Document Yr9oBJQzN08VaweVwzbm4zO3k

BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) 6S689 PRODUCT: SPEC-AID 8Q302 .......... SECTION 7-------------------- SPECIAL PROTECTIVE EQUIPMENT-..................-................ USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE,REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES .......... SECTION 8--------------------STORAGE AND HANDLING PRECAUTIONS.............................. STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) >V* Vr*** VoWrih'r*****V<-->V**Vr *iWnhV>Wr* *-A"*VoV*sWf*VoV**AtAdWc *A-jWnV-Jr* APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. . . . TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: 3,548 GALLONS DUE TO (078);12,774 GALLONS DUE TO (162) . . . RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D001=IGNITABLE ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NAl993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: TRADE SECRET(078)--ALKYL AROMATIC , 2.0-5.0% ; TRADE SECRET(162)--ALIPHATIC ALCOHOL , 2.0-5.0% ; ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: TRADE SECRET(078)--ALKYL AROMATIC ; TRADE SECRET(162)--ALIPHATIC ALCOHOL ; NFPA/HMIS : HEALTH - 2 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000006902 ' -l . l.FJ AL SA: . data shff ' % H> >\ JUl*. LAkt < fiAk. f V i A .* HOUR TtLt^HOSf (^U|f.2y?5S Stnct iW f S686 DATE! REVISED 12/20/&9 CHEMICfV. NAME AMI' SYtttNYMSt SECTION I - PRODUCT IDENTIFICATION MATERIAL SAFETY DATA SHEET TRADE NAME AMD SYNONYMS! tf.PHACHEM 1106 DETERGENT CHEMICAL FAMILY} FORMULA} PROPRIETARY SECTION II - HAZARDOUS INGREDIENTS PAINTS, MtfSDUAJI^S, * SOLVENTS I X TLV (Uniis) OTHER INGREDIENTS Solvents} I X I TLV (Units) HAZARDOUS MIXTURES Of OTHER LIQUIDS, SOLIDS, OR GASES} NONE X I TLV (Units) SECTION III - PHYSICAL DATA SOILING POINT <F4)J AFfflOX. 212 Decrees F VAPOR PRESSURE im. Hg.)i Wfc. Vtf>GR DENSITY <AIR=1)} IMx. SOLUBILITY IN WATER} 100X APPEARANCE AMD ODOR} CLEAR TO AHFER LIQUID WITH CLEAN, FRESH ODOR. | SPECIFIC GRAVITY (H20=l)i I i PERCENT, VOLATIUH I BY VOLUME (X) i ! i EV^-ORATION rate: I I_____Udter_____ -1) j | Appiox 1,024 NOT DETERMINED 1 SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLA*! POINT (Method Used)} NO*. EXTINGUISHING MEDIA*. NCWC NECESSARY Lei! Fl.ArtttABLE LIMITS Get; SPECIAL FIRE FIGHTING PROCEDURES} COOL FIF EXPOSED DRUMS WITH WATER TO AVOID RUPTURING THAT CAN RESULT IN SLIPPERY AND DANGEROUS FOOTING. unusual fire and dtlosion hazards: NC* SAL 000006903 *i . i LM X.u iv ' i- ' DATA SHEET P. O. BUX iUi. LAM CHAKuti. l.A 7'*>.. 24 HOUR TELEPHONE (31*1 625 7551 Srncf mi S6a$ MATERIAL SAFETY DATA StCET SECTION V - HEALTH HAZARD DATA APtVOCM 1386 DETERGENT THRESHOLD LIMIT VALUE: Uto. EFFECTS OF OVEREXPOSURE! CAN CAUSE SKIM IKYME8S AND IRRITATION TO DUS ON DIRECT CONTACT. EnOWjENCY AND FIRST AID PROCEDURES! MAY CAUSE IRRITATION IF SPIASCD INTO EYES. WASH EYES WITH FRESH WATER AND IT IRRITATION PERSISTS, SEE PHYSICIAN, WASH WITH FRESH WATER WITH CONTACT OF SKIN AND CLOTHING. TNGESriONi IF SWALLttED, CUE LAiiGE AMOUNTS OF WATER IF VICTIM IS COMPLETELY CONSCIOUS AND DO NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION. STABILITY I UNSTABLE I SECTION VI - REACTIVITY DATA I ' CONDITIONS TO AVOID! t STABLE I XXX I ! NCOMPAT IPILITY <K,iU*riAls to avoid)! MAID CONTACT WITH COWCDFTlSATra ACIDS. ALKALIES OR OXIDIZING AGENTS. HAZARDOUS IfCtmiSinON PROMCTS! NONE KNOWN HAZARDOUS POLYMERIZATION I MAY OCCUR I| I---------------------- ----------- I--------------J I WILL NOT OCCUR I XXX \ CONDITIONS TOAVOID! SECTION VII - SPILL OR LEAK PROCEDURES STEPS 10 BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED! WASH TO S&IER OR DRAINAGE WITH WATER IF ACCEPTABLE. MAY NEED TO ABSORB WITH INERT MATERIAL AND SHOVEL TO WASTE RECEPTACLE. WASTE DISPOSAL METHOD! DISPOSE OF IN ACCORDANCE WITH STATE. FEDERAL. AND LOCAL REGULATIONS. SECnON VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type)! NOE NECESSARY VENTILATION | LOCAL EXHAUST I SPECIAL! I WICHANICAL (General) I OTHER! GOCRit DILUTION PROTECTIVE GLOWS! RECOMMENDED | EYE PROTECTION! RECOW1ENDEB OTHER PROTECTIVE EQUIPMENT! SAFETY EQUIPMENT ADEQUATE TO WCID~FraLONa5TsK7N*AND"tTFcONTACyT. SECTION IX - SPECIAL PRECAUTIONS FY<EC,AUTIONS TO BE TAKEN IN HANDLING AND STORING: DO NOT TASTE OR SWALi.OW. WASH HANDS THOROUGHLY AFTER iMUMG. AVOID PROLONGED CONTACT WITH SKIN. DO NOT GET IN LYES. PREVENT CONTACT WITH FOOD, CHEWING AND SMOKING MATERIALS, OTHER PRECAUTIONS! SUGGEST THIS PRODUCT WOT Bf MIXED WITH CONCENTRATED ACIDS, ALKALIES OR OXIDIZING AGENTS. sM. 000006904 r CPC COASTAL PRODUCTS & CHEMICALS, INC. HOUSTON, TEXAS U.S.A. PRODUCT SAFETY BULLETIN ALUMINUM SULFATE IN AQUEOUS SOLUTION (LIQUID ALUM) AI2(S04)3* 49 H20 PHYSICAL DATA CHEMICAL NAME: ALUMINUM SULFATE - LIQUID COMMON NAME: LIQUID ALUM FORMULA: . . ai2(So4)3 49 H20 STATE: LIQUID (20C/68F - 14.7 psia) FORMULA WEIGHT: ............ 1224 86 SPECIFIC GRAVITY: .......... 129-134 (a) 15C/59F CONCENTRATION: .. 8 0-8.6 %-AI2C>3 BOILING POINT: .... 102C/215.6F MELTING POINT: ............ -10C/14F ODOR: .................. COLOR: ................ Clear, water white pH VALUE: .......... ................. 1.6 to 2.5 REACTIVITY/CORROSIVITY: Similar to dilute sulfuric acid Stainless steel and plastic are resistant to corrosion. STABILITY: Begins to decompose at temperatures above650C/1200F. Forms sulfur trioxide and aluminum oxide at temperatures above 650C/1200F. SAFETY PRECAUTIONS PERSONAL SAFETY EQUIPMENT | HANDLING AND STORAGE RESPIRATORY: ........ None Required HANDS-BODY: .......... .......... Plastic or Rubber Gloves FACE-EYES: .............. . Clear Goggles or Face Shield OTHER EQUIPMENT: .. . Slicker Suit STORAGE: Stainless steel or specially lined tanks. Typical liners include fiber reinforced plastics and rubber. TRANSPORTATION: Shipped in stain less steel or specially-lined tank cars and trucks. DISPOSAL: Dispose unused material according to environmental regulations. Contact CP&C's Technical Services De partment to develop Disposal plan. Con tainers must be thoroughly emptied prior to disposal. Incineration may produce sulfur trioxide fumes. SPECIAL NOTE: Establish a spill prevention, control and countermeasure plan with the assistance of CP&C's Technical Services Department. Alum can be neutralized with Caustic Soda or Lime. ZARDS Non Flammable EXTINGUISHING MEDIA: Use water to keep the temperature below 650C/ 1200F to prevent decomposition UNUSUAL FIRE/EXPLOSION HAZARDS: Decomposition at 650CC/1200F produces sulfur trioxide which may add to combustion. SPECIAL PROCEDURES: Wear protective clothing to avoid potential irritation by mist to the skin, eyes and mucous membranes. SAL 000006905 ~ 7 HEALTH HAZARDS & MEDICAL PROCEDURES (r 8 026 GENERAL INFORMATION: The most common injury from exposure is local tissue irritation. If exposure occurs or if poisoning is suspected, inform physician immediately of type and extent of exposure, describe the victim's symptoms and follow medical advice. INCIDENT INHALATION: Irritation of the respiratory system may be a warning ot exposure to acidic mist. FIRST AID Remove the victim from the contaminated atmosphere, if breathing has stopped, initiate CPR. CPR and weak breathing may be supplemented with a bag-mask respirator or a manually operated oxygen supply which delivers at least 1 liter/second. CALL PHYSICIAN IMMEDIATELY. INGESTION: Oral and gastrointestinal irritation. Local tissue damages. Nausea, vomiting, diarrhea and gastrointestinal bleeding may occur. Large amounts may cause serious injury. Immediately dilute swallowed material by orally administering large amounts of water or milk. Induce vomiting. Continue administering fluid until vomitus is clear. NEVER administer liquids orally to an unconscious person. Call physician or Poison Control Center immediately. EYE CONTACT: Irritation. Sulfuric acid burns. Immediately flush victim's eyes with running water for 15 minutes. Hold eyelids fully open to expose entire eye surface to water. Call physician immediately. Continue flushing eyes for another 15 minutes if medical help is not immediately available. SKIN CONTACT: Irritation. Immediately remove contaminated clothes under a safety shower. Flush skin with running water for at least 15 minutes. Call physician immediately. | f ` ADDITIONAL INFORMATION Vs j THRESHOLD LIMIT VALUE (TLV): No TLV has been established for aluminum sulfate by the American Conference of Governmental Industrial Hygenists. TIME WEIGHED AVERAGE: .... N/A NEUTRALIZING AGENT: ........ None TOPICAL TREATMENT: ........... Water INTERNAL TREATMENT: ___ Water or Milk This irilormanon is presented in good faith without any representation or warranty, expressed or implied, regarding it's accuracy Or correctness We do not assume responsibility and expressly disclaim liability tor loss, damage or expense arising out of or in anyway connected with the handling, storage, use or disposal ol this product. FOR ADDITIONAL INFORMATION CONTACT: COASTAL PRODUCTS & CHEMICALS, INC. TECHNICAL SERVICES DEPARTMENT 3160 Interfirst Pla2a Houston, Texas 77002-5217 Telephone: (713) 739-7400 SAL 000006906 Telex: 853169 Bulletin No. CPC-681001 MATERIAL iAf LTY f>ATA'SHEE: date: revised im/vo CHEMICAL NME ms SYNONYMS: CHEMICAL FAMILY: } r BOX lOli, LAkk CHkkLl 1^4-MOUR TELtPHONfc LSUW WS^Sl' Since mi csejr~ SECTION I - PRODUCT IDENTIFICATION MATERIAL SAFETY DATA SHEET rRAQE NAME ANT* SYNONYMIC AlPHACHEH 20W DEGREASER FORMULA: PROPRIETARY SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIONS, t SOLVENTS I X I TLV (Units) 1 OTHER INGREDIENTS So lvents; X TLV (Units) HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES, iAVY AROMATIC SOLVENT ALIPHATIC. NAPTHA X TLV (Units) 25 pr> 100 ppfe SECTION III - FWYSICAL DATA SOILING POINT (F,>: i SPECIFIC GRAVITY' (H20=*l>! VAPOR PRESSURE (Hk Hg.)S 1 | PERCENT, VOLATILE! | BY VOLUME (X) VAPOR KNSITV <AIR*1>; N,D. I SOLUBILITY IN WATER! INSOLUBLE 1 ) EVAPORATION RATE! J< _ __*!> APPEAR/tfCE ARD OMR! DARK LIQUID WITH HYDROCARBON ODOR, I i SECTION IV - FIRE AND EXPLOSION HAZARD DATA Apprnx UWC. UNK. FLASH POINT (Method Used)5 TYPICALLY 130 Degrees F (PHCC) Let: EXTINGUISHING MEDIA! WATER SPRAY, DRY CHEMICALS, FOAM OR CARBON DIOXIDE. FLAMMABLE LIMITS Uell Sf'EEIAl FIRE FIGHTING PROCEDURES! USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL. IF A LEAK OR STILL HAS HOT TONIYED WATER SPRAY TO DISPERSE THE VAPORS, USE AIR SUPPLIED RESCUE EQUIPMENT FOR ENCLOSED AREAS, UNUSUAL FIFE AND EXPLOSION HAZARDS: DO NOT STORE OR MIX WITH STRONG CXJDMTS. SAL 000006907 M-.VnRIAL SAi'tl i DATA SHEET V (> BOX KKfe. I A.KF CHARLtS, LA TOK': 24-HOUR TELfcPHONt (3lt5) 625 >'* ijSSSSfr Sim* 1961 CS 685 MATERIAL SAFETY DATA SJCET SECTION V - IEALTH DATA ALFHAOEM 2084 DGGREASER THRESHOLD LIMIT VALUES UNDETERMINED (SEE SECTION II) EFFECTS OF OVEREXPOSUREt CDfTRAI. NERVOUS SYSTEM ItKfSSION WITH DWVJItCSS AND POSSIBLE LNCOKSCIOUBNESS AT HIGH CONCENTRATION 0T VAPOR. EMERGENCY AND FIRST AID FROCEWJRESJ EYC5. FLUSH WITH WATER FOR 15 MINUTES, GET MEDICAL. ATTENTION. SKINS REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. SHOILD SYMPTOMS OF OVBKtflJSURC TO VAPORS OCCtl? REMOVE TD FRESH AIR. IF UNCONSCIOUS, tfflY ARTIFICIAL RESPIRATION. HO NOT INDUCE VOMITING ir SWALLOWED. SECTION VI - REACTIVITY DATA STABILITY j UNSTABLE i i CONDITIONS TO AVOIDS | STABLE I XXX I INCOMPATIBILITY (Materials to avoid); CONTACT WITH STRONG OXIDIZERS MAY CAUSE REACTIONS. HAZARDOUS DEC0KTOS1TI0N PRODUCTS; CARBON KON0XIIC IN TEE CAGE OT INCOMPLETE COMBUSTION, HAZARTOUS POLYMERIZATION I MAY OCCUR I} I----------------------------------------i-------------i \ WILL NOT OCCUR | XXX i CONDITIONS TOAVOIDS SECTION WI - SPILL OR LEM PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED! CONTAIN SPILL IF POSSIBLE. VENTILATE AREA. AVOID BREATHING VAPOR. USE SELF CONTAINED BREATHING APPARATUS OR FRESH AIR MASK FOR LARGE SPILL IN CtWItO AREA. WIPE UP OR ABSORB AND SHOVEL UP. REMOVE ALL IGNITION SOURCES. WASTE DISPOSE. METHOD; DISPOSE OF IN ACCORDANCE WITH LOCft.., STATE, AND FEDERAL REGULATIONS. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type)! FRESH AIR MSK OR APPARATUS IF PROWJCT USED IN CONFIfO AREA. VENTILATION I LOCAL EXHAUST XXX I---------------------------------------- I MECHANICAL (General) I SPECIE.: I 0T1CR! PROTECTIVE GLOES: SUGGESTED | EYE PROTECTION; SUGGESTED OTHER PROTECTIVE EQUIPMENT* SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO E TAKEN IN HANIUNG ANT' STORING*. KEEP CONTAINER CLOSED WICN HOT IN USE. KEEP AWAY FROM HEAT AND FLAME. OTHER PRECAUTIONS? AVOID PROLONGED OR REPEATED SKIN CONTACT, REPEATED CONTACT OF SIMILAR MATERIALS ON LABORATORY ANIMALS HAS RESULTED IN TT INDUCTION OF TUMORS. SAL 000006908  1 1 Cl 21259 USDS DATES S/14/1* CHANGE HO.S 827* 14)4 MATERIAL SAFETY DATA For Aaalstanca, Centaat: Regulatory Affair* Dapt. HACH COMPANY PO Bax 1*7 Aaa*. IA SOU# PO BOX *07 (800! 227-4224____________________________AHE8, 1A SOPH SHEET Emergency Telephone Rocky Mountain Felaen Ctr, (303) *23-571* I. PRODUCT IDEMTIFICATIOH CATALOG NO.: 2125* PRODUCT HAW: Olgaatlon Solution for COD 0-1500 ppm Ran** CAS NO.S NA CHEMICAL NAME> Not applicable FORMULA) Not applicable CHEMICAL FAMILY: Not applicable II. INGREDIEKTS Sulfuric Acid ACS Brad* PCT: <83 TlV: 1 ag/M3 CAS NO.) 7*64-13-* HAZARD Vary corrosive SARAt LISTED PEL r 1 0I9/H3 Mercuric Sulfati PCT: <5 CAS NO.t 77B3-3S-* TLV: 0.05 n*/M3 * H* RCRA: DO0* HAZARD: Cause* burns: vary toxic SARA: LISTED PEL: C: 0.1 mg/MS Hg Chronic Acid pCTt <1 CAS NO.) 13530-48-2 SARA) NOT LISTED TLV) 8.05 mg/M3 at Cr PEL: 8.5 ms/MS a* Cr HAZARD: Corrosive) extremely toxic) emcar hazard SUvar Sulfete PCT: <2 CAS NO.1 L02*4-2*-5 SARAt LISTED TLV: a.ai ag/MS a* Ag PEL: 0.01 a<g/M3is Ag HAZARD) Toxicity unknown) aiay cause Irritation Denlnrr1lid Watar PCT: to IPO CAS NO.: 7732-18-5 TLV) Not opplleabla HAZARD: Nona SARA: NOT LISTED PEL: Not applicable III. PHYSICAL DATA Avoid contact with ay**, akin and clothing Da nat breath* mist ar vapor. Math thoroughly after handling. PROTECTIVE EQUIPMENT: fume hood, dlsposabla glove*, lab gradt fogglaa, lab coat VII. FIRST AID EYE AND SKIN CONTACT: Immediately flush eyas and akin with water for IS lnutas. Remove contaminated clothing. Coil phyalelan. INGESTION: Do not Induce vomiting. Glva largo quantities af water. Qlv* > least 1 ounce of milk of magnoala In an equal amount of water, ar the whites of 3 aggs. Never give anything by meuth to an unconaelau* parson Call physician. INHALATION: Remove te fresh sir. Give artificial raaglratlan If naeassary Call physician. VIII. SPILL AND DISPOSAL PROCEDURES IN CASE OF SPILL OR RELEASE: The toxicity af mareury la such that tha element and Its compounds should not bo allowed ta contaminate air ar water. Consult yeur EPA ar similar agency ta determine the recommended disposal method In your area. Far large spills, contain tha aalll with Inert material and evacuate the area. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AM) LOCAL REGULATION. IX. TRANSPORTATION DATA D.O.T. PROPER SHIPPING NAME: Sulfuric acid solution HAZARD CLASS: Corrosive Material ID: UN183B l.C.A.O. PROPER SHIPPING NAME: Sulphuric acid solution HAZARD CLASS: 8 ID: UN1830 GROUP: 11 I.M.o. PROPER SHIPPING NAME: Sulphuric Acid Solution HAZARD CLASS: 6 10: UNI83* GROUP: II STATE: llauld APPEARANCE: Turbid, light onngt ODOR: Not determined SOLUBILITY IN: HATER: Nlsclbla ACID: Not datarminad OTHER: Sodium hyd-oxlde solution BOILING POINT: >100*C HELT1NG PT.: NA srec GRAVITY: >1.8 pH: <8.5 VAPOR PRESSURE) Not determined VAPOR DENSITY (lr*lli ND EVAPORATION RATE: Nona METAL CORROSIVITY - ALUMINUM! Corrosive STEEL: Corrosive STABILITY: See Conditions to Avoid STORAGE PRECAUTIONS: Protect from light and froa contamination by arganle natar lal*. IV. FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT.! Not applicable METHOD: NA FLAMMABILITY LIMITS - LOWER: NA UPPER: NA SUSCEPTIBILITY TO SPONTANEOUS HEATING! Nona SHOCK SENSITIVITY: Nana AUTOIGNITION PT.! NA extinguishing MEDIA: Not applleabla FIRE/EXPLOSION HA2ARDS: May aailt toale fumaa In fir* HAZARDOUS DECOHP. PRODUCTS: May emit toxic fun** Of aulfur oxldas In fir* OXIDIZER: nlld NFPA Cedes: Health) 3 Flammability: Reactivity) 1 MFPA Symbol: M CONDITIONS TO AVOID: Exposur* to light or organic contamination (trill affect product stability). Contact kith strong caustics. X. REFERENCES 1) TLV's Threshold Limit Values and 81olo*lcal Exposure Indices far 1*881*89. American Conference of Governmental Industrial Hygienists. 1988. 2) Air Contaminants, Federal Register, Vol. 54, No. 12, Thursday, January 19, 1*8*. PP. 2332-2*83. 3) In-house Information 41 Technical Judgment 5) NIOSH/OSMA Occupational Health Guideline* for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1*81. *) IARC Monographs an the Evaluation of tha Carcinogenic Risks ta Human*. World Health Organization (Velum** 1-42) Supplement 7, 1*87, Franc*. 7) Outside testing. SARA: This product contains a chemical ar chemical* subject to the report; requirements of section 313 of Title 111 of the Suparfund Amendment* an: Reputhorltatlon Act of 1*8* and 40 CFR Part 372. PER CALIFORNIA PROPOSITION *5: ''WARNING - This product contains chemlco. known to tha Stata of California to eaus* canear." V. HEALTH HAZARD DATA THIS product hay BE: corroslva to eyes, skin and respiratory tract. ACUTE TOXICITY: Oral rat LD50 426 n*/Kg Vary toxlo ROUTES of EXPOSURE: Ingestion, Inhalation target ORGANS: Hot determined CHRONIC TOXICITY: Erosion of the teeth, chronic Irritation or inflammation ROUTES OF EXPOSURE: Inhalation TARGET ORGANS: teeth, lungs CANCER INFORMATION: An Ingredient Of this mixture 1a a recognized e arelnogen. ROUTES OF EXPOSURE! Inhalation TARGET organs: Not determined OVEREXPOSURE: Severely burnt any tissue contacted. Breathing In the mist or vapor may causa teeth erosion or the mouth to become sore end else difficulty in breathing. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory condition* VI. PRECAUTIONARY HEASURES Caution. Protect from light. SAL 000006909 THE INFOR MAT 1 ON CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVFR, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY 0* THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. (C) HACH CO. 1**0 -.1 $ SAL 000006910 MATERIAL SAFETY DATA SHEET NALCO PRODUCT nalco 5547 emulsion breaker Emergency Telephone Number & S 6 88Medical (708) 920-1510 (24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5547 EMULSION BREAKER DESCRIPTION: Blend of oxyalkylates in a hydrocarbon solvent NFPA 704M/HMIS RATING: 2/2 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY OInsignificant l=Slight 2=Moderate 3=High 4=sExtreme 0 OTHER* * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Heavy aromatic naphtha Naphthalene Ethylbenzene Xylene 68603-08-7 91-20-3 100-41-4 1330-20-7 40-70 1-5 5-10 5-10 * * * * * SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes irritation to skin and eyes. Combustible. Prolonged inhalation of vapor may be harmful. Do not get in eyes, on skin, or on clothing. Wear goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, SAL 000006911 01401*5 NALCO CHEMICAL COMPANY ONE NAt CO CENTER NAPERVILLE. ILLINOIS 60563-1 198 Ar IMALCD MATERIAL SAFETY DATA SHEET PRODUCT WALCO 5547 EMULSION BREAKER Emergency Telephone Number Medical (708) 920-1510(24 hours) i% Ci m __________________________________ g a o fig SECTION 4 FIRST AID INFORMATION { CONTINUED ) do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INHALATION: Can cause moderate irritation. Can cause moderate irritation. Prolonged inhalation of vapor may be harmful. SYMPTOMS OF EXPOSURE: ACUTE: inhalation of high concentrations of product can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: Prolonged skin contact of product can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions not previously mentioned, or identified in Section 6 or 14. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted on this product. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear amber SPECIFIC GRAVITY: FLASH POINT: FORM: Liquid ODOR: 0.97 9 60 Degrees F Minimum 120 Degrees F (PMCC) Hydrocarbon ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Minimum 120 Degrees F (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: Containers exposed in a fire should be PAGE 2 OF 8 SAL 0000069X2 MALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 1 9B ADr 7G9-1C7r'-- 1 ODC * MATERIAL SAFETY DATA SHEET PRODUCT nalco 5547 emulsion breaker NALCO Emergency Telephone Number Medical (70S) 920*1510 (24 hours) C S 6 89 SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. FEEDING EQUIPMENT: Do not use this product with rubber, polyethylene, neoprene, Hypalon, Buna-N, vinyl, PE, ethylene propylene or polyurethane. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C02 may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.) when attaching feeding equipment, doing maintenance or handling product. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. PAGE 3 OF 8 SAL 000006913 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 n NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5547 EMULSIOH BREAKER Emergency Telephone Number Q S68SMedical (708) 920-1510 (24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 10. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - COMBUSTIBLE LIQUID, N.O.S. COMBUSTIBLE LIQUID NA 1993 CONTAINS - AROMATIC HYDROCARBONS, NAPHTHALENE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Heavy aromatic naphtha - Skin Naphthalene - Irritant Ethylbenzene - Eye irritant Xylene - Eye irritant irritant, combustible PAGE 4 OF 8 SAL 000006914 ioa NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET jpRODUCT NALCO 5547 EMULSIOt^REAKER NALCQ Emergency Telephone Number Medical (708) 920-1510(24 hours) / S6 8S SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Naphthalene == TWA 10 ppm, STEL 15 ppm ACGIH/TLV 52 mg/m3 79 mg/mJ ACGIH/TLV Ethylbenzene = TWA 100 ppm, STEL 125 ppm ACGIH/TLV 434 mg/m3, 543 mg/m3 ACGIH/TLV Xylene = TWA 100 ppm, STEL 150 ppm ACGIH/TLV 434 mg/m3, 651 mg/m3 ACGIH/TLV Naphthalene = TWA 10 ppm, STEL 15 ppm QSHA/PEL 50 mg/m3, 75 mg/m3 OSHA/PEL Ethylbenzene = TWA 100 ppm, STEL 125 ppm OSHA/PEL 435 mg/m3, 545 mg/raJ OSHA/PEL Xylene = TWA 100 ppm, STEL 150 ppm OSHA/PEL 435 mg/m3, 651 mg/m3 OSHA/PEL CERCLA/SUPERFUND, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substance and if 3,400 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802). SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. PAGE 5 OF 8 SAL 00069Z5 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS GOSB3-1 198 N IMALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5547 EMULSION BREAKER Emergency Telephone Number CS6RSMedical (706) 920*1510 (24 hours) c SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following ingredient(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. Naphthalene Ethylbenzene Xylene 91-20-3 100-41-4 1330-20-7 1-5 5-10 5-10 TOXIC SUBSTANCES CONTROLACT(TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined underRCRA 40CFR 261 (consult Section 11), * * * * * * FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: * This product contains the following ingredients covered by the Clean Water Act:* * Naphthalene - Section 307, 311 Ethylbenzene - Section 307, 311 Xylene - Section 311 * * * CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: * This product contains the following ingredients covered by the Clean Air Act: * * Ethylbenzene - Section 111 Xylene - Section 111 * * * STATE REGULATIONS: CALIFORNIA PROPOSITION 65: Substances known to the State of California to cause cancer may be present as an impurity or residue. MICHIGAN CRITICAL MATERIALS: This product contains the following substance(s) identified on the Michigan Critical Materials Register: * * * * * * Naphthalene, Xylene * * PAGE 6 OF 8 000006916 a NALCO CHEMICAL COMPANY ONE NALCO CENTER aofa 7CB-3G5-1 OOO NAPERVILLE. ILLINOIS 60563-1 1 98 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5547 EMULSION BREAKER NALCO Emergency Telephone Number $689Medical (70S) 9201 51 O (24 hours) ^ SECTION 14 REGULATORY INFORMATION ( CONTINUED ) STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Ethylbenzene Heavy aromatic naphtha Naphthalene Oxyalkylated resin Xylene 100-41-4 68603-08-7 91-20-3 Trade secret 1330-20-7 INTERNATIONAL REGULATIONS: * * This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # Heavy aromatic naphtha Naphthalene Ethylbenzene Xylene 68603-08-7 91-20-3 100-41-4 1330-20-7 % Concentration Range 40-70 1-5 5-10 5-10 * * * SECTION 15 ADDITIONAL INFORMATION F 302665 SECTION 16 USER'S RESPONSIBILITY * This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature, individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. PAGE 7 OF 8 SAL 000006917 I II M-i--M----e-- NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 605B3-1 198 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5547 EMULSION BREAKER NALCO SECTION 17 BIBLIOGRAPHY Emergency Telephone Number hours,eS6 89Medical (708) 920-1510 (24 hours) ( CONTINUED ) CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OP POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 04/17/90 DATE PRINTED: 05/12/90 PAGE 8 OF 8 SAL 000006918 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 138 /.n c- * * MATERIAL SAFETY DATA SHEET JpRODUCT nalco 5151 corrosion inhibitoi NALCO 6S62Emergency Telephone Number Medical (70S) 920-1510 (24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAMES NALCO 5151 CORROSION INHIBITOR DESCRIPTION: An aqueous solution of alkyl primary amine and alkanolamine compounds * * * NFPA 704M/HMIS RATING: 3/3 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY 0*lnsignificant l=Slight 2=Moderate 3-High 4=Extreme 0 OTHER* * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Methoxypropylamine Monoethanolamine 5332-73-0 141-43-5 SECTION 3 PRECAUTIONARY LABEL INFORMATION 10-20 40+ WARNING: Causes burns to skin and eyes. Do not get in eyes, on skin, or on clothing. Wear goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SAL 000006919 l" 9 Skx Oo^-H NAICO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS E50563-1198 n NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5151 CORROSION INHIBITO GS682Emergency Telephone Number Medical {708) 920-1510 (24 hour*) SECTION 4 FIRST AID INFORMATION ( CONTINUED > NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage * depending on the length of exposure and on the first aid action given. * Corrosive to skin with possible permanent damage depending on* length of exposure. Can cause allergic contact dermatitis in susceptible individuals. * Can be harmful or fatal. * Can be corrosive to the mucous membranes and the lungs. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): Methoxypropylamine LDS0 = 750 mg/kg Monoethanolamine LDS0 = 2,100 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): Methoxypropylamine LD50 = 2,600 mg/kg Monoethanolamine LDS0 = 1,000 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 6.6/8.0 Corrosive - Methoxypropylamine PRIMARY EYE IRRITATION TEST (ALBINO RABBITS) : EYE IRRITATION INDEX DRAIZE RATING: 104/110.0 Extremely irritating - Methoxypropylamine SKIN SENSITIZATION: Skin sensitization expected. PAGE 2 OF 9 SAL 00006920 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 190 area ^os-t^os-1 ooo N MATERIAL SAFETY DATA SHEET 1 PRODUCT NALCO 5X51 CORROSION INHIBITO NALCO Emergency Telephone Number Medical (706) 920-1510 (24 hours) 82Cr S 6 SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) OTHER TOXICITY RESULTS: Methoxypropylamine. Bacterial mutagenicity bioassay (Ames) negative. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) VISCOSITY: POUR POINT: BOILING POINT: FLASH POINT: FORM: Liquid 8.5 lbs/gal. Completely I.02 @ 60 Degrees F II.4 42 SUS 8 100 Degrees F Less than -30 Degrees F Greater than 200 Degrees F @ 760 mm Hg None ODOR: Amine ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-97 ASTM D-86 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None * * EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, * carbon dioxide or other extinguishing agent suitable for Class B fires. Use * water to cool containers exposed to fire. For large fires, use water spray or * fog, thoroughly drenching the burning material. * * UNUSUAL FIRE AND EXPLOSION HAZARD: Ammonia, CO, CO, may be evolved under fire conditions. * * SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: N-nitrosamines, many are cancer causing agents to laboratory animals, may be formed when certain amines are mixed with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide concentrations. FEEDING EQUIPMENT: Do not use with copper, brass, aluminum or bronze, rubber, neoprene, polyurethane, Buna-N or ethylene propylene. Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. PAGE 3 0F 9 SAL 000006921 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6Q`363-119S MATERIAL SAFETY DATA SHEET NALCO PRODUCT nalco sisi corrosion inhibitor! Emergency Telephone Number Q S 6 8 Medical (708) 920*1510 {24 hours) SECTION 9 REACTIVITY INFORMATION ( CONTINUED ) Avoid contact with strong acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, CO,, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. * * * * SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. * * VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is recommended if gross exposure is possible. * The availability of an eye wash fountain and safety shower is recommended. * if clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section li. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. PAGE SAL 000006922 4 OF 9 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 NALCO MATERIAL SAFETY DATA SHEET ]PRODUCT >uaco 5151 corrosion inhibito Emergency Telephone Number Medical (708) 9201510(24 hour*) g ^ SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 10. Keep the spill away from heat, sparks, flames and welding operations. Ventilate area and evacuate employees from exposure if the airborne concentration exceeds the TLV. Refer to Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be incinerated in accordance with local, state and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - ORGANIC AMINE COMPOUND * * * SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Methoxypropylamine - Corrosive, sensitizer Monoethanolamine - Corrosive Monoethanolamine * TWA 3 ppm, STEL 6 ppm ACGIH/TLV PAGE 5 OF 9 SAL 000006923 MALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 196 NALCO MATERIAL SAFETY DATA SHEET ]PRODUCT NALCO 5151 CORROSION INHIB1T0: Emergency Telephone Number MdleM708) 920-1510(24 hours) _ 6 8^ SECTION 14 REGULATORY INFORMATION ( CONTINUED ) 8 mg/m3, 15 mg/m3 ACGIH/TLV Monoethanolamine = TWA 3 ppm, STEL 6 ppm OSHA/PEL 8 mg/m3 , 15 mg/m1 OSHA/PEL Methoxypropylaxnine = TWA 10 ppmr STEL 20 ppm Workplace Environmental Exposure Limit (WEEL) CERCLA/SUPERFUND, 40 CFR 117r 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: * * * * * * XX Immediate (acute) -- Delayed (chronic) -- Fire hazard -- Sudden release of -- Reactive hazard health hazard health hazard pressure hazard * * * * Under Section 311, submittal of MSDS's or a list of product names to the local * emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: * * A - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. * * * C SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): * This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. * A TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). PAGE 6 OF 9 SAL 000006924 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563*1198 C.r^E.'A 70H-305- 1 DOO N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5151 CORROSION INHIBITO Emergency Telephone Number 9 S6#fMedical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40CFR 261 SUBPART C & If this product becomes a waste, it does not meet the criteria of a hazardous waste. D: FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredientsare specifically listed. . CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the CleanAir Act: Monoethanolamine -Section 111 STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. * MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Methoxypropylamine Monoethanolamine Water 5332-73-0 141-43-5 7732-18-5 INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # % Concentration Range Methoxypropylamine Monoethanolamine 5332-73-0 141-43-5 10-20 40+ * * * * * * * * * * * * * PAGE 7 OF 9 SAL 000006925 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1196 N NALCO MATERIAL SAFETY DATA SHEET 1PRODUCT nalco 5151 corrosion inhibito Emergency Telephone Number Medlcal(708) 920-1510(24 hours) 6S6R* SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. O., eds., Macmiliian Publishing Company, Inc., N. Y., 2nd edition, 1980. chemical HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. I ARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE PAGE 8 OF 9 SAL 000006926 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AQf-'fl 7Q9-3or> i onn MATERIAL SAFETY DATA SHEET PRODUCT nalco sisi corrosion inhibitoi IMALCO SECTION 17 BIBLIOGRAPHY Emergency Telephone Number Medical (70S) 920-1510(24 hours) GS682 ( CONTINUED ) WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 04/18/90 DATE PRINTED: 05/12/90 PAGE 9 OF 9 sal 000006927 NALCO CHEMICAL COMPANY ONE NALCO CENTER 9 NAPERVILLE. ILLINOIS 60563-1 19B fit NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Med leaf (70S) 920-1510 (24 hours) SAL 000006928 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 N NALCQ MATERIAL SAFETY DATA SHEET PRODUCT NALCO 89RB068 CORROSION INHI Emergency Telephone Number Medical (312) 920-1510 (24 hours)* C^ S6 ft j SECTION 1 PRODUCT IDENTIFICATION TRACE NAME: NALOO 89RB068 CORROSION INHXBI DESCRIPTION: An imidazoline in heavy aromatic naphtha NFPA 704M/HMXS RATING: 3/3 HEALTH 2/2 FIAMMABTT.ITY 0/0 REACTIVITY (^Insignificant X=Slight 2=Moderate 3=Hi<i 4=Extresne 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evalution has identified the following chemical ingredient (s) as hazardous. One or more is being claimed as a trade secret under OSHA's Hazard Coimonication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS t APPROX.% Heavy aronatic naphtha Proprietary imidazoline 64742-94-5 Proprietary 40-70 40-70 SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes bums to skin and eyes. Ccmbustible. Do not get in eyes, on skin, or on clothing. Wear goggles or face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away frctn heat and cpen flame. Keep container closed when not in use. Errpty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids cpen. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vaniting. Give water. Call a physician. Remove to fresh air. Treat synptcns. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control synptans and clinical condition. 000006929 CAUTION: If unconscious, having trouble breathing or in convulsions. PAGE 1 OF 8 jSJmlcx- OZi4&c NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 Hi NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 89RB068 CORROSION XNHIB: Emergency Telephone Number Medical (312) 920-1510 (24 hours}* GS68! SECTION 4 FIRST AID INFORMATION < CONTINUED ) do not induce vomiting or give water. NOTE TO IHYSICIAN: Probable mucosal damage may cxmtraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Can be harmful. Prolonged inhalation of vapor may be harmful. SYMPTOMS OF EXPOSURE: A review of available data does not identify any syirptcjns fran exposure. AGGRAVATION OF EXISTING OCNDITTCNS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but acute studies have been conducted on a similar product. The results are shewn belcw. ACUTE ORAL TOXICITY (ALBINO RATS): LD50 ~ 1,122 mg/kg 95% Confidence Limit = 887 - 1,420 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): ID50 = Greater than 3,000 mg/kg PRIMARY SION IRRITATION TEST (ALBINO RABBITS) : SKIN IRRITATION INDEX DRATZE RATING: 8.0/8.0 Extremely irritating (Corrosive) COMMENTS: Third degree bums were apparent on all application sites. PRIMARY EYE IRRITATION TEST (AIBINO RABBITS) : EYE IRRITATION INDEX ERAIZE RATING: 110/110.0 Extremely irritating (Corrosive PAGE 2 OF 8 SAL 000006930 NALCO CHEMICAL COMPANY ONE f\JALCO CENTER NAPERVILLE, ILLINOIS 6056G-10Sd N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 89KB068 OQRRC6ICN LNHIB Emergency Telephone Number Medical (312) 9201510 (24 hours}* G S6 8I SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED CCMMENTS: Caused permanent damage to the cornea and iris. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear light antoer FOFM: Liquid SOLUBILITY IN WATER: Qxpletely SPECIFIC GRAVITY: 0.92 60 Degrees F VISCOSITY: 39 cst @ 60 Degrees F POUR POINT: less than -30 Degrees F FLASH POINT: 152 Degrees F (FMOC) ODOR: Hydrocarbon ASTM D-445 ASTM D-97 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 152 Degrees F (FWCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY; Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION FRDDUCTS: In the event of combustion CO, 002, NOX may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY FROTECITON: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is reccmmended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. PAGE 3 OF 8 SAL 000006931 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60568-1024 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCD 89RB068 CORROSION INHIB1 6 S 6 81Emergency Telephone Number Medical (312) 9201510(24 hours)* SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED ) VENTILATION: General ventilation is reccuinended. Additionally, local exhaust ventilation is recaronended where vapors or mists may be released. TPDIECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is reocnmended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recccroended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CAIi THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILT, CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any cxmoercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCIA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCIA in Section 14. For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 10. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart c, (i.e. D001 through D017) nor is it listed under Sufcpart D. As a non-hazardcxas liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cementl so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be incinerated in accordance with local, state and federal regulations. PAGE 4 OF 8 SAL 000006932 NALCD CHEMICAL COMPANY ONE NALCO CENTER * NAPEHVILLE. ILLINOIS G05S6-1D54 AncA3i9-9ei-9500* "Effective November 11 1989 the a/ea code w/'i be changed to 708 N IMALCO MATERIAL SAFETY DATA SHEET 1 PRODUCT NALCO 89RB068 CORROSION INHXB GS 6 81Emergency Telephone Number Medical (31 2) 920-1510(24 hours)* SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD COCE - CCKRQ6IVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - ORGANIC AMINE CCMPOUND SECTION 14 REGULATORY INFORMATION Hie following regulations apply to this product. FEDERAL REGUIAJTCNS: OSHA HAZARD CCIMJNICATION HUE, 29 CFR 1910.1200: Based cn our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown belcw. Heavy arcanatic naphtha - Combustible, skin irritant Proprietary imidazoline - Corrosive to eyes/skin Heavy arcmatic naphtha - 100 ppm TLV Manufacturer's reccmmendaticai CERCLA/SUFERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUFERHJND AMENDMENTS AND REAL7IH0RIZATICN ACT OF 1986 (TTTIE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CER 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the follcving EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard PAGE 5 OF 8 $AL 000o 6933 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLIMOIS 60566-1024 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALOO 89RB068 CORROSION INHIB! 6 S 6 81Emergency Telephone Number Medical (312) 9201510(24 hours)' SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning caimissicn, state emergency response comrission and local fire department is required after October 17, 1987 if you have: - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. After October 17, 1989, MSDS(s), or a list of product names for all hazardous substances between zero (0) and 10,000 pounds, not previously reported, must be submitted. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA) : The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710) . RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER P0LLLTIQN OONIRDL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307 , 40 CFR 116/formerly Sec. 311: None of the ingredients Eire specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Preposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: PAGE 6 OF 8 SAL 000006934 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60568-1024 AREA 3 1 3-9G 1 -9500" 'Elective Novemoe'tt. ?9S9 the a-ea cooe v " be changes ro 708 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 89RB068 OCKROSION INHIB! GS68!Emergency Telephone Number Medical (312) 920*1510 (24 hours)' 8ECTION 14 REGULATORY INFORMATION ( CONTINUED ) Itiis product does not contain ingredients listed by State Right To Know taws. INTERNATICNAL REGULATIONS: Ifiis is a WHMXS controlled product under The House of Carmans of Canada Bill 070. The product contains the following substance (s), frcre the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient (s); Chemical Name CAS # % Concentration Range Heavy aromatic naphtha Proprietary imidazoline 64742-94-5 Proprietary 40-70 40-70 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY Hois product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., KLaassen, C. D., and Admur, M. O., eds., Macmillian Publishing Ccxrpany, Inc,, N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipinoott Company, N.Y., 1981. DANGEROUS FTOFERITES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. PAGE 7 OF 8 ooooo6935 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 89RB068 OORROSICN TNHTRl Emergency Telephone Number Medical (312) 920-1510 (24 hours) S68l 8ECTION 17 BIBLIOGRAPHY ( CONTINUED ) IAKC MDNOGRAFHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y-, 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS CN CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, CH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart 2, Toxic and Hazardous Substances, Occupational Safety and Health Adndnistration (QSHA). THRESHOLD T.TMTT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 06/15/89 DATE JRINIED: 03/21/90 PAGE 8 OF 8 SAL 000006936 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-102-4 APE A 312-961 -3500 BETZ INDUSTRIAL DIV. 8T 1 QUALITY WAY, TREVOSE, PA.19047 BETZ MATERIAL SAFETY DATA SHEET (PAGE 1 OF 3) 24 HOUR EMERGENCY TELEPHONE NO.(215)355-3300 PRODUCT: SLIMICIDE C30A PRINTED: 05-15-90 PRODUCT APPLICATION : BIOCIDE. ---------- SECTION 1-------------------------HAZARDOUS INGREDIENTS---------------------------------- INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE AND CHRONIC HAZARDS OF THIS FORMULATION. AROMATIC SOLVENTS,PREMIUM***CAS#64742-94-5;COMBUSTIBLE LIQUID?EYE IRRITANT; MANUFACTURER'S RECOMMENDED EXPOSURE LIMIT:100PPM;PEL/TLV:NONE. N-METHYLPYRROLIDONE* * *CAS#87 2-5 0-4 ; COMBUSTIBLE;POTENTIAL EYE AND SKIN IRRITANT;PEL/TLV:NONE;MANUFACTURER'S RECOMMENDED EXPOSURE LIMIT:100PPM. BIS(TRICHLOROMETHYL)SULFONE***CAS#3064-70-8;CORROSIVE(EYES);SEVERE IRRITANT(SKIN);PEL:NONE;TLV:NONE. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9/COMBUSTIBLE LIQUID;IRRITANT(EYE); MANUFACTURERS SUGGESTED EXPOSURE LIMIT:10OPPM;PEL:NONE;TLV:NONE. METHYLENE BIS(THIOCYANATE)***CAS#6317-18-6;IRRITANT(SKIN);CORROSIVE (EYES); TOXIC(ORAL INGESTION);PEL:NONE;TLV:NONE. NONYLPHENOXYPOLY (ETHYLENEOXY) ETHANOL***CAS#9016--45--9 ; EYE AND SKIN IRRITANT; v PEL:NONE;TLV:NONE. SECTION 2------------------------ TYPICAL PHYSICAL DATA PH: 5% EMULSION (APPROX.) FL.PT.(DEG.F): 154 P-M(CC) VAPOR PRESSURE(mmHG): <10 Vise cps70F: 15 EVAP.RATE: ND WATER=1 PHYSICAL STATE: LIQUID 3.3 ODOR: SLIGHT PUNGENT SP.GR.(70F)OR DENSITY: 1.080 VAPOR DENSITY(AIR--1): >1 %SOLUBILITY(WATER): 0 APPEARANCE: YELLOW TO AMBER FREEZE POINT(DEG.F): <-30 SECTION 3------------------------ REACTIVITY DATA------ STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. ( sAt oo6 93? GS679 BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: SLIMICIDE C30A --------SECTION 4-------------------------HEALTH HAZARD EFFECTS------------------------------------------------------- .CUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN.POTENTIAL SKIN SENSITIZER ACUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** DERMAL EXPOSURES WILL DEFAT AND DRY SKIN AND CAUSE SEVERE SKIN IRRITATION INHALATION OF VAPORS/MISTS/AEROSOLS CAUSES EYE AND RESPIRATORY IRRITATION,DIZZINESS,HEADACHE,NAUSEA. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE HIGHLY TOXIC IF INHALED. ---------- SECTION 5---------------------------FIRST AID INSTRUCTIONS-------------------------------------------------SKIN CONTACT*** REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT ( NHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA.APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING. IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ---------- SECTION 6------------------------ SPILL, DISPOSAL AND FIRE INSTRUCTIONS-------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER.THE CONTAMINATED ABSORBENT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS. FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 00006933  8 6 79 BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) ,, .xODUCT: SLIMICIDE C30A --------- SECTION 7--------------------- SPECIAL PROTECTIVE EQUIPMENT--------------------------------- USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES ---------- SECTION 8-------------------------STORAGE AND HANDLING PRECAUTIONS----------------------------STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR f **A*B*O*V*E**T*H*E**P*R*O*D*U*C*T**F*L*A*S*H**P**O*IN**T*. ***************************************** ' J.HIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) ************************************************************************** APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...FIFRA(40CFR):EPA REG.NO. 3876- 61 TREAT AS OIL SPILL . . . RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002=CORROSIVE (SKIN) ...DOT HAZARD/UN#/ER GUIDE# IS: CORROSIVE TO SKIN.COMBUSTIBLE UN1760/#60 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - B SAL 000006939 BETZ INDUSTRIAL DIV. $680 1 QUALITY WAY, TREVOSE, PA.19047 BETZ MATERIAL SAFETY DATA SHEET (PAGE 1 OF 3) 24 HOUR EMERGENCY TELEPHONE NO.(215)355-3300 PRODUCT: SLIMICIDE C41A REVISIONS TO SECTIONS: -;EDIT:2 PRINTED: 05-15-90 PRODUCT APPLICATION : BIOCIDE. ---------- SECTION 1------------------------- HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE AND CHRONIC HAZARDS OF THIS FORMULATION. AROMATIC SOLVENTS,PREMIUM***CAS#64742-94-5/COMBUSTIBLE LIQUID;EYE IRRITANT; MANUFACTURER'S RECOMMENDED EXPOSURE LIMIT:100PPM;PEL/TLV:NONE. N--METHYLPYRROLIDONE***CAS#872--50--4;COMBUSTIBLE;POTENTIAL EYE AND SKIN IRRITANT;PEL/TLV:NONE;MANUFACTURER'S RECOMMENDED EXPOSURE LIMIT:100PPM. STODDARD SOLVENT;CAS#8052-41-3;COMBUSTIBLE LIQUID;IRRITANT;PEL=NONE; TLV=100PPM. B-BROMO-B-NITROSTYRENE***CAS#7166-19-0;EYE,SKIN AND RESPIRATORY IRRITANT; PEL:NONE;TLV:NONE. METHYLENE BIS(THIOCYANATE)***CAS#6317-18-6;IRRITANT(SKIN);CORROSIVE (EYES) ; TOXIC(ORAL INGESTION);PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT(E019);EYE AND SKIN IRRITANT;PEL:NONE;TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5008P SECTION 2------------------------ TYPICAL PHYSICAL DATA PH: 50% SOL. (APPROX.) 4.1 FL.PT.(DEG.F): 156 P-M(CC) VAPOR PRESSURE(mmHG): <10 Vise cps70F: 10 EVAP.RATE: <1 BUTYL ACETATE=1 PHYSICAL STATE: LIQUID ODOR: SLIGHT PUNGENT SP.GR.(70F)OR DENSITY: 0.976 VAPOR DENSITY(AIR=1): >1 %SOLUBILITY(WATER): 0 APPEARANCE: YELLOW TO BROWN FREEZE POINT(DEG.F): <-30 SECTION 3------------------------ REACTIVITY DATA STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000006940 GS680 BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: SLIMICIDE C41A -------- SECTION 4-------------------------HEALTH HAZARD EFFECTS------------------------------------------------------ .CUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO SKIN.ABSORBED BY SKIN.MAY CAUSE DERMATITIS ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES, POSSIBLY CORROSIVE ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED OVEREXPOSURES MAY CAUSE REPRODUCTIVE SYSTEM TOXICITY?MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS,HEADACHE AND NAUSEA. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ORALLY INGESTED. ---------- SECTION 5--------------------------- FIRST AID INSTRUCTIONS-------------------------------------------------SKIN CONTACT*** REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA.APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ---------- SECTION 6-------------------------SPILL, DISPOSAL AND FIRE INSTRUCTIONS-------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER.THE CONTAMINATED ABSORBENT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- DISPOSE OF IN APPROVED PESTICIDE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 000006941 GS680 BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) .^ODUCT: SLIMICIDE C41A --------- SECTION 7-----------------------SPECIAL PROTECTIVE EQUIPMENT----------------------------------- USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** GAUNTLET-TYPE NEOPRENE GLOVES,CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES.FACE SHIELD --------- SECTION 8-----------------------STORAGE AND HANDLING PRECAUTIONS--------------------STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR f **A*B*O*V*E**T*H*E**P*R*O**D*U*C*T**FL*A*S*H***P*O*IN**T*. ***************************************** iHIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) ************************************************************************** APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...FIFRA(40CFR):EPA REG.NO. 3876- 127 TREAT AS OIL SPILL ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NA1993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 2 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - D SAL 000006942 CENTURY PAPERS INC. 4902 GULP FREEWAY HOUSTON. TEXAS 77023 PHONE NO. 713-928-5171 MATERIAL SAFETY OATA SHEET MANUFACTURER: SPARTAN CHEMICAL CO. 110 N. WESTWOOD AVE. TOLEDO, OH 43607 EMERGENCY PHONE NO. 419-531-5551 SECTION 1- PROOUCT IDENTIFICATION SHEET NO. 0111 PRODUCT NAME: AIRLIFT FRESH SCENT (BULK) PROOUCT NO. 498-4048. 498-4056, 498-4056, 498- 4081 DATE: JANUARY 2, 1987 BS675 SECTION 2- HAZARDOUS INGREDIENTS CAS NO. %WT: CHEMICAL NAME: PEL: ACGIH: STEL: CARCINOGEN 67-63-0 1-5 ISOPROPANOL 980 980 1225 NO SECTION 3- PHYSICAL OATA BOILING POINT: 212F. SPECIFIC GRAVITY: 1.0 VAPOR PRESSURE: 75 F. PERCENT SOLID 8Y WEIGHT: 3-5 VAPOR DENSITY: UNKNOWN EVAPORATION RATE: <1 SOLUBILITY IN WATER: PH: 5.0 - 7.0 COMPLETE APPEARANCE ANO ODOR: PALE BLUE LIQUID. PLEASANT FRAGRANCE. MATERIAL IS LIQUIO. SECTION 4- FIRE AND EXPLOSION HAZARD DATA FLASH POINT: NONE METHOD USED - ASTM - D92 FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: N/A SPECIAL FIRE FIGHTING PROCEDURES: NONE UNUSUAL FIRE ANO EXPLOSION HAZAROS: NONE SECTION 5- HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE - CONDITIONS TO AVOID: THRESHOLO LIMIT VALUE: N/E MAY CAUSE SKIN ANO EYE IRRITATION. AVOIO CONTAMINATION OF FOOD. GET IN EYES? AVOIO CONTACT WITH SKIN AND CLOTHING. DO NOT CONDITIONS AGGRAVATED BY USE: UNKNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT EMERGENCY AND FIRST AID PROCEDURES: IF SWALLOWED, DRINK LARGE QUANTITIES OF WATER. IN CASE OF IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. CONTACT, LEAST 15 SECTION 6- REACTIVITY DATA STABILITY: STABLE INCOMPATIBILITY (CONDITIONS TO AVOID): STRONG OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN HAZARDOUS POLYMERIZAT ION: WILL NOT OCCUR SAL 000006943 0 2(45 1 'JLOu MATERIAL SAFETY DATA SHEET PAGE PROOUCT NAME: AIRLIFT FRESH SCENT PRODUCT NO- 498-40*8, 498-4056, 498-4072, 498-4081 G S 6 75 SECTION 7- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO: FLUSH WITH WATER THROUGH SANITARY SEWER SYSTEM. WASTE DISPOSAL METHOO: SAME AS ABOVE SECTION 8- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SPECIFY TYPE): NONE VENTILATION: LOCAL EXHAUST: X MECHANICAL (GENERAL): PROTECTIVE GLOVES: RUBBER GLOVES EYE PROTECTION: SAFETY GLASSES OTHER PROTECTIVE EQUIPMENT: NONE SECTION 9- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: OTHER PRECAUTIONS: NONE NOTHING SPECIAL ( 00o6944 CENTURY PAPERS INC. 4902 GULP FREEWAY 10UST0N. TEXAS 77023 ^HONE NO. 713-928-5171 ''MATERIAL SAFETY DATA SHEET MANUFACTURER: SPARTAN CHEMICAL CO. INC. 110 N. WESTWOOD AVE TOLEOO, OH 43607 EMERGENCY PHONE NO. 419-531-5551 SECTION 1- PRODUCT IDENTIFICATION SHEET NO. 0113 PRODUCT NAME: AIRLIFT FRESH, FLORAL, C LEMON PRODUCT NO. 4^6-4064. 498-4013, 498-4102 OATE: OCTOBER 4, 1985 S6 76 SECTION 2- HAZARDOUS INGREDIENTS CAS NO. CHEMICAL NAME: TLV: LISTED AS A CARCINOGEN IN NTP, IARC OR OSHA: 142-82-5 74-98-6 1-5 10 HEPTANE PROPANE SECTION 3- PHYSICAL DATA BOILING POINT: N/A VAPOR PRESSURE: 75 F. VAPOR OENSITY: UNKNOWN SOLUBILITY IN WATER: 75 X PH: 7.0 - 7.5 1600 1800 NO NO SPECIFIC GRAVITY: 0.99 PERCENT SOLID BY WEIGHT: 3-5 EVAPORATION RATE: <1 (CONCENTRATE) APPEARANCE AND ODOR: MIST. PERFUME FRAGRANCE, NO RESIDUE MATERIAL IS LIQUID. SECTION 4- FIRE AND EXPLOSION HAZARD DATA FLAME EXTENSION: 0" METHOD USED - ASTM - 03065 FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: WATER' FOG SPECIAL FIRE FIGHTING PROCEDURES: USE SOME EQUIPMENT OR SHIELDING TO PROTECT PERSONNEL AGAINST BURSTING. RUPTURING OR VENTING CONTAINERS. UNUSUAL FIRE AND EXPLOSION HAZARDS: AT ELEVATEO TEMPERATURES (OVER 54 C. / 130 F. ) CONTAINERS MAY VENT, RUPTURE OR BURST. SECTION 5- HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE CONDITIONS TO AVOID: THRESHOLD LIMIT VALUE: N/E MAY CAUSE EYE IRRITATION. PRIMARY ROUTES OF ENTRY: CONDITIONS AGGRAVATED BY USE: UNKNOWN EMERGENCY AND FIRST AID PROCEDURES: IN CASE OF EYE CONTACT, IRRIGATE WELL WITH WATER. CALL A PHYSICIAN. IF IRRITATED, SECTION 6- REACTIVITY OATA STABILITY: STABLE INCOMPATIBILITY (MATERIALS TO AVO D): STRONG OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SAL 000006945 2 <4 5Z material safety oata sheet PRODUCT NAME: AIRLIFT FRESH- FLORAL t LEMON (AEROSOL) PRODUCT NO. A9B-406<*# A98-4013, 498-A102 G S6 76 SECTION 7- SPILL OR LEAK PROCEDURES STEPS TO 86 TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CLEAN UP SPILLS WITH ABSORBENT MATERIAL. SURFACES CAN BE CLEANED WITH OETERGENT AND WATER. LARGEST CONTAINER IS ONE (1) POUND. WASTE DISPOSAL METHOD: DO NOT INCINERATE OR PUNCTURE AEROSOL CONTAINER. ACCORDANCE WITH STATE OR LOCAL REGULATIONS. OISPOSE OF IN SECTION 8- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SPECIFY TYPE): NONE REQUIRED VENTILATION: LOCAL EXHAUST (SPECIFY RATE): MECHANICAL (GENERAL): X PROTECTIVE GLOVES (SPECIFY TYPE): NOT NECESSARY EYE PROTECTION (SPECIFY TYPE): NOT NECESSARY OTHER PROTECTIVE EQUIPMENT: NONE SECTION 9- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: CONTENTS UNDER PRESSURE. DO NOT USE NEAR FIRE, SPARKS OR FLAME. DO NOT STORE WHERE TEMPERATURES COULD EXCEED 54C/I3OF. OTHER PRECAUTIONS: NONE sal 0006946 CENTURY PAPERS INC. 4902 GULF FREEWAY HOUSTON. TEXAS 77023 PHONE NO. 713/92 B-5171 68677 MANUFACTURER: F000S6RVICE L LODGING PRODUCTS OIVISION WINTON HILL TECHNICAL CENTER W**A*AU" 6071 CENTER HILL ROAO CINCINNATI. OHIO 45244 EMERGENCY PHONE NO. 1-800-562-1100 SECTION 1- PROOUCT IDENTIFICATION SHEET NO. 0801 PRODUCT NAME: FOODSERVICE JOY BRAND CODES: , 08163, 08514. ITEM NO: 412-0914, 412-0973. 412-0922. 412-0931, INGREDIENTS/CHEMICAL NAME: CLEANING AND SUDSING AGENTS (ANIONIC AND NONIONIC SURFACTANTS), DISPENSING AIO (ETHYL ALCOHOL), WATER, STABILIZING AGENTS, AND PERFUME. SECTION 2- HAZARDOUS INGRED I ENTS/1 DENT ITY INFORMATION HAZARDOUS INGREOI ENTS AS DEFINEO BY OSHA, 29 CFR 1910.1200. CHEMICAL NAME COMMON NAME CAS NO. ACGIH TLV, OSHA PEL, OTHER ETHANOL ETHYL ALCOHOL 64-17-5 1000PPM 1000PPM N.K. DOT CLASSIFICATION: COMBUSTIBLE LIQUID NOT REGULATED IN PACKAGING OF LESS THAN 110 GALLONS. <NA 1993) SECTION 3- PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT (F.): N.A VAPOR PRESSURE (MM HG. ): N, A VAPOR DENSITY <AIR=1): N. A SPECIFIC GRAVITY (H20=l): 1.02 PERCENT VOLATILE BY VOLUME(%>: 63% EVAPORATION RATE (NBUOAC^l): N.A APPEARANCE ANO ODOR: YELLOW LIQUID, LEMON ODOR SOLUBILITY IN WATER: APPRECIABLE SECTION 4- FLAMMABILITY AND REACTIVITY FLASH POINT (METHOD USED): 132 F. CLOSED CUP. ALTHOUGH THIS PRODUCT HAS A FLASH POINT BELOW 200F. (CLOSEO CUP), IT IS AN AQUEOUS SOLUTION CONTAINING ETHYL ALCOHOL WHICH DOES NOT SUSTAIN COMBUSTION. EXPLOSIVE LIMITS: LEL: N.A. UEL: N.A EXTINGUISHING MEDIA: USE C02, WATER OR DRY CHEMICAL. SPECIAL FIRE FIGHTING PROCEDURES: NONE KNOWN , UNUSUAL FIRE HAZARDS: NONE KNOWN STABILITY: STABLE CONDITIONS TO AVOID: NONE KNOWN INCOMPATIBILITY (MATERIALS TO AVOID): PRODUCTS CONTAINING CHLORINE. HAZARDOUS OECOMPOSITION/BY PRODUCTS: CHLORAMINES IN SMALL QUANTITIES. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONOrTIONS TO AVOID: NONE KNOWN SECTION 5- HEALTH ANO SAFETY DATA ROUTES OF ENTRY: ORAL, SKIN CONTACT, EYE CONTACT. HEALTH HAZARDS (ACUTE AND CHRONIC): NONE KNOWN SIGNS AND SYMPTOMS OF EXPOSURE: EXPECTED TO BE EMETIC IF INGESTED. MAY CAUSE NAUSEA AND/OR DIARRHEA. MAY CAUSE MILO TRANSIENT IRRITATION IF ACCIDENTAL EYE CONTACT OCCURS. PROLONGED CONTACT WITH CONCENTRATED MATERIAL MAY BE TRANSIENTLY IRRITATING OR DRYING TO SKIN. SAL 000006947 MATERIAL SAFETY DATA SHEETS PRODUCT NAME: FOODSERVICE JOY PRODUCT NO. A12-09I4, 412-0973, 412-0922, 412-0931 PAGE 2 68677 SECTION 5- HEALTH AND SAFETY DATA CONTINUED, MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: PRE-EXISTING DERMATITIS MAY 8E AGGRAVATED BY PROLONGED CONTACT WITH CONCENTRATED MATERIAL. EMERGENCY AND FIRST AIO PROCEDURES: EYE CONTACT: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES. INGESTION: ORINK A GLASSFUL OF WATER. SKIN: IF PROLONGED CONTACT OCCURS, RINSE THOROUGHLY WITH SPILLED ON CLOTHING, CHANGE CLOTHES. WATER. IF SECTION 6- PRECAUTIONS FOR SAFE HANDLING AND USE PRECAUTIONS TO 8E TAKEN IN HANDLING ANO STORING: NONE REQUIRED OTHER PRECAUTIONS: DO NOT MIX WITH CHLORINE BLEACH AS TRANSIENT,IRRITATING FUMES MAY RESULT. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO: FLUSH SMALL QUANTITIES DOWN ACCEPTABLE SEWER. (CONTAINS BIODEGRADABLE SURFACTANTS.) PREVENT SPILLS FROM REACHING WATERWAY. SORBENTS MAY 8E USED WASTE DISPOSAL METHOO: SMALL TO HOUSEHOLD QUANTITIES MAY BE DISPOSED OF IN SEWER. FOR LARGER QUANTITIES INCINERATION IS PREFERRED. 00 NOT LANDFILL. DISPOSAL IS TO BE PERFQRMEO IN COMPLIANCE WITH ALL REGULATIONS. SECTION 7- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SPECIFY TYPE): NONE REQUIRED WITH NORMAL USE. VENTILATION: LOCAL EXHAUST NOT REQUIRED WITH NORMAL USE EYE PROTECTION: NONE REQUIRED WITH NORMAL USE. IF A SPLASH IS LIKELY. CHEMICAL GOGGLES MAY 86 NEEDED. PROTECTIVE GLOVES: NONE REQUIRED WITH NORMAL USE. PROTECTIVE GLOVES (RUBBER, NEOPRENE) SHOULD BE USED FOR PROLONGED DIRECT CONTACT. OTHER PROTECTIVE EQUIPMENT: NONE REQUIRED WITH NORMAL USE. THE SUBMISSION OF THIS MSDS MAY BE REQUIRED BY LAW, BUT THIS IS NOT AN ASSERTION THAT THE SUBSTANCE IS HAZAROOUS WHEN USED IN ACCORDANCE WITH PROPER SAFETY PRACTICES AND NORMAL HANOLING PROCEDURES OATA SUPPLIED FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH IS SAL 000006948 ' MATERIAL (058441-0102P SAFETY DATA SHEET -EOQ16293-4039 SUPER-SCENT )[DATE of issue 02/13/90 paqe SUPERSEDES 02/13/90 Ol 7I SECTION I - GENERAL INFORMATION CHEMICAL NAME 8 SYNONYMS N/A CHEMICAL FAMILY PETROLEUM DISTILLATE TRAOE NAME A SYNONYMS SUPER-SCENT FORMULA X<--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP. AODRESS (NUMBER. STREET. CITY. STATE & ZIP CODE) BOX 152170 IRVING, TEXAS 75015 PREPARED BY: KELLY SEALS/T.S.CHEMIST | PRODUCT COOE NUMBER ! EMERGENCY TELEPHONE NUMBER 4039 214-439-1381 SECTION II - HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) | HAZARO ALIPHATIC PETROLEUM DISTILLATE COMBUST. | TLV* lOOPPM 1 ! PEL* ! CAS* 500MG/M3 1 8008-20-6 SECTION I IA - NON-HAZARDOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER Nd TRADE SECRET REGISTRY * 409363-521 IP SECTION III - PHYSICAL DATA (CONTINUED) SUPER-SCENT SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM HG). VAPOR DENSITY (AIR-1) PH 9 ioo`,; PERCENT. VOLATILE BY VOLUME <%) SOLUBILITY IN WATER VISCOSITY 1350 j SPEC GRAVITY (H2D-1) jO.4 j COLOR RED j N/A j COOR CHERRY |N/A j CLARITY CLEAR 17E 1 j EVAPORATION RATE i 0.08 j (BU AC 1 ) j j NEGLIGIBLE j NON VISCOUS :O.BO PAGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOO USED) 160 T.C.C. | FLAMMABLE LIMITS ! LEL ! 10 EXTINGUISHING MEDIA "ALCOHOL* XC--FOAM <-* FOAM X<--C02 DRY X<--CHEMICAL WATER < -- SPRAY SPECIAL FIRE FIGHTING PROCEDURES ESTINGUISH ALL SOURCES OF IGNITION AS WITH ALL PETROLEUM FIRES. WEAR SELF-CONTAINED BREATHING APPARATUS. ! , uel [n/a <--OTHER UNUSUAL FIRE S EXPLOSION HA2ARDS N/A NFpA HAZARD RATING <O-INSIGN1FICANT;15LIGHT;2MODERATE;3*HIGH:4-EXTREME): 1 <--HEALTH 2 <--F LAMMABILITY O <--REACT I V ITY <--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED F0R_M1XTURE. SEEK SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) IRRITANT TC EYES INGESTION CAN CAUSE NAUSEA, AND DIARRHEA. SAL 000006949 ./ (COKTIM^D) SOPER-SCENT SECTION V - HEALTH HAZARD OATA PAGE : 03 ASPIRATION OF INGESTED MATERIAL PNEUMONITIS AND CAN BE FATAL. MARKED IRRITATION TO EVES. INTO LUNGS CAN CAUSE CHEMICAL - CHRONIC - (LONG TERM EXPOSURE) 186 78 PRIMARY ROUTE OF ENTRY: X<-- INHALATION INGESTION <-- ABSORPTION EMERGENCY A FIRST AID PROCEDURES INHALATION : NOT A HAZARD. EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER FOR 10 MINUTES , LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. TREATMENT IS MOST EFFECTIVE WITHIN ONE MINUTE. SKIN CONTACT: TYPICALLY NOT A HAZARD. WASH WITH SOAP AND WATER. INGE5TI0N : DO NOT INDUCE VOMITING. KEEP PERSON WARM, OUIET. AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. NOTES TO PHYSICIAN : GASTRIC LAVAGE IS INDICATED. DO NOT INDUCE VOMITING. SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: I ARC < - - YES NTP <--YES DSHA C--YES ACGIH C--VES OTHER <--YES X<--NO XC--NO X<--NC X<--NO X<--NO ALIPHATIC PETROLEUM DISTILLATE UNK-MAN LDLO 1176MG/KG 1. ORL-RAT LD50 28G/KG 1. ORL-RBT LDSO 28G/KG 1 . SECTION VII - REACTIVITY DATA STABILITY |X<-- STABLE <--UNSTABL | CDNDIDTIONS TO AVOID !---------------------------------------------------------------------------------------------------------------------- N/A_ INCOMPATIBILITY {MATERIALS TO AVOIOI STRONG OXIDIZERS f (CONTINUED) SUPER-SCENT SECTION VII - REACTIVITY DATA HAZARDOUS DECOMPOSITION PRODUCTS CARBON DIOXIDE HAZARDOUS r WILL NOT j X < --OCCUR polymerization! ! N/A MAY <--OCCUR 1 CONDITIONS TO AV0I0 l PAGE : 04 SECT1DN VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ELIMINATE ALL IGNITION SOURCES. USE ABSORBANT SUCH AS PAPER, VERMICULITE, ETC. TO CONTAIN SPILL. DC NOT FLUSH TO SEWER. PLACE INTO LABELED CONTAINERS. WASTE DISPOSAL METHOD SMALL AMOUNT: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. DISPOSE OF REMAINING AMOUNT IN ACCORDANCE WITH FEDERAL. STATE. AND LOCAL REGULATIONS. LARGE AMOUNT: DESTROY BY LIQUID INCINERATION. CONTAMINATED ABSORBANT MAY BE DISPOSED OF IN A LANDFILL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULAITONS. NEUTRALIZING AGENT N/A SECTION IX - SPECIAL PROTECTION INFORMATION REQUIRED VENTILATION USE OF PRODUCT AS AN CDORIZER REQUIRES NC SPECIAL VENTILATION. RESPIRATORY PROTECTION N/A PROTECTIVE GLOVES N/A EYE PROTECTION N/A OTHER PROTECTION N/A SAL 000006950 f SUPER-SCEMT SECTION X - STORAGE AM> HANDLING INFORMATIPAGE : 05 STORAGE TEMPERATURE 120 F.C--MAX 30 F . < -MIKI INDOOR X HEATED PRECAUTIONS TO BE TAKEN IN HANDLING & STORING KEEP AWAY FROM IGNITION SOURCES. STORE ON SIOE TO PREVENT CONDENSATION AND SUBSEQUENT CONTAMINATION OF PRODUCT. KEEP CONTAINER TIGHTLY CLOSED. OTHER PRECAUTIONS KEEP AWAY FROM CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT. REFRIGERATED OUTDOOR SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C . A.S. NUMBER UPPER % LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE 111 OF THE SUPERFUND AMENDMENTS AND REAUTHOR12AT ION ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED ANC LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS ANO HERBICIDES). OR THE PROOUCT IS USED AND LABELEC FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--IMCO SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER < - -TARIFF 6 D <--IATA < --MILITARY AIR (AFR 71-4) ! ID NUMBER ! REPORT QTY | LIMITED QTY | NET EXPLOSIVE WT. ( (CONTINUEO) SUPER-SCENT SECTION XI I - TRANSPORTATION (FDR FUTURE USE) PAGE ; 06 AEROSOL PROPELLANT(S) 1 . VENOOR`S MSDS- SECTION XIII - REFERENCES THE INFORMATION CONTAINED HEREIN IS BASED ON OATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NC RESPONSIBILITY FDR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE RODUCT. SAL 000006951 APR 0 2 SI MATERIAL. SAFETY OATA SHEET M/M INSTANT ADHESIVE (037927-0429 EOO16293*4910 ) DATE OF ISSUE S 05/20/88 SECTION 1 - GENERAL INFORMATION PAG* : 01 S674 CHEMICAL NAME 6 SYNONYMS N/A TRAOE NAME 6 SYNONYMS M/M INSTANT ADHESIVE CHEMICAL FAMILY METHACRYLATE FORMULA X<--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP . ADDRESS (NUMBER. STREET, CITY. STATE A ZIP CODE) BO* 152170 IRVING. TEXAS 7*015 PREPARED BY: RICHARD ST0LLEY/T.5.CHEM. ! PRODUCT COOE NUMBER [ EMERGENCY TELEPHONE NUMBER 4910 214*438-1381 SECTION II* HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOV ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PROOUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) POLY METHYL METHACRYLATE ETHYL CYANOACRYLATE | HAZARD IRRITANT SKIN IRR. | TLV* N/A 2 PPM 1. J PEL* N/A N/A ; CASA 9011-14-7 7085-85-0 SECTION 111 * PHYSICAL DATA BCILING PT.<FAHRENHEIT) i>300 F. J SPEC GRAVITY (H20-1) VAPOR PRESSURE (MM HG) !<0.2 ` COLOR J CLEAR LIQUIO : 1.050 (CONTINUED) VAPOR DENSITY (AIR-1) PH 100*4 PERCENT, VOLATILE BY VOLUME (%) SOLUBILITY IN WATER VISCOSITY M/M INSTANT ADHESIVE SECTION III - PHYSICAL DATa i3 i ODOR SHARP IRRITATING |N/A | CLARITY TRANSPARENT |N/A l ' EVAPORATION RATE ( (BU AC - 1 ) i NEGLIGIBLE J!0-10 ! SEMI -VISCOUS PAGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) >200 F. T.C.C. ! FLAMMABLE LIMITS {N/A EXTINGUISHING MEDIA ALCOHOL" X<-- FOAM <--FOAM X<--CQ2 DRY X<--CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES N/A S lel 1 i UEL 1 WATER < - -SPRAY <--OTHER UNUSUAL FIRE A EXPLOSION HAZARDS N/A FNFPA HAZARD RATING (0*1NSIGN1 I CANT ; 1 - SL IGHT:2"MODERATE;3*HI6H;4-EXTREME): 3 < *-HEALTH 1 <-*FLAMMABILITY O <--REACT IV1TY <--SPEClAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : 2PPM ESTIMATED 1. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) SKIN IRRITATION. DERMATITIS AND ADHESION. IF INTRODUCED INTO THE EYES. WEEPING WILL OCCUR ANO POSSIBLE DOUBLE VISION. A LARGE DROP MAY CAUSE THERMAL BURNS. - CHRONIC - (LONG TERM EXPOSURE) SKIN IRRITATION DERMATITIS AND ADHESION LENDING ITSELF TO LOSS OF SKIN TISSUE. ,,SAl 00000 6952 02 W :)0 M/M INSTANT ADHESIVE SECTION X - STORAGE ANO HANDLING INFORMATIPAOC : OB 6 S6 74 STORAGE TEMPERATURE ! INOOOR 1 lO F . < "MAX 40 F . <- "MIN , X [HEATED | PRECAUTIONS TO BE TAKEN IN HANDLING 6 STORING STORE BELOW 75 F. FOR MAXIMUM SHELF LIFE. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. REAO ENTIRE LABEL before USING PROOUCT. [refrigerated} outdoor 11 SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S NUMBER UPPER ** LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 3t3 OF TITLE III OF THE SUPERFUNO AMENDMENTS AND REAUTHOR IZAT ION ACT Of 1986 AND 40 CFR PART 373. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USEO AND LABELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USEO AND LABELED FOR FACILITY GROUNOS MAINTENANCE (SUCH AS FERTILIZERS ANO HERBICIDES), OR THE PROOUCT IS USEO ANO LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <*-49 CFR C--1MC0 SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER OOT SPS CONTAINER AEROSOL PROPELLANT< 5) ("TARIFF 6 0 < - - I ATA < - -MIL I TARY AIR (AFR 71-4) | ID NUMBER S REPORT OTY | LIMITED OTY | NET EXPLOSIVE WT. c M/M INSTANT AOHESIVE SECTION XIII - REFERENCES PAGE : 06 1 . VENDOR'S MSDS . THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NC WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS OaTA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSEO BY THE USE . STORAGE OR DISPOSAL OF THE PROOUCT IN A MANNER NOT RECOMMENDED ON THE PROOUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE, OR DISPOSAL OF THE PRODUCT. SAL 000006953 (coooco) ->r Information Conoco Inc. Page Purchase Requisition of Priority RLOC Department. REB Ship To Shaded Areas RQ Loc Requisition No. 257943for Purchasing Dept. Use Only 316 CD Date Req'd at Dest. Order Previous P.O. Via Type now Tagging Instructions NATIONAL CHEMSEANCH F.O.B. Point Freight Terms \ttn: JOR HAPTNER lequisitioner Date *31tf-i*91-555tt S ANDERSON 03-13*90 Tax Status Special instructions Charge Exempt h Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Distribution Charge Carrier Project ID Clauses Payment Terms v`- r ' W-Y AFE Reporting ______________ 7*111-3-0-55-03-30 Data Control WO. 03-13-y0 S055 ard Stock No. D#*crlptipn Equip. NO. Time Tim# Inlt. Slat. Ordr#d Req'd unit Cod# FY til 1515l norm Oat* Required No. 0<d#r#d luu# Ofy lasuM NATI0NL12ER DEL FLOYD OFFICE EACtt-12- EACtf -h Qaepamj.ffli5%3HDia ahdkrsoh to chsmseaechuok) dc-no^ duplcjjtk firm ^ SS|toK3RAW gy oprovala - Operalng Dept. SAL 000006954 Approval - Purchasing Dept. . Ayeni.r MAIL FREIGHT BILLS TO P.O. 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M, WM HUM ui Lb........ b- OSH* 1ST* IMS. T*H 14. S !/!> IWSKM *b. M * H 7 ISMF ID III (i/A) 13) 9 {II |*| bHIM. IW1KH. TISTI. "7". MIWH.WMSL MIS-Ill. 4TMUI. SIM. *141. 4SM (1) lb MTS. M1SCI. Mil*. MIWH. MIS. IHH. "7". HIM 1MI|. IMIS-Wl. IIUS-HI. 41MU, SIM. SIS4. M i>44 |C| lb 7S7MM.M1SCH 1BIMH. MIS. MISCH IMIIHH. IMIS. ' 7 . MlS-Ml. MIS-171.. IMII-HI. Mill HI. SIULH. SIM. <1*1. 4941 It) HMTMT |t| Uh H 7I1S Upb MSDS-141 .2 0*11 Rvrisid: 04/04/M Mm Mvmm hums. Shi win* bn* uuiMMIbS tarnbiMMi irtiW DUors s*t pthMhci i*iM**. SHssssSa emMi. m Uw tm ii.Iim.iUI, irmuu* mn. a M wmHw " MM, Sim M IstH Hf.UM*. MSDS-14.3-.4 ilalitvltld 04/04/B8 OOOQO6959 SM- MATERIAL SAFETY DATA SHEET APPROVED ST 0 S LABOR DEPT, ESSENTIALLY SIMLA* TO FORn Q$HA 174 PRODUCT IDENTITY: I2C TANK CLEANER I. SUPPLIER CIRCLE N ENTERPRISES, INC. P. 0. BOX 7109 HUNTSVILLE, TX 77340 PHONE (409) 291-2876 S688 II. HAZARDOUS INGREDIENTS AATERIAL Heavy Aroiatic Solvent Naphtha Light Aroaetic Solvent Naphtha CAS I `&4742-94-S '64742-95-6 CAS I PEL IOSHA) TLV (ACGIH) SARA TITLE III UT. X (RES. SECTION 100 ooi . . ._i.il ag/cu. ___ No! iPPlic.a&le._____________ 100 pot S.O iq/cu Not Applicable CEILING STEL IOSHA 4 AC6LHI None Known None KnownNone Known None Known ` `hazard rating " ........................ " -HEALTH INPPA1: 0 `HEALTH (HfllSJ: 3 FLArtflABlLITY: 2 REACTIVITY: 0 DOT SHIPPING NAflE: Coaoound Cleaning, Liouid (NA1993) DOT DRUft LABEL: None III. PHYSICAL DATA BOILING RANGE : GRAVITY i oO'F : `API : SPECIFIC GRAVITY (Uater=l) POUNDS/GALLON : VAPOR PRESSURE lit of Hg)l20 VAPOR DENSITY lair-1) : WATER ABSORPTION : ACID ABSORPTION {54 HiSO.i ; DRY HHE (Ethersil : \ VOLATILE BY VOL : APPEARANCE : ODOR : ' SOLVENCY rARAnEIEri: KK.3 Irtydrogen Bonding) : PK5 (Polarity) : 0K2 Dispersion) : REFRACTIVE INDEX : 198 211 257,'C / 329 412 494*7 |*=End Point) 22.1 .921 7.672 .4 4.8 noderate Hoderate Long 95.0 Liouid,Uater-White Aroiatic 19.1 39.4 41.5 ksjo-- ------------------- ------ V 000006960 SAL PRODUCT IOENTITY: I2C TANK CLEANER S63S PAGE 2 IV. FIRE 4 EXPLOSION HAZARDS lOUEft FLAMMABLE LlfllT IN AIR [X by voi): 1.0 PLASH POINT l TEST flETHODJ: ?2`C / 162`F tPPlJ FLAMMABILITY CLASSIFICATION: class III A EXTINGUISHING MEDIA class ill A ; NFPA Class 8 extinguishers (COi or foaa) for class 111 A liquid fires, EXTINGUISHING nEDIA : NFPA Class 8 extinguishers (COO or foaail : tor class 111 A liquid fires. SPECIAL FIRE FIGHTING PROCURES ; Mater spray aay be ineffective on fire but can orotect fire fighters ft cool closed containers. : Use fog nozzles if water is used. Do not enter confined fire-soace without full : bunker gear. iHclaet with face shield..bunker coats,.glovei.ft.rubber boots). : Use N10SH approved positive-pressure self-contained breathing apparatus. UNUSUAL : COMBUSTIBLE! Keep container tightly closed. Isolate froa EXPLOSION. oiidizers, heat, ft open tlaae. "AND TIRE : Closed containers ay explode if exposed fo eitreae'TVeat. PROCEDURES: Abolyiftfl to hot surfaces requires special precautions. _____ . : Eaoty container very hazardous! Continue all label precautions! V. HEALTH EFFECT DATA THRESHOLD LIH1T VALUE: Not Applicable PREVENTION Use only with adequate ventilation. OF OVER- Avoid prolonged breathing of vapor or spray aist. EXPOSURE Avoid prolonged or repeated contact with skin. ORGANIC EFFECTS: INHALING: Anesthetic. Irritates respiratory tract. OF ACUTE : Can cause serious nervous srsteadepression. OVER- : EYE ft SKIN CONTACT:friaary irritation to skin, defatting, deraatitis. EXPOSURE : Priiarr irritation to eyes, redness, tearing, blurred vision. ; SWALLOWING: Haraful or fatal if swallowed. Swallowing can cause abdoainai irritation, nausea, voaiting and diarrhea. ORGANIC EFFECTS: EYE ft SKIN CONTACT:Liouid can cause ere irritation. Of CHRONIC : Mash thoroughly after handling. OVER- ; EXPOSURE CANCER KAZARO : Possible cancer hazard based on tests with laboratory aniaais using : Ethylene Oude. Overeiposure aay create cancer risk. CONDITIONS : Persons with severe sk:n, liver or kidney orotleas should avoid use. AGGREVAUO : EMERGENCY ft : In case of contact with skin, flush with plenty of water. For eyes. FIRST AID : flush with olenty of water for '.5 tinutes ft get aedical attention. PROCEDURES; After high vaoor exposure, reaove to fresh air. If breathing is difficult give oxygen. If breathing has stooped give artificial respiration. If swallowed. CALI A PHYSICIAN IMMEDIATELY! : Never give anything by south to 3n unconscious cerson. V SAL 000006961 product identity: I2C TANK CLEANER GS633 VI. REACTIVITY DATA PAGE i STABILITY : Stable CONDITIONS TO AVOID: Isolate froa oxidizers, heat, & open fiaae. tuTERlALS TO AVOID : Isolate froa strong oxidizers such as oeraanganates, chroaates & oeroiioes. HAZARDOUS : Carbon flonoxide, Carbon Dioxide, DECOMPOSITION: Phosphorus Pentozide froa burning. PRODUCTS VII. SAFE HANOLING & USE PRECAUTIONS SPILL OR LEAK PROCEDURES Stop soil! at source. Dike area & contain. Fuao spilled liquid A put contaiinated soil in DOT approved containers for disposal. Label iaaediately. Clean up reaainder with absorbent aaterials. HASTE DISPOSAL : Dispose of waste by legal aethods coaplying with local, state & Federal regulations. KTHOD If Questions exist, contact the appropriate agencies. -OTHER -- . $tore large aaounts in structures tadj for QSHA Class ULi liquids. PRECAUTIONS ; .Avoid free fall of liquid. : Ground containers when transferring.- -Do not fiaae cut, braze-or.weld. : Eactx container very hazardous! .oatimi Ali. Ubei precautions!, _ _ _____ __ ______ ----- VIII. CONTROL MEASURES RESPIRATORY PROTECTION: Not Applicable (SPECIFY TYPE) VENTILATION : LOCAL EXHAUST : Necessary HECHANICAL(GENERAL) : Acceptable ............. : SPECIAL : None OTHER " *; None----------------- ' " " .............-- " PROTECTIVE : Hear OSHA Standard goggles or face shield. Consult Safety Eouipaent Supplier. CLOTHING: Hear gloves, apron h footwear iaoervious to this aaterial. Hash clothing before reuse. - NOTICE DELTA DISTRIBUTORS,INC. disciaias all expressed or iaolied warranties of aerchantability or fitness for a particular purpose, with respect to the product or inforaation provided herein. All inforaation appearing herein is baseo upon data obtained froa aanufacturers and/or recognized technical sources. While the inforaation is believed to be accurate, we take no representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore users.are responsible for verifying the data under their own operating conditions to deteriine whether'the product is suitable for their particular purposes and they assuae all Tlsks'of'their use: "handling;------and disposal of the product. Users also assuie all risks in regards to the publication or use of, or reliance upon, inforaation contained herein. This inforaation relates only to the product designated herein, and does not relate to its use in coabination with anr other aaterial or in any other process. DATE : 10/89 SAL 000006962 CIRCLE N ENTERPRISES, INC. P. 0. BOX 7109 HUNTSVILLE, TX 77340 Phone (409) 291-2876 U2C TANK CLEANER CONTAINS: PETROlEUn NAPHTHA G S 6 33 WARNING 1 COnfiUSTlBLE! INHALING: ANESTHETIC. IRRITATES RESPIRATORY TRACT ACUTE OVEREXPOSURE CAN CAUSE SERIOUS NERVOUS SYSTER DEPRESSION EYE 1 SAIN CONTACT:PRIISARY IRRITATION TO SKIN, DEFATTING, DERHATITIS PR MARY IRRITATION TO EYES, REDNESS, TEARING, BLURRED VISION WASH THOROUGHLY AFTER HANDLING SUALLOUING: HARMFUL OR FATAL IF SWALLOWED SHALLOWING CAN CAUSE ABDOMINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANINALS USING ETHYLENE OIlDE. OVEREXPOSURE HAY CREATE CANCER RISK 'PERSONS WITH'SEVERE SKIN, LIVER OR KIDNEY PROBLEMS SHOULD AVOID USE Isolate froi oiidizers, heat, I open flaae. Use only with adequate ventilation. 'Avoid prolonged breatTung of vaoor'or soray aist. ..Avoid prolonged or repeated contact with skin. Hear OSHA Standard goggles or face shield. Consult Safety Eouipaent Supplier. "Wear gloves, apron I footwear iaoervious to this aaterial. Wash clothing before reuse. Keep container tightly closed & upright when not in use to prevent leakage. Eipty container very hazardous! Continue all label precautions! Ground containers when transferring. Do not flaae cut. braze or veld. DISPOSAL: Recycle or dispose of observing local,state i Federal health, safety I pollution lavs. If spilled. Hop up & dispose of. FIRST AID : In case of contact with skin, flush with plenty of water. For eyes, flush with plenty of water for IS ainutes & get aedical attention. After high-vapor exposure, reaove to fresh air. If breathing is difficult give oxygen. If breathing has stopped give artificial respiration. If swallowed, CALL A PHYSICIAN IMMEDIATELY! Never give anything by south to an unconscious person. Consult HSDS for further information. FOR INDUSTRY USE ONLY KEEP OUT OF THE REACH OF CHILDREN . DATE : 10/S9 DOT SHIPPING NAHE: Compound Cleaning, Liouid 1NA19931 DOT DRUH LABEL: None Legal responsibility is assuied only for the fact that all studies reported here i opinions are those of qualified experts. Buyer assuaes all risk & liability. He accepts i uses this aaterial on these conditions. ATTENTION! THIS CONTAINER HAZARDOUS WHEN EMPTY OR PARTIALLY EHPTY. SINCE CONTAINERS RETAIN PRODUCT VAPOR OR LIOUID RESIDUES. ALL HAZARD PRECAUTIONS RUST BE OBSERVED. RESIDUAL VAPORS RAY EXPLODE ON IGNITION. DO NOT CUT, DRILL. GRIND, OR WELD ON OR NEAR THIS CONTAINER. HAZARD RATING HEALTH INFPA): 0 HEALTH (HfUSJ: 3 FtAHHABIlIlY: 2 REACTIVITY: fl SAL 0006 963 TEXACO INC. INDUSTRIAL HYGIENE. TOXICOLOGY. AND MATERIAL SAFETY DATA SHEET note no representation is made as to the accuracy of the information HEREIN. SEE PAGE 7 FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED. synonyms Texaco Chemical Company Emergency Telephone No. (409) 722-8381 Address 4800 Fournare Place P.O. Box 430 Bellaire. TX 77401 Chemical Name and/or Family or Description Alkvl Phenol Ethoxvlate THIS PRODUCT IS CLASSIFIED AS: X HAZARDOUS BY DEFINITION NO.($> . .. WARNING STATEMENT: WARNING! CAUSES IRRITATION TO EYES NOT HAZARDOUS... ON ATTACHED EXPLANATION SHEETS OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) Eyes: Chemical type goggles must be worn. Skirt % Inhalation: 1 . Ventilation: Exposed employes should exercise reasonable personal cleanliness; this includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. Gloves resistant to chemicals and petroleum distillates recommended. None required when handling at minimum feasible temperatures. Normal missible Concentrations: A.r: None established EMERGENCY AND FIRST AID PROCEDURES First Aid Eyes: Flush thoroughly with water for at least fifteen minutes.Get medical attention. Skin: Wash exposed areas with soap and water. Ingestion None considered necessary. Inhalation: None considered necessary. Other Instructions: None. S'r' S'.' r c; rriinfi d N A - S`*:i A-'- 'a'.,. sAt 0006 964 G S 6 98 PHYSIOLOGICAL EFFECTS: Effects, of Exposure Acute: Eyes: _ Causes moderate eye irritation. Code No. _.C52^ . _ Stun. Slightly irritating with possible redness, edema or drying of the skin. Hay cause dermatitis on prolonged or repeated contact. Respiratory System: Believed to be minimally irritating. Chronic Ames mutagenicity test = negative Other: -Cell transformation - neg.; Rat hepatocyte (UDS) - neg. Sensiiitatton Properties: Skia Yes No -- Unknown Respiratory: Yes No Unknown Median Lethal Dose <LDW LC 50 KSpecies) Oj,Approximately 3 g/kg (rat)_l _ si ijthtl v t ox i c inflation ---------- 1 e r rr ial --- N.D. 3 B./V.Z Other--------------------------------- --L_ (rabbit)l practically non-toxic irritation Index, Estimation of Irritation (Species) 5k|fl _____________ 2, A/8.0 (rabbit): slightly irritating Eyes 35.5/110 (rabbit); moderately irritating Symptoms of Exposure^S_g^g_^boye_ fIRC PROTeCTlQN WOWATION Ignition Temp. F. N.D. Flammable Limits (%) Lower N. D. Plash Point F. Method) Upper N.D. A60F (COC) Products Evolved When Subjected to Heat or Combustion: Heating in air may produce irritating aldehydes, acids, and ketones. c Recommended Fire Extinguishing Agents And Special Procedures: According to the National Fire Protection Association Guide, use water spray, dry chemical, foam, or carbon dioxide. Hater or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons at tempting to stop the leak. Unusual or Explosive Haiards: None. $AL 0000 6?65 NO - Not Ofierrmnod N A No! App'icable **u *0 uon *J*mO sjaxipixo Boojis WH J1AA Jv (S|rr)*p >qjnj >oj g Bed uo siuujujo3 (vuoi)rpp* * *MO|q po^oeqo si sjtpo j|) npiM A|)u|o;a s*ot*y m 1jnoso )pg oq v - jnoDQ "..................... suoiitiueiuAjog snopjtitH l -( 996900000 HVS < L -J*V1 (Ohujuj) ------------- jmo j I U uoa*jod*A3 JOOt & 3S3 Oil Al!S0DS'A 1 3-j ty- ujn|OA Aq iqeiOA iu ja<. "fos Aviqnjos on Idnpojd painupun >o h<3 1 Jopo sqq* 11 *pa jo joo MeJ39_ssxj^f^> *PO P1* dutJteddy J7~Ajisubq iOdcA (l *O^H)-------------------------------- ^qt-|------ Ai.AejQ o)iod$ I> jnssjg jodA *CTM (dcJ 1UIOJ 0oi|iog S31iH3<IOad TVOlSAHd QNV 1VDIW3HD *V*N -WO^'ldcfe |i) sstiQ pieitH j.00 p93tn?3J go# :u*N Buddms adojg xOa papTOAC oq pgnoqs uoxgeuxareguoo jage^ *pa2xaixuxm q pxnoqs sajnqejadmaq q9xq oq ajntodxa go *poxjaj *pauxequxetn aq pxnoqc sajngejadmaq Suxxpueq xqiseag mruBTuxq laOejoig pur 6ui|pueH 'uoijeijodsuejx JO) sjuaajBjinbeu *6ui|pucq J3}| Aiqfinojoyi nsM SA (|)IM 19V1UC3 piOAV >1 ) S3A3 01 NOliViiyai S3SHV3 NINUVAA SNOlinVCBHd, njog paseqojnd sqx ui papjeosxp gx aqten enopjezeq e go exjaqxjo goao gou saop pue soxq*xjag -Oejeqo y>D>J Jog pagengeA uoaq *eq qonpojj tuoxqeoxgtesexD agse^1 is^jcujey *dn gaAoqs pue geijageot agqegins uo qjosqe Jo dn adjrt ajqtesod gx ggxdj uxequo3 *saAa qqtA qoequoo pxoAy I00E6-P2fr (008) D^blW3H0 ll*D sjjids uojeijodsuJi) feBevan 10 6e)f?ijg 40 **3 ui sjnpoojy (uoxgeoTjx**exD q*H Jog t^jeoay aag)'snopjezeq |ewagea 9ut -ggnsaj aqg japuaj Aea *oqa *8at8oojd `ajnqxxa *suojgenjogsuejg 'am qonpojd asneoaq tx *xqj_ *aq8en tnopjezeq jog exjaqtja VH3H sqaaa gpnpojd jaqgaqM <xef^*TP 5 amxq aqg qe 'auxmjagap og tgonpojd go jan aqg go Agxxtqtsuodsaj aqg *1 gx `YHDH Jpun :pomw |sodsiQ isM j ^ "i? *' ''* * ' s< ' ' '~\l ^ ; `S' ^^ *,Nauaaioua TVJiewNoaiANa 869S9 J w G S698 .cowiposrriof Code ^ " 1 't C>y Chenical/Common Nana CAS No. v(oxy-l,2-ethanediyl), alpha-(nonylphenyl)- 9016459 *uega-hydroxy- Exposure Linit ___ Range in X 100.Ot F-val. tion of this product indicates that it is hazardous according to OSHA /vpper.-*>x A criteria and/or Texaco s hazard criteria. t SAL 000006967 QQEO-*Z* (008) 03U1W3H3 li' ni^S uotin-iodstur/x issa-'Zzc (6ow w S0A4{ppv/*|*>!UJ*q3 (1W1X3> 00te-l8 (VLSI ll* 696900000 TVS *wnf/*MWW Aufujaauo^ u6i)*uuO|U| }*uOf>ippv joj 0960i ^JOA 'suioid H4M onuoAV J01s&4Diso/v\ 0002 'oui ooexaj. '\ 002 1X3) 00ES-IC8 (16) 3NOHd3131 A0N3DU3W3 1 3HJ. V H '93>|d ut sfiunq umjp pur posop joupiuoo de* qveq jo auit|j udo oj sodx* jo z^jnssvjd iou oq `sanppaj 9 9 9 3ujoj) sausn) atxo) jo uo;$o|dx *9jij snt iq&iuj sj urt)uo A)duie jo fiutppM jo Sumn^ `sirtjopuj 0Aipv9j jo 9 04 3 *3 9 9 #0'diqvunuvjj 'djxoj JOp pasn jj snopjzq q u*a sjaupjuoo Ajdui -snopjfzeq q u sj u;r)uoAjdiu asnsift TJOli-OVO ) 00'00I % ut aXuey *V`N : ,8*13 *nopjP2eH XOO payeynSaj 30^ :auEN 3uyadyqs Jadoj<; xoO eyjaiyjp pjezeq s^ooexsj, jo/pus etjoxtjo v xzpt *idv VHSQ 3 SuTpJoooe snop.iE'ZEq sy ly jBqj sa^Eoypuy }onpojd iyq^'jo uoy^Br - ;a3 _XxojpAq-e9svo_ 69*7 9 T06 - (T^uMdy^uou) -eqdye 4 (yXypauBqja-z * |-Axo) Ayoj ijywTT sjnsodx3 *N SVD apcfj uoanno3/jB;>t<naq;) jo^oop E TT*D sajnuyn gj jpeoj }B jo} Ja^en jo X^uayd q^yn saAa qsnyj jos^uoo jo aseo uy Suyypueq jaqje Ayq9nojoq} qiBfl sarta Miyw qpe^uoD pyoAy S3A3 01 N0I1V1I9HI S3Sf!VD IDNIMHVrt 6 S 6 98 ADDITIONAL COMMENTS STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 198<) No critical materials present. Considered to be relatively loxic to ucjualic life ui concentration as low as 5 PPM. GS224 tMsX V. '-'J* C SAL 000006969 ht F- E. Bentley il-i5-a5 Dele MO ~ Mol D#ifm*ned . Q Nevv y . Coordinator of Product Safely 0 Revised. Supersedes 10-15-85 MA ~ Mol Applicable Cr S 6 98 VT NCk'E: THIS OATA IS FURNISHED GRATUITOUSLY INOEPENOENT OF ANY SALE OF THE PRODUCT. ON-V FOR YOUR INVESTIGATION AND INDEPENDENT VERIFICATION WHILE THE INFORMATION IS BLLILVED TO BE CORRECT. TEXACO INC. MAKES NO REPRESENTATION AS TO THE ACCURACY OF THE INFOR MATION CONTAINED HEREIN. TEXACO INC. SHALL IN NO EVENT BE RESPONSIBLE FOR ANY DAMAGES OF WHAT SOEVER NATURE DIRECTLY OR INOlRECTLY RESULTING FROM THE PUBLICATION OR USE OF OR RELIANCE UPON OATA CONTAINEO HEREIN. NO WARRANTY. EITHER EXPRESS OR IMPLIED OF MERCHANTABILITY OR FITNESS OF ANY NATURE WITH RESPECT TO THE PRODUCT OR TO THE DATA HEREIN IS MADE HEREUNDER OATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY. PROCESS, USE. OR DISTRIBUTE. ANO ENCOURAGED TO ADVISE ANYONE WORKING WITH OR EXPOSED TO SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. EXPLANATION OF THE INDUSTRIAL HYGIENE. TOXICOLOGY, AND MATERIAL SAFETY DATA SHEET PRODUCT INFORMATION Trade Name and Synonyms Refer to the code number and name under which me product is marketed and the common jmmerciJi name ol U>e product Manufacturer's Name and Address Salt explana tory- i Chom.; . Name and/or Family or Description Reie' :o chemical, generic, or descriptive name ol elements and compounds. For purposes ol this form, a product is defined as ha.-jrdous if <l possesses one or more ol the following charateristics: (11 has a tiash-pomt Deiow 200 degrees Farenheit. closed cup or sub ject to spontaneous heating. (2) has a threshold limit value below 500 ppm gases and vapor below 5 mg/m3 for dust fumes and mist, and below 25 MPPCF for mineral dust: (3) a single dose oral L050 below 500 mg/kg; (4) causes burns to the skin in the short-term exposure or is systemically loxic by skin contact; (5) has been demonstrated to be a skin or eye irritant or causes respiratory irritation; (6) may cause skin oi respiratory sensitization; (7) has teratogenic, mutagenic or other toxic effects: (8) may cause asphyxia or pneumoconiosis; (9) in the course ol normal operations may produce dusts, gases, funws. vapor. mtsL or smoke which have one or more of the above characteristics; (10) con tains a component which may be carcinogenic according to NTP (National Toxicology Program). IARC (international Agency for Research Cancer). OSHA (Occupational Safety and Healtn Administration). EPA (Environmental Protection Agency) and/or NCI (National Cancer Institute); (11) has a median LC50 m ar of 200 ppm or less by volume of gas ot vapor, or 20 mg/i or less of misL fume or dust when dmtms.ered by inhalation. OCCUPATIONAL CONTROL PROCEDURES (Consult your Industrial Hygienist or Occupational Health Specialist) ' oieciive Equipment 'rpe of protective equimeni ihat is necessary - 'jt ihe sate handling and use ol this product Ventilation Normal means adequate to maintain permissible concentrations Ventilation type. t.e. local exhaust, mechanical, etc. Permissible Concentrations Indicates Threshold Limit Value (TLV) and/or Time Weighted Average (TWA) as established by the American Conference of Govermental in dustrial Hygienists and/or standards promulgated by the Occupational Safety and Health Adminis tration. EMERGENCY AND FIRST AID PROCEDURES Administer first aid and emergency procedures m case of eye and/or stun coniacL ingestion and inhalation. PHYSIOLOGICAL EFFECTS Acute Exposures (Eye. Skin, Respiratory System) Refers to the most common effects Ihat would be expected to occur Irom direct contact with the product Chrome * Refers to the effects that are most likely to oc cur from repeated or prolonged exposure. Sensitizer Means a substance which will cause on or m normal living tissue, through an allergic or photodynamic process, a hypersensitivity which becomes evident on reapphcaiion of. or expos ure to, the same substance. Median Lethal Dose or Concentration (LDS0.LC50) Refers to that dose or concentration of the ma terial which will produce death in 50 per cent of the animals, for inhalation, exposure time is in dicated. Irritation Index Refers lo an empirical score (Draize Meihod) tor eye and skin irritation which tested by the meth od described, if numbers are not available, a yes or no answer indicates whether or not the mat erial is an irritant FIRE PROTECTION INFORMATION ignition Temperature SAL 000006970 Refers to Ihe temperature in degrees Farenheit. at which a liquid will give olf enough flammable vapor to ignite and burn continuously for 5 sec onds. Flash Point (State Method used) Refers lo the temperature in degrees Farenheit. ai wfi-rh i liquid v -1 Mvt- fill .`rii.i.'i'! jt.i,. G S698 atnmaOte Limits Celers lu trie range of gas or vapor concentration (pelcent D volume in air) which will burn or e_ oae il an igmiion source is present Lower " jins the me lower flammable limit and upper i' jans the upper liammeDle limit given in per cent. Products Evolved When Subjected to Meal or ComDusiion The products evolved when this material is sub>ected to heat or combustion, includes temper juye at which oxidation or other torms of degra dation occurs. Recommended Fire Extinguishing Agents and i jsciai Procedures S tellies tne fire fighting agents that should be u` d io extinguish ,fires If unusual fire hazards a , nvolved or special procedures indicated, this specified. t_-isui.ua Fire or Explosive Hazards Soecific1. hatards to personnel in case of fire, exP-ostve .anger. ENVIRONMENTAL PROTECTION Specifies now this product can be successfully disposed of. Indicates precautions necessary m the event that leakage or breakage occurs. Included are (a) clean-up procedures, (b) personal protective equipment if necessary, (c) hatards that may be cieated. it. fire, explosion, etc. PRECAUTIONARY LABEL ..pc' '. at is required or recommended. jments lor Transportation. Handling and tje Cr -cifies handling and storage procedures. Gives is!.. DOT. or other regulations related to safety -z health lor transportation. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point (or Range) in degrees Farenheii or Celsius Boiling Pomt at 7 60 mmHg. Vapor Pressure Pressure exerted when a solid or liquid is in equilibrium with its own vapor. Specific Gravity The ratio ot the density of the product to the density of water. Vapor Oensitv The ratio of the density of the vapor at satura tion concentration ( 20 degrees Celsius or 68 degrees Farenhen ) to the density of an at 760 mmHg. Appearance and Odor Refers to the general characterization of the mat erial. e.g. powder, colorless liquid, aromatic odor, etc. pH Refers to the degree of acidity or baS>CUy of the material in a specific concentration. pH)-5 pHS - 7 pH? -9 pH9- t 4 - STRONGLY ACiDlC WEAKLY AClCHC WEAKLY BASIC STRONGLY BASIC Solubility Relers to the solubility of a material by weight in watei at room temperature. The term negli gible. less than 0.1 %; slight. 0.1 to 1%: moder ate. 1 io 10%; appreciable, 10% or greater. Gives solubility in organic solvents where appropriate. Percent Volatile By Volume Refers to the amount voiatued at 20 degrees Celsius or 68 degrees Farenheti when allowed to evaporate. Evaporation Gives the rate ot evaporation compared to a s (andar d Viscosity Measure of flow characteristics in Kinematic vis cosity in Cendstofc.es. Hazardous Polymerisation Hazardous polymerization is that reaction which takes place at a rate which produces large amounts of energy indicates whether it may or may not occur and under what storage conditions. Does the Material React Violently Indicates whether the material will react violently, releasing large amounts of energy when exposed under conditions listed Composition Components of the product as manufactured. Texaco Inc. 2000 Westchester Avenue White Plains, New York 106S0 Phone {914} 831-3400 (Beacon} SAL 000006971 Material Safety Data Sheet May be ut.ec to comply with OSHA's Hazard Communication Standard. 29 CFRI19ia^g9(r^ii=>nr1arfl musti nn'iiilteiTlitf^rM i ilu requirements. lOENTITy (As used on Label ana Ust) J ' ( NIEDERHOFER TANK CLEANER #2, BI^&NO . ^^^Section 1 <50* water) Manuiaciurer's Name ' NIEDERHOFER ENTERPRISES Adaiess (Humber. SVeef. Crty, Stare, and ZIP Code) p. O. BOX 3236 BAYTOWN, TEXAS 77522 1 7 507 BAYWAY DRIVE U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMB No. 1218-007? Note. Blank spaces are nor permuted. 8 any nem is not appkcaote. or no information ts avadabte, me space must he marxed to moca'a mar Emergency Telephone NumDer 713/424-7742 Telephone Number tor tniormanon 713/424-7742 Dale Prepared DECEMBER 29, 1987 Signature ol Piepa/er (opoonaJ) ^ fj / s/ , / Section II -- Hazardous Ingredients/ldentity Information Hazardous Components (Specific Chermcat identity; Common Name(s)) NONE KNOWN TO BE HAZARDOUS OR TOXIC OSHA PEL ACGlH TLV Oiner urmis Recommended A* (optional) OTHER: WATER CONCENTRATE SO* 50* Section III -- Physical/Chemical Characteristics bo>nng Point DEGREES F. VApot Pte&suie (mm Hg ) Vapor Density (AJR 1) SCKwtxiiry in Water 207-220 Specific Gravity (HjO I) Melting Pomt APPROX. 78 Evaporation Rale (Butyl Acetate - 1) ______________ EMULSIFIED Appearance and Ooor MICKEY EMMULSION Section IV -- Fire and Explosion Hazard Data fidsn Ponti <,veinod Used) Flammable l_>miis P.M.C.C. 200 F. UNKNOWN Eninguisnmg Media Cpy- HALAN, FOG, FOAM ii^rCioi Pic fugnnny Pioceouitrs NOTTFV SAFETY. REMOVE SOURCE OF FLAME AND CONTAIN WITH DIKE. LEL EXTINGUISH 0.9541 N/A Ul . ------ -- r jiiJ LApiJStOl HilJUS Nrt ^CIAt. PROBLEMS KNOWN. USE STANDARD TECHNIQUES USED WITH PETROLEUM BASED MATERIACS SAL 000006972 CSrti ? ^6900000 1VS S3rIDDOO aHVONVAS 3SR UO'I>-*lOld 3*3 Juio istoeds yyviviad dooai NOisaidxa ; tsevi3 iex>l ' OOOP;i|u3*\ a^Hin fed*i Ajr>*?s) uo'iy' : . j.on S3jnse9^ JOJ1UOQ -- A 3`13*S SOS3T.8VIX5n9WOD 33H3 QNV NV310 V3HV : SUOIinP>9i.J . vC, <3aJ,vm&i37i rm mv iooj <rs:w6uuois pus 6uiipush ui uotbi Q oi suo<in*oad `TII3 0NV3 aaAOHddV O.L 3A0W3N OtxfWW (odso ssM 'LNY8HOS8V HAIM dfl MOId `NIVANOD ONV 3X10 '30dn0S 330 AOHS ' AAHd'/S Adl^^T pottHjg to poyeBi9>j si tsueuMN ss^Q u1 ue^L 9 o> *0*13 sn pue Buhpubh aj*s -o* suoiinffoaJd -- ilA uo|i3*s MVIOlSAHd 33S )~ 7H3J,VM ONINNtTd HlLIM S3J.DNJW 51 S3A3 HSfllJ `831-VM ONV d\^J5 HilfA NlV^i "Vtc.)H. 1' ,.'W **mp*oaJd Vi ou '^9 irvsotfnj Aq p*i*aj66v V -1 *von>Du>Q v>-n NMONXNH #jnsot3 )D sujomJuiA^ pus su&*s tpeisinfiotj vwso /.sudeifiouovM oyvi idlN A3<ueCouo/sQ 4UOSs6u( NMON^MTl (smoAfO ov* 9vk>v) sojstsw uusew tUtMS iUOMP|PUU| eacQ pjez^H :Am>3 10 -- IA 1 's X P*OAV OI SOO1ipOO0 >0300 N M'M >n*>0 OOllSTWUlA o<j snoo'*v*VJ NMOKX 3NON sionooxJAq kj uonreocmoooo siwdistsm NMON* 3NON {pOAV oi SJSUBJPW) A|i|iQ*JS<3vLro3u| S3Hn,LVH3dW3Ji HOIH D*o*y ot SUOCVOOOO X ios woswun Aiwjsig IC0 AllAllDWb -- A U0UP3S 669S d MATERIAL SAFETT DATA SHEET Substantially Similar to Form OMB No, 1218-0072 NAME Niederhofer powdered for de-gassing (KT3) MANUFACTURER detergent SEATEX CORPORATION 6325 HURST ST. HOUSTON, TX 77008 EMERGENCY TEL. #: (713) 868-1461 DATE PREPARED: March 23, 1988 HAZARDOUS MATERIAL Sodium Hydroxide HEALTH-2 FIRE-0 HAZARDOUS INGREDIENTS C.A.S. # OSHA PEL TLV 1310-73-2 2 mg/m3 ACGIH TLV OTHER 2 mg/m3 N.A. NFPA/HIMIS REACTIVITY-0 SPECIFIC HAZARD-ALK PHYSICAL CHARACTERISTICS BOILING POINT-Not Applicable FLASH POINT (DEGREES C)-N.A. SPECIFIC GRAVITY (H20=l)- Not Applicable EVAPORATION RATE (BUTYL ACETATE*1) --N.A. PERCENT VOLATILE - PHYSICAL DESCRIPTION - White granular powder with pine order FLAMMABLE LIMITS* LEL-N.A. UEL-N.A. EXTINGUISHING MEDIA* The material will neither burn or support combustion. SPECIAL FIRE FIGHTING PROCEDURES* Not Applicable UNUSUAL FIRE AND EXPLOSION HAZARDS* None 0 REACTIVITY DATA UNSTABLE- STABLE- X CONDITIONS TO AVOID* None MATERIALS TO AVOID: Strong acids HAZARDOUS PLOYMERZATION: Will Not Occur HEALTH HAZARD DATA POSSIBLE ROUTES OF ENTRY: INHALATION - No SKIN - No INJESTION - Yes ACUTE HEALTH HAZARD: Will produce irritation ingestion or contact with eye. CHRONIC HEALTH HAZARD: None known CARCINOGENICITY: NPT-No IARC MONOGRAPHS - No OSHA REGULATED to mucus - No membranes upon TOXICOLOGY ORAL LD 50 - Not determined DERMAL IRRITATION-Not determined !YE IRRITANT - Not determined SAL 0006974 GS700 MATERIAL SAFETY DATA SHEET Page 2 SYMPTOMS OF EXPOSURE: EYE - Irritation, burning and redness SKIN - Burns, irritation, drying, and cracking. INHALATION - Not likely to occur under circumstances of use. INGESTION - Burns of mucosa, gastric distress and irritation. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:None known EMERGENCY AND FIRST AID PROCEDURES SKIN - Flush skin with water. Remove contaminated clothing and do not rewear until cleaned. EYES - Flush eve with water for 15 minutes while holding open lids. If irritation persists, see a doctor. INAHALATION - Not likely to occur under conditions of use. INGESTION - Drink a large quantity of water or milk. DO NOT INDUCE VOMITING! Do not give acid neutralizing agents. See a doctor immediately! HANDLING AND DISPOSAL SPILL CONTROL PROCEDURE: Material should WASTE DISPOSAL PROCEDURE: May be flushed HANDLING SAFETY: No special procedures. PROCEDURES be collected. to sewer. PERSONAL HYGENE RESPIRATORY PROTECTION: None TYPE REQUIRED: None VENTILATION REQUIRED: LOCAL EXHAUST - No GENERAL MECHANICAL SPECIAL - N.A. OTHER: N.A. PROTECTIVE EQUIPMENT SUGGESTED:Chemical safety gogles, rubber permiable) gloves, rubber (noa-permiable) apron and boots WORK HYGENE: Wash hands immediately use. - Yes (Non- SAL 000006975 t ,> MATERIAL SAFETY DATA PAGE 1 OF 3 SHEET ************************************** PREMIER INDUSTRIAL CORPORATION 4500 EUCLID AVENUE CLEVELAND, OHIO 44103 MAIL TO: CONOCO REFINERY WHSE OLD SPANISH TRAIL WESTLAKE LA 70669 * EMERGENCY/INFORMATION TELEPHONE: * * 216/391-8300 jwfc * * * * * * ************** * FORMULA: 47866 DATE: 03/21/86 * MSDS EFFECTIVE: 03/15/90 BY: CMB * SUPERSEDES MSDS OF:08/28/89 * * COF: 742394 * INVOICE: 378685 * * SDS KEY: 0746998 ******* ****** * * * * * * * * * * * ************** DEAR CUSTOMER: IN COMPLIANCE WITH THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA TITLE III, SECTION 313), FEDERAL HAZARD COMMUNICATIONS REGULATIONS (WHMIS AND OSHA 29 CFR 1910 1200) AND IN THE INTEREST OF INFORMED USE OF OUR PRODUCT, WE ARE PROVIDING YOU WITH THIS MATERIAL SAFETY DATA SHEET <MSDS). THIS MSDS WILL BE UPDATED REGULARLY TO REFLECT THE MOST RECENT INFORMATION N OUR POSSESSION. PLEASE ENSURE THAT OBSOLETE MSDS SHEETS IN YOUR FILES FOR .HIS PART NUMBER ARE DISCARDED . WE THANK YOU FOR YOUR CONTINUED PATRONAGE AND LOOK FORWARD TO PROVIDING *3U WITH ADDITIONAL QUALITY PRODUCTS AND SERVICES. -****************** SECTION I - PRODUCT IDENTIFICATION ********************** PART NUMBER: 92180 PRODUCT NAME: PREMIER ETP CUTTING FLUID AERO TRADE NAME/SYNONYMS: ETP CUTTING FLUID CHEMICAL FAMILY: AEROSOL, LUBRICANT ******************** SECTION II - HAZARDOUS INGREDIENTS *********************** INGREDIENT CAS NO. WT % PEL TLV STEL UNITS LC50, PPM LD50, MG/KG ******************** ********** ***** **** **** **** ***** ******************** PROPANE 00074-98-6 5 1000 N/A N/A PPM M LO 10000N/A ISOBUTANE 00075-28-5 5 N/A N/A N/A N/A N/A PETROLEUM OIL 64742-63-8 80-90 5* 5* 10*MG/M3 N/A RAT 113000 RAB A 2000 INGREDIENTS TOTAL WT 7. ARE BELOW 1007. ONLY IF ALL OTHERS UNLISTED ARE NOT CONSIDERED HAZARDOUS BY ANY FEDERAL (OSHA, WHMIS, SARA), ANY STATE OR PROVINCE, OR LOCAL RIGHT-TO-KNOW REGULATIONS SYMBOLS, ABBREVIATIONS AND NOTATIONS: N/A=NOT AVAILABLE OR APPLICABLE, C=CEILING LIMIT, SISKIN DESIGNATION ^LISTED IN SARA TITLE III SECTION 313,*=IF FOUND AS DUST, MIST OR FUME M=HUMAN, RAB=RABBITS, GPG=GUINEA PIGS, MIC^MICE I=INGESTION,A=SKIN ABSORPTION, LO=LITTLE OBSERVABLE EFFECT, NO=NO EFFECT PEL=OSHA PERMISSIBLE EXPOSURE LIMIT, TLV=ACGIH THRESHOLD LIMIT VALUE STEL=SHORT TERM EXPOSURE LIMIT, @=AMONG 5 MOST PREDOMINANT SUBSTANCES SAL 000006976 6S580 ,RT: 92180 PRODUCT NAME: PREMIER ETP CUTTING FLUID AERO PAGE 2 OF 3 ******************* SECTION III - PHYSICAL DATA **************************** PILING PT DEG F/C: -44F / -42C SPECIFIC GRAVITY: O. 93 PQR PRESSURE<MM HG):4. 7 ATM ^VOLATILE VOLUME: 10 VAPOR DENSITY(AIR = 1>: 1. 6 EVAPORATION RATE:<WATER=1) <1 SOLUBILITY IN WATER: NIL WATER/OIL DIST COEFF:O APPEARANCE AND ODOR: TAN LIQUID/ PETROLEUM ODOR. PHYSICAL STATE: LIQUID,AEROSOL FREEZE PT DEG F/C: N/A THRESHOLD ODOR/PPM: N/A OTHER:N/A PH:N/A ******************* SECTION IV - FIRE AND EXPLOSION HAZARD DATA ************ CLASSIFICATION: FLAMMABLE AEROSOL NFPA RATING: 1,4/0 COMBUSTION PRODUCTS: CO, C02 FLASH POINT DEG F/C: -40F/-4OC LELX: 1. 8 UELX:9. 5 EXTINGUISHING MEDIA: C02, DRY CHEMICAL FOAM. UN/NA/PIN#: UN1954 SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING EQUIPMENT. AUTO IGN. TEMP DEG F/C: 700F / 371C UNUSUAL FIRE AND EXPLOSION HAZARDS: EXPOSURE TO FIRE, HEAT OR PROLONGED SUNLIGHT MAY CAUSE BURSTING. IF USED IN CONFINED SPACES, HAZARDOUS VAPORS MAY SPREAD OR BUILD UP IN LOW AREAS. EXPLOSIVE POWER: HIGH IMPACT SENSITIVE: NO BURNING RATE: HIGH STATIC SENSITIVE: YES FLAMMABLE ******************* SECTION V - HEALTH HAZARD DATA ************************** PRODUCT GUIDE:TLV (SEE SECTION II) STEL: (SEE SECTION II) JUTES OF ENTRY: EYE/ INHALATION EFFECTS OF OVEREXPOSURE: ACUTE: YES EYE IRRITATION CHRONIC: YES LUNGCONGESTION CAUSES EYE IRRITATION. VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC AND RRITATE UPPER RESPIRATORY SYSTEM. EXCESS INHALATION MAY CAUSE DIZZINESS, -rIDDINESS, AND NAUSEA. MISUSE OR DELIBERATE INHALATION MAY BE HARMFUL OR FATAL. PROLONGED AND REPEATED INHALATION MAY BE HARMFUL TO RESPIRATORY SYSTEM. LISTED AS A SUSPECTED CARCINOGEN: NO EMERGENCY AND FIRST AID PROCEDURES: EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN. it CALL PHYSICIAN. SKIN: WASH THOROUGHLY WITH PLENTY OF WATER it SOAP. INHALATION: IF AFFECTED/ REMOVE TO FRESH AIR. INGESTION: SEEK PHYSICIAN IMMEDIATELY/ SHOW MSDS OR LABEL/ DO NOT INDUCE VOMITING. ******************* SECTION VI - REACTIVITY DATA **************************** STABLE: YES CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS, FLAMES, OR SOURCES OF IGNITION. INCOMPATIBILITY(MATERIALS TO AVOID): YES STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: YES CO, PYROLYSIS PRODUCTS HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: N/A ******************* SECTION VII - SPILL OR LEAK PROCEDURES ****************** LISTED IN: SARA TITLE III, #302: NO #304, CERCLA: NO #313: NO STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: IN CASE OF SPILL: REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA. CLEAN UP WITH ABSORBENT MATERIAL. CONTAIN AND PICK-UP WASTE MATERIALS. PUT IN A SEALED APPROVED CONTAINER. EPORT QUANTITY, LB: N/A KG: N/A TPQ,LB: N/A REGULATIONS: WHMIS, RCRA OTHER: N/A HAZARD WASTE: FLAMMABLE,AEROSOL ; N/A DISPOSAL METHOD: DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. DO NOT PUNCTURE, INCINERATE (OR BURN) CONTAINERS. SAL 000006977 G S 5 80 RT: 92180 PRODUCT NAME: PREMIER ETP CUTTING FLUID AERO PAGE 3 OF 3 ********* SECTION VIII - SAFE HANDLING AND PROTECTION INFORMATION *********** RESPIRATORY PROTECTION: USE ONLY IN WELL VENTILATED AREAS. VENTILATION-LOCAL: RECOMMENDED MECHANICAL: REQUIRED SPECIAL:N/A OTHER: N/A PROTECTIVE GLOVES: SOLVENT RESISTANT EYE PROTECTION:SAFETY GOGGLES OTHER PROTECTIVE EQUIPMENT: IF VENTILATION IS INADEQUATE, WEAR APPROVED RESPIRATORY EQUIPMENT. ESTIMATED LD50# MG/KG: YES ORAL RAT 13000# DERMAL RABBIT 2000. ESTIMATED LC50# PPM: YES INHALATION MAN 10000 SENSITIZATION: NO IRRITANT: NO SYNERGISTIC AGENTS: NO ******************* SECTION IX - SPECIAL PRECAUTIONS ************************ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP IN A COOL PLACE. KEEP AWAY FROM HEAT# SPARKS. FLAMES# OR SOURCES OF IGNITION. AVOID PROLONGED OR REPEATED BREATHING OF GAS, FUMES, VAPOR OR SPRAY MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WASH THOROUGHLY AFTER USINQ. OTHER PRECAUTIONS: DO NOT PUNCTURE# INCINERATE <0R BURN) CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ALWAYS READ AND FOLLOW DIRECTIONS ON PRODUCT LABEL. IN CASE OF ACCIDENT OR ILLNESS, SEEK PHYSICIAN IMMEDIATELY, SHOW LABEL OR MSDS. ADDITIONAL TECHNICAL DATA SHEETS AND/OR MATERIAL SAFETY DATA SHEETS (MSDS) RE AVAILABLE UPON REQUEST. FOR PROFESSIONAL AND INDUSTRIAL USE ONLY. THE INFORMATION AND RECOMMENDATIONS PROVIDED HEREIN ARE BELIEVED TO BE ACCURATE OF THE DATE HEREOF. HOWEVER, SUCH INFORMATION AND RECOMMENDATIONS ARE r .,CIVIDED WITHOUT WARRANTY OF ANY KIND AND PREMIER INDUSTRIAL CORPORATION DISCLAIMS ANY AND ALL LIABILITY OR LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON SAME. SAL 000006978 TEXACO INDUSTRIAL HYGIENE. TOXICOLOGY. AND MATERIAL SAFETY DATA SHEET NOTE NO REPRESENTATION IS MADE AS TO THE ACCURACY OF THE INFORMATION HEREIN. SEE PAGE 7 FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED. Trade Name and Synonyms 70203 MORPHOLINE Manufacturer's Name Texaco Chemical Company Emergency (409) DlsTRfft| ited dv Address 3040 Post Oak Blvd. P.0. Box 27707 Houston. TX 770 hemical Name and/or Family or Description Morpholine__________________________ THIS PRODUCT IS CLASSIFIED AS: ______ CARCINOGENIC BY OSHA. IARC. OR NTP PCgTFy|C BOX 10370 ----------------- N^^EANsJ.70,8;o27a X NOT CARCINOGENIC^0^ 733-6600 YARNING STATEMENT: DANGER! FLAMMABLE CAUSES SEVERE EYE & SKIN BURNS & MAY CAUSE BLINDNESS HARMFUL IF SWALLOWED; MAY FORM SUSPECTED CANCER- CAUSING NITROSAMINES IF MIXED WITH NITRITES '4 rotective Equipment (Type) Eyes: Chemical type goggles with face shield must be worn. contact lenses. Do not wear Skirt When handling large quantities subject to splashes and spills, impervious suits, gloves and rubber boots must be worn. Inhalation: Ventilation: Supplied air respiratory protection for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. Local exhaust ventilation recommended ermissible Concentrations: Air: 20 ppm (70 mg/cubic meter) 8 hr. TWA (ACGIH 1986-87) ACGIH skin, see Add. Cmts. Pg.6. 20 ppm OSHA Permissible Exposure Limit (PEL) irst Aid Eyes: Skirt Ingestion: Flush thoroughly with water for at least fifteen minutes.Get immediate medical attention. If drenched, remove contaminated clothing under safety shower and flood exposed areas with water. Get immediate medical attention. Wash clothing before reuse. Destroy contaminated shoes. Do NOT induce vomiting. Give large quantities of water. Call a doctor. Inhalation: Remove to fresh air; if not breathing apply artificial respira tion.Get medical attention.Keep affected person warm and at rest Other Instructions: None. SAL 000006979 N.D. - Not Determined < - Less Than N.A. - Not Applicable > - Greater Than GS 226 Effects of Exposure Acute: Eyes: Believed to be extremely irritating with possible permanent eye injury. Vapor may cause transient corneal edema (hazy vision) Skirt Corrosive; expected to cause severe skin damage with burns and blistering. Toxic effects due to skin absorption possible. Respiratory System: May cause irritation of upper respiratory tract. Chronic: Two-year inhalation oncogenic study negative in rats Other: - Sensitization Properties: Skin: Yes------ No Unknown Respiratory: Yes No Unknown Median Lethal Dose (LD^o LC 50 KSpecies) Ora| _________________ 1*05 g/kg (rat): moderately toxic Inhalation -------------Dermal -------------------Other ----------------------- no deaths (rat),12,000 ppm 8 hr; revers. respiratory tract injury .500 g/kk (rabbit); moderately toxic____________________________________ N. D. ______ _____ _____ Irritation index, Estimation of Irritation (Species) gkjn_________________ Believed to be 6.6-8.0/8.0 (rabbit); corrosive Eyes Believed to be 80-110/110 (rabbit); extremely irritating Symptoms of Exposure See above__and pg. 6 Additional Comments. F1RF PROTECTION INFORMATION Ignition Temp.E. 590 Flammable Limits (%) Lower 1 8 Flash Point F. (Method) Upper 1Q 8 (TCC) Products Evolved When Subjected to Heat or Combustion: Ammonia, carbon monoxide, and carbon dioxide may be formed on burning in limited air supply. Recommended Fire Extinguishing^ Agents And Special Procedures: According to the NFPA Guide 325M, water soluble, flammable liquid fires may be extinguished by dry chemicalfoam, or carbon dioxide. Water may be ineffective on flames, but should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons attempting to stop the leak. Unusual or Explosive Hazards: Explosive air-vapor mixtures may form. SAL 0006980 N.D. - Not Determined - Less Than N.A - Not Applicable > - Greater Than 2 GS 226 Waste Disposal Method _. 4 .. Re-evaluation of the product may be required by the user at the time of disposal, since the product uses, transformations, mixtures and processes may change classification to non-hazardous or hazardous for reasons other than, or in addition to ignitability. (See Remarks for Waste Classification.) Procedures in Case of Breakage or Leakage; (Transportation Spills Call CHEMTREQ (800) 424-9300) Eliminate ail ignition sources including internal combustion eng ines and power tools. Ventilate area. Avoid breathing vapor. Use SCBA or supplied~air mask for lg spills or in confined areas.Con tain spill.Remove with inert absorbant.Avoid all personal contact Waste Class ification: Product (as presently constituted) has the RCRA characteristic of ignitability and if discarded in its purchased form would have the hazardous waste number D001. PRECAUTIONS DANGER! FLAMMABLE CAUSES SEVERE EYE & SKIN BURNS & MAY CAUSE BLINDNESS HARMFUL IF SWALLOWED; MAY FORM SUSPECTED CANCERCAUSING NITROSAMINES IF MIXED WITH NITRITES Do not get in eyes, on skin or clothing. Keep away from heat, sparks and flame. Avoid breathing vapor or mist Keep container closed. Use only in weii-ventilsted locations. Wash thoroughly after handling. Requirements for Transportation, Handling and Storage; Transport, handle and store in accordance with OSHA Regulation 1910.106 and applicable DOT regulations. DOT Proper Shipping Name: Morpholine DOT Hazard Class (if applicable); Flammable liq. UN2054/Corros. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point PF) 263 Vapor Pressure Specific Gravity 1.0017 0^0=1) Vapor Density-- Appearance and Odor clear , color less 1 iq . , ammonia odor (mmHg) (Air=1> pH of undiluted product --^ ^ Solubility APPrec Percent Volatile by Volume 100 Viscosity 2.23 cP 9 20C Evaporation .t -5.; Other - )=1 Hazardous Polymerizations Occur X Do not occur The Material Reacts Violently With: (If others is checked below, see additional comments on page 6 for futher details Air Water Heat Strong Oxidizers Others None of These N.D. - Not Determined < - Less Than N.A - Not Applicable > - Greater Than SAL 000006981 fr S 2 26 rhfim1ca1/Common Name CAS NO. Exposure Limit Ranae in % Morpholine 110918 20ppn TWA 20ppm TWA 3Oppm STEL 30ppm STEL !(SKIN) (SKIN) OSHA S ACGIH 100 Hazardous according to OSHA (1910.1200) or one or- more state Rlght-To-Know lists. HI !. Title ill Section 302/304 Component NONE ' - Extremely Hazardous Substance CAS No. % ( RQ (Lbs) TPQ (Lbs) II. CERCLA Section 102(a) Hazardous Substance Component NONE CAS No. % RQ (Lbs) III. Title III Section 311 Hazard Categorization Acute Chronic X IV. Title III Section 313 Toxic Chemicals Component NONE Fire XIV. Pressure CAS No. Reactive % Not Applicable SAL 00006982 G S 2 2 70203 MORPHOLINE OANGER! FLAMMABLE CAUSES SEVERE EYE & SKIN BURNS * MAY CAUSE BLINDNESS HARMFUL IF SWALLOWED; MAY FORM SUSPECTED CANCERCAUSING NITROSAMINES IF MIXED WITH NITRITES Do not get In eyes, on skin op clothing. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Keep container closed. Use only in wel1-ventllated locations. Wash thoroughly after handling. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a doctor. Wash clothing before reuse. Destroy contaminated shoes. If swallowed. DO NOT induce vomiting. Call a doctor. Never give anything by mouth to an unconscious person. In case of fire use foam, dry chemical or C02. Use water spray to keep containers cool. Chem 1 ca 1/Common Name _______________________________ CAS No. Range in % Morphol1ne 110918 100.00 azardous according to OSHA (1910.1200) or one or more state Rlght-To-Know lists. HMIS Health ; 3 Reactivity Flammability: 3 Special DOT Proper Shipping Name: Morpholine DOT Hazardous Class : Flammable llq. UN2054/Corros. O CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep container closed and drum bungs in place. HEALTH EMERGENCY TELEPHONE: (914) 831-3400 (EXT. 204) Texaco 2000 Westchester Avenue White Plains, New York 10660 For Additional information Concerning: Fuels/Lubricants/Antifreezes call (914) 831-3400 {EXT.204J Chemicals call 1512! 459-QS43 Transportation Spills call CHEMTREC (800) 424-9300 5 SAL 000006983 6 S 2 26 STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1989) No critical materials present. DO NOT USE sodium nitrite or other nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines could be formed. Aquatic toxicity rating: TLM-96 HRS - 100-1000 PPM; practically NON-TOXIC. ACGIH "SKIN" NOTATIONappropriate measures should be taken to prevent cutaneous absorption since the TLV is based on overexposure to the mucous membranes. Like many aliphatic amines,this product is not extensively biodegraded under laboratory conditions of the five day test. Reacts violently with acids. SAL 000006984 To determine applicability or effect of any law or regulation with respect to the product, users should consult his legal advisor or the appropriate government agency. Texaco does not undertake to furnish advice on such matters. F. E. Bentley By - Date 09-14-89 New Title ^oord^nator of Product Safety Revised. Supersedes 04-19-88 N.D. - Not Determined < - '.ess Than N.A. - Not Applicable > - Greater Than THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT 1$ PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. EXPLANATION OF THE INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL SAFETY DATA SHEET PRODUCT INFORMATION Trade Name and Synonyms Refer to the code number and name under which the product is marketed and the common commercial name of the product Manufacturer's Name and Address Self explana tory. Chemical Name and/or Family or Description Refer to chemical, generic, or descriptive name of single elements and compounds. OCCUPATIONAL CONTROL PROCEDURES (Consult your Industrial Hygienist or Occupational Health Specialist) Protective Equipment Type of protective equipment that is necessary for the safe handling and use of this product Ventilation Normal means adequate to maintain permissible concentrations. Ventilation: type, i-e- local exhaust, mechanical, etc. Permissible Concentrations Indicates worker exposure limits, such as the Threshold Limit Value (TLV) as established by the American Conference of Governmental Industrial Hygienists or standards, promulgated by the Occupational Safety and Health Administration (e.g., PEL). TLV-Time Weighted Average (TWA) is the concentration in air averaged over an 8 hour daily exposure. TLV-Ceiling (C) is the ceiling limit on concentration that should not be exceeded during any part of the working day. "Skin" Notation (ACGIH) indicates that dermal absorption can contribute to overall exposure fol lowing direct contact or exposure to airborne material. Permissible Exposure Level (PEL) is the time weighted concentration in air averaged over an 8 hour daily exposure. EMERGENCY AND FIRST AID PROCEDURES Administer first aid and emergency procedures in case of eye and/or skin contact, ingestion and inhalation. PHYSIOLOGICAL EFFECTS Acute Exposures (Eye, Skin, Respiratory System) Refers to the most common effects that would be expected to occur from direct contact with the product Chronic Refers to the effects that are most likely to oc cur from repeated or prolonged exposure. Sensitizer Means a substance which will cause on or in normal living tissue, through an allergic or photodynamic process, a hypersensitivity which becomes evident on reapplication of. or expos ure to. the same substance. Median Lethal Dose or Concentration (LD50.LC50) Refers to that dose or concentration of the ma terial which will produce death in 50 per cent of the animals. For inhalation, exposure time is in dicated. Irritation Index Refers to an empirical score (Draize Method) for eye and skin irritation when tested by the meth od described. If numbers are not available, an estimated score indicates whether or not the material is an irritanL FIRE PROTECTION INFORMATION Ignition Temperature Refers to the temperature in degrees Fahrenheit at which a liquid will give off enough flammable vapor to ignite and burn continuously for 5 sec onds. Flash Point (Method used) Refers to the temperature in degrees Fahrenheit at which a liquid will give off enough flammable vapor to ignite. Flammable Limits Refers to the range of gas or vapor concentration (percent by volume in air) which will burn or ex plode if an ignition source is present Lower means the lower flammable limit and upper means the upper flammable limit given in percent SAL 00006 985 Products Evolved When Subjected to Heat or Combustion. The products evolved when this material is sub** jected to heat or combustion. Includes temper ature at which oxidation or other forms of degra dation occurs. Recommended Fire Extinguishing Agents and Special Procedures Specifies the fire fighting agents that should be used to extinguish fires. If unusual fire hazards are involved or special procedures indicated, this is specified. Unsusual Fire or Explosive Hazards Specifies hazards to personnel in case of fire, ex plosive danger. ENVIRONMENTAL PROTECTION Specifies how this product may be disposed. Indicates precautions necessary in the event that leakage or breakage occurs. Included are (a) clean-up procedures. (b) personal protective equipment if necessary, (c) hazards that may be created, i.e. fire, explosion, etc. PRECAUTIONS Label that is required or recommended. Requirements for Transportation, Handling and Storage Specifies handling and storage procedures. Gives ICC. DOT, or other regulations related to safety and health for transportation. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point {or Range) in degrees Fahrenheit 760 mmHg. Vapor Pressure or Celsius Boiling Point at Pressure exerted when a solid or liquid is in equilibrium with its own vapor. Specific Gravity The ratio of the density of the product to the density of water. Vapor Density The ratio of the density tion concentration ( 20 degrees Fahrenheit ) to mmHg. of the vapor at satura degrees Celsius or 68 the density of air at 760 Appearance and Odor Refers to the general characterization of the mat erial. e.g. powder, colorless liquid, aromatic odor, etc. pH Refers to the degree of acidity or basicity of the material in a specific concentration. pH 1-5 pH5-7 pH7-9 pH9-14 - STRONGLY ACIDIC WEAKLY ACIDIC WEAKLY BASIC STRONGLY BASIC Solubility Refers to the solubility of a material by weight in water at room temperature. The term negli gible. less than 0.1 %; slight, 0.1 to 1%; moder ate, 1 to 10%; appreciable. 10% or greater. Gives solubility in organic solvents where appropriate. Percent Volatile By Volume Refers to the amount volatilized at 20 degrees Celsius or 68 degrees Fahrenheit when allowed to evaporate. Evaporation Gives the rate of evaporation compared to a standard Viscosity Measure of flow characteristics in Kinematic vis cosity in Centistokes. Hazardous Polymerization Hazardous polymerization is that reaction which takes place at a rate which produces large amounts of energy. Indicates whether it may or may not occur and under what storage conditions. Does the Material React Violently Indicates whether the material wilt react violently, releasing large amounts of energy when exposed under conditions listed. Composition Components of the product as required by OSHA (1910.1200) and one or more stale Right to Know laws. SAL 000006986 Texaco 2000 Westchester Avenue White Plains, New York 10650 Phone (914) 831-3400 (Beacon) DcLiA-OlilEGA A utchitoloukH. Lid.P O. Sox 81518 24 HOUR EMERGENCY 318-237-5091 Lafayette. LA 70598-1518 CHEMTREC 800-424-9300 PROOUCT NAME OMNI-CLEANt* PROOUCT CODE: 4 - EXTREME 3 - MICH EHAPO HAZARD RATING HEALTH USE NFPA 00 1 - SLIGHT 0* INSIGNIFICANT HMIS 00 MATERIAL SAFETY DATA SHEET DOT Hazard Class Non-regulated OOT Shipping Name N/A un Number N/A MATERIAL OMNI-CLEAN 1 COMPONENT INFORMATION COMPONENT SUMMARY CASflN OSHA/PEL RCAC' special 00 00 ACGIH/TWA Omni-Clean is a patented, blended formulation of fatty acids and surface active agents which is completely non-hazardous, non-toxic and biodegradable and is listed on the U.S. Environmental Protection Agency NaUooal Contingency Plan contained in Section 300.86 of subpart H. All constituents are listed on the EPA's NCP Technical Bulletin D-42. II PHYSICAL DATA appearance Clear FREEZING PT < 0*C 80ILING PT > IO0*C VAPOR PRESSURE N/A VAPOR DENSITY N/A 1 ,M FLASH PT * 1 TEMP FIRE AND EXPLOSION HA2AR0 DATA NONE EXPLOSIVE LIMITS EXTINGUISHING MEDIA NONE LELNAp UELNAp NONE h?o solubility complete PERCENT VOLATILE. N/A NONE VISCOSITY SPECIFIC GRAVITY EVAP RATE iSuAc-tf 1.00 25/23 N/A PECIAl FIRE FIGHTING PROCEDURES Not a hazard, non-flammable. This product is an Emulsifying Film Forming Foam fire suppression agent. UNUSUAL FIRE AND EXPLOSION HAZARDS NONE JV_________ REACTIVITY DATA____________________________________________________________________ STABILITY Stable_________________________________________________ HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID NONE INCOMPATA0ILITY IMATERIALS to AVOlOl NONE KNOWN HAZARDOUS OECOMPOsTtiON PfiOOUCTS NONE KNOWN ingestion- Chronic Non-toxic None known SAL 000006987 f MOOUCT NAME OMNI-CLEAN ,, DELrA-OVTlcGA A utchttoloflUM. Lll. P 0 8ox8l5T8 Lafayette. LA 70598*1518 24 HOUR EMERGENCY 318-237-5091 CHEMTREC 800-424-9300 PROOUCT CO06: 4 - (KTACUt 3 - HIGH EHAPO S 6 TO HAZARD RATING HEALTH AM irar IRe NFPA 0 0 0 0 1 * SLIGHT 0 * INSIGNIFICANT HMIS 0000 MATERIAL SAFETY DATA SHEET _VJ_________EMERGENCY ANO FIRST AID PROCEDURES_____________________________________________________________ inhalation Not an expected route of exposure. If irritation or distress should occur, remove subject to fresh air. EYE CONTACT SKIN CONTACT INGESTION - Flush eyes with water for at least 15 minutes. None needed. Drink one or two glasses of water. Vlt________SPILL OR LEAK PROCEDURES_____________________________ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush over with water WASTE OlSPOSAL METHOOS N/A Non-toxic, biodegradable - Acceptable for NPDES discharge or to POTW VIII SPECIAL PROTECTION INFORMATION___ VENTILATION None RESPIRATORY PROTECTION None PROTECTIVE GLOVES Not required EYE PROTECTION None required - but splash goggles are recommended. OTHER PROTECTIVE EQUIPMENT None JXTOXICITY INFORMATION Sk.nPiStRBn Non-irritating Eve imtaru [RBn Slight irritant________________________ X STORAGE ANO HANOLING PROCEDURES Agitation is recommended before use. Use normal safety precautions when handling drums. Store in tightly closed original shipment containers at ambient temperatures between 40* and I00*F. XI_________REGULATORY AND ENVIRONMENTAL INFORMATION We certify that none of the base chemical components of this product are listed on (he TSCA inventory; each constituent is approved by the (J.S. FDA. This product contains no chemicals identified by the State of California as carcinogens or reproductive toxicants. Biodegradable. Contains no heavy metals, cyanide or chlorinated hydrocarbons. D.O.T. Hazard Class: Non-regulated. (J.S. EPA Classification: Non-hazardous. (All product constituents are non-hazardous and NOT included within the Hazardous Constituents section, Appendix VIII, Volume 45, No. 98, Rules and Regulations, Federal Register, May 19, 1980.) Disclaimer OMNI-CLEAN is on the (J.S. Environmental Protection Agency's NCP Product Schedule. This listing does NOT mean that EPA approves, recommends, licenses, certifies, or authorizes the use of OMNI-CLEAN on an oil discharge. This listing means only that data have been submined to EPA as required by Subpart H of the National Contingency Plan, section 300.86. Failure to comply with these restrictions or any other improper attempt of the product shall constitute grounds for removing the product from the NCP Product Schedule. Prepared bv CHRIS DUGAS Safety Manager Effective Oale mm9 END of MATERIAL SAFETY DATA SHEET SAL 000006938 Material Safety Data Sheet May to used lo comply with OSHA's Hazard Convnunicaton Standard. 29 Qm 1910.1200. Standard must to coneoied for (pacific repuiremertt*. OOfTTTY (At Used on Uto and Utt) FEMCO Grade H-RK U.S. Department of Labor Occupational Safety and Health Administration (Nofl*Maftdatory Form) Form Approved OMB No. 1218-0072 ' W S 6 7T Note: &m* spaces ere not perrmtied F any sem a not astute, or no ! rtbrmeoort 0 evadatte, Fie apace mvar Oe merged to ftdbe.v hat Section 1 Manufacturer'* Name FILTER-MEDIA CCMPANY Addrae* (Numtm, SUM, C*y. Siam, and ZtP Coda) 3603 Westcenter Drive Houston. Texas 77045 Emergency Telephone Number (713) 780-9000 or (713) Telephone Number lor imormaoort (713) 780-9000 Oeia Prepared 495-5654 1-22-90_________________________________________ ___ yzrzsfisw Section B -- Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Wenttty: Common Nam**)) OSHA FEU __________________ TVne-------------------------------------------- 15 ma/tnl Chemical Name: Aluminum Silicate ACOIH TUV lOiroAi3 Other Um*a ffernmmended ^-- H todta*) ----- ______________________________________ (Canbined Form)_.._fNcn detgrtab^e free silica) FEDERAL AND STATE REGULATIONS SOMETIMES CHANGE jCP DIFFER. WHILE FEMCO AUKP*1 SILICATE HAS BEEN DETERMINED TO OFFER NO MORE THAN A NJISMCE HAZARD VJilCH CAN BE CONTROLLED WITH PROPER EXHAUSTING AM) HOUSEKEEPING PROCEDURES, FILTER MEDIA, INC. MAKES NO WARRANTY WITH RESPECT TO FEDERAL AND STATE REGULATIONS AND DISCLAIMS ALL LIABILITY FRCM RELIANCE THEREON. Section III -- Physfcal/Chemlcal Characteristics Softng Poire Specific Gravity (HjO -1) Vapor Pressure (mm Hg.) Vapor Denetfy (MR i) SohjtzGtf * water N/A N/A N/A MeMng Point Eraporarion Rata (Buiyf Acetate - 1) ______ __________ Insoluble Appearance and Oder White, inert, finely divided pewier. Odorless. Section IV -- Flrt and Explosion Hazard Data n*3h Pont (Mthod Used) Flammable Limns Fire Proof N/A E*tngvcy*ng Media _____________ None required. Product has been used to extinguish fires. P*ciaf Fut Fightng Procedure* None. Fire Proof. LEU N/A 2.30 2,400 deg. N/A UEU N/A t-tousual Fra and Explosion Hazardi None. SAL 000006989 Fge 2 - M.S.D.S. GS671 Stdton V -- Reactivity Oats SteMy Unstable Statue X Conmne to A**) None known. Incompatibility (Ate/erta/e to A0*A ______________________ Hydroflour ic Acid Haztodous Decomposition or QyprcAjca _ None known. Hazardous Potymerteaiion May Occur Wil Not Occur Conddons to Avoid None X Section VI -- Health Heard Data Route# at Entry: Wttrtoon?yes Skin? no Ingestion? yes Hearn HaxArde (Acute *nt/Cfmef is an innocuous dust. Excessive concentrations of such an innocuous dust may impair visibility and may cause deposits in the eyes, nasal passages, and ears. Use NICSH approved devices for eye and respiratory proCacticnT so* as *6900 or MSA Caofo II for breathing and African Optical AO1010 or APR 10SO fat eyes._____________________________________________ _________________________ Careincgerbcity: None NTP? NA WRC Mcnographe? N/& OSHA Regulated? Nb Signs and Symptoms of Exposure Sneezing and dryness of mucous merrbrane (inhalation) dry chapped skin (contact). Tearing and redness of eyes.__________________________ Medal Conditions Generally Aggravated toy Exposure Respiratory Ailments, Dermatitis and Eye Conditions, Contact Lenses. Emergency and First Aid Procedures Skin and eyes - wash well with water. Respiratory: Move to fresh air. Ingestion: no known specific effects, If irritation or discanfort occurs, seek medi Section VII -- Precautions for Safe Handling and Use Steps Be Taken in Case Material Is Released or Spiled S^eep or vacuun and deposit in suitable container. Not or toxic, if unused. Waste Otoposal Method Precautions to 8s Taken n HandBng and Storing _________________________________________ Keep dry. Avoid foimaticn of dust. Ground equipment __________________________________________ properly to prevent static discharge. Other Precautions None. -- Section VIII -- Control Measures Respiratory Protection fSpecxy Typo) VeniUbon loeaf Exhaust As needed to reduce dust. Special N/A Mechanical (Gen#*) N/A l Other J N/A Protean* G>ovs Ey* protection Safety glasses: ___Not necessary___________________________ Other ftotecUve Ctoihing or Equipment None AC1010 or AOR 1050 Work/Hyyonuc Practices Practice good housekeeping procedures. SAL 000006990 MATERIAL SAFETY DATA SHEET G S672r Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175** 1 Page: 1 PRODUCT NAME: DOWEX (R) MARATHON A CHLORIDE FORM ANION EXCHANGE RESIN Effective Date: 0L/17/89 Date Printed: 04/11/90 M$D$:001152 1, INGREDIENTS: {% w/w, unless otherwise noted) Trimethy 1 amine functionalized, chloromethylated copolymer of styrene and diviny1 benzene in the chloride form Water CAS# 060177*39-1 CAS# 007732*18-5 This document is prepared pursuant to the 0SHA Hazard Communication Standard (29 CFR 1910*1200). In addition, other substances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: Not applicable VAP PRESS: Not applicable VAP DENSITY: Not applic. SOL. IN WATER: Insoluble SP. GRAVITY: Density 44 1b/ft3 APPEARANCE: White to amber solid ODOR: No to low odor. (beads). 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: Not applic. METHOD USED: Not applic. FLAMMABLE LIMITS LFL: Not applic. UFL: Not applic. EXTINGUISHING MEDIA; Dry chemical. (Continued on Page 2) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000006991 MATERIAL SAFETY DATA SHEET G 6 72 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175*1 Page: 2 PRODUCT NAME: DOWEX (R) MARATHON A CHLORIDE FORM ANION EXCHANGE RESIN Effective Date: 04/17/89 Date Printed: 04/11/90 MSDS:001152 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) FIRE & EXPLOSION HAZARDS: Product is not combustible until moisture is removed, then resin starts to burn in flame at 230C. Autoignition ocurs above 50OC. Possible fire combust I on products: Alkyl benzenes, vinylbenzenes, naphthalene, benza1dehydes, phenol, carbon dioxide, water, organic amines, chlorine, nitrogen oxides, ammonia, methyl chloride. FIRE-FIGHTING EQUIPMENT: Wear positive pressure self-contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Stable under normal handling and storage conditions. See incompatibility statement. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) Warning: Oxidizing agents such as nitric acid attack Organic ion exchange resin under certain conditions and could result in a slightly degraded resin up to an explosive reaction. Before using strong oxidizing agents, consult sources knowledgeable in handling such materials. HAZARDOUS DECOMPOSITION PRODUCTS: See possible combustion products in section 3* HAZARDOUS POLYMERIZATION: Will not occur. 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Sweep up. Caution: May be slippery. DISPOSAL METHOD: Bury resin in licensed landfill or burn in approved incinerator according to local, state, and federal regulations. For resin contaminated with hazardous material, (Continued on Page 3) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000006992 SHEETMATERIAL SAFETY DATA 6S672 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175^1 Page: 3 PR00UCT NAME: DOWEX (R) MARATHON A CHLORIDE FORM ANION EXCHANGE RESIN Effective Date: Oit/17/89 Date Printed: OL/11/90 MD:00ii52 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: (CONTINUED) dispose of mixture as hazardous material according to local, state and federal regulations. 6. HEALTH HAZARD DATA: EYE: Solid or dust may cause irritation or corneal injury due to mechanical action. SKIN CONTACT: Prolonged or repeated exposure not likely to cause significant skin irritation. SKIN ABSORPTION: Skin absorption is unlikely due to physical properties. INGESTION: Single dose oral LD50 has not been determined. Single dose oral toxicity is believed to be low. No hazards anticipated from ingestion incidental to industrial exposure. INHALATION: Vapors are unlikely due to physical properties. SYSTEMIC OTHER EFFECTS: No specific data available, however, repeated exposures are not anticipated to cause any significant adverse effects. 7. FIRST AID: EYES: Irrigate immediately with water for at least 5 minutes. Mechanical irritation only. SKIN: No adverse effects anticipated by this route of exposure. INGESTION: No adverse effects anticipated by this route of exposure incidental to proper industrial handling. INHALATION: No adverse effects anticipated by this route of exposure. (Continued on Page M (R) Indicates a Trademark of The Dow Chemical Company ft An Operating Unit of The Dow Chemical Company SAL 000006993 MATERIAL SAFETY DATA SHEET G S672 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 17541 Page: 4 PRODUCT NAME: DOWEX (R) MARATHON A CHLORIDE FORM ANION EXCHANGE RESIN Effective Date: 04/17/89 Date Printed: 04/11/90 MSDS:001152 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE(S) : None established. VENTILATION: Good general ventilation should be sufficient. RESPIRATORY PROTECTION: No respiratory protection should be needed. SKIN PROTECTION: No precautions other than clean body-covering clothing should be needed. EYE PROTECTION: Use safety glasses. 9, ADDITIONAL INFORMATION: REGULATORY REQUIREMENTS: SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title Ml) and is considered, under applicable definitions, to meet the * following categories: Not to have met any hazard category SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice reasonable care and caution. Metal equipment should be compatible with feed, regenerant, resin form, and effluent of that process. TSCA CONSIDERATIONS: Every different salt or ionic form of an ion-exchange resin is a separate chemical. if you use an ion-exchange resin for ion-exchange pruposes and then remove the by-product resin from its vessel or container prior to recovery of the original or another form of the resin or of another chemical, the by-product resin must be listed on the TSCA Inventory (unless (Continued on Page 5) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000006994 MATERIAL SAFETY DATA SHEET 6S672 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175^1 Page: 5 PRODUCT NAME: DOWEX (R) MARATHON A CHLORIDE FORM ANION EXCHANGE RESIN Effective Date: OL/17/89 Date Printed: OL/11/90 MSDS:001152 9. ADDITIONAL INFORMATION: (CONTINUED) an exemption is applicable). It is the responsibility of the customer to ensure that such isolated, recycled by-product resins are in compliance with TSCA. Failure to comply could result in substantial civil or criminal penalties being assessed by the Environmental Protection Agency. MSDS STATUS: Revised Section 9* (R) Indicates a Trademark of The Dow Chemical Company The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult The Dow Chemical Company For Further Information. * An Operating Unit of The Dow Chemical Company SAL 006995 MATERIAL SAFETY DATA SHEET G S673 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 5X7-636-4400 Product Code: 175^3 Page: 1 PRODUCT NAME: DOMEX (R) MARATHON C HYDROGEN FORM CATION EXCHANGE RESIN Effective Date: OA/IV89 Date Printed: 0A/11/90 MSDS:001153 1- INGREDIENTS: (% w/w, unless otherwise noted) Sulfonated copolymer of styrene and divinylbenzene in the hydrogen form Water CAS# O69OI1-20-7 CAS# 007732-18-5 This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: Not applicable VAP PRESS: Not applicable VAP DENSITY: Not applicable SOL. IN WATER: Insoluble SP. GRAVITY: Density 50 1b/ft3 APPEARANCE: Light yellow to amber ODOR: Not applicable. solid (beads). 3. EIRE AND EXPLOSION HAZARD DATA: FLASH POINT: Not applic. METHOD USED: Not applic. FLAMMABLE LIMITS IFL: Not applic. UFL: Not applic. EXTINGUISHING MEDIA: Dry chemical. FIRE 6 EXPLOSION HAZARDS: Product is not combustible until moisture is removed, then resin starts to burn in flame at (Continued on Page 2) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 00000699^ MATERIAL SAFETY DATA SHEET S67S Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175^3 Page: 2 PRODUCT NAME: DOMEX (R) MARATHON C HYDROGEN FORM CATION EXCHANGE RESIN Effective Date: 04/14/89 Date Printed: 04/11/90 MSDS:001153 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) 230C. Autoignition occurs above 500C. Possible fire combustion products: alkylbenzenes, viny1 benzenes, naphthalene, benzaldehydes, phenol, carbon dioxide, water, sulfur oxides, organic sulfonates. FIRE-FIGHTING EQUIPMENT: Wear positive pressure self-contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Stable under normal handling and storage conditions. See incompatibility statement. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) Warning: Oxidizing agents such as nitric acid attack organic ion exchange resins under certain conditions and could result in a slightly degraded resin up to an explosive reaction. Before using strong oxidizing agents, consult sources knowledgeable in handling such materials. HAZARDOUS DECOMPOSITION PRODUCTS: See possible combustion products in section 3* HAZARDOUS POLYMERIZATION: Will not occur. 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Sweep up. Caution: May be sIippery. DISPOSAL METHOD: Bury resin in licensed landfill or burn in approved incinerator according to local, state, and federal regulations. For resin contaminated with hazardous material, dispose of mixture as hazardous material according to local, state, and federal regulations. (Continued on Page 3) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000006997 MATERIAL SAFETY DATA SHEET GS6 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175^3 Page: J PRODUCT NAME: DOMEX (R) MARATHON C HYDROGEN FORM CATION EXCHANGE RESIN Effective Date: OVH/89 Date Printed: Oli/H/90 MSD$:001153 6. HEALTH HAZARD DATA: EYE: May cause severe eye irritation. May cause moderate corneal injury. Effects are likely to heal. SKIN CONTACT: Prolonged exposure may cause skin irritation. May cause more severe response if skin is abraded (scratched or cut) . SKIN ABSORPTION: Skin absorption is unlikely due to physical properties. INGESTION: Single dose oral toxicity is believed to be low. No hazards anticipated from ingestion incidental to industrial exposure. INHALATION: Vapors are unlikely due to physical properties. SYSTEMIC OTHER EFFECTS: No specific data available, however, repeated exposures are not anticipated to cause any significant adverse effects. 7. FIRST AID: EYES: Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical personnel. SKIN: Wash off in flowing water or shower. INGESTION: No adverse effects anticipated by this route of exposure incidental to proper industrial handling. INHALATION: No adverse effects anticipated by this route of exposure due to physical properties. (Continued on Page 4) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000006998 MATERIAL SAFETY DATA SHEET G S67 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175^3 Page: 4 PRODUCT NAME: DOMEX (R) MARATHON C HYDROGEN FORM CATION EXCHANGE RESIN Effective Date: 04/14/89 Date Printed: 04/11/90 MSDS:001153 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE(S) : None established VENTILATION: Good general ventilation should be sufficient. RESPIRATORY PROTECTION: No respiratory protection should be needed. SKIN PROTECTION: For brief contact, no precautions other than clean body-covering clothing should be needed. Use impervious gloves when prolonged or frequently repeated contact could occur. If handling when skin is abraded (scratched or cut), wear a glove which provides a physical barrier. EYE PROTECTION: Use chemical goggles. 9. ADDITIONAL INFORMATION: REGULATORY REQUIREMENTS: SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 3H and of the Superfund Amendment and Reauthori2ation Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: An immediate health hazard SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice reasonable care and caution. Metal equipment should be compatible with feed, regenerant, resin form, and effluent of that process. TSCA CONSIDERATIONS: Every different salt or ionic form of an ion-exchange resin is a separate chemical. If you use an ion-exchange resin for ion-exchange purposes and then remove the by-product resin (Continued on Page 5) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000006999 MATERIAL SAFETY DATA SHEET S6 73 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 175*0 Page: 5 PRODUCT NAME: DOWEX (R) MARATHON C HYDROGEN FORM CATION EXCHANGE RESIN Effective Date: 04/14/89 Date Printed: 04/11/90 MSDS:001153 9. ADDITIONAL INFORMATION: (CONTINUED) from its vessel or container prior to recovery of the original or another form of the resin or of another chemical, the by-product resin must be listed on the TSCA Inventory (unless an exemption is applicable). It is the responsibility of the customer to ensure that such isolated, recycled by-product resins are in compliance with TSCA. Failure to comply could result in substantial civil or criminal penalties being assessed by the Environmental Protection Agency. MSDS STATUS: Revised Section 9* (R) Indicates a Trademark of The Dow Chemical Company The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult The Dow Chemical Company For Further Information. * An Operating Unit of The Dow Chemical Company SAL 000007000 #Material Safety -Datasheet (conoco) Emergency Medical Telephone (800) 441-3637 INCA OIL 6^8667 L MATERIAL IDENTIFICATION Name Inca Oil CAS Registry Number Mixture; See Section XI Synonyms Steam Cylinder Oil, Petroleum Lubricating Oil Product Code 7161 Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) IL OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients Hydrogen Sulfide CAS Registry Number 7783-06-4 Concentration <0.1% Hazardous Physical Properties None in. PHYSICAL DATA Appearance and Odor Black liquid; Mild petroleum hydrocarbon odor Spedfie Gravity (HaO = 1) 0.89 Boiling Point/Range 900 - 120CTF % Volatiles (by volume) Nfl Vapor Pressure Nil Solubility in Water Insoluble Vapor Density (Air = 1.0) >1 Evaporation Rate Nil IV. REACTIVITY DATA Stable: X Unstable____ Hazardous Decomposition Materials: Hazardous gases/vapors produced are carbon dioxide; incomplete combustion may produce carbon monoxide. Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. LUBC0260/August 1989 SAL 000007001 Conoco Inc., P.O. Box 2197, Houston, TX 77252 Genera! Information No. (713) 293-5550 6S667 V *--/ m * V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 47CTF (PM1 AutoignJtion Temperature 75CTF Handle and store fan accordance with NFPA procedure for Class 1HB Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. SpedalFlre Fating Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cooL Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other trade materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association 1NFPA1 Classification Health 1 Fire 1 Reactivity 0 HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 VL TRANSPORTATION AND STORAGE Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Not Regulated IATA/IMO: Not Restricted VTI. HEALTH HAZARD INFORMATION Exposure Limits for Inca* Ofl PEL None Established TLV: None Established Exposure Limits for Hydrogen Sulfide PEL 10 nom. 14 me/m5 STEL 15 ppm. 21 mg/m3 TLV: 10 ppm. 14 mp/m* STEL 15 ppm. 21 mpAn3 Du Pont AEL 10 ppm - 8 & 12 Hr. TWA Primary Routes of Exposnre/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: This product contains highly solvent-refined lubricating oils or other petroleum-derived oils which mouse skin painting studies have shown to not cause skin tumors. The product does not pose a significant health hazard, but as with many petroleum products, poor hygienic practices or inadequate engineering design that allow prolonged or repeated exposure may cause minor skin irritation. This product may be a source of hydrogen sulfide if exposed to extremely high temperatures. If hydrogen sulfide is present, low concentrations are irritating to the eyes, skin and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis and death may occur. Remember that good hygienic practices are helpful in preventing adverse health effects. Exposure can be minimized by using protective clothing or devices and contaminated skin should be washed. Intermittent or occasional skin contact with the material is not expected to have serious health effects as long as good personal hygiene measures, such as those outlined in this material safety data sheet, are followed. Carcinogenicity: None of the components in the material is listed by NTP, IARC, or OSHA as a carcinogen. LUBC0260/August 1989 2 SAL 000007002 i \ * ? * n VIIL EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eves with plenty of water for at _ physician. 1 ., ' Skin: In case of contact, Immediately wash skin with soap and plenty of water! If irritatkur consult a physician. ;: *?; Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial difficult, rive oxygen. Chfl a physidan.'^^ , ^ ", \ - ^ -- /.v :FV* - Ingestion: If swallowed, do not induce vomiting. Give large quant mouth to an unconscious person. Gall a physidau.*53^ Notes to Physician: Gastriclavageby qualified medk^^sonnel DL SPILL, LEAK In Case of Spin or Leak: Contain spill immediately in smallest potential ignition sources. Recover sis much of the product as other mechanical means. Residual fluids^shouM berecovered by using* product, contaminated soJL'debrhTMid*^otherTnaterfals should be plac disposal. Avoid washing, draiinlngor dfrecting material to storm*oFsa NOTE: Review FIRE AND EXPLOSION HAZARDS before pi PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method:, JRecydeas much of the recoverable pi transportation and disposal."`must !be^'fit accordance witfi"applicable] regulations.:. - PRECAUTIONARY MEASURES ' ~ ^ ' Respiratory Protection: Select appropriate NIOSH-apprqyed maintain exposures below the acceptable limits in the Healthjlasard approved air-supplied respirator^^self-contained Vreathing eq situations where the level majp^excSfy& Proper respiratof sefec trained personnel and based on the contaminant(sV tlre degiree'of respiratory protection Ventilation: Normal shop ventilation. - 1' Protective Gloves: Should be worn when the potential exists for prolonged or repeated skin contact. NBR or neoprene recommended. Eye Protection: Safety glasses with side shields; chemical splash goggles if splashing is probable. Face shield is recommended where material is handled hot and splashing may occur. Other Protective Equipment: Skin contact should be minimized. Complete protective clothing if material is being handled hot. Launder or discard contaminated dothing. Discaidextrenu11 >-"- -- shoes. XL LUBC0260/August 1989 GS6 6? SUPERFUND AMENDMENTS AND REAU7H0RIZAT20N ACT OF 1986* TITLE ID SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard __ Delayed (Chronic) Health Hazard __ Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 list of Toxic Chemicals (40 CFR 372) None TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material Is a mixture as defined by TSCA The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however. It could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. Thfc material could also become a hazardous waste if it Is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, Regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116, SECTION 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (-PROPOSITION 65-) The material does not contain ingredients) subject to the Act. LUBC0260/August 1989 4 SAL 000007004 ( tt 6S6 67 PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following hazardous substances: Categories: H * Hazardous Substance ( 1.0%) S Special Hazardous Substance (2 0.01%) E Environmental Hazard ( 1.0%) Ingredient Hydrogen Sulfide CAS Registry Number 7783-06-4 Category E Nonhazardous ingredients) information is withheld as trade secret in accordance with Section 11 of Pennsylvania Worker and Community Right to Know Act MSDS Code: LUBC0260 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT! 8/89 - Replaces MSDS dated 4/89 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. LUBC0260/August 1989 5 SAL 000007005 3 V 21oo-z^ MATERIAL SAFETY DATA SHEET Zfrte- oziostt Dow Chemical U*S.A.* Midland, MI 48674 tmergency Phone: 517-636-4400 Product Code: 19677 Page: 1 PRODUCT NAME: DERAKANE (R) 470-36 VINYL ESTER RESIN 6 86 68 Effective Date: 04/07/88 Date Printed: 04/20/88 tt$DS:00079fc 1. INGREDIENTS: Styrene monomer Vinyl ester resin CAS# 000100-42-5 30-50% CAS# 068002-44-8 BALANCE This document is prepared pursuant to the QSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances not 'Hazardous1 per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA; BOILING POINT: 294Ft 146C - based on styrene, VAP. PRESS: '7 mmHg @ 20C - based on styrene. VAP. DENSITY: 3-6 - based on styrene. SOL. IN WATER: Insoluble. SP. GRAVITY: 1.04-1.10 APPEARANCE: Straw yellow, viscous liquid. ODOR: Pungent styrene odor. 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: 70-90F METHOD USED: PrtCC ASTM 0-93 FLAMMABLE LIMITS .LFL: 0.88% - based on styrene UFL: 6.8% By vol - based on styrene EXTINGUISHING MEDIA: Water fog. foam, alcohol foam, CQ2, dry chemical. FIRE 5 EXPLOSION HAZARDS: Upon exposure to heat or flame, an an exothermic reaction can develop, followed by decomposition of product. Keep vapors away from possible ignition sources. (Continued on Page 2) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000007006 ' d 9SE0 8 SDIiSdld NOIdWUHD ZT:TT 06, 8T ddb MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 19677 Page: 2 Cr S 6 6 8PRODUCT NAME: DERAKANE (R) 470-36 VINYL ESTER RESIN Effective Date: 04/07/88 Date Printed: 04/20/88 MSDS-.000796 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) FIRE-FIGHTING EQUIPMENT: Wear goggles and positive pressure, self-contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Do not store in direct sunlight at temperatures above'120F, 49C. INCOMPATIBILITY: material * (SPECIFIC MATERIALS TO AVOID) 0xidi2ing HAZARDOUS DECOMPOSITION PRODUCTS: Pyrolysis products such as CO. HAZARDOUS POLYMERIZATION: May occur. Avoid contact with metal salts such as ferric and aluminum chlorides, unintended contact with peroxides, and depletion of inhibitor levels. Avoid exposure to direct sunlight or temperatures above 120F '(4)C) . 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Treat as flammable liquid; keep heat, flame or spark producing equipment away. Protect personnel fromstyrene vapors. Soak up spills in absorbent material such as sand and collect in suitable containers. - Residual resin may be removed using steam or hot soapy water. Solvents, are not recommended for cleanup unless the recommended exposure guidelines and safe handling practices for the specific solvent are followed* Consult appropriate solvent MSDS for handling information and exposure guidelines. For large spills, evacuate upwind up spills and contain wi th dike. DISPOSAL METHOD: Resin can be disposed of through burning in an adequate incinerator or burying in an approved landfill in accordance with federal, state, and local regulations. SAL 000007007 (Continued on Page 3) (R) Indicates 8 Trademark of The Oow Chemical Company P'd * An Operating Unit of The Dow Chemical Company 9SE0 8 SDIlSWId NOIdWdHO t>T:TT 0S, 8T ddd MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517*636-4400 Product Code: 19677 Page: 3 PRODUCT NAME: DERAKANE (R) 470-36 VINYL ESTER RESIN G S6 68 Effective Date: 0^/07/88 Date Printed: 0^/20/88 MS0S:0Q0796 6. HEALTH HAZARD DATA; EYE: May cause moderate eye irritation. May cause slight corneal injury. Vapors may irritate eyes. Vapors may cause lachrymation (tears) . SKIN CONTACT: Irritation, removal, Prolonged or repeated exposure may cause skin Material may stick to skin causing irritation upon SKIN ABSORPTION: A single prolonged exposure is not likely to result In the material being absorbed through skin in harmful amounts. The L050 for skin absorption in rabbits is >2000 mg/kg, INGESTION: Single dose oral toxicity is low. The oral LD50 for rats is >LOOO mg/kg. If aspirated (liquid enters the lung), may be rapidly absorbed through the lungs and result in injury to other body systems, INHALATION: Excessive vapor concentrations are attainable and could be hazardous on single exposure. Signs and symptoms of excessive exposure may be anesthetic or narcotic effects. Excessive exposure may cause irritation to upper respiratory tract. SYSTEMIC & OTHER EFFECTS: Repeated excessive exposures to high amounts may cause central nervous system, liver, kidney effects and respiratory or eye irritation. Repeated excessive exposures to smaller amounts may cause central nervous system effects and respiratory or eye Irritation. Styrene is reported to have caused hearing loss in laboratory animals upon exposure to high concentrations (sixteen times the TIV and higher); however, the relevance of this to humans is unknown. Neither the data from various long-term animal studies nor from epidemiology -of workers exposed to styrene provide an adequate basis to conclude that styrene is carcinogenic. In laboratory animals, styrene did not produce any effects on the fetus even at exposure concentrations having an adverse effect on the mother. In animal studies, styrene has been shown not to (Continued on Page U) (R) Indicates a Trademark of The Dow Chemical Company SAL 000007008 * An Operating Unit of The Dow Chemical Company 903 8S SOIlSdld NIOIdWbhD 87:11 0b, 8T ddd MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517*636-4400 Product Code: 19677 Page: 4 PRODUCT NAME: DERAKANE (R) 470-36 VINYL ESTER RESIN S6 68 Effective Date: OL/07/88 Date Printed: Oit/20/88 MSDS:000796 6, HEALTH HAZARD DATA: (CONTINUED) interfere with reproduction. Results of in vitro ('test tube') and animal mutagenicity tests.on styrene have been inconclusive. 7, FIRST AID: EYES: Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical personnel. SKIN: Wash off in flowing water or shower. INGESTION: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. INHALATION: 'Remove to fresh air. if not breathing, give mouth-to-mouth resuscitation. If breathing is difficult, give oxygen. Call a physician. NOTE to PHYSICIAN: The decision of whether to induce vomiting or not should be made by an attending physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. 8, HANDLING PRECAUTIONS: EXPOSURE GU1 DEL 1NE (S): The QSHA permissible exposure limit (PEL) for styrene Is 100 ppm, 8-hour time weight average. The ceiling is 200 ppm and the peak is 600 ppm* Dow internally uses the ACGIH threshold limit value (TLV) of 50 ppm, 8-hour time weighted average and a short term exposure limit (STEL) of 100 ppm. VENTILATION: Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. (Continued on Page 5) (R) Indicates a Trademark of The Dow Chemical Company SAL 000007009 * An Operating Unit of The Dow Chemical Company 9'd 9SE0 66 SDIiStHd NOIdWdHO ZT : TI 06/ 31 ddb MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636*4400 Product Code; J9&77 Page: 5 PRODUCT NAME: DERAKANE (R) 470-36 VINYL ESTER RESIN 6 S 6 68 Effective Date: 04/07/88 Date Printed: 04/20/88 MSD$:000796 S. HANDLING PRECAUTIONS: (CONTINUED) RESPIRATORY PROTECTION: When airborne exposure guidelines and/or comfort levels may be exceeoed, use an approved air-purifying respirator. SKIN PROTECTION: Use protective clothing impervious to this material* Selection of specific Items such as gloves* boots, apron* or full-body suit will depend on operation. EYE PROTECTION: Use chemical goggles. If vapor.exposure causes eye irritation, use a full-face respirator. Eye wash fountain should be located in immediate work area. 9. ADDITIONAL INFORMATION: REGULATORY REQUIREMENTS: SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories1 promulgated under Sections 3H and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title HI) and Is considered, under applicable definitions, to meet the following categories: An immediate health hazard A delayed health hazard A fire hazard SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice good care and caution to avoid skin and eye contact and to avoid breathing vapors, for additional precautions, see Dow bulletin, DERAKA.NE (R) vinyl ester resins - fabricating tips. MSD5 STATUS: Revised section 1. (Continued on Page 6) (R) Indicates a Trademark of The Dow Chemical Company SAL 000007010 a An Operating Unit of The Dow Chemical Company Z'd ?Se 3ZS S0X1Sbid NOIdWdHD 97:77 06, 8T ddtf MATERIAL SAFETY DATA SHEET Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone; 517-636-44Q0 Product Code: 19677 Page: 6 PRODUCT NAME: DERAKANE (R) 470-35 VINYL ESTER RESIN G S6 68 Effective Date: 04/07/88 Date Printed: 04/20/88 MSDS:00079& (R) Indicates a Trademark of The Dow Chemical Company The Information Herein Is Given In Good faith, But No Warranty, Express Or Implied, Is ttade. Consult The Dow Chemical Company For Further Information. SAL 00070I1 ft An Operating Unit of The Dow Chemical Company 8'd 9SE0 SDIlSHld NOIdWUHD 02:IT 06, 8T ddb Material SafetWy Data Sheet PARTALL FILM I*0 ?a TMmCWBM hUM lM< UUi an* Iimi K.rr.F.C. t a 2690-2 RVNX i .$D/lB. MAZAftD MATING SECTION 1 - hVLw NOVEMBER 1, 1987 .<*c' rv SliC, -- f A Manufacture fit XCD " M0PI*T| . -<>. r j 4 Aflortu ____________________ P.0. SOX 1045______________ Lnitrptp TtMpftOCM St. Ch*mirc .. 1.aOO<2-*MO REXC3_______1-BC5-9S3-6SQ5 City, Situ, and ZIP CARPJKTERIJS, CA S3013 Oinulemntnauon Calk REXCD 1-805-963-6505 2 3 0 SECTION 2 - HAZARDOUS INGREDIENTSTDENTITY Huatooui Compenantii, icn.mital A cemmon MmriM OSHA PEL ETHYL ALCOHCx, NORMAL BUTYL ALCOHOL (SKIN ABSORBABLE) 1000 100 ATLCVCiH 1000 so CAS _ - -s' 64-17-5 71-36-3 DENATURING AGENTSi (ONE OR MORE OF THE FOLLOWING MAY BE PRESENT) x METHYL ALCOHOL ethyl acetate METHYL IS03UTYL KETONE (SKIN ABSORBABLE) 200 200 400 400 100 SO SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS RST* ? 15E-220 GSpreacviifticy (H,0-11 SoloeLty __ _ i Water COPPLt "t Density |Air -- 11 JSPoSo?*" GREEN LI0UI0/ALC0H0w:c 1.2 WReeaitcrtivity in Meltmf Paint C.9H NO M/A (LESS THAN 35) (LESS THAN IX) (LESS THAN IX 67-55-1 U1-7S-6 ioe-io-1 Vapor Pmnrrt irrwTi Hfi 2E.B7 SECTION 4 - FIRE & EXPLOSION DATA fiAii, Poim 75 F. Method Uw-i C.C.C, FmmmaPia Limit* LL wt Air by Velum* Um 3,3* UEL Upper }6,7J TAeumt^pipcnrsmiuonr. 5?u itinruuAer Madi* USE FOAM, CO2 OR DRY CHEMICAL Special pin Fifhunc Pr^eecurn THE UCf Or SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED FOR FIRE FIGHTERS. WATER WAY =: UNSUITABLE as an EXTINGUISHING MEDIA,' BUT HELPFUL in keeping aooaoent containers gco_, AVOID SPREADING BURNING LICUID WITH WATER USED FOR COOLING PURPOSES. UnuuuaJ Fin *ne EspiMWR Haa*rw LO'Ul FLASH POINT. KEEP WORK AREAS FREE OF HOT METAL 5URFACE5 AND OTHER SOURCES OF IGNITION. SECTION 5- PHYSICAL HAZARDS (REACTTVTTY DATA) StaOiuty UiMUOi* Sta&M Coneiuona tc Avoie OPEN FLAMES, hot surfaces, electrical arcs or any ignition source. Ineoir.pataeiiity iMatenaw ic Avci4: THIS PRODUCT IS INCOMPATIBLE with STRONG OXIDIZING AGENTS, STRONG ACIDS OR BASES, alkali totals, halogens and strong alkalies. HuweM Dempoiucg. Fraeuctt THERMAL DECOMPOSITION IN THE PRESEN ,E OF AIR MAY YIELD CARSON MONOXIDE AND/OR Zn?33K CIQXIPE. ABOVE 20PC C, ACET LDSHYDE. CROTON ALDEHYOE ANO1 ACETONE. fiUWPW Miv Occur " Foiymansanor. Will So: Occur 0 ALTHOUGH THE lNr0RMATI3N AND SUGGESTIONS CONTAINED HER* IN have SEEN COMPILED rRO!Y SOURCES =rj rrVrD RELIABLE, THERE IS NC WARRANT* 0r ANY KINO, EXfifitSSiD On IMPLIED AS TO THE COMPLETENESS DR ACCURACY ' SAL 000007012 & 'd 9S0 8S SDIiStHd KIOIdWUHO 02:11 06, 8T ydy SECTION 6 - HEALTH HAZARDS Cfi 66& ACUTE HEALTH EFFECTS AND ROUTES OF POTENTIAL ENTRY. PLUS SYMPTOMS OF OVEREXPOSURE: 1, INHALATION: EYE,irritates NOSE, throat, AND RESPIRATORY TRACT. KAY 0 22DEPRESSION WITH SYMPTOMS OF HEADACHE, I INESS, LOSS OF ANO EVEN OEATH IN EXTREME CASES. CAUSE CENTRAL COORDINATION, nervous SYSTEM UNCONSCIOUSNESS, 2. SKINi 3. EYES* h INGESTION* EXPOSURE TO LIQUIO CAN CAUSE DEFATTING, DRYING, AND IRRITATION. IRRITATION TO CONJUNCTIVA 01GASTROINTESTINAL IRRITATION, INONCSS, DIZZINESS, HEADACHE, TO SEVERE ILLNESS, UNCONSCIOUSNESS. AND PERHAPS EVEN OEATH, FROM DENATURING AGENTS. NAUSEA, AND VOMITING LEADING iNOTE TOXIC EFFECTS ARE CHRONIC HEALTH EFFECTS; CLASSIC ALCOHOLIC SYMPTOMS INCLUDING BIZARRE BEHAVIOR, SLURRED SPEECH AND LACK OF COORDINATION, POSSIBLE LIVER AND KIDNEY DAMAGE. DEFATTING OF SKIN, CHRONIC CONJUNCTIVITIS, CENTRAL NERVOUS. SYSTEM DEPRESSION, ofSign* and Symptoma Expoivre OVEREXPOSURE TO FUMES - LIGHT HEADED, NAUSEOUS: EXPOSE VICT IM TO FRESH AIR. Medical Condition* Generally Aggravated by Eapeiurt Chemical Luted u Carcinogen or PotenuaJ Carcinogen PREEXISTING EYE. SKIN. CENTRAL NERVOUS SYSTEM OR RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT 1National Toxieolofy e* -- Prograa N # I.A.R.C. Monograph* 'lee G No # OSHA Yee * No # Emerpocv and fint Aid rrocoduree \. inhalation IF LICHT HEADED OR HAVING BREATHING DIFFICULTIES EXPOSE VICTIM TO FRESH AIR AND/OR OXYGEN. IF BREATHING STOPS, BEGIN ARTIFICIAL RESPIRATION AND SEEK MEDICAL ATTENTION. ROUTES OF ENTRY i-tyt FLUSH IMMEDIATELY WITH COLD WATER FOR IS MINUTES, ANO SEEK MEDICAL ATTENTION. 3.Stun WASH WITH SOAP AND WATER. ATTENTION. IF IRRITATION FROM CONTACT PERSISTS, SEEK MACICAL a. ingestion IF THIS PRODUCT IS SWALLOWED, 5EEK IMMEDIATE MEDICAL ADVICE INDUCT AND/OR VOMITING IF THE VICTIM IS CONSCIOUS. ATTENTION.________________________________________________________________ SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken it H andiutf ue Storage STORE AWAY FROM OPEN FLAMES, HEAT AND SPARKS. STORE ONLY IN AREAS APPROVED FOR FLAMMABLE LIQUIDS. REPACK ONLY INTO O.O.T. APPROVED GLASS OR POLYETHYLENE CONTAINERS SUITABLE FOR flammable LIQUIDS. Omar Frectuuoni WATER MAY BE UNSUITABLE AS AN EXTINGUISHING MEDIA, BUT HELPFUL IN'KEEPING ADJACENT AREAS COOL. AVOID SPREADING BURNING LIQUID WITH WATER USED FOR COOLING PURPOSES. EMPTY CONTAINERS MAY CONTAIN VAPORS THAT ARE FLAMMABLE AND/OR EXPLOSIVE. Step* to be Ttain m Cue Krro SOURCES Op IGNITION AND HOT METAL SURFACES ISOLATED FROM THE SPILL. FLUSH SPILLED INT0Matenalu Aaie*dorSp.UodmTrRIAL SUITABLE RETAINING AREAS OR CONTAINERS. SMALL AMOUNTS OF SPILLEO MATERIAL 7 0MAY BE ABSORBED WITH ANY S AN ARD ABSORB ANT, CAUTION1! FLOORS COVERED WITH RESIDUAL MATERIAL BECOME EXTREMELY SLIPPERY WHEN WET. V uu DiipoeeJ Mrthaoa tConeuit federal. iuu. and Inca; fefuiatieftii SECTION 8 - SPECIAL PROTECTION INFORMATIOWCONTROL MEASURES Respiratory Protection :Sp*a#j'Typei THE USE GF RESPIRATORY PROTECTION DEPENDS ON VAPOR CONCENTRATIONS ABOVE THE TIMEWEIGHTED TLVt USE A NIOSH APPROVED CARTRIDGE RESPIRATOR OR GAS MASK._________________ ' enuiauon rrttecuve Gave* Local Exhaust Mecnaucal <Geo*raA IMPERMEABLE GLOVES FOR SENSITIVE INDIVIDUALS Eye Protection Special EXPLOSION PROOF VENTILATION SAFETY CLASSES, GOGGLES DR FACE SHIELD. a^iSltflqu'pTDent EYE WASHES ANO SAFETY SHOWERS ARE RECOfTENDED IN WORK AREA. SAL 000007013 Worfc/Hygnenit Fraetiee* CONTAMINATED CLOTHING SHOULO BE REMOVED ANO WASHED IN HOT WATER WITH SOAP. :pp i 3 '90 ! 0 : 04 0 0 4 3 03 0 3 5 E ~*hE . 0 1 l' f%S BETZ PROCESS %&*) CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 GS664 (713) 367-2442 MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 PRODUCT : PROCHEM 3F28 DISTRIBUTED: MAY-10-1990 (PAGE 1 OF 3) EFFECTIVE DATE 12-13-89 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: APPENDIX/9 PRODUCT APPLICATION : AN OIL BASED ANTIFOULANT. --------- SECTION 1---.................... HAZARDOUS INGREDIENTS................................... - INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9:COMBUSTIBLE LIQUID;IRRITANT(EYE); MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT(E256);IRRITANT;PEL/TLV:NONE. THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5139P ' TRADE SECRET INGREDIENT(014);FLAMMABLE;CORROSIVE;REPRODUCTIVE TOXIN;TOXIC; PEL/TLV:10PPM. TSRN 125438 - 5175P --------- SECTION 2................... ....... TYPICAL PHYSICAL DATA-------------------------------------- --------------- PH: 50% EXTRACT (APPROX.) FL.PT.(DEG.F): 145 P-M(CC) VAPOR PRESSURE(mraHG): <10 VISC cps70F: 13 EVAP.RATE: ND WATER=1 PHYSICAL STATE: LIQUID 11.6 ODOR: HYDROCARBON SP.GR.(70F)OR DENSITY: 7.5LBS/GAL VAPOR DENSITY(AIR=1): >1 %SOLUBILITY(WATER) : 0 APPEARANCE: LIGHT YELLOW TO AMBER FREEZE POINT(DEG.F): <-30 --------- SECTION 3----------------------- REACTIVITY DATA.................................................................... STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B* THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000007014 fi&l BETZ PROCESS CHEMICALS, INC tr S 6 64 P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: PROCHEM 3F28 ........... SECTION 4........................... HEALTH HAZARD EFFECTS...................... ............... ...................... ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SEVERE IRRITANT TO THE SKIN.MAY CAUSE DERMATITIS.MAY BE ABSORBED. ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES, POSSIBLY CORROSIVE ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** CHRONIC EFFECTS OF THIS FORMULATION HAVE NOT YET BEEN FULLY EVALUATED MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS.HEADACHE AND NAUSEA. --------- SECTION 5..............................FIRST AID INSTRUCTIONS....................................................... SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ........... SECTION 6................. '------- SPILL,DISPOSAL AND FIRE INSTRUCTIONS...................... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 000007015 f&Ajfc BETZ PROCESS CHEMICALS, INC 6 S 6 64 P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: PROCHEM 3F28 --------- SECTION 7.............. ............ SPECIAL PROTECTIVE EQUIPMENT............ ........................... USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES ........... SECTION 8........................... STORAGE AND HANDLING PRECAUTIONS--------------------------- STORAGE INSTRUCTIONS*** KEEP DRUMS 6 PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR t ftgOVE THE PRODUCT^FLASH^POINT^^^^^^^^^^^^^^ ^^ THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) ************************************** ***************** ******************* APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. . , . TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: 1.8 GALLONS DUE TO (014);TREAT AS OIL SPILL . , .RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NA1993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3- ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000007016 BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET 6 S 6 fif 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 DISTRIBUTED: MAY-10-1990 PRODUCT : BETZ DM-1588 (PAGE 1 OF 3) EFFECTIVE DATE 12-12-89 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: 2,APPENDIX/9 PRODUCT APPLICATION : AN OIL BASED ANTIFOULANT. --------- SECTION 1---................... HAZARDOUS INGREDIENTS--................................ INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9;COMBUSTIBLE LIQUID:IRRITANT(EYE) : MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT(190);COMBUSTIBLE;EYE IRRITANT;PEL:NONE:TLV:NONE. TSRN 125438 - 5231P TRADE SECRET INGREDIENT(108);COMBUSTIBLE LIQUID;IRRITANT(EYE AND SKIN); PEL:NONE;TLV:NONE. TSRN 125438 - 5210P ----- SECTION 2-----------------------TYPICAL PHYSICAL DATA............................................... ............... PH: 50% EXTRACT (APPROX.) FL.PT.(DEG.F): 145 P-M(CC) VAPOR PRESSURE(mmHG): <10 VISC cps70F: 18 EVAP.RATE: ND WATER=1 PHYSICAL STATE: LIQUID 12.2 ODOR: HYDROCARBON SP.GR.(7OF)OR DENSITY: 7.4LBS/GAL VAPOR DENSITY(AIR=1): >1 %SOLUBILITY(WATER): 0 APPEARANCE: YELLOW FREEZE POINT(DEG.F): -15 SECTION 3---................ -REACTIVITY DATA STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000007017 /AS BETZ PROCESS |W| CHEMICALS, INC Cr S 6 P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: BETZ DM-1588 ........... SECTION 4...........................HEALTH HAZARD EFFECTS............................................................ ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SEVERE IRRITANT TO THE SKIN ACUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** IRRITATION OF UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** DERMAL EXPOSURES WILL DEFAT AND DRY SKIN AND CAUSE SEVERE SKIN IRRITATION; INHALATION OF VAPORS/MISTS/AEROSOLS CAUSES EYE AND RESPIRATORY IRRITATION,DIZZINESS,HEADACHE,NAUSEA. ........... SECTION 5..............................FIRST AID INSTRUCTIONS......... ............................................. SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ........... SECTION 6---------------------- SPILL,DISPOSAL AND FIRE INSTRUCTIONS...................... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER \ SAL 000007018 ftXS BETZ PROCESS |Kj CHEMICALS, INC GS66S P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: BETZ DM-1588 --------- SECTION 7........................... SPECIAL PROTECTIVE EQUIPMENT........................................... USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES --------- SECTION 8........................... STORAGE AND HANDLING PRECAUTIONS................................. STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION. STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: TREAT AS OIL SPILL . . .RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002=C0RR0SIVE (PH) ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NA1993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE).DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000007019 APR 1 0 1990 Bftz Laboratories, Inc. 4636 Soncrton Road, Trevose, Pa. 19047 6 S 6 6 6Betz Material Safety Data Sheet 84 Hour Emergency Telephone (Health or Accident) 15/355-3300 REAGENT : POTASSIUM CHROMATE INDICATOR CODE 213 EFFECTIVE DATE 01-17-90 PRINTED: 04/03/90 REVISIONS TO SECTIONS: APPENDIX;EDIT:5 REAGENT APPLICATION : FIELD TEST REAGENT --------- SECTION 1----------------------- HAZARDOUS INGREDIENTS------------------------------- INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC REAGENT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. POTASSIUM CHROMATE(CR VI)**eCAS#7789-00-6;OXIDIZERJ CORROSIVE;POTENTIAL SKIN SENSITIZER;POTENTIAL KIDNEY TOXIN;SUSPECT CARCINOGEN; PEL:0.1MG/M3(CEILING)AS CR;TLV:0.05 MC/M3 AS CR. ( ALTHOUGH EVIDENCE IS INCONCLUSIVE,EPA AND OSHA CONSIDER ALL CrVI COMPOUNDS POTENTIAL HUMAN CARCINOGENS.INCREASED RISK OF LUNG CANCER HAS BEEN OBSERVED IN CHROME PRODUCING,PLATING,ALLOY AND PIGMENT INDUSTRIES. RESULTS OF ANIMAL TESTS INDICATE SOME CrVI COMPOUNDS MAY BE CARCINOGENIC TO MAN BY INHALATION.IT IS THEREFORE PRUDENT TO TREAT ALL CrVI COMPOUNDS AS SUSPECT CARCINOGENS AND TO MINIMIZE WORKER EXPOSURE TO DUSTS/MISTS. --------- SECTION 2-----------------------TYPICAL PHYSICAL DATA--------------------------------- PH: AS IS (APPROX.) FL.PT.(DEG.F): >200 SETA(CC) VAPOR PRESSURE(mroHG): ND VISC cps70F. ND EVAP.RATE: <1 ETHER1 PHYSICAL STATE: LIQUID 8.9 ODOR: NONE SP.GR.(70F)OR DENSITY: 1.013 VAPOR DENSITY(AIRt); ND ^SOLUBILITY(WATER): 100 APPEARANCE: YELLOW FREEZE POINT(DEG.F): ND --------- SECTION 3---------------------- REACTIVITY DATA---------------------------------------------- STABLE. BETZ TANK CLEAN-OUT CATEGORY JB' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 00007020 MATERIAL SAFETY DATA SHEET (PACE 8 OF 3) 6 S6 66REAGENT: POTASSIUM CHROMATE INDICATOR - --SECTION 4---------------------- HEALTH HAZARD EFFECTS-------------------------------------------------ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN.POTENTIAL SKIN SENSITIZER ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** MISTS/AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED OVEREXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY;MAY INCREASE RISK OF CANCER;MAY CAUSE SKIN SENSITIZATION. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** INHALATION MAY CAUSE IRRITATION OF RESPIRATORY TRACT;SKIN CONTACT MAY CAUSE ITCHING AND/OR REDNESS. --------- SECTION 5-------------------------FIRST AID INSTRUCTIONS--------------------------------------------IN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR IS MINUTES r'* CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM. DILUTE CONTENTS OF STOMACH.INDUCE VOMITING BY ADMINISTERING SOAP SOLUTION EMETIC,OR OTHER STANDARD METHOD IF SOAP SOLUTION IS NOT AVAILABLE. IMMEDIATELY CONTACT A PHYSICIAN. --------- SECTION 6-----------------------SPILL,DISPOSAL AND FIRE INSTRUCTIONS-----------------SPILL INSTRUCTIONS*** GENERAL-VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL,SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. SPECIFIC- SPILL RESIDUE MAY BE REDUCED WITH ACID BISULFITE SOLUTION DISPOSAL INSTRUCTIONS*** FOR DISPOSAL USE A COMMERCIAL WASTE TREATMENT OR DISPOSAL COMPANY OR IN-HOUSE USE A CHROMATE REMOVAL SYSTEM IN ACCORDANCE WITH RCRA REGULATIONS.INCINERATION OF CHROMATES WITH CHLORIDES OR CHLORINE BEARING ORGANICS MAY BE HAZARDOUS. WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: FLOOD UITH WATER.USE OF C02 OR FOAM MAY NOT BE EFFECTIVE. SAL 000007021 MATERIAL SAFETY DATA SHEET (PACE 3 OF 3) 686 66REAGENT: POTASSIUM CHROMATE INDICATOR ----------- SECTION 7---------------------------SPECIAL PROTECTIVE EQUIPMENT----------------------------------------USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECT ION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT REAGENT EXPOSURE IS LIKELY * USE HIGH EFFICIENCY PARTICULATE CARTRIDGES RECOMMENDED SKIN PROTECTION*** RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES --------- SECTION 8-----------------------STORAGE AND HANDLING PRECAUTIONS--------------------------STORAGE INSTRUCTIONS*** KEEP CONTAINER CLOSED UHEN NOT IN USE. DO NOT FREEZE. IF FROZEN,THAW AND MIX COMPLETELY PRIOR TO USE HANDLING INSTRUCTIONS*** ( CONTAINS AN OXIDIZER. AVOID ALL CONTACT WITH REDUCING AGENTS, 5 OILS, GREASES, ORGANICS AND ACIDS. DO NOT ALLOW TO DRY. **********#*****:*****#************************************************* THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) ************************************************************************** APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: 7.9 GALLONS DUE TO POTASSIUM CHROMATE . . .RCRA = IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D007=CHROMIUM ...DOT HAZARD/UN#/ER GUIDE# IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOUN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: POTASSIUM CHROMATE(7789-00-6) ...SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: POTASSIUM CHROMATE(7789-00-6) , 11.0-15.OX ; ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE> AND DELAYED(CHRONIC) ..MICHIGAN CRITICAL MATERIALS: POTASSIUM CHROMATE(7789-00-6) ; rPA/HMIS : HEALTH - ; FIRE - 0 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B 000007022 MATERIAL SAFETY DATA SHEET EASTMAN CHEMICAL PRODUCTS, INC. EASTMAN KODAK COMPANY Kingsport, Tennessee 37662 6S6^ 6^ 3 For Health Hazard Information, Call: (615) 229-6094 For Other Information, Call Your Eastman Representative Eastman Operator: (615) 229-2000 Date of Preparation 05-31-89 riON I. IDENTIFICATION Name: "TENOX" 4A Food-Grade Antioxidant -- Synonym: PM 3539 -- Formula: Mixture SECTION II. COMPONENT AND PRECAUTIONARY DATA JP0NENT: Approx Weight % CAS Reg No Eastman Kodak No Ccsfn oi 1* EULyl ated hydroxyanisole* {.citric acid free) 70 6001-30-7 023399 30 25013-16-5 951177 See Section VI-A for information on exposure limits. ^Hazardous chemical as defined by OSHA, 29 CFR 1910.1200. B, PRECAUTIONARY LABEL STATEMENTS: Coution! MAY CAUSES SKIN AND EYE IRRITATION AT ELEVATED TEMPERATURE, VAPOR MAY CAUSE IRRITATION OF EYES, NOSE, AND THROAT Avoid contact with eyes and prolonged or repeated contact with skin. Avoid breathing vapor from heated material. Use with adequate ventilation. Wash thoroughly after handling. FIRST AID: In case of contact, immediately flush eyes and skin with plenty of water. Get medical attention if symptoms persist. Wash clothing before reuse. In case of irritation of eyes, nose, and throat by vapor, remove from exposure, treat symptomatically, and get medical attention if symptoms persist. Since emptied containers retain product residue, follow label warnings even after container is emptied. FOR MANUFACTURING USE ONLY SAL 000007023 MSDS-10.535A-1 (05-89) Replaces 11-87 Edition GS663 SECTION III. PHYSICAL DATA (1) -- Appearance and Odor: Light, straw-colored liquid; slight phenolic odor. -- Boiling Point: >482C (>900F). -- Specific Gravity water- 1): 0.951 at 20C. -- Vapor Pressure: Negligible. -- Solubility in Water: Negligible. SECTION IV. FIRE AND EXPLOSION HAZARD DATA (1) -- Flash Point: 152C (306F), Method Used: Setaflash Closed Cup. -- Flammable Limits: Not determined. -- Extinguishing Agent: Water spray, dry chemical, foam, or CO2. -- Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Water or foam may cause frothing which can be violent and possibly endanger the life of the fire fighter. -- Unusual Fire and Explosion Hazards: None. SECTION V. REACTIVITY DATA -- Stability: Stable. -- Incompatibility: Oxidizing materials can cause a reaction. -- Hazardous Decomposition Products: As with any other organic material, combustion will produce carbon dioxide and probably carbon monoxide. -- Hazardous Polymerization: Will not occur. SECTION VI. TOXICITY AND HEALTH A. EXPOSURE LIMITS -- Threshold Limit Value (TLV) for vegetable oil mist: 10 mg/m3-TWA, ACGIH, 1988-1939. -- Threshold Limit Value (TLV) for other components: Not established. -- OSHA Permissible Exposure Limit (PEL) for vegetable oil mist: 15 mg/m^-TWA (total), 5 mg/m^-TWA (respirable fraction). -- OSHA Permissible Exposure Limit (PEL) for other components: Not established. B. EXPOSURE EFFECTS Inhalation: Vapor from heated material may cause irritation. Eyes: Liquid and vapor from heated material may cause irritation. Skin: May cause irritation. Carcinogenicity Status: Butylated hydroxyanisole (BHA), a component of this material, has been classified in Group 2B by the International Agency for Research on Cancer (IARC) (2); and, for hazard communication purposes, BHA is considered a carcinogen or potential carcinogen under the OSHA Hazard Communication standard. U. S. Food and Drug Administration (FDA) and U. S. Department of Agriculture (USDA) regulations continue to permit the use of BHA as an antioxidant in foods. SAL 000007024- MSDS-10,535A-2 (05-89) Replaces 11-87 Edition Cr S 6 6 3 The sAfety of BHA as a food-grade antioxidant was originally demonstrated in a large number of feeding studies carried out with rats and dogs in several laboratories (3). These studies showed no adverse effects at levels several hundred times those currently permitted in the diets of humans in the U.S. More recently, long-term feeding at high levels (1-2X in the diet) to rats, hamsters, and mice has produced benign and malignant tumors of the forestomach, but no other sites (4). In these studies, food containing high levels of BHA may be in almost constant contact with squamous epithelium in the rodent forestomach (5). Experiments in these rodents with forestomachs and in a species with an equivalent structure (pars esophagea in pigs) have shown that levels of BHA above 0.5% in the diet produce hyperplasia of the forestomach (and possibly of the pars esophagea in pigs), but no such changes were found in similar studies in animals (including a rodent) that do not have a forestoroach, i.e,, dogs, monkeys, and guinea pigs (3). Humans do not have any region of the stomach comparable to a forestomach, and no-effect levels were far above those to which humans could reasonably be exposed under current regulatory limits. A weight-of-the-evidence assessment of the available evidence strongly suggests that the finding of forestomach tumors in mice, rats, and hamsters given very high doses of BHA is not relevant to humans ingesting BHA at levels currently permitted in food in the U.S. C. FIRST AID Inhalation: Remove to fresh air, treat symptomatically, and get medical attention if symptoms persist. Eyes: Immediately flush with plenty of water for at least 15 min and get medical attention if symptoms persist. Skin: Wash skin with soap and plenty of water. Get medical attention if symptoms persist. Wash clothing before reuse. D. TOXICITY DATA Toxicity data for the antioxidant used in this formulation are available in the following EASTMAN CHEMICAL PRODUCTS, INC. MSDS: Butylated hydroxyanisole (citric Acid free) MSDS-10.991A SECTION VII. VENTILATION AND PERSONAL PROTECTION A. VENTILATION Good general ventilation (typically 10 air changes per hour) should be sufficient to control airborne levels. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in special circumstances such as poorly ventilated spaces, spraying, heating, etc. B. RESPIRATORY PROTECTION If respiratory protection is needed, an appropriate N10SH-approved res pirator for organic vapor and/or mist should be worn. If respirators are used, a program should be established to assure compliance with OSHA Standard 29 CFR 1910.134. SAL 000007025 MSDS-10,535A-3 (05-89) Replaces 11-87 Edition G S6 63 C. PKTN AMD EYE PROTECTION Wear safety glasses with side shields (or goggles). A face shield is recommended. Impermeable gloves should be worn. An eye bath and washing facilities should be available. Wash thoroughly after handling. SECTION VIIT. SPECJAh STORAGE AND HANDLING PRECAUTIONS Keep from contact with oxidizing materials. Since emptied containers retain product residue, follow label warnings even after container is emptied. SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES Steps to be Taken in Case Material is Released or Spilled: Spills may be collected with absorbent materials. Prevent runoff from entering drains, sewers, or streams. Waste. Disposal Method: Incineration. Observe all federal, state, and local laws concerning health and environment. SECTION X. ENVIRONMENTAL EFFECTS DATA This material lias not been tested for environmental effects. Data for the components of this material (6-12) have been used to provide the following estimate of environmental impact: this material is expected to have a high biochemical oxygen demand and significant potential to cause oxygen depletion in aqueous systems, a high potential to affect some aquatic organisms, a moderate potential to affect the germination and/or early growth of some plants, and a low potential to affect the growth of some plant seedlings. The direct, instantaneous discharge to a receiving body of water of an amount of this material which will rapidly produce by dilution a final concentration of 1.0 rag/L or less is not expected to cause adverse environmental effects. After dilution with a large amount of water, followed by secondary waste treatment, this material is not expected to cause adverse environmental effects. SECTION XI. TRANSPORTATION DOT Hazard Cljssification: Not regulated by DOT. SECTION XII. REFERENCES 1. File data, Material Safety Frogratn, Eastman Chemicals Division, Eastman Kodak Company, Kingsport, Tennessee. 2. I ARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO HUMANS, Vol. AO. International Agency for Research on Cancer, Lyon, France, 1986, pp. 123-159.3 * S. 3. Sutylated HydroxyanJsole - A Monograph. Washington, DC, International Life Sciences Institute (1LSI), 1986. A. GANN 77, 1083-1090 (1986). S. George, W. Comparative anatomy and physiology of rodent stomachs. European meeting of the Toxicology Forum. Geneva, Switzerland, September 22-26, 1986. SAL 000007026 MSDS-10.535A-A (05-89) Replaces 11-87 Edition I CS6 63 6. Unpublished data, Health and Environment Laboratories, Eastman Kodak Company, Rochester, New York. 7. K. Verschuercn. HANDBOOK OF ENVIRONMENTAL DATA ON ORGANIC CHEMICALS, 2nd Edition. Van Nostrand Reinhold Company, New York, 1983. 8. Batel1e's Columbus Laboratories. WATER QUALITY CRITERIA DATA BOOK - VOLUME 3 - EFFECTS OF CHEMICALS ON AQUATIC LIFE, Selected Data from the Literature Through 1968. U.S. Environmental Protection Agency, Washington, Project No. 18050 GWV, Contract No. 68-01-007, May 1971. 9. WATER RES 13, 627-630 (1979). 10. WATER RES 13, 623-626 (1979). 11. Z WASSER ABWASSER FORSCH 15, 1-6 (1982). 12. Z WASSER ABWASSER FORSCH 11, 161-164 (1978). SECTION XIII. HAZARD RATINGS Health Flammability Reactivity HMIS* Rating: 1 1 0 NFFA** Rating: 1 1 0 NOTICE: These ratings involve data and interpretations that may vary from company to company and are intended only for rapid, general identification of the magnitude of the specific hazard. TO DEAL ADEQUATELY WITH THE SAFE HANDLING OF THIS MATERIAL, ALL THE INFORMATION CONTAINED IN THIS MSDS MUST BE CONSIDERED. The customer is responsible for determining the proper personal protective equipment needed for its particular use of this material. '"Hazardous Materials Identification System's jHMIS) Revised RAW MATERIALS RATING MANUAL, National Paint & Coatings Association, Fall 1984. **NFPA 704 Standard System for the Identification of the Fire Hazards of Materials, National Fire Protection Association, 1985. The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers. C/10535A/220912/R-1, S-l, F-l, C-0 SAL 000007027 MSDS-10,535A-5 (05-89) Replaces 11-87 Edition TrAcE SYS TJ3MS r X NO ------ 933# Corporate Dr., 1801, Schertz, TX. 78L54 Itonuficturers of ma r k -- i t; Fax:(512) 651-5401 Phone:<512) 651-9651 AP* 0 2 W* MATERIAL SAFETY DATA SHEET 686 63 Date: February 26, 1990 I.PRODUCT IDENTIFICATION Tfd# Ndffl#l MAKK-IT Synonyms: None Chemical Family: Metal Soap(s) in solvent Formula: Proprietary Hazardous Ingredients / OSHA: A. Trichlorotrifluoroethene = 88%-98% B. Metal Salts of 2-Ethylhexanoic acid = 12%-2% Warning Statement: Do not ingest II. PHYSICAL DATA Boiling Point: 117 F. Specific Gravity: 1.5 (Water=l) Vapor Density: 2.9 (Air=l) Appearance & odor: Clear to dark amber Melting Point: n/a Vapor Pressure: 330 mm. Solubility <H30): .02 % by wt. liquid - mineral spirits odor. FIRE AND EXPLOSION DATA Flash Point: None (Closed Cup) Flammable Limits: None Extinguishing Media: Foam,C02,Water Spray,Dry Chemical Special Firefighting Procedures: None Unusual Hazards: Exposure to heat builds up pressure in Cool with water stream. containers. IV. HEALTH HAZARD DATA Threshold Limit Value: 1000 PPM Effects of Overexposure: Lightheadedness,giddiness,shortness of breath,possible narcosis at high concentration Emergency and First Aid Procedures: Inhalation: Remove to fresh air. Call a doctor. Do not give epinephrine or similar drugs Eye Contact: Flush with water Skin Contact: Wash well with soap and water Ingestion: Call doctor immediately. Report ingestion of product by chemical name and family (above). In case of severe emergency, call Trace Systems for specific trace elements in formulation. (CONTINUED) SAL 00000702B 8 S6 62 L E SYSTEMS^IMC^ SDS - February 26, 1990 \ REACTIVITY DATA Stability: Stable Conditions to avoid: Open flames or high temperatures Incompatibility: Alkalai or alkaline earth metals Hazardous Decomposition Products: Hydrofluoric and hydrochloric possible phosgenes Hazardous Polymerization: Will not occur acids; /I. SPILL OR LEAK PROCEDURES Steps to be Taken: Ventilate area - especially low points Remove open flames Waste Disposal Method: Evaporate outdoors VII. SPECIAL PROTECTION INFORMATION Respiratory: Use air mask in very high concentrations Ventilation: Local exhaust if large amount of vapor present Mechanical exhaust in low areas Protective Equipment: Gloves and goggles when handling liquid VIII. SPECIAL PRECAUTIONS Handling and Storing: Store in clean dry area. Do not heat above 125 F. SAL 000007029 Apr o i en Material Safety Data Sheet flLERO. 920i405-923RO.? ircxTiraxcuru*^ " * 1827 Red Oil GS6 58 gwufacM-a Heriam Instrument Xi4"" 10920 Madison Cleveland, OB 44102 tBajrintidmTik(<PvPmuyiwtJua 33SW tfe- 216-281-1100 216-281-1100 9/1/88 SECTION 1 - IDENTITY Cgig>oc Kane M m UMj (Tva*s/mnH* M*'*^l<******^ / Rred Oil Om M*. N.A. --------------------------------------------------------------------------------------------------- 5=^--------------------------------------------'---------------- ---------------------NjAs------------------------------------------------------------------- ----------- Petroleum Hyrtrftcarhnn N.A. SECTION 2 - HAZARDOUS INGREDIENTS Pmxap*! Huartfoui GcmpoaesUi] <cAm*7 A (nftmw hbi|i Deodorized Kerosine (CAS # 8008-20-6) % 50 Petroleum Distillate (CASf64741-77-1) 40 Petroleum Lube Oil (CASI64742-65-0) Red Dye (CASf4477-79-6) 10 Trace TVmhftlrf Unit VaAj# tmkai 50mg/M^ AS mist 5mq/^ AS mist 5ma/M^ as mist N.A. SECTION 3 - PHYSICAL & CHEMICALCHAKACTER1ST1CS (Fire A Explosion DsU) SoOiftt Paul kP)trVcrostluVnotli\iiki r ASoVfufuemilitv mApe MOdMerM 370 F N.A. V^pQT PMtyiAk-U Negligible Red, odorless >1 Sf*d6t Cnvit7(K/>*)l Zvipnuat lUu I--------------n RuAinty a ** .827 N.A. N.A. Vapor NiwwanKf \ rJ 280 F ftpvul r*ptrwbra rkaLSubW liBMi A A % VdA Lew 2.1 LT^ 6.0 KSf^ co2.pr3fnich..,ftaasr n.a. Do not extinguish with water Ue>uu*] Ftr tx^i>*x>e Hiurtil M*A SAL 000007030 G S 6 58 SECTION 4 - PHYSICAL HAZARDS jjgj*1* ImnitiiAtr (Mfunab %*"** Avoid exposure to_heat Strong oxidltlng iqtnti flaiiXiSUmPkOmu CO, CO. Kuirte* _ Kiyfttw O deetflST Pl)MraUa WiBNMOccttr 8 UAvtid FILE HO. 920:405-923RO-2 SECTION fi - HEALTH HAZARDS TVwbeU Limit Value 5 ing/W as mist Stem ud J. Amu <tipoww Ovwiywuw High concentration of vapors causa i CVmic Qurvapowga ________________________________________ _______ MrdjcalCeodilioBf GaMrafly A**Tv*urf b> N.A* headache, nausea tfcemiVaJ titled u Cvdbocta r Feuetia) CarciaogrB OSHA fVmiaaJbW rtporurr limit N.A. led F*r*i Aid rrocadume hKaoucfciaaJ Toakaloc *It*e & ACCIK TVwtttW limit Value N.A. 1.A.JLC. Ym D Meofrph* N* CX OtwEimvi limb Ua^ N.A. l. IfthtllUSB X- y*i Remove to fresh air Flush with water S Sto 4 iaf**uoa Wash with soap and water Do not induce vomiting, consult physician 'esurST SECTION 6 - SPECIAL PROTECTION INFORMATION Knpjnor* ProMTUot sp<>V' Not required VcoUUuoe N.A. Local CithJawuat N.A* hroioctiv* """ oiov pix proof Oiba; Protaetiv*"- Oo(K<4 of quipm*ot None IM) N.A. "ftyt ******* CMoa) N.A. Safety Classes N.A SECTION T - SPECIAL PRECAUTIONS AND SPILLT-EAK PROCEDURES JFawKaawUiLoaa4, be b*STuawkraft ,, ,_ Keep container closed Fracasucaa N.A. &-<? u bt Taka* i CUT if feWuarf or SpOlad Use absorbent to soak up Wau Disposal Incineration SAL 000007031 IMPORTANT Do doI leave any blank apacea. If required Information U unavailable, unknown, or dcx-t not apply, Indicate. A-34284 APR o a to - *JateriaJ Safety Data Sheet 920t405-923RU*2 . #100 Red Unity Oil tAilf *# Z2m Heriam Instrument J.D920 Macuson Ave. Cleveland, Ohio 44102 KKf^scjt^ftCtrU* rrfffmiF--rtf^rtbm . ; ~ ^ SECTION 1 - IDENtSy-^ If **to1' 100 Red Unity Oil CWsaical *F?inZrm_ik___________________ N-A-______________________________ N.A. 6 S 6 5 9. 216*281-1100 216-281-1100 9-1-88 CWN*. Esr' N.A. JKLA.__________________ _ SECTION 2 - HAZARDOUS INGREDIENTS Prieap*.' Cottypo*m' fcA*a*em' 4 eocasa mafl'#__________________________________ _______ TVrvboV liait V*Jwf Monocbloronapbthalene (CAS# 25586-43-0) 54________________________ N.A. Naphthalene (CAS# 91-20-3)110 ppm Pichloronapbtbalene (CAS* 1825-30-5)TraceN. A. Petroleu-T. Distillate (CAS* 64741-77-U______ 3Smg/K3 c ^ ft Petroleum Lube Oil (CAS* 64742-65-0)9^5mg/M3 as mist Red Eve (CAS? 4477-79-6)________________ TrrAv* SECTION 3 - PifYSICAL 8 CHEMICAL CHARACTERISTICS (Tire A Explosion Data) Smiiag Ptae: VcOuji fcy Vo^uat fV 430 F m N . A. Sca)bbt> tom"* Nil Vet Dmmty (Air - it >1 R^cific Cnvtt; th^D)i tvKvitat Mu t ... ter*" l.o N.A. Nil Vlffi Red, moth ball odor fW Km _ _ _ _ rWacniU Lmwt* .2 85 F teAj%byVofcmr TTAfiaf-" c2 Dry hen>- Asssr IVia* Prwrfw Toxic vapors mav _be_p_roduced,_ use self-containpd breathing apparatus VsvirxJ and ll^uacc Rucd< N.A. SAL 000007032 g's6 59 i nos 4 - PHYSICAL HAZARDS jESS* i &SST Do not' heat iMMubatr Oxidizing agents 4lUWUI 5*eoa^>o*jUo* ProtfvflU HCl _________ X7 Oww P (Smdjlim PeJ>-BtfriutM WO Kt Oww * Anid K.A. FILE WO. 20t405-923RP-2 SECTION 5 - HEALTH HAZARDS dSt^L 50~ mg/M^ EoTud J. Anti fymptom# *f Eiywoi otan I CWwir (Svu^ofwt NiAu- Updicfe] Co&diuoa* Canl) Acrvt< b? Csfevurv N.A. Vapors may irritate eyes. skin dermatitis Ck+a>u} Lir-W u Ctreuegn * PoUBUfcJ CfcrCL&Of OS K A PtmuM/feir Eifocurr Ltsul N.A. yh>ttfj0rBufcJTptjtfrji<-C H* XD ACGIH TVwboU Uai\ v*h N.A. txxt:--vs-bN X OUrlffMiint limit taid y.A. . Ati Prvcadum ) Ifch&llUOb Remove to fresh air 1 Ei I Su Flush with water for IS minutes Wash with water, remove contaminated clothing 4i Do not induce vomiting, consult physician CSKA V- C M X> SECTION 6 - SPECIAL PROTECTION INFORMATION ftmpiraiAn Prmctwc (Sp^K Tyj N.A. r''reitljuos Yes UcMi tibasci Ptbutuv* Obvn Oil proof Ou* Proi^cTjv, o. E^uipt N.A. N.A. <CnJ N.A. Iptoil N.A. OtW Safety Glasses N.A, SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Keep container closed g--_ ' 1-- ~ ________**** AvniH breathing vapnr^ nd rnntact with sV^n ( Clean up spills with absorbent ) -------------- Incineration ____ ______________ ^ IJU OtJDQMi MnboOa SAL 000007033 IMPORTANT Do boI Imvi jjy blank ipece*. If required taformbtioo U onav&Qjtblc, unknown, or doe* not feppTy, 90 LodicoW. A-34285 II I W-------- ' Material Safety Data Sheet Ma* b* f U> comply iili OSHA't HtuH Camatuateatiaa tscrs 1910,1900. IumIcri mm to --writad im Ifictflr mntricuu . " -LBTK>. -920:405-924BA-3 gvck iDDnrnnt *W1Icilia Nut M a M^ IM) -- #295 Fluid G s 6 60 SECTION 1 - KanttCMtorart Kue AidiM* Ctty, 9tate, aai QP Keriam Instrument 10920 Madison Ave Cleveland, Ohio 44102 Emreeacy Telephone No. (216) .281-1100 Otto lafarmatica CMb (216) 281-1100 r r .. _ 6ECTION 2 - HAZARDOUS INGREDIENTSTDENTTTY Haaardoua Ccmpo&raUa) (chemical A camman BamUM OSHA fcl Acetylene Tetrabromide (CAS#79-27-6) Monochloronaphthalene (CAS#25586-43-0) Naphthalene (CASI91-20-3) Dichloronaphthalene (CARil 825-30-5) Red Dye (CAS#4477-79-6) N.A. N.A. N.A. N. A N.A. . 2 -23-90__________________ __ ACG1H TIV Other Exposure limit# 14mg/M^ M.R. N.A. N.A. 10 ppm N.A. NA N.A. . mh N.A. V (aptionali CAS NO. inn* . >1% Trace Trace Trace SECTION S - PHYSICAL & CHEMICAL CHARACTERISTICS P'wt'Ttf Point 474F Specif Grraavvisity 2.95 SotubJity to Water SSSSo, Vapor Dcatny tAJr * II ^ ^ .062G/100G # 60 F Tted color, moth-ball. tVDe_odor ftoaeltmty in Water Vtltiti Pcint None SECTION 4 - FIRE & EXPLOSION DATA Flaeh Non-- - Method ***' Flashing Astalfnitioa Temperature N.A. ExUnfuiahar Media Flammable Limit* LEL to Air * by Volume Le*er Non-flairmabl e SjpoeiaJ Fire Fifbtinf Proccduraa Full protective gloves, clothes and boots. Vapor Pituvur town Kf UEL Upper N.&. Use self .02 ___________________ contained breathing apparatus^ Unuaua! Fire and Czploaioe KaxanU N.A. 00000703A SAL OO&rtL* U2t) 90-te9~0(*l aU9-9^09Tl*o6to?^0 3U| '<uidux>3 unuflpqr^ uretj*ury |0 <X-twQ Aq peiuuj yij-fto `ntdiptn 00 *.{|dd joa f9op 40 UitoiqiiQ '|q{itAian f) aoqirajo/uj pupbM j| i93da ipn^q Xa abjj )oa oq IXVXUOdWl fitOXOOOOO 1VS MOtUUJ V N )a*<niml>3 9qi^oq *V*N <no S3x66o6 Aqajes "VN tds jxj Y'N {UTqOiMtptMt -sjodBA s9ao^6 snoiAaediui TN w(rial Bui^Bajq PToav ST3A uaoiq Borjtrna*^ sanasvaw iohxnoo/wou,vwho3ki NOLioaiOHd TVioadS - b noixoss "Vdd I&X>I ^Oe^UOQ ttwiipJw pao( fwi '*m* `i*Jpej *dn daans 04 punodujoo 6uiqaosq5 asn 'eaae a^exx^uaAptr<*s m '**3 1 u T*X 1 d*i3 pesoxo asuTPiuoo dad# *40*41100 utxs pup aAa ptoA SX) oq aapo eoiqoejd #(ep|no YHSO) tuaa x 4 saodPA xojquog atuoiS P*1* Pv^puiy of U*T*X *1 ntofinfsijj sanaaaooHd Mvaimras o>rv sKOuavoaad ivioaas - t N01103S uuc^u4,4 luuipejw i{33S 'fcUT^TuJGA donput qou oa BOpulQl > / 6uiqqoxo paqeuTurequoo eAoaiaa 'aaqpA pue deos qqxn qsPM uoxquaqqp XBDtp^ 'saqnupn sx aoj aaqpft qqxn qsnxa r '11014113446 XBSipaui Jl^SS `'JTP qpaaj o4 aAotueyH / A31N3 U**S S ( 30 M<3 ( \saxaoa \ aon^MOl 'l K O --A VHSQ 8 *M vqtfufeooH O "A am 8 M iiSo4^ Mjnpaoou pry ii*j ____________ pci Ajulaui3 WIOBOA3 (l^awj M >>octji3 ri p*tn fiwtuQ *Y"N MMOS3 ptllAljJfV ^nurniQ looeiipqoj *Y"N ________f MMOdSJ JO Ni^ja/S ________ __________ __ ______________________ pciwifr AanCuy otup6ao 'aopo axqpadjBesxci w"Vl SQHVZVH HXTV3H - 9 NOU033 V*M P*wv a 0 *.N QMA sei ainwmitf ij. ggrtc ggq Aq uoiqTcotiaooaa japTurug uafojpAH pw auimoja Hnwaniapaou wa}w|Ma*Aiaamwqfl wwputiH ' V&9S 3 -jeqqtU pu^ soj^sexa qsaa ' siesta snauej-ubti _______ dmww*-- (Viva UIAU3V3H) SdWZVH TV3tSAHd"9 N0I103S Material Safety Data Sheetin 11 bi 1 11 --i. ` : ^--*XI4K>* 920:405-92488-3 - ---------eapcKipCHnFim GdiMtNiMlMfiiUdtolW pr.v w l n)j wll* OSHA'i tUuri Ce*nttietja* tuadard. fiCTS 1*)0. U00. Iiaadard mmi to --iiUto to firfflr raqirinwiaii 4175 Blue Fluid _ ' CrS 6 61 SECTION 1- Itodtourn Kuh Heriam Instrument +Mnm 10920 Madison Ave. cttj, Sun, aad ZSf Cleveland# Ohio 44102 ftinttoi if Nnoii >r / J,s s7 f5?N* (216) 281-1100 - (216) 261-1100 2-23-90 6ECTI0N 2 - HAZARDOUS INGREDIENTS/IDENTITY tfasardoua Cmpeocetd) tetoaidl A temaac aaa*d OSHA m Mixture of Brccdnated Ethyl Benzenes N.A. . ACC1H nv N.A. Oitor Eipwtn touu N.A. % fepciacttlt 100% ChoAS. - Rrrm^thvlbenzenes (CAS11585-07-5) - Dibromoethylbenzenes(CAS#30812-87-4) - Tribrorroethylbenzenes (CAS#31195-17-2) Uprnspnp fCAS#8008--20--6) Blue Dve (CASf17354-14-2) N.A. N.A. 50mg/M3 N.A. N.A. N.A. >2% Trace SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS 400-500 F (250300C) Vipor Dm*tyiAfrl) 9.4 fcohabiitv lb Wiir Negl igihle_____________________________ Appeirib tM Oder * Clear liguid, light to straw yellow^ moth ball odor. &**/>-n 1.73-1.75 ^- Viper Prtjiufr tom lUmivity tft Wilrr Hrhiw PeiM N.A. N-A. N.A. SECTION 4 - FIRE A EXPLOSION DATA flub *,al None Mitfcod U*to riimmibk Litoiu 1XL to Air V by Volun* Lmr ^ ^ Aete-lfnitisQ Timptrstwt Ttrt Praadim ErUnxuiihrr Mdi Water, m . rhpmiral Fnm Non~ f1armable UEL Uppirr JfcLA* Ifousu*! Pit* isd Explotiee Kturdi N.A. SAL 000007036 SECTION S-THYSICA1/HAZARPS (REACTIVITY DATA) G S6 61 **b0tty ItuSC14* TaS3** Avoid contact with finely divided reducing metals (Aluminun) bromnaubflity " m**n****' Avoid contact with finely divided reducing metals._____________ ... " lPUTMfUW^wMidrU*. Hydrogen Bromide* Carbco Monoxide^ Carbcn Dioxide K*yOerr b Cpeditiofti WS Km Occur B to Avoid " -- SECTION 6 - HEALTH HAZARDS t.Acuto tGknak Nasal or skin irritation Ijmploiu oiCtpmurt NdSdl ilTitStion Possible liver and Kidney damage Mdca) Condition* GeoeraUy Ai^ravaud by Eopecur* NA CUmittl Liaud a* Cardaocta m Fount!*) Carciaotn jg ^ Nation^ Toilkokigy Y-- P Prfr* No B 1AAC. Yto O Mmnfrtpli* No S BMfttTKy tad Frot Aid rtoeadoroa gfcjn vash with soap and water.________________________ OSKA Vm No B I. lahalaiien Remove to fresh air. ROUTES OF ENTRY 1 Eye* 3. Stin 4 I&fecuofi Flush with water. Wash with water and soap. Induce vomiting. SECTION 7 - SPECIAL PRECAUTIONS AND SPILLLEAK PROCEDURES Precaution* to b* Taieo teHandiiAtandSioratt________Avoid skin and eve contact and avoid breathinq vapors. biker Precaution* N.A. Slap* u> Maiertai bue fTuawb*t*c*i4n Ca* or Spilled Position pail or drum to minimize leak. Absorb spilled material with absorbent. Nelho^i^oMuJi federal, uu. and toeaJ refutation*) Contact local EPA. SECTION 8 - SPECIAL PROTECTION INFORMATION'CONTROL MEASURES Kevpiraiery Protection Specify T>**> Oraanic VaDor Cannister WctititjOfl |*-1 Meckinio) Yes E^.t NA_ N.A. Protective Glov" Rubber Gloves PElro* t*cn fifwda! N.A. Safety Goqqles Otoe N.A. Other Protective Ckn_tutk| or Lquipnest ^VkHypenit Praetic** Pnvpralls__ SAL 000007037 Wash thorouahlv with soao and water after use. ___ IMPORTANT Do not Wove any blank apaeea. If required Information b unavailable, unknown, or doei not apply, ao indicate. CO-Flft Prirn*d by LabelmMUf, Drwuon of Anancan Labelm** Conip*ny a* Chicago. B. C064&-671 1-e00~62V&60fl (32') 47*^900 MATERIAL SAFETY DATA SHEET NALCO PRODUCT nalqt, 5270 liquid CS65TEmergency Telephone Number Medical (312) 920-1510(24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NAIOO 5270 IZQUID DESCRIPTION: A blend of alkyl phosphates alkyl phosphoramide salt in heavy aromatic naphtha NFPA 704M RATING 1 HEALTH 2 FIAMMABILETY 0 REACTIVITY 0 OTHER 0=lnsignificant 1=Slight 2=Mbderate 3=High 4=Extrenve SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Qcanmunication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT (S) CAS ft APPROX. % Heavy arcanatic naphtha 64742-94-5 10-20 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: May cause irritation to skin and eyes. Prolonged inhalation of vapor may be harmful. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHAIATION: Flush with water for 15 minutes. Call a physician. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is kncwn. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. PAGE 1 OF 6 SAL 000007038 NALCO CHEMICAL COMPANY NAPERVILLE. ILLINOIS 60566-1024 6 S 6 5T MATERIAL SAFETY DATA SHEET NALCO 2 PRODUCfoiim 5270 LIQUID Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION raiMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INHAIATION: May cause irritation with prolonged contact. May cause irritation with prolonged contact. Prolonged inhalation of vapor may be harmful. SYMPTCMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of heavy aromatic naphtha can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: Prolonged skin contact with heavy aromatic naphtha can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING CONDITIONS: A review of available Hat-a does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted on this product. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Pale yellow DENSITY: SOLUBILnY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: POUR POINT: FLASH POINT: FORM: Liquid 7.7 lbs/gal. @ 60 Degrees F Insoluble 0.94 @ 60 Degrees F 6.5 110 cts @ 100 Degrees F -40 Degrees F 150 Degrees F (FMCC) ODOR: Kerosene ASTM D--1298 ASTM E--70 ASTM D-2983 ASTM D~97 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 150 Degrees F (FMOC) ASTM D-93 EXTTNGUISIIING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. PAGE 2 OF 6 SAL 000007039 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 AREA 312-961-9500 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5270 LIQUID Emergency Telephone Number Medical (312) 920*1510 (24 hours) 6S 6ST SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL. DEQCMFOSI TION H30DUCTS: In the event of combustion CO, 002, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTTLATION: General ventilation is recommended. PROTECTIVE EQUIFtMENT: Use impermeable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.) when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-H0UR TELEPHONE NUMBER (312-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as saw dust, clay, soil or any commercially available absorbent. Shovel PAGE 3 OF 6 SAL 000007040 NALCO CHEMICAL COMPANY ONE NALCO CENTER < NAPERVILLE, ILLINOIS 60566-1034 AREA 312-361-9500 MATERIAL SAFETY DATA SHEET NALCO PRODUCT^ 5270 LIQUID Emergency Telephone Number Medical (312) 920-1510(24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. DISPOSAL: If this product heormes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Ccarservation and Recovery Act (RCKA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. As a non-hazardous liquid waste, it must be solidified before disposal in a landfill. Can be incinerated in accordance with local, state ani federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA: 96 hour static acute LC50 to Bluegill Sunfish = 54 ppm 96 hour static acute I50 to Rainbw Trout 72 ppm 96 hour static acute LC50 to Bull Mirmcws = 4.7 ppm If released into the eiwironment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CCMEUSTTBLE LIQUID, N.O.S. NA 1993 CONTAINS - AROMATIC HYDROCARBONS SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shewn belcw. Heavy aromatic naphtha - Ctsnbustible, irritant Heavy aromatic naphtha - 100 ppm TLV PAGE 4 OF 6 SAL 000007041 i NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 AREA 312-961-9500 N NALCQ MATERIAL SAFETY DATA SHEET PRODUCTnaxod 5270 LIQUID Emergency Telephone Number Medical (312) 920-1510 (24 hours) C$657 SECTION 14 REGULATORY INFORMATION Manufacturer1 s recommendation ( CONTINUED ) CERCXA, 40 CFR 117, 302: Notification of spills of this product is not required. TOXIC SUBSTANCES CONTROL ACT (TSCA) : The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710) . RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPAKT C & D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER POLLUTION CONTROL ACT, Cl FAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW IAWS: This product does not contain ingredients listed by State Right To Know Laws. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your PAGE 5 OF 6 sal OOQqo fSJALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 AHSA 312-961-9500 N NALCO MATERIAL SAFETY DATA SHEET PRODUCfeiro 5270 liquid mergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 16 USER* S RESPONSIBILITY { CONTINUED ) local sales representative for ary farther information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, FB 33-135855, 1983. CASAREIT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J. , Klaassen, C. D., and Adraur, H. O., eds., Macrol 1 lian Publishing Ccatpany, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Ccanpany, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving-, ed.. Van Nostrand Reinhold Ocsnpany, N.Y., 6th edition, 1984. IARC PONOGRAPHS ON THE EVAIIJATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: Wbrld Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE W0RKR0CM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: John J. Kasper, MSc., Manager Product Safety DATE CHANGED: 11/04/86 DATE PRINTED: 03/12/87 PAGE 6 OF 6 SAL 000007043 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 AREA 312-961-9500 m 11 CYJXNAM/O GS 656 AMERICAN CYANAMID WAYNE, NEW JERSEY 07470 Page 1 of 5 MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE: (201) 835-3100 MSDS NO. 0086-03 CAS NO. 000121-75-5 DATE: 3/22/89 PRODUCT IDENTIFICATION TRADE NAME CYTHION Insecticide, "The Premium Grade Malathion" SYNONYMS: KALATHION; 0,0-dimethyl phosphorodithioate of diethyl mercaptosuccinate; Butanedioic acid,f(dimethoxyphosphinothioyl)thiol, diethyl ester; S-fl,2-bis(ethoxycarbonvl) ethyl!0,0-dimethvl phosphorodithioate CHEMICAL FAMILY: Orqanophosphate MOLECULAR FORMULA: CinHiqOfiPS* MOLECULAR WGT.: 330.36 WARNING STATEMENTS CAUTION. KEEP OUT OF REACH OF CHILDREN. INHALATION, OR SKIN CONTACT. HARMFUL BY SWALLOWING, HAZARDOUS INGREDIENTS COMPONENT Malathion CAS. NO. 000121-75-5 % 91-96 TWA/CEILING 10 mg/m3 Shr TWA REFERENCE: Malathion 10.0 mg/mJ : ACGIH-88 (skin) PHYSICAL PROPERTIES APPEARANCE AND ODOR: Clear, brown to colorless liquid; characteristic mercaotan odor BOILING POINT:____________ 312.8`F 156*C g 0.7 rnn Hq. MELTING POINT:37.13*F 2.85`C VAPOR PRESSURE:0.00004 mm Hq g 30*C SPECIFIC GRAVITY: 1.23 g 25'C VAPOR DENSITY:Not Applicable % VOLATILE (BY VOL.): Negligible OCTANOL/H?Q PARTITION COEF.: 777 EVAPORATION RATE: Negligible SATURATION IN AIR (BY VOL.): Not Available PH: In water it is neutral or slightly acidic. On standing in water it will become more acidic. SOLUBILITY IN WATER: 145 ppm g 25 *C SAL 0000070A4 MSDS No. 0086-03 S 6 56 Page 2 of 5 FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT: FLAMMABLE LIMITS: AUTOIGNITION TEMP.: DECOMPOSITION TEMP: >325 * F >162.7*C (METHOD: TAG Open Not Aoplicable Not Available Slow decomposition Cup) above 48.8*C (120 F) FIRE EXTINGUISHING MEDIA: Use water, foam, carbon dioxide, or dry chemical to extinguish fires. FIRE CONTROL TACTICS: Wear self-contained, positive pressure breathing apparatus and full fire fighting protective clothing. Keep unnecessary people away. Use as little water as possible. Dike area of fire to prevent pesticide run-off. Use spray or fog - solid stream may cause spreading. Do not decontaminate personnel or equipment, or handle broken packages or containers without protective equipment as specified in the Exposure Control Section. Decontaminate emergency personnel with soap and water before leaving the fire area. Avoid breathing dusts, vapors and fumes from burning materials. Control run-off water - if water enters a drainage system, advise the authorities downstream. NFPA HAZARD RATING Hazard rating not assigned by NFPA. REACTIVITY DATA Stable @ 25`C CONDITIONS TO AVOID: Unstable >48.8*C Storage at 50-115`C leads to nonhazardous decomposition. Heating at >150C causes rapid decomposition. Reactivity with strong base may generate excessive heat. Unstable 8 pH 12. POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: HAZARDOUS DECOMPOSITION PRODUCTS: Strong alkalies and strong oxidizers. Thermal decomposition may produce hydrogen sulfide, methyl mercaptan dimethyl sulfide, and oxides of carbon, sulfur, and phosphorus. SAL 000007045 MSDS No. 0086-03 GS6 56 Page 3 of 5 HEALTH HAZARD INFORMATION TOXICITY DATA AND EFFECTS OF OVEREXPOSURE: The oral LD50 for male rats is 2,800 mg/kg and for ferqale rats it is 1,000 mg/kg. The dermal LD50 for rabbits is 4,100 mg/kg. This product is considered to be slightly toxic by ingestion in single doses and to be no more than slightly toxic by single skin applications. This product is not irritating to the rabbit eye but it is slightly irritating to the rabbit skin. Inhalation exposure is not likely to produce any significant effects due to the low vapor pressure of the product. Overexposure to an aerosol may produce cholinesterase-deoression. EMERGENCY & FIRST AID PROCEDURES: If Swallowed: Induce vomiting by giving 2 glasses of water and (a) stimulating back of throat with finger or (b) giving syrup of ipecac 30 ml. Never give anything by mouth or induce vomiting in an unconscious person. Obtain medical care without delay. Give oxygen if person has difficulty breathing. Give artificial respiration if person is not breathing. If on Skin: Remove contaminated clothing without delay. Wear impervious gloves. Cleanse skin thoroughly with soap and water. Do not omit cleansing hair or under fingernails if contaminated. Obtain medical care without delay. Give oxygen if person has difficulty breathing. Give artificial respiration if person is not breathing. If in Eyes: Immediately irrigate with plenty of water for 15 minutes. If Inhaled: Remove from exposure. Administer oxygen if there is difficulty in breathing. Obtain medical care without delay. 0000070*6 SAL MSDS No. 0086-03 GS656 Page 4 of 5 EXPOSURE " CONTROL METHODS NOTES TO PHYSICIAN: MA LATH I ON ULV is a parasympathomimetic agent. Erythrocyte cholinesterase activity should be measured. Signs and symptoms include, progressively: headache, lightheadedness, mioses with loss of-accommodation, nausea, vomiting, hyperhidrosis, muscle fasciulations, sphincter failure, coma, and death. If signs or symptoms are present, give atropine, 4 mg, I.V. Repeat every 10 minutes until atropinized. Observe for at least 48 hours. Opiates and phenothiazine tranquilizers are contraindicated. Exposure to eyes and skin-should be prevented by wearing chemical splash goggles, rubber gloves, apron, and boots. A long sleeve shirt and full length pants (or coveralls) should also be worn. Wash hands with soap and water before eating, smoking, or using the toilet. Shower after completion of work shift. Launder clothing prior to reuse. SPILL OR LEAK PROCEDURES Wear rubber boots, gloves, and splash goggles. Absorb spilled material with clay or soda ash. Sweep up and place in closed container. Treat contaminated area with full-strength liquid chlorine bleach; let stand for 15 minutes and repeat procedure. Flush area with water. WASTE DISPOSAL: Dispose in accord with local, state, and federal regulations. ADDITIONAL REGULATORY INFORMATION SARA Title III Data Section 311 & 312 Hazard Categories Immediate Health Hazard - Y Delayed Health Hazard - N Fire Hazard - N Reactive Hazard - N Sudden Pressure Release Hazard - N Section 302 Extremely Hazardous Substances - None Section 313 Toxic Chemicals - None CERCLA Reportable Quantity Kalathion 100 lbs. (45.4kg) SAL 000007047 SPECIAL PRECAUTIONS APPENDIX HANDLING AND STORAGE: GS656 Page 5 of 5 Because of this material's flash point, areas containing this material should conform to the codes (such as, NFPA 30 and NFPA 70) governing Class III Combustible Liquids. , Do not contaminate water, food, or feed by storage or disposal. Store in a secure, dry, well-ventilated separate room, building or covered area. Not for use or storage in the home. Keep away from sources of ignition and protect from exposure to fire and heat. Segregate from oxidizers and incompatible materials listed in the Reactivity Data Section. CYTHION Insecticide, "The Premium Grade Malathion" is a registered trademark American Cyanamid Company SOURCE AND SHEET NO.: DATE INFORMATION DATE: 0036-03 3/22/89 The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. SAL 000007048 ML iT'l ' - fl/falHndkrodt "Material Safety Data ^ Emergency Phone Number: 314-982-5000 A. . A ,y MaiUnckrodt provides the informatu .jntained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving thia information must exercise their independent judgment in determining its spproprlateness for a particular purpose. jjgtf mr iniT'r.... MaUackredt auks* as rspseseeSstloas, implied, efmerchantability, Otaem for a i the laforaaatioa set forth herein or to the preded U which the 1 refera. Accordingly, Malliackrodt will not be respondbis for i usiilTiag frnm m nfrr rrtlsnrr npra sllisckrodt. isc . Science Products Division, P O Bos M, Paris, KY 43061. ETHYL ALCOHOL DENATURED PRODUCT IDENTIFICATION: Synonym*: Denatured ethyl aioohol; alcohol; potato alcohol Formula CAS Noj 64-17-5 Molecular Weight: 464)7 Qkemkal Formula: cjH$0 (major oompoocat) Hazaidout Ingredients: CAS# 67-56-1 Methyl alcohol 141-76-6 Ethyl acetate 106-10-1 Methyl isobutyl fcctooe B006-61-9 Oasoiine PRECAUTIONARY MEASURES DANGDO MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. FLAMMABLE! AFFVCT6 CENTRAL NERVOUS SYSTEM. MAY CAUSE BLINDNESS. CAUSES ouuunoN. Keep away from heat, sparks and flame. Keep container dosed. Use with adequate ventilation. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Avoid breathing vapor. EMERGENCY/FIRST AID If swallowed, induce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. In all cases* call a physician. SEE SECTION 5. DOT Hazard Gass: Flammable Liquid SECTION 1 Physical Data Appearance: Gear, colorless liquid. Odor Mild odor. Solubility: Infinite in water. Boiling Point: 78*C (172.4V) Melting Point <-I14*C (-173V) Specific Gravity (water I): 0.B0 Vapor Dcnsity(Air"l): 145 Vapor Pressure (mm Hg* 47 @ 2S"C (TTY) Evaporation Rate: (BuAc l):ca. 33 - SECTION 2 Fire and Explosion Information Fire: Flammable. Fire data is for ethyl alcohol: Flash point 13*C (35*F) (dosed cup). Auto ignition temperature: 422*0, (793*F) Flammable limits in air, % by volume: Id - 3.3, uel - 194). Dangerous fire hazard when exposed to heat or flame. Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool. Water may be used to flush spills away from exposures and to dilute spills to non-flammable mixturea. Special Information: in the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Vapors can flow along surfaces to distant ignition source and (lash back. SECTION 3 RcactMtv Data Stability: Stable under ordinary conditions of uae and storage. Hazardous Decomposition Products: May produce carbon moooxide and carbon dioxide when heatad to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Strong oatMaera. beat aad sourres of ignition. SECTION 4 Leak/Snill Disposal Information Ventilate area of leak or spill Remora all sources of ignition. Clcaa-up personnel require protective cfcKtting and respiratory protection from vapors. Gootain end recorar liquid when possible. Collect aa hazardous waste and atomhue fas a suitable RCRA approved combustion chamber, or absorb with vennkulite, dry sand, earth or similar material for disposal as hazardous waste in a RCRA appiwed facility. Do not flush to sewer! Ensure compliance with local, state and federal regulations. Effective Date: 07-13-87 Supersedes 01-15-86 SAL 000007049 ETHYL ALCOHOL DENATURED Effective Dat{ '*13-87 Supersedes 01-15-86 ETHYL ALCOHOL DENATURED SECTION S___ Health Hurd Information RE/HEALTH EFFECTS Inhalation aiycuw Irritation to tha wppar ragrifattwy met PnkM|td uponm to high concentration may cause inmnlnrm. las of appetite, and inability to coocentnteAlethyl alcohol component affecta vision by acting upon the optic nerve. Exposure may retail la vision impairment or blindness. Cm cause gastritis, vomiting, central nenroua system depression, headache, and dirtiness. Other symptoms mey parallel those from iahalatioa exposure. Skin Contact; Miyame irritation. Prolonged contact may produce diacoknatioo. Skin absorption of methyl alcohol oompooent may ocov with symptoms paralleling those of Inhalation exposure Eye Contact; May cause severe Irritation. Splashes may cause pain, blurred vision, and eye damage. Cfcreak Exposure: Piokmged skia exposure may cauae drying and cracking of skin. May affect the nervous system. May cauae vision impairment, brer injury and pancreatitis. Aggravation of Pre-atitieg Conditions: Persons with preexisting skin disorders or eye problems, or impaired kidney or respiratory function may be more susceptible to the effects of the substance. "to to"kb tt B. FIRST AID Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, Induce vomiting Immediately by giving two glasses of water, or milk if available and sticking finger down throat. Call a physician immediately. Never give anything by mouth to an unconscious person. Skin Exposure: Remove any contaminated clothing. Wish skin with soap or mild detergent and water for at least IS minutes. Get medical attention if irritation develops or persists. * Eye Exposure: Wash eyes with plenty of water for at least IS minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. C. TOXICITY DATA (RTECS, 1982) Ethyl alcohol: Oral ret LD50:7060 mg/kg Inhalation ret LCSO: 20,000 ppm/lQH Mutation references cited. Reproductive effects cited. Irritation skin rabbit: 400mg open mild eye rabbit 100mg/24H severe Methyl alcohol: Orel rat LDSO: 5628 mg/kg Skin rabbit LD50: 20 gm/kg. Mutation references cited. Reproductive effects cited. Ethyl acetate: Oral rat LDSO: 11300 mg/kg Inhalation rat LCSO: 1600 ppm/8H SECTION 6 Occupational Control Measures Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 1,000 ppm (TWA) for Ethyl Alcohol 200 ppm (TWA) for Methyl Alcohol 400 ppm (TWA) for Ethyl acetate -ACGIH Threshold Limit Value (TLV): 1,000 ppm (TWA) For Ethyl Alcohol 200 ppm (TWA) 250 ppm (STEL) skin for Methyl Alcohol 400 ppm (TWA) for Ethyl acetate Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation Is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of It into the general work area. Please refer to the ACGIH document, 'Industrial Ventilation, A Manual of Recommended Practices1, most recent edition, for details. Personal Respirators: (NIOSH Approved) If the TLV Is exceeded a full facepiece chemical cartridge respirator may be wont up to the maximum use concentration specified by the respirator supplier. Alternatively, a supplied air full facepiece respirator or airiined hood may be worn. Skin Protection: Gloves and lab coat, apron or coveralls. Eye Protection: Use chemical safety goggles. Contact lenses should not be worn when working with this material Maintain eye wash fountain and quick-drench facilities in work area. SECTION 7 Storage nd SpcdaUnfonnatlop Protect against physical damage. Store in n cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage Is preferred. Separate from oxidizing materials. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment. ETHDA in o N O o o o < t/J Mallinckrodt Material Safety Data Emergency Phone Number: 314-982-5000 Mailinckrodt provide* the Information cuutained herein In good faith but makes no repreoentatlon aa to ita comprehenaivaneaa or accuracy. Individuals receiving this information must exercise their Independent judgment in determining its appropriateneu for a particular purposs. MaMaduedl Mahai earapraaretade--, ar warrmrtlm. afchar txprem m Implied, afwarthwrtabtUty, Bbatsa far epartkalar purpoaa wHb rmpart >e the iafermatioa set forth bereia or to the product to which the lafermattoe refers. Accordingly, Mallinckrodt will not be responaibie for damages nsultteg flrom nse ofor reliance upon this Information. MaUinckradl. Inc., Science Product* Division, P.O. Box M. Paris. KY 43061 This Ad^gndunxMMSLNotJBs Detached from the MSDS Identifies SARA 313 substancefsl Any copying or redistribution of the MSDS must include a copy of this addendum (Chem.Key: ETHDA) Addendum to Material Safety Data Sheet REGULATORY STATUS Hazard Categories for SARA Section 311/312 Reporting Acute Chronic Fire Pressure Reactive XXX Product or Components of Produa: ETHYL ALCOHOL DENATURED codes: 2849 2902 2866 2919 H867 The following percentages correspond one to one with the produa codes given here. * Ethyl alcohol (64-17-5) 85%, 90%, 89%, 94%, 94% Methyl alcohol (67-56-1) 3.6%, 3.6%, 3.7.%, 3.7%, 3.7% Ethyl acetate (141-78-6) 5%, 5%, < 1%, < 1%, < 1% Methyl isobutyi ketone (108-10-1) 0.9%, 0.9%, 0.9%. 0.9%, 0.9% Gasoline (8006-61-9) < 1%, < 1%, < 1%, < 1%, < 1% SARA EHS Sea. 302 RQ (lbs.) TPQ (lbs.) SARA Section 313 Chemicals Name List Chemical Category CERCLA Sec. 103 RQ (lbs.) RCRA Sec. 26133 No No No No No No Yes No No No No No No No Yes No No No No No No 5000 5000 5000 No No ' U154 U112 U161 No .9 U 0 SARA Section 302 EHS RQ: Reportable Quantity of Extremely Hazardous Substance, listed at 40 CFR 355. SARA Section 302 EHS TPQ: Threshold Planning Quantity of Extremely Hazardous Substance. An asterisk (*) following a Threshold Planning Quantity signifies that if the material is a solid and has particle size equal to or larger than 100 micrometers, the Threshold Planning Quantity 10,000 LBS. SARA Section 313 Chemicals: Taodc Substances subject to annual release reporting requirements listed at 40 CFR 372.65. CERCLA Sec. 103: Comprehensive Enviromental Response, Compensation and Liability Act (Superfund). Releases to air, land or water of these hazardous substances which exceed the Reportable Quantity (RQ) must be reported to the National Response Center, (800-424-8802); Listed at 40 CFR 302.4 RC.RA: Resource Conservation and Reclamation Aa. Commercial chemical product wastes designated as acute hazards and toxic under 40 CFR 261.33 Effective Date: 07-13-87 Supersedes 01-15-86 SAL 000007051 ETHYL ALCOHOL DENATURED HAY 0 7 B1 20M3 USDS BATE 3/21/11 CHANGE WO.t isir MATERIAL Par Aaalstinad, Contact: Reawletery Affaire Dapt. PO Bax 117 Mil, IA SIIU <) 227*4224 SAFETY DATA HACH COMPANY PO BOM 117AfCSp 1A 5*411 SHEET rot I 514-tPA ZS9MB MACH MOCBB* ttlt Eaaritoty Telephene tacky Mountain Pelaen Ct l!*J) 423*5711 Z. PRODUCT IDENTIFICATION VIZ. FIRST AID CATALOO NO. I 21993 CAB HO.l HA FORMULA! Hat applicable II. INGREDIENTS PRODUCT HUCt Moehramlx CHEMICAL HAHEi Hat applicable CHEMICAL FAMILY: Hat appllctbla -Proprietary component! FCTt 111 CAS HO.i Praprlatary SARA: HOT LISTED TLY: Nat aatafallsha* PEL! Net aatabllahed HAZARDi Hat determined III. PHYSICAL DATA STATEi lain APPEARANCE! White eryatalllne powder ODOR: Acrid SOLUBILITY IN: MATER: 42.12 f/111 RL 9 2IC ACID: Soluble In H2S04 OTIC*: Nat drtermlnad BOILING POINT: HA MELTIHO PT.i 175C deeomp. SPEC ORAVITY: 1.1 pH: ilk tain l-S VAPOR PRESSURE: Hat applicable VAPOR DENSITY (ilr-l)l MA EVAPORATION RATE: HA *TAl CORROSIVITY - ALUMINUM: HD STEEL: Ml STABILITY: Stabla STORAGE PRECAUTIONS: Start In coal, dry placa away fra* axldlzabla aatarlel. IV. FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT.i Net appllcabla METHOD: HA FLAMMABILITY LIMITS - LOWER: HA UPPER: HA SUSCEPTIBILITY TO SPONTANEOUS BATING: Nana SHOCK SENSITIVITY: Nona AUTOIGHITION PT.t HA EXTINGUISHING MEDIA: watar FIRe'EXPLOSiON HAZARDS: Stranf oxidizer: nay raact viclantly with raducara and cembuatlble material! HAZARDOUS DCCOMP. PRODUCTS: Net determined OXIDIZER: Strang NFPA Cadas: Haalth: 9 Flexibility: I Reactivity: I COPBITIOHS TO AVOID) Heat, acrlatwra; aantaet with nitric acid, illvar aalts, axldlzabla ar aombuatlbla aatarlel, raducara, alualnua, aadlum peroxide V. HEALTH HAZARD DATA EVE AMD SKIN CONTACTi Immediately flush ayaa with water far IB mlnutee. Cal phyaiclan. Flush akin with plenty af water. IHDESTION: Give larit amnt ltlaa af watar ar milk. Call phyalolan Immediately. UR4ALAT10N: Remove ta fraah air. Give artificial rasplratlcn If naaaaaary. Call physician. VIII. SPILL AND DISPOSAL PROCEDURES IH CASE OF SPILL OR RELEASE: Caver with reducer (a blaulflte, ar a farrau aalt but net carbon, tulfur ar atrens rtdwcini aiental. Mix wall and spray with watar. A aulflta ar a farraua salt will reaulr* addition of tape 3H-H2S04 ta praaieta rapid raductlan. Sceap alurry inta a aantalnar of watar and tada ash. Math dawn the drain with exceae watar. Mash slta thcroufhly with a tatp solution containing cam* radwaar. DISPOSE OF IH ACCORDANCE N1TH ALL FEDERAL, STATE, AND.LOCAL REBULAT10MS. IX. TRANSPORTATION DATA O.O.T. proper SHIPPING NAME: Ammonium Parsulfata HAZARD CLASS: Oxidizer ID: UNI444 I.C.A.O. PROPER SHIPPING MAfC: Aaaaniua Paraulphata HAZARD CLASS: 9.1 ID: UN1444 GROUP: lit I.H.O. PROPER SHIPPING NATCi ANifilin Persulphate HAZARD CLASS: S.l ID: UM1444 GROUP: III X. REFERENCES 1) TLV's Threshold Halt Valuta and Dleleiical Expeeure Indlcaa far 11991161. Aaarlcan Canfaranca of Govarnaantal Industrial HyglPitlsta, 11GB. 21 21 CFR 1101 - 111! (Coda af Federal Raaulatlana - Labor) 9) Vendor Infereatlen. 4) Technical Judiaent THIS PRODUCT HAY BE: lrrltatln* tc ayaa, akin, raaplratery tract, and aiy ceuta ellarfle akin raaetlan. ACUTE TOXICITY: Orel rat LD5I 921 7kg Moderately toxic ROUTES OF EXPOSURE: Inflation, Inhalation, contact TARGET ORGANS: Net determined ChftONIC TOXICITY: Met deteralned ROUTES OF EXPOSlRE: Net determined TARGET ORGANS: Hat determined CANCER ^FORMATION: Hat appllcabla ROUTES OF EXPOSURE: Hat applicable TARGET ORGANS: Net applicable OVEREXPOSURE: Irritation, nauaaei chronic overexposure may eauaa akin rath ICD1CAL CONDITIONS AGGRAVATED BY EXPOSURE: Nona reported VI. PRECAUTIONARY MEASURES Math thoroughly after handling. Aveld contact with ayaa, akin and elethlng. Da net breathe chemical*. Start away from axldlzabla matarlal. PROTECTIVE EGUlPtQfT: adequate ventilation, safety aliases, disposable lavas f\l in fO a o o o < 07 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARD I NO THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE TKREOF. 40 HACH CO. 11)1 fconoco) Vendor information Conoco inc. Page Purchase Requisition --V Priority RLOC Depaijprent REB Refining Ship To Shaded Areas RQ Loc Requisition No. for Purchasing Dept. Use Only 316 2598G5 CD Ship Date Req'd at Dest. Order Previous P.O. Via Type NORMAL Tagging Instructions HACH F.Q.B. Point Freight Terms P. 0. BOX 389 LOVELAND. CO 80539 \ttn: Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Carrier Project ID Clauses Payment Terms -_ . AFE Reporting HAILED tequisitioner 800-227-4224 Date Distribution Charge ---- >- i i_______ RACHKLLE 318-491-5406 X4/23/90 Tax Status Special instructions Charge Exempt r* 7411-3-0-149-03-13 ickat tm Oats 42/3/90 Control W.O. $149 EQuip. NO. Tima Tims init. Stat. Ordered Req'd MR 9 fiALL SOS Unit Cods Description #20883-00 No CHromlx _ ____#22791-00 Safety Cap APPsrfv^D: R COWDES Date Required ML 00070S, 7411-3-0--14SK-03-13 iwm Quantity No. Ordered 13 Units of Issue Pries berxet 2 5 each Qty. issuoo HAILED ORDER TO HACH ACCOUNT #82797 1 Approvals Operating Oepi. 9-t%6 X8. vi- T~ Approve! Purchasing Dept. Hf7* MRM DATE: 4/1B/B* OMNOC HO.I 741 MATERIAL Far AllIttfMli C*MHtl litulitiry Affair* Dft< PO las l? Ami, ia Satie (M> 21M2M SAFETY DATA SHEET HACH OAOLSB1 kOOUOn HACM COMPANY PO MX 4*7 CMrw ..................... ' flacky Mountain Palace Ctr MCI. 1* MB1I_____________________ <1411 42B-17U_______________ X. PRODUCT IDENTIFICATION VII. FIRST AID CATA100 MO.l IM7I CA MO. f MA FORMULA: Mat applicable PROOUCT MAX: Of# fr ChleMne CXNICAL MAX i Met applicable ctfWCii family: Mat applicable II. INGREDIENTS Organic Salt ITretfe Secret) PCT: < CAS HO.I Conf Ident lalSAIIA: MOT LISTED TLVi Mot sstabllshod TCLi Wet established HAZARD: Texlolty unknown SadliM Phosphate, Dibasic, Anhydrous PCT, 4| CAS MO.1 755B-7B-4 TLVi Mat sstsbllshsd HAZARD: Moderately toilet aey eauae SARA: MOT LISTED PEL* Mat established Irritation DFD Salt fTrsds Saarat) Krt <% CAS MO.i Cenfldntldl*A*Ai HOT LISTED TLVt Mat established U Mot ostobllshod MLZARDi Kodorotoly texlei nay eevee skin eeneltJxetlen Otter eanpenent yen <1 CAS MO. MA TLV: Met sppllesbla HAZARD: Mot applledble SARA: HOT LISTED PEL: Met apellesbl* Any eeapenent of thla mixture not teoolfleolly lleted <e. "ether eeweanente") 1 not considered to sreaont o oorolnoson heiard. III. PHYSICAL DATA STATE: eelld APPEARANCE: White te oolo sink eewdor ODOR: Mane SOLUBILITY IN: KATES: Soluble ACID: Soluble OTtCR: Nat determined OIL I MO POINT: MA XLT1N9 PT. MO SPEC SRAVITYl ND pH: Mot dotor: VAPOR PRESSURE: Mot applicable VAPOR OEMSITV (elrt)l MA EVAPORATION RATE: MA HETAL CORROSIVITY - ALUMINUM: 10 STEEL: MD STABILITY: Stable STORAOC PRECAUTIONS! Stare In a eaal, dry. dark alaea. EVE AMD SRIN CONTACT: laaedletely flush ayes with water far IB alnutes. Call physlelan. Renews eentenlnated olothln*. Math akin with caap and plenty ef water. IMOESTION: Siva large auantltia* ef water ar am. Call ehyelelen laaaedlottly. IiBMlATlCNi Raaova te freth air. VIII. SPILL AND DISPOSAL PROCEDURES 1M CASE OF SPILL OR RELEASE: Sweep up powder. Avoid breathing aeterltl. Dissolve In water. Flwoh dawn tna drein with ixni water. DISPOSE OF IN ACCORDANCE KITH ALL FEDERAL > STATE. AND LOCAL REGULAT1OMS. IX. TRANSPORTATION DATA D.O.T. PROPER SHIFPIMO MAX: Mot Currently Rapuloted HAZARO CLASS: Mot oppllooblo ID: MA l.C.A.O. PROPER SHIPPINO MAX: Mot Currently Populated HAZARD CLASS: MA ID: MA OROVPl HA l.M.D. PROPER SHIPPING MAX: Met Currently Reauleted HAZARD CLASS: f ID: MA OROUPt MA X. REFERENCES 17 TlV'e Thraehald Lllt Velves and Bleletleel Exposure Indleas far IBMIBIS. AMarlesn Canfaranea ad ovariwaantsl Industrial Hypleniats. ISM. tl Air CantMlnant*. Fedarpl Replttar> Val. 14, Me. 12. Thvrpday, January 11, 1BSB. pp. 17 In-heate Inferaetlan 41 Teehnlaal )fiaest SPECIAL HOTCi Thit praduet Pty only ba vied as s analytical reapant far tha dataralnatlaa af ahlarlna In water due te reovlraaant* ef tha TestJe abetaneaa Central Aat (TSCAK XV. FIRE, EXPLOSION HAZARO AND REACTIVITY DATA FLASH FT.l Not applicable XTHOO: MA FLAHHAB1LITY LIMITS - LOWRs MA UPPER: MA SUSCEPTIBILITY TO SPONTANEOUS XATIHD: None SHOCK SENSITIVITY: Nano AUTOIONITION PT.i HO EXTIN9UISHIM0 MEDIA) water, dry ehealeel, alcohol fota or carbon dlezlde FIRE/EXPLOSION HAZARDS: May aalt toxlo fumes In fire HAZARDOUS DECOHP. PRODUCTS: Kay ealt tecle fuwea of phespbarue oxides In fire OXIDIZER: Me NFPA Codes: Heelthi I Flnnwebllltv: 1 Reactivity: $ CONDITIONS TO AVOID: Extreme tanperetvris, exeats nolstur*. exposure ta llbht V. HEALTH HAZARO DATA THIS PRODUCT HAY BE: Irritating te eye* and rasplrstary tract, and nay esuss llarple skin reaction. ACUTE TOXICITYl SllRhtly tesla ROUTES Of EXPOSURE: inpeltlon, Inhaletlen TAROCT ORGANS: Met deternlned CHJON1C TOXICITYl Met determined ROUTES OF EXPOSURE: Infection, Inhaletlen TARGET ORGANS: Wet deternlned CANCER INFORMATION: Net determined ROUTES OF EXPOSURE I Met deternlned TARGET ORGANS: Met dateraSned OVEREXPOSURE: Centeet aey eevse lrritstlen, ikln eensitlietlon XDtCAL CONDITIONS AOGRAVATED BY EXPOSUREi Allarsy er saneitlvlty te salts ef M.M-Olethyl-p-Phenyienedlowln# in o ro o o o o < ISi VI. PRECAUTIONARY MEASURES Avoid eentaet with eyas. Avoid erelansad ar repestad contact with tfcjn. Do net breethe dust. Mesh thereufhly after hendlln*. protectrvE EOUirXNT: edeevete ventllatlen, safety slsesas. slevee dlspeseble TX INFORMATION CONTAIXD HEREIN IS BASED CN DATA CONSIDERED TO BE ACCURATE. HOXVER, M> WARRANTY IS EXPRESSED OR IMPLIED REGARDING TX ACCURACY OF TXSe DATA OR TX RESULTS TO BE OBTAINED FROM TX USE THEREOF. Hech Conpeny, WORLD XADQUARTERS, PO Box MB, leveling, CO B055B Hdch Curepa, BP 22, B580B Heagr 1, BCLGIW eure,,, BP j?,_ H#i<ur f BrLC!Tl)M (C) HACH CO. 1BBP PAOE 1 OF PAGE 1 rr | f Ccoooco) /endor Information Conoco Inc. Page Purchase Requisition of Priority RLOC Department REB Refining Ship To Shaded Areas RO Loc Requisition No. A CD for Purchasing Dept. Use Only 316 259184 Ship Date Req'd at Dest Order Previous P.O. Via Type S/21/90_____ Tagging Instructions EACH INST, F.O.B. Point Freight Terms BOX 907 AMES, IOWA Sftfti* 50810 ttn: Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Carrier Project ID Clauses Payment Terms -- AFE Reporting MATT.FD equisitioner Date Distribution Charge ' *--- J SUE 318-491-5558 X 4/9/90 Tax Status Special Instructions Charge Exempt 6% ket Oa S9184 4/9/90 Control WO . >077 Equip. NO. Time Time IniL - Star Ordered Req'd Unit Code Mi 35 MAIL NOR Date Required -a Stock No. Description CHLORINE TEST KIT( Free 3 total 4 0-10 male) Cat. Bo. 21290-00 Model GH-80 21003--*00 Hach Turbindlaeter Saaple Celia 7411-3-0-77X-03-30 Sal u 'O55 -/ 21/ 90 7411-3-0-77-03-3C Kern No. Quantity Ordered Units of Issue Price 1 1 each Oty. Issued 2 2 pkfis APPROVED: ELLEN RISIGNER ACCOUNT f ft77971_____________________________________ kati yp n^nEB TO ______________ , - Operiling Dept / (JL'Ls-yCLsv -s v i-t-ae L&r... &CT_____ Approval Purchasing Dept. MSDt MKl HAHOC MB. S74S MATERIAL rr AitlitlMt, C*tMtl Affair* Rapt. PO Na 117 tali, |A SdtlB mi> i-m_____________ SAFETY DATA SHEET HACH COMPANY CMPfanay TtlohMi firS.fi TO MX Raefcy Maintain Palaan Ctf wc>. u mhi______ ________ m m-im 5S X. PRODUCT IDENTIFICATION wr ATALQQ MO.I tt7B PRODUCT MAfCt DPR Fra* Ctilarlna Rtf*M J mo.i W OCKICM MAMEt Mat applleabl* FORMULA* Mat irrilcabl* CUBICAL FAMILY! Nat applicable IX. INGREDIENTS Orunla Salt (Trad* Secret) ACTi <M CAS MO.i ConfldantlalSARAt HOT LISTED TIVj Mot eetebllahad PEL: Net ettebllahed HAZARD* Taalalty unknown Sedluw Pheaahate, Dlbatla. Anhydreva rcTj < CAS MO. l 7550-7t' TlVi Mat aatebllahed HAZAkOi Madaretely toaUl aay eaua# SAPAI MOT L1STE0 PEL> H* eatebllahad Irritation MO Salt (Trad* taaratl fCTl <1 CAS MO. l Confidant laISARAi MOT LISTED TlVi Mat tatiblJihad TEL I Met oatabllihad MUMP) Pfedarataly taaioi aay aavia akin imlUiitiaa VII. FIRST AID AMD SKIM CONTACT (Mediately fluah *ya* with water far IS alnuta*. Call fhyalalan. Raaav* aantawjnatad aletMnf. a*h akin with *a* and plant vatar. IMQESTtONi Olva lara* auantltlas af water *r a|jk. Call phyalalan Ja**lately. IMhalaTIONi Raiaev* t* frath air. VIII. SPILL AND DISPOSAL PROCEDURES IN CASE OF SPILL OR RELEASE! Swaaa ua aawdar. Avoid MtitMni aatarial. Dltaalaa In witar. Fluah down tha drain with ixcei* water. DISPOSE OF IN ACCORDANCE HITH ALL FEDERAL, STATE. AMD LOCAL REOULATIOMS. IX. TRANSPORTATION DATA D.O.T. PROPER SHIPPIMO MA*Ci Nat Currently Raiulatad HAZARD CLASS! Mat applicable IDi MA I.C.A.O. PROPER SHIPPIMO NAME! Mat Currently Rtfuletid HAZARD CLASS! MA IDl MA OROUPt KA Other at*iMAt ACT I <1 CAS MO.I MA TLVI Mat availed*!* hazard i Mat aaallaaoia SACAt NOT LISTED PCIt Mat applicable I.M.O. PROPER SHIPPIMO WAX: Mat Currently Ratulatad HAZARD CLASS! MA IDl MA SROtIPi NA X. REFERENCES Any ********* af tM* (Utrri net apaalflaally Hated ll|> "ether eaawaftaata1') 1* net eonaJdarad t* eraeant earalneeen heaerd. III. PHYSICAL DATA STATE* aalld appearAMCC i WMt* t* pal* pjafc eewdar OOOti N#n# SOL US HI TV lMi MATE* i Salable ACID) Soluble OT>Oi Hat datarainad SOIL IMO POIHT* MA PCLTIMO PT. m SPEC MKAVJTVf ND PHI Mat datarali VAPtdt PRESSURE! Mat aeellaabt* VAPOR OEMS I TV r*Jrl>i MA EVAPORATION RATE! HA METAL CORROSIVITY - ALLWIMMi M> STEEL! MO STADlLITVl steal* ITOtMC MMOttMti Star* lit a e**l dry, dark tliii. tl TLV'a Throehald Halt Value* and f]*l*l#*l tapeaure Indtcae far mltd*. A*rJ*n Canfarana* af Savariwaantal Infuttrlal Hyslenlata, HW. 2) Air Cantaalnontt, Fadaral laatatar, val. So, Ma. if. Thurtdey, Jeaaary t, iasa. *a. un-ttis. S> tn-heuee Jnfaraatlen 4) Taahnlaal Judawant SPECIAL MOTEi Thla Rfaduat aay anly la a*d * an analytical raaaant far Ihi fataralnatlaa a* ehlerlae in water du* t* raaulraaant* af the Teal* Suletenaaa central Aat (TSCA). IV. FIRE t EXPLOSION HAZARO AND REACTIVITY DATA FLASH PT.i Hat applicable THOOi MA FLAW1AB1LITV LIMITS - LOWER: MA UPPER I MA SUSCEPTIBILITY TO SPONTAICOUS HEATINO! Nana SHOCK SCMSITIVITYl Mona AUTOIONITION PT.i HD EXTtMRUISHlMO WDIAi watar, dry ahawlael, alaahal feaa *r carbon dlaxlde FIRE/EXPLOSION HAZARDS! Miy fait taxle fvaas In fira HAZARDOUS DCCOHP. PRODUCTS: May *alt teale fwaas af bheaahoru* oxides In fir* OXIDIZER* M* MTPA Cadaai Haalthi 1 FItaxability: 1 Reaetldltyi S CONDITIONS TO AVOID: Extreae teaperaturaa, ataata aalitura, exposure t* Uffit V, HEALTH HAZARD DATA THIS PRODUCT MAY SEi lrrltatlni t* ayai and respiratory tract, and aay eaua* allaral* akin reaction. ACUTE TOXICITY! SUshtly taxle ROUTES OF EXPOSURE! (nfaatten, InhalatJea TAROET ORGANS! Hat datarainad CtStONIC TOXICITY! Net datarainad ROUTES OF EXPOSURE! Jnaastlen, Inhalation TAROCT ORGANS: Nat datarainad CANCER JITCKMATJON) Nat datarainad ROUTES OF EXPOSURE! Net datarainad TARSET OftOAMSl Net datarainad OVEREXPOSURE: Contact aay eauto Irritation, akin aanaltJratlen kCDICAL CONDITIONS AOORAVATEO BY EXPOSURE! Allerfy or sensitivity to aalt* af W.H-Olathyl-p-Phanylanadlaalne VI. PRECAUTIONARY MEASURES Avoid tentaat with y*a. AvtJf preJ*f*d *r rapattad contiet with ik|n. Da nat braath* duat. Nath thr*ufhly after hanailn*. PROTECTIVE EQUIPtCNTI tdteval* ntil*tl*n, tafaty lava* flaxai, djseoaabl* S4L 0007056 TTC INFORMATION CONTAINED HEREIN JS BASED CM DATA CONSIDERED TO BE ACCURATE. HOWEVER, Mo WARRANTY JS EXPRESSED OR IMPLIED AECARDIMO THE ACCURACY OF T>ESE DATA OR Tx RESULTS TO BE OBTAINED FROM n USE THEREOF. Hath Ceapany, WORLD tCADOUAKTERS, PO Baa Sdd, lavaland, CO BB5S* Hath Curcaa, BP 22d, BSaa Naaur 1, BCLOIUH Nh Ei"'an. BP ??a, M,-or 1 . ,BeFilnOtIllMM (Cl HACH CO. ltd* PAGE 1 OF PAGE I cr I I Apr o 2 vet S600 MATERIAL SAFETY DATA SHEET EASTMAN CHEMICAL PRODUCTS, INC. EASTMAN KODAK COMPANY Kingsport, Tennessee 37662 For Health Hazard Information, Call: (615) 229-6094 For Other Information, Call Your Eastman Representative Eastman Operator: (615) 229-2000 Date of Preparation: 05-19-89 SECTION I. IDENTIFICATION -- Name: "TECSOL" A Solvent, 95% -- Synonyms: PM 3957; Denatured ethyl alcohol -- Formula: Mixture SECTION II. COMPONENT AND PRECAUTIONARY DATA COMPONENTS: Approx Percent CAS Reg No Eastman Kodak No Ethanol* Isopropanol* Methanol* ** Methyl isobutyl ketone* ** Water 80 64-17-5 113301 9 67-63-0 900212 4 67-56-1 900467 1 108-10-1 900416 6 7732-18-5 035290 See Section VI-A for information on exposure limits. ^Hazardous chemical as defined by OSHA, 29 CFR 1910.1200. **Chemical subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. B. PRECAUTIONARY LABEL STATEMENTS: 1N WARNING! FLAMMABLE LIQUID AND VAPOR CAUSES EYE IRRITATION Keep away from heat, sparks, and flame. Avoid contact with eyes. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. SAL 000007057 FIRST AID: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if symptoms persist. , ' :;yhcL 021535 MSDS-10.214A-1 (05-89) Replaces 12-88 Edition  J5 A A 0 IN CASE OF FIRE: Use water spray, dry chemical, "alcohol" foam, or CO^. Water may be ineffective in fighting the fire. Use water spray to keep fire-exposed containers cool. IN CASE OF SPILL: Eliminate all Ignition sources. Use water spray to disperse vapors and to dilute to a nonflammable mixture. Use water spray to protect personnel attempting to stop the leak. Prevent runoff from entering drains, sewers, and streams. Since emptied containers retain product residue, follow label warnings even after package is emptied. Do not cut, drill, grind, or weld on or near this container. FOR MANUFACTURING USE ONLY SECTION III. PHYSICAL DATA (1) -- Appearance and Odor: Clear liquid; alcohol odor. -- Boiling Point: Approx 78C (172F). -- Specific Gravity (HO = 1): Approx 0.79 at 72F/60F. -- Vapor Pressure: 40 mm Hg at 19C (66F). -- Volatile Fraction by Weight: 1.0. -- Vapor Density (Air = 1): 1.59. -- Solubility in Water: Appreciable. SECTION IV. FIRE AND EXPLOSION HAZARD DATA (1) -- Flash Point (ethanol): 13C (56F), Method Used: Tag Closed Cup. -- Autoignition temperature: >404C (760F); Method Used: ASTM D 2155. -- Flammable Limits (ethanol): LEL 3.53% (at 25C [77F]) UEL 21.2% (at 64C [147F]). -- Extinguishing Agent: Water spray, dry chemical, "alcohol" foam, or CO^. -- Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Water may be ineffective in fighting fire. Use water spray to keep fire-exposed containers cool. -- Unusual Fire and Explosion Hazards: Flammable liquid and vapor. (See Section VIII.) Vapors are heavier than air and may travel along the ground or may be moved by ventilation to an ignition source and may flash back. SECTION V. REACTIVITY DATA -- Stability: Stable. -- Incompatibility: Oxidizing materials can cause a vigorous reaction. -- Hazardous Decomposition Products: As with any other organic material, combustion will produce carbon dioxide and probably carbon monoxide. -- Hazardous Polymerization: Will not occur. SAL 000007058 MSDS-10,214A-2 (05-69) Replaces 12-88 Edition 5 S oA n. RESPIRATORY PROTECTION An appropriate NIOSH-approved respirator for organic vapor must be worn if exposure, is likely to exceed recommended exposure limits (see Section VI-A). If respirators are used, a program should be established to assure compliance with OSHA Standard 29 CFR 1910.134. C. SKIN AND EYE PROTECTION Wear safety glasses with side shields (or goggles). For operations where prolonged or repeated skin contact may occur, impervious gloves are recommended. An eye bath and washing facilities should be available. SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS Material is classified as a Flammable Liquid. Keep away from heat, sparks, and flame. Keep container closed. Use with adequate ventilation. Vapors are heavier than air and may travel along the ground or may be moved by ventilation to an ignition source and flash back. Comply with all federal, state, and local codes pertaining to the storage, handling, dispensing, and disposal of flammable liquids. Since emptied containers retain product residue, follow label warnings even after container is emptied. Do not. cut, drill, grind, or weld on or near this container. SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES Steps to be Taken in Case Material is Released or Spilled: Eliminate all ignition sources. Small spills may be collected with absorbent materials. water spray to disperse vapors and to dilute to a nonflammable mixture. Prevent runoff from entering drains, sewers, or streams. Use Waste Disposal Method: Mix with compatible chemical which is less flammable and incinerate. Observe all federal, state, and local laws concerning health and environment. SECTION X. ENVIRONMENTAL EFFECTS DATA Data for the major components of this material (3-9) have been used to provide the following estimate of environmental impact: this material is expected to have a high biological oxygen demand, a significant potential to cause oxygen depletion in aquatic systems, a low potential to affect aquatic organisms and secondary waste treatment microorganisms, ready biodegradability, and a low potential to bioconcentrate. If diluted with a large amount of water, a moderate quantity of this solvent released directly or indirectly into the environment is not expected to have a significant impact. SECTION XI. TRANSPORTATION DOT Hazard Classification: Flammable liquid. Harardous components: See Section II. Flashpoint: See Section IV. Proper DOT Shipping Name: Denatured alcohol. NA Number: 1986. SAL 900007059 MSDS-10.214A-4 (05-89) Replaces 12-88 F.dition I <rS6 00 SECTION VJ. TOXJCITY AND HEALTH A. EXPOSURE LIMITS Exposure Limits in ppm for Hazardous Components Component Ethanol Isopropanol Methyl alcohol Methyl isobutyl ketone AOGIH, 1988-89 Skin TLV TWA TLV STEL Notation 1000 - No 400 500 No 200 250 Yes 50 75 No OSHA PEL TWA 1000 400 250 50 STEL - 500 - 75 Skin Design No No Yes No -- NIOSH industrial hygiene analytical methods are available for the preceding components. (2,3) B. EXPOSURE EFFECTS Inhalation: High vapor concentrations may cause upper respiratory tract irritation and narcosis (sleepiness, dizziness, etc.). Eyes: Liquid and vapor cause irritation. Skin: Low hazard for usual industrial handling. C. FIRST AID Inhalation: Remove to fresh air. Treat symptomatically. If breathing is difficult, give oxygen. Get medical attention if symptoms persist. Eyes: Immediately flush with plenty of water for at least 15 minutes and get medical attention if symptoms are present after washing. D. TOXICITY DATA Toxicity data for the components of this material are available in EASTMAN CHEMICAL PRODUCTS, INC. MSDSs as follows: Ethanol Isopropanol Methanol Methyl Isobutyl Ketone ECPI MSDS-10,681A ECPI MSDS-10,145A ECPI MSDS-10,486A ECPI MSDS-10,599A SECTION VII. VENTILATION AND PERSONAL PROTECTION A. VENTILATION Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Local exhaust ventilation or an enclosed handling system may be needed to control air borne levels below recommended exposure limits (see Section VI-A). SAL 007060 MSDS-]0,214A-3 (05-89) Replaces 12-88 Edition <f H n ft SECTION XT I. REFERENCES 1. File data. Material Safety Program, Eastman Chemicals Division, Eastman Kodak Company, Kingsport, Tennessee. 2. NJOSH MANUAL OF ANALYTICAL METHODS, 3rd Edition. Issued by the National Institute for Occupational Safety and Health. U.S. Government Printing Office, Washington, 1984, Methods 1300, 1400, 2000. 3. Unpublished data, Health and Environment Laboratories, Eastman Kodak Company, Rochester, New York. 4. K. Verschueren. HANDBOOK OF ENVIRONMENTAL DATA ON ORGANIC CHEMICALS, 2nd Edition. Van Nostrand Reinhold Company, New York, 1983. 5. WATER RES 13, 623-626 (1979). 6. Z WASSF.R ABWASSER FORSCH 15, 1-6 (1982). 7. Z WASSER ABWASSER FORSCH 10, 161-166 (1977). 8. Z WASSER ABWASSER FORSCH 11, 161-164 (1978). 9. A. J. Leo and C. Hansch, Editors. CHEMICAL PARAMETER DATA BASE. Medicinal Chemistry Project, Pomona College, Seaver Chemistry Laboratory, Claremont, California, June 21, 1985. SECTION XIII. HAZARD RATINGS Health Flammability Reactivity HMIS* Rating: 1 3 0 NFPA** Rating: 1 3 0 NOTICE: These ratings involve data and interpretations that may vary from company to company and are intended only for rapid, general identification of the magnitude of the specific hazard. TO DEAL ADEQUATELY WITH THE SAFE HAND LING OF THIS MATERIAL, ALL THE INFORMATION CONTAINED IN THIS MSDS MUST BE CONSIDERED. The customer is responsible for determining the proper personal protective equipment needed for its particular use of this material. ^Hazardous Materials Identification System's (HMIS] Revised RAW MATERIALS RATING MANUAL, National Paint & Coatings Association, Fall 1984. **NFPA 704 Standard System for the Identification of the Fire Hazards of Materials, National Fire Protection Association, 1985. The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers. C/10214A/091374/R-1, S-2, F-3, C-0 SAL 000007061 MSDS-10,2i4A-5 (05-89) Replaces 12-88 Edition ^i<:A?.'WftfVt*6AFETY DATA SHEET *p^3 ARCAPIANl MATERIAL SAFETY DATA SHEET C.<?S77 EMERGENCY TELEPHONE: (SO*) 642-4573 A. GENERAL INFORMATION Trad# Na** (coMon naat or synony*) ANHYDROUS AMMONIA Chtaieal na# ANHYDROUS AMMONIA, AMMONIA CAS IC.A.S. No. 01S3 | 7644-41-7 Foraula NH3 Addr##* (No.,Str##t,Clty,Stat and Zip Cod#) Arcadian Corporation P.O. Box 265 Paraippany, N.J. 07054 Director, Product 3af#ty iPhon# Nuab#r I <504) 64E-4S07 Molocular Ut. | SEE SECT, K |ls#u# Dat# |R#vi*#dDaT# (MAY 197$ IaUC.16,1989 B. FIRST AID FLOOD AFFECTED BODY AREA. EYES. WITH WATER IMMEDIATELY FOR AT LEAST 15 MINUTES. IMMEDIATELY REMOVE PATIENT TO UNCONTAMINATED AREA. IN CASE OF SEVERE EXPOSURE, CALL A PHYSICIAN AND KEEP PATIENT COMFORTABLE. WARM AND QUIET UNTIL HIS ARRIVAL. PROMPT ARTIFICIAL RESPIRATION WITH 100X OXYGEN MAY BE REQUIRED. INGESTION' GIVE LARGE QUANTITIES OF WATER, BUT DO NOT INDUCE VOMITING. CALL A PHYSICIAN. GIVE NEUTRALIZING AGENTS, SUCH AS CITRUS FRUIT JUICES OR DILUTE V1NIGAR. NOTICE *** This product #af#ty dt sh##t 1# off#r#d soltly for your information, conild#rtion #nd invtstlg#tion. Arcadian Corporation provid#* no warranti##, #ith#r axprta# or impliad, and assuaas no rasponsibility for th# accuracy or coapl#t#n##s of th# data contained h#r#in. ______ 1 PSJB 7 SAL 000007062 CCT 12 '89 10*06 ARCADIAN CQRP. ARCADIANI P. 3" 9 MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE: (S04> 648-4573 >)>>ANHYDR0U6 AMMONIA C. HAZARDS INFORMATION - Health GS 377 Inhalation HIGHLY IRRITATING TO THROAT AT APPROX 8R0NCH0SPASM, CHEST PAIN, PINK FROTHY LCLO(RAT): 2000 PPM/4H. 2500-6500 PPM MINUTES. REF. (a) * <b) . PPM. CAUSES EDEMA, DYPSNCA, UH. LC50<HOUSE>:4S37 PPM/1H IDERED DANGEROUS TO LIFE IN 30 Ingestion SYMPTOMS flHILAR TO INHALATION. LUNG IRRITATION AND PULMONARY EDEMA AFTER tE-24 HOURS' DELAY. Skin IF CONTACT WITH GAS PROLONGED MORE THAN A FEU MINUTES. SEVERE BURNING PAIN AND CORROSIVE DAMAGE. CONTACT WITH LIQUID INTENSELY IRRITATING. -Y* $2t}&iTIRRITAVi8NID 18 INTCNSELY IRRITATING. CONTACT WITH GAS AT 700 PPM Porslesabie Concentration Air: 35 PPM- OSHA STANDARD AT A 35 PPM STEL FOR_1 MINUTES EXPOSURE BASED ON CONSIDERATION OF NASAL AND AIRWAY IRRR .ITATION. REF.(g). Biological .NONE ESTABLISHED. Unususal chronic toxicity WE KNOU OF NO REP0RT8. C. HAZARDS INFORMATION - Flro and Protact Ion Flash Point: N/A C Auto Ignlt. Tasporituro: 65! IjOpen cup |TM|ciosad cup Floanable limits In sir (X by vol) C Upper: 85 Lower: 16(HORIZONTAL PROPAGATION) Unusual flro and axploelon hazards > PRESENCE OF OIL OR OTHER COMBUSTIBLE MATERIALS WILL INCREASE THE FIRE | HAZARD. SEE HAZARDOUS COMBUSTION PRODUCTS, SECTION G. PAGE 2 of 7 SAL 000007063 CCT 12 '88 105 08 ARCADIAN CORP. ARCADIANl P.4,8 MATERIAL SAFETY OATA SHEET EMERGENCY TELEPHONE: (504) 64E-4573 > > >>ANHYDROUS AMMONIA ,<?3 77 D. PRECAUTIONS/PROCEDURES Fir# extinguiehing agents RECOMMENDED STOP FLOU OF CAS. Fir# extinguishing agents to AVOID ALL STANDARD AGENTS ARE ACCEPTABLE. (WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM) Special fir# fighting precautions STOP FLOU OF CAS. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL AND TO PROTECT MEN EFFECTING THE SHUT-OFF. WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS APPROVED BY NIOSH. itllation NATURAL VENTILATION SHOULD BE PROVIDED. MECHANICAL (GENERAL) VENTILATION IF NATURAL VENTILATION IS FOUND INADEQUATE. Norsal Handling AVOID HEATING CONTAINERS. ELECTRICAL INSTALLATIONS MUST BE SPECIAL. REF (a), P. 46. SEE REF. (C> FOR ADDITIONAL INFORMATION. SEE SECTION K. Storage PREFERABLY STORED OUTSIDE. OTHERWISE IN COOL, WELL-VENTILATED, NONCOMBUSTIBLE LOCATION. AWAY FROM ALL POSSIBLE &OURCES OF 1SNITi6n. Spill or leak FOR LIQUID SPILL DUE TO TANK OR CYLINDER FAILURE. EVACUATE AREA AND WAIT FOR EVAPORATION. A PERSON WITH COMPLETE PROTECTION MAY BE SENT BACK TO DIKE SPILL AND THUS MINIMIZE AREA FROM WHICH EVAPORATION TAKES PLACE. FOR CAS LEAK, EVACUATE, BUT A PERSON UITH COMPLETE PERSONNEL PROTECTION MAY BE SENT BACK TO CLOSE OFF VALVE, ETC. KEEP IGNITION SOURCES AWAY. Special Precautiona/Proceduree/Label Instruct ion# FOR ADDITIONAL HANDLING PROCEDURES, SEE COMPRESSED CAS ASSN *| PAMPHLETS: C-8, "ANHYDROUS AMMONIA...TRANSPORT.STORAGE AND USE-: AND C-|, AMERICAN NATIONAL STANOARO: "SAFETY REQUIREMENTS FOR STORAGE AND HANDLING OF anhydrous ammonia.* 3 PACE 3 o# 7 SAL 00000706A OCT 12 '89 10:09 ARCADIAN CCRP. arcadian P.5^8 MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE: (504) 648-4573 )>> >ANHYDROUS AMMONIA E. PERSONAL PROTECTIVE EQUIPMENT GS377 Respiratory protection UP TO tOO PPM CHEMICAL CARTRIDGE RESPIRATOR*, SUPPLIED-AIR RESPIRATOR* OR SELF-CONTAINED _R__E_A__T_H__I_N- _A.P...P...A...R...A..T..U. S.__100-300 _PpH, CHEMICAL CARTRIDGE RES PIRATOR* WITH FULL FACEPIECE. 300*500 PPM# CANISTER GA8 K*, SUPPLIED- AIR RESPIRATORS, OR SELF-CONTAINED SRE ATHING APPARATUS. SI SECTION K Ey*s end fee* CHEMICAL GOGGLES IF <1) ANY POSSIBILITY OF CONTACT WITH GREATER THAN fOX AQUEOUS*AMMONIA; OR <S> REASONABLE POSSIBILITY OF CONTACT WITH LE8S THAN 10* AQUEOUS AHM6nIa. DO NOT WEAR CONTACT LENSES. SAFETY GLAS8ES UNDER OTHER CONDITIONS Hands, arts, and body PROTECTIVE CLOTHING UNDER THE SAME CONDITIONS AS FOR CHEMICAL GOGGLES. IMMEDIATELY REMOVE UNDER WATER STREAM* NON-IKPERVIOUS CLOTHING THAT StCOMES CONTAMINATED WITH BREATHER THAN 10N AQUEOUS AMMONIA. PROMPTLY REMOVE SAME WITH 10X OR LESS AQUEOUS AMMONIA. Othar clothing and equipment EYE-WASH FACILITY AT SITES OF HANDLING OR STORAGE IF AQUEOUS AMMONIA STRONGER THAN 10X IS PRESENT. F. PHYSICAL DATA aMaterial is (at noraal conditions) Appearance and Odor SHIPPED AS A LIQUID IN C0HPRE8SED,GREEN (NON-FLAMMABLE CAS) LABEL. SEE SECT. K. LIQUID SOLID GAS Boiling Point: -33.35 DEG.C Melting Point: -77.7 DEG.C Specific Cravity<H*01)J 0.68 Vapor Density (AirB1> : 0.594 Solubility In Water (X by wt.) pH <G IS DEC.C) 47 SEE SECTION K. Vapor Pressure a (as Hg at 800 (P8IGI 109 6 Evaporation Rate a X Volatiles by voluae C) 1 00 jutyl Acetate IXEther 1) . Time: <1 PAGE 4 of T sal 00007o 65 OCT 1Z *99 10:10 ARCADIAN CORF. ARCADIANI s. 9- $ MATERIAL SAFETY DATA SHEE*! EMERGENCY TELEPHONE: <S04) 648-457: > > >>ANHYDROUS AMMON!/ 6 S 3 7? G. REACTIVITY DATA Stability Conditions to Avoid Unstable 0 8tblo NOT APPLICABLE. Incompatibility (Mttriilt to ovoid) SEPARATE FROM OTHER CHEMICALS* PARTICULARLY OXIDIZING GASES* CHLORINE, BROMINE* IODINE*AND ACIDS.* - REF. (cl, PS. 47. SEE SECTION K. Hazardous decomposition produets NORMAL COMBUSTION OF AMMONIA IN AIR YIELDS NITROGEN AND WATER ( STEAM) UNDER CERTAIN CONDITIONS OF TEMPERATURE AND PRESSURE SOME QQUUAANNTTITY OF OXIDES OF NITROGEN MAY ALSO BE FORMED. a^Hazard polyaorlzatlon Conditions to Avoid NOT APPLICABLE. y Occur Will Not Occur PAGE S Of 7 SAL 000007066 :<T 12 '89 10:10 hRChC:*S CORP. P.--8 ARCADIANl MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE: (504) 640-457? CSS7T . > > > >ANHYDROUS AMMONI* I. ENVIRONMENTAL Dagradabllity/aquatic toxicity NOT APPLICATE - INORGANIC. AMMONIA IS A FERTILIZER, IT MAY PROMOTE EUTROPHICATION MENTAL CONTROL PINRAWCATTICEERSWASYHSO. ULDU. SEN---O--AT- NDC--A---UD--SI-S-E-PO8--SI--C-A-_-NL--I-*EIMCPALNOTYINENGVIPRROONPMEERNTEANLVIRON- IMPACT. EPA hazardous substanca? xj YES Q If so# roportabla quantity: 100 i NO 40 CFR 11S-117 Vast a disposal nathod*(disposar auat comply with disposal and discharga laws) DISPOSAL OF ANHYDROUS OR AOUEOUS AMMONIA MAY BE SUBJECT TO FEDERAL, STATE AND LOCAL REGULATIONS. USERS OF THIS PRODUCT SHOULD REVIEW THEIR 6pERA* TIONS IN TERMS OF APPLICABLE FEDERAL, STATE ANJL^OCAL LAWS AND REGULATIONS THEN CONSULT WITH APPROPRIATE REGULA+ORY AGENC;i*ES -B--E--F--O--R---E----D---IS---C--H---A--R--G---I-N--G- OR" DISPOSING OF WASTE MATERIAL. RCRA Status of unusad notarial: I NOT A "HAZARDOUS WASTE". SARA - SEE SECTION K. 4#a2?" REFERENCES Is this listad notarial? YES NO NIP (List) Q [x] I ARC (Monographs) QJ |xj aYES NO OSHA (Carcinogan) ACSIH (TLV List) [7] Q Ptrnlssabla concantration rafarancas OSHA REGULATIONS# 09 CFR 1910.1000. 08HA PCRM2SSABLE EXPOSURE_ LIMIT VALUE I?A^2iop5gFiRI5?l0,lBH5.TERH EXP0SURE LIHIT> t,s MINUTgs> 8BASED ON THE RtgTrrto'r^'si^ndardirTDrTr^r^GAS* DOT HAZARDOUS MATERIALS^TABLE 49 CFR 170 101. 49 CFR Ganaral (a) (b) SEE TECH. GUIDE NO. 7 # "HANDBOOK OF HAZARDOUS MATERIALS#" AM. MUTUAL XN8URANCE ALLIANCE# 00 NO. WACKER, DR# CHICAGO. DREISBACH# R.H.*& HANDBOOK OF POISONING", 9TH ED., 1977, LANGE MEDICAL PUB.. LOS ALTOS. SECTiON K. B P$1e7 & SAL 00007067 OCT 12 '89 10! U ARCADIA CCRP. P.3' S ARCADIAN! MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE: (504) *48-4573 K ADDITIONAL information CrS 377 > > >>ANHYDROUS AMMONIA SECTION A - MOLECULAR WEIGHT 17.04 (FORMULA WEIGHT) SECTION D * NORMAL HANDLING - THE LATTER SHOWS THE NEEO FOR PERSONNEL TRAINING ADEQUATE INSPECTION OF EQUIPMENT. SEE REF.(d) FOR FEDERAL 08HA STANDARDS. SECTION E - RESPIRATION PROTECTION - ^REFERS TO A SPECIFIC CARTRIDGE OR CANISTER FOR NH3 GAS. SECTION F - APPEARANCE AND ODOR - COLORLES8 GAS IS DRAWN FROM THE CYLINDERS. IT HAS A STRONG# PUNGENT# CHARACTERISTIC OOOR. SECTION F - OH - 1 1 6 FOR 1.0 N AO. SOLN.i 11.1 FOR 0.1 N AO. SOL.; 10.6 FOR 0.0T N AO. SOLN. SECTION G - INCOMPATIBILITY (MATERIALS TO AVOID) * NOTE HAZARDOUS RE ACTIONS.HAVE SEEN_DOCUMENTED FOR_CONTACT OF ANHYDROUS AMHONIA WITH! ACETALDEHYDE# ACROLEIN. BORON# BORON TRIOXIDE# BROMINE# CHLORINE# CHLORITES# CHROMIUM TRIOXIDE. ETHYLENE OXIDE. FLUORINE# GOLD# HY^OCHLOROUS acxdviooiAe# mercury,nitric Acid# nitrogen ttroxide# Aitrog^n trichloride NITR6gEN TRiFLUORIDE# PHOSPHOROUS TRIOXIDE# PICRIC AfclD# POTASSIUM Silver~chloride, ri vioL&NTLY. TH WATER CAN EXPLODI SECTION I - TITLE III - SARA ANHYDROUS AHHONIA/COHPONENTS/IMPURIT2E8 LISTED XL _ REPORTING) 40 CFR PART 355 - EXTREMELY HAZARDOUS SUBSTANCES - -------- 170 - HAZARDOUS CHEMICAL REPORTING - AAPPLICABLE SARA - SEC' ION 311 IMMEDIATE DELAYED EPA HAZASRUDDDCENATTE|rGEOSRSIEUSRE HEALTH HEALTH FIRE RELEASE REACTIVE 40 CFR PART 378 - TOXIC CHEMICALS - AMMONIA SECTION J - GENERAL (c ) NFPA MANUAL 49. 11 HAZARDOUS CHEMICALS DATA". 1975# NATIONAL TECTXON ASSOCIATION# 470 ATLANTIC AVE.# BOSTON. AA 08819 FIRE PRO- <d> NFFA MANUAL 491M# "MANUAL OF HAZARDOUS CHEMICAL REACTIONS"# 1971# SAME PUBLISHER AS REF.(c) ABOVE. <) "CASE HISTORIES OF ACCIDENTS IN THE CHEMICAL XN0U8TRY"# VOLS. 1-3 COVERING 1951-44. WITH SUPPLEMENTS. MANUFACTURING CHEMIST8 ASSOCIA TION. 1685 CONNECTICUT AVE.# WASHINGTON# DC 80009. it) F--E--D--- AL 08HA SAFETY AND HEALTH STANDARDS# SUBPART H "HAZARDOUS HAT RI. ALS". SECTION 1910.101# "COMPRESSED CASSES (GENERAL REQUIREMENf~S)" L SECTION 1910.Ilf# "STORAGE AND HANDLING OF ANHYDROUS AMMONIA6".# AND OTHER SECTIONS. PROPOSED REVISION: 41 FEDERAL IREGISTER 17887# APRIL 83# 1974. (g) NIOSH CRITERIA DOCUHCNT, 1974# HEW, PB844499. NTIS. <fi) NIOSH "RECOMMENDED STD. FOR OCCUPATIONAL EXPOSURE TO AMHONIA",JAN.1975 (i) NXOSH/OSHA "POCKET GUIDE TO CHEMICAL HAZARDS", 1978. PAGE 7 Of 7 SAL 000007068 HAY 0 7 iffl MATERIAL SAFETY DATA SHEET An explanation oi the terms used herein may be found in OSHA 20 CFR 1910 1200. avertable from OSHA regionalor area offices (Eeeentlatty similar le U.S. Department of Labor Form OSHA-20 and generally aecapiad in Canada for information purposas) Do Not Oupllcata This Form. Request an Original. EP&P 4830-A October 1965 c A O.Q 2 PRODUCT CHEMICAL NAME FORMULA PSA Adsorbent H*5 Activated Alumina Ai,0,-H,0 TRADE NAME PSA Adsorbent H-5 | SYNONYMS 1 CHEMICAL I FAMILY MOLECULAR WEIGHT Alumina Hydrate Adsorbent Alumina Aluminum Oxide 101.94 MATERIAL (CAS NO.) Aluminum Oxide (1344-28-1) Water(7732-18-5) Sodium Oxide (1313-59-3) Iron Oxide (1309-37-1) Silica, Amorphous (7631 -86-9) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) <95 < 10 <1 <1 <1 Nuisance particulate 10 mg/m3 Total dust 5 mg/m3 Respirable dust Not applicable None currently established 5mg/mJ(Rouge) 10 mg/m3 Total dust 5 mg/m3 Respirable dust (Nuisance dust) (15 mg/m3 Total dust) (5 mg/m3 Respirable dust) (Not applicable) (None currently established) (10 mg/m3) (20 mppcf) (None currently established) i BOILING POINT, 760 mm. Hg SPECIFIC GRAVITY (H,0 = 1) Not Applicable FREEZING POINT 3.1 -3.3 depending on grade VAPOR PRESSURE AT 20C Not Applicable Not Applicable VAPOR DENSITY (air = 1) Not Applicable SOLUBILITY IN WATER, by wt. Insoluble PERCENT VOLATILES BY VOLUME Not Applicable EVAPORATION RATE (Butyl Acetate = 1) Not Applicable APPEARANCE AND ODOR No odor--depending on product, may appear as off-white bead, pellet or mesh. L IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 304-744-3487 In Canada 514-645-5311 For routine information contact your local supplier Union Carbide requests the users oi this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of ils customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION LJ ENGINEERING PRODUCTS & PROCESSES UNION CARBIDE CANADA LIMITED Li ENGINEERING PRODUCTS & PROCESSES Copyright 1985 Union Carbide Corporation 0Z15( b Page i of 4 SAL 000007069 EP&P 4830-A PRODUCT; PSA Adsorbent H-5 C AO 02 THRESHOLD LIMIT VALUE: See Section II. VJ WEALTH HAZARD DATA EP*P 4830-A October 1985 EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING--No evidence ol adverse effects from available information. SKIN ABSORPTION--No evidence of adverse effects from available information. INHALATION--May cause irritation of the nose and throat, accompanied by cough and chest discomfort. SKIN CONTACT--May cause irritation and local reddening. EYE CONTACT-- May cause eye irritation seen as excess redness of the conjunctiva. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: Prolonged inhalation may cause chronic lung injury. OTHER EFFECTS OF OVEREXPOSURE: None currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Breathing of dust may aggravate asthma and inflammatory or fibrotic pulmonary disease. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST-AID PROCEDURES: SWALLOWING--If ingested in large quantities, drink two glasses of water. Induce vomiting if the patient is conscious. SKIN--Wash with soap and water. INHALATION-- Remove to fresh air. If symptoms persist, see a physician. EYES--Flush eyes with water for 15 minutes. NOTES TO PHYSICIAN: This product is a desiccant and generates heat as it adsorbs water. The used product can contain material of a hazardous nature, identity that material and treat accordingly. r 000007070 SAL PROOUCT: PSA Adsorbent H-5 t=.!l=H!.U.l!fM,1=1.1. EP&P 4830-A t ao (firer 1985 FLASH POINT (test method) Not Applicable AUTOIGNITION . A ,. TEMPERATURE Not AppLcable FLAMMABLE LIMITS LOWER IN AIR, % by volume Not Applicable UPPER .... , .. Not Applicable EXTINGUISHING MEDIA: Activated alumina is nonflammable. Use media appropriate for surrounding fire. May use foam. CO,. dry chemical or water. SPECIAL FIRE FIGHTING PROCEDURES: Depends on the use of the material. Used material may contain products of a hazardous nature. The user of this product must identify the hazards of the retained material and inform the fire fighters of these hazards. UNUSUAL FIRE AND EXPLOSION HAZARDS: None currently known. -n ifc -'r.i -i--t STABILITY UNSTABLE STABLE X CONDITIONS TO AVOID: Reacts violently with chlorine Irifluoride, producing flame. May cause ethylene oxide to polymerize violently, releasing heat. HAZARDOUS DECOMPOSITION PRODUCTS: Pure product does not burn Other decomposition products will come from the retained products of use and would include the decomposition producls of the retained product. HAZARDOUS POLYMERIZATION May Occur Will not Occur X CONDITIONS TO AVOID: None currently known. [^ ~ v.<__ _ STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep the spill area, collect and place the Spilled material in a waste disposal container. Avoid raising dust. WASTE DISPOSAL METHOD: Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal, state and local regulations. SAL 000007071 Page 3 of 4 PRODUCT: PSA Adsorbent H-5 C A 0 0 2___________________________ r VIII. SPECIAL PROTECTION INFORMATION : ` EP5P4830-A October 1985 .v RESPIRATORY PROTECTION (specify type): Where there is excessive dustiness, wear a respirator selected as per OSHA 29 CFR 1910.134 and approved by NIOSH/MSHA. LOCAL EXHAUST--As appropriate to minimize dust MECHANICAL (general)--Not Applicable VENTILATION SPEC/AL--Not Applicable OTHER--Not Applicable PROTECTIVE GL )VES: Use gloves impermeable to dust where prolonged hand contact is possible. EYE PROTECTION: Safety glasses or goggles selected as per OSHA 29 CFR 1910.133 OTHER PROTECTIVE EQUIPMENT: Eyewash fountain m CAUTION: Causes severe or mild eye irritation. Breathing dust maybe harmful. May cause skin irritation. Open container slowly to avoid dust. Do not gel in eyes. Avoid breathing dust and prolonged contact with skin. Use with adequate ventilation. Keep container closed. Wash thoroughly after handling. Do not ingest. Before using you should know the hazards of the products adsorbed on the Adsorbent. The products could be flammable or toxic. You should know and follow the safety precautions related to the adsorbed product. OTHER HANDLING AND STORAGE CONDITIONS: Pouring dry material can cause static electricity build-up. Ground container where electric sparks must be prevented. Keep container sealed tightly to maintain product quality. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the dale of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. EPSP EP&P 4830-A 85-0941 10/85 1M GENERAL OFFICES IN THE USA: Union Carbide Corporation Engineering Products & Processes 39 Old Ridgebury Road Danbury, CT 06817-0001 IN CANADA: Union Carbide Canada Limited Engineering Products & Processes 123 Eglinton Avenue East Toronto, Ontario M4PIJ3 Other offices in principal cities all over the world Lithographed in U S.A Page 4 ot 4 SAL 000007072 m 01 m UKtION CARBIOt MATERIAL SAFETY DATA SHEET An *ipdmrntiafi oiIt* mms u*3 may ># foundm OSHA ?9 CFft 19)0 12QQ, avBfobfo from OSHA ngtom/or ere* offices (Essnllally slmllw to U S. Departmont of Labor FormOSHA-20 and gnr*My accaptad Jn Canada for (nformailon purposes) Oo Not Oupllcata This Form. Request an Original. EP&P 4828-A October 1d85 cU 3# PRODUCT CHEMICAL NAME FORMULA PSA Adsorbent H-3 Silica Get SiO, plus water (HjSiOj) TRADE NAME PSA Adsorbent H-3 SYNONYMS CHEMICAL FAMILY MOLECULAR WEIGHT Amorphous Silicon Dioxide, Silicic Acid Amorphous Silica Not Applicable r. --yvi- For mixtures of this product request the respective component Materials Safely Data Sheets See Section IX. MATERIAL (CAS NO.) Wt(%) 1904-1985 ACGIH TLV-TWA (OSHA-PEL) Amorphous Silica (7631 -86-9) 100 10 mg/m3 Total dust (20 mppcf) 5 mg/m3 Respirable dust (None currently established) EP&P 4828-A ______ - Jii BOILING POINT, 760 mm. Hg SPECIFIC GRAVITY (H,0 = 1) Not Applicable 2.1 FREEZING POINT VAPOR PRESSURE AT 20C Not Applicable Not Applicable VAPOR DENSITY (air s 1) PERCENT VOLATILES BY VOLUME APPEARANCE AND ODOR Not Applicable SOLUBILITY IN WATER, % by wt. Insoluble Not Applicable EVAPORATION RATE (Butyl Acetate = 1) Not Applicable No odor--depending on product, may appear as a dry white bead, pellet or mesh. L IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 304-744-3487 In Canada 514-645-5311 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish (his same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product ol the same product hazards and safety information. UNION CARBIDE CORPORATION D ENGINEERING PRODUCTS & PROCESSES UNION CARBIDE CANADA LIMITED f ! ENGINEERING PRODUCTS & PROCESSES Copyright > 1985 Union Carbide Corporation SAL 000007073 Page i of 4 PRODUCT: PSA Adsorbent H-3 EP&P4828-A October 1985 r LIMIT VALUE: See Section li. EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING--No evidence of adverse effects from available information. SKIN ABSORPTION--No evidence of adverse effects from available information. INHALATION--May cause irritation of the nose and throat, accompanied by cough and chest discomfort. SKIN CONTACT--May cause irritation and local reddening. EYE CONTACT--May cause eye irritation, retina diseases, and choroid atrophy. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: May cause upper respiratory tract irritation with discomfort of nose and throat. If high concentrations are inhaled over a long period of time, lower respiratory tract irritation may result in coughing and produc tion of sputum. Submicron amorphous silica does not cause pneumonoconiosis in man. OTHER EFFECTS OF OVEREXPOSURE: None currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology information and ot the physical and chemical properties of the material suggest that overexposure is unlikely to aggravate existing medical conditions. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST-AID PROCEDURES: SWALLOWING--If ingested in large quantities, drink two glasses of water. Induce vomiting if the patient is conscious. SKIN--Wash with soap and water. INHALATION--Remove to fresh air. If symptoms persist, see a physician. EYES--Flush eyes with water for 15 minutes. See a physician, preferably an ophthalmologist; immediately. NOTES TO PHYSICIAN: This product is a desiccant and generates heat as it adsorbs water. The used product may be contaminated by material of a hazardous nature. Appropriate treatment will be dependent upon the identity of such contaminants. Page 2 of 4 SAL 000007074 PRODUCT: PSA Adsorbent H-3 '4iv. FIRE AND EXPLOSIQN HAZARD DATA EP&P 4828-A *051tober 1985 FLASH POINT (test method) Not Applicable AUTOIGNITION A_, TEMPERATURE Not Applicable FLAMMABLE LIMITS LOWER IN AIR, % by volume Not Applicable UPPER Not App|jcable EXTINGUISHING MEDIA: Silica Gel is nonflammable Use media appropriate for surrounding fire. May use foam, CO,, dry chemical or water. SPECIAL FIRE FIGHTING PROCEDURES: Depends on the use of the material. Used material may contain products of a hazardous nature. The user of this product must identify the hazards of the retained material and inform the fire fighters of these hazards. UNUSUAL FIRE AND EXPLOSION HAZAROS: None currently known. STABILITY UNSTABLE STABLE X CONDITIONS TO AVOID: Reacts with Hydrogen Fluoride. INCOMPATIBILITY (materials to avoid): Chlorine trifluoride, manganese trifluoride, oxygen difluoride, fluorine. HAZARDOUS DECOMPOSITION PRODUCTS: Pure product does not burn. Other decomposition products will come from the retained products of use and would include the decomposition products of the retained product. HAZARDOUS POLYMERIZATION Mav Occur Will not Occur X CONDITIONS TO AVOID: None currently known. E1 J STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Sweep the spill area, collect and place the spilled material in a waste disposal container. Avoid raising dust. WASTE DISPOSAL METHOD: Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal, state and local regulations. SA*- 000007075 Page 3 ol 4 PRODUCT: PSA Adsorbent H -3 EP4P4828-A October 1985 I.SPECIALPAOTECTION INFORMATION RESPIRATORY PROTECTION (specify type): Where there is excessive dustiness, wear a respirator selected as per OSHA 29 CFR 1910.134 and approved by NIOSH/MSHA. LOCAL EXHAUST--As appropriate to minimize dust MECHANICAL (general)--Not Applicable VENTILATION SPECIAL--Not Applicable OTHER--Not Applicable PROTECTIVE GLOVES: Use gloves impermeable to dust where prolonged hand contact is possible. EYE PROTECTION: Safety glasses or goggles selected as per OSHA 29 CFR 1910.133 OTHER PROTECTIVE EQUIPMENT: Eyewash fountain CAUTION: Causes eye irritation. Breathing dust may be harmful. May cause skin irritation. Open container slowly to avoid dust. Do not get in eyes. Avoid breathing dust and prolonged contact with skin. Use with adequate ventilation. Keep container closed. Wash thoroughly after handling. Do not ingest. Pouring dry material can cause static electricity build-up. Ground container where electric sparks must be prevented. Keep container sealed tightly to maintain product quality. Before using you should know the hazards of the products adsorbed on the Adsorbent. The products could be flammable or toxic. You should know and follow the safety precautions related to the adsorbed product. OTHER HANDLING AND STORAGE CONDITIONS: pH in 5% slurry is approximalely 3.5-8.0 depending on grade. The opinions expressed herein are those of qualified experts wilhin Union Carbide. We believe that the information contained herein is current as of the dale of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation lo determine the conditions of safe use of the product. EPSP GENERAL OFFICES IN THE USA: Union Carbide Corporation Engineering Products 4 Processes 39 Old Ridgebury Road Danbury, CT 06817-0001 IN CANADA: Union Carbide Canada Limited Engineering Products & Processes 123 Eglinton Avenue East Toronto, Ontario M4P IJ3 Other offices in principal cities all over the world. EP&P 4828-A 85-0941 10/85 1M Lithographed in U.S.A. Page 4 ol 4 SAL 000007076 MALLINCKRODT Material Safety Data Sheet Mallinckrodt provide* llH information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALUNCKRODT MAKES NO REPRESENTATIONS. OR WARRANTIES, EITHER EXPRESS OR 1MPUED, OP Mallinckrodt, Inc Science Products Division, P.O. Box M Puis, KY 4Q361 MERCHANTABILITY. FITNESS FORA PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET PORTH HEREIN ORTO THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALUNCKRODT WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING PROM USE OF OR RELIANCE UPON THIS INFORMATION. Emergency Telephone Namben 314-982-3001)____________ XYLENE SECTION! Physical Data SECTION 3 Reactivity Data PRODUCT IDENTIFICATION: Synonyms: Dimethyl benzene, zykrl Formula CAS Nu 03040-7 Molecular Weight: 106.17 Oiemical Formula: CgHyo Hazardous Ingredients: Xyten* bomeit pao 100-41-4 Ethyl benzene PRECAUTIONARY MEASURES DANGOB HARMFULOR FATAL IP SWALLOWED. HARMFUL IF tXKAlXB. VAPOR HARMFUL. FLAMMABLE AFVSCtt CKKTRAL NSXVQVS SY8TVM. CAUSatRRRATfON. Keep away from beat, sparks and flame. Avoid contact with eyes, skin and clothing Keep container dosed. Use with adequate ventilation. Avoid breathing vapor. Wash thoroughly after EMERGENCY/FIRST AID If irritation develops call a pbysidan. If swallowed, do not induce vomiting. Call a physician immediately. Iflnhakd, remove to fresh air. IT not breathing, give artificial respiration. If breathing k difficult, give oxygen. In cased contact, immediately flush (tin or eyes whb plenty ofwater for at least 13 minutes. In all cases caU a physician. SEE SECTIONS. DOT Hazard Class: Flammable liquid Appearance: Qear, colorless liquid. Odor Characteristic odor. Solubility: Insoluble in water. Boiling Point: 137-140TC (27*48410 Melting Point: -25*C(-irF) Specific Gravity: 0J6 Vapor Deadly (Airul); 3.7 Vapor Pressure (nun Hg): 8@2trC(**F) Evaporation Race: (Butytacetate 1) 0.7 SECTION 1 Fire and Emlonkm Information Stability: Stable under ordinary conditions of use and storage. Hazardous Decompodtion Products: Involvement in a lira causes formation of carbon monoaide and unidentified organic components. Hazardous FNrfymerlxntioa: This substance docs not polymerize. Incompatibilities: Strongoddizsre, heat and sources of ignition. Fire: Flammable. Flashpoint: 26J2*C (79*P)(TCQ(Minimum) Autoignition: ca. 46J**C (867T). FlamanMe Umfta in air, vofume % (IXKTXJ)- Explosion: Above flash point, vapor-air mixtures are explosive witiun flammable limits noted above. Fire Extinguishing Media: Dry chemical, foam or aubon dioxide. Water spray may be used to keep fire expoacd containers coot Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full faoepieoe operated in the pressure demand or other positive pressure mode. Vapors can flow along surface* to distant ignition source and flash back. SECTION 4 Lenk/Solll Disposal Information Ventilate area of leak or spill. Remove all soutees of ignition. Henrtting nqefpmr nt mast hr frrtamfrrt tn jarrrnl iparting Ocan-up personnel require protective dothing and respiratory protection from vapors. Dike tpilL Contain and recover liquid when possible. Disnosal: Collect as hazardous waste and atomize in a suitable RCRA approved combustion chamber, or abaorb with vermtculite, dry sand, earth or similar material for disposal u hazardous msie in a RCRA approved facility. Do not flush to tcwerl Reportable Quantity (RQXCWA/CT.RClA): 1000 lbs. Ensure compliance with local, state and federal regulations. i GO SAL 0007q77 i\iA <**& S Effective Date: 02-16-89 Supersedes 07-13-87 NFPA Rating*: Health: 2 Flammability: 3 Reactivity: 0 XYLENE 8351 Effective Date: 02-16-89 Supersedes 07-13-87 XYLENtE tj} SECTION 5 Health Hazard Information A. EXPOSURE/HEALTH EFFECTS Iskiladoo: hiaiiriM vapon maybe Irritating to the noee and throat, uiakiirta of high concentrations may result la nausea, vomiting, headache, ringing hi the earn, and seven breathing difficulties wfakfa maybe delayed tit onset Substeraal pain, cough, and heemeaens ara also reposted. High vapor concentrations are anesthetic and central nervous system Ocprrecsnts. Ingestion: IngrttVin causes burning sensation In mouth and stomach, nausea, vomiting and salivation. Minute amounts aspirated into the Kings can produce a severe hemorrhagic poeumonitis with severe puhnoony injury or death. SUa Contact: Skin contact results in loss of natural oils and often results in a characteristic dermatitis. Eye Contact: Vapon an cause irritation. Splashes ate toste to eye tissue. Hemorrhagic infltmatocy lesions may develop. Chronic Eipowit: Chronic Inhalation can cauae headache, toss of appetite, nervousness and pale skia. Repeated or prolonged skin coniact may cause a skin rash. Repeated exposure of the eyes to high conceatretioas of vapor may cause reversals eye damage. Aggravation of Pre-existing Conditions: Pcraoas with pre-existing skin disorders or eye problems, or impaired liver, Udaey or respiratory function may be more susceptible to tits effects of the substance. B. FIRST AID Inhalation: If inhaled, remove to fresh sir. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestioa: Aspiration hazard. If swallowed, get Immediate medical attention. Vomiting may occur spontaneously, but DO NOT INDUCE! If vomiting occurs, keep head below (tips to prevent aspiration Into lungs. SUa Exposure: Remove any contaminated clothing. Wash sltin with soap or mild detergent and water for at least IS minutes. Gel medical . attention if irritation develops or persists. Eye Exposure: Wash eyes with plenty ofwater for at least IS minutes, lifting lower and upper eyelids occasionally. Get medical attention imarediatcly. C. TOXICITY DATA (RTECS, 1986) Xvtene:Oral ret LDSft 4300 mg/kg Inhalation ntLCSO: 3000 ppm/4H Irnatatkm eye rabbit: 87 mg mild Skia rabbit 300 mg/24 moderate Mutation data cited. Reproductive data cited. Ethvl benzene: Oral ret LD50:3500 mg/Kg Skin rabbit LD50: 17800 mg/Kg mutation data cited reproduction data cited. SECTION 6 Occupational Control Measures Airborne Exposure Limits: -OSHA Permissible Exposure Unit (PEL): 100 ppm CTWA) ISO ppm (STBL) xylene 100 ppm (TWA) 125 ppm (STEL) ethyl benzene -ACGIH Threshold Limit Value (ILV> 100 ppm (TWA) ISO ppm (STEL) xylene 100 ppm (TWA) 125 ppm (STEL) ethyl benzene Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it caa cornrot the etnimons of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACOIH document, 'Industrial Ventilation, A Manual of Recommended Practices', most recent edition, for details. Personal Respirators: (NIOSH Approved) If the TLV is exceeded a full facepiece chemical cartridge respirator may be om up to the maximum use roneea(ration specified by the wipiretor supplier. Alternatively, a iapplied air full facepieee respirator or airtined hood may be nun. Use czptosioa proof equipment SUa Protection: Wear impervious protective clothing including boots, gloves, lab coat, aproo or coveralls to prevent skin contact. Eye Protection: Use chemical safety goggles and/or c full faee shield where vp1--H*! is possible. Contact Isaacs should not be worn when wottingwith this material. Maintain eye wash fountain and quick-drench facilities to wort area. SECTION 7_ Storage and Special lafocmatlea Protect against physical damage. Store in a cool, dry well-vefiiilaied location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from oxidizing materials. Containers should be bonded and grouaded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools end equipment. EMPTY CONTAINERS: Can contain explosive vapors. Do attempt to deaa sfawe residue is difficult to remove. Do aot prswarira, cut, weld, brace, solder, drill, grind or expose such containers to heat, sparks, flame, static electricity or other sourcesof \ ignition: they may explode and cause injury or death. XYLE1 SAL 000007078 1 MALUNCKRODT Material Safety Data Sheet Msllirckrodt provides the information contained herein in good faith hut nukes no representation as to iu comprehensiveness or accuracy. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALUNCKRODT MAKES NO REPRESENTATIONS. OR WARRANTIES. EITHER EXPRESS OR IMPUED. OP Mallindcrodt, Inc Science Products Division, P.O, Box M Pahs, KY 40361 MERCHANTABILITY, FITNESS FOR a PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR TO THE PRODUCTTO WHICH THE INFORMATION REFERS. ACCORDINGLY. MALUNCKRODT WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OP OR REUANCE UPON THIS INFORMATION. Emergency Telephone Number: 314-982-5000 Addendum to Material Safety Data Sheet REGULATORY STATUS Identifies SARA 313 wbstancefri (Chem.Key: XYLEl) Product or Components of Product: XYLENE Xylene (1330-20-7) 8396 Ethylbenzene (10041-4) 17% Hazard Categories for SARA Section 311/312 Reporting . Acute Chronic Fire Pressure Reactive XXX SARA EHS Sect. 302 RQ(lbs.) TPQ (lbs.) SARA Section 313 Chemicals Name List Chemical Category CERCLA Sec. 103 RQ (lbs.) RCRA Sec. 26133 No No No No Yes Yes No No 1000 1000 U239 No S8S3 SAL 000007079 SARA Section 302 EHS RO: Reportable Quantity of Extremely Hazardous Substance, listed at 40 CFR 355. SARA Section 302 EHS TPQ: Threshold Planning Quantity of Extremely Hazardous Substance. An asterisk () following a Threshold Planning Quantity signifies that if the material is a solid and has a particle size equal to or larger than 100 micrometers, the Threshold Planning Quantity - 10,000 LBS. SARA Section 313 Chemicals: Tone Substances subject to annual release repotting requirements listed at 40 CFR 372.65. CERCLA Sec. 103: Comprehensive Enviromental Response, Compensation and Liability Act (Superfund). Releases to air, land or water of these hazardous substances which exceed the Reportable Quantity (RQ) must be reported to the National Response Center, (000-424-8802); Listed at 40 CFR 302.4 RCRA: Resource Conservation and Reclamation Act. Commercial chemical product wastes designated as acute hazards and toxic under 40 CFR 26133 Effective Date: 02-16-89 Supersedes 07-13-87 4 XYLENE WW m-'Ub SUUlWtefcl fcULVfcNIk Ml/, MU. I 1484 1 l r, U4 Cr S 6 44 MATERIAL SAFETY DATA SHEET flFt'POVn BY If B LABOR DEPT, ESSENTIALLY SIMLA* TO FORM OSHA 174 PRODUCT IDEWIITV: 660366 KOI #1 I. SUPPLIER s!HjTH^5j w\` n r.nm HCUSTti:i,u" 77241 FHO`IEj 7J3*?37-?500 r.HFTfiEC nmi 1-B00-42M300 II. HAZARDOUS INGREDIENTS Section 313 Supplier Notification 7*-.jg profit ;or.tim the tjxie ctieilcfiij Subject the reporting rtuuircMfite M FmUo Ji! d U's Es^rgeacy FI inning fc Coatunity Right-To-Know Act o4 1936 t o4 *0 CFR 372. PM Eft IM ITMvbub testcne TMuan* fr.dcris IQStST U-50 IDFAL) LH^ST KTTC^H IC5^ (VAPCSS) C-9E5T NM 1050 tBI INI ta= f t?9-99-3 4HH icCsH-Ses-3 t? M I 105*98-3 1C3-69-3 108-89-3 KL I03HA) 100 ppa 750 PCS CE1LIVB 300 pen W'j* M.ynn TLtoVo lApCpCi im 730 BPS BIEL IDSpA l RC61H) ISO ppa !Wfl pp SARA TITLE Itl i*. i iKfcb. StCIIOH) M <3U,3I2,3IM>CF.A) 1? (3tt,ll2,31?,FCRA> 3000 eo/iglRatsi 5300 pp* foicel 4000 ig/kg (Rabbits) WAIAR3 MUK6 .jjfoi.HJ ri'-f-fti: 2 HEALTH (HtilSh I rtA'IJIABILlTYt 3 \ .ft 5ECTJCR 3)3 Mft2AF:j)S: Acute Health, Fire REACTIVITY* 0 DOT SHlFrJf-E Mi*>'Ei Cwpsuntf Cleaning, Liquid DO) i)&yv5 LAPEL FUrrable liquid III. tniLKiS rou-cc . tssyjTY * T40 ; ?AF1 : srrcjfic EfiTVITY TMsrM) : FO^Bf/BALLM s VtroR FFEEEfiFc `f<! s{ Hu!920 VATOR DENSITY (ai*i) ! WATER A85CRPTI0H s AGIO ABSD^FTI0i <854 tLSffj} i &Qf THE <FU??*M) t 1 VOLATILE Br VOL s AFFEAWWCE ; OC?R : SOLVENCY FfT-`V!ETFR5: H!'B coer Fending) s f'r'B (Fp'aritv! 1 C-kl IPisse'-sier.T ) PE'RACTIVE l-TO s PHYSICAL DATA 57 !10 lit 34.2 .es4 7.114 53.2 3.0 Appreciable Appreciable 4.1 100.0 Liquid.Water Ketone 21.0 41.7 37,3 1.400 SAL 000007080 HAR-21-9Q WED 14'.06 SOUTHWEST SOLVENTS FAX NO. 7139371103 P. 04 GS6 44 iWW mPfirjtv. 660366 KCl *1 FAEE 2 IWE& TV. FIRE EXPLOSION HAZARDS L14]T IK MR U by vo1): !,6 flASK POINT HES' iSETKCDh -16*C / 2'F UCC) FU'WLlTr CUbglflCAIJOH! class I 8 EMl^VISiW j NFFA Class 8 extinguishers (COf or feaM r.r.ifi j tor tUnb 1 I liquid Mrs*. srr.CIAL MRE t fiWUttS Ff,0f,Ef'.M?'? : { ; sriny ay be ineffective on fire but can protect fire filters b cool contain*'*, l!e fog riz!ss If mitt i\ used. tq not snicr tenfimfi fire-spec? #Uhoat foil burkes near, tYelnst with fite shield, bunker coats, Mayes t ribbr bQfifnl. ita M3pciQVCd Miitivi p*auiu tolfcofuiiMe'br*ming ipifoatus. IXFiOMOti ft?:D FIFE EX^EHt-t Ftft-'KftBVt!\ Xwp container tightly doted* Isolate fro* oxidizers, heat, sparks, electric egisipccnt i open flaw. Closed cjvttainefi ray explode if exposed to extras belt, /'polying to hot surfaces requires special precaution*-. Espty container very hazardous! Continue ail label precautions! V. HEALTH EFFECT DATA U-'ir Vf-LiJEs 125 pyn iEvaporated Blend) ^c\;piymu OF Q7EFEWWIVP? , \>;S onjy with iJeunate ventilation. : Avoid breathing ot vapor er spray fist. ; Avoid contact Kith skin 8 eyes. ORPHIC EFFECTS: milffif Anesthetic. Irritates respiratory tract, uf : Can cause serious nervous systei diprestim. OVERFlFOSUPf s Can cause daeaoe to kidneys. blood, nerve*, liver 8 lung*, i r.Z i exit; tf}HUCi;Mty irritation to skin, defatting, streatUii. : Priary irritation to eyes, redness, tearing, blurred vision, : Absorption thru skin increases exposure. ; FiiAl! PHIhG? Hareful or fits] if srellur^. r ^slloiino can cause abdonina] irritation, nausea, venting and diarrhea. OSftlHIC EFfECT*: Vapor harafu). Tan cause dasaeo to kidneys, hUnd, nervti, liver h lung:. C!A:w:T- . tit 8 SUN CWHAtTiliquig tin cause eye irritation, OVER- : M?sl> thoroughly after handling. EXfOSWE s ChHtEfi : This pi Ddnct has re carcinogens listed by lARC,HlP,NlOSH,OSHF0r A$JH, : as of this date, greater or equal U O.IZ, : This product lay contain lesj than }M fPf nf Pemeni. i K-jl-L'jusHsrM faurim in such It* concentrations. CCi'BlTJO'!? s Fersons ith severe skin, liver or kidney problems should avoid use, faShEMTED i E'^SEKCY i : FIRST AID ; Fr:?CEE'J*f5: /n ccse cf contact with stir*, flush with plenty of water. For eyes, fltsh with plenty gf wipe fnr 15 ninutec ! oot *:dieal attMlw, Mibi nigh viper eipbs'jrf, rov to fresh air. If breathing is difficult give oxygen. If breathing has stopped give artifiriai respiration. :r CAU A PHYSItitw iMWiMELT! *?e-.fer ^ivfi anything Di amith In an uncoftociouc person, f / V OOOOOTOSl SAL Mfc.r.-OO WED 1 <1 ` 07 SOUTHliEJT SOLVENTS f/W MO. 7129271102 R. 06 6 S 6 44 FfcOSlU 660366 XCI #1 mi i ?TABRlTf ! Stable VI. REACTIVITY DATA rn`p|Tip`,`5 in MfllDi isolate Iron oxidizers, heat, spares, electric equipment I open flaae, K< AWiC ; Isolate free str^g cjiditqrs 5vch as oersanganates, chrasates t peroxides. ^i'Hc.CC';5 5 Carton tfgnoxide, Caption Dioxide frci buying. PErO'ifOSITI^i ff.flfiinR ; VII. SAf-fc HANDLING & USE PRECAUTIONS 'f 'LL OS LEM rTiPimiPtS } Sine spill at sau'ce, file ires 4 contain, ftfSfi "NllpH 1 iqaid l pul contaninated sen i in DDT app. tre,' tuntaln?rs fer mpocsl. Ubel inoedialvlr. s Clean up ruiainder with absorbent ewkrwls. KASIE DlfOSN :Tim Or'-tR FRECWTlnqq Tispgte of *:cte by lea*! felly's complying with local, state V fedB'-tl regulations, H \il, tent ail the appropriate egenctei. wapars ray ianjte explosively I spread long distances. Prevent vapor buildup. Pul cat pilot lights 4 turn oM igrijlicn sources during use It until all vapors are gone, Tin nab Ami iU.. 0`!,'1!-J'P. f1 Stoic large eecurts in il-uctures ease to* OSKfl Class I B liquids. Avoid free UU of liquid. 6?uyrirf containers *hen transferring. Co not flttc cut, saw, drill,bre:e or field, E-pty container very hazardous' Continue ail label precautions! VIII. CONTROL MEASURES jUMbTCfiT tT'OTlCHD'l: Ventilate to k*p air belcH 45 pp*. If flver TLV, in accordjn:e With i'f CFR 1910.134, <?fSC'eV (r11J : L*se H1C5H approved positive-pressure seH-contiined breathing apparatus. : Consult Safely Equipment Supplier, use explosion^proof equipment". VFHTUATiru; . tGCfii EJtHALST \ IVf^arv hFrm'ir.M rtSMERUl ftetef-uiU ; -I "M'ii. : flan* OTHER \ Hone ROTFCTIVC : i'esr [SM Standard gcgales <r face shield. Consult Safety cquipfent Supplier. ClOiHIH'i w"r gloves, aprpn S fonfurar iaparviouo to this material. Wash clothing before reuse. NOTICE :CL*TH*S5T SOL'.' t C'Ol disLlaifla ell expresse: or implied tommies of serchmtabili tv or litriss f<?' ? eartirular purpose, Kith respect to Ins product or information provided herein. Ml info'-vtic': *:p?5rir3 herein is based vF3n tiiU hMainprt free nnuhcturcM and/Ci r cL-.y.ii^'J tcihej?*! w":. HMU tr-e intcKfatioh >? believed to fc accurate, ne take nc refrssenUtiPns a8 to its accu-Hy sr sufficiency. Conditions of use are bsy-^u! cur control, and ttwefgft \'*qr* ve r =eps^si t i? v?'*' fylhh the data under SKft vv*: r.l mg i-'nrtition* to C0tcr*l?.5 'IhStl.s* Itir p*od-S! s| s.it-hlt- fhtlr particular p.irpsjss v< J D-sy sssu-e all risks cl tbPir ucp, I'andling, >?* 'f^1 ni t^s predict. a 1 j_ .s.-ire all rlsxs in regards to the publication or use of, or reliance uron, irfornation contained herein. This irfr'sMgp relates ciMy ta the product o'ESign?tcd herein, and does net rolat? to it! uss in cc^tin?tiTr with other niterisl or in any other process. PATE : WW SAL 000007082 MATERIAL SAFETY DATA SHEET chvisow Appwess Mobay Corporation fitiTir e< aaomi MOBAY CORPORATION BayerQJ AGRICULTURAL CHEMICALS DIV [SION P.0. Box 4913, Hawthorn fio ad *iue c-re luPCflSfws 06/30/89 02/18/89 20 1 ( M'CC*CV C*Ll ChIMTAEC 1titP*UNl *0 I3> > 00 ClISTflICT OP COLUMBIA UOftAT *ON-TANS*0*TATtON (UtAO< MC ' *0 (616) 242-2582 l t/* * O o o e a o t0 * I. PRODUCT NAME.............. PRODUCT CODE NUMBER CHEMICAL FAMILY____ CHEMICAL NAME........... SYNONYMS........... T.S.C.A STATUS OSHA HAZARD CCTWJN[CATION STATUS................................... : fMPO 20% Wettable Powder ^ Formula No. 021642 ---- PyPUlHrutd liiseuidiOe Cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dfehloroethenyl)-2,2-dimethyl - cyclopropanecarboxylate Cyfluthrtn Registered under F1FRA, therefore, excluded from TSCA regulation. This product Is hazardous under the criteria of the Federal OSMA Hazard Communication Standard 29 CFR 1910.1200. SARA TITLE III DATA........... : Section 311 4 312 EPA Hazard Categories: 2 Immediate Health Hazard _ Fire Hazard Delayed Health Hazard " Reactive Hazard Sudden Pressure Release Hazard NFPA 704H RATINGS O-lnsignificant 3-High 1-Slight 4-Extreme 2-Moderate 1 Health 2 Other fl Flammability 2 Reactivity STRUCTURE O CM 7 TMtxoChC-CMOfc CM. II. HAZARDOUS INGREDIENTS COMPONENTS TEMPO CAS i168359-37-5 Ingredient 1476 (Trade Secret) Ingredient 1968 (Trade Secret) Ingredient 1878 (Trade Secret) X 20 5-10 1-S 1-5 OSHA-PEl Not Established Not Established Not Established Not Established ACGIM-TLV Not Established Not Established Not Established Not Establ ished W Af 4M Product Code: 021642 Page 1 of 2 III. PHYSICAL DATA APPEARANCE................................ COIOR........................................... ODOR............................................. ODOR 1HRFSH01D....................... MOLECULAR HEIGHT.................. MELT POINT/FREEZE POINT.. BOILING POINT......................... VAPOR PRFSSURE....................... VAPOR OENSITY (AIR-1)____ pH.................................................. SPECIFIC Gravity.................. BULK DENSITY............................ SOLUBILITY IN WATER............ X VOLATILE BY VOLUME.......... Powder Tan Slightly aromatic Not Established 434.2 (for TEMPO) Not Applicable Not Applicable 3.3 x 10 m Hg Z0`C (for TEMPO) Not Known 9.2 (1% Solution) Not Applicable Approximately 30 Ibs/cu ft 1.3-2.6 ppb (for TEMPO) Not Established IV. FIRE 4 EXPLOSION DATA FLASH POINT*F(*C).................: Not Applicable FLAMMABLE LIMITS - Lei........................................... : Not Appl icable Uel........................................... : Not Appl icable EXTINGUISHING MEDIA..............: Water Spray. SPECIAL FIRE FIGHTING PROCEOURES/UNUSUAl FIRE OR EXPLOSION HAZARDS: If involved in a fire, wear self-contained breathing apparatus and stay up wind. V. HUMAN HEALTH DATA PRIMARY ROUTE(S) OF ENTRY......................................... : Dermal contact and inhalation of the product are the primary routes of entry. Inhalation of aerosol dunr spray application of the product as part of its end u is another potential route of entry. HUMAN EFFECTS ANO SYMPTOMS OF OVEREXPOSURE: ACUTE........................................... : The active Ingredient in this product has low toxicity and Mo specific systemic symptoms of overexposure are known to occur in humans. Moderate eye or skin irritation may occur from contact with the powder or spray mixture. Paresthesia (a tingling or burning sensation on the surface of the skin) nay also result from skin contact. This Is a frequently reported symptom of overexposure to synthetic pyrethroids and normally subsides without treatment within 24 hours. Allergic skin reactions may also occur In some susceptible individuals. Mucous membrane irritation Involving the nose, throat and upper respiratory tract may occur from inhalation of aerosols during end use o: the product such as spray application. Product Code: 021642 Page 2 of l 4S 6 4 S' CHRONIC Based on animal studies no adverse effects or symptoms would be expected from chronic exposure to the active ingredient in this product during normal use. MEDICAL CONDI!IONS AGGRAVATE BY EXPOSURE.: Nj specific medical conditions are known which may he aggravated by exposure to the active Ingredient in this product. Although, as with all materials which can cause upper respiratory tract irritation, persons with a history of asthma, emphysema, of hyperreactive airways disease may be more susceptible to overexposure. CARCINOGENICITY: EXPOSURE LIMITS: OSHA PEL............................... : ACGIM TlV............................. NTP: Not Listed I ARC: Not Listed OSHA: Not Listed Not Established Not Estahl 1 shed VI. EYE CONTACT............................. EMERGENCY fc FIRST AID PROCEDURES aHold eyelids open and flush with steady, gentle stream n? water for 15 minutes. Get medical attention. SKIN CONTACT........................... Warh skin iiwediatel/ with soap and warm water. Get rciical attention if irritation persists. INC! MION................................. If inyociion Is suspected, call a physician or poison control center. If medical assistance cannot be given immediately, induce vomiting and get to a hospital. To induce vomiting, administer 1 or Z glasses of water and stick finger down throat. Repeat until vomitus is clear. Go not attempt to give anything by mouth to an uncon scious or convulsing person. INHALATION............................... : If a person is overcome by excessive exposures to dusts or aerosols of this material, remove to fresh air cr uncontaminated area. If not breathing, give artificial respiration, preferably mouth-to-mouth. Get medical attention as soon as possible. NOTE TO physician................: No specific antidote is available. Treat poisoning victims symptomatically. Product Code: 0216*2 Page 3 of 7 SAL 000007084 VII. EMPLOYEE PROTECTION RECOMMENDATIONS EYE PROTECTION...................... : Goggles should be used when needed to prevent dust or spray mixture from getting into the eyes. SKIN PROTECTION.....................*. Avoid skin contact. Use chemical-resistant gloves and additional protective clothing when needed to prevent dermal exposure. RESPIRATORY PROTECTION...: Under normal handling conditions no respiratory protec tion is needed. However, If needed to prevent respiratory irritation, a respirator approved for dusts and mist by NIQSH may be used. VENTILATION............................. : Control airborne concentrations of TYCOft 50 DF through the use of general and local exhaust ventilation where needed. OTHER........................................... : Clean water should be available for washing in case of eye or skin contamination. Educate and train employees in safe use of the product. Follow all label instruc tions. Launder clothing after use. Wash thorougnly after handl ing. VIII. REACTIVITY DATA STABILITY................................... : POLYMERIZATION........................: INCOMPATIBILITY I MATERIALS TO AVOID)...: HAZARDOUS DECOMPOSITION PRODUCTS................................. : Stable under normal use conditions Will not occur Alkaline media Not Established IX. SPILL QR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED: Isolate area. Avoid breathing dusts and skin contact. Use recoimended protective equipment while carefully sweeping up and place in covered container for re-use if possible. Scrub contaminated area with soap and water. Repeat and rinse with water. Prevent contamination of streams, sewers, or other waterways. CERCIA (SUPfRFUNO) REPORTABLE QUANTITY: No components are listed. WASTE DISPOSAL METHOD: Follow all federal, state and local regulations. Bury material in EPA-approved landfill or but in an inefnerator approved for pesticide destruction. Empty containers must be handled with care due to product residue. RCRA STATUS: This product Is not a hazardous waste under RCRA. Product Code: 02164? Page 4 of 2 GS 643 5UPERFUND AMENDMENT AND REAUTHORIZATION ACT (SARA), TITLE III: Section 302 Extremely Hazardous Substances: No Components Listed Section 313 - Toxic Chemicals: No Components Listed X. SPECIAL PRECAUTIONS fc STORAGE DATA STORAGE TEMPERATURE w (MIN./MAX-)........................: None/30-day average not to exceed 100 F. SPECIAL SENSITIVITY (HEAT, LIGHT, MOISTURE): Heat, moisture PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING: Store in a cool, dry area designated specifically for pesticides. Do not store near any material intended for use or consumption by humans or animals. XI. SHIPPING DATA D.O.T. SHIPPING NAME.........: TECHNICAL SHIPPING NAME..: 0.0.T. HAZARD CLASSIFICATION...................: UN/NA NO................................... REPORTABLE QUANTITY...........: D.O.T. LABELS REQUIRED...: D.O.T. PlACAi'.DS..................... : FRT. CLASS BULK..................... : FRT. CLASS PKG....................... : Not Regulated Cyfluthnn Not Applicable Not Applicable None None None Insecticide, Agricultural Insecticide, Agricultural N.0.J., 0/T Liquid N.O.I., 0/T Liquid XII. ANIKAL TOXICITY ORAL, LDLO Male Rats (fasted): 3084 mg/kg Female Rats (fasted): 1733 mg/kg DERMAL, LDSO Male and female Rabbits (24 hr$.): >2000 mg/kg INHALATION, LCSO................. : Male and Female Rats (4 hrs.): >1.180 mg/L (analytical);>12.052 rrg/L (nominal). Male and Female Rats (1 hr.}:>24 ng/l (extrapolated from nominal value). EYE EFFECTS............................ : Fabdit (no wash) - Transient primary eye irritant with all effects being reversible by Oay 7 after application. SAt 000007065 Product Code: 021642 Page 5 of l SKIN EFFECTS........................... : Rabbits (4 hrs.) - Mild primary dermal irritant. SENSITIZATION.........................: Male Guinea Pig (Buehler) - no evidence of inducing delayed dermal sensitization. SUBCHRONK/CHROHIC TOXICin No studies have been conducted on this product as formulated. In a subchronic inhalation toxicity study with the active ingredient, rats were exposed 6 hours per day for 5 days per.week for 13 weeks. The rats which were exposed to 0.09 mg active ingredient/nr air tolerated the treatment without ill effect. A 3-month feeding study indicated that rats can tolerate dietary concentrations up to and including 100 ppm technical material without ill effects. In chronic feeding studies on the active ingredient, NOELs (no-effect levels) of 200 ppm, and 160 ppm were obtained for nice, rats and dogs, respectively. OTHER Carcinooenicitr............: The active ingredient was tested for carcinogenicity in feeding studies using rats and mice. Dietary levels up to and including 450 ppm in rats and SOO ppm in mice were employed in these studies. These studies revealed no evidence of carcinogenic potential for the active ingredient. Teratogenicity..............: Gavage studies with the active ingredient using rats have shown maternal toxicity at 10 mg/kg body weight, but no embryotoxicity or teratogenicity at levels up to and Including 30 mg/kg body weight. When rabbits were subjected to the same testing, maternal toxicity was evidenced at 15 mg/kg, but no embryotoxic or teratogenic effects were seen at levels up to and including 45mg/kg body weights. Reproduction................ : A reproduction study in which rats were fed the active ingredient in their diet revealed no detrimental effects on reproduction at a level of SO ppm. Levels of 150 ppm and above produced overt toxicity in the parental animals. At these toxic levels, effects including reduced litter size and reduced body weights in pups, were observed. N,?Nr.otnx.lcJlX..............: Studies which have been done utilizing the active ingredient in hens have indicated that at extremely high dose levels (5000 mg/kg), very minimal to minimal nerve damage occurs. When rats were exposed to 40 or 80 mg AJ/kg/day for 14 days and then observed for 3 months, minimal nerve effects were seen immediately after dosing, At 3 months, no effects were observed. Studies which hive been done that are more relevant to field exposure (dermal and Inhalation.exposure) were uniformly negative. M-iiUqgnigity................ : In vitro and In vivo mutagenesis data exist an the technical material, the vast majority of wnich are negative. Product Code: 021642 Page 6 of l GS 643 ftflUAUC/ftyfllH toxicity Data exist only on the active Ingredient. They include: Ltbu - nr. [static)............................. LC50 - 96 hr. (static)............................. LC50 - 48 hr. (static)............................. 8-day Dietary LC50 (Bobwhite Quail).. 8-day Dietary LC (Mallard Ducks)........ Oral LD50 IBobwhite Quail)..................... 1.5 ppb (Bluegill) 2.914 ppb (Rainbow Trout) 0.14 ppb (Oaohnia maonal >2000 ppm >5000 ppm >5000 mg/kg XIII. DOCUMENTATION REASON FOR ISSUE.................: APPROVED BY............................: TITLE........................................ : To add SARA Title III Data and NFPA 704M Data and to revise the Vapor Pressure Value William J. Brinkman Industrial Hygiene Manager SAL 0 0 0 0 0 7 0 8 6 Product Code: 021642 Page 7 of l i I MATERIAL SAFETY DATA SHEET 3 Id Americas Inc. 001206 Wilmington. Delaware 19697 Phone (302) 575-3000 (24 hours) ;ecTIOW 1 MWrt t HA2A&D tumwr_______ __ __ ___________ Perm No.: 4104MC) Data: 03/12/M . ' Material name: ^fALOMP-OgPc>d*nticldt Balt Pack < r-* 639 Hazard sunoary (as defined by OSHA Hazard Communication Standard, 29 CPI 1919.1200): Physical hazards: None Health hazards: Harmful (The active ingredient is designed to cause bleeding after repeated ingestion) Bead the entire KSDS for .gor thofoysh ,Y#lwtioo of th hirdi. SECTION 2 INGREDIENTS Brodlfacoun (CAS 55073-10-0) Cereal formulation 1%1 (0.0051 11 11 TLV (ACCIH) Mot Usttd 11 ______________________________ __________ 1____________ Ingredients not precisely identified are proprietary or nonhazardous. All ingredients appear on the EPA TSCA Inventory, Values are not product specifications, gt * greater than. It less than, ca approximately S IOK 3 PHYSICAL DATA rolling point: 228-230*C (Brodlfacoum) v*por pressure (n&Hg at 20*0: Negligible ?r density (air 1): Not applicable liability in water: Insoluble pH: No data Bulk density: 38-42 lbs./cu.ft. \ volatile by volume: Negligible Appearance and odor: Green pellets with faint odor SECTION 4 FIRE AND EXPLOSION HAZARD DATA Plash point (and method): Not applicable Autolgnltlon temp.: No deta Flammable Halts (STP): Not applicable Extinguishing media: Vater fog, foes, carbon dioxide, dry cheslcal, ha Ion 1211. Special fire fighting protective equipment: Self-contained breathing apparatus with full facepiece and protective clothing. Unusual fire and explosion hazards: None known. SECTION 5 REACTIVITY DATA____________ tability: Stable under normal conditions. 000007087 SAL G S 6 89 material safetx data sheet (continued) ... ... -m,~rr SECTION S REACTIVITY DATA (continued)_________________________________________ Incompatibility (materials to avoid): None known. Hazardous decomposition products: combustion products: carbon dioxide, carbon monoxide. Hazardous polymerization: will not occur. SECTION 6 HEALTH HA2ARP ASSESSMENT_________ General: No toxicity data are available on this preparation; information on its active components Is used for the health hazard assessment. Ingestion: The acute oral LDjq in rat is probably above 5 g/kg. lelatlve to other materials* single dose of this product Is practically nontoxic by Ingestion, Hodge, H.C. and Sterner, J.H., American industrial Hyglena Association Quarterly, 10:4* 93* Dec. 1949. Eye contact: No Irritation Is likely to develop following contact with huaan eyes. Skin contact: No Irritation is likely to develop following contact with hisan skin. Skin absorption: Rat and rabbit acute dermal LD50 of 0.25A liquid concentrate Is above 5 g/kg. Systeaically toxic concentrations are unlikely to be absorbed through the skin In man. Inhalation: No toxic effects are known to to be associated with Inhalation of dust from this material. Other effects of overexposure: Effects are those of anticoagulant overdosage: reduced blood clotting ability with spontaneous bleeding In various body organs. Body accumulation Is likely to result from repeated exposures to Brodlfacoum since Its half-life Is estimated to be 120 days. First aid procedures: Sk^n: Wash material off the skin with copious amounts of soap and water. Xf redness, itching or a burning ssnsatlon develops* get medical attention. Eves: Immediately flush with copious amounts of water for et least IS minutes. If redness, itching or a burning sansatlon develops, have eyes examined and treated by medical personnal. ---cent Inued--- SAL 000007068 a.-aial wrm data sheet (continued) G S 6 39 t * t HEALTH HMMD KSSESSHBHT tCgttlWJ First eld procedures (continued): ynoestlon: Give one or two glasses of water to drink. If gastrointestinal symptoms develop, consult medical personnel. (Sever give anything by south to on unconscious person.) inhalation: temove victim to fresh sir. If cough or other respiratory symptom* develop* consult medical personnel. note to Physician: vitamin Kj la entldotsl st doses of 10-20 mg combined with blood (or plasms) transfusions as cates of severe hemorrhage. Treatment should be continued until prothrombin tines have stabilised at normal levels. Naif life of brodlfaco^B it estimated to be 120 days In animal work. ECTION 7 SPILL Oft LEAK PROCEDURES______________________________ Steps to be taken In case material is released or spilled: Sweep up and recover or mix material with moist absorbent and shovel Into waste container. Disposal aethod: This material is toxic to fish and wildlife. Do not contaminate waterways by cleaning of equipment or by disposal of wastes. Untreated effluent should not be discharged where it will drain into lakes* streams, or ponds. Discarded product Is not a hazardous waste under ACRA, 40 CFR 261. container disposal: Puncture or otherwise destroy empty container before disposal. U.ION S SPECIAL PROTECTION INFORMATION__________________________ Tiv* or suggested control value: No TLV assigned. Minimize exposure In accordance with good hygiene practice. controls exposures to brodlfecoum (active Ingredient) to below 2 ug/m3. XCIA jVtntllatlon: As needed to control exposures. Respiratory protection (specify type): If needed, use KSHA-NIOSH approved respirator for pesticides. Protective clothing: Impervious gloves and apron. PVC has been shown to be impervious to brodlfacous. Eye protection: Safety glasses with side shields. Other protective equipment: Eyewash station In work area. SAL 000007089 GS6 39 MATERIAL SAFETY DATA SHEET (continued) -- -- -___ - SECTION 9 SPECIAL PRECAUTIONS OR OTHER CXWEWTS' . precautions to be taken In handling or storing: Store In cool dry ere* away fro products with strong odors. Keep In *n ere* suitable for pesticide storage. Do not store near feed* food# or within the reach of children or pets. Prevent accunulatlon of dust. Prevent skin contact promote good personal hygiene. ?.ev. of H3508-A The lnforsatlon herein is given in good faith hut no warranty# expressed or laplied# is Bade. ( sal 00709o MATERIAL SAFETY DATA SHEET ICI Americas Inc. Wilmington. Delaware 19897 Phone 13021 575-3000 124 hours! ACTION 1 MAME 6 HAZARD SUMMARY Date: 002116 Form Mo.: 4696h(A> 07/25/66 GS6 Hazard summary (as defined by OSHA Hazard Communication Standard. 29 CFR 1910.1200): Physical hazards: None Health hazards: Inhalation (TLV), irritant (skin, eye), skin sensitizer, harmful (respiratory) Read the entire USDS for a more thorough evaluation of the hazards. ECTION 2 INGREDIENTS Cypermethrin (CAS 52315-07-8) calcium silicate (CAS 1344-95-2) Amorphous silica (CAS 7631-86-9) Other ingredients 1\ 1 *0 1 1 1 1 TLV (ACGIH) 1 Not listed 1 10 mg/m^ 1 10 mg/m3 1 Not listed 11 1 ingredients not precisely identified are proprietary or nonhazardous. This 1 material is exempt from TSCA registration. Values are not product specifications, gt a greater than,-It * less than, ca * approximately ACTION 3 PHYSICAL DATA___________________________________________ Boiling point: Not applicable vapor pressure (omHg at 20*C): No data Vapor density (air * 1): No data . Solubility in water: Dispersible pH: 8.6 Specific gravity: No data \ Volatile by volume: Negligible Appearance and odor: Off-white, slightly aromatic powder SECTION A FIRE AND EXPLOSION HAZARD DATA Flash point (and method): Not applicable Autoignition temp.: No data Flammable limits (STP); Not applicable SAL 0Q00Q7091 Extinguishing media: Water fog, foam, carbon dioxide, dry chemical, halon 1211. Special fire fighting protective equipment: Self-contained breathing apparatus with full facepiece and protective clothing. Unusual fire and explosion hazards: None known SECTION 5 REACTIVITY DATA_____________ Stability: Stable under normal conditions. GS640 MATERIAL SAFETY DATA SHEET (continued) _ __ SECTION 5 REACTIVITY DATA (continued)_______________ Incompatibility (materials to avoid); Oxidizing agents DEMON* 40VP Hazardous decomposition products: Combustion products: Carbon dioxide, carbon monoxide, nitrogen oxides, annonla, halogen, halogen acids, possible trace amounts of carbonyl halide. Hazardous polymerization: Will not occur. SECTION 6 HEALTH HAZARD ASSESSMENT________________________________________________ General: The health hazard assessment is based on acute toxicity screening studies. Ingestion: The acute oral LD^q in rat is l.S g/kg. Relative to other materials, a single dose of this product is slightly toxic by Ingestion, Hodge, H.C. and Sterner, J.H., American Industrial Hygiene Association Quarterly, 1Q:4, 93, Dec. 1949. Eye contact: This material Is moderately Irritating In a rabbit eye Irritation test. It will probably irritate human eyes. Skin contact: This material is mildly irritating in a rabbit dermal irritation test. Irritation will probably develop following repeated and/or prolonged contact with human skin. This material is a skin sensitizer in animal testing. Dermatitis and skin sensitization can develop after repeated and/or prolonged contact with human skin. skin absorption: The acute dermal LD50 in rabbit is above 2.0 g/kg. Systeralcally toxic concentrations are unlikely to be absorbed through the skin In man. Inhalation: No toxic effects are known to to be associated with inhalation of dust from this material. Other effects of overexposure: Nausea, vomiting with colicky pain, tenesmus, diarrhea, convulsions, unconsciousness, and respiratory failure can develop following ingestion of this product. Sal 0000709a VTERIAL SAFETY DATA SHEET (continued) $8640 _ ' DEMON# 40 WP Ft M 6 HEALTH HAZARD ASSESSMENT (continued)_______________________ ____________________________ First aid procedures: Skin: Wash material off the skin with copious amounts of soap and water. If redness, itching or a burning sensation develops, get medical attention, wash contaminated clothing and decontaminate footwear before reuse. Eves: Immediately flush with copious amounts of water for at least 15 minutes. If redness, itching or a burning sensation develops, have eyes examined and treated by medical personnel. Ingestion: Give one or two glasses of water to drink. If gastrointestinal symptoms develop, consult medical personnel. (Never give anything by mouth to an unconscious person.) Inhalation: Remove victim to fresh air. If cough or other respiratory symptoms develop, consult medical personnel. CTION 1 SPILL OR LEAK PROCEDURES___________________________ ______________________________ Steps to be taken in case material is released or spilled: Wear skin, eye and respiratory protection during cleanup. Keep out of sewers and drains. Sweep up and recover or mix material with moist absorbent and shovel into waste container. Disposal method: his material is extremely toxic to fish. Do not contaminate waterways by cleaning of equipment or by disposal of wastes. Untreated effluent should not be discharged sere it will drain into lakes, streams or ponds. Container disposal: Bopty container retains product residue, observe all hazard precautions. Do not distribute, make available, furnish or reuse empty container except for storage and shipment of original product. Remove all hazardous residue from container using appropriate solvents (e.g., triple rinsing). Then offer for recycling/ reconditioning or puncture or otherwise destroy empty container and dispose of in facility permitted for nonhazardous waste. :CTION 8 SPECIAL PROTECTION INFORMATION TLV* or suggested control value: No TLV assigned. Minimize exposure in accordance with good hygiene practice. 1CI operates its facilities such that employee exposure to this material Is kept below 0.5 mg/m^ 8-hour TVA. Ventilation: Use local exhaust to keep exposures to a minimum. Respiratory protection (specify type): If needed, use MSHA-NIOSH approved respirator for pesticides. tective clothing: Impervious gloves. Depending upon conditions of use, additional protection may be -squired such as apron, arm covers or full body suit. Eye protection: Chemical tight goggles. sal 000007093 <r S 6 40 MATERIAL SAFETY DATA SHEET (continued) SECTION 8 SPECIAL PROTECTION INFORMATION (continued) Other protective equipment: Eyewash station and safety shcwer in work area. DEMON* 40 WP 3ECTION 9 SPECIAL PRECAUTIONS OR OTHER COMMENTS_______________________________________________________ Precautions to be taken in handling or storing: Prevent skin and eye contact. Observe TLV limitations. A sensitized Individual should not be exposed to the product which caused the sensitization. Do not store near feed or food. The information herein Is given in good faith but no warranty, expressed or implied, is made. \ r SAL 000070 94 y^ n \ MATERIAL. SAFE n DATA b'Ht!E T ktAlT RLOCJ S (KANUT .liniLK> v M .1 p` ID: .1`,/O'J t. 7 4 n ''LM^E. FT ST l t'NTROL. GULF' STREET ,*. 1. C l ES L A 7060 3 - EG :0 I _ ION OF S 6 41 UKJ'tK Ml): E'kOh nii : ; , : ,'t- o F-0 Oi m; i;- o IMC, ion'1 MOkTOM ClCG. Oi.OTIi. L, i; ;1 !* s r:-KAForOi fy- tSTANCE Umu. or NO CM-- r; GcAi.n f..-,! . - > -r.-M- -' . 1 :-mvrpn' \ i ': 7- 1-M ` 1; l'r-,N ^ L N > - l-TC.t V-', i Z :i. 1 ; ,r ` : K < r: L. - LA I UN S 0 A j. 1 rC.Gl.L S names ' G f N 01: 'I uR: 0 iPHAC i i n i; ;G < 7 nUAL'Ll i'_ 3 , - 1 MPANDJ. ONE > i.joi-' n.H' JLA: MIXTURE . k; ; 1 K A f 1 R M (Mi f'fi Ht'ALTH: 3. r f k*~ ; n Ktv.rriy'n rs o Ofl'-Cl AL : NOME / 04 C. K1 1 L K` 1 A DA I E J. bol/fc D: '-> / Go SUPL KLL: Nf.iML h Al. AK'D P A f i liii Si- AL t. 0 " i'l i N 1 P A L - l. L K 1 U < ` 1 - sl.Ioh r o=nt'v>t n-. 2-noLti kh \ E HAZARD!)U 1:5 1NGRb'It3!EH fS~ C.C-TsPC'.Ot NT D 1 EHACINOME :Ml RTS CAS NO. 42721-99-3 fn.F'GSURL LinliS, K.` n OSHA AClilH QlHt.K X PEL VlO Linn 0. OOP 2 NOME NONfc. NOME DAL AMI.E NONE NOnL NunE HhZhKV MO Mb! M'OML -------------------------------------------------------------------physical properties Cl 1 iC ... iP, F'CCmT, I*i L. G F : MO DATA GAf-'OR PRESSURE, MM Hb/ CC1 /fc.G C - FOUND PCC:nn DCS v : MO DA i A >' OuMl vnOR LfL.rrCIT? *. AIK= j. n \ f. R-3 > : MO DAY * r CM'm K ': JL. t.; t' ; J. Or I RATE &)J 7 i'-r i 1 m ` . L'C. i S , :17 i-! Y 1 SR . i !- 'Pi SC , . 'i ,, t I.: ~ 'i mO DA t A Found NO' wcm i- i... U m 1 . Ciu. :>l' i.t - i T (. r0 ' A L F, i TE.M T I'.: -li . j. 1111 . ; L * : ,) : r > ooP 1 , 1,, j P ; ,'n lH.;` Lp-'i't: riM'D i' !. A 1 ! I.) 1 ' 1 ('1 1 ,, j ; *, CH v '.. 11 t',-.' t: \ !- 1 L: -j J.C.. C -<, l "i,'rl. . ' , 1 Ai'i': i fi MEDIA? PL. f CASH S'-... Ml'H Or Coa- A-:-..,- r , >} -> C < 3 l : *' O 2' J 7 ,Mc|0 3 F C:ll CO.b>i *Vl</i v'J ;M'03 i t. : :ANC> SAL 000007095 GS6411 MATERIAL SAFETY DATA SHEET r 7, PAJ.T BLOCKS < *-'1. ANUT BUTTER) PU 4. REVISION OF: 04-27-fafc 1--R. REMOVE CONTAMINATED CLOTHING AND SHOES; WASH BEFORE KtUSE. GtV ' It ICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING. .SVAL l OWFIi: IF CONSCIOUS, IMHEDIA1 ELY INDUCE VOMITING BY GIVING 2 ASSF;-. OF WATER AMO STICKING A FINGER DOWN THE THROAT. Gb? IMMEDIATE MCAL AT IE NT I ON. HO NOT GIVE ANYTHING Hr MOUI'H TO AN UNCONSCIOUS ' CONVULSING PERSON. ORAL AND INTRAVENOUS AL>MINISTRATION OF VITAMIN K HL SOLUBLE) AND BLOOD TRANSFUSION MAY ALSO BE NECESSARY. --------------------------------------------------- HEALTH HAZARD INFORMATION---------------------------------------------------------- vlMARY ROUTES OF EXPOSURES SWALLOWED IONS AND SYMPTOMS OF EXPOSURE INHALATIONS NONE CURRENTLY KNOUN. EYE CONTACT: NONE CURRENTLY KNOWN, SKIN CONTACTS NONE CURRENTLY KNOWN. SWALLOUEDs NORMAL REACTION TO OVERDOSE OF ANTICOAGULANT. INITIAL 'tMPTOMS MAY include back pain, abdominal PAIN, VOMITING, A1 TACKS OF NOSE LEED AND GUM BLEEDING, PALLOR AND WEAKNESS. HF ONI C EFFECTS OF EXPOSURE: NO SPECIFIC INF ORMAT ION AVAILABLE. F DI CAL CONDITIONS GENERAL!, r AGGRAVATED BY EXPOSURE: HOPE P'EPOkTED. --------'------------- -------------------------- ----------- TOXICITY DA 1 A------------------------------------------------------------------------- k, \ : Pa;' i.. CEO = l 00 CO-CO (BAIT BlOCK? - 7:. `-j :; 0 - * ; o < v i - ... i* 1 h r \ a c . j n c ... > LH*-! A j pnp'.a s' ; \;r : <-0 Da i'A P'J'.'NC * 'O:! 1.1 TY : ih;S r:A Il>; IS r;Of C. l? ;; ` ; l E :i Tu L;: c ; NOGFN ! K _ HAT 1 COAL TOXIC OL GO- r rRGGPAM, ' `-'E Ir-;; ? iv A ! j UMAt. A o'.. HI, F l'P -'LEAF CH ON CANCLh', UP THE OcCUFAT !JNAL bAl-E f AND HEALTH A'.!ir. IN 1ST KA I I UN -K DATA: NONE PERSONAL PROTECTION VENTILATION: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MINIMIZING DUST EMISSIONS AT THE POINT OF USE. RESPIRATORY PROTECTION: IF USE CONDITIONS GENERATE DUSTS, WbAR A NIOSH- APPROVED RESPIRATOR APPROPRIATE FOR THOSE EMISSION LEVELS. APPROPRIATE RESPIRATORS MAY BE A FULL FACEPIECE OR A HALF MASK AIR-PURIFYING CART RIDGE RESPIRATOR WITH PARTICULATE. FILTERS, A SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-AIR RESPIRATOR. EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS. IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING UiIH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN CtE INJURY. PROTECTIVE CLOTHING: LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES. RUBBER CLOVES, AND RUBBER APRON, t' 'PER PROTECTIVE MEASURES s AN EYEWASH AND SAFETY SHOWER SHOULD BE KBY AND READY FUR USE. --------------------FJRE AND EXPLOSION INFORMAfION----------------------------------------------------- , i'l_G F : c'DMC r:;/f h:.j it U'-'-Eli: NtjfSE ^ ''c'.'i . h i 'l/' '"! ;'3 A: USE. '-'Ml i R , DRt t ammabl L l. j ni i s In air, LOWER : _ K JUE _ UHPER : N-JNt J LhL , L CL-', jR ALi_UHUL S/"- 00007096 i; ! I- r : ` - . . 4*31 MATERIAL SAFETY DATA SHEET PG 3 A N'S BAIT BLOCKS (PEANUT BUTTER) REVISION OF:04-2/-88 Cr S 6 41 F,, f A' FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD LEAR SELF- ON! AIMED BREATHING APPARAIUS AND FULL PROTECTIVE ClOIHING. USE UAIEft hrat TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. NOS UAL AIRE Am I.i EXPLOSION HAZARDS: HONE. --------------------------------------------------------- HAZARDOUS REAC TIVI T t------------------------------------------------------------- 1 ARIL IIY: STABLE POLYMER i in i 3. UN w. -.01 OCL.Uk ONDl'T i ONS TO AVOID NONE ATERIALS U) AVOID: KEEP WATER AND MOIST AIR OUT OF THE CONTAINER SAZAkDOUS DL'COMPOSi I I ON PRGDUC1 S: MAt LIBERATE L Arr' I'M MONO*, IDE UK ARBC'iN DIOXIDE. SPILL, LEAK, AND DISPOSAL PROCEDURES CTl'ON 10 TAKE FOR SPILLS OR LfcAKc.: WL AR PROTECTIVE EQUIPMENT 1 nCLUD ii-ii 'UDDER BOOTS, RUBBER GLOVES, RUDDER APRON, AND A SELF-CONTAINED PM ATH1NG APPARATUS IN THE PRESSURE DEMAND MODE OK A SUPPLiCD-AIK -ESPIRATOR. IF THE SPILL OR LEAK IS SMALL, A FULL FACEPIECE AIR- UPIFYING CARTRIDGE RESF'IRA\OR EQUIPPED UllH PARTICULATE FILTERS MAY Eh ATISFACTORr. IN ANY EVENT, ALLAYS LEAR EYE PROTECTION. FOR SNAIL PILLS, SLEEP UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FUR AROE SPILLS, SHOVEL INTO DOT-APPROVED UASTE CONTAINERS. KEEP OUT Of EWERS, STORM DRAINS, SURFACE WATERS, AnLi SOIL. Cf--PLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPuh: TING, HANDLING" AND DISPOSAL OF UASTE. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED ir" 'LEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATtKlAL. d ULT APPROPRIATE FEDERAL, STATE AND LOCAL. REGULATORY AGENCIES Tu ASlERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER UASTE DISPOSAL, AS ADOVt. SPECIAL PRECAUTIONS STORAGE AND HANDLING PRECAUTIONS: STORE IN A COOL, DRY, UELL-VEN\lLAlfc i i PLACE AUAY FROM INCOMPATIBLE MATERIALS. KEEP BAGS OR FIBER DRUMS DRY AT ALL TIMES. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. REPAIR AND MAINTENANCE PRECAUTIONS: NONE, OTHER PRECAUTIONS : CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, UJ'il kF TA]N PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD uaRmIM&S AmD hand IF EMPTY CONTAINERS a S If THE f Ufc RE F ULL . *-' r A! D:`Ui.'LA :: F M;w] .-`f- JNAL M r I Lr.L Hi.;UkU , 11*' 1 {' ---------- NO rILL-------------- k :.j... t k s .1 P i I r V r I LJAI-KS ROGLPS TNG. ("VU.\K*' ) LXPRlrbSLY D 1 ELL. AI riR ALL tAfh'tSt t k IMPLIED WARRANTIES OK MERCHANTABILITY AND FITNESS Fi>* A PAPTiC i 'LAK ?' OPPOSE , WITH RFSkeCT TO THE PRODUCT OR INFORMAT ION PROVIDED Hi h,LlN. * ? ' 1 INFORMATION APF'EARTNG HEREIN IS BASED UPON DA f A OBTAINED FROM THE MjF ACT URfc R AND/OR RECGGNI2 EL* ILC-HNICAL SOURCES. WHIlE l HE INFOkMA{ , OH IS BELIEVED TO BE ACCURATE, VUS-K MAKES NO REPRESENT A TIONS AS TO ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE AkE BEYOND Vu&R'S CON- AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER JR OUN OPERATING CONDITIONS TO DETERMINE WHETHER I HE PRODUCT IS SUITABLE FUR THEIR PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS UF THEIR USE, HANDLING, AND DISPOSAL OF THE PRUDUCT, OR FROM THE RUBlICA- h ROD: 050.365Z6 14:42:02 17 NOV 19UU CUST: 45700174 INVOICE: 4Sy^j7 ::*6 SAL 00007097 GS641 MATERIAL SAFE IY HATA SHEET AiON'S BAIT BLOCKS (PEANUT BUTTER) Pb 4 REVISION 0F:04-27-8S ION OR USE OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN. THIS fMFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT -ELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANt OTHER ROCESS- ** END OF MS DS **** ROD : 05036526 14:42:02 17 NOV 1V8S CUSTs 45700174 INVOICE: 459507366 SAL 000007098 168 MATERIAL SAFETY DATA SHEET AEROSOL CB PURGE CB-80 SHIP TO: 45700174 MCKENZIE PE5T CONTROL 717 GULF STREET LAKE CHARLES LA 70601-0635 PC 1 REVISION OF:02-14-89 GS 642 ORDER NO: 450503490 PROD NO: 05045Q66 VAN WATERS & ROGERS INC. 16C0 NORTON BLDG. SEATTLE, WA 93104-1564 ------------------------------------------------------- EMERGENCY ASSISTANCE------------------------------------------------------------------ FOP EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC <800) 424-9300. -------------------------------------------FOR PRODUCT AND SALES INFORMATION---------------------------------------------- CONiACT YOUR LOCAL VAN LATER? S* ROGERS BRANCH OFFICE -----------------------------------------------------PRODUCT I DENT I r I CAT I on--------------------------------------------------------------- PRODUCT NAME: VW:-.n. CB--80 AER05uL ?N5ECT KILLER ERA .REG. NO. 9444-96-550 Mi-1 ON NAMES/SYNONYMS: NONE CAS NO. : UNAlib I GN'ED VW*R CODE: P4463 FORMULA: MIXTURE HAZARD RATING <NFrA HEALTH: 1 FIRE: 0 REACTIVITY: 0 SPECIAL: NONE 704 CRITERIA) DATE ISSUED: 12/58 SUPERCEDES: 03/88 HAZARD RATING SCALE: 0=fiIN JMAL 3=SERIOUS 1"SLIGHT 4=SEVERE 2=H0DERATE HAZARDOUS INGREDIENTS- COMPONENT PYRENTHRINS ODORLESS MINERAL PROFANE CAS NO. 800-34-7 64742-4B-9 74-98-6 % UNK UNK UNK EXPOSURE LIMITS, OSHA ACG-IH PEL TLV 5 500 NONE 5 100 1000 MG/M3 OTHER LIMIT HAZARD NONE NONE NONE TOXIC OSHA/ACGIH LIST FLAMMABLE PHYSICAL PROPERTIES- BOILING POINT, DEG F: NOT VAPOR PRESSURE, MM HG/20 DEG C: 3362 APPLICABLE BELTING POINT, DEG F: NOT APPLICABLE VAPOR DENSITY <AJR=1): NOT APPLICABLE SPEC IFIC^GRAVITV^ WATERED: 1.20 WATER SOLUBILITY, V.: INSOLUBLE iP P -- AP ANC u. AND ODD R - EVAPOPAT 1 ?_>N P A^E ( BUTYL ACETATE= 1 ' Nfl DATA ,r'?v DR r' FOG WITH CHARACTERISTIC PYRE7HRIN ODOR IN FOUND -ERCSuL D I SPENSER SAL 000007099 - ;NHA1_EC: Rc.MO-'E_TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION Jr NOT 'E-THIN'l- GET JMMEDIATt. MEDICAL A : 7F,k:ttr.?g CASE OF EYE CONTACT; IMMEDIATELY FLUSH YES WITH LOTS OF RUNNING WaTc.R FOR 15 MINUTES, LIFTING The UPPER AN LOWER EYE5-1D3 OCCASIONALLY. OD; 0504 5366 10.03:4; '4 Q9 vA'ST 457001 .NVOICfc GS 642+ 468 MATERIAL SAFETY DATA SHEET 'ROSOL CS PURGE CB-BO PG 2 REVISION OF: 02-14-89 IT IMMEDIATE MEDICAL ATTENTION. N CASE CF SKIN CONTACT: IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND '-TER REMOVE CONTAMINATED CLOTHINv AND SHOES; WASH BEFORE REUSE. GET DICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING. ~ SWALLOWED: PRODUCT IS A GAS OR SPRAY AND CANNOT BE SWALLOWED. ----------------------------------------------------- HEALTH HAZARD INFORMATION-------------------------------------------------------- RJMARt ROUTES OF EXPOSURE: INHALATION IGNS AND SYMPTOMS OF EXPOSURE INHALATION; MAY CAUSE HEADACHE.- NAUSEA- VOMITING. EYE CONTACT: NONE CURRENTLY KNOWN. SKIN CONTACT: MAY CAUSE DERMATITIS- SWALLOWED: PRODUCT IS A GAS OR SPRAY' AND CANNOT BE SWALLOWED. CHRONIC EFFECTS OF EXPOSURE: MAY CAUSE CARBOXYHEMOGLOBINEMIA. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE; NONE REPORTED. ---------------------------------------------------------------------- TOXICITY DATA------------------------------------------------------------- Nw DATA FOUND FOR THE PRODUCT HOWEVER. FOR ITS COMPONENTS: ORAL RAT LD50 DERMAL RABBIT LD50 INHALATION RAT LC50 PYRETHRINS ODORLESS MINERAL SPIRITS METHYLENE CHLORIDE PROPANE 200 MG/KG >25 ML/KG 2. 52 G/KG NO DATA FOUND NO DATA FOUND >5 ML/KG 592 PPM/4 HRS (NO DEATH) >4, 64 G/KG 14.400 PPM/7 HRS -NO DATA FOUND- CARCINOGENICITY: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN BY THE NATIONAL TOXICOLOGY PROGRAM. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OTHER DATA: ME I'HYLFNE CHLORIDE HAS SEEN SHOWN TO INCREASE THE RATE 6r SPONTANEOUSLY OCCURJNG MALIGNANT TUMORS IN ONE STRAIN OF LABORATORY 4. HAZARD ALERT ISSUED BY THE STATE OF CALIFORNIA DEPARTMENT OF HEALTH SERVICES REFORTS RECENT STUDIES SHOW THAT METHYLENE CHLORIDE CAUSES r:?vCER IN LABORATORY ANIMALS. THE I ARC CARCINOGENIC DETERMINATION IS ANIMAL INDEFINITE. AN EPIDEMIOLOGICAL STUDY OF MALE HUMANS CONTINUALLY E*'POSED TO ESTIMATED TWA CONCENTRATIONS CF 30-125 PPM FOR UP TO 30 YEARS INDICATED NO INCREASE IN MORTALITY COMPARED TO THE GENERAL MALE POPULATION. IN *M . KAL BTUMS3. METHYLENE CHLORIDE HAS BEEN SHOWN NOT TO 2NTER- -CPE UI H REPRODJC7ION. EXPOSURES HAVING NO EFFECT ON THE MOTHER SHOULD EFFECT ON 7HE FETUs. iti i Cf+Lu'RIDt DID NOT CAUSE BIRTH DEFECTS IN ANIMALS.- OTHER EFFECTS WERE IN THE FETUS ONLY AT DOSES A'-iJCH CAUSED TOXIC EFFECTS >0 THt MOTHER ALTHOUGH RES*. - IS OF AMES BACTERIAL TESTS HAVE GENERALLY BEEN C5ITIVE, OVERALL THE DATA SUGGEST TO SOME SCIET1STS THAT GENOTGXIC POTENT IAL DOES NOT APPEAR TO BE A SIGNIFICANT FACTOR IN METHYLENE CHLORIDE TOXICITY ------------------------------------------------------------ PERSONAL PROTECTION-------------------------------------------- VENTILATION: GENERAL ROOM VENTILATION. RESPIRATORY PROTECTION: NONE REQUIRED. EYE PROTECTION: NONE REQUIRED. SAL 000007X00 \ 0: 03: 42 27 UUN 19e9 COST: 45700174 INVOICE: 450503490 .0 MATERIAL SAFETY DATA SHEET AEROSOL CB PURGE CB-BO PG 3 REVISION OF:OS-14-09 PROTECTIVE CLOTHING NONE REGUIRED. 6S642 OTHER PROTECTIVE MEASURES: NEARBY AND READY FOR USE. AN EYEWASH AND SAFETY SHOWER SHOULD BE FIRE AND EXPLOSION INFORMATION---------------------------------------- FLASH POINT, DEG F: NONE METHOD USED. NONE EXTINGUISHING MEDIA: USE DRY CHEMICAL, USE WATER TO FIGHT FIRE. C02, FLAMMABLE LIMITS IN AIR, X LOWER: N/D UPPER: N/D OR ALCOHOL FOAM. DO NOT SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR SELF- CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHINO. USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. UNUSUAL FIRE AND EXPLOSION HAZARDS: EXPOSURE TO TEMPERATURE ABOVE 130 DEGREES MAY CAUSE BURSTING. HAZARDOUS REACTIVITY--------- STABILITY: STABLE POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: OPEN FLAMES, WELDING ARCS, OR OTHER HIGH TEM PERATURE SOURCES WHICH MAY INDUCE THERMAL DECOMPOSITION. MATERIALS TO AVOID: ACIDS, OXIDIZING MATERIALS. k .ZARDGUS DECOMPOSITION PRODUCTS: HAr LIBERATE CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE- CHLORINE, OR PHOSGENE. -SPILL, LEAK, AND DISPOSAL PROCEDURES* XL) f-jTION "0 , AKE FOR SPILLS OR LEAKS* IF CONTAINtR BEGINS TO LEAK < THRDUG PUNCTURE, ETC. ) ALLOW I; TO DISCHARGE COMPLETELY IN A WtLL VENTILATED AR THEN DISPOSE IN A SAFE PLACE. IF SPILL OR LEAK IS INDOOR, VENTILATE AREA BY OPENING WINDOW"- AND TURNING ON rANc-. --TAY OUT OF ARc.A AS MUCH A3 POSSIBLE UNTIL CLEARED. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING, AND HANDLING AND DISPOSAL OF WASTE. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER WASTE DISPOSAL, AS ABOVE. SPECIAL PRECAUTIONS- STORAGE AND HANDLING PRECAUTIONS: STORE IN A COOL, DRY, WELL-VENTILATED FLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT PUNCTURE OR INCINERATE. REPAIR AND MAINTENANCE PRECAUTIONS: ON OR NEAR THIS CONTAINER. DO NOT CUT, GRIND, WELD, OR DRILL OTHER PRECAUTIONS CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED. WILL RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. ----------------------------------------------------PGR ADDITIONAL INFORMATION------------------------SAL 00007101 'INTACT DOUGLAS EISNER, TECHNICAL DIRECTOR- VAN WATERS Z< ROGERS INC DURING BUSINESS HOURS, PACIFIC TIME >206)447- 5911 ------------------------- .---------------------------------------------NOTICE---------------------------------------------------------------------------- AN WATERS * ROGERS INC. < "VW7R'r) EXPRESSLY DISCLAIMS ALL EXPRESS C5045866 10. 03: 4, 27 JUN 1939 COST 45700174 INVOICE: 450503490 _.e fig 6 4 24 material SAFETY data SHEET EROSOL CB PURGE C5-80 PG 4 * REVISION OF; 02-14-89 R IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR URP05E, WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN. ** LL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE 'ANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA- ICN IS BELIEVED TO BE ACCURATE/ VW-S-.R MAKES NO REPRESENTATIONS AS TO TS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND VW&R'S CONHOL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER HEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS UITA0LE FOR THEIR PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF "HEIR USE/ HANDLING/ AND DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICA- 1014 OR USE OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN. THIS NFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN. AND DOES NOT ELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER ROCESS. REVISION 12/88; EXPANDED FORM AND APPEARANCE. REVISED FIRST AID AND HAZARD OF SWALLOWING. REVISED PERSONAL PROTECTION, SPILL AND LEAK PROCEDURE AND HANDLING ADVICE. ^k ^ **** END OF MSDS *#** - p. nr.; 00045866 i r 03. a: 27 JUN 1969 OUST: 45700174 INVOICE; 450503490 SAL 000007102 CHEMICAL MANUFACTURING CO. MAM OFFICE AND PLANT: CLEVELAND. OMO 44114 OI4TRISUTION CIMTIlU/ftALIt OWlCtt: NATIONWIDE MATERIAL SAFETY DATA SHEET G S 6! 3 8 I. IDENTIFICATION StAta Scrub Lotiorirarl NfimC ClaanT - Saw toprovd A formulated lotionized jy^ akin cleaner D.O.T. Shipping Name: _______________________ Hazard data: N/A________________________ ID No, N/A Label N/A R. HAZARDOUS INGREDIENTS Material Aliphatic petroleum distillates (CAS # 64741-65-7) Silica abrasive (CAS #7631-86-9) Weight* < 50% < 10% tut - 500 ffpa None listed III. PHYSICAL DATA Bolling Point (F) 00 data Specific Gravity (Water = 1) 0,935 Volatile By Weight (%) * 80 Wright Per Gallon: (Pounds) JLi Solubility In Water appreciable ^ N/A Appearance A Odor: A viscous abrasive blue green emulsion with a mild odor. IV. FIRE A EXPLOSION HAZARD DAYA Flashpoint (F*)(Method Us*J): 126f., by t.c.c. Extinguishing Media: Foam, dry chemical or carbon Spe^Rre Fighting Procedures: NOTE: contains petroleum Explosion Hazards_ SAL 000007103 GS638 V. HEALTH HAZARD DATA Effects Of Overexposure DMCER* Harmful or fatal if swallowed. Contains petroleum distillates. Direct contact with eyes may cause irritation. FIRST AID PROCEDURES If Swallowed not induce vanitin9* Cal1 a physician iitmediately. Contains petroleum distillates. H Inhaled N/A If In Eyes: yt lwdbMy wtt ptanty of cool wvtor for at iooot IS taunt. _ If irritation persists contact a physician HOnSMn: N/A SAL 000007104  4 G S 6 38 VI. REACTIVITY DATA Stability STABLE Conditions 16 Avoid: None INCOMPATIBILITY <*.% ** Do not mix with any other chemicals,____________ ___ Hazardous Decomposition Pmducts: dermal decomposition may produce carbon dioxide and/or carbon monoxide. HA2AR00US fOLYMOBZATlOK WHX NOT OCCUR VII. SPILL OR LEAK PROCEDURES Steps To Be Taken if Material Is Released Or Spitted Soak up spill on State Oil Absorbent# sand or vermicu- lite and discard. Flush residue with plenty of water to the drain Waste Disposal Method Do not reuse empty containers for any purpose. Flush thoroughly with water# crush and discard._________________ Mom A1 StH and loot RjQuhfloni fl>9<Hlng Hath OhfiemL Sal 000007105 GS 6 38 VKI. SPECIAL PROTECTION INFORMATION cyv pwBOH m prwcvnv ^9V9V vi fv^viBwvG vi| wiv yW m m Wf wnsB PMlIni BDJHJPI PWP| piWw Respiratory Protection Ncne required________________ Ventilation _ NorTnal 3:0011___________________________ Protective Gloves Non^required Eye Protection N/A Other Protective Equipment __A_______________________ \ IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage DANGER: Harmful or fatal if swallowed. Contains' petroleum distillates. Product is combustible. Do not use near heat, sparks or open flame. Do not weld or cut empty drums, OTHER PRECAUTIONS: Do not reuse empty drums for any purpose. Destroy by crushing or return to a drum reconditioner. Reed end follow an label Erections and precaution* before using the product These product* are Intended for industrial and Institutional use only. Not Intended for household use or resale. KEEP OUT OF THE REACH OF CHILOREN. While we believe that the date contained herein I* tactual end the opinions expressed are those of qualified experts, the data are not to be taken ae warranty or representation tor which the company teaume* legal responsibOfty. They are offered solely for your consideration. Investigation, end verification. Any use of these date and Information must ba determined by the user to be In accordance with applicable Federal, State, and Local Iwrs and regulations. HEALTH AND SAFETY INFORMATION MAY 1989 (216) 861*7114 SAL 000007106 CHEMICAL MANUFACTURING CO. MAM OfFICC AMO PUNT: CLEVELAND. OHIO 44114 DISTRIBUTION CCNTCRI'IAlll OTflCCS NATIONW'OC MATERIAL SAFETY DATA SHEET I. IDENTIFICATION Stae* Scrub Lotionltad NUDE Skin Clunu - Naw Inpiovd A formulated lotionized skin cleaner D.O.T. Shipping Name: N,/A_______________________ Hazard Clata: N/A________________________ ID No. N/* Label A/A H. HAZARDOUS INGREDIENTS Material Aliphatic petroleum distillates (CAS # 64741-65-7) Silica abrasive (CAS #7631-86-9) Weight* < 50% < 10% TLV 500 ppm None listed III. PHYSICAL DATA Boiling Point (F) no Specific Gravity (Water = 1) _^935 Volatile By VWght (H) < 90 Weight Per Gallon: (Pounds) 7,8 Solubility In Water appreciable ^ N/A Appearance & Odor: A viscous abrasive blue green emulsion with a mild odor.IV. IV. FIRE & EXPLOSION HAZARD DATA Flashpoint (P) (Method Used): by TX.C. Extinguishing Media: Foam, dry chemical or carbon dioxide. Special Fire Fighting Procedures: _ NOTE: contains petroleum distillate. Unusual Fire & Explosion Hazards. None V. HEALTH HAZARD DATA Effects of Overexposure Harmful or fatal if swallowed. Contains petroleum distillates. Direct contact with eyes may cause irritation. FIRST AID PROCEDURES if Swallowed 00 not induce vomiting. Call a physician immediately. Contains petroleum distillates. if Inhaled N/A_________________________________ if In Eyes: Ru*ft eyi vttfc plenty o< cool tor M Irat IS mfcMMi If irritation persists contact a physician. if On Skin: N/A SAL 00007107 VI. REACTIVITY DATA Stability stable Condition* To Avoid: None INCOMPATIBILITY ^ to Do not mix with any other chemicals. Hazardous Decomposition Products: Thermal decomposition may produce carbon dioxide and/or carbon monoxide. HAZARDOUS POLYHEMZATKM MU NOT OCCUR VII. SPILL OR LEAK PROCEDURES Steps To Be Taken H Material Is Released Or Spilled Soak up spill on State Oil Absorbent, sand or vermicu- lite and discard. Flush residue with plenty of water to the drain Waste Disposal Method n<=}t reuse empty containers for any purpose. Flush thoroughly with water, crush and discard. PpBo* AD F*d*r. SW> *nd LM4 IWguWloM Hia^dtog Mm* CNapoMf. VIII. SPECIAL PROTECTION INFORMATION prowelion md pfotKth* gton art <*canwMndM mrf Mm you ant vtth aiy cencMMM MuttrW ftranglh products Respiratory Protection t>ane required__________________ Ventiletion Wonnal roctn__________________________________ Protective Gloves None y, P[otec)|on n/a_____ Other Protective EquipmentIX. N/A IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage DAM3ER: Harmful or fatal if swallowed. Contains petroleum distillates. Product is oormustible. Do rot use near heat, sparks cr ccen flame. Do r.ct weld or cut empty drums. OTHER PRE3CWITCIB: Do not reuse empty drums for any purpose. Destroy by crushing or return to a drum, reccrciti oner. Read and follow all label directions and precautions before using the product. These products are Intended for industrial and institutional use only. Not Intended for household use or resale. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein Is tactual and the opinion* expressed sre those of qualified experts, the data are not to be taken a* a warranty or repreeentatlon far which the company asaumes legal raopotv sitrillty. They are offered solely for your consideration, Investigation, and verification. Any use of these data and Information must be determined by the user to be in accordance with applicable Federal. State, and Local laws and regulations. SAL 00000710B 5 (conoco) /endor Information Conoco Inc. ^ Page Purchase Requisition of Priority RLOC Department REB Refining Ship To ALLSTATE CHEMICALS Shaded Areas RQ Loc Requisition No. for Purchasing Dept. Use Only 316 25G887 do k *- ** *' Ship Date Req'd at Dest. Order Previous P.O. via Type i OH Tagging Instruc ions F.O.B. Point Freight Terms \ttn: lequisitioner Date 191-5558 SUE ANDERSON 02-22-90 Tax Status Special Instructions Charge Exempt 6% Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Carrier Project ID Clauses Payment Terms -- AFE Reporting Distribution Charge .* J V -i 7*11-3-0-55-03-08 :ket Data Control WO Equip. No. " 02-22-90 SO-55 ird Slock No. Description Time Time init stat. Ordered Req'd Unit Code Date Required PV +** 1155 norm __________7 k 11-3-0-55-03-08______________ ____ __________ ltm Oyanttty Unit* of ________________________________ _________ _____No._____ Ordered Issue Price Oty. Issued SCRUB V DISPENSER 1 5 EACH FLOYD VINCENT ArT 0 nW NOTIFY FLOYD ON ARRIVAL nnwp rRMINGRDER ANDERSON TO STATE uO HOT DUTL -T6T R op..-el* - Operating Depl. 1-86 Approval - Purchasing Dept. ______________ 1 SAL 000007109 ^PERMATEX ZpJm INDUSTRIAL MATERIAL SAFETY DATA SHEET Emergency Tel. Number (203) 278-1280 I, PRODUCT IDENTIFICATION GS637 Product Name: Hydraulic Jack Oil ITEM: No.: 80054, 55 Product Type: Hydraulic Fluid Part No.: 78E, 78F Ingredients Zinc Compound* Severely Hydrotreated ** Naphthenic Oil Methacrylate Polymer Surfactant II. COMPOSITION % by Wt. <0.5 >95 1-5 <0.05 Hazard Skin/Eye, Irritant TLV 5mg/m3 (mist) Skin/eye irritant *It has been shown in preliminary tests, that certain zinc compounds, when applied to skin of male experimental animals adversely affect spermatogenic activity. **Skin/eye/inhalation irritant. It is our best technical judgement that, with proper precautions, normal use of this product poses no such chronic hazard. III. CHEMICAL AND PHYSICAL PROPERTIES Vapor Pressure: <5 mm Specific Gravity: 0.905 G 60 Deg. F. Vapor Density: Not available Boiling Point: 175-300F Solubility in Water: Negligible pH: Does not apply Appearance: Amber Liquid Odor: Mild petroleum Page 1 of 3 SAL 000007110 57 PERMATEX INDUSTRIAL CORPORATION 30 Tower Lane Avon Park South Avon. CT C6001 (203) 677-7727 FAX (203) 674-8552 GS 6 87 HYDRAULIC JACK OIL Page 2 of 3 IV. TOXICITY AND HEALTH HAZARD DATA Toxicity Low order of toxicity Skin and eye irritant. TLV: 5mg/M3 (mist) Symptoms of Overexposure Prolonged exposure may cause dermatitis. Breathing of mist or vapor may cause irritation of the pulmonary tract or aspiration pneumonia. EMERGENCY TREATMENT PROCEDURES Ingestion Do not induce vomiting. Consult physician. Inhalation Not likley to occur except as mist. Remove to fresh air. symptoms persist, obtain medical attention. If Skin Contact: Wash with soap and water. physician. If irritation persists, consult a Sye Contact: ' ush with water for at least 15 minutes. Seek medical attention RSONAL : ROTECTION: S. ety glasses or goggles. Skin Neoprene or plastic gloves. Ventilation ufficient to maintain vapor concentration below TLV. V. FLAMMABILITY AND EXPLOSIVE PROPERTIES Flash Point: >200F Method: Open Cup Explosive Limits (% by volume in air) Lower: DNA Upper: DNA% Recommended Extinguishing Agents: Carbon dioxide. Foam, Dry Chemical, Hazardous Products Formed by Fire or Thermal Decomposition Irritating organic vapors. Unusual Fire or Explosion Hazards None known Compressed Gases Name: None Pressure at Room Temperature: Does not apply SAL 000007111 58 r HYDRAULIC JACK OIL Page 3 of 3 t * ability VI. REACTIVITY DATA X Stable ____Unstable &S6 87 Hazardous Polymerization ____.May Occur X Will Hot Occur Hazardous Decomposition Products (non-thermal) None known Incompatibility Strong oxidizers. VII. SPILL OR LEAK AND DISPOSAL PROCEDURES Steps to be taken in case of spill or leak: Contain spill. Soak up in an inert absorbent. Clean up residue with soap and water, store in a closed container until disposal. Recommended methods of disposal: Incinerate or landfill following EPA and local regulations. VIII. STORAGE AND HANDLING PROCEDURES ;orage Keep away from flames, sparks, or hot surfaces. Handling Avoid skin contact. Keep away from eyes. Avoid prolonged breathing of vapors. IX. SHIPPING REGULATIONS Type or Class DOT: Unrestricted IATA: Unrestricted Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Date: January 1, 1989 I 59 SAL 000007112 Lv2gp PERMATEX WeSuM industrial 8S637 SARA TITLE III HYDRAULIC JACK OIL 80054, 80055 The ingredients listed below are listed in Section 313 of Title III of the Superfund Amendments and Reauthorization Act. INGREDIENT None CAS NUMBER AMOUNT January 1, 1989 Stephen Repetto Research Chemist, Environmental Health & Safety SR/rbh 60 iMnr lerrniAL CORPORATION 30 Tower Lane * Avon Parx Soulh . Avon C SAL 000007113 C5CC" 2031 677-7727 FAX (203) 674-6552 CHEMICAL MANUFACTURING CO. MAIN OFFICE AND PLANT: CLEVELANO. OHIO 44114 DISTRIBUTION CEMTtAS/SALCS OFFICES. NATIONWIDE MATERIAL SAFETY DATA SHEET S 6 3 6 I. IDENTIFICATION Name formula 360 sta gel A formulated solvent based degreaser D.O.T. Shipping Name: Hazard Class: _ ID No.___ N/A II. HAZARDOUS INGREDIENTS Material Aromatic Petroleum Distillates (CAS #64742-95-6) N/A N/A Label N/A WelghtH TIV >80% 100 III. PHYSICAL DATA Boiling Point (F)370~413F Specific Gravity (Water = 1) Q-904 Volatile By Weight (<K) > . Weight Per Gallon: (Pounds) gai. Solubility In Water emulsifiable pH N/A_____________ Appearance & Orion A clear colorless liquid with a petroleum odor. l I i SAL 00007li4 6S686 IV. FIRE A EXPLOSION HAZARD DATA Flashpoint (P) (Method Used): 145f bv T.c.c. Extinguishing Media: Cartocn dioxide.foam.or dry chpmiral Contains petroleum Special Fire Fighting Procedures: distillates,water may ineffective. Unusual Fire & Explosion Hazards Firefighters should wear self-contained breathing apparatus* V. HEALTH HAZARD DATA Effects of Overexposure - DANCOt: Harmful or fatal if ^wallowed. Contains Petroleum Distillates. Direct contact with eyes or skin may result in irritation. Prolonged breathing of vapors may result in dizziness* drowsiness, headache or nausea. FIRST AID PROCEDURES If Swallowed Do not induce vomiting. Contains__________ Petroleum Distillates. Contact a physician_______ immediately. ; If Inhaled ^emDve person to fresh air. If irritation or difficulty in hreathing persists, contact a physician. .if..In Eyes: Rush lyn imnwdlatafy rfth ptonty of cod *dm tor M Wad 1$ minutes.C._o_n_t_ain. s Petroleum Distillates. Contact a physician immediately. Do not wear contact lenses tdiile using this prnHnr>t_____________________ __________________ If On Sldn: Wash thoroughly with soap and water- Tf ... irritation persists.contact a chvsician- j I ! t i I SAL 000007115 VI. REACTIVITY DATA Stability STABLE ft S 6 36 Conditions To Avoid: Exposure to heat, sparks and open flame INCOMPATIBILITY Strong oxidizers. May adversely effect seme plastics. Hazardous Decomposition Producta:Burnin9 state Sta-Gel Concentrate may result in fprmation of Carbon Monoxide and/or Carben Dioxide gases. hazardous polymerization will not occur VII. SPILL OR LEAK PROCEDURES Steps To Be Taken If Material Is Released Or Spilled Remove all sources of heat, sparks or flame. Ventilate the area ot tne spill. Absorb the spill on State Oil Absorbant, sand or vermiculite. Flush residue with plenty or water. Waste Disposal Method Do not reuse empty drums. Flush thoroughly with water,crush and discard;or give rinsed drums to a drum reconditioner for recycling. Mem AM tear*. Stilt and Local Regulation* Ragatfns Mata WapoaaL 8686 VIII. SPECIAL PROTECTION INFORMATION Eyi prefectton and prefectfvt gto*s r recowwwrxfed any time you ort * any concamrfead IrfeutUfeJ strength cfeaning product*. Respiratory ProtectionUse in wel1 ventilated areas. VnnfilfltirtitLcal mechanical exhaust ventilation is rWXllltk^Ud^d. -------------------------------- Protective Gloves requi red Eye Protection rpgm _ Other Protective Equipment A source of clean water should be nearby in case of accidental eye contact IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage CAUT1CN: Qjrtoustible. Keep away fren heat and open flame. Harmful or fatal if shallowed. Contains Petroleum Distillates. Avoid prolonged breathing of vapor. Use with adequate ventilation. Keep container tightly claeed and stored away front beat, spares .open flams or **>ere temperature* say exceed 120"P. OTOER PRECAUTIONS: Do not reuse en^xy drvra for any purpose. Do not cut or weld empty drum. Destroy empty drums by crushing or returning to a dru* reccnditicner. OTHER PRECAUTIONS Read and follow all label direction* and precautions before using the product. These products are Intended for Industrial and Institutional use only. Not intended for household use or resale. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal respon sibility. They are offered solely for your consideration, Investigation, and verification. Any use of these data and Information must be determined by the user to be In accordance with applicable Federal, State, and Local laws and regulations. 78R3 HEALTH AND SAFETY INFORMATION SEPTEMBER 1988 (216) 861-7114 SAL 000007117 CHEMICAL MANUFACTURING CO. UAJN OfflCC ANO flANT: CLEVELAND, OHO 44114 OtlTIHAVTION CtNTtflaraALCS OMCt NJkTIOMWIOC MATERIAL SAFETY DATA SHEET I. IDENTIFICATION A formulated solvent based degreaser Name FORMULA 360 STA GEL iyp#----------------------------- D.O.T. Shipping Name: Hazard data: _ 10 No. N/A N/A N/A Label N/A It. HAZARDOUS INGREDIENTS Material Aromatic Petroleum Distillates (CAS #64742-95-6) Weight* > 80% TLV 100 pgm III. PHYSICAL DATA Bolling Point fF)3?0~413F Specific Gravity (Water = 1) 0-904___ 7.6lbs Volatile By Weight (*) > 85% Weight Per Gallon: (Pounds) <3^. Solubility In Water emuisifiabie ... pH n/a Appearance & Odor A clear colorless liquid with a petroleum odor. (V. FIRE & EXPLOSION HAZARD DATA Flashpoint (P)(Method Used); 145f by t.c.c. Extinguishing Media; Carbon dioxide.foam.or drv chemical Contains petroleum Special Fire Fighting Procedures: distillates.water imv fag ineffective. Unusual Fire & Explosion Hazards Firefighters should wear self-contained breathing apparatus. V. HEALTH HAZARD DATA Effects of Overexposure DAM3EK: Harmful or fatal if swallo*ed. Contains Petrol&su Distillates. Direct contact with eyes or shin nay result in irritation. Prolan)*! breathing of vjpors ray result in dizziness, drwsmess,headache or nausea. FIRST AID PROCEDURES If Swallowed 00 not induce vomiting. Contains Petroleum Distillates. Contact a physician_____ immediately. A Inhaled Remove person to fresh air. If irritation or difficulty in breathing persists, contact a physician. _____________________________________________ ,if, I.n _Eyes: Flush iy*t immsdlfealY with pttmy of cool wafer lor M lasti 15 Mfeufet. Conta. in: Petroleum Distillates. Contact a physician immediately. Do not wear contact lenses while using this product. If On Skin: Wash thoroughly with soap .and water. If irritation persists,contact a rhvsician. I? SAL 000007118 VI.REACTIVITY DATA STABLE Stabiltty________________ ComMons To Avoid: ^Posure to heat,sparks and open flame INCOMPATIBILITY *. * a**, Strong oxidizers. May adversely effect seme plastics. Hazardous Decomposition Products:31117111^ State Sta-Gel Concentrate nay result in formation of Carben Monoxide and/or Carbon Dioxide gases. HAZARDOUS KXYVERUATKM WILL NOT OCCUR VII. SPILL OR LEAK PROCEDURES Steps To Be Tsken If Material Is Released Or Spilled Remove all sources of heat,sparks or flame. Ventilate the area of the spill. Absorb the spill on State Oil Absorbant,sand or vermiculite. Flush residue with plenEy'oF"waTerT-"'------^--------"""" Waste Disposal Method Do not reuse empty drums. Flush thoroughly with water,crush and di scard;or give rinsed drums to a drum reconditioner for recycling. Fftew Al Ftdmf, SM* wti UcW RyuWBww Wwto OWfOwl. VIII. SPECIAL PROTECTION INFORMATION Ep proMctton intf praticllw glow* n ncommtmM mg Una fju mt wKh xty uhmiiMWS MMtntf rtranglh clMMng product* Respiratory Protection Use in ventilated areas. Ventilation1-003! mechanical exhaust ventilation is Vwamded;---------------------------------------------------- Protective Gloves required Eye Protection required Other Protective Equipment A 5Quroe of-clean watem should be nearby in case of accidental eye contact IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage CAITT1CN: GarOust-ifcle. Keep may frem heat ind open flames. Harmful or fatal if swallo^d. Contains Petroleim Distillates. Avoid [x-olcriged breathing of vapor. Use with adequate vwitiLatlon. Keep container tightly closed and stored away frem h**t. spirts .open flames or <4iere temperatures may exceed 120*P. OnffiF PRECAUTIONS; Do rot reuse entpey drime foi any purpose. So not cut or weld anpty druns. Destroy empty dnsns by arualunq or returning to a dna reconditioner. OTHER PRECAUTIONS Read and follow all label directions and pracautlons before using the product. These products are Intended for Industrial and institutional use only. Not intended for household use or resale. KEEP OUT OF THE REACH OF CHILDREN. While we h^ileve that the data contained herein Is factual and the opinions expressed ire those of qualified experts, tha data are not to be taken as a warranty or representation tor which the company assumes legal respon sibility. They are offered solely for your consideration, investigation, and verification. Any use of that# data and Information must be detarmined by the user to be In accordance with applicable Federal, State, and Local laws and regulations. * __ _ 78R3 HEALTH AND SAFETY INFORMATION (216) 861-7114 SEPTEMBER 1988 __ - q SAL OOOOOr-LX? {conoco) endor Information Conoco Inc. Page Purchase Requisition ^ 0, Priority RLOCTiDepartment REB Refining Ship To STATE CHEMICAL Shaded Areas RQ Loc Requisition No. for Purchasing Dept. Use Only 316 . 25G859 A CD Ship Date Req'd at Dest. Order Previous P.O. Via Type RECD Tagging Instructions F.O.B. Point Freight Terms \ttn: RECD iequisitioner RACHELLE 2/26/90 Date ax Status Special Instructions Charge Exempt Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Carrier N->. Project ID Clauses Payment Terms AFE Reporting Distribution Charge ,,j _j____ i_______ 7411-3-1240-46-14-4950 cnet Date Control w.o. Equip. No. Tim* Time Inft. Sat. Ordered Raq'd Unit Code Data Required 56859 2/26/90 3 m AFL R1 C RE(| REC; IEC 46 'Art stock No. OeacRrtp4tlo9n50 No. OfdorotiIwuoPrlco1**^ Formula 360 gel Arenatlc BC-1 ------ 7411-3-1240-46-14-MB4950 ,t4m CH-*nll(v Unit* of -6 | 12 gal cans APRPOVED: A LEWIS ORDERED BY FIELD CONFIREMD RODER TO STATE CHEMICAL DO HOT DUP - App.uvala - Operating Deot. Approval Purchasing Opt, B-1&5 X&, 11-as RECEIVED BY: SAL 000007120 2-3* (o % S The tatifCHEMICAL MANUFACTURING CO. Ml MAIN OFFICE AND PLANT: CLEVELANO. OHIO 44114 DtSTfABUTlON CCNTEAS/9ALES OPF<CCS NATIONWIDE I. IDENTIFICATION Name BC-1 MATERIAL SAFETY DATA SHEET $335 TP A Comolated aolvmit degraaaar Shipping Name: Hazard Clast: . Consumer Ccxiroodity ORM-D ID Ho. N/A Labtl None required IX. HAZARDOUS mTBUALS Material weight % TIV Tetrachlecoethylen* (CAS #127*18*4) < 24 50ppm Methylchlorofocia (CAS #71*55-6) < 73 350ppa Carbon Dioxide (CAS #124*38*9) <3 5000ppn this product contain* Tatrachloroethylane {Perchlcoroethylene) and Hethylchloroform (1,1,1-txichloroethane) which are toxic chemicals subject to the reporting raquixmoanta of Section 313 of Title IXI of the Superfund JmenAneat* and Reauthoriaatlon Act of 1986 (SARA). III. PHYSICAL DATA Bolling Point |F| _____________ Specific Gravity (Water=l| n/a Volatile By Weight (%|___1QQ% Weight Per Gallon: (Pounds) - n/a Solubility In Water _____ liPH,, n/a Appearance A Odor A clear aeroso1 spray with a chlorinated odor. SAL 000007121 IV. FIRE * EXPLOSION HAZARO DATA Fluhpolnt(F|(Mithod Ustd): Ngns. Ho flame extension. #868" Exllngillthlng Midli: N/A------------ ----------------------------------------- SPECIAL FIREFIGHTING PROCEUtRESs Keep containers Cool. Dm shielding to protect personnel from venting, rupturing, or bursting containers, UNUSUAL FIRE AM> DCPL06ICN HAZARDS: Exposure to temperatures above 120*F may cause cans to vent, rupture, or txiret, V. HEALTH HAZARD DATA CTVHCTS CF OVEREXPOSURE: WARNING: Vapor may be harmful. Prologjed or repeated breathing of vapors sey result in dizziness,drowsiness,heedadie, nausea,or naaal and/or respiratory irritation. Direct contact with skin or eyes say cause irritation. Do not take internally. CHRONIC WQV3CTO5URE: Overexposure to this material (or its components) has boon suggested as a cause of liver abnormlities.kidney daffuge,lmg damage,brain dima'je,and spleen daumge in hurans. Ihe National Cancer institute has eroclurfod from the results of a bioassay that tetratfiloroethylcne is a liver carcinogen when given orally to mico. MBHOU, COMJITICffS AGGRAVATED BY FXiOSURE: Liver disease and rhythm disorders of the heart. FIRST AID PROCEDURES II Swallowed Seek medical attention immediately. If a doctor >s o iansdiately available,induce vomiting using Syrup of Ipecac (folio* all label directions). Do not nake an unconscious person vomit. II Inhaled--------------------------------------------------------------------------------------- Get ikz. jU to fresh air. Mnunister artificial respiration if breathing has stopped. Get imnediate medical attention. NOTE TO PHYSICIAN: Do not give stirulants. Epinephrine or ephedrine may adversely affect the heart with fatal results. If In Eyes: FtoU tru imtttfUttlf wl* flinty tH ml safer Jar at taaat 15 emu^^nsu^^- a physician imnediately. Contact lenses should not be worn when, working with this nrodnot. II On Skin: Wash with plenty of soap and water, Remove contaminated clothing. Tf imi-aiLim Ipersists.consult a ^lygiiHan Health & Safety Information (216)861-7114 Sal 00007122 VI. REACTIVITY DATA Stability STABLE Conditions To imid-Bcposure to temperatures above 12QF INCOMPATIBILITY ut*m Pun cocygen,strong caustics* strong oxidizers, chemically active light metals such as lithium or eodiim. Hazardous Decomposition Products: Burnin9 i9 pTM*** formation of HCl. CO, Fhoigene, or Oilorina gases. result in ** HAZARDOUS POLYMERIZATION WILL NOT OCCUR VIL SPILL OR LEAK PROCEDURES Steps To Be Taken It Material Is Released Or Spilled^ Ventilate____ area. Absorb spill with State Oil`Absorbent, sand,or vermiculite. Waste Disposal Method---------------------------------------------------------------------- Do not puncture or incinerate. Give empty cans to a waste disposal service equipped to safely handle and dispose of pressurized containers. Follaw All Fidtral. SUti and lteal (Uguiallena ftafartfinf Waili Oliposal. SAL 000007123 VIII. SPECIAL PROTECTION INFORMATION Ei mMM and pnHrtM ftovu an MMttlai tlTMlttl cJn*M* r*tfvct*. M| Umr** wirt wllk My CMCtutrini Hhn TLV it exceeded,wear NXOSH approved certxidgs respirator fitted with organic vapor cartridges. Self-contained breathing apparatus required Respiratory Protection W3rking ta r ventilation. *" wlth " > Always use adequate ventilation. Do not un thia yroduct in VentliatiOfl poorly witllated tpacea. ProtactiVI Rlnu.Jteccrmended Ey, Protection Required Other Protective Equipment naarby in case of occidental eye contact. A source of clt>an water should bo IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage UM04ING: Contents under pressure. Do not store in open sunlight or other areas where temperatures my exceed 120"F. Do not puncture can or dispose of in fire or incinerator. Uoe with adequate ventilation. BC-1 is a pnwr-rCul solvent. Although it is safe on most plastics.it may attack soma plaaticn, rubber.polymeric fibers, and save coatings. NFPA RATING: Health: 2 Flanraafaility: 0 Reactivity: 0 Other Precautions Asad vd follow all Labal direction# and precautions before using the yroduct. These prefects are intended for industrial nee only. NOT FCR HOUSEHOLD USE OR RESALE KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein is fadual and Ihe opinions expressed are those ol qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consideration. Investigation, and verification Any use of these data and information must ha determined by the user to be in accordance with applicable Federal. State, and Local laws and regulations. * 58R9 JANUARY* 1989 SAL 000007124 r Q~5 u> % s *? The taflfCHEMICAL MANUFACTURING CO. MAIN OFFICE ANO PLANT CL6VELANO. OHIO 44114 oit*iution CEHT*nt'ik.ts Officis N*no*>wioe IDENTIFICATION Nama BC-1 MATERIAL SAfETY DATA SHEET A (onulatad T|P# aplvanc degresses O.O.T. Shipping Name: Hazard Clatt; - Consumer Ccrmodity ORM-D ION.. None required II. HAZARDOUS WflHUAL* Material TWtrartloroethylsne (OS 1127*161-4) Htthylchlomfont (CAS 471-55-6) Carte* Dioxide (CXS 1124-38-9) Wei^it % < 24 < 73 <3 n>v SO jpn 350 pp 5000 ppn This preducL centains Tatcartlorocrtylat* (PerrtletoothyUne) and Hatttylrtlorofort (1.1,1-trirtlareaUim) vhirt art taric chenicel* subject to the reporting requirement* at Caetiin 313 of Title III of the Superfmd Nwdmti and Reeuthorisatian Act of 1986 (SAM). III. PHYSICAL DATA Boiling Point (F| N/A .Specific Gravity (Water=1) n/a Volatile By Weight (%} . 10P%_ Weight Par Gallon: (Poundtj Jilt. Solubility In Water < -1pH__________________ ^____________ . ... A clear aerosol spray with a Appearance & Odor:_______________________ -----------------------------------chlorinated odor. 1 IV. FIRE EXPLOSION HAZARD DATA Flashpoint |0F)(MithOd Used): Hone. .Ho flame extension. Extinguishing Media: __ ______________________________________ SPECIAL rrRETIGKn>C PROdXAKES: Keep containers cool. Use shielding to protect perecnnel frtn venting, rupturing, or bursting ocntainera, UNUSUAL FIRE NC EXPUD6ICN HAZARDS: Btpoeure to tengiersturaa above 120`F wy cauee cans to vent, rupture, or burst. V. HEALTH HAZARD DATA CTTHCTS OF OVEREXPOSURE: WARNING: Vapor nay be harmful. Prolonged or repeated breathing of vapors ray result in dirainees.drcusim-sn.headache. nausea,ox nasal anl/or respiratory irrtt.lt ton. Direct contact with Mein or eyes ray cause jrritati<n. Do not take internally. CHRONIC CMMfypaSUU'tverexpscjre to this nwtorial lor its component*) has been suggested as -i cause of 1 ivei ainor^il j ties.Kiuney d/vnjge, 1 uikj Uarage,brain d.initge.and tpleen dirage m hjivins. The National C-inccr institute has concluded (hn the results of a hioasnsy that tetraidiloroethyiene is a liver njrnnoqcr. when given orally to rrucu. MEDICAL aUDlTUTiS AGGRAVATED By BUtKURE: lover disease arid rhytftm disorders of the heir". FIRST AID PROCEDURES II Swallowed Seek medical attention unrudiately. 11 1 doctor is :r-' ir*h.it"i y available.irduce veruting using Syrup of Ipecac (folio* all latel directions). Do not rake an unconscious person vomit. II Inhaled C-nt jr.-r jt, rc fresh air. Mruni stcr artificial respiration if brc.ithinq has stopped, Get unnediate medical attention. NOTE TO PHYSICIAN: Do rot give stimulants. Epinephrine or eprtedrxn* ray jdvt.hrly affect the heart with fatal results. II In Eyet: flush rh tniMdlittly with Itinty essl mm tsr il Im 15 suauistCQPSUlt a physician immediately. Contact lenses should not be v^n_jf/hen_MprkinQ_with this prndur?f.. II On Skin: Wash with plenty of soap and water. Remove_cont.amiriated clothing. Tf i rri i-ai-i nn eersiss^.y?nftiilt a phys/i ,-i.. | - J":3i. SAL OOOOO7125 V'.- VI. REACTIVITY OATA Stability_____ gTfigLg.......................... ..... .................. ....... - . Conditions To iwn^-Exposure to temperatures above 12QF INCOMPATIBILITY iMtllrlitt IoAioiEI pure oxygen,trurig caustics, stxcng OxidlZArs.chemically active light netals eud) as lithiun or sodliai. Hazardous Decomposition Products: Bun'in' ,flia formation of HCl. CO. Phosgene, or Chlorine gases. toy result in the HAZAROOUS POLYMERIZATION WILL NOT OCCUR VII. SPILL DR LEAK PROCEDURES Sleps To Be Taken II Material Is Released Or Spilled, Ventilate area. Absorb spill with State Oil`Absorbent, sand/or vermiculite. Waste Oisposa! Method l>> n'i> raiTTturn or incifKir.ite. Give empty cans to a waste disposal survico L>^uif^ed to safely handle ana disjnse of pressurized containers. follow All fidtrtl. Slati m IkM Atgulillom AigirOlrt| Wnlo DIoruiI VIII. SPECIAL PROTECTION INFORMATION (y pronclion led p>M*ttlvt gkvu in rtcemiMiMM ley limi rsvwsrk wit# aay conconlnlod ledutirul utmglts ckinlng p<Mwcu ZLV is exceedad,w*ar NICSi approved caxtriAje respirator fitted with organic vapor cartridges. Self-contained breathing apparatus required Resrpiratory9 Prelection venti-lat1*tinonw.or*ing in CCTlfinw1 araas vlt* Alweyi; use adequate vwitilaticn. Do not use this jraiuct in Ventilation poorly iwttilated spaces. Protective6loveeccnmended_ Eye Protection___Required Other Protective Equipment A source of clean water should be nearby in case ot accidental eye contact.IX IX SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage lARNDT,: Contents under pressure. Do not store in open sunlight or other ireaB where tunperatures may exceed 120F. Do not puncture car or dispose of in fire or incinerator. Use with mJcquaLe vnntilaticn. BC-1 is a prw-rtul solvent. Although it is safe on mint plastics.it may attack seme plmticr;, rubber,polymeric fibers, and scire coatings. NTPA RATING: Health: 2 Flanmebility: 0 Reactivity: 0 Other Precautions Dead end folio* all label directiois and precaution* before uairq the product. Theee product. are intended for industrial uee oily. NOT PCR HOUSEHOLD USE CR RESALE KEEP OUT OF THE REACH OF CHILDREN. While we believe that lha data contained herein is (actual and the opinions expressed are those of qualified experts, the dita are not to be taken as a warranty or representation lor which the company assumes legal responsibility. They are offered solely for your consideration, investigation, and verification Any use of these data and Information musl be determined by the user to be in accordance with applicable Federal. State, and Local laws and regulations 58R9 SAL 000007126 The tatlfCHEMICAL MANUFACTURING CO. , H.I.E UXM OFFICE ANO PLANT: CLCVELANO. OHIO 44114 WB'w DltTftltUTlOM CCNTCna/SAltt Of nett NATIONWIOC MATERIAL SAFETY DATA SHEET 6 S 6 34 I. IDENTIFICATION ____ CONCRETE PATCH A concrete j^ patching compound D.O.T. Shipping Name: N'A____________________________ Hazard Class: N//A____________________________ ID No. N/A Label _**/__ II. HAZARDOUS INGREDIENTS Material Weight* TLY This product contains no hazardous ingredients, at greater than one percent, as defined by Federal and State Worker Right-to-Know Laws* III. PHYSICAL DATA Bolling Point (F) N/A Specific Gravity (Water = 1) n/a Volatile By Weight (H) ^ TOUtil< Weight Per Gallon: (Pounds) n/a Solubility In Water slightpH n/a Appearance & Odor. A fine brcwn earless powder. | SAL 000007127 GS634 IV. FIRE & EXPLOSION HAZARO DATA Flashpoint (F*) (Method Used): n/a Extinguishing Media: Concrete Patch is itself a pood extinguishing agent. Special Fire fighting Procedures: None Unusual Fire & Explosion Hazards N^A V. HEALTH HAZARO DATA Effects of Overexposure Inhalation of dust will cause respiratory tract irritation. Direct eye contact causes irritation. May be harmful if swallowed. FIRST AID PROCEDURES II Swallowed Contact a physician or Poison Control Center iirmediately. If Inhaled Renove person to fresh air. If irritation continues, seek medical attention. If In Eyes: Fluth */** townodtotofr Mi pfenty of cool wmm tor M tent 15 *w***. . ^ irritation continues, get immediate medical attention._______________________________________________ If On Skin: Wash with soap and water.______________ SAL 000007128 GS634 VIII. SPECIAL PROTECTION INFORMATION Ey> pnjfcctton and pmtictM glow* arc wco--wdid any ttma you worfc wWi any coocantralad MuatrW ftrtngOi cleaning praducl Respiratory Protection Dust mask Ventilation Normal roccn ventilation Protective doves recctTTnerK3ed Eye Protection required Other Protective Equipment None IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage Store in a cool, dry place. Do not reuse empty containers for any purpose. OTHER PRECAUTIONS Read and follow all label directions and precautions before using the product. These products are Intended for Industrial and Institutional use only. Not Intended for household use or resale. KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein Is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal respon sibility. They are offered solely for your consideration, Investigation, and verification. Any use of these data and Information must be determined by the user to be In accordance with applicable Federal, State, and Local laws and regulations. HEALTH AND SAFETY INFORMATION MAY 1989 (216) 861-7114 SAL 000007129 VI. REACTIVITY DATA Stability stable, nG S 6~ ^34* Conditions To Avoid: Damp or high humidity storage. INCOMPATIBILITY pned* * **q None known, Hazardous Decomposition Products: slight amount of_________ ammonia. HAZARDOUS POLYUEHZATOH WRJ. HOT OCCUR / j * t VII. SPILL OR LEAK PROCEDURES Steps To Be Taken If Material Is Released Or Spilled Sweep up and discard. Waste Disposal Method Discard in nonbumable trash. This is a nonhazardous waste. Follow AH Fed*#*, State end Locel Hegulatione Regarding DMe DtepOML SAL 000007130 CHEMICAL MANUFACTURING CO. U&IN OffICf AMO PLANT: CLEVELAND. OMO Mt14 DltTAIUTOM CINTSRt 'tAlf OFFICC4 NATKMWIOC MATERIAL SAFETY DATA SHEET I. IDENTIFICATION NilM CONCRETE PATCH A concrete lypa patching compound O.O.T. Shipping Nam: N/A____________________________ Hazard Clan: N/A____________________________ 10 No. _*/* Label II. HAZARDOUS INGREDIENTS Material Weight* TLY This product contains no hazardous ingredients, at greater than one percent, as defined by Federal and State Worker Right-to-Know Laws. III. PHYSICAL OATA Bofflng Point (F)_n/a__ Specific Gravity (Water * 1) n/a Volatile By Weight (*) Weight Per Gallon: (Pound*) n/a Solubility In Water SlightpH n/a Appearance ft Odor A fine bream odorless pewder. IV. FIRE ft EXPLOSION HAZARD DATA Flashpoint P) (Method Used): N/A Extinguishing Media: Concrete Patch is itself a good extinguishing agent. Special^ Fire Fighting 'Procedures: None Unusual Fire ft Explosion Hazards H/ft V. HEALTH HAZARD DATA Effects of Overexposure inhalation of dust will cause respiratory tract irritation. Direct eye contact causes irritation. May be harmful if swallowed. FIRST AID PROCEDURES If Swallowed Contact a physician or Poison Control Center immediately. If Inhaled RenCFVe person to fresh air. If irritation continues, seek medical attention. SAL 000007131 It Eyes:ll) Hurt *?* iMMttlUly wtth pttntjr Oi tool nUi lor It teM IS ownuMt. H Irritation continues, get imnediate medical attention. If On Skin: Wash with soap and water. VI. REACTIVITY DATA Stability STABLE__________________________________________ Conditions Tb Avoid: Damp or high humidity storage, WCOHWCneiUTY VMM * m Ncrte kncwn.____________ Hazardous Decomposition Products: Slight amount of 3inncfiid HAZARDOUS KU1CRCATION Ml NOT OCCUR VII. SPILL OR LEAK PROCEDURES Steps lb Be Taken If Material Is Released Or Spilled 3weeP UP and discard. Waste Disposal Method Discard in nonbumable trash. This is a nonhazardous waste. FoSm A* MM. SM* and Local AaguMUsni fla^ardlng Wam* DtapouL Vlil. SPECIAL PROTECTION INFORMATION E|* pmaacUsn d pnMcMia ^oaa an racBiwiimdad mtf tfena jwi rat wWi wtf concanttaM Induatrtat Hwgdi prodwttt. Respiratory Protection Dust _________________________ Ventilation Normal roan ventilation Protective Gloves recormendea Ey# protection required Other Protective Equipment -None IX. SPECIAL PRECAUTIONS Precautions To Be Taken In Handling Storage Store in a cool, dry place. Do not reuse empty containers for any purpose. OTHER PRECAUTIONS SAL 000007132 Read end follow all label directions end precautions before using the product. These products ere Intended tor Industrial and institutional uea only. Not Intended for household use or resale. KEEP OUT OF THE REACH OF CHILDREN. While we bsdeve that the data contained herein ie tactual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or ispieasnlatlon for which the company aatumee legal reeporvsiblilty. They are offered solely for your consideration, Investigation, and verification. Any use of these data and Information must b# determined by the user to be In accordance with applicable Federal, State, and Local laws and regulations. (conoco) Vendor Information Conoco Inc. Page Purchase Requisition Priority RLOC REB Of .mom . Refipf Ship To Shaded Areas RQ Loc Requisition No. for Purchasing Dept. Use Only 316 25G8G8 A . Date Req'd at Dest. Previous P.O. Via Type J]QK Tagging Instructions STATE CHEMICAL F.O.B. Point Freight Terms Conoco Inc. Carrier Refinery Warehouse Old Spanish Trail P.O. Box 37 Project ID Clauses Westlake, LA 70669 Attn: Requisitioner - Date 491-5556 SUE ANDERSOH 02-22-90 Tax Status Special Instructions Charge Exempt 6% Distribution Charge _____________ 7411-3-1310-46-14-5001 Ticket , Data Control W.O. Equip. No. *5001.. Time Time Init. Slat. Ordered Reqd Unit Coda Data Required fUA-- ft* noral Jt6 ' ^r>Hf,rRETE PATCH__________________________________________ _ J___ <3*1*4 PAW*H # 5 A^PWiT.H* PAVriTJq > ? h li Units of RiCH Rtnu "T---------- ^ AR*THIfP flMU.r/lHV /9 * JJ ^ (C^lAr^ <2AU,______ _________________________________________________ l ) i (XafflRHIMQORDgB DO HUT DUPLICATE--------------------------- - Operating Dept Approval - Purchasing Dept. SAL 000007133 VISTA MATERIAL SAFETY DATA SHEET Houston, Texas 77224 1. PRODUCT IDENTIFICATION MANUFACTURING SITE Lake Charles Chemical Plant ADDRESS TRADE NAME P.O. Box 727, Old Spanish Trail Rd., Westlake, LA 70669 HEAVY AROMATIC DISTILLATE Cl0 54 SYNONYMS Hydrocarbon mixture containing cyclic and unsaturated compounds CAS NUMBER(S) 68513-69-9 Residues (Petroleum), steam-cracked light TELEPHONE NO. (713) 588-3491 EMERGENCY TELEPHONE NO. (318) 494-5142 2. COMPONENTS AND HAZARD CLASSIFICATION HAZARDOUS INGREDIENTS: Napthaiene 20% Indan/Styrene/Tetralins 20% Benzene 5.5% Ethylbenzene 6.5% Toluene 6.5% Components of this product are listed carcinogens - see Section 5. Carcinogen, irritant, and flammable as defined by the OSHA Hazard Communication Standard. Contains no chemicals subject to SARA 302 reporting. SARA 311/312"Fire HazardH"lmmediate (Acute) Health Hazard", and "Delayed (Chronic) Health Hazard" Contains a maximum of 5.5% benzene (CAS# 71-43-2), 6.5% Toluene (CAS# 108-88-3), and 6.5% ethylbenzene (CAS# 100-41-4) which are chemicals subject to SARA 313 reporting. 3. PHYSICAL DAVA | BOILING POINT (F) 164 SPECIFIC GRAVITY (H*0= 1) 0.921 VAPOR PRESSURE (mm Hg.) Unknown SOLUBILITY IN WATER Negligible MELTING POINT VAPOR DENSITY Unknown Unknown APPEARANCE AND ODOR Brown, oily liquid; strong aromatic odor. 4. FIRE AND EXPLOSION DAIA FLASH POINT (TEST METHOD) 70F (PM) AUTOIGNITION TEMPERATURE FLAMMABLE LIMITS IN AIR. % BY VOL. LOWER Unknown Unknown UPPER Unknown | j [ EXTINGUISHING MEDIA Water spray (fog), foam, dry chemical, or C02. $AL 000007134- I SPECIAL FIRE FIGHTING Stop source of leak. Cool exposed equipment with water spray. Use self- I PROCEDURES contained breathing apparatus if fighting fire in confined spaces. UNUSUAL FIRE AND EXPLOSION HAZARD This material can release sufficient vapor to form an explosive mixture in air. Produces thick, black smoke when burning. Pa9e 1 of 4 C I 0 54HEAVY AROMATIC DISTILLATE 5. HEALTH HAZARD INFORMATION f \ FIRSTtAID^^^^^ EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Call a physician. SKIN: Remove contaiminated clothing. Wash with soap and water. If irritation persists, seek medical attention. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. INGESTION: If swallowed, call a physician immediately. ONLY induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. NATURE OF HAZARD Vv - . . -_r EYE: Vapors and liquid may be Irritating to the eyes. SKIN: Repeated or prolonged skin contact can cause defatting and lead to dermatitis. Skin absorption can occur. INHALATION: Irritating to nose and upper respiratory tract. May cause CNS depression and reversible effects on liver and kidneys. Chronic effects due to the benzene content include possible cancer (leukemia), bone marrow effects, and injuries to the blood- forming tissues. [ INGESTION: Systemic effects may occur. EXPOSURE LIMITS? None established. Based on benzene content, a value of 1.0 ppm for an 8-hour TWA is recommended by Vista. STEL of 5 ppm for 15 minutes. TOXICITY DATA 1....., No specific data available on this product. Data for benzene and other similar aromatic hydrocarbons would Indicate this material to be an eye and skin Irritant, and possibly toxic through skin absorption. Benzene LC^ of 10,000 ppm after 7 hours exposure has been reported. This product contains polynuclear aromatic hydrocarbons. Some polynuclear aromatic hydrocarbons have been shown to cause skin tumors in laboratory animal tests. Benzene has been recognized as a human carcinogen by IARC and NTP. Styrene has been recognized as a human carcinogen by IARC. Benzene Is regulated by OSHA as a carcinogen. 000007135 SPECIAL PRECAUTIONS Page 2 of * AVOID INHALATION AND REPEATED SKIN CONTACT. HEAVY AROMATIC DISTILLATE 1054 Evacuate the area and eliminate all sources of ignition. Contain the spill. Absorb spill with inert material, then place in a chemical waste container. For large spills, dike for later disposal. Dispose of only In accordance with local, state, and federal regulations. REPORTING: Contains a maximum 5.5% benzene (CERCLA RQ = 10 lbs.), 6.5% toluene (RQ = 1,000 lbs.), 6.5% ethylbenzene (RQ = 1,000 lbs.), 20% styrene (RQ = 1,000 lbs), and 20% napthalene (RQ = 5,000 lbs.) WASTE CLASSIFICATION: The product has the RCRA characteristic of Ignitability and if discarded In its purchased form would have the EPA Hazardous Waste Number of D001. Re-evaluation of the product may be required by the user at the time of disposal, since the product uses, transformations, and mixtures may change the classification to non-hazardous or hazardous for reasons other than, or in addition to, ignitability. 8. SPECIAL, PROTECTION INFORMATION VENTILATION RECOMMENDATIONS Adequate ventilation to reduce levels of air contaminants below that which may cause personnel injury or illness. Exposure limits listed under Section 5. HEALTH HAZARD INFORMATION. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT EYES: Chemical goggles or safety shield. SKIN: Full protective clothing, boots, and gloves. RESPIRATORY PROTECTION: If needed, use NIOSH/MSHA-approved organic vapor respiratory protection. SAL 000007136 Page 3 of 4 HEAVY AROMATIC DISTILLATE CI054 VISTA 9. SHIPPING, TRANSFER AND STORAGE SHIPPING INFORMATION DOT PROPER SHIPPING NAME: DOT HAZARD CLASS: DOT IDENTIFICATION NUMBER: ADDITIONAL INFORMATION: Flammable Liquid, N.O.S. Flammable Liquid UN 1993 See Section 7 for reportable quantities. IATA NAME AND DESCRIPTION: IATA UN OR ID NO.: IATA CLASS OR DIVISION: IATA SUBSIDIARY RISK: Flammable Liquids, N.O.S. UN 1993 3 None TRANSPORTATION AND STORAGE ( ELECTROSTATIC ACCUMULATION HAZARD: USUAL SHIPPING CONTAINERS: STORAGE/TRANSPORT TEMPERATURE: STORAGE/TRANSPORT PRESSURE: LOADING/UNLOADING TEMPERATURE: Yes - ground all equipment Pipeline, tank cars, tank trucks Ambient Ambient Ambient f HANDLING AND STORAGE MATERIALS AND COATINGS SUITABLE: Carbon Steel THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH VISTA BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. VISTA'S PRODUCTS ARE INTENDED FOR SALE TO INDUSTRIAL AND COMMERCIAL CUSTOMERS. VISTA REQUESTS THAT CUSTOMERS INSPECT AND TEST OUR PRODUCTS BEFORE USE AND SATISFY THEMSELVES AS TO CONTENTS AND SUITABILITY. VISTA DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY VISTA WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO VISTA. Prepared: i/IB/90 Revised: MSDS#2/MSOS/LC.Ol7 SAL 000007137 Page 4 ol 4 MAR-B5-1990 09:1? FROM ROCKUOOD SYSTEMS A TO 13184915613 ROCKWOOD SYSTEMS CORPORATION a >.02 0 40 EAST MAIM STREET ANCASTER, TEXAS 75146 14/227-3100 USDS #:1 4.4.2 MATERIAL SAFETY DATA SHEET BADE NAME: RSC Jet-X Concentrate >&C I. D. HUMBER: 526-0018 iNMJEI): March 22, 1080 SUPERSEDES: August 8, 1986 Cr S 6 S 1 A ________________________ *C. A. S^ HO------ aSliA-XBA ASSIHJTWA a. Ethyanol 64-17-5 1000 PPM 1000 PPM b. Dipropylene Glycolmethyl 34590-94-8 100 PPM 100 PPM Ether c. Sodium Phosphate Monobasic 7558-80-7 None** None** d. Disodium Orthophosphate 7558-79-4 None** None** e. Fluoronated Surfactant (not assigned) None** None* . Alkyl & Alkoxy Sulfonates None** None** g. Mixed Fatty Alcohols None** None** XiflPTIONAh) L ss than 5* : -7 x 1, 2% or less 1/ 2* or less 5S or less 2( -35* 1- 5* ** No limits given; not rated hazardous. * CAS# req. only for hazardous ingredients; others optional ___ PUTSIHAlu-DATA BOILING POINT..................................... Not determined VAPOR PRESSURE:................................ Not determined VAPOR DENSITY:.................................. Not determined EVAPORATION RATE:........................... Not determined SAL 00007138 SOLUBILITY IN WATER:....................Soluble SP. GRAVITY..........................................1. 01 - 1. 03 PERCENT VOLATILE:...........................Not determined VOLATILE ORGANICS:........................ Not determined pH:............................................................. 5.8 - 6.8 VISCOSITY:............................................ 5 - 20 cps @ 78 Deg. F. APPEARANCE AND ODOR:.................... Clear Green Pourable Liquid-------- A via* inns: M/D - Mot Determined M/A - No t Applicable r-WR-05-1990 08:18 FROM ROCKWOOD SYSTEMS TO 13184915613 \03 , *V $ ROCKWOOD SYSTEMS CORPORATION SS631 MATERIAL DATA SHEET USDS: 1.4. 4.2 MARCH 22, 1969 EIRE AMD EXPLOSION .HAZARD DATA PAGE 2 OF 5 FLASH POINT.............................................Not flammable FLAMMABLE LIM1T8 - LEL:.............N/A FLAMMABLE LIMITS - UEL:.............N/A EXTINGUISHING MEDIA*...................... Use media proper to primary cause o|f fire SPECIAL FIRS FIGHTING PROCEDURES* None UNUSUAL FIRE AND EXPLOSION HAZARDS: None 4. REACTIVITY DATA__________________________________________________________ STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: Strong Oxidizers HAZARDOUS POLYMERIZATION:Will Not Occur JL___EHY1RQHMENTAL. .IHEPRMAXIQH SPILL RESPONSE: Spill area may be slippery, rinse thoroughly. Mafbe soaked up with sand or other inert material and disposed of via regulabions for non-hardous waste. May be gradually rinsed to sewer only with cppius amounts of water to prevent nuisance foaming. RECOMMENDED DISPOSAL: Dispose of In compliance with all State, Lboal and Federal Regulations. 6^_ SUGGESTED, FIRST AID____________________________ EYE CONTACT; Flush with water 15 minutes SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. IF SWALLOWED: If conscious, give large amount of fresh water, if symptoms continue, seek medical help. OTHER FIRST AID: cai nnnnftTi^9 N/D ~ Not Determined N/A " Noti AppllcabXe f^fiR-05-1990 08:19 FROM ROCKWOOD SYSTEMS TO 13184915613 3.04 J ROCKWOOD SYSTEMS CORPORATION 68631 MATERIAL DATA SHEET USDS: 1.4.4.2 MARCH 22, 1989 PAGE 3 OP i 7. PRKCAUTIOHARY_lN&nmXIQH--------------------------------------------------------------------------------------------------------- Store in Original Container; Do not mix agents; Avoid skin and <ye contact; Avoid ingestion. SPECIAL PROTECTION: EYE PROTECTION5 Chemical Goggles Recommended. Eyewash availab; lity. SKIN PROTECTION: N/A VENTILATION: Mechanical(general) recommended. RESPIRATORY PROTECTION: Not normally necessary. ____ HEALlli^A4AHILJ16lA_______________ EYE CONTACT: Mild Irritant I SKIN CONTACT: May cause a mild transient irritation. INHALATION: Not anticipated to be a problem INGESTION: * Irritating to mucous membranes - large dose could prcduce narcosis. SIGNS AND SYMPTOMS OF EXPOSURE: Skin redness, eye redness or walering. MEDICAL CONDITIONS: Chronic dermatitis Carcinogenicity: NTP - No IARC Monographs - No OS HA Rej . No SAL 000007140 Abbreviations: S/D - Sot Determined S/A - Sot Applicable The information on this Data Sheet represents our current data and best opinion as to the proper use in handling of this product under nori >al conditions. Any use of the product which is not in conformance wi h this *__ f %>A n nrtmh / na f. i r>n uith anv material safety data sheet B-LUBE AEROSOL^ ^ B ''A t^A0* : 01 (024453-0409M -EO0M2B3-8OO* )jg**"'.............. {'*"ItyffiU................ SECTION Z - GENERAL INFORMATION CHEMICAL NAME 6 SYNONYMS N/A CHEMICAL FAMILY AEROSOL SELT DRESSING TRADE NAME 8 SYNONYMS B-LU6E AEROSOL FORMULA X<--MIXTURE G-S-6 3 2 MANUFACTURERS NAME; NATIONAL CHEMSEARCM DIV. OF NCH CORF. ADDRESS (NUMBER. STREET. CITY. STATE A ZIP CODE) BOX 192170 IRVING. TEXAS 7S01S PREPARED BY: KELLY SEALS/T.S-CHEMIST ! PRODUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER 5004 214-438-1361 SECTION 11- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) 1,1.1 TRICHLOROETHANE CARBON DIOXIDE j HAZARD | TLV* IRRITANT 350PPM ASPHYXIANT 5000PPM | PEL* 350PPM lO.OOOPPM \ CAS# 71-SS-8 124-38-9 SECTION 11A - NON-HAZARDOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNOER NO TRADE SECRET REGISTRY * 409363-5134P B-LUBE AERDSOL SECTION III - PHYSICAL DATA PAGE : 02 BOILING PT. (FAHRENHEIT) VAPOR PRESSURE (MM HG). VAPOR DENSITY (AIR-1) PH 100% PERCENT. VOLATILE BY VOLUME (%) SOLUBILITY IN WATER VISCOSITY ! 165 | SPEC GRAVITY (K201) O <0 | COLOR AMBER {4.6 ! DOOR {CHLORINATED I N/A J CLARITY ,TRANSPARENT {82 { EVAPORATION RATE {5.0 i <BU AC - 1 ) 1 J NEGLIGIBLE [ VISCOUS 1 .050 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) NON-FLAMT.C.C. FLAMMABLE LIMITS EXTINGUISHING MEDIA 'ALCOHOL* X<--FOAM <-"FOAM X<--C02 ORY X<--CHEMICAL LEL ,'N/A WATER X<--SPRAY SPECIAL FIRE FIGHTING PROCEDURES SPRAY WATER ON AEROSOL CONTAINERS TO COOL THEM AND AVOID RUPTURING. UEL !n/a_................ <--OTHER UNUSUAL FIRE & EXPLOSION HAZARDS N/A LEVEL 1 AEROSOL (NFPA 306) _ ......................................................................... _........................................... NFPA HAZARD RATING (O-INSIGNt FI CANT ; 1"SLIGHT:2*M0DERAT E;3"H1GH;4*EXTREME ) : 3 <--HEALTH 1 <--FLAMMABILITY O <--REACTIVITY C--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. SAL 000007141 B-LU8C AEROSOL $ 6 3*(CONTINUE CTION V * HEALTH HAZARD DATA Mtt : 09 EFFECTS OF OVEREXPOSURE . ^ . J|M0BT T,,B eXFtSU.) HEADACHE. BLURRED VISION. NAUSEA. AND DIZZINESS. . _ __ - CHRONIC - _{LONG TERM EXPOSURE> ASPHYIXIATINQ U. PON PROLONGED BREATHING 0# CONCENTRATED VAPORS. MAJOR RESPONSE IS CNISS DEPRESSION. IRRITATING TO SKIN AND MUCOUS MEMBRANES. S PRIMARY ROUTE OP ENTRY: X<" INHALATION <-^lNGE$TION EMERGENCYB'FIRST AID PROCEDURES ABSORPTION MOVE TO*FSESH^A?R AND TREAT SYMPTOMATtCALLY. GIVE OXYGEN IF BREATHING IS DIFFICULT GIVE ARTIFICIAL RESPIRATION IF BREATHING STOPS. GET MEDICAL HELP. EYE CONTACT: ___ FLUSH WITH WATER 5- MINUTES. PERSISTS. SEE A PHYSICIAN IF IRRITATION SKIN CONTACT: WASH WITH SOAP AND WATER. ATTENTION. IF IRRITATION PERSIST. SEEK MEDICAL DO NOT 1 NOuSe * VOM1T1NG EVEN IF VOMITING OCCURS. IF IT OCCURS. KEEP HEAO BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS. MEDICAL ATTENTION IMMEDIATELY. 6ET NOTES TO PHYSICIAN : DEPENDING ON THE AMOUNT INGESTED ANO RETAINED A WELL AS THE TOXICITY OF THE PRODUCT. GASTRIC LAVAGE SHOULD BE EMPLOT__O___B_E__C_A_U__S__E___OF P_U_L_M_ ONARY ASPIRATION. I* CORUTOSE. A CUFFEO ENDOTRACHEAL TUBE WILL PREVENT ASPIRATION. CONSULT A p6lS0N CONTROL CENTER. SECTION VI > TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY 1ARC <--YES NTP <--VES 05K4 <--YES$ ACGIH <--YE5 OTHER <--YES X-*NO X<--N0 X<--NO X<--NO X<--NO 1,1.1 TR1CHL0R0ETHANE 0&L-HMN TOLO: B70MG/KG TFX:CN 2. IHL-HMN TCLO: 920PPM/MG TEX.CSN 2. ORL-RAT LD50: 10.300MG/KG 2. SECTION VII - REACTIVITY DATA STABILITY |X<--STA6LE <-UN5TABL CONOIDTIONS TO AVOID (CONTINUED) B-LUBE AEROSOL SECTION VII - REACTIVITY DATA INCOMPATIBILITY (MATERIALS TO AVOID) STRONG ALKALIES. ACIDS. AND SELECTED AMINES. HAZARDOUS DECOMPOSITION PRODUCTS CAN AT DECOMPOSITION TEMPERATURES RELEASE CARBON DIOXIDE. HYOROGEN CHLORIDE. ANO PHOSGENE. ANO CARBON MONOXIDE HAZARDOUS WILL NOT <--OCCUR MAY <--OCCUR CONDITIONS TO AVOID POLYMERIZATION N/A PAGE ; 04 SECTION VIM - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SPILL IS UNLIKELY, PRODUCT IS IN AN AEROSOL CONTAINER. IF SPILLED, PREVENT FROM ENTERING SEWER OR WATER SOURCES. VENTILATE ENCLOSED AREA. CLEAN UP WITH RAGS OR ABSORB WITH SAND. COTTON WASTE OR OTHER ABS0R6ANTS. WASTE DISPOSAL MCTHOO DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL. STATE AND LOCAL POLLUTION REGULATIONS. NORMAL METHOD: WRAP EMPTY CAN WITH SEVERAL LAYERS OF NEWS PAPER AND DISCARD IN TRASH. NEUTRALIZING AGENT N/A SECTION IX - SPECIAL PROTECTION INFORMATION REQUIRED VENTILATION SUFFICIENT VENTILATION TO BE EOUAL TO OR BELOW THE ALLOWABLE CONCENTRATION. RESPIRATORY PROTECTION TYPICAL USE OF PRODUCT DOES NOT REOUIRE THE USE OF A RESPIRATOR. PRODUCT IS MISTED. USE NIOSH APPROVEC MASK FOR SPRAY MISTS. IN EMERGENCY SITUATIONS. THE FOLLOWING RESPIRATORS ARE RECOMMENDED: SOOPPM CCR0V/SA/SC8A lOOOPPM CCROVF/GMOV/SAF/SCBAF ESCAPE: GM0V/SC6A PROTECTIVE GLOVES V1T0N, PVA OR EQUIVALENT FOR REPEATED OR PRO* LONGED SKIN CONTACT IS ANTICIPATED. IF SAL (CONTINUED) B-LUBE AEROSOL SECTION IX * SPECIAL PROTECTION INPORMATIOPAQE : 05 CYE PROTECTION CHEMICAL GOGGLES IP METHOO OP USE PRESENTS THE LIKELIHOOD OP EVE CONTACT. OTHER PROTECTION N/A GS63* SECTION X - STORAGE ANO HANDLING INFORMATION STORAGE TEMPERATURE 1 INDOOR 120 P.<--MAX 35 F.4--MIN j [HEATED \ PRECAUTIONS TO BE TAKEN IN HANDLING A STORING FOLLOW LABEL DIRECTIONS. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHI LOREN. REF8IGERATED{ OUTDOOR SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT 1,1,1 TRICHLOROETHANE 71-55-6 80 THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER * LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LA8ELE0 FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USED ANO LABELED FDR FACILITY GROUNDS MAINTENANCE <SUCH AS FERTILIZERS AND HERBICIDES), OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--1MC0 SHIPPING NAME HAZARD CLASS <- -TARIFF 6 D <--IATA <--MILI TARY AIR (APR ?t-4) | ID NUMBER S REPORT QTY (CONTINUED) B-LUBE AEROSOL SECTION XII - TRANSPORTATION (FOR FUTURE USE) LABELS UNIT CONTAINER | LIMITED QTY DOT SPS CONTAINER i NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) PAGE : 06 SECTION XIII - REFERENCES 1. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT, 2ND EDITION. ACG1H, 1965. 2. NIOSH REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES 1982. THE INFORMATION CONTAINED HEREIN IS BASED ON OATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION, HOWEVER. NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF NATIONAL CHEMSEARCH DIV. OF NCH CORP . ASSUMES WC RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. $Al 000o07I43 ^*1100000 TVS J FEU TOE 11S46 DELTA DISTRIBUTORS X NC P. 02 MATERIAL SAFETY DATA SHEET APPROVED BY U $ LABOR KPT, ESSENTIALLY SIMILAR TO FORM QSHA 174 PRODUCT IDENTITY* <^Tanfc Cleaner *2C^ I. SUPPLIER G S6 33 II. DaTR DISTRIBUTORS t4B24 ROOFER RB HOUSTON.TI 77047 PHONE; >13-433-6771 CHENTftEC PHONE: I-800-424-9300 HAZARDOUS INGREDIENTS MATERIAL Keavv Aronatic Solvent Naphtha tight Aroaatic Solvent Naphtha CAS 164742-94-3 164742*95-6 CAS I PEL <0$HA> IIV (ACS1H) too100 ppa too MO CEILlK 5-0 #g/cu 5.0 #g/cu PEAK (OSKA) None Know; None Known No AC61H STEL values given HAZARD RATING HEALTH (NFPA)i 0 HEALTH MUSH 3 FLAMMABILITY* 2 REACTIVITY: 0 DOT SHIPPING MAKE: CoibustiMl Li quid,WS (NAIMS) DOT MUM LABEL; None SARA TITLE III NT. Z (REG. SECTION) Not Applicable Not Applicable III. PHYSICAL DATA SOILING RAH6E t GRAVITY I 60*f i `API : m 211 2574'C / 3B9 412 494IT (l*End Point) 22.1 SP.GR. (Nat*r*l) : .V21 LB/6AL : VAPOR PRESSURE (A of HglWO .4 VAPOR DENSITY <air*l> i 4.6 HATER ABSORPTION t Moderate ACID ABSORPTION (851 Ht$04> Moderate DRY TINE (Ether*1) > t VOUTILE BY VOL : APPEARANCE : 1004 95.0 Liquid.Light Straw ODOR i HKB (Hydrogen Bonding) i Aroaatic 19.2 PK) (Polarity) : 39.4 m (Dispersion) : 41.2 REFRACTIVE INDEX : 1.530 NIXED AKIUHE POINT (Acid Insolli 23*C / 747 7.672 IV. FIRE & EXPLOSION HAZARDS LONER FLAMMABLE LIMIT in air a by volh '1.0 FLASH POINT (TEST METHOD)) 72*C t 162*F (TCCI FLAMMABILITY CLASSIFICATION: class 111 A EXTINGUISHING ) NFPA Clast I extinguishers <C0t or 4oa) MEDIA t Tor class 111 A liquid fires. SPECIAL FIRE ) Hater spray tay be ineffective on fire but can protect fire fighters k cool closed containers. FIGHTING ) Use fog AOtiies if water is used. So not enter confined fire-space without full PROCEDURES : bunker tear. (Heiwet with face shield, butter coats, gloves I rubber boots). i Use KIOSK approved positive-pressure self-contained breathing apparatus. UNUSUAL : COMBUSTIBLE! Keep container tightly closed, isolate free EXPLOSION t oxidizers, beat, k open fliit* AND FIRE ) Closed containers aay explode if exposed to extreae heat. PROCEDURES) Applying to hot surfaces requires special precautions. t Eepty container very hazardous! Continue all label precautions! legal responsibility is issuaed only for the fact that all studies reported here ( opinions are those of ualififd experts, buyer assuaes all risk k liability. He accepts t uses this aaterial on these conditjions. Si aust keep 4 copy of this MSBS where aaterial is handled. SAL 0000071^5 G 7-89 TUG 11S46 DELTA DISTRIBUTORS# rNC P . OS G S6 33 PRODUCT IDENTITY! a*5Tank Cleaner i?C V- REACT IV I TV DATA STABILITY r Stable CONDITIONS TO AVOID: Isolate free oxidizers, heat, l opeft flat*. AATEtlALS TO AVOID i Isolate tree strong oxidiamr* such as permanganates, chromates t peroxides. HAZARDOUS : Carbon Honoiide, Carbon Dioxide Tree burning. DECOMPOSITION: PRODUCTS : 0 VI. HEALTH HAZARD DATA ^ THRESHOLD UK1T VAUIEs Not Applicable PREVENTION t Vm ooIjt with adequate ventilation OF OVER* t Avoid prolonged breathing of vapor or spray oist. EXPOSURE i Avoid prolonged or repeated contact aith skin. ORGANIC EFFECTS: EYE I SKIN CONTACTS Prioary irritation to skin, defatting, derutitis. OF ACUTE OVER- s Prieary irritation to eyes, redness, tearing, blurred vision. * SNALL0N1NG: Manful or fatal if suallOMd. EXPOSURE : SaralfoariAo can cause abdooinal irritation, nausea, votitiog and diarrhea. ORGANIC EFFECTS} EYE t SKIN CONTACT: Liquid can cause eye irritation. OF CHRONIC : Nash thoroughly after handling. OVER* I EXPOSURE : CANCER HAZARD 5 ossitie cancer hazard based on tests *itft laboratory aniea/s using Ethylene Oxide. Overexposure say create cancer risk. CONDITIONS Persons with severe skin, liver or kidney problem should avoid use. A6GREVATC0 EMERGENCY l t In case of contact tfith skin, flush vith plenty of hater. For eyes, FIRST AID : flush Kith plenty of uater for 13 minutes k get oedical attention. PROCEDURES: After high vapor exposure, remove to fresh air. If breathing is difficult rt ive tfyoeft* If breathing has stopped give artificial respiration, f snalloued, CALL A PHYSICIAN !MEDIATELY! Never give anything by aouth to an unconscious person. VI X. SAFE HANDLING St USE PRECAUTIONS SPILL OR LEAK : Stop spill at source. Dike area l contain. Pump spilled liquid l put contaminated soil PROCEDURES : in DOT approved containers for disposal. Label immediately. : Clean up remainder uith absorbent oaterials. WASTE DISPOSAL : Dispose of vast* by legal methods coiplying ith local, state I Federal regulations. HETMOD : It questions exist, contact the appropriate agencies. OTHER i Store large aaounts in structures tide for 0SHA Class 111 A liquids. PRECAUTIONS : i Avoid tree fall of liquid. Ground containers Mhen transferring. Do not flame cut, braze or ueld. > Eepty container very hazardous! Continue all label precautions! VIII. CONTROL MEASURES RESPIRATORY PROTECTION: Not Applicable ISPECIFY TYPE) : VENTILATION i LOCAL EXHAUST i Necessary MECHANICAL (GENERAL) > Acceptable : SPECIAL : None OTHER : None PROTECTIVE : (Tear CSHA Standard goggles or face shield. Consult Safety Equipment Supplier. C10THIN6: Rear gloves, aproh 4 footwear impervious to this naterial. Hash clothing before reuse. DATE : 02/89 n c SAL 000007146 MATERIAL SAFETY DATA SHEET Substantially Similar to Form OMB No. 174 . ftODUCT NAMEl SUPER 8TEAM/HDL MANUFACTURERS Seatex Corporation 6325 Hurst St. ~'1ERGNCY TELEPHONE NO.1713-868-1461 DATE PREPARED106/27/S9Houston, Tx. 77006 HAZARDOUS INGREDIENTS Sodium Hydroxide C.A.S. # 1310-73-2 OSHA PEL/TLV 2 mg/m3 mg/m3 mg/m3 ACGIH TLV 2 mg/m3 mg/m3 mg/m3 STEL OTHER LIMITS mg/m3 None mg/m3 mg/m3 HEALTH - 2 FIRE -O REACTIVITY -O SPECIFIC HAZARD -Aik BOILING POINT - 212 DEG.F FLASH POINT - DE6.F METHOD USEDs CQC SPECIFIC GRAVITY - 1,09 EVAPORATION RATE (BUTYL ACETATE*1) t 1 '/.VOLATILE* PHYSICAL DESCRIPTIONi Yellow-green, water clear liquids mild odor. na FLAMMABLE LIMITS! LEL - na UEL - na EXTINGUISHING MEDIA! Material will burn. SPECIAL FIRE FIGHTING PROCEDURES Firefighters should wear selfcontained breathing apparatus as in all chemical fires. UNUSUAL FIRE AND EXPLOSION HAZARDS! None not UNSTABLE - STABLE - X HAZARDOUS DECOMPOSITION PRODUCTStMay produce oxides of carbon upon oxidation. CONDITIONS TO AVOID* MATERIALS TO AVOID* Strong acids, strong oxidizing agents. HAZARDOUS POLYMERZATIONi WILL NOT OCCUR POSSIBLE ROUTES OF ENTRY* INHALATION CUTE HEALTH HAZARD*Dehydration and uurning of all caucus membranes. CHRONIC HEALTH HAZARD!' - Yes INGESTION -Yes SKIN defatting of skin. Severe -Yes irritation and CARCINOGENICITY! NTP -No IARC MONOGRAPHS -No OSHA REGULATED -No ORAL LD/50 - Unknown DERMAL IRRITATION - Serious EYE IRRITATION - Severe SYMPTOMS OF EXPOSURE! EYE -- Irritation, burning. 6KIN - Irritation, burning. INHALATION - Irritation and damage to mucus membranes. INGESTION -Irritation and damage to mucus membranes. CONDITIONS AGGRAVATED BY EXPOSURE -Unknown FIRST AID SKINi Flush with water and neutralize with vinegar. SAL 000007147 EYESt Flush with water for 15 minutes. See a physician immediately. iNHALATZONl Remove to fresh air. INGESTIONi IJrink water or milk followed by citrus juice. See a physician mediately. SPILL SAFETY*Stop, leak, dilute material spilled with acetic acid <vinegar) to less than pH lO. DISPOSAL INFORMATION! Flush diluted material to sewer. ------------- GS448 A. *IAL SAFETY DATA SHEET pg* 2 TORAGE AND HANDLINGS Store in a dry,cool place. ERSONAL HY6ENE* ESPIRATORY PROTECTION - Ye* YPE -- Mist mask. \ ENTILATION* ENERAL MECHANICAL - X LOCAL - SPECIAL - None required RDTECTIVE EQUIPMENT REQUIRED! :UBBER GLOVES - X RUBBER APRON ACE SHEILD - RUBBER BOOTS - CHEMICAL SPLASH GOGGLES - X SHIPPING INFORMATION! >0T LABLE NONE REQUIRED - X REQUIRED - ORROSIVE - OXIDIZER - POISON - FLAMMABLE(COLOR> J.N. NUMBER - NOT REQUIRED - X - < > SPECIAL INFORMATIONS CREATED BY S.K SAL 000007148 r MATERIAL SAFETY.DATA SHEET Emergency Telephone Consumer Product* Oivaioft, Division ot Borden. Inc. 4) *57-5200 180 EAST BROAD STREET. COLUMBUS. OHiO 4321S (OPERATION ALERT) THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 REQUIRES THAT THE INFORMATION CONTAINED ON THIS SHEET BE MADE AVAILABLE TO YOUR WORKER INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY NAME ~KRYL0N CRYSTAL CLEAR 5PRAY COATING (J S 6 26 TYPE: AEROSOL ACRYUC SPRAY 22-Nov-85 APPLICATION: ITEMS 1301,1302, 1303, 1304___________________________________________ ______________ SIGNAL WORD--DANGER! THIS MATERIAL IS A '`HEALTH HAZARD" ANO/OR A "PHYSICAL HAZARD" AS DETERMINED WHEN REVIEWED ACCORDING TO THE REQUIREMENT Of THE OCCUPATIONAL SAfETY AND HEALTH ADMINISTRATION 29 CFR PART 1910.1200 "HAZARD COMMUNICATION" STANDARD. CHEMICAL HAZARD RATING HEALTH=2(M00ERATE) FlftE*=4(EXTREM) REACTIVITY *0(LAST) 29CFR1918.1200 HAZARDOUS MGREOIENTSIREPORTEO HEALTH EfffCTS CAS REGISTRY NO. MATERIAL DESCRIPTION Vo BY WT. 67*64*1 ACETONE 11.2 CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. CiZ2)NE$$, NAUSEA, VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. ACG1H EXPOSURE LIMIT: 750 PPM, 8-HR TWA OSHA 29CFR191Q EXPOSURE LIMIT: 1000 PPM. 8*HR TWA NIOSH .miMENT NUMBER: 78*173 74*98*6 PROPANE 12.9 THIS MATERIAL IS A SIMPLE ASPHYXIANT. SIGNS AND SYMPTOMS OF OVEREXPOSURE INCLUDE CYANOSIS. RESPIRATORY DISTRESS. HEADACHE. DI22INESS, DROWSINESS, UNCONSCIOUSNESS AND ASPHYXIATION. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. ACGIH EXPOSURE LIMIT: SEE ACGIH TLVS. APPENDIX E OSHA 29CFR1910 EXPOSURE LIMIT: 1000 PPM, 8-HR TV/A 75-28*5 ISGflUTANE * 17.1 10548*3 TOLUENE OVEREXPOSURE MAY CAUSE LIVER DAMAGE. 11.1 OVEREXPOSURE MAY CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS. NAUSEA. VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. ACGIH EXPOSURE LIMIT: 100 PPM. 8-HR TWA OSHA 29CFR1910 EXPOSURE UMiT: 200 PPM. 8-HR TWA NIOSH DOCUMENT NUMBER: 73*11023 142*82*5 HEPTANE 22.4 CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, OlZZINESS. NAUSEA. VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION ACGIH EXPOSURE LIMIT: 400 PPM,'8*HR TWA OSHA 29CFR1910 EXPOSURE LIMIT: 500 PPM. 8-HR TWA NIOSH DOCUMENT NUMBER: 77-151 1330-20*7 XYLENE 15. OVEREXPOSURE MAY CAUSE LIVER DAMAGE OVEREXPOSURE MAY CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS. NAUSEA, VOMITING. UNCONSCIOUSNESS ANO EVEN'ASPHYXIATION. 'ACGIH EXPOSURE LIMIT: 100 PPM, 8-HR TWA OSHA 29CFR1910 EXPOSURE LIMIT: 100 PPM. 8-HR TWA NIOSH DOCUMENT NUMBER: 75-168 64742-94*5 HEAVY AROMATIC SOLVENT NAPHTHA (PETROLEUM) 2. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS, NAUSEA. VOMITING. UNCONSCIOUSNESS ANO EVEN ASPHYXIATION. PHYSICAL DATA VAPOR PRESSURE - SEE CAN PRESSURE VAPOR DENSITY HEAVIER THAN AIR SOLUBILITY IN WATER - SLIGHT SPECIFIC GRAVITY LIGHTER THAN WATER cVAP RATE FASTER THAN BUTYL ACETATE BOILING POINT; APPEARANCE; ODQR-N.A. PERCENT. VOLATILE BY WEIGHT: 94 PERCENT NON-VOLATtlE BY WEIGHT: 6 PRESSURE IN CONTAINER. PSlG 70 f. APPRQX 60 ACUTE HEALTH HAZARD DATA SKIN ABSORPTION: NO HAZARDS KNOWN TO BORDEN, INGESTION: MAY BE HARMFUL IF SWALLOWED. INHALATION: MAY BE HARMFUL IF INHALED. LIQUID OR VAPOR CAN CAUSE IRRITATION OF NOSE. THROAT AND LUNGS. SKIN: CAUSES IRRITATION. EYES. CAUSES IRRITATION. HANDLING PRECAUTIONS INHALATION: AVOID BREATHING VAPOR OR MIST. USE WITH ADEQUATE VENTILATION. SKIN: AVOID CONTACT WITH SKIN. EYES: AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. EMERGENCY AND FIRST AID PROCEDURES INTERNAL: If SWALLOWED, DO NOT INOUCE VOMITING. CALL A PHYSICIAN IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. SKIN CONTACT: FLUSH SKIN WITH WATER. IF IRRITATION PERSISTS, CAU A PHYSICIAN. EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CAU A PHYSICIAN. ' SEE REVERSE SIDE DISCLAIMER--SEE REVERSE SIDE NOR (M) KD-1301 11/13/85 SAL 000007149 ft S 6 2JS________________ AND EXPLOSION HAZARD OATA EXTREMELY FLAMMABLE. CONTENTS UNOER PRESSURE; EXPOSURE TO HIGH TEMPERATURE MAY CAUSE BURSTING. AVOIO RADIATORS. STOVES. DIRECT SUNLIGHT, OR OTHER HEAT SOURCE, oo not puncture or incinerate container. do not spray near open flame.____________________ REACTIVITY DATA *' NORMALLY STABLE AS DEFINED IN FNPA 704-12(4.3.1). MAJOR DECOMPOSITION PROOUCTS; CO. COa SPECIAL PROTECTION INFORMATION APPROVED RESPIRATORY PROTECTION REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. USE GOGGLES OR FACE SHIELD If SPLASHING IS LIKELY. WEAR IMPERVIOUS GCOVES AS REQUIRED TO PREVENT SKIN CONTACT, WEARING SAFETY GLASSES, SAFETY SHOES. HARO HATS AND Suitable Clothing is standard practice in many INDUSTRIAL OPERATIONS._____________________________ _ SPILL OR LEAK PROCEDURES ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BOOJES OF WATER. WASTE DISPOSAL METHOO DISPOSE OF ACCORDING TO LOCAL. STATE. AND FEDERAL REQUIREMENTS. EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT. PUNCTURE OR WElO ON OR NEARBY. INCINERATION WILL CAUSE CONTAINER TO BURST VIOLENTLY. STORAGE PRECAUTIONS 00 NOT STORE AT TEMPERATURES OVER 120 F. DOT CLASSIFICATION 0RM*0 CONSUMER COMMODITY NOR (M) KD-1301 11/13/85 DISCLAIMER seller makes no warranty, express or implied, concerning the product or THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY BORDEN, except that the product shall conlorm to contracted specifications, and that the product does not infringe any valid United Slates patent. The information provided herein was believed by Borden to be accurale at the time of preparation or prepared from sources believed to bo reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all Jaws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any Kind, whether as to product delivered or for non-delivery of product, and whether based on contract, breach of warranty, negligence or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seiler be liable for incidental or consequential damages, whether Buyer's claim is based* on contract, breach of warranty, negligence or otherwise. SAL 000007150 MATERIAL SAFETY DATA SHEET ! uOX 949 Amarillo, Texas 79105 Product Name: MR. MICRO PROCESSOR CLEANER Number: 1680 Aerosol Emergency Phone: 806-372-8523 8 86 27 Hazardous Description: Compressed Gas N.O.S. Non-Flammable Gas UN1956 Hazard Rating Health: i Fire: 0 Reactivity: 1 0-Least 1-Slight 2-Moderate 3-High 4-Extreme I - HAZARDOUS COMPONENTS Ingredient 1,1,2-Trichlorotrifluoroethane (Freon TF) CAS No. 76-13-1 % 74 Hazard OSHA F'EL lOOOppm ACGIH TLV lOOOppm (STEL 1250ppm) Diehl orodifluoromethane Carbon Dioxide 75-71-8 25 124-33-9 '--i OSHA PEL lOOOppm ACGIH TLV lOOOppm OSHA PEL 5000ppm ACGIH TLV 5000ppm II - PHYSICAL DATA Boiling Point: 47 C Specific Gravity: NIF Solubility in Water: O Vapor Density (Air -- 1): Appearance: Clear 116 F 6.5 water-white mobile liquid pH: NA % Volatile: 1O0 % Solids: O Evaporation Rate (HsO -- 1): NIF with slioht ethereal odor. Ill - FIRE AND EXPLOSION HAZARD DATA FlashPoint: None TCC Method Explosion Limits LEL: NA UEL: Extinguishing Media: water, -foam,, dry chemical, carbon dioxide. Special Fire Fighting Procedures: Fire fighters should wear self contained, positive-pressure apparatus and avoid skin contact. NA breathing Unusual Fire and Explosion Hazards: SAL 000007151 Aerosol cans may erupt with force at temperatures above i:zu aegrees F. NA - Not Applicable (continued on next page) NE Not Established 1680 Aerosol ~S627 IV-HEALTH HAZARD DATA Effects of Overexposure INHALATION: Major route of exposure. Vapor is heavier than air and can cause suffocation by reducing the available oxyqen for breathing. Breathing high concentrations of vapor may cause light-headedness, giddiness, shortness of breath, confusion, and may lead to narcosis, cardiac irregularities, unconsciousness or even death. EYES: Liquid can cause slight, temporary irritation with slight temporary corneal injury. Vapors can irritate eyes. SKIN: Not a corrosive or irritant; however, repeated or prolonged exposure can cause defatting of skin. INGESTION: Single dose toxicity is low to moderate. If vomiting occurs the liquid can be aspirated into lungs, which can cause chemical pneumonia and systemic effects. Human psychotropic, gastrointestinal, and central nervous system effects possible. emergency and First Aid Procedures INHALATION: Remove to fresh air. If breathing has stopped, administer artificial respiration. Seek medical attention. EYES: Flush eyes for at least fifteen minutes with clear water. If irritation persists, seek medical attention. SKIN: Wash with soap and water. INGESTION: DO NOT INDUCE VOMITING! Give 2 glasses of water and immediately seek medical attention. NOTE: Adrenalin and' other similar cardiac stimulants should NOT be used to treat effects of overexposure to this product. See section I. None of the ingredients in this product are listed on the 05HA, IARC, NTP list of possible carcinogenic, mutagenic, or teratogenic chemicals. V - REACTIVITY DATA SAL 0o0071s? Stability: STABLE Incompatibility (materials to avoid) Conditions to Avoid: Contact Reactive alkali metals, strong acids & bases. Hazardous Decomposition Products: Hydrogen chloride, phosgene, chlorine, carbon Hazardous Polymerization: WILL NOT OCCUR Conditions to Avoid: None with open flame, heat. dioxide, and carbon monoxide. frnntimiPd on next Daoe) NE - Not Established 1680 Aerosol VI SPILL OR LEAK PROCEDURES 6 S 6 27 Evacuate area. Ventilate area well and avoid breathing vapors. Vapor ncentration will be highest along floor and in low lying areas. Pick up quid on suitable absorbent and store in sealed containers. VII - WASTE DISPOSAL METHODS Material may be disposed of by a licensed reclaimer or incineration facility. Consult local, state, and federal disposal authorities for approved procedures. Do not incinerate or destroy aerosol cans. VIII - EMPLOYEE PROTECTION Respiratory Protection: Use NI OSH approved organic vapor mask. Ventilation: Do not use in closed space. Ventilation required. Hands: Solvent resistant gloves such as Neoprene or PVA. Eyes: Wear splash proof safety goggles or glasses. Special Precautions: Keep aerosol cans in cool place out of direct sunlight. Keep this and all chemicals out of reach of children. This product for industrial use only. IX - OTHER INFORMATION NA - Not Applicable Prepared By: J. Witcher sAL 000007153 Date: 8-15-89 NE * Not Established Chemtronics OSHA Safety Data Sheet Static Free Cl 600 IDENTIFICATION Name: Static Free Synonym*: Freon' TF, Freon' 113. IPA CAS Name: 1.1.2-Tnchloro1.2,2-Trifluoroethane Isopropanol Carbon Oioxide Propellant Ann-Static Agent Chemical Family: Halogenated hydrocarbon, alcohol Formula: CCl?FCF?CI CH?CHOHCH3 CAS Registry No.: 76-13-1 67-63-0 124-38-9 N/A Manufacturer. Chemtronics Inc. 661 Old Willets Path Hauppauge. NY 11788 Medical/Transporfahon Emergency Phone: 516-582-3322 PHYSICAL DATA (Propellant Free Basis) Boiling Point (F): 118 (initial) Density: t.54 (5) 70F Vapor Density (Air - 1): ^ 1 pH Information: N/A Form: Volatile solution Color Colorless Percent Volatile by Volume: 99 Vapor Pressure: 474 mm Hg @ 70F Solubility in H20: Negligible Evaporation Rate (Ether --1): > 1 (faster) Appearance: Clear Odor Slight alcohol-hke HAZARDOUS COMPONENTS Material(s): 1.1,2-Tnchloro- Approximate Vc - 1,2,2-Trifluoroethane -- Isopropanol Carbon Dioxide Propellant * - 4 Coco Alkylbis (2-Hydroxyethyl) Methyl Ammonium Chlorides -- V HAZARDOUS REACTIVITY Stability: Materials are stable but cans are under pressure. Avoid spraying near open flame or red hoi surfaces. Decomposition; Can be decomposed by high temperatures (open (lames, glowing surfaces, etc.) lorming halogen acids, phosgene in small amounts. Incompatibility: Finely divided reactive metals--powdered Al, Zn. Be. etc. Polymerization: Will not occur. FIRE AND EXPLOSION DATA f ish Point Nonflammable Method: Not determined / utoignition Temperature: Not determined Flammable Limits in Air, % by Vol.: Lower Not determined Upper; Not determined Autodecomposition Temperature: Not determined. Fire and Explosion: Pressurized aerosol containers at elevated temperatures may vent, rupture or burst and add to flying and falling debris. Intense heat may cause decomposition with emission of halogen acids. Extinguishing Media: Special Fire Fighting Nonflammable instructions: Self-contained breathing apparatus ($C8A) may be required if aerosols rupture and contents are spilled under fire conditions. G-S6 28 HEALTH HAZARD INFORMATION Principal Health Hazards: Inhalation: Excessive inhalation of concentrated vapor can cause light-headedness, giddiness, shortness of breath, dizzi ness and may lead to narcosis, anesthesia, cardiac irregu larities. unconsciousness or death. Trichlorotrifluoroethane LC 50 Rats 52.000 ppm/4 hrs. Eye: Coniact may cause irritation. Oral: Allhough oral toxicity is low (Trichtorotrifluoroethane LD 50 Rats 43.000 mg/kg) ingestion ol this material is to be avoided. Skin: Contact may cause dryness and irritation. This material is poorty,absorbed through the skin (Trichlorotrifluoroethane Rabbit ALD > 11.000 mg/kg). Exposure Limits: Material: Trichlorolrifluoroethane Isopropanol TLV(ACGIH): lOOOppm 460 ppm PEL(OSHA): 1000ppm 400ppm Safety Precautions: Avoid breathing vapors and prolonged skin exposure. Use only in well-ventilated area. First Aid: Inhalation: Excessive vapor inhalation: Move patient to fresh air. If necessary, give artificial respiration or oxygen. OO NOT give epinephrine or similar drugs as such drugs may induce ventricular arrhythmia. Eye. Immediately flush with plenty of water for at least 15 minutes. Call a physician. Skin: Flush with waler Get medical attention if irritation is present. Oral: No specific intervention is indicated as the compound is not likely lo be hazardous by ingestion. However, consul! a physician if necessary. DO NOT induce vomiting as the hazard of aspirating the material into the lungs is a greater hazard than allowing it to progress through the Gl tract. Note to Physician: Because of possible increased risk of eliciting cardiac dysrythmias. catecholamine drugs, such as epinephrine, should be considered only as a last resort in life-threatening emergencies. Medical Conditions Possibly Aggravated by Exposure: Cardiovascular Disease: See Principal Health Hazards. In halation Section. Other Health Hazards: Freon" 113, is not listed as a carcinogen by IARC, NTP or OSHA. Based on animal studies and human experiences, this fluorocarbon poses no direct hazard to man relative to systemic toxicity, carcinogenicity, mutagenicity or teratogen icity when occupational exposures are below its TLV. Isopro panol is listed on NTP carcinogen list and IARC potential carcinogen list. sM_ 00000*7154- ^S628 PROTECTION INFORMATION Generally Applicable Control Msenrer Normal ventilation. Local exhaust should be used when large amounts are released. Mechanical ventBation should be used in low places. Personal Protective Equipment; Do not spray liquid on skin. DISPOSAL INFORMATION SpW, Leek or Release: Ventilate area. Remove open flames or red hot surfaces. Alow to evaporate. Waste Disposal: Allow to evaporate Do not puncture or incin erate aerosol cans. Comply with federal, slate and local regulations. SHIPPING INFORMATION Domestic--Other Than Air (DOT): Proper Shipping Name: Consumer Commodity Hazard Class: ORM D UN No.: DOT Label: DOT Placard: International Water or Air (IMO/ICAO): Proper Shipping Name: Aerosol, nonflammable gas NOS. Hazard Class: 2 UN No~ I960 IMO/ICAO Label: Aerosol, nonflammable gas contains CO? OTHER INFORMATION Shipping Containers: Aerosol Cans Storage Conditions: Do not store near sources of heat in direct sunlight or where temperatures exceed 120"F. Do not puncture or damage containers. Rotate stock. Date Revised: 6/87 Person Responsible: S.H. Stein, Ph.D. * Chemtronlcs Inc. 681 Old Willets Path Hauppauge, NY 11788 (516) 582-3322 The information contained herein is based on current technical data and tests which we beiieo* lo be accurate and ratable. It is intended for use by pertoro having lechnicaJ krvxrieOge and skiA, at their own discretion and risk. VA can assume no tiabdity tor result* obtained or damage* incurred trough improper use of product or application of data Contact Chemtrorucs for hsmer information. 'Registered trademark of E.I. DuPont De Nemours & Company (Inc.) SAL 000007155 Chemtronics OSHA Safety Data Sheet Freez-lt/Freez-lt Antistat Cl50, C220, C150-S, C151 IDENTIFICATION Name: Freez-lt Synonyms: Freon* 12. FC-12 Dymel* 12. Dichlorodifluoromethane CAS Name: Methane, Dichlorodifluoro Chemical FamHy: Halogenated Hydrocarbon Formula: CCGFj CAS Registry Noj 75-71-8 Manufacturer Chemtronics Inc. 681 Old Wiiiets Path Hauppauge, NY 11788 Medical/Transporlalion Emergency Phone: 516-582-3322 PHYSICAL DATA Boiling Point (F): -21.6 Density: 1.311 g/cc @ 77 F Vapor Density (Air=1): 4.2 pH Information: Neutral Form: Liquefied Gas Color Colorless Percent Volatile by Volume: 100 Vapor Pressure: 80 psig @ 77 F Solubility in HzO: ' 0.028% by wt @ 77 F Evaporation Rale (Ether=1):>8 Appearance: Clear Odor Slight ethereal odor HAZARDOUS COMPONENTS No carcinogens as per OSHA. IARC and NTP lists. Maleriat(s): Approximate %: Dichlorodilluoromethane 100 HAZARDOUS REACTIVITY , Stability: Material is stable. However, avoid open flames and high temperatures. Decomposition: Can be decomposed by high temperatures (open flames, glowing surfaces, etc.) forming hydrochloric and hydrofluoric acids, possibly carbonyl halides. Incompatibility: Alkali or alkaline earth metals--powdered Al. Zn, Be. etc. Polymerization: Will not occur. FIRE AND EXPLOSION DATA Flash Point: None Autoignition Temperature: Not determined Method: TOC Flammable Limits in Air, % by VoL Lower: Nonflammable Upper Nonflammable Autodecomposilion Temperature: Not determined Fire and Explosion: Pressurized aerosol containers at elevated temperatures may vent, rupture or burst and add to flying and failing debris. Intense heat may cause decomposition with emission of halogen acids. Extinguishing Media: Nonflammable Special Fire Fighting Instructions: Self-contained breathing apparatus (SCBA) may be required if aerosol cans rupture and contents are released under fire conditions. G S 6 29 HEALTH HAZARD INFORMATION Principal Health Hazards: Inhalation: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Breathing high concentrations of vapor may cause light-headedness, giddi ness. shortness of breath, and may lead to narcosis, cardiac irregularities, unconsciousness or death. LC 50 Rats, 800,000 ppm/30 min. Skin: Liquid contact can cause frostbite. Eye: Liquid contact can cause frostbite. Tests in rabbit eyes with a 50% solution in mineral oil and with vapors resulted in no observable damage. Oral: Rats were fed Dichlorodifluoromethane dissolved in peanut oil. No deaths occurred at highest feasible dose 1000 mg/kg. Exposure Limits: Material: TLV(ACGIH): Dichlorodifluoromethane 1000 ppm PEL (OSHA): 1000 ppm .Safety Precautions: Avoid breathing vapors and liquid contact with skin or eyes. Use only in well-ventilated area. First Aid: Inhalation: Remove to fresh air. call a physician. If not breath ing. give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Do not give epinephrine or similar drugs. . Eye: In case of liquid contact, immediately Hush eyes with plenty of water.tor at least 15 minutes. Call a physician. Skirt Flush with water. Treat for frostbite if necessary. Note to Physician: Because of a possible increased risk ol eliciting cardiac dysrythmias, catecholamine drugs, such as epinephrine, should be considered only as a last resort in life-threatening emergencies. Medical Conditions Possibly Aggravated by Exposure: Cardiovascular Disease: See Principal Health Hazards, Inhala tion Section. Other Health Hazards: Dichlorodifluoromethane is not classified as carcinogenic by IARC. NTP or OSHA. Based on animal studies and human experiences this fluorocarbon poses no hazard to man relative to systemic toxicity, carcinogenicity, mutagenicity or teratogenicity when occupational exposures are below its TLV. PROTECTION INFORMATION Generally Applicable Control Measures: Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should be used when large amounts are released. Mechanical ventilation should be used in low places. Personal Protective Equipment: Lined butyl gloves should be used when handling liquid. Chemical splash goggles should be worn when handling liquid. Under normal manufacturing conditions, no respiratory protection is required when using this product. Self-contained breathing apparatus (SCBA) is required if a large release occurs. SAL 000007156 GS6 29 DISPOSAL INFORMATION_______________________________ Spill, Leak or Release: Ventilate area--especially low places where heavy vapors might collect. Remove open flames. Waste Disposal: Allow to evaporate. Do not puncture or incinerate aerosoi cans. Comply with federal, state and local regulations. SHIPPING INFORMATION Domestic--Other Than Air (DOT): Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D UN No.: DOT Label: DOT Placard: International Water or Air (IMO/1CAO): Proper Shipping Name; Dichlorodifluoromethane Hazard Class: 2 UN No.: 1028 IMO/lCAO Label: Nonflammable Gas OTHER INFORMATION Shipping Containers: Aerosol Cans Storage Conditions: Do not store near sources of heat, in direct sunlight or where temperatures exceed 49*C/120*F. Do not puncture or damage containers. Rotate stock. Date Revised: 6/87 Person Responsible: S.H. Stein, Ph.D. ( Chemtronics Inc. 681 Old Willets Path Hauppauge, NY 11788 (516) 582-3322 , The information contained herein is based on current technical data and tests which we believe to be accurate and reliable, ft is mended tor use by person* having technical knowledge and skiH. at their own discretion and risk. We can assume no liability lor results obtained or damages ncurreo through improper use ol product or application of data. Contact Chcmuorvcs tor further information. Registered trademark of E-l. Du Pont De Nemours a Company fine.) SAL 000007157 Chemtronics OSHA Safety Data Sheet Electro-Wash C80, Cl 60, C240, C240-4 IDENTIFICATION Name: Chemical Family: Electro-Wash Halogenated Hydrocarbon Synonyms: Formulae Trichlorotrifluoroethane. CCI2FCCIFj/CCI3F/C02 Freon'TF, FC-113, Trichloro- Tluoromethane, R-11, Freon* 11 CAS Name: CAS Registry Noj 1,1,2-Trichloro-1.2,2-Tri- fluoroelhane 76-13-1 Trichlorofluoromethane 75-69-4 Carbon Dioxide Propellant 124-38-9 Manufacturer: Chemtronics Inc. 681 Old Willets Path Hauppauge, NY 11788 Medical/Transportation Emergency Phone: 516-582-3322 PHYSICAL DATA (Propellant Free Basis) Bolling Poinl (F): 75-118 Density: 1.46 g/cc @ 77F Vapor Density (Air=1): 4.6 @ 77 F pH Information: Neutral Form: Liquid Color Colorless Percent Volatile by Volume: 100 Vapor Pressure: 334mm Hg @ 77*F Solubility irrHjO: Negligible Evaporation Rate (Ether=1): 1 Appearance: Clear Odor Faint solvent odor HAZARDOUS COMPONENTS No carcinogens as per NTP, IARC or OSHA lists. Material(s): Trichlorotrifluoroethane Trichlorofluoromethane Carbon Dioxide Propellant Approximate %: 20-50 50-70 3 ,, HAZARDOUS REACTIVITY Stability: Material is stable. However, avoid spraying near open flames or red hot surfaces, Do not heat aerosol containers above 49C/120*F. Decomposition: This compound can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrochloric and hydrofluoric acids, possibly carbonyl halides. Incompatibility: Alkali or alkaline earth metals--powdered Al. Zn, Be. etc. Polymerization: Will not occur. FIRE AND EXPLOSION DATA Rash Point None Method: TOC Autoignition Temperature: Not determined , Flammable Limits in Air, *k by VoL Lower: Nonflammable Upper Nonflammable Autodecomposition Temperature: Not determined. Fire and Explosion: Pressurized aerosol containers at elevated temperatures may vent, rupture or burst and add to flying and falling'debris. Decomposition may occur. Extinguishing Media: Nonflammable Special Fire Fighting Instructions: Self-contained breathing apparatus (SCBA) may be required rf aerosols rupture and contents are spilled under fire conditions. G SM 3 0 HEALTH HAZARD INFORMATION Principal Health Hazards: Inhalation: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Breathing high concentrations of these products can cause light-headedness, giddiness, shortness of breath, and may lead to narcosis, cardiac irregularities, unconsciousness or death. Trichloro trifluoroethane LC 50 Rats 52.000 ppm/4 hrs. Trichlorofluoromethane LC 50 Rats 26,200 ppm/4 hr. Skin: Not a corrosive or irritant after single contact However, repeated liquid contact can cause defatting of the skin resulting in irritation. This material is poorly absorbed through the skin (Tpchlorotnfluoroethane Rabbit ALD> 11,000 mg/kg). Eye: Liquid contact can cause discomfort usually no extended effect Oral: Although oral foxicity is low (Trichlorotrifluoroethane LO 50 Rats 43,000 mg/kg; ALD for Trichloroftuoromethane is greater than 37.25 mg/kg in Rats) ingestion of Trichlorotrifiuoroethane is to be avoided. Exposure Limits: Material: Trichlorotrifluoroethane Trichlorofluoromethane Carbon Dioxide Propellant TLV (ACGIH): 1000 ppm 1000 ppm 5000 ppm PEL (OSHA): 1000 ppm 1000 ppm 5000 ppm Safety Precautions: Avoid breathing vapors and prolonged skin exposure. Use only in well-ventilated area. First Aid: Inhalation: Remove to fresh air, call a physician. If not breath ing, give artificial respiration, preferably mouth-to-moulh. If breathing is difficult give oxygen. Do not give epinephrine or similar drugs. Eye: Immediately flush with plenty of water for at least 15 minutes..Call a physician. Skin:' Flush with water. Get medical attention if irritation is present. Oral: No specific intervention is indicated as the compound is not likely to be hazardous by ingestion. However, consult a physician if necessary. Do not induce vomiting as the hazard of aspirating the material into the lungs is a greater hazard than allowing it to progress through the intestinal tract Note to Physician: Because of possible increased risk of eliciting cardiac dysrythmias, catecholamine drugs, such as epinephrine, should be considered only as a last resort in life threatening emergencies. Medical Conditions Possibly Aggravated by Exposure: Cardiovascular Disease: See Principal Health Hazards. Inhala tion Section. Other Health Hazards: Electro-Wash is not listed as a carcinogen by IARC. NTP or OSHA. Based on animal studies and human experiences, this mixture poses no hazard to man relative to systemic toxicity, carcinogenicity, mutagenicity or teratogenicity when occupational exposures are below its recommended TLV. SAL 000007158 G S6 SO PROTECTION INFORMATION Generally Applicable Control Measures: Normal ventilation (or standard manufacturing procedures is generally adequate. Local exhaust should be used when large amounts are released. Mechanical ventilation should be used in low places. Personal Protective Equipment Butyl gloves should be used to avoid prolonged or repeated exposure. Chemical splash goggles should be available for use as needed to prevent eye contact Under normal manufacturing conditions no respira tory protection is required when using this product Selfcontained breathing apparatus is required if a large spill occurs. Do not spray liquid on skin. DISPOSAL INFORMATION__________________ __ Spill, Leak or Release: Ventilate area. Remove open flames or red hot surfaces. Alow to evaporate. Waste Disposal* Allow to evaporate. Do not puncture or incinerate aerosol cans. Comply with federal, state and local regulations. SHIPPING INFORMATION Domestic--Other Than Air (DOT): Proper Shipping Name; Consumer Commodity Hazard Class: ORM-O UN No.: DOT Label: DOT Placard: International Water or Air (IMO/ICAO): Proper Shipping Name: Aerosol, nonflammable, NOS Hazard Class: 2 UN No.: 1950 IMO/ICAO LabelAerosol. nonflammable gas, contains C02 OTHER INFORMATION_________________________ ________ Shipping Containers: Aerosol Cans Storage Conditions: Do not store near sources of heat, in direct sunlight or where temperatures exceed 120" F. Do not puncture or damage containers. Rotate stock. v Date Revised: 6/87 Parson Responsible: S.H. Stein, Ph.D. Chemtronics Inc. 691 Old Wiilets Path Hauppauge, NY 11788 (516)582-3322 SAL 0000071 R 9 The information contained hereto t* based on current technical data and tests which we believe to be acoxete and reliable. It is intended (or use by persora having technical knowledge and skin. at their own discretion and risk. We can assume no liability tor mutts obtained or damagee etcurred through improper usd of product or application of data. Contact Cbemiromc* (or turther information. Registered traoemaru of E.I. Du Pont De Nemours & Company (Inc.) mELMtltM MATERIAL SAFETY DATA SHEET K-9290-9 Refinery cokar water clarifier MSPS NOl 05007509 6S624 MANUFACTURBR/SUPFUER: Wtlchtn, Inc. P, 0. Eos 920941 Houston, Texas 77292-0941 TIL* (713) 462-4763 EMERGENCY HEALTH INFORMATION: (600) 447*3735 EMERGENCY SPILL INFORMATION! ($00) 424-9300 CMZMTRIC, U.S.A. OTHER PRODUCT SAFETY INFORMATION) (312) $56-3516 IMPORTANT COMPONENTS: Hydrophvllic polyacrylate: trad# secret polymerized polyol: trad# secret. No exposure limit established. warning statement: Danger! cause* eye damage and akin burns. Can cause of the south, throat and eshophagut. HMIS/NFPA CODES: lHSAlTH;3MrLAMMAHILm;l)(REACTIVITY;!) APPEARANCE AND ODOR: Clear, viscous solution. irritation HEALTH HAZARD INFORMATION EYE EFFECT! causes eye damage. first AID: immediately flush eyes with plenty of water for at least 15 minutes, then get immediate medical attention. PROTECTION: Do not get in eyes. Wear chemical goggle#. SKIN EFFECT: Causes skin burns. FIRST AID: Immediately wash exposed skin vith soap and water. Get prompt medical attention if irritation develops. Remove contaminated clothing, including shoes, and thoroughly clean and dry befors reuse. PROTECTION: Do not get on skin or clothing, wear impervious clothing and gloves, wear face shield. INHALATION EFFECT: No significant health hazards Identified. SAL 000007i60 FIRST AID! If adverse effects occur, remove to uncontaminated eras. Give artificial respiration if not breathing. Get medical attention. PROTECTION: None required; however, use of adequate ventilation is good Industrial practice.  8624 HEALTH HAZARD INFORMATION CONTINUED INGESTION EFFECT] Can cause severe irritation of the south, thrott and esophagus. See Toxicology Section. FIRST AID: t! swallowed, drink plenty of water, got ianediata sodical attontion. . FIRE AND EXPLOSION INFORMATION______________________________________ ________ FLASHPOINT! Abovt 2Q0P (93#C) ASTM 056 EXTINGUISHING MEDIA] Agentf approved for Class 0 hamds (e.g., dry chemical, carbon dioxide, halogenated agents, foam, steam) or water fog, UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic vepor* art given off when heated. _________________________________ REACTIVITY INFORMATION DANGEROUS REACTIONS] Mixing with bases can evolve heat and cause spattering. hazardous DECOMPOSITION! Can fora toxic oases if exposed to open flame or high heat. Incomplete burning can produce carbon monoxide, carbon dioxide, and other harmful products. STABILITY: Stable. ___________ CHEMICAL AND PHYSICAL PROPERTIES BOILING POINT: Above 95*F (35*0 pHi 19,4 SOLUBILITY IN WATER] Totally soluble. SPECIFIC GRAVITY (WATER 111 VISCOSITYi 161) cP e 2**C 0.971 FOUR POINT] 25F (4*0 ASTM D97 ___________ SAL 000007161 PAGX 03 OF 04 NU1 U5UU/UX _STORAGE AMO ENVIRONMENTAL PROTECTION 68624 STORAGE REQUIREMENTS* NO special requirement*. SPILLS AND LEAKS I Remove mechanically or contain on an absorbent material, WASTE DISPOSAL} Disposal ftuflt ba In accordant:* with applicable federal, state, or loeal regulations. Enclosad-controllad incineration it reeonaended unless directed otherwise by applicable ordinances. Do not landfill. Residual and spilled material are hazardous vasts due to corrosivity. empty containers: The container for this product can present explosion or lira hazards, even vhen emptied! To avoid risk of injury, do not cut, puncture or veld on or near this container. Since the emptied containers retain product residue, follow label warnings even after container la emptied. ____ ____________ TOXICOLOGICAL INFORMATION _ Specific toxicity taste have not been conducted on this product. Our hazard evaluation is based on information from similar products, the ingredients, technical literature, and/or professional experience. This product Is considered hamful by ingestion because it is corrosive and nay cause severe irritation or burns of the mouth, throat and esophagus. No component of this product present at levels greater than 0.14 la Identifiad as a carcinogen by NTP, IARC or osha. REGULATORY INFORMATION CERCLA REPORTABLE QUANTITY: This product is not reportabl# under 40 CPR Part 302.4. DOT proper SHIPPING NAME: Corrosive Liquid, N.O.S., UN1760. OSHA HAZARD COMMUNICATION STANDARD* Corrosive. RCRA STATUSI This product is not subject to the 40 CPR Part 263,30 land ban on the disposal of certain hazardous vaatei. SARA STATUS: This product is regulated under the following eection(s) of Sara Title III, 42 use 9601. Spllla or releases of the product may be reportable as determined by the information given below: SECTIONS 311 AND 312 OF SARA AND 40 CPR FART 370* This product is defined as hazardous by OSHA under 29 CPR Part 1910.1200(d). SAL OOOOOTlb^ n*7<?r? MADS HOi 05007909 SS624 FAGS 04 OF 04 REGULATORY INFORMATION - CONTINUED r T6CA STATUS\ AU of the components of this product art listtd on the TSCA Inventory. ISSUE INFORMATION BY I R. 0* Firmer, Director Product Safety fc Toxicology ISSUED: February 93, 1990 Thlt material safety date sheet end the information it contains if offered to you in good faith as accurate. Wa have reviewed any information contained In this date sheet which we received from sources outside our company, we believe that Information to be correct but cannot guarantee Its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations, it is the user's obligation to evaluate and use this product safely and to comply with all applicable lavs and regulations, no statement made in this data sheet shell be construed as a permission or recommendation for the use of any product in a manner that might infringe existing patents, no warranty is made, either express or Implied. SAL 000007163 J.T.BAKER INC* 222 RED SCHOOL LANE* PHILLIPSBURG* NJ 06865 MATERIAL SAFETY OATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC # (800) 424-9300 -- NATIONAL RESPONSE CENTER 8 (800) 424-8802 C4884 -02 EFFECTIVES 05/01/69 G $6 25COBALT* 1000 PPM (0.100% W/V) PAGE: 1 ISSUED: 05/16/89 J.T.BAKER INC.* 222 RED SCHOOL LANE* PHILLIPSBURG* NJ 08865 zzi;>tt|t zzzz== SECTION I - PRODUCT IDENTIFICATION sxs-- PRODUCT NAME: COBALT* 1000 PPM (0.100% W/V) CCMMON SYNONYMS* N/A CHEMICAL FAMILY.: ATOMIC ABSORPTION STANDARDS FORMULA: CO IN HN03 FORMULA NT.: 58.90 CAS NO*: N/A N1GSH/RTECS NO.: N/A PRGOUCT USE: LABORATORY REAGENT PRODUCT CODES: 6927 PRECAUTIONARY LABELING ISSSSSSSZSSSZ**SXS*SSXS3SZ33ZSSISZ Z Z 3 3Z Z ZZZZZZZZ33ZZZ.ZZZZZ3ZZZZZZZZSSZSZZ3 BAKER SAF-T--DATA* SYSTEM HEALTH FLAMMABILITY REACTIVITY CONTACT 2 MODERATE 0 NONE 1 SLIGHT 3 SEVERE (CORROSIVE) LABORATORY PROTECTIVE EQUIPMENT GOGGLES SHIELD* LAB COAT APRON VENT HOOCS PROPER GLCVES U.S. PRECAUTIONARY LABELING DANGER CAUSES BURNS* HARMFUL IF SWALLOWED* CO NOT GET IN EYES* ON SKIN* ON CLOTHING. AVOID BREATHING TIGHTLY CLOSED CONTAINER. USE WITH ADECUATE VENTILATION. AFTER HANDLING. VAPOR. KEEP IN WASH THOROUGHLY INTERNATIONAL LABELING AVOID CONTACT WITH EYES. AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER* KEEP CONTAINER TIGHTLY CLOSED. SAF-iT-DATA* STORAGE COLOR CODE: WHITE (CORROSIVE) CONTINUED ON PAGE: 2 SAL 00007164 J.T.BAKER INC* 222 REO SCHOOL LANE* PHJLLIPSBUR6* NJ 06865 MATERIAL SAFETY DATA SHEET 26-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC 8 (600) 624-9300 -- NATIONAL RESPONSE CENTER # (600) 424-6802 ^ C4884 -02 6S625 EFFECTIVE: 05/01/69 COBALT** *1000 PPM (0.1002 W/V) PAGE: 2 ISSUEO: 05/16/89 3 3 3* .****: ^xxsaxxsxxsssx: SECTION II - COMPONENTS COMPONENT WATER NITRIC ACID COBALT CAS NO* 7732-18-5 7697-37-2 7440-48-4 WEIGHT 97-99 1-2 <1 % OSHA/PEL N/E 2 PPM 1 MG/M3 AC6IH/TLV N/E 2 PPM 05 MG/M3 : x SS_P :::= 222^SSS333Z=2 = :2Sa3ZS = S3S3S333XSZSZ3IX> = 31SIS SECTION III - PHYSICAL DATA BOILING POINT: 100 C (212 F) (AT 760 MM HG) "ELT1NG POINT: C (32 F) (AT 760 MM HG) SPECIFIC GRAVITY: 1.00 (H20=i) S0LU8ILITY(H20)1 COMPLETE (100*) VAPOR PRESSURE (MMHG): N/A VAPOR DENSITY (AIR*1): N/A EVAPORATION RATE: N/A * VOLATILES BY VOLUME: N/A (21 C) PH: 1*0 (0*114 HN03) CCCR THRESHOLD 4P.P.M.): N/A COEFFICIENT WATCR/QIL DISTRIBUTION: N/A APPEARANCE L ODOR: CLEAR* PURPLE LIQUID. PHYSICAL STATE: LICUIO 3 S SJS 333=SS5353333S3SXS23S=33SS353S533S33=XX3SSXSXXXSX33X3Sa3X33333X3X*X33333 SECTION IV - FIRE AND EXPLOSION HAZARD OATA FLASH POINT (CLOSEO CUP): N/A NFPA 704M RATING: 3-0-0 AUTOIGNITION TEMPERATURE: N/A FLAMMABLE LIMITS: UPPER - N/A LOWER - N/A IRE EXTINGUISHING MEDIA USE EXTINGUISHING HEOIA APPROPRIATE FOR SURROUNDING FIRE* CONTINUED GN PAGE: 3 SAL 000007165 J.T.Bj4K INC* 222 RED SCHOOL LAHE* PH JLLIPSBUR6 NJ 06865 MATERIAL SAFETY DATA SHEET 24-fHOUR EMERGENCY TELEPHONE -- (201) 859*2151 CHEMTREC # (800) 424-9300 -- NATIONAL RESPONSE CENTER # (600) 424-8602 C4884 -02 EFFECTIVE: 05/01/89 GS685C08ALT* 1000 PPM (0.100* W/V) ISSUEO PAGE: 3 05/16/89 X 3 X XX33p33SX3X3^3333SXZS3333SS33SXX3333333S3S33S35=33SSS333335333553333SXSSS33 SECTION IV - FIRE AND EXPLOSION HAZARO DATA (CONTINUED) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULO HEAR PROPER PROTECTIVE ECUIPMENT AND SELF-CCNTAINEC BREATHING APPARATUS WITH FULL FACEPIECE CPERATED IN POSITIVE PRESSURE HOOF. UNUSUAL FIRE C EXPLOSION HAZARDS NONE IDENTIFIED. TOXIC GASES PRODUCED OXIDES OF NITROGEN EXPLOSION CATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. L LCSION DATA--SENS ITIVITY TO STATIC OISCHARGE NONE IDENTIFIED. SECTION V 333S3XXX33X3333S333X8X3XSSXS333333X3XXSX3333 HEALTH HAZARD OATA THRESHOLD LIMIT VALUE (TLV/TWA): .050 MG/M3 SHCRT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT (PEL): NOT ESTABLISHED TOXICITY OF COMPONENTS INTRAPERITCNEAL MOUSE LD50 INTRAVENOUS MOUSE L050 FOR CRAL RAT LC50 FOR COBALT CARCINOGENICITY.: NTP: NO FOR WATER WATER IARC: NO Z LIST: NO CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFP6CTS NONE IDENTIFIED. CONTINUED ON PAGE: 4 CShA REG: 190 25 1500 NO G/KG G/KG MG/KG SAL 000007166 J.T.BAKER INC. 222 REO SCHOOL LANE PHILLIPSBURG. NJ 0686S MATERIAL SAFETY OATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEHTREC # (800) 424-9300 -- NATIONAL RESPONSE CENTER 0 (800) 424-8802 C48S4 -02 6 S 6 2 5 EFFECTIVE: 05/01/89 COBALT. 1000 PPM <0.100% W/V> PAGE: 4 ISSUED: 05/16/69 Sa 3^ISX^SXZSZSSgSaS3XX332IX3>Z3X23aai<ZX333IX>Z3EXZZX.>XSSSSIZ1SSXZSZ<XIZSSXX SECTION V - HEALTH HA2AR0 OATA (CONTINUED) EFFECTS OF OVEREXPOSURE INHALATION: IRRITATION OF NCSE AND THROAT. COUGHING* DIFFICULT BREATHING SKIN CONTACI: BURNS EYE CONTACT* BURNS. IRRITATION SKIN ABSORPTION: NONE IDENTIFIED INGESTION: NONE IDENTIFIED CHRONIC EFFECTS: NONE IDENTIFIED TARGET ORGANS NONE IDENTIFIED MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED PRIMARY ROUTES OF ENTRY NONE INDICATED EMERGENCY AND FIRST AIO PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED. 00 NOT INDUCE VOMITING. IF CONSCIOUS* GIVE WATER. MILK. QR MILK OF MAGNESIA. INHALATION: IF INHALED. REMOVE TO FRESH AIR. IF NOT BREATHING. GIVE ARTIFICIAL RESPIRATICN. IF BREATHING IS DIFFICULT. GIVE OXYGEN. SKIN CONTACI: IN CASE CF CONTACT. IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFGRE RE-USE. EYE CONTACT! IN CASE OF EYE CONTACT. IMMEDIATELY FLUSH WITH PLENTY CF WATER FOR AT LEAST 15 MINUTES. -SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO CONTINUED ON PAGE: 5 SAL 000007167 J.T.BAK6R INC. 222 REC SCHOOL LANE* PHILLIPSBURG# NJ 08665 MATERIAL SAFETY 0 A T A SHEET 24-*HQUR EMERGENCY TELEPHONE -- (201) 659-2151 CKEMTREC (800) 424-9300 -- NATIONAL RESPONSE CENTER * (800) 424-6802 C4884 -02 EFFECTIVE: 05/01/89 COBALT* 1000 PPM (0.100* W/V) G S6 25 PAGE: 5 ISSUED 05/ 16/89 sxs*is3sa*>*s*is3ssa> issttsitiiisft(s3siiisfisti((attiisxtix3: xxxtxxxtxxxx SECTION V - HEALTH HAZARO DATA (CONTINUED) EXTREMELY HAZARDOUS SUBSTANCE: YES CERCLA HAZARDOUS SUBSTANCE: TOXIC CHEMICALS* GENERIC CLASS: TSCA INVENTORY: YES YES YES CONTAINS COBALT LBS) ANO NITRIC * 1*000 LBS) CONTAINS NITRIC CONTAINS COBALT C15 (RO a 1 LB. TPC * 10*000 ACID (RC * 1*0C0 LBS* TPC ACIO (RO * 100C LBS) ANO NITRIC ACIO CZXXXZ=^ZXXSZ3X;C=S==Z=3=Z==ZZ=3=ZZZXZZZ23=EXSSXXX33XZXXZZZZ3XX3SSXS:3ZXZ:2:X SECTION VI - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR C XITIONS TO AVOID: NONE DOCUMENTED t* ^OMPAJIBLES: NONE IDENTIFIED DECOMPOSITION PBOOUCTS: OXIDES OF NITROGEN ss--SS:3ZZXSS3X9S33XXI3SZ3XSXXSXSX33X338ISX3XZSSZ3X3X3XXXaxXXS3X3 SECTION VII - SPILL DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE HEAR SELF-CQNTAINEO BREATHING APPARATUS AND FULL PROTECTIVE CLCTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NCN-CCMBUSTIBLE ABSORBENT MATERIAL ANO PLACE INTO CONTAINER FDR LATER DISPOSAL. FLUSH SPILL AREA WITH WATER. J. T. BAKER NEU1RASORB(R) ACIO NEUTRALIZER IS RECOMMENDED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FECERAL* STATE* AKC LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS HASTE NUMBER: D002 (CORROSIVE WASTE) CONTINUED ON PAGE: 6 SAL 00000716a J.T.BAKER INC. 222 RED SCHOOL LANE* PHILLIPSBURG* NJ 06865 MATERIAL S A F E T V DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 855-2151 CHEMTREC # (800) 424-9300 -- NATIONAL RESPONSE CENTER 8 (800) 424-8802 C4684 -02 G S6 25 EFFECTIVE: 05701/09 COBALT* 1000 PPH (0.100* W/V> PAGE: 6 ISSUEOS 05/16/89 X/SB IStZSBBXZBSSItSXXS*XXXXX>S**KS*XSaSSS*SSSSSSSSSS*XXSSSXSB SECTION VIII - INDUSTRIAL PROTECTIVE EQUIPMENT EYE/SKIN PROTECTION: THIS IS A LABORATORY-USE PROOUCT FOR WHICH NO INDUSTRIAL PROTECTIVE EQUIPMENT HAS BEEN DESIGNATED. SECTION IX - STORAGE AND HANDLING PRECAUTIONS SAF-T-OATA* STORAGE COLOR CODE: WHITE (CORROSIVE) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION = SX4SSS 2 S 2 S S SjSSS^3SSSSSS3SSSS = SXSSSSSSSSSSSSXSSXSSXXSSSSSXS5SSXX3XXXXXXXXXX DOMESTIC <0.0.TV) PROPER SHIPPING NAME: NITRIC ACID* 40* OR LESS SOLUTION HAZARD CLASS: CORROSIVE MATERIAL (L1CUID) UN/NA: NA1760 REPORTABLE QUANTITY: 1000 LBS. LABELS: CORROSIVE REGULATORY REFERENCES: 49CFR 172.101! 173.266 INTERNATIONAL Cl.M.O.) PROPER SHIPPING NAME: NITRIC ACID* SOLUTIOJi HAZARO CLASS: 8 UN: UN2031 MARINE POLLUTANTS: NO LABELS: CORROSIVE REGULATORY REFERENCES: 49CFR 172.1025 PART 176! IMO I.M.O. PAGE: 8107 PACKAGING GROUP: II AIR (I.C.A.O.) PROPER SHIPPING NAMe: HAZARD CLASS: UN: UN2031 LABELS: CORROSIVE "EGULATORY REFERENCES : NITRIC ACIO* SOLUTION 8 49CFR 172.1015 173.65 PART PACKAGING GROUP: 1755 ICAO/IATA II U.S. CUSTOMS HARMONIZATION NUMBER: 362200000C0 CONTINUED ON PAGE: 7 SAL 000007169 J.T.BAKER INC. 222 RED SCHOOL LANE* PHILLIPSBURG* NJ 08865 MATERIAL SAFETY OATA SHEET 24'rHOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC ff (800) 424-9300 -- NATIONAL RESPONSE CENTER (800) 424-6802 C4884 -02 EFFECTIVE: 05/01/89 6 S 6 2 5COBALT* 1000 PPM <0.100* W/V) PAGE: ? ISSUED: 05/16/89 s S SJt 9 9 S.P SSZSsaEZSSXZaSXSSSSXSXSSSSSSSSZZXSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSSS N/A * NOT APPLICABLE OR NOT AVAILABLE N/E * NOT ESTABlilSHEO THE INFORMATION IN THIS MATERIAL SAFETY OATA SHEET MEETS THE RETIREMENTS OF THE UNITEO STATES OCCUPATIONAL SAFETY ANC HEALTH ACT ANO REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENOEO ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN* OR SUPERVISED BY A PERSON TRAINED IN* CHEMICAL HANDLING. THE USER IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL FOR HIS OR HER PARTICULAR APPLICAJION. DEPENDING ON USAGE* PRCTECTIVE CLOTHING INCLUDING EYE ANO FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREAJHING CHEMICAL VAPORS/FUMES EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS ' EMICAL MAY INJERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES . E SO VARIEO* BAKER CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION MITH OTHER CHEMICALS OR MATERIALS. BAKER WARRANTS THAT T"c CHEMICAL MEETS THE SPEC IF ICAT IONS SET FORTH ON THE LABEL, t ER OiSCLAIMS ANY OTHER WARRANTIES* EXPRESSED OR IMPLIEO WITH REGARD TC THE PRODUCT SUPPLIED HEREUNDER* ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY ANC EVEN DEATH* ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS CF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE* BAKER WILL PERIODICALLY REVISE THIS MATERIAL SAFETY OATA SHEET. IF YOU HAVE ANY QUESTIONS* PLEASE CALL CUSTOMER SERVICE (1-800-JTBAKER) FOR ASSISTANCE. COPYRIGHT 1989 J.T.BAKER INC. * TRADEMARKS OF J.T.BAKER INC. APPROVED BY QUALITY ASSURANCE DEPARTMENT. -- LAST PAGE -- SAL 000007170 PHONE: MATERIAL SAFETY DATA SHEET THE CORTEC CORPORATION 310 CHESTER STREET ST. PAUL# MINNESOTA 55107 612-224-5643 OR TOLL FREE 1-800-4-CORTEC TELEX: 297447 EMERGENCY PHONE NO,: CHEMTREC (FOR SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT): 1-800-424-9300 (DAY OR NIGHT) SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME: Cortec VCI-347 CONCENTRATE 6 2$ PRODUCT DESCRIPTION: Proprietary mixture of" ''ppeeltroleum based corrosion inhibitors combined with surfactants and emulsifiers. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME(S) WEIGHT PERCENT OCCUPATIONAL EXPOSURE LIMITS TLV OR PEL ORAL LD-50 Severely hydrotreated mineral oil Polyethoxylated (5) tallow alkylamines 30-32 18-20 5mg/cu~, meter (oil mist) N.E. N.E. 500rog/kg-rat Aromatic hydrocarbons 1-2 50 ppm- N.E. Ethylene glycol 1-2 2 5 ppm N.E. SECTION Til - PHYSICAL DATA. - - COLOR: Brown PHYSICAL FORM: Viscous Liquid % VOLATILE(weight): 6% BOILING RANGE: N.E. ODOR: Sweet odor EVAPORATION RATE: Nil VAPOR PRESSURE; N. E. VAPOR DENSITY: N.E SPECIFIC GRAVITY: 1.01 (25 C) pH: 9.0-9.5 (1% aqueous) MELTING RANGE: N.A. WEIGHT GALLON: 8.55 lb/gal SECTION IV - FIRE AND EXPLOSION DATA FLAMMABILITY CLASSIFICATION: N.E. FLASH POINT: 155 F (TCC) FLAMMABLE LIMITS: LEL: N.E. UBL: N.E. EXTINGUISHING MEDIA: Water, carbon dioxide or other dry chemical firefighting agents. UNUSUAL FIRE AND EXPLOSION HAZARDS: None SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear self contained breathing apparatus. VCI-347 PAGE 1 OF 3 SAL 000007171 SECTION V - HEALTH HAZARD "DATA EMERGENCY AND FIRST AID PROCEDURES: Eye contact: Immediately flush eyes with large quantities of water for at least 15 minutes. Get prompt medical attention. Skin Contact: Pat off spillage with clean cloth. Do not rub. Wash affected area with soap and water. Consult a physician. Inhalation: Remove person to an uncontaminated area/ administer oxygen it necessary. If breathing has stopped, administer CPR. Get immediate medical attention. Ingestion: DO'NOT INDUCE VOMITING. Dilute with milk or water. Get immediate medical attention. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: none known. PRIMARY ROUTES OF ENTRY: eye contact, skin contact, inhalation. Carcinogenic? OSHA: no NTP: no IARC: no HEALTH HAZARDS (acute and chronic) / EFFECTS OF OVEREXPOSURE (1) (2) (3) Skin contact with this product can cause severe irritation. Eye contact will cause severe irritation and possible damage unless prompt first aid measures are taken. Inhalation of product vapors is not expected to pose a significant health hazard due to the low vapor pressure of the product. Inhalation of particle mists resulting from spraying or atomizing this product is expected to cause upper respiratory irritation and therefore should be avoided. (4) Ingestion of this product may cause severe irritation to the mouth, throat and stomach. SECTION VI - REACTIVITY DATA STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of nitrogen, carbon, sulfur, phosphorous and zinc. incoMPATABILITY: Strong acids, alkalis and oxidizing agents. CONDITIONS TO AVOID: Contact with incompatible materials. VCI-347 PAGE 2 of 3 SAL 000007172 SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDs Absorb on sweeping compound or other absorbent material. Keep out of streams and waterways. WASTE DISPOSAL: Incinerate or dispose of in accordance with exist ing Federal, State and Local environmental regulations. SECTION VIII -"'SAFE HANDLING AND ^SEr INFORMATION RESPIRATORY PROTECTION: A NIOSH approved dust/mist respirator recommended if particle mists are generated. PROTECTIVE GLOVES: Chemical resistant rubber or plastic. EYE PROTECTION: Safety goggles OTHER PROTECTIVE EQUIPMENT; Eye wash station, safety shower. is SECTION IX - SPECIAL PRECAUTIONS AND STORAGE DATA PRECAUTIONS TO BE TAKEN IN HANDLING; Avoid eye and skin contact. Avoid inhalation of particle mists. PRECAUTIONS TO BE TAKEN IN STORING: Keep containers tightly closed. Store away from heat and open flame. "EMPTY" CONTAINER WARNING: "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All other containers should be disposed of in an environmentally safe manner in accordance with governmental regulations. SECTION X - SHIPPING DATA DOT SHIPPING NAME:Alkaline Corrosive Liquid n.o.s. DOT HAZARD CLASS.: Corrosive Material T.S.C.A- STATUS: listed DOT REQUIRED LABELS: Corrosive N.A. NUMBER: 1719 TECHNICAL SHIPPING NAME: Corrosion Inhibitor FREIGHT CLASS BULK: Same as above LTL: 70 TL: 35 MW: 30 PREPARED BY: Mike Tarvin TITLE: Chemist DATE PREPARED: 06/15/88 APPROVED BY: Boris Miksic TITLE: President DISCLAIMER: This information is furnished without warranty, ex pressed or implied, except that it is accurate to the best know ledge of The Cortec Corporation. The data on this sheet relates only to the specific material designated herein. The Cortec Corporation assumes no legal responsibility for use or reliance upon these data. * N.E. NOT ESTABLISHED N.A. NOT APPLICABLE VCI-347 PAGE 3 of 3 SAL 000007173 PHONE: MATERIAL SAFETY DATA SHEET THE CORTEC CORPORATION 310 CHESTER STREET ST. PAUL, MINNESOTA 55107 612-224-5643 OR TOLL FREE 1-800-4-CORTEC TELEX: 297447 EMERGENCY PHONE NO. : CHEMTREC (FOR SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT): 1-800-424-9300 (DAY OR NIGHT) SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME: Cortec VCI-376 PRODUCT DESCRIPTION: A proprietary waterborne corrosion resistant coating. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME(S) WEIGHT PERCENT OCCUPATIONAL EXPOSURE LIMITS TLV OR PEL ORAL LD-50 Butyl Cellosolve 5-10 25ppm *(skin) 50ppm **(skin) Mineral Oil 5-6 5mg/cu meter (oil mist) * ACGIH Threshold Limit Value (TLV) ** OSHA Permissible Exposure Limit`(PEL) - Carcinogenic? OSHA: no NTP: no I ARC: ,1480rag/kg-rat N.E. no SECTION III - PHYSICAL DATA COLOR: off-white PHYSICAL FORM: Liquid % VOLATILE(weight): 60-65% BOILING RANGE: N.E. ODOR: characteristic EVAPORATION RATE: N.E. VAPOR PRESSURE: N.E. VAPOR DENSITY: N.E. SPECIFIC GRAVITY: 1.037(25 C) pH: 9.0 - 9.5 MELTING RANGE: N.A. WEIGHT GALLON: 8.5 lb/gal SECTION IV - FIRE AND EXPLOSION DATA FLAMMABILITY CLASSIFICATION: N.E. FLASH POINT: 146 F C.CC FLAMMABLE LIMITS: LEL; N.E. UEL: N.E. EXTINGUISHING MEDIA: Water, carbon dioxide or other dry chemical firefighting agent. UNUSUAL FIRE AND EXPLOSION HAZARDS: none $4^ OoO07j SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear self contained breathing apparatus. Cortec VCI-376 page 1 of 3 G S6 21 SECTION V - HEALTH HAZARD DATA EMERGENCY AND FIRST AID PROCEDURES: Eve Contact; Flush with water for at least 15 minutes. Consult a physician. Skin Contact: Wash area with soap and water. If irritation persists, consult a physician. Inhalation: Remove to uncontaminated area, administer oxygen if necessary. Administer CPR if breathing has stopped. Get immediate medical attention. Ingestion: Do not induce vomiting. Get immediate medical attention. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: none known. PRIMARY ROUTES OF ENTRY: inhalation, skin contact, eye contact, skin absorption. HEALTH HAZARDS (acute and chronic) / EFFECTS OF OVEREXPOSURE: (1) Repeated or prolonged, skin contact with this material may cause skin irritation. (2) Butyl cellosolve can be absorbed through intact skin, therefore direct skin contact should be avoided. (3) Eye contact with this material causes irritation. (4) Excessive inhalation of high vapor concentrations may irritate the upper respiratory tract. If the product is sprayed or atomized, inhalation of particle mists may irritate the upper respiratory tract and should be avoided. (5) Ingestion of this product is expected to be harmful. (6) Chronic effects resulting from long terra overexposure to butyl cellosolve may cause hemolysis of red blood cells leading to possible liver and kidney damage. SECTION VI - REACTIVITY DATA STABILITY: Stable HAZARDOUS POLYMERIZATION: will not occur HAZARDOUS DECOMPOSITION PRODUCTS: oxides of carbon, nitrogen and sulfur. INCOMPATABILITY: strong acids, alkalis and oxidizing agents- CONDITIONS TO AVOID: contact with incompatible materials. Cortec VCI-376 page 2 of 3 SAL 000007175 QS 6 21 SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb on sweeping compound or other absorbent material. Keep out of streams and waterways. WASTE DISPOSAL: Incinerate or dispose of in accordance with exist ing Federal/ State and Local environmental regulations. " SECTION VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: A NIOSH approved chemical cartridge respirator to remove vapors or dust/mist respirator to remove particle mists. PROTECTIVE GLOVES: chemical resistant rubber or plastic. EYE PROTECTION: safety goggles OTHER PROTECTIVE EQUIPMENT: eye wash station, safety shower SECTION IX - SPECIAL PRECAUTIONS AND STORAGE DATA PRECAUTIONS TO BE TAKEN IN HANDLING: Avoid skin and eye contact. Minimize breathing of vapors or particle mists. PRECAUTIONS TO BE TAKEN IN STORING: Keep product from freezing, store at 40 F or above. Keep away from heat and open flame. SECTION X - SHIPPING DATA DOT SHIPPING NAME: N.A. U.N. / N.A. NUMBER: N.A. DOT HAZARD CLASS.: N.A. T.S.C.A. STATUS: Listed DOT REQUIRED LABELS: N.A. TECHNICAL SHIPPING NAME: Paint and related material, compounds FREIGHT CLASS BULK: Same as above LTL: 65 TL: 35 MW: 36 PREPARED BY: Mike Tarvin TITLE: Chemist APPROVED BY: Boris Miksic TITLE: President DATE PREPARED: 04/24/88 DISCLAIMER: This information is furnished without warranty, ex pressed or implied, except that it is accurate to the best know ledge of The Cortec Corporation. The data on this sheet relates only to the specific material designated herein. The Cortec Corporation assumes no legal responsibility for use or reliance upon these data. * N.E. = NOT ESTABLISHED * N.A. = NOT APPLICABLE Cortec VCI-376 page '3 of 3 SAL 000007176 PHONE: MATERIAL SAFETY DATA SHEET THE CORTEC CORPORATION 310 CHESTER STREET ********** gv22 ST. PAUL/ MINNESOTA 55107 612-224-5643 OR TOLL FREE 1-800-4-CORTEC TELEX: 297447 EMERGENCY PHONE NO.: CHEMTREC (FOR SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT): 1-800-424-9300 (DAY OR NIGHT) SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME: Cortec VCI-309 Powder PRODUCT DESCRIPTION: A proprietary blend of amine salts. SECTION II - INGREDIENTS INGREDIENT NAME(S) WEIGHT PERCENT OCCUPATIONAL EXPOSURE LIMITS TLV OR PEL ORAL LD-50 Trade Secret 10 mg/cu. meter (as nuisance dust) N.E. Carcinogenic? OSHA: no NTP: no IARC: no SECTION III PHYSICAL DATA COLOR: White PHYSICAL FORM: Fine Powder % VOLATILE (weight) : 0% BOILING RANGE: N.E. ODOR:. slight amine EVAPORATION RATE: Nil VAPOR PRESSURE: .0001mraHg( 20 C) VAPOR DENSITY: N.E. SPECIFIC GRAVITY: N.A. pH: 7.0 (1% aqueous) MELTING RANGE: 167-175 C WEIGHT GALLON: N.A. SECTION IV - FIRE AND EXPLOSION DATA FLAMMABILITY CLASSIFICATION: N.E. FLASH POINT:N.A. FLAMMABLE LIMITS: LEL:N.A. UEL: N.A. EXTINGUISHING MEDIA: Water, Carbon Dioxide or other dry chemical firefighting agents. UNUSUAL FIRE AND EXPLOSION HAZARDS: None SAL 000007177 SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear self contained breathing apparatus. VCI-309 powder page 1 of 3 GS622 SECTION V - HEALTH HAZARD DATA EMERGENCY AND FIRST AID PROCEDURES] Eve Contact; Flush eyes with large quantities of water for at least 15 minutes. Consult a physician. Skin Contact: Wash affected area with soap and water. If irritation persists, consult a physician. Inhalation: Remove person to an uncontaminated area, administer oxygen if necessary. If breathing has stopped, administer CPR. Get immediate medical attention. Ingestion: If person is conscious, give milk or water and induce vomiting. If breathing has stopped, start CPR. Get medical attention MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: none known. PRIMARY ROUTES OF ENTRY: Inhalation, skin contact, eye contact. HEALTH HAZARDS (acute and chronic) / EFFECTS OF OVEREXPOSURE: (1) Eye contact with this product may produce irritation. (2) Repeated or prolonged skin contact with this product may produce mild skin irritation. (3) Inhalation of product vapors is not expected to pose a significant health hazard due to the low vapor pressure of the product. Excessive inhalation of dusts resulting from the use of this product may be harmful and should be avoided. C (4) Ingestion of this product may be harmful. There are no specific data known to exist on the aoute or chronic oral toxicity of the components in this product. However, the amine salts contained in this product are expected to have a low order of oral toxicity. SECTION VI - REACTIVITY DATA STABILITY: stable HAZARDOUS POLYMERIZATION: will not occur. HAZARDOUS DECOMPOSITION PRODUCTS (under fire conditions): oxides of carbon and nitrogen. INCOMPATABILITY: Strong acids, alkalis and oxidizing agents. CONDITIONS TO AVOID: Contact with incompatible materials. S4L 000717S VCI-309 powder page 2 of 3 86 22 SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up. WASTE DISPOSAL: Incinerate or dispose of in accordance with exist ing Federal, State and Local environmental regulations. SECTION VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: A NIOSH approved dust/roist respirator is recommended. PROTECTIVE GLOVES: Chemical Resistant Rubber or plastic. EYE PROTECTION: Safety goggles OTHER PROTECTIVE EQUIPMENT: Eye wash station SECTION IX - SPECIAL PRECAUTIONS AND STORAGE DATA PRECAUTIONS TO BE TAKEN IN HANDLING: Avoid inhalation of dusts. Avoid eye contact and prolonged or repeated skin contact. Workers should thoroughly wash hands with soap and water prior to smoking, drinking, eating or using lavatory. PRECAUTIONS TO BE TAKEN IN STORING: Keep containers tightly closed. SECTION X - SHIPPING DATA DOT SHIPPING NAME: N.A. U.N. / N.A. NUMBER: N.A. DOT HAZARD CLASS.: N.A. T.S.C.A. STATUS: Listed DOT REQUIRED LABELS: N.A. TECHNICAL SHIPPING NAME: Amine Salts FREIGHT CLASS BULK: LTL: 70 TL: 40 MW: 30 PREPARED BY: Mike Tarvin TITLE: Chemist APPROVED BY: Boris Miksic TITLE: President DATE PREPARED: 04/11/88 DISCLAIMER: This information is furnished without warranty, ex pressed or implied, except that it is accurate to the best know ledge of The Cortec Corporation. The data on this sheet relates only to the specific material designated herein. The Cortec Corporation assumes no legal responsibility for use or reliance upon these data. * N.E. = NOT ESTABLISHED * N.A. = NOT APPLICABLE VCI-309 powder page 3 of 3 SAL 000007179 VH PHONE: MATERIAL SAFETY DATA SHEET THE CORTBC CORPORATION 310 CHESTER STREET g gOO ST. PAUL, MINNESOTA 55107 612-224-5643 OR TOLL FREE 1-800-4-CORTEC TELEX: 297447 EMERGENCY PHONE NO.: CHEMTREC (FOR SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT): 1-800-424-9300 (DAY OR NIGHT) SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME: Cortec VCI-369 aerosol PRODUCT DESCRIPTION: A proprietary blend of amine carboxylates and other corrosion inhibitors in an oil carrier in aerosol form. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME(S) WEIGHT PERCENT OCCUPATIONAL EXPOSURE LIMITS TLV OR PEL ORAL ID-50 hydrotreated light napthenic distillates, petroleum 20-25 5mg/cu. meter (oil mist) N.E. Propane 15-20 1008 ppm N.E; Isobutane 15-20 1008 ppm N.E. SECTION III - PHYSICAL DATA COLOR: Brown VAPOR PRESSURE: N..E. PHYSICAL FORM:Viscous Liquid VAPOR DENSITY: N.E. % VOLATILE (weight): 50% SPECIFIC GRAVITY: .95 (20 C) BOILING RANGE:N.E. pH: 8.0-8.5(l% aqueous) ODOR: Petroleum MELTING RANGE: N.A. EVAPORATION RATE:slower than ether WEIGHT GALLON: 7.9 lbs/gal SECTION IV - FIRE AND EXPLOSION DATA FLAMMABILITY CLASSIFICATION: Flammable FLASH POINT: N.E. FLAMMABLE LIMITS,: LEL: N.E. UEL: N.E. EXTINGUISHING MEDIA: Water, Carbon Dioxide or other Dry Chemical firefighting agents. UNUSUAL FIRE AND EXPLOSION HAZARDS; Contents of aerosol cans are under pressure. Contents are flammable. SAL 000007180 SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear contained breathing apparatus. VCI-369 aerosol page 1 of 3 GS62S SECTION V - HEALTH HAZARD DATA EMERGENCY AND FIRST AID PROCEDURES: Skin Contact: Wash affected area with soap and water. Consult a physician if irritation persists. Eye Contact: Flush eye(s) with large quantities of water for at least 15 minutes. Consult a physician. Ingestions; If swallowed, DO NOT INDUCE VOMITING. Seek immediate medical attention. Inhalation: Remove person to an uncontaminated area. Administer oxygen if necessary. Start CPR if breathing has stopped. Seek medical attention. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE; none known. CARCOGENICITY: NTP: no OSHA: no IARC: no PRIMARY ROUTES OF ENTRY: Skin contact, eye contact, inhalation. HEALTH HAZARDS (acute and chronic) / EFFECTS OF OVEREXPOSURE: 1. Repeated or prolonged skin contact with petroleum and related products tends to remove natural skin oils leading to irritation and dermatitis. 2. Eye contact with this product will cause irritation. 3. Inhalation of product vapors and/or aerosol mists should be avoided. Excessive inhalation may cause nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. 4. Ingestion of this material can cause gastrointestinal irritation. Also, aspiration of this material into the lungs can cause, chemical pneumonia. SECTION VI - REACTIVITY DATA STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS; Oxides of Carbon, Nitrogen and Sulfur. INCOMPATABILITY: Contact with strong acids, alkalies and oxidizing agents. * CONDITIONS TO AVOID: Contact with strong acids, alkalies and oxidizing agents. VCI-369 aerosol page 2 of 3 SAL 000007181 G S623 SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb on sweeping compound or other absorbent material. Keep petroleum out of streams and waterways. WASTE DISPOSAL: Incinerate or dispose of in accordance with exist ing Federal, State and Local environmental regulations. SECTION""VIII - SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: Use a NIOSH approved respirator to remove vapors or particle mists when necessary. PROTECTIVE GLOVES: Chemical resistant rubber or plastic EYE PROTECTION: Safety goggles. OTHER PROTECTIVE EQUIPMENT: Eye wash station, safety shower. SECTION IX - SPECIAL PRECAUTIONS AND STORAGE DATA PRECAUTIONS TO BE TAKEN IN HANDLING: Avoid eye and skin contact. Avoid inhalation of product vapors an/or particle mists. PRECAUTIONS TO BE TAKEN IN STORING: Caution: Contents under pressure. Do not puncture or incinerate. Store away from heat or open flame. Store below 100 F. SECTION X SHIPPING DATA DOT SHIPPING NAME: Compressed gas n.o.s. U.N. / N.A. NUMBER: 1954 DOT HAZARD CLASS.: Flammable gas T.S.C.A. STATUS: Listed DOT REQUIRED LABELS: Flammable gas TECHNICAL SHIPPING NAME: Petroleum Distillates/Araine Salts FREIGHT CLASS BULK:Same as above LTL: 65 TL: 35 MW: 30 PREPARED BY: Mike Tarvin TITLE: Chemist APPROVED-BY: Boris Miksic TITLE: President DATE PREPARED: 06/08/88 DISCLAIMER: This information is furnished without warranty, ex pressed or implied, except that it is accurate to the best know ledge of The Cortec Corporation. The data on this sheet relates only to the specific material designated herein. The Cortec Corporation assumes no legal responsibility for use or reliance upon these data. * N.E. = NOT ESTABLISHED * N.A. = NOT APPLICABLE VCI-369 aerosol page 3 of 3 SAL 000007182 SNT BY* XEROX Telecopier 7017! 2- fl-flfl ! 18*`41 ! , 2152788070*3184815813 MATERIAL SAFETY DATA SHEET ;# 3 MANUFACTURER'S NAME RESC0 PRODUCTS, INC. hbcttONi NAMt AND hUOUUtt AOOftESS (STREET, CITY, STATE AND ZIP CODE) P. Q. BOX 108, NORRISTOWN, PA 19404 TOmLnaIvIE, COMMON NAME OH SPECIFICATION; ` RS-5A , ........ HV 1 .... -........... .......... cmemhjai,familyorPRooucTtyp6 inorganic (jxides fchCtJONH COMPOSITION CHEMICAL NAME Alum, silicate 911Irenus material Calr.fnm A1 urntrate % COMMON NAME Rea* ; can rr/Nj i # Gfoa . Y NAIF <90 Perlite________ Jt_ NAIF Cements_________ Jt__ 12042-68-1 CONTACT . TECHNICAL DEP r. EMERGENCY TKLEPHON NO. (215) 279-501 \ '! oat. 2/10786 Revision* OSMA 3 RSRMIEEIVS EXPOSURE LIMIT ACG1H r CARON* ooin TLV (Y/N) NAIF NAIF N l.NAIF . .5 nta/m'* 6 5/l5mg/m^ N N ri-------------------------------------------------- i jRegulated as per, lists,:. 5sw .29 CFR 19.10.,..5i kuiai ACG1H., HHS/NTP an 1 IARC. 1 ARphulat.ed_ AS ner llsiii- NIL Annual Rennrt. nr -Car Jnnnpn^lAftf Mnnnnranhl -- StCtloN HI PHYSICAL ANb CMfeMlCAl bAtA Percent Volatile by Volume: OX Solubility in Water: Slight hulk Density: 45 lbs./cu.ft. loose P.C.E.: > tone 19 ph (10X solution): *9.0 Physical Appearance: White powdef* & aggregate StCtlON IV Nhfc ANb FxPLoslClN Wi\2Ahb bAtA Flash Point--Explosion Potential--Flammable Limits-Extinguishing Me 3ia This product is rion-flammable andwlll hot support combustion. Inhalation: Skin: EyeS: Note: SECTION V HEALTH AND FIRST AID (SEE SECTION II FOR TLV) Nuisance dust. See Section IX. FIRST AID: Remove to dust-free krea May dry/chap skin. May cause burns. FIRST AID: Wash affected area with soap and water. May abrade eyes. May cause burns. FIRST AID: Flush eyes with water for at least fifteen (15) minutes. Seek medical attention. See Section IX. SAL 000007183 3NOTE: The two numbers in the TLV and PEL columns represent the respirable fraction/ total fraction. SENT BY= XEROX Telecopier 7017: 2- 8-90 i 1BU1 CAP 48^2^6070^184815613 StCtloN U| CORROSIVITY AMD NfAfctlVItY t)At A Stability* Stable Conditions to be avoided*NAIF Polymerisationi Will not occur Incompatabilityi NAIF SECTION VII STORAGE. HANDLING AMD USE PROCEDURES Normal storage and Handling* $ee below ;# 4 Normal Uset Good housekeeping and good hygenic practidea ahou d be employed* Steps to be taken in case of leaks or spills* Employ dust-free Cleanup procedures. waste Disposal Methods The tearout and disposal of this product may generate dust* During tearout, observe the exposure limits ovtlined in Section 11# and the personal protection precautions, in Seel ion Viii^ Disposal shall be in accordance with Federal, State# and bocal Regulations* stc.liofJ VMI hkhsoWAl PRotECtloM iRESFiwATOftyjHoTiCTioN{specifvtypel Use N1QSH or MSHA approved respirator.___ VENTILATION LOCAL Sufficient to keen dust below TLV's. MECHANICAL {GENERAL) OTHER protective gloves iye protection OTHER EOUIPMENT Recommended Recommended SECTION IX SPECIAL PRECAUTIONS 1 -- This product contains SILICA and CALCIUM ALUMINATE CEMENT. Silica - Inhalation Of this dust in the respirable "size range presents a potential health hazard. Exc issive inhalation will Increase your risk of serious respiratory disease (Silicosis). Calcium Aluminate.Cement -an alkaline material which may cause eye or skin inj jry. SAL 000007184 The Information and recommendations set forth herein ere token from sources believed to be accurate as of the date hereof; however makes no warranty with respect to the accuracy of the Information or thd Material Safety Data Sheet May be used to comply with jSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements. IDENTITY (As Used on Label end Ust) High performance molecular sieve U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form! Form Approved fl 1 A 49 OMB No. 1218-0072 Nnte- ftCan4r snecea am nor nennttmd. K anv item t* nr* e^Srehte n, M mtormsOon is evaAOfc, (he space must be merited lb indicete mat Section 1 Manufacturer's Name LAPORTE INDUSTRIES LIMITED Address (Number. Street. City. Stale, and ZIP Code) P.O. Box 2 Moorfield Road WIDNES, Cheshire, England. WAS OJU Emargency Telephone Number (U.K.) 051-424-55S5 Ext. E Telephone Number tor information (U.K.) 051-495-2222 Date Prepared 12th Mav 1988 Signature of Preparer (optional) Section II -- Hazardous Ingredtenta/ldentity Information Hazardous Components (Specific Chemical identity; Common Name(s)) Other Limits OSHA PCIACGIH TLVRecommended_______ H (optional) MOLECULAR SIEVE 3A, 4A. 5A. 13X ALKALI ALUMINOSILICATES__________ _______________________________________________ 80-84 not___________ not__________________________________ C.\ AY BINDER_____________ (Bentonite)______ _________ (Fullers Farth)-------------------- (Sepiolite)_________ controlled controlled ____________________ 3 not___________ ngj_____________lOmo/m______ 16-20 controlled controlled UK Health _______ _______________________________ and Safety__________ _______________________________Executive____________ AttaoulQite/PolvQcsskitel _______________________________Recommended_______ ______________ _______ Limit Section ill -- Physical/Chemical Characteristics n/A = not applicable Boiling Point N/A Vapor Pressure (mm Hg.) N/A Vapor Density (Aifi 1) N/A Solubility in Water Insoluble Appearance and Odor __________________Buff coloured spheres - noodour Specific Gravity (HjO - 1) Melting Point Evaporation Rate (Butyl Acetate - 1) Section IV -- Fire and Explosion Hazard Data Flash Point (Method Used) Non flammable Flammable Limits N/A Extinguishing Media ____________________ Use Extinouisher to suit cause of fire Special Pre Fighting Procedures ________ None_________________________________ bulk density 0.66-0.76 N/A N/A LEL N/A UEL N/A SAL 000007X85 Unusual Pre and Explosion Hazards Heat evolved with water contact in a confined space this may generate pressure build up due to steam OSHA 174 Sect '985 C A O 49 jetton V -- Reactivity Oats Stability Unstat Stable v/onditione to Avoid Incompatibility ' ' _______ Materials subiect_to catalytic, decomposition Hazardous Decomposition or Byproducts Product--mav become ho.t on contact with water Hazardous Polymerization May Occur Conditions to Avoid Will Not Occur e.a. Hydrogen PerrwiHa Section VI -- Health Hazard Data Route(s) of Entry inhalation? Yes Hearth Hazards (Acute and Chrome/ Desiccant Properties Skin? ____________ fcifl___________ N/A Ingestion? YC None Carcmogencrty: NTP? IARC Monograpfte? OSHA Regulated? ______________________________________________ Vol.42 D.1 59______________________________ ___ _____ Binders - Inadequate evidence for carcinogenicity to humans_________________________ S*gn$ and Symptoms of Exposure ____________________________ Hry month and_____________________ M/A__________________________________ . _____________________________ Nose_________________________________________________________________ ledieai Conditions Generally Aggravated by Exposure Asthma_______________________________ Nona_____________________ Emergency and First Aid Procedures __Eyes and Skin - .Vash with plenty of water_________________________________________________ _____________________________________ Ingestion________- Q_rjQk._pJen_tv.oJ.^yater ____________________________ Section VII -- Precautions for Safe Handling and Use________________________________________________ Steps to Be Taken m Case Material Is Released or Spilled Collect beads,and dispose of in accordance with federal, state o^local regulations Avoid treading on beads as they represent a slip hazard________________________ _______ Waste Disposal Method _____________________ Dispose_of in accordance..with local and national, regulations Precautions to Be Taken in Handling and Storing __________________________________________Store dry and awav from substances subject to ____________________________________ catalytic decomposition_________________________________ Other Precautions _____________________ None________________________________________________________________ _____ Section VIII -- Control Measures Respiratory Protection (Specify Type) Dust respirator if not exhaust ventilated Ventilation Local Exhaust Dependant on process Mechanical (General) 0r maj Special Other None None Protective Gloves Industrial Eye Protection No special Other Protective Clothing or Equipment Normal workwear clothing Worx/Hygiemc Practices ____________________ Wash at end of work period and before eating reauirement SAL 000007186 Page 2 uSOro . BIG TR 18PU5i51I8*TlnchoustonI tx 77253 MATERIAL safety data sheet 1 -- GENERAL INFORMATION PAGE PROCOCT NAME HYDROGEN GS 1 93 EMERGENCY TELEPHONE NO. 713-368-0302 MANUFACTURERS NAME BIG THREE INDUSTRIES* INC* TRADE NAME/SYNONYMS HYDROGEN CHEMICAL NAME AND SYNONYMS HYDROGEN REVISION DATE: 06<23/89 .1D CHEMICAL FAMILY INORGANIC FLAMMABLE GAS UN 1049 FORMULA H2 CAS FAMILY 1333-74-0 ********** SECTION NOTES ********** MSOS INFORMATION NUMBER: 17131 896-21*0 I I HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF LIQUIDS AND GASES 0/0 TLV HYDROGEN ** NONE ESTABLISHED I I I - P H Y S I C _A L D_A_T A 100 ** L .LING PC I NT -423. OF (-252.70 5 1 ATM SPECIFIC GRAVITY (AIR ^ 1): 0.0695 3 70F 122.10 1 ATM VAPOR PRESSURE N/A PERCENT VOLATILE BY VOLUME (0/01 N/A (GAS) SITY 0.005209 LB/CU FT 3 70 F (21.1 Cl C 1 ATM EVAPCRATION RATE N/A (GAS) SOLUBILITY IN RATER 2.14SCC/I00CC H20 3 32 F (0 C) MATERIAL AT NORMAL CONDITION GAS EXPANSION RATIO (LIQUID TO GASI N/A (GAS) APPEARANCE AND ODOR COLCRLESS* ODORLESS, TASTELESS GAS IV-F1RE AND EXPLOSION HAZARD DATA PlaIh pBinJ (METHOD USED) FLAMMABILITY LIMITS IN AIR (0/0 BY VCLI LOWER 4.1 UPPER 74.2 EXTINGU1SHING MEDIA WATER, DRY CHEMICAL, CARBON DIOXIDE. SPECIAL FIRE FIGHTING PROCEDURES EVACUATE UNNECESSARY PERSONNEL. SHUT OFF SOURCE OF HYDROGEN IF POSSIBLE. COOL SURROUNDING CONTAINERS WITH WATER SPRAY. HYDROGEN FIRES SHOULD NOT BE EXTINGUISHED UNTIL THE SUPPLY OF HYDROGEN HAS BEEN SHUT OFF AND THE SURROUNDING AREA COOLED, BECAUSE OF THE DANGER OF RE-IGNITION AND EXPLOSION. VENTILATE AREA ANO REMOVE ANY POSSIBLE SOURCE OF IGNITION. DO NCI ENTER AREAS CONTAINING FLAMMABLE MIXTURES, DUE TO THE IMMEDIATE FIRE AND EXPLOSION HAZARD. SELF--CENTAINED BREATH ING APPARATUS MAY BE REQUIRED FCR RESCUE PERSONNEL. SAL 000007187 BIG THREE INO^TR^ INC. GS 1 98 HOUSTON, TX 77253 W HATE 1 A L SAFETY OATA PRODUCT NAME HYDROGEN SHEET PAGE UNUSUAL FIRE AND EXPLOSION HAZARD HYDROGEN BURNS WITH A PALE BLUE ALMOST INVISIBLE FLAME. HYDROGEN IS LIGHTER THAN AIR AND CAN ACCUMULATE IN THE TOP OF ENCLOSED SPACES. THEREFORE, A POTENTIAL EXPLOSION HAZARD FROM RE-IGNITION EXISTS. PRESSURE CAN BUILD UP DUE TO HEAT AND CYLINDER MAY EXPLODE IF PRESSURE RELIEF DEVICES SHOULD FAIL TO RELIEVE PRESSURE. HYDROGEN WILL ACT AS A SIMPLE ASPHYXIANT IF IT DISPLACES OXYGEN. AUTOIGNlTION TEMPERATURE: 1058 F (570 Cl ELECTRICAL CLASSIFICATION: CLASS 1, GROUP B V-HEALTH HAZARD DATA THRESHOLD LIMIT VALUE NONE ESTABLISHED UNUSUAL CHRONIC TOXICITY SEE OVEREXPOSURE SECTION* CARCINOGENICITY NOT LISTED BY IARC, NTP, OSHA ROUTES OF EXPOSURE INHALATicn -ECTS OF OVEREXPOSURE HYDROGEN IS NONTOXIC, BUT MAY CAUSE SUFFOCATION BY DIS PLACING THE CXYGEN IN THE AIR. EXPOSURE TO OXGYEN-DEFICIENT ATMOSPHERES MAY CAUSE DIZZINESS-, NAUSEA, VOMITING, DIMI NISHED MENTAL ALERTNESS, LOSS OF CONSCIOUSNESS, AND DEATH. IT SHOULD BE NOTEO THAT BEFORE SUFFOCATION COULD OCCUR, THE LOWER FLAMMABILITY LIMIT OF HYDROGEN IN AIR WOULD BE EXCEEDED; POSSIBLY CAUSING BOTH AN CXYGEN--OFF ICIENT AND AN EXPLOSIVE ATMOSPHERE. IT SHOULD ALSO BE RECOGNIZED THAT COLLAPSE AND ASPHYXIATION MAY OCCUR WITHOUT EXPERIENCING ANT OF THE ABOVE SYMPTOMS. TOXICOLOGICAL PROPERTIES: HYDROGEN IS NONTOXIC BUT IT IS AN ASPHYXIANT IF IT DISPLACES OXYGEN IN THE AIR. EMERGENCY AND FIRST AID PROCEDURES PERSONS SUFFERING FROM LACK OF CXYGEN SHOULO BE MOVED INTO FRESH AIR. IF VICTIM IS NOT BREATHING, AOMINISTER ARTI FICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. OBTAIN PROMPT MEDICAL ATTENTION. SELF--CONTAINED BREATHING APPARATUS MAY BE REQUIRED FOR RESCUE WORKERS. _____ VI- RE A C TIVITY DATA 'ABILITY STABLE CONDITIONS 10 AVOID NONEINCOMPAT ABILITY (MATERIALS TC AVOID) SAL 000007188 2 r PAGE 3 material safety data SHEE,fiS198PRODUCT NAME HYDROGEN HYDROGEN WILL REACT VIGOROUSLY OR EXPLOSIVELY WITH MANY HAZARDOUS DECOMPOSITION PRODUCTS NONE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID NONE. V II-- SPIEL OR LEAK PROCEDURES* VIII STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED EVACUATE ALL UNNECESSARY PERSONNEL FROM AFFECTED AREA. ELIMINATE ANY POSSIBLE SOURCES OF IGNITION AND VENTILATE area, if possible move cylinders tc an isolated outdoor AREA. SHUT OFF SOURCE OF HYDROGEN, IF POSSIBLE. IF LEAKING FROM CONTAINER OR VALVE, CONTACT THE CLOSEST 8IG THREE INDUSTRIES LOCATION, OR YOUR SUPPLIER. WASTE DISPOSAL METHCO DO NOT ATTEMPT TC DISPOSE OF RESIDUAL OR UNUSEO QUANTITIES. RETURN TC YCUR SUPPLIER FOR DISPOSAL. VIII -- SPECIAL PROTECTIVE INFORMATION RESPIRATORY PROTECTION ISPECIFY TYPCI USE SELF-CONTAINED BREATHING APPARATUS OR POSITIVE PRESSURE AIR LINE WITH MASK IN QXYGEN-OEF1CI ENT ATMOSPHERES. RESPIRATORS WILL NOT FUNCTICN. VENTILATION SEE NCTES* PROTECTIVE GLOVES N/A EYE PROTECTION SAFETY GLASSES ARE RECOMMENDED WHEN HANDLING HIGH PRESSURE CYLINDERS. OTHER PROTECTIVE EQUIPMENT SEE NOTES* 444******* SECTION NCTES ********** PROVIDE EXPLOS ION--PROOF SYSTEM ADEQUATE TO ENSURE HYDROGEN DOES NCT REACH ITS LEL OF 4.1 *. SAL 000007X89 BIG THftpE as 198 HOUSTON NAT R I A L SAFETY PRODUCT NAME HYDROGEN INC DATA SHEET PAGE LCCAL EXHAUSTS YES MECHANICAL: YES, EXPLOSION PROOF SAFETY SHOES WHEN HANDLING CYLINDERS* EXPLOSION PROOF LIGHTING AND HIRING IN AREAS WHERE HYDROGEN IS STORED OR USED. I X-SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING STGRE AND USE WITH ADEQUATE VENTILATION. DO NOT STORE WITH IN 20 FEET OF OXYGEN OR ANY OTHER OXIOIZER* CYLINDERS SHOULD BE STORED UPRIGHT WITH VALVE PROTECTION CAP IN PLACE AND FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED OVER* PROTECT CYLINDERS FROM PHYSICAL DAMAGE; 00 NOT OftAG, ROLL* SLIDE, CR DROP* USE A SUITABLE HAND TRUCK FOR CYLINDER MOVEMENT* POST "NO SMOKING OR OPEN FLAMES" SIGNS IN THE STORAGE AND USE AREAS* THERE SHOULD BE NO SOURCES OF IGNITION. ALL ELECTRICAL EQUIPMENT SHOULD BE EXPLOSION PROOF IN THE STORAGE ANO USE AREAS* STORAGE AREAS MUST MEET NATIONAL ELECTRIC CODES FOR CLASS 1 HAZARDOUS AREAS* DO NOT ALLOW THE TEMPERATURE WHERE CYLINDERS ARE STORED TO EXCEED 125 F <52 CJ. ^.O.T. LABELING FLAMMABLE CAS - RED LABEL VALVE CONNECTION 350 OTHER PRECAUTIONS DO NOT "CRACK" HYDROGEN CYLINDER VALVE BEFORE CONNECTING IT, SINCE SELF--IGNITION HAY OCCUR. HYDROGEN IS THE LIGHTEST GAS KNOWN AND MAY COLLECT IN THE TOP OF BUILDINGS WITHOUT PROPER VENTILATION. HYDROGEN DIFFUSES RAPIDLY THROUGH POROUS MATERIALS AND MANY JOINTS ANO FITTINGS* IT MAY LEAK OUT OF A SYSTEM WHICH IS GA-TIGHT FOR AIR OR OTHER GASES. LEAK CHECK SYSTEM WITH SOAPY WATER, NEVER WITH A FLAME. NEVER STRIKE A WELDING ARC ON ANY COMPRESSED GAS CYLINDER* REFILLING CYLINDERS WITHOUT THE CONSENT OF THE CYLINOER CWNER IS A VIOLATION OF FEDERAL LAW <49 CFR). MISCELLANEOUS INFORMATIONS FURTHER INFORMATICN ABCUT HYDROGEN CAN BE FOUND IN THE FOLLOWING PAMPHLETS PUBLISHED BY: THE COMPRESSED GAS ASSOCIATION (CGA1 1235 JEFFERSON DAVIS HIGHWAY ARLINGTON, VA 22202 <7031 979-4341 G--5.3: "COMMODITY SPECIFICATION FOR HYDROGEN" P-I: "SAFE HANDLING OF COMPRESSEO GASES IN CONTAINERS" P--14: "ACCIDENT PREVENTION IN OXYGEN-RICH AND OXYGENDEFICIENT ATMOSPHERES" SB-2: "OXYGEN-DEFICIENT ATMOSPHERES* IN ADDITION, YOU MAY ALSO REFER TO NFPA PAMPHLETS 50-A AND SAL 000007X90 PRODUCT NAME 51 "OXYGEN FUEL GAS SYSTEMS FOR WELDING AND CUTTING". NFPA RATINGS: HEALTH: FLAMMABILITY: reactivity: 0 4 0 0 A 0 CERCLA RATINGS: HEALTH: FIRE: REACTIVITY: PERSISTANCE: 0 3 0 3 LISTED IN TSCA INVENTORY: YES PAGE 5 THIS PRODUCT SAFETY DATA SHEET 1$ OFFERED SOLELY FOR YOUR INFORMATION# CONSIDERATION# INVESTIGATION, IN COMPLIANCE WITH HAZARD COMMUNICATION STANDARD 29 CFR 1900.1200. BIG THREE INDUSTRIES# INC. PROVIDES NO WARRANTIES# EITHER EXPRESS OR IMPLIED. *AL 0007J9J! R. T* VANDERBILT'COMPANY, INC* Industrial Minerals and CheroicaIs 30 Winfield Street Norwalk, CT 06855 (203) 853-1400 TWX 710--468-2940 Cuslameii-Infai 12580060228 39835 CONOCO INC* REFINERY WAREHOUSE OLD SPANISH TRAIL WESTLAKE LA 70669 ( Date! 01/29/90 Revised: 09/28/88 MATERIAL m SAFETY DATA SHEET Page CS652 Supersedes! 01/29/86 I* PRODUCT IDENTIFICATION 600055 Trade Name! THERMAX* <Atl Grades) Chemical Name? Carbon black, CAS Reg * No. 1333-86-4 Synonyms: Carbon, N--991 Black, N--990 Black, N--908 Black, N-907 Black Hazardous Ingredients/OSHA? Carbon black Hazard* Irritant Careinogenic Ingredients/OSHA/NTP/IARCf None II, WARNING STATEMENTS WARNING* Harmful if inhaled* May cause irritation. III* PHYSICAL AND CHEMICAL DATA Appearance and Odor: Hark grey powder or pellets, no odor Density, at 25 deg C Mg/cu m5 1.80 SoLubitity in Water! Negligible Percent VolatiLes by Volume? Negligible pH! 9*5 for 100 g/l dilution (* - Registered in U.S. Patent and Trademark Office) SAL 000007192 Information presented herein has been compiled from sources considered to be dependable ana is accurate and reliable to the best of our Knowledge ana belief but is not guarantee<3 to be so. Nothing herein is to be construed as recornmenOing any practice or any product in violation of any patent or in violation of any law or regu'ation. ft is the user's responsibility to determine tor himself the suitability ot any material tor a specific purpose ana to adopt such safety precautions as mav he r-e-.essarv We make no warranty as to the results to tie obtained in using any material ana. since conditions of use are not under our control, we must GS652mDSi THERMAX (All Grades) Pag 2 of 4 IV* FIRE PROTECTIOK Flash Point (deg C/deg F> ? N/A Extinguishing Media* Carbon dioxide# foam Special Firefighting Procedure? None Unusual Fire Hazard* None V* REACTIVITY DATA Therma l Stability? Stable Materials to Avoid? Strong oxidizers such as chlorates# bromates# nitrates, liquid oxygen* Hazardous Polymerization? Will not occur* Hazardous Decomposition Products? None ( VI* HEALTH HAZARD DATA Exposure Limits? OSHA 3*5 mg/cu m/Q hr. TWA ACGIH 3*5 mg/cu m/8 hr. TWA Effects of Overexposure? Particulate dust irritant to upper respiratory tract# eyes and skin* May cause drying of nasal passages* SAL 000007193 information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and be"*' but is not guaranteed to be so Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation cf any la* cr rp-_.iaticn i- 's the uv?-'s responsibility to determine for himselt the suitability of any material for a specific purpose and to adopt such safety precautions as ' " ..... : "'O 'n? ct usn a-c nnt u~"1er ou' conti-c1 we CrS6 52MSDSt THERMAX (Alt Grades) Page 3 of 4 VII* PHYSIOLOGICAL EFFECTS SUMMARY Slight to moderate skin and eye irritation (reversible) has been reported in dusty envircnments* Reports of reduced lung capacity due to prolonged exposure to excessive dust level areas do not exist. Damage* however* appears nonneoplastic/non-fibrotic/non-malignant in nature* In effect* there is little weLL--demonstrated health hazard to humans from exposure to product* Medical Conditions Generally Aggravated By Exposure* Unknown* VIII* PRECAUTIONS FOR SAFE HANDLING Avo i d inhalation of dust concentrations exceeding standards* SAL 000007194 Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and be Put is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product m violation of any patent or in violation of any cr regu'ation it is the users responsibility lo determine for hlmsetf the suitability of any material for a specific purpose and to adopt such safety precautions .. .. - he nt-*a -,e-* ,n u?,nc any mater ai 3nd since cond nons of use are not under our control we m CrS652MSDSi THERMAX (ALL Grades) Page 4 of 4 IX, PROTECTION AND CONTROL MEASURES Protective Equipment: Zf dusty conditions exist* use chemicaL goggles and skin protection* Respiratory Protection? Aii--purifying particle respirator (quarter or half mask) if engineering controls are in sufficient to maintain safe dust levels* Ventilations Local exhaust recommended <100--200 fpm capture velocity)* X, EMERGENCY AND FIRST AID PROCEDURES Eye Contacts Flush with water. Skin Contact? Uash with soap and water* Inhalation* Expose to fresh air, but no acute respiratory reaction is expected* XI* SPILL AND DISPOSAL PROCEDURES Spill or Leakage Procedure* Contain spills* Minimize dust generation into air* Deposit and store in closed containers* Waste Disposal? Dispose as per applicable state and local regulations* For Additional Information Contact? Environmental Affairs R* T* VANDERBILT CO., INC. 30 Winfield Street P*0* Box 5150 Norwalk* CT 06856 TeL* No*? <203) 853-1400 SAL 000007195 information present herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and pel but is not guaranteed to be so Nothing herein is to be construed as recommending any practice or any product in violation of any patent or m violation of any a* ' <nr hi-^K the v.:13finrv of anv material for a specific Purpose and To adopi such safety precaul'0"s as DC HD. 1180 .OR 2 6 tttt Telephone 17 RfUISIOH HD. 1 MATERIAL SAFETY DATA SHEET Anderson laboratories, Inc. 5901 Fitzhugh Avenue Fort Worth. Texas 76119 27-4474 EMERGENCY TEL. 800-424-93 I.C. Nfl. 13450, 13500, 13550, 13600, 14200, 14250, 14300, 14350, 14450, 14455, 14500, 14510, 14550 csm; (CHEMTREC) 3/30/67 materials listed in this Oats Sheet are classified in accordance with the definitions set forth in 29CFR Part 1910.120 NDtUCTJiAHE: EUFTER, pH 7 CQNCEHTRAU t:UF r Eft SOLDI 1DH. pri ? 2, For Giensa St sin SUFFER SDLUTIBH, pH 6.4, Giordano DUFFER SDLUTIBH, pH 6.8, French, Modified DUFFER SDLUTIDH, pH 5.58 +- 0.02 at 25 deg. C (OFFER SOiUTICH, REFERENCE STANDARD, pH 6.00 +- 0.02 at 25 deg. C DUFFER SDLUTIDH, pH 6.47 +- 0.02 at 25 deg. C DUFFER SOLUTION, pH t.86 * ~ 0.02 at 25 deg. C DUFFER SOLUTION, Reference, pH 7.00 i- 0.01 at 25 deg. C '6 U F r E R SOLUTION DLBfc CODED pH 7.00 *- 0.01 at 25 deg. C DUFFER SDLUTIDH, ;.h 7.38 + - 0.01 at 25 deg. C COFFER SOLUTION. pH 7.60 f- 0.02 DUFFER SOLI IBH, pH 6.00 +- 0.02 AT 25 deg. C CHEMICAL FAMILY: Phosphate Hfl I S_DE SI CftT IDK: HAZARD MATERIALS IDENTIFICATION SYSTEM DOT SHIPPING NAME: fc/R HEALTH1_ 4 - Severe Hazard HAZARD CLASS 8/H FLAMMABILITY. 0 3 - Serious Hazard 1 D. NO. . t'./P. REACTIVITY ___ 0___ 2 - Moderate Hazard PERSONAL PROTECTION 1 - Slight Hazard glasses C - Minimi Hazard COMPONENTS 1/. OP GREATER Contains carci nogeni c: ocp pounds 0.12 or greaterYes___ %.No. ; Then i cal:2 AS. NO___________________________________!H!N TP /1 ARC_________________ i ___ Exposure_L inits :~_:S!_______________________________________________________ C arci no gen__ I__ TLU____1__STElIPEL ' 1List i I1 . Sidiun Phosphate, di basic .7558-79-4 <1 RAX I HO K/A N/A S N/A ii a t ddassnm Phc-spha t:e, 110 1:0 basiC :/77S-77-G : <1 MAX ! m N/fi N/A ! N/A 1$ : HATER 7 / 32-iC -5 , MATRIX ; NO X/fi x/ft ; H/A 1 PERTINENT PHYSICAL DATA: foiling F o i r-t ?v T____ vUi-O' : fcsi'ff r/4 __ nn m at N/h___ deg C 'lilting Point x. rV3pnr5tl0n . iH2;f i c b r a v f o Faster Si-oyer than ether. X Hot applicable h b \ '. . r L i :ht er tr.sn yad-r. X Not apc1 '" i'o" uf ns i c u. Heavier Lightc.f f.an air X Not aprli cable. reararc-e and c-o-' odorless ^nd odorless liguid cable. SAL 000007196 Cr S 6 51 l?l AHO EXPLOSION DATA flammability Classification ______ 'ftinguishing lledia: _____ Foar- __ ;suai Fire and explosion Hazards DDT,Flash Pt _______________ xHot applicable Alcohol Fean, _____ Dry ChenicjiMater Fog.- ___ X___ Wot applicable Hone HEALTH HAZARD DA:A. of over--ex jjos.'.'T'e: hay sau:-,e e;f irrjtatic-n Tc-Uity Data: Hill kSDUK FDR THU PRDLDCT Target Srgafts; Ckifi jfss*i eyes. F-inary Routes cf Entry:___X___ E-emai,Inhalation,Ingestion Eneroe ftc and firs-. ;t Procedures. U splashed m fyes flush u:tr-, tater for at least ID minutes UiCTUIT'f; It -a p 1 t >/ ______ _Unso able, _____________ X_ Hazardous Pi-lyneriiaf ion: _______ ^a'j occur Hazardous Decomposition Products: KUNL Conditions to avoid: NONE Incompatibility materials to avoid) NONE Stable X uili not occur. :;FUl AND LEAK PSDCEGUSES rsvhU spill area uith co&iuvs amounrs of wits? VrU. HAf&L:r,G fiHf iicC IKFCFhA: lf!j Respiratory Protection: Hot . , p U: 1 ? VEWT1LATIDW: Hot applicable Protective glovesYes ___X___ ho Aprons_____ Lab Coat_______ Eye ProtectionXYes ______ Ho (glasses___ X____ goggles) "fulfil, precautions.slXiCOLOcICAL PROPERTIES DHkKQMW. Do not get ir: eyes. Avoid skin Giiht act. t.i.j'ii- inhalation ane contc-:': uith skin and eyes DiSCLAIflER Hr LIABILITY information in this USDS *as cGtainey frnn sources uhich ue believe are reliable. HOWEVER, THE INfQfiflATJUN U VIDED WITHOUT MY gEPRESCHTAT'EN CR WARRANTY; EXPRESS OR IMPLIED, PEGARDIHC ITS ACCURACY OR CORRECTNESS. conditions or methods t-t itandiina, storage, use and disposal of the product are beyond our control and nay be bey Khculetfae. FGR iHZS AND OTHER REftCDHS. WE DD HOT ASSIWE RESPOKSlblLlTY MRECTLY DR INDIRECTLY AHb EXPRESSLY DISC oUITY FDR LOSS; UHA9E DR EXPENSE ARISIKC DOT OF DP IK ARY WAV CEriKECTED WITH THE HANDL1H6, STDRASE; USE DR DUPE THE PRODUCT DR THE IHFDRftATlQH FUR8IVHED THEREWITH.*** SAL 000007197 chemists helping'chemists in research & industry aldrldi chemical co. p.O. Box 355, Milwaukee, Wisconsin 53201 USA ATTNs SAFETY DIRECTOR CONOCO INC REFINERY WAREHOUSE PO BOX 37 OLD SPANISH TRAIL WESTLAKE LA 70669 Telephone: (414) 273-3850 TWX; (910) 262*3052 Aldrichem Ml Telex: 26 843 Aldrich Ml FAX: (414) 273-4979 606 50 DATES 03/08/90 COST#: 923153 - PO#s 316--LPA 256781 MATERIAL SAFETY DATA SHEET PAGE MPRFO? DCUC2T5#H: 5240C5L6^if-^iE^^^ftev;^'' IDENTIFICATION NAME: ALIOUAT 336 NONYHS r* - ; ALIOUAT 336 ALIOUAT 336N * ALIOUAT 336-PTC * HETHYLTRICAPRYCYLAHMONIUM CHLORIDE *METHYLTR|OCTYLAHMONIUII CHLORIDE * 1-OCTANAMINIUH* N-METHYL-N*N-DIOCTYL-e CHLORIDE (9CI) TRICAPRYLMETHYLAMHONIUM CHLORIDE * TRlCAPRYLYLMETHYLAMMONIUK CHLORIDE * TRIOCTYLHETHYLAHHONIUM CHLORIDE * TOXICITY HAZARDS ---------------------------- TlwS NO: BR8575000 AMMONIUM* METHYLTRIOCTYL-* CHLORIDE 3XJCITY DATA IL-RAT LD50S223 MG/KG /R--RAT LD50S6600 UG/KG ORL-MUS L0505280 MG/KG IPR-MUS LD50I3300 UG/KG EVIEWS* STANDARDS* AND REGULATIONS _ NOES 1983SHZD X79025 NIS 25 TNF 105 EPA T5CA2.-CHEHICAL INVENTORY* 1986 ARGlEHAVI^AEMftuSCLE WEAKNESS) NOS mn it-mm AEHA** 33-3-68/71 AEHA** 33-3-68/71 TNE 105 TF6 7 ir DEPRESSION) ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL EfTRY IN RTECS FOR COMPLETE INFORMATION, HEALTH HAZARO OATA CUTE EFFECTS HARMFUL IF SHALLOWED. causes severe eye Irritation. CAUSES SKIN IRRITATION. material is irritating to mucous MEMBRANES ANO UPPER RESPIRATORY TRACT. - - IRST AID ' - IN CASE OF CONTACT* IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING ANO SHOES. ____ IF INHALED* REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT* GIVE OXYGEN. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE. CONTINUED ON NEXT PAGE SAL 000007198 4l0BimHl44 AM--> CMBlt Bout-lO LWKtOTKOl* (40 M Bd I 4Q ae 1--ihcoB4-1030 8^14*<4'6m--I >MB-- 11*747 HgMtMl!O*K*=U**HM4 wanovcntiiM SaiI 27. Fe-- am 7ran* F-4700C Straatn>M| 74--(xw aaiarato (an *90074 ***** F FAX 4*761243 AMricft CMnks *xl WJ74O--tF?fwteWmrtf*eTnoem. 4 FAxaamsoiIMw 330442 Aioncfi I AJdrich Japan K(y0B--OO --490SuNiNctwIIUI 0>lW Fn. T*ne Tt4p*om 0326*0116 FAX: 032M0167 --t< Vc a* Cbimi ci aiw 'HUnlll *4-- 74-- 410639*77 TMn.2tSAQ-E FAX. 11443*0*4 AWWi CMM41C*, U4 T9* OM me*--a. Nm Kfiad OBMIMI, Dow SP* 4JL Ta--am4. 074742221I 7*--417234 *1*9*0 FAX: D747423779 Amm*mC-- Omn a co. KO OTTmM-baT*pMW71e.4i4lV3743H2494i4*7100 FAX: 073294)1 >4/734 chemists helping chemists in research & industry aldrlch chemical co. P.O. Box 355, Utlwtukoo, Wisconsin 53201 USA Telephone: (414) 273-3650 TWX: (910) 262-3052 AMrlchem Ml Telex: 26 843 Akkich Ml FAX: (414) 273-4979 S 6 50 MATERIAL SAFETY DATA SHEET PAGE 2 OUST#: 923153 PO#8 316--LPA 256781 PRODUCT #s 20561-3 CAS #85137-55-3 HFs C25H54CLN SPECIFIC GRAY JPEARANCE AND OD VISCOUS YELL FLASHPOINT (TINGUISHIN6 CARBON OIOXI DRY CHEHIC 4ATER SPAA.. PfcuIAL FtREFIGH WEAR SELF^CO PREVENT C '(USUAL FIRE EMITS TO NCOMPATIBIL STRONG 0 AZAROOUS CO CARBON M NITROGEN HYDROGEN iTEPS TO BE WEAR RESP, RUBBER GL ABSORB ON DISPOSAL* VENTILATE rARE . (ASTE DISPOSALyiETHOO DISSOLVE 0* MIX THE CHEMICAL INCINERA OBSERVE ALL OE WEAR APPROPRIAT GLOVESt SAFETY GO&fctS SAFETY SHOWER ANO EYE_____ USE ONLY IN A CHEMICAL FUN 00 NOT BREATHE DUST DO NOT GET IN EYES# ON SKINe ON CLOTHING^" CONTINUED ON NEXT PAGE SAL 000007199 AjetKfi CMh SoMwt Lmmwi M Bd 1 ----t-n- 1*6 M 8-1630 rwapAon*. 9**ud 11*747 Alonai-CtnaM 8xrx F-07000 Smcouri TMefton* 8833T010 tmk. taoore na a FAX 18711383 aam o*Kt %jx MT7aMir_C?AMienO* M027MHM8eM*l 7ax aaaxMi Riode 8M.b*1 10 AilIda Mltiractia CMVM-Ku. TedW ***** 03M801M M**}in AMnoc*aOcM5IdrOanOi Hi M100 Alcotand-- 81*08* TMer<OfW 818038877 INcaiNWSM FFAAXX* 8811888833880088** uwiOwhcaui T0h8* OQMIaIn.cCtcwor*t. 8H8m8mUHM TaMpAcav 07*7823311 TM* 417238 AIM* O FAX 07*7823778 AHUsa-OmiM* 0>W18 c. n D-782* 8mm aaa TMPMm 7338878 TMaa; 714838 A*88 8 'A* 0733887 >38488 t chemists helping chemists in research & industry j aldrlch chemical co. P.O. Box 355, Milwaukee, Wisconsin 53201 USA Telephone: (414) 273-3850 TWX: (010) 262-3052 Aldrichem Ml Telex: 26 643 Aldrich Ml FAX: (414) 273-4970 6S6 50 MATERIAL SAFETY DATA SHEET PACE 3 CUST#s 923153 PO#t 316--LPA 2567BI PROOUCT #2 20561-3 CAS #:5137-55-3 MF: C25H54CLN NAME: AL1QUAT 336 ------ PRECAUTIONS TO BE TAKEN IN HANOLING AND STORAGE -- AVOID PROLONGED OR REPEATEO EXPOSURE* WASH THOROUGHLY AFTER >IANDLINGe TOXIC 1 IRRITANT. i?v - KEEP TIGHTLY CLOSED*' HYGROSCOPIC M_ STORE IN A COOL DRY PLACE. ADDITIONAL PRECAUTIONS AND COMMENTS TIONAL INFORMATION rRlCAPRYLYLMETHYLAMMONIUM CHL0RI06 ALIOUAT IS A REGISTERED TRADEMARK OF HENKEL CORPORATION* if 10VE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE L NCLUSIVE AND SHALL BE USEO ONLY AS A GUIDE* ALDRICH SHALL NOT BE HELO ABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE OVE PRODUCT* SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL RMS AND CONDITIONS OF SALE* jPYRIGHT 1990 ALDRICH CHEMICAL CO INC* (CENSE GRANTEO TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY* n-i-T1)*i SAL 000007200 *ai#OTVMa* AidnOi apJm&g LwiMmeM 1*0 M BO LMMnmlun 140 M e-ioaa TiHQHqm . 0i*ai 114747 HP4.M 04021474* Fr***4 S*>1 77. FoM4 4m Txb* 7-47000 900i4* Tccn (M2701O tKt U7smjT*mi *90074 AWfcn F *r UMTi Cr<MK* V4 Ptotro Tom*. 4 20127 HUW 7022913*** Ta tMtOS ***** I fi* aawm Jw* UKiMMoJK(MnMJM iOMW4*ncM CMyoda-Mu, Tokyo TooKM 032SM1M fUHTSMil? it* *A***.*9**0C*o1n>e04* 1*1 21Q0 tKOCWM (Utdrm TaMpMn* tlWNTT TM.221HtAOe-C FAX. 114*90004 UMMO iQbiTm AJ9** CtiMlcot Co_ LM Th* OW (Ackyw*. Mm Amo ON*m.DnMU Tt*pMonr 07*7(22211 T*ta. 4I77M ATM, 8 FAX 0747123m AJOrtcn-CAMM * Co *a 0-7(24 SUinftMn TMMAon* 7329*70 TiMi. 714*30 Ajon 0 FAX. 073290713*7239 Cconoco) Conoco Inc. Purchase Requisition Page of Shaded Areas RQ Loc Requisition No. for Purctaetrig Dept. ^jSeOnly 316 256781 CO e r Information Priority RLOC Departrqeffl flfeB Frefining Ship Via Date Req'd at Dest. Order Type Previous P.O. ROHKAL Ship Jo Tagging Instructions M-nttlCH CHEMICAL f.O.B. Point i-reight Terms p. 0. BOX 355 MILWAUKEE. Wt 53201 - ttn: HAILED 800-558-9160 equisit^gjr Date Conoco Inc, Carrie# Refinery Warehouse Old Spanish Trail P.O. Box 37 Project ID Westlake, LA 70669 Distribution Charge t. Clauses < AFE Reporting HACHELLE 318-491-5406 2/21/90 Tax Status Special Instructions rge Exempt o% 7411-3-0-149-03-13 ( D*t* Control WO 56781 2/21/90 S149 Equip. No. Tim* Inlt Stat. Ord*rd SH 9 HAIL NRO 20* 561-3 Allquat 336 (Xlkg) 7411-3-0-149-03-13 12 luue rric* bott] es Oty. IstuM APPROVED: & COWDEH / (7/ S) HAILED ORDER TO ALDRICH CHEMICAL 0 + A - OperaUng Dept Approve) - Purchasing Dept SAL 000007201 CENTURY PAPERS INC. 4902 GULF FREEWAY HOUSTON, TEXAS 77023 TEL. NO. 713/928--5171 MANUFACTURER: S 6 45S.C.JOHNSON C SON. INC^i RTEALC.INNE.6. W4I 1543/643013--25701717 V U EMERGENCY TEL. NO. 414/631-2000 .aterial safety oata sheet SECTION 1 IDENTIFICATION OF PROOUCT PROOUCT NAME: COMPLETE FOR FLOORS PRODUCT CODE: 14650-032, __ ITEM NO. 420-1604, 420-1612, 420-1647 ISSUE DATE: SHEET NO. 0547 DECEMBER 12f ~1989 NATIONAL ITEM#: 2244XX SECTION Z. INGRcOIENTS CAS NUMBER WEIGHT X EXPOSURE LIMIT MOOIFIEO ACRYLIC POLYMER ETHYLENE GLYCOL DIETHYLENE GLYCOL MONOETHYL ETHER AMMONIUM HYDROXIOE 107-21-1 111-90-0 1336-21-6 10-20 1-3 1-3 1-3 NE 50 PPM ACGIH TLV-TWA 30 PPM SUPPLIER RECOMMENDED 25 PPM (ACGIH TLV-TWA); 50 PPM (OSHA PEL) AS AMMONIA WATER 80-90 NA THESE MATERIALS ARE SUBJECT TO THE REPORTING REQUIREMENTS UNDER THE SUPERFUND AMENDMENTS ANO REAUTHORIZATION ACT OF 1986 (SARA) TITLE III, SECTION 313 AND CFR PART 372. NA = NOT APPLICABLE; NO = NOT DETERMINED; NSR = NO SPECIAL REQUIREMENT SECTION 3 PHYSICAL OATA BOILING POINT (F): A30VE 200 SPECIFIC GRAVITY (WATER*1): 1.03 VAPOR PRESSURE (MM HG.): NA PERCENT VOLATILE (8Y VOLUME): NA /APOR DENSITY (AIR=1): NA EVAPORATION RATE (SUTYL ACETAT6=1): SOLUBILITY IN WATER: COMPLETE PH RANGE: 9.2 - 9.6 FREEZING POING (F): ND APPEARANCE/ODOR: OPAQUE, TAN LIQUIO WITH MILD WAX OR AMMONIACAL ODOR NO SECTION 4. FIRE AND EXPLOSION HAZARO DATA FLASH POINT (F)(TEST METHOO): NA FLAMMABLE LIMITS: NA EXTINGUISHING MEDIA: FOAM. C02. DRY CHEMICAL, WATER FOG SPECIAL FIRE FIGHTING PROCEDURES: NORMAL FIRE FIGHTING PROCEDURES 3E USED. UNUSUAL FIRE EXPLOSION HAZARDS: NO SPECIAL HAZARDS KNOWN MAY SECTION 5 REACTIVITY OATA STABILITY: STA3LE CONDITIONS TO AVOIO: NONE KNOWN INCOMPATIBILITY - MATERIALS TO AVOID: NONE KNOWN HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE KNOWN HAZARDOUS DECOMPOSITION PRODUCTS: WHEN EXPOSED TO FIRE, PRODUCES PRODUCTS OF COMBUSTION. NORMAL SECTION 6. SPILL, LEAK ANO DISPOSAL PROCEDURES SPILL*RESPONSE: DO NOT LET SPILLED OR LEAKING MATERIAL ENTER WASTE WATERCOURSE. CONTAINS AMMONIA ANO ZINC. MAY BE TOXIC TO AQUATIC LIFE. ABSORB WITH OIL-DRI OR SIMILAR INERT MATERIAL. SWEEP OR SCRAPE UP ANO CONTAINERIZE. OISPOSAL: NO SPECIAL METHOD. OBSERVE ALL APPLICABLE FEOERAL/STATE REGULATIONS AND LOCAL ORDINANCES REGARDING DISPOSAL OF NON-HAZAROOUS MATERIALS. WASTE FROM NORMAL PROOUCT USE MAY BE SEWERED TO A PU3LIC-OWN6D TREATMENT WORKS (POTW) IN COMPLIANCE WITH APPLICABLE FEDERAL, STATE, ANO LOCAL PRETREATMENT REQUIREMENTS. SAL 000007202 MATERIAL SAFETY DATA SHEET ,, PROOUCT NAME: COMPLETE FOR FLOORS ^ Gi% S 6* 4a 5w PROOUCT NO* 420-1604, 420-1612, 420-1647 U U SECTION 7, HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: NA SIGNS AND SYMPTOMS: NA sicTION_aT EMERGENCY ANO FIRST AID PROCEDURES pAce 2 FIRST AID PROCEDURES: NA SECTIONTM"* SpidAL PROTECTION INFORMATION RESPIRATORY PROTECTION: NO SPECIAL REQUIREMENTS UNOER NORMAL USE CONDITIONS. VENTILATION: NSR PROTECTION GLOVES: NO SPECIAL REQUIREMENTS UNOER NORMAL USE CONDITIONS. EYE PROTECTION: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONOITIQNS. OTHER PROTECTIVE MEASURES: USE GOOD PERSONAL HYGIENE PRACTICES. SECTION 10. ADDITIONAL INFORMATION ANO PRECAUTIONS PRECAUTIONARY LABELING: NA HANDLING AND STORAGE CONDITIONS: STORE IN A COOL. ORY PLACE WITH ADEQUATE VENTILATION. KEEP FROM FREEZING. HMIS RATINGS: HAELTH 0, FLAMMABILITY 0, REACTIVITY 0 PREPARED BY: ROBERT 5. 03REIN CHEMICAL INFO. ADMINISTRATOR THE INFORMATION HEREIN IS GIVEN IN GOOO FAITH. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE. ANY USE OF THESE DATA ANO INFORMATION MUST BE DETERMINED BY THE USER TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL. STATE, ANO LOCAL LAWS ANO REGULATIONS. r i SAL 000007203 CENTURY PAPERS INC 4902 GULP FREEWAY HOUSTON, TEXAS 77023 TEL. NO. 713/928-5171 material safety data sheet manufacturers S.C. JOHNSON C SON. INC. RACINE. WI 53403-5011 TEL. NO. 414/631-2777 EMERGENCY TEL. NO. 414/631-2000 G S 6 46 ITEM NO. 409-0802 SECTION 1. IDENTIFICATION OF PROOUCT SHEET NO. 0576 PRODUCT NAME : LEMON SHINE-UP (PRESSURIZEO) PROOUCT CODE : 14440-017-018 PROOUCT NO. 409-0802 ISSUE 0AT6: 06CEM86R 12. 1989 NATIONAL ITEM#: 3234XX SECTION 2. INGREDIENTS CAS NUMBER WEIGHT X EXPOSURE LIMIT ISOPARAFFINIC HYDROCARdON SOLVENT PROPANE,ISOBUTANS, N-8UTANE 64742-48-9 74-98-6, 75-28-5. 106-97-8 10-20 10-20 400 PPM (SUPPLIER RECOMMENOEO) 1000 PPM (OSHA PEL) (PROPANE) 800 PPM (ACGIH TLV-TWAKN-BUTANE) SILICONE FLUID 63148-62-9 1-3 NO WATER 70-80 NA NA = NOT APPLICABLE; N0_= NOT DETERMINED; NSR = NO SPECIAL REQUIREMENTS SECTION 3. PHYSICAL OATA SOILING POINT (F): NA SPECIFIC GRAVITY (WATERED: 0.9 VAPOR PRESSURE (MM HG.): NO PERCENT VOLATILE (BY VOLUME): NA VAPOR OENSITY (AIR-1): NO EVAPORATION RATE (BUTYL ACTAT=1): SOLUBILITY IN WATER: NEGLIGIBLE PH RANGE: NA FREEZING POINT: NA APPEARANCE/QOOR: OISPENSEO AS CREAMY SPRAY WITH LEMON ODOR NA SECTION 4. FIRE ANO EXPLOSION HAZARD OATA FLASH POINT (F) (HETHOO USED): UNDER 20 (TCC) (PROPELLANT) FLAMMABLE LIMITS: NO EXTINGUISHING MEDIA: FOAM. C02. ORY CHEMICAL. WATER FOG SPECIAL FIRE FIGHTING PROCEDURES: NORMAL FIRE FIGHTING PROCEDURES HAY 8E USED. FIGHT FIRE FROM MAXIMUM DISTANCE OR PROTECTED AREA. COOL ANO USE CAUTION WHEN APPROACHING OR HANOLING FIRE-EXPOSED CONTAINERS UNUSUAL FIRE C EXPLOSION HAZAROS: CONTAINER MAY BURST IN HEAT OF FIRE. SECTION 5. REACTIVITY DATA ~ STABILITY: STABLE CONDITIONS TO AVOID: NONE KNOWN INCOMPATIBILITY - MATERIALS TO AVOID: NONE KNOWN HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONOITIONS TO AVOID: NONE KNOWN HAZARDOUS DECOMPOSITION PRODUCTS: WHEN EXPOSED TO FIRE, PRODUCES NORMAL PROOUCTS OF COMBUSTION. SECTION 6. SPILL, LEAK ANO DISPOSAL PROCEDURES SPILL WASTE RESPONSE: ELIMINATE ALL IGNITION SOURCES. ABSORB WITH OIL-ORI OR SIMILAR INERT MATERIAL. SWEEP OR SCRAPE UP ANO CONTAINERIZE. OISPOSAL: DISPOSE OF AEROSOL CAN BY WRAPPING ANO PLACING IN TRASH. DO NOT PUNCTURE OR 8URN CONTAINER. OISPOSE OF SPILLED RESIDUES ANO MULTIPLE UNITS IN ACCORDANCE WITH ALL FEOERAL/STATE REGULATIONS AND LOCAL ORDINANCES. SAL 000007204 MATERIAL SAFETY DATA SHEET k PROOUCT NAME: LEMON SHINE-UP (PRESSURIZED) PRODUCT NO. 409-0802 ^ V S ft & A UU O PAGE 2 SECTION 7. HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: EYE CONTACT SIGNS AND SYMPTOMS: DIRECT CONTACT OF PROOUCT WITH EYES CAN CAUSE IRRITATION.^ SECTION 8. EMERGENCY AND FIRST AID PROCEDURES FIRST AID PROCEDURES: FLUSH EYES WITH WATER FOR 15 MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL AIO. SECTION 9. SPECIAL PROTECTION INFORMATION RisPIRATORY PROTECTION: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. VENTILATION: GENERAL ROOM VENTILATION ADEQUATE. PROTECTION GLOVES: NO SPECIAL REQUIREMENTS UNOER NORMAL USE CONDITIONS. EYE PROTECTION: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. OTHER PROTECTIVE MEASURES: USE GOOD PERSONAL HYGIENE PRACTICES. SECTION 10. ADDITIONAL INFORMATION AND PRECAUTIONS PRECAUTIONARY LABELING: CAUTION: 00 NOT USE NEAR FIRE, FLAME OR PILOT LIGHT. 00 NOT SET ON STOVE OR RADIATOR OR KEEP WHERE TEMPERATURE EXCEEDS 120 F AS CONTAINER MAY BURST. 00 NOT PUNCTURE OR THROW IN FIRE. KEEP OUT OF REACH OF CHILOREN. NEVER USE ON FLOORS OR SURFACES THAT ARE WALKEO ON AS THE PRODUCT'S INGREOIENTS COULO MAKE THEM SLIPPERY. AVOID OVERSPRAY. HANDLING AND STORAGE CONDITIONS: STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP FROM FREEZING. 00 NOT PRESSURIZE, CUT, HEAT, WELD OR EXPOSE CONTAINER TO FLAME EXPLOSION COULD OCCUR. HMIS RATINGS: HEALTH 1, FLAMMA8ILITY 4, REACTIVITY 0 PREPARED BY: ROBERT B. O'BRIEN CHEMICAL INFO. ADM. THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE. ANY USE OF THESE DATA AND INFORMATION MUST BE DETERMINED BY THE USER TO 06 IN ACCORDANCE WITH APPLICABLE FEOERAL, STATE, AND LOCAL LAWS AND REGULATIONS. SAL 000007205 CENTURY PAPERS INC. 4902 GULF FREEWAY HOUSTON. TX 77023 PHONE NO. 713/ 928-5171 MANUFACTURER: /i m mg CARROLL COMPANY tt"S 6`47 2900 W6ST kingsi*ey rd. WW GARLANO f TX 75041 EMERGENCY TELEPHONE NO. (214) 278-130*^ SECTION 1- PRODUCT IDENTIFICATION PROOUCT NAME: MR. JON 2 BOWL CLEANER ISSUE OATE: DECEMBER 12f 1989 SHEET NO. 0311 PRODUCT COOE : 454 ITEM NO. 408-0475 , 408-0483 SECTION 2- HAZARDOUS INGREDIENTS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES: % HYDROCHLORIC ACID 25 X SECTION 3- PHYSICAL OATA SPECIFIC GRAVITY(H20=1): 1.139 SOLUBILITY IN WATER: APPEARANCE AND QOQR: BROWN LIQUID, PUNGENT COMPLETE SECTION 4- FIRE AND EXPLOSION HAZARD OATA UNUSUAL FIRE AND EXPLOSION HAZARDS: PRODUCT ACTS WITH METALS TO PRODUCE FLAMMABLE HYDROGEN. SECTION 5- HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: UNDETERMINED EFFECTS OF OVEREXPOSURE: SKIN C EYE- CAN CAUSE SEVERE BURNS. INGESTION- f -HARMFUL OR FATAL IF SWALLOWSO. INHALATION- CONTAINS CORROSIVE FUMES. ' -HARMFUL IF INHALED. EMERGENCY ANO FIRST AID PROCEDURES: SKIN- WASH WITH SOAP AND WATER. EYE- -FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION- IF SWALLOWED. GIVE LARGE AMOUNT OF MILK OR WATER TO ORINK. GET MEDICAL ATTENTION IMMEDIATELY. INHALATION- MOVE TO FRESH- AIR. SECTION 6- REACTIVITY OATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: AVOID CONTACT WITH GASES AND CHLORINE BLEACHES. SECTION 7- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: FLOOO AREA WITH WATER AND MOP UP. SECTION 8- SPECIAL PROTECTION INFORMATION^ VENTILATION: RECOMMENDED PROTECTIVE GLOVES: EYE PROTECTION: GOGGLES , IF SPLASH MAY OCCUR. RECOMMENOED SECTION 9- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING: CLOSEO TO AVOID ESCAPE OF CORROSIVE FUMES. KEEP CONTAINER TIGHTLY SAL 000007206 CENTURY PAPERS. INC4902 GULF FREEWAY HOUSTON, TEXAS 77023 PHONE NO. 713-928-5171 ATERIAL SAFETY DATA SHEET SECTION 1- PRODUCT IDENTIFICATION PRODUCT NAME: PUMici SCOURING BARS MANUFACTURER: UNITEO STATES PUMICE CO, 20219 BAHAMA STREET CHATSWORTH. CA. 91311 EMERGENCY PHONE NO* 818-828-0300 SHEET NO. 1347 PROOUCT NO. 403-1005 ISSUE DATE: DECEMBER 12, 1989 SECTION 2- HAZARDOUS INGREDIENT$/IDENTITY INFORMATION HAZARDOUS COMPONENTS: PUMICE (VOLCANIC GLASS) THERE IS NO FREE CRYSTALLINE SILICA PRESENT SECTION 3- PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: N/A VAPOR PRESSURE: N/A VAPOR DENSITY: N/A SOLUBILITY IN WATER: NOT SOLUBLE SPECIFIC GRAVITY: N/A MELTING POINT: 2390 F. EVAPORATION RATE: N/A APPEARANCE ANO ODOR: ODORLESS SOLID SECTION 4- FIRE ANO EXPLOSION HAZARD DATA FLASH POINT: NA FLAMMABLE LIMITS: EXTINGUISHING MEDIA: N/A SPECIAL FIRE FIGHTING PROCEDURES: NONE UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE LEL: NA UEL: NA SECTION 5- REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID: NONE INCOMPATIBILITY: NONE HAZARDOUS DECOMPOSITION OR BYPRODUCTS: NONE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE SECTION 6- HEALTH HAZARD DATA ROUTES OF ENTRY: INHALATION, INGESTION HEALTH HAZARDS (ACUTE AND CHRONIC): DRY SAWING OR GRINDING MAY RESULT IN THE RELEASE OF DUST PARTICLES WHICH, ACUTE, MAY CAUSE IRRITATION OF EYES, NOSE OR THROAT ANO CHRONIC MAY RESULT IN LUNG OISEASE (SILICOSIS) IF EXPOSED FOR PROLONGED TIME- CARCINOGENICITY: NTP: NO IARC MONGRAPHS: NO OSHA REGULATED: NO SIGNS ANO SYMPTOMS OF EXPOSURE: IRRITATION OF EYES, NOSE OR THROAT OR SHORTNESS OF BREATH. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: PRE EXISTING LUNG OISEASE SUCH AS EMPHYSEMA OR ASTHMA. EMERGENCY ANO FIRST AID PROCEDURES: IRRIGATE EYES GENEROUSLY WITH CLEAN WATER FOR 15 MINUTES, IF IRRITATION PERSISTS, CALL A PHYSICIAN. SAL 000007207 ATERIAL SAFETY DATA SHEET ^^ r'RODUCT NAME: PUMICE SCOURING BARS PROOUCT NO. 40Q-1005 PAGE CS648 SECTION 7- PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN HANDLING ANO STORING: NONE OTHER PRECAUTIONS: WEAR NIOSH APPROVED RESPIRATOR AND TIGHT FITTING GOGGLES WHEN SAWING OR GRINOING, OR SAW 6 GRINO WHEN WET SECTION 8- CONTROL MEASURES RESPIRATORY PROTECTION (SPECIFY TYPE): NIOSH APPROVED PARTICULATE RESPIRATOR VENTILATION: MECHANICAL: IN CONFINED AREA PROTECTIVE GLOVES: WHEN REQUIREO EYE PROTECTION: TIGHT FITTING GOGGLES OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NONE WORK/HYGIENIC PRACTICES: N/A SAL 000007208 CENTURY PAPERS INC. 902 GULP FREEWAY HOUSTON* TEXAS 7T023 PHONE Nu. 713/928-5171 XTERIAL SAFETY DATA SHEET SECTION 1- PRODUCT IDENTIFICATION PROOUCT NAME: SWEEP 6Z ISSUE DATE: DECEMBER 12, 1989 SECTION 2- HAZARDOUS INGREDIENTS PRESERVATIVES ANO SOLVENTS: DUPONT ORGANIC OIL RED B LIQUID PINE SAWDUST MINERAL OIL MANUFACTURER: SORB-ALL CO. 2200 NANCE HOUSTON, TEXAS 77226 EMERGENCY PHONE NO. 713/223-4575 SHEET NO, 1306 s 6 49ITEM NO. 401-0019^ _ . ^ %: .4* 60% 40% TLV (UNITS) ALLOYS ANO METALLIC COATINGS: BASE METAL: N/A METALLIC COATINGS: N/A ALLOYS: N/A FILLER METAL PLUS COATING OR CORE FLUX: OTHERS: N/A %: N/A TLV(UNITS) HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS OR GASES: N/A SECTION 3- PHYSICAL DATA BOILING POINT (F.): VAPOR PRESSURE (MM HG.): SOLUBILITY IN WATER: APPEARANCE ANO ODOR: REO SPECIFIC GRAVITY (H20=l): PERCENT VOLATILE SY VOLUME: SECTION 4- FIRE AND EXPLOSION HAZARD DATA FLASH POINT (MEHTOD USED): OPEN CUP 360 F. EXTINGUISHING MEDIA: WATER SPRAY, CHEMICAL FOAM. ORY CHEMICAL, C02. SPECIAL FIRE FIGHTING PROCEDURES: EVACUATE PERSONNEL UNUSUAL FIRE ANO EXPLOSION HAZARDS: SECTION 5- HEALTH HAZARD OATA THRESHOLD LIMIT VALUE: NONE FOUND EFFECTS OF OVEREXPOSURE: NONE EMERGENCY FIRST AID PROCEDURES: NONE ilcTION 6- REACTIVITY_OATA STABILITY: STABLE INCOMPATIBILITY (MATERIALS TO AVOID): ,,,, iAL 000007209 UNKNOWN MATERIAL SAFETY DATA SHEET TRADE NAME: SWEEP EZ ITEM NO* 401-0019 PAGE 2 8649 SECTION 6- REACTIVITY DATA CONTINUED...... HAZARDOUS DECOMPOSITION PRODUCTS: N/A HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION 7- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SWEEP UP AND DISPOSE IN TRASH BIN. WASTE DISPOSAL METHOD: COMMON LANDFILL. SECTION 8* SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SPECIFY TYpil: VENTILATION: LOCAL EXHAUST, MECHANICAL (GENERAL). PROTECTIVE GLOVES: NOT REQUIRED EYE PROTECTION: OTHER PROTECTIVE EQUIPMENT: NONE SECTION 9- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: DO NOT STORE NEAR OPEN FLAME. OTHER PRECAUTIONS: WEAR SAFETY GLASSES. ooooo sM- 10:01 06 8 ddW SECTION I -- IDENTIFICATION PRODl CT NAME: St A PA tch GS6 19 PRODUCT TYPE* A fo rmulAted road patching compound OOT S HIPPING NAME* Not Hazardous according to DOT de f i nition s DOT t AZARO CLASS: Not AppI I cab I (N/A) DOT 0 NO.: N/A DOT LABEL* N/A SECTION II -- HAZARDOUS MATERIALS MAtmAlA WEIGHT PERCENT iLVlunlts) V Thii'product does not contain any ingredients considered hazardous according to Federal and Stats Worker Right* t o-Know laws. SECTION III -- PHYSICAL DATA BOILING POINT* over <00 % VOLlAT I LE BY WT . : 2 SPECIFIC GRAVITY (WATER 1): WT. PER GALLON* 13 to 14 N/A SOLUBILITY IN WATER Negligible pH: N/A APPEARANCE AND ODOR: a black solid road patch with an asphaltic binder SECTION IV -- FIRE AND EXPLOSION HAZARD DATA FLASHPOINT (METHOD USED): None to 200F EXT1N3UISHING MEDIA: ABC Fire Ex t I n g.u 1 s he r SPEC 1*1 FIREFIGHTING PROCEDURES: None UNUSUAL FIRE.AND EXPLOSION HAZARDS: None SAL 000007211 WSTWWTIOH HNTMI HalloNWPO* iMI IPflING onovc AV, CINCINNATI, OHIO 44m...S1MT4IOO Ul OUTH nn IT, ACMTON, WA t7QJAMSAL0F ;DOE BIVO. ATUNTA, GAXU..A04/W111 0 FRANOSCO *T, TOAAANCS, CA tOStt...nVttl 1714 122S TANEY VT. K KANSAS C*TY, uo Wi J1 tHOWAiAL Ja..CUMwO0 (EACH. tU 077W ..2CUMJMM INFASTRV STATION. BOX2W74 AO WtOAA*. AjftTO WCO PJ 777* XW. *4TH ST,*UUtt. Ft 0 c t u b <' i 30 I" <d !9ur Page \ of 3 &s:st n h x 6 --s -yyw StffCHEMICAL dlC MANUFACTURING CO. MAIN OFFICE ANO PLANT 20:! 0S< 8 atfW 3100 HAMILTON AVlNUC' CLEVELANO. OHIO 4AIU TELEPHONE! C2IS) ai-7H4 PRODU 3T NAME: Sta Patch G S6 19 SECTION V -- HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE: cases of direct contact. Nona expected, Mild eye Irritation could occur I LLB..3I AID PROCEDURES F SWALLOWED: Treat i ymp1oma 11ca I I y. t o ln see t. This material would be very dlfflcu IF lN HALEDi N/A. IF IN EYES: Flush eyes immediately with plenty of cool water for at least 15 minutes. If irritation continues get medical advice. IF ON SKIN: Wash with soap and water. SECTION VI -- REACTIVITY DATA STA8 . I TY t STABLE CONO I HONS TO AVOID: Contact with petroleum solvent. NCOM'ATIBILITY (Materials to avoid): None HAZAR )OUS DECOMPOSITION PRODUCTS: None Contact with acids HAZARDOUS POLYMERIZATION WILL NOT OCCUR. r- SECTION VII -- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Clear residue iwth small amount of solvent cleaner. Pick up with shovel WASTE DISPOSAL METHOD: Follow all Federal) State and Local ragulations r g a r ling waste disposal. nonha urdoui wutt, If material is over two years old dispose of as MSTAISUTION 1 1NTIM HAHO#YriOj 13 710600MOl pftlNO GftOVB AVI, CINCINNATI, OHIO <Utt..& /t <31 SOUTH ffH ST, MENTON. WA HOfl.-204/QIW: 1T0 JAMES ALMI Ode ILYO- ATLANTA, QA 130 FRANCISCO ST, TOWUNCE, CA IOtM..4fVUa TU 1221 TANEY T, n. kuv*a city. UO Hi t._4iVM4-6S 21 fNOlTA3ALea,CUFFW>BEACH,NV.HT3J...|/4*J-6fl08 U INFANTRY 5TAHON, BOX 2WT4 MO HEOftAS. MOTO WCO 00321 TTTA M H l*TW KT , Itmi Witt JClv ! 0C5 SAL 000007212 00 : T nh KOd CHEMICAL MANUFACTURING CO. MAIN OFFICE AND PLANT t/k3 t, I Wb B dON JlOO HAMILTON AVCNUC* CLCVCLANO, OHIO 44M4 TELEPHONE: <2161 S0I-71U PR0D1CT NAME: St a Pa tch GS6 19 SECTION VIII -- SPECIAL PROTECTION INFORMATION Eye i rotectlon end protective glove* re recommended Anytime you work with any concentrated Industrial strength cleaning products. RESP RATORY PROTECTION: N/A VENT LATION: If used Inside--ventilate area. PROTECTIVE GLOVESi optional EYE PROTECTION: optional OTHER PROTECTIVE EQUIPMENT: None SECTION IX -- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store In a cool, dry place In original labeled Oo not reuse empty container for any purpose. Store indoors during winter. Keep container covered when not In use. container. OTHEF PRECAUTIONS: Read and follow all label directions and precautions before using the product. These products are Intended for industrial use only. FOR INDUSTRIAL USE ONLY KEEP OUT OF THE REACH OF CHILDREN. While we believe that the data contained herein Is factual and the opin<i on*'expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consider4*tion. Investi gation, and verification. Any use of these data and information must ba determined by the user to be in accordance with applicable Federal. State, and Local laws and regulations. (HSTPUIUTiOAjCIMTIM NATIONWIDE: 2001 EPRINO OAOVt AVC., CINCINNATI. OHIO SOUTH TTM *T., FENTON, WA MOU.-.SMITM IM) UOJAMESALpf IMCBLVOh ATLANTA OA3033S..40iiaai< ttfl PIUNCIICO IMOMANGt CA MM2...HSfUa ITU iSttTAMCV ?, m. ka*5a| City. UO r industrial *. CUFFWOOO IEACH. NJ. 0T7,,,20l/6M-MeO fifi INFANTRY STATION. BOX 29174 W PlEOAAJ. PUERTO RICO # TTO N.W. MTH *T,, MtAMJ, FT, t 0 SAL 000007213 T0: Psan of It T n H X 06--8 -- Jd 0 w MATERIAL SAF EM SCIENCE A 01V IS ION OF EM INOUSTR1ES III WCCDCREST CHERRY HILL N.J. 08034-0395 ETY OATA SHEET PREPARATION DATE .......................: OCT 27, *8? INFORMATION PHCNE NLMBER i (609) 354-9200 CHEMTREC EMERGENCY NUMBER: 1-800-424-9300 1----------------------------------------------------------------------------------- ---------- I NFPA HAZARO RATINGS I I HEALTH 2 I REACTIVITY : l FLAMMABILITY SPECIAL HAZARDS*: 3 N/A CATALOG NUMBER(S) CHEMICAL NAME.**. TRADE NAME....... C.A.S. NUMBER.... CHEMICAL FAMILY.. FORMULA............... MOLECULAR HEIGHT. OOT SHIPPING NAME OOT NUMBER....... SECTION I - GENERAL INFORMATION MX08I9 MX0826 METHYL TERT-BUTYL ETHER TERT-BUTYL METHYL ETHER 1634-04-4 ALIPHATIC ETHER CH3CC(CH3 )3 88.14 N/A N/A GS6 18 SECTION II - HAZARDOUS INGREDIENTS -NONE OTHER THAN SPECIFIED PROCUCT SECTION III- PHYSICAL DATA BOILING POINT (C 760 MM HG).: 55C MELTING POINT (C)............... : -HOC SPECIFIC GRAVITY(H.2.0 * 1)....: 0.740 VAPCR PRESSURE. .(MM HG)............... .. 245 25C PERCENT VOLATILE BY VOL (*)..: 99+ VAPCR DENSITY (AIR*1)........ : N/A EVAPORATION RATE (eUAC*l ) . i N/A SOLUBILITY IN hATER (*)......: 4.6 APPEARANCE AND ODOR..................... : COLORLESS LIQUID SECTION IV - FIRE C FLASH POINT (F)............... .. -18F FLAMMABLE LIMITS LEL 1.65 FLAMMABLE LIMITS UEL %: 8.4 EXTINGUISHING MEDIA....: *'ALCOHOL** FOAM C02t DRY CHEMICAL FIRE FIGHTING PROC...........: EXPLOSION HAZARD DATA MSDS-MX0619 PAoE u a WEAR SELF-CONTAINED BREATHING APPARATUS FIRE C EXPL. HAZARDS...: G S6 18 -EXPOSURE TO AIR MAY RESULT IN FORMATION OF EXPLOSIVE ** SECTION V - HEALTH HAZARD DATA (ACLTE AND CHRONIC) ACGIH TLV/QSHA PEL (TWA)............ : 6 PEL: NONE ESTABLISHED TOXICITY DATA..................................... : -ORL-RAT L05Q; A ML/KG SYMPTOMS OF EXPOSURE ............... .. -VAPOR IRRITATING-CAN BE HARMFUL TO CENTRAL NERVCLS SYSTEM CAUSES EYE IRRITATION MAY CAUSE SKIN IRRITATICN ORAL TOXICITY LOW MEDICAL CCND. AGGRAVATED BY EXP: DATA NOT AVAILABLE* ROUTES OF ENTRY**......................... INHALATION* INGESTICN OR SKIN CONTACT. CARCINOGENICITY..................................... .. SEE COMMENTS* SECTICN XI IF NO INFORM ATION APPEARS* THE MATERIAL IS NOT LISTED AS A CANCER CAUSING AGENT. EMERGENCY FIRST AID.............................. GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE SKIN: WASH THOROUGHLY WITH SOAP AND WATER EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FCR AT LEAST 15 MINUTES INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPEO INGESTION: OG NOT INDUCE VOMITING; GET IMMEDIATE MEOICAL ATTENTION SECTION VI - REACTIV I TY OATA STABILITY......................................: YES CONDITIONS TO AVGIO.......... .. -CONTACT WITH HEAT* SPARKS OR FLAME EXPOSURE TC AIR MATERIALS TO AVOID******* ( ) WATER < ) ACIDS ( ) BASES ( ) CORROSIVES (X) GXIQIZE8S ( ) OTHER (SPECIFY)-N/A HAZARDOUS POLYMERIZATION* OATA NOT AVAILA ELE. HAZARDOUS DECOMPOSITION* -COX SECTION VII - ENVIRONMENTAL PROTECTION PRCCECLRES SPILL RESPONSE: -REMOVE ALL IGNITION SOURCES; DIKE SPILL* TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL WASTE DISPOSAL: TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT LOCAL STATE AND FEDERAL REGULATIONS* SECTION VIII - SPECIAL PROTECTION INFORMATION VENTILATION* RESPIRATORY PROTECTION* PROTECTIVE CLOTHING* EYE PROTECTION -MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION PROTECTIVE GLOVES (NITRILE* PVA* VITCN CR EQUIVALENT) SHOULD EE WORN MS0S-MXC819 PAGE B : C2 0000072X5 sal TG PREVENT SKIN CCNTACT SAFETY GLASSES WITH SIOE SHIELDS MUST BE WGRN AT ALL T IMES SECTION IX - SPECIAL PROTECTION INFGRMATIGN G S 6 18 HANCLING STORAGE : -KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE STORE IN A COOL AREA AWAY FROM IGNITION SOURCES AND CX IOIZERS AVOID PROLONGED STORAGE CHECK PEROXIDE CONTENT BEFORE HEATING MATERIAL DO NOT ALLOW TO EVAPORATE TC NEAR DRYNESS DC NOT BREATHE VAPOR CO NOT GET IN EYES* ON SKIN CR ON CLGTHING DC NOT TAKE INTERNALLY ELECGTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRCCUCT WQRK/HYGIENIC PRACTICES: WASH THOROUGHLY AFTER HANCLING. OC NOT TAKE INTERNALLY. EYE WASH ANO SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. SECTION X - OTHER INFORMATION COMMENTS........................................ : -* (ABEL-PENSKY) ** PEROXIDES N/A REVISION HISTORY.................... : 10/01/84* N/A OCT 27* *87 N/A = NOT AVAILABLE: MSDS-MXCS19 REV. 1/87 PAGE & : C3 sal O0oo7,16 FOt 3I4-LPA-2S476? 733 MATERIAL SAFETY DATA SHEET HACH ORDER!: 6971)7 MSDS DATE! 12/29/68 CHANGE HQ.i 7557 For Assistance. Contact: Regulatory Affairs Dost. PO Bd 117 Aaias, 1A Sldld I. PRODUCT IDENTIFICATION HACH COMPANY PO BOX 907 aws, ia soeia VII. FIRST AID E-. rgency Taleehon* 0 Roefcy Mountain Poison ctr. (SIS) 623-9716 6S 616 CATALOG MO.: 759 CAS HO. : 5115-96-9 FORMULA: C7H605 H20 II. INGREDIENTS PRODUCT NAh: Gallic Acid Monohydrata CHEMICAL NAME; 5,4,5-TrIhydroxyben201e Acid CHEMICAL FAMtLV: O'ltnlc Acids EVE AND SKIN CONTACT: Immediately flush ayes with watar for IS minutot physician. Hash skin with soap and planty af watar. INGESTION: Olva lirgi quantities of watar or wllR. call physician Immediately. INHALATION: Remcva to frash air. Gallic Acid Monohydrata PCTi >17 CAS NO.: 9999-96-9 TLV: Not established HAZARD! Hay causa irritation SARA: NOT LISTED pel: Not established Impurities PCT: <3 CAS HO.: HA TLV: Not ostlbLlshod HAZARD: Toxicity unknown; stay causa III. PHYSICAL DATA SARA: NOT LISTED PEL: Not ast abl1 shad Irritation STATE: solid APPEARANCE: Hhlta or light yallow ODOR: Nona SOLl/DlLITY IN: HATER: SUphtly soluble ACID: Not determined OTHER: Alcohol! flycarol, acotona BOILING POINT: NA MELTING PT.: 291C dacenp. SPEC GRAVITY: 1.694 pH: Of SX soln. * 2.9 VAPOR PRESSURE! Not applicable VAPOR DEHSITY tair*l>s NA EVAPORATION RATE: NA METAL CORROSIVITY - ALUMINUM: 9.6)11 ln/yr STEEL: WD STABILITY: Stabla STORAGE PRECAUTIONS: Stora tightly closed and pretactad from light. IV. FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT.t Not appllcabla METHOD: MA FLAWASlLITY LIMITS - LOWES: MA UPPER: MA SUSCEPTIBILITY TO SPONTANEOUS tCATIMG: None SHOCK SENSITIVITY: Nana AUTOIGNITION PT.: NO EXTINGUISHING MEDIA: watar, carbon dioxide, or dry chemical FIRESEXPLOSION HAZARDS: May aait acrid saeka and fuaas HAZARDOUS DECOMP. PRODUCTS! Acrid Saoka and fuaas OXIDIZER: No NFPA Codas: Haaltht 1 Flammability: 1 Raaetlvltyt 0 CONDITIONS TO AVOID: Exposure to haat. flames, light; contact with exldlzars, alkali hydroxides and carbonates, smmenla, laid acatatas, silver saltsV. V. HEALTH HAZARD DATA VIII. SPILL AND DISPOSAL PROCEDURES IN CASE OF SPILL OR RELEASE: Coyer contaalnatad surfaces with soda ash 0 sodium btcarbonata. Mix and add watar if nacaasary. use litmus paper eiaka sura pH of slurry it neutral or add neutralizer until mletura tto bubbling. Scoop up the slurry and wash the neutral waste down the dral with excess watar. Hath tha slta with soda ash solution. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL. STATE, AND LOCAL REGULATIONS. IX. TRANSPORTATION DATA D.O.T. PROPER SHIPPING NAME: Not Currently Ragulatad HAZARD CLASS: Not appllcabla ID: MA t.C.A.O. PROPER SHIPPING NAME: Not Currently Ragulatad HAZARD CLASS: NA ID: HA GROUP: NA X. REFERENCES 1) TLV*s Thrpsheld Limit Values and Biological Exposura Indices for 196 1999. American Conference of Governmental Industrial Hygienists, 149 21 29 CFR 1900 1111 (Coda of Federal Regulations - Labor) 31 Sax, Merck, Chemical Dictionary 4) Gesselln, R.E. at el. Clinical Toxicology af Commercial Products, St Ed. Baltlmora: Tha Williams and Mllklns Co., 1994. 5) Sax, H. Irving. Dangarous Properties of Industrial Materials, 6th E New York: Van Nostrand Relnhetd Co. 1994, 6) Technical judgment 7) Tha Merck Index, 14th Ed. Rahway, Maw Jersey: Merck end Co., Inc., 1993 9) Vendor information. 1) Ml OSH Registry of Toxic Effects of Chemical Substances, 1999-96. Cincinnati: U. S. Department of Health and Human Services. April, 1 SPECIAL NOTE: This product is Analytleel Grade. THIS PRODUCT MAY BE: irritating to eyas, skin and respiratory tract. ACUTE TOXICITY: Moderately toxic ROUTES OF EXPOSURE: Ingestion, inhalation, contact TARGET ORGANS: Net determined CHRONIC TOXICITY: Not determined ROUTES OF EXPOSURE: Not determined target ORGANS: Not determined CARCINOGEN, MUTAGEN, TERATOGEN DATA: Not applicable ROUTES OF EXPOSURE! Not appllcabla TARGET ORGANS: Not appllcabla OVEREXPOSURE: May esusa Irritation. If swallowed, may causa nausea and diarrhea. MEDICAL CONDITIONS AGGRAVATED 9V EXPOSURE: None reported VI. PRECAUTIONARY MEASURES Hash thoroughly tftar handling. Avoid contact with ayes, skin and clothing. Do not braatha chemicals. PROTECTIVE EQUIPMENT! adequate ventilation, safety glasses, disposable (loves oooooi^1 S THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED <C> MACH CO. tllO J.T.BAKER INC* 222 RED SCHOOL LANE* PHILLIPSBURG* NJ C6865 MATERIAL SAFETY DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC (800) 424-9300 -- NAT1CNAL RESPONSE CENTER S (600) 424-8602 A7440 -04 EFFECTIVE: 05/01/89 ARSENIC* 1000 PPM (0.100* W/V) JTBAKER INC.* 222 REO SCHOOL LANE. PH ILLIPS8URG* NJ 08865 PAGE: 1 ISSUED: 05/16/89 Cr S6 IT SECTION I - PRODUCT IDENTIFICATION *ssX3XXX^S3S=a=XXXXXXXX*XX**XXXXXX*XXX*XXXX*XXX33X=XXSXX PRODUCT NAME: ARSENIC* 1000 PPM (0.100* W/V) COMMON SYNONYMS: N/A CHEMICAL FAMILY: ATOMIC ABSORPTICN STANDARDS FORMULA: AS203 IN HCL FORMULA W T : 74.90 CAS NO.: N/A NICSH/RTECS NO.: CG3325000 PRODUCT USE: LABORATORY REAGENT PRODUCT CODES: 6919 PRECAUTIONARY LABELING 3X=^XXXXSX5S3SXX3XXSXX3S3XXXXXXXXSSXSSXS BAKER SAF-T-DATA* SYSTEM HEALTH FLAMMABILITY - 4 0 EXTREME (CANCER NONE REACTIVITY CONTACT -2 -2 MODERATE MODERATE CAUSING) LABORATORY PROTECTIVE EQUIPMENT GOGGLES t SHIELDS LAB COAT C APRON* VENT HOODS PROPER GLOVES U.S. PRECAUTIONARY LABELING POISON DANGER CAUSES IRRITATION. HARMFUL IF INHALED. MAY BE FATAL IF SWALLGWEC. CAUTION: CONTAINS INORGANIC ARSENIC. CANCER HAZARD. DO NOT GET IN EYES* ON SKIN* ON CLOTHING. 00 NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL. NEUTRALIZE WITH SODA ASH OR LIME AND PLACE IN CRY CONTAINER. INTERNATIONAL LABELING AVGJC CONTACT WITH EYES. AFTER CONTACT WITH SKIN. WASH IMMEDIATELY WITH PLENTY CF WATER. KEEP CONTAINER TIGHTLY CLOSED. SAF-T-DATA* STORAGE COLOR CODE: WHITE (CORROSIVE) CONTINUED ON PAGE 2 SAL 000007218 J.T.BAKER INC* 222 REO SCHOOL LANE* PH ILL IPSBIRG NJ 08665 (} JO IT ntf H A'T' ERIAL SAFETY OATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC <800) 424-9300 -- NATIONAL RESPONSE CENTER 8 (600) 424-6602 A 7440 -04 EFFECTIVE: 05/01/89 ARSENIC* 1000 PPH (0*100% W/V) PAGE: 2 1SSUE0: 05/16/89 2SS9SSSSSSSSSXS3SSSXeXXS2SCXJCKXX2*KSBXKXS3SSSS*S*S = SSXX = 3SSS = 33ZS25 = = = SS = S = Ss = SECTION II - COMPONENTS COMPONENT, ARSENIC TRICXIDE HYORGCHLGRIC ACID WATER CAS NO. 1327-53-3 7647-01-0 7732-18-5 WEIGHT <1 1-2 97-98 X CSHA/PEL N/E 5 PPM N/E ACGIF/TLV N/E 5 PPM N/E SECTION III - PHYSICAL OATA 3XZZBS*SSSXSXSSSXS(SSSZSSSSZXSSZXEZSZSSS33SSSSSSSSSSSSSSSSSSS = S = S= = = = = = = SSS = BOILING POINT: N/A VAPOR PRESSURE (MMHG): N/A MELTING POINT: N/A VAPOR OENSITY <AIR=1): N/A SPECIFIC GRAVITY: N/A (H20=l) EVAPORATION RATE: N/A SOLUBILITY(H20): COMPLETE (100%) ( % VOLATILES dY VCLOME: -99 (21 C) PH: N/A OOCR THRESHOLD (P.P.M.): N/A PHYSICAL STATE: LIQUID COEFFICIENT WATER/OIL DISTRIBUTION: N/A APPEARANCE L ODOR: CLEAR* COLORLESS LIQUID. COCRLESS. SZSJSXSSSSXXXSXXSXZXXXZXXZXXXZXSXXXXXXXBXIXXXXXXSXZXSXZXSS SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): N/A NFPA 704M RATING: 3-C-G AUTGIGNITION TEMPERATURE: N/A FLAMMABLE LIMITS: UPPER - N/A LONER - N/A FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURRCUNOING FIRE. CONTINUED ON PAGE: 3 SAt 0007219 J.T.BAKER INC 222 RED SCHOOL LANE* PHILLIPSBURG. NJ 06865 MATERIAL SAFETY DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 05*5-2151 CHEMTREC * (800) 424-9300 -- NATIONAL RESPONSE CENTER * (000) 424-6002 A7440 -04 ARSENIC* 1000 PPM (0.100* W/V) 6S6 IT page: 3 EFFECTIVE: 05/01/89 ISSUED: 05/16/89 SECTION IV - FIRE AND EXPLOSION HAZARD GATA (CONTINUED) gss^sssisiss.BstKsssastssctstscBcccsccstsssscssssxsssssssssssszsssssssssssssss SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULO WEAR PROPER PROTECTIVE EQUIPMENT ANO SELF-CONTAI NEC BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE UNUSUAL FIRE EXPLOSION HAZAROS REACTS WITH MOST METALS TO PRODUCE HYDROGEN GAS* WHICH CAN FCRM AN EXPLOSIVE MIXTURE WITH AIR. TOXIC GASES PRODUCED HYDROGEN CHLORIDE* HYDROGEN EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. SECTION V - HEALTH HAZARO CATA Z Z X -p. ZSZSZZZZSSZ=SZZS=Z2ZSrXXZSSSXZZSSSSCSSSSSSSZXZZSSSSSSSSXSZS32SSSS THRESHOLD LIMIT VALUE (TLV/TWA): 7 MG/M3 (5 PPM) TLV (CEILING) IS FOR HYDROGEN CHLORIDE. SHCRT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT (PEL): 7 MG/M3 (5 PPM) PEL (CEILING) IS FOR HYDROGEN CHLORIDE. TOXICITY CF COMPONENTS ORAL RAT LD50 FOR ARSENIC TRIQX IDE ORAL MOUSE L050 FOR ARSENIC TRIOXIDE INTRAPERITQNEAL MOUSE LD50 FOR HYDROCHLORIC ACID ORAL RABBIT LD50 FOR HYDROCHLORIC AGIO 1NHALATI0N-IHR RAT LC50 FOR HYDROCHLORIC ACID INTRAPERITONEAL MOUSE LD50 FOR WATER INTRAVENOUS MOUSE LD50 FOR WATER 15.1 39 .4 40 9CC 3124 190 25 PG/KG FG/KG MG/KG PG/KG PPM G/KG G/KG CONTINUED ON PAGE: 4 SAL 000007220 J#T.BAKER INC* 222 RED SCHOOL LANE* PHILL1PSBLRG* NJ 08865 MATERIAL safety data sheet 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC A (800) 424-9300 -- NATIONAL RESPONSE CENTER # (600) 424-6602 A 7440 -04 S6ir EFFECTIVE 05/01/89 ARSENIC* 1000 PPM (0.100* W/V) PAGE: 4 ISSUED: C5/16/89 ISS^ISX SECTION V - HEALTH HAZARD OATA (CONTINUED) :33S3S333S33e3S33SS2S333333SSS3 CARCINOGENICITY: NTP: YES 1ARC: YES Z LIST: YES CSHA REG: YES CARCINOGENICITY THIS PROOUCT CONTAINS ARSENIC* WHICH IS LISTED AS A NTP HUMAN CAftCINCGEN AND AN IARC HUMAN CARCINOGEN (GROUP 1). REPRODUCTIVE EFFECTS NONE IDENTIFIED* EFFECTS OF OVEREXPOSURE INHALATION: IRRITATION OF HUCGUS MEMBRANES* SEVERE IRRITATION Gfi BURNS OF RESPIRATORY SYSTEM* PULMONARY EOEMA LUNG INFLAMMATION SKIN CONTACT: IRRITATION* BURNS ^ EYE CONTACT: IRRITATION* BURNS SKIN ABSORPTION NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL* NAUSEA. VOMITING* PARALYSIS. SEVERE BURNS TO MOUTH* THROAT* ANO STOMACH CHRONIC EFFECTS NONE IDENTIFIED TARGET ORGANS LIVER* KIDNEYS* EYES* SKIN* RESPIRATORY SYSTEM* LUNGS. LYMPHATIC SYSTEM MECICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED PRIMARY ROUTES OF ENTRY INHALATION* INGESTION. EYE CONTACT. SKIN CONTACT EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED* IF CONSCIOUS. GIVE LARGE AMOUNT OF MILK* MILK OF MAGNESIA. OR WHITES OF EGGS BEATEN WITH HATER* INDUCE VOMITING* INHALATION: IF INHALED* REMOVE TO FRESH AIR* IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION* IF BREATHING IS CIFFICULT, GIVE ! OXYGEN* CQNT1NUE0 ON PAGE: 5 00000722-1 SAL  j4*ir J.T.BAKER INC* 222 RED SCHOOL LANE* PH ILLIPSBURG* NJ 08865 MATERIAL SAFETY 0 A T A SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC * (800) 424-9300 -- NATIONAL RESPONSE CENTER U (800) 424-8602 A7440 -04 EFFECTIVE: 05/01/89 ARSENIC. 1000 PPM (0.100* W/V) Cr S 6 IT PAGE: 5 ISSUED: 05/16/89 S3>*XXXXXX2XXXXXXXX222X223223r233X2322X2SX2X23XS = SXX = S32SX22X2XXXS = = sxss:- = s= _ = SECTION V - HEALTH HAZARD DATA (CONTINUED) SKIN CONTACT: IN CASE OF CONTACT* IMMEDIATELY FLUSH SKIN WITH PLENTY CF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. MASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY CF MATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES ANO LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: YES CONTAINS ARSENOUS CXIDE (RC 5.000 LBS. TPO = 100/10.000 LBS) AND HYDROGEN CERCLA HAZARDOUS SUBSTANCE: CHLORIDE (RQ = 1 LB. TPC = 500 LBS) YES CONTAINS ARSENOUS OXICE (RC = 5000 LES) TOXIC CHEMICALS: ( GENERIC CLASS: YES ANO HYORCCLORIC ACIO (RC = 500C LBS) CONTAINS ARSENIC ANO HYORCCHLGRIC ACID C15 1SCA INVENTORY: YES STATE LISTS: FOR PRODUCTS SOLD IN THE STATE CF CALIFORNIA. THE STATE REOLIRES THAI ME PROVIDE TO USERS AND THEIR EMPLOYEES THE FQLLOmING MESSAGE: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOMN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. XXXXXXXXXX2XX2233XXXXXX2XXX523X32X2XXXXXX233XXX2SXXX22XS22222222222S22222X2XX2 SECTION VI - REACTIVITY CATA STABILITY: STABLE HAZAROOUS P0LYM6RIZATIGN: *ILL NOT CCCUR CONDITIONS TO AVOID: HEAT INCOMPATIBLES: SOOIUM* ALUMINUM. ALKALIES. CARBONATES* STRONG BASES. STRONG OXIDIZING AGENTS. CHEMICALLY ACTIVE METALS* MOST COMMON METALS. SULFURIC ACID. CHLOROSLLFCNIC ACID DECOMPOSITION PRODUCTS HYDROGEN CHLORIDE. HYDROGEN* CHLORINE CONTINUED ON PAGE 6 f SAL 000007222 J.T.BAKER INC 222 REO SCHOOL LANE* PFILLIPSBORG Nj 08865 MATERIAL SAFETY DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMTREC * (600) 424-9300 -- NATIONAL RESPONSE CENTER (800 424-8602 A 7440 -04 G S 6 17 EFFECTIVE: 05/01/89 ARSENIC* 1000 PPM (0.100% W/V) PAGE: 6 ISSUEO: 05/16/89 *3Sp2XXXXXZX2X3SXKXS32XZX3X3XX3ZZXZXa3ZZZSZZX2ZZ2ZXZZXXZZ25XZXXXXXZZZX32XZZ2SZ SECTION VII - SPILL C DISPGSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE NEAR SELF-CONTAINED 8REATH1NG APPARATUS AND FULL PROTECTIVE CLCTHING. STOP LEAK IF YOU CAN OC SO WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL* CAREFULLY PLACE MATERIAL INTO CLEAN* DRY CONTAINER ANO COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. J. T. BAKER NEUTRASQRB(R) OR TEAM* *LGW NA+( ACIC NEUTRALIZERS ARE RECOMMENCED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FECERAL* STATE* ANO LGCAL ENVIRONMENTAL REGULATIONS. iPA HAZARDOUS WASTE NUMBER: P012 (ACUTE HAZARDOUS WASTE) SECTION VIII - INDUSTRIAL PROTECTIVE ECU IPMENT V^X2 2ZZZ2XX3ZZZZZXZZSZX2SS222XX33Z2SCZZXZSZSZZZXXXXZ3X3X2X2ZZZXX222XZS2X332XXX EYE/SKIN PROTECTION: THIS IS A LABORATORY-USE PRODUCT FOR WHICH NO INDUSTRIAL PROTECTIVE EQUIPMENT HAS BEEN DESIGNATED. SECTION IX - STORAGE ANO HANDLING PRECAUTIONS X3Z_pZXSX3XXXXZ2XSXX3XX222S2X22XZZX222Z222X2XXXXX = ZZXXXXXX2XX2Z2XXX3XX2SXS3SXXX SAF-T-DATA* STORAGE COLOR CODE: WHITE (CORROSIVE) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. FROM INCOMPATIBLE MATERIALS. STORE IN CORRGSICN-PRCCF AREA. ISOLATE SECTION X - TRANSPORTATION DATA ANO ADDITIONAL INFORMATION X X = ? XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXsXXXXXXXXXSXXXXZXXXXXXXXXXXXXXXXXXXXXXXXXXX DOMESTIC (D.Q.T.) PROPER SHIPPING NAME: HYORQCHLORIC ACID. SOLUTION HAZARO CLASS: CORROSIVE MATERIAL (LICUIC) UIM/NA: UN 1789 REPORTABLE QUANTITY: 5000 LES. > 3ELS : CORROSIVE CONTINUED ON PAGE: 7 SAL 000007223 J*T.BAKER INC* 222 RED SCHCOL LANE* PULL IPS8L8G NJ 08865 MATERIAL SAFETY OATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 CHEMT8EC ft (800) 424-9300 -- NATIONAL RESPONSE CENTER ft (EOG) 424-8802 A 7440 -04 EFFECTIVE: 05/01/89 ARSENIC* 1C00 PPM (0*1002 W/V) 6 S 6 IT PAGE: 7 ISSUED; 05/16/89 SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION (CONTINUED) REGULATORY REFERENCES: 49CFR 172*101* 173*263 INTERNATIONAL (I*M*0*) PROPER SHIPPING NAME: HYDROCHLORIC ACID* SOLUTION* MIXTURE HAZARD CLASS: 8 I*M*0 PAGE: 8102 UN: UNI 789 MARINE POLLUTANTS: YES PACKAGING GROUP: II LABELS: CORROSIVE REGULATORY REFERENCES: 49CFR 172.102* PART 1761 IMO AIR (I.C.A.O.) PROPER SHIPPING NAME: HAZARD CLASS: UN: UNI789 LABELS: CORROSIVE REGULATORY REFERENCES HYOROCHLORIC ACID* SOLUTION* MIXTURE 8 PACKAGING GROUP: II 49CFR 172*101; I73.6I PART 175; ICAG/IATA ^-S* CUSTOMS HARMONIZATION NUMBER: 382200000C0 N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED THE INFORMATION IN THIS MATERIAL SAFETY OATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY ANO HEALTH ACT ANO REGULATIONS PROMULGATED THEREUNOER (29 CFR 1910*1200 ET* SEC*) ANO THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM* THIS DOCUMENT IS INTENDED ONLY AS A GUIOE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN* OR SUPERVISED BY A PERSON TRA1NE0 IN* CHEMICAL HANDLING. THE USER IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE* PROTECTIVE CLOTHING INCLUDING EYE AND FACE GUARDS ANO RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. EXPOSURE TO THIS PRODUCT HAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED* BAKER CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. BAKER WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FCRTH CN THE LABEL* BAKER 01SCLAIMS ANY OTHER WARRANTIES* EXPRESSED OR IMPLIED WITH REGARD Tn THE PRODUCT SUPPLIED HEREUNDER* ITS MERCHANTABILITY OR ITS FITNESS 1 . A PARTICULAR PURPOSE. CONTINUED ON PAGE: B SAL 000007224 J.T.BAKER INC. 222 RED SCHOOL LANE* PH ILLIPS0URG* NJ 06665 MATERIAL SAFETY DATA SHEET 24-HOUR EMERGENCY TELEPHONE -- (201) 659-2151 CHEMTREC * (600) 424-9300 -- NATIONAL RESPONSE CENTER * (80C) 424-86C2 GS61TA 7440 -04 ARSENIC* 1000 PPM (0*100% */V) EFFECTIVE: 05/01/89 PAGE: 6 ISSUEO: 05/16/89 a s s a = s s:s:::::::s:::::sss3:s 33 3 3 THE USER SHOULD RECOGNIZE THAT THIS PROOUCT CAN CAUSE SEVERE INJURY AND EVEN OEATh* ESPECIALLY IF IMPROPERLY HANOLEO CR THE KNOWN OANGERS CF USE ARE NOT HEEDED* READ ALL PRECAUTIONARY INFORMATION* AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE* BAKER WILL PERIODICALLY REVISE THIS MATERIAL SAFETY QATA SHEET. IF YOU HAVE ANY CUESTICNS* PLEASE CALL CUSTOMER SERVICE (1-800-JTBAKER) FOR ASSISTANCE. 32 COPYRIGHT 1989 J.T.BAKER INC* * TRADEMARKS OF J.T.BAKER INC* s as APPROVED BY QUALITY ASSURANCE DEPARTMENT* -- LAST PAGE -- c S4t ooo7225 MSDSPLUS Chubb National Foam, Inc GS615 __ AOW Plus page lT "of 3 material safety data 1SO Gordon Drive LiOnviUe, PA 19353 Phone: 215 363-1400 s,heet FAX 215 524-9073 Section I Manufacturer's Name and Address Chubb National Foam, Inc. 150 Gordon Drive Lionville, PA 19353 Emergency Telephone No.: (215) 363-1400 Product Name: National AER-Q-WATER Plus Chemical Name and Synonyms: Surface Active Agents & Fluorinated Surfactants - Aqueous Film Forming Foam AFFF Section II Hazardous Ingredients This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: CAS # Chemical Name Percent by Weight TLV-TWA 107-21-1 Ethylene Glycol 15 max. 50 ppm-ceiling 1imit (vapor) Section III Physical Data of Product Specific Gravity (H20 = l ) : 1.03 pH: 8 Solubility in Water: 100% Appearance and Odor: Straw Yellow Liquid - Mild Pleasant Odor SAL 000007226 The Electronics Groan V *. . 6 S6 IS MATERIAL SAFETY DATA SHEET AOW Plus page 2 of 3 Section IV Fire and Explosion Hazard Flash Point: None (Cleveland Open Cup) Section V Health Hazard Data Primary Routes of Entry: Ingestion, Skin and Eye contact. Effect of Acute Overexposure and First Aid: Aer-0-Water Plus has been tested for acute toxicology to mammals and found to be essentially non-toxic and non-irritating to the skin. However, ingestion may cause diarrhea and repeated skin contact will remove the oils from the skin and cause dryness. / Wash with water, if exposed, and apply hand cream, WARNING: \ contact with the eyes should be avoided as Aer-O-Water Plus is a primary eye irritant and if left untreated could cause permanant eye damage. Flush with water and seek immediate medical attention. Section VI Reactivity Data Stability: Stable Hazardous Polymerization: Will not occur SAL 000007227 MSDSPLUS C 6 1 AOW Plus page 3 of 3 Section VII Spill or Leak Procedures (Including Waste Disposal Method) Concentrate: Flush with water to dilution of 10,000:1 (0,01%). Direct diluted material to holding pond or, if regulations permit, to Waste Treatment Plant, Foam: Flush with water to dilution of 300:1 . Direct diluted material to holding pond or, if regulations permit, to Waste Treatment Plant. Section VIII Special Protection Information Eye wash facilities recommended. Section IX Special Precautions Avoid ingestion, inhalation and skin absorption. Date: October 26, 1989 SAL 000007228 NATIONAL FOAM GS6 14 150 Gordon Drive, Lionville, PA 19353 Ptione 215 363*1400 Telex 685-1056 fax (215) 524-9073 MSDSXL3 XL-3 page 1 of 3 MATERIAL SAFETY DATA SHEET Section I Manufacturer's Name and Address? National Foam System, Inc. 150 Gordon Drive Lionville, PA 19353 Emergency Telephone No.: (215) 363-1400 Product Name: National AER-O-FOAM XL-3 Chemical Name and Synonyms: Protein Hydrolysate Section II Hazardous Ingredients Common Name Chemical Name % Cone Ethylene Glycol 1,2-Ethanediol 10 max Hexylene Glycol 2-Methy1-2,4 Pentanediol 10 max TLV 50 ppm ceiling li (vapor) 25 ppm ceiling li Section III Physical Data of Product Specific Gravity (H-O^) i 1.16 Solubility in Water: 100% Appearance and Odor: Dark Brown Liquid - Organic Odor Section IV Fire and Explosion Hazard Flash Point: None (Cleveland Open Cup) O00007?-, G S6 14 MATERIAL SAFETY DATA SHEET XL-3 page 2 of 3 re section V Health Hazard Data This product contains materials which, in their pure form, may cause the following effects upon overexposure: Ethylene Glycol - may cause eye and skin irritation on contact, nose and throat irritation on inhalation of vapors and digestive tract irritation, nervous system depression, visual disturbances, kidney damage, convulsions and coma on ingestion. Animal studies of large doses showed liver and kidney damage and birth defects. Hexylene Gylcol - may cause eye and skin irritation and nervous system depression. Large amounts may cause nose and throat irritation on inhalation of vapors and digestive tract irritation on ingestion. Effects of Over-exposure Internal consumption may cause diarrhea Removes oils from skin. Emergency and First Aid Procedures: Flush skin with water for 15 minutes. Flush eyes with water for 15 minutes. Apply hand cream to restore oil to skin. Section VI Reactivity Data Stability* Stable Hazardous Polymerization: Will not occur MATERIAL SAFETY DATA SHEET G S6 14 XL-3 page 3 of 3 Section VII Spill or Leak Procedures (Including Waste Disposal Method) Concentrate: Flush with water to dilution of 1,000:1 (0.1%). Direct diluted material to holding pond or, if regulations permit, to Waste Treatment Plant. Foam* Flush with water to dilution of 30?1. direct diluted material to holding pond or, if regulations permit, to Waste Treatment Plant. Product is biodegradeable at 1% or lower concentrations. Section VIII Special Protection Information Eye wash facilities recommended. Section IX Special Precautions Avoid ingestion, inhalation and skin absorption. Date? October 1, 1987 SAL 000007231 P12S3 IRIETHYU WF_ GLYCOL MATERIAL SAFETY DATA SHEET PG REVISION OF- 501-24-90 *** Of HCt, REQUEST *** ORDER NOs PROD NOs 0176:5000 "AH HACKS Z ROGERS INC. , SUBSIDIARY OF UNIVAR 1600 MORION BLDG- SEA I I I..L. WA V8104--1564 (40B) 435-0700 -- -- ............ ........ -EMfcRGFNCY ASSISTANCE-------- ----- --------------------------------- -- TOR FMERGEIICY ASSISTANCE INVOLVING CHEMICALS CALL CHENTRE.C <800)424-9300 -----------------------------------------------POP PRODUCT AND SALES INFORMATION----------------------------------------------- CONTACT YOUR LOCAL VAN WATERS & ROGERS BRANCH OFFICE ---------------------------------------------------------- PRODUCT IDENTIFICATION---------------------------------------------------------------- PRODUCT HANts TRIETHYLENE GLYCOL COMMON NAi'IF.S/SYNONYMS: IRIETHYLLHC GLYCOL? TEG CAS NO.: 112-27-6 VW&R CODE: P1233 FORMULA: C6 H14 04 IIAZARD RATING (NFPA 323M) DATE ISSUED: OS/89 SUPERCEDES: 08/87 HEALTH: 1 FIRE s l RLACTI'TTY: 0 '.'PT C Lit 3 NONE HAZARD RATING SCALE: O-MTNIMAL 3 "SERIOUS 1 Cl Uill) 4s-SEVE.Rt ' MODERATE --------------- ------ - ---------------------- HAZARDOUS 1NURLD1E.M1S------------------------------------------------- COMPONENT T RIET HYLENE GLYCOL EXPOSURE LIMITS- PPM USHA ACGJ.H OTHER % PEL JLV LIMIT >99 NONE HONE NONE HAZARO NONE ----------------------- ----- ------------------------------ PHYSICAL PROPER I IPS BOILING POINT, DLG F: 546 MELTING POINT, DEG F: N/A SPECIFIC GRAVITY (WATEK-1)s APPEARANCE AND ODOR: COLORLESS LIQUID? MILD ODOR VAPOR PRESSURE, till HG/20 DEG C* VAPOR DENSITY (AIR-1): 1.1 WATER SOLUBILITY, %: EVAPORATION RATE (BUTYL. ACE TA TE-1.) s NIL 3.2 100 <1 --------------------------- ----- -----------------------------FIRST AID MF.ASURES------------------------------------------------------------- IF INHALED: REMOVE TO FRESH AIR. GIVE Aft IIFICtAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL AllENTION. IN CASE OF EYE CONTACTS IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WA1FR FUR 15 MINUTES, LIFTING THE UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL. ATTENTION. IN CASE OF SKIN CONTACT: IMMEDIATELY WASH SKIN UHH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES? WASH BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING. PROD: 04763000 16:33:31 26 FEB 1990 COST INVOICES SAL 007232 G S333 PI 255 trietmyleme glycol MATERIAL SAFETY DATA SHEET PG 2 REVISION OFaOl 24-90 \f swallowed: if conscious, imheotaph v imuirt vomiting by giving 2 UlASStS UP WATER AND SUCKING A FINGER DOWN 1 ML IHRUAT. GET IMMEDIATE nenicAL artenrion. no Nor give anything by modih ro an unconscious UK CONVULSING PERSON. -------------------------------------------------------HEALTH HAZARD INFORMATION----------------------------------------------------------- PRIMARY ROUTES OK EXPOSURE: SKIN OR EYE CONTACT SIGNS AHl.i SYMPTOMS 01 EXPOSURE INHALATION: NONE CURRENTLY KNOWN EYE CONTACT: LIQUID ANU MIS! MAY IRRITATE THE EYES. SKIN CONTACT: BRIEF CONTACT MAY DRY THE SKIN. PROLONGED OR RE PEATED CONTACT MAY IRRITATE THE SKIN. CAUSING DERMATITIS. A SINGLE PRO LONGED EXPOSURE tS NOT LIKELY TO RESULT IN THE ABSORPTION OF HARMFUL AMOUNTS. MAY CAUSE A MORE SEVERE RESPONSE IF THE SKIN IS ABRADED. SKIN SENS I f IVA MON TESTING IN 25 HUMAN VOLUNTEERS DID NOT FIND ANY SFNSITIVATIUN TO OCCUR. SWALLOULD: SWALLOWING LARGE QUANTITIES MAY CAUSE NAUSEA AND VOMITING AND MAY CAUSE INJURY. THE TRIE THYLENE GLYCOL PRODUCED BY SONF MANUFACTURERS MAY CONTAIN SMALL AMOUNTS OF DIETHYLENE GLYCOL, IN WHICH CASE SWALLOWING MAY PRODUCE CNS DEPRESSION AND KIDNEY DAMAGE, WHICH MAY BE FATAL, AND LIVER DAMAGE. CHRONIC EFFECTS OF EXPOSURE: NO SPECIFIC INFORMATION AVAILABLE. MEDICAL CONDITIONS GENERALLY AUGRhVATF.D BY EXPOSURE: PRE-EXISTING EYE, SKIN, AND RESPIRATORY HISUPOLPS UR IMPARKED LIVER AND KIDNEY FUHCTION. -------------------- ------------------------------------------ I Ux ||;l ) t DAI A-------------------------------------------------------------------------- ORAL: RAT L050 - 1/ G/KU; HUMAN LULO ^ 5000 MG/KG DERMAL: HO DATA POUND INHALATION-: MO DATA POUND CARCINOGENIC! I r': THIS MAI ERIAL IS HUT CONSIDERED TO BE A CARCINOGEN BY THE NATIONAL. TOXICOLOGY PROGRAM, I HE IN TE'RHA TIDNAL AGENCY FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OTHER Uni A: HOME ................ ................... .........----------------- PERSONAL PROTECT ION------------------------------------------------- ------------------- VENTILATION: GENERAL ROOM Vt-NTIl AT TUFT. RESPIRATORY PROTECTION: IF USE CONDITIONS GENERATE MISTS, WEAR A NIOSHAPPRUVEO RESPIRATOR APPROPRIA I FOR I HOSE EMISSION LEVELS. APPROPRIATE RESPIRATORS MAY BE A FUEL FACEPIECE. OR A HALF MASK AIR-PURIFYING CART RIDGE RESPIRATOR WITH PARTICULATE FILTERS, A SELF CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, UR A SUPPLIED-AIR RESPIRATOR. EYE PROTECTION: CHEMICAL GOGGLES UNLESS A FULL FACEPIECE RESPIRATOR IS ALSO WORM. II IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NUT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY. PRO TECriVE CLOTHING: LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES, AMO GLOVES. OTHER PROTECTIVE MEASURES: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. ----- -------------- ------ --------------- FIRE AND EXPLOSION INFORMATION------------------------------------------------------ PRODS 04/o.16:5523.1 26 FED 1*90 COST: INVOICE: 5A(, 000i ^3 >1255 IRtl^THYLENE GLYCOL MATERIAL SAFETY HAT A SHEET GS388 PG 3 REVISION OF301-24-90 FLASH POINT, OEG F* 350 FLAI1MAB E LIMITS IN AIR, X METHOD USt.li s FNCC LOWER: 0.9 UPPERS 9.2 EXTINGUISHING MEDIA8 USE WATER iPPAY. DRY CHEMICAL OR COS. Hpl-CIAl. FIRE FIGHTING FROCLHURLS: FIRE FIGHTERS SHOULD WEAR SELFCONTAINED BREATHING APPARATUS. USE HA I t"R SPRAY TO COOL NEARBY CUW! AIMERS AM l.i STRUCTURES EXPOSE l! TO FIRE. l.jj HJvTR.I l l.pF r.Mi'i EXPLOSION UA V-dV. NUHL . ------------------ --------------------- HAZARDOUS REACT 1VI1 Y------------------------------------------------------------- STABILITY: S TABLE POLYMER t ZATION: WILL. NOT OCCUR LUNl.il LIONS 10 AVUIUs EXCESSIVE HEAT. WILL IGNITE IN AIR AT 700 DEG F. MATERIALS TO AVOIDa OXIDIZERS. HAZARDOUS DL.COHPUSI! ION PRODUCTS: MAY LI DERATE' CARBON MONOXIDE OR CARBON DIOXIDE. -----------------------------------------SPILL, LEAK, AMD DISPOSAL PROCEDURES---------------------------------------------- ACTION TO TAKE FOR SPILLS OR LEAKS: WEAR PROTECTIVE EQUIPMENT INCLUDING RUDBfcR D001S, RUDDER GLOVES, RUDDER APRUM, AMD A SELF-CON I AIMED BREA THING APPARATUS IN THE PRESSURE OFMAND HONE OR A SUPPLIED-AIR RES PIRATOR. It THE SPILL UR LEAK IS SMALL. A FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR PAPfICW AfS MAY BE SATISFACTORY. tN ANY EVENT, ALWAYS WEAK EYE PROTECTION. HIP SMALL SPILLS UR DRIPS, MOP OR WIPE UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, CONTAIN BY DIKING WITH SOIL UR OTHER NUN `COMBUSTIBLE SOR BENT MATERIAL AND THEN PUMP INTO DOT-APPROVED WASTE CONTAINERS? OR ABSORB WITH NON-COMDUSTIDLt SORBENT MATERIAL, PLACE RESIDUE IN DOT- APPROVED HASTE CONTAINERS. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATERS, AND SOILS. CUNPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING, AND HANDLING AND DISPOSAL OF WASTE. * DISPOSAL METHODS: DISPOSE 01 CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER WASTE DISPOSAL, AS ABOVE. ------------------------------------------------------------ SPECIAL. PRECAUTIONS-------------------------------------------------------------------- STORAGE AND HANDLING PRECAIH TONS: C i nRE IN A COOL, DRY. WEI.L-VENTIt A TED PLACE AWAY FROM INCOMPATIBLE WATER**.I KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO NOT USE ! REFUH TO EMPTY CONTAINER. WASH THOROUGHLY AFTER HANDLING. DO HOT GET IN EYES, ON SKIN, OR ON CLOTHING. REPAIR AND MAINTENANCE PRECAUTIONS* DO NOT CUT, GRIND, WELD, OR DRILL OH OR HEAR IHIS CONTAINER. OTHER PKECAUI I0IIS8 CONTAINERS. EVE! 1 THOSE THAI HAVE BEEN EMPTIED, WILL RETAIN PRODUC f RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WIRE FULL. --------------------------------- ------------------ *: or ADUf I TONAL INFORMATION------------------------------------------------------- COHl ACT USDS COORDINATOR, VAN WATERS & ROGERS INC. DURING BUSINESS HOURS, PACIFIC TIME (400)435-8700 xxVAN WAIT PS ROGERS me. f vtpftESSLY DISCLAIMS ALL EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO IT IF. PRODUCT OR INFORMATION PROVIDED HEREIN.** ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE PROD: 0 476:1000 16*55 siH 26 FED 1990 COST INVOICES SAL 000007234 P12i5 TRierHYLENC GLYCOL MATERIAL SAFETY DATA SHEET PG 4 REVISION OKSOI--24-90 MANUh AC fURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA- I ION IS BELIEVED TO BE ACCURATE. VW&R MAKES NO REPRESENTATIONS AS TO rrs ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND VU^R'S CON TROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES AND THEY ASSUME AH PTRkfi nt 08/8/s CURRtC TED NKPA REFERENCE^'EXPANDED HAZARDS OF EYE AND~SKIM* CONTACT AND SWALLOWING. EXPANDED AGGRAVATED MEDICAL CONDITIONS. REVISED FbRGOHAL PROTECTION, SPILL AND LEAK PROCEDURES AND HANDLING A lJ V 1 C# &. m OB/89 8 CHANGED HEADING AND CONTACT INFORMATION. **-*x E 51 D 0 F M S 0S PROD 5 04761.000 16s5U83i 26 FEB 1990 CUS1 1 **xx INVOICES SAL 000007235 MATERIAL safety oata sheet TRILL (006447-0382P -E0016293-S907 )|OATE QF I SSUE j 01/11? 80 RAGE : 01 'usirvii SECTION I - GENERAL INFORMATION CHEMICAL NAME A SYNONYMS N/A TRADE NAME A SYNONYMS TRILL CHEMICAL FAMILY SULFUR IC AC ZD DRAIN OPENER FORMULA X<--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP. AOORESS (NUMBER. STREET. CITY. STATE * ZIP CODE) BOX 152170 IRVING. TEXAS 75019 PREPARED BY: KELLY SEALS/T.S.CHEMIST j PROOUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER 5907 214-438-1381 SECTION 11- HAZARDOUS XNGRE01ENTS THE HAZARDS PRESENTED BELOV ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PROOUCT MIXTURE HAS NOT BEEN TESTEO AS A WHOLE. CHEMICAL NAME (INGREDIENTS) SULFURIC ACID | HAZARD CORROSIVE S TLV* 1MG/M3 ! PEL* 1MG/M3 ! CASA 7664-93-9 SECTION 11A - NON-HAZARDOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES ANCi CAS NUMBERS ARE PROTECTED UNOER NU TRADE SECRET REGISTRY * 409363-5118P SECTION 111 - PHYSICAL DATA (CONTINUED) TRILL SECTION III * PHYSICAL DATA BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM HG). VAPOR DENSITY (AZR*1) PH * 100*4 PERCENT. VOLATILE BY VOLUME <%) SOLUBILITY IN WATER VISCOSITY 625.00; SPEC GRAVITY <H20*1) :1.835 o.oo! COLOR OARK BROWN o.ooi DOOR ACIDIC io* < t ! CLARITY UNIFORMLY OPAQUE o.ooj EVAPORATION RATE ! (BU AC - 1 ) ! 000 COMPLETE NON-V Z 5C0US PAGE : 02 5ECT10N IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) NON-FLAMT.C.C. EXTINGUISHING MEDIA "ALCOHOL* X<--FOAM <--FOAM { FLAMMABLE LIMITS t X<--C02 DRY X<--CHEMICAL 1j N/.A L6L WATER <--SPRAY ! , UEL ;n/a <--OTHER SPECIAL FIRE FIGHTING PROCEDURES USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS WHERE THIS MATERIAL IS INVOLVED IN A FIRE. UNUSUAL FIRE * EXPLOSION HAZARDS WHERE SULFURIC ACID IS INVOLVED IN A FIRE. 00 NOT USE WATER SPRAY AS THIS CAN RESULT IN A POSSIBLE VIOLENT REACTION. SEE SECTION VII. NFPA HAZARD RATING (0-1NS 1GNIF1CANT;1-SLIGHT;2"MODERATE ; 3H1GH:4EXTREME>: 3 <`-HEALTH O <--FLAMMABlLITY 1 <--REACTIVITY <--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) A DILUTE SOLUTION IS AN IRRITANT TO SKIN ANO MUCOUS MEMBRANES OUE TO SAL 000007236 CS3S4 (CONTINUED) TRIkL SECTION V - HEALTH HAZARD DATA PAGE : 03 ITS ACIDITY AND MIAAY CAUSE IRREPARABLE CORNEAL DAMAGE AM) BLINDNESS AS WELL AS SCARRING OF THE EYELIDS. A CONCENTRATED SOLUTION CAUSES iERBURNING AND CHARRIINNG Of T--H----E_$K;N_M----K---I__H____I_S____E__y_|_N____M___O__R__E___R__A__P__ID__L__Y I_N__J_U__R.I.O.U.S TO MUCOUS MEMBRANES ANO EXCEEDINGLY DANGEROUS TO THE EYES. INGESTION CSTAOUMSEASCH SERIOUS BURNS OF THE MOUTH OR PERFORATION OP THE ESOPHAGUS OR - CHRONIC -___(LONG TERM EXPOSURE) NONE OTHER THAN THOSE SECONDARY TO TISSUE OBSTRUCTION. PRIMARY ROUTE OF ENTRY: <-- INHALATION <--_INGESTlON X<-- ABSORPTION EMERGENCY ( FIRST AID PROCEDURES OBJECT isKTO*SEEK MEDICAL ATTENTION IMMEDIATELY. GET PERSON OUT OF CONTAMINATED AREA TO FRESH AIR. IF BREATHING HAS STOPPED. ARTIFICIAL RESPIRATION SHOULD BE STARTED. OXYGEN MAY BE A0MXN1STERE6. IF READILY AVAILABLE. SEEK MEDICAL ATTENTION IMMEDIATELY^__ EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR HOLDING EYELIDS APART TO ENSURE FLUSHING OF THE ENTIRE FOLLOW WITH A 1* SOLUTION OF BAKING SOOA IN WATER. SEEK MEDICAL ATTENTION IMMEDIATELY. AT LEAST IS MINUTES EYE SURFACE. WIPE AC1D10FFGENTLY. FLUSH OFF SKIN WITH PLENTY OF WATER. FOLLOW WITH AN APPLICATION OF A PASTE OF BAKING SODA OR MAGNESIA. REMOVE CONTAMINATED CLOTHING ANO FOOTWEAR AND WASH CLOTHING BEFORE REUSE. DISCARD FOOTWEAR WHICH CANNOT BE DECONTAMINATED. SEEK MEDICAL ATTENTION IMMEDIATELY. INGESTION : IF SWALLOWED, DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. OSINK A TEASPOON OR MORE OF MAGNESIUM, CHALK. WHITING OR SMALL PIECES OF SOAP MOXSTENEO WITH WATER OR MILK. SEE A PHYSICIAN AT ONCE. N/A NOTES TO PHYSICIAN SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTEO AS CARCINOGEN OR POTENTIAL CARCINOGEN BY I ARC <-- YES NT <--YES OSHA <-"-YYEESS ACGIH <<----YYEESS OTHER <--YES X <--NO X<--NO X<--NO X<--NO X<--NO SULFURIC ACID EYE - RABBIT: 1.300 MG SEV 4. UNK - MAN LDLO; 135 MG/KG 4. ORAL - RAT LDSO: 2140 MG/KG 4. INHALATION - GUINEA PIG LC50: 8 MG/M3 TRILL SECTION Vlt - REACTIVITY DATA PAGE : 04 c STABILITY jX<--STABLE n/a <--UNSTABL i CONDXOTIONS TO AVOID INCOMPATIBILITY (MATERIALS TO AVOID) WATER. SOLVENTS, STRONG OXIDIZERS. COMBUSTIBLE MATERIALS. ALKALIS. METALS. CHLORATES. HAZARDOUS DECOMPOSITION PRODUCTS HYDROGEN EVOLUTION IN CLOSED METAL CONTAINERS. WHEN HEATEO TO DECOMPOSITION. CAN EMIT TDXIC FUMES OF NITROGEN OXIDES. HAZARDOUS ' WILL NOT | X <--0CCUR__ MAY [ CONDITIONS TO AV010 <--OCCUR | POLYMER IZATION!N/A SECTION VIII > SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED NICSH/WSHA APPROVED SELF-CONTAINED BREATHING APPARATUS. FOLLOW OSHA REGULATIONS FOR RESPIRATOR USE (SEE 29 CFR 1910.34). GAS-TIGHT GOGGLES, COVERALLS AND RUBBER BOOTS. GLOVES AND APRON. ADD NON-COMBUSTIBLE DRY ABSORBANT, SHOVEL (SWEEP UP). PLACE IN AN APPROVED DOT CONTAINER AND SEAL. wash resx6ue with large amounts of water, wash contaminated clothing. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL. STATE AND LOCAL REGULATIONS CONCERNING HEALTH AND POLLUTION. VIA APPROVED CHEMICAL WASTE OISPOSAL METHOD, IF REGULATIONS PERMIT. DISPOSE OF CLEAN UP DEBRIS, CONTAMINATED MATERIAL AND RESIDUES. NEUTRALIZING AGENT AOD SLOWLY TO A SOLUTION OF SODA ASH AND SLAKED LIME WITH STIRRING; FLUSH TO DRAIN WITH LARGE VOLUMES OF WATER. SECTION IX - SPECIAL PROTECTION INFORMATION REOUIRED VENTILATION GOOD INDUSTRIAL HYGIENE PRACTICE OICTATES THAT THE WORK AREA SHOULD BE ISOLATED AND CONTAINED AND PROVIDED WITH ADEOUATE LOCAL EXHAUST VENTILATION OR OTHER CONTROLS TO MAINTAIN THE AIR CONCENTRATION OF SULFURIC ACID BELOW 1 MG/M3 AS RE0U1RED BY OSHA. RESPIRATORY PROTECTION NIOSH HAS CONCLUOEO THAT ADHERENCE TO THE PRESENT FEDERAL STANDARD OF 1 MG/M3 OF AIR. IN CONJUNCTION WITH A STRONG PROGRAM OF WORK PRACTICES. WILL PROTECT THE WORKER FROM SULFURIC ACID EXPOSURE FDR UP TO 10 HOUR WORKDAY, 40 HOUR WORK WEEK OVER A WORKING LIFETIME. THE IOLH LEVEL IS 80 MG/mA. RECDMMENDED RESPIRATOR SELECTION. FOR EXPOSURES: < 50MG/M3-GMAGHIEP/HIEPF/SAF/SCBAF /ui _c f t be rf SAL 000007237 (CONTINUED) TWILL trdOi)4 SECTION IX - SPECIAL PROTECTION IMFOftWUTtOPAQI : OB PROTECTIVE GLOVES _ RUBBER GLOVES SHOULD BE WORN. EVE PROTECTION PACE SHIELD SHOULD BE WORN OTHER PROTECTION COVERALLS. RUBBER APRON ANO SAFETY BOOTS. SECTION X * STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE 120 F.<--MAX 32 F<--MIN INDOOR X !HEATED PRECAUTIONS TO BE TAKEN IN HANDLING A STORING STORE IN ORIGINAL CONTAINER. DO NOT GET JN EYES. ON SKIN OR ON CLOTHING. DO NOT TAKE INTERNALLY. AVOID BREATHING MIST OR FUMES. PROTECT AGAINST PHYSICAL DAMAGE AND WATER. SEPARATE CARBIDES. CHLORATES. FULMINATESE. NITRATES. PICRATES. POWDERED METALS AND COMBUSTIBLE MATERIALS. OTHER PRECAUTIONS STORE IN A COOL. DRY PLACE. FOLLOW LABEL DIRECTIONS. KEEP OUT OF REACH OF CHILDREN. NOTE: WATER ON SULFURIC ACID WILL CAU5E SPATTERING. FUMING AND EVOLUTION OF HEAT. !REFRIGERATED! OUTDOOR SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT SULFURIC AGIO 7664-93-9 UE THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FDR ROUTINE is useojanitorial work, or the ppoduct anp labeled pop facility grounds MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES), OR THE PRODUCT IS USED ANO LABELED FOR MAINTAINING MOTOR VEHICLES- TRILL SECTION XII - TRANSPORTATION - (FOR FUTURE USE) PAGE : 06 APPLICABLE REGULATIONS <--49 CFR < -- IMCC SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DDT SPS CONTAINER AEROSOL PROPELLANT(S) -TARIFF 6 C <--IA TA <--MILITARY AIR (AFR 71-4) | ID NUMBER } REPORT QTY | LIMITED QTY | NET EXPLOSIVE WT. SECTION XI I) - REFERENCES 1 . NIOSH POCKET GUIDE TC CHEMICAL HAZARDS. 1978. 2. HANDBOOK OF TOXIC AND HAZARDOUS CHEMICALS ANO CARCINOGENS. 2ND EDITION. MARSHALL S1TTIG. 1985. 3. NIOSH REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES. 1982. 4 . DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION. N. IRVING SAX. 5. VENDOR'S MATERIAL SAFETY DATA SHEETS. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION, HOWEVER. NC WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PROOUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS AS5UME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. DR DISPOSAL OF THE PRODUCT. SAL 000007238 Emergency Phone Humber(800) 457-2022 Material Safety Data Sheet GULFTENE 10 Page 1 oi f Chevron This Material Safety Data Sheet contains environmental, health and toxicology information for your employees* Please make sure this information is given to them. It also contains information to help you meet community right-to-know/emergency response reporting requirements under SARA Title III and many other lavs. If you resell this product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. The Chevron MSDSs have been reformatted and expanded to provide you vith useful hazard warnings and health evaluations and to facilitate your compliance vith local. State and Federal regulations. 1. PRODUCT IDENTIFICATION GULFTENE 10 DANGER1 - HARMFUL OR FATAL IF SWALLOWED - COMBUSTIBLE SYNONYM: GULF Decene-1 (CIO) PRODUCT INFORMATION: (713)754-4260 Revision Number: 4 Revision Date: 10/05/89 KSDS Number: PE0018 NDA - No Data Available NA - Not Applicable Jrepaxed According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by the Chevron Environmental Health Center, Inc., P.0. Box 4054, Richmond, CX 94804. $AL oa. 0007239 X-OOS051 (Gc-rai G S3 60 GULFTTHK 10 Pigt 2 of 6 2. FIRST AID ETC CONTACT: No first aid procedures are required. However, as a precaution flush eyes with fresh water for 15 minutes. Remove contact lenses if worn. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. INHALATION: If respiratory discomfort or irritation occurs, move the person to fresh air. See a doctor if discomfort or irritation continues. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice. 00 NOT make person vomit unless directed to do so by medical personnel. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. Note to Physician: Ingestion of this product or subsequent vomiting can result in aspiration of light hydrocarbon liquid which can cause pneumonitis. 3 IMMEDIATE HEALTH EFFECTS EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. SKIN IRRITATION: Prolonged or frequently repeated contact may cause the skin to become cracked or dry from the defatting action of this material. DERMAL TOXICITY: If absorbed through the skin, this substance is considered practically non-toxic to internal organs. RESPIRATORY/1NHALATI ON: If inhaled, this substance is considered practically non-toxic to internal organs. This substance may be irritating if inhaled. Signs and symptoms of respiratory tract irritation may include, but may not be limited to, one or more of the following: nasal discharge, sore throat, coughing, bronchitis, pulmonary edema and difficulty in breathing. INGESTION: If swallowed, this substance is considered practically non-toxic to internal organs. Because of the low viscosity of this substance, it can directly enter the lungs if it is swallowed (this is called aspiration). This can occur during the act of swallowing or when vomiting the substance. Once in the lungs, the substance is very difficult to remove and can cause severe injury to the lungs and death. 4. PROTECTIVE EQUIPMENT Revision Number: 4 Revision Date: 10/05/89 KSDS Number: PE0016 NDA - No Data Available NA - Not Applicable S*L 0000072* X-OOSfm (01--B9i GUUTENE 10 Pag* 63 of <r S 3 60 m protection: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create high airborne concentrations, the use of an approved respirator is recommended. VENTILATION: No special ventilation is usually necessary. However, if operating conditions create high airborne concentrations of this material, special ventilation may be needed. 5. FIRS PROTECTION FLASH POINT: (PM) 120F (530 AUTOIGNITION: NDA FLAMMABILITY: 1-5% EXTINGUISHING MEDIA: C02, dry chemical, foam and water fog. NFPA RATINGS: Health 0; Flammability 2; Reactivity 0; Special NDA; HMIS RATINGS: Health l; Flammability 2; Reactivity 0; Other NDA; (Least-0, Slight-1, Moderate-2, Hioh-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive violence. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises above 85 F. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire document. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and water vapor; incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA. stability: This material is considered chemically and thermally stable. Revision Number: 4 Revision Date: 10/05/89 MSDS Number: PE0018 NDA - No Data Available NA - Not Applicable 000007 sM- x-ocscc: n-B9) GS360 6ULFTKNK 10 Pat* 4 of C HAZARDOUS POLYMERIZATION; Polymerization will not occur. INCOMPATIBILITY: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. DO NOT USE OR STORE near flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AREA. Keep container closed. DO NOT veld, heat or drill container. Replace cap or bung. Emptied container still contains hazardous or explosive vapor or liquid. CAUTION! Do not use pressure to empty drum or explosion may result. 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbon solvents? APPEARANCE: Clear, colorless liquid. BOILING POINT: 170C (338F> MELTING POINT: NA EVAPORATION: NDA SPECIFIC GRAVITY: 0,75 4 15.6/15.6C VAPOR PRESSURE: 1.6mm Hg 75F PERCENT VOLATILE (VOLUME V): NDA VAPOR DENSITY (AIR-1): 4.84 VISCOSITY: NDA POUR POINT: NA FREEZING POINT: -66C (-86.8F) insoluble in water. 8. SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE HUMBER: (800) 424-9300 (24 hour). SPILL/LEAK PRECAUTIONS: Eliminate all open flame in vicinity of spill or released vapor. Stop the source of the leak or release. Clean up releases as soon as possible, observing precautions in Protective Equipment. Contain liquid to prevent further contamination of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. DISPOSAL METHODS: Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. Revision Number: 4 Revision Date: 10/05/89 MSDS Number: P50018 NDA - No Data Available NA - Not Applicable SAL 000007242 X-0OS021 (01-89 GULTtKNI 10 Page 5 of G S3 60 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100%. PERCENT/CAS* COMPONENT/REGULATORY LIMITS 100.0 % GULFTENE 10 CONTAINING < 2.0 % CAS124185 DECANE-N < 95.0 % CAS872059 DECENE-N-1 3.0 % OLEFINS-BRANCHED TLV - Threshold Limit Value STEL - Short-term Exposure Limit RQ - Reportable Quantity CC - Chevron Chemical Company PEL T?Q CPS CAS Permissible Exposure Limit Threshold Planning Quantity CUSA Product Code Chemical Abstract Service Number 10. REGULATORY INFORMATION DOT SHIPPING NAME: NDA DOT HAZARD CLASS: NDA DOT IDENTIFICATION NUMBER: NDA SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects; NO 2. Delayed (Chronic) Health Effects; NO 3. Fire Hazard; YES 4. Sudden Release of Pressure Hazard; NC 5. Reactivity Hazard; NO WHEN A COMPONENT OF THIS MATERIAL IS SHOWN IN THIS SECTION, THE REGULATORY LIST ON WHICH IT APPEARS IS INDICATED. DECANE 10. REGULATORY LISTS: 01-SARA 313 04-CA Prop. 65 01-MASS RTK 05-MI 406 03-NT? Carcinogen 06-IARC Group 1 Revision Number: 4 Revision Date: 10/05/89 MSDS Number: PE0018 NDA - No Data Available NA - Not Applicable S*L 000007243 >.-0GSa2: iC'i-89' G S 3 60 CULFTCMK 10 Pag# 6 of 6 07-IARC Group 2A 08-IARC Group 2B 10-PA RTK 11-NJ RTK 13-MN RTK 14-ACG1H TLV 16-acgih calculated TLV 17-OSHA PEL 19-Chevron TLV 20-EPA carcinogen 22-TSCA SECT S SNUR 23-TSCA SECT 6 RULE 25-TSCA SECT 8A CAIR 26-TSCA SECT 6D REPORT 28-Canadian WHMIS 09-SARA 302/304 12-CERCLA 302.4 15-ACGIH STEL 18-OSHA STEL 21-TSCA SECT 4 24-TSCA SECT 12 EXPORT 27-TSCA SECT 8E XI. PRODUCT TOXICOLOGY DATA m irritation: The Drai2e Eye Irritation Score (range, 0-110) in rabbits is 0.7. SKIN IRRITATION: The Draize Skin Primary Irritation Score (range 0-8) for a 24-hour exposure (rabbits) is 0.9. DERMAL TOXICITY: The dermal LD50 in rabbits is greater than lOg/kg. respiratory/inhalation: The 1-hour inhalation LC50 in rats is > 320 ppm (0.03%). INGESTION: The oral LD50 in rats is greater than lOg/kg. 12. ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: All available data is expressed elsewhere in this document. t****t*tt*****************t*t*tft*ft*t**ftft**t**t**ftt*******t**t*fttt*** V The above information 1$ based on the data of which we are aware aod is believed to be correct as of the date hereof. Since the information contained herein nay be applied under conditions beyond our control and with which we nay be unfamiliar and since data made available subsequent to the date hereof nay suggest modification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. 000001*^ 5 M- Revision Number: 4 Revision Date: 10/05/89 MSDS Number: PE0018 NDA - No Data Available NA - Not Applicable x-nn^rr' irr-RS' MATERIAL. SAFETY DATA SHEET BRILLIANCE AEROSOL. PAGE : 01 (0O6447-0382P -E0016293-S0S3 )!DATE OF ISSUE | 09/11/89 { SUPERSEDES ! 09/01/99 SECTION I - GENERAL INFORMATION CHEMICAL NAME 8 SYNONYMS N/A TRADE NAME 8 SYNONYMS BRILLIANCE AEROSOL CHEMICAL FAMILY AEROSOL GLASS CLEANER FORMULA X<--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP ADDRESS (NUMBER. STREET. CITY. STATE 8 ZIP CODE) BOX 152170 IRVING. TEXAS 75015 PREPARED BY: KEVIN UHL/T.S. CHEMIST { PRODUCT CODE NUMBER J EMERGENCY TELEPHONE NUMBER 5053 214*438*1361 SECTION IX* HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE- CHEMICAL NAME (INGREDIENTS) ISOPROPANOL ISOBUTANE [ HAZARD COMBUST. FLAM [ TLV40OPPM N/E 1 PEL400PPM N/E ! CAS' 67-63-0 75-28-5 SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) |lBO VAPOR PRESSURE (MM HG) . [131 | SPEC GRAVITY (H20-1) [ COLOR [WHITE :0.9" (CONTINUED) VAPOR DENSITY (AIR-1) PH 1O0K PERCENT. VOLATILE BY VOLUME <%) SOLUBILITY IN WATER VISCOSITY BRILLIANCE AEROSOL SECTION III - PHYSICAL DATA [2.0 { ODOR ALCOHOL DOOR [8 ! CLARITY OPAQUE EMULSION [97 1 j EVAPORATION RATE 1 (BU AC 1 ) [ COMPLETE (0-50 t [ NON-VISCOUS PAGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) IBS F T.C.C. FLAMMA8LE LIMITS [% BY VOLUME IN AIR LEL 12.0 UEL 12.0 EXTINGUISHING MEDIA `ALCOHOL" X<-- FOAM <-*FOAM X<--CC2 DRY K<--CHEMICAL WATER <-SPRAY <--OTHER SPECIAL FIRE FIGHTING PROCEDURES USE WATER SPRAY TO COOL EXPOSED CONTAINERS. WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION WHEN FIGHTING FIRES IN CONFINED AREAS TO PREVENT EXPOSURE TO ACRID SMOKE AND HAZARDOUS DECOMPOSITION PRODUCTS. UNUSUAL FIRE 8 EXPLOSION HAZARDS AEROSOL CONTAINERS MAY BURST WHEN EXPOSED TO ELEVATED TEMPERATURES FOR EXTENDEO PERIODS. LEVEL 1 AEROSOL (NFPA 3OB) NFPA HA2ARD RATING (O-INSIGNIFICANT : 1 SLIGHT;2*MODERATE;3-HIGH4-EXTREME^: 1 <--HEALTH 3 <-'FLAMMABILITY O <--REACTIVITY C--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE * (SHORT TERM EXPOSURE) ACUTE EXPOSURE TO LOW CONCENTRATIONS OF THIS MIXTURE MAY RESULT IN MILD IRRITATION TO EYE OR SKIN TISSUE. - CHRONIC - (LONG TERM EXPOSURE) PROLONGED CONTACT CAN CAUSE APPRECIABLE IRRITATION TO EYES LEADING TO SAL 000007245 BRILLIANCE AEROSOL G S 4 41 (CONTINUED) SECTION V HEALTH HAZARD DATA PAGE : 03 CORNEAL OPACITY IN REPEATEO SEVERE EXPOSURES. INGESTION OR INHALATION OP LARGE QUANTITIES OP THE VAPOR MAY CAUSE FLUSHING, HEADACHE, DIZZINESS, MENTAL DEPRESSION, NAUSEA, VOMITING. NARCOSIS, ANESTHESIA AND COMA. TARGET ORGANS: CONTACT-EYES. SKIN INGESTION-CENTRAL NERVOUS SYSTEM, LIVER PRIMARy"rOUTe"oP-ENTRy"~X<-- INHALATION*INGESTION <- ABSORPTION EMERGENCY A FIRST AID PROCEDURES REMOVE PERSON FROM AREA TO FRESH AIR. IRRITATION PERSISTS. SEEK MEDICAL ATTENTION IF OBJECT ISCTOSEEK MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY FLUSH WITH PLENTY OF MATER FOR AT LEAST 15 MINUTES HOLOING EYELIDS APART TO ENSURE FLUSHING OF THE ENTIRE EYE SURFACE. SEEK MEDICAL ATTENTION IMMEDIATELY. IF OVEREXPOSED^WASH WITH PLENTY OF SOAP AND WATER. PERSIST, SEEK MEDICAL ATTENTION IMMEDIATELY. IF IRRITATION JF SHALLOWEST^DO NOT INDUCE VOMITING. GIVE LARGE OUANTITIES OF WATER. IF AVAILABLE, GfVE SEVERAL GLASSES OF CITRUS JUICE. NEVER GIVE ANYTHING BY MOUTH TO An UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION IMMEDIATELY. NOTES TO PHYSICIAN : MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: LIVER DERMATITIS.CONDITIONS OF THE SECTION VI - TOXICITY INFORMATION PROOUCT CONTAINS CHEMICAL LISTEO AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC <--YES NTP <--YES OSHA <--YES ACGIH <--YES OTHER <--YES X<--NO X<--NO X<--NO X <--NO X<--NO 1SOPROPANOL EYE-HMN - 20 PPM 2. ORAL-HMN - TOLO 15.710 MG/KG:CNS oral-man ldlc bboomg/kg 2. IHL-HMN TCLO 400 ppm 2. 2. SECTION VII - REACTIVITY OATA STABILITY 1|X<--STABLE "" - <--UNSTABL } C0N01DT10NS TO AVOIO - -- -- -- KEEP AWAY FROM HEAT. SPARKS. HOT SURFACES AND OPEN FLAMES. (CONTINUED) BRILLIANCE AEROSOL SECTION VII - REACTIVITY DATA INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZERS. SUCH AS SODIUM OR CALCIUM HYPOCHLORITES. OXYGEN. BROMIDES. HAZARDOUS DECOMPOSITION PRODUCTS DXIOES OF CARBON AND ACRID SMOKE. LIQUID HAZARDOUS ' WILL NOT ] X <*-OCCUR POLYMERIZATlONjN/A MAY ! CONDITIONS TO AVOID <--OCCUR } PAGE : 04 SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN JN CASE MATERIAL IS RELEASED OR SPILLED SMALL SPILL: TAKE UP WITH ABSORBANT MATERIAL S PLACE IN NON-LEAKING CONTAINERS SEALED TIGHT FOR PROPER OISPOSAL. LARGE SPILL: AEROSOL SO LARGE SPILL IS UNLIKELY. FLOOD CONTAMINATED AREA WITH A DETERGENT AND WATER AND FLUSH TO SEWER. WASTE DISPOSAL METHOD WRAP EMPTY CONTAINER IN SEVERAL LAYERS OF NEWSPAPER AND PUT IN TRASH. DISPOSE OF IN ACCORDANCE WITH FEDERAL. STATE AND LOCAL REGULATIONS CONCERNING HEALTH. POLLUTION. NEUTRALIZING AGENT LARGE AMOUNTS OF WATER WILL NEUTRALIZE. SECTION IX - SPECIAL PROTECTION INFORMATION REQUIRED VENTILATION TYPICAL USE OF THIS PRODUCT DOES NOT REQUIRE SPECIAL VENTILATION. EXHAUST IS SUFFICIENT. LOCAL RESPIRATORY PROTECTION TYPICAL USE OF THIS PRODUCT DOES NOT REOUIRE THE USE OF A RESPIRATOR. IF MISTING. USE A NIOSH APPROVED MASK FOR SPRAY MIST. PROTECTIVE GLOVES TYPICAL USE OF THIS PROOUCT OOES NOT REOUIRE GLOVES. FOR CONTINUOUS CONTACT USE RUBBER GLOVES. EYE PROTECTION GOGGLES ARE 5UGGESTE0 IF METHOD OF APPLICATION PRESENTS POSSIBLE EYE CONTACT. sal 00 00 *246 r (CONTINUED) OTHER PROTECTION N/A BRILLIANCE AEROSOL SECTION IX - SPECIAL PROTECTION INFORMATIONAGE : OB ft S 4 41 SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE j INDOOR 120 F . < -"MAX 32 F<--MIN [ X [HEATED ! PRECAUTIONS TO BE TAKEN IN HANDLING A STORING KEEP AT MODERATE TEMPERATURES. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT. [REFRIGERATED! OUTDOOR [ [X SECTION XI - REGULATORY INFORMATION CHEMICAL NAME N/A C.A.S. NUMBER UPPER < LIMIT THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LA8ELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED ANO LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--IMCO SHIPPING NAME HAZARD CLASS LABELS <--TARIFF 6 D <--IATA <--MlLITARY AIR (AFR 71-4) [ ID NUMBER j REPORT QTY | LIMITED QTY (CONTINUED) BRILLIANCE AEROSOL SECTION XII - TRANSPORTATION (FOR FUTURE USE) UNIT CONTAINER DOT SS CONTAINER { NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) SECTION XIII REFERENCES 1. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT. 2N0 EDITION, ACG1H. 19SE. 2. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, 6TH EDITION. N. IRVING SAX. PAGE : 06 THE INFORMATION CONTAINED HEREIN IS BASEO ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION, HOWEVER. NC WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP . ASSUMES NC RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENOED USE. STORAGE. CR DISPOSAL OF THE PROOUCT. % SAL 000007247 FM.66001 MfNEPAL OIL 9ST MATERIAL SAFETY DATA SHEET PG 1 F s 01-24-yo shi:p n.): 4s000x02 CONOCO INC REF IN T ML-J P 0 KOX 37 WEST!. AKE LA 7 0669 ORDER NO: 460533386 PROD NO: 04411095 0AN WATERS & ROGERS INC., SUBSIDIARY OF UNIVAR 1600 HORTON BLDG. SEATTLE, WA 98104-1564 (408) 435-8700 ------------------------------------------------------------EMERGENCY ASSISTANCE----------------------------------------------------------------- POP EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMCREC <800)424-9300 ----------------------------------------------- POR PRODUCT AND SALES INFORMATION--------------------------------------------- CON V ACT' YOUR LOCAL VAN WAVERS 6 ROGERS BRANCH OFFICE ---------- ----- -.... - -------------------------------PRODUCT IDENTIFICATION-------------------------------------------------------------- PRODUCT MANE: MINERAL OIL- TECHNICAL COMMON HAMES/SYNONYMS: SONTEX? PAROL? DRAKEOL; RE.YI! T ECK ; ARC0PRIME ( I'M ) CAS MO.: 8042-4/-S VW&R CODE: PI 166001 FORMULA: UNDEE INED HA7ARD RA 1'ING < M AWUFAC TURER ) HEAL)H: 0 FIR E " 1 K'l-.ACI UTfY: 0 SPEC! Al.: NOME DATE ISSUED: 03/89 SUPERCEDES: 10/8/ HAZARD RATING SCALE: 0=MINIMAL 3=SERIOUS 1=SLIGHY 4=SEVERE 2=M0DERAIE ------------------------------------------ HAZARDOUS INGREDIENTS------------------------ CONPONEM T MINERAL I'JIL CAS MO. 8042-47-5 % >99 EXPOSURE LIMITS, PPM OSHA ACGIH OTHER PEL TLV LIMIT NOME NONE NONE HAZARD NONE < I M ) TRADEMARK OF ARCO PETROLEUM PRODUCTS COMPANY ----------------------------------------------------------- PHYSICAL PROPERTIES-------------------------------------------------------------- HU It. IMG Pn I.Mf, DEG F: 520-60? VAPOR PRESSURE, MM HG/2Q DEG C: <1 ME!. TING POINT: DEG I- a M/D VAPOR DENSITY < A!R=1>: >1 SPECIFIC GRAVITY (WAfER-l): 0.829-0.863 WATER SOLUBILITY, 7.: IN SOLUBLE AxPir AKA MCE ASCII ODOR: CLEAR EVAPORATION RATE (ETHYL E I HER-l) : <1 l I.UID, ODORLESS OR SLIGHT PE'I ROLEUM ODOR --------------------------------------------------------------FIRST AID MEASURE'S---------------------------------------------------------------- IT IHHAiTTis REMOVE ID FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT h i-: ea n i r i-! i.vur t mn e d i a rt: n e d e c al at r e n t i um . fM C:ASE ill- I- Ylr CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WA j R i- UR 15 ME NOTES, LIFTING I HE UPPER AND LOWER EYELIDS OCCASIONAL! Y. OFT TMMt-'i? ATt MI-DJCAL ATTENTION. TH T-AI:f t'.f GKI'M CUH TACT : IMMED I AT ELY WASH SKIN WITH LOT'S OF SOAP AND WATCH. PT-Mnvh CUM TAM I MATED CLOTHING AND SHOES; WASH BEFORE REUSE. GET PPf Jf'f Z 044 1 ? 0`r >18 25 22 Ft& 1990 CUS1 : 45000382 INVOICE": 460533386 SAL 000007248 GS504I--; 1.AA00 MAI FR J AL. SAFETY DATA SHtf 1 fl I' hi': S.'Al... ij 11 9E f 9 P6 REVISION OF S01-24-VO M!-OI'CAI At CENT I CM IF lKft.T 5 ATION PERSISTS AF TER WASHING. ! F f:WA! I OWt fit HD NOI' 'INDUCT VOMITING. IF CONSCIOUS- GIVE L.U I S 01- WATLK ji | i l-; n .[ MMF. .0 l A V F. I7!:: D J' CAL AT TENT CUN . 00 NOT GIVE AMY l HI MG BY H i n AM UMCUNSl:] Dim OK* CONVULSING PFKSON- - ... ................................... .... .................HF.A1.1H HAZARD tNFORMAf ION-------------------------------------------------------- in- rima.!-.-r LHi.nrs or exposure: skin or eye contact, MvMS ArH! SYMP1 ons OF EXPOSURE * MHA! .AT TOM: NuNfc. CURRENT LY KNOWN. imhalat ion. !:. r CJHVACf: NON:- CURRENT:. r KNOWN. SKI N CONTACT: NuML CUKREHiLY KNOWN. L wAU .OWED : NONE CURRENTLY KNOWN. cinvoN': c ti-rr.c'i s or fxposurf:: no specif ic information avatlable. medical cohdt r tons generally aggravated by exposures none reported. - ----------------------------- ----- ------------------------------- TOXICITY DATA------------------------------------------------------------------------- ! v'.F.. i WATS LlIPC " E 8/KG i i n i-.; m !..: ! A B V-.! T I..! i p o - IV G / K G IriFAi. ATI ONS NO DATA FOUND PARC?MOKEorcnY: HUE MATERJA!. IS NOT CONSIDERED TO BE A CARCINOGEN n'r HA ! i; O'MAI. TOXICOLOGY PROGRAM- THE IN VFRMAT I.ONAL AGENCY FOR RESEARCH ON CANCER, OR the OCCUPA riONAL SAFETY AMD HEALTH ADMINISTRATION A f|-!i:P 0 -) ! A : HONE N f s:'... A 5 L DM : CFNFkAL ROOM VEM 1 I LA i 1. ON . KF'SPjRATORY PROTECT TONS IF' USE CONDITIONS GENERATE VAPORS OK MISTS, WEAK A Hi'OSH-APPROVED RESPIRATOR APPROPRIATE FOR I'HUSE EMISSION LEVELS. APPROPRTA I F' RESPIRATORS MAY HE A FULL. FACEPIECE OR A HALF MASK AIK- >-:!*TEXTNG CAP V'RIDGE RESPIRATOR EQUIPPED FOR ORGANIC VAPORS/MIS IS, A PEI F-CONTATNED BPFA'I HIMG APPARATUS IN IMF PRESSURE DEMAND MODE, OK A SUPPL EU - A J! R RESP IRA TOR. i Y! PRUTFCT'.1 OHr CHEMICAL GOGGLES AND FULL F ACESHIELH UNLESS A FULL. FACEPIECE RESPIRATOR IS ALSO WORM. IT IS GENERALLY RECOGNIZED THAT fiRMTAC-i I FUSES SHOULD NOT DE WORM WHEN WORKING WITH CHEMICALS BECAUSF CONTACT ! .F riSFF; MAY LCM IP i DU f'P TO THE SEVERITY OF AN EYE INJURY. PPPI rPTTUE CLf.n FLING: LOMU SLEEVED SHIR'J , TROUSERS, SAFETY SHOES, PU PDF p mCVFS., AMU KODB'rP APRON. ii'iPI'P PROTECT IV1!- ME AS! IKES 5 AN EYEWASH AND SAFETY SHOWER SHOULD BE O'-Av-.-pY k'Ea.uY i-IS LJSF. ----- --------------------------------... -KIKE AMU EXPLOSION INFORMATION----------------------------------------------- ---- -J A PM -TJ : M r . 'Jpc n l.O-SPO METHOD USLD" LUC - XT 1 W1-IJ <>.UIMG MEDIA: USE l`RY USF WATER TO ETCH T f T'KE. CHEMICAL, CO.:!, FLAMMABLE LIMITS IN A I! R % LOWER: N/U UPPER: H/i.i OR ALCOHOL FOAM. DO HOT spec I A) ! R F 1 ICITTFHG PROCEDURES: I- IRE FIGHTERS SHOULD UF.AR SF LF COM : A ) )!> D HkFA ''FI !'UU APPARATUS AMD FUL L PRO TEC 11 VE Ct.U TH IMG. USE WA T i- !: CPF.-AT {p. f:OOL MFARBy CONTAINERS AND STRUCTURES] EXPOSED TO FIRE. UNUSUAL - t! RE AND EXPLOSION HAZARDS: NONE. |. }. m i j ; n/|^i()v FT'- h 1 990 OUST : 4H000SSL` INVOICE: ^ZOEPPPU SAL 000007249 p 11, >*,6001. rt'l NEPAL OIL 9ST L !MATERIAL SAFETY DATA SHE Cr S5 04 TM REVISION OF : 01-24-90 ------------------------------------- ----------------------HAZARDOUS RH.ACTIVn Y----------------------- ---- ----- -------------------------------- SIAM!'! YT'Y'n STABLE LUNnitlOMS TO AVOIDS NOME PtU. YMCRI 7A I'TON 2 WILL HU f OCCUR HA fEft V AL S TO AVOIDS OX.I DINERS HAZARDOUS DECOMPOSITION PRODUCT QS HAY LiBERA'lfc. CAR DOM MUMOXJ'Ufc. UK carbon d i:ox riif. -------- --------------------------------SPILL, LEAK, A Hi. I DISPOSAL PROCEDURES---------------------------------------------- ACTION 10 TAKE FOR SPILLS OR LEAKSs WEAR PRO (ECfIVE EQUIPMENT INCLUDING RUPDl: R BOOTS, RUBBER GLOVES. RUBBER ARROW, AMU A SELF-CONTAINED HRFAT MI MU APPARATUS I.H THE PRESSURE DEM AMD MODE OR A SUPPL !. E D~AIR RES- Fl RAT OR. IF THE SPILL OR LEAK IS SMALL, A FULL FACEPIECE AIft-PUKS! F YI MG PAR f ElDOE RESPIRATOR EQUIPPED FOR ORGANIC VAPORS MAY BE SA) ISFAC TORY. IN ANY EVENT, ALWAYS WEAR EYE PROTECTION. FOR SMALL SPILLS OR DRIPS, rinp OR WIPE UP AND DISPOSE UK IN DO {'-APPROVED WASTE COM i AIMERS. FOR LARUE SPILLS, CONTAIN BY DIKING WITH SOIL OR OTHER NON-COMBUSTTBLE SUPBENI MATERIAL AND THEN PUMP INTO DOT-APPROVED WASTE CONTAINERS? OR ABSORB WITH MOM-COMBUSTIBLE SORBENT MATERIAL, PLACE RESIDUE IN DOT- APPROVED WASl CON rAINERS. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATERS, AND SOILS. COMPLY WITH A I.. I.. APPLICABLE GOVERNMENTAL REGULATIONS OH SPILL REPORT INN, AND HAMDL '.NO AMD DISPOSAL OF WASTE. DISPOSAL ME. I HODS: DISPOSE OF CONTAMINATED PRODUCT AND MATER1 ALS USED TM PlfAMCNG UP SPILLS OR LEAKS IN h MANNER APPROVED FOR f 1-1 1 S MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AMU LOCAL. REGULATORY AGENCIES ID ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTF': EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AMD MISTS AMD ARE. SUBJECT 10 PROPER WAS ME DISPOSAL, AS ABOVE. ------------------------------------------ ---- ------------- SPECIAL PRECAUTIONS------------------------ ----- ----------------------------------------- STORAGE END HANDLING PftECAU !' .1. OHS: STORE C H A DRY, WELL-OEM S I LATfc.D PLACE* AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY Cl. OCT D WU!-H MO I IN USE. DO MOT USE PRESSURE 'TO EMPTY CONTAINER. WASH THOROUGHLY AFTER HANDLING, HO NOT GEO IN EYES. ON SK 3 N,, UR ON CLim-UNh. keep away from heat, sparks, open flame or dxiAtiers. PFPA5 k AND MAINTENANCE. PRECAIH IONS: NONE. ni'RFR PRFCAU I* JONS* CONTAINERS, EVEN THOSE I HAT HAVE BEE El EMPTIED, WtLL KLTAXN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARMINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. ---------------------------------------------------- COR ADDITIONAL INFORMATION---------------------------------------------------------- CONTACT MSDS COORDINATOR, VAN WATERS E ROGERS INC. DURING BUSINESS HOURS, PACIFIC TIME <40S)43S-87U0 **VAH WATERS * LOUT L S INC- < "VW&FC ) EXPRESSLY DISCLAIMS ALL EXPRESS OR *MP\ TED WARRANTIES OF MERCFfAN TAB EL I I'Y AND FI ) ML SC TOR A PARTICULAR PURPuSF, WITH RESPECT TO THE PRODUCT OR INFORM AT TON PRUV3 DED HEREIN.** AM j MFO.RMA { TOM APPEAR TNG HEREIN .1. S BASF: 0 UPON DATA OBTAINED FROM I HL HAMID AC TOPER AND/OR RECOGNIZED TECHM.! CAL. SOURCES. WHILE. THE INF OPMA- WON TO pFi li-'VFD TO PL ACUUKAIE - VUG ft MAKES HO ftEftftESEN I A l AS HJ ITS ACCURACY OR SUFF ICXENCY. CONDITIONS UP USE ARP BEYOND VWLK-'S CCIM- i ft \ i i AMD mERl-FURE USERS ARE RESPONSIBLE TO VERILY IHl.S UA I A UNDER I Hi- i R OWN OPERATING CONDITIONS TO DLTFRHINE UHL ! HER I HL PRODUCT j S PUT f ABLE LOR LEPER PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF "I Hf"'! R USE, HANDLING. AND DISPOSAL OF THE PRODUCT. OR FROM THr- PUBL.T CA- rri/rl OR* URL' OF. uft RELIANCE UPON, INFORMAT ON CUM TA'LMhO HEsftiM, (HIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DUL S NO! R! A i F TO J TS USE IN COMBINATION WIIH ANY 0 1 HER MAlERIrtL 0 W IN AMY U! ft1-R ((SID : 044 3 1 09 1.2 LED 1990 COST: 4S00tX::32 INVOICE: 4sOSP:.-::::s sac 000007250 (-1 t/.-.A001. g g Q ^ NATFRIAL SAFETY DATA GHf'Fl m MFK'Al. CUL 9Kt pf.-i'M 'li-'SG. KG <1 kfvn-noM ni- soi --24-S'o r <;!-| ^Mi-.\ < H6>UUMij AMO HuHt'ACI I.' Ml-URIM A f I GM . x- x- X- x I-. N 11 G M G n XX-XX- yv'i'iL!: o40 1 1. Ov!;< .1.':-': : FI : 22 IV VO CUP!': 4ROOOVG2 l MVDi !;i : <i S4t 000007 25Z BETZ INDUSTRIAL 4636 SOHERTON ROAD, TREVOSE, PA. 19047 BETZ MATERIAL SAFETY DATA SHEET 84 HOUR EMERGENCY TELEPHONE <HEALTH OR ACCIDENT) 815/355-3300 ODUCT :FLOWPRO 1508 EFFECTIVE DATE 05-18-89 PRINTED: 8/27/90 REV:SEC.3 ODUCT APPLICATION : DUST CONTROL AGENT. ------ SECTION 1------------------------- HAZARDOUS INGREDIENTS-------------------- ------------- FORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC ODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE STED. REFER TO SECTION 4 (PAGE 8) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE ID CHRONIC HAZARDS OF THIS FORMULATION. SEVERELY HYDROTREATED HEAVY NAPHTHENIC DISTILLATE***CAS864748-58-5; POTENTIAL SKIN IRRITANT;PEL:SMG/M3(OIL MIST);TLV:5MG/M3( OIL MIST). -------- SECTION 2 TYPICAL PHYSICAL DATA H: 50% EXTRACT (APPROX.) L.PT.(DEG.F): 362 P-h(CC) APOR PRESSURE(mmHG): <10 ISC cps70F 314 VAP.RATE: <1 ETHER-1 HYSICAL STATE: LIQUID 5.7 ODOR: MILO SP.GR.(70FJOR DENSITY: 0.893 VAPOR OENSITY(AIR*1): >1 XSOLUBILITY(UATER): 0 APPEARANCE: AMBER FREEZE POINT(DEG.F): -5 -- SECTION 3 REACTIVITY DATA iTABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK ;* ^AN-OUT CATEGORY 'B' HERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000007252 MATERIAL SAFETY DATA SHEET (PACE & OF 3) GS525 30DUCT FLOUPRO 1502 EFFECTIVE DATE 05-16-69 -------- SECTION 4------------------------ HEALTH HAZARD EFFECTS------------------------------------------------------- CUTE SKIN EFFECTS ** PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. CUTE EYE EFFECTS * SLIGHTLY IRRITATING TO THE EYES CUTE RESPIRATORY EFFECTS * PRIMARY ROUTE OF EXPOSURE VAPORS*GASES,MISTS AND/OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT HRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE DEFATTINC-TYPE DERMATITIS. EDICAL CONDITIONS AGGRAVATED *** NOT KNOUN YMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS,HEADACHE AND NAUSEA. ----------SECTION 5-------------------------- FIRST AID INSTRUCTIONS--------------------------------------------------;*IN CONTACT*** REMOVE CONTAMINATED CLOTHING.UASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES ire CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSIClAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR UATER ---------- SECTION &------------------------ SPILL,DISPOSAL AND FIRE INSTRUCTIONS-------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** UATER CONTAMINATED UITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). DRY CHEMICAL,CARBON DIOXIDE,FOAM OR UATER S*L ooooo725b MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) GS525 ! VCT: FLOUPRO 1502 EFFECTIVE DATE 05-16-89 * -SECTION 7------------------------ SPECIAL PROTECTIVE EQUIPMENT--------------------------------------- 5 PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.138-134. USE SPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. NTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS COMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY* USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. ^COMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY ^COMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES -------- SECTION 8-------------------------STORAGE AND HANDLING PRECAUTIONS-----------------------------TORACE INSTRUCTIONS*** KEEP DRUMS ft PAILS CLOSED UHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS P 'LING INSTRUCTIONS*** -MMEDIATELY REMOVE CONTAMINATED CLOTHING,WASH BEFORE REUSE **N*O*R*M**AL**C*H**E*M*IC*A*L**H*A*N*D**LI*N*G************************************************ K MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANOARD K**..J*L*O*+M*.**H*E*R*S*H**(*E*N*V*IR*O*N**M*E*N*T*A*L**I*N*F*O*R*M*A*T*I*O*N**C*O*O**R*D*IN*A*T*O*R*)******************* APPENDIX: REGULATORY INFORMATION HE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE FFECTZVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. NY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. . .TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ..REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: REAT AS OIL SPILL . .RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS UASTE .DENTIF1 CAT ION NUMBER IS: NOT APPLICABLE ..DOT HAZARD CLASSIFICATION: NOT APPLICABLE ..DOT SHIPPING DESIGNATION IS: NOT APPLICABLE ..THIS PRODUCT CONTAINS THESE CHEMICALS KNOUN TO THE STATE OF CALIFORNIA TO ;AUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AM0UNT8 ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: DELAYED(CHRONIC) ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS v <\/HMlS : HEALTH - 1 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000007254 UnitedCatalysts Inc Girdler and CC! Catalysts Post Office Bo* 32370 Louisville, Kentucky 40232 Telephone 502-634*7200 Telex 204190. 204239 Facsimile 502-637-3732 MATERIAL SAFETY DATA SHEET N-239 SECTION I PRODUCT IDENTIFICATION Trade Name and Synonyms: N-239 Chemical Family: Inorganic Formula: Al203+Co0+La203+Mo0s 8ECTION II HAZARDOUS INGREDXENT8 Hazardous Components in the Solid Mixture COMPONENT CAS No. % Aluminum oxide Cobalt oxide Lanthanum oxide Molybdenum trioxide 1344-28-1 1304-96-6 1312-81-8 1313-27-5 80-90 1-5 1-5 0w 1 H* t_n OSHA/PEL ACGIH/TLV 10.0 mg/m3 0.05 mg/m3 *NIA 10.0 ma/m3 0.05 mg/m3 *NIA 10.0 mg/m3 10.0 mg/m3 SECTION III PHYSICAL DATA Appearance and Odor: Blue extrusions. No odor. Melting Point: Greater than SOO^C, greater than 1450F. Solubility in Water: Insoluble. Bulk Density: 37 Ibs./cu. ft. Percent Volatile by Weight at 1000F: Less than 5%. SECTION IV FIRE EXPLOSION DATA Fire and Explosion Hazard Negligible fire and explosion hazard when exposed to heat or flame by reaction with incompatible substances. Updated: January 29, 1990 SAL 000007255 Page l Post Office Box 32370 Louisville. Kentucky 40232 Telephone 502-634-7200 Telex 204190. 204239 Facsimile 502-537-3732 A 0 47 MATERIAL SAFETY DATA SHEET N-239 Flash Point Nonflammable. Firefighting Media Dry chemical, water spray, or foam. For larger fires, use water spray fog or foam. Firefighting Nonflammable solids, liquids or gases: Cool containers that are exposed to flames with water from the side until well after fire is out. For massive fire in enclosed area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of the tank due to fire. 8ECTION V HEALTH HAZARD DATA Health hazards may arise from inhalation, ingestion, and/or contact with the skin and/or eyes. Alumina particles deposited in the eye may cause necrosis of the cornea. Ingestion may cause stomach and intestinal distress. Salts of alumina may cause dermatoses, eczema, conjunctivitis, and irritation of the mucous membranes of the upper respiratory tract. Prolonged inhalation of alumina dust may result in pneumoconiosis. Lung damage (Shaver's Disease) may result from inhalation of finely divided aluminum oxide particles; it is complicated by silica and oxides of iron in the inhaled air. Excessive inhalation of cobalt may cause irritation of the respiratory tract; asthma-like symptoms with cough, dyspnea, chest tightness and wheezing; lung damage; and pneumoconiosis. Ingestion may produce nausea and vomiting, diarrhea, and sensation of hotness. Chronic ingestion may cause blood abnormalities (polycythemia), increased clotting time, hyperplasia of the bone marrow and thyroid gland, cardiomyopathy, and damage to the pancreas in sensitive individuals, prolonged or repeated contact with the skin, in the absence of proper hygienic practices may result in dryness, irritation and/or an allergic dermatitis. Contact with the eye may cause redness, irritation, and/or conjunctivitis. Research data on cobalt and cobalt compounds based on animal injection studies indicates that cobalt may be a possible carcinogen. Updated: January 29, 1990 SAL 000007256 Page 2 UnitedCatalysts Inc. Tp Girdler and CCI Catalysis Post Office Box 32370 Louisville, Kentucky 40232 Telephone 502-634-7200 Telex 204190. 204239 Facsimile 502-637-3732 MATERIAL SAFETY DATA SHEET N-239 C A 0 47 Prolonged excessive inhalation of lanthanum may result in pneumonitis or granuloma of the lung. Lanthanum may cause delayed blood clotting, leading to hemorrhages. Overexposure may lead to hemoglobinemia. Symptoms of exposure are chills, fever, headache, muscle pains, abdominal cramps, nausea, malaise, and hemobloginurea. Skin contact, in the absence of proper hygienic practices, may result in irritation and skin granulomas. Eye contact may cause irritation and/or conjunctivitis. Molybdenum trioxide may cause irritation of the eyes and mucous membranes. Prolonged, excessive inhalation may affect the liver, kidneys, and red blood cells? cause hypothyroidism; and/or produce molybdenum-induced gout. Ingestion of excessive amounts may produce signs of copper deficiency. First Aid (Inhalation) Remove to fresh air immediately. If breathing has artificial respiration. Keep affected person warm medical attention immediately. stopped, give and at rest. Get First Aid (Ingestion) If large amounts have been ingested, give emetics to cause vomiting. Stomach siphon may be applied as well. Milk and fatty acids should be avoided. Get medical attention immediately. First Aid (Eyes) Wash eyes immediately and carefully for 30 minutes with running water, lifting upper and lower eyelids occasionally. Get prompt medical attention. First Aid (Skin) To avoid repeated or prolonged contact with this chemical, use good hygienic practices. Wash with soap and a large amount of water. Get medical attention if irritation or inflammation develops. 8ECTION VI REACTIVITY DATA Reactivity Is stable under normal temperatures and pressures in sealed containers. Hazardous polymerization will not occur. Molybdenum trioxide may emit toxic fumes when heated to decomposition. Updated: January 29, 1990 SAL 000007257 Page 3 & UnitedCatalystsInc, V Girdler and CCI Catalysis Post Office So* 32370 Louisville. Kentucky 40232 Telephone 502-634-7200 Telex 204190. 204239 Facsimile 502-637-3732 C A 0 47 MATERIAL SAFETY DATA SHEET N--239 SECTION VII SPILL OR LEAX PROCEDURES Notify safety personnel of spills or leaks. Clean-up personnel need protection against inhalation of dusts or fumes. Eye protection is required. Vacuuming and/or vet methods of cleanup are preferred. Place in appropriate containers for disposal, keeping airborne particulates at a minimum. Disposal Consult applicable local, state, and federal regulations to select the method of disposal. Recover metal components by reprocessing whenever possible. SECTION VIII SPECIAL PROTECTION INFORMATION Respiratory Protection Provide a NIOSH/MSHA jointly approved respirator in the absence proper environmental control. Contact your safety equipment supplier for proper mask type. of Ventilation Provide general and/or local exhaust ventilation to keep exposures below the TLV. Ventilation used must be designed to prevent spots of dust accumulation or recycling of dusts. Protective Clothing Wear protective clothing, including long sleeves and gloves, to prevent repeated or prolonged skin contact. Eye Protection Chemical splash goggles designed in compliance with OSHA regulations are recommended. Consult your safety equipment supplier. SECTION IZ REGULATORY INFORMATION This product contains substances which appear on lists of the indicated act or agency. XX American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values for Chemical Substances in the Work Environment SAL 000007258 Updated: January 29, 1990 Page 4 UnitedCatalysts Inc. Girdler and CCl Catalysis Post Office Box 32370 Louisville. Kentucky 40232 Telephone 502-634-7200 Telex 204190. 204239 Facsimile 502-637-3732 MATERIAL SAFETY DATA SHEET N--239 C A 0 47 ___ California Proposition 65 ___ Clean Air Act 40 CFR 61 ___ Clean Water Act 40 CFR 116 Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) 40 CFR 302 ___ International Agency for Research on Cancer (IARC) Monographs on the Evaluation of Carcinogenic Risks to Humans Volumes 1-42. ___ NTP Annual Report on Carcinogens XX Occupational Safety and Health Administration (OSHA) 29 CFR 1910 ___ Resource Conservation and Recovery Act (RCRA) 40 CFR 261 Subpart C XX Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III Section 313 40 CFR 372 XX Toxic Substances Control Act (TSCA) 40 CFR 700 SECTION X BIBLIOGRAPHY Clinical Toxicology of Commercial Products, Fifth Edition, Gosselin, Smith, Hodge, Williams and Wilkins, Baltimore, 1984. Dangerous Properties of Industrial Materials, Sax, N. Irving, ed.. Van Nostrand Reinhold Company, New York, 7th Edition, 1989. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Overall Evaluations of Carcinogenicity: An Updating of IARC Monographs, Volumes 1-42, Lyon: World Health Organization, International Agency for Research on Cancer, 1987. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Silica and Some Silicates, Volume 42, Lyon, World Health Organization, International Agency for Research on Cancer, 1987. Kentucky Occupational Safety and Health Standards for General Industry, 29 CFR Part 910 as adopted by 803 KAR 2:020 with Amendments as of July 31, 1986, Promulgated by Occupational Safety and Health Administration, U.S. Department of Labor, Kentucky Occupational Safety and Health Program, Kentucky Labor Cabinet, Commerce Clearing House, Inc., Chicago 1986. sAi_ 000007259 Updated: January 29, 1990 Page 5 Post Office Box 32370 Louisville. Kentucky -40232 Telephone 502-634-7200 Telex 204190. 204239 Facsimile 502-637-3732 MATERIAL SAFETY DATA SHEET N--239 Occupationa1 Diseases, A Guide to their Recognition, U. S. Department of Health, Education, and Welfare, Public Health Service, Center for Disease Control, NIOSH, Revised Edition, 1977. June Patty 's Industrial Hygiene and Toxicology, Clayton, G.D., Clayton, F.E., eds., John Wiley and Sons, New York, 3rd Edition, Volume 2, A-C, 1981. TLVsr Threshold Limit Values and Biological Exposure Indices for 1988--1989, American Conference of Governmental Industrial Hygienists, Cincinnati, OH, 1988. MSDS's from Suppliers of Raw Materials. SECTION XI The information presented herein is believed to be accurate but is not warranted. Recipients are advised to confirm in advance that the information is current and applicable to meet their circumstances. * No Information Available Doc. #615 Updated: January 29, 1990 SAL 000007260 Page 6 PU47 MATERIAL SAFETY DATA SHEET SQIUM HYPOCHLORITE LIQUICHLQR 12.5 PG 1 REVISION OFi12-12-8? SHIP TO: 45000382 CONOCO INC REFINING P 0 BOX 37 WESTLAKE LA 70669 ORDER NOS 451500017 PROD NOS 04367186 VAN WATERS 8. ROGERS INC., SUBSIDIARY OF UNIVAR 1600 NORTON BLDG. SEATTLE, UA 98104-1564 (408) 435-8700 ----------------------------------------------------- EMERGENCY ASSISTANCE----------------------------------------------------------- FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC (800)424-9300 -------------------------------------------F0R PRODUCT AND SALES INFORMATION----------------------------------------- CONTACT YOUR LOCAL VAN WATERS a ROGERS BRANCH OFFICE --------------------------------------------------- PRODUCT IDENTIFICATION--------------------------------------------------------- PRODUCT NAME: SODIUM HYPOCHLORITE ` CAS NO.: MIXTURE COMMON NAMES/SYNONYMS: LIQUID BLEACH, VWaR CODE: P1147 LIQUICHLOR; HYPOCHLOROUS ACID? SODIUM SALT SODA BLEACH FORMULA: NA 0 CL HAZARD RATING (NFPA 704 CRITERIA) HEALTH: 2 FIRE: 0 REACTIVITY: 2 SPECIAL: OXY DATE ISSUED: 09789 SUPERCEDES: 08/89 HAZARD RATING SCALE: 0=MINIMAL 3*SERI0US 1=SLIGHT 4-SEVERE 2=MQDERATE HAZARDOUS INGREDIENTS COMPONENT CAS 1NO. EXPOSURE LIMITS , MG/H3 OSHA ACGIH OTHER X PEL TLV LIMIT HAZARD SODIUM HYPOCHLORITE 7681 -52-9 SODIUM CHLORIDE 7647 -14-5 7-16 5-13 NONE NONE NONE NONE NONE NONE CORROSIVE; OXIDIZER NONE SODIUM HYDROXIDE WATER 1310 -73-2 0.05-0.9 2 2 NONE 7732 -18-5 BALANCE NONE NONE NONE CORROSIVE? TOXIC NONE PHYSICAL PROPERTIES- BOILING POINT. DEG F: VAPOR PRESSURE, MM HG/125 DEG F DECOMPOSES AT 125 MELTING POINT. DEG F: 9.4-10.4 VAPOR DENSITY <AIR=1>: SPECIFIC GRAVITY (WATER=1): 1.1-1.3 WATER SOLUBILITY, %: APPEARANCE AND ODOR: LIGHT EVAF'ORATION RATE (BUTYL ACETATE=1): YELLOW TO GREEN CLEAR LIQUID? CHLORINE ODOR. 100 0.9 100 AS WATER FIRST AID MEASURES- IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. PROD: 04367186 13:47:57 01 MAR 1990 OUST: 45000382 INVOICE: 451500017 SAL 000007261 *1147fip S3 04 MATERIAL SAFETY DATA SHEET SODIUM HYPOCHLORITE LIQUICHLOR 12.5 PG 2 REVISION OF:12-12-8? IN CASE OF EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 15 MINUTES. LIFTING THE UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. IN CASE OF SKIN CONTACT: IMMEDIATELY FLUSH SKIN WITH LOTS OF RUNNING WATER FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES? WASH BEFORE REUSE. GET IMMEDIATE MEDICAL ATTENTION. IF SWALLOWED: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LOTS OF WATER OR MILK. OR MILK OF MAGNESIA. GET IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE BAKING SODA OR ACID ANTIDOTES. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON. ------------------------------------------------- HEALTH HAZARD INFORMATION----------------------------------------------------- PRIMARY ROUTES OF EXPOSURE: SKIN OR EYE CONTACT, INHALATION. SIGNS AND SYMPTOMS OF EXPOSURE INHALATION: INHALATION OF FUMES OR MISTS CAUSES RESPIRATORY TRACT IRRITATION AND IRRITATION OF MUCOUS MEMBRANES. IF SODIUM HYPOCHLORITE IS MIXED WITH AMMONIA OR OTHER CHEMICALS, EVOLUTION OF CHLORINE OR HYPOCHLOROUS ACID RESULTS. THESE GASES CAN PRODUCE PULMONARY EDEMA. EYE CONTACT: LIQUID AND MISTS MAY SEVERELY IRRITATE OR DAMAGINFLAMMATION SWALLOWED: MISTS AND LIQUID ARE EXTREMELY CORROS MEMBRANES AND STOMACH. THE TISSUES. CAUSOMINAL PAIN. NAUSEA, VOMITING, CIRCULATORY COLLAPSE, CONFUSION, DELERIUM, COMA, AND COLLAPSE. SWALLOWING LARGE QUANTITIES CAN CAUSE DEATH. SWALL CHRONIC EFFECTS OF EXPOSURE: IRRITATION EFFECTS INCREASE WITH STRENGTH OF SOLUTION AND TIME OF EXPOSURE. PROLONGED OR REPEATED EXPOSURE CAN LEAD TO CONSTANT IRRITATION OF EYES AND THROAT. PROLONGED OR REPEATED CONTACT MAY CAUSE DERMITITIS AND SENSITIZATION. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE REPORTED. -------------------------------------------------------------- TOXICITY DATA------------------------------------------------------------------ ORAL: FOR 5% SOLUTION RAT LB50 = 13 G/KG FOR 12.5% SOLUTION RAT LD50 - 5 G/KG DERMAL: RAT LD50 >3.0 G/KG INHALATION: NO DATA AVAILABLE CARCINOGENICITY: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN BY THE NATIONAL TOXICOLOGY PROGRAM, THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER, OR I HE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OTHER DATA: NONE ------------------------------------------------------PERSONAL PROTECTION------------------------------------------------------------- VENTILATION: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MINIMIZING EMISSIONS AT THE POINT OF USE. RESPIRATORY PROTECTION: WEAR A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE VAPOR OR MIST CONCENTRATION AT THE POINT OF USE. APPROPRIATE RESPIRATORS MAY BE A FULL FACEPIECE OR A HALF MASK AIR-PURIFYING CART RIDGE RESPIRATOR EQUIPPED FOR ACID GASES/MISTS, A SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-AIR RESPIRATOR. EYE PROTECTION: CHEMICAL GOGGLES AND FULL FACESHIELD UNLESS A FULL FACEPIECE RESPIRATOR IS ALSO WORN. IT IS GENERALLY RECOGNIZED THAT PROD: 04367186 13:47:57 01 MAR 1990 CUST: 45000382 INVOICE: 451500017 SAL 000007262 P1147 MATERIAL SAFETY DATA SHEET SODIUM HYPOCHLORITE LIQUICHLOR 12-5 fir S 3 04 PG 3 REVISION OFl12-12-8? CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY. PROTECTIVE CLOTHING: LONG-SLEEVED SHIRT, TROUSERS, RUBBER BOOTS, RUBBER GLOVES, AND RUBBER APRON- OTHER PROTECTIVE MEASURES: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. FIRE AND EXPLOSION INFORMATION- FLASH POINT, DEG F: NOT FLAMMABLE METHOD USED: N/A FLAMMABLE MITS IN AIR, X LOWER: N/A UPSURROUNDING FIRE. SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR SELFCONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING- USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. UNUSUAL FIRE AND EXPLOSION HAZARDS: CONTAINERS OF THIS MATERIAL CAN EXPLODE UNDER FIRE CONDITIONS. OXYGEN MAY BE LIBERATED UPON CONTACT WITH CERTAIN METALS. TOXIC FUMES ARE LIBERATED BY CONTACT WITH ACIDS OR HEAT. HIGHLY EXOTHERMIC REACTIONS WITH ORGANIC MATERIALS AND OXIDIZABLE MATERIALS MAY CAUSE FIRES. ------------------------------------------------------HAZARDOUS REACTIVITY----------------------------------------------------------- STABILITY: STABLE POLYMERIZATION: WILL NOT OCCUR STABILITY DECREASES WITH CONCENTRATION, HEAT, LIGHT EXPOSURE, DECREASE IN PH AND CONTAMINATION WITH HEAVY METALS SUCH AS NICKEL, COBALT, COPPER AND IRON. CONDITIONS TO AVOID: EXCESSIVE HEAT, EXPOSURE TO LIGHT, EXCESS ALKALINITY, AND CONTAMINATION OF ANY KIND. MATERIALS TO AVOID: ETHER, AMMONIA ACIDS, REDUCING AGENTS, OXIDIZABLE MATERIALS, COMBUSTIBLE MATERIALS SUCH AS WOOD, CLOTH OR ORGANIC MATER IALS, HEAVY METALS SUCH AS IRON AND COPPER AND THEIR ALLOYS, AND DIRT. ALSO MAGNESIUM, ALUMINUM, TIN, OR MANGANESE. HAZARDOUS DECOMPOSITION PRODUCTS: HOCL, CHLORINE, HCL, NACL, SODIUM CHLORATE, AND OXYGEN WHICH DEPEND ON PH, TEMPERATURE AND TIME. ------------------------------------ SPILL, LEAK, AND DISPOSAL PROCEDURES-------------------------- --------------- ACTION TO TAKE FOR SPILLS OR LEAKS: WEAR ALKALI-RESISTANT SLICKER SUIT AND COMPLETE PROTECTIVE EQUIPMENT INCLUDING RUBBER GLOVES, RUBBER BOOTS. AND A SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE OR A SUPPLIED-AIR RESPIRATOR. IF THE SPILL OR LEAK IS SMALL, A FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED WITH ACID GASES/MISTS FILTERS MAY BE SATISFACTORY. IN ANY EVENT, ALWAYS WEAR EYE PROTECTION. FOR SMALL SPILLS OR DRIPS, MOP OR WIPE UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, CONTAIN BY DIKING WITH SOIL OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND CAREFULLY NEUTRAL IZE WITH DILUTE HYDROCHLORIC ACID. KEEP NON-NEUTRALIZED MATERIAL OUT OF SEWERS, STORM DRAINS, SURFACE WATERS, AND SOIL. THIS PRODUCT IS VERY TOXIC TO AQUATIC LIFE. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING, AND HANDLING AND DISPOSAL OF WASTE. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER WASTE DISPOSAL, AS ABOVE. ----------------------------------------------------- SPECIAL PRECAUTIONS------------------------------------------------------------- STORAGE AND HANDLING PRECAUTIONS: STORE IN A COOL, DRY, WELL-VENTILATED PROD: 04367186 13:47:57 01 MAR 1790 CUST: 45000382 INVOICE: 451500017 SAL 000007263 GPU47UT S3 04 MATERIAL SAFETY DATA SHEET SODIUM HYPOCHLORITE LIQUICHLOR 12.5 PG 4 REVISION OF * 12-12--09 PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO NOT USE PRESSURE TP EMPTY CONTAINER. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. STORE IN ORIGINAL CONTAINERS ONLY AT TEMPERATURES BELOW 85 DEG. F. DO NOT STORE NEAR ACIDS, OXIDIZABLE MATERIALS, OR ORGANICS. DO NOT STORE ON WOODEN FLOORS, PALLETS, OR NEAR WOOD OF ANY KIND. REPAIR AND MAINTENANCE PRECAUTIONS: NONE. OTHER PRECAUTIONS: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED. WILL RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. DO NOT MIX THIS PRODUCT WITH OTHER CLEANING AGENTS THAT MAY LIBERATE CHLORINE GAS VAPORS (I.E. ACIDIC AGENTS). THIS PRODUCT DEGRADES WITH AGE; USE IT WITHIN ONE MONTH OF RECEIPT. IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER INCONSISTENT WITH ITS LABELING. ----- -----------------------------------------FOR ADDITIONAL INFORMATION------------------------------ ----r-l-'+r CONTACT MSDS COORDINATOR, VAN WATERS & ROGERS INC. DURING BUSINESS HOURS, PACIFIC TIME <408)435-8700 A NOTICE- **VAN WATERS & ROGERS INC. <"VW&R"> EXPRESSLY DISCLAIMS ALL EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE PRODUCT OR IHFORMATION PROVIDED HEREIN.** ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA TION IS BELIEVED TO BE ACCURATE, VW&R MAKES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY, CONDITIONS OF USE ARE BEYOND VW&R'S CON TROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE. HANDLING, AND DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICA TION OR USE OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN. THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS. REVISION-- 12/8?: REVISED SYNONYM *** END 0F MSDS *** PROD: 04367186 13:47:57 01 MAR 1990 CUST: 45000382 INVOICE: 451500017 SAL 000007264- CENTURY PAPERS INC* V902 GULF FREEWAY HOUSTON, TEXAS 77023 TEL. NO. 713/928-5171 MANUFACTURER: S.C.JOHNSON t SON. INC. RACINE. WI 53403-5011 TEL. NO. 414/631-2777 EMERGENCY TEL. NO. 414/631-2000 MATERIAL SAFETY DATA SHEET 6 S 5 99 SECTION 1. IDENTIFICATION OF PROOUCT SHEET NO. 0534 PRODUCT NAME: G P FORWARD CLEANER ISSUE DATE: DECEMBER 12, 1989 PROOUCT CODE: 14520-006 ITEM NO. 406-1471, 406-1489, 406-1497. NATIONAL ITEM#: Z131XX SECTION 2. INGREDIENTS CAS NUMBER WEIGHT % EXPOSURE LIMIT SODIUM HYDROXIOE SODIUM SILICATE NONYLPHENOL POLYETHYLENE GLYCOL ETHER WATER 1310-73-2 1-3 1344-09-8 26027-38-3 3-6 1-4 80-90 2 MG/M3 (CEILING) (ACGIH TLV-TWA) (OSHA PEL) NA NA NA NA-NOT APPLICABLE; NSR-NO SPECIAL REQUIREMENT NO-NOT OETERMINEO SECTION 3. PHYSICAL DATA BOILING POINT <F): ABOVE 200 VAPOR PRESSURE (MM HG.): NA VAPOR OENSITY (AIR*1): NA SOLUSrtITY IN WATER: COMPLETE FREEZING POINT <F): ND APPEARANCE/ODOR: CLEAR, GREEN SPECIFIC GRAVITY (WATERED: 1.0 PERCENT VOLATILE (BY VOLUME): NA EVAPORATION RATE (BUTYL ACETATE-1): PH RANGE: 12.5 MIN. (UNDILUTED) LIQUIO. ND SECTION 4. FIRE ANO EXPLOSION HAZARD DATA FLASh'pOINT (F) (TEST METHOoi: NA FLAMMABLE LIMITS: NA EXTINGUISHING MEDIA: FOAM, C02, DRY CHEMICAL, WATER FOG SPECIAL FIRE FIGHTING PROCEDURES: NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. COOL ANO USE CAUTION WHEN APPROACHING OR HANOLING FIREEXPOSED CONTAINERS. UNUSUAL FIRE C EXPLOSION HAZARDS: CORROSIVE MATERIAL (SEE SECTIONS 5, 9). CONTAINER MAY BURST IN HEAT OF FIRE. SECTION 5. REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOIO: NONE KNOWN INCOMPATIBILITY-MATERIALS TO AVOID: STRONG AGIOS (E.G., HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE KNOWN HAZAROOUS DECOMPOSITION PROOUCTS: WHEN EXPOS0 TO FIRE, NORMAL PRODUCTS OF COMBUSTION. MURIATIC PRODUCES ACIO). SECTION 6. SPILL, LEAK ANO DISPOSAL PROCEDURES SPILL RESPONSE: ABSORB WITH OIL-DRI OR SIMILAR INERT MATERIAL. SWEEP OR SCRAPE UP AND CQNTAINERIZE. RINSE AFFECTED AREA THOROUGHLY WITH WATER. WEAR/USE APPROPRIATE PROTECTIVE EQUIPMENT. WASTE DISPOSAL: FOR UNOILUTEO PRODUCT: DISPOSAL IS REGULATED UNDER THE RESOURCE CONSERVATION ANO RECOVERY ACT AS A CORROSIVE WASTE. DISPOSAL OF REGULATED QUANTITIES SHOULD BE BY NEUTRALIZATION AT A PERMITT60 FACILITY IN ACCORDANCE WITH ALL FEDERAL/STATE REGULATIONS ANO LOCAL ORDINANCES REGARDING DISPOSAL OF CORROSIVE WASTES. WASTE FROM NORMAL PROOUCT USE MAY BE SEWEREO TO A PU8LIC-0WN6D TREATMENT WORKS (POTW) IN COMPLIANCE WITH APPLICABLE FEDERAL, STATE, ANO LOCAL PRETREATMENT REQUIREMENTS. SAL 000007265 MATERIAL SAFETY OATA SHEET PAOOUCT NAME: G.P.FORWARD CLEANER PRODUCT NO. *06-1471, 406-1*89, 406-1497 PAGE 2 ..JELS.&55____ _ SECTION 7. HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: SKIN CONTACT SIGNS AND SYMPTOMS: DIRECT CONTACT OF PRODUCT WITH EYES CAN CAUSE IRRITATION. PROLONGED OR REPEATED CONTACT OF UNDILUTED PRODUCT WITH SKIN MAY CAUSE IRRITATION. IF TAKEN INTERNALLY, PRODUCT MAY CAUSE CORROSIVE DAMAGE TO MOUTH, THROAT OR STOMACH. SECTION 8. EMERGENCY AND FIRST AID PROCEDURES FIRST AID PROCEDURES: FLUSH EYES WITH WATER FOR 15 MINUTES. IF IRRITATION PERSISTS. SEEK MEDICAL AID. WASH SKIN WITH PLENTY OF WATER. IF IRRITATION PERSISTS, SEEK MEDICAL AID. IF PRODUCT IS SWALLOWED, DRINK LARGE AMOUNTS OF WATER OR MILK AND SEEK MEDICAL AID. SECTION 9. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: NO SPECIAL REQUIREMENTS UNOER NORMAL USE CONDITIONS. VENTILATION: NSR PROTECTION GLOVES: ANY IMPERVIOUS MATERIAL. EYE PROTECTION: FOR UNDILUTED PRODUCT: CHEMICAL WORKERS SPLASH-PROOF GOGGLES. OTHER PROTECTIVE MEASURES: USE GOOO PERSONAL HYGIENE PRACTICES. LAUNDER CONTAMINATED EQUIPMENT BEFORE REUSE. SECTION 10. ADDITIONAL INFORMATION AND PRECAUTIONS PRECAUTIONARY LABELING: CAUTION: EYE IRRITANT. FOR INDUSTRIAL USE ONLY. 00 NOT GET IN EYES. HANDLING AND STORAGE CONDITIONS: KEEP OUT OF REACH OF CHILDREN. STORE IN A COOL, ORY PLACE WITH ADEQUATE VENTILATION. KEEP FROM FREEZING. WASH THOROUGHLY AFTER HANDLING. PRODUCT RESIDUE MAY REMAIN ON/IN EMPTY CONTAINERS. ALL PRECAUTIONS FOR HANDLING THE PRODUCT MUST BE USED IN HANDLING THE EMPTY CONTAINER AND RESIDUE. ADDITIONAL INFORMATION: NA HMIS RATINGS: HEALTH 3, FLAMMASLILZTY O, REACTIVITY 0 PREPARED BY: ROBERT B. D'RIEN CHEMICAL INFO. ADMIN. THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH. NO WARRANTY. EXPRESSED OR IMPLIED, IS MADE. ANY USE OF THESE DATA AND INFORMATION MUST BE DETERMINED BY THE USER TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS. ^ 0oo07266 /, arc THREE INDUSTRIES* INC r 0* bOX *04> HOUSTON* TX 77253 * 'AGE material safe T Y 0 A T j HE E T I-GENERAL INFORMATION PROOUCT NAME OXYGEN GS2 71 EMERGENCY TELEPHONE NO* 713-368-0302 MANUFACTURERS NAME BIG THREE INDUSTRIES* INC. TRADE NAM6/SYN0NYMS OXYGcNJ OXYGEN USPS AVIATORS BREATHING OXYGEN CHEMICAL NAME AND SYNONYMS OXYGEN REVISION DATES 09/05/89 PRODUCT ID. UN 1072 FORMULA 02 CHEMICAL FAMILY OXIDIZER CAS NUMBER 7792-44-7 (A$0) *****+** SECTION NOTES * MSDS INFORMATION NUMBER* (713) 396-2140 I-HAZAR00U3 INGREDIENTS * hazardous^mixturBs of lToui ds""an3"gas es" OXYGEN ** NONE ESTA3LI SHED OiO IOC TLV * II 1-PHYSICAL DATA OILING POINT -297*3F (-133*00 4 1 ATM RAVITY (AIR * 1)3 1*1049 4 70F (21.10 1 ATH V^Oft PRESSURE N/A .'ENT VVOOLATILE BY VOLUME (0/0) N/A (GAS) llTY 0*08279 LB/CU FT 70 F (21.1 041 ATM JON RATE N/A (GAS) Y IN WATER 4.89SCC/100CC H20 3 32 F (0 C) MATERIAL AT NORMAL CONDITION GAS , EXPANSION RATIO (LlOUID TO GAS) N/A (GAS) APPEARANCE ANO ODOR COLORLESS* ODORLESS* TASTELESS GAS I V - F I ft E AND EXPLOSION HAZARD OATA FLASH POINT N/A FLASH POINT (METHOD USED) FLAMMABILITY LIMITS IN AIR (0/0 BY VOL) LOWER N/A UPPER N/A EXTINGUISHING MEDIA MATERIAL IS NONFLAMMABLE. USE EXTINGUISHING MEDIA APPRO PRIATE FOR SURROUNDING FIRE. SPECIAL FIRE FIGHTING PROCEDURES THOUGH NOT FLAMMABLE ITSELF* OXYGEN VIGOROUSLY ACCELERATES COMBUSTION* IF POSSIBLE* SHUT OFF OXYGEN GAS AND REMOVE CYLINDERS FROM FIRE AREA OR COOL WITH WATER TO AVOID EXCES SIVE PRESSURE BUILD UP* % LT 'UAL FIRE AND EXPLOSION HAZARD SAL 000007267 MATERIALS WHICH DO NOT BURN IN AIR MAY BURN IN AN GXYGEN6NRICHE0 ATMOSPHERE WHERE THE OXYGEN CONTENT EXCEEDS 21*. OXYGEN MAY FORM EXPLOSIVE CDMPQUNOS WHEN EXPOSED TO COM BUSTIBLE MATERIALS OR OIL* GREASE* AND OTHER HYDROCARBON MATERIALS* PRESSURE CAN 8UIL0 UP DUE TO HEAT ANO CYLINDER MAY EXPLODE IF PRESSURE RELIEF DEVICES SHOULD FAIL TO FROM LK CHARLES 141 e S271 BIG THREE INDUSTRIES* INC* P. 0* SOX 30A7 HOUSTON, TX 77253 MATER I A L SAFETY DATA SHEET "RODUCT NAME OXYGEN RELIEVE PRESSURE* p. >AGc V-HEALTH HAZARD OATA THRESHOLD LIMIT VALUE NONE ESTABLISHED UNUSUAL CHRONIC TOXICITY SEE OVEREXPOSURE SECTION* CARCINOGENICITY ROUTES OF EXPOSURE NOT LISTED BY I ARC* NTP * OSHA INHALATION EFFECTS OF OVEREXPOSURE BREATHING 80% UR MORE OXYGGEEN AT ATMOSPHERIC PRESSURE FOR MORE THAN Aa FeWL H__O__U__R__S M.A..Y. C_ AUSE NASAL STUFFINESS* COUGH* SORE THROAT* CHEST PAIN ANO BREATHING DIFFICULTY* BREATHING OXYGEN AT HIGHER PRESSURE INCREASES THE LIKELIHOOO OF AD VERSE EFFECTS HITHIN A SHORTER TIME PERIOO* EXPOSURE TO OXYGEN AT HIGHER PRESSURES FOR PROLONGED PERIODS HAS BEEN FOUND TO AFFECT VIStONi NEUROMUSCULAR COORDINATION AND ATTENTIVE POWERS. TOXICOLOGICAL PROPERTIES: AT NORHAL CONCENTRATION AND PRESSURE* OXYGEN POSES NO TOXI CITY HAZARDS* HOWEVER* AT ELEVATED CONCENTRATIONS AND PRES SURES* OXYGEN MAY CAUSE ADVERSE EFFECTS (SEE ABOVE). Sw^RGENCY AND FIRST AID PROCEDURES REOUCE OXYGEN PRESSURES TO 1 ATM AND/OR MOVE VICTIM INTO FRESH AIR. RESCUE PERSONNEL SHOULD BE A WARE CF EXTREMl FIRE HAZAROS ASSOCIATED WITH OXYGEN-ENRICHED ATMOSPHERE: c VI-REACTIVITY DATA STABILITY STAOLE CONDITIONS TO AVOID NONE. INCOMPATABILITY (MATERIALS TO AVOID) OXYGEN REACTS EXPLOSIVELY WITH ETHERS* ALCOHOLS# AND HYDRO CARBON MATERIALS. KEEP OXYGEN CONTAINERS FREE OF OIL AND/OR GREASE* HAZARDOUS DECOMPOSITION PRODUCTS NONE* HAZARDOUS POLYMERIZATION WILL NOT OCCUR F^NOlTIONS TO AVOID NONE* SAL 000007268 VII-SPILL OR LEAK PROCEDURE FROM LK CHRRLES 141 big three industries. INC P* 0. BOX 3047 HOUSTON* TX 77*53 MATERIAL SAME T Y DATA Bk'.OUCT NAME OXYGEN CS271 SHEET P. 9 I AC& STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED EVACUATE ALL UNNECESSARY PERSONNEL FROM AFFECTED AREA. SHUT OFF SOURCE OF OXYGEN IF POSSIBLE. VENTILATE AREA TU PREVENT XYGN-ENRJCHD ATMOSPHERE. REMOVE SOURCES OF HEAT OR IGNI- ?i82srhMhN*:G= F.IN.R.OD.MU..S.CT.O.RNIETS.A.I.NL.EO..RC..A.OT.R.IO..NV..*A.L.OV..RE.*.Y..OC.UORNTSACUTPPTLHIEER. WASTE OISPOSAL METHOD 00 NOT ATTEMPT TO OiSPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN TO YOUR SUPPLIER FOR DISPOSAL. FOR EMERGENCY Di$PQ~ Phfeft E SECURE IN A THE CYLINDER AND DLJ* WELL-VENilLATEO AREA OR OQWN > LOWLY OUTDOORS. TO THE ATMOS- GI Vllt-SPECIAL PROTECTIVE INFQRHA T l RESPIRATORY PRCT6CTI0N (SPECIFY TYPE) NONE* .cNTILATION OR MECHANICAL WHERE GAS IS PRESENT -- *$EE NOTES* >c TECTIVE GLOVES IF USED* MUST BE CLEAN AND GREASE FREE EYE PROTECTION SAFETY GLASSES ARE RECOMMENDED WHEN HANDLING HIGH PRESSURE CYLINDERS. OTHER PROTECTIVE EQUIPMENT SAFETY SHOES WHEN HANDLING CYLINOERS. ********** SECTION NOTES ********** LOCAL EXHAUSTi SUFFICIENT TO PREVENT OXYGEN-ENRICrttD ATMOSPHERES OF OVER ZiX OXYGEN. IX-SPECIAL PR CAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING STORE ANO USE WITH ADEQUATE VENTILATION. OXGYEN IS HEAVIER THAN AIR AND LEAKING GAS COULD ACCUMULATE IN LOW AREAS OR CONFINED SPACES CAUSING AN OXYGEN-ENRICHED ATMOSPHERE. CYLINDERS SHOULD u STORED UPRIGHT WITH VALVE PROTECTION CAP In place and firmly secured to PREVENT falling or being KNOCKEO OVER. PROTECT CYLINDERS FROM PHYSICAL DAMAGEf 00 NOT DRAG* ROLL* SLIDE* OR DROP. USE A SUITABLE HAND TRUCK FOR CYLINDER MOVEMENT. DO NOT ALLOW THE TEMPERATURE WHERE CYLINOERS ARE STORED TO EXCEED 125 F (52 C>. DO NOT STORE OXYGEN CLOSER THAN 20 FEET FROM FLAMMABLE OR COMBUSTIBLE MATERIALS. KEEP CYLINOERS FREE FROM OIL AND GREASE. LABELING QXIDUER -- YELLOW LABEL SAL 000007269 FROM L.K CHARLES Ml BIG THREE INDUSTRIES* INC* Cr S 2 71 P. O* BOX 304? HOUSTON* TX 772SJ HATER IAL SAFETY DATA SHEET <OOUCT NAME OXYGEN P.10 'AGE CGA 5*0 Oft CGA 870 (PIN INDEXED) IHEft PRECAUTIONS ALL GAUGES * VALVES* REGULATORS* PIPING ANO EQUIPMENT TO Be UACSCEDORDINANCOEXYGWEINTH SCEGRAVICPEAMMPHULSETT 365-C4L.1EA*NEDOXFYOGREN OX1$YGNENOT STEORVBICEE IN USED AS A SUBSTITUTE FOR COMPRESSED AIR, NEVER STRIKE A W6L0ING ARC ON ANY COMPRESSED GAS CYLINOER. REFILLING CVYIOLLINADTEIORNS OWFITHFOEDUETRATHL E LACWON(S4E9NT CFORF ) T HE CYLIND6R uOwWnNicERi> IS A a 00 T PLACARDS OXIDIZER DOT PROPER SHIPPING NAME 5 QXYGtN MISCELLANEOUS INFORMATION: FURTHER INFORMATION ABOUT OXYGEN CAN Be FOUND IN THE FOLLOWING PAMPHLETS PUBLISHED BY: THE COMPRESSED GAS ASSOCIATION (CGA) 1235 JEFFERSON DAVIS HIGHWAY ARLINGTON* VA 22202 ( 703) 979-4 341 G-4.3* "COMMODITY SPECIFICATION FOR OXYGEN" G~48 "OXYGEN" G-4.1: "CLEANING EQUIPMENT FOR OXYGEN SERVICE" P-U "SAFE CLEANING OF COMPRESSEO GASES IN CONTAINERS" P-14: "ACCIOENT PREVENTION IN OXYGEN--RICH ANO 0XYG6N- OEFICIENT ATMOSPHERES" S8-8: "USE OF 0XY-FU6L GAS WCLDING ANO CUTTING APPARATUS" AV-8S "CHARACTERISTICS ANO $AFc HANDLING OF CRYOGENIC LIQUID AND GASEOUS OXYGEN" NFPA RATINGS! HEALTH* flammability; REACTIVITY: Amis RATINGS* HEALTHS PLAMMAOILJTY; REACTIVITY: CERCLA RATINGS: HEALTH: FIRE: MftSlSm LISTED IN TSCA INVENTORY: YEJ rIS PRODUCT SAFETY DATA SHEET IS GFFER60 SOLELY FOR YOUR INFORMATION EXP!$RIEOSESR1A2rTIOIMNP* LIINEVDE*S0ITGIGATHTRIOENE* lNINDUCSOTMRPlEL*IA'NC^ECW. ITPHROHVAIDZEASRDNOCOWMMARURNAICNATTIEIOSN* STANDARD either SAL 000007270 23. 90 03: 1 3 PM F E T R J T E -- SHEA MATERIAL SAFETY DATA SHEET &S 27 6 PAGE 1 PETR0LITE CORPORATION 369 MARSHALL AVE. ST.LOUIS MO 63119 U.S.A REVISION DATE I 11/29/89 EMERGENCY PHONEi 1-314-961-3500 CHEHTREC EKBR NOt 1-900-424-9300 SECTION 1 PRODUCT IDENTIFICATION PRODUCTt PET1300 TRADE NAKEi PETROTEC (IF HAZARDOUS PER D.O.T. CFR TITLE 49) SHIPPING NAME* Flammable Liquid, N.O.S. LABEL* 002 000 000 HAZARD CLASSt Flammable Liquid IC#t UN1993 CHEMICAL DESCRIPTION POLYAM INE -ART L QUATERNARY IN ISOPROPANOL AND WATER. SECTION 2 HAZARDOUS INGREDIENTS CAS NUMBER MATERIAL * * Polyamlno-aryl quaternary % 30-60 EXPOSURE LIMITS Not Established 00067-63-0 Isopropanol 10-30 ACGIH TLVi 400ppffl TWA OSHA PEL* 400ppm TWA ACGIH STELt500 ppm **Specific chemical identity is being withheld for confidential business purposes. #w***********A*i*******'#******#***i****ii*******ir#*************i*t****A*it SECTION 3 PHYSICAL DATA SPECIFIC QRAVITY(H20 = 1.0960 F)* 1.055 VAPOR PRESSURE: Not Established VOLATILITY* Significant SOL. IN WATER* Soluble APPEARANCE AND ODORt Amber liquid. Alcohol odor. SECTION 4 FIRE AND EXPLOSION HAZARD DATA FLASH POINT: SO F PLASH METHOD* SFCC ASTM D-362S FLAMMABLE LIMITS* Not Established EXTINGUISHING MEDIA: use water or C02. spray or ogf alcohol-type foam, * *CONTINUED ON PACE* 2*** dry chemical SAL 000007271 MATERIAL SAFETY DATA SHEET PAGE 2 * * `CONTINUATION Or PET1300 *** riRZ FIGHTING PROCEDURES! use a self-contained breathing apparatus with full facepiece operated in pressure-demand or othar poaitiva pressure mod*. Flammable. Cool fire-exposed containers using water spray. UNUSUAL riFJ AND EXPLOSION HAZARDS* Flammable liquid, vapors of which can form an ignitable mixture with air. Vapors can flow along surfaces to distant ignition sources and flash back. SECTION 5 HEALTH HAZARD DATA B7TZC78 OF OVEREXPOSURE* INHALATION* Exposure to elevated vapor concentrations may result in eye, note and respiratory irritation. Prolonged contact may causa drowsiness, dizziness and, in extreme cases, narcosis. Inhalation of mists or exposure to very high vapor concentrations may eauae extreme eye, noee and respiratory irritation, and may result in lung damage. Prolonged over exposure may result in chemical pneumonitis and systemic effects. SKIN AND EYE CONTACT J Hay cause mild to moderate skin irritation and dermatitis on prolonged contact. Contact with eyes may cause moderate irritation and mild but reversible eye injury. Systemic effects resulting from repeated or prolonged skin absorption may include kidney and liver injury as well as other organ damage. EYE IRA. SCOREi 2 (O-None, 4-Severe) SKIN IRR SCORE* 1 (O-None, 4-sovere) DERMAL LD50: >2.0 g/kg(Rab.) INGESTION! Harmful if swallowed. May cause headache, gastrointestinal disturbances, dizziness, and nausea. May result in irritation or burns of mouth and digestive tract. ORAL LD50i 0.9 g/kg (Rat) EMERGENCY AND FIRST AID PROCEDURES! If contacted, wash skin immediately with soap and water. Remove contaminated clothing and wash before reuse, if irritation or burns develop, consult a physician. If in eyes, irrigate with flowing water Immediately and continuously for fifteen minutes. Consult a physician. * * *CONTINUED ON PAGE* 3*** SAL 000007272 w i o Avi. ^i-tr ROUITE-SHEA MATERIAL SAFETY DATA SHEET F- C 4 CS2 7 6 PAGE "CONTINUATION Of FBT13O0 *** it Ingested, DO NOT indue# vomiting. If conscious, drink promptly large quantities of water. call a phyticitn Immediately. NOTE TO PHYSICIAN! Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock and convulsion may be necessary. If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if symptoms persist or exposure was severe. SECTION 6 REACTIVITY DATA STABILITYi Stable under normal conditions of storage and uae. INCOMPATIBILITY! Small spill - Dilute with water end absorb on paper, cloth or other material. Large spill - Dike to prevent entering any sewer or water way. Transfer liquid to a holding container* Flush residues to sewer. Use personal protective equipment as necessary. HAZARDOUS DECOMPOSITION PRODUCTSi Oxides of nitrogen. HC1. HAZARDOUS POLYMERIZATION; Will not occur. **************************************************************************** SECTION 7 SPILL AND LEAK PROCEDURES IF MATERIAL IS SPILLED OR RELEASED Small spill - Absorb on paper, cloth or other material. Large spill - Dike to prevent entering any eewer or water way. Transfer liquid to a holding container. Cover residue with dirt, or suitable chemical adsorbent. Use personal protective equipment as necessary. DISPOSAL METHOD! Place chemical residues and contaminated adsorbent materials into a suitable waste container and take to an approved waste disposal site. Dispose of all residues in accordance with applicable waste management regulations. DECONTAMINATION PROCEDURES! Not appropriate. `CONTINUED ON PAGE* 4*** ooooo-r*13 SM- * J. = ^ J 1 J - XVI ^ t-tiKOL 1 r te. -- Srtfe^i MATERIAL SAFETY DATA SHEET t' u & Cr S 2 7 s' PAGE 4 CONTINUATION OF FET1300 ** t*it*A*<U*****4***************tt***********Al>*****AM***ll**il*4****** SECTION 8 SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION* When concentrations exceed the exposure limits specified, use of a NIOSH-approved organic vapor cartridge respirator with full facepiece ie recommended* Where the protection factor of the respirator may be exceeded, use of a selfcontained breathing unit may be necesaary* VENTILATION* General ventilation should be provided to maintain ambient concentrations below nuisance levels. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits* PROTECTIVE CLOTHING* Chemical-resistant gloves and chemical goggles, face shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. SECTION 9 SPECIAL PRECAUTIONS Flammable liquid. Avoid heat, sparks and open flames* Avoid breathing of vapors and contact with eyes, skin or clothing. Keep container closed when not in use. Hazardous product residue may remain in emptied container. Do not reuse empty containers without commercial cleaning or reconditioning. 4************A***********ll****************1*A***ft***A***#****************** Although the information and recommendations set forth herein are believed to be correct as of the date hereof. Petrolihe makes no representations to the accuracy of such information and recommendations. It is the user's responsibility to determine the suitability and completeness of such information and recommendation for its own particular uee.Petrollte shall not be responsible for any direct,indirect,incidental or consequential damages of whatsoever nature resulting from the publication,use of or reliance upon such information and recommendations. PETROLITE EXPRESSLY DISCLAIMS ANY AND ALL WARRANTIES OF EVERY KIND AND NATURE INCLUDING THOSE OF MERCHANTABILITY AND OF FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE PRODUCT, THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN, OR ANY USE OR RELIANCE THEREON. $al 0ooo^ 0 3. 23. so 03 1 3PM *<F*T'R,OL ITK -- SHEA ENVIRONMENTAL DATA SHEET -P o GS 27 q PETROLITE CORPORATION 369 MARSHALL AVE. ST. LOUIS MO $31X9 U.S.A. PAGE 1 REVISION DATE* 03/23/90 EMERGENCY PHONE* 1-314-961-3300 CHEHTREC EMBR NO* 1-000-424-9300 PET1300 SARA TITLE III, SECTION 313 Thii notification is incorporated into the Material Safety Data Sheet IMSDS) for the Petrolite product named above. When phyaicaily attached to the MSDS thia notification must not be detached from the MSDS. Any copying and rediatrlbution of the MSDS to which thia notification is attached must include copying and redistribution of thia notification. Thia petrolite product contains no toxic chemicals subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1966 and 40 CFR 372 in excess of the applicable de minimis concentration. SAL 000007275 FROM LK CHPRIES t41 SIS THREE INDUSTRIES INC* P. U. 30X 30 4 7 HOUSTON f TX 77*33 MATERIAL SAFETY DATA GS2 64 SHEET P.16 PAGE I-GENERAL INFORMATION PRODUCT NAME NITROGEN EMERGENCY TELEPHONE NO* 713-d6a-D302 MANUFACTURERS NAME BIG THREE INDUSTRIES* TRADE NAME/SYNONYMS NITROGEN# NITROGEN NF CHEMICAL NAME AND SYNONYMS NITROGEN REVISION DATE 2 OB/24/69 PRODUCT 10* CHEMICAL FAMILY INERT GAS INC* UN 1066 FORMULA N2 CAS NUMBER 7727-37-9 ***** SECTION NOTES ********** MSOS INFORMATION NUMBER: (713) 396-2140 I I H A l A R D^G J S l_N GREUZE NTS HAZARDOUS MIXTURES OF LIQUIDS AND GASES NITROGEN ** NONE ESTABLISHED TLV L0( ** III -- PHYSICAL DATA r'MNG POINT -320.4F (-195*30 ii 1 ATM ;iFIC GRAVITY (AIR * i>S 0.9*7 3 7C F (2i*lC) C 1 ATM OR PRESSURe N/A , ,h ,, PERCENT VOLATILE DY VOLUME (0/0) N/A (GAS) NSITY 0*37245 L 3/CU FT w/ 3 70 F (21*1 C) L 1 ATM Evaporation rate n/a (gas5 SOLUBILITY IN WATER 2.33SCC/100CC H20 3 32 F <0 C) MATERIAL AT NORMAL CONDITION GAS EXPANSION RATIO (LtDUlO TO GAS) N/A (GAS) APPEARANCE ANO DOOR COLORLESS ODORLESS, TASTELESS GAS I V - F I R c AND EXPLOSION HAZARD DAT FLASH POINT N/A FLASH POINT (METHOD USED) FLAMMABILITY LIMITS IN AIR (0/0 tlY VOL) LOWER N/A UPPER N/A EXTINGUISHING MEDIA MATERIAL IS NONFLAMMADLE NITROGEN fieltHER BURNS NCR SUP PORTS combustion* USE EXTINGUISHING media appropriate for SURROUNDING FIRE* SPECIAL FIRE FIGHTING PROCEDURES NONE NITROGEN WILL ACT AS A SIMPLE ASPHYXIANT IF IT DISPLACES OXYGEN*. IF POSSIBLE, REMOVE NITROGEN CYLINDERS FROM FIRE AR SA OR C" OOL WITH WATER TU AVOID EXCESSIVE PRESSURE JUILOUP. S__E__LF-C__O_N__TAINED BREATHING APPARATUS MAY *6 REQUIRED F 'R RESCUE WORKERS# USUAL FIRE ANO EXPLOSION HAZARD SAL 000007276 PRESSURE CAN BUILD UP DUE TO HEAT AND CYLINDER MAY tXPLOOE IF PRESSURE RELIEF DEVICES SHOULD FAIL TO RELIEVE PRESSURE SllTnfr.NTTTOM TCMPCPaTUPT: M/A FROH LK CHARLES Ml MA 'ROOUCT NAME NITROGEN big threc INQUIRIES. INC p. a. BOX 104? MOUSTUMf TX 77*3* A F E T Y OATA SHEET ELECTRICAL CLASSIFICATION: NONhAZaROOUS V-McALTH HAZARD DATA threshold limit value NUNS established UNUSUAL CHRONIC TOXICITY *SE OVEREXPOSURE SECTION* CARCINOGENICITY NOT LISTED or I ARC NTP* OSHA ROUTES OF EXPOSURE INHALATION EFFECTS OF overexposure NITROGEN IS NONTOXIC 'JJT HAY CAUSE SUFFGCAT TON BY OISPLACING THE OXYGEN IN THE AIR. EXPOSURE TO OXYG6N-0EFICI ENT ATMOSPHERES HAY CAUSE DIZZINESS# NAUSEA# VOMlTlNu# OIMINlSHEO MENTAL ALERTNESS t LOSS OF CONSCIOUSNESS. AMO DEATH* IT SHOULD iiE RECOGNIZED THAT COLLAPSE AND ASPHYXIATION MAY OCCUR WITHOUT EXPSRIZ NCIN* ANY OF THE ABOVE SYMPTOMS. TOXICOLOGICAIMPROPERT 163: NlTROGiN^IS^A^SIMPLE asphyxiant. EMERGENCY AND FIRST AID PROCEDURES PERSONS SUFFERING FROM LACK OF OXYGEN SHOULD bE MOVED INTO FRESH AIR. IF VICTIM IS NOT BREATHING# ADMINISTER ARTI FICIAL RESPIRATION. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. DOT AIN PROMPT MEDICAL ATTENTION. SELF-CONTAINED BREATHING APPARATUS MAY 3E REQUIRED FDR RES CUE WORKERS. Vi-RC ACTIVITY J A I A STABILITY STABLE CONDITIONS TO AVOID NONE. INCOMPATABILITY (MATERIALS TO AVOID) NONE. . HAZARDOUS DECOMPOSITION PRODUCTS NONE. HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID NONE. SAL 000007277 VII-SPILL OR LEAK PROCEDURES W------------------------ ------------------ ---------------------- ------------------------- ---------------------------------------------------" STEPS TO SE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEJ AGE c NOU03NNOO 3/0*A 13^V"1 N33VC - SVO SlQVHWVOdNON ownaevi x*l . 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BOX 3047 HOUSTON* TX 7725*3 MAT 5 A I AL A F T Y DATA AOOUCT NAME NITROGEN $H eT ^ 5dO THER PRECAUTIONS NEVER STRIKE A WELDING ARC ON ANY COMPRESSED CAS CYLINDER. REFILLING CYLINDERS WITHOUT THE CONSENT OF THE CYLlNOER OWNER IS A VIOLATION OF FtDCRAL LA* (<*9 CFR>* UQT PLACARD: JMFLAMmA^L! GAS DOT PROPER s `PING nahg* nitrogen; or nitrogen* compressed Siscellaneou. *n=ormatijns FURTHER INFORMATION ABOUT N1TRJCCN CAN a FUUNO IN THE FOLLOWING PAMPHLETS PUBLISHED uY: THE COMPRESSED GAS ASSOCIATION <CS4) 1235 JEFFERSON DAVIS HIGHWAY ARLINGTON* VA 22202 (703) 979-L3LI G- 10l: "COMMODITY SPECIFICATION FOR NITROGEN" P-iS "SAFE HANDLING OF COMPRESSED GASES IN CONTAINERS" P-9: "THE INERT GAGES ARGON* NITROGEN* AND HELIUM" P*Hl "ACCIDENT PREVENTION IN CXYGCN-RICH AND OXYGEN- DEFICIENT ATMOSPHERES" S3-2: "OXYGEN DEFICIENT ATMOSPHERES" NFPA RATINGS? HEALTH: FLAMMABILITY: REACT IV ITY: HrtlS RATINGS: HEALTH: FLAMMA3I REACTIVI *Y: CERCLA RATINGS; HEALTH: FIRE:0 REACTIVITY: PERSISTANCE: LISTED IN TSCA INVENTORY: YES P.19 AGE THIS PRODUCT SAFETY DATA SHEET IS OFF ft u SOLELY FOR YOUR INFORMATIONS CONSIDERATION* INVESTIGATION* IN COMPLIANCE WITH HAZARD COMMUNICATION STANDARD 29 CFR 1900.1200. DIG THREE INDUSTRIES* INC. PROVIDES NO WARRANTIES EITHER EXPRESS OR IMPLIEO. SAL 000007279 FROM IK CHARLES 141 BIG THREE INDUSTRIES* INC. P 0. 30X 30*7 HOUSTON? TX 77253 MATERIAL SAFETY DATA CS264 sheet PACE I-GENgUL INFORMATION PRODUCT name nitrogen EMERGENCY TELEPHONE NO* 713-863-0302 MANUFACTURERS NAME BIG THREE INDUSTRIES? trade name/synonyms nitrogen; nitrogen nf CHEMICAL NAME AND SYNONYMS NITROGEN REVISION DATE* 03/2A/89 PRODUCT 10. CHEMICAL FAMILY INERT GAS INC. UN 1066 FORMULA N2 CAS NUMBER 7727-37-9 *#***** SECTION NOTES * MSDS INFORMATION NUMbER; (713) 396-21*0 I I - H A Z A_R 0 0 J 5 I N_C R E D I E N T S HAZARDOUS MIXTURES OF lT'GU IDS AND~CA$S~ TLV NITROGEN ** NONE ESTADLISHED L0(' III-PHYSICAL DATA ar ` ING POINT -32D.4F (-195.30 Z 1 ATM ^ .IFIC GRAVITY (AIR * i): 0.9&7 3 7C F (21.1C) & 1 ATM 'OR PRESSURc N/A y,, *tRCENT VOLATILE BY VOLUME (0/0) N/A (GAS) NSITY 0.072AS L3/CU FT a ?D F (21.L C) ( 1 ATM Evaporation rate n/a uas5. Solubility in mater 2.33scc/ioocc H20 a 32 F (0 C) material at normal condition gas EXPANSION RATIO (LIOUID TO GAS) N/A (GAS) APPEARANCE ANO ODOR COLORLESS t ODORLESS* TASTELESS GAS IV-FIRc AND EXPLOSION HAZARD DAT* FLASH POINT N/A FLASH POINT (METHOD USED) FLAMMABILITY LIMITS IN AIR (0/0 DY VOL) LOWER N/A UPPER N/A EXTINGUISHING MEDIA MATERIAL IS NONFLAMMABLE. NITROGEN NEITHER BURNS NCR SUP PORTS COMBUSTION. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. ,,,,Qn cal 000007280 SPECIAL FIRE FIGHTING PROCEDURES 5>AU NONE# NITROGEN WILL ACT AS A SIMPLE ASPHYXIANT IF IT DIS PLACES. OXYGEN# IF POSSIBLE? REMOVE NITROGEN CYLINDERS FROM FIRE AREA OR COOL WITH WATER TU AVUIO EXCESSIVE PRESSURE BUILDUP. SELF-CONTAINED BREATHING APPARATUS MAY & REOUI RED F 'R RESCUE WORKERS. USUAL FIRE ANO EXPLOSION HAZARD ' PRESSURE CAN DDILD UP DUE TO HEAT AND CYLINDER MAY EXPLODE IF PRESSURE RELIEF DEVICES SHOULD FAIL TO RELIEVE PRESSURE. FROM IK CHARLES Hi MA ^OOUCT NAME NITROGEN am three INDUSTRiIEcSa INC P* O" r BOX 30*7 HOUSTON# TX 772 53* a f e t y oata sheet ELECTRICAL CLASSIFICATION: NONHA2AftOOUS v-healTh hazard data iRCSIlOLO limit value NONE ESTABLISHED *U$UAL CHRONIC TOXICITY *SE OVEREXPOSURE SECTION* 4RCIN0GENICITY NOT LISTED JY I ARC t NTP. USHA OUTES OF EXPOSURE INHALATION FFgCTS OF OVEREXPOSURE NITROGEN IS NONTOXIC* HUT MAY CAUSE SUFFOCATION 3Y 02SPLACING THE OXYGEN IN THE AIR* EXPOSURE TO OXYGEN-DEFICIENT ATMOSPHERES HAY CAUSE UItiINESS. NAUSEA t VOMITIN*. DlMlNlSHED MENTAL ALERTNESS * LOSS OF CONSCIOUSNESS. AND DEATH* IT SHOULD GE RECOGNIZED THAT COLLAPSE AND ASPHYXIATION MAY OCCUR WITHOUT bXPERIC .VClNi* ANY OF THE ABOVE SYMPTOMS. TOXICOLOGICAL PROPERT IES: nitrogen~i$~a simple asphyxiant* mergency ano first aid procedures AGE */ SELF-CONTAINED BREATHING APPARATUS HAY 3E REwUIftEO FUR RES CUE WORKERS* Vl-RCACTIVITY DATA i TAGIL ITY STABLE CONDITIONS TO AVOID NONE* INCOMPATA0ILITY (MATERIALS TO AVOID) NONE* HAZARDOUS DECQMPOSITION PRODUCTS NONE* h. .ARUOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID NONE ^ o0qqo7281 VII-SPILL OR LEAK PROCEDURES W----------------- ------------ ------------ ----------------- -------------------- --------------------------------- -------------------------- STEPS TO 36 TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED rr N0I1D3NN00 3A1VA Nj 3 VC - ?VD ?"lGVWWVldNON ONnsevi *1*0 - (0 3 S?t 0330X5 01 03*010 2VV CVDONITAD 3V3H* 3VniW3dH31 3H1 MODIV ION PC INIhHAOK vscnidad vod xonvi onvh sonvuns v asn *dovo vo r3oi*s *~ncv *rv*o ion oo t3cvwve tvoiSAHd wovd svaonnAO loaiovd V3AC G3*0nNX CN13* VO CMVlVd 1N3A3W 01 03*003$ ATM*Id ONV =SOVDd N1 dVD NOIiODiOVd DA IV A HUM lHCIVdO C3V0U 3 mnOHS CVDCNT1A0 NDI1V1I1N3A 31VO03aV HUM 3$n QNV 3*01$ Z8ZA00000 "IVS ONIXOU ONV ONItONVH NI N3XV1 30 01 SNC110V03** S r: o I 1 n v 0 3 V d IVJDDdS-Xl S3A TlVOINVHOrW S3 A HS0VHX3 1V001 ( 3V3Hd$0WlV 1N3IOI330*N3AOXO> * S*61 u013n T1 1N31NOO NT.SAXO CNIV5MCH CIOAV 01 31Vnr>3CV ********** S31CN NOI103S ********** SV30NI1AD OMDaNVH N3HM S20HS A13dV$ iNDwdin*3 3AiiD3irw<j vbhio SVDONnAD 3*nsS3*d HCIH ONIICNVH N3HM G3nN-3WKCD3V 3VV S3SSV10 AlSdVS f;criD3iovd V/N S3A010 3AI1D3U . S3ION 33S* ' _J N0UVTUN3A NCHDtiOrl 1CN "HIM S*CiV*IdS3V S3*3Hd$0WlV 1NDI0 J dr 0-Y3CAXC Nl X$VW HUM 3N11 VI V 3*OS$3*d SAlllSOd VO $01V*VddV 0NTW1V3VC G3NI VlN0D~d"13$ 3$0 (3dAl AdlODdS) NCI 10310Vd A*ClVVTdS3* 0 J 1 vw *ndn I 3a 1 i 31P d -fri 0 I~d S - I I 1 A 3fV 81 ^ kl, ^ ^ TvrCCino VC V3*V 031V0J1N3A-^T5M V N1 l*3L4*t2wiV 3H1 01 Al^CT* 1N3A ONV V3CNHA0 3V0D3S MV* -OdSlO A0N50V3W3 *0d DVSPdSlO Vtd VrlllddOS VOOA 01 NV013* S3I1UNVD0 ODSONO *0 "IVOCICDV dC J$Gd$tn 01 ldWiliV ION 00 00H13W TVSOdSlO 31SV* vUTddns vnoA xo 4nouydoi S3I*1S0CM *3*U CIS 1$3$C10 3H1 13V1NG0 3A1VA VO X3N1V1N0D WOVd ON7XV31 dl S3V3Hd50WlV 1N3ID?d30-N35AX0 dO NOJlVWVOd lN3A3Vd Cl N011VD01 VOdCinO NV 01 SV30N11AO 3AOW3V VO SV3VV 03SOTDN3 31VH1N3A 31I$S0d dl NDOOVIIN dO 30VOOS ddO 10HS V3VV 031D3ddV KOVd 13NNOSV3V AVVSS333NNH HV 31XnOVA3 i 5 3hr *9ZS* VIVO AlDdVS 57XxoIr **0oNO*ICdOOH or; 1 S3IV1? PONl 33V-*1 1VI 018 N300VIIN 3WVN lOnOOVc V3 1VW 1H S318bK3 *1 MOtti PROM LK CHARLES 141 0 S 2 64 THREE iNDUSTAies* INC & Hit,P. 0. HUUS T3.N# MATERIAL vOOUCT NAME NITROGEN A F T Y OAfA SHE 5iO HER PRECAUTIONS NEVER STRIKE A WELDING ARC ON ANY COMPRESSED GAS CYLINDER# REFILLING CYLINDERS WITHOUT THE CONSENT OF THE CYLINDER OWNER IS A VIOLATION OF FEDERAL LA* (<*9 CFR>* UOT PLACARD! JMFLAM.^AoLS GAS DOT PROPER $ ?ING NAME! NITROGEN; OR NI TROSENt COMPRESSED MISCELLANEOUS INFORMATION: further Information about nitrogen can ae founo in th:; FOLLOWING PAMPHLETS POLISHED oYs THE CQMPRESSEO GAS ASSOCIATION <CSA) 1235 JEFFERSON DAVIS HIGHWAY ARLINGTON* VA 22202 ( 703) 9 79-091 P. 1%9 page S3-2: "OXYGEN DEFICIENT ATMOSPHERES" NFPA RATINGS: HEALTH: FLAMMABILITY: REACTIVITY: HMIS RATINGS: HEALTH: FLAMMA3I REACTlVi Y: CERCLA RATINGS: health; FIRE:0 REACTIVITY: RESISTANCE: LISTED IN TSCA INVENTORY: YeS CTOHNISSIDPREORDAUTCIOTNS* AFINEVTYESOTAIGTAATISOHNE*ET INIS COOFMFPgLRIAENuCESOWLEITLHY FHOARZARYDOURCOIMNFMOURNMICAATITOI^N 29 CFR 1900.1200. BIG THREE INDUSTRIES* INC. PROVIDES NO WARRANTIES" EXPRESS OR IMPLIEO. standard EITHER sal 0007^3 FROM IK CHARLES Ml 9IG THRE INDUSTRIES# INC. P. U. BOX 30 47 HOUSTON# TX 77253 MATERIAL SAFETY DATA S264 SHEET P.16 IPAGE i-gensral i nfoama r ion product name nitrogen EMERGENCY TELEPHONE NO. 7l3-d63-03O2 MANUFACTURERS NAME BIG THREE INDUSTRIES# TRADE NAME/SYNONYMS NITROGEN# NITROGEN NF CHEMICAL NAME AND SYNONYMS NITROGEN REVISION DATE * 0S/24/B9 PRODUCT 10. CHEMICAL FAMILY INERT GAS INC. UN 1066 FORMULA N2 CAS NUMBER 7727-37-9 ***#*** SECTION NOTES ******** MS OS INFORMATION NUMBER: (713) <396-2140 I I -JJJ1 Z_A R OJi J S INGREDIENTS HAZARDOUS MIXTURES OF LIQUIDS AND GASES* 0/0 NITROGEN ** NONE ESTABLISHED 10< III -- PHYSICAL DATA BOILING POINT -320.4F (-195.30 B 1 ATM ;C IF IC GRAVITY (AIR * i): 0.9*7 ) 7C F (2 L 1C) b l ATM v '.OeiRn Pi- Ra Et-S?SeUi iRft E* tNi //AA PERCENT VOLATILE BY VOLUME (0/0) N/A (GAS) NSITY 0.37245 L3/CU FT 3 70 F (21.1 C> L 1 ATM Evaporation rate n/a (gas5 Solubility in water 2.33scc/ioocc hzo a 32 f (q o MATERIAL AT NORMAL CONDITION GAS EXPANSION RATIO (LIQUID TO GAS) N/A (GAS) APPEARANCE AND ODOR COLORLESS# ODORLESS# TASTELESS GAS IV-FlRc AND EXPLOSION HAZARD 0 A T X TLV #f* FLASH POINT N/A FLASH POINT (METHOD USED) FLAMMABILITY LIMITS IN AIR (0/D BY VOL) LOWER N/A UPPER N/A EXTINGUISHING MEDIA MATERIAL IS NONFLAMMABLE. .NITROGEN NEITHER BURNS NCR SUP PORTS COMBUSTION. USE EXTINGUISHING MEDIA APPROPK IAT FOR SURROUNDING FIRE. SPECIAL FIRE FIGHTING PROCEDURES SAL 000007284 NONE. NITROGEN WILL ACT AS A SIMPLE ASPHYXIANT IF IT DIS PLACES OXYGEN. IF POSSIBLE# REMOVE NITROGEN CYLINDERS FROM FIRE AREA OR COOL WITH WATER TO AVUIO EXCeSSIVE PRESSURE JUILOUP# SELF-CONTAINED JRlATHING APPARATUS MAY &6 REQUIRED F "`R RESCUE WORKERS. USUAL FIRE AND EXPLOSION HAZARD / PRESSURE CAN BUILD UP DUE TO HEAT AND CYLINDER MAY EXPLODE IF PRESSURE RELIEF DEVICES SHOULD FAIL TO RELIEVE PRESSURE. Aiirnfr.NTTTnM rcMOPfiAtiioc! M /A FROM LK CHRRLES 141 MA PRODUCT NAME NITROGEN BIG THRg INDUSTRIES. INC p. o BOX 50*7 HOU$ TUN* TX 7725* a f e t y oata sheet p. 17 f ACE< ELECTRICAL CLASSIFICATION: ^UNHAZARDOUS v-health hazard ATA THRESHOLD LIMIT VALUE NUNS ESTABLISHED UNUSUAL CHRONIC TOXICITY *SEE OVEREXPOSURE SECTION* CARCINOGENICITY NOT LISTED JY I ARC NTP, OSHA ROUTES OF EXPOSURE inhalation EFFECTS OF OVEREXPOSURE NITROGEN IS NONTOXIC. BUT MAY CAUSE SUFFOCATION BY DI5- PLACING THE OXYGEN IN THE AIR:, EXPOSURE TO OXYGEN-OEFICItEeNT ATMOSPHERES SHED MENTAL tossMAY CAUSE UIZZIHESSS-*. N__A__U_S__E_A__* V__O__M__I_T_I_N__G,* _O__I_M___INl- ALERTNESS of Consciousness* and death* IT SHOULD OE RECOGNIZED THAT COLLAPSE AND ASPHYXIATION MAY OCCUR WITHOUT EXPERIE NCl.Ni# ANY OF THE ABOVE SYMPTOMS* TOXICOLOGICAL PRQPERT IES: nitrogen" s"a~simple~ asphyxiant. EMERGENCY AND FIRST AIO PROCEDURES W PERSONS SUFFERING FROM LACK OF OXYGEN SHOULD *E MOVED INTO FRESH AIR. IF VICTIM IS NOT BREATHING* ADMINISTER ARTtFICIAL RESPIRATION* IF BREATHING IS DIFFICULT* ADMINISTER OXYGEN* OBTAIN PROMPT MEDICAL ATTENTION. SELF-CONTAINED BREATHING APPARATUS MAY 3E REQUIRED FOR RES CUE WORKERS* VI-REACTIVITY DATA STABILITY STABLE CONDITIONS TO AVOID NONE* INCOMPATABILITY (MATERIALS TO AVOID) NONE* HAZARDOUS DECOMPOSITION PRODUCTS NONE* ZARUOUS POLYMERIZATION CONDITIONS TO AVOID WILL NUT OCCUR NONE* SAL 00007285 VII -- SPILL OR LEAK PROCEDURES W----------------- --------------------------------------------------------------------------------------------------------------------- STEPS TO 3E TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED r FROM IK CHARLES Ml BIG THREE INDUSTRIES* INC 0. LlOx s5<*7 HOUSTON* TX 77253 rt A T fc R I A L SAFETY DAT PRODUCT NAME NITROGEN 6 S 2 64 Hi EVACUATE ALL UNNECESSARY PERSONNEL FROM AFFECTED AREA. SHUT OFF SOURCE OF NITROGEN IF POSSIoLE VENTILATE ENCLOSED AREAS OR REMOVE CYLINDERS TO AN OUTDCuR LOCATION TJ PREVENT FORMATION OF OXYGEN-DEFIClENT ATMOSPHERES* IF LEAKING FROM CONTAINER OR VALVE * CONTACT THE CLOSEST 3IG THREt INDUSTRIES LOCATION* UR YOUR SUPPLIER * WASTE DISPOSAL METHOD DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED JUANTlTIcS. RETURN T. C^L Y_O__U_R_ SUPP-LIER FOR DISPO_ S_ A_L. FOR EMERGENCY ODISPOSAL SECURE CYLINDER AND VENT jLOwLY TO THE ATMOSPHERE IN A WELL-VENTILATED AREA DR OUTDOORS. P. 19 AviE V_I I I - S P E_C I A L P s_J T t_C T t V I U F U R M A T I 0 U RESPIRATORY PROTECTION (SPECIFY TYPE) USE SELF-CONTAINED OREAT Hi N APPARATUS OR POSITIVE PRESSURE AIR LINE WITH MASK IN OXYScN-UEFICIENT ATMOSPHERES* RESPIRATORS WILL NOT FUNCTION. VENTILATION *SEE NOTES* V. jTECTIVE GLOVES N/A Ws PROTECTION SAFETY GLASSES ARE RECOMMENDED WHEN HANDLING HIGH PRESSURE CYLINDERS. OTHER PROTECTIVE EQUIPMENT SAFETY SHOES WHEN HANDLING CYLINDERS. ******** SECTION NOTES ********** ADEUUATE TO AVOID LOWERING OXYGEN CONTENT TJ uELOn 19.5 \ (OXGYEN-DEFICIENT ATMOSPHERE) LOCAL EXHAUST; YES MECHANICAL: YES IX-- SPEC I AL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING STORE AND USE WITH ADEQUATE VENTILATION. CYLINDERS SHOULD BE STORED UPRIGHT WITH VALVC PROTECTION CAP IN PLACE AND FIRMLY SECURED TO PREVENT FALLING OP. BEING KNOCKED OVER* PROTECT CYLINDERS FROM PHYSICAL DAMAGE* DO NOT DRAG* ROLL* SLIOE* OR DROP. USE A SUITABLE HAND TRUCK FOR CYLINDER MOVEMENT* DU NOT ALLOW THE TEMPERATURE /(HERE CYLINDERS ARE { STORED TO EXCEED 125 F (52 C). ' 7.T* LABELING NONFLAMMABLE GAS - GREEN LAjEL VALVE CONNECTION sAL 000007286 FROH LK CHARLES 141 PRODUCT GS264 HAT 5A 1 NAME NITROGEN -l AL THREE P. INDUUS5TTIRIES O* 30X * INC HOUSTON, TX A F E T Y DATA SHEcT 530 OTHER PRECAUTIONS never strike a welding arc on any compressed gas cylinder. REFILLING CYLINDERS WITHOUT THE CONSENT OF THE CYLINDER OWNER IS A VIOLATION OF FtOCKAL lAw (<,9 CFR) UQT PLACARD: JMFLAMMAoLE GAS DOT PROPER S VINO NAMES NITROGEN; UR NITROGEN* COMPRESSED MISCELLANEOUS *vFORM AT ION! FURTHER INFORMATION A3 OUT NITROGEN CAN 6E FOUND IN THE FOLLOWING PAMPHLETS PUBLISHED vY: THE COMPRESSED CAS ASSOCIATION (CGA) 123$ JEFFERSON DAVIS HIGHWAY ARLINGTON* VA 22202 ( 703) 979-041 G-IO.U "COMMODITY G ? EC IF ICAT ION FOR NITROGEN" P-i: "SAFE HANDLING UF COMPRESSED GASES IN CONTAINERS" P-9: "THE INERT GAGES ARGON* MITRUGSN, AND HELIUM" PH> "ACCIDENT PREVENTION IN CXYJCN-RICH AND OXYGEN* DEFICIENT ATMOSPHERES" S3-2: "OXYGEN OEFICIrNT ATMOSPHERES" NFPA RATINGS: HEALTH* FLAMMABILITY; REACTIVITY: 0 0 0 s`-*/ Hrtis RATINGS: health; FLAHMA3I reactiv; *Y: o Q o CERCLA RATINGS; HEALTH; FIRE:0 REACTIVITY: PERSISTANCE: 0 J 3 LISTED IN TSCA INVENTORY: YeS P. 19 ACE* THIS PRODUCT SAFETY DATA SHEET IS OFFERED SOLELY FOR YOUR INFORMATION^ * CONSIDERATION# IN VEST IGAT lONt IN COMPLIANCE WITH HAZARD COMMUNICATE STANDARD 29 CFR 1900.1200. BIG THREE INDUSTRIES, INC, PROVIDES NO WARRANTIES, EITHER EXPRESS OR IMPLIED. SAL 000007287 FROM LK CHARLES 141 aav 1M MWW UlUVIJ I )V i L Jl 1 DC t P. 0* ^UX 30*7 HOUSTON* TX 7 725 3 M A T ft I A L SAFETY a r a G S264 ihe e r Pall wage (-GENERAL I NFURMAT I 0 ?i Product name NITROGEN* REFRIGERATE!) LIQUIO EMERGENCY TELEPHONE NO* 713-366-0302 ANUFACTURERS NAME BIG THREE INDUSTRIES. RAGE NAME/SYNONYMS LIQUID NITROGEN (lIN) .hemical name ano synonyms ,,_ NITROGEN* REFRIGERATED LlwUlD ,,,, r .EVISION DATES 08/2A/89 PRODUCT ID. :m6MICAL FAMILY INERT GAG INC* UN 1977 FORMULA N2 CAS NUMBER 7727-3 7-9 `**** SECTION NOTES 4'++ + **** HSOS INFORMATION NUMBER: (713) J96-21A0 ii-hazardous_ingreoients HAZARDOUS MIXTURES OF LIUUIOS~ANO~GASCS~ NITROGEN ** NONE ESTABLISHED OiO I0( TLV II l-PHYSICAL DATA sailing point -320.*f (-195*30 <a t atm SPECIFIC GRAVITY (H20 * i)8 0*8093 3 BOILING PT* C l ATM V/ '`R PRESSURE N/A ^ % Pi ENT VOLATILE ,3Y VOLUME (0/0) . ,A N/A r><*.,,*ITY 50*A9 LB/CU FT 3 BOILING PT* 3 l ATM tPOKATION RATE N/A, ^CUBILITY IN WATER N/A T >tfr MATERIAL AT NORMAL CONOITION LIQUID EXPANSION RATIO (LIWUIO TO GAS) 1:696*5 appearance and odor COLORLESS* ODORLESS GAS IV-FIRE AND EXPLOSION HAZARD DAT) FLASH POINT N/A FLASH POINT (METHOD USED) , , FLAMMABILITY LIMITS IN AIR <0/0 OY VOL) LOWER N/A UPPER N/A EXTINGUISHING MEDIA MATERIAL IS NONFLAMMABLE. NITROGEN NEITHER BURNS NOR SUP PORTS COMBUSTION* USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE* SPECIAL FIRE FIGHTING PROCEDURES NONE * NITROGEN WILL ACT AS A SIMPLE ASPHYXIANT IT IT DIS PLACES OXYGEN* LIQUID NITROGEN WHEN SPILLED WILL VAPORIZE RAPIDLY CAUSING A VAPOR CLOUD THAT WILL CREATE AN OXYGENDEFICIENT ATMOSPHERE. EVACUATE TH AREA OF THIS VAPOR CLOUD UNLESS WEARING SELF-CONTAINED BREATHING APPARATUS* U UAL FIRE AND EXPLOSION HAZARD SAL 000007288 >w/ CONTACT WITH "COLO" LIQUID OR GASEOUS NITROGEN HAY CAUSE FROSTBITE* VISIBILITY MAY JE OBSCURED IN THIS "VAPOR CLOUD"* AUTOIGNITION TEMPERATURES N/A FROM LK CHPRLES 141 UU IHKfet INDUSTRIES* ISC* 6 S 2 64 j> o* Ijx 30*7 HOUSTON# TX 77233 * . MATERIAL $ A F E T Y 0 A T A 3DUCT NAME NITROGEN* REFRl GERATED LIOUIO SHEET P. 12 FACS ELECTRICAL CLASSIFICATION: NONHAZARUOUS V-rlcALTH HAZARD DATA RESHOLD LIMIT VALUE NONE ESTABLISHED USUAL CHRONIC TOXICITY *SEE OVEREXPOSURE SECTION* RCINOGENICITY NOT LISTED 3Y lAROt NTP, OSHA ,UTES QF EXPOSURE INHALATION, EYE/SKIM CONTACT FECTS OF OVEREXPOSURE NITROGEN IS NONTOXIC* 3UT MAY CAUSE SUFFOCATION AY DIS PLACING THE OXYGEN IN THE AIK. EXPOSURE TO OXYGEN-DEFICIENT ATMOSPHERES may CAUSE DIZZINESS# NAUSEA, VOMITING, DIMINI SHES MENTAL ALERTNESS, LOSS JF CUN5ClOUSNESS, AND DEATH. ......... .. .... ......._____ ___ FROSTBITE ARE PAINLESS AND APPEAR WAXY WITH A POSSIBLE YELLOW COLOR, THEY WILL BECOME SWOLLEN, PAINFUL, AND PRUNE T(J INFECTION WHEN THAWED, TOXICOLOGICAL PROPERTIES: NITROGEN*IS A SIMPLE ASPHYXIANT, CONTACT WITH COLD LlUUlO OR PIPING HAY CAUSE COLD CONTACT BURNS, "FROSTBITE*, MERGENCY AND FIRST AID PROCEDURES PERSONS SUFFERING FROM LACK QF OXYGEN SHOULD UE MOVED INTO FRESH AIR, IF VICTIM IS NOT BREATHING, ADMINISTER ARTI FICIAL RESPIRATION* IF BREATHING IS DIFFICULT, AQMINISTER OXYGEN* OBTAIN PROMPT MEDICAL ATTENTION# SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED FOR RES CUE WORKERS# If CONTACT WITH CRYOGENIC LIQUID NITROGEN HAS CAUSED FROST' Site, oo not rub the affected area, as tissue damage may OCCUR, FLUSH THE AFFECT0 AREAS WITH WARM WATER, Du NOT USE HOT WATER# OBTAIN PROMPT MEDICAL ATTENTION* VI-RtACTIVlTY DATA STABILITY STABLE '"'NDITIONS TO AVOID NONE. INCQMPATABILITY (MATERIALS TO AVOID) NONE. SAL 000007289 S^ARDOUS DECOMPOSITION PRUOUCT3 NONE# r f'" FROM "IK CHARLES 141 NAME MATER IAU SAFETY 0 NITROGEN* REFRIGERATED LIQUID A T A GS264 SrtitT P. 13 f AG6 AROGUS polymerization toinoNS ro avoio NONE* will not occur 0 R leak procedures =PS TO ae taken in case material is RELEASED or spilled evacuate all uUnNnNeEcCeEsSsSaArRyY WHERE AN OXrGE* " PEPSONNL FROM V4P<)R ri ,nin shaSusaI^ff UUS88In orTtLsf crnoiton'33iC=OFF SYi9sIiu' Sf5rf"ktUSCMT eWSITHii'>LI*QfUraIDFn ciloSittATlON SPRAY WITH LARGS AMOUNTS OF WATER FROM UPWIND. iF^FAKINGFROM CONTAINER OR CONNECTION* CONTACT THE CLOSEST irr^THREE INDUSTRIES LOCATION* OR YUUR SUPPLI6ft. SlLF-CQNfl^MED BREATHING APPARATUS WtLL HE REQuIRcO IN OXYGcN--Q6P 1" CIENT AREAS SUCH AS NITROGuN VAPOR CLOUDS. STE DISPOSAL METHOD RETURN TaTVOUR SUPPLll^FjR^ojfprjSiL1* PrtBNUS0 QUANTITIES, HkiAEjjRT8^52isiuT0r?ft inmmui SPOLA TED VIII-SPECIAL PRUT5CTIV I N F 0 R M A Mon ESPIRATORY PROTECTION (SPECIFY TYPE) USsEe self-contained saeatning apparatus or positive pressure A t*R LINE WITHMASKINOXYGEN-OcFICIENT ATMOSPHERcl. * KgESPIRATORS WILL NOT FUNCTION. VENTILATION SEE NOTES* 'ROTECTIV6 GLOVES LOOSE-FITTING THERMAL INSULATED/LEATHER YE PROTECTION FULL FACE SHIELD AND SAFETY GLASSES ARE RECOMMcNDEQ WHEN HANDLING N2 LIQUID OTHER PROTECTIVE EQUIPMENT LONG SLEEVE SHIRT FOR LIQUID HANDLING. SAFETY SHOES IF HANDLING CYLINDERS. ******* SECTION NOTES ********** ADEQUATE TO AVOID LUWERING OXYGEN CONTENT TO oELOW 19*5 (OXYGEN-DEFICIENT ATMOSPHERE). LOCAL EXHAUST: YES MECHANICAL: YES SAL onnnn-> 0007z9o ___________ ___________ c a u r'i o^TTs' -PRECAUTIONS TO SE TAKEN IN HANDLING ANO STORING FROM LK CHARLES Ml GS 264 Ul IIIKCC 14UV&1Klfc*t IML. a;P HOUSTON nK mU OPUCT NAME MATERIAL SAFETY 0 NITROGEN* REFRIGERATED LIQUID A T A MEET P.14 PAGE STORE AMO USE WITH ADEQUATE VENTILATION* CONTAINERS SHOULD 8E STORED UPRIGHT AND FIRMLY SECURED TO PREVENT FALLING Oft USING KNOCKED OVER* PROTECT CONTAINERS FROM PHYSICAL DAMATRfiUcC] K00FONROCT OONRTAACIN#ERROMILOfVESMLEINDTE*? OLKtQUDRIOOPJ*oNTUASXENEAftSSUITA.!BL*E HA4NLD CYLINDERS) WILL VENT NITROGEN IF INTERNAL PReIsuRE BUILDS^ UPg |0 THESE CONTAINERS SHOULD Sfc STOREO IN WELL-VENULAfl60 O.T. LABELING NONFLAMMABLE LIQUID - SREfcN LAuCL ALVE CONNECTION 295 FOR LIQUID? 580 FOR GAS THEft PRECAUTIONS reoCCLLTPPBRIORRORlQAjEELLIuTUOPSSOTPSSiI*oDLEUUPEDRRIPEEMNNSIAIAIINTTNNNRR_RGDYW6OQLAHGMAIr,UECCSANFNTHYOEFNWCDRFERTROXOEAIlALPAUIVSNLACLLTI"ENDCSTRBRDUEtIUTS3R.PE5OStRUATCTMUTPWHRRPAIHPAAYEEIIPN'APNSPROTEGEAECA*DcXCCT.TMA.IU*O!RRUCMUR!BE$U.jOTJSMWSFNT^EtIHmLdLLY6SNt.9TGPCDE6RRP^OEJE,5LROjS*LLUOw^ODI*Gw*TTU.NOHiwCN!l;EV0LDl* OLIENAFOORABNRNEREO3CMYDATOOEMUXWaTIFTOSEHRUEECRMHEE DOT placard* nonflammable liquid DOT PROPER SHIPPING NAMES NITROGEN* REFRIGERATED LIQUID MISCELLANEOUS INFORMATION* FURTHER INFORMATION ABOUT IICUIO NITROGEN CAN THE FOLLOWING PAMPHLETS PUDlIShEU dYs BE FOUND IN THE COMPRESSED GAS ASSOCIATION CCGA) tWIWMJi1235 JEFFERSON DzzAzVoISz HIGHWAY PPGP---9-11lS2OJ *U"*S-TAgF'IEC4OHNMSAMARNOSDDLIoTINY^GS^POsEoF C^cCIFGOIgMCPA?RTE5ISO^SNE^D^FO?GRA2SEN0SIlToARN-INODGCEHONE"NLITUAMIN" ERS" P-U* m&mnhpihs9he! OXYGEN- S3-. AV-! SgtftaSEftS1 ARGON" NFPA RATINGS* HEALTH* F*km8iHrs HMIS RATINGS: HALtHt FLAMMABILITY* REACTIVITY* CERCLA RATINGS: mi\Hs REACTIVITY* PlRSISTANCE* lisreo in r$CA investory* yss SFL oooo OlZ?1 FROM LK CHARLES Ml aux INCinuci l NUUV IIKKiltmttfi i Pm Qm 304? HOUSTON* TX ??253 MATERIAL SAFETY DA T A 'RdOUCT NAME NITROGEN# REFRIGERATEQ LtUUIO CS264 S H fe T P. 13 t AS6 THIS PRQOUCT SAFETY DATA SHEET 15 JFPERED SOLELY FOR YOUR INFORMATION ONSXDERATIONt INVESTIGATION# IN COMPLIANCE WITH HAZARD COMMUNICATIO STANDARD 9 CFR 1900.liOO. 8IG THREE INDUSTRIES* INC* PRUVIOeS NO WARRANTIES EITHER XPRESS OR IMPLIED* I m r-jO SAL 000007292 w >i in PI 123 MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE ^ 2(r S 1 S* PQ 1 REVISION OF: 03-07-90 MAIL TO: 43000382 CONOCO INC REFINING P O BOX 37 WESTLAKE LA 7066? ORDER NO: 431SOG111 PROD NO: 04310034 VAN WATERS & ROGERS INC. . SUBSIDIARY OF UNIVAR 1600 NORTON BLDO. SEATTLE. WA 98104-1364 (408) 433-8700 EMERGENCY ASSISTANCE-------------------------------------------------------- FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC (800)424-9300 ------------------------------------------FOR PRODUCT AND SALES INFORMATION--------------------------------------- CONTACT YOUR LOCAL VAN WATERS St ROGERS BRANCH OFFICE --------------------------------------------------PRODUCT IDENTIFICATION------------------------------------------------------- PRODUCT NAME: HYDROCHLORIC ACID COMMON NAMES/SYNONYMS: HYDROCHLORIC ACID; MURIATIC ACID; HYDROCHLORIC ACID 10 BE; HYDROCHLORIC ACID 9X CAS NO. : 7647-01-0 VWStR CODE: PI 123 FORMULA: H CL HAZARD RATING (NFPA 49) HEALTH: 3 FIRE: O REACTIVITY: O SPECIAL: NONE DATE ISSUED: 03/90 SUPERCEDES: 02/90 HAZARD RATING SCALE: 0=MINIMAL 3-SERIOUS 1 -SL IGHT 4-SEVERE 2-MODERATE -HAZARDOUS INGREDIENTS- COMPONENT CAS NO. EXPOSURE LIMITS. PPM OSHA ACGIH OTHER X PEL TLV LIMIT HAZARD HYDROCHLORIC ACID 7647--01--OM 9-37 3 3 CEILING CEILING WATER 7732-18-3 BALANCE NONE NONE NONE NONE CORROSIVE NONE -------------- PHYSICAL PROfERTIES-- BOILING POINT. DEG F: 150 - 230 VAPOR PRESSURE. MM HG/20 DEG C: 30 AT 77 DEG F MELTING POINT. DEG F: N/A VAPOR DENSITY (AIR-1>: N/A SPECIFIC GRAVITY (WATER-1): A--1. 14; B-l. 16; WATER SOLUBILITY. X: C-l. 18; D-t.07 APPEARANCE AND ODOR: CLEAR. EVAPORATION RATE (BUTYL ACETATE-1): N/A COLORLESS TO PALE YELLOW WITH PUNGENT. IRRITATING ODOR. (A--18 DEG BE HYDROCHLORIC ACID) B-20 DEG BE HYDROCHLORIC ACID; C--22 DEG BE HYDROCHLORIC ACID; D-10 DEG BE HYDROCHLORIC ACID) -FIRST AID MEASURES- IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. sAL 000007293 PROD: 04310034 02:19:47 21 MAR 1990 OUST: 43000382 INVOICE: 431300111 GS192 PI 123 ' ~ MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE PO 2 REVISION OF:03-07-90 IN CASE OF EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 30 MINUTES* LIFTING THE UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. IN CASE OF SKIN CONTACT: IMMEDI ATS*Y FLUSH SKIN WITH LOTS OF RUNNINQ WATER FOR 30 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOESj WASH BEFORE REUSE. GET IMMEDIATE MEDICAL ATTENTION. IF SWALLOWED: DO NOT INDUCE VOMITING. IF CONSCIOUS* GIVE LOTS OF WATER. GET IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON. ------------------------------------------------HEALTH HAZARD INFORMATION------------------------------------------------- PRIMARY ROUTES OF EXPOSURE: SKIN OR EYE CONTACT* INHALATION. SIGNS AND SYMPTOMS OF EXPOSURE INHALATION: VAPORS AND MISTS ARE EXTREMELY CORROSIVE TO THE NOSE* THROAT* AND MUCOUS MEMBRANES. BRONCHITIS* PULMONARY EDEMA* AND CHEMICAL PNEUMONITIS MAY OCCUR. IRRITATION* COUGHING* CHEST PAIN* AND DIFFICULTY IN BREATHING MAY OCCUR WITH BRIEF EXPOSURE WHILE PROLONGED EXPOSURE MAY RESULT IN MORE SEVERE IRRITATION AND TISSUE DAMAGE. BREATHING HIGH CONCENTRATIONS MAY RESULT IN DEATH. EYE CONTACT: VAPORS* LIQUID* AND MISTS ARE EXTREMELY CORROSIVE TO THE EYES. BRIEF CONTACT OF THE VAPORS WILL BE SEVERELY IRRITATING. BRIEF CONTACT OF THE LIQUID OR MISTS WILL SEVERELY DAMAGE THE EYES AND PROLONGED CONTACT MAY CAUSE PERMANENT EYE INJURY WHICH MAY BE FOLLOWED BY BLINDNESS. SKIN CONTACT: VAPORS, MISTS* AND LIQUID ARE EXTREMELY CORROSIVE TO THE SKIN. VAPORS WILL SEVERELY IRRITATE THE SKIN AND LIQUID AND MISTS WILL SEVERELY BURN THE SKIN. PROLONGED LIQUID CONTACT WILL BURN OR DESTROY SURROUNDING TISSUE AND DEATH MAY ACCOMPANY BURNS WHICH EX TEND OVER LARGE PORTIONS OF THE BODY. SWALLOWED: VAPORS. MISTS* AND LIQUID ARE EXTREMELY CORROSIVE TO THE MOUTH AND THROAT. SWALLOWING THE LIQUID BURNS THE TISSUES* CAUSES SEVERE ABDOMINAL PAIN* NAUSEA. VOMITING* AND COLLAPSE. SWALLOWING LARGE QUANTITIES CAN CAUSE DEATH. CHRONIC EFFECTS OF EXPOSURE: MAY RESULT IN AREAS OF DESTRUCTION OF SKIN TISSUE OR PRIMARY IRRITANT DERMATITIS. SIMILARLY. INHALATION OF VAPORS OR MISTS MAY CAUSE VARYING DEGREES OF DAMAGE TO THE AFFECTED TISSUES AND ALSO INCREASING SUSCEPTIBILITY TO RESPIRATORY ILLNESS. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE REPORTED. -------------------- ----------------------------------------TOXICITY DATA--------------------- ORAL: RABBIT LD50 900 MG/KG DERMAL: NO DATA FOUND INHALATION: RAT LC30 3*124 PPM/1HR CARCINOGENICITY: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN BY THE NATIONAL TOXICOLOGY PROGRAM* THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER* OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OTHER DATA: NONE SAL 000007294 -PERSONAL PROTECTION- VENTILATION: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAIN TAINING EMISSIONS AT THE POINT OF USE BELOW THE PEL. RESPIRATORY PROTECTION: WEAR A NIOSH-APPRGVED RESPIRATOR APPROPRIATE FOR THE VAPOR OR MIST CONCENTRATION AT THE POINT OF USE. APPROPRIATE RESPIRATORS MAY BE A FULL FACEPIECE OR A HALF MASK AIR-PURIFYING CART RIDGE RESPIRATOR EQUIPPED FOR ACID GASES/MZSTS. A SELF-CONTAINED r* PROD: 04310034 02:19:47 21 MAR 1990 CUST; 43000382 INVOICE; 431300111 PI123 MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE S12 PQ 3 REVISION OF: 03-07-90 BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-AIR RESPIRATOR. EYE PROTECTION: CHEMICAL GOGGLES AND FULL FACESHIELD UNLESS A FULL FACEPIECE RESPIRATOR IS ALSO WORN. IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY. PROTECTIVE CLOTHING: ACID-RESISTANT SLICKER SUIT WITH RUBBER APRON* RUBBER BOOTS WITH PANTS OUTSIDE* AND RUBBER GLOVES WITH GAUNTLETS. OTHER PROTECTIVE MEASURES: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. ----------------------------------------- FIRE AND EXPLOSION INFORMATION- FLASH POINT* DEG F: NONE FLAMMABLE LIMITS IN AIR* X METHOD USED: N/A LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA: USE WATER SPRAY. DRY CHEMICAL OR C02. SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR SELFCONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. UNUSUAL FIRE AND EXPLOSION HAZARDS: EXTINGUISH ALL NEARBY SOURCES OF IGNITION SINCE FLAMMABLE HYDROGEN GAS WILL BE LIBERATED FROM CONTACT WITH SOME METALS. HAZARDOUS REACTIVITY- STABILITY: STABLE CONDITIONS TO AVOID: NONE POLYMERIZATION: WILL NOT OCCUR MATERIALS TO AVOID: ALKALIS* OXIDIZING OR REDUCING MATERIALS* CYANIDES* SULFIDES* OR COMBUSTIBLE MATERIALS. KEEP AWAY FROM FORMALDEHYDE SINCE THERE ARE REPORTS THAT BIS-CHLOROMETHYL ETHER. A POTENTIAL CARCINOGEN. MAY BE FORMED. ALSO KEEP AWAY FROM AMINES. VINYL ACETATE* PROPYLENE OX IDE, BETA-PROP IOLACTONE* AND METAL OXIDES. HAZARDOUS DECOMPOSITION PRODUCTS: MAY LIBERATE HYDROGEN CHLORIDE. -----------------------------------SPILL* LEAK, AND DISPOSAL PROCEDURES---------------------------------------- ACTION TO TAKE FOR SPILLS OR LEAKS: WEAR ACID-RESISTANT SLICKER SUIT AND COMPLETE PROTECTIVE EQUIPMENT INCLUDING RUBBER GLOVES* RUBBER BOOTS* AND A SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE OR A SUPPLIED-AIR RESPIRATOR. IF THE SPILL OR LEAK IS SMALL, A FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR ACID GASES MAY BE SATISFACTORY. IN ANY EVENT, ALWAYS WEAR EYE PROTECTION. FOR SMALL SPILLS OR DRIPS, MOP OR WIPE UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS* CONTAIN BY DIKING WITH SOIL OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL AND CAREFULLY NEUTRALIZE WITH SODA ASH OR LIME. IF SODA ASH IS USED* PROVIDE ADEQUATE VENTILATION TO DISSIPATE THE CARBON DIOXIDE GAS. KEEP NON--NEUTRALIZED MATERIAL OUT OF SEWERS* STORM DRAINS* SURFACE WATERS* AND SOIL. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING* AND HANDLING AND DISPOSAL OF WASTE. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL* STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES# GASES AND MISTS AND ARE SUBJECT TO PROPER WASTE DISPOSAL* AS ABOVE. SAL 000007295 --------------------------------------------------- Spec iaL PRECAUTIONS-------------- ------------- STORAGE AND HANDLING PRECAUTIONS: STORE IN A COOL* DRY, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO NOT USE PRESSURE TO EMPTY CONTAINER. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES* ON SKIN* OR ON CLOTHING. PROD: 04310034 02:19:47 21 MAR 1990 CUST: 43000382 INVOICE: 431300111 Ft 123 CS192 MATERIAL SAFETY DATA SHEET HYDROCHLORIC ACID 22 BE PO 4 REVISION OF:00-07-90 REPAIR AND MAINTENANCE PRECAUTIONS: DO NOT CUT* GRIND* WELD* OR DRILL ON OR NEAR THIS CONTAINER. OTHER PRECAUTIONS: CONTAINERS* EVEN THOSE THAT HAVE BEEN EMPTIED* WILL RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. --------------------- FOR ADDITIONAL INFORMATION- CONTACT MSDS COORDINATOR* VAN WATERS & ROGERS INC. DURING BUSINESS HOURS* PACIFIC TIME <408>433-8700 --------------------------- OTHER REGULATORY INFORMATION* THE COMPONENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY OF CHEMICAL SUBSTANCES. DO NOT DETACH THIS SECTION FROM THE MSDS AND BE SURE TO INCLUDE THIS SECTION WHEN COPYING THE MSDS. THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALCS) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: NAME CAS NO. X* WT. HYDROCHLORIC ACID 7647-01-0 9-37 UNDER MASSACMUSETTES RIGHT-TO-KNOW LAW* HAZARDOUS SUBSTANCE AND EXTRA ORDINARILY HAZARDOUS SUBSTANCES COMPONENTS PRESENT IN THIS PRODUCT WHICH REQUIRES REPORTING ARE: EXTRAORDINARILY HAZARDOUS SUBSTANCES CHEMICAL CAS NO. CONCENTRATION <*> O. 00G1X HYDROCHLORIC ACID 7647-01-0 9-37 UNDER THE PENNSYLVANIA RIGHT-TO-KNOW LAW* HAZARDOUS SUBSTANCES AND SPECIAL HAZARDOUS SUBSTANCES COMPONENTS PRESENT IN THIS PRODUCT WHICH REQUIRE REPORTING ARE: HAZARDOUS SUBSTANCES CHEMICAL CAS NO. CONCENTRATION <-> IX) HYDROCHLORIC ACID 7647-01-0 9-37 CALIFORNIA 3CAGMD: N0* -----------------------NOTICE- **VAN WATERS 6 ROGERS INC. ("VWfcR") EXPRESSLY DISCLAIMS ALL EXPRESS OR IMPLIED WARRENTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE* WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN. ** ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA TION IS BELIEVED TO BE ACCURATE* VW&R MAKES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND VW&R 'S CON TROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE* HANDLING* AND DISPOSAL OF THE PRODUCT* OR FROM THE PUBLICA TION OR USE OF* OR RELIANCE UPON* INFORMATION CONTAINED HEREIN. THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN* AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS. REVISION------------- 03/90: ADDED SYNONYM PROD: 04310034 02:19:47 21 MAR 1990 SAL 000007 296 CUST: 43000382 INVOICE: 431300111 P1123 MATERIAL SAFETY DATA SHEET G 1 92 HYDROCHLORIC ACID 22 BE _ _REV ISI ON OF03-07-90 pq 3 REVISED X COMPOSITION IN INGREDIENT AND OTHER REGULATORY INFORMATION ***# END OF MSDS **** PROD: 04310034 02:19:47 21 MAR 1990 CUST: 43000382 INVOICE: 431300111 N NALCO Material Safety Data Sheet Description and Explanation of Terms Emergency Telephone Number ^ Medical (708) 920-1510 (24 hour*) w O 5 8 2 General The Material Safety Data Sheet (MSDS) has, over the years, become the major media for transmitting health and safety information on chemical products. It is therefore natural that it has been included in the new OSHA Hazard Communication Standard (29CFR 1910.1200) as the key document along with the container label to provide hazard information to employees and employers. These new OSHA regulations require chemical manufac turers to evaluate each chemical produced to detennine if it is hazardous The definition of "hazardous" has been expanded from the usual "flammable, corrosive, oxidizer, explosive, toxic or highly toxic agents, carcinogen, etc" to include combustibles as well as irritants. Consequently, many products that had not previously been classified as "hazardous" now fall into this classification under OSHA. The new regulations require chemical manufacturers and importers to prepare and distribute an MSDS for all hazardous chemicals and that each container of hazardous chemical leaving the workplace be labeled. In addition, the chemical manufacturer is to provide a copy of the MSDS to the purchaser at the time of shipment or before. Nalco has established a computerized program to send MSDS's to each purchaser upon receipt of a first order after November 25, 1985. The MSDS will automatically be sent to the attention of the purchasing agent at the "ship to address." A revised MSDS will also be sent to that same address when a change has been made to the MSDS. MSDS's will also continue to be available through your Nalco Sales Representative or upon request to Nalco. The Nalco MSDS complies with all of the requirements of the OSHA regulation. In addition, it provides you with all of the important information regarding the safe handling of our products, recommended protection measures, tox icological data, and the status of our products under various federal and state environmental and safety regulations. In short, we have put all of this information into one document for your convenience and easy use. Nalco, as part of our overall commitment to product safety, is providing MSDS's on all of our chemical products regardless of whether the product is hazardous or not The OSHA regulations require an MSDS to be pre pared only for certain hazardous chemicals This MSDS section description and explanation of terms is designed to assist your interpretation of the MSDS so that you may receive full value from the document Section 1 - Product Identification This section identifies the Nalco product by Trade Name or Product Number. This is the same trade name or product number that will appear on the product container allowing you to match up the product label with the MSDS. Nalco also provides a generic chemical description of all major ingredients, both hazardous and non-hazardous. This is designed to give your health and safety personnel information on the class of chemistry(s) in our product without compromising the proprietary nature of the formulation. The third part of this section is the National Fire Protec tion Association (NFPA) 704M rating designation. This popular rating system is used to give you a quick summary of the hazards of the product regarding health, flam mability, reactivity and other hazards. Based on NFPA definition, an organic product will always have a flam mability rating of at least (1) with inorganics having a rating of (0). Section 2 -- Hazardous Ingredients We have evaluated our formulations for hazardous proper ties and identify those chemical ingredients which we believe cause or contribute to the hazard. As required by OSHA, these substances are identified if they are present in quantities greater than 1%, or in the case of car cinogens, greater than 0.1%, or if our hazard evaluation determines a hazard exists at lower concentrations. The hazardous ingredients are identified by specific chemical name and their CAS number (the Chemical Abstract Service number for that specific chemical). To assist your industrial hygiene and safety personnel Nalco identifies general or relative concentration ranges into which the exact percentage of the hazardous ingredient falls. This should enable your safety pro fessional to evaluate the need for air sampling, employee monitoring, or other protective measures. Since most of our product formulations are proprietary, exact per centages will be given only when there are no trade secret concerns. In a few cases where disclosure of specific chemical name and CAS number of a hazardous ingredient would release trade secrets, we have identified the chemical as "pro prietary" as permitted by the OSHA regulation. In the event of an injury or accident, procedures are established to communicate the specific identity to health pro fessionals who may have need for this information. In all SAL 000007298 NALCO CHEMICAL COMPANY ONE NALCO CENTER o NAPERVILLE. ILLINOIS 60583-1138 [708) 305-1000 S58 2 <4 ALGO________________________________________________________________________ cases, the hazard information and safe handling recom mendations are provided. Section 3 -- Precautionary Label Information The drum or product container is labeled showing product identity, health and safety precautions as well as other information on handling and use of the product That por tion of the label which covers health and safety pre cautions is included in this section of the MSDS. In this way, you can easily refer to what is shown on the drum label without actually seeing the container. Empty drums or containers may contain residual product and should be treated in accordance with the label require ment unless the empty container has been properly recon ditioned. By EPA Standards (RCRA - 40CFR 261.7), a container is considered to be "empty" when it contains: 1) no more than 1 inch (2.5 centimeters) of product, or 2) no more than 3% by weight of the total capacity of the con tainer if the container is less than or equal to 110 gallons in size or 3) no more than 0.3% by weight if the container is greater than 110 gallons in size. Empty drums that formerly contained chemicals listed in 40CFR 261.33 (c) must be triple rinsed using a solvent capable of removing the commerical chemical to qualify as "empty." Quantities of chemical greater than those indicated above which remain in the container are considered "wastes" when dis posing of the container and appropriate RCRA regulations will apply. Section 4 -- First Aid Information This section is designed to provide first aid information for the typical routes of exposure. The recommendations should be followed in all cases. If exposure causes unex pected or delayed effects, or severe reaction or injury, you should immediately consult a physician. Nalco ALERT, our medical emergency system (312/920-1510) should be called by the attending physician or others. Nalco ALERT operates 24 hours/day, seven days/week and is staffed by trained professionals. Section 5 -- Health Effects Information This section describes the nature of the hazardous effect resulting from exposure if no first aid or improper first aid is given. The primary routes of exposure such as eye, skin, inhalation or ingestion are listed along with the effects that could occur from acute (single) exposure and chronic (repeated) exposure. The most likely exposure for our pro ducts would be due to unsafe practices which result in skin or eye contact from splashes during handling or feeding of the product. Section 6 -- Toxicology Information Our health hazard evaluation for a product is based upon one or more of the following: 1. Results of toxicological tests conducted on a product. 2. Toxicological test results for a product ingredients), 3. Use of lest results on a similar formulation or product and, 4. Use of information obtained in the open literature or supplier information for an ingredients). In this Section, we present summaries of results of such toxicity tests. Explanations of results are given as needed In most cases, results are those from acute, single exposure testa conducted with laboratory animals. As such, it should be remembered that the test procedures are quite stringent so that direct extrapolation of results to comparable human exposure must be viewed in that context The types of acute animal tests which are routinely con ducted include oral, dermal and inhalation lethality studies and eye and akin irritancy studies. The lethality studies involve administration of the chemical to groups of test animals at various graded dose levels and recording mor tality as one end point The mortality-dose response allows for the calculation of the LDM or LCj by appropriate statistical methods. The LDH's that dose (amount) of chemical usually expressed in grams or milligrams per kilogram of animal body weight (g/kg or mg/kg) which would produce death in one half of a group of animals administered the chemical. The LCso is equivalent to LD^o except it uses concentration rather than dose and is expressed as parts per million (ppm), milligrams per liter (mg/I) or milligrams per cubic meter of air (mg/M3). Oral and dermal testa use LD$o while inhalation tests use LCM. In both cases the smaller the value the more "toxic" the chemicaL Eye and skin irritancy tests utilize weighted numerical scores to assess degree of injury or irritation In many instances, such numerical scores are also given descriptive ratings such as mildly or severely in-itating. Most grading systems are modeled after those described by Draize, et ol (referred to in the Bibliography, Section 17) in their original eye and skin irritation test procedures Results of skin sensitization tests conducted primarily on animals are presented. Human data is given if available. Generally, these test results will be for one or more chemicals in a formulation rather than the formulation itself. When available and applicable, results of tests conducted to assess hazards other than lethality, will be provided in this Section under -- "other toxicity results" and "chronic studies." These types of tests include life-time cancer studies, reproduction tests, and tests designed to uncover birth defects (teratology studies). These tests are usually conducted on individual chemical(s) rather than on for mulated products. Other short-term bioassays for changes to genetic cells are run with bacterial and other cells. While these tests identify genetic changes in tissue, the usefulness of the information as a prediction of a similar effect to humans SAL 00000799 continues to be a scientific uncertainty. If this data is available, it will be provided in this sectioa Since OSHA has broadened the criteria for acute health hazards and since the numerical rating is not uniformly accepted by all governmental agencies and scientific bodies, we are including OSHA's definitions below: Highly toxic substance is one having: 1. An oral LD$o of 50 mg/kg or less. 2. A dermal LD$o of 200 mg/kg or less. 3. An inhalation LCM of 200 ppm or less of gas or vapor, or 2 mg/I or less of mist, fume or dust A toxic substance is one having: 1. An oral LDM between 50 and 500 mg/kg. 2. A dermal LDM between 200 and 1000 m&'kg. 3. An inhalation LCm between 200 ppm, 2,000 ppm of gas or vapors, or between 2 and 20 mg/1 of mist, fume or dust A corrosive substance is one which causes third degree bums and scar tissue from 4-hour skin contact to rabbits. A skin irritant is one which causes redness and swelling which does not persist and results in a numerical score of 5 out of 8 in greater than 50% of the animals tested. An eye irritant -- under 1910.1200 an eye irritant is one which at a minimum results in a grade 2 redness and/or swelling of the conjunctiva in at least 4 of 6 test animals when tested by the methods described in 16CFR 1500.42 or other appropriate techniques. The maximum attainable score using the Draize procedure is 110 (80 for cornea, 10 for iris, and 20 for conjunctiva). Use of a finite irritation index to assess a chemical's poten tial as an eye irritant, Le. x/110 cannot always be made because of inconsistencies between OSHA's definition and the standard Draize scoring technique. In some instances, an index as low as 2.7/110 is sufficient to warrant the eye irritation hazard statement while in other instances an index of 6/110 would not In cases of conflict such as this we will point them out on the MSDS. This rating system tends to classify many substances as irritants which would not be so classified under other regulations. Section 7 -- Physical and Chemical Properties To assess the physical hazards of our products, we per form appropriate tests using procedures recommended by the American Society for Testing and Materials (ASTM). Their procedure number is identified accordingly. The tests vary depending on the physical form and chemical nature of the product These physical or chemical test results are one of the factors reviewed in determining the need for or type of subsequent toxicological testing. The results are also used to identify hazardous physical proper ties which require labeling according to the Department of Transportation (DOT} regulations or for waste classification for disposal under the Resource Conservation and Recovery Act (RCRA). Section 8 - Fire and Explosion Information If the product exhibits flammable characteristics, informa tion is provided on the recommended method for fighting Tire. Unusual fire or explosion hazards are also given. OSHA 29CFR 1910.1200 and the Department of Transportation (DOT) consider products with flash points of less than 100 degrees Fahrenheit (F) as flammable materials. Chemicals with flash points between 100 degrees F and 200 degrees F are classified as combustible. On the other hand, the Resource Conservation and Recovery Act (RCRA) -- 40CFR 261 subpart C and D define those chemicals with flash points of 140 degrees F and below as ignitable. Section 9 -- Reactivity Information The potential for our products to aggressively react with other commonly found chemicals or to decompose represents a special hazard. Information is provided on possible interaction with other chemicals as well as reac tion of our products on commonly encountered materials of construction used for chemical and feeding handling systems. Section 10 - Personal Protective Equipment Handling chemicals such as attaching feed pumps or transferring chemicals from one container to another con stitutes the most likely exposure to operating personnel Recommendations are provided to protect personnel handling product spills, the type of ventilation needed, and the protective equipment (respirator, gloves, goggles, etc) that should be used This is one of the most important sections of the MSDS and the overall hazard communication program and should be well understood and put in practice by operating personnel. Section 11 -- Spill and Disposal information The disposal of wastes generated at a facility is one of the biggest problems facing industry. This section provides information on how to handle and clean up product spills and guidance for proper disposal should our product be considered a "waste" intended for disposal Section 12 -- Environmental Information This section provides information useful for assessing environmental impact of products or product constituents. When available and where applicable, information on parti tion coefficients. Biochemical Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) is presented. SAL 000007300 Results or acute aquatic bioassays are presented These bioassays, usually conducted on rainbow trout and bluegill sunfish are useful in assessing potential for adverse effects on aquatic vertebrates. Results are usually expressed as 36-hour LC*o values in milligrams per liter water (mg/I) or parts per million (ppm). The LCso is the concentration which is lethal to 50% of a group of fish exposed for the time period indicated It is synonymous with the term TL$o (the concentration which would result in the survival of 50% of a given test group). In many instances, 24 and 48 hours LCM values are given. When applicable, a 96hour, no-observed effect concentration is presented based upon lack of adverse effects and mortality. While we know of no published list which ascribes a des criptive rating to LC*o values, listed below are ratings we use as internal guidelines: 96-Hour LCm <1.0 ppm >I.0<5.0 >5<10.0 >10000 >1000 000 >1000 Rating Extremely toxic Highly toxic Toxic Moderately toxic Slightly toxic Essentially non-toxic Section 13 -- Transportation Information All hazardous chemicals are subject to regulation by the Department of Transportation (DOT}. Section 13 identifies the DOT proper shipping name and hazard class for the product, if any. This name will appear on all shipping documents. Many times the name will reflect the hazard and not necessarily the exact chemical name identified in Section 2. DOT hazard classifications are not always in agreement with those of OSHA. Section 14 -- Regulatory Information Today chemical products are regulated from the time they are manufactured, during use, should any environmental release occur, and when the material is finally ready for disposal. Section 14 provides information on the status of our products under the various federal and state regulations that may govern its manufacture, use or dis posal Specifically, under the OSHA Hazard Communica tion Rule 29CFR 1910.1200, the reason for classifying the product as being hazardous is provided. A "hazardous classification" is triggered by such things as 1) being combustible {flash point 100-200 degrees F), 2) being flammable (flash point less than 100 degrees F), 3) being a skin or an eye irritant, 4) presenting chronic health hazards such as liver damage, nerve damage, etc., 5) listed on the National Toxicology Program (NTP) Annual Report on Carcinogens or found to be a potential carcinogen by the International Agency for Research on Cancer (IARC), 6) or OSHA having an established workplace exposure limit or recommended limits. Threshold Limit Value (TLV) can be established by either OSHA |OSHA uses the term Per missible Exposure Limit (PEL)|, the American Conference of Governmental Industrial Hygienists (ACGIH) or by the chemical manufacturer. Three categories of TLV*s are recognized: 1) the Threshold Limit Value-Time Weighted Average (TLVTWA) - the time-weighted average concentration for 8 nor mal 8-hour workday and a 40-hour workweek, to which nearly all workers may be repeatedly exposed day after day, without adverse effect, 2} Threshold Limit ValueShort Term Exposure Limit (TLV-STEL) - the concentra tion to which workers can be exposed continuously for a short period of time without suffering from a) irritation, b) chronic or irreversible tissue damage, or c) narcosis of suf ficient degree to increase the likelihood of accidental iiyury, impair self-rescue or materially reduce work efficiency, and provided that the daily TLV-TWA is not exceeded. A STEL is defined as a 15-minute timeweighted average exposure which should not be exceeded at any time during a workday even if the 8-hour timeweighted average is within the TLV and 4) Threshold Limit Value-Ceiling (TLV-C) -- the concentration that should not be exceeded during any part of the working exposure. We frequently receive questions on the status of our products under other federal environmental laws. For this reason, when applicable, we are providing information on product status under major laws. 1. OSHA Hazard Communication 29CFR 1910.1200 -- These regulations have been discussed previously in this document 2. Other OSHA Regulations -- OSHA has established specific regulations for various chemicals. If these regulations apply to our products, the regulation and its applicability is identified. 3. CERCLAfSuperfund 40CFR 117.302 - This Law requires the reporting of spills of certain chemicals when the quantity spilled exceeds certain specified amounts. If Nalco's product contains one of the specified chemicals, the quantity of Nalco product, which must be spilled before the notification require- ' ment is "triggered," is calculated and the chemical is identified. 4. Toxic Substances Control Act (TSCA) -- Only substances that are included on the TSCA 8(b) Inven tory list, have been exempted, or have been cleared through a TSCA premanufacturing notification (PMN) can be legally manufactured and used in the U.S.A. As other sections of TSCA are implemented, other regulations may apply and will be addressed. sal. 00O73Oi N NALCO G S 58 2 5. If our product requires registration or govern mental clearances for use in intended applications (examples, pesticides under FIFRA, food additives under FDA, drinking water additives, fuel additives under EPA, use in meat and poultry plants under USDA) the status under the appropriate law is indicated 6. Resource Conservation and Recovery Act (RCKA) -- Our products as sold are not wastes and therefore not covered by this Act However, should someone decide to declare them a waste and discard them, then they must be evaluated to determine how RCRA might cover the waste. This information is provided on our products should they become "a waste." Please refer to com ments in Section 3 of this document regarding empty containers. 7. The Federal Clean Air and Water Acts 40CFR 60 and 61 and 40CFR 401.16 and 116 contain sections which specifically list chemicals for which these regulations apply. If Nalco products contain as ingredients any of the chemicals listed under these sections, they will be identified This will allow assess ment of their impact, if any, on discharge or emission permits. We also get similar questions regarding the status of our products under state regulations. State laws are becoming more common and it is difficult to cover all the specifics of each state Law in this limited space. However, many states' (such as Michigan) list those materials which they consider hazardous or use criteria for listing chemicals. Examples of these criteria are the established TL-V*s by OSHA or ACGIH or the presence of the chemical on a list such as the National Toxicology Program (NTP) Annual Report or International Agency for Research on Cancer (IARC) list for suspect carcinogens. We are identifying those chemicals for which there is an established TLV or that appear on the NTP or LARC lists. Section 15 -- Additional Information There may be additional information available than what is covered in other sections affecting health, safety and regulation of our product Section 15 provides space to present this additional information. Section 16 -- User's Responsibility This section is designed to serve as a reminder that the information provided is of use only if it is transmitted to the persons who handle the product or work in locations where hazardous chemicals are used or stored. The infor mation is developed based on recommended uses for our products. Other applications may warrant additional review. Section 17 -- Bibliography In addition to this MSDS section description, we may find it of value to know the source material used in evaluating our products other than specific toxicity tests or physical/ chemical tests we may have performed. The references below along with this document serve as a brief descrip tion of the hazard determination procedure we use in evaluating our products. Typical Bibliographic Sources Used Annual Report on Carcinogens, U.S. Department of Health and Human Services, Public Health Service, PB 33135855. 1983. Casarett and Doull's Toxicology, The Basic Science of Poisons. Doull, J., Klaassen, C. D., and Amdur, M. O., eds., Macmillian Publishing Company, Inc., N.Y., 2nd edition, 1980. Chemical Hazards of the Workplace, Proctor, N. H., and Hughes, J. P.. eds., J. P. Lipincott Company, N.Y., 1981. Dangerous Properties of Industrial Materials, Sax, N. Irving, ed.. Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Ceneva: World Health Organiza tion, International Agency for Research on Cancer, 1972-1977. Patty's Industrial Hygiene and Toxicology, Clayton, G. D.. Clayton, F E., eds., John Wiley and Sons, N.Y., 3rd edition. VoL 2 A-C, 1981. Registry of Toxic Effects of Chemical Substances, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, VoL 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). Threshold Limit Values for Chemical Substances and Physi cal Agents m the Workroom Environment with Intended Changes, American Conference of Governmental Industrial Hygienists, OH. SAL 000007302 n N ALGO SA<- 000007303 Bfgislred fiaijema'ks o* Nalcu Chemical Company "589 Naico Cnem-cai Company ah R.ghis Reserved pi'"imuS* i?89 Form 75S material safety data sheet G S33 3 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 87792 Page: 1 PRODUCT NAME: TRIETHYLENE GLYCOL - TECHNICAL Effective Date: 08/29/89 Date Printed: 01/26/90 MSDS:000271 1. INGREDIENTS: (X w/w, unless otherwise noted) Triethylene glycol CAS# 000112-27-6 99^ This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances not 'Hazardous1 per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: 5^5-9F; 286C VAP PRESS: < 1.0 mmHg 20C VAP DENSITY; 5.18 SOL. IN WATER: Completely miscible SP. GRAVITY: 1.1 @ 25/25C APPEARANCE: Colorless liquid. ODOR: Wild odor. 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: 350F; 177C METHOD USED: PMCC FLAMMABLE LIMITS LFL: 0.9% UFL: 9.2% EXTINGUISHING MEDIA: Water fog, alcohol resistant foam, C02, dry chemica1. FIRE EXPLOSION HAZARDS: Not available. FIRE-FIGHTING EQUIPMENT: Wear positive pressure self-contained (Continued on Page 2) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000007304 MATERIAL SAFETY DATA SHEET C S 33 3 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 87792 Page: 2 PRODUCT NAME: TRIETHYLENE GLYCOL - TECHNICAL Effective Date: 08/29/89 Date Printed: 01/26/90 MSDS:000271 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Will ignite in air at 700F. INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) Oxidizing materia 1. HAZARDOUS DECOMPOSITION PRODUCTS: Burning produces normal products of combustion, including carbon monoxide, carbon dioxide, and water. HAZARDOUS POLYMERIZATION: Will not occur. 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Small spills: Soak up with absorbent material and collect for disposal. Large spills: dike to prevent contamination of waterways, then pump into suitable containers for disposal. DISPOSAL METHOD: Burn in an approved incinerator in accordance with all local, state, and federal laws and regulations. 6. HEALTH HAZARD DATA: EYE: Essentially nonirritating to eyes. SKIN CONTACT: Prolonged or repeated exposure may cause skin irritation. May cause more severe response if skin is abraded (scratched or cut). SKIN ABSORPTION: A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful (Continued on Page 3) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000007305 material safety data sheet GS33 3 Dow Cheaical U.S.A.* Midland, MI 48674 Energency Phone: 517-636-4400 Product Code: 87792 Page: 3 PRODUCT NAME: TRIETHYLENE GLYCOL - TECHNICAL Effective Oate: 08/29/89 Oate Printed: 01/26/90 MSDS:000271 6. HEALTH HAZARD DATA: (CONTINUED) amounts. The dermal LD50 has not been determined. INGESTION: Single dose oral toxicity is low. The oral LD50 for rats is 16800-22060 mg/kg. INHALATION: No adverse effects are anticipated from inhalation. SYSTEMIC S OTHER EFFECTS: Based on available data* repeated exposures are not anticipated to cause any significant adverse effects. Did not cause cancer in long-term animal studies. Birth defects are unlikely. Exposures having no adverse effects on the mother should -have no effect on the fetus. In animal studies, has been shown not to interfere with reproduction. 7. FIRST AID: EYES: Irrigate immediately with water for at least five minutes. SKIN: Wash off in flowing water or shower. INGESTION: Induce vomiting if large amounts are ingested. Consult medical personnel. INHALATION: Remove to fresh air if effects occur. Call a physician. NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of the physician in response to the patient. 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE: AI HA WEEL is 10 mg/m3 for polyethylene glycols. VENTILATION: Provide general and/or local exhaust ventilation to (Continued on Page A) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 00007306 MATERIAL SAFETY DATA SHEET S33 3 Don Cheaical U.S.A.* Midland, MI 48674 Eaergency Phone: 517-636-4400 Product Code: 87792 Page: i* PRODUCT NAME: TRIETHYLENE GLYCOL - TECHNICAL Effective Date: 08/29/89 Date Printed: 01/26/90 MSDS:000271 8. HANDLING PRECAUTIONS: (CONTINUED) control airborne levels below the exposure guidelines. RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required for certain operations, use an approved air-purifying respirator. In misty atmospheres, use an approved mist respirator. SKIN PROTECTION: For brief contact, no precautions other than clean body-covering clothing should be needed. When prolonged or frequently repeated contact could occur, use protective clothing impervious to this material. Selection of specific items such as gloves, boots, apron or full-body suit will depend on operation. If hands are cut or scratched, use impervious gloves even for brief exposures. EYE PROTECTION: Use safety glasses. 9, ADDITIONAL INFORMATION: REGULATORY REQUIREMENTS: SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthori2ation Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Not to have met any hazard category SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice reasonable care to avoid exposure. Trace quantities of ethylene oxide (E0) may be present in this product. While these trace quantities could accumulate in headspace areas of storage and transport vessels, they are not (Continued on Page 5) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company SAL 000007307 MATERIAL SAFETY DATA SHEET $S 33 $ Dow Cheaical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product Code: 87792 Page: 5 PRODUCT NAME: TRIETHYLENE GLYCOL - TECHNICAL Effective Date: 08/29/89 Oate Printed: 01/26/90 SDS:000271 9. ADDITIONAL INFORMATION: (CONTINUED) expected to create a condition which will result in EO concentrations greater than 0.5 ppm (8 hour TWA) in the breathing 2one of the workplace for appropriate applications. OSHA has established a permissible exposure limit of 1.0 ppm 3 hr TWA for E0. (Code of Federal Regulations Part 1910.1047 of Title 29) MSDS STATUS: Revised Sections 6 and 8. (R) Indicates a Trademark of The Dow Chemical Company The information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult The Dow Chemical Company For Further Information. * An Operating Unit of The Dow Chemical Company SAL 000007308 COASTAL CHEMICAL COMPANY/ INC. P.C. BOX 32C ABEEVILLE/ LA 70511-C320 s a 3 *, v CONOCO/ INC. ATTN: SAFETY DIRECTOR P C BOX 4000 ATTN: PURCHASING DEPT PONCA CITY/ CK. 74603 2/23/90 E OUR INV. * 37099 DEAR CUSTOMER: THE ATTACHED MATERIAL SAFETY DATA SHEET FOR THE PRODUCT OUR RECORDS INDICATE THAT YOU HAVE PURCHASED OR MAY PURCHASE FROM COASTAL CHEMICAL COMPANY/ INC. HAS 3EEN CAREFULLY PREPARED IN AN EFFORT TO MEET THE WORKERS' PIGHT-TC-KNOW LAWS AND TO PROVIDE INFORMATION NECESSARY TO YOUR EMPLOYEE SAFETY TRAINING PROGRAM. PLEASE REVIEW ALL OF THE INFORMATION CN THIS SHEET WITH ALL INDIVIDUALS THAT WILL F0RESEEA5LY CO*E INTO CONTACT WITH THIS PRODUCT. IT SHOULD E RECOGNIZED THAT PERSONS AT OTHER LOCATIONS WHO MAY COME INTO CONTACT WITH THIS PRODUCT HAVE THE RIGHT-TO-KNOW1. THEREFORE/ IT IS VERY IMPORTANT THAT THIS INFORMATION REACH ALL INDIVIDUALS WHO WILL DIRECTLY OR INDIRECTLY COME INTO CONTACT WITH THIS PRODUCT/ INCLUDING YOUR CUSTOMERS. IT IS COASTAL CHEMICAL CO./ INC.'S POLICY TO CONSTANTLY REVIEW ITS LABELS FCfi COMPLETENESS AND COMPLIANCE WITH VARIOUS LAWS/ ORDINANCES/ RULES AND REGULATIONS. IF YOU REPACKAGE THIS PRODUCT/ YOU MUST PASS THIS INFORMATION ON TO YOUR CUSTOMERS AND THEIR EMPLOYEES. IF THE PRODUCT IS COMBUSTIBLE OR FLAMMABLE/ SPECIAL WARNING LABELS MUST BE AFFIXED TO THE CONTAINERS. YOU SHOULO ALSO ADVISE YOUR CUSTOMERS AND THEIR EMPLOYEES OF THE POTENTIAL HAZARDS CF THE EMPTY CONTAINERS. 'EMPTY' CONTAINERS ARE THOSE THAT CONTAINED PRODUCT AND HAVE NOT BEEN PROFESSIONALLY CLEANED AND RECONDITIONED. 'EMPTY' CONTAINERS SHOULD NOT 8E USED FOR ANY PURPOSE SINCE THEY MAY CONTAIN EXPLOSIVE VAPCRS. ALL CONTAINERS/ INCLUDING EMPTY CR PARTIALLY EMPTY CONTAINERS/ SHOULD 9E STORED IN A SECURE AREA AWAY FROM ALL HEAT/ SARK/ FLAME/ OR OTHER IGNITABLE SOURCE. IF YOU ARE NOT THE PERSON RESPONSIBLE FOR THE SAFE HANDLING OF THIS PRODUCT/ PLEASE FORWARD THIS INFORMATION TO THE APPROPRIATE INDIVIDUAL. THANKING YOU FOR YOUR BUSINESS/ WE REMAIN SINCERELY/ JIM DOYLE/ PRESIDENT PRODUCT: TFIETHYLENE GLYCOL SAL 000007309 r' GS44 9 Shell MATERIAL ?73? (a-#Sl 24 HOUR EMERGENCY ASSISTANCE SAFETY DATA SHEET MSDS NUMBER } 7,150-9 GENERAL MSDS ASSISTANCE PAGE 1 SHELL: 713-473-9461 ACUTE HEAl'H j FIRE O' !&* i CHEMTREC: 800-424-9300 i SHELL 713-241-4819 REACTIVITY ^ TA IfAST c HAZARD RATING HIGH 3 SLIGHT < EXTREME - A mCCE F. ATf 2 BE SAFE READ OUR PRODUCT SAPGTT INFORMATION . . ANO PASS IT ON For acute and chronic health effects refer to the discussion in Section SECTION I yproduct NEODENE(R ) 12 ALPHA OLEFIN NAME CHEMICAL ^ DODECENE-1 NAME r CFAMILY1* ^ LINEAR ALPHA OLEFIN SHELL CODE 3192 SECTION II-A NO. P NEODENE 12 ALPHA OLEFIN i CIO AND BELOW 2 C12 3 C14 AND ABOVE PRODUCT/1NGRED1 ENT COMPOSITION CAS NUMBER PERCENT MIXTURE , 872-05-9 1 12-41-4 64743-02-8 lOO <2 97 <2 SECTION II-B NO. ACUTE ORAL L050 P NONE ESTABLISHED ACUTE TOXICITY DATA ACUTE DERMAL LD50 ACUTE INHALATION LC50 SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT BASED ON ESSENTIALLY SIMILAR PRODUCT TESTING. PRODUCT IS MINIMALLY IRRITATING TO THE EYES. SKIN CONTACT 3ASED ON ESSENTIALLY SIMILAR PROOUCT TESTING. PRODUCT IS SLIGHTLY IRRITATING TO THE SKIN. PROLONGED OR REPEATED LIQUID CONTACT CAN RESULT IN DEFATTING ANO DRYING OF THE SKIN WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS. INHALATION THIS PRODUCT IS PRESUMED TO HAVE A LOW ORDER OF ACUTE INHALATION TOXICITY. INGESTION BASED ON ESSENTIALLY SIMILAR PRODUCT TESTING. PRODUCT IS SLIGHTLY TOXIC. BUT INGESTION MAY RESULT IN VOMITING; ASPIRATION (BREATHING) OF VOMITUS INTO THE LUNGS MUST BE AVOIDED AS EVEN SMALL QUANTITIES MAY RESULT IN ASPIRATION PNEUMONITIS. SAL 000007310 C S 44 9 r-ODUCT NAME: NEODENE(R) 12 ALPHA OLEFIN MSDS PAGE 7,150-8' 2 SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. ASPIRATION PNEUMONITIS MAY BE EVIDENCED BY COUGHING. LABORED BREATHING AND CYANOSIS (BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR. AGGRAVATED MEDICAL CONDITIONS PREEXISTING SKIN AND EYE DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV OCCUPATIONAL EXPOSURE LIMITS NO. OSHA PEL/TWA PEL/CEILING TLV/TWA ACGIH TLV/STEL P- SHELL INTERNAL STANDARD - 100 PPM OTHER SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH PLENTY OF WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. SKIN CONTACT REMOVE CONTAMINATED CLCTHING/SHOES AND WIPE WASHING WITH SOAP AND WATER. IF IRRITATION 1NT1L CLEANED. EXCESS FROM OCCURS, GET SKIN. FLUSH SKIN WITH MEDICAL ATTENTION. DO WATER. FOLLOW BY NOT RESUE CLOTHING INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEOICAL ATTENTION. INGESTION DO NOT INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY. KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS- GET MEDICAL ATTENTION.- NOTE TO PHYSICIAN IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED. EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS. GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. SECTION VI NONE IDENTIFIED. SUPPLEMENTAL HEALTH INFORMATION SAL 000007311 SECTION VII BOILING POINT: 401 -4 IS (DEG F) MELTING POINT: NOT AVAILABLE (DEG F) PHYSICAL DATA SPECIFIC GRAVITY: 0.764 (H201) SOLUBILITY: (IN WATER) SLIGHT VAPOR PRESSURE: 0. 155*75 OEG F (MM HG) VAPOR DENSITY: 5.8 (AIR-1) PRODUCT NAME: NEODENE(R) 12 ALPHA OLEFIN EVAPORATION RATE (N-BUTYL ACETATE * 1): appearance AND ODOR. COLORLESS LIQUID. MILD HYDROCARBON ODOR, G S449 MSOS PAGE 7,150- 3 SECTION VIII FLASH POINT AND METHOD: 168 DEG F SETAFLASH FIRE AND EXPLOSION HAZARDS FLAMMABLE LIMITS /% VOLUME IN AIR LOWER: N/AV UPPER: N/AV EXTINGUISHING MEDIA USE WATER FOG. FOAM, DRY CHEMICAL OF C02. AND CAN BE REIGNITED ON SURFACE WATER. DO NOT USE A DIRECT STREAM OF WATER. PROOUCT WILL FLOAT SPECIAL FIRE FIGHTING PROCEDURES ANO PRECAUTIONS CAUTION. COMBUSTIBLE. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS. GLOVES AND RUBBER BOOTS). INCLUDING A POSITIVE PRESSURE NIOSH APPROVEO SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. UNUSUAL FIRE AND EXPLOSION HAZARDS CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO DIRECT FLAME CONTACT SHOULD BE COOLED WITH LARGE QUANTITIES OF WATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE. SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID CONTACT WITH OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. PROTECTIVE CLOTHING AVOID CONTACT WITH EYES- WEAR SAFETY GLASSES OR GOGGLES AS REPEATED CONTACT WITH SKIN. WEAR CHEMICAL RESISTANT GLOVES MINIMIZE CONTACT. APPROPRIATE. AVOID PROLONGED OR AND OTHER CLOTHING AS REQUIRED TO ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. SECTION XI ENVIRONMENTAL PROTECTION SAL 0000073 12 SPILL OR LEAK PROCEDURES CAUTION. COMBUSTIBLE. SPILLED MATERIAL IS SLIPPERY. - LARGE SPILLS -* ELIMINATE POTENTIAL SOURCES OF IGNITION. WEAR APPROPRIATE RESPIRATOR AND OTHER PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY. SAND. OR OTHER SUITABLE MATERIAL: PLACE IN NON-LEAKING CONTAINERS AND SEAL TIGHTLY FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTION AS ABOVE. SMALL SPILLS ** TAKE UP WITH AN'ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. G S 44 9 PRODUCT NAME: NEODENE(R) 12 ALPHA OLEFIN USDS PAGE 7,150-9' 4 SECTION XII SPECIAL PRECAUTIONS KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS AND FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAV IGNITE EVEN LIQUID PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. EXTINGUISH PILOT LIGHTS. CIGARETTES AND TURN OFF OTHER SOURCES OF IGNITION PRIOR TO USE AND UNTIL ALL VAPORS ARE GONE. WASH WITH SOAP AND WATER BEFORE EATING. DRINKING. SMOKING OR USING TOILET FACILITIESCONTAMINATED CLOTHING BEFORE REUSE. LAUNDER SECTION XI22 TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: COMBUSTIBLE LIQUID D.O.T. PROPER SHIPPING NAME: PETROLEUM OIL. N.O.S. OTHER REQUIREMENTS: D.O.T. ID.# * NA 1270. GUIDE SHEET 27. ECTION XIV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III. SECTION 313, THE EDS' SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS SECTION XV SPECIAL NOTES SECTION XI - ENVIRONMENTAL PROTECTION HAS BEEN REVISED. THE INFORMATION IN THE "WASTE DISPOSAL" AND "ENVIRONMENT PROTECTION" HAS BEEN REMOVED AND INCLUDED IN THE ATTACHED ENVIRONMENTAL DATA SHEET. IN ACCORDANCE WITH SARA TITLE HI. SECTION 313, THE EDS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. CHANGE FROM PREVIOUS REVISION: FLASH POINT CHANGE FROM 168 DEG. F PMCC TO 16B DEG. F SETAFLASH. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO U$ AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:JULY 14. 1989 BE SAFE READ OUR PRODUCT SAFETY INFORMATION ...AND PASS IT ON (PRODUCT LIABILITY LAW REQUIRES IT) J. C. WILLETT SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210 SAL 000007313 CS449 Shell ENVIRONMENTAL DATA SHEET S7449 [-87) EDS NUMBER 7.150-2 PAGE 1 PRODUCT ^ NEOOENE(R) 12 ALPHA OLEFIN PRODUCT v CODE f 31921 SECTION I NO. PRODUCT/COMPOSITION COMPONENT P NEOOENE 12 ALPHA OLEFIN 1 CIO AND BELOW 2 C12 3 C 1 4 AND ABOVE CAS NUMBER MIXTURE 872-05-9 1 12-41-4 64743-02-6 PERCENT 100 <2 97 <2 SECTION II NO. EHS RQ (LBS) (-i) SARA TITLE III INFORMATION EHS TPQ (LBS) (-2) SEC 313 ( *3) 313 CATEGORY (-4) P 311/312 CATEGORIES ( "5 ) 1H-1, P-3 _ *1 REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE. SEC.302 *2 * THRESHOLD PLANNING QUANTITY. EXTREMELY HAZARDOUS SUBSTANCE. SEC 302 -3 * TOXIC CHEMICAL. SEC 313 4 * CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C). MUST 8E USED ON TOXIC RELEASE INVENTORY FORM 5 HAZARO CATEGORY FDR SARA SEC. 311/312 REPORTING HEALTH H-1 IMMEDIATE (ACUTE) HEALTH HAZARD H-2 * OElAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 FIRE HAZARD P-4 SUDDEN RELEASE OF PRESSURE HAZARD P-5 REACTIVE HAZARD SECTION III ENVIRONMENTAL RELEASE INFORMATION SECTION IV RCRA INFORMATION PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS. SAL 000007314 G S44 9 "RODUCT NAME: NEOOENE(R) 12 ALPHA OLEFIN EDS 7.150-2* PACE 2 THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:FEBRUARY 05, 1990 ................................ -.............. SHELL OIL COMPANY ENVIRONMENTAL AFFAIRS P. 0. BOX 4320 HOUSTON, TX 77210 FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL (713) 241-2252 FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461 CHEMTREC: (800) 424-9300 SAL 000007315 N NALCO MATERIAL SAFETY DATA SHEET IPRODUCT XRI-ACT 1800 INHIBITOR Emergency Telephone Number 6 S 58 2Medical (708) 920-1510 (24 hour*) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: TRI-ACT 1800 INHIBITOR DESCRIPTION: An aqueous solution of amines NFPA 704M/HMIS RATING: 3/3 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0* Insignificant 1-Slight 2=Moderate 3=High 4=Extrenie 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Cyclohexylamine Ethanolainine Methoxypropy1amine 108-91*8 141-43-5 5332-73-0 10-20 10-20 10-20 SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes burns to skin and eyes. Combustible. Do not get in eyes, on skin, or on clothing. Wear goggles and face shield and rubber gloves when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician at once. Remove to fresh air. Treat symptoms. Call a physician at once. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. PAGE 1 OF 9 NALCO CHEMICAL. COMPANY ONE NALCO CENTER AREA 700-305- 1 OOO SAL ^00O073l6 NAPERVILLE, ILLINOIS? 60563-1193 SHifftociq?? MATERIAL SAFETY DATA SHEET NALCO PRODUCTtri-act 1800 inhibitor Emergency Telephone Number Medical (708) 920-15t0 (24 hours) ( SECTION 4 FIRST AID INFORMATION ( CONTINUED ) CAUTION: If unconsciousr having trouble breathing or in convulsions, do not induce vomiting or give water. MOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTECS) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Corrosive to the skin, possibly resulting in third degree burns depending on the length of exposure and on the first aid action given. Can cause allergic contact dermatitis in susceptible individuals. Can be harmful or fatal. Can be corrosive to the mucous membranes and the lungs. Can cause an allergic reaction in susceptible individuals. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have been conducted on this product along with acute toxicity studies on the hazardous ingredient(s) in Section 2. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LDS0 = 1267 mg/kg 95% Confidence Limit - 1,047 to 1,532 mg/kg COMMENTS: Excessive salivation, squinting of the eyes, loss of muscular coordination, prostration and irregular breathing were observed. ACUTE DERMAL TOXICITY (ALBINO RABBITS): PAGE 2 OF 9 sal. 00q0 731 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-119B AREA 709-305- 1 OOO MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR G S 58 2Emergency Telephone Number Medical (708) 920-1510 (24 hour*) SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) LD5# = Greater than 2,000 mg/kg COMMENTS: Redness, swelling, and blanching of the skin were noted. Scab formation was due to the corrosive action of the product. However, no systemic signs of toxicity were observed. SKIN SENSITIZATION: Cyclohexylamine can cause sensitization in susceptible individuals. PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: Corrosive COMMENTS: Severe redness, swelling, and blistering of the conjunctiva were observed. Opacification of the cornea was also noted. Due to the extreme corosive action of the test material, no Draize index rating could be assigned. OTHER TOXICITY RESULTS: Cyclohexylamine. .A battery of tests including the Ames test, sister chromatid exchange, cell transformation, mouse lymphoma and rat hepatocyte/DNA repair provided inconclusive evidence of mutagenic activity. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: FLASH POINT: FORM: Liquid 8.2 lbs/gal. Completely 0.99 @ 77 Degrees F 12.6 pH (at 1%) 11.2 S cps 8 77 Degrees F 8 Degrees F 135 Degrees F (PMCC) ODOR: Amine ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 135 Degrees F (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. PAGE 3 OF 9 sal 00oor3i* NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 708-305- 1 OOO MATERIAL SAFETY DATA SHEET NALCQ PRODUCTTRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical(708) 920*1510(24 hours) SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: N-nitrosamines, many are cancer causing agents to laboratory animals, may be formed when certain amines are mixed with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide concentrations. Avoid contact with strong acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, CO,, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors or mists may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) PAGE 4 OF 9 SAL 000007319 NALCO CHEMICAL COMPANY ONE NALCO CENTER AREA 708-305- 1 OOO NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Alumber Medical (708) 920-1510 SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14, For large indoor spills, evacuate employees and ventilate area. responsible for control and recovery should wear the protective equipment specified in Section 10. Those DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001 & D002. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - CYCLQHEXYLAMINE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. PAGE 5 OF 9 SAL ooq73zo NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 AREA 708-305- n OOO MATERIAL SAFETY DATA SHEET NALCO PRODUCT tri-act isoo inhibitor Emergency Telephone Number Medical (708) 920-1510 (24 hours) ( SECTION 14 REGULATORY INFORMATION Cyclohexylamine - Corrosive, combustible Ethanolamine - Corrosive, combustible Methoxypropylamine * Corrosive, combustible ( CONTINUED ) Cyclohexylamine * TWA 10 ppm, 41 mg/m3 ACGIH/TLV Ethanolamine = TWA 3 ppm, STEL 6 ppm ACGIH/TLV 7.5 mg/m3 15 mg/m3 ACGIH/TLV Cyclohexylamine - TWA 10 ppm, 40 mg/m3 0SHA/PEL Ethanolamine = TWA 3 ppm, STEL 6 ppm 0SRA/PEL 8 mg/m3 15 mg/m3 OSHA/PEL Methoxypropylamine = TWA 10 ppm, 20 ppm (15 minute exposure) TLV Weel Guidelines CERCLA/SUPERFUND, 40 CFR 117, 302: notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product contains cyclohexylamine, which is listed in Appendix A and B as an Extremely Hazardous Substance. The statuatory threshold planning quantity for this substance is 10,000 pounds. A release of 10 pounds of product will require a notification to your State Emergency Response Commission. You may also be required to notify the NATIONAL RESPONSE CENTER - See CERCLA/SUPERFUND, above. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local PAGE 6 OF 9 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINl-._ 60563-1190 AREA 708-305- 1 OOO MATERIAL SAFETY DATA SHEET MALCO PRODUCT tri-act 1800 inhibitor Emergency Telephone Number Medical (708) 920-1510 (24 hours) as 58 2 SECTION 14 REGULATORY INFORMATION fire department is required after October 17, 1987 if you have: - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. ( CONTINUED ) SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Ethanolamine - Section 111 Cyclohexylamine - Section 111 STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Cyclohexylamine 108-91-8 PAGE 7 OF 9 SAL 000007322 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1-100 AREA 700-305-1 OOO NALCQ MATERIAL SAFETY DATA SHEET PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (706) 920-1510 (24 hours) ( SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Ethanolamine Methoxypropylamine Water 141-43-5 5332-73-0 7732-18-5 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U-S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND D0ULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D,, and Admur, M. 0., eds., Macmillian Publishing Company, Inc. N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H,, and Hughes, J. P,, eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed.. Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. I ARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and 5ons, N. Y., 3rd edition, Vol. 2 A-C, 1981, REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department Of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 PAGE 8 OF 9 SAL 000007323 n NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 AREA 70B-305- 1 OOO MATERIAL SAFETY DATA SHEET MALCO PRODUCT tri-act isoo inhibitor Emergency Telephone Number Medical (708) 920-1510 (24 hour*) G &S8 2 SECTION 17 BIBLIOGRAPHY ( CONTINUED ) supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORXROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 04/03/90 DATE PRINTED: 04/07/90 PAGE 9 OF 9 SAL 000007324 MALCO CHEMICAL COMPANY ONE MALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 700-305-1000 G S58 2 NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (708) 920*1510 (24 hours) SAL 000007325 NALCO CHEMICAL COMPANY OfME NALCO CENTER NAPERVILLE. ILLINOIS 80563-1190 AREA -70S-305- 1 OOO -G SO 6 4 Bti Laboratories, Inc. 4636 Sontrton Road, Trevoee, Pa. 1904? Beti Material Safety Data Sheet 24 Hour Emergency Telephone (Health or Accident) 815/355-3300 IACENT : HARDNESS INDICATOR CODE 290 EFFECTIVE DATE 05-18-89 PRINTED: 04/06/90 REVISIONS TO SECTIONS* 3 EAGENT APPLICATION : FIELO TEST REAGENT --------SECTION 1------------------------- HAZARDOUS INGREDIENTS---------------------------------- NFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC EAGENT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE ISTED. REFER TO SECTION 4 (PACE 8) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE ND CHRONIC HAZARDS OF THIS FORMULATION. THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA REGULATIONS. SECTION 2------------------------ TYPICAL PHYSICAL DATA PH: NO DATA FL.PT.(DEG.F ) : NA VAPOR PRESSURE<mmHG): NA VISC Cps7OF: NA EVAP.RATE: NA WATER*1 PHYSICAL STATE: POWDER ODOR: NONE SP.GR.(70F)OR DENSITY: NA VAPOR DENSITY< AIR*1 > : NA XSOLUBILITY(WATER): 100 APPEARANCE: BLACK FREEZE POINT(DEC.F>: NA SECTION 3------------------------REACTIVITY DATA *iBLE. BETZ TANK CLEAN-OUT CATEGORY 'A' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. 00073,6 CS06 4 MATERIAL SAFETY DATA SHEET (PACE OF 3) *CENT: HARDNESS INDICATOR -SECTION A------------------------ HEALTH HAZARD EFFECTS------------------------------------- UTE SKIN EFFECTS ** PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN UTE EYE EFFECTS *** MODERATELY IRRITATING TO THE EYES UTE RESPIRATORY EFFECTS *** DUSTS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT TRONIC EFFECTS OF OVEREXPOSURE*** NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS. IDI CAL CONDITIONS AGGRAVATED *** not KNOUN fMPTOMS OF EXPOSURE *** MAY CAUSE EYE,SKIN,AND/OR RESPIRATORY TRACT IRRITATION. --------SECTION S--------------------------- FIRST AID INSTRUCTIONS-------------------------------------------------KIN CONTACT*** REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN YE CONTACT*** MMEDIATELY FLUSH EYES WITH WATER FOR IS MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT NHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA.APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. NGESTI ON* ** ENERAL-DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM PECIFIC- DILUTE CONTENTS OF STOMACH.INDUCE VOMITING BY ONE OF THE STANDARD METHODS.IMMEDIATELY CONTACT A PHYSICIAN ----------SECTION 6-------------------------SPILL, DISPOSAL AND FIRE INSTRUCTIONS-------------------3PILL INSTRUCTIONS*** iENERAL-VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.SWEEP JP AND PLACE IN WASTE DISPOSAL CONTAINER. SPECIFIC- FLUSH AREA WITH UATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** GENERAL-WATER CONTAMINATED UITH THIS REAGENT MAY BE SENT TO A SANITARY SEWER,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT REAGENT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 000007327 6 6064 MATERIAL SAFETY DATA SHEET (PACE 3 OF 3) EAGENT: HARDNESS INDICATOR -------- SECTION 7------------------------- SPECIAL PROTECTIVE EQUIPMENT--------------------------------------SE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE ESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS ENTILATION PROTECTION*** ADEQUATE VENTILATION ECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT REAGENT EXPOSURE IS LIKELY, USE A RESPIRATOR UITH DUST/MIST FILTERS. ECOMMENDED SKIN PROTECTION*** RUBBER GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY ECOMMENDED EYE PROTECTION*** AIRTIGHT CHEMICAL GOGGLES --------- SECTION 8------------------------- STORAGE AND HANDLING PRECAUTIONS-----------------------------TORACE INSTRUCTIONS*** KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP DRY HANDLING INSTRUCTIONS*** , NORMAL CHEMICAL HANDLING t.\ ********%*******************************%************************* HIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD 1AROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) <****%****************************************************************** APPENDIX: REGULATORY INFORMATION rHE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. *NY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: NOT APPLICABLE ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS UASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE ...DOT HAZARD/UN#/ER GUIDE# IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 302 CHEMICALS. NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: PRODUCT IS NONHAZARDOUS UNDER SECTION 311/312 ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 1 : FIRE - 0 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 00007328 3143 04/06/90 Betz Industrial Division 4636 Sojfrton Road Trevose, Pa. 19047 CONOCO INC. REFINERY UAREHOUSE 1000 SOUTH PINE PONCA CITY OK 74603 Attention-- Plant Manager/ Safety Officer/Industrial Hygianist GS06 4 Ra: Hatarial Safety Data Sheets (USDS): Osha Hazard Communication Standard Dear Oust omer- Thank you for your recent order of a Betz Reagent(s). The OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) requires that all manufacturers/suppl i ers of chemicals, send material safety data sheets (MSDS) to their customers with or prior to the receipt of those chemicals by the user. In compliance with this standard you will find enclosed, MSDS for the Betz reagent(s) you recently ordered. The standard requires that personnel who may come into contact with these products be appraised of any hazards that may be associated with these reagent(s), therefore please route this information to the correct areas within your organization. Should you have and questions about the contents of these MSDS, contact Hal Hersh at 215-953-2442. please Betz is fully committed to the stewardship of its many product lines and to the full disclosure of any health or environmental hazards they may contain. The protection of health and safety in the workplace and surrounding community, and the protection of the environment in which we all live and work requires dedication and team effort. Betz appreciates being part of your team and will ever strive to be equal to the trust you have placed in us. Very Truly Yours, F. S . Spoerle Vice President Engineering Betz Industrial Division 00Oo? 3^9 4 / \ MATERIAL SAFETY DATA SHEET EMERGENCY PHONE (504) 344-7147g j g g PRODUCT IDENTIFICATION TRADE NAME: CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: CAS NO.: "ETHYL** MMT" Methylcyclopentadienyl Manganese Tricarbonyl Organometallic CpH^Hn 12108-13-3 78,0,1 SUMMARY OF HAZARDS COMBUSTIBLE. Toxic by inhalation, skin absorption and ingestion. See "Chronic Effects of Overexposure". See "Other Health Effects". HAZARDOUS COMPONENTS NOTE* CAS MO. EXPOSURE LIMIT Methylcyclopentadienyl Manganese Tricarbonyl NL 12108-13-3 0.2 mg/K3 (as Mn) TUAfl (skin) (ACCIH). NOTE: Carcinogenicity listing of components at concentrations greater than or equal to 0.1% indicated by: 3 = NTP; # = IARC; = OSKA; Other; NL = Not Listed. 4MOTE: Carcinogenicity listing indicated by: SNTP: 0=IARC: &=OSHA,- *=other; NL=Not Listed._____________ CHEMICAL & PHYSICAL PROPERTIES APPEARANCE/00OR: Orange l iquid/pleasant herbaceous odor. BOILING POINT: * 232*C/450F. VAPOR PRESSURE im Hg (3 20'C/68*F): SOLUBILITY IN UATER: 0.05 TO ppm O 20C/68f). SPECIFIC GRAVIU: 1.38 SAL 0007330 ('O -? GS 168 # TMDC NAME: -ETHYL" HMT FIRE 6 EXPLOSION HAZARDS FLASH POINT (METHOO): FLAMMABLE LIMITS: EXTINGUISHING MEDIA: HAZARDOUS THERMAL DECOMPOSITION PROOUCTS: SPECIAL EIRE FIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION HAZARDS: 83CC/182*F (TCC). Hot established. Dry chemical, water spray (fog), foam or carbon dioxide. Include oxides of carbon and manganese Do not breathe smoke or vapors. None known. PRACTIVITY DATA STABILITY: CONDITIONS TO AV010: MATERIALS TO AVOID: HAZARDOUS POLYMERIZATION: Stable. Exposure to extreme heat or open flame. None known. Will not occur. HEALTH HAZARDS INHALATION: SKIN ABSORPTION: INGESTION: CHRONIC EFFECTS OF OVEREXPOSURE2 OTHER HEALTH EFFECTS: Expected to be toxic. CJ Expected to be toxic. Expected to be toxic. A 90-day chronic inhalation study of MHT indicated that 3 mg/M^ of MKT showed detectable effects in nice. The tungs appear to be the organ most sensitive to MHT both acutely and chronically. Metabolism studies of MMT indicate it is excreted through the urine. Oxidation of the methyl group to the alcohol or acid reduces the toxicity of the compound and aids in its excretion. MMT may cause central nervous system stimulation. HEALTH HAZARDS - Continued TOXICITY DATA: TRADE NAME: "ETHYL* HUT* GS16 v' ORAL LD5q (rat) = 58 mg/kg. DERMAL U>5q <rabbit> = 618 mg/kg. INHALATION LCjq 220*247 g/N3/1h. EMERGENCY FIRST AID PROCEDURES INHALATION: EYE CONTACT: SKIN CONTACT: INGESTION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth*to*mouth. If breathing is difficult, give oxygen. Get medical attention. Begin iamediate eye irrigation with cool water. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Destroy contaminated shoes. Ircfcjce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. Get medical attention. EXPOSURE CONTROL INFORMATION EXPOSURE LIMITS: EYE PROTECTION: PROTECTIVE GLOVES: RESPIRATORY PROTECTION: LOCAL VENTILATION: MECHANICAL VENTILATION: OTHER: See "Hazardous Components" section. Chemical goggles. Resistant to chemical penetration. N10SH approved organic vapor respirator. In emergency situations, NIOSH approved self contained breathing apparatus (SCBA). At source of vapors. R ec cmnerided. If skin contact or contamination of clothing is likely, protective clothing should be worn. SAL 0000733^ 4S168 t TRADE NAME: `ETHYL* HMT ENVIRONMENTAL PROTECTION SPILLS OR LEAKS: Eliminate sources of ignition. Ventilate area. Contain any spills with dikes or absorbents to prevent Migration and entry into sewers or streams. Take up small spills with dry chemical absorbent. Large spills may be taken up with ptirp or vacuua and finished off with dry chemical absorbent. Hay require excavation of contaminated soil. DISPOSAL ME1HOOS: Under the CERCLA/RCRA regulations in effect December 29, 1986, this material is not regulated as a hazardous waste or material. Therefore, it may be disposed of as an industrial waste in a manner acceptable to good waste management practice and in compliance with applicable local, state and federal regulations. MHT liquids should be used in product blending or disposed, preferably by incineration, in an approved facility. Spill residues may be disposed of in a secure chemical landfill. STORAGE REQUIREMENT: Store in well-ventilated, cool, dry area. Close container when not in use. ADDITIONAL PRECAUTIONS OR COMMENTS For information on the disposal of contaminated soil, contact your local Ethyl representative. All containers and equipment that have been in contact with MHT should be decontaminated by rinsing with a solvent such as kerosene, diesel fuel or tight fuel oil and followed by thorough washings with soap and water. All rinsate should be contained, recovered and disposed of as hazardous waste. If absorbent material (e.g. wood) becomes soaked with HMT, it should be removed and disposed of as hazardous waste. REVISED: 09/22/88 SUPERCEDES: 08/06/87 MSOS prepared by: Ethyl Corporation, Health and Environment Department FOR ADDITIONAL NON-EMERGENCY MSOS INFORMATION, CONTACT: ETHYL CORPORATION HEALTH t ENVIRONMENT DEPARTMENT 451 FLORIDA STREET BATON ROUGE, LA 70601 (504) 388-7717 FOR ALL OTHER NON-EMERGENCY INFORMATION. CONTACT YOUR LOCAL ETHYL SALES REPRESENTATIVE. THIS MATERIAL SAFETY DATA SHEET CONTAINS AT LEAST THE INFORMATION REQUIRED BY THE FEDERAL OSHA HAZARD COMMUNICATION RULE, COMM 29 CFR 1910.1200 (g) (2). r SAL 000007333 GS168 TRADE NAME: ... MMT ADDENDUM TO MSDS DATED: 1/1/89 MSDS ADDENDUM Regulatory Information SARA Title III, Section 313 This sheet has been prepared as a supplement to the Ethyl Corporation Material Safety Data Sheet. According to 40 CFR, Part 372, Subpart C, it must remain with the MSDS and all copies thereof. DO NOT DETACH! This product contains the following tox'ic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:' COMPONENT CAS NUMBER PERCENTAGE* 2 Methylcyclopentadienyl manganese tcicarbonyl 12108-13-3 100 2 319 E sal 0000?33i EXPLANATION OF MATERIAL SAFETY DATA SHEET TERMINOLOGY ^ G S16 8 - PRODUCT IDENTIFICATION ADE NAME AND SYNONYMS The name under which the product is sold and common synonyms. EM!CAL NAME AND FORMULA Chemical descriptive name and the chemical formula. \$ NO. Chemical Abstract Service Registry number which identifies the product. Peak - The maximum concentration and duration of exposure allowable above the ceiling concentration for an 8-hour shfft. ACCIH - American Conference of Governmental Industrial Hygienists. OSHA - Occupational Safety and Health Administration. NIOSH - National Institute of Occu pational Safety and Health. JMMARY OF HAZARDS CARCINOGENICITY LISTING Emphasizes major hazard(s) associ ated with the product. Further details are provided in subsequent sections. COMPONENTS DNENT NAME Chemical, generic, or proprietary that identifies the product or \ .lonents of a mixture. Inclusion of a component is not necessarily based on hazard criteria, Indicates whether a component is thought to be a cancer hazard based on human experience and animal data. NTP - National Toxicology Program. IARC - International Agency for Research on Cancer. Other - Hay include preliminary data or studies not yet evaluated by the major agencies. Also includes ACGIH and NIOSH listings. :XPOSURE LIMIT The airborne concentration at which most workers can be exposed without any expected adverse effects. Source be Ethyl guideline, ACC1H TLV (Threshold Limit Value), or OSHA PEL (Permissible Exposure Limit). TYPES OF EXPOSURE LIMITS TWA_ - the time-weighted average concentration for a norma) 8-hour workday and a AO-hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect. STEL (Short-Term Exposure Limit) s 15 minute time-weighted average exposure which should not be exceed ed at any time during a workday even the 8-hour time-weighted average - within the TLV. CHEMICAL AND PHYSICAL PROPERTIES APPEARANCE/ODOR Description of material at normal temperature and pressure that may be useful in identifying the presence of the product. BOILING POINT The temperature at which the vapor pressure of the liquid is equal to the pressure of the atmosphere. MELTING POINT (FREEZINC POINT) Temperature at which a substance changes from the solid to liquid state. VAPOR PRESSURE The pressure exerted at any temper ature by a vapor existing in equi librium with its liquid or solid phase. CEILING - the concentration that should not be exceeded during any part of the working exposure. SOLUBILITY IN WATER The amount of the product, by weight, that will dissolve in a given weight of water at a specified temper ature. Negligible $1ight Moderate Appreciable Complete grams/100 H,Q -c 0.1 0.1 - 1.0 1 - 10 10 Soluble in all proportions SPECIFIC GRAVITY Ratio of the weight of a voltane of the product to the weight of an equal volume of water (1iquids/solids) or air(gases). EVAPORATION RATE Ratio of the rate of vaporiza tion of the product to the rate of a known material. PERCENT VOLATILES The percentage of the product (liquid or solid) that will evaporate at ambient tempera ture. POUR POINT The lowest temperature at which a liquid will flow when the container is inverted. VISCOSITY A measure of flow characteris tics of a liquid, expressed in units called Centistokes (cSt). FIRE AND EXPLOSION HAZARDS FLASH POINT (CLOSED CUP METHOO) Lowest temperature at which the product will give off enough vapor to ignite. FLAMMABLE LIMITS Range of vapor concentration (percent by volume in air) which will burn or explode in the presence of spark or flame. LEL is the lower explosive limit and UEL is the upper explosive limit. EXTINGUISHING MEDIA The fire fighting agents which are recommended for use. 000?335 tZAROOUS THERMAL DECOMPOSITION PRODUCTS Known hazardous products resulting from heating or burning the compound. 'ECIAL FIREFICHTINC PROCEDURES General firefighting procedures of chemical fires are not described, but special procedures are given, if required. HUSUAL FIRE AND EXPLOSION HAZARDS Hazards not covered by other sec tions of the MSDS pertaining to chemical reactions in the presence of heat and/or fire. REACTIVITY DATA stability Indicates the susceptibility of the product to dangerous decomposition. CONTITIONS AND MATERIALS TO AVOID Cives the conditions and materials that may cause undesirable reactions r instability of the product. HAZARDOUS DECOMPOSITION PRODUCTS Describes the hazardous materials produced from a chemical reaction. HAZARDOUS POLYMERIZATION Indicates the tendency of the pro duct's molecules to combine in a violent reaction. HEALTH HAZARDS Gives the immediate effects of over exposure to the product by skin or eye contact, breathing vapors or dust, and ingestion. Common symptoms which may occur from exposure to the product are given. CHRONIC EFFECTS Refers to the effects thay may occur after repeated or prolonged overexposure to the product. OTHER HEALTH EFFECTS Includes medical conditions which may be aggravated by exposure to the product. TOXICITY Gives numerical results from animal tests on the product. LD or LC is the dose level that kills half of the animals tested. EMERGENCY FIRST AID Gives emergency and first aid instructions for treating over exposure by inhalation, ingestfon, and skin and eye contact. NOTE TO PHYSICIAN Hay give any contraindicated treatment for a licensed health care professional to conduct. EXPOSURE CONTROL INFORMATION EYE PROTECTION Specification of eyes or face protection beyond normal use of safety glasses. PROTECTIVE CLOVES Indicates the need for protec tive gloves when skin contact may occur. RESPIRATORY PROTECTION Specification of the type of respirator recommended for use during routine or emergency situations. VENTILATION Specification of the type (local/general) of ventilation recommended to capture contam inants or prevent the build-up of hazardous atmospheres. OTHER Specification of other recom mended personal protective equipment based on type and degree of hazard. ENVIRONMENTAL PROTECTION SPILLS ANO LEAKS Indicates special precautions for clean-up of spills and leaks and preparation of chemical for disposal. DISPOSAL METHOD Tells the EPA classification of the product as well as the pro per disposal procedure. EPA Environmental Protection Agency RQ Reportable Quantity - The amount of the product or one of its components that, when spil led, must be reported to the EPA and possibly other regula tory agencies. ^ RCRA - Resource Conservation and Recovery Act. CERCLA - Comprehensive Environ mental Response, Compensation and Liability Act. STORAGE REQUIREMENTS Any unusual requirements or precautions for storange of the product. ADDITIONAL PRECAUTIONS OR COMMENTS States or re-emphasizes any special precautions or handling requirements. .Ithough the information and recommendations set forth herein (hereinafter ''Information") are presented in good faith and believed to be correct as of the date hereof. Ethyl Corporation mikes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its safety and suitability for their purposes prior to use. In no event will Ethyl Corporation be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. NO REPRESf TI0N5 OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY Oih... NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. SAL 000007336 MATERIAL SAFETY DATA SHEET MALCO PRODUCT NALCO 5151 CORROSION INHIBITOI G S 2 3 QC/nergency Telephone Number ^ Medical (708) 920-1510(24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5151 CORROSION INHIBITOR DESCRIPTION: An aqueous solution of alkyl primary amine and alkanolamine compounds * * NFPA 704M/HMIS RATING: 3/3 HEALTH l/l FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3-High 4=Extreme 0 OTHER* * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Methoxypropylamine Monoethanolamine 5332-73-0 141-43-5 10-20 40+ SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes burns to skin and eyes. Do not get in eyes, on skin, or on clothing. Wear goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * * * * * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. PAGE 1 OF 9 000007337 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 706-305- 1 OOO G S 23 6 NALCO MATERIAL SAFETY DATA SHEET*' PRODUCT NALCO S151 CORROSION INHIBITOl Emergency Telephone Number Medical (708) 920-1510 (24 hour*) SECTION 4 FIRST AID INFORMATION ( CONTINUED ) NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Corrosive to skin with possible permanent damage depending on length of exposure. Can cause allergic contact dermatitis in susceptible individuals. Can be harmful or fatal. Can be corrosive to the mucous membranes and the lungs. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): Methoxypropylamine LD* = 750 mg/kg Monoethanolamine LDSC - 2,100 mg/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): Methoxypropylamine LDSff = 2,600 mg/kg Monoethanolamine LDS0 - 1,000 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 6.6/8.0 Corrosive - Methoxypropylamine PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: 104/110.0 Extremely irritating - Methoxypropylamine SKIN SENSITIZATION: Skin sensitization expected. PAGE 2 OF 9 s4{. NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINu^ 60563-1198 a qp a 7nq^ns. i nnn N IMALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5151 CORROSION INHIBITol Emergency Telephone Number Medical(708) 930-1510(24 hours) G S 23 6 SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) OTHER TOXICITY RESULTS: Methoxypropylamine. Bacterial mutagenicity bioassay (Ames) negative. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: POUR POINT: BOILING POINT: FLASH POINT: FORM: Liquid 8.5 Ibs/gal. Completely I.02 @ 60 Degrees F II.4 42 SUS ? 100 Degrees F Less than -30 Degrees F Greater than 200 Degrees F @ 760 mm Hg None ODOR: Amine ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-97 ASTM D-86 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: Ammonia, CO, C0a may be evolved under fire conditions. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: N-nitrosamines, many are cancer causing agents to laboratory animals, may be formed when certain amines are mixed with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide concentrations. FEEDING EQUIPMENT: Do not use with copper, brass, aluminum or bronze, rubber, neoprene, polyurethane, Buna-N or ethylene propylene. Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. PAGE 3 OF 9 007339 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 700-305- 1 OOO v U A* V SJ N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5151 CORROSION INHIBITO Emergency Telephone Number Medical (708) 920*1510 (24 hours) r SECTION 9 REACTIVITY INFORMATION ( CONTINUED ) Avoid contact with strong acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, CO,, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. PAGE 4 OF 9 SAL 000007340 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 iflPA 7nR.^ns.i nnn N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5151 CORROSION XNHIBITol Emergency Telephone Number Medical (706) 920-1510 (24 houre) 6S*3 6 SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) For large indoor spills, evacuate employees and ventilate area. responsible for control and recovery should wear the protective equipment specified in Section 10. Those Xeep the spill away from heat, sparks, flames and welding operations. Ventilate area and evacuate employees from exposure if the airborne concentration exceeds the TLV. Refer to Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be incinerated in accordance with local, state and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - ORGANIC AMINE COMPOUND * * * SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. * FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Methoxypropylamine - Corrosive, sensitizer Monoethanolamine - Corrosive Monoethanolamine = TWA 3 ppm, STEL 6 ppm ACGIH/TLV * * * * * * * PAGE 5 OF 9 SAL 000007341 NALCO CHEMICAL COMPANY OME NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 AREA 708-305- 1 OOO G S236 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5151 CORROSION INHIBITOI Emergency Telephone Number Medical (708) 920-1510 (24 hour*) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) 8 mg/m3, 15 mg/m3 ACGIH/TLV Monoethanolamine * TWA 3 ppm, STEL 6 ppm OSHA/PEL 8 mg/m3, 15 mg/m3 OSHA/PEL Methoxypropylamine * TWA 10 ppm, STEL 20 ppm Workplace Environmental Exposure Limit (WEED CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORI2ATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: 5ECTI0N 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard -- Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). PAGE 6 OF 9 SAL 000007342 NALCO CHEMICAL. COMPANY ONE NALCO CENTER NAREHVILLE. ILLINOIS 60563-1 1GB MATERIAL SAFETY DATA SHEET IMALCO PRODUCT NALCO 5151 CORROSION INHIBITol Cmerge/icy Telephone Number Medical (706) 920-1510 (24 hours) G S 23 6 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Monoethanolamine - Section 111 STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Methoxypropylamine Monoethanolamine Water 5332-73-0 141-43-5 7732-18-5 INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # % Concentration Range Methoxypropylamine Monoethanolamine 5332-73-0 141-43-5 10-20 40+ PAGE 7 OF 9 SAL 000007343 NALCO CHEMICAL COMPANY OKIE NALCO CENTER NAPERVILLE. ILLINOIS 6OS63-1190 AREA "700-305- 1 OOO &S236 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 51S1 CORROSION INHIBITOI Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OP POISONS, Doull, J., Klaassen, C. D.r and Admur, M. 0., eds., Macraillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P.f eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE PAGE 8 OF 9 ^ 0007,,,. ______ ____ NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS oJ563-119B /-OFa 7HR^ns-1 nnn MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5151 CORROSION INHIBITol Emergency Telephone Number Medical (706) 920-1510 (24 hours) 6823 6 SECTION 17 BIBLIOGRAPHY ( CONTINUED ) WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 04/18/90 DATE PRINTED: 04/28/90 PAGE 9 OF 9 SAL 000007345 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 700-305- 1 OOO