Document YZxmeD3dQXKrNZ220N032gjN

)is* A 50983 DOW CHEMICAL U.S.A. TEXAS DIVISION FREEPORT. TEXAS 77541 ENVIRONMENTAL HEALTH REPORT EVALUATION OF ASBESTOS EXPOSURE TO INSULATORS AT GLYCOL "A" file no. A18-23 nirc November 21. 1973 author R.L. Silverthosne- CHECKED Summary Contractor insulator exposure to asbestos fibers were evaluated during the removal of insulation on two columns at Glycol "A". The timeweighted average (the average exposure of asbestos fibers to employees during an eight hour work day) and peak exposures to asbestos fibers are within acceptable levels, although the peak exposures could approach maximum allowable concentrations due to the variability in the asbestos handling procedures. The employees should continue to wear respiratory protection during the handling of asbestos, and every effort should be made to wet down the asbestos insulation before and during removal. GO --I CD CD Distribution F. A. Newman A-510 /File CD UQ. AN OPERATING UNIT OF THE DOW CHEMICAL COMPANV i 01 I SI001S File No. A18-237 -2- INTRODUCTION Environmental Health Services was asked to evaluate the exposure of Insulators to asbestos fibers during the removal of asbestos insulation from two reaction towers at Glycol "A". METHODOLOGY Breathing zone and general area air samples were collected on 47 mm-diameter(.8 micron pore size) membrane filters at a sample rate of about 2.0 LPM. The air pumps used were M.S.A. permissible portable personnel pumps. The fibers on the filters were counted by the standard phase-contrast microscopy technique at 450 magnifi cation by the Texas Division Microscopy Laboratory. DISCUSSION Table A shows the insulator exposures to asbestos fibers based on an eight hour work day when insulation is being removed from reaction towers. His time weighted average and peak exposure are within acceptable levels based on the present OSHA standard. Table B shows the results of the sample analyses for the various Insulator operations. The highest asbestos fiber concentration, up to 1.29 fibers/ml, were found during the actual removal of insulation by the employee. Because of the variability in the asbestos handling procedures the employee peak exposures could exceed the allowable ceiling concentration; CONCLUSION 1. The employees time weighted average and peak exposures to asbestos fibers are within acceptable levels. RECOMMENDATION 1. Ashestos insulation should be stored in plastic bags, tagged and sealed for disposal. 2. Employees who work regularly with asbestos should have clean work clothes daily. (Work clothes should not be taken home for laundering). File No. A18-237 -3- RECOMMENDATIONS (continued) 3. Continue the work practice of wearing respiratory protection whenever asbestos is handled. 4. Employees with significant exposure should shower at the end of the work day. 5. Water should be used to wet down the insulation before and during the dismantling operation. This will reduce the possibility of asbestos fibers becoming air borne. 6. Environmental measurements should be made annually to determine the adequacy of precautions taken. 7. The contractor employer should be familiar with Subpart G, section 1910.93a, of the Federal Register. 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MO. iMTI A 1* - 11-7 C** t*0e.Csv 1 A ~ ' S' O 1 >?-/ to t /O/z/73 MATEMAL LAMPLINO METHOD TtAFPSNO MEDIUM A 1 l t 3 ftfl lOUVUHT WJWII jTTFlOF tOWFIMHT {Cttl,,la> *) 5")u | FLO* IMMCATO* MTTiaO lUMPLt FLO* **T(' OUTHOC TEMP. -F/fi'r,, INSIDE TEMP. -/3j. Vj. i* --ibJ.A--?*,... s' ;i (Ventilation, etc.) .! ___________ !l. % SAMPLE CONTAIN!* MO. NO. P / C, /4"6 b a<, <. DIICOIPTION OP UUPII TIM STAflT iNdtaefT COMCIMTIATION o A ~b * tM * 21_. A/o ps1^/i/i ifj i / *> >o 2-Tj.t . >" A, f*st ** jvi~t ~6*0 A v * * /cV 1/ i 5 , L l e. c/o rf. 4 i l i j' <_ A ^ o w jcjyf ______ bis k. m l<- . 1 a 1 k t. sj -L tl if 0 lm a is H. 14s* h as ^? 7 -1^ * * r i J * ir s . a b 9 is ~t j i Apply , .J I.U * CiS ~6 a yi i* 0 I*s ,!! ST00I5I 14 ?L 6 Ah bait. + ** Z Z ` 2r rs? 30 At. 2-/7 * / O -O- \AS 4 v b. t s i "fr c-o^rwy <// tv .f 4ud /<*+ T ** ^ L iM **-<_ ^ (J r / 4r l* > t ^ t *-t* .4- i y^"! 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ENVIRONMBNTAL RESEARCH .MPLE RECORD RtLC Mttttlfl A /*- 2 V7 PDOCIU A * *~6 va rjiav LOO. NO. OATC Itt s & A ~ / S' 0 / A-iSroi >oh~h^_______ MATERIAL UMPUNO MCTHOO TRAPPING MCOIUM A 5 L15 s .e.l(olait. Fr/<<* ' jut * > t! t ?0 <r *, IOUVMRWT MUMAIR TTM OP EQUIPMENT IPWOV INDICATOR ICTTMO wm.1 PLOW RATE outsoi Tiur. lutuoi tnw. M SA Pumps__________________ i %______________ *. 1 *F SAMPLE COMTAMR ML MOL p</**p ?? S A l*+t DISCSIf T10M Of SAMfLI ^ iau a 5 ^ . 01 Ut * -&T e. \4J* I/U-&J f r A-it.'* X S^atf-t a.J . TIME STMT INOT COMCINTtATION i <' h /0 J C . 1. it -f/ 1r S T 0 0 I5 I16 , i | i ! na Him* it i.ii. i-u mo R. L. Silverthorne Safety and LP, B-101 THE DOW CHEMICAL COMPANY TEXAS DIVISION CENTRAL LABORATORY FREEPORT DESCRIPTION OATS or SAMPLI REPORT OF ANALYSIS Atr Filters (Insulators *1.8) 10-2-73 LM OATS THIS HCPOMT. 10-17-73 1308-00020 Particles and fibers were counted on eight air filters from areas which involved the use and handling of asbestos. Individual counts were made for particles greater than 2. 5 microns, fibers 5 microns to 10 microns, and fibers greater than 10 microns. The numbers reported are as total number of counts per filter square. ST00I5I 17 Yr. LDM dv SlCNCO. Ad. /2?a/ STOO15118 DOW CHEMICAL. U.S.A. TCXAS DIVISION /3QSCHARGE NO.______ SUBJECT J>JR___ EjA SHEET, ,OF_ AUTW. NO.. FILE NO. BY_ E ___ dat:. .CMCCXCO BY_ `3 v'.?- "A? SflAJPAS. J^ESCR/RT/OA/ + 35/9 TE &/ Xnsulctto'rs A-/80J /o-2- 73 Nc. oF T~2lS'jQ>S / /$qa.uore trZ Xr>Ju/>*tors A-IQGI 10-2- 73 It3 Xn-su/ators io-2-73 /Square A- /80/ 99 4 Xnsulatot'-s /0-2- 73 /square A -/So) r\ 3 * * it Xnsulaton /o - 2 - 73 A-180} #0 Xnsulators /0-2-73 /s^uart*. A-18OI /&<?*/<? re. 7 Xnsulafors /o-2-73 A 'J8of /stg-tarz. ft3 Xnsulators /o-2 - 73 A -/BO/ /square / Partic/aS >SL^ /J 49 /O T 4Z8 /a 0 2oo 900 /3 V 6>S-f .-- 4Z O / $ S472 930 F/QERS S/x. -- /0/u. / F'&/?< > - M- (0 3 18 Jl/ O ~ 8 / (, ^4 * 8 . "r 5/C> / i OZ O 0 8 O. !Z O /e <.. \ 0 v? ^ *5<* /s cw -- / 0 /(wcirc, /&ruci re.