Cell (518) 915-5677 From: McCoy, Mary <MMcCoy@ducommun.com> Sent: Monday, December 11, 2023 4:34 PM To: Sam Mento - Village of Coxsackie PD <smento@villageofcoxsackiepolice.com> Subject: RE: RCRA Contingency Plan This email comes from outside the organization. Do not click links or open attachments unless it is an email you expected to receive. Hello Chief, I sent a RCRA Contingency Plan back in October. I wasn't sure if you received it - it was a rather large file. 1 Attachment 9 Page 27 of 29 Did you receive it? M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com From: McCoy, Mary Sent: Friday, October 27, 2023 3:23 PM To: Sam Mento - Village of Coxsackie PD <smento@villageofcoxsackiepolice.com> Subject: RCRA Contingency Plan Hi Chief Mento, I've attached a RCRA Contingency Plan, which we are supposed to submit to you as per 40 CFR 262.262(a) and (b). If you have any questions or comments, please contact me. Would you kindly acknowledge receipt? M Mary A. McCoy, PE 203.300.7303 cell Safety Suggestions: EHSSupportNY@ducommun.com From: Sam Mento - Village of Coxsackie PD <smento@villageofcoxsackiepolice.com> Sent: Thursday, April 20, 2023 1:51 PM To: McCoy, Mary <MMcCoy@ducommun.com> Subject: Contingency Plan This email originated from outside Ducommun. Hover your mouse over any link to verify it. Do not click any links or open any attachments unless you trust the sender and know the content is safe. Good Afternoon, Mary I received a message from Chief Burdick regarding a contingency plan for your company. The village of Coxsackie Police Department is the responding agency for the village of Coxsackie. If you require any further feel free to respond to this email. Thank you, Chief Samuel Mento Coxsackie Police Department 2 Attachment 9 Page 28 of 29 119 Mansion Street, Coxsackie N.Y. 12051 PD (518) 731-8122, Fax (518) 731-2508 Cell (518) 915-5677 CONFIDENTIALITY NOTICE: This email transmission and any attachments to it may contain confidential information proprietary to Ducommun Incorporated and its subsidiaries or their customers. If you are not the intended recipient, a person responsible for delivering it to the intended recipient, or have received this transmission in error, please notify the sender and destroy the original transmission and its attachments without reading or saving. 3 Attachment 9 Page 29 of 29 Attachment 10 Adhesives Sealant Waste Determination Form No.: Last Reviewed Date: Revision No.: Coxsackie, New York F-00663 Hazardous Waste Determination Worksheet - 10/17/2023 A Authorized By: WI-00216 Environmental Management System - Requirements Page 1 of 2 DCO Site: Coxsackie 171 Stacey Road Coxsackie, NY 12051-2613 EPA ID: NYR 000 219 550 Date: 6/17/2024 By: Mary McCoy Waste Stream Common Name: Adheaseive/sealant debris Check one: RCRA Haz Waste Non-RCRA Haz Waste Not Haz Waste RCRA Waste Codes: NA State Waste Codes: NA 0 Source Code: NA 0 Form Code: NA 0 Management Method: #N/A (For California sites, if this waste is subject to 22 CCR 66266.1 and is not recycled, attach justification.) UN#, Proper Shipping Name, Hazard Class, Packing Group: NA ERG: NA Check one: Ongoing RQ Threshold: NA Intermittent One-time Other information: Previous analytical results indicate non-hazardous Waste generation process (listed, characteristic); chemicals used; location within facility: Adhesive and sealant mixing and usage generating cups, wooden mixers, rags, syringes laden with dried adhesives and sealants. Attachment 10 Page 1 of 17 #=CL# LIMS USE: FR - MARY MCCOY LIMS OBJECT ID: 70299090 June 12, 2024 Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Mary McCoy Ducommun Aerostructures 171 Stacy Road Coxsackie, NY 12051 RE: Project: SEALANTS/ADHESIVE DEBRIS 5/24 Pace Project No.: 70299090 Dear Mary McCoy: Enclosed are the analytical results for sample(s) received by the laboratory on May 24, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: Pace Analytical Services - Melville If you have any questions concerning this report, please feel free to contact me. Sincerely, Daniel H. Bonitto daniel.bonitto@pacelabs.com 516-370-6000 Project Manager Enclosures cc: Linda Barley, Ducommun Aerostructures Pedro Dumaua, Ducommun Aerostructures Eugenia Lighthouse, Ducommun Incorporated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena2lyotifc1al7Services, LLC. Page 1 of 16 #=CP# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 Pace Analytical Services Long Island 575 Broad Hollow Rd, Melville, NY 11747 Connecticut Certification #: PH-0435 Delaware Certification # NY 10478 Maryland Certification #: 208 Massachusetts Certification #: M-NY026 New Hampshire Certification #: 2987 CERTIFICATIONS New Jersey Certification #: NY158 New York Certification #: 10478 Primary Accrediting Body Pennsylvania Certification #: 68-00350 Rhode Island Certification #: LAO00340 Virginia Certification # 460302 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena3lyotifc1al7Services, LLC. Page 2 of 16 #=SA# SAMPLE ANALYTE COUNT Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 Lab ID 70299090001 Sample ID 24052301-MAM PACE-MV = Pace Analytical Services - Melville Method EPA 6010D EPA 7470A EPA 8260C ASTM D2216-05M Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 Analysts JWT JP2 BBL NAA Analytes Reported Laboratory 7 PACE-MV 1 PACE-MV 13 PACE-MV 1 PACE-MV REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena4lyotifc1al7Services, LLC. Page 3 of 16 #=AR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 ANALYTICAL RESULTS Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 Sample: 24052301-MAM Lab ID: 70299090001 Collected: 05/23/24 07:00 Received: 05/24/24 08:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010D MET ICP, TCLP Arsenic Barium Cadmium Chromium Lead Selenium Silver 7470 Mercury, TCLP Mercury 8260C MSV TCLP 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) Benzene Carbon tetrachloride Chlorobenzene Chloroform Tetrachloroethene Trichloroethene Vinyl chloride Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4-Bromofluorobenzene (S) Percent Moisture Percent Moisture Analytical Method: EPA 6010D Preparation Method: EPA 3005A Leachate Method/Date: EPA 1311; 05/28/24 23:28 Pace Analytical Services - Melville <0.050 <1.0 0.014 3.9 0.21 <0.050 <0.050 mg/L mg/L mg/L mg/L mg/L mg/L mg/L 0.050 1 05/30/24 07:07 05/30/24 12:17 7440-38-2 1.0 1 05/30/24 07:07 05/30/24 12:17 7440-39-3 0.012 1 05/30/24 07:07 05/30/24 12:17 7440-43-9 0.050 1 05/30/24 07:07 05/30/24 12:17 7440-47-3 0.025 1 05/30/24 07:07 05/30/24 12:17 7439-92-1 0.050 1 05/30/24 07:07 05/30/24 12:17 7782-49-2 0.050 1 05/30/24 07:07 05/30/24 12:17 7440-22-4 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311; 05/28/24 23:28 Pace Analytical Services - Melville <0.00020 mg/L 0.00020 1 06/03/24 08:00 06/03/24 14:36 7439-97-6 Analytical Method: EPA 8260C Leachate Method/Date: EPA 1311; 05/29/24 23:40 Pace Analytical Services - Melville <0.010 <0.010 0.20 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 0.010 5 0.010 5 0.025 5 0.010 5 0.010 5 0.010 5 0.010 5 0.010 5 0.010 5 0.010 5 05/31/24 20:11 75-35-4 05/31/24 20:11 107-06-2 05/31/24 20:11 78-93-3 05/31/24 20:11 71-43-2 05/31/24 20:11 56-23-5 05/31/24 20:11 108-90-7 M1 05/31/24 20:11 67-66-3 05/31/24 20:11 127-18-4 M1 05/31/24 20:11 79-01-6 05/31/24 20:11 75-01-4 92 % 100 % 105 % 80-120 5 75-122 5 73-122 5 Analytical Method: ASTM D2216-05M Pace Analytical Services - Melville 2.8 % 0.10 1 05/31/24 20:11 17060-07-0 05/31/24 20:11 2037-26-5 05/31/24 20:11 460-00-4 05/28/24 06:25 Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena5lyotifc1al7Services, LLC. Page 4 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 QC Batch: QC Batch Method: 350108 EPA 7470A Associated Lab Samples: 70299090001 METHOD BLANK: 1811176 Associated Lab Samples: 70299090001 Mercury Parameter Units mg/L Analysis Method: Analysis Description: Laboratory: EPA 7470A 7470 Mercury TCLP Pace Analytical Services - Melville Matrix: Water Blank Result <0.00020 Reporting Limit 0.00020 Analyzed 06/03/24 14:23 Qualifiers METHOD BLANK: 1810954 Associated Lab Samples: 70299090001 Mercury Parameter Units mg/L Matrix: Water Blank Result <0.00020 Reporting Limit 0.00020 Analyzed 06/03/24 14:35 Qualifiers LABORATORY CONTROL SAMPLE: 1811177 Mercury Parameter Units mg/L Spike Conc. 0.001 LCS Result 0.0010 LCS % Rec 100 % Rec Limits 80-120 Qualifiers MATRIX SPIKE SAMPLE: Mercury Parameter 1811178 Units mg/L 70298087004 Result <0.00020 Spike Conc. 0.001 MS Result 0.0011 MS % Rec 105 % Rec Limits 75-125 Qualifiers SAMPLE DUPLICATE: 1811179 Mercury Parameter Units mg/L 70298087004 Result <0.00020 Dup Result <0.00020 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena6lyotifc1al7Services, LLC. Page 5 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 QC Batch: QC Batch Method: 349768 EPA 3005A Associated Lab Samples: 70299090001 METHOD BLANK: 1809333 Associated Lab Samples: 70299090001 Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L Analysis Method: Analysis Description: Laboratory: EPA 6010D 6010D MET TCLP Pace Analytical Services - Melville Matrix: Water Blank Result <0.010 <0.20 <0.0025 <0.010 <0.0050 <0.010 <0.010 Reporting Limit 0.010 0.20 0.0025 0.010 0.0050 0.010 0.010 Analyzed 05/30/24 11:49 05/30/24 11:49 05/30/24 11:49 05/30/24 11:49 05/30/24 11:49 05/30/24 11:49 05/30/24 11:49 Qualifiers LABORATORY CONTROL SAMPLE: 1809334 Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L Spike Conc. 0.5 0.5 0.5 0.5 0.5 0.5 0.25 LCS Result 0.48 0.50 0.50 0.49 0.50 0.47 0.24 LCS % Rec 95 100 99 99 100 94 98 % Rec Limits 80-120 80-120 80-120 80-120 80-120 80-120 80-120 Qualifiers MATRIX SPIKE SAMPLE: Arsenic Barium Cadmium Chromium Lead Selenium Silver Parameter 1809336 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L 70299194001 Result <0.050 <1.0 <0.012 <0.050 <0.025 <0.050 <0.050 Spike Conc. 0.5 0.5 0.5 0.5 0.5 0.5 0.25 MS Result 0.48 <1.0 0.47 0.47 0.49 0.46 0.26 MS % Rec 91 95 94 93 95 84 102 % Rec Limits 75-125 75-125 75-125 75-125 75-125 75-125 75-125 Qualifiers SAMPLE DUPLICATE: 1809335 Arsenic Barium Cadmium Parameter Units mg/L mg/L mg/L 70299194001 Result <0.050 <1.0 <0.012 Dup Result <0.050 <1.0 <0.012 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena7lyotifc1al7Services, LLC. Page 6 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 SAMPLE DUPLICATE: 1809335 Chromium Lead Selenium Silver Parameter Units mg/L mg/L mg/L mg/L 70299194001 Result <0.050 <0.025 <0.050 <0.050 Dup Result <0.050 <0.025 <0.050 <0.050 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena8lyotifc1al7Services, LLC. Page 7 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 QC Batch: QC Batch Method: 350048 EPA 8260C Associated Lab Samples: 70299090001 METHOD BLANK: 1810642 Associated Lab Samples: 70299090001 Parameter 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) Benzene Carbon tetrachloride Chlorobenzene Chloroform Tetrachloroethene Trichloroethene Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L % % % Analysis Method: Analysis Description: Laboratory: EPA 8260C 8260 MSV TCLP Pace Analytical Services - Melville Matrix: Water Blank Result <0.0020 <0.0020 <0.0050 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 92 106 98 Reporting Limit 0.0020 0.0020 0.0050 0.0020 0.0020 0.0020 0.0020 0.0020 0.0020 0.0020 80-120 73-122 75-122 Analyzed 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 05/31/24 15:20 Qualifiers METHOD BLANK: 1806683 Associated Lab Samples: 70299090001 Parameter 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) Benzene Carbon tetrachloride Chlorobenzene Chloroform Tetrachloroethene Trichloroethene Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L % % % Matrix: Solid Blank Result <0.010 <0.010 <0.025 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 93 105 97 Reporting Limit 0.010 0.010 0.025 0.010 0.010 0.010 0.010 0.010 0.010 0.010 80-120 73-122 75-122 Analyzed 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 05/31/24 19:31 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wriAttettnaccohnmseenntto1f0PaPcaegAena9lyotifc1al7Services, LLC. Page 8 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 METHOD BLANK: 1809269 Associated Lab Samples: 70299090001 Parameter 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) Benzene Carbon tetrachloride Chlorobenzene Chloroform Tetrachloroethene Trichloroethene Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L % % % Matrix: Solid Blank Result <0.010 <0.010 <0.025 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 90 104 95 Reporting Limit 0.010 0.010 0.025 0.010 0.010 0.010 0.010 0.010 0.010 0.010 80-120 73-122 75-122 Analyzed 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 05/31/24 19:51 Qualifiers LABORATORY CONTROL SAMPLE: 1810643 Parameter 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) Benzene Carbon tetrachloride Chlorobenzene Chloroform Tetrachloroethene Trichloroethene Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L % % % Spike Conc. 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 LCS Result 0.043 0.046 0.046 0.049 0.051 0.052 0.047 0.056 0.051 0.039 LCS % Rec 86 93 92 98 102 104 94 112 101 78 94 108 98 % Rec Limits Qualifiers 66-133 69-134 33-165 78-117 64-135 79-117 79-123 65-120 v1 79-115 49-118 80-120 73-122 75-122 MATRIX SPIKE SAMPLE: Parameter 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) Benzene Carbon tetrachloride Chlorobenzene Chloroform Tetrachloroethene 1811272 Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 70299090001 Result <0.010 <0.010 0.20 <0.010 <0.010 <0.010 <0.010 <0.010 Spike Conc. 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 MS Result 0.30 0.27 0.42 0.28 0.33 0.32 0.29 0.37 MS % Rec 120 107 88 114 131 128 117 147 % Rec Limits Qualifiers 61-139 58-138 33-148 70-130 56-143 74-122 71-129 64-124 M1 M1, v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wrAitttetancchomnseenntt 1of0PPaacegeAn1a0lytoicfa1l 7Services, LLC. Page 9 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 MATRIX SPIKE SAMPLE: Parameter Trichloroethene Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 1811272 Units mg/L mg/L % % % 70299090001 Result <0.010 <0.010 Spike Conc. 0.25 0.25 MS Result 0.30 0.26 MS % Rec 122 103 92 108 100 % Rec Limits 73-125 33-127 80-120 73-122 75-122 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wrAitttetancchomnseenntt 1of0PPaacegeAn1a1lytoicfa1l 7Services, LLC. Page 10 of 16 #=QC# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 QC Batch: QC Batch Method: 349510 ASTM D2216-05M Associated Lab Samples: 70299090001 Analysis Method: Analysis Description: Laboratory: ASTM D2216-05M Dry Weight/Percent Moisture Pace Analytical Services - Melville SAMPLE DUPLICATE: 1807706 Parameter Percent Moisture Units % 70298976003 Result 65.8 Dup Result 66.6 RPD Qualifiers 1 SAMPLE DUPLICATE: 1807707 Parameter Percent Moisture Units % 70299165001 Result 17.8 Dup Result 16.2 RPD Qualifiers 9 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wrAitttetancchomnseenntt 1of0PPaacegeAn1a2lytoicfa1l 7Services, LLC. Page 11 of 16 #=QL# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALIFIERS Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. BATCH QUALIFIERS Batch: 349775 [1] The post digestion spike for sample 70299194001 (PDS 1809350) did not meet acceptance criteira for Silver, Arsenic, Barium, Cadmium, Chromium, Lead, and Selenium. [2] The serial dilution for sample 70299194001 (SD 1809351) did not meet acceptance criteira for Arsenic, Barium and Selenium. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wrAitttetancchomnseenntt 1of0PPaacegeAn1a3lytoicfa1l 7Services, LLC. Page 12 of 16 #=CR# Pace Analytical Services, LLC 575 Broad Hollow Road Melville, NY 11747 516-370-6000 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: SEALANTS/ADHESIVE DEBRIS 5/24 70299090 Lab ID 70299090001 70299090001 70299090001 70299090001 Sample ID 24052301-MAM 24052301-MAM 24052301-MAM 24052301-MAM QC Batch Method EPA 3005A EPA 7470A EPA 8260C ASTM D2216-05M QC Batch 349768 350108 350048 349510 Analytical Method EPA 6010D EPA 7470A Analytical Batch 349775 350149 Date: 06/12/2024 04:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wrAitttetancchomnseenntt 1of0PPaacegeAn1a4lytoicfa1l 7Services, LLC. 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