Document YDYYwJOwnx9dO3zqmNzvm4e2k
Taft/ 1717 Die Highway, Site S10/Coington, Kentucky 41011-4704 1717 Dixie Highway, Suite 910 / Covington, Kentucky 41011-4704 Te 859.331 2638 Fo: 513.381 6613 Tel: 859.331.2838/Fax: 513.381.6613 wtaflavicom www.taftlaw.com
Rosen sor ROBERT A. BILOTT ferns 859,547.4306 rut bilott@taftlaw.com
JJaannuuaarryy 33,,22001188
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potentially-relevant, historic records that might not otherwise be available to the State.
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TaftStettiis Hollister LP Taft Stettinius & Hollister LLP -- 21807977.1
Chicago Cincinnati Cleland Cambs. Dayton /ndianaalls Northern Kentucky Phoenix Chicago / Cincinnati / Cleveland / Columbus / Dayton / Indianapolis / Northern Kentucky / Phoenix
11447711..00000011
Exhibit 1471
State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862
SSTTAATTEE 0077554433095588
AAlleetthheeaa MM.. HHuuyysseerr JPPaaanggueea22~ 3,2018
DuPont ng efCuts oy DuPont during the course of DuPont's long-term business relationship with 3M with
respect to certain perfluorochemical issues and products.
Encls.
bert A Bilott
so 21807977.1
147711..000002
J STATE 07543959
3M General O~Tc~s
SL Paul. MN 55144.-1000
6~Z 733 lifo
17~0
.
3m
SNR MATERIAL SAFETY
DATA SHEET
Copyright, 1997, Minnesota Mining and Manufacturing Company.
CUE EY i em a All rights reserved. Copying and/uP downZoading of this information for
the purpose of properly utilizing 5M produc~s is allowed provided %he~=
BE eR RR has at, l) the information is copied in fulI with no changes unless prior agreemen~ EEEEEE it ovine ssid is obtained from 5M, and
2] neither the cop~ nor the er~glnat is resold or o~herwise distributed ~ith the intention o~ earning a profit ~hereon.
DIVISIOM= SPECIALTY CHEMICALS DIVISION TRADE NAHE:
HE me srerevresaentteorss FC-118 FLUORAD ~rand Fluoroche~cal SuPfactant
BnaEreRs TnelCr FSrCEooEHRy ID MDMBEH/U.P,C.:
98-0211-q8~2-9 98-OZll-80~Z-q
98-0Z11-8858-0
00-51155-02697-7 00-51155-10865-5 00-51155-10971-7
ELH 98-0211-~885-7
98-0Zl1-8083-5
SINE 00-51155-027~5-~
OQ-Sl155-10918-Z
SBPERGEDES: AUGUST Z~, 1996 DOCUMENT: I0-~221-7
= Te I. INGREDiEnT
WATER ....................... ~ ........
AMMONIUM PERFLUOROOCTA~OATE ..........
Spm BE oe AMMONIUM PERFLUOROHEPTANOATE ......... AMMONIUM PERFLUORQHEXANOATE .......... AMMONIUM PERFLUOROPENTANOATE .........
C.A.S. pO. 77~2-18~5
~825-Z6-1 61~0-~5-4
21615-47-~
68259-11-0
PERCENT
80
18
0.1
1.0
0
O.I
0.1
1.0
PHYSICAL DATA
orwn ess BOILING POINT= ...............
VAPOR PRESSURE: .............. VAPOR DENSITY: .......... ~...
WEERDE 180 C (Typical)
18 mmHg Cole
0.62 Air = !
Calc ~ 20C
EVAPORATION RATE: ............ < 1.0 Butyl Aeota~e = 1 SOLUBILITY IN WATER= ........ oomplete
Be al SP. GRAVITY: ................. I.IZ Water = 1
PERCENT VOLATILE= ........... 8~ ~ pH: .......... ~ .............. ca. S
fo YISCOSITY= .................. N/D ~ELTING POINT ................ N/A REA NGG 65001 Lah colored Mauka shioht oder. APPEARANCE AND ODOR: Light oolaPed liquid; slight odor.
Cr rm ---- I -- 3. FIRE AND EXPLOSION HAZARD DATA
PR. Tm es, sess: FLASH POINT= ................. > I00 C Setaflash ~LAMMABLE LIMITS - LEL: ..... FL~J~MABLE LIMITS - UEL: ..... N/A A~TOIGNITION T~PERATURE: ... EXTIMOUISHIN~ MEOIAr Water, Carbon dioxide, Dry chemica!, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear fu]! pro%active cloth~ng~ including heIme~
sel~-cen~ained~
I. Abbreviations: 3 AH, N/D - Not ~aterminad YhN/A - Hot Applicable
EID599980
11447711..00000033
STATE 07543560 STATE 07543960
3M General Offices
3M Centcr
St. Paul, MN 55144-1000
_ HATERIAL GAPEIY
612 733 |110
DATA SHEET
3M[EE MSDS: FC-11~ FLUORAD Brand Fluovochemleal Su~Zactan%
a
FEBRUARY 7, 1997
--TE-------- FIRE AND EXPLOSION HAZARD DATA (continued}
positive pressure or pressure damaed brea~hing
SIE I JE pro~ec~Eve coverEng ~or exposed areas of the head.
erie UNUSUAL F~RE AND EXPLOSION HAZARDS:
Pa See Hazardous Decomposition ~ec~on for produe~s
PAGE: 2 of 6
o
INCOMPATIBILITY - MATERIALS TO AVOID:
Ho~ Applcable
HAZARDOUS ~OL~ERIZAT~ON~ W1~ No~ Occur
A HAZAEDO~S DE~OHPOSIT~0N PRODUCTS: te wt tomes vn Carbon Monoxide and Carbon D~oxide~ Oxides o~ Ni~rogen, Hydrogen
Fluoride, Ammonia.
C-- 5. ENVIRONMENTAL ~NFORNATION Eee SPILL RESPONSE: aaL 0 Ts SO we Refer ~o o~her sections of ~his MSDS ~or information regarding
physical end health hazards, respiratory pro~ac~ion, ventilation, and
personal pro~ec%ive equipment. In th~ U.S.A.~ cal~ (~12) 755-1110 or
(612) 755-6~00 ~er Z~-houP sp11 assistance. Con~a~n sp~ll. Cover
H~%h absorbent mateP~al. Col~ec~ spilled ma~er~al.
EE St Sle rt af, Sa, For sp~lls ~o ground~ Collee~ contaminated soil. Pump contaminated
TE er EE approved containers, and seal, For spills %0 ground or surface
~ur%her needs.
RECONNENDED DISPOSAL:
PE rstE titan wes a combustible material.
Combustion ppoduc~s Hill include HF.
RE Yemetet Pass ontaminated water through anion exchange resin.
con%act 3H ~or assls%ance.
If necessary~
EEE on oe ga ENVIRONMENTAL DATA: Data for product sol~ds: Chemical 0x~gen Demand (COD): Nil
(.000700g/g). 3~ochem~cal Oxygen Demand (BOD20): Nil; 96-Hr. LCBO, DZueg~l Sunfish {Lepom~s macroohlrus); 569 mg/L~ 96-Hr. LCb0~ Fa~head
HE EE nt SL EL Be Hinnow(P~mephales prome]as)~ 766 mg/L; ~8-HP ECb0~ Daphn~a magna:
mg/L; l~-Day ECSO (cell dry waigh~, Green Algae (Selenastrum
FE RE RR capr~aornu%um) 75 mg/Lo $o~! Adsorption Coe~ic~en~ (Koc): 17~
~nd~ca%es very h~gh mobility. (Study used a sandy loam soil).
REG~ATORY INFORI~ATION:
_"TTUTPTWMTM Volatile Organic Compounds= VOC Less HZO& Exempt Solvents=
Abbreviations: N/D - Re% De%ermEned N/A - Mot Applicable.
EID5999~I
11447711..00000044
STATE 07543961
STATE 07543961
spe MATERIAL SAFETY
DATA SHEET
= : | HSDS: FC-118 FLUORAD Brand Fluo=oehemical Surac~an~ FEEL 3 gn es erst rac no sors | FEBRUARY 7w 1997
PAGE~ 3 of 6
I S~nce regulations vary~ consult applicable regulations uP authorities Br rE STE: BRI Se before d~spoSa~o U,So EPA Hazardous Waste Number = Hone Not UoS.
EPA Hazardous).
TETINRTALE The components of ~his produc~ are
registration Pequiremp~ta o~ TSCA~
BETES in compliance with the
EINECS, CDSL and AICS.
chemical
EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No
REACTIVITY: He
ACUTE: Yes CHRONIC Yes
6. SUGGESTED FIRST AID
EYE CONTAGT~ Immediately f~ush eyes wi~h large amounts of water for at least 15
minutes. 8et ~mmedla~e medical a~-~en~icn.
SKIN GONTACZ: Immediately wash skin Hith soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur~ cell a physician.
Wash contaminated c~o%hing before reuse end dispose of contaminated
If s~gas/~ymp~oma oocur~ remove person to fresh air. If
rm Tar I en i 0 s~gns/symp%oms, cont~nue~ call a physician.
IF SNALLOWED:
70kSodiee vonbting. Brink (xo siasses of water. Call a piyicieen e Do not ~nduoe vomiting. Drin~ ~Ho g~aases o~ ~ataP. Cal~ a ph~s~ciano
7. PRECAUTIONARY INFORNATION
PRITETMiteck. eae vented amgstes. EYE PROTECTION: Avoid eye contact.
Wear vented goggles.
SKIN PROTECTION: Avoid skin contact, Wear appropriate gloves when handling this
material, A pair Of gloves made from %he ~ollowing material(s) are
rooommendedl butyl rubber, Use one or more of %he follow~ng
ERREERE personal protection ~tema as necessary to prevent skin contact; head
cover~no~ coveralls, Protective garments (other than gloves) should be made of either of the following ma%er~alst polye~hylene/polyv~nylidene chloride (Saranex)
Coverall made of Tyvak(r). Wear rubber boots when cleanino up spills.
rE eps morT ecrone: r oe ncaa VENTILATION PROTECTION: Use with appropriate local exhaust ventilation, Provide sufficient ventilation %o maln%ain emissions below recommended exposure limits, I~ exhaust ventilation s not adequate~ use appropriate respiratory pro%action,
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mls%s or spray. Avoid breathing of
Abbreviations: N/D - Not Determined R/A - Hot Applicable
EID599982
11447711..00000055
---- STATE 07543962
3m
pre---- MATERIAL SAFETY
DATA SHEET
SL Paul. MN 55144-1000 612 733 111~
MSOS: FC-11B FLUORAD B~and Fluomcchemal Su=Za~"t:ant
r--m ------------------ FEBR~AR~ 7, 1997 PRECAUTIONARY INPORHATION
gcontlnued3
PAGE: ~ o~ 6
airborne ma%er~al. $alec% one o~ %he ~ollow~ng NIOSH approved
respirators based on e~rborne coRoeR~ra~on o~ on%amEnan%s and in
accordance w~%h OSHA regula%~ons= ~ul~-~ace h~gh-e~c~eno~
ATR Bh TI AIS resp~ra~or~ ~u~l-~ece suppl~ed a~r respirator.
PREVENTION OF ACCIDENTAL INGESTION: Do no% ea%, dr~nk or smoke when using %h~s produc%. Wash exposed areas %ho~oughly w~%h soap and water. Wash hands a~%er handl~ng and before
RECOMMENDED STORAGE:
PEA SLIT so ston ite win is Do no% s%ore con%aJners on %he~P s~des. ~eep con%airier closed when Ro% ~n use.
S%ore a% room %empera%ure.
FIRE AND EXPLOSION AVOIDANCE: Keep container %~ghtly closed. Ho smoking wh~le handl~ng th~s
EIEFERIEE sews maw ma%erEaI.
OTHER PRECAUTIONARY INFORMATION:
HHIS HAZARD RATINGS= HEALTH= 2 FLAMMABILITY= 1 REACTIVITY= 0
PERSONAL PROTECTION= X (See pPecau%~ons, sec~on 7,)
EXPO~JRE LIMITS
I INGREDIENTS
~AL~E
WATER ................................ NONE
AMMONIUM PERFLUOROOCTANCATE .......... 0.01
AMMONIUM PERFLUORONEPTAHOATE .........
0.1
EEEEEL us EE AMMONIUM PERFLUOROHEXANOATE ..........
O.1
AMMONIUM PERFLUOROPENTANOATE .........
0.i
D~IT NONE
mg/m~ mg/m5
mg/m3
mg/~
LEBEL M SKIN NOTATION: L~s%ed substances ~ndica%ed w~%h "Y" E pln %he pote~%~al con%P~hu%~on %0 %he overall exposure by
~nclud~ng mucous ~embPane and eye~ e~%heP b> airborne
TYpE AUTH
NONE NONE
TWA ACBIH Y
TWA SM
Y
TWA 3H
Y
TWA 5M
Y
under SKIN refer %he cu%sneous Pou%e o~, mope par%~culaPly,
aia? SRR Th LE ET Hi. SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: A~er~can Conference o~ ~oveP~m~%al Indus%P~al
er MEBE ee ow | AIHA= American ~ndus%P~al Hyg~ne Assoc. Workplace Env~ronmen%al
-. 5M: 5M Med~ca~ ~epar~en~ Guideline
- NONE= None
Exposure
teve~
rm 8. HEALTH HAZARD DATA
EYE CONTACT:
No ~oX~c~%y da%a fop ~he solution. Ammonium perluoroalky]
TREE aTEES ser | carboxyla~e can be irr~%a%mg ~o %he eye and may cause eye injury rom airhorRe exposure. ET et tent SKIN CONTACT: tnt eet i ty tr Nay be absorbed %hrou~h %he skin and perm,s% n %he body fop an
Abbrevia%ions: N/D - No% De%ermEned N!A - Hot App]icehle
To
I
| snes EID599983
|
11447711..00000066
STATE 07543063 STATE 07543963
a MATERIAL SAFETY
DATA SHEET
3mFE HSDS: FC-118 FLUORAD Brand
FEBRUARY T, 1997
SE8. HEALTH HAZARD DATA
3M~entcr ~L PauI, MN 55144-1000 612 733 !110
Fluorochemica~ Su~fa=~anb (on~Lsued)
PAGE=
. a
5 oF 6
extended time,
No ~oxcity da~a ~or the solution. Ammonium pePfluoroalkyl
carboxylate is slightly toxic when absorbed through the skin; it is non-irritating to the skin.
ENret by etn sd ri inh es fr1 tid ~NHALATZON: Hay be absorbed by inhalation and persist in the body for on ex~ended
time.
:.
Me toxicity data ~or the soZution. Ammonium
BSE EET iy carboxylate may cause respiratory system irri~atlon ~Pam inhalation;
can be considered moderately ~oxie by inhalation on a single exposure;
FEESRRS a, a median letha~ =omcen~ra%~on ~op a q-hour exposure ~n the e~bino EE EE E ER RA is 980 milligrams per cubic meter. Re,eared inhalation exposure
produced liver changes and elevated blood organo~luoride levels in
IF SWALLOWED:
TT -------- Ingestion is not a likely ~oute of exposure to th~s p~oduct.
opt tei, gt He {oxicity da~a ~or the molu~ion Ammonium perfluoroalkyl SE ER EE, earboxyla~e ~ considered moderately ~oxLc ~rom a ~ingle ora~
CANCER:
"be madTE WARNING: Contains a chemical which can cause cancer. (]B25-26-1) (1983 and 1995 studies onducted ~o~n~ly by 5H and BurghS).
ESET ig, tote1 TL LTE Ammonium perfluoroalkyl carboxylate was not mutagenlc in invitro EE ror in SLR mutageniclty assays. Did no~ caUSe cell transformation in a mammalian
REPRODUCTIVE/DEVELOPmENTAL TOXZRS:
Ammonium gerf~uoroalkyl carboxylste was not tera~ogenic in rabbits by
TREE]A a SrA oral administration and Has no~ terategenic ~o rats by garage and
inhalation exposures.
Sm SECTION CHANGE DATES
HEALTH HAZD. DATA SEGTION CHANGED SINCE AUGUST 23~ 19~6 ISSUE
|
Abbreviations= N/D - No~ Determined N/A - Not Applicable.
EIDS99984
11447711..00000077
STATE 07543064 STATE 07543964
os MATERIAL SAFETY
DATA SHEET
3M Center
St. PauI, MN 55144-I000 612 733 1110
17~5
3m
---------------- M~DS: F0-118 FLUORAD B~and FEuo~o~hemcal Surae~an~
FEBRUARY 7, 1997 SECTZON GHANGE DATES
PAGEs 6 of 6
TL -- | Abbreviations= N/D - Not De~ermEned N/A - Not Applicable
@
The Enfarmaton En thEs Materia Safe%y Data Sheet (NSDS) is believed to be
correc% as of the da%e issued SM MAKES NO WARRANTIES~ EXPRESSED OR IMPLIED, INCLUDING, OUT NOT LIMITED TO, AHY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE DR COURSE OF PERFORMANCE OR USAGE OF TRADE,
User is responsible for determining who%her %he 3H product is fi~ for a
par~JcuiaP purpose and suitable fop userts method of use oP application. Given %ha variety of factors %hat can affec~ the use and application of a 5M product;
some o~ wh~oh are uniquely Hi%bin %he user's knowledge and control, it is
essential %ha% %he user evaluate the 3H product %0 de%ermine who%her i% is fit
unre edm Ges L SA S for a particular purpose and suitable for usePIm me%had o~ use oP application.
3H provides ~nformation in e~ec~ran{c form as a service to i~s customers. Due to the remote possibility tha~ electronic transfer may have resulted in errors/
~ts completeness oP accuracy. In addition, ~n~ormation obtained from 8 do%abase
may no% be as current as %he information in %he MSDS available ~irectly ~Pom 5H.
EID599985
11447711..00000088
ssn STATE 07543965
#vomComsasrtuGyrm0,7iovwnmiesst kg sd tog Conc ~opRdght, 199"7, MinnesOta Mining and Manufacturing Compang.
Fill HghJs reserued. Copylng and/or downloading nf this
eito a eso eps aniragts Information for the" purpnse of properIg utilizing 5M prnduct$ Sime pied at. ls allowed proulded that: 3 ae ro aiem I uluta hno changn es ies Z) thB InformatiOn Is copied In FuI~ witl~ no changes unless riorseaSoamned e om 4nnd. prior agreement Is obta]nod from 5M, and Frciettn op or iheort avd parse 2] neither the copg nor the original [s resold or ntherttJ]se ted eri 1Coin 3 rN rn. rtistr]buted mlth the Intention of earning a profit thereon.
Dos sree coma ouson DIDI$1ON: SPECIDLTY CHEMICALS HILIISlON Te TRADE NAME:
i tans Parca sutatan FC-I 1A FLUODFID Brand Fluoroc.hemlcal Surfactant ANE ZD NUMBER/U.P.C.= REIS on fasasm-1 3-021-085.1 gn.1135.2705 gS-O2| I--,4B~2-g DD-S1135-D26g"7-7 98-0211-48AS-"7
frofeshinier dnhiaian peda] 98-02!1-8012-4 00-51155-10865-5 Shiitesos mr 98-0211-A858-0 00-5[ 155-10971-`7 Sre19,e197) t~$nEO: February' 19, | g97 . a vn SUPERSEDES: February 07, 1997
98-0211-808'5-5
00-51135-D2745-5 QQ-51t55-109iA-2
11Di-UHENT= 10-4221-'7
TNA 1, IN~BEDIENT
Cassa C.R.S, NO. Pmaw PEBCENT
ww mms w WRIER..._.................. 77:32-18-5
80
EN PRC $5261 18-21 BMMONI UM PEBFLUURDOCTflNOATE............. 5825-25-1 18
/:]MMONIIrM PEBFLUQ BOHEPTFINQRTE.......... 6130-4=;-4 0,1
fre ts-- e rn . AMMONIUM PEBFLDDBDHEXANDATE........... 21615-4"/-4 O
PENNFAIRING. 65253113 0110 BMI'~.N/L,~ PERFLUOBOPEi~'flNOATE............ 68259-1 !-O 0.l
- 21
-0.1 - i.O
2. PHY$1AL DATA
re wae BDILINr- PAIN'/" Ti (Tuplcal)
roms. yy DRPOR pTIE~SLIRE:............. 18 mmHg
Calc @ 2AC
DAPDB DENSITY:--.......... 0.62 Alr,,I
Calc @ 2QC.
momo 1t. ance EUAPDBF~flAN RBT~:............. < I.O DoOAc..1
ST o E oat SOLUBILITY IN WAIl:A:........... complete
SE SPECIFIC 6RRUITY:........... 1,12 mater-I
PEW'ENT I/DLRTIL:.:, ........ 8D %
Sai pA"
m-- ca, 5
LII~I:O~IIY-......... N/D
PN MELTING PD|NP
Test3 oNat etrares NA Nt Fleas Gim: e ]]hbreulatlnns: N/g -Not Determined N/A - Nat Applicable CA - Approximately
PP11..88119955 |
EIDiob
11447711..00000099
SSTTAATTEE 0077554433996666
s-- ome10 as an rrsr tacth MSD~ FC-118 FLUOBO0 Brand FluorochemIcal Sotfectant
Februa~ 19, 1997
PAGE
2~.P~AYYSSII~CRALLOOGfTlTRR_ ((ccoonnttiinnuueedd))
-
sotmrt moesrs:i ir RPPERRANL-' AND OOQR: Light =:glottal liquid; slight odor.
PR LEOO NI 5. FiRE AND EXPLOSION HAZARD DATA
nan cme FLASH POINT"
....... :, 1 O0 C Setaflesh
A FLHHMABLE LIMITS - LEL:,.~..,
fS e THn na) FLAHMAnLE LIMITS - AEL:_~..... N/R
fltlTOl GNIIIDN TEMPEAATUAE:.... N/A
piEATINGHISXI NG MAD IA: LUaler, ar~on dioxide, Dry chemical, Foam
SSPPEECCI1RRLLFFIIRREEFFIIGGHFTTIflNNGGPPRBOOCCEEDDU~RIREESS::
oscone, esos ams. st conan, tUaar full protectWe clothing, Inclu01ng heimel, self-contained, rca poslllue l]mssure Dr pressure demand breathing apparatus, buel~er coat ma A fo and pants, bands around arms, uJaist and legs, fac= mask, and
t~r~tectlue ceuering for el~posed areas of the hood.
et oman ees or stof cation. `UUNNUUSSUURALLFIFRIREEAANNDENEP~PLLOOSSIIOONN HHAAZZAARRDDSS:: See Hazartfous Decomposition section for products of combustion,
4. REBETIVIT~ DATA
S~mBEIILILTYY:=SStIaabbllee.
.
IINCDNPIPCATOIBILM~IY -P-MMAARTTEERTBIIRRLLIS$/1CCBOONNIIDTITI|LOONNSSITToOTAAUVOOYIIDC::
ret Not Applicable ees a oc rao ot cs ]tRZHBDDUS PALYHERIZATI.ON: Xazerdeus pOi~Jmerlzetion wig not occur. ecn tm osm s sae rHe les , ren Carbo~ Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen
RuoH~e. Ammonia.
RE5, ENVIRONMENTAL INFORMATION res: SPILL RESPONSE: Rr ar5c cr ts g Refer to other sections of tills HSDS for Information regarding EB h ntse Br teeyOLE LCSDa physical and health hazards, respiratory protection, uentilatlon, end
personal protectTuP equipmeot. In the U.S.A., call (612) 733-I 11g or (612) 7~-610D for 24-hour spill assistance, Contain spill, Cover
i re er Coe ~ith ~bso~ent malabar, Collect spilled malarial.
Reston: et esNA eats3We Bhbroz~latinns: N/D - Not Aalerminod NIA - Not Applicable CA - Approldmatelg
PP11.88119955.22
:
;
Eons |
:
11447711..00001100
STATE 07543067 STATE 07543967
.
MFesru1a-n191g,0109510 ren rca sectTs ' I~1s]]~: F-118 FLUDRA]] Brand Fluerochemlcei Surl'aclant
February 19, 1"997
PAGE
SBIR NORTON antnand) 5, ENLI]RONMENTRL ]NFURHATIQN (continued)
orn ogous otcontami sc. Pomg cosmic 1:or Spills to ground: Collect contaminated sell, Pump contaminated EE oi ete rant lr er, Pace Cod ws water from puddles or stagnant storm sewers. Place collected waste in
approu~d cob:arBors, and seal. For spills to ground or surface
enRay reps SASH.Coo 110Sms u~'ate~ Notify appropriate authorities. Contact 5M to eualuate ft lurlher needs. coma sees: ]~ECOMHENDEO DISPOSAL: iva ninco acommerfac nessa of incinerate In an Industrial or commercial facility In the presenoe of Commemara, amsosion rE Se a combustible material, oCombustlon PrOducts will include HF.
Pass cenlamlnated water through anion excl~ange rosin. ] f necessary,
SE Y # ,'on:act 5M for assistance. ummm ENUIBDNMENTAL DATA: uaTopicsos: hice Gg ean Co: 1 Data forproduct solids: Chemlcel Oxygen Demand (CO0): Nil Ciao tae) Dotan BS05 i: 5, (,OODTggg/g], Biocltemlcel Oxygen Demand (BOD2O): Nil; gS-Hr. LCSD, et Lp ue: 308304AE, se Bluegill Sunfish (Lopoml; macroch]rus}: 569 my/L; gE-Hr. LESO, Fathead Pes roe T6060 (35 ts mn 652 Minnew(PlmePhales prome]as]: 756 my/L; ~8-Hr ECSO, Oaphn[a magna: 6~ uA Gay C33 (hry wen re ge lpr my/L; 14-Dad EChO (cell d~ weight), Brean Rlgaa [Salanastrum lama1 ok hin ocr ace 1, ~prico~utum) 7~ mg/L. Soil Adso~lion Coefficient (Keel: 17, tesrg mB. (510830183 $043 oa ]n~[~tes u8rg high mobliity, [study used a sandy loam soil).
REGtlLRTQRy INFORMATION:.
etesrg: Compe: ir. Volatile organic Compounds: N/R. BCHELrsan wena JJOC Less HZO & Exempt Soluents: N/H, Ssreqtons sy, cout gsc regions svt '~lnce Rgulallens nard, cons.ult applicable regulations or authorities Ear dopo 3.58 ards AS amor ho kU. before [llsposaf, U,S, EPR Hazardous LUaste Number = None (Not U,S. Davesrtoe. EPli Hazardous). he companens a is raear 1 arptance inte chic The components of this product are in complfance with the chemical eatenrecent of 5 INGE, Cn. nd ES registration requirements of TSCR, El NEES, CDSL and Rife. ean manocuss: PRR XRZARD CLASS: TRC Wad a PSSENEo REACTN:o REITE: Ys EARYNe I:IRE XAZAP,~ No PRESSURE: No RERETIUITY: No RCUTE: Yes CHRONIC; Yes
soe rT -- 6. SUG~;ESTED FIRST RID
eae ~EYE I~DNTRL-i': Tele sh se wh rgsma ofate orates 15 Immedl'alely flush eyes ~Jllh Iarge amounts ~f ~ater for at Isast 15 te.ot nected en, minutes, Got imme~iate medical attention, Trediat a ski itso sn are sunsofwa. ans Immediately wash Sl<In with soap and large amounts of u~ater. Remnue aminedcian. ig srs ocr CO A, contaminated clothing. If slgns/sgmptom~ occur, call a physician,
Eo conrsada Gong To Fans on Gooof manistes l!Jash contaminated clothing bel,ore reuse and dispose of c~ntaminate~
shoes.
ET Ero TT TI ................................................................ Fo3e Nat rs eaines NA FPS CRESTOR gbb~iations: N/O - Not Determined HIE - Hat Rppficable CR - Approximately
PP11..88119955.33 Eos EIDO08494
11447711..00001111
SSTTAATTEE 0077554433996688
E m8Rus ran rca a 6, SUGGE~EED FIRST RID (continued)
aawnn
mame: 1NHltLATION:. Fe spt cn, ros to re s If signslsgm~toms occur, remove person to fresh air. If en. ~igns/sqmptoms continue, call a phys[cian. TE son, gre amo,ca hg. SlllltLLDW
not induce vomiting. Drink two glasses of weler. Call a physician.
ET 7. PRECRUTI9NRRY IHFORMRTIgH re: EYE PROTECTION: TE cs, wearers Ruvid eye contact. Wear uented goggles. samo: SKIN PROTECTION: TREE, beasortsgees es vncng ls ~uold skin coolant, tLlear appropriate glooes when handling lhls Te hg ta Be TAS material, R pair of gloves made from the following material(s) are
recommended; burst rubber. Use one or more of the rnllowlng
F chap ame a prSe 48Cotst esd personal protection Items as necessa~ to prevent skin contact: head Ey et et mts ie on ge hed covering, coveralls. Protective garments (other than gloves) should
Tr re eErt en be made of either of the following materials;
polgethglene/polyuinytidene chloride {~:aranex}
Cormeen se seerssen cae Coueral! made of TRUnk(r). Wear rubber boots when cleaning up spills, sveemomno: i~ECDMMNDD VENTILRTIO;'q: i oe He ast etn, Frais fic Use with apprapHate local exhaust ventilation, Provide sufficient emt amit. ventilation to maintaln emissions below recommended exposure limits. at oon ok ees Soe pe If euhaust ventilation is not adequate, use appropriate resplratorg in, protection.
`Fw~eEs~pPiIRaRgToQnReY PpoRoOTTEECCTTIIOONN::
pipiens -------- Avoid breathing of vapors, mists nrspray. Ruold breathing of SRE, oe er Be airborne material. Select one of the following NIOSH approved
resplralors based on airborne concentration of contaminants and In
ohn fac a ey accordancam[th OSHR regulations: full-face high-erriclencg filter A respirator, fall-face supplied air respirator. ' rec of sco no: PREVENTION OF flCC[OENTRL INGESTION:. ar Lh nr te osc, en cor no not oat, drink or smoke when using this pro~luct, Wash exposer[ mm eesa eSs evio areas thoroughlzJ.wilh soap and water. Wash hands after handling and
before eating.
r[eSoaatets ni hl tes. trea rea tora. lZEEOHMEND11 STORRGE: no not store containers on their sides. Store at room temperature.
Keep container closed zuhen not In use.
tation 3StenNtAVFe 8 Fors o Rbbreu|ations; HID - Not Determined N/A -Nat flppllcable CR - Rpproxlmatelg
.PP11..88119955.44 womes & EID008495
11447711..00001122
SSTTAATTEE 0077554433096609
|
Te5c:aEn113,0199o7na Brand ereScrTfacttaRnt
2FRGERITONAY BEOATION (coins
Fsma sion: FIRE 8NO EI{PLDSI0N AVOIDANCE= Kei onianer gi oss. Nontamale. Keep container tightly closed, Nonflammable. maacnme on: OTHETI FRECBIJTIONARY INFORMR~ION: mings Smoking hl wing is productcan ras No smoldng: Smoking while using t?zls product can rasull In Containof18 tices 35m0ek soenrd 1s ne fortion z:ontamlnal~on of the tobacco and/or smoke ~znd lead to the formation aria econ ross ras nen 1 at" the hazardous decompos|tlon products mentioned in section 4 of
~hls
}IMiSHRZA~D RRIINGS: HEALTH: 2 FLAMMABILITY: I RERCTIUiTY: 0
PERSE PACE (5 rcastons, scion 2) PER'~DNAL PE~TECIION~ X {See precautions, sectloll 7,)
wasscuvas EXPOSURE LIMITS
nai huewr vee umsk INI;RErIIEI'R"
URLUE UNIT TYPE AUTR SKIN+
Eo a F~=B...................... NONE NONE ETI. 081 RS Tn GE ILHMDNIUMPERFLUORQACTANQATEo........ Erma oF hd AMMDNIUM PERFLUOAOHEPTANOR~........ EroPERMIT 0) vai TR Nf R~ONIUMP~FLUQRQXEHflNOR~....... IMPRLRORORE 61 HES Tun BY B~NIUH P~RFLUDROPE~ANORT~........
NONE NONE I],Ol ~G/M3 0.I MG/~ O.l MG/M3 O. I MG/M3
~A ~A TWA T~A
gCGIII Y
~M Y 5M Y ~ Y
SKINNGTETION: Usted sbstance cca thse SKIN e ter to * SKIN N~HilON: Listed substances Indicated mith 'Y' under SKIN refer to Rotel catisaton t a cosaexport cams ree the putentlal contribution to the overall exposure by the cutaneous route igcs Ta at Seg Sono, or BH in~ludlng mucous membrane and ere, either by airborne or, more particularly, Birch contact ih heSs. Des 08 Sher iSuro: bg ~irett ~ntact ~itR the substance. Uah!cles can altar skin abso~tlon.
sscor rosa ore. SDURL"E OF EXPQSUAE LIMIT DATA: HCE, rca Courseof Gormmeatal Insta agossts - AEEIH: Emerlcan Conference of Ooueromenta] Industrial Hgglenlsts Ihatune aminnaevs apostles - ~M: 3M Recommended ExpoSure Guidelines
- N0~ None E~tabllshed ~
A ~. HERLTH HAZRRI] BETA
recone E'~E CON'~CT~ Ne Lo) 310 forte suo. meen erfvrosigt. No t0xlc|tg data rot tile solution. Emmonlum perfluoroalkgl raisB oAne 1h aed) se arhoxglate =an be Irritating to the eye and may cause eye inJuts
&=m ai~orne e~pesure.
Sratrough he skin a ers hbo foron May be ab~a~ed thraugh the skin and pa~sl in the body for an me extended tim~ 5 ey dat or thst,Amatoprorat ~Q t~xlE]~y data for th~ solution. Ammonium perfluoroaikgl Srey TE Lv hn ssomed su on 11 c~oxglale is sllghl(~ toxic w~en absorbed t~rough the skin; ena tn - aon-lrHlating to the
Feaeatt7i3o-Nnost etrmined WA Not Topless Shohpra B~reulatlnns: HID - Not Determined N/FI - NoI Applicable CI] - Approximately
PP11..88119955..55 fro. El'D008496
11447711..00001133
SSTTAATTEE_0077554433997700
PP11..88119955..66
MSTTein108 198AAD Brad Porsche Sraceantto H~OS; FC-118 FLIInFIRD Brood Fluoruchemlcal Surfactant
Yr'brL~artJ 19. |997
PRG 5
Sz 8. HEALTH HBZFIIID OATh ene (continued)
ammo. INHRLRTIQN:.
; "
idbeSareesby tas32 ers1 ht bdfor 3 tended Hag be absorbed by Inhalation and persist in the body for an extended
Telime.
Notate ot or hesoutien. motor serruersati No toHl~lty data fur the solution. Rmmonfum perfluoroal~gl Errata ss apronsien etn rom haat: z:arhe~glale rnag cause Rsp[rato~ system Irritation from Inhalation;
| SimnSaECcSioynitaatrsstcoomnrccaooneautftfreoo,wsRebgytpecnitrlsesaaxynnpwaetoarnn 4ci1lssesupieneesro: 980 m~llig~ms 92~ cubic meter, Repeated inhalat[o~ eHgosufe haar hgh 5d SRA Ho a i . p~duced liue~ changes ~nd eleuat~ blood o~gano~luoride leuel In
~t~
swmoues: IF SIDALLOLUEQ: gusitos ont a Wty ostofnprto hs roe. Ingestion is not a liE:Big route of exposure to this product, No ey at forte sein morn serores. NO toxicltg dot3 for the solution Rmmonlum perfluorualk:gI `Sromiates Consomrd modurian toe rom ngaart carbnxgtate Is considered mode~telg toxic from a single oral pecunrae 59 ra) + 4 mF 5.Bod BG. eHposu~ acute u~l ~DSO (rat) Is 540 my. per ~g. of body weight. ee ERNCEt~ i cenaa comics nen cncss coca, (5825.21) LUAANING: Contains a chemical ~uhlch can cause cancer. (3925-26-It 153 193shi conducted oro) 1 0 pen and 1993 studie~ conducted Jointly by 3M and OuPonl]. ramemae: HIffAW:'N I I:ITY: ronan pres crseete wes not agen a ales | Ammonium perfluoroal~:lJl carbnxylate w~s not mutagenlc In iaultr~ ape sso, 0 ot cosecl ramon3 maaan mulagantcitg assays. Old not cause cell transformation in a mommallan soH apnsmermmaaonpsoe.cTEnRNS: REPRODtlI:/IIIE/DEUELOPMENTAL TSH I I~," rien erro) corbosoe ss ot Lrtageric rb Ammonium perfluoraall~gl cerboxglale was not teralOgenlc In ~bbits bg Emi ds ap 10 es 08 ~ml administration and was nut t eratogenlc to rats by gauage and
~halatlnn e~:posures.
A
RICHTIENRRY1.SECTION CHRNGE SINCEFabs ]~AEIEAITi'I]]NAR~ INFD. SEL'TIQN CHANOE9 SINCE February O,07, 1991997 1S5EISSUE
brE ati3oE n luted At F-- rc-- Go sp-- arouaiet P.bbmu[ations; HID -Not Determined N/A - Not Applicable CA - Appronfmately
mer EID008497
11447711..00001144
SSTTAATTEE 0077554433997711
=
mm SOE TE-118FLUSRAD ws BrandPsorocheSumraictcanat
FE ----, The tn1"armatlon i'n this Material Safetg Data Sheet {HSDS] Is belleaad to oe be correct as of the dale Issued. 3M MXI~ES NO tURRRXNTIES. EXPRESSED DR BA Sh IHPLIED, INCLUDING, ]lilt NOT LIMITED TO, PiNY IMPL] EO tlJRRRRNTY OF Ee STP HERCHRNTRBIL]TV OIt FITNES FDR R PRRTICULI~R PU~iPOSE OR COURSE OF FE re PEGFOllMRNCE OR USItGE OF TRFIDE. User Is responsible for determining A a ce, whether the ~H product is fit for a particulal' purpose and Suitable rot EE user's realized at" use or application. Gluen the uarletg or factors that E ie Sh can afle~11he use and application or" a 3H product, some of mh|ch are E E EE r e E uaiquelg withlu Ihe user's knowledge and control, it Is essential that
the user eoaluate the 5M product to ~[otermlne whether It Is fit fo~" a part~:ular purpose and suitable for user's method of use or application.
S Be T mT 5H provides inl'ormation~n electronic farm as ~ service to its customers,
Oue lo the remote po~sil~llZtg that electronic irons rer map haue ~esulted
i in e~a~, omissions or alterations In this Inr~atlon, 3M makes no
rep~sentatlons as to [ts ~ampieteness or accuracg. In
En znrn~a/Znn nblaine~ from a database map nnt be ~s current as the EEE TT intonation in the ~SD~ available d~rectly from ~M,
PP11..88119955..77
11447711..00001155
mows EIDO08498 &
Stateorsiaom2 STATE 07543972
Taft/ 1717 Die Highway, Site S10/Coington, Kentucky 41011-4704 1717 Dixie Highway, Suite 910 / Covington, Kentucky 41011-4704 Te 859.331 2638 Fo: 513.381 6613 Tel: 859.331.2838/Fax: 513.381.6613 wtaflavicom www.taftlaw.com
Rosen sor ROBERT A. BILOTT ferns 859,547.4306 rut bilott@taftlaw.com
JJaannuuaarryy 33,,22001188
BBYY EEMMAAIILL AANNDD RREEGGUULLAARR UU..SS.. MMAAIILL
AAAslleseitthsheteaaantMM.S.oHHliuucyiystsoeerrrGeneral A44Su44si55stiesMMti1ainn1nnn0tee0SssoootltiacaitSSottrrreeGeeettneral SSStt.u.itPPeaau1ul1l,,0MM0iinnnneessoottaa 5555110011--22112288
RRee:: PPeerrfflluuoorroocchheemmiiccaallss iinn MMiinnnneessoottaa
DDeeaarr MMss.. HHuuyysseerr::
MinnesW Woteea uuinnnddceoernrssntteaacnntddiottnhhaawttiyyhoouuitsaaroreengooonnieenogoffittnhhveeesaattittgtoaortrnineoenyyssinrrteeopptrrheeesseepnontttieinnngtgiatthlheepuSSbttlaaittceehooeffalth ttMbhherrineeennaatetksppnooootssaweeniddnabbcbyyoonpupneteerrtflchluuteioootrnroooxwccihhiiteehtmmyiitoicscfaaolalnssngd((oiinpinnoccgtllueundidntiinivnageglsPPthiegFFaaOOlttiAAohnaaenfninfddetocPPtFtFshOOeaSsS)ps),oo, ctieiinnnaccttlliueauddldiipnwniuggtbhwwlihcheaxahtpteohhasaaltusshre ttcboouereaarnnneddnktnddpioisoswtppenoonsstaaialballoooufpftuppbteehlrireffcliuthouoeoxrarioclocticthhyheetommhfieiaccaana,ldlsstpiihnonetttehShnteetaiaeteelnnovvhifierroaMonlinthmmneneenenftfste.o.cttaIIsnn raccesooqsnnuonneceesicactttteieiododnnowuwwriititthahhsetsthxhiiipsssotasnucree in licloonuccfraaortertiimnnnagtgtpiccooeentrrettinaantiininMailddnpoonuccebuuslmomicteeanhn,tetssagiltttvhhheaanttthomrmeuiiarggthh,ittnthvsseohhleeSvddetamllitiegegnhhttot fooinMnnlittnihhgneeaethhsiiioosstnttaooarrrygyeaqaaiunnnedsdtstttieEim.mdiinI.noggduuoorffaPsssouusnccisthhtdaen.ce in NpiNnoeeftomemrnomtouiuaarrltssiloynaa-nnrieddnleCCMvoaoinnmmtnp,peahasnionsytyato,(("r`gDiDivuurePPencooonnorttud"))sr ttithnhhrvraoootuulvmggeihhgmhwwethhniinctcohhitnwwoliteetihgeggaraatwiiioninnseeeddabgaaeacciccaneevsasstissElatt.oboIl.ccedeerfurtotaaPtiinhonentStdaete.
potentially-relevant, historic records that might not otherwise be available to the State.
respondTTihhnuugss,,topputuhrrisssuuoaannn-ttgttooointthgh,ee pSSotttaaettneet''issalrreepqquuubeleissctt hffoeorarlaatsshssitishsrttaeaanntc,ceewiienn iihnnavvveeessttaiigtgaatttaiincnhggedaannsddeveral
dd(reaoossccpuuiomnmndeeidncnitnattsgsedpptorrbootyhddiuutschceeoednd*-EgiinInoDilt"nitiigdgg,aoatcptiiuooonmtneenffnrrtoitaommlnputthumheebbelinncrooinhnn-e-gccaoolpntrnhfeififtddhieexrne,nt"aitiataw,llhwibbeucushshiinmanievegseshssatrrtetbeaceccoohrrreeddsdsspooosnfefsvDiDevuuerPPa.olonntt
We(as
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understand indicated by
understand
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the documents originated with The "EID" document numbering prefix),1
the documents originated with The
3M Company which might
3M Company
and weresent be responsive.
and were sent
ttoo
r1 eOOflnneeectsooffttthhheeefaddcootcctuuhmmateenintttisss
reflects the fact that it is
aaaallsnnsoooonn-hh-caacossonfnaaifdidddeooenctcniuutaimmalel,,ennpptltlaacciioonnntntitiftfrfr''oossll
ttnnrriiuuaamlml beebxexehhriroibboififtt
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TaftStettiis Hollister LP Taft Stettinius & Hollister LLP -- 21807977.1
Chicago Cincinnati Cleland Cambs. Dayton /ndianaalls Northern Kentucky Phoenix Chicago / Cincinnati / Cleveland / Columbus / Dayton / Indianapolis / Northern Kentucky / Phoenix SSTTAATTEE 0077554433095588
11447711..00001166
AAlleetthheeaa MM.. HHuuyysseerr JPPaaanggueea22~ 3,2018
DuPont ng efCuts oy DuPont during the course of DuPont's long-term business relationship with 3M with
respect to certain perfluorochemical issues and products.
Encls.
bert A Bilott
so 21807977.1
147711..000017
J STATE 07543959
3M General O~Tc~s
SL Paul. MN 55144.-1000
6~Z 733 lifo
17~0
.
3m
SNR MATERIAL SAFETY
DATA SHEET
Copyright, 1997, Minnesota Mining and Manufacturing Company.
CUE EY i em a All rights reserved. Copying and/uP downZoading of this information for
the purpose of properly utilizing 5M produc~s is allowed provided %he~=
BE eR RR has at, l) the information is copied in fulI with no changes unless prior agreemen~ EEEEEE it ovine ssid is obtained from 5M, and
2] neither the cop~ nor the er~glnat is resold or o~herwise distributed ~ith the intention o~ earning a profit ~hereon.
DIVISIOM= SPECIALTY CHEMICALS DIVISION TRADE NAHE:
HE me srerevresaentteorss FC-118 FLUORAD ~rand Fluoroche~cal SuPfactant
BnaEreRs TnelCr FSrCEooEHRy ID MDMBEH/U.P,C.:
98-0211-q8~2-9 98-OZll-80~Z-q
98-0Z11-8858-0
00-51155-02697-7 00-51155-10865-5 00-51155-10971-7
ELH 98-0211-~885-7
98-0Zl1-8083-5
SINE 00-51155-027~5-~
OQ-Sl155-10918-Z
SBPERGEDES: AUGUST Z~, 1996 DOCUMENT: I0-~221-7
= Te I. INGREDiEnT
WATER ....................... ~ ........
AMMONIUM PERFLUOROOCTA~OATE ..........
Spm BE oe AMMONIUM PERFLUOROHEPTANOATE ......... AMMONIUM PERFLUORQHEXANOATE .......... AMMONIUM PERFLUOROPENTANOATE .........
C.A.S. pO. 77~2-18~5
~825-Z6-1 61~0-~5-4
21615-47-~
68259-11-0
PERCENT
80
18
0.1
1.0
0
O.I
0.1
1.0
PHYSICAL DATA
orwn ess BOILING POINT= ...............
VAPOR PRESSURE: .............. VAPOR DENSITY: .......... ~...
WEERDE 180 C (Typical)
18 mmHg Cole
0.62 Air = !
Calc ~ 20C
EVAPORATION RATE: ............ < 1.0 Butyl Aeota~e = 1 SOLUBILITY IN WATER= ........ oomplete
Be al SP. GRAVITY: ................. I.IZ Water = 1
PERCENT VOLATILE= ........... 8~ ~ pH: .......... ~ .............. ca. S
fo YISCOSITY= .................. N/D ~ELTING POINT ................ N/A REA NGG 65001 Lah colored Mauka shioht oder. APPEARANCE AND ODOR: Light oolaPed liquid; slight odor.
Cr rm ---- I -- 3. FIRE AND EXPLOSION HAZARD DATA
PR. Tm es, sess: FLASH POINT= ................. > I00 C Setaflash ~LAMMABLE LIMITS - LEL: ..... FL~J~MABLE LIMITS - UEL: ..... N/A A~TOIGNITION T~PERATURE: ... EXTIMOUISHIN~ MEOIAr Water, Carbon dioxide, Dry chemica!, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear fu]! pro%active cloth~ng~ including heIme~
sel~-cen~ained~
I. Abbreviations: 3 AH, N/D - Not ~aterminad YhN/A - Hot Applicable
EID599980
11447711..00001188
STATE 07543560 STATE 07543960
3M General Offices
3M Centcr
St. Paul, MN 55144-1000
TE HATERIAL GAPEIY
612 733 |110
DATA SHEET
3M[EE MSDS: FC-11~ FLUORAD Brand Fluovochemleal Su~Zactan%
a
--TE-------- FEBRUARY 7, 1997 FIRE AND EXPLOSION HAZARD DATA (continued}
PAGE: 2 of 6
A Tip moo s ah" positive pressure or pressure damaed brea~hing
pro~ec~Eve coverEng ~or exposed areas of the head.
mEUNUSUAL F~RE AND EXPLOSION HAZARDS: See Hazardous Decomposition ~ec~on
for
produe~s
beA Siete wt tomes vn INCOMPATIBILITY - MATERIALS TO AVOID: Ho~ Applcable HAZARDOUS ~OL~ERIZAT~ON~ W1~ No~ Occur
HAZAEDO~S DE~OHPOSIT~0N PRODUCTS:
Carbon Monoxide and Carbon D~oxide~ Oxides o~ Ni~rogen, Hydrogen Fluoride, Ammonia.
Be 5. ENVIRONMENTAL ~NFORNATION Eee SPILL RESPONSE: aaL 0 Ts SO we Refer ~o o~her sections of ~his MSDS ~or information regarding
physical end health hazards, respiratory pro~ac~ion, ventilation, and
personal pro~ec%ive equipment. In th~ U.S.A.~ cal~ (~12) 755-1110 or
(612) 755-6~00 ~er Z~-houP sp11 assistance. Con~a~n sp~ll. Cover
H~%h absorbent mateP~al. Col~ec~ spilled ma~er~al.
EE St Sle rt af, Sa, For sp~lls ~o ground~ Collee~ contaminated soil. Pump contaminated
TE er EE approved containers, and seal, For spills %0 ground or surface
~ur%her needs.
P RE E rstE titan Ywemeetset RECONNENDED DISPOSAL: a combustible material.
Combustion ppoduc~s Hill include HF.
Pass ontaminated water through anion exchange resin. If necessary~
con%act 3H ~or assls%ance.
ENVIRONMENTAL DATA:
Data for product sol~ds: Chemical 0x~gen Demand (COD): Nil
"ERE ne pcs mn sem cant (.000700g/g). 3~ochem~cal Oxygen Demand (BOD20): Nil; 96-Hr. LCBO,
DZueg~l Sunfish {Lepom~s macroohlrus); 569 mg/L~ 96-Hr. LCb0~ Fa~head
HE EE nt SL EL Be Hinnow(P~mephales prome]as)~ 766 mg/L; ~8-HP ECb0~ Daphn~a magna:
FE RE RR mg/L; l~-Day ECSO (cell dry waigh~, Green Algae (Selenastrum
capr~aornu%um) 75 mg/Lo $o~! Adsorption Coe~ic~en~ (Koc): 17~
~nd~ca%es very h~gh mobility. (Study used a sandy loam soil).
REG~ATORY INFORI~ATION:
o
_"TTUTPTWMTM Volatile Organic Compounds= VOC Less HZO& Exempt Solvents=
Abbreviations: N/D - Re% De%ermEned N/A - Mot Applicable.
EID5999~I
11447711..00001199
STATE 07543961
STATE 07543961
spe MATERIAL SAFETY
DATA SHEET
= : | HSDS: FC-118 FLUORAD Brand Fluo=oehemical Surac~an~ FEEL 3 gn es erst rac no sors | FEBRUARY 7w 1997
PAGE~ 3 of 6
I S~nce regulations vary~ consult applicable regulations uP authorities Br rE STE: BRI Se before d~spoSa~o U,So EPA Hazardous Waste Number = Hone Not UoS.
EPA Hazardous).
TETINRTALE The components of ~his produc~ are
registration Pequiremp~ta o~ TSCA~
BETES in compliance with the
EINECS, CDSL and AICS.
chemical
EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No
REACTIVITY: He
ACUTE: Yes CHRONIC Yes
6. SUGGESTED FIRST AID
EYE CONTAGT~ Immediately f~ush eyes wi~h large amounts of water for at least 15
minutes. 8et ~mmedla~e medical a~-~en~icn.
SKIN GONTACZ: Immediately wash skin Hith soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur~ cell a physician.
Wash contaminated c~o%hing before reuse end dispose of contaminated
If s~gas/~ymp~oma oocur~ remove person to fresh air. If
rm Tar I en i 0 s~gns/symp%oms, cont~nue~ call a physician.
IF SNALLOWED:
70kSodiee vonbting. Brink (xo siasses of water. Call a piyicieen e Do not ~nduoe vomiting. Drin~ ~Ho g~aases o~ ~ataP. Cal~ a ph~s~ciano
7. PRECAUTIONARY INFORNATION
PRITETMiteck. eae vented amgstes. EYE PROTECTION: Avoid eye contact.
Wear vented goggles.
SKIN PROTECTION: Avoid skin contact, Wear appropriate gloves when handling this
material, A pair Of gloves made from %he ~ollowing material(s) are
rooommendedl butyl rubber, Use one or more of %he follow~ng
ERREERE personal protection ~tema as necessary to prevent skin contact; head
cover~no~ coveralls, Protective garments (other than gloves) should be made of either of the following ma%er~alst polye~hylene/polyv~nylidene chloride (Saranex)
Coverall made of Tyvak(r). Wear rubber boots when cleanino up spills.
rE eps morT ecrone: r oe ncaa VENTILATION PROTECTION: Use with appropriate local exhaust ventilation, Provide sufficient ventilation %o maln%ain emissions below recommended exposure limits, I~ exhaust ventilation s not adequate~ use appropriate respiratory pro%action,
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mls%s or spray. Avoid breathing of
Abbreviations: N/D - Not Determined R/A - Hot Applicable
EID599982
11447711..00002200
---- STATE 07543962
3am
ps MATERIAL SAFETY
DATA SHEET
SL Paul. MN 55144-1000 612 733 111~
MSOS: FC-11B FLUORAD B~and Fluomcchemal Su=Za~"t:ant
r--m ------------------ FEBR~AR~ 7, 1997 PRECAUTIONARY INPORHATION
gcontlnued3
PAGE: ~ o~ 6
airborne ma%er~al. $alec% one o~ %he ~ollow~ng NIOSH approved
respirators based on e~rborne coRoeR~ra~on o~ on%amEnan%s and in
accordance w~%h OSHA regula%~ons= ~ul~-~ace h~gh-e~c~eno~
ATR Bh TI AIS resp~ra~or~ ~u~l-~ece suppl~ed a~r respirator.
PREVENTION OF ACCIDENTAL INGESTION: Do no% ea%, dr~nk or smoke when using %h~s produc%. Wash exposed areas %ho~oughly w~%h soap and water. Wash hands a~%er handl~ng and before
RECOMMENDED STORAGE:
UIT Rr. vo motos te wee wis Do no% s%ore con%aJners on %he~P s~des.
~eep con%airier closed when Ro% ~n use.
S%ore a% room %empera%ure.
FIRE AND EXPLOSION AVOIDANCE: Keep container %~ghtly closed. Ho smoking wh~le handl~ng th~s
EERIE) se may ma%erEaI. OTHER PRECAUTIONARY INFORMATION: HHIS HAZARD RATINGS= HEALTH= 2 FLAMMABILITY= 1 REACTIVITY= 0
PERSONAL PROTECTION= X (See pPecau%~ons, sec~on 7,)
EXPO~JRE LIMITS
INGREDIENTS
~AL~E
WATER ................................ NONE
AMMONIUM PERFLUOROOCTANCATE .......... 0.01
AMMONIUM PERFLUORONEPTAHOATE .........
0.1
ERE UE BO AMMONIUM PERFLUOROHEXANOATE ..........
O.1
AMMONIUM PERFLUOROPENTANOATE .........
0.i
D~IT NONE
mg/m~ mg/m5
mg/m3
mg/~
EE p SKIN NOTATION: L~s%ed substances ~ndica%ed w~%h "Y" er aT ts gree %he pote~%~al con%P~hu%~on %0 %he overall exposure by
~nclud~ng mucous ~embPane and eye~ e~%heP b> airborne
TYpE AUTH
NONE NONE
TWA ACBIH Y
TWA SM
Y
TWA 3H
Y
TWA 5M
Y
under SKIN refer %he cu%sneous Pou%e o~, mope par%~culaPly,
EHR S EEI OA EE ik, SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: A~er~can Conference o~ ~oveP~m~%al Indus%P~al
TL Or LE mrs ts AIHA= American ~ndus%P~al Hyg~ne Assoc. Workplace Env~ronmen%al
: H -. 5M: 5M Med~ca~ ~epar~en~ Guideline ESRE SA | - NONE= None
Exposure
teve~
rE8. HEALTH HAZARD DATA
EYE CONTACT:
No ~oX~c~%y da%a fop ~he solution. Ammonium perluoroalky]
TREE aTEES ser | carboxyla~e can be irr~%a%mg ~o %he eye and may cause eye injury rom airhorRe exposure.
E SKIN CONTACT: n Nay be absorbed %hrou~h %he skin and perm, s% n %he body fop an
Abbrevia%ions: N/D - No% De%ermEned N!A - Hot App]icehle
To
Tr
| snes EID599983
|
11447711..00002211
STATE o7saases STATE 07543963
a MATERIAL SAFETY
DATA SHEET
3mFE HSDS: FC-118 FLUORAD Brand
FEBRUARY T, 1997
SE8. HEALTH HAZARD DATA
3M~entcr ~L PauI, MN 55144-1000 612 733 !110
Fluorochemica~ Su~fa=~anb (on~Lsued)
PAGE=
. a
5 oF 6
extended time,
No ~oxcity da~a ~or the solution. Ammonium pePfluoroalkyl
carboxylate is slightly toxic when absorbed through the skin; it is non-irritating to the skin.
ENret by etn sd ri inh es fr1 tid ~NHALATZON: Hay be absorbed by inhalation and persist in the body for on ex~ended
time.
:.
Me toxicity data ~or the soZution. Ammonium
BSE EET iy carboxylate may cause respiratory system irri~atlon ~Pam inhalation;
can be considered moderately ~oxie by inhalation on a single exposure;
FEESRRS a, a median letha~ =omcen~ra%~on ~op a q-hour exposure ~n the e~bino EE EE E ER RA is 980 milligrams per cubic meter. Re,eared inhalation exposure
produced liver changes and elevated blood organo~luoride levels in
IF SWALLOWED:
TT -------- Ingestion is not a likely ~oute of exposure to th~s p~oduct.
opt tei, gt He {oxicity da~a ~or the molu~ion Ammonium perfluoroalkyl SE ER EE, earboxyla~e ~ considered moderately ~oxLc ~rom a ~ingle ora~
CANCER:
"be madTE WARNING: Contains a chemical which can cause cancer. (]B25-26-1) (1983 and 1995 studies onducted ~o~n~ly by 5H and BurghS).
ESET ig, tote1 TL LTE Ammonium perfluoroalkyl carboxylate was not mutagenlc in invitro EE ror in SLR mutageniclty assays. Did no~ caUSe cell transformation in a mammalian
REPRODUCTIVE/DEVELOPmENTAL TOXZRS:
Ammonium gerf~uoroalkyl carboxylste was not tera~ogenic in rabbits by
TREE]A a SrA oral administration and Has no~ terategenic ~o rats by garage and
inhalation exposures.
Sm SECTION CHANGE DATES
HEALTH HAZD. DATA SEGTION CHANGED SINCE AUGUST 23~ 19~6 ISSUE
|
Abbreviations= N/D - No~ Determined N/A - Not Applicable.
EIDS99984
11447711..00002222
STATE 07543064 STATE 07543964
os MATERIAL SAFETY
DATA SHEET
3M Center
St. PauI, MN 55144-I000 612 733 1110
17~5
3m
---------------- M~DS: F0-118 FLUORAD B~and FEuo~o~hemcal Surae~an~
FEBRUARY 7, 1997 SECTZON GHANGE DATES
PAGEs 6 of 6
TL -- | Abbreviations= N/D - Not De~ermEned N/A - Not Applicable
@
The Enfarmaton En thEs Materia Safe%y Data Sheet (NSDS) is believed to be
correc% as of the da%e issued SM MAKES NO WARRANTIES~ EXPRESSED OR IMPLIED, INCLUDING, OUT NOT LIMITED TO, AHY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE DR COURSE OF PERFORMANCE OR USAGE OF TRADE,
User is responsible for determining who%her %he 3H product is fi~ for a
par~JcuiaP purpose and suitable fop userts method of use oP application. Given %ha variety of factors %hat can affec~ the use and application of a 5M product;
some o~ wh~oh are uniquely Hi%bin %he user's knowledge and control, it is
essential %ha% %he user evaluate the 3H product %0 de%ermine who%her i% is fit
unre edm Ges L SA S for a particular purpose and suitable for usePIm me%had o~ use oP application.
3H provides ~nformation in e~ec~ran{c form as a service to i~s customers. Due to the remote possibility tha~ electronic transfer may have resulted in errors/
~ts completeness oP accuracy. In addition, ~n~ormation obtained from 8 do%abase
may no% be as current as %he information in %he MSDS available ~irectly ~Pom 5H.
EID599985
11447711..00002233
ssn STATE 07543965
.|
*R vaiconpsarEee Eawem.m etic. ~opRdght, 199"7, MinnesOta Mining and Manufacturing Compang.
Fill HghJs reserued. Copylng and/or downloading nf this
RT. Information for the" purpnse of properIg utilizing 5M prnduct$ pi ls allowed proulded that: tttst rr es Z) thB InformatiOn Is copied In FuI~ witl~ no changes unless Sh prior agreement Is obta]nod from 5M, and bn 2] neither the copg nor the original [s resold or ntherttJ]se I rtistr]buted mlth the Intention of earning a profit thereon.
Ee DIDI$1ON: SPECIDLTY CHEMICALS HILIISlON wi TRADE NAME:
i -------- FC-I 1A FLUODFID Brand Fluoroc.hemlcal Surfactant Tn ZD NUMBER/U.P.C.= i eine gS-O2| I--,4B~2-g DD-S1135-D26g"7-7 98-0211-48AS-"7
ims 98-02!1-8012-4 00-51155-10865-5 Ln 98-0211-A858-0 00-5[ 155-10971-`7 nh t~$nEO: February' 19, | g97 E BE EE SUPERSEDES: February 07, 1997
98-0211-808'5-5
00-51135-D2745-5 QQ-51t55-109iA-2
11Di-UHENT= 10-4221-'7
rd Case. mon 1, IN~BEDIENT
C.R.S, NO.
PEBCENT
Fra {0 WRIER..._.................. 77:32-18-5
80
CL Tim 7 1 BMMONI UM PEBFLUURDOCTflNOATE............. 5825-25-1 18
/:]MMONIIrM PEBFLUQ BOHEPTFINQRTE.......... 6130-4=;-4 0,1
ELE AMMONIUM PEBFLDDBDHEXANDATE........... 21615-4"/-4 O
BENINPERFLUOROPOAINONTE.._. 8259-11-0 0.1 ~10 BMb~.N/].,~ PERFLUOBOPEI~'flNOATE............ 68259-1 !-O 0.l
- 21
-0.1 - i,O
2. PHY$1AL DATA
e re-- T its BDILINr- PAIN'/"
(Tuplcal)
DRPOR pTIE~SLIRE:............. 18 mmHg
Calc @ 2AC
DAPDB DENSITY:--.......... 0.62 Alr,,I
Calc @ 2QC.
EUAPDBF~flAN RBT~:............. < I.O DoOAc..1
iiSOLUBILITY IN WAIl:A:........... complete
SESPECIFIC 6RRUITY:........... 1,12 mater-I
PEW'ENT I/DLRTIL:.:, ........ 8D %
iT pA"
m-- ca, 5
= LII~I:O~IIY-......... N/D
MELTING PD|NP
Fm or VA Gi - ]]hbreulatlnns: N/g -Not Determined N/A - Nat Applicable CA - Approximately
PP11..8195
|
':
mocks
11447711..00002244
STATEo7sasoes STATE 07543966
s-- ome10 as an rrsr tacth MSD~ FC-118 FLUOBO0 Brand FluorochemIcal Sotfectant
Februa~ 19, 1997
PAGE
2~.P~AYYSSII~CRALLOOGfTlTRR_ ((ccoonnttiinnuueedd))
-
sotmrt moesrs:i ir RPPERRANL-' AND OOQR: Light =:glottal liquid; slight odor.
PR LEOO NI 5. FiRE AND EXPLOSION HAZARD DATA
nan cme FLASH POINT"
....... :, 1 O0 C Setaflesh
A FLHHMABLE LIMITS - LEL:,.~..,
fS e THn na) FLAHMAnLE LIMITS - AEL:_~..... N/R
fltlTOl GNIIIDN TEMPEAATUAE:.... N/A
piEATINGHISXI NG MAD IA: LUaler, ar~on dioxide, Dry chemical, Foam
SSPPEECCI1RRLLFFIIRREEFFIIGGHFTTIflNNGGPPRBOOCCEEDDU~RIREESS::
oscone, esos ams. st conan, tUaar full protectWe clothing, Inclu01ng heimel, self-contained, rca poslllue l]mssure Dr pressure demand breathing apparatus, buel~er coat ma A fo and pants, bands around arms, uJaist and legs, fac= mask, and
t~r~tectlue ceuering for el~posed areas of the hood.
et oman ees or stof cation. `UUNNUUSSUURALLFIFRIREEAANNDENEP~PLLOOSSIIOONN HHAAZZAARRDDSS:: See Hazartfous Decomposition section for products of combustion,
4. REBETIVIT~ DATA
S~mBEIILILTYY:=SStIaabbllee.
.
IINCDNPIPCATOIBILM~IY -P-MMAARTTEERTBIIRRLLIS$/1CCBOONNIIDTITI|LOONNSSITToOTAAUVOOYIIDC::
ret Not Applicable ees a oc rao ot cs ]tRZHBDDUS PALYHERIZATI.ON: Xazerdeus pOi~Jmerlzetion wig not occur. ecn tm osm s sae rHe les , ren Carbo~ Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen
RuoH~e. Ammonia.
RE5, ENVIRONMENTAL INFORMATION res: SPILL RESPONSE: Rr ar5c cr ts g Refer to other sections of tills HSDS for Information regarding EB h ntse Br teeyOLE LCSDa physical and health hazards, respiratory protection, uentilatlon, end
personal protectTuP equipmeot. In the U.S.A., call (612) 733-I 11g or (612) 7~-610D for 24-hour spill assistance, Contain spill, Cover
i re er Coe ~ith ~bso~ent malabar, Collect spilled malarial.
Reston: et esNA eats3We Bhbroz~latinns: N/D - Not Aalerminod NIA - Not Applicable CA - Approldmatelg
PP11.88119955.22
:
;
Eons |
:
11447711..00002255
STATE 07543067 STATE 07543967
.
MFesru1a-n191g,0109510 ren rca sectTs ' I~1s]]~: F-118 FLUDRA]] Brand Fluerochemlcei Surl'aclant
February 19, 1"997
PAGE
SBIR NORTON antnand) 5, ENLI]RONMENTRL ]NFURHATIQN (continued)
orn ogous otcontami sc. Pomg cosmic 1:or Spills to ground: Collect contaminated sell, Pump contaminated EE oi ete rant lr er, Pace Cod ws water from puddles or stagnant storm sewers. Place collected waste in
approu~d cob:arBors, and seal. For spills to ground or surface
enRay reps SASH.Coo 110Sms u~'ate~ Notify appropriate authorities. Contact 5M to eualuate ft lurlher needs. coma sees: ]~ECOMHENDEO DISPOSAL: iva ninco acommerfac nessa of incinerate In an Industrial or commercial facility In the presenoe of Commemara, amsosion rE Se a combustible material, oCombustlon PrOducts will include HF.
Pass cenlamlnated water through anion excl~ange rosin. ] f necessary,
SE Y # ,'on:act 5M for assistance. ummm ENUIBDNMENTAL DATA: uaTopicsos: hice Gg ean Co: 1 Data forproduct solids: Chemlcel Oxygen Demand (CO0): Nil Ciao tae) Dotan BS05 i: 5, (,OODTggg/g], Biocltemlcel Oxygen Demand (BOD2O): Nil; gS-Hr. LCSD, et Lp ue: 308304AE, se Bluegill Sunfish (Lopoml; macroch]rus}: 569 my/L; gE-Hr. LESO, Fathead Pes roe T6060 (35 ts mn 652 Minnew(PlmePhales prome]as]: 756 my/L; ~8-Hr ECSO, Oaphn[a magna: 6~ uA Gay C33 (hry wen re ge lpr my/L; 14-Dad EChO (cell d~ weight), Brean Rlgaa [Salanastrum lama1 ok hin ocr ace 1, ~prico~utum) 7~ mg/L. Soil Adso~lion Coefficient (Keel: 17, tesrg mB. (510830183 $043 oa ]n~[~tes u8rg high mobliity, [study used a sandy loam soil).
REGtlLRTQRy INFORMATION:.
etesrg: Compe: ir. Volatile organic Compounds: N/R. BCHELrsan wena JJOC Less HZO & Exempt Soluents: N/H, Ssreqtons sy, cout gsc regions svt '~lnce Rgulallens nard, cons.ult applicable regulations or authorities Ear dopo 3.58 ards AS amor ho kU. before [llsposaf, U,S, EPR Hazardous LUaste Number = None (Not U,S. Davesrtoe. EPli Hazardous). he companens a is raear 1 arptance inte chic The components of this product are in complfance with the chemical eatenrecent of 5 INGE, Cn. nd ES registration requirements of TSCR, El NEES, CDSL and Rife. ean manocuss: PRR XRZARD CLASS: TRC Wad a PSSENEo REACTN:o REITE: Ys EARYNe I:IRE XAZAP,~ No PRESSURE: No RERETIUITY: No RCUTE: Yes CHRONIC; Yes
soe rT -- 6. SUG~;ESTED FIRST RID
eae ~EYE I~DNTRL-i': Tele sh se wh rgsma ofate orates 15 Immedl'alely flush eyes ~Jllh Iarge amounts ~f ~ater for at Isast 15 te.ot nected en, minutes, Got imme~iate medical attention, Trediat a ski itso sn are sunsofwa. ans Immediately wash Sl<In with soap and large amounts of u~ater. Remnue aminedcian. ig srs ocr CO A, contaminated clothing. If slgns/sgmptom~ occur, call a physician,
Eo conrsada Gong To Fans on Gooof manistes l!Jash contaminated clothing bel,ore reuse and dispose of c~ntaminate~
shoes.
ET Ero TT TI ................................................................ Fo3e Nat rs eaines NA FPS CRESTOR gbb~iations: N/O - Not Determined HIE - Hat Rppficable CR - Approximately
PP11..88119955.33 Eos EIDO08494
11447711..00002266
SSTTAATTEE 0077554433996688
E m8Rus ran rca a 6, SUGGE~EED FIRST RID (continued)
aawnn
mame: 1NHltLATION:. Fe spt cn, ros to re s If signslsgm~toms occur, remove person to fresh air. If en. ~igns/sqmptoms continue, call a phys[cian. TE son, gre amo,ca hg. SlllltLLDW
not induce vomiting. Drink two glasses of weler. Call a physician.
ET 7. PRECRUTI9NRRY IHFORMRTIgH re: EYE PROTECTION: TE cs, wearers Ruvid eye contact. Wear uented goggles. samo: SKIN PROTECTION: TREE, beasortsgees es vncng ls ~uold skin coolant, tLlear appropriate glooes when handling lhls Te hg ta Be TAS material, R pair of gloves made from the following material(s) are
recommended; burst rubber. Use one or more of the rnllowlng
F chap ame a prSe 48Cotst esd personal protection Items as necessa~ to prevent skin contact: head Ey et et mts ie on ge hed covering, coveralls. Protective garments (other than gloves) should
Tr re eErt en be made of either of the following materials;
polgethglene/polyuinytidene chloride {~:aranex}
Cormeen se seerssen cae Coueral! made of TRUnk(r). Wear rubber boots when cleaning up spills, sveemomno: i~ECDMMNDD VENTILRTIO;'q: i oe He ast etn, Frais fic Use with apprapHate local exhaust ventilation, Provide sufficient emt amit. ventilation to maintaln emissions below recommended exposure limits. at oon ok ees Soe pe If euhaust ventilation is not adequate, use appropriate resplratorg in, protection.
`Fw~eEs~pPiIRaRgToQnReY PpoRoOTTEECCTTIIOONN::
pipiens -------- Avoid breathing of vapors, mists nrspray. Ruold breathing of SRE, oe er Be airborne material. Select one of the following NIOSH approved
resplralors based on airborne concentration of contaminants and In
ohn fac a ey accordancam[th OSHR regulations: full-face high-erriclencg filter A respirator, fall-face supplied air respirator. ' rec of sco no: PREVENTION OF flCC[OENTRL INGESTION:. ar Lh nr te osc, en cor no not oat, drink or smoke when using this pro~luct, Wash exposer[ mm eesa eSs evio areas thoroughlzJ.wilh soap and water. Wash hands after handling and
before eating.
r[eSoaatets ni hl tes. trea rea tora. lZEEOHMEND11 STORRGE: no not store containers on their sides. Store at room temperature.
Keep container closed zuhen not In use.
tation 3StenNtAVFe 8 Fors o Rbbreu|ations; HID - Not Determined N/A -Nat flppllcable CR - Rpproxlmatelg
.PP11..88119955.44 womes & EID008495
11447711..00002277
SSTTAATTEE 0077554433096609
Te5c:aEn113,0199o7na Brand ereScrTfacttaRnt
2FRGERITONAY BEOATION (coins
Fsma sion: FIRE 8NO EI{PLDSI0N AVOIDANCE= Kei onianer gi oss. Nontamale. Keep container tightly closed, Nonflammable. maacnme on: OTHETI FRECBIJTIONARY INFORMR~ION: mings Smoking hl wing is productcan ras No smoldng: Smoking while using t?zls product can rasull In Containof18 tices 35m0ek soenrd 1s ne fortion z:ontamlnal~on of the tobacco and/or smoke ~znd lead to the formation aria econ ross ras nen 1 at" the hazardous decompos|tlon products mentioned in section 4 of
~hls
}IMiSHRZA~D RRIINGS: HEALTH: 2 FLAMMABILITY: I RERCTIUiTY: 0
PERSE PACE (5 rcastons, scion 2) PER'~DNAL PE~TECIION~ X {See precautions, sectloll 7,)
wasscuvas EXPOSURE LIMITS
nai huewr vee umsk INI;RErIIEI'R"
URLUE UNIT TYPE AUTR SKIN+
Eo a F~=B...................... NONE NONE ETI. 081 RS Tn GE ILHMDNIUMPERFLUORQACTANQATEo........ Erma oF hd AMMDNIUM PERFLUOAOHEPTANOR~........ EroPERMIT 0) vai TR Nf R~ONIUMP~FLUQRQXEHflNOR~....... IMPRLRORORE 61 HES Tun BY B~NIUH P~RFLUDROPE~ANORT~........
NONE NONE I],Ol ~G/M3 0.I MG/~ O.l MG/M3 O. I MG/M3
~A ~A TWA T~A
gCGIII Y
~M Y 5M Y ~ Y
SKINNGTETION: Usted sbstance cca thse SKIN e ter to * SKIN N~HilON: Listed substances Indicated mith 'Y' under SKIN refer to Rotel catisaton t a cosaexport cams ree the putentlal contribution to the overall exposure by the cutaneous route in tos ara ae, ber Sono. or pri, in~ludlng mucous membrane and ere, either by airborne or, more particularly, Birch contact ih heSs. Des 08 Sher iSuro: bg ~irett ~ntact ~itR the substance. Uah!cles can altar skin abso~tlon.
sscor rosa ore. SDURL"E OF EXPQSUAE LIMIT DATA: HCE, rca Courseof Gormmeatal Insta agossts - AEEIH: Emerlcan Conference of Ooueromenta] Industrial Hgglenlsts Ihatune aminnaevs apostles - ~M: 3M Recommended ExpoSure Guidelines
- N0~ None E~tabllshed ~
A ~. HERLTH HAZRRI] BETA
recone E'~E CON'~CT~ Ne Lo) 310 forte suo. meen erfvrosigt. No t0xlc|tg data rot tile solution. Emmonlum perfluoroalkgl raisB oAne 1h aed) se arhoxglate =an be Irritating to the eye and may cause eye inJuts
&=m ai~orne e~pesure.
Sratrough he skin a ers hbo foron May be ab~a~ed thraugh the skin and pa~sl in the body for an me extended tim~ 5 ey dat or thst,Amatoprorat ~Q t~xlE]~y data for th~ solution. Ammonium perfluoroaikgl Srey TE Lv hn ssomed su on 11 c~oxglale is sllghl(~ toxic w~en absorbed t~rough the skin; ena tn - aon-lrHlating to the
Feaeatt7i3o-Nnost etrmined WA Not Topless Shohpra B~reulatlnns: HID - Not Determined N/FI - NoI Applicable CI] - Approximately
PP11..88119955..55 fro. El'D008496
11447711..00002288
SSTTAATTEE_0077554433997700
PP11..88119955..66
MSTTein108 198AAD Brad Porsche Sraceantto H~OS; FC-118 FLIInFIRD Brood Fluoruchemlcal Surfactant
Yr'brL~artJ 19. |997
PRG 5
Sz 8. HEALTH HBZFIIID OATh ene (continued)
ammo. INHRLRTIQN:.
; "
idbeSareesby tas32 ers1 ht bdfor 3 tended Hag be absorbed by Inhalation and persist in the body for an extended
Telime.
Notate ot or hesoutien. motor serruersati No toHl~lty data fur the solution. Rmmonfum perfluoroal~gl Errata ss apronsien etn rom haat: z:arhe~glale rnag cause Rsp[rato~ system Irritation from Inhalation;
| SimnSaECcSioynitaatrsstcoomnrccaooneautftfreoo,wsRebgytpecnitrlsesaaxynnpwaetoarnn 4ci1lssesupieneesro: 980 m~llig~ms 92~ cubic meter, Repeated inhalat[o~ eHgosufe haar hgh 5d SRA Ho a i . p~duced liue~ changes ~nd eleuat~ blood o~gano~luoride leuel In
~t~
swmoues: IF SIDALLOLUEQ: gusitos ont a Wty ostofnprto hs roe. Ingestion is not a liE:Big route of exposure to this product, No ey at forte sein morn serores. NO toxicltg dot3 for the solution Rmmonlum perfluorualk:gI `Sromiates Consomrd modurian toe rom ngaart carbnxgtate Is considered mode~telg toxic from a single oral pecunrae 59 ra) + 4 mF 5.Bod BG. eHposu~ acute u~l ~DSO (rat) Is 540 my. per ~g. of body weight. ee ERNCEt~ i cenaa comics nen cncss coca, (5825.21) LUAANING: Contains a chemical ~uhlch can cause cancer. (3925-26-It 153 193shi conducted oro) 1 0 pen and 1993 studie~ conducted Jointly by 3M and OuPonl]. ramemae: HIffAW:'N I I:ITY: ronan pres crseete wes not agen a ales | Ammonium perfluoroal~:lJl carbnxylate w~s not mutagenlc In iaultr~ ape sso, 0 ot cosecl ramon3 maaan mulagantcitg assays. Old not cause cell transformation in a mommallan soH apnsmermmaaonpsoe.cTEnRNS: REPRODtlI:/IIIE/DEUELOPMENTAL TSH I I~," rien erro) corbosoe ss ot Lrtageric rb Ammonium perfluoraall~gl cerboxglale was not teralOgenlc In ~bbits bg Emi ds ap 10 es 08 ~ml administration and was nut t eratogenlc to rats by gauage and
~halatlnn e~:posures.
A
RICHTIENRRY1.SECTION CHRNGE SINCEFabs ]~AEIEAITi'I]]NAR~ INFD. SEL'TIQN CHANOE9 SINCE February O,07, 1991997 1S5EISSUE
brati3on luteRd AT t Frc Go spam rouat iet P.bbmu[ations; HID -Not Determined N/A - Not Applicable CA - Appronfmately
mer EID008497
11447711..00002299
SSTTAATTEE 0077554433997711
=
mm SOE TE-118FLUSRAD ws BrandPsorocheSumraictcanat
FE ----, The tn1"armatlon i'n this Material Safetg Data Sheet {HSDS] Is belleaad to oe be correct as of the dale Issued. 3M MXI~ES NO tURRRXNTIES. EXPRESSED DR BA Sh IHPLIED, INCLUDING, ]lilt NOT LIMITED TO, PiNY IMPL] EO tlJRRRRNTY OF Ee STP HERCHRNTRBIL]TV OIt FITNES FDR R PRRTICULI~R PU~iPOSE OR COURSE OF FE re PEGFOllMRNCE OR USItGE OF TRFIDE. User Is responsible for determining A a ce, whether the ~H product is fit for a particulal' purpose and Suitable rot EE user's realized at" use or application. Gluen the uarletg or factors that E ie Sh can afle~11he use and application or" a 3H product, some of mh|ch are E E EE r e E uaiquelg withlu Ihe user's knowledge and control, it Is essential that
the user eoaluate the 5M product to ~[otermlne whether It Is fit fo~" a part~:ular purpose and suitable for user's method of use or application.
S Be T mT 5H provides inl'ormation~n electronic farm as ~ service to its customers,
Oue lo the remote po~sil~llZtg that electronic irons rer map haue ~esulted
i in e~a~, omissions or alterations In this Inr~atlon, 3M makes no
rep~sentatlons as to [ts ~ampieteness or accuracg. In
En znrn~a/Znn nblaine~ from a database map nnt be ~s current as the EEE TT intonation in the ~SD~ available d~rectly from ~M,
PP11..88119955..77
11447711..00003300
mows EIDO08498 &
Stateorsiaom2 STATE 07543972