Document Ya0KmEkQoYyRERMrj86zw76n

S.Vt-32-M^ (REV. 4-79) Shell Oil Company Shell Chemical Company Interoffice Memorandum DECEMBER 9, 1982 FROM: SENIOR INDUSTRIAL HYGIENIST DEER PARK MANUFACTURING COMPLEX TO: ALL MANAGERS SUBJECT: DPMC EXPOSURE GUIDELINES AND MINIMUM RESPIRATOR USE REQUIREMENTS Attached for your future reference is a guideline outlining the minimum respiratory protection to be used for selected chemical substances. Also included is information pertaining to the current permissible exposure limit, known primary toxicity effects, reported odor threshold, and protective clothing requirements, etc. The introductory page included offers additional information on this subject. It is recommended that current protective equipment and clothing procedures be reviewed for consistency with these guidelines. It is suggested that this document be retained with the departmental material safety data sheet book. Please let me know if there are any questions or comments concerning this guideline. It is anticipated that this guideline will be updated on an annual basis. Any suggested additions (or corrections) to this listing should be identified for the Industrial Hygiene group. P. J. Snyder PJS/mh cc: PJS Chron LAM 000371 DPMC-16083 SCVJ CO 5 5 |zLO O slJ> <D c5$>5S5 - ^ 5|S^ |recc CO CM I o CT C a E co to a; c qj r CT > 4-> (/) 3 "O C a* .c QJ 44 QJ CM E O O * o X <n QJ 44 co u c c 44 Q. tu (ft qj *D O) 5 o o <4- 0) o 4-> s- qj .o E 3 > .O "O at >> QJ in * T5 ir- a> 0) 4-> f- 3 +- Q. E QJ O Xu 4-> QJ V*) X44 O Xo m +J c X -rO r- TJ x a; *b ft o QJ H- 0) a qj f-- m 0> m u O o> 0) c _ CO QJ r- a< g JO O) >>>, 5 u O' ra- j4-> oj c! 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O JQDJ >QJ a> D XJ c *r- QJ c x: 44 oin 5o QJ QJ 44 X? in 3 QJ E X> s- C f-- > C L. lO 44 U C oj <n QJ QJ "O J= o -- u QJ t-- E Q. ro re T3 sz re 4J T3 S- QJ zz o -* rd 4-- O OO C o re C S- o CM in *-- O xr h* 25 LU JO a. ro 0+4 v. zc oo L. O -< f- u a> U in -r- r I-- +4 -- ro QJ s o S- O re QJ O CL E x> o o rO QJ C S+> 3 C3 c z1-- to-- m O O 3, *c^ cr QJ 3 s. oc U in <c o ro 1- -M ^2 *-,a_ UJ c CL o ou s- E 0) ro 4- U CM ro re- in 13 00 a\ 0) ro Q. K Jt + DPMC-16084 LAM 000372 th e re is n o t a common a b b re v ia tio n , e n te r a re a so n a b le a b b re v ia tio n (see a tta c h e d te n le t t e r s or le s s , o r th e common name o f th e c o n ta m in a n t, i f fZi P o> < o to z in QJ <D JZ r- -M O. EC <0 *r-- X OJ (O 4-> s- <o o x> 4- 0 * s_ 0) 0 T3 O O CL> (J L- c0 O -P r+J (/) r- ro "O EO O in 0 "O o> OJ C CO 1-- 3 -f> rO co uO OJ "O CL O OO a> <d +-> . rO 4-> u a) Q. 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CL ro r "O dJ S-- QJ 4-> 1Z dJ 00 0 z d) dl tn ,w,<' O Q) OJ tn E E *P O 0 a> .g >> E O ro O A Q) "O 4Z dJ -P L. di +> *rm OJ > u OJ 4-> S- to a> tn *0 P rO rO 41 1 r- cn E ro O +-> r-- O ro O dl 43 rCL-O r- 01 4-> *rr-- 43 -r E S- tO 4- r-- MO o CM co ** lo to * * 18. ANALYSIS REQUIRED:I f NAME. E n te r th e f u l l a b b re v ia tio n '. DPMC-16085 LAM 000373 2 9 . OVERALL LOG AND DESCRIPTION OF EMPLOYEE'S WORK. A b r i e f , b u t d e s c r ip t iv e a c c o u n t o f th e ta s k s p e rfo rm e d d u rin g th e sam ple p e rio d sh o u ld be e n te re d in th is s e c tio n . comment s e c tio n fo r a t le a s t one o f th e b a tch e s o f sam ples b e in g s u b m itte d . you fe e l th e re may be some c o n fu s io n , th e f u l l name s h o u ld be re c o rd e d in th e 01 u d> /-N W/\ C CO d p s01 pCO au> 3> U o s/ c 10 d p m l^N mm CD `r- c-- L. tn 01 p co in 3 "03) C p ro CL o O{.l wC irn- c35 P. in 3 4_) a) o *- 'Z 01 do -- u Erm&o rQdo- 01 ro dP P l-H -PCp* .J SIGN box z 01 U 01 4Pro - ECo 0) d p 4O Pc piodoi p c o c orP CO u ro-- d3 P d>i *Ou3l 3 PC 3 01 d "3 3 diOn rin-- in r>--> CcO co dp01 ID 3 ce CJ -0C) o <C o --: p<t.0 1/5 O U</J) dco --1 -- - -3 01 HP- SCdCO P3 UccJ s01- 05 oCM m f- c o P 1- "3 CC3T)PP-0r-) c6 PV. 3in o d 01 41 d (0f 3o u0) din o. in m (0 TP" c <H4H- 3 P c oi "<3i> uoi PL- 44--O *rd"D ai U D) C ia~i u10 3-- m O' rP-- Ua> 3in m ai P {. rai 3in j= o> d ai du*- ds r+--> C3 r* Z CP 3 *crd01 3 P S x X 01 U t-H d 01 t-- d 0) Up 1u0 HMzZD *3 0in1 3 3 doi m OcJ =E it-- JI 1001 tn -aT e TM re X- 0p1 ID TJ 01 " ^^ W 4_ re 0) o5 5$0p1 2" '5 p S ^ 3 <0 01 +* 5*.E o 5* +aji y* oo) m H O -*(oO A] Jrz --> W P op -O ro-l . r--n. fli jj E -j mP x, 1w0 oi E-E o.- 0 -5 -C c + re 01 E Q. 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P3 U <C4O3C CO E in P in E t. ai p c a u >r* "O c fo" p u <D o u J3 P OJ .a u u in CD O u p Q Ol o KC-) LpU tPQ) p co_> 4- U. o 4O Z 0d1 HoH P>> Id---4 u a: oi ccoj dE P3 QC m m u0) "O D 10 a> u O) uu o a> c o E a) TCJ <0 O) -- c ro f- 3 P *o u - 3> T5 C *3 OC u c a> oIA u 3 d a> Erco P in U3 <1) d E3 *C3 C ro 0c) o *c3 ro 0) 3 ECcO d01 u Up0cJ1 p L. . p01 o1-- pc oo *- >CD- OP P a. z <CO E d O o a> uo J3 0 d 1 O' CNJ a> in d Xo d "03) P 10 c 3) r* m a 3 ai 0) d ECO in a d u p 3 0) o EO P- o P CM p in rso_ "ro Pm 30)^ 0) PE ed p0) c o o CO LU oO 2: ro m h0--C --(0 H<- 3CT CO 3 rH CM CM esi rcosi csi IT) CM CD CM rC^M oo CM contam inant code lis t ) . I f DPMC- 16086 LAM 000374 should be e n te re d . The com puter w i l l be capable o f a s s o c ia tin g th e se m u ltip le samples and c a lc u la tin g a TWA th e y are to be in c lu d e d in a TWA c a lc u la tio n ) se( ivfe ra l samples are c o lle c te d th ro u g h o u t th e day to necessary, a n d /o r to make a d d itio n a l re p re se n t the s h if t , the number o f a d d itio n a l samples *4 3 . NUMBER OF ADDITIONAL SAMPLES ( T o ta l number - 1 ). I f 30. SKETCH AREA. T h is space sh o u ld be used to s k e tc h th e work a re a , i f uo! "O>0) cCr> p bc> ((S0) a> +j 4o- CErtooL 4uo- Xu0E)) "t3Dao> C3 0oEo) o> 4-> TCr3o 0Ecro) 443ocEu0r3(u-o0->> O) 4-> u L4cQUJ) . QLCzUDC: 2 ULoo2U Oz < hLa>U--. hzL2Uor HtZ-/H> , Ocr*) EttC/o)L 4ou~ "Oow3>r 44E3Scc0t--o>>-) +4StcCaE3--o>>>. J40-Z>) TX4rL0-oJJ>). r-- uro -oC r* x0:) 4O~ -auD E3C 0utrfoo*) *pr3>oo" "Orc-- z4O->) 4O0Erco) -4OC->) J40-Z>) 0) LcU L40uc-U>) LCCzUOC z CD OL--U c L<aUs> aCH-Ds4 <C-> c o X4r(-oJ>. rUo 4O "u0Oto1 J4a-C> LuL0cU>. LH<OU- Csj PO CO cn ro co -4aC->> 4Eos-- -cao; 4aEa->>t r0--) X3 j4roO-o> 4c3uO-> J3Q QtOtoo. sCO-Lf 03E> o*> 0) 4cotSr-o>*-* JrDuro 4QOaC<E3r-D">.' O> JuoZu u0ca) 4C3Oac->J a> 4otL-o>. 4ou- *t30oo) TOJ 4E0->) 0) to zuf* * to au> x>0>) CcD 4-> Xof0tuta--o3->; tCEtooL LSou- oozhLzU" LzLLuaOaLUUUUss. ^* iO(J -wQ aLaUs. *urco> ZLZ_U) *Xr(S--r0J-O> ruo in KD co ro UU4> uusac3O>. 0) Eu CL c o to CD c * uu "O ro 0 u O) ro a! C 4- uID "O c c ro 3 o> ro 4-> r* TtJ- C ou0> 0> "Oc tO ai 4-> 4-> 3C Q5Q-). TQaD>. E3 CL S- fO to u3c0>) E c E0) 4-> Oc) F- tQEroo. itou& c f-- E3a r-- o> Of tCEtooL iUcaa>t t40C->) 3uO o 0> ** oZ w (0 c0a*>) *x+f--J: -^0Q) o oE> u4ot-o>> 4uro-o> 3 a; 0) O> -uC -uC -aC> *- L4OcU-U>) u LuacU 4O->J * to u u01 0s>- a>> o> "O 0) z 4-> to LU UJ oz z <t-- ZJ c 3 LLi t-- u o o u ocs o z M > LU LOUS 4O->f uu a. a. o z y ZD 0> <t < O f (/> u> O H- co ccKoo ocor o^ E Ji to 5^ Q. c s a> D. lO H<0 reo 4-> m <c F 5 v.-/ (0 3 2Q* to qs 0^ TJ CD a> 3 CO J- > C c U .p. ro 0) > "O c 4- E F" O "O O) 0> ^CSJ 0> u x: -C 4-> > " ti 4-> to 4t0-o>> o> >> ro nj XJ O) c Jozj 3C "O 0> 01 rE" u o 0) to +J a> t- 15 w oID tCa->L - LO r?-o o> 4-> 4o->> tO JZ to 0) *1r-0 __ Lro. 0J C <0 c 'ZCa3> *! to (u0 uo 4O->) s. ca> 40->) *0-) ro . ^ t- 3 CL to uaj: 5 4o- EO 5? * to o 0> 0) Oq. ro **-> LXU T3 2c ->O> 4t0-o>) T3atoJ> ot-> ro in 0) u ic H LU 00 CO Li. HH to z E LO a> u> u. -4 o O iH 2 LU o> .T orf Q- 4J ^ JC to LU > O S3 >O -C h- 0> 1 <C J-- > .r- 00 Z 01 c LU CJ ro to a> lu i~ u oc o a. >-- 4- LU (0 QZ _LUJ "O3#>- *T0UrJ-) O- ^I</rtcoo) C-U0CM>) - -O c _ -^ 3O' 0u1 3 -OC I _>>o " o I* SS 2 Sg Q. ro ETO *- c o i- +J oT3o- 4J (0 M- (/) j= o> to - a> 3O' 52 a> w to o 5& 0 a> "o > jz 4-> " 4r-o> < C a> to : 0) o uc CXr LL 1 a> C 4-> oc c a> 4-> ro 3 => j: in ** m2 * o c = .2 S 2CL ou Xn a* " a> a; -C 4-> 0) 4o-> (O a> Q. E<0 to 10 c o 4-> *"(O50 co ro to ro 4-> 5a> > o 4Sa3a->>-. E uo -40C->) 0) tfo*>o ro ^ a> TJ 0) (0 - E CL E to (0 c to o ^ ro s c u TJ = a> to TJ notes fo r lo c a tio n use. value. DPMC-16087 LAM 000375 2m ro -D 4-5 CD 3 ro- .o 3 C a c o u Q) -Q E 3 C ro 4-> O 4-> ro -C 4-> 4-5 .O O) 4-5 ro O cx (0 U) t- lO iZ ro 55 2u m -C0 54J a10) *ro- Co i 0) 0) 4-5 -C c H- 0) 3 O o> 3 O U 4-> C 0> 4-> lO t/) c o u ro E CJ u 4-> to 3 e <o Ero 4-> o> c o 0) JZ 4-5 to 0) Q. Ero in ro 3 E T3 0) 3 U ro u ro 5 to o o> 4J ^Q. m| in <4 4-5 re ai to c ro ro JZ :* *- U ore *-> t. <- u3 -- re in *o aif- ic ai m Q. r-- ai >-- >, o e a. <*- +J U EO <*- (0 Hi 11 O in -C I-- I-- +j 4-> o. q. a> >*-- o> ee -r* c 10 15 C Q ai ifluiDQin-i ct jz -f- t->x p- s0) X> >> c o <0 >> 5- a. 4-> a. E (0 3 u C O 3 to 0) in - +> ret/i o re c -r- re are o c >o*re- r-- LxD r>o-->+ro>- p ro au cl u re E lli wO oO E lu -Oi <f- re 3 u re re *- ro Er4-5 4J u ro 4-5 to 4-5 to ro tro ro ro 4-> 4-5 3E ro a. E ro to re jC +J E o t- c o p- ro E ao 0) 4-5 T3 cro a; 4-5 to >> to ro -C 4-> >> -Q o | i* o>5 sO -- -0o) "O 5o u to ro cu fo- ro 4-5 J3 ro (. F-- ro *f>^ ro E leu r-- * ro O 4-5 x: u ro r-- 4-5 4-> .c C to o "O o o ro a> <+- -E "O ro 3 XJ -C r-- *r-- c o O -- r- r*" c ro -C r > to 3: to to c r-- -r" ro ro ro <c >> "O E 3 o o r- H- r--- r-- 4-5 O. U o E ro = ro ro Q- ro c S- 3 c ro 3 tO ro to ro Cl O 0) ro c CL E r-- X *r-- u oj &. k- ni ro 3 3 to to +-> o O Q- o4*--* ro x x E ro a> t3o o troo 4-> ro o ro 4-> 0>) "O05 5 3 rro- Cro- ro *to s_ o 4-> r-- 4-> ruo cro Ero go ro to JZ ro *r- 4-5 >> o ro E 'a. c ero *En a> C\J o =** 4-> 3 ro ro ro c ro *r- ro ro <o e ro -*-> cc oo XroJ c *r- ro o u ro ro o E 4-5 S- to _c to ro +> ** ro to k- ro "O o *r-- 4r-o> o > cn ro ro -X c _a -a U *r- O -C C Di J-P roc o u r- O) 1-- -- JC o 4-> 0.4-5 E ro c ro tf- o rox z UqJ: 0C54-rC5o 4-5 => *r- ro M~ t/> o XOL UJ irroo- oE3 tco" s noo X 4-> S- o o ro o z; C 3 S * ro E ip- 4-5 ro 2" Q. E ro to 4-> c ro u f-- 4-- t^. 3 to c T-- o 4-5 ro 3 XI X3 ro 4-> ro u ro u ro x> 4-> 0 c c ro u ro O) ro "O c ro ro ^ >u ro ro D U ro 4-) to jz #05 t- X ro o ? XJ 1 ro to E --x: 4-> ro * <*- tJ ro ro Zj ro => w J* <> UJ CD c iI--_ iWn O ai ZU Z CL <E ai (-> c- i <r c ro to ^ Q. .Rs E ro to xi a> .c . * to to jj ^ in . a* 4-> ro u o 12 "a> to -- m CSJ o Cl x tn O) ro _ o 4-> U o r"l ro c S ro o ow o-St; ** "0 "j ai D O * in o [" -J. i * ro 7 r. ro ro 1 O) ^ x -* c *oi- rwo *ry> w t 5 >> ro S a> c jc 10 ai >> 3 TJ Cn'T in ego*1 ri- , Cl X a> a> o u c^ c o 2 oZ * o -a *" 0) 5 T3 re "go uO 9Ein" re j_ c *- o o CL ^(0 +J m t. , re -- uT E *- CL t! t* in 5 o re af i nwu i*#- or <-- <c 0) in . . 3 f5 Z T3 W ^ Q ai o O -X CL _ :* o x 51 01 ts S-0 " -O re CL -o tO 5-- UJ 3 S 9! o) c oc o < (/) to - H-- l/> X <C O 4-> u ^ XJ o o 4-> ro ro u u 3 O to ro ro u ro ro to ro ro to ro c o to sro Q. t C o 5O "O c ro ro w 3 to O CL X ro o t. 4-5 C o u c o 4> o c to ro j or- &.S X ro u ro 4- c; --i u o . 4-> "o _ _F ro -3 21 O= 0) o 4*5 go 3 to ! Lx 3 U __ 85 . 4J W C s > .2 5 O to c o u ro 4-5 uro TJ to to X to ro -rto JZ ro 4-5 4^ c ro ro C u 05 c u -f- X . re ZE c-- _ - r W ^ T> ^CL IQ -rU3 X <- C 0 i*- ai .a s- c = 05 in to *r- *r ro to >> -*-> s T3 c ro ro 01 (- E ^ ro ro jj T3 O) i- -o w to 3 y g'n ^ 8- i i re ^ re c 3 o * T> in r* r- in S-> 3 ai < O L- !z= -icfl oI_ o O. -> * (J z re . 1-1 4-> x: c c co o ro oc z c 'i < *- ro o -X 4J H CO C U. o - u z CD x ro H Of co .a 4-> T3 *5 5u re- ro to x> c| ^s ie Ow o a 8|E cr c ro ro til o W to ro * >, X5 r"o Isrwo at re ** > 05 o *j re cm_ a> m^ ai 3 o m o O re O_* x to u ocplTfWli ^rUe, 3 re 5^-5 ^05 <k re ^ 5f^ O m re -x o o r o o o ^ x> o-re 5| U C u. o o 4-5 00 to 4-5 ro S_ CO to * H- >> z UJ ro c z u ro z ro ro o CL o co u ro troo c >rroo o to 4-5 rCo E E O O T5 rCo JC. 05 c o ro JZ c o p o c 4-> 3 to 4-> cro E E O o Tr3o -o o u c o uo to o 4-5 ro aro ro XJ i-- ro 4J 3' Q. E O U ro H* in KD ^b * croo* be sto re d and can be re trie v e d fo r o u tp u t re p o rts . DPMC-16088 LAM 000376 in tra c t The assignm ent o f t h is code re q u ire s a c o n s id e ra tio n o f s e v e ra l te c h n ic a l v a ria b le s w hich may a f f e c t o r o th e rw is e b ia s th e m o n ito rin g r e s u lt. For any one measurement, s in g le o r m u ltip le fa c to r s may be re le v a n t. These v a ria b le s in clu d e those which are obvious, such as th e proper s e le c tio n and use o f a sam pling d e vice , and those w hich may be more ambiguous. T h is l a t t e r c a te g o ry may in c lu d e w e a th e r in flu e n c e s , pump perform ance, w o rke r tam pering and chem ical in te rfe re n c e s . The assignm ent o f a data c la s s if ic a t io n code on iIUs^3*Sl1 si i5?-?o ro & 5ro ? rrrooo rroo<X> __ <_ CD & fi- C oi 3 01 u ro p t- -C 3 t/j o m i/> c X " o p S 01 <0 X > 0> JOE c o e o w o> >> r- = 0> ro <0 2?-- P C +> -c t- r> r C V) S g-t Ol t<0 ^(0 .r -- 6 <0 tJ 01 TJ > Q- U) 10 p <0 *o 01 c ai *F-- CD co ;p^ u Q-, 0> E 3 5 uS <J o 2 *o "D Z p c <0" T<JU to uo "O c 0) o -C -i- >* a P C 01 w E 0> u PP to ia p U 4-> in 3 ro ** IA u 0Swo1- Lol. 3 o ^ S' o>___ ^ t- C to OT 01 >> P V) in ** ID C -->>"Q. 8*2 ai E 5u CTro (0 01 II to 00 in 01 IS > n *- p ro 3 o> Juc S U 01 ZI -o ?3 P C 01 ia 3 to ro *r- to w> ~ V) <= (0 01 .,e t3 CL ai s- c P yO 0l_ Q. in to So o CL ai fi- to gj X U E o Ql ro TJ Q.O c ro c C ro to 4J ^ ^ Q. E 4>r-- _^fl_ urr_ rEo ro tOi_ ^ 4C-> =CD 0 n j= 0) >- ro at ra- </D> UJ c *o 01 p 3 ro p-- fl) 0) Dig c at E 3 u o *- 10 >- to 0 ro 5 o ; X3 . *o a) t. 5 ^ -t-> m 0) *,_ 4- _q ro a> 01 o -o ** X ^ 01 4-> c c S^-o ~>,^,2 r- S. w _ ro-c 3 <c o to n r- p* u at 3 in C at o --> C 0 4o C "o T3 =0 10 +> 0)-o C CU t- 4^ O. O "O U) cm m E _ to to Q. in *o at O *3 O K- O r-- m u <c at *0 _l u at u o at E t t-- *0 at 0) fc. 3 in O Ur^o *-U E at -c ^ JI totO u O Q. 4->4-> c t- X to to O to 4>->> in c o a. in at t- fi at > at o CO c to in at 4-> in --> u 3 "O c o u o x: 5 c o in fi at O. in at o -C f-- ^- F~ o >>*- in at to c O "3 *o at c at a> X) -r- m cm to to u in C *rO - c 4-> O tO rm U - to 4- U -- f" in * in r-- to in f-- m u to to u 4-t to to o *-> to r- "O to *- c c *- at u x: o p u 01 fip-- "O .p 3 O at fi- 3 in 4-> c at E * o 4-> fito Ol at o tf-- at JC +> 4-> to O) c r- > U 3 T3 "D C at o 4-t u Lt 3 "O c o u p in ro u >> at o > s- S- o at ^c fi- c o in o mm m u roat > cl u Ql 3 > CO 0) fi at . t? a^t at ,,1r^: s 5) > 3: r-- CO tO < to fi- a4-> O s- in 4-> 3 C in O O 3 C r"O t-i in r- I> fi- ui at o0 od CL CO co 3 tn .c ** * Ou OJ co p- jz. X>* Sro 0 (0 p* hi *- -C -p -p m 5 >> -O ro -p +j u in 3 -r- "D cc ro o 4- u O) >1 W X >1 ,-- >ro ro ^ P" ^ 5- W c HH ^ P o w H-- T, o L. c o <1) c= c Oin Oy) t- at Q.^_ -3r-, *p^-- at 1- u -- r C 0) >3 JZ 0 v- CO t- Ol P P3 ? ID O r-> _ Q. 3 E0O i- i~ Clx; c a. 4-> ro ro C >1 u ro -p ro .e *<E 4-> 3 c c O X ro c *j o ro * t> (J UJ .X a l*_ l/) L .^13 iinn 10 in"Wrwo -- ro u uo r- 4-> w t? ro CD C pfiO P c o E at c at O) >v JC to u *p in 3 T5 C at in at m c o a. m aZt in ^ at at in u c to *-3 i? cT -p 3 fi- to U' at S' 3 u ro *= S -p - ro o =o co ca, r ro *- cr> c o o mcu 2 o> 3 4-> in p y -i- u 0 CD C U 3 O) c <J c o '>10 X0 01 ^ -- TJ P 10 C n (0 35 p X w Z3 S TJ Cc 0) M 0 ? 01 > 01 fi- $- TJ C O u r-- -C CD *r-- 01 x 01 P ro u IA 01 O 01 "O X) c c cO ro p-- P 0 to O) p- c fi- c J 0 0> p 0. p p p ro c to p0 0 TJ 01 0 IA p p E0 01 p >> 01 p-- fi- C c 01 xa CD 3 01 0 fi- TJ E T 10 r-- 3 IA 3 O 01 p U ai 10 TD 01 E fi. fi. P 0 xa N U O &- r OP ro >> Q.-0 C fi- c fi- C *=> ro CD O. CD C 0 ro > 5 fiO 01 JZ p" r--- IA IA in at p > p Q. 01 ro E PE "D >>-p p ro O C o. at um * o o- o. ro u U to c c D) in o ^3 cc to I- T3 p CC in CO in in 10 o O) u c o p > T3 a. .0 at P to u r- o fi. P O to in in fi- at c UJ Q.x: o o. o o a Q. < C=D L5 O. u a> in at s- in hi fi at < CP 1/) CO < a (0 to at -oT3 *> m cn K DPMC-16089 LAM 000377 use r e e p The fu tu r te and p ro tio n . ccura ra a s id e the con on s has been taken In to exposure is dependent v a ria b le employee c to oLA P p 3- O LA -C L. a (A ' LA *f" CL e to la 10 c Jo f- 4-> ^ X to LA P C *r* LA E to LA top 4-> E >> XI 3 4-> P *33 p P ^l ss LA P LO *-- c *O C-. 4r->- tO* E fO to *Q3 OCC 3 Oo P pE - oc> O LA to E a? >, a c p 'j: "O P c .o O3 U 4-> 3 Q LA P u P P to > c CO o 3 c 10 3 s222 ^t5E- O C -C u 055 oP uuu>> uu>u>* /"N 3Qi u3 U o > ur- 0) 4-> -- >>to c > a> >> 3 CO3 c 3 LArH C O to \ u 0C5la s- u u.. ai 3 - 4->U O 10 r to 3 4-> P-O tpuo tuo oo-.J S p pto 3 g t- w CP 3 3o XI u u a4-> 4-5 o 9-J- P C LA .JT P p u u uto o f-- P op 3 o E >* e to- uo p o pc > LA 3 to -Co (0 u w wc 0) 4PJ 3P >1 a. 3# 4-> 0c ru-- P P rO" Op 3 U 4-> .Q 0 - u 4-- LA to 4-5 4^4-5 P & P 4-> p 4-> 3 3 p*to 05 u rr---- (PJ JO3 P O P> r-- Pu P P P 3C 3Cla 0 u L. 3 4-> C O 3 x: O O(A u < a. 3 P 1--4 U cr H- O OP V) to 3 p p X? c o O) r-- 4-5 P c f-- > s- >> pu LA o P 4-> Up u 4-> o 3 1 O to JC 4^ g-o ^P CO > r-- r- (- 4-> 0) to CL 4-> O c t0) Cl LA *3 p. CL N 3 >> p LA (A C p 4-> 3 o Cp Cto mg EE P U LA P (J C * to U3 4J C 3 3P .o t- LA P LA *4- O LA &- r-- CP O 4-> P r- C 4-> -r- o. E 3 5- P C P to o -C U 4-> p -C P P o> *3 3O LA * 5- 0.0 4-5 X !" -X p 4-> to ro p JD o Co. o 4-5 p 3 3 LA c o 4-> r" 3 o u p c r-- O 3 X) O' 0 p a> a> c X3 0) ll r-- Q >. o> (0 >1 P Ef 05 3 a> 1-- P O) o ro J a s~ O C s/ X O u> 3 c -0 P -* c 4-> P r* LA 3c cr p 3c LA LA 3P U 3 fP> 4-5 P P3 Cl C u0 *" -r--5 4^ 2 P fli r-- P f* O 4-> u O? P "5 w m33 3 r- w 4-5 u p to p U !- LA LA >> 4_> C f-- cD P vLA 4-5 Pu t. P o f-- P C P c. o p c. o - U >i p p o> A p a-x PEP ot P LA P C. A x: 4-> p r- 05 JC a. E LA U P LA E P P CL i- E Pom JZ O 4J a. 4-5 3 LA O o. X p r-- to 3 4-5 O P 4-5 c p LA P U a- 05 LA U *r* LA 4-5 >> i c w -g o ai jJ" tO CL Xf--D Ea. to la - p P LA LA Pp f" 4-5 CL 3 4- E P -C O LA 4-5 4-* P C -C P 4-> E to LA LA o> c f-- P 4-> LA 4^ LA u P p to LA P L- to P 3o 4-- (J 05 o Pc 5- CL P to Uw P c o ro x: 4-5 c LA LA u to p CL P s-Q o P ro 3 jC 4-> P Cl U P CL u "O ro CL i-- L. f-- O to O. to Q3 3u U to to to O) c CL E to ro c <0 o> c u 33 3 X3 PP LA P a EtO p CT c U P cc L- S- to - J- Sm/ c Uo LA oo p o. o c o p .0 LA .r-s LA P gi LA LA O f-- P a. 3 0 r" ij p r_ 3 0 XI to E Pu c. 0 P **- LA >> * P P XI 05 c a. 4-5 E P LA LA P r-- U O 4-5 P c a. c E0 P P LA E O) P 4- C P r- O 05 C -r- C P O) O CL >> LA P > ^ 4-> P t- _ CL 4-> to 3 4- r p 3 C 4to-5 4- ^ 4-5 O) C LA i P pu 4-> O o' Ei P .1- 1-4 3 O XZ 4-5 P z: p u 4-5 p c < \ CT C r1- a E p to p s p 4-5 CL P U u c u c5 Ol -ru c X3 0 E </> ro u 0 j= ^ -r= * 0" 0 !E x: 4-g> o^ LA r-- C CD E c - r w < c o OUP c O p to >> C^ 4-5 U JO 4- r- 0) to to a> P t- ro (J (0 a> (A 4-> p (0 CSJ o tLoA ro p uto 3 0 *- P 05 O 05 C cue p 4J (V c r 1 *r LA I-- J 0 r- 4-5 C C LA Q. t- -f- 0 " to s~ E 0 P p E O'3 p p s- XI ai a. LA LA 4-> H* < XI ese of each o f th m entation hat docu t c la s s ific a tio n o f th is data. each sam pling form presumes o f exposure data on f i l e as DPMC-16090 LAM 000378 cT>TOO T>O> TTTTOOOO 3T0O go *l&- TO TO --. sTO-8<ZT>1<O00 1g*j 32 SS l is T|O &^ TTTTTTTOOOOOOO TO *uTTuT*TouTTTT5OOOOOOOO puTuaO>CO c r- X E TO tA TO 4- X3 O CD STO TO tA P 3C TO TO X CD H- X LT> ^ STO P PO C TO TO O "O o Xu (_> s- p TO c TO TO (A E TO E a: O u O TO O TO t/7 TO (A ^ TO S4 r-- >> 3 U CT O TO P STO J- >> O sXo TO P __J TO S. TO O TO TO i- --J cn >> 3 3= O TO O r- X S- p P tA tA CU -o to to x >> PX B x> O TO 4S_- 1t*-. CD rf-- TO XI 3 to cr P CD O >TO "X o .c op p TO CD E o *0 C *> ** E f0 c q_ ai -c T3 E E o oi 3 ai- > a.*-- -c a 3 j r- a> O' f ^ ai in U 4-> E 10 Ol 01 Ol C r- TJ C i- H JO <- fc- o E +> O E 4-> (0 4-> O. ai u >- EE C C 1-0 0 Ol*-- E >- C <0 -*-1 i- u 4- (0 fc. o t- O ID X p ft) w*r r > fl> C r-- CL TO O o >>o E >P c TO - = X CT TO p >>C tA 3 x) f- tA TO C X 3 TO u p tA tA TAO* 3 * "f- t<D U f-- 0) u x .c P c X TO P tA TO ^ +> = | -o C <0 P TO T3 = *o *F" ttf o o u P tA O. r- y* 01 E c o 33mO E 0"_2 4- p 0) 0 TO P c Ol E= -3 u TO C E >- J? u TO >-- -2 tA t- Q.^ E tA 3E u TO w (0 Q> TO ifl W >> u CD '" s. e.^ 4-> P to X TO P TO <D U TO *- W TO t X s- 3 o L. XO S- o u U \X o 4- T3 X Q1 O) C TO c o r P T3 0) 01 U C to c <-- TO C iO- C TO P PO TO {X 3 -D U o> 5tA X C o O <D U O i- Q. p o 3 O 3 C T-- TO O TO C J- x| o u X C O n TO > TO P TO C o u TO U r- E C TO P TO o. 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TO Ai 4-> C 3 O E TO C * o c 4A TO U c TO C TO 4-> (A I1 4- (j t- X3 *rOU ^ 4-- TO O X TO o>.2> C XJ I- TO r-rXJ E TO C (A CT 3) C tn x aa> tA w c - 3 4-> X TO U CP r-- tA X tA E TO TO -- CO u o o -- C r-- (0 o 4-- in c o *o 'jj a> T3 10 Ow (j 0) c3o X TO E O r TO U r- 4~> U TO o^ ^u TO TO 4-- 4 X TO TO fc. lA .r- TO XX 3t o TO **- 0) >0 4- JE 18 <JJ (A 4_> (A C TO u0 TO 01 S. >*c 3 U 2 in U E <0 < x: TD 51 O 01 4-> x: ro 3 o> 5 TO </> CT C C TO .T3 U C- TO *o u " TO 0C o uTO IA T) ."2 TO C (A U TO C O C- c U o TO 3X 3p Up o *D tA c3 i- o E o u tA tA C TO tmT-O TO U Cfty U TO U L. 3 TO U o Xu o I-- o TO "O o u c o TO U tA tA TO TO X 4-> TO U 3 "D TO U 3 O 2 XJ o STO X Ui c TO tA TO X 4-> L. TO TO o 0) Vt CcT tA *0 TO C > TO OX E TO TO "O 0) ro 0) o >* o tr- O Ol E CNJ LU O u ' TO TO tA CO f; to u Q, <TO "O "D (p C &. 3 -o C rL- 3 OO >5 tA I TO 5o 0) n O o o tA tA TO t- 0) a. X a; x TO 4. +* O TO TO U Xo 3 +* 4s->- I-- TO TO X O U O) Xu u3 w-o L^ O. -Op PU fr, TO TO *f"-- * U0 O tA U4JCSJ Ol O cuO P * XP TO E *s* TJ TO 3 O CO tA u 3 O 2 u P tA P tA IA >> tX IA S_ P U o u 3 "O o u X t>> X Eg ro O tA O TD C o P TO r-- TO XU 3 tA "O r-- TO > I E o p c 3 O E C o c J* c 3 C S- P IA o "O X P E O W Qf X O TO X3 o -a pE T5 0) 3 jC O I- LAM 000379 DPMC-16091 xa>: p 33QU> QJ 3 3O 1 . PaU> a> >0) m* P JO o> rO>o>) Q. E 0> X>)> u<Qv. 2g 0-0 F^ ^o P tn to. P u 3ao u ^ Co u 3*u D>*p- C PF" -- IA O. v> E JO troe *--a c L- in. irn- *O> c **ar.>-t r--> -Or- in O(CirvCd0j- ia-+ioaaiU-nnJtmc<*t--D3Q>Cj->. Otol at *nt-- (. JC *OiJn 4J re-- c>to> P- (A EU ca> ErQ~, JrJ--3O o p r0--> (A J0Z) oEJO. d) h w a. E* JO ^ Ww c OtS=.i -0c) J- 33 ^ X>3i( pOc 3 >tuto<o3uc uJO p > 'to UUJJu3UOO Q) 30SU3)- XOr- 3P0*-) 3pca> *r" XQ>i fj----J>O> 3 Xo(A >Co- rXptJJo--OOX0) j^C 33(A p IA cc c3r"* a3u03>: IA {uuuc0s3a->-) o s~ o (cA o oo (aUC0uA>) u3uo 3C(0 Pco(rA- r--J"OciS(a3u0oA-*>). O tO. r(ocA" Pr" 3Cou X3o(A P&OO-. JO a>(0 I/) a a E JO X0) JO u 3OUc n4r(Cor-A"> t3JCO 0JiO-) XW0a1> 3oCo 3u3 rp30J"O^* >J0O) - * XP01 0> 3U *3 a> 3 *O 3 a u a oi/). c 0) a> P' JO t Of o P t0-> CA (0 u3 . i/> ro O c0 O 5s 1o o *-> a, -g S- 0<= = W ro U o!- QOt -<v*-- OJ- (t/n> CL 10 E <-- i--i U o +> (Vo uo co to u in in r--to (J ua30o>) O23 -O to at XZ 4-> to *8 ^ "5 = aS> w a> oi uw .Ht. jo o > o c a> 0) sJO c o 5sJO? -c> U-O c a> a> -S a. P3 Ta3> I-- CO JO o oo S- s- o ro -C CM OO 0> 3 O o c o JO u (A tr> JO u 0> X p a 3u 3 oj u 0 1 I 0) cL E JO <a 3 X P *5 0) Eo. to in t- to c o +j to *rEc-- to +J c o u +> ro CO at U i~ 10 o a. CL CNJ t o a, 5 3" oI O IA U TT ^ (u0A) J-H /\ 3 C .* O 10 U10 -*U" _? J3 O u " " O 5a C I- O * ^O L ^ o atat jE c3 5CO s o-D^ ? = 3 .w tit 10 % at - +> ff E^ re C ^ CNJ or- p m *o JO a cai aa>t -5 J 10 u 3 U O u x 0/ o; JD 3 P (A lA JO ru CNI O E u o P 0) CT JO -C P o flj o -1 > p p v JmO U .O o CA <I&O ^ aj OI 0) J3 330> JO -O o, *5 3- 2-0- <0 t- w 3 (AO O 0> JZ at r- tA E <H> <-- O. JO (A O JO CO (A U (A 0> 0> U JO 01 3 X^ O UJ u O a# , LAM 000380 DPMC-16092 DPMC-16093 LAM 000381 NORTH AREA NAME Complex DPMC North DPMC South Operations East Catalytic Reforming Catalytic Cracking Gas Recovery Aromatics West Aromatics East Hydrocracking Operations West Distilling Thermal Cracking Solvents and Treating Alkylation Dispatching Tank Farm Dispatching Docks Operations Lube/Phenol Acetone Phenol A Phenol B Lube A Lube B Lube C JEP CODE 910400 910422 910434 910464 910426 910425 910427 910424 910423 910428 910416 910419 910420 910418 910417 910496 910488 910430 910431 910404 910432 910433 910459 ENTRY TO BE MADE - - Cat Reforming Cat Cracker Gas Recovery Arom West Arom East Hydrocracking - Distilling Therm Crack Sol-Treat A1 kylation Dispatching Docks - Phenol A Phenol B Lube A Lube B Lube C LAM 000382 DPMC-16094 NORTH AREA NAME Utilities Utilities - CPS Utilities - Distribution Utilities North Lab North/Analytical Wet Chemistry GC Section Phenol Section Lab North/Operations Main Lab GLC Room Catalyst Room Shipping Room Motor Lab Stockroom Bottlewasher Room Lab Courtyard Sample Carrier Room Maintenance North Paint Shop Carpenter Shop Instrument Shop Garage Main Shop Environmental Operations Complex Environmental Operations North JEP CODE 910478 910479 910437 910409 910480 910481 910482 910483 910401 910412 910413 910414 910411 910415 910410 910402 910403 910469 910494 910495 910484 910489 910487 910456 910457 ENTRY TO BE MADE Utilities CPS Utilities Distribution Utilities North Lab North/Analytical Wet Chemistry GC Section Phenol Section Lab North Operations Main Lab GLC Room Catalyst Room Shipping Motor Lab Stockroom Bottlewasher Room Courtyard Carrier Room Maint. North Paint Shop Carpenter Shop Instrument Shop Garage Main Shop Environ. Complex Environ. North DPMC-1609 LAM 000383 SOUTH AREA NAME Complex DPMC North DPMC South Intermediates and Solvents G Department AC/D-D 100-200 ECH 300-400 CA Vinyl Chloride Oxy 150 Section EDC 100 Section VCM 200 Section HCIN Area C Department A Department BA/SR Department Gerbitol Area Olefins OP II Light Olefins Treating Isoprene OP II Pyrolysis OP II/III Butadiene OP II/III Hydrotreating OP III Light Olefins OP III Pyrolysis JEP CODE 910400 910422 910434 910466 910461 910439 910440 910441 910447 910448 910442 910443 910449 910472 910474 910405 910407 910473 910475 ENTRY TO BE MAI - .G G 100-200 G 300-400 CA VCM VCM-150 VCM-100 VCM-200 HCIN C A BA-SR Gerbitol LO LO-Treating LO-Isoprene PY BD HT L03 PY3 DPMC-16096 LAM 000384 SOUTH AREA NAME Utilities South Resin Operations Liquid Resins (ERU-5) Solid Resins Epon II Warehouse Epon VI Warehouse Bisphenol A(I,2,3) Resin Solutions Speciality Resins Continuous Unit ECH Finishing EPON I Utilities Distribution O.I.S. West Rack Site III Denaturing Plant LRDF Non-Shell Chemical Exposures JEP CODE 910447 910463 910436 910429 910498 - 910497 - 910435 910460 910446 - - - 910499 910445 910492 910491 910493 910408 910486 ENTRY TO BE MADE Utilities South - Liquids Sol ids Solids-EP2D Solids-EP6 BPA Solutions Specialities Specialities-Continuous Specialities-Finishing Specialities-Epon I - Distribution-West Rack Distribution-Site III DP Plant Offsite LAM 000385 DPMC-16097 SOUTH AREA NAME Lab South Stockroom Instrument Lab Solvents Lab Intermediates Lab Olefins Lab Resins Lab Environmental Lab Process Chemical Lab Instrument Repair Shop-Maint.So. Maintenance South E Area CWT South Environmental Operations Complex Environmental Operations South Other Non-Operating Area - DPMC South Non-Operating Area - DPMC North JEP CODE 910454 910453 910467 910462 910465 910451 910450 910452 910468 910455 910470 910485 910471 910456 910444 ENTRY TO BE MADE Lab South Stockroom Instrument Lab Solvents Lab Intermediates Lab Olefins Lab Resin Lab Environmental Lab Maintenance South E Area CWT South Enviornmental - Complex Environmental South DPMC South DPMC North LAM 000386 DPMC-16098 Rev. 04/16/82 OPERATING CONDITION/OPERATION CODES OPERATING CONDITION (01-15) (30 CHARACTER DESCRIPTION) 01 Normal 02 Startup 03 Upset 04 Spill/Leak 05 Shutdown/Turnaround 06 Maintenance 07 Disassembling equipment 08 Other OPERATION (16-60) (30 CHARACTER DESCRIPTION) 16 Entering vessel 17 Collecting sample 18 Filling drum 19 Filling tank car 20 Filling tank truck 21 Removing insulation 22 Sandblasting 23 Breaking into a line 24 Analyzing QC sample 25 Unloading 26 Changing filters 27 Pouring 28 Tank inspection 29 Checking gauges 30 Decontam. pump/other equipment 31 Gauging tank 32 Making/Brking. transfr. line conn 33 Adjusting valves or blinds 34 Containing leak or spill 35 Other mechanical work 36 Other operating tasks ' LAM 000387 DPMC-16099 Rev. 04/16/82 COMMENT CODES COMMENTS (0-75) (75 CHARACTER DESCRIPTION) 01 Not actual exposure. Respirator worn. 02 Sample invalid. Pump malfunctioned. 03 Monitoring in parallel with OSHA. 04 Local ventilation system in work area. 05 Major engineering changes made. 06 Levels skewed to right. Looking at problem areas. Not random samples. 07 Sample result of employee complaint. 08 Random sample. 09 Worst case situation. 10 Initial based determination per OSHA' requirements. 11 Periodic monitoring required by OSHA regulation. 12 Work practices apparently not normal. 13 Pump did not run entire sampling period. Pump failure. 14 Pump may not have run entire sampling period. 15 No record of pump calibration. Flow rate and volume cannot be checked. 16 Starting and stopping flow rates not given. 17 Incorrect flow rate used. 18 Lab found sample damaged. 19 Lab found loose material on sample filter. 20 Sample lost in analysis. Equipment malfunction. 21 Interferences with analysis prevent quantification of specific contaminant. 22 Sample stored too long before analysis. 23 Lab found sample contaminated. 24 Sample stored incorrectly. 25 Sample shipped incorrectly. 26 Sample volume too small. Insufficient to permit analysis. 27 Sample tubes arrived at lab without end sealing caps. 28 Sample not received in lab. Lost in shipment. 29 Sample appears to have been tampered with. 30 Openings in end of charcoal tube too small. 31 Extremely high breakthrough found in lab analysis. 32 Contaminants in sample collector inconsistent with what was expected. 33 Sample not under observation throughout sample period. 34 No blank submitted with sample. 35 Incorrect sample collector used. 36 Developmental sample collector or analytical technique. Result uncertain. 37 Data collected prior to implementation of JEP's at location. 38 Unit of measurement for noise dosimetry = % PEL. 39 Dosimeter Set at 85 dBA threshold. 40 Dosimeter Set at 87 dBA threshold. 41 Dosimeter Set at 90 dBA threshold. LAM 000388 DPMC-16100 Rev. 04/16/82 42 115 dBA peak level exceeded. Noise of sufficient intensity to produce reading present during sample period. 43 Same day duplicate sample. 44 Weather conditions may have effected results. 45 Method not validated by Shell IH Lab-WRC. 46 Sample not analyzed. Collector contaminated during sampling. 47 Sample invalid. Dosimeter malfunctioned. 48 Dosimeter would not recalibrate. 49 Dosimeter was not cleared prior to use. 50 Welding in enclosed area in pipe rack. 51 115 dBA peak level exceeded. Reading suspect. No apparent noise of sufficient intensity to produce reading. LAM 000389 DPMC-16101 Rev. 04/16/82 I.H. SAMPLING FORM - ANALYSIS REQUIRED CODE-ASSIGNMENT LIST CHEMICAL COMPOUNDS ACETIC ACID ACETONE ACETONITRILE ACROLEIN ALDICARB ALDRIN ALLYL ALCOHOL ALLYL CHLORIDE ALLYL GLYCIDYL ETHER AMMONIA ANDRIN ANILINE ASBESTOS ATRAZINE AZODRIN MCN AA AC AGE 900,632 900,501 900,603 900,502 900,503 900,668 900,504 900,505 900,506 900,507 900,669 900,663 900,508 900,509 900,510 BENZENE BIDRIN BLADEX BROMOFORM BUTADIENE BUTANOL BUTYL GLYCIDYL ETHER BUTYL OXITOL GLYCOL ETHER BGE BOGE 900,511 900,512 900,513 900,514 900,628 900,515 900,516 900,636 CARBON DIOXIDE CARBON DISULFIDE CARBON MONOXIDE CARBON TETRACHLORIDE CHLOROBENZENE (MONO) CHLOROFORM CIODRIN CRESOL (PARA) CRESYL GLYCIDYL ETHER CUMENE CYANURIC CHLORIDE CYCLOHEXANE C02 CS2 CO CARBON TET P-CRESOL CGE CYC CYCLOHEX 900,517 900,518 900,519 900,520 900,650 900,521 900,522 900,589 900,523 900,524 900,525 900,526 DD SOIL FUMIGANT DIACETONE ALCOHOL DIAZINON DIBROM DIBROMOCHLOROPROPANE DIBROMO METHANE DICHLOROBENZENE DICYCLOPENTADIENE DIELDRIN DIETHYL GLYCOL DD DAA DBCP DBM DCB DCPD DEG 900,527 900,528 900,529 900,530 900,586 '900,573 900,531 900,634 900,670 900,638 DPMC-16102 LAM 000390 DIISOBUTYLENE DIMETHYL DISULFIDE DIMETHYL METHYL PHOSPHONATE DIMETHYL PHOSPHONATE DIOXANE DIETHANOL AMINE DIETHYL AMINE EPICHLOROHYDRIN ETHANOL PENTOXONE 2-ETHOXYETHANOL ETHYL ACETATE ETHYL ALCOHOL ETHYL AMINE ETHYL AMYL KETONE ETHYL BENZENE ETHYL BENZOATE ETHYLENE DIAMINE ETHYLENE DIBROMIDE ETHYLENE DICHLORIDE ETHYLENE GLYCOL ETHYLENE OXIDE FERROUS OXIDE FORMALDEHYDE GAMMA GYLCIDOXY PROPYL TRIMETHOXY SILANE GLACIAL ACRYLIC ACID HEPTANE HEXACHLOROCYCLOPENTADIENE HEXANE N-HEXANE HEXYLENE GLYCOL HYDRAZINE HYDROGEN CHLORIDE HYDROGEN CYANIDE HYDROGEN FLOURIDE HYDROGEN SULFIDE IONOL IONOL HEAVY ENDS IONOL LIGHT ENDS ISOPENTANE ISOPROPYL ALCOHOL ISOPROPYL AMINE ISOPROPYL ETHER MESITYL OXIDE 2-METHOXY ETHANOL METHYL ALCOHOL METHYL BUTYL KETONE DIB DMDS DMMP DMP DHEA DEA ECH ET ACETATE ETOH ET AMINE EAK ETBZ EDA EDB EDC EG EO FEO FORM G-GPTS GAA HCCPD HEXG N2H4 HCL HCN HF H2S I PA IP AMINE IPE MO MEOH MBK Rev. 04/16/82 900,621 900,572 900,532 900,533 -900,581 900,646 900,645 900,534 900,597 900,656 900,535 900,536 900,582 900,622 900,537 900,651 900,623 900,538 900,539 900,639 900,540 900,643 900,576 900,667 900,664 900,541 900,671 900,542 900,653 900,637 900,644 900,649 900,585 900,543 900.544 900.545 900,600 900,599 900,652 900,546 900,583 900,630 900,624 900,658 900,547 900,548 DPMC-16103 LAM 000391 METHYL CHLORIDE METHYL ETHYL KETONE METHYL ISOBUTYL CARSINOL METHYL ISOBUTYL KETONE METHYL ISOCYANATE METHYL MERCAPTAN METHYL OXITOL METHYL TERTIARY BUTYL ETHER METHYL THIOACETALDOXIME METHYLENE BIS(4 PHENYL) ISOCYANATE METHYLENE CHLORIDE MONO ETHANOLAMINE MONOBUTYL CRESOL MONOMETHYLAMINE MONOMETHY LCH LOROACETOACETAMIDE NICKEL CARBONYL NITRIC ACID NITROGEN DIOXIDE N-NITROSODIBUTYLAMINE N-NITROSODIETHYLAMINE N-NITROSODIMETHYLAMINE N-NITROSODIPROPYLAMINE N-NITROSOMORPHOLINE N-NITROSOPIPERIDINE N-NITROSOPYRROLIDINE NONANE NUDRIN OCTANE ORTHOCHLOROBENZOIC ACID ORTHODIMETHOXY BENZENE OXAZOLIDONE OXITOL GLYCOL ETHER OZONE PENTANE PENTOXONE PENTOXONE HEAVY ENDS PENTOXONE LIGHT ENDS PHENOL PHENYL GLYCIDYL ETHER PHOSDRIN PHOSGENE PHOSPHINE PYDRIN RABON RC-716 RM-14 RM-17 + oxides MECL MEK MIBC MIBK MIC MEOX MTBE MSAO MDI MECL2 MBC MMA MMCAA NI CARBO HN03 N02 NDBA NDEA NDMA NDPA NMOR NPIP NPYR OCBA ODMB OGE PGE RM17 + ox Rev. 04/16/82 900,549 900,550 900,631 900,551 -900,625 900,665 900,642 900,650 900,606 900,659 900,584 900,662 900,601 900,570 900,571 900,552 900,610 900,553 900,614 900,612 900,611 900,613 900,617 900,615 900,616 900,607 900,554 900,574 900,587 900,666 900,604 900,635 900,555 900,633 900.619 900.595 900.596 900.620 900.556 900.557 900,640 900,592 900.558 900.559 900,593 900,661 900,618 DPMC-16104 LAM 000392 SECONDARY BUTYL ALCOHOL SHOP LIGAND SILVER AMINO OXALATE SOLN SILVER OXALATE SODIUM CYANIDE SODIUM HYDROXIDE STYRENE SULFIODINE SULFUR DIOXIDE SULFUR TRIOXIDE SULFURIC ACID TERTIARY BUTYL ALCOHOL TERTIARY BUTYL ALCOHOL-CONSTANT BOIL MIX TERTIARY BUTYL BENZENE TERTIARY BUTYL BENZOIC ACID (PARA) TERTIARY BUTYL TOLUENE TETRA ETHYL LEAD TETRAHYDROFURAN TITANIUM TRICHLORIDE TOLUENE TOLUENE DIISOCYANATE TRICHLOROBENZENE TRICHLOROETHANE TRICHLOROETHYLENE TRIETHYLAMINE TRIISOBUTYLENE TRIMETHYL PHOSPHATE TRIMELLITIC ANHYDRIDE TRIMETHYL PHOSPHITE TRIPHENYL PHOSPHINE VAPONA VINYL CHLORIDE MONOMER XYLENE SBA SHOP LIG. NAOH S02 S03 H2S04 TBA TBB P-TBBA TBT TEL THF TT TDI TCB TCETHANE TCE TEAM TMPO TMA TMP TPP VCM Rev. 04/16/82 900,647 900,577 900,591 900,590 "900,654 900,641 900,560 900,605 900,561 900,609 900,610 900,626 900,594 900,602 900,608 900,627 900,629 900,562 900,575 900,563 900,660 900,578 900,579 900,564 900,648 900,598 900,565 900,657 900,566 900,580 900,567 900,568 900,569 LAM 000393 DPMC-16105 ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BISMUTH BORON BROMINE CADMIUM CALCIUM CARBON CHLORINE CHROMIUM (TOTAL) CHROMIUM (HEXAVALENT) COBALT COPPER CERIUM GOLD IODINE IRIDIUM IRON LEAD (ORGANIC) LEAD (INORGANIC) LITHIUM MAGNESIUM MANGANESE MERCURY MOLYBDENUM (SOLUBLE) MOLYBDENUM (INSOLUBLE) MOLYBDENUM (TOTAL) NICKEL (SOLUBLE) NICKEL (INSOLUBLE) NICKEL (TOTAL) PHOSPHORUS PLATINUM POTASSIUM SCANDIUM SELENIUM SILICON ELEMENTS SB AS BR CD CA C CL CR TOT CR HEX PB ORG PB INORG MOLY SOL MOLY INSOL MOLY TOT NI SOL NI INSOL NI TOT K SI Rev. 04/16/82 900,401 "900,402 900,403 900,404 900,405 900,406 900,407 900,408 900,409 900,410 900,411 900,412 900,413 900,414 900,415 900,416 900,449 900,417 900,418 900,419 900,420 900,421 900,422 900,448 900,423 900,424 900,425 900,426 900,427 900,447 900,428 900,429 900,446 900,430 900,431 900,432 '900,433 900,434 900,435 DPMC-16106 LAM 000394 SILVER SODIUM STRONTIUM SULFUR TIN TITANIUM TUNGSTEN VANADIUM ZINC ZIRCONIUM Rev. 04/16/82 900,436 NA 900,437 900,438 S 900,439 SN 900,440 900,441 900,442 V 900,443 ZN 900,444 900,445 lam 000395 DPMC-16107 Rev. 04/16/82 MISCELLANEOUS ASPHALT FUMES BENZENE SOLUBLES CATALYST DUST CHEMICAL WASTE CHROMATE BASE PAINT COAL DUST CYCLOHEXANE SOLUBLES FIBERGLASS FLUE GAS FUEL GAS GASOLINE GREASES KRATON PRODUCTS LATEX PAINT LEAD BASE PAINT LEL LUBE ADDITIVES LUBE BASE STOCKS LUBE OILS MEDICAL SUPPLIES AND VACCINES MERCAPTANS MINERAL DUST NUISANCE DUST OIL BASE PAINT OIL MIST OPERATOR-LABORATORY REAGENTS POLYBUTYLENE PELLETS POLY NUCLEAR AROMATICS POLYPROPYLENE PELLETS POLYPROPYLENE POWDER POLYPROPYLENE VAPOR POLYSTYRENE PRODUCTS PREMIXED PREPOLYMERIZED CATALYST RECOVERED VOLATILES SANITARY WASTE SILICA SILVER SLUDGE SLOP OIL SLUDGE SOLDERING FUMES SOUR WATER STODDARD SOLVENT TOTAL HYDROCARBON USED MOTOR OIL WATER BASE PAINT WELDING FUMES WOOD DUST ASPLT FUM BZ SOL CAT DUST CYCLO. SOL. MIN DUST NUSCE DUST .- PNAS PMPP SOLD FUM STOD. SOL. THC WELD FUM 900,801 -900,802 900,803 900,820 900,837 900,822 900,843 900,827 900,831 900,840 900,805 900,825 900,823 900,835 900,836 900,846 900,833 900,832 900,811 900,826 900,830 900,810 900,804 900,834 900,806 900,817 900,845 900,807 900.815 900,814 900.816 900,824 900,813 900,828 900,819 900,808 900,818 900,812 900,821 900,842 900,839 900,841 900,844 900,847 900,838 - 900,809 900,829 LAM 000396 DPMC-16108 NOISE HEAT COLD ALPHA BETA GAMMA/X-RAY INFRARED ULTRAVIOLET MICROWAVES VIBRATION HIGH PRESSURE LOW PRESSURE LASER ULTRASONIC PHYSICAL AGENTS UV HI PRESS LO PRESS Rev. 04/16/82 900,000 900,001 900,002 900,003 900,003 900,005 900,006 900,007 900,008 900,009 900,010 900,011 900,012 900,013 LAM 000397 DPMC-16109 </) p o co ro O S- <D X O) J- tO *r- oo S- r- X tO to C OP O O) U 3 co XJ S- 4-> (O O) tO z o c c sr- P LlJ C 0) U C O -Q 3 CD <c T3 U XJ CJ >> o c nLUr 03 S- O CO' E Q- O >-o o (J tO s. 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Qo o o o0- o CVJ o o oo LO o LO Od SHELL DEER PARK MANUFACTURING COMPLEX EXPOSURE GUIDELINES irE 00 o o o oo Io o o to o Cd o o CVJ 0LO0 o Co<D CO OV o to o o CVJ o o OO LO o LO m CVJ CD o I 00 o LU Cl. o o o o o CVJ o o o in o LO O oo CO CD c o p CD O < i- CD P (D X 4-^ vi E 33 LU O P Q r-- ,-- r--- X? >> - to CD O i-- X5 p x: e r-- CD r- oo CJ s: i- CJ r-- >) Pc x: r-- E r-- r* < o CD 3 c CD o r-- r-- p O >> r-- >> C t-- E c o <D e r" r--* r-- 3 E cCJ CJ r-- r-- r-- E <c < c <c < DPMC-16110 LAM 000398 S U BS TAN C ETW OSHAA ~ STEL 1981 A C G IH S H E LL DPMC ST E l. THAT S T E L TWA HEALTH DATA/COMMENTS I o E 0) sz J-> to Cl) 0) JE c to o3 r- <8 to +J O 4-> Q. 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S- E (8 O CO U CD c CD 14 c CD 02 LAM 000399 0) "O r O3 r-- 4rS1-- c o o 02 CD C CD r-- "O <8 M 3 CD 1 CO #* 1-- DPMC-16111 C atalyst Dust not otherwise c la s s ifie d . - SHELL DPMC HEALTH DATA/COMMENTS CD r-- W XI 03 E CD to Q_C to O. oc Q. o o c ^ 4-> o T3 U r-- -- a; 4-> 04- Q. -C4- w o t0o) ro to WX3 _Q SZ CD <0 -P+J w e wo r-- -Oq Cl 00 1 w CO 4-> O 03 4- 03 4- > <D O ro *r- 4-> 4-3 - O wu Ww *f" <0 0) c E "O oc in to 4-> u 03 4-- 4- 03 U *T" 4-> o o W (O zz (O 03 *rN-- > E +- p to Q_ 1/3 "U3O Ttc3o oVCDwo O 4- "O CM O to c T3 03 COO 03 03 w0 CL *r-- 03 c 4-0 03 4-3 Id W 03 O OVr- 4-3 "O EE 03X*--1 O C rU'i-- to CD*-- to -o O 03 C 03 r- 03 U w to CO CC 03 <0 CO -O (fl*r o w 3w *-- +0-3> 0 40->3 03 "O O0r3 aO 3=0 COD E Oc --t CL*rZL Q.4-> CT1 l/l CIO) C +-> M-l- f- O .xLc oo1pto- C3O <O+_) HJ <+- io 0) +-> to <J 0) +-> (J O 3 r- ia t(1) r- O T3 +-> > X -r- a> a -p o o 4-3 4-> 3 C !- CL OT3 # E i-- W (1 041 11 4>-3) OCO Q. 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CO *o w CO I-- 03 03 CN 03 >> N '-- c ro CO a 03 wcd- C ro cj> 03 E 3 Lt. 03 "rO-- X 4-> to 3 O o 4-3 E 3 XEr?o o to r--r>o> 4r-o3 o DPMC-16112 LAM 000400 S B U S LAM 000401 OSHA STELTWASTEL 1981 ACGIH SHELL DPMC SUBSTANCE TWA TWA STEL HEALTH DATA/COMMENTS IO o -C o u CO JZ S <0 a> uc o -o OJ O f-- _Q -M CO c +-> 0) o oi 0) c -> 3 <D CL T3 * E Q- Q_ O) C 4-> <0 +-> E - Q_ &- Q. s_ r- O O co c\j S- o i- Cl co (0 <D >C OO id o un CO I-- Oo O ID O CO oo ID O id CO r- oo o ID o co I oo o LD o r-* CO a> c 0) r~ a CO 4-> c OJ 0J c CL c0 O X r-- 0J O JC >> oo 1 o CO >> o r-- 0) c o c 4-> <D 1- O r-- +->0-0 rO S- -- +-> CO </> r- 21 to s. o S- Q_ E to to Q-+-> s. a u o a; CL O +CO O 4> 1-- a A r-- r" > S- "O oc +J CO CO S- >> -r- -C o 4-> <D 4-> -i- *4- ro O 3*4r-- o i- -t-> O SCO -o +-> O <0 -r- O O i-- +-> c C s- x: -Q 3 CTf" O CO -Q C <y r- C <D a) E +j<iS- Q. co jQ o: a.+-> -rCO r-- CO MCVJ t E w r- * S- Q. o O O r- CL Q. 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LD +-> O SCTZI a> co +-> Q-*i~ CO X3 *0 - a; c +> (O +-> O u (U <D CO 4-> o <D LU -M *o I o ID CNJ oo ID O -- ooo o r-- LD ID ID CVJ o I o o o LD ID CNJ CD ^ ro p e n ig a n t CL 0) oc .c <D o r-- o CL = CNJ -D r--- o x CO < i-iZu 4-J O1 C <D r-- _ zc <D c >c L_ o Q. o OQ C +J S w 11 r-- ^ CL) U O O l O -J >,o <o CO ) o U Q- r-- "O n: f- O O r-- *--" O O^ CL) c CL) Ec CO r-- r-- E O cO c CO >> -C +-> +-> <D 0) T-- r* oO DPMC-16114 LAM 000402 OSHAS T E L T W A _____________TWA 1981 ACGIHS T E L T W A SHELL DPMC S T E L H E A L T H DATA/COMMENTS SUBSTANCE <D jQ to CO O Cl <z o QS- o to _Q ro CO o1 1 LO O ` <D C SE S- UJ -M > 0) "O a .c >> 4-> 5o 0 .5 o*s (D c oo 04- CU C7> Oc o a. s- rO to asT. a o tQo +-> to +-> L> CD 44- Q) O *r-- Z 4o-> 'fo- o s- 0) to 0) >> c Xo OSJ- (J (O +-> o <D CU S- to rco a * o s- to r- 3 f-- (O O *r- JZ 4-> +-> Qi-M o a> s- u CM o CO 00).0 S-Q CO*f- ro 030 E 0) . 3= CO O o* 4-> to CU >> to ro O0) CL to oolto O O stO O O S- ra oo r-- (D X 4- hO- 4<-0 a> 4-> 3 UJ O CL^OC o ro o o 1 1 to LO oo 1 LO LO CM I-- o oooooo o * r-- CO o oo oo P" oo o o o r-- LO 15.0 00.0 6 .0 oo i LO o 1 CM LO CM a o ooOoOO o CM CO oo O o oo O o r-- o LO oo *A r-- r* 1 i 1 1 1 1 o o 1 o o oooOooo to CO o o oo oo o p-- o LO oo o r-- o CM AA r-- r-- c r- s"O >> JZ o so J= (J n CL UJ a> "O u Oo a> c r-- o r-- O C r" E u >> a c sz E o C n-- *o LU rO r-- <D JZ a> (D a> CO o c c C i-- o c r-- > r-- p-- i-- JZ ro >, >> >> >> >> >^4-> JZ -C JZ -C ' -C JZ LU 4-> +> 4-> +> +J 1 UJ LU LU LU LU UJ LU E to to* 3o 4-> o O3 QJ E 4- 4<U- +O-> o cn 4-r> c!- tao> OJ 4(-O> C<o +*>+>CO t-- _Q CU S- E c s- > DPMC-16115 LAM 000403 HEALTH DATA/COMMENTS SHELL DPMC TW ASTEL - cn JZ -*-> (0 OS C a 3 <n *o c oo TQ.+J 03 in 1-- +-> in O 0) oo c (0 O z: u in rin o o as e -o c as >> j= 4-> as Qo 3 in as +-) O >> 0) r- M-- O *4-- a. a) as r-- jQ r* #-o in +-> in c as O as N a --> as r- _ c o r* r- as +-> o Cl >> E as oou m +-> _Q #0 -M as o r- as cr-- CL Q. in <n a> =s CO in +-> c as +> n >> o +> as *r-- Q. in OS O' t/> QJ (/> >> a> o i-- 0) O -- <4-- -l-> >4- E-tJ (U P Wt- C 1--0 10 <- "i- +J O -Q E r- -i- a> i- /> /> +J S_ </)</> 1/7 r- O O >> I-- Q_ </) -o QJ 0J 1" 07-f-> (0 t C 3+> 3 O (0 Z i-- (O <4- in o OS +M(D CO z o * -a o o r-- -Q k >> as o r- "D as IM as J o> 3 o r- o . u OS 1" a> CD o, o O So ^o CVJ as r~ -Q r-- in in o a O T" 4-> O O in .o as n 00 J>3> -o OiOnS QO. Q. <C &3= Q-H-1 LO OCD r-- <C o I CO .05 5 .0 100.0 mg m3 oo ioon mo o i i ooin o o r-- o oo o in oo in in ooo o o oin CVJ o ifr in o o o o io-- m oion o CO 1 ,i--n ooooo in oin oo oin o r-- "id- CVJ o It O CO OO * in CVJ STEL 1981 ACGIH S T E L__________ TWA OSHAS U B S T A N C E T W A 11i o O o ooin oOin Oo in o CVJ i1 as as +j as cas Q- as Xas re ii c as c N as "O >> 31 as Xr? as "Or- O r-- r<--+- - 3 O 00 as as u> CD oO "sO_ "O >> zn 3T ' i |i Oi in om O rO-- O o o o oo o o o m O LO r~ i o in CVJ O as +-> E in _DQ_ as 43- -3O in "D aass as e -J U3. u r- *3 as as os LaUs in as as -o n oX r-- -O O fTM -oC o o _as U3. as o i-- O r-- +J X f-- ea: LU o cC r-- E >) 4-> 3 a>>. o 3 CL iTM ***** O tn CD ass: 2 in as ians as as "aOs r- X o r-- >> 4-> O +i-n> 3 o JD iOn QiOn. CL Oin cn in r0 r0 CD as itn" as -- Q -- --< M --i 2^ s: DPMC-16116 LAM 000404 XJ C7> O cc "O C fO o- C *f~ 03 lO u *3 . 3 QJ-D V) Q3 X3 in moc in o c o s- o o s- o C a-r C a_-r- 00 oo * l/) +fO-> d 0/)}!i--n 4->- +J ** W fO W*r &. 03 in +j >) O C >> o c d (DUO) a; u o CZi &- a S- u o <o c CL O (O c +> z o s- 4-> z: o +-> L3 o in 4-> u d UJ C<o P JOZJ J<O0 c x: <a +-> cn 4-> <O0 --Cf- +J tO*r- o x: U S- t- s- M5- -+Cj 4(-O> in s- x: +-> M +J fO * in a) G> >> 03 J2 03 T* XJ i-- in C -Q in <0 TOm CL C in r- O c JX. 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Ol to to o a oc 00 ISI r- P OS-l| oto `xtoo: c3r QJ *o s<c *o c as a> +-> to "O 3 to +J 3+J Or- 3 </>**- e o o "O 0) -C > TC3D OC) CED CD "O <CUJ "O i- i- U -wrre-s g 3 ai -r- -a 3 o E <o c Of-- -O as re c asm c X>i> "O CD to O Ol O SCL <c 3 -C hu To3 o -0Q3 00 f>l*0jf-i0.t LU o W3 O S- 4-> O -l-> E o o o^ T -P T3 CD 0>"0 P hh CD i-- CD CD U to r-- to E O O res O O re <C 4- -O Ur J 0Q.-3--=* O COD LO C 0-8 o o o CM o .t o LO x: CD "0O) -a *r- r- to </) +-> Cr- 3o o oo o o o oo to oo o-- to io-- O o LO o o o oo oo o LO oo oto o o o oo CM o o o CD t. CD oc o cCuCDD Cp>O> 3 PrCO ca; C3D '1--n f--O CCcDJ CtoQ r-- Z3O' IP--ro Pto f--O a3 3 LL. acr*> f"--O CD 3 PfoO 1-- CcD CD r-- X -P CD OSno-- x: CJ r-- s. 1-- DPMC-16118 LAM 000406 OSHA 1981. . . . AC6IH ' - ' ' l I.SUBSIT 'A -NCE-- -- ` ' "" TWA 1' ' STEL .........--" ` TWA STEL .1 SHELL DPMC ...T....W...A.. 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