Document YDL4EjvN4O6MRpKRNdVrNnarn

!A)0 ''0/ U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY RATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) ... '-m, 55b "tS SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. Richard Klinger Inc. (513)*498-118! address ,'Xumbcr. Street. City. Stctc. and ZIP Code) 2350 Campbell Road Sidnev. Ohio 45365 CHEMICAL NAME ANO SYNONYMS TRADE NAME AND SYNONYMS Compressed Rubber Bonded Asbestos Sheet Packing Klinger K-61 White CHEMICAL FAMILY FORMULA Mixture of SBR Rubber and Asbestos N/A SECTION II HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES. & SOLVENTS % TLV (Units) pigments Titanium Dioxide h- \k% ICMg/M3 ALLOYS AND METALLIC COATINGS BASE METAL TLV % (Units) N/A CATALYST VEHICLE SOLVENTS ADDITIVES OTHERS N/A ALLOYS N/A N/A N/A METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS N/A HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES N/A N/A N/A N/A TLV % (Units) Chrvsotile Asbestos CAS #1332-21-4 70- 90 #1 Stvrene-Butad iene Rubber CAS #9003-55-8 Titanium Dioxide CAS #13463-67-7 8- 15 #2 h- lOMe/M3 #l-Two fibers/cc greater than 5 urn in length. #2-No TLV established. BOILING POINT (F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR*1) SOLUBILITY IN WATER APPEARANCE ANO ODOR SECTION III - PHYSICAL DATA Decompose SPECIFIC > GRAVITY (H^OM) N/A PERCENT. VOLATILE BY VOLUME {%) N/A EVAPORATlpN RATE < . =1) Insoluble Solid off_whte 1.65-1.85 1 ! N/A N/A SECTION IV - FIRE AND EXPLOSION HAZARD DATA flash POINT (Mtnoo used) N/A FLAMMABLE LIMITS EXTINGUISHING MEDIA Water, Carbon Dioxide. Drv Powder, or Foam. SPECIAL FIRE fighting PROCEDURES Firefighters should use self-contained breathing equipment N/A and eve protection for the rubber fumes. UNUSUAL FIRE AND EXPLOSION HAZARDS The rubber, once ignited mav need extra cooling to prevent reignition. PAGE (1) (Continued on reverse side) Form OSHA-20 Rev. May 72 2- SECTION V - HEALTH HAZARD DATA THRESHOLD EiMIT VALUE (TLV) - .Asbestos - 8 hour TWA (Time Weighted Average) of 2 fibets/cc greater than 5 um in length. - EFFECTS OF OVEREXPOSURE - The material in its finished form presents no known health hazard. A chronic health hazard may be created if further processing of the sheet allows asbestos fibers to be released into the atmosphere. .Inhalation of free asbestos fib4r over a long period of time can cause lung disorders, including asbestosis, pleural plaque, lung cancer* and mesothelioma. SECTION VI - REACTIVITY DATA STABILITY - The material has" infinite storage stability,. INCOMPATABILITY - Strong oxidizers, strong acids, or bases. HAZARDOUS DECOMPOSITION PRODUCTS - Burning rubber (See Section IV), and free asbestos (See Section V). HAZARDOUS POLMERIZATION will not occur. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Dust from sheet should be treated as free asbestos. Secure area and clean up using HEPA-filtered vacuum, or wet sweep. DO NOT clean up in a method that generates dust into atmosphere. WASTE DISPOSAL METHOD - Bury in solid landfill as required by 29 CFR 1910.1001 (N)(2). SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION - None required where local controls ensure negligible asbestos dust released into atmosphere. Where local controls not adequate, use respirator approved pursuant to 29 CFR 1910.1001 (D)(2). See section IX - Special Precautions. VENTILATION - Where dust producing processes are used, local ventilation, air filtration and good work hygiene must be used to ensure negligible asbestos dust released to atmosphere. EYE PROTECTION - None required for normal use. OTHER PROTECTIVE EQUIPMENT - None required for normal handling or fitting of gaskets. Where gasket removal involves scraping, wire brushing, or other potential dust pro ducing operations; local ventilation, air filtration, 'good work hygiene, and where applicable, wetting down should be used to ensure negligible asbestos dust released to atmosphere. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - In the manufacture of Klinger com pressed asbestos sheet packing, the asbestos is encapsulated into the sheet by a rubber matrix. In normal handling of sheet and cut gaskets, no significant release of asbestos dust occurs. In the production of cut gaskets; local ventilation, air filtration, and good work hygiene must be used where the production process may release fibers into the workplace. The material must not be drilled, sawed, ground, sanded, or subjected to any other dust producing process without the necessary equip ment required to ensure that released fibers are' contained. SECTION X - DATE AND SOURCE OF INFORMATION DATE - November 20, 1985 NAME - Derek Coomber, Vice President ISSUE #85-01 CQRPORAnON l/JJ - O / 6 G> DO NOT DUP* C '-I THIS FORM REQUEST AN ORIGINAL 1 -- Caif'-i-. Corporation requests that usefs of "Calidria" Asbestos stiidytois data sheet io become aware of the product's hazards, end promote safe handling of the product by making this infer' av.siiabte to itsdmployees, agents, and contractors. If the material is resold. Ca`Mt;a Corporation requests that the purchaser be fumi3r<i>d a copy of this daia sheet and advised- to provide the mfc..r,anoo heroin to its employees, agents arid . contractors. v. SECTION I ............................ PRODUCT IDENTIFICATION ' -- .M -- v `v Product"Name: CALIDRIA ASBESTOS. Chemical/Alloy Name: -Chrysotile Asbestos. Synonyms:' Asbestosi White Asbestos, Hydrated Magnesium Silicate. C.A.S. Numbers: 1332-21-4, 1309-38-2 Formula/Composition: Mgfi(OH)gSi40io+Fe304 \ SECTION II PHYSICAL DATA Sizes: 3/8" pellets to powder. Specific Gravity: 2.45 approximately. (H20=l). Odor: None. Appearance: White fibrous solid or pellets. Bulk Density: 15-45 lb/ft3, as packaged. (Depends on product form.) Molecular Weight: Not applicable. Solubility in Water: Very slightly soluble. Melting Point: F (C) Dehydrates above 1112 (600). Boiling Point: F (C) Not applicable. Vapor Pressure: Not applicable. Percent Volatile: Absorbed H2O 1-4Z by weight. Structural H?0~13% by weight. Evaporation Rate: Not applicable. SECTION III HAZARDOUS INGREDIENTS Material or Component (CAS #) Weight %PEL Data (TWA Unless Noted) Chrysotile Asbestos (1332-21-4) 95-98% 2 fibers/cc longer than 5u (1)(2)(3)(5) 10 fibers/cc longer than 5u, ceiling (1)(2)(3)(5) 0.1 fibers/cc longer than 5p (4) - ~ 0.2-0.5 fibers/cc longer than 5u (1) (Proposed) Magnetite Fe-^04 (1309-38-2) 0.5-2 - ---I ------- - -- -- - j--------_____________________________________ j -- Reference*: l OSHA Stenderd 1910.1001 2 HSKA Stend.rd 5 mg/cu m respirable dust 15 mg/cu m total dust 10 mg/cu m total dust 3 Current ACCIH * NIOSH Recoonendet ion (1)(2)(5) (1) (2)(3) 5 Celidria Intem.l Standard Emergency H.E.L.P Telephone: 304-744-3487 Calidria Corporation P.O. Box K, King City, California 93930 Jt SECTION IV HEALTH HAZARD DATA oaiidna ~ Asbestos (21 " `4. ACUTE EFFECTS OF OVEREXPOSURE Route of Exposure: Inhalation: Any dust (including asbestos) which is inhaled in substantial amounts, may irritate the respiratory tract. Extreme exposures can overwhelm the normal respiratory defense mechanisms and result in temporary difficulty in breath'itig. Skin Contact: Asbestos splinters may penetrate the skin and cause asbestos "corns." Skin Absorption: Not applicable. Eye Contact: May cause irritation and abrasions. Ingestion:________ No known effects. CHRONIC EFFECTS OF OVEREXPOSURE Route of Exposure: Inhalation: Overexposure to Chrysotile Asbestos has caused damage to lungs (asbestosis), lung cancer and mesothelioma of the pleura and peritoneum. Symptoms, which are usually hot manifested until 15-20 years after exposure, include labored breathing, chest pains, weakness, and chest tightness. Pleural thickening, plaques and effusion are nondisabling conditions, seen separately or together, that have been associated with prolonged asbestos exposure. The risk of lung cancer is greatly increased for those who smoke cigarettes regularly in addition to having asbestos exposures. Skin Contact: Not applicable. Skin Absorption: Not applicable. Eye Contact: Same as acute effects. Usually reversible on removal from exposure. Ingestion: Some studies indicate that asbestos overexposure is implicated as a cause of gastro-intestinal and laryngeal cancers, but the evidence is conflicting._________________ _________________________________ EMERGENCY AND FIRST AID PROCEDURES Route of Exposure: Inhalation: No acute toxicity: Remove to fresh air. If breathing is difficult, oxygen may be administered. If breathing has stopped, administer artificial respiration. Call a physician. Skin Contact: Remove asbestos slivers promptly. If "asbestos corn" develops, surgical removal may be required. Eye Contact: Ingestion: Irrigate gently with water for 15 minutes. Refer to ophthalmologist to rule out possibility of damage to cornea or eyeball by fibers. None indicated. NOTES TO PHYSICIAN A medical surveillance program must be established for asbestos--exposed persons in accordance with the requirements of the Occupational Safety and Health Administration's standard for Asbestos (29 CFR Part 1910.1001). Calidria Asbestos (3) I SECTION V' FIRE W* P LOSION DATA \ Combustibility: Not combustible. ______ ___ !'1v;m^le Limits: Not applicable. Flash Point (Test Method); Not applicable. Autoij>rition Temperature: Not applicable. Explosion Tendency: Not applicable;_____ Extinguishing Media: Use media appropriate tor ^.urrounding material in fire gituat-ion. Special Fire-Fighting Procedures: Avoid media and procedures that cause airborne;, dust. Personnel involved in fire-fighting should use NIOSH/MSHA-approved self-contained breathing apparatus a*.l full protective clothing. _Unusual Fire and Explosive Hazard: See above.______ __________________ .________ ____________... SECTION VI REACTIVITY DATA Stability: Stable (Temperatures in excess of 1112 F (600 C) cause loss of _______ ___________ bound water) .__________________________________________________________________ _ Conditions to Avoid: None.__________________________________________________________________ _ Hazardous Decomposition Products: None.__________________________________________________ Material to Avoid: None. SECTION VII SPILL, LEAK, AND DISPOSAL INFORMATION Steps to be Taken if Material is Spilled or Released: Avoid breathing dust. Notify Safety personnel of spill. Permit only trained clean-up personnel in the spill area. Use wet methods or approved vacuum cleaning system to pick up spilled materials. Use water or other dust suppressants where sweeping is unavoidable. Do not stir up dust. Clean-up personnel should wear approved respirators and protective clothing. Waste and contaminated protective clothing must be placed in dust-tight containers and be properly labeled for disposal. Neutralizing Agents: Not applicable.______ ________________________________________ Waste Disposal Method: Bags, friable asbestos, waste and scrap material should be disposed of in a manner which will avoid airborne concentrations of asbestos, such as the use of dust-tight trash bags or containers. Such containers should be labeled in accordance with 40 CFR 61.20. Asbestos is also classified as a hazardous material under CWA 307(a) and has a reportable quantity of one pound. Deposit waste containers in a secured landfill in accordance with Federal, State, an<T local regulations._____________________________________________________________________________________ 2 3 1935 SECTION VIII SPECIAL PROTECTION INFORMATION Ventilation: Provide adequate exhaust ventilation and capture filtration to remove asbestos particulate from the workplace and minimize its dispersion into the environment. .Isolate work areas and post signs where asbestos contamination may exceel PEL. Hand- or power-operated tools which may release asbestos in excess of the PEL must be equipped with local exhaust systems. __________________ _______ ___________ _________ ________________________^alidriaw Asbestos -(4) SECTION VIII SPECIAL PROTECTION INFORMATION (Continued) Personal. Protective-Equipment: Respiratory Protection (Type): Where asbestos exposure in excess-of the permissible limits . is anticipated, wear a NIOSH/MSHA-approved respirator; a reusable or single-use air purifying respirator up to 10 times the PEL: a powered air purifying respirator up to 100 times the PEL: a continuous-flow or pressure-demand Type C supplied air respirator for greater than 100 times the PEL. Eye Protection: Goggles.?re recommended. Follow Safety Rules. Gloves/Clothing: ' Gloves are recommended during handling. Other: For concentrations in excess of the ceiling limit special clothing, such as coverall's, whole-body clothing, head coverings, gloves, and foot coverings are __________________ required under CFR 1910.1001. _____________ ______________ SECTION IX SPECIAL PRECAUTIONS Precautionary Statements: WARNING CANCER HAZARD Breathing asbestos dust can cause lung damage and cancer. cancer is greatly increased, for smokers. The risk of lung Do not create or breathe dust. Do not dry-sweep or use air hose for cleaning. Do not take protective equipment or clothing home. Do follow recommended work practices. Do wear approved respiratory protection and protective clothing as required by applicable regulations. Do use vacuum or wet cleaning methods. Do dispose of dust, friable waste materials and contaminated protective equipment in dust-tight containers. FOR INDUSTRIAL USE ONLY Precautions for Handling and Storage: Store asbestos in closed containers (dust-tight) in a clean, dry, secure area. Protect containers from damage. Do not open containers in a manner that can release dust without providing proper enclosure or control measures. Use dust suppression control measures at all stages of asbestos handling, use and disposal. Follow good housekeeping practices to prevent accumulation of asbestos-containing dusts. Avoid inhalation of asbestos.. _____ Other Precautions: Material Listed as Carcinogen in: National Toxicology Program Annual Report (NTP): Known carcinogen. International Agency for Research on Cancer (IARC): Group I - Carcinogenic to humans. OSHA 29 CFR Part 1910, Subpart Z: Occupational Exposure to Asbestos, Notice of ____________ Proposed Rulemaking, F.R. Vol. 49 No. 70, p. 14116 et seq. Tues., Apr. 10. 1984. Copyright All rights reserved, 1984. ' Effective Date: December 31, 1984. Calidria Corporation believea that the data herein are current at of the effective date of this data sheet, and that the opinions herein are chose of qualified experts. Since the product and the information herein will be used outside the control of Calidria Corporation, it is the user's responsibility to establish conditions for safe use of the product. The data herein relates only to the product of Calidria Corporation and nay not be applicable for products of other manufacturers.