Document Yrjy8Ba9MyBmXak2wOwGxK1qE
AIRCO VINYL. ULSIONS
for all-weather exterior and Interior latex paints
N20616
GLD005952
A Division of Air Reduction Company
Incorporated
Mir Re d u c t io n Ch e mic a l & Ca r b id e Co .
150 East 42nd Street New York 17, N. Y.
GL0005953
RCO VINYL ULSIONS
for all-weather exterior | and interior latex paints
contents
Airco Vinyl Resins (Table) ............................................. 2
Vinyl Latex Paints....................................................... ' 3
FLEXBOND PVAc Copolymer Emulsions.................... 7
11 *-&'3
IS
14
SMjj SlS
16 g|
18 m
18
19
Polymers Department
GLD005954
2
f.jpyyin; ivy ijHUjjwi i.i in l i,u luiiuwjiwi.^y
.V.
VINYL RESINS
6RADE
DESCRIPTION
FILM
WATER t
CLARITY-. S RESI5TANCEM EXTERIOR ;
FLEXBOND* Copolymer polyvinyl acetate emulsions
800 811 855
Very flexible, high molecular weight
Flexible, high molec ular weight
Fine particle size; high flexibility; high PVC formulations
Clear ^Ecelieri0
Clear JDrcellentJ;
'Clear,' FittSf
-^SPs?
MmMm,
M
FLEXAC Polyvinyl acetate homopolymer emulsions
FA-5
High molecular weight; clear, glossy, excellent film former even at low tempera tures
Clear
jjpi
ii- rate*,7-. - I..V&
VINAC* Polyvinyl acetate homopolymer emulsions
WR-50 Clear, water-resistant
films, borax stable
Clear
VINAC Polyvinyl acetate beads (resin in solid form)
B-7 8-15 B-25
Small, glass-1 ike spherical beads; nonblocking on storage, without refrigeration. All pass 8-mesh screen, dissolve read ily in wide range of solvents. Films are clear, glossy, non toxic, water resistant
"Clear;
Clear:
Clean-
Cjv iV' -Vri' :
-l
GL0005955
In less than a decade, vinyl latex paints have captured an important share of the paint market. Their sales appeal has established them as the leader for interior use and now their application and per* formance advantages are extending this leadership to exterior paints.
The widening market for vinyl latex paints has been stimulated by advances in polymer technology and by the development of vinyl emulsion vehicles designed for specific applications. The Colton Polymers Department of Air Reduction Chemical & Carbide Com pany, a division of Air Reduction Company, Inc., is a pioneer in the development of polyvinyl acetate copolymer resins and emulsions. In addition to paints, Airco resins and emulsions are used extensively in the manufacture of adhesives, textiles and paper.
Three types of Airco vinyl emulsions are available for paint manu facturing applications: FLEXBOND copolymer polyvinyl acetate; FLEXAC polyvinyl acetate; VINAC polyvinyl acetate. Each has properties and characteristics which make it suitable for specific applications. This manual has been planned to help the paint formulator in determining which PVAc emulsion would be best for his manufacturing and formulating procedures and for his end product
ADVANTAGES OF VINYL LATEX PAINTS
Vinyl latex paints have become the first choice for interior use on the basis of their consumer appeal. Quality appearance, low odor level, rapid drying, and ease of clean-up established their leadership for interiors. For exterior use, they also offer superior tint retention and resistance to dirt and chalking. Vinyl latex paints form a "breathing" film which allows the evaporation of moisture from exterior surfaces and prevents blistering.
To the paint manufacturer, the advantages of vinyl latex bases in clude unusual ease of formulation and manufacture, low odor level and nonflammability.
While these advantages are found in most vinyl latex paint formula tions, finished paints exhibit a wide range of performance properties, governed by the emulsion vehicle used. Each emulsion has distinctive physical properties which influence the performance of the finished paint. One of the key factors is the molecular weight of the polyvinyl acetate emulsion. Another is the presence of a plasticizing comon omer. Both the type and percentage of comonomer are important. Other factors include the particle size and the type of emulsifier sys tem. In a high quality emulsion, high molecular weight, combined with high comonomer content, produces paint films which are out standing for toughness, flexibility, resistance to thermal shock and shock from airborne particles, and resistance to ultra-violet light. Examples of such quality polymers are FLEXBOND 800 and FLEXBOND 855.
Airco FLEXBOND copolymer resins are among the highest molec ular weight PVAc emulsions on the market today. The film-forming properties of polymers and correspondingly, the performance qual ities of vinyl paints are related directly to molecular weight. As molecular weight increases, there are corresponding improvements in the physical properties of films, with the "highest polymers" form ing the toughest films. Comparisons of intrinsic viscosity measure-. ments of a large number of emulsions point up the high molecular
VINYL LATEX PAINTS
GLD005956
4 weight of FLEXBOND copolymers. In addition, FLEXBOND resins
are linear polymers with almost negligible crosslinking. These properties contribute to the toughness of films and to good paint flow
characteristics.
The comonomer content of Airco FLEXBOND resins contributes to flexibility and freedom from shock-brittleness. The percentage of comonomer present in FLEXBOND resins could not be tolerated by low molecular weight resins without excessive tackiness. The com bination of high comonomer content plus high molecular weight produces films which are inherently tough and flexible, even at low temperatures. These characteristics make FLEXBOND copolymers ideal for exterior paints.
Airco research and development on copolymers continues, aimed at tailoring resins to maximize key properties, such as adhesion to chalky surfaces.
TECHNICAL SERVICE
Airco's staff of polymer specialists at the Paint Technical Service Laboratory in Cleveland, Ohio, combines a thorough knowledge of resins and emulsions with practical experience in the paint industry. Supplementing this background in applications is the basic research on polymers conducted by the Central Research Laboratories of Air Reduction Company, Inc., at Murray Hill, New Jersey. Research and development on surface active agents is centered at Airco Chemical & Carbide's Bound Brook, New Jersey laboratories.
To serve customers throughout the nation, Air Reduction Chemical & Carbide maintains sales offices and warehouses in principal cities.
GLOOO^
Airco's Paint Technical Service Supervisor J. H. Fickenscher, Paint Specialist Lee Newman, and Technical Manager H. L. Jaffa call on paint manufacturers throughout the nation. Airco Technical Service specialists are available to assist with advice on formulations, manufacturing procedures, storage and handling, etc. They are prepared to work with manufacturers who wish to explore the advantages to be
gained from polymer technologybroadening product lines, improving formulations, reducing production easts, increasing profit margins,
5
Technically trained sales representatives are supplied with up-todate information on new products and applications. Customer serv ice includes the prompt handling of orders, sample requests, and requests for technical service.
Airco resins and emulsions are produced at Cleveland, Ohio; Elkton, Maryland; and City of Industry, California. Their quality is assured by Airco control of the key steps of manufacture from the basic raw materials, calcium carbide and acetylene, through the production of the intermediate vinyl acetate to the preparation of the finished polymer.
Exterior house paints based on s variety of systems are being evaluated by Airco in a now housing development in suburban Parma, Ohio, in only 2 years' exposure the superiority of FLEXBOND based paints Is apparent Like the house shown at near left the houses painted with FLEXBOND formulations still look freshly painted, bright, and clean.
610005958
8 Pane! A-G, painted with FLEXBOND 800 emulsion, demonstrates the Importance of high molecular weight and high eemonomer content for exterior use. Commercial low molecular weight emulsions were used on panels A-45 and A-80. All three paints were
at 25% PVC; two coats were applied directly to imprinted white pine. The panels were exposed three years, 45* S, at Elkton, Md.
Although FLEXBOND 811 is similar in most respects to FLEXBOND 800, it does not have the same high degree of flexibility and elongation. To obtain optimum film formation, baking is recom mended. Films of this material, whether clear or pigmented, exhibit color stability, even under adverse conditions.
FLEXBOND 855 -- A Fine Particle Size, Highly Flexible Terpolymer Emulsion
FLEXBOND 855 permits the formulation of paints with very high pigment concentrations. An extremely high PVC may be obtained without the use of film-forming aids which are present in many other emulsions and which may impair freeze-thaw stability. Films of FLEXBOND 855 combine high clarity and gloss with good waterspot resistance and flexibility. Excellent scrub resistance and stain removal are obtained even at 60% PVC and higher. Many fine particle size PVAc emulsions have a relatively low molec ular weight and as a result their films are lacking in toughness and resistance to shock. However, FLEXBOND 855 combines fine par ticle size with the advantages of high molecular weight. Paints based on FLEXBOND 855 also offer exceptional color development, and excellent flow and levelling. FLEXBOND 855 is a popular vehicle for the formulation of roof paints. The flexibility of FLEXBOND 865 permits the paint film to expand-and contract with the dimensional changes which occur-in roofing materials.
Painted In 1356, this shingle house in Madison, New Jersey, Is still a bright blue and does not need
repainting. Before being painted with a FLEXBOND formulation, this
suburban house had to be repainted every three years with oil paint.
10
PHYSICAL PROPERTIES
Total Solids Viscosity* Odor Color pH Free Monomer Particle Size Mechanical Stability** Solvent Tolerance*** Weight per Gallon Solids per Gallon (approx.) Borax Stability
55-57% 800-1200 cps. Very slight VVhite-Milky 5.0-6.5 Less than 0.4% 0.5 Micron Excellent Good 9.2 lbs.
5.15 Excellent
* Brookfield Viscometer Model LVF (#3 spindle/60 RPM/77*F.) ** Hamilton Beach Mixer #33 (high speed) *** Emulsion diluted with 95% ethanol to 18% diluent
FLEXAC FA-5
FILM PROPERTIES
Density Clarity Gloss Heat Stability* Light Stability Aging Characteristics Film Formation** Water Resistance
1.18grams/cc. Clear, water white High Very good Very good Excellent Excellent Excellent
* Three hours at 300"F. ** Polymer should be plasticized to obtain maximum film properties
GL D005961
A High Molecular Weight Emulsion for Interior Use
11
FLEXAC FA-5, a polyvinyl acetate homopolymer, is recommended for the manufacture of interior paints, semi-gloss finishes and floor paints. It is not designed for exterior use.
Outstanding properties of interior paints made with FLEXAC FA-5 are: high critical pigment volume concentration; excellent scrub resistance and stain removal, and superior low temperature coalescence.
The high molecular weight of this homopolymer produces films and paints with unusual toughness and resistance to abrasion and shock. Coupled with these properties is the inherent flexibility of a film which requires a low level of additional plasticizer.
The high pigment binding capacity of FLEXAC FA-5 enables the formulation of interior paints at a low raw material cost, without detracting from scrub resistance, stain removal, and other important paint properties. The ability of FLEXAC to form films at low tem peratures makes it ideal for paints which are to be used in new construction, where low temperatures may prevail for a large part of the year.
With its high gloss, clarity and superior water-spot resistance, FLEXAC FA-5 produces an excellent semi-gloss paint. Additional resins are not required to impart hardness and tack-free films, since FLEXAC FA-5 films are inherently tack-free and hard at room temperatures. Pigment volume concentrations as high as 17% and 18% have been used with this resin to formulate semi-gloss paints with a 60 gloss meter reading of over 60.
Film gloss and hardness also make FLEXAC FA-5 an ideal base for emulsion floor paints. Water resistance, ease of cleanup and stain removal, as well as wet and dry abrasion resistance, are obtainable in floor paints. A semi-gloss FLEXAC FA-5 formulation, tested over cement panels on a Gardner Straight Line Scrub Tester, withstood 4,000 cycles. (This test was run both dry and wet, with a diaper cloth and pumice.) A sample of this paint has been used in high traffic plant areas, including a concrete shipping dock, which is exposed to weather at all times. Durability on these exposures has been remarkable.
FLEXAC FA~S
Painted In October, 1957, this Northfield Center, Ohio, house Indicates the durability of a FLEXBOND formulation on a variety of surfaces. Asbestos shingles, clapboards, and masonry surfaces are still bright red, unmarred by chalking, cracking, or blistering.
GLD005962
12
PHYSICAL PROPERTIES
Total Solids Viscosity* Odor Color pH Free Monomer Particle Size Mechanical Stability** Solvent Tolerance*** Weight per Gallon Solids per Gallon (approx.) Borax Stability
55-57% 1100-1400 cps. Very slight Milky white 4.5-6.0 0.5% max. 0.5 Micron Excellent Good 9.25 lbs.
5.15 Excellent
* Brookfield Viscometer Model LVF (#3 spindle/60 RPM/77*F.) ** Hamilton Beach Mixer #33 (high speed). *** Emulsion diluted with 95% ethanol to 18% diluent.
VINAC WR-50
FILM PROPERTIES
Density Clarity Heat Stability* Light Stability Film Formation Water Resistance
* Onehourat300*F.
1.19grams/cc.
Clear
Good
Excellent Excellent Very good
GLD005963
A Water Resistant PVAc Homopolymer
VINAC WR-50 may be formulated into paints for many types of surfaces--wood, plaster, fiberboard, acoustical tile, concrete, cinder block, asbestos, and gypsum. VINAC WR-50 may be used without a plasticizer, or modified with a suitable plasticizer to obtain desirable properties. It is being used commercially as a vehicle for exterior paint applications. VINAC WR-50 also makes an excellent primersealer.
One of the interesting uses of VINAC WR-50 is in ready-mixed joint cements and speckling compounds. With VINAC WR-50 it is possible to load pigments into the joint cement ("mud") or spackling com pound without breaking the emulsion. The ability to tolerate high pigment loadings and also to produce excellent bonding of tape to board is unique to VINAC WR-50 and has added to its value aB an easy-to-handle emulsion.
Complementing VINAC WR-50 as a base for joint cements and spackling compounds are two polyvinyl acetate homopolymers in powder form, VINAC RP-250 and VINAC RP-251. As white, redis persible powders, VINAC RP-250 and VINAC RP-251 are ideal for the formulation of dry joint cements and spackling products. A de tailed bulletin on VINAC spray dried powders describes the use of VINAC RP-250 and VINAC RP-251 in these products. Suggested formulations on the use of VINAC WR-50 in joint cements and spack ling compounds are also available from Airco's Paint Technical Service Laboratory,
IS
VINAC WR-SO
neXBOND, VINAC, end FLEXAC emulsions are produced a! this new plant at City of industry (near los Angeles), California, and at Cleveland, Ohio, and Elkton, Maryland. The Elkton plant also produces dibutyl maleate and dibutyl phthalata. SURFfNOL surface active agents are produced at Bound Brook, New Jersey, and Cslvart City, Kentucky, where Alroo manufactures high-purlty vinyl acetate monomer.
GID005964
14 SUGGESTED FORMULATIONS
One of the outstanding advantages of polyvinyl acetate emulsions is the case with which they can be formulated into quality paints. FLEXBOND copolymer emulsions are particularly easy to handle because additional plasticizers are not required. FLEXBOND, FLEXAC, and VINAC paints are formulated according to proced ures which are familiar to the paint industry. Formulations for the basic types of interior and exterior paints are shown on the following pages. These formulations were developed in A rco's Paint Technical Service Laboratory to assist paint chem ists in the development of their own commercial formulations. Aires's suggested formulations show which surfactants and pig ments should be used to obtain the optimum benefits from a particular emulsion system. The raw materials suggested in these formulations are listed on page 20. The list includes alternate materials which could be substituted, without detracting from the properties of the emulsion system. Any subs:itution, of course, affects the properties of the formulation and each change should be studied carefully for its effect upon other raw materials and its contribution to the finished paint.
MANUFACTURING PROCEDURES
In the suggested formulations which follow, materials are listed in the recommended order of addition. The materials are handled in three basic steps--preparation of the pigment paste, grinding the paste, and the "let down" of the finished paint. Conventional paint manufacturing equipment is suitable for each step. Except for the
Airco maintains test fences at Elkton, Maryland (right);
Murray Hill, New Jersey; Miami, Florida; and Los Angeles, California.
Emulsion vehicles and exterior formulations are evaluated carefully tc meet the needs of paint manufacturers
in all parts of the country.
use of water as a medium, the handling of polyvinyl acetate paints is similar to the handling c-f conventional paint systems.
In the first step of formulation, the pigment pastfe is started from a mixture of water, surface active agents, thickener, freeze-thaw sta bilizer and antifoam. After these materials have been thoroughly mixed, the prime pigments and ex'.enders are added incrementally. In order to develop maximum shear during the mixing operation, the paste must be kept fairly heavy and a final viscosity adjustment should be made prior to milling. The paste dispersion can be ground efficiently by high speed mills, or by pebble or stone mills.
The "let down" ordinarily is carried out in a thinning tank which has low speed agitation. At ihis point, the balance of film forming aids, wetting agents, thickeners or antifoamers is added. When these materials have been stirred thoroughly into the paste, the required amount of emulsion is added. It is important at this step to avoid vortexing which may cause foaming problems. After a final vis cosity adjustment with thickener solution or water, the paint is ready for packaging.
SUGGESTED FORMULATIONS
ADDITIONAL FORMULATIONS
In addition to the suggested formulations presented for FLEXBOND 800, FLEXBOND 855, FLEXAC- FA-5, and VINAC WR-50, other formulations on these emulsions are available. New formulations using these emulsions in other type? of paints are issued periodically by the Paint Technical Service Laboratory. Also available are formu lations for the use of FLEXBOND 811 in industrial coatings and up-to-date formulations using Colton Polymers in government spec ifications for PYAc paints. Formulations for thixotropic paints have also been prepared, in a range of raw material costs.
PRIMER SEALER 80010
1. Cellosize QP-4400 (3%Solution).............. 130
2. Potassium Tripolyphosphate................... 2
3. Colloid 581-B............................................. 2
4. Ross & Rowe 551............................. -....... 5
5. PMA-18........ ............................................ 0.3
6. Ethylene Glycol........ ................................. 18
7. Titanox RA-50............
75
8. ASP-400.............
no
9. Wollastonite P-1 ....................................... 55
10. Water..............
200
11. Carbito! .........................................- 16
12. FLEXBOND 800 ................................. - 415
SOLIDS: ...................................................44.4% PVC:........-...-...... ........ .......-................. 29-9%
YIELD: .... .............. ....................... 100 gallons RAW MATERIAL COST:................. $1.10/gallon VISCOSITY:....................................75 2 K. U.
EXTERIOR TINT BASE 80015
1. Natrosol 250 High (2% Solution)............. 200
2. Nopco NDW...................................... -......... 2
3. Tamol731...
2
4. SurfynolTG
.
4
5. Ross & Rowe 551.......
3
6. Ethylene Glycol ........................................... 25
7. PMA-18
6
8. Ti-Pure R-610 ...........
..150
9. Lorite ............................................................115
10. Water ............................................................155 11. Carbitol Acetate.. ........................................ 13
12. FLEXBOND 800............................................ 380
SOLIDS:... ........
44%
PVC:...........
.....32.2%
YIELD:..............................................100 gallons
RAW MATERIAL COST:.................. $1.35/gallon
VISCOSITY:.................. ................ 88 2 K. U.
INTERIOR FLAT (LOW COST) 80013
1. Methocel 65-HG, 4000 cps. (3% Solution) 180
2. Tamol 731 -...........
3
3. Igepal CO-610....................... ................. . 4
4. Nopco NDW............
2
5. Ross & Rowe 551.............
2
6. Ethylene Glycol........................................ 25
7. PMA-18 ................................................... . 0.3
8. Titanox RA-50 ...............
..125
9. Zeolex 80 ................................................ 30
10. Satintone *1..........
.100
11. Asbestine 3X ...........
..150
12. Water ......... 13. Butyl Carbitol Acetate....................
285 6
14. FLEXBOND 800......
210
SOLIDS: ..........................
45.9%
PVC:..........
.--59%
YiELD:.............................................100 gallons
RAW MATERIAL COST:.................. $0.98/gaflon
VISCOSITY:................................... 80 = 2 K. U.
EXTERIOR WHITE 80014
1. Natrosol 250 High (2% Solution) _ .... .........200
2. Polyglycol P-1200 .......... ......... ... ............... 3
3. Igepal CTA-639 -........ -- -... ........ . 2
4. Ross & Rowe 551_______ .... ........ --....... 3
5. Ethylene Glycol .... --.......... ..... ------------ 25
6. PMA.gft
ft
7. Nnpr.n NOW
9
8. Titanox RA-50 -......... ............. ________225
9. Titanox A-168-LO ..................-___- -.... ..... 25
10. Nytfli ann
7n
11. Water_____ .. ............. ....... ... --.........195 32. Carbitol Acetate ____________ ......... ..... 12
33. FLEXBOND 800 ............... -... .. .. ......... -.340
sni ms-
46%
PVC:
. ... -.........-... . ................36%
y if i n.
101 gallons
RAW MATERIAL COST:....... ........ $1.52/galton
VISCOSITY: - . ____
.92 A 2 K. U.
INTERIOR FLAT 80011
1. Methocel 65-HG, 4000 cps. (3% Solution) .160
2. Tamo' 731________-_________ _--........ 5
3. Surfynol TG-----------
3
4. Nopco NDW 2
5. Ethylene Glycol ---- ------------------.---------25
6. PMA-18 ................. ................... ... ........... 0.3
7. Titanox RA-50 -__
...225
8. Zeolex 80.........
15
9. Carbium------------
135
10. Cetite 281__________
35
11. Water......-- ---------
220
12. Butyl Carbitol Acetate----------------- -- -- 8
13. FLEXBOND 800
310
SOLIDS:___________________________ --50% PVC:___ _________________________47.5% YIELD:....... ............ ........... -.... . 100 gallons RAW MATERIAL COST:$1.39/gallon VISCOSITY:_____________ ______87 2 K. U.
INTERIOR TINT BASE 80012
1. Methocel 65-HG, 4000 cps. (3% Solution) .160
2. Tamol 731 2
3. Ross 4 Rowe 551------------------------------- 3
4. Igepal CO-610_____________ 4
5. Nopco NDW 2
6. Ethylene Glycol --..........--------------------- 25
7. PMA-18 _________________ ____ ______ 03
8. Titanox RA-50 -150
9. Lorite50
10. Carbium__________________________ 150
11. Celite 281_____
35
12. Water____________________________ --198 13. Butyl Carbitol Acetate-------------------------- 8
14. FLEXBOND 800 330
SOLIDS:49.8%
PVC:45.9% YIELD:100 gal Ions RAW MATERIAL COST:$1.22/gallon VISCOSITY:85 2 K. U.
G L000596'?
PRIMER SEALER 85510
Cellosize QP-4400 {3% Solution) Potassium Tripolyphosphate... ...
Colloid 581-B................. ........ -- Ross & Rowe 551............. ...--..Ethylene Glycol _....... .... -...........
Bufen 30..... ...........-...........-...Unitane OR-54Q........... ... ..... -
Lorite ..... .... ................ .............. Mistron HGO-75........................
Water ........ ................................. Carbitol ......... .............. --......-
12. FLEXBOND 855 ...........- --
..... ..370
SOLIDS: ...... .... ...... ....
PVC:......... _.................. YIELD: -............ .... .. RAW MATERIAL COST: VISCOSITY:........ ..... ...
.........45.2%
... ..... 35.6% .102 gallons
H.05/gal)on 12 2 K. U.
EXTERIOR TINT BASE 85515
Natroso! 250 High (2% Solution)......... ...... 250
Tamol 731.............................. -....... ....... -- 4
Nopco NDW................................................. 2
Ethylene Glycol....................... .................... 25
PMA-30... .........
6
Ti-Pure R-610 ........ _... ........ -.... ........ -.... 150
Camel-TEX ....... ... ...... -............. -.............. 75
Lorite.. .....
75
Potassium Carbonate............. -.............-..... 1
Water .............
-125
Carbitol Acetate.......... ............................. 12
Igepal CO-610... .........
3
13. FLEXBOND 855 ............
--350
SOLIDS: ... ............... .......-.... -..............-45.7% PVC:..................... ........... -........... -..........35.9% YIELD:.......................................... . .101 gallons RAW MATERIAL COST:.................$1.33/gallon VISCOSITY: .... ................ .............90 2 K. U.
INTERIOR FLAT (LOW COST) 85513
Cellosize QP-4400 (3% Solution)............. 190
Tamol 731...._................ ...................... ..... 5
Igepal CO-610.. ....................................... 3
Nopco NDW .. ..
..................- 2
Ethylene Glycol .......................... ........ 25
PMA-30 ..........
....... ............ 0.3
Unitane OR-54C
120
Zeolex 80... ........................
40
Satintone #1.......
............... --100
Asbestine 3X......
150
Potassi urn Carbonate ........................... . 1
Water ............ _............... ...... ..............-.295 Butyl Carbitol Acetate........... ................-- 5
14. FLEXBOND 855 ........................
200
SOLIDS: ..............................1 ... 1145.8% PVC:......... ............... ........ ... ....................59.4% YIELD:........ ....................................101 gallons
RAW MATERIAL COST: ..........- $0.96/gallon
VISCOSITY:................................... 83 2 K. U.
EXTERIOR WHITE 85514
Natroso! 250 High (2% Solution) Polyglycol P-1200 ____________ Igepat CTA-639 4. Ross & Rowe 551 5. Ethylene Glycol 6. Nopco NDW 7. PMA-30 8. Titanox RA-50
9. Titanox A-168-LO 10. Nytaf 300
11. Water 12. Carbitol Acetate
13. FLEXBOND 855
smins-
4R%
PVC-
sn 7*
y ip i rv
RAW MATERIAL COST:
$1
VISCOSITY:.... _ ... ____ ____90 + ifK. U.
INTERIOR FLAT 85511
\
Cellosize QP-4400 (3% Solution) Nopco NDW
Tamol 731 Surfynol TG. Ethylene Glycol
PMA-18 Unitane 0R-540
Al-Sil-Ate W Camel-TEX
Gold Bond R_______ Potassium Carbonate
Water Butyl Carbitol Acetate
14.
soi ins-
4ft 7%
PVCYIFI rv
R1.4% QQmltniM
RAW MATERIAL COST:
$1 .r>7ea,!fm
VISCOSITY:________ ____ ... .. 87 2 K. U.
INTERIOR PUT TINT BASE 85512
Cellosize QP-4400 (3% Solution) Nopco NDW Tamol 731 Surffnot TG Ethylene Glycol ..... PMA-30 Unitane OR-540 Camel-TEX Lorite Gold Bond R Potassium Carbonate
12.
Butyl Carbitol Acetate
14. FLEXBOND 855
.225 .260
SOLIDS:
PVC: YIELD: RAW MATERIAL COST:
VISCOSITY:__________
...4ll%
.51.7% .100 gallons .$1.10/gallon
2 K. U.
GLD005968
1. Methocel 65 HG,4000 cps. {3% Solution) ..160
2. Colloid 581-B ..........-.............
2
3. Tamol 731......... -......-........-...................... 5
4. Ethylene Glycol -.........
25
5. PMA-18 ........... -......-.......... -...-......-....- 0.3
6. Ti-Pure R-510..... .... .........._............... ......200
7. Zeolex 80.................................. -...... -...... . 25
8. Asbestine 3X ...................
140
9. Lorite .......
100'
10. Potassium Carbonate..... ..............
1
11. Water .......
290
12. Igepal CO-610 ... ..................................... 3
13. Carbitol Acetate............
12
14. FLEXAC FA-5..................
200
15. AIRCOFLEX DBP ................................. 10
SOLIDS: .......
49.9%
PVC:..............
57.3%
YIELD:......................................... .......100 gallons
RAW MATERIAL COST:.....
.....$U6/galkm
VISCOSITY:............ .......................89 2 K. U.
PRIMER-SEALER FA-510
Methocel 65 HG, 4000 cps. {3% Solutionhl55 Colloid 581-B
Tamol 731
Igepal CO-610
Etthyieine Glycol
PMA-18______
. 0.3
Ti-Pure R-510.....
..100
Gamaco______
.100
ASP-400______ Potassium Carbonate ...
.. 75
_1
Water____ _________ Surfynol TG_________ Carbitol
.241
-2
.. 16
FLEXAC FA-5..... AIRCOFLEX DBP
.320 .. 13
SOUbS: .......
PVC:____________
YIELD: RAW MATERIAL COST: VISCOSITY:............... ..
______ 36% .100l gallons _..$1.04/ga!lon ..~78 2 K. U.
INTERIOR FLAT (LOW OOStf
FA-513
1. Methocel 65 HG, 4000 cps. (3% Solution) .135 2. Colloid 581-B 2 3. Tamol 731___________ 5 4. Ethylene Glycol 18 5. PMA-18 0.3 6. Ti-Pure R-510_____________________ 150 7. ASP-100:._____________________ 125 8. Gamaco175 9. Ceiite 28150 10. Potassium Carbonate 1
11. Water _____________________________ 344 12. Surfynol TG 3 13. Carbitol Acetate 8
14. FLEXAC FA-5_________________________ 155 15. AIRCOFLEX DBP____________ _________ 9
SOLIDS:_____ ___________________ --50.3% PVC:------------------------------------------------- 68% YIELD:_________________________ 100 gallons RAW MATERIAL COST:$0.93/gaiion VISCOSITY:____________________82 2 K. U.
1. Cellosize QP-4400 (3% Solution) ........... 175 2. Colloid 581-B ........................... ...... ..... 3 3. Tamol 731 .................................. ...... ..... 5 4. Surfynol TG................. ........ ....... ............ 3 5. Ethylene Glycol.......................... . ....... 25 6. PMA-18 .................... -....... .... ..... ............ 0.3 7. Horse Head R-750....................... ............. 100 8. Snowflake White...... .................. ........... . 75 9. AAP-^nn
10. Water .......................................... ............ 270 11. Carbitol Acetate........... ... ............ ............ 8
12. VINAC WR-50 ............................. .............235 13. m
SOLIDS:
..........................
40.6%
PVC:....... ................ .. ................ .......... 36.3%
YIELD: ...... .... .... ........................ ... 100 gallons
RAW MATERIAL COST: ............. . $0.95/galion
VISCOSITY:................................. 74 2 K. U.
1. Cellosize QP-4400 (3% Solution)
-.150
2. Tamol 731
5
3. Ross & Rowe 551..... --.......
2
4. Surfynol TG
._
.. - 3
5. Colloid 581-B .... . .... ...
. _2
6. Ethylene Glycol
.... _ 20
7. PMA-18
. . 0.3
8. Horse Head R-750 ............
-.225
9. Snowflake White
.315
10. ASP-100
50
11. Ceiite 281
- 35
12. Water 13. Carbitol Acetate
______265 8
14. VINAC WR-50 15. AIRCOFLEX DBP
.:
Pfifl 10
SOLIDS:
503%
PVC:
.... .50.3%
YIELD:
............,, .100 gallons
RAW MATERIAL COST:________ _ $1.29/gallon
VISCOSITY: - . ___ ...... .85 + 2K.U.
GLD005969
SHIPPING -- HANDLING -- STORAGE
Airco emulsions are available in drum, tank truck, and tank car quantities. Drum shipments are available in 5, 10 and 30 gallon drums, lined 55 gallon open-head metal drums and 55 gallon liber drums. Emulsions should be stored and compounded in tanks made of wood, stainless steel, glass coated steel or steel which has been coated to resist acidic corrosion. Engineering information and tech nical assistance on storage tank installations are available from Airco. Polyvinyl acetate emulsions exhibit good stability when stored under normal conditions. It is advisable, however, to use shipments within six months. Since emulsions may freeze, proper precautions must be taken during cold weather. Storage areas should be kept above 50eF. During storage, some stratification of the emulsion may occur. Strati fication may be corrected by rolling or agitating containers before using the emulsion.
The information end recommendations contained In this bulletin are. to the beat of our knowl edge, accurate and reliable. No guarantee of their accuracy it made, however, and the products discussed are sold without warranty, express or implied, and upon condition that the purchasers shall make their own tests to determine the suitability of such produets for their particular purposes and uses. Nothing in this bulletin constitutes permission or a recommendation to practice or use any invention covered by any patent owned by this company or by others.
1$
1. Cellosize QP-4400 (3% Solution} ____ __145
2. Colloid 581-B ............... ............ .____
2
3. Tamol 731..... --.... ............... -... _____ 5
4. Ethylene Giycol -....... --..... ...... ............ 25
5. Ross & Rowe 551................. .... ............. 2
6. PMA-18 ......... ......... ............... . ............. 0,3
7. Horse Head R-750............ .......-- .......... ..170
8. Snowflake White ...... ......... .... . ............ 150
9. ASP-100 .......... ............. ....- ............ 50
10. ........... .100
11. Water ................ ............ ........... ....... ......305
12. Carbitol Acetate ... ................... .......... 8 13. Surfynol TG ..... .. ....... ..... -- . .. . 3
14. VINAC WR-50 .......... ............ ...... ______ 200 15. AIRCOFLEX DBP____ _________ ...... ...... 11
SOLIDS: ................................... ............50.2% PVC: ............. ..... ........ .......... .........._59.7% YIELD;............ ........................... .... 100 gallons
RAW MATERIAL COST;... .......... ...$L04/ga(fon VISCOSITY;... ....... ............... ...... . 80 2 K. U.
CL0005970
1. Cellosize QP-4400 (3% Solution)200 2. Tamol 731------------------------------------------------5
3. Ross & Rowe 551-______________________ 2 4. Colloid 581-B2
5. Ethylene Glycol25
6. PMA-186
7. Titanox RA-50200
6. Tltanox A-16S-L020
9. Nytal 30050
.10. Water225
11 Carbitol Acetate------------------------------------ 7
12. Surfjnol TG3
13. VINAC WR-50 14. AIRCOFLEX DBF
.300 . 25
SOLIDS:-- -------------------------
PVCr______________________
YIELD?______._______;__
RAW MATERIAL COSfs ___ VISCOSITY: --___ _________
;______ 43% _____ 30.5% .101 gallons $1.43/gailon
85 2 K. U.
20
RAW MATERIAL LISTING
ADDITIVES Thickeners: Cetosize WP-300 Cel osize QP-4400 Cetosize QP-1S000 Methocel 65 HG 4000 cps. Methocel 65 KG 400 cps. Natrosol 250 Medium Natrosol 250 High
Dispersants and Wetting Agents: Igepat CO-610 Igepal CO-630 igepal RC-520 Igepal CTA-639 Potassium Tripolyphosphate
Ross & Rowe 551 Surfjnol TG Tamol 731 (25% Solution) Tergitoi NPX Tergitol NP-14
Ant foams: Colloid S81-B Nopco NDW Polyglycol P-1200 Surf?nol 104-A Surtfnol 104-E
Film Formers: Carbitol Carbitol Acetate Butyl Cellosolve Acetate Butyl Carbitol Acetate
Freeze Thaw Stabilizers: Ethylene Glycol Diethylene Glycot
Mildewcides: PMA-1B Troysan PMA-30 Bufen 30 Key X-10
Plasticizers: Aircoflex DBP Berzoflex 9-88
PRIME PIGMENTS Titanium Dioxide: Horse Head R-750 Horse Head R-760 Ti-Pure R-510 Ti-Pure R-610 Tv-Pure R-900 Ti-Pure FF Titanox RA-50 Titanox RANC Titanox A-168-LO Unllane OR-540
Union Carbide Chemicals Company
The Dow Chemical Company Hercules Powder Company
Antaira Chemicals DivisionGeneral Aniline & Film Corp.
Victor Chemical Division-- Stauffer Chemical Company
Ross & Rowe, tnc. Air Reduction Chemical & Carbide Co. Rohm & Haas Company
___ ^-i- ssi..
Colloids, Inc. Nopco Chemical CoDow Chemical Company Air Reduction Chemical & Carbide Co.
Union Carbide Chemicals Company
Nuodex Products Co. Troy Chemical Co. Buckman Laboratories, Inc. Key Chemicals Corporation
Air Reduction Chemical & Carbide Co. Tennessee Products & Chemical Corp.
New Jersey Zinc Company E. I. DuPont de Nemours & Co., Inc.
Titanium Pigment Corporation
American Cyanamld Company
GLD005971
COLOR DISPERSIONS California Ink Company, Inc. E. I. DuPont de Nemours & Co., ine. Harshaw Chemical Company Holland Color & Chemical Company Imperial Color Chemical A Pacer
EXTENDER PIGMENTS Calcium Carbonates; Camel-CARS Camel-TEX Camel-WITE
Carbium Gamaco Cal White Snowflake Duramite Witcarb Vi-Cron
Clays: ASP-100 ASP-400 Satintone #1 Attagel 30 Al-Sil-Ate 10 Al-Sil-Atew Hydrite Flat Hydrite PD-10
Mica: 325 Mesh. Water Ground Mineralite 3X
Silicas: CeliteSSl Oustex Micro Silica Gold Bond R 1160 Silica
Talcs: Asbestine 3X Mistron HGO-75 Nytal 300
Proprietary Extenders: Lorite Wollastonite P-1 Zeolex SO
Harry T. Campbell Sons' Inc.
Oiamond Alkali Company The Georgia Marble Company ThompsoivWeinman & Company Witco Chemical Company, tne. C. K. Williams A Company
Minerals & Chemicals Philipp Corp.
Southern Clays, Inc. Georgia Kaolin Company
The English Mica Company Mineralite Sales Corp.
Johns-Manvllle Company Tamms Industries, Inc. Innis-Speiden A Company, Inc.
International Tale Sierra Talc A Clay Company R. T. Vanderbilt Company, Inc.
DeLore Division, National Lead Co. Godfrey L Cabot, Inc. J. M. Huber Corporation
f>*tMTto H U. C. A.
CID005972
Gt-t>005973
Air Re d u c t io n Ch e mic a l & Oa r b id e Co .
A Division of Air Reduction Company, Incorporated * 150 East 42nd Street, New York 17, N. Y.
PH-1061-10M