Document YD4OzzvrYx1OB0r5MYM8ZJkz0

ARARG 3Shy ATTACHMENAT 1 Submittal to 084 000004 XY&! EAR CH pLFron "ENE Does NOT avtoin CBT Analytical Report Fluorochemical Monitoring Report CSR Inc. Exygen Research Report No. L0002133 Testing Laboratory Exygen Research 3058 Research Drive State College, PA 16801 Requester William Mizel CSR Inc. PO Box 201857 Arlington, TX 76006 Phone: (817) 633-7236 000005 ALL DATA CONTAINED IN THIS REPORT WAS GENERATIEYD EX\QEN RESEARCH I3E058 sDen Bovoeon on Page Lof8 Xm ang. Summary Twenty-two solid media samples were received by Exygen Research from CSR, Inc. The media represent samples of air collected on OVS tubes and bulk solid materials. The samples were analyzed for perfluorooctanoic acid (PFOA) by solvent extraction followed by liquid choromatography / mass spectrometry (LCMS) analysis. The OVS tubes were separated into three fractions for analysis. Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD resin and PUF backing. FforracptoisosnisblAe fauntdurBe awnearlyesiesx.tracted with 1 ml of acetone. Fraction C was not analyzed but saved Bulk solid materials were extracted into methanol. The methanol extracts were diluted with water and subjected to solid phase extraction (SPE) to remove interferences and concentrate the extract. Chain-of-custody information can be found in Attachment A. Attachment B contains the raw data and analytical conditions for the OVS tube analysis. Attachment C contains the raw data for the bulk solids analysis. ALL DATA CONTAINED IN THIS REPORT WAS GENERATEBYD EXYGEN RESEARCH -- 000006 Results Summary pae9 wtoaow roe n 10 seotew p2ea Veo weetow 1Tss Tose westow Tooetro EC 1434C 1Lisse poe westow poroeny pr ostow SAairmpVloeldum(e1) PraOctAion mPFmO)A 2E7o 70 <0o10010 NA p<o.r00y0 NA [To Tou 2522 Fa <00000040s NA [>To] aatz az <Zoo1l0o <0o0o0000z NA NA [Toom on | a0s0 3% 0<200 NA <0o0.0000058 NA [To | Gm os] 44133 00.0000058 413 FO 1NA 20077 07 <ootte0 NA <0000000042 NA [ToGi ow | 11335 i <5o1100 p<0r0y00:7 NA NA [oz oom ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page3ors 000007 Air Volume ProA Sampled (L) g/traction) g Taorras jas 11390 13 5<o1100 NA Z<o0s0000077 NA words [Tom Thom] Toansas ano a8a Z<oo1n0 NA S<oo0NooA1nt C--O 1pr9m ame Ss2e7r 37 Z<oo01i0 NA Z<o000000038 NA wow [To ows] Tweooons JE S0o15o NA S000000s0 NA moma [Tis Too Toorsa ono <0o1100 NA <Z0o.00000038 NA sores [To<T ooe | jreeaezon Soar7 Sr <o31100 NA <0000000s3 NA C--O 1060338 Tso a377 7 Z<oo1o0 NA Z<o0o0m0a3 NA stew [ox Tow NA = Not Anaivzed ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Pagedof 000008 Notes: 1. "<" is defined as not detected at or above the reported level. 2. Sample results have not been corrected for blank results or matrix spike recoveries. 3. Please note the following descriptions of the OVS sample tube fractions: Fraction [Fraction Description 8 15t set beads extract c [2nd set beads extract (not analyzed) ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Pagesof8 000009 Summary of PFOA in Solids [SBaumlpk-lAe>wold Bulk-B vile Fab-A Mem-A Wipe-A Athan Wipe-B #1 baw. Fab-B TS6P1FOA (ng/g) (as received) 170 314 89 2560 834 155 ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page bor 8 0000: 10 QC Data (OVS Tubes) Lcs aAndcoanntarollyzsead.mplTehewaasccseppitkaebdlewirtahngPeFfOorAcotnotgriovleraecfoivnaelrycoinsc7e5n-tr1a2t5i%o.n of S00 ppb. The fractions were separated Sample 1Gentiication raPwF-pOpAb) CCoonnttrrooll 11BA 69294 (% PreFcoOvAery) Blanks Sample Igentication Vol. Of Ai (1) rPawF-OpAb PFOA (ug/raction) 11449911A5 1T4a <<00.1100 OC Data (Bulk Material Matrix Spike Recovery `mSaatmrpilxesBpiuklekr-eAcowvaesryspiisk7e0d-w1i3t0h%P. FCOoAnceanntdraantiaolnyszerdeptroedseetntertmhienaempoeurnctenotfrmeactoveerriya.l The acceptable range in the sample extract. for Sample IGentication "Amount Spiked [Amount Found in SaPmpFlOe|A Amount Recovered | Recovery BukA [so ng/ml) 1 ng/mL) ser T (ng/mLs ) ] %) Laboratory Duplicate: Samples Bulk-A was analyzed in duplicate. 30% for solid samples. The maximum relative percent difference between duplicates is Sample 1Gentiication Samplo Results "Sample DuplicaPteFOA ng/g gi %) Buk A[sei[s | eoe ss | ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH PageTof8 000011 Signatures CN4% Uo iAdN Paul Gonnoly, LOWS Team Loader in M. Fa7he.rty,Vice2 Presidant OtLahbMeemberrs ContribufotDiantga KaJarmeensRyMisllhear Meloy EQ DSatse ALL DATA CONTAINEDIN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page of 000012 E n8 3058 Research Drive Phone: 814-272-1039 State College, PA 16801 Fax: 814-231-1560 RESEARCH BTR "LPorgojienct SCcobmmpiatneyd NBaym:e: SLotgairnesType: DDauteeDSattaer:t: RReecceeiivveedd DBya:te: SLporbeead Sample: LPEroxoyajgneectnNoTtSieDlsIe:PIT,ype: Conform Notes: TEE F2o204040718 EE LoginGro 000u 213p B s EEE "ConCofnoforrmm CCOOCC Sample TTrruee WCiSlRi,amInMgizel CCoonnffoorrmm RSeaqmupelset:: TTrruuee TImmediate Receipt of Samples 0043//0263//22000044 0A3M/M19E/R2M00A4N, MARK AnRaIlSyHsAi,sKoAfRPEFNOA in Solids and OVS Tubes/ ROUTINE package exczrer CComosimneer# cose cuz coir corm corsa common Ccoxomssos CCooorns ScCooarmooiisoo CCoommienrs CCCoootsme CCcooommiirnn Ccoomimn caren Package 2Go5s0s9Weght 383s 175 39g 09s sss 103g aaps 063345 o5533s45 2254 32p4 235p o62p4 e63p4 Packages / Containers at ate Conston Shope s2C3a2n00i0n 9Un5c0o5mp0r0amsed Z1SXwASeNs0ORRAT1S pH 5C0o0nmaiGnioearrTPiapsei 500mFNlaooy Past 550000mmNuGaoayrPrlaastt 500meNGaahosrrast 550000m1MGGararonerlsst ANrtai ren eAArittneee ARAiiimnneee ennrieene AAAiiinnneee eAsreo AMerinnee Prasoernaetie none None rove Nore None none NNoorvee NNoonnee NNNooonnneee NNNooonnweee NNNooornneee NNoonnee NNoowvee Temp Convoltemp. et3ka wg. Lot DisclonsMandedsy EreR cenepn a wan 000013 aLzo3gzo0n0t Cm ReportVersionP:agMear1101142004 4:16PM Instance: Roos2128 THETA aPE o7or aT , RRA CoCCmporanoyeNome: eCISSaR,eeceofpSamptles DfPuorgleere t' Suummm SRBoevcaeormenaSdeabr:t aAMrMaEtRAeN, MARK Br-ooonTSiemTeypee: AArnaalisAofTPEFSOA in Sls and OVSTubes ROUTINE rSagemeSos TY CCCoooStnotoemRGeoag,v.es,moi TTTuoeee fipragset can aos ErSveLasn Packages sSEoInscrs orees TsE / Containers MmiAsNrmME GGiroeos mGaaove 3 GmLweiewdtm Gomme ro Sm=oCeeiets wet o oCmoemmaaa = peeed ohheeord o SI SmEm ma ai poa p= bvree =wwoooe eECrroolmmaI or Lpproievat fi ooooeeee Gem ue oe tJ ceecenct o woo dJn, A--. Co 000014 w--_ eparss TTT Sampled 100021330001 Lo002133-0002 100021330003 L0002133.0004 100021330005 L0002133.0006 L0002133-0007 Lo002133.0008 100021330009 Lo002133.0010 100021330011 Looo21a30012 100021330013 00021330018 100021330015 Lo002133.0016 L0002133.0017 Loooz133.0018 100021330019 100021330020 Comainer conz9308 oozes co0z9400 coozs401 conz9ioz conzeu0s conzsios conzeios co0z9405 conzsior conzeus covzaon conzesto coozeat conzesrz conzenns oozes co0z94ts conzents conzen7 312312004 Loginpt Samples Mavk Fracien Sample SOUD Sos Buka souD Soies Bue SOUD sods Fava SoUD seis Mema SOUD sous Woe SOUD Soids Weed SOUD Seis Fad GAS OVSTubes 1489A Gas OvsTubes 14898 GAS OVSTubes 140A GAS OvSTubes 1408 GAS ovsTwes mA GAS OvSTubes 14928 GAS OVSTubes 143A cas ovsTwes esB GAS OVSTubes 1e9tA GAS OVSTubes 1448 aS OvSTubes 195A GAS OVSTubes 14958 GAS OvSTubes 14%6A Report VersionP:aMgaer3o1f142004 4:16PM atoSamDpatelRoceovded Date D outiz0e 03102004 OsB ouvz00s ouoz00s 04620 ouri00t 03192004 040620 ounz00n oio00s 0aE20 our22004 ou192008 040620 outaz0s 03102008 OMB out2200 Ou192008 OADSIZ ouroz00 ou0BX outezo0s oursz outozo0s ouosiz ou102004 04108200 outezo0s ouos209 03192004 04108200 3192004 04108200 ou1o200 ou08200 owto2004 o40e200 oute2004 ouos00 outez004 ouosz00: owtezo0s ososz0n ou0ez00004015osi08z200 Instance: WRE009R 2139E ras cosas r-- costs r-- con carson cosa r-- coma oczsons coz uwozrssaoz fe-- r-- coors [r-- [-- wezrssaon cosar wnoarssaon coisas warssonsz e-- wears corn -- cron [r---- -- wnarssouss coms r-- cuss wnorssanss cos [r-- -- [a -- Gs owns wa ws overaes wre ws overs os [a -- ws ove wea ws ove ums ws ovsmm won Gs ove won ws ome worn ws overs mrs Gs ovis za ws omen zn Gs oversea ws owes wan ws ovis usta ws ovens nama Gs ovemow comin ws ovsTien cots wanes RostVern:Mar 112008 41650 Segiagie Pagesold ovreaos oso ovremos oso cures oars [-- ovens oan ovis oss cures oun ovens owes ovreane oun ovreaos ou ovens ues ovis ounemo ovens son [-- [E-- ovneanos auosaon ovnsaom oun ovneane uous ours ousron 000016 ---- IEEE JiN > S3t0a5t8e RCeoslelaegrec,h PDAriv1e6801 PhoFnaex:: 881144.-223712.-11508309 SAMPLE CONDITION UPON RECEIPT FORM : Protocol #_ Exygen Study # Date & Time Received Condition of Samples A, x 0p fin Low te2e pe dseactra Temporary Storage Location _Drefly Initials & Date es [rg ley . Waybill # [2 27K 16903 Yoi9 FUT Kett ring A rhddy pun bo fh +5 ly . Smo ws Geom 000017 EeChAeEaEmSE 1 i 3 BA i}4;] SHIAE Po TO:a --a e, --on - a STATE COLLEGE PA 16801 0Ne w9.es) PR 168 0-10 Pl RDAO 6H CP Bl UePvSeGnRn:OU12N7Dex 80 03 3s amis _ Ny bo; : } scons. \ YU oer |E Aakt ; -- i | Er eer 1 coms in . i: 5 errr 000018 TI ven nari way . Analytical Request Form Facpoeticssri pn FEE ACCOUNTS iii | AEE LAB USEONLY FRITH C`oSerndRpeupoartnTeo C.OR Ae aogoss: B A9mo 0oSnov x Xi % as boveI - Nomen Amie PShoonnde:vi(6c17T2o) 633 ALi Fax: ($17) b5Y 71% bCuompnanyName: SAX TTT | oROLuE ereame | SH ST INTERNAL ACCJOsUNTS clanNama: A ------ Fe SreotAddess: -- | Binlgo CostCone: seen AiCodes ani 4 [J Taxable [JNonTaxable (Texas ClientsOnly) Toprona oi) Fano) LT] VL SALE UEDA | SAPALRVEOL | [vasa|evsam33n00]| AWALYSRREFGUEoSTaED (ov mais peri al lwael [aun Peon i wat| grea > T 30 Fen _ s| Lo|wa [a Peon b | vas You | PFoa ----- Eo RoFa. Vag ga Pees w 230 fron " ofa -- n Pron v a [TS ~ | ASo| n 30 Pron "5 | Way \ank -- Comrts TT GRA OF GustobYTTI Quaject Qed: Duc A Oe -------------------------- pTra_y)Tfine (3 agin 3 0(m3 U)rrgetntpveetom) (3 Saemeooy ------------ 1 iy,//dCaeri y oa u1n tli [NEA RECr -- Glfeladinant, eroc-aene BE 9 amiga ZSs IR 4p MIF 5. || 1 HHH H H i 5..n 0.: |. Ee gH E TITn TIESls 1(2s0i0a20i1iye8 Q2: H Hv IOT OM HEES f3 agdidsf Qxog; s Ladd | 3d IESy: BE: 5 < : 3 [9 5 19F44344949| PEERRME 53 <Zz::i 2 fi :2 i|] HSE ER aNE ilE:FE | : 3 Oils: i GEilsdd 812 J wO OriallWEed|t5 3iBf| e E3 EH R I0RN | : sc ME glesg| =[TITTTT] z sil RI < i 3 bd 55 Df 9| a3 ld = :i |] 2h] Hi 90408] ZF = : BHzZ008T 34 23 Zdlaa0d4934d348d | |=< zB Wd HS 33 H = Sequence: C: \WRCHENA1\SEQUENCEA033004F.5 sequence Table: Method and Injection info Fart: Line Location Sampletlame Method inj SampleType Injolume Datafile PSLVouivalilel:: S SsummEoIe TPCoivovinaadsviSSSIIinNNRaEE. 05 vVViaiRl 3SlReotvIelrcoTioek BBivooiunn BEEnmsse o ifvuvi inEosaa LBoovwueah BEEmiNm 8 ovvviiinfa HCoROoANTER i2voag vins ova mamnmsn ms of5e ivviiinlga mmEnadnse B32 OvoivDee2n BmEREEC Oo3 VvviSggESm DE Sew B3 ooovvveee yRmEonnm 3i% vMheiIlEy i vid Bs 1 EENmE mn G8GE OVoEvLPin%e SmEhNeaeCB.ow iGovvvieinddg ommmaEa 9$3 VhoviaP% Bova S SEhehe e .Bh SAE 8 o Hoi h n mMMaRaemm FoRnE RmImNm omfwoesenmii1 cgsaammpsle mRmwmMeeRnn looaaalnnl rRFoaommtsteaR 1i1 cSSehmhive FTTooorsssiinnn 111 ssseeemmmiiess TFToooarmssaiinnn 1|1 ssSeeamreielee fTSooorrseeitnn 111 ssseaemmmemiiese ffRaoMcnS Torgin 111 1 sgfemereileee Semis fFFooosaicsrn 111 ssseearrriieeee STTooomaasosinin |11 eSseammmeeelliees RfTooormgssiiinn 111 sssaeemmmeiisse fffoaomseaohmn 1|1 ssseeeeimlss TfTooormsssiiinnn 111 SSseeemmmeeillsee FTToodosoirr s1| osenammemeiiee TTTooormsssiionnn mim 1|1 SSseeemmmeeillsee sm TTToososiinm1|inSseemmeeelee fmSoomimtsmiimn Toms |111 Ggfsaerlmenlmees lRlEmmMEssR )Lloigoiidnd ffRmmmmolbooa oonn 000021 LeuS3 3/30/04 4:50:40 6 miter fp Pi tage 1 ot 2 Sequence: C:\HECHEN\1\SEQUENCENG32004F.5 Catibration part: Line Location Samplename Method _ Callev Update RF Update RT Interval P52 ovoVivieilrsls: SSSTmOOiF0%Tpme bPPoUOMmMSeSRn 231 RRReeebpplilesaccceee vvAveeerrrsagegese 2 TS OvVViiSlsEsi SSS0MU3IS00PTbDRb SOV 7 SD Ioo0he mtoomsmensn 5i3 RRReeebbiilsscccese AvAvveeerrssnseee bomasR 3 heblece verse 5oS5vIiVvisAal:SSSSI0D01I0T'he Si vidi SIDI ER RrBooommsmauann 5Z1 MMheeeorrtaagsseee AAmveeerresisree ROMS i herase Mersse 55$65 vVoviiiaadlse7 SSSTOIO SSlOD0TbDmhonse RFROoommMssuAnn 55 AMhvvveeerrraasgsceee AvAvveeerrrsassgeee wes) 3/30/08 4:50:40 ou smisterJOY5 fe 000022 Page 2 of 2 LC/MS SYSTEM AND OPERATING CONDITIONS Client: CSR Inc. EXYGEN STUDY: 10002133 Instrument: Computer: Software: HPLC Equipment: HPLC Column: Column Temp.: MMoobbiillee PPhhaassee ((BA)):: Hewlett-Packard 1100 LC/MSD (LCMS 3) API-ES Interface - Negative SIM mode Nitrogen: 10 L/min at 300C Fragmentor: Variable; Vcap: 3500V Hewlett-Packard Kayak workstation Microsoft Windows NT 4.0 Agilent Chemstation Version A.08.03 HP G1379A Solvent Degasser HP G1311A Quaternary Pump HP G1313A Autosampler HP G1316A Column Thermostat HP G1946A MSD Thermo-Hypersil Keystone Betasil C18, 30 x 2.1 mm x 3um 30C H2PmLMCAgmrmadoeniMeutmhaancoeltate in OmniSolv Water Time %A %8 0.0 90 10 59..00 1100 9900 9.0 STOP STOP TPootsatlTriumnet=im5em=in1.4 min. Flow Rate: 0.3 mL/min Injected Volume: 5 pL 000023 Ions monitored: Analyte TH-PFOS (1.5.) PFOA (POAA) Surrogate lon (m/z) a7 369 513 Extraction Date: March 30, 2004 Analyst: James R. ier A471 Yt 3E0x5y8geRnesReeasrecahr Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580 000024 Method C:\HPCHEN\1\WETHODS\03300447 Calibration Table Calin. Daca Moditied Wednesday, March 31, 2004 9:04:59 a caBtasceudtaocne I pIenatkeranraelsstandard RRRoeeoll.. NRRoeenffeerrreeefnn.cceeWiWWniidnnoddwooww i|| 505...000000000 m+in RUPoanurc.taiiaiNlbornaCrtaeleditbrpaeWtaiiknosdnow | | nY0eo.st0,00reimpeionnrttietdied peaks are recalibrated Correct ALL Ret. Times. No. only for idencifica peaks SRceeulirggvinene Type | EQTqunuaiadulrdaetd(i"scomse(osnpoeemaekpsepaekdasiktsfdeidrfi,ffefren,re,esebsseeleobwbe)eilooww) AARvveeecrraaaiggbeeraRRteeistopenonntsiseoenciTnignse:!oi AFvleoraatgiengalAlvercaagleibNreawtio5n0s CalibPrraitnitCooaunltibRreoafptoirrotencoaTplatibibiorenastiaofntserwRietchailnibarasteiqounence: I tNRhoeersmusaleqltuseRnoecfpeo.rftiirssatdfotneceyrclRweeiccah(leb(nrbdaircnakgteivpoirnnegv:ious bracket) IDeSfv TaultIe TsDampAlmeounItSTO NIanmfeormation (if not set in sample table) 37 S00 a0000 TaRros SSSiiigggnnnaaalll 213.1: WWWeSDnDLtL 453162357,,, BBHIilCCe.ew34s62z86..7771:34s62t9s7.777 RenciTailne"si"Wl Aoom3u]t Area Amt/Ares Ref Grp ame 20273010135 53500000011000000000000000 332.06967735537038000558 111...77v36a6m80t44e430d0 11 apres i&5 33300000011000000000000000 732!.365626o30r27a67e00s 3111.s56547a03s00a003e33 7.381 2 317 5510000l1000000000000000 723.9354c54e50s77i05e01s0 211 .3s0557aa7s00c05ee30s3 1 pron 5i5 25150000011000000000000000 215.3258527c75a50e0es8s 1115.e53571007300033300 7.47 3 &71 1070570"00010001000000000000 14375653015122704a50s259 533 22d10is6ada6e3ees3 1 summooaTs 435215000011000000000000000 84108.65923665752666e07s430 111...136273633031103833300 &7107305000010100000000000000 336 .oa76s13s3700as0ee0ss 111 3s340365e3300s003e33 2000414 3/31/04 9:05:54 A Jmilier JA Vifey 000025 Page 1 of 3 Method C:\HECHEM\1\NETHODS\0330047 1 Nore compound-specific settings CoC"mTpuiornuvenedW;TiynpdTeoHw-proS pPcront5.653 min To 8.073 min CSeaitLgfevibenrlaci3on Lever weightsj!:et LLLeeevvveeelll 132 ha3: LLLeeevvveeelll 7 0i: CoTmpiomuendW:indporron + Prom 5.652 min To 8.100 min ComTpoonuenai:ndsomrRoGATS From 7.227 min To 8.570 min Fear sum Tani "eo Bntrics in tablerss rn | oe1] os _-- oi o$l? Calibration carves 4 || CmTsoeDrr1reol4na2t7i,aoinB:iecpe.a26#.17:473377.+3700000 P ~ RFoerrmiialvaa:l7vSt"ad. meD0e0v.0: 0 o.d0a0s - -7 [ | Cali7 braJxi:tioAAnrmaeoauLnett vRealtRiaoWteiioghts: evel: 1 a4s) aa 7] adLeevvesle:3:i1a3 miaess iiia Farape 77]| wBrooon Saets;expB.iclwirea27:m69. [o125es i47 coFRroerrrmieiallvaaat:lioysnt:aa. mDevs. bx +o06l.o3i5a8n5s8 pt 5" a 5 adsnlez | ht " , F b: 1.11680 | c:i Amoun-t1.m6a1t4i26oe-2 | || a= osmt ire y: Area Ratio : ; 7 200414 3/31/04 9:05:54 Au miter AT Vifer 000026 Page 2 of 3 Method C:\HPCHEM\1\METHODS\033004F eaprat oz 01s osp 01 rd oud y~~i _-%7]| mSsUoR1ROG51A3T,E aEtrceexspi.z.zRiT:sia7i.n747 % | cReosrirdeulaaltioStnd. Dev.: 05..9090925867 Formulaai:" y = aHxl:si+abcxse+2 b: 175954081 ex:: Amount4.3R1a6t0i6oe-4 | y: Area Ratio Ie . 7 I 200414 3/31/04 9:05:54 AM jmiller FET Vif 000027 Page 3 of 3 SSaammppllee NIanmfeo:iSwTaDrm1u0p.ppb 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13030415\A199168\FC000001.D AIcnqjeOcpteironatoDrate1: j3/m3i0l/l0e4r Instrument + bcooars 5:09:40 BM vSieaqlLNion.e : Inj. No. 17 1 Dilution 1 mil vel. su AAcnqa,lysMiesthoMdethod :: Last Changed: Cp:o\aHaPsCuHRE.uM\1\METHODS\0320047.4 3/31/04 09:05:00 am ni - RunFCcouoelTFoTOGTR: SDT 27 ECS THE CRENSTORTTSaTSRT TOT RPTES. Neg.SW Frag Var | aso00 7.496. THOS, } 2205000000 :iH 150000000 !i 5000 Tr JiN SO59,T ECE38873697 (CHESTOR0S0FSIA ToRE8 T FCO0000T0] APVig,ESWS5 F.is Var :- "600 7217-pron,h 11240000 ii | 1000 ow 2 I~ 600] VA o a0 le Er ee zmeme med I 7 7 3 3 Pe eo 7698. suRRoGATE 500 i 85 | 00d Bfi ~ ee ar Sh i A ome Ne ` 2 o Compoe und ane re& n mount Weas Ret. 8 T Signal Desc 5 ng pTrHonPFOS SURROGATE 4387190358..7305 sess 52 520000.100 77.719 37 less NSSDDLL 346297,, EEIICC--346286..771:346397..77 MEDI 513, EIC-s12.71513.7 "75nd of Report av Peoosrs Wed, 31. Mar. 2004 08:31:55 am Page 1 of 1 000028 SSaammpleeKfaomree STD 10 ppb : Data File iC: \PCHCEhemNto\r\13I0305\25\DA201A216\TFE0A0000\2.5 PTIrrag iconmery | tYFoybuTiPR Fite iE pl nneeFP mov ii3 si TAacrant,iyeeMgehetnhmoHedesthod +|| SCpoomOeaNsBruCmR.EnAI\HETHODSAa 0330047 so ERTART ETO SSR SFT APES i FTi oa. Tweros, 3zp0oro0om00 i7: mreo | poodpteee JA I. TR ECR TRE RESTOR OES COT APES ie Sh Fr Th, ooo I" ii 600- i / -- 400 a wo ; EES TATE ESORO AEE RAPESi. SFToiss. summooae E ol i and vod 2504 SY wo] en - RE eran her Co TFraonnoeoeanrs hme eBiesre eaw ea RT Sm pee 8 aie Ia soes aTralme vi weonnd r 533537,, r BEioRuaenEe 7E47N7 pps reas Wed, 31. ar. 2004 03:33:15 am Page net 2 000029 Ssaammmpilee NTaEmse 50 50 pob : Data file .C:\HPGHEN\1\DKTA\Chemscor\13030612\A203200\FC000003 rtTaieeesetiponnepatae t|Ieesire ese mn fTserqheiieeinn 3:3 toes if ve sa AsToneydt,iyuCWihoaernhnoWedesth>o?a ||. SCs\ARToPrCenRnEsN\2 \WETHODS 0E3300H47 1 zwooon 5TT EC TET RESTOR ERTS opoom pro 5000- APNEe SSWroFToes i ii; i NTETR soo ENSTORTOS RIOT APES Ne SWFJaan ron? 2oh50n0y. !: hes i ee w DST ESTE HEN TOR A8RSE opo-s APES Ne SF"0v-ar sunsooate w-hoog om Compound awe frTrobnros--- g =r a Sseiessiais r7 T SnPree TTEm T 7p Vfwenntii3i5ar3,, eBwreemmaennaa in] Tr scocars Wed, 35. war. 2008 09:34:31 am page 2 06 2 000030 sSaammppllee NIanfmoe::STD 100 ppb 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13030748\A205440\FC0000.0D4 AIcnqjecOtpeiroantoDrate Instrument : j3m/i3l0l/e0r4 C0014 Sisei2s mM vSieaql LNion.e Inj. No. 3p1y Dilution I Im vel. | su AAcnqa,lysMiesthoMdethod |: Last Changed pC3/o:3A\1AH/SP0UC4RH.EmM\1\METHODS\00353:0005:40F0 am | =00 [SOT ERE TAT CRESTOR SOA AROSHOFCO0000H By APES. ig, SW: Frag Var 7287. eros | 25=000 !i | rs | ro 3] f 5000 J JN| NSD $53 E1355 7353 T (7 CHEOSRT030746E0547F0CREG004 B7APWePSEW.SF.ag Var 5 sod 7254- ROA 500 | -"ono | a0 | DEERST-- E T STORSTARORA 7CORO J i, OES vaNrrS: --F----------i or p || oo J 7731. SURROGATE, ||e| |Iol | dee Compound Tans z rea TbHr_opnrOS SURROGATE s360317732.16176 10383 05 i Cd rene BN AmIount eas. RET7 STgral Deas. i i 5s20.02.300 Tosas 77l.32e047 7731 SwSDDI1 SDI 346297., 513, EEllCCaea6z8e.77:143367..77 ElCus1z.71513.7 i Ena oF Report wv - rco0ars Wed, 31. Mar. 2004 09:35:33 am Page 1 of 1 000031 SSaammppllee NInafmoe:STD 250 ppb 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13030810\A207360\FC000005.D AIcnqjeOctpieonraDtatoer:: 3j/m3i0l/l0e4r Instrument peoosts 6:11:58 BM vSieaql LiNon.e Inj. No. 1 5a 1 Dilution i my. vel. sa AAcnqa.lysMiesthoMdethod Last Changed : CP:o\RHRPCSHUE1RM\1\METHODS\033004F.H 3/31/04 05:05:00 am a6000 {WOT 2 ECS TET T CHEST ORT OZ 0FCom000B5y PFE. aSW Fag Vr 7295. THeFOS.% s205000000 i| 2105000000 ;: 10000 | soorr ------------ P! N HDT $53. ECS T3697(C7 HENSTOR 30308GA6Z0=C0000 BY APTES igSiFag Vr 5 PS 100] 7302. pr"2 15000 f 1120500000- 1 57050000 i{ 2500o]d EE ES IHLWS t RSD 5T5 ECHETE TTS C7HEMTORTI0308 RZ0707C000B0Y APTS ie Sf Fr Vr T po 00 i 7729: summocaTe | =2500 2000 i od | 500 i L Compound Wam ne = PHF_OpAros SURROGATE 123029615450993601.637542 " ! . ount 2s0405.0s0 2570 Meas.eReet. eT "~~. A Signal bese 77..320908 NSSDDLI 436297., EEIiCc.e3sz6e8..77::432673.77 7.725 SDI 513, Elc.s13.71513.7 +2 End of Report av Pco0s1s Wed, 31. Mar. 2004 03:36:39 am Page 1 of 3 000032 = Ssaammppllee NIanfmoe::STD 500 ppb 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13030945\A203408\FC000006.D AIcngjeOctpieonraDtatoer:: j3m/i3l0/l0e4r 6:27:35 PM vsieaql LNion.e s DIinlsuttriuomnent +iaPC00414 Imnjj.. Nvoe.l. Ea 1 AAcnqa.lysMiesthoMdethod :: PCO:A\AHSPUCRH.EMM\1\METHODS\033004F.} Last Changed : 3/31/04 09:05:00 am [SDT427EiCTazz7C6HESTORTS038 STAZO008FCO00008 0] APES: NegSW.Frag Var 35000. 7279. THPFOS, 30000. } 25000 20000 i! | reco 10000 | 5000 rr mbi be WED369, EIG-368.7963 7 (3CHENSTORTTS0: : C0008 6) APVES. Nig, SI:.Fag: Var 5 35000 7299. pron 30000. 25000 ' 20000 . 15000 10000 S000 i 0d Rs ele pyre SDT 513, EC T2T5137 3(CHEMSTORT3030348: 1 00005 0) APESeg,. SW. Frag Var 5 mi 3 5000 7.730 SURROGATE, 4000. 3000 2w0o00] etme -- Compound Name 3 -- Area rset Aro1unt Weas. Ret. T t i ptr :Sop Signal bese. 5 TpHr-oPnFOS SURROGATE 22770309833118441 1181.93 a50s0.s00 77..228769 514.35 7.730 MMSSDD1I 436297,, EBIICC.e346286..77::346297..77 MSDI 513; BICa512.7:513.7 +++ Bnd of Report +++ Pcooars Wed, 31. Mar. 2004 09:37:51 am Page 1 of 1 00033 SSaammppllee NIanfmoe::STD 750 ppb 2 Data file :C:\HCHEM\1\DATA\Chemstor\13031032\A92266\FC000007.D AIcnqjeoctpieonraDtatoer:: Instrument j3/m3i0l/l0e4r PCo0a1s Giaaiio mw vSieaql LNion.e Inj. No. : s7 1 Dilution jt 3. vel. su AALcnaqsa.tlysCMihesatnhgoMededthod +| C3P\/o3RH1AP/SC0UH4RE.MM\1\ETHODS\00333:05094:75.7Mpn SOT EIGER TET CREN0SST03OTHR TOT APES Reg SWF7r.276V.aTr PFOS 20000 25000 : i 20000 15000 : : 1o000 500 i; re ed OTS EET 6A0T 7HENSTORTSOTOSEROZBGFI CO0000T 01 APIES eg,SMi. Fag:Vo i 7283-pron "0000000 i i 20000 i" 10000 i oko e SOT ETE ICSESTS TH7 ES TOR SUSGSO 288+1CO0000T 01 APES. eg, SM. Fg: Vor := 7000. 7710 SURROGATE, 0 s000 ! 0 2000 i| 2000 000tre re | mid 3 Se Compo-- und Wane = Fo1unt Wess. REL. Ti Signal Desc. : SpubrRroRanoeGyATE fe52i44v341i67i52i64i0.30 es0501.070 s0302 77..228736 7.710 4SSDDY1 MSD1 346297., 313, BEBIIIcCC..es3s162286...777:::834162337...777 ppg ---- PCO0AL Wed, 31. Mar. 2004 04:01:22 pm rage 1 of 1 000034 Ssaammppllee NInafmoe::STD 1000 ppb 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13031168\A94208\FC000008.D AIcnqjeocpteiroantoDrate :+ 3j/m3i0l/l0e4r Instrument : poooa1s isan BM vSieaqlLNion.e mj. No. 2 1 Dilution `1 my vel. : sa AAcnqa.lysMiesthoMdethod Last Changed :: : PC3/:O3\A1HR/PS0CU4HRE.MM\1\WETHODS\00333:0509:45F7.Mpn SDT 27 ICSE TET CHES TORT0SHRBRGIORFCO00005 0 APegE,SW.SFra7g2. :8V4aTHPFOS 0000. 25000 n i 20000 15000 ai} 10000 a ; rr-- r ih TOS ECA TI60T (7CHENSTORT0TT6SASHE : Oy RPRES egSW.; FragVor - : aoe 7299. pron, 50000 i 40000 ' 30000 0 20000 ' | 10000 oi " _ ree [m STSESTE Td T C7 ENSORSTSR RGHESSY1CO00008 0) APES NegSW Frag vor 5 soao0000. 7737. SURROGATE, 7e00o0 ; "S000000 ; 32000000 1000ix NO - VR, pm Sr Compound awe = TmoIunt eas Ret. T5 S1 ignal Desc a PHr-opnrOS SURROGATE 2536693906151894 7050730 sS0e00..0503 77..22983 Tosisas 7.737 uSSDDY 432679,, EETICCe-a32668..77::432679..77 uSDY 513, EIC-512.7:513.7 "+2 Ena of Report wr PCO04LE Wed, 31. Mar. 2004 04:02:36 pm rage 1 of 1 400035 SSaammppllee aInmfeo::solvent blank 1 Data file :C:\HPCHEN\1\DATA\Chemstor\13031375\A96192\FC000003.D hIIonnosjterocuptmeieronnattobra|te:|| 33mC/i03l00l/ae0lr4s TI VSInejqi: LmNio.ne: 515 Dilution i In: vel. sul ALAcanqsa.tiysMCihesantMgheetdohodd:|| 3GP/;O3\M1HA/PS0CU4HRE.NM\I\METHODS\030331050541F5.71pm ST 27ECR TTTRESTORSATE RGR AFCoo0003 BY APESNeg SWEFra726V7a.r ros a2s0000000 Bji 2205000000 i| T105000000 1} oo 5000- IY J ! Ee EIGER 7T6(C7RE9 NSTOR AGS TAF7C000 BY APESNegSW3 Fgvar Nu-- i= soo , |= [|I aw 723. proA ! . 300 ~~' !|lowed : Sl errs mre rere TTEEE TAT E7 STOS HOROB7CONGO APES. - Si: Far :r | =sso pod Latso | as 2B 00 rAAme - 7743. SURROGATE SLE !Lil one JI a Wonk auld a Corp--o---u2 nd Name een 4 Fount s Wess Ret T f Sigal ewe om TSbiorRorRnooasate s2265s54l.3078831 aHSete0e.00 J72.a328a57 VSMEpoDiD 343126375,,. BBEiiiccce--asaz1s3s.7..i774ii23e73s.777 Phir ---- Poovaze Wed. 31. Mar. 2004 04:03:43 pm Page 1 of 1 000036 Ssaamrpilse NIanmfeos!urrogate 2 Data file :C:\PCHEN\1\DATA\Chemstor\13031405\A217409\FC000010.D ATIennndjeeorcutpmieoernnattobrate 1+| Bm3e/i3ol0ojseeirss iiss Em WISenqhj LeNion,e pir3i Diturion i move sul LRhonagan,ieyeMcihesantgmheedtohodd:1| C5p:/o3\a1RS/PT0CR8H.EMM\I\WETHODS0\301303500004Fam SET EC TT CRESSISRTSAOTRRFORTS 57 APESFSFTaaosV.oTRS Sss000000 222000000 ; Tsooom 01 JA ee STRECR 89T Z RTORETSONSAASTTAZ wo RT 0 APES. i Si: FoTans ron : = hou wo i 0 Hoo, wpos i- | ree ee ---- - FEST EEE STOR RTI CRROTO YATES, Sh F 7755- sumv sooATE " Pp soo 0 | oo | eis i. Compe Taw FSroompmnrooaasts : wes SSee77rs79is.30 : ee we: t Wen Wet. : Sigal bec. : p P sI o0i00CH T 7a NwNeaobpb 34S13e37a,,. mBErireccessaiszsse..vr7i:1s34ts2a07s77 RE reer 000037 Roo ht, $i. Mar. G00 0407:05 9% sage + of 2 paca File Co\RRCCHheEmoN130\315I37 \AE1B533R0\RTC00R003\3 ane ann Hh 3 i A rca, ve esnnoaen || SSsioAemmensei pson woo reoe TREO= - p25eoo0dn0n0 | sooo. I ; won EE ATa ors: iii ; i {il Fi oon} | wo30000 onol wdETE3 woorr aor i" _ : TEEN EAn --NSr wE---- LP | c1o0e 00m. e ; e i aw fr ee ; oHeY Ta 000038 fciansst name:i2153-39 . sata ile 1C/\RPCHBA 1\DRTA\Chanson 13031752 2214401000012.D imI TcmiR se neeM3e e0nM hee ssfmerhnkee su53l: aAE ca.eesE choaedcnoa +|SpEch oAms a mHoDs0H330t087. _ ET RESTOR RGF ESS A-- Soorll ; wbdo 5000~ - E 7 E 7 : som C' h= e -- | Toomn || 150003 -je _ iH" I oo Ta BES ;ETR7 E PEE Sh7 Fr sco, om= -- wo :: os D on e --a { i --_-- z Compu Ta ress Asos sae Tiga5 meee m SiaTRoRtrootnas sBsaanaani ase L SBoooElE rTen Ehen Ean, mEEemaEsmGvii)nsd TR ree ecoona ole Bho Wore 2004 0520125 om vase 1 ot 1 000039 SSaammpplleeNaInmfeo::12133-36 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13031853\A223360\FC0000.13D AIcnqjeOcpteiroantoDra:te : 3j/m3i0l/l0e4r Inst runent PCooats 5126135 BM Svieaql LNion.e Inj. Ne. : f1e1) Dilution 1 m3. vel su AAcnqa.lysMiesthoMdethod Last Changed :: CP:O\RPACHSEUM1R\1\METHODS\033004F.H 3/31/04 09:05:00 am {wn [STi ECE TT CHES TORT BSR CO00TI 0) APESReg SW72F8g8.vaTrHPFOS, 3306000000 ni 252000000 }: 1150000000 \: 500073 EE -- d| N _ [SDT ECR TR 7RES TORSO OS ROR: CO0TS 07 APES eg Shii Frag ver i= ||e 7258. pros, i IE IE I ! sod An 200) mer DTTESTEE (7ENS TOROSSS AEZOiFCO00T0S) APES. eg :SW Frog Vor 5 sono 7783 SURROGATE 4000 3000 | om | wo eo e------ Compound Tame 1 rea PHF_OPAFOS SURROGATE 311875203.969 12 3785335 To1uRt sl0i0.s00 395.38 i i! Weds Ret. T . ret Ne Signal bese P 77..228946 7.783 SSDDII 432679., EBIICC-e346286..77::346297..77 SDI 513, BICes12.7:513.7 2 Ena of Report we PC00414 Wed, 31. Mar. 2004 09:11:26 am Page 1 of 1 00040 _ Ssaammppllee INnafmoe::12133-37 : Data file :C:\HPCHEM\I\DATR\Chemstor\13031914\A225344\FC000014 .D AIcnqjeOctpieonraDattoer:: j3/m3i0l/l0e4r Instrument Pcooals Bia2016 BM SvieaqlLiNon.e : Inj. No. + 1f5n1 pilution ii mil vel. su ARenqa,lysMiesthoMdethod Last Changed :: C3P:/O3\R1HR/ES0CU4HR1E.M\1\METHODS0\90:30350:00.40FMam 40000, OTT ECE TE CRESTOR TSRRSFCO000TE APES eg SHH Frog Var a0. HPFOS 2a0600.0 25000 "?| 200] | `1e0000000 i|{ 5000 ed A . SOT ECE TERT (7CENSORTOOARIZ 1 0) APES.Ng, S5W Fis Var i a0 7219. pro,H 0 on ! 0 i00on Cy JAVA wd L STS ECE CE3 NSORSAGES :FEO000BT) RPTES Ne SW3EFrag Var 5 | smo 7731 SURROGATE, re il 00 | 200 ja 1000 V Telenor RN etd! mp Co Compound Wane Area Fount Weas. Ret.T Signral rBese. PTrHoPnFOS SURROGATE 34702151.045763 37187.81 510.02.900 77..227790 ale 231 MNSSDDLL 432679,, EEICCe-432668..77::432679..77 MSD1 513, EIC-512.7:513.7 Ena or Report +n PCO0ALE Wed, 31. Mar. 2004 09:12:34 am Page 1 of 1 000041 SSaammppllee NIanfmoe::12133-6 : Data file :C:\HPCHEM\1\DATA\Chemstor\13031976\A98112\FC000015.D AIcnqjeocpteiroantoDrate Instrument: m3/i3l0l/e0r4 7C00als Slaves mM SVeiq aLi.ne Ins. Ne. i1s1 Dilution my vel. sul AALancsa.tiyaMCiehstahnoMgdeedthod :| PG3/O:3A\1AK/SP0UC8RH.EMM\1\METHODSa\30i3s3s0:05471Fom po WOT 27 EXGRAaETET CHEN TOR AES EASA AFCORGOTDEO APYESNedSHH FraagnsVa"rmerrog, 3S5o0o0o0 iX 2205000000 4! 10500000 ii 000 eA iAy HTSE EXC-G88 753 T (3SHEN TORTATASTEAGR 24ICORGOFDEy APYESNeg: SH.Fa Var 3 : 00 rate. pro, | 200 i | en | oo il TST ECE a"0w0n0 i| sm | | 20 || stoe 01 I Compound Tame STUFHRrpoRRnOoGSATE STE E3 RNST 76082 I COoO0TS APRESS.: Fog Vir 3= 7722. SURROGATE, } ;! z Area 16331323902541554.2738 ---- TmIount sSW070i.00e0 ------_----_--_-- n ----- Weas. RET. TT Signal Desc : 737..02288m83 uNNSSsDDpIL 435261753,., EEEllICCc--.43s26i68z...777:1143126379...777 IEE Report wo [ Wed, 31. Mar. 2004 04:05:45 pm Page 1 of 1 000042 SR irerler nSee:| ShRuEeEL rnin gEaagaern ao RRS EeSFTon ren: || ==== |= ; =: EN Gy-- "MSD 360, EIC=368.7:(C3H6E0) T302 176AT000961FCO00016.0) APES, Neg, SIM,Frag: Var 8 | -====== Toon; Pro 0 Set | - "MST513, sro EIC=5127513.7 (CHEMSTORI13032 176A100006FCO00016.0) API-ES. Ee Neg. SI arei M.FraVga:r imshi 78 | w-ao e Hn i comp I |S SU --N ------ _--_----_-- WA_------ TH_PFOS 323992,78 500.00 7.276 SDI 427, EIC.426.7:427.7 000043 SSaammppllee NIanmfeo:12133-10 1 Data file :C:\HPCHEN\1\DATA\Chemstor\13032237\A230976\FC000017.D AIcnqjecotpieornatoDrate Tngeranent :+ 3m/i3l0l/e0r4 PCo0ats Siis:09 PH vSieaql Limon.e Inj. No. Te1 Dilution I nj. vel. : su AAcnqa,lysMiesthoMdethod Last Changed : CP3:/o\3RH1A/PS0CU4HRE.MM\1\METHODS\00393:00054:F0.0Ham STE ECE TCTTHENSEESET SET O FCRGgaR NT Oy APES Neg, SW7F260v.aTrHPFOS, 20000 25000 }: 2000 15000 10000 | 500 _e--DTS, ECR TR C7HEWSTORSO AESTG: IGI07 APTEFiSS:IFragVp r d 1 2257.proR, || 7s0t0o0m0 j soon | | 40000 aEm T e 2S0o000 i T0000 Lee eJ TTS ERSTE TI ST 7HENSTOR OSES RESTOS 7RCO000TT 01s APYeEi SSHa.FogT : Vr E - | som 7770. SURROGATE. | oo i som am j | ooo | eter oo nd Spr L.CompouE nd Wae ne e em= errRrTounRt EeEasPE Ret. T eSigrnealErBpes heel PHr_opnros SurRoOATE 2577720023134348 Jeers 1s STi0le00 77.2909 isass 7070 wMSEDD1I MSDY 432679,, 513, EEEIIlCCC-e.aa3e2286..777::154312637...777 IER of Report wv Peooars Wed, 31. Mar. 2004 09:13:16 am Page 10f 1 000044 Ssaammppllee NInafmoe::12133-11 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13032323\A102144\FC000018.D AIcnqjeoctpieonraDtatoer:: 3j/m3i0l/l0e4r 5:34:52 BH vSieaqlLiNon.e : 118 DiIlnsuttriuomnent : 1peooars mmj3.. vNeol. : sul1 AAcnqa.lysMiesthoMdethod : CP:O\RHRPCSHUE1RM\1\NETHODS\033004F.4 Lact Changed : 3/31/04 03:59:57 pn SOT 27 ECE TTT (CENSTOR Saaz SA G2 HAFCToo0Te 07 APES., SW.Frag Var "0000. 7217. THPFOS 35000 | 2205000000 {s200s00 . 10000 S00er ------ :-- SDT T65 EC68 73607 (7CHENSTOR USESATOZ 4A1 COOUOTB OY APTES. Neg. SW:E Fag Var 5o 11860000 7289. pronA 11420000 t 10000 0 od eee em ered. NST S73ECSTE TTS (7CHESTORTUSZ32SR 2A1FCOTUOTB0) APES,Neg: SI: Fag Var i p. ra27r. SURROGATE, |Ia"000 | | 1000e-- | | Compound NamerT rea a ounT t Weas. R5 et. T Signal Desc 5 in PHr-oPnFOS SURROGATE 1230435183.91615 39150 64 250.07.300 77..228737 i580 7727 MMSSDDI1 346297,, EEIICC<-432666..77:.432679..77 NSDL 513, BICe512.7:513.7 275na of Report +r PCo0414 Wed, 31. Mar. 2004 04:09:35 pm Page 1 of 1 000045 Ssaammppllee NIanmfeo:12133-12 1 Data ile :C:\HPCHEM\1\DATA\Chemstor\13032360\A104064\FC000013.D RIenqjeoctpieonraDtatoer:: j3/m3i0l/l0e4r 5:50:34 BM vSieaqlLifon.e 2105 DiIlnsuttriuomnent f: apeooats Imnjj.. Nvoo.l : su1 AAcnqa.lysMiesthoMdethod +: PCO:R\AHSPUCRH.EMM\1\WETHODS\033004F.} Lasc Changed + 3/31/04 03:59:57 pn RISD TETECTS TT(CENSORAZROA ROSA CTTaOY APES, Nog. SW. Frag Var po 7270. Teros | a0s0o000o 2205000000 :" 510000000 :: 50005 J iL Sy - 200 SOT 359,E EIGT 73E593T(E6CHE8ES TTORTA 0S260AA T CH75a07 APTEES.Saeg,SSI Fra2g27V7o.r PRON 8 50 1500 i; 1250 1000 hh I i wl A --v ee HOT ECSTET STE (7CHREMSTOR 3032R5DG36CON0OOTASBy APES Nei. SI: Frag Var 5 "oe 000 7737. SURROGATE, 3080000 22050000 11500000 : [I 0s. pra FE -- -- errr ert) Seen L Compound wane reT a Ca TnounT t Weas. Ret.5 T Signal5 Desc mn HPF_OpArOS SURROGATE 1339119493.60398 33598100 s6050.100 77.227m0 38.8 7737 uNSSDD11 432673,, EElICCe<a3z668..77::43267..77 NSD1 513, EICe512.7:513.7 22TEna of Report wiv PC00414 Wed, 31. Mar. 2004 04:12:14 pm Page 1 of 1 000046 Ssaamrmgiee Naaemse STO 250 pp . Data File -C.\HPCHEN\1\D13N03T24A51\\ACZh37e36m\FsCE00o03r0.\ TaS neilar pttoebee Elh: nne ersten peaahneLeiene mo t:: sud h poy, te estmedod S|+ ESiMeo O \WETHODS\0e33r004a7 n OT soo TETEO ERCES PS SWToFmeres owoo toon : pss Pe5000 A : E a TT T OA OES C SF | oJo16e0ro0d0 7.286 PFOA prp~eocds ) -ot I oo ;-- ol rE TTTE: TON ESF1 E ESS: FTro. sommooaTs = oEeS || =-1a00: : i a o n; cE sp U:SEwee ------ Ve REST an T-------- WM------ frrTaon -- nFSntse mBSoreneees gEammare E wEemn i aan E mmeesse aerraan inn? TS Era sate FE. Page 1of 3 000047 Sqiinmgyee nfaaguisoivest Yak s Data file -C.\HPCHEM\1\DKTA\Chemstor\13032488\A106048\FCO00021.D P a Tnectr r ion i ace eamel arno ois me Sea Laihneea 53: iio HH mov sat AREeeiqig.ymMeesthomdachod +| EpoAnBasSunC.RmEN\1\WET023H53O080D14S85\0em so TEC TRE COROT ET ATeE moresR" 3op00no00 opod. odo T S TST zRES TR R 7CHI PVES -- " i-- N eo py450- A 350. 7.340- PFOA N/ 300 EI / os Vv ad 200 Tw 1 A rm a reeset 7 7 a 3= I" 3eb00sd wo. soa: rs > A 1804 om Toiyvos Nr I wr ad sma arspind I 1Fret [ # 1= iTrsova en Tee er Te pwonr1i2, a Eoeane.e ATid Tr -- Poses tole $20 Bate 2000 ssiBL IN Page 1 of 1 00048 SSaammpplleeNaInmfeo:12133-13 3 Data file :C:\HPCHEM\1\DATA\Chemstor\13032573\A108032\FC000022.D AIcnqjeocpteiroantoDrate Instrument : 3j/m3i0l/l0e4r + PCO0AL4 Tow372s BM Svieaql LNio.ne: Inj. No 22 1 Dilution T m3 vel. : sul AAcnqa.lysMiesthoMdethod:: Last Changed + CP3/O:3A\1AH/SP0UC4RH.EMM\1\WETHODS\0033:35090:457.Mpm _-- ROT 27 ECS TET CRESTORSTAIB0T2FCO000220) APVES. Fe,SH.F7r27a6g.VoTrHPFOS, 225000000 25000 i i 250000000 | | r50o0o0 ; HOT S59 ECS TRST 7RESTOR IOTISTSRTOS0S2:FCO00022D) APVog,ESWSF:os Vor iP 1000 7280. pFOR3 oon i 0 wi / wi eee TET EGRET (7CHENSTORISETSORE1 FCO0002Z 0 APES,NegSW: Frag var 3= | 77. suRRoasTE "wn 3000 2000 1000 Compound Hane Hpr-oPnFOS SURROGATE = 35903970.287556 38306.29 i h i ee i Fo1unt Weas. RC.T 7 Signal Bese i : S1070..3030 a1 77..220786 7lnas uSSDDLI 4SD1 432679,, 513, EEEIIICCCe--a35261682...777:::435261793...777 Ena of Report -or PCOOALS Wed, 31. Mar. 2004 04:45:55 pm Page 1 of 1 200049 Sample Name:L2133-14 1 Sample Info: Data file :C:\HPCHEM\1\DATA\Chemstor\13032740\A110016\PC000023.D AIcnqjeOcpteiornatoDrate :i 3j/m3i0l/l0e4r 10:52:50 PM vSieaqlLNion.e 2232 DIinlsturtuimoennt 1+5 PCO0414 nnjj.. vNoo.l. sul1 AAcnqa,lysMiesthMoedthod :i CPO:R\APSCUHRE.MM\1\METHODS\033004F M Last Changed : 3/21/04 03:59:57 pm ano SDT S27 ECR T4277 CRESTOR S032 OAT 00SFCOUO0Z0S) APTESS NWegLFraVagr 7213. THPFOS, 35000 30000 25000 20000 ! 15000 10000 !i S000 rr 3 3 5 CE meTe m HSDT 363, EXC=368 7350.7 (CHEWSTOR SEZ AOA TIOBTO\FCOPO0ZID) APIES, eg, SIN Fra: Var ! 70001 7288. PrOA| 000. 5000 | 4000. 2000 2000 :| | ood1 md -- I ee SOTE573, E EIC=5F T275137FR(ECHOEWTSTEORVTF 3GO0T3oT F2C7O04E 0D02A30T)APLES, Neg.SSoI. F Frag: Varrage 4500. 7754. SURROGATE, 43050000. i 23500000. i: 21050000 ' 1s0000 mas cement tas a = CompS oundANamA e S SArS ea SARrSouUnt Meas. Ret. TSU Signal Desc. NE" TPHF-OPAFOS SURROGATE 73308610.981231 33845.78 5520.05.200 77..228769 367.99 7.764 SMSDDI1 346297,, BBIICC-=346286..77::346297..77 MSD1 513, EIC-512.7:513.7 "++ End of Report +++ PCO0414 Wed, 31. Mar. 2004 04:48:12 pm Page 1 of 1 00050 men sata le -C.\HPCHEN\I\1O30A33T83C8 hRLeLLnI3sE\tRCoORr00\24 Acq Operator : jmiller vial No. 23 J EhRs | A-- hlee semen oHzes00ar TBS TE EERE oe ES STey: ---on ki: pooo3 I AAi eo EE oo os | 1ti4oo0o0.0o. ; | | |[| aoo 0"!! || J2.000 SSe EE r O : g R ; a R eS SIh cngI -- . wo4000 ;i | |- j com an | 0 i beersserra --= Ee RR I ete Eg eg Ee ee 000051 Ssaammppllee NIanfmoe::12133-16 1 Data file :C:\HPCHEW\1\DATA\Chemstor\13032862\A246528\FC000025 .D AIcnqjeOctpieonraDattoer:: m3/i3l0l/e0r4 Instrument : cooais 11023:57 mM vSieaql LiNon.e Inj. No. 2251 Dilution il 3. vel. : su AAcnqa.lysMiesthModethod Last Changed :+ CP:OR\AHSPUCRH.EMM\1\METHODS\0330041F 3/31/04 09:05:00 am ST 7 as000 ; ECS TECENSORTSO BEERS CO000208) APES NegSF72G87VaTrHeFOS: woo 25000 | 205000000 ': 1S0000000 !i Ne i --_-- ISTE,EeCeRs TT OERSTO TCERACIRFECEOTSAESEBDYAAPPEES, Nog SWFragVar 5 PY | moi 72m. pron | 20 i 15000 i 10000 Ii S00 i ot r --------h pee iE-- SOT BESTT STS7CHEMSTOR T0386AEA8S25iFCOOGZS0) APHESNog SI:R Frog var T me: |3 7727. SURROGATE, 0 2000 ; 200 i | oo | oder - rer le CTomEpouEnd E Wanere Se==mperFoSuTntE TPHr_oPnFOS SURROGATE 15205106873.40059 as0s0i.e0s0 34084.31 3178 WedsE.rRaEE. gTh rtd - Speer mnSig gnal DS esc eres 77..226m7 SMSDDI1 436237,, EEIICC--346286..77::346297..77 7.721 MSD1 513, EIC-512.7:513.7 "+2 "Ena of Report wre Pco0a14 Wed, 31. Mar. 2004 03:18:23 am Page 1 of 1 000052 J on . save File. <C:\PCHM\E\O1N36T33A09\21AC11h35a200nCa00c2o6.r Ieie nTeseeT anion R mae 3x mpheosenpli pBeEe LJ: rA Fcoas.ivaHotteheenaedsspes +| sSiEosnmseetm.onstozsfoisneers || s=omo ||| 2a= osm0v0o0 | w=Ss I ARECreo soe ~i= || oo | |P [2E00e 03eeeime we wr wr SRT ST, OE iro SCEAE SS ! # | I i . S AFCO N APES. SiSF HTorreon b v; eers .: P ve he E th mn er,: ;: Pe 1000. |i oe Fffye--e ! _._. SBrEaEne bag WBwemEs jginm mumme E memoersmes re J nt 5, wre so saree page 1 of 1 000053 Ssaammppllee NIanfmoe::12133-18 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13033129\A115904\FC000027.D AIcnqjeOctpieonraDattoer:: 3m/i3l0l/e0r4 Instrument pcooats 10:55:13 PM SvieaqlLNion.e +: mj. Ne. 22671 Dilution ta 3. vel. : 5 ul AAcnqa,lysMiesthMoedthod :: Last Changed: CPO:R\AHSPUCRH.EMM\1\WETHODS\033004F.M 3/31/04 03:59:57 pm SGT 27 ERC TET CRENSOTTSOESRAWTSG0AF0000207) APIS. ig,SW,F72a83.VaHr eFOS a3s0000000 2 i 2205000000 Hih 1150000000 : S000 rere ;o SDT 555 ECE TT(3CRENISSUTITOERTT53047FOO0002T 07 ATES. eg SV, Frag Var i 7280. proA, 12000 10000 hi : ao00 ; 6000. wooo 1' 200r 0 d SOT 573 ECSTESTE (3CRENSTORAOSTESA T50:4FOO0002T 07 APES. ag, S5V. Fra Vr 5 m 2a5c0o0. 7748. SURROGATE,i i" 2050000 2000 | 11500000 0]> i Te . id Compound Wane rea RrIount Weas Ret. T5 Signal Desc mi pHr-oPnrOS SURROGATE 2599791002.92222 3428452 sT0o0o.l0e0 77..228838 3e2le2 7.78 SSDD)1 342679,, BE1ICC--432668..77::346237..77 SDI 513, EICo512.7:513.7 52nd of Report wir Pcooara Wed, 31. Mar. 2004 04:51:56 pm rage 1 of 1 000054 SSaammppllee NIanmfeo::12133-19 2 Data file :C:\HPCHEN\1\DATA\Chemstor\13033217\A117888\FC0000.28D AIcnqjeocpteiroantoDrate Instrument : 3j/m3i1l/l0e4r + PCO0AL4 Tiioisi Am Svieaql LNion.e Inj. No. 2a01 Dilution i ny vel. su AAcnqa.lysMiesthoMdethod Last Changed :: + CP3O:/M\31AH/SP0UC4RH.EMM\1\WETHODS\00333:0509:45F7.Mpn JHST ECE TET CENSORS TAT 7 BRE Ne SW 7F21g7.VTeHFOS, 2a0s000000 | 22000000 :\ 1500000 i} soon E rr TJNo TOTSECE 369T C7RENSTORTOSS TAT : OI RPRES eg,SI:Fro Var Ss PY 10200 7285. pron\| 7-0000 i! : sooo aw] Jno{ N \ I| JOTST ECS TET (7HENSTOROSTITAT T89S:COO 0) APVES: Weg :SHFrog Vor Bn 7754. SURROGATE, 5 Pe won i 30003 t 200 1 1000 Ermr-- I nmrtountdI Suse pros erg CromrpoE undGNaG e r eArgegai Founte Weas. Ret. Tv SpiggnalpiBe ese eel Ps-urRpoRnFOOGSATE 30Se77415.00534 35730.20 sT0r0.e00 Jess 77.227s7 7754 sMEpDlI VEDI 432675,, 313, BBEiCIC-Ce3ea6zs86.i.7z7::3476289173...777 IER or Report +n Pcooara Wed, 31. Mar. 2004 04:52:54 pn Page 1 of 1 000055 SSaammppllee NIanmfeo:12133-20 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13033279\A118872\FC000028.D AIIcnnqgjteorcputemireonnattoDrace 1i + 3m/i3l1l/e0r8 PCO0ALs Lenin sVeiam lihone Ing. No, 2351 Dilution i vel. | sul AALcnaqds.tiyaCMiehstahnogMdeedthod + G3Po/O\3R1HS/PU0CR4H.EMM\1\METHODS\0033310550145F71on NSD as000 427.EIC=426.7427 7 (CHEMSTOR\13033270AT19672FC0000200) APIES.Neg.SMF7r2a6g3.vaTrHprOS, } 3205000000 i 2000 . | 1o5o00o0. !. | soo ee Gn STI ETC TT (HENSTOR SESRTA:S FCO00A 0T BY APES, We= SN Fi Ver 3 a seo Tara. pronh bwwd } osecs hn oo wi 300 No 200 Meee eee een 1c005 OTTESTTEEXCCRETETSTSSCRCEENSSORTORS SSEEA7T TAFFCOO00A 00223B0y)AAPPEES.SaSWSh Fia7g72VV2ar.rSURROGATE.: 3500 : 3000- ' | 22s50o00o00 ooo fo CO ompoR undGanGeeaeemeeBeiHeoercence STowiRo-RpnoraoasTe SB39ii9a20a6s0ss.s08 Fouprnt Mlsoe0en.s00 t NNp ee Wews ERTetS . 1 T Signal Bese.See seat a27.2m063 NVweSsooonni 4$S21e73a, BBBiiiccc---s34ie2zs6.7r7:3e462i87..77 ITE of Report oon Pcoos1a Wed, 31. Mar. 2004 04:53:55 pm Page 1 of 1 000056 sSaammppllee NIanmfeo :L2133-21 2 Daca file :C:\HPCHEM\1\DATA\Chemstor\13033475\A121856\FC000030.D AIcnqjeocpteiroantobrate |: 3m/i3l1l/e0r4 Tngeramenc Poooats iio An SVeialmione Inge Na, 25: Dilution HH vel. | sul LAAcanqsa.tlyscMihesatnhgoMededthod |:| C3o/;m3\A1RS/EU0CR4H.EMM\1\WETHODS\0a3i3l0s0r4sF74pm [SO5 T EC TT CHEN STOR SOTAESSA0 3050000005 2205000000 1105000000 s00p40S ey | MSD 360, EIC=368.7.360.7 (CHEM3S 0334T 75 O 1218R 56F\1 CO0030.0) | 8n0o0 s60o0. "w APiEe SSi F72r81a-yTerOs 3' i: dh, _ API-ES, Neg, SIM, Frag:27Vsar. pron Senet 'HH Ao |e TET ERSTE T "000 em ea et 3ENSTORSTSATEEEA7FCO0007007 AES Vg Si: Fig Var Tm 725. suRRocaTe, ] 2000 2000 |H' | | wl y Compe Nameee ren Foune t Wea. Ret. T Sipgarli eBese Sm oe SFtrmopRnroocsaTE 2Se9d3aa7eo01a.r01 WSBoli0iet00 72.3as6m1 NNNasSD0A31 435261733.,, BEBIilCcc---54313s26..777111354613s37...7)7 IIE of Report oer poooiis Ved, 31. War. 2004 04:54:24 pm Page 1 of 1 000057 Ssaammppllee NIanfmoe::12133-22 3 Data file :C:\HPCHEN\1\DATA\Chemstor\13033536\A123712\FC000031.D AIIcnnqjsetcortupimeoernnattobrate :|| 33m/0i30l10l/4e01r4 Se An SYeaaLoine | Ing Ne. 3313 Dilution i In. Vel. si ATAcanqsa.elysmcihesatnhMgoeedtdhod |1 3Cs/oo3n\1nH/sP0uC8mR.EuM\1\ETHODS\o30l353a010s474.pm SO 27 EXCRETE TTT T CHER TOR 42a5o0n000 | 25s0o0o0 2015000000 soopotSo0 | A T2337CHES 07 APES. eg SH Fg Var Tare. eros 4 n: iA4 ewnigE ETS, C G5EST TOR TS TET PCTOT OT ES, a Sh io72V0o0e-rm m7rons sem 8 w00l3 | ! wi | it wd | : Np wd JN 200d) rr rn - asoTST prperess 222005000000 o5o0o0 1set -- ECT3ESTOS SO SATEST04 : 3 BT APES Fge Sif Frog var T Tw 7152. SURROGATEi ESS In: ~. ea y -- --~ S ComE poundT Nae E =Ea TouE t E Wawa GET T TSiEgmTa eBeeet min SuFRrRoenorcoasTE 9 3390504i103034 3sTea0s.e00 7a7.l2se7s8 wNNsSaoDb11i 43$261733,. BBBiIlccoe--a3ez1sss.77711i43a136s73777 ihe of Report rer poooirs Wed, 31. Mar. 2008 08:55:13 pm 000058 Page 1 of 1 SsaammpplleeNnafmoe:STD 250 ppb x Data file :C:\HPCHEM\1\DATA\Chemstor\13033597\A260352\C000032 .D hIIennqgjteOrcutpnieeonnrtaDtatoer::: j3m/i3l1l/e0r4 P0014 Ta A SvIienjaq.lLdNioon..e 5s3 Dilucion a ml vel. : sul AAcnqa.lysMieothMoedthod Last Changed +| : PC3/O:3A\1AH/SP0UC4RH.EMN\1\METHODS05\:00353:000014am SOT7 ECE ETCHTOE RT SOT COR E APES S agSW F7r7ag2.Ver ros, 250001 : 20000 5 15000 10000 :: 5000 tot ! | soon HESDT585EERCE 7R36T3 (ECHNENSTOORRTIOOS aTATAOTFECOCROGUaRSEO0Y7 APEFS.i,ShSii#57V2V7ae0r. Prog 12w0o0o0] :! s00000 ; aproesn 1 200Ee : aa aa3 pe 2250 TS Ei TET ENSTOR ES GRASFOO TY APeEg SSh Fs77v4a1rSURROGATE 205000 : 11520500 ! || omwesd V| osoml { : Se L Corpound ae ren Founs t Weas. Ret. T Signal esei a TpSirU-oR7nRFOOGsATE 2114164807881730.50.03010 225032022.0ii0 777..42277128 SHWseDDi1 435216733,, BBBIiiCcciis3216628...777:::453216733..777 - IiEna oF Report we peooa1s Wed, 31. Mar. 2004 08:19:07 am 000059 Page 1 of 1 SSaammppllee NIanmfoe:solvent blank 3 Data file :C:\HCHEN\1\DATA\Chemstor\13033659\R125760\FC0000.33D AIcnqjeocpteiroantoDrate |: j3m/i3l1/l0e4r T2853 A SvieaqlLiNnoe 35 TnDsileurtuinoennt i: Pooars mmjl. Nvoe.l. : suI AAcnqa,lysMiesthoMdethod :: CP:O\RHAPSCUHRE.MM\1\METHODS\033004F.} Lasc Changed 3/31/04 03:59:57 pn WOT 127 ECTS T4277 CRESTOR S0365oR Z8TOF 00330)"APFES:NegSW Frag Var 25000 7287. pros 20000 25000 i3 20000 15000 : 10000 i so Ee ey J{ Npr HDT 369 EIGER 89 T 7HENSTORNS03SGSFRTIST00E03O3F D)APVES.NeSWi.Fis Var := 0 2 "wo 3 250 7325. roa. | , 300 \./ J 20 20 me J rem a rs pe OTT, ECT TTS T (7CRESTORe TT 50e R287810COOOUSS Dy APESNeg :SL rere Fisg Var : P a0s A: po0 i1 20 AL 2T0L0 TI i ra mtr Compound Name PHF-OPArOS SURROGATE 2= 42770.85103.50 0.00 a cunt Wess. Ret.T8 Signal Des8 c om 0a0i.00 770.323657 0200 0.000 MwESDDI1 346297,,ElEcICi-a3z6e8..771432673..77 NSDL 313, Elc-a13.71813.7 Ena of Report wv co0ars Wed, 31. Mar. 2004 04:56:06 pn 000060 Page 1 of 1 Ssaammppllee NIanmfeo:12133-23 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13033831\A127672\FC000034.D cIngjeOcpteiroantoarte :: 3j/m3i1l/l0e4r 1iaai2s AM vSieaqlLiNon.e + 333 DiIlnsuttriuomnent +tapoooars mmj3.. Nvoe.l. : Et1 AAcnqa.lysMiesthoMdethod :: CP:O\RHAPSCUHRE.MM\1\METHODS\033004F.M Last Changed 3/31/04 03:59:57 pm "WSO 127, EIC=F25 T4277 (CHENSTORISGa383TATZTSTAFCUO00503] APES.Nog, STW. FragVar 7280. THPFOS, 35000. 30000. ' ! 25000. | 20000 :} | 1000 10000 : 500e 0 ee EEE dN { , SDT369, EICE3(C38HEN8T7OR3I0633803TA7278723 CO000340) APTESNeg.SW&.Frag Var 5 7200. PFOR, fi70t0 |3 S00 i wwdl A A Ne 0d ee NISTSTS ECR TE TST (C3 REMSTORI0TSATIEBO721FCOGO0S 0) APTES Neg Sw5i Frag var 5 P as 7.748. SURROGATE, | 4a0000 3 | 025000 : 2500000. 1 1000. sotr econ etd M.om Compound Name 3 rea Amo1unt Weas. Ret. T 5 Signal Desc m TPHF-OPAFOS SURROGATE 21890951.1635.31 3407596 51040..4050 77..228500 380.08 7.748 MMSSDD1I 432679,, EEIICCe-d32668..77::432675..77 MSD1 513, EIC2512.7:513.7 "++ End of Report rev pCo0a14 Wed, 31. Mar. 2004 04:56:41 pm Page 1 of 1 000061 sSaammppllee NIanmfeo:12133-24 3 Data file :C:\HPCHEM\1\DATA\Chemstor\13033916\A129728\FC000035.D AIIcnnqsjteorcuptmeieronanttoDrate : jP3C/mO3i01lA/lL0eS4r 2100105 WM vSieaql LNio.ne: Inj. No. 3352 1 Dilution iy ml vel. sul Acnqa,lysMiesthoMdethod :: CP:O\AHAPSCUHRE.MM\1\METHODS\033004F 4 Last Changed 3/31/04 03:59:57 pm "000 NOT 27 EC TTT CENSSATEOFR CaRgeSssBy PESWagSWFag Var 7274- THPROS 2a0s0o0000 2205000000 150000000 soorereeee eee lo HOTS EC 8 TST (Z HESOMTOGRS27T 20: CO000R50) APES: WeT , SW ia T Var T. 1000 Tan pron 9a0o0 | |]waHi0w | A 1 or \ m J TT SDT STS ECSTETES (C7RENS TOROS ECATOIS0TA07F 03SOY APTS,Neg SH:Y Favor" i - 7754. SURRCGATE, "000 i 2000 n 0003 1000 i J Sr med A Compound Name Ty= Tr mounT t WT eas. Ree t.T TSignal Bese Tl P FHr-opnrOS SURROOATE 73000663.241838 35915.12 F s0.0I 0 C7E .274 391.97 7758 MSEDDLI 432679,, BB1iCc-e3s6z8e..77::346297..77 MEDI 313, Blc-s12.7:513.7 Freeper ---- pco0a1a Wed, 31. Mar. 2004 04:57:33 pm Page 1 of 1 C0n062 sample Name:12133-25 2 " sample Info: Data file :C:\HPCHEM\1\DATA\Chemstor\13033576\A131712\FC000036.D AIIcnnqsjteorcuptmeieronanttoDrate +:| m33/ai30l1al/le0sr4 SSA iSInedjql. LvNioon..e 53fl Dilution i vel. | su ALAcanqsa.elysMCiehstahnogMdeedthod ||: CP3:/O3\A1HA/SP0UC4RH.EMM\1\ETHODS\0033310505415F71pn TETEi 25000 ETT (CHESTORAUST AT TAFCoO00B3y APES, egSW F2r85.VaTraps,} 3205000000 : | 2s00o00 | socoo0-- Pe SiAL, ara i 88 E38 RT S7HENSTOATRAT7FSORGOES7 APTES. ogSh: FoVr := 80. 776p.r Fon 0 : aon : 00| 300 { ed/ mT . 0 Meee eee ern er remem ett2 et DTS CSTET 7RETO TOS TEATS TAFCTa 7 By APESRg S:hFr ar Tam 00 7728 SURROGATE, 4000 3000 i 2000 1000 hme Compound Fame z ew TSBiormorRnooasaTe 2Fpr3e1iv7i7e0ee.d15 i ed; FoIunt Hews RETi Signal Bw ese: S3f0a%0e0 237.53268%5 wuVSeeDDi1i 43$612537.,, EBEilIccCe--as3z16s28...777111433216733..777 IIE of Report oer rco0ira Wed, 31. Mar. 2004 04:58:10 pm Page 1 of 1 000063 Ssaammppllee NInafmoe.:12133-26 . Data file :C:\HPCHEM\2\DATA\Chemstor\13034172\A133632\FC000037.D AIIcnnqjesOctpteirrouantmoDeratnet:: 3j/m3i1l/l0e4r PC00AL4 SATE Sveiqal LNion.e 3. No. 35 1 Dilution 1 Inj. Vol. : 5 ul AALcnaqas.tlysMCihesatnhgoMededthod + + CP3:/O3M\1AH/SP0UC4RH.EMM\1\METHODS0\30:35390:05471Fpn J TET EERE TTCHENSTORTSA FARTSSSEFCO0003T 0) APES Weg SW F72g50.verTHPFOS | as0ons i 2500 f15o000 10000 :: i 50010 L Noo - SENTSE ERC TTT (3HENS TORTIUSAA AAS TFCOO00s 3T 0) PES, eg SHE Fis Var 7274. pron i a | 2500 ` 200 : 1500 : 1000 had Ne i i ee--t meen OTST "ceo ESTE STE 2 (HENS TORTAESATARTEAFCOO003T0) APES, egSH6 Frog77V3a4r. SURROGATE,] 8 m 32050000 i: 22050000 500 [: . 10s0o0dme _ pr = J -- x CompT ound aT ne rea Fount Weas. Ret. T Signal Desc. i = SUPRroRpnOrGoAsTE 3210107023.90.500 32128 sSo0c0d.s0.0 Sebaz 77.22648 2734 SSDD)Y SDI 432679,. 513, BEEIIICCC---453216628...777:::453216733...777 **+ End of Report *** - pC00414 Wed, 31. Mar. 2004 04:59:17 pm Page 1 of 1 000064 SSaammpplleeNaInmfeo::12133-27 ) Data file :C:\HPCHEN\1\DATA\Chemstor\13034233\R135616\C000038.D RIIennqjesOcttpireounrmaDetatnoetr::: P3m/i03l01l/1e08r4 24700 A vSIinejaq.lLiNvoon..e 338s1 Dilution "a 3 vel sul AALcanqsa.tlysCMhieastnhgoMededt:hod | CP3:/O3R\1AH/SP0UC4RHEN\1\METHODS0\30:35350:0547Fpn "comS o D27 GEE TETCHEN TORSO SFCOUOGaA APESNe, SHF7a26g8.Var FOS, a2s0000000 } i 2250000000 ii 510000000 ; { 000 "HYSE ee EICE7363 (C7 RENSTORVAUSAZEF1CTOOAOT0TR80)TAAPHEeS,Nee SWF703 son] 715. orn TET - , | = fi 000 i s000 ! 2000 | wo | SE el HTSEICHSTTETTR5137A (RER R NSE TOE RATASRTGSaFACOEE O0E0TS80A) APeEyt SSWES F.Var So C= s m wo] 7747. SURROGATE, "000 | 000 | 2000 i S|E Comoepound ane S SEreaS FY ount Hews. Ret. TSU Signal Deie SS " SPUrRoRpnOrGoAsTE 33Ss07s97i30s55i63s15e3 GGs0201.800 777..02206a88 wHWeSepDi1L 435261793,., EFEI1IcCCeoas43126268...777:::343126373...777 - I Ena SE Report nov - rcooaia Wed, 31. Mar. 2004 04:59:43 pm Page 1 of 1 000065 Ssaammppllee NIanmfeo:L2133-26 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13034294\R137408\FC000035.D AIcnqjeOcpteiroantoDrate |:: j3/m3i1l/l0e4r 3102038 AN vSieaql LNion.e 3365 DiTlnguttriuomnent :bE bcooars Imnijl. vNeol.. 5 ulH AAcnqa.lysMiesthoMdethod :: CP:O\RHAESCUHRE.MM\1\WETHODS\0330047.4 Last Changed : 3/31/04 03:53:57 pm SDT 27 ECS TT(CRESTORESR AOS FCO0Ea BY RPE, Nog, SWI Fg Var 3500 2219. THero3 3020500000. i| 205000000 |! 1S0000000 ee iI A, _ SOT 89, EIC3E8 7360 (C7 ENSOR TIO SHR 70H7FCTUD0 BY APES, S ie T : Fi Var 5P 12000 7a8s- pron 10000 : e000 ; a0 | al | om | ods pr ee gpm -- NSTSTS ECSTET(CZ RESTOR IS HAT7A08 :FCHagma08 BY APES. Fi. SW. Fg Var m o5o0o 7752. SURROGATE, 5 23500000 h | 2205000 i| 15100000 i{ || 201 eee mm ritmSeema] Compound ame rea Tmount Weas. i Ret. T Signal Bi ese: ai; rHo_nb,ros SURROGATE 340414637.35.238 35247003 IS0s0.o00 i7.z3e7s5 ies 7.782 MSSDDI 348297,, EEIICC--346386..771:346397..77 MSD1 513, BIC-512.7:513.7 2"50a of Report sev om Hed 3%. Wal. 2008 OS/007\T $i 000066 ---- SSaammppllee NIanmfeo:12133-29 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13075255\A464640\ FCO040.D RIenqjeOcpteiroantoprate : j3m/i3l1/l0e4r 3i2si6 AN vSieaql LNion.e 037 DIinlsuttruimoennt + C1ooi1s mm3j.. Nvoo.l sa1 RAenqa,lysMiesthoMdethod:i CP:OA\AHSPUCRH.EMM\1\METHODS\033004F Lase Changed : 4/1/04 10:12:43 am SG27T E28 727 CHES TORTA07 S255A607COTTA OY APES. Nog: SHE Fa Var -- 36000 7204 THPFOS,| 2250000000 1 2105000000 10000000 ;i ps EE SDE E87 8(RENSTOR RESRSA :FCGOOTOBY RPWaES : , Fr5 " 1000 2272. PrOMX 00 | 0600 : 0p 5000 ode J St Aor" TST ECTS {C7HEN TORSO IS AAeAER:COMES ByAPE> SWa Sh Frag var oe 50000 7743. SURROGATE. 32500000 20250000 500 i: 1000 : | weer i a : 7 erode1 fr Compound Wane rea Fount Weas. Ret. T Signal Desc TPHr.oPsFOS SURROGATE 53603308.6795.59 34005.48 1s060.s00 77.a26m8 32.81 7.743 SwSDDI1 346297., EBIICC-e3a6286..77::346297..77 SDI 513, EICos12.7:513.7 "27nd of Report ev PESOS Riot, 4. BoE. 3006 OeRasb3 am Pade 3 OF 3 000067 SSaammppllee NIanfmoer:L2133-30 2 Data file :C:\HPCHEN\1\DATA\Chemstor\13075455\A467264\EC000041.D AIcnqjeocpteironatoDarte :i 3m/i3l1l/e0r8 333057 AM SvieaqlLmion.e i3 DIinlsuttriuomnent i 200041 IInnjs.. vNoe.i. su1 AAcnqa.lysWiesthoMdethod +| OC:A\AHSPUCRH.EMM\1\METHODS\0330044F Lase Changed 1 4/1/04 T0112:43 am po. HST 27 EiC=i38 ETT HENSTORCHEHaSe Ty ARES eg S7F258.VaTrHPFOS 2305000000 i 2205000000 . 1T50000000 : s000PE F HST RE E1388 788T (7SHES TORSO ATS F7 USER Oy APTS: S:h Fra Var s= 2500 720 pron 32050000 a o00i0 .! 78 I i 1000 0 /\, -- i Net eee ---- SDT--ESTETET 2E.ES TORSO SSSAAEa AFOOTOY APES Fag SW5I Fag Var --_-- mi 000 3 7721 SURROGATE 35200000 ; 2205000 : 1ow5o0ol0 err e pe redd mSosre Compound Wane T en ouT n Hews. REET Tonal Deve bropn.ros SomRocaTE 320637314663.855 Foeesiee lsee0a.s00 77.223a8 Ssoas 7a SSDDLI 432679,. EEiICCe.s3z6s8..77:346297..77 Nabi $13, Bic-s1.71513.7 Iona of Report en -- Ta 1. hor. 2006 10:35:18 am 000068 -- . sSaammppllee NIanfmoe::12133-31 . Data file :C:\HPCHEM\1\DATA\Chemstor\13075628\A469566\FC000042.D cInqjeocpteironatoDrate + 3j/m3i1l/l0e4r Instrument: PC00AL4 Siasias aM vSieaql LNion.e mj. No. + 32s 1 Dilution ir mi vel. : su LAAcanqca.elysCMihesantMgehetdohodd:| 4PC/:O1\A/HA0PS4CUHRE.MM\1\METHODS\0T3o3:01024:4F3.4am | ao [ST ER TTCRESTORSTGCRORAE) APES eg SH 72F1ra9.THPFOS 2250000000 !: 2250000000 n 150000000 1i s000- ee . | TISDT S50 EIGER T3607 (HENS TOR SOTSGTRABO8sH4FCOZ 0) APFES, Wo, &SI.Fig Vor eRe 7250: roa aon o0n ;: 0 wd, :A. wi -- eee remem mn TOTS ECETEST(7 CHENSS07T62O5ARe5 I RES, eg. S:i Frog Var -- = 7764. SURROGATE, d25o00 f 220500003 | 2m00l0 } 1000 soo mr om rrnd . i Compound Wane 7 rea Rn1ount Weas. Ret. T: Signal Desc i = Bropnr.os SURROGATE 30se3a6.417150 33678.26 si0s0.e00 77.0227%9 365.20 7764 SWDEID SDI 345621373,,, EEBIIICcCoi-sa3z16e28...777::1453216739...777 Ena of Report +e 2C004Ls The, 1. ADE. 2008 0:18u4 8B Page 1 of 3 000069 SSainmplie NTaanree:12133-32 y Data file :C:\HPCHEM\1\DATA\Chemstor\13075764\A472256\FC000043.D oITnapjcercomtpmeieronanecebrate 1|1 3Bs/emaviiojalenent 4ioiiie am SwInejaq.hLeiNonr!e 5pH:] Dilution i vei sui ARLcanaaa,tiyeMCiehecahnogmdeedtho0d +| C4p;o0\rHnsPsCuHR.EMN\1\WETHODS\01320004s% am 27 EC TTT CRESTOR TER EGC soso0n00 0oo0n To0onon pd I PES. SF7285o.reros: i i ! A I--o--o EOTSCRETR T CRESTTOORRESTTI ERS EOCI BY AEPETNNeeEST WSFF ,aaVrrr ron "= : p1o4d0n0. n ! Ep]d ! wi~ A . e veered re -ee em"MSD 513E , IC=T 5(C1 HEM2 SE TO. RI17 307: 57645A471 2253 6\FC. O007 043.0) | 2ho0s0t API-ES. Neg. SI IM, Frag7:1V5a1r-- sumRo-- GATE } mi TT | p=20d00 i $09pi Compound B Tan 1 weE Fo7 u S ews RETi -- STgnal Deve P-- roprs SoFmroRpnorooasTa SS1o5oi8st5i0ao5803 ms5oeo%o a77iaaaenms wWWo5hn1y 133255733,,. BEBirieceeoasstrss..aTrliasrE6is..n1 Tina SE Report ore bcooa1a Ths, 1. ADT. 2004 20sifedt an Paget oz} 000070 Ance,Evetnonaen + SsNoEnssmoomarsesar _e--e RRA BT RJR . " - oh--o20000- I E idaS cEE r TE e -- T Se SE ie = | w-n ; Tn onJ | | eb=00o0TM :d n I SR a=on ; --,} ==== eo 2 h4 a 5 wat mon 8 - mis 000071 _ Ssaammppllee NIanmfeo:solvent blank : Data file :C:\HPCHEN\1\DATA\Chemstor\13075865\A474560\FC000045 .D AIcnqjeOctpieonraDtatoer:: 3m/i3l1l/e0r4 $3605 AN vSieaqlLidon.e + 5i2s DiIlnsuttriuomnent Pc1 ooa1s mm3y.. vNeo.l su1 AAcnaa.lysMiesthoMdethod :: PC:O\RHAPSCUHRE.MM\1\METHODS\033004F.K Last Changed : 4/1/04 20:12:43 am aso00 20000 25000 20000 15000 "0000 S00 A ee SDT 427 EES TAT T(CHESTORTAUS065AaST0a7COO00isOY APES.Nog.SW~ FragVar ~ 7210. THerOS, || ` SDT 359, ECR 76 T(C3 RESTOR 307 S065Ra7TASS07FCTRO0AS OY A--PESNi. SW:I ment Fg: Var dons ETT, wo ss 200 | 20 5 | 0d rn : 7344. prOA ' Lou rr J [eIm EICE--TT--S --(HE--NS TORTS S885RATS : COO 02 320000 f: 225a0 | = it BY RPIESr :Nei o SI Far g Var ~ i --= 3 :: iHSN - [L I CoA mpoindR Nama eNe GNIreB a y TrN ount i Weas| aRedti.t T erSiegna~l~breesep. eepeoy pHr_opnr0S SURROGATE 2675950.0773.53 0.06 5.50506.00 72..320780 0.00 0.000 NMSSDD11 432673,, EEIlCC-e3d6s8..77::432679..77 WSDL 513, EIC-512.7:513.7 EE ---- PCo0414 Thu, 1. Apr. 2004 10:21:07 am Page 1 of 1 000072 SSaammppllee NIanmfoe!:12133-33 ) Data file :C:\HPCHEM\1\DATA\Chemstor\13075965\A477184\EC000046.D AIcnqjeocpteiroantoDrace |+ 3m/i3l1l/e0r8 Ssiise AM VSieaqlLimnoe ia DIinlsuttriuomnent i| pcooiis mInlg Nveel. sa3 cALnqaas.tlyeMCiehstahnoMgdeedthod|+ pC4/o:1m\/AH0SP8UCRH.EMN\1\ETHODS\00131320104457am || som 275- TprOS;, | [J s25o00o0 :! | Tsaonoa scoer pn TSE ECR TTC3ENSOR SETS EA1FCO000%B APTES. egSW Fragvar a PS || wo Tass. ron 515000 i 1T2o5c0o |[I = ;| .: } odTTSOER ECSTTETT STE E(CRESTOO R TAETE SGESHaTTARE Or SRES Fe SShF 75r7.r suRRoGATE | iow | aSowm :; | zZomu Too . aaa J so: Tm -------------- I a" LCompound Tame z Arex we1unt Wess Ret. T: Signal bessTa FSormopRnrooasaTE Slreoaoisievazie.s06 FsmoEoEo 737s 0 wNNeeSbDDs1 133336733,,.BlBEciicociosa3iz6zes...r714i3s36i7s9...77 Io Repers on 2000424 Te, 1. Apr. 200% 10:22:08 am Page 1 of 1 000073 SSaammppllee NIanmfoe::12133-34 2 Data file :C:\HECHEN\I\DATA\Chemstor\13076096\A479616\FC000047.D AIcnqjeocpteiroantoDra:te : 3j/m3i1l/l0e4r Si07:3a AN vSieaqlLiNon.e IpdH DIinlsturtuimoennt }irbcooars mmji. vNeoi.. : sm1 AAcnqa.lysMiesthMoedthod : CP:O\RHRPSCUHRE.MM\1\METHODS\033004F.M Last Changed: 4/1/04 0:12:43 an TTT TMSD1427.E1C=426T4ZT7(CHEMSTOR\13076008A496TFCO0004TDO) APLES.Neg.SM.Frag var [or To ero as000 : 20000 i 220500000 : = 3 | 10000. ' AL S B RSD359, EICE358 7369CRS ENSe TS E ORTSO7RORBS FACCAOT00SS HTB60) APIES. Neg,T SNSE EFag Var Se - 7280-pron 1a6000. 1\ 12100000 :: | = | 800 "-wo Ce \ I reminNdeo PP "MSD 0 513,EIC=5127513.7(CLHEMSTORI13076006A496 164\FCO0004T D) API-ES, Neg . S IxM. F r ag7:7V4a0r. -- me SURROGATE e 0250000 2500 | =1500 ! | i psee rr Sg -- ae Compound Wane Er C ea TTa FounT t WT es. Rete . T TSignal bese 8 me bropnros SURROGATE 30T13s9873.70560 32620.80 s2e00.800 77..227830 356.69 7.740 SwSDDI1 432675,, BEIICCa-a3z668..77::432679..77 MSDL 513, EIC-512.7:513.7 +2 Ena of Report ov Pcooars Thu, 1. Apr. 2004 10:23:15 am rage 1 of 1 000074 sSaimmpilce wIanmfeo:12133-35 2 Data file iC: \HPCHSN\1\DATA\Chemstor\13076165\A482304\FC000045. AITcnnajdecocuptmeieronanttobarte: || 3J3/om3ol30l/ae0ir4s SER eWihneNe!e i83 Dilution yl Vel su AALcnaqas.ityaCMihesathngoMededthod1+| 4Cp/oo3\a/nR0sC4uHRE.Nm\1\NETHODS\0130200014370 am NTT ECR TTT CENSOR SAT APES SFTa00- Tupr0s, s2s0000000 %' 25000 20fr0e0e0s ;H 1s0o00mo0e oA ; DT ETT (3HENSTORO TRS F1 EROBSy RiPSES 7 Fro or 3 2250 Tarn. pron 270500 : 11520%0 S| v7e5e0 5% : HT ECT 7RESTORE : APES ei SNF i= aS5o00 7147- SuRROGATE: : 32050000 0" 2s0c0o0 : oo j ee 5003 mid Mp oe en py 5. = Foneros SJoeaori7ei.n56 SSohoeo 77a2m6 WNebpi 132a73,. EBircceoaezse.ri7s4e27r.s7 SommocaTa Side e Enc Np 353, Brcesial sss Eo Repers on 000075 Peoosts hu, 1. Apr. 2008 10:24:25 am Page 1 of 1 SSaammppllee NIanfmoe::sTD 350 ppb : Data ile :C:\HPCHEN\1\DATA\Chemstor\13035313\A25888\FC000043.D hIongjeocpteiroantobra|te:| 3J/m3i1l/e0r4 Sana mn VSeiq eLirne 5: DiTtndueroiuomnent |i3co0sts n3j vNeio. l:| su3 AALcnaqas.lysCMinesatnhgoMedeathod :| Cp5:/o3\m4aW/sP0uC8RH.EMM\1\METHODS\20537200801400F1.am a 2500 2000 500 Too 00. -- 1005a 7 : o0o0o awoaoa a20o0e ]0 e [EE TS ESET T zRENSTOR SSTSRR7FCO ATES, 2pi0e0s i0 17000 PByod orp Wa SuFRrooRnnoroGsATE := H1f3ir5sr0ee6l03a E Z C Zseoeio0 27RE adm Ea ot Raper or Tam. Tassos. Cd ; ia 72807."4 iit i ed Sp :SH Fo Tr= Tso. SURROGATE iSN | 7 3 NwNeabDp:I 433263753,,, sBEillccee--a3szsises7rr1iis4se2is7s.s7) poo0sra Wed, 31. Mar. 2004 08:21:17 am Page 1 of 1 000076 sSaammppllee NIanfmoe::solvent blank 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13076277\A484608\FC000050.D AIcnqjeOctpieonraDattoer:: 3j/m3i1l/l0e4r 5:54:15 AM vSieaqlLiNon.e : 002 DiIlnsuttriuomnent +irPcooars Imnyj.. Nveol. : sul1 AAcnqa.lysMiesthoMdethod :i CPO:R\AHSPUCRH.EMM\1\METHODS\033004F .M Last Changed 3/1/04 10:12:43 am [BT ECTSTRET 7 (CHEN TTOORRY30782R 7AASASOBE F CO OO0) APeESS,iNe.SSW F Frag Var ~~~ | aso0 7276. THeFOS | ao ; 25000 ; 20000 15000 10000 500 ! e SOT355, E1CEI887360.7 z(CHEWSTORYFS0TS27TARBAG0HiFOOTEe D0) APVES. Nes, SW. Fiat Var i een "wo A 0 7.345. prOA : 0 i 20 ed Ne RESTeS13, EICSSETETR73E(CHESTORAO76 2 aSAST8FOO0005007 ATES: eg S:W Frag Var JS SE 2o0d 200 225000] 2200 w3oII CCoEmSpoTund TaRne UR RreEa 2 rNNA Ne Rnount-- TFeae. a Ret.TT FTSigma Bee parr . mw TPHr-oPnrOS SURROGATE 826730.0585305 0.00 6s.0607.00 77.023756 0.00 0.000 MMSDDL1 346237,, EEIICC+e346286..77::346257..77 SDL 513, EIC-512.7:513.7 "2 Ena of Report wv reo0s14 The, 1. Apr. 2004 10:25:15 am Page 1 of 1 000077 SSeammppllee NTaamtee STO 10 ppb : Data file :C:\HPCHEM\I\DATA\Chemstor\13035435\A297752\FC000051 ATIcnnqajcercoitpmieeornnattoare|:|| J32m/ci3od3o/sl0ie8sr Cons snieya eeti.ne 533 Siiucion i vel: su ALAcanana,eiyewCiehstahnMogedetdhod|: Cp5/o:3m\1a/sR0uP8R.CmHEM\I\WE0T0333H20O005D470S0\am 25000 SOTET ECE TTT CENSOFRSSSBy APES ag SW FrTara. eros, 3 2000 | sso ' ono 5000 1 | =pT TE ERC To TLSLR pad S TT 2 R STOR ST 2C08 APEegS$ F Vor | wo=w :! = : ms nl cnt | 4h000o A' NN SS E TT ECE TTS AENSTOR GSES S CSE08OY RPENeSSFE vr 4SR . 7754. summosATE SS2o0- ;: Hpood I. | | Zoo ~ FAW v 803m NT 7 ~ er" reer Compound Wane id Fane ews Fe To Siam swe SToFamr-orenoraoasTs sEeasEairEaiee SF EoRooE] 7am wNNepSmaDa 1S32e17a3,,, mBBriicecasasizsses r1ri4is7ae.nss7 ao Repere nt 00078 pcooata Wed, 31. Mar. 2004 09:28:35 am Page 1 of 1 - ssaammppllee NIanfmoe::STD S0 pb 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13076373\A497424\FC000052.D AIcnqjeocpteironatobrate Tnstrument i 3J/m3i1l/l0er4 | #C00als Sasi Am Svieaql Liwon.e Inj. No. i 5: i Dilution vel. sul AAcnqa.lysMiesthMoedthod Lace Changed i| 4CP/:O1\R/HA0ES8CUHRE.MM\1\METHODS\003:31020:44F3.Mam STII EETE CHEN STORES ARTEFCOO00ST 0] APES Na SWF7i2vg04.arFOS 20000 : 25000 20000 5000 10000 sac0 : rSD-- T S59 -- E0368--80TGe 7HENSOTTOS ARRTETTEE7 REe APTSNeg S3WFvar eT e. 7272. RON 000 : 2500 2000 500 1000 so FA odNSE ESTES CiRENSTOR SAA: Or APES eg Sh Frag Var TTTw 7725. SURROGATE, sc0o0 " 0 wl Compound Nand Ty= bropnr.os SimRocaTE Si26a1c64c04o7 Jose ss Fount 0S0o.d0s0 23s I: i AA L| Ne = Hews REET Signal bi ese me 72.2m64 aims WVSEDDLI WeD1 435261753,,, EiEEcIlCce--a3sz61s82...777::435261753...777 TITER or Report ve peo0a14 Thu, 1. Apr. 2004 10:26:18 am Page 1 of 1 000079 ~ Ssaammppllee NIanfmoe::STD 100 ppb 1 Data file :C:\HPCHEN\1\DATA\Chemstor\13076451\A489984\FC0000.S3D hIcngjeOcpteironatoDrate : j3m/i3l1l/e0r4 Sarior mw vSieaql LNion.e 553 DIinlsuttriuomnent + e1Cooirs mInijl. vNoe.l. : sul1 AAcnqa.lysMiesthMoedthod :: CPO:A\RHSPUCRH.EMM\1\METHODS\033004F.M Last Changed i 4/1/04 0:12:43 am SG 7 ECE TTTCENSOI07SRREASSENCOO0053 0 APES Ni SWEFg Var 7am. rFOS | a0 25000 2000 | soo 100003 so040 ohm ee }|fey SOT HG ECE76ST C& HTOER S0NTSAGG AASSUEAiFCO00GST0) APTS igE,ESNB.EFTrSa gVeare-vesuer 7200. pra ers da mrsell | eo 5000 2 aot 000{ |I 2o0od | b J s amr RSs D 575, ECS TTTTR (E CREME STOR ARMBSSSEOAFTCO O0S00AS3S0) Tt er AAPVES.NegSW.Frab Va m : 7748. SURROGATE | 1000 [_-- | ps ' ||| we we anA - | S`EConpd oind Name YENS = Tm nY ount Fieas. Ret.ST ENSN ignaAl b" isesSegUeeerpeere TPHF_OPAFOS SURROGATE 256147483.70616 7253.66 51s0.05.300 7.7.228704 asiss 7.78 MSSDDIL 346257), EEIIGCe3i6s8c..77::346237..77 MSD) 513, EICa812.7:511.7 +52 na of Report ev PC00414 Thu, 1. Apr. 2004 10:26:59 am Page 1 of 1 000080 SSaammpplleeNaInmfeo:STD 250 ppb 3 Data file :C:\HPCHEM\1\DATA\Chemstor\13076550\A492352\FC000054.D AIcnqjeocpteiroantoDr:ate : 3j/m3i1l/l0e4r Instrument Bcovars seas AM SVieaql LiHnoe Inj. vo. 5a 1 Dilution J mi vei. : sa AAcnqa.lysMiesthoMdethod CP:OR\RHSPUCRH.EHM\1\METHODS\03300.4FH Last Changed + 4/1/04 10112743 am SOT 27 ERSEZS TET CHES TORCTOESS00SE0F 5HBy APES egSHY Fag Var 7a72. THeFOS 20000 25000 2 0000 ; 15000 | 10000 | somo j | h-- ee An TSO 389, ECR 9 (7 CRESSSST0AAO023R52: FCIO008% OY APES:Neg S:W Frag Vor ~~ i - 1i0000000 72m.pro,7 1102000000 "' | || eexoo '. 2000 em er oo Sep OTST ETE TSTET C7HEN TOR 07SSSOATEEEA<FCTROSN BY AVES Neg SW5 Fag Ver ip 1 7750. suRROGATE, | wreoo 11520500 1000 i 7050 Iia 0d rere rmmeen Sepranes Compound Tame I Aver ReI w Wem Wee T: Slgml bel - Thpr_opnrOS SURROGATE 2141754052141163 1551350 s20100.00s0 77..227725 207.48 7.789 SuDsIp 436297., EBIICCe-a32668..77:1432679..77 MEDI 513, Bicesiz.7isis 7 LER of Report sev cooans Thu, 1. Apr. 2004 10:29:06 am Page 1 of 1 000084 sSaammppllee NIanfmoe::STD 500 ppb L Data ile :C:\HPCHEM\1\DATA\Chemstor\13076612\A434656\FC000055 .D InAIscnqtjerocuptmeieronanttoDrate : j3/m3i1l/l0e4r bcoars 7012113 AN vSieaql LNion.e mj. Ne. : ESs 3 Dilution ia Im). vel sul ARenqa.lysMiesthoMdethod |: CP\ORHAPSCUHRE.MM\1\METHODS\033004F Lase Changed + 4/1/04 0:12:43 an HOT 2ECTS T4277 CHENSTOR 30766 2AAGACBO00S055F0) APYES:Ne.SW Fag Var - son 2288. TPFOS 25000 1 20000 15000 \ 10000 IN s000-- { FN ST ESECS TE S7FEVSTOR OTSRISES1FCO BY APES.Fag S`WF Var = oud 7276. pron, 25000 ' 20000 : 15000 i 10000 5000ooo - et; SDT STS ESTETET 7HENSTORTSO SsTERA TF 000055 By APTES ey SI:T Fag Vr io 7737. SURROGATE 22500000 i: 220500003 0 11050000 i' | Eeer A S--- Compound Name z= cu1 nt Hews Ret. T : STgRal Bese o PHF-OAp.FOS SURROGATE 223305242220.8089 31545.33 ase070i.3080 77.l226786 Mrs 7m uuSSDDI1 346297., EEIICC.e3s6286..77::346297..77 SDI 513, EXcsiz.7isiair ITER of Report wer rcooata Thu, 1. Apr. 2004 10:29:53 am Page 1 of 1 000082 sSaasmppllee tTaomres 50 750 ppb 3 Data file SC: \PCHEN\1\DKTA\Chimstor\13076574\M97152\FC000035 Injection pare sen rave seq iinet 5 AThctqeerOmpneernattor +|HHjdmoilnlesr vimiaolevNoe. + sid6: hRHeeeadt.iyamttehetahmomedesthod|+| vCSo\emRaPssCuRnE.Mu\1\WETHODS\2 02300417 TET TART ERT SSBF CGSAR rFae. TorP os, 20 : 20000 i |C aos0mnd e e y d:iN WSO 360, EIC=360.7.389.7(CHEM30S 7667T 4A4GO 715R 2FCO\ 0006I .D) API-ES,Neg, SIM, Frag: Var. -- 2 SaSpSisaaoorooonoeoonnodmn Tors. roniJ||i| | 2000 i eee TEESE TET 2RESTOR eR RSG AF3 CO APoEgSSSsW Fa_ Tvraos_ r. sunmooaTe,8 om | aod n 220m005 } i ompI nd Ne S TA wo Roaney Ras We Signal bee, a SiFRoopncraotss pSEernlse SeEoosRo Tiaine vwVEeobtmi 1S3365753,.) mBBiienneaszeeeniiria4s3es0n Ta of reper ihe co0dis he 1 pte 2008 6E30GL 47 Sage 2 oE 1 000083 SSaammppllee NIanmfeo STD 1000 ppb 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13076736\M35648\FC000057.D AIcnqjeocpteironatoDra|te:| 3m/i3l1l/e0r8 Tan vSieaqlLinen.e Ed7 DIinlsuttriuomnent i PCO0ALs 3mj.. vNeei. sm1 AAnca.iysMiesthModethod :i CP:O\RHSPUCRH.EMM\1\METHODS\033004F.M Last Changed 4/1/04 1012143 am | ST ECSAZE TA CREWSTORTS SFCO00057 25000 | ooo APES, eg SW rFarge.Vaer ros | so soo oh ST EGRET 7CONS TORTS SSAA68:C0057 APE--S--, ----ST: Fa Vir = ST [E - 0000 Tas pro | mL ev | || mo 10000 TI BT 3 TOR :COS T ESSR herr a TSBT E T, | ro 77a. suReocaTe || soomm i | 20a0o0 .! 2000000 : od Compound Wane Te EArT ea e TFount Weas. ee wet. T Signea)nTeT se ee o SoFRroRnRoaOaSTe 2D2357a4072e365.895 SSsuoliosso o7adamae NNMSSEDpDLiI 543126375,,. EFEiiiccci.aaeez1se2..74is72157336..0777 TER oF Report +o PC00ILE Thu, 1. Apr. 2004 10:31:16 am page 1 of 1 000084 Sequence: C:\HECHEM\I\SSQUENCEN0401054 Sequence Tables Method and Injection Info Part: Line Location Sanpletame Method IS vVViaialalll: SSsbmmo1io0pfeeshn PpPoOMmMoMSuUrR S$ ovVviiisaalll::: SSSTlmDsos00obbppp GrOoomMmesoARr 7S VVViiiaaalll?s32 SSSo1ml0ve7ono%tobbipoaemk obpmooammasssUUuRRR 111200 VVViiiaeslll 51 52 1Sso9tl1v3oe5no0t30pD2ah0nk FrFooommmssstvURRR V113 DvViiTes:3 $$S 7100 5100m 0bpeeee PFTooomAmsAuSsnR 111756 VVViiiaaalll:s s550m07253%0000 bbppbbb pFPoOomMmaAssSouURRR 15 VT SE looohe romson Catibration rare: Line Location Samplename Method 25 vVViiiaaalll:3l SSSmT05iI0o00pfbeembno PPPOOoRMmMSSUUURRR S VVViiiaaalll:ss S5STT1DD073250000 bbbphp GoFOOmMMsSSuUImRR 1133G vVViiiassli??1 S$S1mT0O01O00p0Pphbeppb bPFoOOmMMaSSsIUuRRR 111756 VVViiilnsi33 SSSTT1D 010000 hbehh rTPooommMSsSUUURRR 1135 Vviisail?e S$100 71000b0obp FPOOMMSSUURR Inj SampleType Injvoluse Datafile 111 Sccaaamripenle 111 ccceallliimnn 11. ccSaaelimiiibne 111 SSseeammmpppllleee 111 cGcaaanliiiisbp 111 cccaaaiiiiinn 1 cali Calley Update RF Update RT Interval 231 RRReeeppplllaaaccceee vAvveeerrrssagggeee <o2f 51 RRReeeppplllaaaccceee vvAveeerrrsssggseee 271 Rhaevvpeelrraaacggeee hAAvvveeerrrsaagggeee -5 i35 Awvveeerrreegggeee vAvveeerrrassgeee 5o-b& 7 AAvveerraaggee AAvveerrasggee 22 LoMS3 4/1/08 10:50:45 AY misses 0t Mi 000085 Page 1 of 1 Method C:\HPCHEM\1\ETHODS\040104F Calibration Table calib. Data Modified Friday, April 02, 2004 8:47:24 AM caBlasceudlaotne : IPnetaekrnAarleaStandard ARebls.. RReeffeerreennccee WWiinnddooww :: RAebls.. NNoonn--xxeeff.. WWiinnddooww UPnacratilailbraCtaeldibrbaeatkison Correct All Ret. Times 05..000000 m%in 55..000000 m%in nVeost, riedpeonrttiefdied peaks are recaibrated No, `only for identified peaks orciurgvienType Weight : QTunacdlruadteidc (s(osmoemeppeeaakkssdidfiffefre.r, sseeeebebleolwo)w) Equal (some peaks differ, see below) ARveecraalgiebraRteisopnonsSeettings:i Average Retention Time aFvleoraatgiengaAlvlercaagleibrNaetwio7n5s3 CalibPrraitnitoountReofporrtecOaprtiibornastio:ns within a sequence: `NCoarlmiablraRteipoonrtTabalfetearftReercaRleicbarlaitbiroantion If thReesusletqsuenofcefiirsstdonceyclweith(ebnrdaicnkgetpirnegvious bracket) DIeSfTaOultISTSOamApmleounItSTD NIanmfeormation (if not set in sample table): oe + S00 02000 -pros SSiiggnnaall 31.: MMSSDDII 432679,, BEIICC=-432668..77::432679..77 Signal 3. MSD 313, EIC-512.7:513.7 RentiTni]mesigLl ATmoophu]nt Aves Amt/Area Ref Grp Name 7.366 1 12 550000..00000000 33.5506174768ees5 11..44207154736e--33 Ii 35 220000..00000000 33.05845270846e58 11..4s1118632s66--33 55 2500001.000000000 23..7088895963ee55 11..6739430034ee--33 7.375 2 71 51000..00000000 2773905.860669e6s8 11..6399033505ee--33 1 23 15000..00000000 24..863358302e5s 11..746633167a6e--33 35 2550001.000000000 12..2731245735e55 21..0824813755ee--33 &7 1070500110000000000 34.58896030006e55 12..912880021e0-33 7.794 3 21 51001.000000000 41527101.3561594788 81..02954401008e-32 1 33 315000110000000000 817.5762.61155e0465 11..414s4613e7-292 S 5T0u0i.o0e0s000 35.i4o5e9r2b4eeess 11.i4e28a5v26e-Z2 7 100.0000 .3013504 1.58635e-2 TH-PFOS PFOA SURROGATE 3000414 4/2/04 8:50:55 AM miller Sn A), 000086 Page 1 of 3 Method C:\HPCHEM\1\M\0E4T01H0O4D.S1 More compound-specific settings: ComTpionuendW:inTdHo-wPFOS + From 5.746 `min To 8.166 min orCiurgvien Type LFionrecaerd CaLleivberlati1on Level Weights:i/ LLeevveell 23 iiaa LLeevveell 45 HE1 LLeevveell 7 1i1n comTpiomuendW:indroowa + From 5.746 min To 8.194 min ComTpiomuendW:indSoUwRROGATE + Prom 7.274 min To 8.625 min Peak Sum Table "emo Entries in tablesss Calibration Curves R[iesRaeT+ + *4||7 TmcheoprP1rReOl4Sa27t,iaotnEelxcpe.azReT.:7:472.73.617800000 | es _~ FRoersmiudluaa:l Sytd.= mxDev.: 0.00000 | | e - | Xi amount7.R0a0t0i0o0 || oad1 - - ! CalibraJitioAnreaLevRealtioWeights: | ead 1 ~ LLeevveell21 +11 { i t Kd t=m 7 J LLLeeevvveeelllsss 11i11 LLeevveells? 1111 Ly JL [eae |e12 : o08d pa + - Ao 57]| PsRpOaR a36t9,expE.iceRT3:se.77.:337569.7 CoRrersiedluaatlioSntd. Dev.: 05.9096600280 | FormaP:UR y SJaPLNe ) | ei -21l005308034e-2 | oeaaddgA | 0s :+ am 7 me7 Ji Area Fatio 2000414 4/2/04 8:50:55 AM jmiller Fer Vij 000087 Tage 25E 3 Method C:\HPCHEN\1\METHODS\0401044F e=r"aotnee ob0no4s8 aLsE || oan ia 3 77]| mSUmRaROG5A13T,E aEtrceexspi.z.RzTi:sn7i.e75% | 4 Correlation: en, 4S15E58D21 p5 Formulaa:: 7y7= aHx1l?1o2o+9z3b e2a0e+0lx 1a 4 ~~ | eJxci:: AArmeoaun-tR7a.Rt9ai8to7i9o8e-4 7 7 3000414 4/2/04 8:50:55 AM miller FY Vifin 000088 Page 3 of 3 SSaammppllee NIanmfeoiw:SaTrOn10up.ppb 2 Data file :C:\HPCHEN\1\DATA\Chemstor\13087308\A913408\FC0000001 AIcnqjeocpteiroantoDrate :| 4I/m1i/i0l4er Tngtrament + PCo0als WA Vseianivon:e: Ing Ne i13 Dilution i ny vel. su AAcnqa.lysMiesthoWdethod |+ pGo;m\aHsPuCmH.EmM\1\METHODS\040L041F Last Changed + 4/3/04 0504726 am Date Tr Runecooccol To_Fccocor "MSD 427. EIC=426.7427 7 [CHEMSTOR 13087308AGT3408 CO00001 D) "oo 00 APES. Neg. SIM, FraTgs:eV.ar pros, ; 20000 ' 0000 ! J WPS SO TT. SOT 55 EC-388 78ST G7 HET0N80S0 T08OICORED APEMES SS i Frog Var S SE Taz.or 101600: oni | o12o00 i | a=0 wo J "- / / 200 rrr" wee DE ctEt Ee E Rn ENSTOR t TSOTa SI RSn SRG 7g FCTErOY A of 2 or APES Fe Sh7 Frog Var ia 1pr0e0s a12000 0s0c0o: 8p"0owso04EE 7.797 ET - - rn. SURROGATE / Compound Naw : ren a Z FE Sigal bese SE TSFior_moprnroocsae 3Fi5i6ie9s9ae0c.e3s8 2SE osooaRA 70asm MNwEEeDDiIL 433265753,,, BBBIirCcc-u.4s33i66z.e7i:i47s32i6793..777 Ro Repore ne Pooos1e 2h, 3. APE. 2004 GR453426 am Page pot 000089 sarple ruses 10 ppb . Bata file. 1CC\APCChosHstoEr1N308\795I0\R\SLSO392N\PET00R0GE\.D eJ yes tunes | EMS emoosyasososs. S won TT O I RRT E SR r(r --S fTSeerd ! --15000 H! | | soooieJ e 7 S 7 N 7 ee J i = | 1==w000 ii" 7.382. PFOA = 500400- 300 =ws E TEET 7 7 e e = 7 oo o.sunmoone2 : = Es, recess arn [Rt ! Po ~ re retiree sn erm \, - |= ! =250 A Jo J e e= rs e r l a ----N ----werie o~ tamer rt - Te TTsr owe 000090 SSaammppllee NIanmfeo :STD 50 ppb 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13037455\A917504\FC0000003 AIIcnnqsjterocuptmeieronanttoDrate ||: 3j4/Cm10i/0l0al4lesr T2i08ias PH VISneijqa. LNwioen..e :23 Dilution i 3 vol su ARLenaqsa.tlysCMihesatnhgoMededthod | 4CP/:o2\n/H0AP4CsHUERM\1\METHODS\00460:1407:4276.4am aso00 SOT 27 EIGER T2TT CRENS TOR aOR EARS INFCO00003 Oy APES. Ney SW. r7a3r86Ver FOS, 2205000000 ; 50000m0 | oo so00 No HST, ECAR 597{HENS ORISHA 047FCO0BAES By PES, F i Shi gVar 3 o= I s000 Ja. pron: 2500 o 2000. IH | wo Hh | od i | so ;. | [TE EEE C7HESTORRATS GTS1 O03 07 APES. | J. O:hFrMaYy"= 7768- SURROGATE, | wo || sco wo } | = 20d Compound Fae TSFiormorRnoocsaTe z= F3358e3367i0001t3863 Fo:unt Ps00Ih.Ch00 Weas REET: wo mar Signal Dee i ry 7.366 es VVseEpoDi1 4$S31e3a7,., BBBiiiccce--aezsisse.7e74i37i.733.6.9777 Ii Ena of Report oer bcoosis PEL, 20 PPE. ZOE 0BIEG:E WR P48 1 9% 3 000091 SSaammppllee NInafmoe::sT 100 ppb 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13087564\A915424\FC0000004 AIIcnnasjterocuptmeieronanttoDrace 1|: mP4o7io1lo/i0ei8rs Tne mn VISneijq.nLNioone | :57 Dilution if Im vel. | sua ALAncaaas.ltysCMihesatnhMgoeedtdhod |. 4Cp/oo2\n/Hs0Pu4CmH.EmM\1\METHODS0\80044071:02417am [JII 0000 25000 || soo 1000 50004 | SSSS I00 Ee | sooomo 42000000. || owwd bt| eM rRe E e z me i | oe -- ji ; SR FE rans.-- proA i ; : ed a eeT. 7754- suRROGATE | s8o00] | w i bCWsoda peW--a-- ren AFuT r e eas REET T Sigal BeT se ee" STEtiomsnRroocsATE 3sGseieaeisesass0o2n5 sf0l0os0'0res2 7e3e6s MMwEEeDDiII 433263733.., BBBriieccse3iaszzsie7.r1.s:3i467s9.77r EER ---- Pcooa1s Fei, 2. Apr. 360s 08:57:27 am 000092 ---- SSaammppllee NIanfmoe::STD 250 ppb 3 Data file :C:\HPCHEM\1\DATA\Chemstor\13087601\A521408\FC000005.D AIcnqjeocpteiroantoDrae|: 4a7m1i/l0l4er Taboo pn SveqiLoine s: DiIlnguetriiomnenc |ibeooata Imnyg. Nvoe.l. | suli AAcnqa.lysMiesthoMdethod :| pGo:a\aHsPuCRH.EMM\1\METHODS\0401041F Last Changed 1 4/2/04 G8047136 am ST ECETECENSOR TRE TAS ss000 CO0005 AP aSE W.F7aS 3g6V7-ar sros || 2a0o0 : | 1500 : | oe | 1s0o00000 Lr HSeeT ECE AT S7 ESTORTS | 1a00o0 osoooo || =o=w AISFG00aeE 07 APIS. SO Fograren TT, . | 2000 EE ee TST EEETTI 3 HENS TORHASTEersTe AGEFCOC0a0n0o8re PaFEi, hSr r BR ee- 792. sumoGATE |0 ; ss IH | wii |H ! ere gens, | Cope Tw 1 Fre fSornyReoraoaste 1S1o92a50z03a01a04a82s5 hm4ewst Weas Ret 76 Signal bese 8 BJSoeo0ee0rs0 271.3ms67 MNweEebDb:I 433326373,,. BEBiliccca3es6iaz8zl.e7.s:37n8193r7..77 oa of Report ot 000093 Peooars Fri, 2. Apr. 2004 08:58:48 am piers SSaammppllee NIanmoe::STD 500 ppb 1 Data ile :C:\HPCHEM\1\DATA\Chemstor\13087848\R923264\FC000006 .D AIcnqjeocpteiroantoDrate : m4/i1l/l0e4r Instrument | pdooais T2i5502s Bm vSieaql LNion.e Ins. No. :: 3 Dilution i 13. vel. | sul RAncqa,iysMies tMehtohodd:: Last Changed | C4P:/O\2A/HA0PS4CUHRE.MM\1\WETHODS\0048001470142F6.Mam a EO _ WSD1427.EiC=426 7427 7 [CHEMSTORVI 3087644AUZ32641FCO00006D) APIES. Neg. SM. Fr7aag mV.ar eros 25000 i 20000 15000 10000 | sd : I I NSDT 369 EIC=388 73637 (C7HENISTORTI308781 AGE3254FICO0G008 0) APES, NeF g, SIN=ag Var _ i 25000 i 7.378 PFOA!A -Tm 11050000004i ; | so ole oC ne er 7 HD 55 EGRTEET(CTHES T-OR3r08r744AF0C34O7 GOoAoPTsSi F SA7 r vl ar h pm = | 7752. SURROGATE, || aa0n00d || i) 20004 | oo 5003 ne CompoungdeName STuPHRr-RopcFaOnSTe eee He J370a07s13e3105 0861 Rouse iis0ss0ll.0ea0 dd ee . Wear Ret. w T g Signal be ese ct e OV 277.7m3sm SSMSoDDAAY 534162337,., BBEiIicCc-e-adee2isss...777i:is4ae2ts7s..7s7 Eri ---- Po00a1a Fri, 2. Apr. 2008 09:00:14 am Page 1 oF 1 000094 SSaammppllee NIanmfeo::STD 750 ppb L Data file :C:\HPCHEM\1\DATA\Chemstor\13088724\A925212\FC000007.D AIcnqjeOcpteironatoDrate :| j4m/i1/l0l4er Instrument Coola T1002 mM vSieaql LNion.e Inj. No. 5s3 Dilution i m3. vei s ul AAcnqa.lysMies tMehtohodd:: CP:O\AHAPSCUHRE.MM\1\METHODS\040104F.H Last Changed: 4/2/04 08:47:26 an || 25000 rm "MSD 427. EIC=426 74277 (CHEMSTOR\I 3088724AS25312 CO00007D) | 15000. oo son{ APIES. Neg. SM. F7ra3g65V.aTr HOS, : : | hHrOT 569 EFC 380(3CHENSST08O8ERRGAT:ACO00007BY y PVE: ie SIT Fay r - || waoooc0 7a.pron, | 20000 | 2200000003 : 1150000000 000oleP _ er ee t S Me m [Te E 7 om TREAT S TSTA:oFEwR 57 APTS.eg SW Fava : o | onl 7791 SURROGATE, | ao } | j Swe i | |i =wt | | veessmtepemmmmrrmrappesse m Compound Name = d FouF nT t eas RTETg Signal Dese PHr.opnros SURROGATE 2S7e7s6a8110..9870 8821.63 5a020s.i0s01 77.a36m5 7722 7.791 wSeDDI1 432679,, BBIICCi-a32668..77:1432679..77 MEDL 313, Elc-ais.7i813.7 i2"Ena of Report sev Pcooans Fri, 2. Apr. 2004 09:01:17 am Page 1 of 1 000095 _ sSaammppllee NIanfmoe::STD 1000 ppb 1 Data file :C:\HPCHEM\1\DATA\Chemstor\13089884\A927296\FC000008.D AIcngjeOctpieonraDtatoer:: 4j/m1i/l0l4er 1:26:48 PH vsieaqlLNion.e : 57 DiIlnsuttriuomnent + 1poooars nnjj.. vNoo.l su1 AAcnqa.lysMiesthoMdethod :: CP:O\RHAPSCUHRE.MM\1\METHODS\040104F.} Last Changed : 4/2/04 08:47:26 am SDT 27. ECHR TAT E 250003 20000 16000 10000 oF Rog. SHFrag: Var 7.364 THPFOS fi i i 40000 30000. 2000 10000 0d 5000 5000 SOT589. ECHR T96973(CHENSTORT me JN 3 APES, Neg. SW3IFrag Var 5 : 7373 PFOA, th | Ses 1 s5 -e = r So5 o m SDT S13, EICS51275137 (CHEWSTOR 08864AS27295FCOO00T80] APES, Ng,SN. FragVar 7765. SURROGATE,% 0 000 200 1000oto Compound Name TPHO_AP.FOS SURROGATE 3 Area i25984286862..3987 3150.88 Rro: unt 955050..5070 582.02 ne Weas. Ret. T: i grit Ses Signal Desc 5 me 77..337634 MMSSDD11 346297,, EEIICC-<346286..77::432679..77 7.795 MSD1 513, EIC-512.7:513.7 ++ End of Report rev PCOO414 Fri, 2. Apr. 2004 09:01:49 am fage tof L 000096 SSaammppllee NIanmfeo:solvent blank 2 Data file :C:\HPCHEM\1\DATA\Chemstor\13090445\A929408\FC000005.D cInqjeocpteironatoDrate : j4/m1i/l0l4er Tia2ite PH SvieaqlLNion.e 05 DiIlnsuttriuomennt i: xbcooars Imnjj.. vNee.i. sul1 AAcnqa.lysMiesthoMdethod : CP:o\nHnPsCuHRE.uM\1\METHODS\040104F.4 Last Changed 4/2/04 08:47:26 am 025000000 7am. pros|2 2250000000 ii 250000000 :i 1s0000000- rr read NOT 59 ECE TT E7 NSTORIOR 7 0 APYESNeg: SI:TFagVar 5 : ar5s0. ., 22s ! Lo, ar2s50 \/ poy rr? wo] | errmsg 7 : : 5 2 0 200 .! / . 2200 oo J | LCompound Hane ToHr-opFOS SURROGATE = 34o6%00065.75 0.00 cunt Weas Ret. T Signal Desc a520000.00 07..030m0 0.00 0.000 NSSDDIL 346237., EEIICC--346286..77::346237..77 MSDL 513, EIC-512.7:513.7 "End of Report ser peo0s1a Fri, 2. Apr. 2004 09:02:28 am Page 1 of 1 000097 Ssaammppllee NTaatmee!:12133-10 2 > Data ile iC: \HPCHEN\1\DKTA\Chemstor\13090966\A931392\FC000010.D ATIcnsajterGciptmeieronanttoprace:|| o4s/mo1io/li0li8esr TEE awInj.hiNenoe ii1 Dilution iT In vei. sul LAAcnaqas.lysCMihesatnhgoMede"thod | C4p:3o\/H0sP8iCH.EN\1\ETHODSGA0a4r01e044am DT ECE TTTCRERORSASTAROFCOOR APES SFTosaV.ar usros 2500 || oomoa | e sooEee nr T rstE e R AAE o STE ORTSTAT IoIoCE OTEr APPrEeSsninS sh Fg arrpm | sooo Tara. prop | 2s0o0n0] ootnoo | oon] eh ee ee | asd Te ECE TE2STOR 4 TOT 39Sh S Fa7705. summocare, 8 mi || al2000. } || o01e5m0o0 :' | o=is i eee- bo Tw `Compound Name Area Amount Meas. Ret. T Signal Desc. SFormonpnrooosnte fSSratiiiseer SSsoeeooo T2ilh3iee%s W}WeSabDoi1 334563357.., BEBicicuasczeeus. 7s1.i4s33n6sa75i77 RR eper or 000098 Pcooii Teh, To Apr. T00E 04EB:IT 9% sage rot 2 SSaammpmliee Khaarmee: STD 250 ppb \ Data file .C:\HPCHEN\I\DATA\Chemstor\13091632\AT33312\FC000011.D pInjerCctriioan mbalrei 1 3Hl7d1es01, EE uhEehhetine po:3 ei Hy ve sa AdHceai.tvaEMehstnhaohedesth>od +|| evEomesoumNAnMETpHODcS 0p4R0i101ie1s oo EER TET ERASERSRFT TES Wt, FgTeier ao~~ 0 = Soonood , |=| 2To00oo0o0 1 |4 ET 7 ORESSS A A ES SFr J\ i _ z wo pr 1aoco } v--1v2o0-o00- ; . po-=m H} h R i R 20 EER T 7 RI EE Fe S7 F Trio. swooATe, T -e | 2000: t | | = ed i See La, weer TST rTaorRneoan SrBoiveasees enaa wfSeroReemr clioiTdmee Woh vo 1ta27e, BmBeeearnne seaenns] Lr 000099 --"-- Set, 2. spr. 20% 93058 am poze tort ~ SSaammppllee NIanmfeo:solvent blank 3 Data file :C:\HPCHEN\1\DATA\Chemstor\13091812\AS35360\FC000012.D. AIcnqjeocpteironatobrate : 4m/i1l/l0e4r 220i mn SvieaqlLNion.e 5 DIinlsuttriuomennt i| 3a0als IIn)j.. vNeol. su3 AAcnqa.lysMiesthoMdethod |: PCOoA\AHSPUCRH.EMM\1\ETHODS\040104F Last Changed i 4/2/04 08:47:26 am SDT ECE TET CENSOR TIO 0000 ASSRO COE APES iSWFr7V7a1 rTHPFOS, 3350000000 | 2500 ;. || oss0o0o0 i |i----~ HISD 5( 8r , IC CSE m TRETE i -- ST S-- ONSO EASTR -- i FCA-- RGASPYT-- EESiDgY,a Shi-- Fa Var-- T 3= Lee eA 22s I| ma0 I aw] | | fmingd rrsn en en rn es - pn Eo. i JN . LL i TST ECS TET CEN STORAH 200 1 ps | aw [I | om . | de NVA VLel o Copound 2 Fae I= EAGERFCO000T2 01 APES: og Sh Frog Var -- . LL . HY \ : - a jv ne Fo7unt Wea REET: Signal Bese. I = TFr_opnros StmRocaTE a4l6s3o20.7 al00 as%o000i00 07..030m0 al%0 5.000 NwsSpDi 432637.,BlBcic-w3aezes.77i34e37r.s7 NSD1 513, Bro-siz.risnsiy preg ---- Pco0ars Fri, 2. Apr. 2004 09:08:15 am Page 1 of 1 000100 SSaammppllee NIanfmoe::STD 10 ppb 3 Data file :C:\HPCHEM\1\DATA\Chemstor\13092264\A937344\FCO00013.D AIIcnnasjterocuptmeieronanttoDrate || 4mp7ei1ol/ol0se4irs Zao VSneisa eLNirenle =1: Dilution i my vei. | sa AALcnaqa.slysMCihesantgMehedtohodd|: C4P/:o2\A/HA0SPaUCRH.EMM\1\METHODS\00540043701426.1am [[7 -- 27ECRCTRTESTORAARGRFCO000TI Oy APESig SH Fi Va Tara. mupros, |[a=so \ || meoold ;' [res | om] |bf eer e DrTeEreGETm 1 STORSE REm S COOSy YAPES, S eS Fg) virR ee SRe ||[I os 270. pron4 iIo=w I:` | wao w d eed FA. ||F |T ]e BS RE TT RESTOR 09228ASESACOTSh 0 APEESNetSo7 Fa Va ~~~ ===p asrhso 7768. SURROGATE. S0200 port PLL . || == iJ i [0Eb it bCar ipound amE e T Area FouT nt Weas. ReT t. T Signal beac ' bSroorpnRr.oocsaTe Se3fsge6at24es5s.53 ssohoeo we 7703s Te wMEeDiI MeD3 432675.. 333 iBIccioszees 71143639777 Eicusianisis.s iy rp ---- soo0sis Fri, 2. Apr. 2008 09:09:57 am Page 1 of 1 000101 SSaanmppllee NIanfmoe::STD 50 pob 1 Data file iC:\HPCHEN\1\DATA\Chemstor\1092531\AS39392\FC000014.D. cInqjeocpteironatobrate | 4j/m1i/l0l4er Instrument | 300ats 3:00:08 mM vSieaqlLivon.e 1| Inj. No. : 12 i Dilution i vel. | sul AAcnqa.lysMiesthoMdethod Last Changed : | C4p/:o3\m/Ha0Ps4CuHRE.mM\1\METHODS\00480:1407:43F6.1am [SOT aso 27 ECR 7 CRESTSOORESRAO GRE CR O0007 ETS eSi Fvi ar 772. Thpros, | pion i |= || ro | oo | sonny SE pr);HDT 54,EIGERTESTT7(CHOS RSOT T TAC SFORS GE OF APPTSEogF SSA Fr 7v2o7r9: .b pron =_m 2500 | wo | so | 1000- | se oo - JE I- EE 37T S EIFS T0 ESTET (RES3 TOR 30 1FCT57 APES eg SO`TFis Vir BER- | 7795. SURROGATE, |I800 " 2003 of be Compound WaneTT Arex TPHr_opnrOS SURROGATE 23843813.5977.7 Se Fount fs2000s.000 SS Weas FEET Signal Bese on 27.3307s3 alas uwSeDiY MSD 436257., 313, BB1icc--4a3e6s..7r1i4s2e7s.77 Bic-s1s.7isi3.7 +2 Ena of Report +r Pcooara Fri, 2. Apr. 2008 09:11:43 am page 1 of 1 000102 SSaammppllee INnafmoe::STD 100 ppb 1 Data file C:\HPCHEM\1\DATA\Chemstor\13092616\4941376\FC000015.D. cInqjeOcpteiroantoDrate :: j4/m1i/l0l4er Instrument: PCODals Ss vsIine.aqliWNoon. e: i33s Dilution 7 vel. sul AAncqa.lysMies tMehtohodd:: PCO:M\AHSEUCRH.EMM\1\METHODS\040104F Last Changed : 4/2/04 08:47:26 am [SOT ERATE 7 CH TORTE REES OS ASTTB CO07E 0 APES, Re SW Fg Var aso 7367. THPFOS, 3205000000: i| 20000 15000 Hi 10000 5000 i i irSrDTr I E8889T(7GENSORO02 SASH-- r TST I COMGIRE APYESNe S:We Fr Varyrd ebeeieer a 7o00 772. pron sooo s000 : i 000 0 3000 ! 2000 } |} .1000r . r WOT STS EXCRETE TTS (CRESTOR 3082 00 ao mE 0} aaR3176FCoo00TBSy ARV ES:Ne SiFa rag r" 7750. SURROGATE, ' i 600- w fre Compound Wane iPr_opnros SURROGATE Area 350074237.34060 9109.37 er To1unt 5s00o.0z0 1034 ! peer a + Weas. REET: Signal see, : = 770.337627 70750 wNSSDDLA 432679,. EEIiCC-e3d6z8e..77:1346337..77 WSDL 513, E1C512.7:513.7 11 Ena of Report ov co0a1a Fri, 2. Apr. 2004 09:13:04 am Page 1 of 1 000103 SSaammppllee NIanfmoe::STD 250 ppb 1 Data file :C:\HPCHEN\1\DATA\Chemstor\13052750\A943256\FC000016.D hIenqjeoctpieonraDtatoer:: 4j/m1i/l0l4er 3:31:20 BM SvieaqlLiNon.e 1 Ts3 DIinlsuttruimoennt +ircooara Iminlj. Nvoe.i. +: s ul1 AAcnqa,lysMiesthMoedthod : CP:O\RHRPSCUHRE.MM\1\METHODS\040104F.4 Last Changed 4/2/04 08:47:26 am SOT 27, EC74=77TACHE7ST6ORT30927SAG 298 CO000T 0) APES:a SW Frag Var ss000 7370. Teros, 3205000000 : | 2105000000 : 10000 | sor EE N itagail GOT 80,EC 7369 7 (7CHENSTORTa0027SOASEF7 CaROOTE By APESNeSW:EFa var T- - I rrr. pron 1124000000 i: || owoo :: | wd i || tooooo rm eni3|Segpr en forse ---- 3 7 T pe | w -- er | zs 7797. SURROGATE || oeol | or] i F Compound Name ea i TmouT nT t Weas. Ref t. T ST ignal Bese.w BHr-opnrOS suRRoGATE 31027222394374 17254.51 520006.5060 77..33770 22531 7.797 WNSSDDLL 432673,. EEIICC-e3d6286..77::346237..77 NSD1 513, ElCe512.7:513.7 EEsrpr---- Pcooa1s Fri, 2. Apr. 2008 09:13:51 am Page 1 of 1 000104 ~ Ssaammppllee NIanfmoe::STD 500 ppb 1 Data file C:\HPCHEN\1\DATA\Chemstor\13033552\A945472\FC000017.D AIcnqjeocpteiroantoDrate :| 4j/m1i/l0l4er Ingerunent 2covers Siacise mM vSieaql Liwon.e Inj. No. 7s 3 Dilution ia m3 vei. : su AAcnqa,lysMiesthoMdethod Last Changed : C4P/:O2\R/H0APaCSHUE4RM\1\WETHODS\084:04170:42F6.Mam HST 27 EWCRAZS TAZ T CHEN3S033T502ROOARTAF C007 Oy PFaESWI:Fi Var -- 0000 Tara. mprOS, 25000 : 20000 | 15000 | | room | 500 SOT Ce 7559(CZ RESTOR SOSS8SE RGA 1FCO BY APES,Ne ST: Fr Va dN : = 25000 781 roa 200 i 15000 | 1s00o0o0]i { Pee s WOT Se TSECSTe E TEST (7 CHENS00SSOTROaA8R37A1FCOR00T7 By PLe ES.e a. S:w Frod Var A : 2p> a0+ 7.800. SURROGATE,% | 2a0s00 | o15m00 i 1000 0 i er Compound Name i rr rea Foiunt eas. RET: ed Signal Desc : ee po PHr-opnr.OS SURROGATE 2732087954755968 S4615.78 sa0s0s.l0e0r a77ls 77.330714 7800 SSDDLI SDI 436297., 513, EEETlTCCC+e.3a86z18e2...777:::438261733...777 "+2 Ena oF Report wer coors Fri, 2. Apr. 2004 05:17:12 am rage 1 of 1 000105 ssaaltee ttaanem:sm0 750 300 . bac ie Co\uEGhanHasonE1305N3730v\47ekOB\RNCsT EaSSmhemrnsnemioT rlmEaE r miCHHiiem uai2: rAG eq, Ive enea n +| E Groemas vmensaStone e. b= EE Ton ere | moo25000- i | hou115000. | 5000 i t wedE _ R E2 TO T 4 797 a S6hr vn 8 .mi | | =o-=e. i; e=s= i : I J. rd rEET To TS--C-- HT-- E ES o-- r Set o-- r ar-- ,: - |wo] | a-oi d |; ; E2bE5eeecoemin ans Smmaennwe B Smaa aran mn i, mmaommmoemneewe1s4 SR scons rei, 2. pr. 2008 091170 am page 1 of 1 000106 SSaimmppllee NInafmoe!:sT 1000 ppb 2 Data file .C:\HPCHEN\I\DATA\Chemstor\13093875\AS45440\FC000015.D ATIcnnqjoeeocrptmeieronanttobrare:| B4I/mo1i7to0i4err ea eiLiihvneee f2:r tte i vel su AhLcnagae.iyawCihesatnngoMederthod :| C4op/o\3mR/rE0sC8uHmE.Nm1\WETHODS 0G4a0t1a074276.1 am | soni |j [pse | soo Ei TECRE AS O AC AESaSi FTaass.rTro | 1w00o0o0 Se rm Re|! esom ooeDr T g 85e EoCe.E TmERTELNNSROORPEOBTRITSEAAEB rFuCOTEETOT gRpFEgaiins lSeTi Fp v7ars a- prop n scremer 8 | sooo | 0000 : | 20000000 !: Too : || EemeRr r E TTS ENSTORr GRCR IRO r APESNeSaT , ST p | i a 7755- suRROGATE: |[ | o|o Ce || =oo 2000 ps } CRT > EEa eeeeeesreeee geeee Froe eer ewemeec REeEsTe l ass ignae l bess e. eseee SFrmornvoioots pEZrogeoa0 ia FSseoEeoRso res 1a [wVeenrbi e3413r37., Bmriecaisztes.Ss 7437.7 rian ao hepere nt eeoosis Fri 2. Apr. 2006 09:18:31 am Page 1 of 1 000107 rawaarAREPORT [ firmerarioda ii rou =vo - Ui n_-sui Som wise o3mian i psrmoonewee - Eom aShnsinnner Sinem Fev 1 prevente wo -T --[Fa S-w s- wea v-h-e sCae ome rawem s m ewomsnm mAoer _--oT_Ok--A pCroots : S Soonms Rnm oo lwe 0 : amb : ow CConntaonrts SSoSamo 1 TORRTr ord kbriof meEeo eetcg t ri 21 PRON Fc 1FO rn Bt. ene Srei g 4) a P com-- a LE0 e<paityseCoem ie et ef el2 feetsr ecco Dapmred : ctoa rooen ooronsem N0 D =Cod rksautntseRa Repe eod neLO0DnDd100 Soest rust MB,0401Joo 000108 LC/MS/MS SYSTEM AND OPERATING CONDITIONS Sponsor Protocol No: NA Exygen Study No: L2133 Instrument: Micromass Quattro Ultima (LC/MS/MS Unit #7) Computer: Software (COMPAQ Professional Workstation AP200 MMiiccrroosmoafstsWLiinmditoewd:s NMT:asVseLrsyimon34.BBuuiilldd1030841 Service Pack 5 HPLC Equipment: HPLC Column Mobile Phase (A): Mobile Phase (B) : HewHHlePPttBAiuPntaaocrskyaamrPpdulm(eHrpP) Series 1100HHPP CVoalcuumunmODveegansser Genesis C-8, 5 cm x 2.1 mm id. x 4 1 (xygen ID:MA13296) (JONESCHROMATOGRAPHY: Part No.FK5962EJ) 2 mM Ammonium Acetate in Water Methanol Analyst EAxmyygeSnheReehsaeanrhchn 032A 3Ph0o5n8e:Re(s8e1a4r)c2h7D2r-i1v0e3,9StaFtAeXC:ol(l5e1g4e),2P3A1-115688001 NOTE: The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set. All Handwritten Peak ID's by: =m 000109 Lo.| EsEsIge0sNsEs bd z | 5 8. E coccceo iq a= | 1&8 i Eon I8 E1oH [[81 HspigHs2 CL ine 8 oibdas | Ia 4 Se 8885888 iH 8 iii bE Li | | 00 IY $3 53 3 FSEHEH E z228388 oven 000119 [$5] 0| lo iqCE |2 |El B=d2 { a yi gl gn 000111 LC/MS/MS SYSTEM AND OPERATING CONDITIONS Sponsor Protocol No: NA Exygen Study No: 1.2133 Instrument: Micromass Quattro Ultima (LC/MS/MS Unit #7) Computer: (COMPAQ Professional Workstation AP200 Software: HPLC Equipments HPLC Column: MMoobbiille PPhhaassee ((A3)):: MMiiccrroosmoafstsWLiinmidtoewd:s NMTa:ssVeyrmseio34n.4 BBuuiilldd 0041381: Service Pack 5 HewYHlPPetBAitPnoaascrakyamPrpdulem(rHpP) Series 1100HP HP CVoalcuumunm ODveegansser G(eTnOesNiEsSCC5,HROoMmAxTO2 GRmAmPHidY. :xP4art(NEox.ygEeKnS9I6D2:EMDA)L256) V2imetMhanAamlmonium Acetate in Water Analyst AErmgyoSnheReohavnedreen 3804 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580 NOTE: The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set. All Handwritten Peak ID's by: _ 000112 -- Scann-- ie ng -- Math-- odr Re--port----------------------------Pa-- ge 1 MTaotshtodM:odified: CT+hu\MAOScStLI0I2OX\1F3L:U5O6R:O5C5HE2N0S0.5BROVACOUD\008 PFOA Printed: Wed vax 31 13:59:16 2008 MB v3)31joy Solvent Delay ( mine ) : 0.00 Runction 1 MM of 1 Mass Pair ( Z8E- ) SSIpnaatne.rr (C`rhDiaamneinveo(lnwsiD)nelsa)y ( + Secs ) 0531.000003 REneapeTaatmCseh:an(nevlinPea}ren|t Daughter aD: ue0ll (Secs) Coll Enezgy (eV) Cone ( V ) : 3.00 363.00 0.20 10 10 000113 Mothod Report LMaestthoMdodFiiflie:ed: Printed: Wce:d\nmeassdsalyy,nxM\arlcuhor3o1c,he2n0s0.4pro13\:a5c3q:u3d2b\water Wednesday, March 31, 2004 13:59:25 HP1100 LC Pump Initial Conditions SolAvvents 8% 00.00 oorr ool o SFtloopw T(immle/mi(nn)ing) Min Pressure (bar) 1500.0300 o OOMvvaeexnnpTTreeemmsppseeurrraaettuu(rrbeearL)Reifgth(tC()eC) 0305.0 slo HP1100 LC Pump Gradient Timetable The gradient Timetable contains 10 entries which are Ti0.m0e0 0a.v0 010 Solo 10a.0 oo o00 0.0 o0r.0 olo F0.l3o0w0 0.300 21.l0000 10To0l0o 2.50 00 5500..00 10000 l0.o0 oo oooo 00..330000 oo 0300 5510500 1350 0000 00 10400.00 00 oooo olo oooo 00..440000 00 0.400 15110.0000 00.00 40000 oooo o0o0 00..330000 HP1100 LC Pump External Event Timetable The Timetable contains 4 entries which are : ITniitmieal 0.00 ColumeeSwitch Conoteact ote on Co[nt7act oe 800100 ootees ooftee oofnt Contoatcets ootree ote Conottaectd oottee ote HP1100 Autosampler Initial Conditions DEDrjraeacwwt PsSoppseeieetddion(u1(/mmmin) 2200000..010 SItnojpecTtiimoen V(omliunsm)e (41) vial Number 115500000 Ea Page 1 Pr4e0s0sure 110000 01000 110000 01000 00 000114 -_ MeTtunhiondg:Method Rep:or\tH.ASSLINK\FLUOROCHENS. PRO\AGQUDB\FLUOROCHEHS Page 1 Printed Wed Max 31 13:59:36 2004 Be, oajalor o EB8O0E i .R00D #60 | | D5au %295.7 00 kh SouRcE (se ) CaHSoepnxiealploalrey1 SAHopeuexsractpeuorreeBlo21ck Temp Desolvation: Temp. Prassuras GAansalydsaleir Vacuum hd % dome Sat Rank 333.%00 -52.93 2a.l0o 0300 310010 Rank 2os5ee-a Analyser iT1EneRreresasy 11 1 ECExonilttlriasnicoen DIiiEneRfroeossy 52 2 waltiplior Gas Flows DecsonoelvGaatsion Sot mank 1105.00 F31E0 2 1Ta0oh 726%0 -eos Rank s7.i0 000115 n CTS YS ETS ONREEIRSn n sotice, Bxtate:03/26-20/08, n Amaiyet A. Sheehan [. hbCaielnigmberastion:|MEe pP:W\aDA aRcL Ga\EINCNHFBEleunNogoScHhToerni\so.iFRaO\osCHusvaDlaBmNyeG3om2j6a0o4s\AR COR Solids |GocthcentR of BE eteE rminaten: 0.99930e 2 e CeCaleibTnroattieosn,ecEuerveo: I1E8e33e8t.6 S* xHa+rB-1.52w.e2i5g6hing: 1s Avi vans: None !i: | Fo | ; | 5 | : or] i 1 | i 650 2, STHe a6 46 55 60 76 #6 ss ialTM Erpgen Saseazch, 3050 Ressareh Drive, Stave Goliege, Fh 16300 000116 QSuatntuifdyySNamoplS:ee1Rteo2p:o01r3t236034A,R Solids, ExtDate:03/26-29/04, Analyst A. Sheehan rage 1 LSaasmtplemodLiifsite:d: P:T\hDuatAap\rLC0M1SM1S37:\3M5a:s1s2ly2n0x0\4Fluorochems. PRO\SaspleDB\032604AR CSR Solids MLeatshtodm:odified:P:Th\uDaAtpar\L0C1US1S3:74\0M:a0s8sy20n0x4\Fluorochans . PRO\MathDB\PFOA non extract 040104 Job Code: Inia, Prin-- ted:----Th-- u Ap-- r 01 -- 13:4-- 2:48 -- 2004----Re TE. TRS EETE ET Re NTaomxe:: 032604AR-201 Ln oo 1: PFOA EE |[cos2604:5, 0.2 ng/mL standard 03z2e604AR-201 Sm (Mn. 2x2) | |% 01-Apr-20L0C4Ma SMS # sos MRM of 1 ChaTnnTel0ES9- 4041 26A5rdea! | adhd Me ne ri eer L10 200 0 300 "400 T780 600 0 700 800 Exygen Research, 3058 Research Drive, State College, PA 16801 000117 J | QSuanetifu y12s1a3ds3p,ly eSaRteNop:o0r3o t260!4AR Solids, ExtDate:03/26-29/04, Analyst A. Sheshan Page 2 LSaasmtplemodLiifsite:d: TPh:\DAaptra\0L1OM1S3M:H3S5?:\M1a2ss2l0y0n4c\Fluorochess .PRO\SasplaDB\O32604AR CSR Solids NoLaabtshtocdom:doed:ified: PTih\uDaAtpae\LOCLHS1H3S:74\0M:a0s8sl2y5n0x4\Fluorochess PRO\MethDB\BFOR non extract 040104 ecPre inrtede :------Tha--aps--01--13:--42:4--8 2--008 ----------------eme---- NTaemxat:: 032606AR-202 1(: CprUon3260.054ng7/m5L,standardI"01-Apr-2004} 09:50: (0p3y2604AR 202 Sm (Mn, 2x2) 506 MRM of 1LCChaM3nSneMl3SE0#S9. || sisi sg`Azreea %-| | oeola Taho 260 300_ ago 500" 606 700 aSr bToime Bxygen Research, 3058 Research Drive, State College, PA 16801 000118 -_-- QStuuadnytNiof:y12S1a3m3p,lSeetRNeop:o0r3t2604AR Solids, ExtDate:03/26-29/04, Analyst A. Sheehan Page 4 SLaasmtplemodLiifsite:d: ThPu:\ADparta\01LCM1S3M:S375\:M1a2ss2l0y0n4x\Fluorochens.PRO\SasplaDB\032604AR CSR Solids MLoatshtodm:odified: TPh:u\ADpar tOa1 \1L3:C4M0:S0H8S270\04Masslynx\.FPlRuO\oMrGtohcDBh\aPFsOsA non extract 040104 Job Code: Printed: Thu Apr 01 13:42:48 2004 -------------------------------------------------- NTaemxot:: 032604AR-204 1: pron a |1023123630-4A5R,-D2F04=1S0m0(Mn, 2x2) 01-Apr-20L04C1M0S:M2S3 # MRM of 1 Channel ES- 1| 00. 1 23520056 413T>5136630 Are: |% | o LTT E00 360 a00 HEE 500 TT ebo 700 Time Boo | Exygen Research, 3058 Research Drive, State College, PA 16801 000119 QStuuadnytNiofryL2S1a3m3p,lSeetRNeop:or0t32604AR Solids, ExtDate:03/26-29/04, Analyst A. Sheehan rage 5 SLaasmtplemodLiifsite:d:P:T\hDuatAap\rLG0M1SH1S37:\3M5a:s1s2ly2n0x0\4Fluorocheas. 7RO\SampleDB\032604AR CSR Solids MLoatshtodm:odified: TPh:u\ADpart0a1 \1L3G:4H0S:0H8S2?0\04Masalynx\.FPlROu\oMertohDcBh\PeFnOsA non extract 040104 Job Coda: Printed: ha Ape 01 13:42:48 2008 NTaomxee:: 032604AR-205 (1C:03p2r6o0n4-3, 2.0 ng/mL osotandard oe !(100302.604AR-205 Sm (Mn, 2x2) [oy TT TA } a MRM of 1LCChaMnSneMlSES-| 35605250 4132>3530650 Area | 100 2.00 300 400 500 6.00 7.00 800 ! Exygen Research, 3058 Research Drive, State College, PA 16801 000120 QSuatntuifdyySNamoplS:eet1RNeo2p:o01r3t236034A,R Solids, ExtDate:03/26-29/04, Analyst A. Sheehan rage 6 LSaasmtplmeodLiifsti:ed: ThPu:\ADparta\01LGM1S3H:S375\:M1a2ss2l0y0n4x\Fluorochens.PRO\SampleDB\032604AR CSR Solids MLaatshtodm:odified: TPh:u\DAaptar\L0C1MS1M3S:74\0M:a0a8sl2y0n0x4\Fluorochans. PRO\HathDB\PFOA non extract 040104 Job Code: Printed: Thu Apr 01 13:42:48 2004 NTaemxet:: 032604AR-206 f&0352268004-2,5.0ng/mLLCstanddaaird |[03i2y604AR-206 Sm (Mn, 2x2) || ol LL bo 3bo 800 01-Apr-2 r-20 0L0C41M0 0S::5M574 S7::2#217)1| 508 MRM of 1 Cha1nn3e>l E3S60:| 88915 5.A9r1e5a bo 500 600 700 800Time Exygen Research, 3058 Research Drive, State College, PA 16801 000121 SQuatntuifdyySNampolSe:et1RNeo2p:o01r3t236034A,R Solids, ExtDate:03/26-29/04, Analyst A. Sheehan Page 7 LSaasmtplmeodLiifsti:ed: PT:h\uDaAtpar\L0C1MS1M3S:73\5M:a1s2sl2y0n0x4\Fluorocheas.PRO\SazpleDB\032604AR CSR Solids MeLatshtodm:odified: TPh:u\DAaptra\L01CHS1M3S:740\:M0a8ssl2y0n04x\Fluorochans.PRO\MthDB\PFOR non extract 040104 Job Code: Printed: Thu Apr 01 13:42:48 2004 TNeaxmte:: 032604AR-207 1: pron 32604-1, 10.0 ng/mL standard p10r3y2604AR-207 Sm (Mn. 2x2) % | olL 700 200 300 oe 185603472 "01-Apr-200L4C1M1:S44M71S2)#7) MRM of 1 Cha4n1n3el>E3S6:11A7r6ed | oe 400 500 600 7] "bo Exygen Research, 3058 Research Drive, State College, PA 16801 000122 QSuatntuifdyySNamoplS:eet1RNeo2p:o01r3t236034A,R Solids, ExtDate:03/26-29/04, Analyst A. Sheehan rage 3 SLaamsptlemodLiisfti:ed: ThPu:\ADparta\01LGM1S3H:S3?5\:M1a2ss2l0y0n4x\Fluorochess.PRO\SampleDB\032604AR CSR Solids MeLatshtodm:odified: :Th\uDaAtpar\L0C1HS1M3S:74\0M:a0s8sL20y0n4x\Fluorochens . PROMethDB\PFOA non extract 040104 Job Coda: Printed: Thu Apr 01 13:42:48 2004 NTaemxet:: 032604AR-203 1: pron I I(C032604-4, 1.0 ng/mL standard I1'010302.604AR-203 Sm (Mn, 2x2) 15607536 lw 01-Apr-200410:07:10 MRM of 1LCChaMnSneMlSES#-7 4131>.0386695 Area td i e 100 300 t 300 400 500 l 600 700 800ime Exygen Research, 3058 Research Drive, State College, PA 16801 000123 Sosfuperr sutra ie Hg4ox =oes 2w 0 RawaTAREroRT raLrnenuvoin sOrhivepin fSaiimtehs: ine si eennse Toe Eicoon LoSeotnnsnesr pwearieie foe rSosme sPAeE RAm sCuo Donl fk wfoert mfooomas _ohoexe Reonem jCiosttas :: SStoemm oo0 smuws i >: : cGoosceh SRReaapipBsunk3 :: iaiersse sBuok*hcnn purieyn iBaaacnnh GiiLiinonesss sSeomon Gaiionns VHoec n[LHiaeinnye Bunpekyn [ri En cSs woneoe eaios wCs ormoeimwnen GWVooo oGormmaeanwnn SS oomommreen &T$ omoem aem &5Soooommaeewmnm S$0 onomaemmamm SoGmawm 0s Low590e299 Ld1Poawms em oCwWobmaaee CCobnWoooawlrs am oCs hooWomwh ae DwBoomw oss aaWS 0T[o= mseem: 1 me aw : aw:m oo0n:s owo:b wEoAo xn : spWiAo ow:e : :: wi:s oo3 : 2: : owe : 2in1nmdn4s? coins MVVeiereeahh S SsDoooo m0m3e26aa0o4n0n1m29 -0D1T1 o1om9a26we83es.. : & mewn 5 we ) : : : : :;: TO OReNmFyode peo icap FPOONNstntgn) tags 60 p cSeoe-0Tie0s%rer FROAFond 1)PFOAfund ni Ex: Vm (1) Sulih Catore omen faE5-t- cCsumtaaanmeants T71e LFao stteCammmeis Doruaetteeehebtaukiaet Fre aeroa0rmeLonfrmeBRnstAaTNh gfr excet N e0 =CRvsSRi treppotm roetr1eo 000d0100 Spit 8.oda 000124 E CINN a soaonn PhoFnoen:S14a27m210a89 Coserin tLeamrsas Chain ofCustodyFortification SSheelt t T Temple r msm oe aaa le LE [CCLENTSAMPLED| EXVGENIDNUMBER |WEIGHT |FORTIFICATIONGo| [ C T T R m weeesgne de T | x [ w T OT n r ] m ear woioseToTw] Eo r a E m Fi --Eg T --] -- o tieen m om e a ] ] VWeeear o omeme] 77 I C Semmes |rSomosmsmmsvaerT ra|nvostTerimeosomne|]cpBaooaleot|] [eeeeee Afr caiin le ee sFeStmcaamsno_ Allsampleswere weighed on balance no. 20 TCiommement1430 Date. ' Analysis Summary: Dua s_0320604 Initials _ CEE niaspae: AM10G3)acloy Setextraction/daatnavaerliyfisedibsy:_#cy 0- 00125 bate yi h EE: ETI bigas! fod | : do BERTIE 1s iis5:: BUEHHATIANITE1#iz 47 ; 8g2 (858 EH-3 HER TTTTTTRh2e7 38% ! 1 2 28, FIT Bled |, be OE sg: 2 Bf pe J z "Fy of P HHH H TTI T EY Boi3 + D: 8 fs i Hh Pgs3s HE: 2 Is Z: : i iz x a5: IZ i 5 5 ii3 23 33a2 3 i {3 35 pe S555 fa Seg 000126 C= 38 5E3E5E5E3E5E8E5E3E8E3E8E3E5C5i8T8R5R5R5R5E5R5R5R5R8R5R5R5R3R5R5L5Y3 85 [3 c | g 8388338838888888883283888855s g | 8 ceveeeeeee ooe o o-Be g dl En : terre [EREEREN] PrEbirn |3 gl & 5 : I | 1 omenss i mmenssiz ne 8l Lo | 2 Hgl setts] erreee Sessslessslossslosssll 585222g00025082 Som mor o1 1H | | |3 || | aiy | 3g En HEE ga 1 i EEEEE sR ff FB &pigSoSiy2I8iu8rleifmassgasUsnvsoiesnTigoaaTtTdaatiiiitnitcydi8 a8o odig3e2 5 Ginna = | iH S LUI 13 |i FEE 5 = 2 3s E 2 53| 3 |&$25:5 | EEE EE En szzzgssgererzoessannnzasnnsanny dddgddgisgdsdss iggddagg Sddddg ceossEssveIvsesIeniussIssnIanEnss TNmteereaRTNRTReEReRRNRIRRNRRSANAS iLoBli :@o |& g| rl CE | nN 5 lf ml || kb{ i 0 ;P ::| H iii y Hill ij SHI eeeoooooveeci enye HE HEH HEH EE HET : THON ere2RINRIRERNERSENTS LC/MS/MS SYSTEM AND OPERATING CONDITIONS Sponsor Protocol No: NA Exygen Study No: 12133 Insrument; Micromass Quatro Ultima (LC/MS/MSUnit #7) Computer: Softwares HPLC Equipment: `COMPAQ Professional Workstation AP200 Microsoft Windows NT: Version 4 Build 1381: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004 HewHlePttBiPnaacrkyarPdum(HpP) Series 1100HP Vacuum Degasser HP Autosampler HP Column Oven HPLC Column: Genesis C-8, 5 cm x 2.1 mm i.d. x 4 u (Exygen [D:MA13296) (JONESCHROMATOGRAPHY: Part No. FK5962EJ) Mobile Phase (A) : Avatyt: Mobile Phase (B) : 2 mM Ammonium Acetate in Water Methanol mTygpshReteasneair 02604 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580 NOTE: The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set. All Handwritten Peak ID's by: AM 03)3iJ0/ 000129 Scanning Method Report Page 1 MTeotshtodM:odified: CTh\uMAOSoStLI0N2X\1F3L:U5O6R:O3C8HE2M0S0.3PRO\ACQUDB\00S PFOA erinted: Zuo Mar 30 10:55:42 2008 ne o3]sooy Solvent Delay ( mins) 0.00 Function : 1 MEM of 1 Mass Pair ( Espo) SSIpTnaatnre.er (rCDihamaientnoenlewiDenylsta)y ( Secs ) 003.::000300 REenpdeaTtismCeha: n(neNlinPea)ren|t Daughter 35:00 Dwell (Secs) Coll Energy (eV) : 413.00 369.00 0.20 10 Cone (V) 10 000130 Method Report rage 1 Wethoed lriitte:e, <o-o\amtaesyst.ymaer\eSnlu3s0r;ocdhoensss.TprooAvSacIqEudbiwater Princes _ TueT sday, MarE en 30,T20R 0E8 10:55:5T 4 hee 03) soloy [TT -- sotvents 60.0 . aa HHSA j FlowoeP(orme/ermmuiine)rous) Tan Brensure (oad) 2:02.3300 408 GSrveenn TTeemmppeeTrIantiuIreeLKateE(+Sc) 25.0 P1100 1 Pump Gradient Timetable he gradient Timetable contains 10 entries which are Tine N 5 o ow rion Pressure P1100 10 Pump External Event Timetable The Timetable contains 4 entries which are : i6at05a oe So3fk Si oSSnie St oo5xf Se oooSffif SoSiti oi P1100 Aucosampler Initial Conditions HBDreeanwt EspBteeeaoddn(utr/mmsin) i2009..100 r $hSEet= ios Simei 31 000131 _-- Tuning Method Report Page 1 Method: C: MASLIN FLUOROCHENS.PRO\ACQUDB\FLUOROCHEMS P--r_in--ted: Tue dar 303086108 2004 fe lu pp 30 80.00 : 460 | | DW aw 295.a 00 l DG hod SouRce (mse) CoCfaenpxeialploalrey 1 AfSoopxuearrpcvoeutreeBlo21ck Temp. Desoivation Temp. Set mank 233%.%00 2T.b93 al0.o0 03000 310002 Pressures AGansalydseellr vacuum Rdbk or26e6-3 Analyser i1T3EneRReerssay11 1 CEEoxnrittiriaenicoen iTIhznReReressg2y7 2 waltiplier Gas Flows Decsoneelvcaatsion Set Rank 111.600 3 6 2sh 2t1.e50.0o 00-695 Rabi s87i.6a 000132 QSutaadnytNiofiyLaC1a3l3i,bSraattioo:n03R2e6p0o4rAt CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheehan Page 1 CLaalsitbrmaotdiiofni:ed: P:W\eDdaMtaar\L3C1MS1M1S:75\2M:a1s4sl2y0n0z4\Fluorochass PRO\CurveDB\032604A CSR Solids Printed: Wed Maz 31 12:00:53 2004 Ames 033104 CC Gaoleifbo lrcaiteinm otn Tocfuhp rDvaeetT:eo rB1m8Pi0nF8aut6iO.o6nAn :+x0.+d 9398889.20936 | CRuersvpeontsypee:tyLpien:eaErx,tOormiaglin:StEdx,cAlruedea, Weighting: 1x, Axis trans: None ! 1.88e5, i | / i|i i | | i | / | J | 1| , | -_ | | |! | | | | 1 oo ~ 00 70 26 50 40 50 60 70 80 90 106" Exygen Research, 3056 Reseach Drive, State College, PA 16801 000133 -_-- QSutaundytNiof:y12S1a3m3p,leSetRNeop:or0t32604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheahan Page 1 LSaassptlemodLiifsite:d: WePd:\MDaarta\3L1CM1S1M:S475\:M4a1ss2l0y0n4x\Fluorochess.PRO\SampleDB\032604A CSR Solids MLeatshtodm:odified:P:T\ueDaMtaar\L3Q0HS0H8S:71\8M:a3s1sl2y0n0x4\Fluozochens. PRO\MethDB\PFOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 RDIaottmaei.DETERTGo -- small TNeaxste:: 032604A-101 *1: pron i} 032604-06.,2 ng/mL standard [013002.604A-101 Sm (Mn, 2x2) | bod a pi1c8s8 "31-Mar-20L04C0M2S:M0S1:#078, MRM of 1 Cha1nn3e>l E3S6-9| 3.A0r6ee4a Co i oll LTTE er ---- ee S en T Tim|e 200 Tso 400 500 600 700 800 Exygen Research, 3058 Research Drive, State College, PA 16801 000134 SQtuuadnytNiofryL2s1a33s,plSeetRNeop:o0r3t2604A CSR Solids, ExtData:03/26-29/04, Analyst A. Sheehan Page 2 LSaasmtplmeodLiifsti:ed: WePd:\MDaarta\31LOM1S1M:S475\:M4a1ss2l0y0n8x\Fluorochess.PRO\SaspleDB\032604A CSR Solids MLaatshtodm:odified: PTu7e\HDaazt3a0\0L:C18H:S3N1S270\04Masslynx\.FPlRuOMceztohOcBh\ePFnOsA non extract 032904 ob code: ePrr inted: r Wed Max 31 1--2:0--0:5--4 --200--4 ---------------------------------- aNaxsee: 032604A-102 ol [1c:03p2r6o0n4:5, 05 igi.standarda "31-Mar-200802:17 032604A-102 Sm (Mn, 2x2) so MRM of LCMSMS 1 Channel ES.| | Koy1 9435 a 413 6.>A63r068e94a | i | ole ren RE oe Time | L100 200 300 40 50 00 600 700 800 Exygen Research, 3058 Research Drive, State College, PA 16801 000135 StQuudaynNtoi:f1y21S3a3s,plSeetRNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheshan Page 3 LSaamsptlemodLiifsite:d: PW:e\dDaMtaar\L3C1MS1M1S:74\5M:a4s1sl2y0n0x4\Fluorochess. PRO\SaspleDB\032604A CSR Solids MLeatshtodm:odified: PT:u\eDaMtaar\L30SM0S87:\1M8a:s3s1ly2n0x0\4Fluorochens. PRO\MGthDB\PFOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2000 TNeaxmte:: 032604A-103 1:eEoR EE |1C032604-4, 1.0 ng/mL standard p0r3e2y604103 Sm (Mn, 2x2) i % _ 31-Mar-20L04C0M2S:M34S:40 14881927 MRM of 1 Cha4n1n3el>E3S6-9 1.2505 Area ookTi 200 300 400 50i0 600 7.070 800Time Exygen Research, 3058 Research Drive, State Collage, PA 16801 000136 QStuuadnytNiof:y12S1a3m3,plSeetRNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheehan Page 4 SLaamsptlemodLiifsti:ed: WePd:\MDaarta\3L1QM1S1M:S475\:M4a1ss2l0y0n4x\Fluorocheas.PRO\SazpleDB\032604A CSR Solids MeLatshtodm:odified: PT:u\eDaMtaar\L3Q0MS0M8S:T1\8M:a3s1s12y0n0x4\Fluorochens.PRO\MathDB\PFOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:5 2004 NTeaxmto:: 032604A-104 1; pron Co [C032604-23.,0ng/mLstandard 31-Mar-200402:51:34) 0130206.04A-104 Sm (Mn, 2x2) MRM of 1LCChaMnSneMlSE#S7-, 489 413> 369 | 36645 2.7265 | Area % | ook pe Time hee OO B0 P ABO SRO. I SOD Exygen Research, 3058 Research Drive, State College, PA 16801 000137 qQUoEmnmAetyy,Ssaapmpttee Sseeeprert en CER Solids, SxtDates03/26-29/08, Analyt A. Shashan J. gocgte ign: FoPataNRIN FSTT SRNTEATEATTSOAR Co S0338 Lore nE esties Sa L otashass. TechmaNTEon nom wesmace, 72508 prion | ok vn 38 sent 8200 we |C032604-2, 5.0 ng/mLstandard is1032604A-105 Sm (Mn, 2x2) | wl " 89299" i (0o TTTAG zn bo 400 500 | 600 31-Mar-2004 03:08:18 LCMSMS MRM of 1 Channel ES-| mies= 6.62e5, 700 80T0im"e Seygen Rasonseh, 2056 Reseach Drive, Stace Collage, BA 16801 000138 gSuUenDtAetSy ssIapieTMTEaCpEeCs Scoun con Soha, BxtDace:03/26-29/04, Anaiyet A. Sheshan op Fm surxplIe e LNiEste:E A:T y\oalR crLaasS\eymIte\eFEiLuucHcsroocSchhaem?nss.. FONSmpLeDB\GSEGD4A Go. Seis PROV tIOB\GRGA non excess 032600 Tr Ge (C032604-1,10.0 ng/mL standard 1032604A-106 Sm (Mn, 2x2) 100 |x ih 4.88 0- L T7TA00T2000 300 TT400 500 31-Mar-2004 03:25:09 LCMSMS #7 MRM of 1 Channel ES- ise| 413 > 369 Time | BBO 700800 Exygen Resenzch, S058 Rasaacch Drive, Siate College, TA 16603 000139 QSuant tifyLu2S1as3dp,lSeeyRtepooN 0r3t26o04A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheehan Page 7 TSaasmkplemodLiifsti:ed: WeP:d\DMaatra\3L1OM1S1M:S478\:M4a1sa2l0y0n4x\Fluorochass .PRO\SaspleDE\032604A CSR Solids NLoaatbshtocaom:doed:ified: T7u\aDaHaar\L3C0HE0M8S:1T8\:3H1a2s50s41yna\FLuPoRzOoMcthhDeB\sBsFO.A non extract. 032904 Printed: Wed vax 31 12:00:5 2008 NTaesxet:: 032604A-107 C 1: pron EEE _ aTMar-200403412 LCMSMS #7 1|00302,604A0-11207 Sm (Mn, 2x2) MRM of 1 Cha4nne1>e l 33s6 || aa 0p 550570905051 esze3! || [ lost R orAaR EzRrA raer zAe ist3o 4am IadaseosontaffipoiFgee Wy Wibadhaly 6827.w77in77g1Tron | Z ERO TE TT 300 400 soo soo 700 sboTim|e Exygen Research, 3058 Research Drive, Stata College, PA 16801 000140 QSutanatidfyySNaaopl!eS1eRte2poo10r3t326304,A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheehan Page 8 SLaasmtplemodLiifsti:ed: WePd:\MDaatra\3L1GM1S1M:S475\:M4a1ss2l0y0n4x\Flucrochess.PRO\SasplaDB\032604A CSR Solids MLaatshtodm:odified: PTu7e\MDaazt3a0\0L8C:1H8S:3M1S270\04Masslynx\.FPLRuOcHertoDcBh\PeFnOs non -rtract 032904 om Code: Printed: Wed Max 31 12:00:54 2004 NTaemxet:: 032604A-108 [R1:eapgreonntBlank JE |03to2o.6044041108 Sm (Mn, 2x2) i| 31-Mar-200i803:58:30 MRMor *C.hCMaSnMnSEeS#l; 131>.346094 | %*1| ! 70ugn 562,58"706008g 65: % g7 ! || 085 9% 15161 530 2s az a] ey, 188 |Lee T0T 0 72300 0 T0 aco S e G6O e 00 T 700 iBm0e0 Exygen Research, 3058 Research Drive, State College, PA 16801 000141 QS uantio eyL1s3ay 5mp,lSeatRo heop;o0r3t! 2604A CSR Solids, BxtDate:03/26-29/04, Analyst A. Shashan Page . i HTSaoarmttphlame:odLiifsti:ed: Last modified: WTFeuPAde:D\vvDaaaarrt\aL\3SC1L61HHEM40MS8EN5.TS1740M\.aW13pa1sse22sl60y00yn48xT\F\luoFroLchuesos..rPPRRoOO\\NcSaatshhpDleBa\DmBBF\sO0R32n6o0n4AeCxSaRctS:oli0d3s2904 Sonoda Printed: Wed Max 31 12:00:54 2004 NTamee: 032606A-105 3 R1eaprgoennStpAn,0g5lmlSE 4 [eo |032604A-109 Sm (Mn, 2x2) w | ]| [I -- [TTR TTE60 se SMar200 01D MSMS 1r%y MRMof 1 ChasnneSloerEneSe-ad | ado 50ETI 600i700sesi, oTo ime Exygun Research, 058 Research Drive, State Collage, PA 16801 000142 SQuatntiuy12s1ad3s3p,lySeetRNNeop:o0ro3t26!04 CSR Solids, BxtDate:03/26-29/04, Analyst A. SheahanPage 10 LSaasmtplmeodLiifsite:d:PW:e\DdatMaar\LC31MSH11S:?4\5M:a4s1sl2y0n0x4\Fluorochess. PRO\SaspleDB\032604A CSR Solid MTLaoatnshtcaom:doad:ified: Tu\e MDara3t0 a08\:1L8:3O1 H20S04MFlSuo7ro\chMassa.PsROa\HlatyhDnB\xPFO\A non extract 032504 Printed: Wed yar 31 12:00:54 2004 TNaamxee:: 032604A-110 [vReeagrent SpK B, 2.0 ng/mL i 1032604A-110 Sm (Mn, 2x2) 100, Ii # [I | F1-Mar-2004 04:31:53 LCMSMS #7 m- 08s - 23165 MRMof1 Channeles 413 > 36 Area 1] | ToTkTTTARG 366 G0 abo 500 w6e 00 760 800Time | Exygen Research, 3058 Research Drive, State College, PA 16801 000143 CquaSntiNfyosaTmplLSeetRoheep:1oGr3t326034A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheahanrage 11 oSSAarTmdEpelmenodLiifsite:d: Tame asdiiod: hW5BeeD:eda\mvtDaaasra)Lt210EaMsT\EhaL?inCseaHasSteVS2LS5yo0e?n8\\FlMuoarsocshlesys.nrFP\RROOFNWSMiaeusCpholDerBD\oBP\Rc0Oh32e6n0on4nsAexCtErRacSt.oli0d32s904 ot Printed: Wed Mar 31 12:00:54 2008 fNaomoed: 032600A-111 [LeLe2n43spk , 50 DF=giL, 100a Sr 2008Okay | 226| 1032604A-111 Sm (Mn, 2x2) 430%0 TTSalc LCMSMS `MRMof 1 Channel ES-| | pls %-| i L | de |TR THbo a0 aso s00. Gooe 760e anThi5 me | Sxygen Research, 3058 Research Drive, State Collage, BA 16801 000144 SQtuuadnytNiof:y12S1a3m3p,leSeRtNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheehanrage 12 LSaasmtplemodLiifsite:d: WePd:\DMaatra\3L1CM1S1M:S4T5\:M4a1ssl2y0n0x4\Fluorochens. PRO\SampleDB\032604A CSR Solids MaLatshtodm:odified: TPu:e\DMaatra\L3C0HS0H8S:71\8M:a3s1sL20y0n4x\Fluozocheas. PRO\MetRDB\PFOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 NTaomxet:. 032604A-112 1: pron I [L2133-1Spk C, 50 ng/mL,DF=10 01130206.014A-112 Sm (Mn, 2x2) | %* 190448860 FRELCMSMS # MRMof 1 Cha4n1n3e>l E3S6.9| 13A1r6ea6 | |[o Time || - 1.00 2.00 300 4.00 500 6.00 700 E00 xExgygen Research, 3058 Research Drive, Staattea CoClollelgeg,e, PA 16801 000145 QSuant tify1a3s1a3s5t p,lSeauRteNpooe 0r3t26!04A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 13 SLaasmtplemodLiifsti:ed: WePd:\MDaatra\3L1MS1M1S:?4\5M:a4s1sl2y0n4x\Fluorochens.PRO\SaspleDB\032604A CSR Solids NLJaaotsnhtocdom:doed:ified: TPu:e\DMaataz\L3G0HS0N8S:71\8M:a3s1sl2y0n0x4\Fluorochess. FROVethDB\PFOA non extract 032904 Printed: Wed Max 31 12:00:54 2004 Neaxmeo:: 032604A-113 11:C03p2r6o04n6; 0:2 ng/mLSsEtandard f1k 03260421113 Sm (Mn, 2x2) wo 00 4247 | od M2a 00405r 2208 MRM of 1LCChaMamSnnaMlS5. Yo`Aereqs |Foll \ a g = = T ir IT Time|| Exygen Research, 3059 Research Drive, State Coll=eoge, PA 16801 000146 QStuuadnytNiof:y1S2a1m3p3l,eSetRNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheshanrage 14 LSaasmtplmeodLiifsti:ed: WeP:d\DMaatra\3L1CM1S1M:S475\:M4a1ss2l0y0n4x\Fluorochess.PRO\SanpleDB\032604A CSR Solids MeLatshtodm:odified: 2T:u\eDMaatra3\0 L0O8:M1S8:M3S1 T2\00M4asslynx\F.PlRuO\oMretohcDBh\ePFnOsA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 NTaezxet:: 032604A-114 1: pron a Lil023123630-41A-,1D14F=S1m0(Mn, 2x2) Po a0; EE as.s 101805 I 31M-RMaMr-of201L0CC4haM0nS5n:eMl3S9E:S#0.72 136.>8326095 Area | | o"l i 100 200 300 "400" 560 600 700 Time 800 Exygen Research, 3058 Research Drive, State College, PA 16801 000147 QStuuadnytNiof:y12S1a3m3p,leSetRNeop:or0t32604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 15 LSaasmtplemodLiifsite:d: PW:e\dDaMtaar\L3O1MS1H1S:?4\5M:a4s1sl2y0n0x4\Fluorochems.PRO\SampleDB\032604A CSR Solids MeLtahsotdm:odified: TP:u\e MDara30t08a:18\:31Ll2y0Cn04x\MFluSorHochSens7.PR\O\MMetahDBs\PFsOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 NTaemxet:: 032604A-115 wePOR [L2133-1 Rep, DF=10 032604115 100. 5m ( a n , 222) | | 102448076 "31-Mar-200405:55:45 MRM of1LCChaMnSnaMlS 5#.7 4136.>53560:5 Area | he 10 200 300 400 - mee Tim|e 500 600 700 '800 Exygen Research, 3058 Research Drive, State College, PA 16801 000148 QSutanutidfyySNamopl!SeeLtReo2p:o10r3t326304,A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheahanPage 16 LSaasmtplmeodLiifsti:ed:P:W\eDdatMaa\rLC3M1SM1S17:\4M5a:s4s1ly2n0x0\8Fluorochass. PRO\SanplaDB\032604A CSR Solids MaLatshtodm:odified: TPue :Mar\30D08:a10M:t3a1ssaL20y0n\ 4x\FlLuorCochH ensS . FRMO\MS eEhD7B\P\FOA non extract 032904 Job Coda: Printed Wed Maz 31 12:00:5 2004 NTaamxee:: 032604A-116 [1L:21p3r3o-n2,DF=10"FE {032604A-116 Sm (Mn, 2x2) | 100- || % i | ool lL tbo 200 "F1-Ma}r-200406:12:32 LCMSMS #7 MRM of 1 Channel Lo] vhi r 41321>13665 Area| pes pe: err Time 300 40 ~50 00 60_0 "7pe 800 | Exvyggen Research, 3058 Research Drive, SSttaate Collegge,e, PA 16801 000149 SQutanutidcyySNamopl:See1tRNe2op:o10r3t326304,A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheahanPage 17 LSaasmtplmeodLiifsti:ed: WeP:d\DMaatra\3L1OM1S1H:S475\:M4a1ssl2y0n0x4\Fluorochess. PRO\SampleDB\032604A CSR Solids MLaatshtodm:odified: TPu:e\DMaatra\3L0QS0N8S:71\8M:a3s1s2Ly0n0x4\Flucrochans.PROMGLHDB\PFOA non extract 032904 Job Code: P-- rinted:_W-- ed Maz 3 1 12:00:-- 54 2004------.---- NTaaxste.: 032604A-117 [L1:213p3r-on3,DF=10 EE J [o0a026.04a-117 Sm (Mn, 2x2) 1 "31-Mar-200406:25; :12 Lemsins #7 7418680 MRM of 1 Cha4nn3e4>labE3eS6d-9) `Areal lw ls i i \ Lo MI ime 100 200 300 400 500 600 7.00 800 Exygen Research, 3058 Research Drive, State College, PA 16801 000150 _-- mm StQuuadnytNiof:y12S1a3m3p,leSeRteNpoo:r0t32604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheehanrage 18 SLaamsptlemodLiifsite:d: WePd:\MDaarta3\1LQS1H1:S475\:M4a1ss2l0y0n4x\Fluorochass.PRO\SazplaDB\032604A CSR Solids MLeatshtodm:odified: TPu:e\DMaatra\L3C0HS0M8S:71\8M:a3s1sL20y0n4x\Fluorochens. PRO\MethDB\PFOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 --rr -------------------------------------------------- NTaemxet:: 032604A-118 1: PFOA SE f[C032604-5, 0.5 ng/mL standard 032604A-118 Sm (Mn, 2x2) 488 joa: 9048 | | *| } 31-Mar-L2C0M0S4MS06:45#; MRM of 1 Cha4n1n3el>E3S6-9 6.264 Ared O I r A e Time | L10200 0 ~ 300 ~400 500 "600 "700 soo| Exygen Research, 3058 Research Drive, State College, PA 16801 000151 StQuuadnytNiof:yL2S1a3m3p,lSeetRNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheshanPage 19 SLaasstplmeodLiifsite:d: WeP:d\DMaatra\3L1CM1S1M:S4?5\:M4as1sl2y0n0x4\Fluorochens. PRO\SampleDB\032604A GSR Solids MLaatshtodm:odified: P Tue :Mar\30D08:a18M:t3a1ssaL20y0n\ 4x\FlLuorCochH ensS .PROH\MGStDBT\PF\OA non extract 032904 Job Coda: Printed: Wed Mar 31 12:00:54 2004 NTaemxet:: 032604A-119 1: pron EE } [L21334,DF=10 0e3a2s604A-119 Sm (Mn, 22) SIM LCMSMS 88 MRMof 1 Chann>el3E0S-0 11004| 15557 1.A0r7eea5l || | |Lo TR d TER abo i ar bo l soo e abo rho oorme Exygen Research, 3058 Research Drive, State College, PA 16801 000152 --_---- SQtuuadnytNiof:y12S1a3s3p,leSeRteNpoo:r0t32604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheshanPage 20 LSaasatplmeodLiifsti:ed: PW:e\dDaMtaar\L3Q1MS1H1S:74\5M:a4s1sl2y0n0x4\Fluorochens. FRO\SanpleDB\032604A CSR Solids MaLatshtodm:odified: Job Code: PTu:e\MDarat30a\0L8:M1S8:M3S1 T2\00M4azslynx\F.PlRuO\oMrGotDcBh\PeFnOsA non extract 032504 Pe rinted: s Wod Mar 31s 12:00:54 20e 04 re. NTeaxste:: 032604A-120 [211:33pr.o5n DF=10 EE |{(100302604A-120 Sm (Mn, 2x2) | |104 | %-|wi _ "31-Mar-2004 07:19:29 LCMSMS #7 224680702 MRM of 1 Cha4n1n3e>1l.5e346s0:6 Areal | Io L100 200 300"40 500 Time | 600 7.00 800 | Exygen Research, 3058 Research Drive, State College, PA 16801 000153 --_-------- StQuuadnytNiof:y12S1a3m3p,leSeRteNpoo:r0t32604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheahanPage 21 SLaassptlemodLiifsite:d: WePd:\MDaarta\3L1CM1S1M:S4?5\:M4a1ss2l0y0n4x\Fluorochess.PRO\SanpleDB\032604A CSR Solids MLaatshtodm:odified: Job Coda: TPu:e\MDaar t3a0\0L8:C1u8:S3M1S270\04MassLynx\.FBlROu\oMretohcDBh\ePFnOsA non extract 032904 P-- rrrinte-- d:---- -- We-- d -- Mar -- 31e1e2e:-- 0e0e:e54tt-- 2004 ---------------- NTaemxet:: 032604A-121 [1Z: psron Dri -- |0130206.010,4A-121 Sm (Mn, 2x2) | "31-Mar-20L04CM07S:3M6:S15#7 75478592 MRM of1 Channel ES:| 4134>.9366059 Areal |% 0 LT100 "200 Time 300 "400 500 600 700 $80} Exygen Research, 3058 Research Drive, State College, PA 16801 000154 --_--m QSuatnutidfyysNamopl:See1Rteo2p:o10r3t326304,A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheahanPage 22 MaSLaatsmhtpoldem:odLiifsite:d:P:W\ePDda:tM\aar\DLa3G1UtS1aH1S\:74L\5MQ:a4Ms1sS2LSy0n07x4\\FMluaozsoschlenysn..xPPRR\OOFM\SOlatumhpOolBar\DBoBF\cO0hA32e6nn0o4nsAexCtSrRacStoli03d2s904 L6abstcomdoad:ified: Tue Mar 30 08:18:31 2004 _Pr--intmed--: m-- Wed Maz 31 12:00:54 2004 NTaaxmees:: 032604A-122 Ef ss7,oreDF= t {0o3o260] 4A-122 Sm (Mn, 2x2) | MMaar.raLtCM0S7M535S0#s7 28482s3 MRM of 1 Cha4n1ne31l>77E3S06-50| reg | | 0- Ho 200 300 400 500ep 600 = 700n8ee00Time Exygen Research, 3058 Research Drive, State College, PA 16801 000155 QSuatnutidfyySNamoplrSeo1tRhe2op:o10r3t326304,A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 23 SLaasmtplmeodLiifsite:d: WeP:d\DMaatra\3L1OH1S1M:S475\:M4a1ssl2y0n0x4\Fluorochess. PRO\SazpleDB\032604A CSR Solids MLaatshtodm:odified: PTu7e\DMaataz\L3C0US0N8S:71\8M:a3s1sl2y0n0x4\Flucrochess. PROMthOB\PFOA non extract 032904 ob code: e Printt ed: ----Wed--Matz-- t3r1 e-- 12:0-- 0:54 -- 2004---------------------- NTeaxmte:: 032604A-123 Co328084,, 11.00gngm/mLL ssttaannddaarrd S{Nlaarr-200480:0097:49 J Lemos 47 rs |032604A-123 Sm (Mn, 2x2) 14687795 MRM of 1 Cha3nne1l>1E53S06-08| | Area | %| i LO 100 200 t 30 ~ 40 0e 0 ' 500 "60l 0 700 60Tim0e| Exygen Research, 3058 Reseach Drive, State Collage, PA 16801 000156 - P------ re oBceaieetheess P Bi e eiA n reomreT oeesrmeeetS seeor eo mreeme w eeee| ewssaeesces oe [2133-1 [| 100 | a| So 964395012 31-Mar-2004 08:26: LCMSMS 4135.>8386669] Are [ol --we L100 200 300 40 '50 00 660 700 800 | rvs Senco, 505 sane seve, Smt ovine, mn 2m 000157 ---- ee--------e ------------e ---------- SQtuuadnytNiof:y12S1a3z3p,leSetRNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 25 LSaasmtplmeodLiifsite:d: WePd:\DMaatra\3L1Qe1s1S:?4\5M:a4s1sl2y0n0x4\Fluorochens. PRO\SaspleDB\032604A CSR Solids MLaatshtodm:odified:P:T\ueDaMtaar\L3C0MS0M8S:71\0M:a3s1sL20y0n4x\Fluorochess . FRO\MOthOB\PFOA non extract 032904 Job Code: P-- rinted: Wed Max-- 31e12:e 00:54e2004 -- -------------- ---------- NTaxset: 032604125 1: pron EE |[L2133-1 Rep 1032604A-125 Sm (Mn, 2x2) 1| 10000 s44381966 31-Mar-20L0C40M8S:M43S:#374 MRM of 1 Cha1nn3e>l 3E0S0.| 5.`9A8re0a6l Lo L100 " - 200 300 400' 500 600 7.00 Time| 8b0 Exygen Research, 3058 Research Drive, State College, PA 16801 000158 gS uantt ify12su 1a3a3p,lSd eeRteopy :or0t32! 604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 26 SLaasmtplmeodLiifsti:ed: WePd:\MDaatra\3L1QS1H1S:T4\5M:a4s1sl2y0n0x4\Fluorochess. PRO\SampleDB\032604A CSR Solids NLTaaotsbhtcoom:doad:ified: PTu:e\MDaart3a0\0L8G:1H8S:3N1S276\08Nasslynx\F.PlRuOVoNratohcDBh\ePFnOsR non extract 032904 Printed: Wed Mar 31 12:00:54 2004 A Tot: -- een 2133.2 ||013002.604A-126 Sm (Mn, 2x2) C| w 254683953 31-Mar-2004 09:00: LCMSMS #7 MRM of 1 ChaWnn3e1>l.38E36S66-0) Areal i |_00TTTAe0 a0 seo abo y 500 G00 760 +baTimme.| Exygen Research, 3058 Research Drive, State CollegNe, TA 16801 000159 QSuEanRtiaeyysNamoplISeeLRteoep:o10r3t326504,A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 27 ZvSaaatmrhpoldem.odLiifsite:d:|Pv2:e\d\Doavnttaaar\\LL3C1HME1SM1S?:T4\3NW:aa4ss1asl2sy9yn0x8a\FFlLuuoorroocchhaessss. .FPRROO\\AStahzDplRe\DEBF\O0A32n6o0n4AexCtOrRacStoli0d32s904 TToosrt cmood:ified: Tue var 30 08:18:31 2004 erinted: Wed vax 31 12:00:54 2008 [ Tee: -- Cvreanss [[(0o3s26100) 4A-127 Sm (in, 232) %, F1Mar-20L04C0MS9iM7S0#37 Eaiss MRM of 1 Cha5 nneSlt5e60. Area | . Time 100 200 300 _ 400 500 600 70~0 80| 0 Exy-gen Ressaxch, 3056 Research Drive,Drive, StaSteate CollegCeol,lege, PA 16801 000160 SQutanutidfyySNasopli5ee1tRNe2op:o10r3t326304,A CSR Solids, ExtDate:03/26-29/04, Analyst A. Shashanrage 20 LSaasmtplmeodLiifsti:ed:P:W\eDdaMtaar\L3Q1SN1S17:\4M5a:s4s1ly2n0x0\8Fluorochess.PRO\SaspleDE\032604A CSR Solids VLaatshtodm:odified: PTu:e\DMaatar\L3C0HS0N8S:718\:M3a1sal2y0n04x\Fluozochess PROMathDB\PFOA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 TNaomxe:: 032604r-126 (1: 0pro3n 226.0n0g/4mL3st,andard_ 03"12006. 044128 Sm (Vin, 262) % oe 34697601 "31-Mar-20L0C40M9S:M33S:#571) MRM of 1 Cha4nn3e2>l3E3S6a:9| "are: olL L100 200300 " 400 _ 500 x- 600 700 Time | 800 Exygen Research, 3058 Research Drive, State College, PA 16801 000161 QSuenitiievy13S1aa35p,tySeaSnnaop:e6se5t26l04A COR Solids, TxtDate:03/26-29/04, Analyst A. SheahanPage 2 FoB ootesmTdtreieod:L : TBTeeeDaaarn SSoicosin oatpehimonni--Fluo--roch--ens.--FRO--VMGt--HOB--\PFO--R n--on e--xtra--ct. --032904 re Printed: Wed Mar 31 12:00:54 2008 LNaomra:i 0326008128 Geen (21334 100,(032604A-129 Sm (Mn, 2x2) | le re 31-Mar-2004 09:50:36/ LCMSMS #7 " 91 MRM of 1 Cha4n1n3el> E3S69-] Area lo*i L100 200 300 400 ~ 500 600 7.00 er T)mo 800 _ Exygen Ressszch, 3058 Research Drive, State College. BA 16601 000162 ------------------------------------ QSuatntuifdy ySaNspo,lSe:eRtLeop:2o0r13t263043 CSR Solids, ExtDate:03/26-29/04, Analyst A. SheehanPage 30 MLoSaatsmhtpoldem:odLiifsite:d:P:W\ePdD:\aDMtaaatr\aL\3GL1CSMH1SS1S:774\\5MM:aa4ss1ssll2yy0nn0xx4\\FFlluuoozroocchhaasnss.. PRO\SampleDB\032604A CSR Solids PROMethDB\BFOA non extract 032904 LJaosbtComdoed.ified: Tue Mar 30 08:16:31 2004 Printed: Wed Mar 31 12:00:54 2004 _-- NTaemxet:: 032604A-130 [2/iee1e 335 ||0310206.04A-130 Sm (Mn, 2:2) "31-Mar_-2004 10:07:21) MRMof 1LCChNaInSeMlS5#.7 2142985042 4131>.438679 Area | %- bo Lo 100 "200 300 "40 500 0 6b0 700 | Time 800 | Exygen Research, 3058 Research Drive, State College, PA 16801 000163 --_--m -- StQuudaynNtoi:f1y21s3a3s,plSeetRNeop:o0r3t2604A CSR Solids, ExtDate:03/26-29/04, Analyst A. Sheshanrage 31 LSaasmtplemodLiifsti:ed: WePd:\DMaatra\3L1CM1S1M:S475\:M4a1ssl2y0n0x4\Fluorochems. PRO\SasplaDB\032604A CSR Solids MeLatshtodm:odified: PTu:e\MDaart3a0\0L8:Q1i8:s3H1S270\04Mass1ynx\F.PlROu\oMrGtohcDBh\ePFnOsA non extract 032904 Job Code: Printed: Wed Mar 31 12:00:54 2004 -------------------------------------------------------- NTaemxet:: 032604A-131 iopeoR LI0232163043A6-131 Sm (Mn, 2x2) |"100. 31-Mar-20L0C41M0S:M24S:#017 490 MRM of 1 Cha4nne1>l 3E36S9.| 732340 5.`2A5ree6a |% | |L100 200 Time| 300 400 ' 500"600 700 8bo | Exygen Research, 3058 Research Drive, State College, PA 16801 000164 QSuatnutidfyySNamoplSree1Rteo2p:o10r3t326304,A CSR Solids, ExtDate:03/26-25/04, Analyst A. SheehanPage 32 SLaasmtplemodLiifsti:ed: PW:e\dDaMtaar\L3M1SM1S1?:\4M5a:s4s1ly2n0x04\Fluorochaas.PRO\SaspleDB\032604A CSR Solids MLaatshtodm:odified:P:T\uDeatMaa\rLG3U0SN0S8:71\6N:a3s1sl2y0n0x4\Fluorochess FRO\MAShDB\PFOA non extract 032904 305 Code: Printed: Wed Max 31 12:00:54 200 NToaxmto:: 03260eA-132 [2|1133e-r7o _ 0|" 3a2604A-132 Sm (Mn, 2x2) 251198035 1 "F1Mar-2008 10:41] :04 MRMof 1LCChMaenSn5eMlS0E#S07: 1.5706 weg `"oo| - Time | L100 200 300 400 ' 500 ' 600 700 "8b0 Exygen Research, 3058 Research Drive, State College, PA 16801 000165 QSuatnatidfyySNamopliSeaLtRNe2ep:o10r3t326304,A CSR Solids, BxtDate:03/26-29/04, Analyst A. Sheahanrage 33 VDSaaatmhtpoldme:odLiifsite:d: WPePd:-M\arD\a35tD1a1\:a4L5HM:a4tSs1sH2ySa0n0?x4\\\FMluaoLsroscChlaynsHn..xPPR\SROOFN\eSlHtaumhpDoSLBze\DPoB7F\cO0hR32en60on4nsAeCxStRracStoli0d32s504 TLoabatcomdoad:ified: Tua Har 30 08:18:31 204 Printed: Wed Mar 31 12:00:54 2008 TNeaxste:: 032604A-133 1: pron Co [co32604-2, 5.0 ng/mL standard 31-Mar-200410:57:53 0326047133 Sm (Mn, 2x2) MRMof 1LCChaMnSneMlSES#.7 ||1100,10, 848.89905 451 >.r3853 e60a95 |% o- Tho TTZ00 3b 40 500 600 700| 8boTim|e Exygen Research, 3058 Research Drive, State Colle"ge, PA 16801 000166 ree---------------------- StQuuadnytiioty12s1a3s3p,leSeRteop:or0t32604A CSR Solids, ExtDate:03/26-29/04, Analyst A. SheshanPage 3 NaLLStaaasshmttpoldmme:ooddLiiiffsiitee:dd::PTW:Pue\adDahb\ taaazr\L3D 3M01SM01Sa 817::\14M85Ha::tas34ss11slyya 22n50n0x0e44\\\ FFlluuooL rzoocchhGeessss..HPBRROOMS \eStaAsDM pBl\ePDES BO\A03.26n0o4nA exCtSrRacSt.ol0i3d2s504 Tob cada: e e Printer d: Wed vax 31 12:e 00:54 2006 r pNarseet: 032604A-13 f[3;Cp0ro3n260104.-0n1gl,mLstandardCo 032604A-134 Sm (Mn, 212) IIMaF20L0C4HM1S:M1S44#8 || 100 1745301 MRMof 1 Chan1n5eTl52E13S00.00 rea |% o L100 200 300 ~ 40 ' 50 00 "600 700 Time || 800 Exygen Research, 3050 Research Drive, State College, PA 16801 . 000167