Document YDDa6pLJVEDYMYzqN64JavJXN

specialty chemicals I li; / ;*. -' . %'. .;V: v^,a;.; DECHLORANE PLUS 515 , \ . , .',;> , ---1' ' V-" '"'; -X\ > , - v DESCRIPTION Dechlorane Plus 515 flame retardant additive is a highly effective, chlorine containing crystalline organic compound prepared by grinding to free-flowing white powder. TYPICAL DATA Chlorine Melting Point Density Vapor Pressure @ 200C Average Particle Size, Microns SOLUBILITY 65% >350 C 1.8--2.0 g/cc 0.006 mm of Hg 5-15 Solvent Grams of Dechlorane Plus 515 per 100 grams of solvent at 25C Benzene Xylene Styrene Trichloroethylene Methyl Ethyl Ketone n-Butyl Acetate Hexane Methyl Alcohol APPLICATION 2.0 1.0 1.8 1.4 0.7 0.7 <0.1 <0.1 Dechlorane Plus 515 is suggested for use as a non-platicizing flame-retardant additive in polymeric system. Its application is in standard moldings. In applications requiring finer part icle size such as films and sheets Dechlorane Plus 25 is recommended. It is commonly used with antimony oxide synergist. SHIPPING INFORMATION Multi-Ply Paper Bag PRECAUTIONARY INFORMATION Net Weight 50 Pounds Gross Weight 50Vi Pounds Dechlorane Plus 515 is relatively inert. Tests indicate that it is relatively non-toxic; however, since it has not been fully evaluated in all respects, prolonged contact with skin should be avoided. Precautions should be taken to avoid breathing the dust. Mlt. 11-1634 May 1980 FOR MORE INFORMATION WRITE SPECIALTY CHEMICALS DIVISION, HOOKER CHEMICALS A PLASTICS CORP., NIAGARA FALLS, N. Y. 14302 FORM 9354 H-W The information presented herein, while not guaranteed, is to the best of our knowledge true and accurate. No warranty or guarantee express or implied is made regarding the performance or stability of any product, since the manner of use and conditions of storage and handling are beyond our control. No suggestion for product use, nor anything contained herein, shall be construed as a recommendation for its use in infringement of any existing patent. DO 086404 CONFIDFNTIA Dechlorane Plus 25 Description: Dechlorane Plus 25 is a highly effective chlorinecontaining organic flame retardant additive, pre pared by grinding, to free flowing, white powder. Data Sheet No. 344D November 1981 Cl Cl Hooker Specifications: Appearance Average Particle Diameter, Microns (Fisher Subsieve Sizer) Average % Retained on 325 Mesh Screen (Wet Screen Analysis) pH (Methanol-Water Extract) Volatiles, % (4 hours at 100C at 5mm Hg) Color - Rd Typical Data: Chlorine Melting Point Density Vapor Pressure @ 200 C Average Particle Size, Microns White, Crystalline, Free-Flowing Solid 5 Maximum 0.15 Maximum 6.0-8.0 0.15 Maximum 93 Minimum 65% 350C (with decomposition) 1.8-2.0 g/cc 0.006 mm of Hg 2-5 Solubility: Solvent Benzene Xylene Styrene Trichloroethylene Methyl Ethyl Ketone n-Butyl Acetate Hexane Methyl Alcohol Grams of Dechlorane Plus 25 per 100 grams of solvent at 25 C 2.0 1.0 1.8 1.4 0.7 0.7 0.1 0.1 DO 086405 CONFIDENTIAL Use: Dechlorane Plus 25 is used as a non-plasticizing flame-retardant additive in polymeric systems. ^6VVc -p.L - ^ For more information write: HOOKER CHEMICALS & PLASTICS CORP., INDUSTRIAL CHEMICALS GROUP, NIAGARA FALLS, N.Y. 14302 IMPORTANT! The information presented herein, while not guaranteed, was prepared by technical personnel and is true and accurate to the best of our knowledge. No warranty or guaranty, express or implied, is made regarding performance, stability or otherwise. This information is not intended to be all-inclusive as the manner and conditions of use, han dling, storage and other factors may involve other or additional safety or performance considerations. While our technical personnel will be happy to respond to questions regarding safe handling and use procedures, safe handling and use remains tne responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be con strued as, a recommendation to infringe any existing patents or to violate any Federal, State, or local laws. pL_o, NFPA Precautionary Information: DECHLORANE PLUS CAUTION! Dust may be irritating to eyes and respiratory system. FIRE HAZARD RATING Precautions Handling A Storage + First Aid + Keep container closed. In Case of; Get medical aid for all over Insure adequate ventilation. FIRE: over exposures. Avoid contact with eyes. Use extinguishing agent In case of eye contact, Avoid breathing dust. suitable for surrounding fire. immediately flush eyes with a Wash thoroughly after Use self-contained breathing direct stream of water for at handling. apparatus and fully protective least 15 minutes while forcibly Wear approved chemical clothing. holding eyelids apart. goggles, dust mask, gloves Fire may liberate toxic gases. If swallowed, do not induce and clothing. SPILL; vomiting, dilute by drinking Do not allow to sewers or Transfer into container for water. If vomiting occurs, waterways. reclamation disposal. administer more water. Heating in excess of 275C/ DISPOSAL: Wash contaminated clothing 525F may cause degradation Material that cannot be used before reuse. and release of toxic gases. or chemically reprocessed should be disposed of in a manner meeting government regulations. Shipping Information: Multi-ply Bag Net Weight 50 pounds Gross Weight 50 pounds Dechlorane Plus 25 is not regulated by the Department of Transportation and, therefore, has not been assigned a DOT hazard classification. Dechlorane Plus is listed in the Toxic Substance Control Act (TSCA) inventory under the CAS Number, 13560-89-9. DO 086406 CONFIDENTIAL INDUSTRIAL & CHEMICALS Data Sheet DECHLQRANE PLUS Oata Sheet No. 340 March, 1981 - Toxicity Summary Study Test Species Result A. Acute Toxicity 1. Acute Oral 2. Acute Dermal 3. Acute Inhalation Albino Rat Albino Rabbit Rat LD50>25 g/kg LD50 78 g/kg LC50 ?2.25 mg/1 iter B. Eye Irritation Albino Rabbit No effect as an ocular irritant was observed. C. Skin Sensitization Guinea Pig The material is not considered a sensitizer. D. Subchronic Toxicity 1. Oral yu-L)ay Albino Rat The test compound was administered in the diet at 1%, 3% and 10% levels. There were no study related mortalities or untoward behavioral reactions. Growth and food intake were normal. No treatment related differences between test and control animals were observed in clinical blood chemistry, hemotology, urinalysis, gross pathology and histopathology at all feed levels. Slightly increased liver weight was observed at the 10% dietary level but not at the lower levels. 2. Dermal 28-Day Exposure Albino Rabbit At levels of 500 and 2000 mg/kg there was practically no irritation with repeated exposure. There were no significant adverse effects noted in the following areas: Body weight, hematology, blood chemistry, urinalysis, and pathology. Statistically significant lower weight of gonads was observed in females of both test groups and lower liver weight in females at the 2000 mg/kg level. The differences were within the general range for young rabbits of this strain and age. do 086407 CONFTDFNTIAl OXY. Occidental Chemical Corporation HOOKER Industrial & Specialty Chemicals Hooker Chemical Center, 360 Rainbow Boulevard South, Box 728. Niagara Falls, New York 14302 716/286-3000 IMPORTANT! The information presented herein, while not guaranteed, was prepared by technical personnel and is true and accurate to the best of our knowledge No warranty or guaranty, express or implied, is made regarding performance, stability or otherwise. This information is not intended to be all-inclusive as the manner and conditions of use, handling, storage and other factors may involve other or additional safety or performance considerations. While our technical personnel will be happy to respond to questions regarding safe handling and use procedures, safe handling and use remains the responsi bility of the customer No suggestions for use are intended as, and nothing herein shall be construed as, a recommendation to infringe any existing patents or to violate any Federal, State, or local laws DECHLORANE PLUS - Toxicity Summary 2- - Data Sheet No. 340 March, 1981 Study 3. Dust Inhalation 28-Day Exposure E. Biodegradation F. Aquatic Toxicity G. Mutagenicity Test Specie Albino Rat Sewage Sludge Bluegill Sunfish Result Exposure levels were 640 and 1524 mg/cubic meter. The following parameters were normal: Body weight, blood chemistry, clinical chemistry and urinalysis, and gross pathological examination. Absolute liver and lung weights and lung to body weight ratios were higher than normal in all or some of the test groups. Some histopathological alterations of the lung tissues were observed. These types of changes are frequently observed with exposure to organochlorine compounds and are normally reversible when exposure is terminated. Dechlorane Plus is degraded under aerobic conditions but not under anaerobic conditions. No deaths were observed in 96-hour static and flow through tests at applied concentrations of up to 100 ppm. Dechlorane Plus did not show a mutagenic response in the following tests: Standard Ames Assay (with and without activation), Ames Assay on Urine from rats treated with Dechlorane Plus, and Mouse Lymphoma Forward Mutation Assay (with and without activation). The information presented herein contains accurate summaries of toxicological studies performed by others under contract to Hooker. While we have no reason to believe that such studies, and the results thereof were not reported accurately to us, and while we do believe such studies and reports to have been accurate, Hooker cannot and does not guarantee or make any representation or warranty with respect to the accuracy of the information. DO 086408 OONFTDFNTTA1 ll hooner Product Nana: DECHLORAN PLUS MATERIAL SAFETY DATA SHEET I PRODUCT INFORMATI N Chemical Name: l,2,3,4,7,8,9,10,13,13,14,14-dodecachloro-l,4,4a,5,6,6a ,7,10,10a,11,12,12a dodecahydro-1,4;7,10-dlmethanodlbenzo (a,e)cyclooctene Jhamical Formula: Cl8H12cl12 Common Name NFPA Hazard Rating Dechlorane Plus Use Additive for polymeric systems to Impart flame- retardant characteristics DOT Hazard Classification Non-Regulated Chemical Family Chlorinated Alleyellc Hydrocarbon EPA Registration No. N/A Inpedients II INGREDIENTS ----------------------TlV*--------------------- TWA STEL DechloranePlus LD50 rat (oral) > 25g/kg LD50 rabbit (skin) > 8 g/kg LC50 rat (Inhalation, 4-hour) >2.25 mg/1 13560-89-9 99.84 Volatile Content Hexachlorocyclopentadlene (C-56) `American Conference of Governmental Industrial Hygienists, i9so 77-47-4 0.15 0.01 0.01 ppm 0.03 ppm Ml TYPICAL PHYSICAL PROPERTIES Boiling Point, 760mm Hg N/A Specific Gravity (HjO * 11 1.8 - 2.0 Vapor Pressure mm Hg 20 C 0.006 0 197C/387F Bulk Density O.b /apor Density (air - 1) N/A Percent Volatile 0-15 Solubility in Water Appaaranaa and Odor Insoluble White, free flowing, odorless powder IV FIRE AND EXPLOSION HAZARD DATA Evaporation Rata ( *11 N/A Other - Melting Point 350C/662F (with decomposition) Molecular Melobt 654 Flash Point Tan Method None Flammable limits in air, % volume Upper N/A Lower ____HZi Auto ignition Temperature Spontaneous Heating N/A Extinguishing Media As appropriate for surrounding fire. Special Fire Fighting Procedures it Personnel Protection use self-contained breathing apparatus and full protective equipment. Unpaid Fite and Explosion Hazards Decomposition by burning In open flame may yield various toxic chlorine compounds Including toxic chlorocarbons and hydrogen chloride. V EMERGENCY PHONE NUMBER AVAILABLE 24 HRS./DAY 1 716 - 278 - 7021 ne information presented herein, while not guaranteed, it to the best of our knowledge jt and accurate. No warranty or guarantee express or implied it made regarding the performance or stability of any product, tinea the manner of use and conditions of storage and handling are beyond our control. No suggestions for product use, nor anything contained herein, shall be construed at a recommendation for i use in infringement of any existing patent. I INDUSTRIAL CHEMICALS GROUP, HOOKER CHEMICALS R PLASTICS CORP. Niagara Falls. New York 14302 086409 CONFTDF NTTqi PRODUCT NAME Incompatibility DECHLORANEPLUS VI REACTIVITY Prolonged heating in excess of 275C (525F) accelerates thermal degradation. Hazardou* Deeomportkm Product* Condition* to Avoid Effaeis of over exposure (Route) Acute Chronic First Aid Procedure* Special Medical Procedure* Antidote/Skin Care Other At temperatures in excess of 275C (525F) degradation products Include hydrogen chloride and hexachlorocyclopentadlene. Avoid elevated temperatures. In excess of 275C (525F). VII HEALTH RELATED DATA Oust causes Irritation to mucous membranes. No effect as occular or lung Irritant and skin sensitizer has been observed. Skin: wash with soap and water; Eyes: flush with a directed stream of water. Although DechloraneP1us additive Is not considered hazardous, basic handling precautions are recotrmended. Ventilation Reipiratory (type) Glove*(type) Eye Protection (type) Other VIII SPECIAL PROTECTION INFORMATION General room ventilation. Approved dust mask where appropriate. Cotton Chemical safety goggles Handling end Storage Precaution* Store In a dry place. IX HANDLING AND STORAGE Reportable Quantity (Section 311 of the Clean Water Act) Step* taken in event ol spill or reieaw X SPILL OR LEAK PROCEDURE Shovel Into drums for reclaim or transfer to disposal. XI WASTE DISPOSAL Incinerate In equipment designed to scrub hydrogen chloride as a product of combustion. Do not flush to sewer. Remark* i Reference*: XII REMARKS AND REFERENCES Hooker Chemicals & Plastics Corp. Product Data Sheets No. 344, 345 and 346. HCC Subatanca No. scn-984 DO 086410 OONFJDFNTTAI. Data 1/81