Document YDgVRJdmXKwaQyz0g20DjNJmk

Ou Pont Chemicals aoaoFR l Revised 23-Sep-91 * - *1. "FREON" 11 # MATERIAL IDENTIFICATION Corporate Number DU000026 "FREON* is a registered trademark of Du Pont. * ' . Printed 09-Apr-92 "J - r - Manufacturer/Distributor Phone Numbers Chemical Family Trade Names and Synonyms Du Pont Registry Number Formula '' Molecular Weight TSCA inventory Status NPCA-HMIS Ratings Du Pont 1007 Market Street Wilmington, DE 19898 - Product Information Transport Emergency Medical Emergency 1-800-441-9442 CHEMTREC: 1-800-424-9300 f-000-441 -3637 HALOGENATED HYDROCARBON F-11. CC0119 DP2Z-97-3 CCI3F " -u -'** ` 137.36 Reported/Included Hearth: i Flammability; 0 Reactivity: 1 Personal Protection rating to be supplied by user depending on use conditions. COMPONENTS Material ______________________________________ CAS Number______Percent METHANE, TRICHLOROFLUQRQ- ("FREON* 11)75-69-4100 * RMutattd am a Toxic Chemical under Section 313 qt TWo III ot the Superfund Amendments and Reauthonzaoon Actor 1989 and 40 GFR part 372. (oonbnued) Printed on Recyded Paper 00 A 061 610 CQNFJOFNT T Ai # PHYSICAL DATA Boiling Point Vapor Pressure Vapor Density % Volatiles Evaporation Rate Water Solubility PH Odor Form Color Density * Appearance 23.9C (75F) 14.7 psia at 25 deg C (77 deg F) 4.9 (Air -1.0) 100 WT% (CCI4 -1.0) Greater than 1 0.1 WT%at25#C(77*F) Neutral Slight ethereal Liquid Colorless -- 1.48 g/cc at 25 deg C (77 deg F) : Clear i" -G 1IH Itrauuxmy____________ stable. However, avoid open Karnes and hign temperatures. incompatibility Incompatible with alkali or alkaline earth metals* powdered Al, Zn, Be, etc. Polymerization Polymerization win not occur. becoapoaition composition products axa hasardous. "IUXON" 11 oan b daccnpoaad toy high tanpenatusaa (pan flaws, glowing natal eusfaaas, ate.) Zonalng hydrochloric and hydrofluoric acid* and posaibly carbonyl halidaa. 'll FIRE AND EXPLOSION DATA Rash Point Will not bum Method TOC Flammable Limits in Air, % by Volume LEL Not applicable (JEL Not applicable Auto ignition Not determined Autodecomposition >593*0 (>110O'F) Fire and Explosion Hazards Drums may rupture under fire conditions. Decomposition may occur. Extinguishing Media As appropriate for combustibles in area. Special Fire Fighting instructions Self-contained breaming apparatus (SCBA) is required if containers rupture and contents are spilled under fire conditions. (continued) C 2090FR Page 2 DO A 061611 CONFTDFNTTAL ^3SSS?SSBK!ECS33rS!tviJJB7 >^**au<Lnt.*u *riu. .fcv.. >,:ljU\,.SliJVjAU. HEALTH HAZARD INFORMATION PRINCIPAL HEALTH HAZARDS (Including Significant Rout**, Bffacts, Symptoms of Ovwraxposura, and Medical Conditioaa Aggravated by Exposure) Inhalation of high concaatratieaa of vapor ia harmful and nay causa heart irregularities, unconsciousness, or death. Intentional misuse or deliberate inhalation nay eauae death without warning. Vapor reduces oxygen available for breathing and ia heavier than air. Causes skin and eye irritation. ANIMAZ. DATA: Inhalation 4-hour LCSO: 26,200 ppn in rata Oral ALD 3725 mg/kg in rats The compound ia not a akin irritant but ia a aild ey irritant. Toxic effects in rats exposed by inhalation Include central nervous system and anesthetic effects at high concentrations. Concentrations of 0.354 and higher caused cardiac sensitization in dogs. Various cardiovascular and circulatory abnormalities have also baan reported in other animals. Changes in the lungs, liver, brain and spleen were observed In a study of rats exposed' by inhalation to 12 tines the TLV. In another study at 25 times the TX.V, rats, guinea pigs, and cats axhibltad no microscopic evidanca of damage to the heart, lungs, kidney, liver or spleen, exposures by ingestion os skin resulted in no evidence of tonicity in rats, dogs or rabbits. 8DMAH HEALTH EFFECTS; Human health effects of overexposure by eye contact nay include eye irritation with discomfort, tearing, or blurring of vision. Skin contact with the liquid aay cause drying f the skin with repeated contact resulting in mild skin irritation with discomfort or rash. Ovarexposure by inhalation may cause temporary nervous system depsessi n with anesthetic effects such as dizziness, headache, confusion, incoord<nation, and loss of consciousness; temporary alteration of the heart's electrical activity with irregular pulse, palpitations, or inadequate circulation, or the effaces of exclusion of oxygen with grossly excessive exposures. Ingestion may include nonspecific discomfort, such as nausaa, headache, or weakness. Individuals with preexisting diseases of the central nervous or cardiovascular system may have Increased Susceptibility to the toxicity of excessive exposures._________________________ Carcinogenicity None of the components in this material is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Applicable Exposure Limits METHANE, TRICHLOROFLUORO- {'FREON" 11) AEL * (Du Pont) None Estaoiisneo TLV (ACGIH) 1,000 ppm, 5.620 mg/m3 (Ceiling) PEL (OSHA) 1,000 ppm. 5,600 mg/m3 (Ceiling) * AEL m Du Forts Acceptable Exposure Lmn Where govemmemaiiy imposed occupational exposure Mis wmcfi are lower than the AEL are in effect, suen limns shall take prececiencs. Safety Precautions Use with sufficient ventilation to Keep employee exposure below recommended limits. cr (continuec \ 2090FR Page 3 0 A 06361? CNFrOftnttai. FIRST AID 'W-Wr xtmxasxoif If high concentration* are Inhaled, lirmerllately to* fresh sis. Keep peseoa calm. It net bxeathia?* ffi** " artificial respiration. j; XX breathing 4s difficult, give oxygen. Oil a physician. -A IC , c j, f , . SKIN CONTACT r* In ease of skin contact, flush skin with plenty f sates for 15 minutes. Get madl cal attention if Irritation is present. - - ' t-j KTK COMtkCT '/ In ease of eye contact,'isnediately flush eyes with plenty of water for 15 minutes. Call a physician. mcassTioM If swallowed, no speeific intervention is indicated as the compound is not likely to be hazardous by ingestion. However, consult a physician if necessary. NrtM to Physician e> -- ' V- BCCQUS# 8f pflSSibl* diituibaiiww uf cardiac rhythm, catecholamine drugs, such as epinephrine, should be used - with special caution in situations of emergency Ufe Support Jo H ... . PROTECTION INFORMATION ^ ; -- y - . Generally Applicable Control Measures and Precautions * .- Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should os used when large amounts are released. Mechanical ventilation should be used in low or enclosed places. Personal Protective Equipment . . Impervious gloves should be used to avoid prolonged or repeated exposure. Chemical splash goggles should be available for use as needed to prevent eye contact Under normal manufacturing conditions, no respiratory protection is required when usina this product. Self-contained breathing apparatus (sCBA) Is required If a spill occurs. t**- - _ <C% DISPOSAL INFORMATION Aquatic Toxicity Spin, Leak, or Release ;*-? **l,r *`-v "FREON" 11: 96-hour LC50, rainbow trout 190 mg/L NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with dean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during dean up. Ventilate area. Do not flush into sewers. Dike spill. Collect on absorbent material and transfer to steel drums for recovery or disposal. Use self-contained breathing apparatus (SCBA) for large spills. Comply with Federal, State and local regulations on reporting releases. Waste Disposal Redaim by distillation or remove to a permitted waste disposal facility. Comply with Federal, State, and local regulations. (oonbmwd) 2090FR Pegs! c A 061 61 ^ CqNFID^NTfAL SHIPPING INFORMATION DOT Proper Shipping Name Hazard Class UN/NANo. Shipping Containers ;* HAZARDOUS SUBSTANCE, UQUIO, N.O.S. (TRICHLOROFLUOROMETHANE) ORM-E NA9188 TankCar Tank Truck Drums Reportable Quantity : 5000 lbs/2270 kg -FREON-11 is NOT REGULATED AS A HAZARDOUS MATERIAL BY DOT, IMO OR ICAO IN CONTAINERS LESS THAN 5000 LBS. STORAGE CONDITIONS Clean, dry area. Do not store above 125 deg F (52 deg C). TITLE m HAZARD CLASSIFICATIONS Acute Yes Chronic No Fire Reactivity Pressure No NO No LISTS: lxtna*Xy Buctcdoua Subafci CXRCIA Hazard Substance Toxic Chemicals -Wo *M -Tan ADDITIONAL INFORMATION AND REFERENCES "rRSOM" 11 contains ary low level* of carbon tetrachloride and cblocotoa, chemicals known to the State of California to cause eaaear. The data in this Materia) Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other marenai or in any process. Responsibility for MSOS: W. J. BrocK Du Pont Chemicals P. O. Box 90709, Chestnut Run Wilmington, DE19880-0709 302-999-5072 * Incfcate* updated saaion. 2090FR End of MSOS Pages 00 ^ O6I6I4 CONFTDFiNTTAl